WQ0011038_Regional Office Historical File Pre 2018

RMENR
Nod Carolina.D­epartment'of Environt"ent and Natural Resources
Pat McCrory
Governor
Luis Mendoza - Site Leader
CNA,Holdings Inc. Celanese Shelby Plant
252,5 Blacksburg Road
Shelby, NC 28073
Dear Mr. Mendoza:,
John E, Skvarlj, III
Secretary`
Ddcember'19, 2014:
Subject: Permit No. WQ00110.38
,CNA Holdings Ino.,
Land Application of'gesidu4I Solids (503 Exempt}
Cleveland County,
In accordance." with your permit renewal "request received October '28, 2014, , 9
we are forwardin''
herewith Permit,N6. "0.110,38 dated Ded..embef. '19,2014, to, CNA Hdldings'In for the continued,
operation of the
stibippt residuals -management program. Please- note that this renewed permit shall
become effective on May 1, 2015 (i.e., -the day after f ter the expiration date :of the existing ing permit), "which
differs from the date of this letter..
This permit `shall- be, effective from May. 1, 2615, until April 30,. 2020,, shall void. Permit NO,
WQ00.11.038, issued "May 3, 2006 and shall be subject. to the conditions and limitations as- specified
therein.. Please pay, particular attention to the monitoring requirements listed in Attachments A and C for
they may, differ from the previous permit issuance. Pailure to establish an adequ
' - . I , '. ate system for collectina
and, mainiaining.tlie r�qpiredoperationdl information shall result in future; compliance problems:
Please note, "that on September 1, QW, North Carolina Administrative Code. Title 15A
o
Subchapter 02T - Waste.Discthe ­., nIot , Disc
harged to Surface Waters was adopted,. Ad(ofdingly; this permit
incorporates e requirements 'of these rules, 'therefore, Please take 11 the time to review
06roughly. The following conditio.ns have beonAdded.modified or deleted,from. th -in.t' ose he last permit
issuance;
L Condition 1.2 and 11113 .- Within 90 - days, of this permit taking effect, the, Perinfitee, shall
begin notilNing theRpgional Office in Fayetteville of each land application.
2., Condition-1.3 and 'HI. 13: Within 186 days oft.his permit taking effect, the Pennittee, shall
place, signs in locations where r dlsiduA4,dre land applied.
3.1 Condition .,11-5:_ Ceiling Concentrations and Cumulative Pollutant Loading Rates- are
established for various metals.
4. Condindittion, I1.9':'APPlication site boundaries of residualsareto be clearly marked.
'
5. Co d o
ion,11.10-Similar to Condition H.13 of 2006 t, but establishes diff6reni: -set of
Procedures for calculating agronomic rates..
6. Condition 11. 11,: .'Nitrogen' application rates to areas grazed pasture to be reduced 25%.
7. Condition ,1113:.-Minimum Sodium Adsorption., Ratio (SAR) required for. additional 'step
before land app,lication allowed iricreased from 5 to 10.
8, Condition 111.2:. Regional office to be inf6rmed 48 hours prior. tb -application of residuals,
to new site. Previously, was -24 hours.
Non -Discharge, Perrnitting Unit
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Rhone*191007-6413CIntemet ht:1j6ortal.ncdenr.org1webMd
An Equal Oppmtunity AFn rmative &fioh Frnplopr - Madb:in partwith fie6yqlad paper

P'r1i..I:nis_Mendoza ;
December 19, 2014
Page 2.of 2
9. Condition IHA: Operations and Maintenance (O&M) Plan to be established.
10. Condition I1L 1 f a-b, h-1: Conditions under which residuals shall riot. be applied.,
11..Condition I1I.12: Public access restrictions different than. those in Condition 11.26 of,2006
permit.
12. Condition 111.15: Nutrient Management Plan corresponds to that in Condition II.11 of 'the
2006 permit, but requirements: have changed.
13. Condition 1V.6 Laboratory parameter analyses of residuals provision corresponds to
Condition 111.5 of 2006 permit, but administrative code has changed.
14. Condition IV.7.d, g, and j: New requirements for records kept on land application of
residuals.
15, ConditionV.1: Requirement for adequate maintenance,
16. Condition VIA: Perrnit may be revoked or modified upon 60-days' notice.
1.7. Condition VI.7: Expansion of facility shall not be granted if Permittee is in violation of
requirements of 15A NCAC 02T ;0120(b).
18. Condition VI.8: Annual fees payment corresponds to Condition VIA of 2000 permit, but
administrative code has changed.
Please' note that on September 1, 2606, North Carolina Administrative Code Title 15A
Subchapter 02T — Waste not Discharged to Surface Waters was adopted. The previous permit, was issued
before this date. Accordingly, this permit,incorporates the requirements of these rules which are reflected
in the .changes listed above.
'If any parts, requirements or limitations contained in this permit are unacceptable, the Permittee
has the right to request an adjudicatory hearing upon written request within 30' days following receipt of
this permit. This request shall be in the form of a written petition, conforming to Chapter 150B of the
North Carolina General Statutes, and ,filed with the Office of Administrative Hearings at 6114 Mail
ServiceCenter, Raleigh, NC 27699-6714. Unless such demands are made, this permit shall be final and
binding..
,If any parts, requirements or limitations contained in this permit are unacceptable, the Permittee
has the right to request an adjudicatory hearing upon written request within 30 days following receipt of
this permit. This request shall be in the form of a written petition, conforming to Chapter 150E of the
North Carolina General Statutes, and filed with the. Office of Administrative Hearings at 6714 Mail
Service Center, Raleigh, NC 27699-6714. Unless such demands are made, this permit shall be final and
binding.
If you need additional information concerning, this matter, please contact Troy Doby at (919) 807-
6336 or [e-mail].
Sincerely,
homaa ceder Director
Division of Water Resources
cc: Cleveland.County Health Departirient([e-mail]►) (Electronic Copy)
Mooresville Regional Office, Water Quality Regional Operations Section (Electronic Copy)
Beth Buffington — Protection and Enforcement Branch (Electronic Copy)
Digital Permit Archive (Electronic Copy)
Central Files

NORTHCAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
-DEPARTMENT OFINVIRONMENT AND NATURAL RESOURCES
.._
RALEIGH.
LAND APPLICATION OF RESIDUAL SOLIDS (503 EXEMPT) PERMIT
In accordance-wi
-ith the Prcivisidns'bf Axtick 21 of Chapter '143, General, Statutes of.North,Car.olina as
amended, and other applicable Laws, Rules, and Regplations
PERMISSION IS HEREBY GRANTED TO
CNA, Holdings, Inc.
Cleveland County,
FORMIE
continued operation of a residuals. management prf6gr4ni for CNA Holdings, Inc. and consistin the,
land application of residual solids (503.exempt) generated from treating ereating engine' I 'g, of red resin waste ,products
(98,60/6) and domestic wastewater (1,.4%) by the approved fAcilities. listed in Attachment A to the
approved sites, listed, in Attachment. B With no, discharge of was
tes. to surface waters, pursuant to_ the
application received October 28,, 2014, and in conformity with' other supporting data subsequently, file d
,and approved by -,the Department of EnVitombeht'and Natural Resource I s I and . considered a part of this
permit. The. Use an f -Part
:and residuals are regulated under Title 40 Code Federal Regulations
.257. This permit does not exempt the,Permiftoe from d(iniPlykig with the federal I , ati' regu ons.
This permit
t shall be effective.from May 1, 2015, until.April 30j 2020 shall void Permit No. WQ001 1038
issued May 3,2006, and shall be, subject 1to "the following specified cdnditidhsand limitations:
I. SCHEDULES'
No later than six months prior to. the.expiratioh of thispermit;the Permittee all - sh , request renewal of
this permit on official -Division forms. Q of the reqqest, the:'Division. ,review the
Upon receipt Aill will
of the,,fki.lities described therein, and if warranted,'Will renew the permit for such period of
time and under such conditions and limitations as. it may deem appropriate. Please note IKOW 15A.
NC
C.AC 02T .005(d)­tequires an updated site map to be submitted with. the , permit. renewal
application.
2
The Permitt6e shall be in Aill compliance with the,, regional, -offce notification requirements
established in Condition IH.3., within 90 days Of the effective date of this permit..
3, The Permittee shall be in full compliance with the signa gp requirements established, in Condition
111. 11 within, 180 days of the effective date of this permit.
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H. PERFORMANCE STANDARDS
1. The subject residuals management program shall be effectively maintained and operated at all times
so there is no discharge to surface waters, nor any contravention of groundwater or surface water
standards. In the event: the facilities fail to perform satisfactorily, including the creation of nuisance
conditions due to improper operation and maintenance, the Permittee shall immediately cease land
applying residuals to .the site, contact the Mooresville regional office supervisor, and take .any
immediate corrective actions.
2 This permit shall not relieve. the .Permittee of their responsibility for damages to groundwater or
surface water resulting from the operation of this residuals management program.
3. Only residuals, generated by the facilities listed in.Attachment A are approved for land application in
accordance with this permit.
4. Only the sites listed in.Attachment Bare approved for residuals land application.
5. Pollutant concentrations in residuals applied to land application. sites listed in Attachment B shall not
exceed the. following Ceiling Concentrations (i.e., dry weight basis) or Cumulative Pollutant
Loading states (CPLRs):
Parameter
Ceiling Concentration
(milligrams per kilogram)
CPLR
(pounds per acre)
Arsenic
75
36
Cadmium
85
34
Copper
4,300
1,338
Lead
840
267
.Mercury
57
15
Molybdenum
75
n/a
Nickel
420
374
Selenium
100
89
Zinc
7,500
2,498
The Permittee shall determine compliance with the CPLRs using one ofthe following methods:
a. By calculating the ekisting cumulative level of pollutants using actual, analytical data from all
historical land application events of residuals, or
b. For land where residuals application have not occurred or for which the required data is
incomplete, by determining background' concentrations through representative soil sampling:
6. Residuals that are land applied shall meet Class B pathogen reduction requirements in 15A NCAC
02T .1106 (a) and (c). 'Exceptions to this requirement shall be specified in Attachment A.
7. Biological residuals (i.e. 'residuals generated during the treatment of domestic or animal processing
wastewater, or the biological treatment of industrial wastewater, and as identified in Attachment A):
that are land applied shall meet one of the vector attraction reduction alternatives in 1.5A NCAC 02T
.1107(a). Exceptions to this requirement shall be- specified in Attachment A.
8: When land applying residuals to any land application site, the following buffer zones shall be maintained at
all times:
a. 400 feet from residences or places of public assembly under separate ownership for surface application
methods; however, the buffer zone requirement, may be reduced to, a minimum of 100 feet upon written
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consent ;of the owner :and approval :from .the Aquifer Protection Section of the appropriate Division's
regional-offfce:in Attachment B ofthispermit;
b. 200, feet from residences or places of public" assembly under separate ownership for subsurface
application methods; however, the buffer zone, requirement.may be reduced to a minimum of 160 feet
upon written consent of the owner and approval from the Aquifer Protection Section of theAppropriate
Division's regional office in Attachment B of this permit;
c. 100 feet from any public or private water supply source, waters classified as SA or SB, and.atiy Class I or.
Class H impounded reservoir used as a source of drinking water_for both.methods
d. 100, feet from any streams classified as WS or B, any other stream, .canal; marsh or coastal waters and any
other,lake or impoundment for.surface application;
e. 50 feet from any streams classified as WS or B, any other stream, canal, marsh or coastal waters and any
other, lake or impoundment for subsurface application;
f. SO feet from property lines.for both surface and subsurface, application methods;:
g. 50 feet from public right of ways for both surface and subsurface application methods;
h. '10 .feet from upslope interceptor drains, and surface water diversions, for both surface: and subsurface
application methods; and
i, 25 feet from downslope interceptor drains; surface water diversions, .groundwater drainage systems, and
surface drainage.ditches.for both, surface and subsurface'application methods.
Some of the; buffers specified, above may not have been included in, previous permits for this residuals
land application program. However, any eland application sites' that are listed in .the .most recently
any Attachment B of this permit, but. were approved with different buffers shah be reflagged. to
complywith these buffers.
9 Land. application areas shall be clearly marked .on each site .prior to and during any residuals
application event:
10., Bulk residuals and other sources of Plant. Available Nitrogen. (PAN) shall not. be applied in
exceedance of agronomic rates: Appropriate agronomic rates shall'be calculated using expected
nitrogen requirements based 'on the, determined Realistic. Yield Expectations (RYE) using any of the
following methods:.
a. Division's pre -approved site specific historical data for specific crop or soil types by calculating
the. mean of the bestthree yields of the last five consecutive crop .harvests for each field.
b. North Carolina Historical ,,Data for specific' crop and' soil types as provided 'by North Carolina
State University Department of Soil Science (http:/inutrierits:soil:ncsu:eduiyields/index php).
A copy shall be kept on file and reprinted every five years in accordance with Condition IV:6.
c: If the.RYE cannot be determined using methods -(a) or (li) above, the Permittee may use the;RYE
and appropriate nutrient application" rates reported in any of the following documents:
i. Crop management plan as outlined by. the local Cooperative -Extension Office, the North
Carolina Department of Agriculture and Consumer- Services, the, Natural Resource
Conservation Service, or other agronomist,
ii. Waste Utilization Plan, as outlined by the Senate Bill.,1217 Interagency Group -'Guidance
Document: Chapter l
(litfio:I/www.n6agr.gov/SWC/tech/documents/9th Guidance Doc 100109 pdf).
iii. Certified Nutrient Management Plan :as outlined by the Natural Resources Conservation
Services (NRCS). These plans "must meet the USDA -MRCS 590 'Nutrierit. Management
Standards(b:/,ftp=fc,se,egov.usda.gov/NHQ�ractice-standards/standardsi590pdf).
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d.- If the RYE and appropriate nutrient application rates cannot be determined, the Permittee shall
contact the Division to determine necessary action.
11. When residuals are land applied to grazed pasture, hay crop realistic nitrogen rate shall be reduced by
25%, in accordance with the USDA NRCS 590 Nutrient, Management Standards.
12. If land application sites are to be over -seeded or double -cropped (e.g., bermuda grass in the summer
and rye grass in "the winter with both crops to receive residuals), then the second crop can receive; an,
application of PAN at a rate not to exceed 50 pounds per acre per year (lbs/ae/yr). This practice may
be allowed as long as the second crop is to be harvested or grazed. If the second crop is to be planted
for erosion control only and is to be tilled into the, soil, then no .additional PAN shall be applied.
13. Prior to land application of residuals containing a sodium adsorption ratio (SAR) of 10 or higher, the
Permittee shall obtain and implement recommendations. from at least one of the following: the local
Cooperative Extension Office; the Department of Agriculture and Consumer Services; the Natural
Resource Conservation Service; .a North Carolina Licensed Soil Scientist; or an agronomist. The
recommendations shall address the sodium application rate, soil amendments (e.g., gypsum, etc.); or a
mechanism for maintaining site integrity and conditions conducive to crop growth. The Permittee
shall maintain written. records of these recommendations and details ;of their implementation.
14. The compliance boundary for residual land application sites shall be specified in accordance with
15.A. NCAC 02L .0107(b). These sites were individually permitted on or after December 30, 1983;
therefore, the compliance boundary is established at either 250 feet from the residual land application
area, or 50 feet within the property boundary, whichever is closest to the residual land application
area. An exceedance.of groundwater standards at or beyond the compliance boundary is subject to
remediation action according to 15A NCAC 02L .0106(d)(2) as well as enforcement actions in
accordance with North Carolina General Statute 143-215.6A through 143-215.6C. Any approved
relocation of the COMPLIANCE, BOUNDARY will be noted in Attachment B.
15. In accordance with 15A NCAC 02L .0108, the review boundary shalt be established midway between
the compliance boundary and the residual land application area. Any exceedance of groundwater
standards at the review boundary, shall require action in accordance with 15A NCAC 02L .0106.
M. OPERATION AND. MAINTENANCE REQUIREMENTS
The residuals management program shall be properly maintained "and operated at all times. The
program shall be effectively maintained and operated as a non: discharge system to prevent any
contravention of surface water or groundwater standards.
2. The Mooresville Regional Office, telephone number [phone], and the appropriate local
government official (i.e., county manager, city manager, or health director) shall be notified at least
48 hours prior to the initial residuals land application to any new land application site. Notification to
the regional supervisor shall be made from 8:00 a.m. until 5:00 p.m. on Monday through Friday,
excluding State Holidays.
3. The Mooresville Regional Office shall be notified via.email or telephone, [phone], at least 24
hours prior to conducting any land application activity. Such notification shall indicate, at a
minimum, the anticipated application times, field IDs, and location of land application activities. If it
becomes necessary to apply to additional fields due to unforeseen events, the Regional Office shall be
notified prior to commencing the application to those fields.
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4.. The Permittee. shall .main ain an approved Operation and Maintenance Plan (O&M Plan) pursuant to
1: SA N6AC 02T .1110. Modifications to the O&M: Plan shall,be thbapproved by. ,Division prior.
utilization of the new� lap,_. The O&M Plan, q_ihd minimum, shall include:
PAP .0 . u
a) Operational fundtidris;
b) Maintenance schedules,
') c S.4f ety, in ,easures;
d) Spill response.,plan,
e Inspection plan.includinthe.following information:
L Names and/or, titles of personnel responsible for conducting the inspections;
ii. Frequency and location. of inspections,
I including those to be'conducted "by the ORC, and
,
procedures to assure that the selected location(s) and inspection frequency are representative
of the residuals management ' program;
iii. betaileO description of inspection proce4ures. including record keeping and actions to be
taken by the inspector in the. event that. noncompliana.6, is observed ,pursuant to 'the
noncompliance notiftcationrequirementsOfiderthe .monitoring and reportingsection of thepermit,,
Sampling and monitoring plan including the following information-
i. Names and/or titles: of personnel responsible for, conducting the sampling and'pp4itorm'
g;
ii. aetailed description.of monitoring procedures including parameters to be. monitored;
,HL Sampling frequency and procedures to assure that representative samples are being collected.
Fluctilatio n in temperature, flow, and other.o erafing conditions -can. aff'60-thp quAlity of the -fesidwils,gathered dufinig a particular
sampling event. The., sampling plan shall ac*co'unt,.fbr
any foreseen. 'fluctuations in -residuals quality and indicate the most limiting times for
residuals to meet pathogen and vector attraction reduction requirements (e.g. fA&ilities that
land -apply multiple times
per yearbqt,ha*e an annual sampling frequency, may need to
sample. during Winter months: when :pathogen reduction 'is most, likely to be negatively
affected by cold temperatures).
5. Upon the, Water Pollution Control -System 'Operators Certification Commission's. (W PQSQCC)
classification of, the, facility, the P'ermittee shall designate and emp
loy a, certified' operator in
responsible charge (ORC) .and one or more certified operators asback-up ORCs in accordance with
'
15A 14C ' AC'08 ' 0 ' 020 1. The ORC or their back-up, shall visit the facilities in accord . anqP with 1 5A
N.CAC, 08G. 0204, or as specified in the most recently approved O&M plan, (i.e., see, Condition III.
4.), and shall comply with. 'all other conditions of 15A,NCAC 08G. 0204: For more information
regarding classification and designation requirements, please -contact, the Division of Water
Resources,' Technical Assistance & Certification. Unit. at [phone].
6,. When the Permittee land "applies 'bulk residuals, a copy of this permit'and a copy of O&M,Plah sWl,
be maintained at the land application sites during land. application, activities.
7. When the Termittee transports .or land applies bulk residuals.. the :,spi.11 control I provisions shall be
maintained mall residuals transport and application vehicles.
'9. Residuals shall not be stotedatany. land application site,, unless written approval has been requested.
and received from the Division.
9. When the Permittee land applies bulk residuals, adequate measures shall be taken to prevent wind
erosion and surface -runoff from conveying residuals from the land application sites onto adjacent
prppqqies-,or'irito surface waters.
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10. When the Permittee land applies bulk residuals, a suitable vegetative cover shall be maintained on
land application sites onto which residuals are applied, or application shall be in accordance with the
crop management plan outlined by the local Cooperative Extension Office, the Department of
Agriculture' and Consumer Services, the NaturalResource Conservation Service, or an agronomist
and as approved by the Division.
11. Bulk residuals shall not be land applied under the following conditions:
a. If the residuals are likely to adversely, .affect a threatened or endangered species listed under
section 4 of the Endangered Species Act or its designated critical habitat;
b. If the application causes prolonged nuisance conditions;
c. If the land fails to assimilate the bulk residuals or the application causes .the contravention of
surface water or groundwater standards;
d. If the land is flooded, frozen or snow-covered, or is otherwise in a condition such that runoff of
the residuals would occur;
e. Within.the 1.00-year flood elevation, unless the bulk residuals. are injected or incorporatedwithin
a 24-hour period following a residuals land application event;
f. .During a measurable precipitation event (i.e., greater than 0.01 inch per hour), or within 24 hours
following a rainfall, event of 0.5 inches pr greater in a 24-hour period;
g. If the slope is greater than.10% for surface applied liquid residuals, or if the slope is greater than
18% for injected or incorporated bulk liquid residuals;
h. If the soil pH is not maintained at 6.0 or greater, unless sufficient amounts of lime are applied to
achieve a final soil pH of at least 6.0, or if an agronomist provides information indicating that the
pH of the soil, residuals and lime mixture is suitable for the specified, crop. Any approved
variations to the acceptable soil pH (6.0) will be noted in this permit;
is If the land does not have an established vegetative cover unless the residuals are incorporated or
injected within a 24-hour period following a residuals land application event. Any field that is in.
a USDA no -till program shall be exempted from meeting this vegetative cover requirement;
j. If the vertical separation between the seasonal high water table. and the depth of residuals
application is less than one foot;
k. If the vertical separation of bedrock and the depth of residuals application is less than one foot;
1. Application exceeds agronomic rates.
12.. The following public access restrictions apply to residual land application sites:
a. Public access to public contact sites (e.g., golf courses, parks, ball fields, etc.) shall be restricted
for 365 days after a residuals land application event;
b. Public access, to non-public contact sites shall be restricted for 30 days after a residuals land
application event.
13. Public access controls shall include the posting of signs with a minimum area of 3 square feet (e.g.,
L5' x 2'). Each sign shall indicate the activities conducted at each site, permit number, and name and
contact information, including the Permittee or applicator's telephone number. Signs shall be posted
in a clearly visible and conspicuous manner at the entrance to each land application site during. a land
application event, and for as.long as the public access restrictions required under III.12 apply..
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14. The followingharvesting,And grazing restrictions, apply to resid
ual land application sites after each
land application evdiit;'
Harvesting and Grazing Description
Restricted
Duration,
Animals- shall not be allowed O;graze during, land application activities and.
restricted. period. Sites that are to be used for grazing shall have fencing. to
30 days
prevent, access, after each landapplicatiQn event.
Food crops, feed crops' ,and fiber crops shall.,not be harvested for:
3 0, -days
Turf grown on land where residuals. have been applied shall not be harv6sted.fbr.-
12 months
Food cropg with harvested parts thAt,to4ch the residual/soilmixture and are
tdtally-above,.the land surface,(e.g,, tobacco; melons, cucumbers, squash, etc.;)
14 months
shall not be harvested for:
When the residuals remain on the I . and surface for four months or longer prior to
incorporation into the soil, food crops with ith harvested. parts below the land.
surface,(e.g.., root -crops such as.pplatppsi,carrots, radishes,etc.) shall not be
20 months
harvested for:
When the residuals remain on theland surface for less than o, four prior t
incorporation into the soil, f6,odcrops With harvested parts belowthe land.
38 months
surface sh.all,notbe harvested for-
15. ThePermit,tee shaltacquire, from each landowner of lessee/gpdrator a Statement detailing the volume
of othef-hutrient sources (i.e, manufactured fertilizers, manures.,or other animal wa9te"pr6duas)'thdt,
.have been, applied to the site, aril a copy
Of the. most recent. Nutrient. Management Plan -.(NMP) f6r
those operations where; aNMP is required by -the US Depaitment of Agriculture — National, Resources
Conservation Service (MRCS) or other State Agencies. The Permittee shall calculate allowable
nutrient loading Kates based. On the provided information and use appropriate reductions.
For- the, Purpose of this permit condition, a, Crop Management, Plan (CMP), , Waste Utilization Plan
(WUP) or, Certified Nutrient Management Plan (CLAMP) shall also be considered a Nutrient
Mahagern6lit-PlAn'..
16. No residuals -shall be land applied unless the gubrftitted Land Owner Agreement Attachment (LOAA)
between the Pprmittde and landowners or lesge'es/operators of the land application site, is
Onfullforoe
and effect. These agreements shall be considered expired concurrent with the permit expiration date,
and shall be renewed during the permit "renewal process.
IV. MONI[TORINGAND,REPORTE*4GREOUI[REAHNTS
L Any Division required monitoring (including groundwater, plant tissue,, soil and surflace—watet
analyses) necessary to ensure . groundwater and s,qrface, water. protection shalt bey established, and aft
acceptable sample reportilng,schedule shall be, followed.
2. Residuals shall be analyzed to demonstrate they are non -hazardous under the 'Resource Conservation
and 'Recovery .Act (RCRA),, The, analyses [co-rrosivity, ignitability, reactivity;, and loxicity
characteristic leaching procedure (TCLP)l shall 'be performed at the frequency .specifidd in
Attachment A, and the Pennittee shall maintain, these results for 0 a minimum of five years. Any
exceptions from the requit6ments in this condition, shall be, specified in. Attachment A.
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The TCLP analysis shall include the following parameters (the regulatory level in -milligrams per liter
is in parentheses):
Arsenic (5.0)
1,4-Dichlorobenzene (7.5)
Nitrobenzene (2.0)
Barium (100.0)
1,2-Dichloroethane (0.5)
Pentachlorophenol (100.0)
Benzene (0.5)
1,1-Dichloroethylene.(0.7)
Pyridine (5.0)
Cadmium (1.0)
2,4-Dinitrotoluene (0.13)
Selenium (1.0)
Carbon tetrachloride (0.5)
Endrin (0.02)
Silver (5.0)
Chlordane (0.03)
Hexachlorobenzene (0.13)
Tetrachloroethylene (0.7)
Chlorobenzene (100.0)
Heptachlor (and its hydroxide)
(0,008
Toxaphene (0.5)
Chloroform (6.0)
Hexachloro-1,37butadiene (0.5)
Trichloroethylene (0.5)
Chromium (5..0)
Hexachloroethane (3.0)
2,4,5-Trichlorophenol (400.0),
m-Cresol (200.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
o-Cresol (20.0.0)
Lindane (0.4)
2,4,5-TP (Silvex) (1.0)
p-Cresol (200.0)
Mercury (0.2)
Vinyl chloride (0.2)
Cresol (200.0)
Methoxychlor (10.0)
2,4-1) (10.0)
Methyl ethyl ketone (200.0)
.Once; the residuals have been monitored for two years -at the frequency specified in Attachment A, the
Permittee may submit a permit modification request to reduce the frequency of this monitoring
requirement., In no case shall the monitoring frequency be less than once per permit cycle.
3. An analysis shall be conducted on residuals from each source generating facility at the frequency
specified in Attachment A, and the Permittee shall maintain the results for a minimum of five years.
The analysis shall include the following parameters:
Aluminum
Mercury
Potassium.
Ammonia -Nitrogen
Molybdenum
Selenium
Arsenic
Nickel
Sodium
Cadmium
Nitrate -Nitrite Nitrogen
Sodium Adsorption Ratio
(sAR)
-Calcium
Percent Total Solids
TKN
Copper,
pH
Zinc
Lead
Phosphorus,
Magnesium
Plant Available Nitrogen
'(by calculation)
4. Residuals shall be monitored, for compliance with pathogen and vector attraction reduction
requirements at the frequency specified in Attachment A, and at the time indicated in the sampling
and monitoring sections of the approved O&M plan. The required data shall be specific to the
stabilization process utilized, and sufficient to demonstrate compliance with the Class B pathogen
reduction requirements in 15A NCAC 02T .1106 (a) and (c), and one vector attraction reduction
requirement in 15A NCAC 02T .1107 (a) shall be. met. Any, exceptions -from the requirements in this
condition shall be specified in Attachment A.
WQ0011038 Version 3.0 Shell Version 141027 Page 8 of '12

