WQ0011038_Regional Office Historical File Pre 2018 (5)

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Celanese
The chemistry inside innovatio6'
CERTIFIED MAIL -7013 6 i qQ oo 00 0
Return Receipt to Lawrence Wolnik
RECEIVELIf,NCc�EIVRiz Jt yr• May 22, 2020
Division of Water Resources
Non -Discharge Branch
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
MOORESVILLWQROS
E REGIONAL OFFICE
Subject: 2019 Biosolids Land Application Program Annual Report
CNA Holdings, Inc. — Permit #W00011038
Celanese Corporation
2525 Blacksburg Road
Grover, NC 28073-9641
www.celanese.com
►� ��i 2 6 2020
t)`P�lh "LI;TIJP�1
1N1F_0JiJ,1^,TOi`d PROCE33ING UNIT
CNA Holdings LLC., - Celanese — Shelby Plant in Grover, North Carolina did not remove nor
apply any biosolids during 2019. The site has not generated biosolids due to the closure of the
polymer operations. The enclosed one (1) copy of the facilities Residuals Land Application
Annual Report concerning our biosolid land application program consist of this letter attesting to
no activity in 2019 anda completed DENR Form ACF
CNA Holdings LLC — Celanese - Shelby Plant is committed to ensuring compliance with all County,
State, and Federal regulations. Should there be a need for further discussion, feel free to call me at
704-480-5728, or contact me via e-mail at [e-mail]
Sincerely,
Jr.
Lawrence WolnikY, Site Director
Attachment

ANNUAL LAND APPLICATION CERTIFICATION FORM
A,
WQ Permit#: W00011038 County:
Facility Name (as shown on permit):
Land Application Operator:
Cleveland County Year: 2019
CNA Holdings, Inc Celanese
N/A Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
® Yes El No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary.
Total number of application fields in thepermit:
Total number of fields utilized for land application during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres utilizes for land application during the year:
Part B - Annual Compiance Statement:
Facility was compliant during calendar year with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. ® Yes ® No.
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .I 105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
Lawrence Wolnik, Site Director Shelby
Permittee Name and Title (type or print)
AA ,2"�R WA -5-zUzo
ature of Permittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

g' RIWEIVEDINcDENR/DWR
MAR 15 2(119
�vc�Ros Celanese
MOORESVILLE REGIONAL OFFICE The Chemistry inside innovation -
Celanese Corporation
2525 Blacksburg Road
CERTIFIED MAIL 7018 0040 0000 4915 0663 Grover, NC 28073-9641
www.celanese.com
Return Receipt to Renee Culler
RECEIVEDII�ICDEQIDWR
March 1, 2019
MAR - 7 2019
Non -Discharge
Permitting Unit
Division of Water Resources.
Non -Discharge Branch R ®�7 !019
1617 Mail Service Center MA
Raleigh, North Carolina 27699-1617
n Tiny i a�l��jC�SSii�G U�lli
Subject: 2018 Biosolid9rLEd11Ap)r)m action Program Annual Report
CNA Holdings, Inc. — Permit #W00011038
CNA Holdings LLC., - Celanese — Shelby Plant in Grover, North Carolina did not remove nor
apply any biosolids during 2018. The site has not generated biosolids due to the closure of the
polymer operations. It is anticipated that land application may be many years out from this
submittal. The enclosed one (1) copy of the facilities Residuals Land Application Annual Report
concerning our biosolid land application program consist of this letter attesting to no activity in
2018 and a completed DENR Form ACF
CNA Holdings LLC — Celanese - Shelby Plant is committed to ensuring compliance with all County,
State, and Federal regulations. Should there be a need for further discussion, feel free to call me at
682-218-6043, or contact me via e-mail at renee.culler cD-celanese.com
Si cerely,
Re Iler
EHS Manager
Attachment

ANNUAL LAND APPLICATION CERTIFICATION FORM
Pcxmit#: WQ0011038 County: Cleveland Year:
2018
Facility Name (as shown on permit): C N A Holdings LLC - Ticona
Land Application Operator: n/a Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calendar year?
El Yes El No If No, skip Part A, and Part B and proceed to the certificatia ( UWsWQ W96
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A: MAR — 7 2019
Total amount of dry tons applied during the year for all application sites: 0
Total number of acres land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2018 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Resources.® Yes El No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Resources.
9. No contravention of Ground, Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Nicole B Coffee, Director Production
Permittee Name and Title (type or print)
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
Si nature of PermitW Date
Signature of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

r— — LW- —0 — d "&— - Ky i
ANNUAL LAND APPLICATION CERTIFICATION FORM
1
Permit#: WQ, 0I Y038 County: Cleveland Year: 2017
Facility Name (as shown on permit): C N A Holdings LLC - Ticona
Land Application Operator: n/a Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calendar year?
❑ Yes ® No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit: 13
Total number of fields land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2017 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water QLro =� o,e �g ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
FEB 5 2018
1. Only residuals approved for this permit were applied to the permitted sites. WQRos
2. Soil pH was adjusted as specified in the permit and lime was applied (if need&?Y %y11tgCRgq T$fTF
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.,
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Resources. r;=h/ D
9. No contravention of Ground Water Quality Standards occurred at a monitoring well Jla ations of
AIV
violations are attached to include appropriate actions and remediations. •1 2018
10. Vegetative cover as specified in the permit was maintained on this site and the cropsrppWffe removed
in accordance with the crop management plan. INPORM,4T10N PROCESSING UNIT
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Nicole B Coffee, Director Production
Permittee Name and Title (type or print)
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
J-aq—li
Signature of Perini Date
Signature of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0011038 County:
Facility Name (as shown on permit):
Land Application Operator:
Cleveland
Year: 2016
CNA Holdings, Inc - Ticona
EMA Resources Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
C Yes 21 No If No, skip Part A, and Part B and proceed to the certification. Aliud�v�
generated but not land applied, please attach an explanation on how the residuals were handled. 13 2017
Part A:
Total amount of dry tons applied during the year for all application sites: 1 0
Total number of acres land application occurred during the year77 0
Part B:
Facility was compliant during calendar year 2016 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. 21 Yes 0 No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if ne
least 6.0 or the limit specified in the permit. I
3. Annual soils analysis were performed on each site receiving residuals duri.r
r
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laYf
5. All other monitoring was performed in accordance with the permit and
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Rafael Gonzalez - Shelby Site Leader Jaj "� 2--3 —1 3
Permittee Name and Title (type or print) Signature of Permittee Date
2/2/2017
Signature of Preparer*
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
Date
Signature of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

PAT MCCRORY
NL;
LGovernorGovaor
ate.
m o DONALD R. VAN DER VAART
Secretar7,
Water kesowces S..JAY ZIMMERMAN
ENVIRONMENTAL QUALITY
Director
March 21, 2016
Ms. Pem. Carter, Senior Environmental. Engineer
CNA Holdings, Inc.- Celanese —Shelby Plant
2525 Blacksburg Road
Grover, North Carolina 28073
Subject: Acknowledgement of Receipt of the 2015 Annual Report
CNA Holdings, Inc. --Celanese — Shelby Plant
Permit No;: WQ0011038
Land Application of. Residuals
Cleveland. County
Dear Ms. Carter.:
The Mooresville Regional -Office (MRO) received and reviewed the 2015 Annual Report
for the above permit. The report reflects there was no land application of residuals.
conducted under this permit in 2015.
The MRO plans to conduct an on -site facility inspection within the calendar year;
however, if you have any immediate concerns or questions, please contact meat
mana.schutteAncdenr.00v or (704) 663A699.
Sincerely,
Maria Schutte, Environmental Specialist
Mooresville Regional Office
Water Quality, Regional Operations Section
Division of Water. Resources, N.CDEQ
CC: Rafael Gonzalez, Site Leader,. CNA Holdings (Email)
Brent Collins, EMA Resources (email)
Nathaniel Thornburg, LAU Compliance, CO -Raleigh (email) .
State of North Carolina Environmental Quality I Water Resources I Water Quality Regional Operations
Mooresville Regional Office) 610 East Center Avenue, Suite 3011 Mooresville, North Carolina 28115
704 663 1699