5. An annual representative soils, analysis (i.e„ Standard Soil Fertility Analysis) shall be conducted on
each land application .site listed in Attachment B on which a residuals land application event" will
occur in :the respective calendar year. This analysis shall.be in accordance with the "Guidance on Soil
Sampling" located in the, Sampling .Instructions section of the NC Department of Agriculture &
Consumer Services' website h ttp:%two w.ncagr;govlagronomvpubs.htm).. The Pe
rmittee shall
maintain these results and a description of the sampling methodologies used to determine soil fertility
for a period of no less than five years,, and shall be made available to the Division upon request. At a
minimum, the Standard Soil Fertility Analysis shall .include the following parameters:
Acidity
Exchlanizeable Sodium Percentage
Phosphorus
Base Saturation (by calculation)
Magnesium.
Potassium
Calcium
Manganese.
Sodium.
Cation Exchange Capacity
Percent,Humic Matter
Zinc
Copper
pH
6. Laboratory parameter analyses shall .be performed on the residuals as they-areland applied, and shall,
be, in accordance with the monitoring -requirements in 15A NCAC 02B .0505.
7. The Pennittee shall maintain records tracking all residual land. application events. At a minimum,
these records shall include the following:
a. Source of residuals;
b. Date of land application;
c. Location.of land. application (i.e., site, field, .or zone number as listed in Attachment B);
d. Approximate areas applied to (acres);
e. Method of land: application;
£ Weather conditions (e.g., sunny, cloudy, raining, etc.);
g. Predominant. Soil Mapping Unit (e.g., CbB2);
h: Soil conditions (e.g., dry, wet, frozen, etc.);,
is Type of crop or crops to be grown on field;
j: Nitrogen Application Rate based on RYEs (if using data obtained from the North Carolina State:
University Department of Soil Science Website, the, printout page. shall be kept on file and.
reprinted'every five years);
k. Volume of residuals land.applied in gallons' -per acre, cubic yard per, acre, dry tons per acre; or wet
ton per'acre;
1. Volume of animal waste or other nutrient source applied 'in gallons per acre, dry ton per acre, or
wet tons per acre;
m. Volume of soil amendments (e.g., lime, gypsum, etc.) applied in gallons per acre, dry, ton per
acre, or wet tons per acre; and
n. Annual and cumulative totals in, dry tons per acre of residuals as well as animal waste and other
sources "of nutrients (e.g., if applicable), annual and cumulative pounds per acre of .each heavy
metal (e.g., shall include; but shall not be limited 'to,. arsenic, cadmium, copper, lead, mercury,
molybdenum, nickel, selenium, and zinc), annual pounds per acre of PAN, and annual pounds per
acre; of phosphorus;applied to each field.
WQ00-11038 Version 3;0 Shell Version 14'1027 Page Q of 12