T/,6 " 6 -(F W"v
ANNUAL LAND APPLICATION CERTIFICATION FO
Permit#: WQ0011038 County:
Facility Name (as shown on permit):
Land Application Operator:
Cleveland
Year: 2015
CNA Holdings, Inc - Ticona
EMA Resources Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
® Yes 21 No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Part B:
Facility was compliant during calendar year 2015 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. 11 Yes ® No
If no please, provide a written description why the facility was not compliant, the dates, ahnd
F6��►�ENPIaWFt
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites. FEB 9 2016
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil p MR
least 6.0 or the limit.specified in the permit. i ONAL OFFICE
3. Annual soils analysis were performed on each site receiving residuals during the past year and three
(3) copies of laboratory results are attached. JAN •1; 9 1A
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached...;ro UTA
TOGS sZ),�
5. All other monitoring was performed in accordance with the permit and reported duririgg'red
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the ,crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Rafael Gonzalez - Shelby Site Leader 2V fil.J,
Permittee Name and Title (type or print) Sign ure of Permittee Date
Z�-Y
1/11/2016
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
" Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (5/2003)

Pat McCrory
Governor
L)r
AZ4J
NC®ENR
North Carolina. Department of Environment and Natural ResourceE
February 24, 2015
Ms. Pem Carter, Senior Environmental Engineer
CNA Holdings, Inc. — Celanese — Shelby Plant
2525 Blacksburg Road
Grover, North Carolina 28073
Dear Ms. Carter:
Donald van der Vaart
Secretary.
Subject: Acknowledgement of Receipt of the 2014 Annual Report
CNA Holdings, Inc. — Celanese — Shelby Plant
Permit No.: WQ0011038
Land Application of Residuals
Cleveland County
The Mooresville Regional Office (MRO) received and reviewed the 2014 Annual Report for the
above permit. The form submitted indicates there was no land application activity during 2014.
Please contact me at [phone], should you have any questions or concerns about this
permit
Sincerely,
Maria Schutte, Environmental Specialist
Mooresville Regional Office
Water Quality Regional Operations Section
Division of Water Resources, NCDENR
CC: Luis Mendoza, Site Leader, CNA Holdings (Email)
Ed Hardee, LAU Compliance, CO -Raleigh (Email)
Mooresville Regional Office
610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115
Phone: [phone] / Fax: [phone]/Customer Service 1-877-623-6748
Internet: www.ncdenr.gov
An Equal Opportunity 1 Affirmative Action Employer — Made in part by recycled paper

ANNUAL LAND APPLICATION CERTIFICATION FORM I Y
Permit#: WQ0011038 County: Cleveland Year:
Facility Name (as shown on permit): CNA Holdings, Inc - Celanese - She]
Land Application Operator: EMA Resources Inc. - Phone:
2014
Plant
336-751-1441
Land application of residual solids as allowed by the permit occurred during the past calenderyear?
RECEIVED
® Yes R1 No If No, skip Part A, and Part B and proceed to the certification. Als'o:;Aifrres1duals we e��tir
generated but not land applied, please attach an explanation on how the residuals were hand 2015
Part A: ii--
Total number of application fields in permit:I n .'3`PItl�_,,
I Total number of fields land application occurred during the year: I 0 I
Total amount of dry tons applied during the year for all application sites:. 0
Total number of acres land application occurred during the year: 0
Part B:
Facility was compliant during calendar year 2014 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. 0 Yes ® No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken. '
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to ache H of at
least 6.0 or the limit specified in the permit. F ��,�
3. Annual soils analysis were performed on each site receiving residuals during the past calen�aiar a��l�ree
(3) copies of laboratory results are attached. o% P''Q '?0/54. Annual TCLP analysis was performed and three (3) copies of certified laboratory results®d?ed.
5. All other monitoring was performed in accordance with the permit and reported during the ye uired
and three (3) copies of certified laboratory results are attached. 1,7-
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penaltie submi ing false information,
including the possibility of fines and imprisonment for know' violation ."
Luis Mendoza - Site Leader 1, ///'
Permittee Name and Title (type or print)
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r)
Signature of P'ermiftee Date
2/2/2015
Signature of Land Applier Date
(if different from Permittee and Preparer)
DENR FORM ACF (5/2003)