8. Three copies of an annual report shall be submitted on or before March V. The annual report shall
meet the .requirements described in the Instructions for Residuals Application Annual Reporting,
Forms. Instructions for reporting and annual report forms are available at
http://Portal.ncdenr.org/web�/��v/qpst'lau/reporting, or can be obtained by contacting the Land
Application'Unit directly. The annual report shall be submitted to the following address:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina,27699-1617
9. Noncompliance Notification
The Permittee shall report by telephone to the Mooresville Regional Office, telephone number (704)
.663-1699, as soon as possible, but in no case more than 24 hours or on the :next working day
following the occurrence or first knowledge of the occurrence of any of the following:
a. Any occurrence with the land application program resulting in the land application of significant
amounts ;of wastes that are abnormal in quantity or characteristic.
b. Any failure of the land application program resulting in a release of material to surface waters:
Any time, self -monitoring indicates the .facility has gone out of compliance with its permit
limitations.
d. Any process unit failure, due to known or unknown reasons, rendering the facility incapable of
adequate residual treatment.
e. Any spill. or discharge from a vehicle or piping system during residuals transportation.
Any emergency requiring immediate reporting (e.g., discharges to surface waters., iinminent.failure of
a storage structure, etc.) outside normal business hours shall be reported to. the Division.'s Emergency
Response personnel at telephone number [phone], (800) '858-0368, or (919) 733=3300.Persons
reporting such occurrences'by telephone shall also file a written report in letter form within: five days
following first knowledge of the occurrence. This report shall outline the actions taken or proposed to
be taken to ensure. that the problem does not recur.
V. INSPECTIONS'
1. The Permittee shall provide adequate inspection and maintenance to ensure proper operation of the
subject facilities and shall be in accordance with the approved O&M Plan.
2. Prior to each bulk residuals land application event, the Permittee or his designee shall inspect the
residuals storage, transport and application facilities to prevent malfunctions, facility deterioration
and. operator errors resulting in. discharges, which may cause the release of wastes to the
environment, a threat to human health or a_ public nuisance. The Permittee shall maintain an
inspection log that includes, at a minimum, thedate and time of inspection, observations made, and
any -maintenance, repairs, or corrective actions taken. The Permittee shall maintain this inspection log
for a period of five years from the date .of inspection, and this, log shall be made available to the
Division upon request.
3. Any duly authorized Division representative znay, upon presentation of credentials, enter and inspect
any property, premises or place on or related to the land application sites or facilities permitted herein
at any reasonable time for the purpose of determining compliance with this 'permit; may inspect or
copy any records required to be maintained under the terms and conditions of this permit; and may
collect groundwater, surface water or leachate samples.
WQO'011038 Version 3.0 Shell Version 141027 Page 1'0 of 12

V1. GENERAL CONDITIONS
1. Failure to comply with the conditions and limitations contained herein may subject the Permittee to
ari enforcement action. by the Division in accordance with North Carolina,. General, Statutes 143-
215.6A .to. "143-21-5.6C..
2. This permit shall. become voidable if the residuals land application events are not. carried: out in
accordance with the conditions_ of this permit.
3. This permit" is effective" only with, respect to, the nature and volume of residuals described in, the
permit application and other supporting" documentation.
4 The issuance, of this permit does not exempt the Permittee from complying with any 'and all statutes;
rules, regulations, or ordinances, which maybe imposed by, other"jurisdicti6 gov Tli nt,agencies
(e.g,, local, state, and federal)., Ofparticular concern to the Division are applicable river buffer rules
in 15A,NCAC 02B:.0200; erosion and sedimentation control requirements ,in IAA NCAC Chapter 4
"and under the Division's General Permit NCG0100 ft any requirements pertaining to wetlands under
15A ,NCAC 02B.._0200 and 02H .0500;. and dooumeritation of compliance with Article 21 Part 6: of
Chapter 143 of the General Statutes:
5: "In the: event the residuals program changes,ownership or the Permittee changes their name, a formal
permit modification" requestahall be submitted to the Division: This request, shall, be made- oil official
Division forms, and shall include appropriate documentation :from 'the parties involved and other
supporting. documentation as necessary.. The Permittee: of record shall remain fully responsible, for
maintaining and` operating the residuals program permitted herein until a permit is issued to the new
owner.
6. This permit is subject to: revocation or unilateral modification upon 60-days' notice:"from the Division
Director, in whole or part for. the requirements lasted in 1,5A NCAC 02T .0110,
7. Unless 'the .Division Director grants a variance, expansion of the permitted residuals program
contained herein shall not be granted if the Permittee exemplifies any of. the criteria in 15A NCAC
02T .0120(b).
8 The Permittee shall. pay the annual fee within. 30 days after being billed by the Division. Failure to
pay the annual fee accordingly shall be cause for the Division to revoke this permit pursuant to 15A.
NCAC .02T.0105(e)(3 ).
Permit issued .this the 1.9'hday of December,:2014
NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION
�vr omas X Reeder,,Director
ivisid of Water"Resources
By Authority of the Environmental Management Commission
Permit Number WQ0011038
WQ0011038 Version 3.0 Shell Version '141027 Page 1'1 of 12