Pat McCrory
Governor
NC®ENRFILE
North Carolina Department of Environment and Natural Resources
Division of Water Resources
Thomas A. Reeder John Skvarla
Director
Ms. Pem Carter, Senior Environmental Engineer
CNA Holdings, Inc. - Ticona
2525 Blacksburg Road
Grover, North Carolina 28073
Dear Ms. Carter:
. Secretary
February 28, 2014
Subject: Acknowledgement of Receipt of the 2013 Annual Report
CNA Holdings, Inc. - Ticona. - Permit No.: WQ0011038
Land Application of Residuals
Cleveland County
The Mooresville Regional Office (MRO) received and reviewed the 2013 Annual Report
(AR) for the above permit. The form submitted indicates there was no land application activity
during 2013. The MRO plans to conduct an on-s'ite facility inspection within the calendar year;
however, if you have any immediate concerns or questions, please contact me at [phone].
Sincerely,
Maria Schulte
Environmental Specialist
cc: Luis Mendoza, Site Leader, Ticona (email)
Chonticha McDaniel, Residuals Management, CO-LAU (email)
Division of Water Resources I Water Quality Regional Operations Section I Mooresville Regional Office One
610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 R7 One
�+ �ll�a
Phone:: www.ncwater.org
. Fax: [phone] Customer Service: 1-877 623-6748 1lA�A®�����
Internet: wuvw.ncwater.org d�
An Equal Opportunity 1 Affirmative Action Employer

ANNUAL LAND APPLICATION CERTIFICATION FORM
Permit#: WQ0011038 County: Cleveland Year:
Facility Name (as shown on permit):
Land Application Operator:
2013
CNA Holdings, Inc - Ticona
EMA Resources Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
0 Yes R1 No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit:
13
Total number of fields land application occurred during the year:
Total amount of dry tons applied during the year for all application sites:
Total number of acres land application occurred during the year:
Part B:
Facility was compliant during calendar year 2013 with all conditions of the land-application-permiI
(including but not limited to items 1-12 below) issued by the Division of Water Quality',�•'_Rl_r i_,Nor;
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR. Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and relmediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant pen s for submitting false information,
including the possibility of fines and imprisonment for kn ing viola ons
Luis Mendoza - Site Leader ' th y
Permittee Name and Title (type or print) Si nature dMrrnittee Date
1/9/2014
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r)
DENR FORM ACF (5/2003)

J - 4
CERTIFIED MAIL 7005 3110 0004 3438 6627
Return Receipt to PEM Carter
Celanese
The chemistry inside innovation"
Celanese Corporation
2525 Blacksburg Road
Grover, NC 28073-9641
www.celanese.com
January 27, 2014
PEMC14:03
North Carolina Dept of Environmental and Nat. Resources- DWQ
Aquifer Protection Service
1636 Mail Service Center
Raleigh, North Carolina 27699-1636
Subject: 2013 Biosolids Land Application Program Annual Report
CNA Holdings. Inc. — Permit #WQ0011038
CNA Holdings, Inc., - TICONA in Grover, North Carolina did not remove nor apply any biosolids
during 2013. The enclosed three (3) copies of the facilities Residuals Land Application Annual
Report concerning our biosolids land application program consist of this letter attesting to no
activity in 2013 and a completed DENR Form ACF
CNA Holdings, Inc — Shelby Facilty is committed to ensuring compliance with all County, State, and
Federal regulations. Should there be a need for further discussion, feel free to call me at 704/472-
4700, or contact me via e-mail at pem.carterO-)ticona.com
Since ely,
PEM Carter
Senior Environmental Engineer
1pemc
Attachment
JAN 31 2014
Water Quality
prrming section