Page Left Blank
WQ0011038 Version 3.0 Shell Version 141027 Page 12 of 12

ATTACHMENT A - Approved Residual Sources
CNA Holdings, Inc.
Certification Date: December19, 2014
Permit -Number: WQ0011038 Version:3A
um
MaximRermif
Monitoring.
Monitoring
Monitoring
Frequency for
Approved-
Owner
Facility Name
County
Biological
Dry Tons
Frequency for
Frequency for
Pathogen &-
Mineralization
Number
Residuals
1
Per Year
Non -hazardous
Characteristics
Metals and
Nutrients a, 5
Vector Attraction
Rate
Reductions 4, 5
CNA Holdings, Inc.
CNA Holdings Inc -A
Sludge/Ho
Cleveland
:NC0004952
Yes
570
Annually
See Table Below
None
03
Total
570
1. Maximum Dry To.ns per Year is the amount of residuals approved for land application from each permitted=facility.
2. Analyses to demonstrate that residuals are non -hazardous (i.e., TCLP, ignitability, reacfivity, and corrosivity)' as stipulated under permit: Condition IV.2.
3. Testing of metalsand nutrients as stipulated underpermit Condition IV.3.
4. Analyses of pathogen and vector attraction reductions as stipulated under permit Condition IV'A..
5. Monitoring frequencies are based. on the actual dry tons applied per year using the table below, unless specified above.
DryTons Generated,
short tons per ear(Established
Monitoring Frequency
in 40 CFR 503 and.15A NCAC OZT :1111
<i19
lNear
>3.19 - 41,650
1/"Quarter 4 times per ear
=>1,650-<16,509
1/60:Days 6 times per,year
=>16,500
11month 12times per ear
If no land application events occur during a required. sampling period (e.g.,no land application occur during,an entire year when annual -monitoring is required), then no
sampling data is required during the period of inactivity. The annual report -shall include an explanation for missing sampling data. Those required to submit'the annual
report to EPA may required to makeup the missed sampling,`contact the EPATor additional information and clarification.
Pagel of l

ATTACHMENT B - Approved Land Application Sites
CNA Holdings, Inc.
Certification Dater December 19, 2014,
Permit Number: WQ0011038 Version:,3.0
Field Id
Owner
Lessee
County
Latitude
Longitude
Net a
AcrNC-CL-101-02
Dominant Soil Series
Footnotes
Crawford, Bobby
Cleveland
35010'56"
81034'22"
'12.60
Pacolet,
i
NC-CL-101-03
Crawford, Bobby
Cleveland
35010'53"
81034'32"
14.50
Pacolet
1
NC-CL-101-04
Crawford, Bobby
Cleveland
35010'42"
81034'13"
8.50
Pacolet
1
NC-CL-101-05
Crawford, Bobby
Cleveland
35010'51"
8103.4'13"
5.60`
Cecil
1
NC-CL-101-06
Crawford, Bobby
Cleveland
35010'43"
81034'02"
450
Pacolet
1
NC-CL-101-07
Crawford, Bobby
Cleveland
35010'35"
8194'15"
10.00
Pacolet
1
NC-CL-103-01
Austrell, Patricia
Patterson, Ben
Cleveland
350123P
81032'25"
28.56
Pacolet
1
NC-CL-103-02
Austrell, Patricia
Patterson,.Ben
Cleveland
35012131"
81°34'31"
8.50
Pacolet
1
NC-CL-104-01
Ellis, Buford
Cleveland
35011'19"
81°34'31"
23.00
Pacolet
l
NC-CL-109-01
Sarratt, Victor
Cleveland
35012'31"
81032'25"
55.50
Pacolet
1
NC-CL-109-02
Sarratt, Victor
Cleveland
35010'45"
81035'20"
34.60
Pacolet
1
NC-CL-109-03
Sarratt, Victor
Cleveland
35010'28"
81035106"
18.00
Pacolet
1
Total
223.80
1. Dominated by soils with a mean seasonal high water table greater than three feet below the land surface. Kesiduals land application events -may occur on these sites
year round.
Page 1 of 1

WATER QUALITY REGIONAL OPERATIONS SECTION
APPLICATION REVIEW REQUEST FORM
Date: October 31, 2014
To: MRO-WQROS: Michael Parker / Andrew Pitner NOV 4 2014
From: Troy Doby, Water Quality Permitting Section - Non -Discharge Permitting Unit
Telephone: [phone] Fax: [phone] E-Mail: [e-mail]
A. Permit Number: WQ0011038
B. Applicant: CNA Holdings, Inc.
C. Facility Name: CNA Holdings Inc -A Sludge/Ho
D. Application:
Permit Type: Distribution of Residual Solids (503)
Project Type: Renewal
E. Comments/Other Information: Please let me know by email to whom you have assigned this
so that I can email questions I would like them to ask during inspection. Thanks!
❑ I would like to accompany you on a site visit
Attached, you will find all information submitted in support of the above -referenced application for your
review, comment, and/or action. Within 45 calendar days, please take the following actions:
® Return a completed WQROSARR Form.
❑ Attach a classification rating sheet.
❑ Attach Attachment B for Certification.
® Return a completed WQROSSR Staff Report
❑ Attach Well Construction Data Sheet.
❑ Issue an Attachment B Certification.
When you receive this request form, please write your name and dates in the spaces below, make a copy
of this sheet, and return it to the appropriate Central Office Water Quality Permitting Section contact
person listed above.
RO-WOROS Reviewer: ��G� Date:
FORM: WQROSARR 02-14 Page 1 of 1

AmA. �
VA
VAI
North Carolina Department of Environment and Natural Resources
Pat McCrory
Governor
Luis Mendoza — Site Leader
CNA Holdings Inc Celanese Shelby Plant
2525 Blacksburg Road
Shelby, NC 28073
Dear Mr. Mendoza:
John E. Skvarla, III
Secretary
October 31, 2014 -
NOV 4 2014
Subject: Acknowledgement of
Application No. WQ0011038
CNA Holdings Inc
Residual Solids System
Cleveland County
The Water Quality Permitting Section acknowledges receipt of your permit application and
supporting documentation received on October 18, 2014. Your application package has been assigned the
number listed above, and the primary reviewer is Troy Doby.
Central and Regional Office staff will perform a detailed review of the provided application, and
may contact you with a request for additional information. To ensure maximum efficiency in processing
permit applications, the Division of Water Resources requests your assistance in providing a timely and
complete response to any additional information requests.
Please note that processing standard review permit applications may take as long as 60 to 90 days
after receipt of a complete application. If you have any questions, please contact
Troy Doby at [phone] or [e-mail].
Sincerely,
Jon Risgaard, Supervisor
Division of Water Resources
cc: *lblores Ale'Regiol1al,,.Qffice, Water Quality Regional Operations Section
Roy Whitaker — EMA Resources Inc; 755 Yadkinville Road, Mocksville NC 27028
Permit File WQ0011038
Non -Discharge Permitting Unit
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Phone: [phone] Internet: http://pdrtal.ncdenr.org/web/Wq
An Equal Opportunity 1 Affirmative Action Employer— Made in part with recycled paper