PUM 8 P From
gn .4 -Y
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iLL
NCDENR
North Carolina Department of Environment and Natural Resources
Division of Water Quality
Pat McCrory Thomas A. Reeder
John Skvarla
Governor Acting Director
Secretary
July 2, 2013
Ms. Pem Carter, Senior Environmental Engineer
CNA Holdings, Inc. - Ticona
2525 Blacksburg Road
Grover, North Carolina 28073
Subject: Acknowledgement of Receipt of the 2012 Annual Report
CNA Holdings, Inc. - Ticona - Permit No.: WQ0011038
Land Application of Residuals
Cleveland County
Dear Ms. Carter:
The Mooresville Regional Office (MRO) received and reviewed the 2012 Annual Report
(AR) for the above permit. The form submitted indicates there was no land application activity
during 2012. The MRO plans to conduct an on -site facility inspection within the calendar year;
however, if you have any immediate concerns or questions, please contact me at [phone].
Sincerely,
Maria Schutte
Environmental Specialist
cc: Luis Mendoza, Site Leader, Ticona (email)
Chonticha McDaniel, Residuals Management, CO-LAU (email)
Division of Water Quality 1 Aquifer Protection Section I Mooresville Regional Office One
610 East Center Avenue, Suite 301, Mooresville, North Carolina 28115 NorthCarOlina
Phone: [phone] Fax: [phone] Customer Service: 1-877-623-6748 ���������
Internet: www.ncwaterquality.org
An Equal Opportunity 1 Affirmative Action Employer

IL ALN1N UAL LA1NL A rrUIUA IU.N UEKIIVI :A11UlN V*,UKM
Permit#: WQ0011038 County: Cleveland Year: 2012
Facility Name (as shown on permit): CNA Holdings, Inc - Ticona
Land Application Operator: EMA Resources Inc. Phone: [phone]
Land application of residual solids as allowed by the permit occurred during the past calender year?
❑ Yes p No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A:
Total number of application fields in permit: ` < `=13'-
Total number of fields land application occurred during the year: k
Total .amount of dry tons applied during the year for all application sites: �" -
Total number of acres land application occurred during the year:
Part B:
L��,_
Facility was compliant during calendar year 2012 with all conditions of the land application permit
(including but not limited to items 1-12 below) issued by the Division of Water Quality. El Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain
corrective action taken.
1.Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at
least 6.0 or the limit specified in the permit.
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three
(3) copies of laboratory results are attached.
4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required
and three (3) copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the
Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were
complied with (applicable to 40 CFR Part 503 regulated facilities).
8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation,
prior authorization was received from the Division of Water Quality.
9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of
violations are attached to include appropriate actions and remediations.
10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed
in accordance with the crop management plan.
11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
12. All buffer requirements as specified on the permit were maintained during each application of residuals.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowmi
Luis Mendoza. - Site Leader ih--I' oi3
Permittee Name and Title (type or print) Signature of Perm/ ttee Date
RECEIVEDIDENPOK -d- 1/8/2013
Signature of Preparer* AD&B 2013 Signature of Land Applier
(if different from Permittee) fferent from Permittee and Preparer)
* Preparer is defined ir('40 CFR Part 503.9 (Aquifer ProtedOn S@l
Date
DENR FORM ACF (5/2003)

N
CERTIFIED MAIL 7007 2680 0003 1602 1047
Return Receipt to PEM Carter
January 25, 2013
PEMC13:01
North Carolina Dept of Environmental and Nat. Resources- DWQ
Aquifer Protection Service
1636 Mail Service Center
Raleigh, North Carolina 27699-1636
Ticona
2525 Blacksburg Road
Grover, NC 28073-9641
Carolina Star Worksite
ISO9001, ISO/TS 16949,
ISO 17025, and ISO 14001
Subject: 2012 Biosolids Land Application Program Annual Report
CNA Holdings, Inc. — Permit #W00011038
CNA Holdings, Inc., - TICONA in Grover., North Carolina did not remove nor apply any biosolids
during 2012. The enclosed three (3) copies of the facilities Residuals Land Application Annual
Report concerning our biosolids land application program consist of this letter attesting to no
activity in 2012 and a completed DENR Form ACF. No land application operator was identified
during 2012, due to no activity which was directly related to the closure/reduction of the Polymer
manufacturer unit.
CNA Holdings, Inc — TICONA is committed to ensuring compliance with all County, State, and
Federal regulations. Should there be a need for further discussion, feel free to call me at 704/472-
4700, or contact me via e-mail at [e-mail]
Sincerely,
C�— e"x'
PEM Carter
Senior Environmental Engineer
\pemc
Attachment
RECEIVERENRIDWQ
JAN 2 8 2013
Aquifer Protection Section
Celanese
Ticona
A business of Celanese