&A'
o
North Carolina Department of Environment and Natural Resources
Pat McCrory
Governor
October 31, 2014
Luis Mendoza — Site Leader
CNA Holdings Inc Celanese Shelby Plant
2525 Blacksburg Road .
Shelby, NC 28073
Dear Mr. Mendoza:
John E. Skvarla, III
Secretary
KV 4 2014
Subject: Acknowledgement of
Application No. WQ0011038
CNA Holdings Inc
Residual Solids System
Cleveland County
The Water Quality Permitting Section acknowledges receipt of your permit application and
supporting documentation received on October 18, 2014. Your application package has been assigned the
number listed above, and the primary reviewer is Troy Doby.
Central and Regional Office staff will perform a detailed review of the provided application, and
may contact you with a request for additional information. To ensure maximum efficiency in processing
permit applications, the Division of Water Resources requests your assistance inproviding a timely and
complete response to any additional information requests.
Please note that processing standard review permit applications may take as long as 60 to 90 days
after receipt of a complete application. If you have any questions, please contact
Troy Doby at [phone] or [e-mail].
Sincerely,
6)\-� L'�t�
Jon Risgaard, Supervisor
Division of Water Resources
cc: Mooresville Regional Office, Water Quality Regional Operations Section
Roy Whitaker — EMA Resources Inc; 755 Yadkinville Road, Mocksville NC 27028
Permit File WQ0011038
Non -Discharge Permitting Unit
1617 Mail Service Center, Raleigh, North Carolina 27699-1617
Phone: [phone] Internet: http:llportal.ncdenr.org/weblwq
An Equal Opportunity 1 Affirmative Action Employer— Made in part with recycled paper

€ m
Celanese
The chemistry inside innovation
Celanese Corporation
2525 Blacksburg Road
Grover, NC 28073-9641
www.celanese.com
PERMIT RENEWAL APPLICATION
FOR THE
LAND APPLICATION OF RESIDUALS
FROM
C N A HOLDINGS, LLC — SHELBY FACILITY
WQ0011038
Prepared by: EMA Resources, Inc.
October 23, 2014

Certified Mail 7011 3500 0000 35714157
Return Receipt to PEM Carter
PEMC14:38
Division of Water Resources
Aquifer Protection Section
Land Application Unit
512 N. Salisbury Street
Raleigh, NC 27604
e7A
13 Celanese
The chemistry inside innovation*"
Celanese Corporation
2525 Blacksburg Road
Grover, NC 28073-9641
www.celanese.com
NOV 4 2014
RE: Renewal Land Application of Wastewater Seidual for C N A Holdings, LLC, Permit WQ0011038
Attention: Mr. Jon Risgaard, Unit Supervisor
Enclosed is 1 original and 3 copies of the completed renewal package for C N A Holdings, LLC —Shelby
Facility. No fee is required for this renewal permit.
You will find included in this permit renewal application the following:
v Cover Letter
• RLAP form
• RSC Form
• LASC form
• Copy of existing permit
• Operations and Maintenance Plan
• Site Cummulative Loadings
Individuals Site Maps
Each form is supplemented with the accompanying attachments and are clearly identified on the
accompanying tabs.
C N A Holdings, LLC—Shelby Facility utilized EMA Resources, Inc. to assist in this renewal package.
C N A Holdings, LLC — Shelby Facility is committed to ensuring compliance with all County, State and
Federal regulations. Should you have any questions concerning this application, please feel free to
contact Roy Whitaker- EMA 336-751-1441 or myself — 704-480-5726.
Respectfully,
dja
PEM Carter
EHS Lead
Engineered Materials
OCT 28 2014
WatarQuality

�
RLAP FORM
2
Existing Permit
3
O & M Plan
4
RSC Form
5
WWTP Vicinity Map
6
Process Flow Diagram
7
Quantitative Justifications
8.
Laboratory Analysis
9
LASC Form
10
Bobby Crawford
11
J. Buford Ellis
12
Victor Sarratt

State of North Carolina
MRR
Department of Environment and Natural Resources
?y Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
INSTRUCTIONS FOR FORM: RLAP 11-13 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items wilflead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall- Submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit website at:
http://portal.ncdenr. org/web/wq/aps/lau
General — This application is for treatment, storage, transport, and/or land application of Class B residuals (may include residuals that
are generated from a water treatment plant or other type facilities) on the proposed or currently approved_land application site(s) under
15A NCAC 02T .1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Land Application Program (FORM: RLAP 11-13) Application: (All Application Packages):
Submit the completed and appropriately executed Residuals Land Application Program (FORM: RLAP 11-13) form. Please
do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments
to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
The Applicant's Certification on Page 5 of this form shall be signed in accordance with 15A NCAC 02T .0106(b). An
alternate person may be designated as the signing official if a delegation letter is provided from a person who meets the
criteria in 15A NCAC 02T .0106(b).
If this project is for a modification of an existing permit, submit one copy of the existing permit.
Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environment and
Natural Resources (NCDENR).
STANDARD REVIEW — Submit the appropriate fee for all new and major modification applications as listed in the table
below.
STANDARD APPLICATION REVIEW FEES:
Facility Classification I New Permit i Major Modification 1
Major (land are permitted for >:300 acres) $1,310 $395
-F-
-F .
Minor (land are permitted for < 300 acres) $810 $245
' - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
adds additional land application areas not previously approved; adds additional residuals sources; or includes the addition of new
treatment or storage units/processes not previously permitted. There is no fee for minor permit modifications.
C. Cover Letter (All Application Packages)
List all items included in the application package, as well as a brief description of the req eptpd permitiing action.
D. Environmental Assessments (May be Required — See 15A NCAC I .0300)
Q Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact: the construction of the
residuals treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands
are used for the construction of the subject facilities.
INSTRUCTIONS FOR FORM: RLAP 11-13 Pagel of 3

E. Operation and Maintenance Plan (New and Renewal Application Packages)
For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
Submit the O&M Plan in accordance with 15A NCAC 02T .I 110 and include at a minimum:
Operational functions; describe the operation of the program to show what operations are necessary for the program to
function and by whom the functions are to be conducted.
l� 1
Maintenance schedules; may include equipments calibration, maintenance of signs, etc.
Safety measures; may include safety training program, manuals, signs, etc.
Spill response plan; including control, containment, remediation, emergency contact information, etc.
Inspection plan including the following information;
Names and titles of personnel responsible for conducting the inspections.
Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the
selected location(s) and inspection frequency are representative of the residuals management program.
Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the
event that noncompliance is observed.
Sampling and monitoring plan including the following information;
Names and titles of personnel responsible for conducting the sampling and monitoring.
Detailed description of monitoring procedures including parameters to be monitored.
Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature,
flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event.
The sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for
residuals to meet pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per
year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most
likely to be negatively affected by cold temperatures.
THE FOLLOWING ADDITIONAL ITEMS (G to M) ARE REQUIRED FOR DEDICATED PROGRAM ONLY.
F. Program Determination
. Dedicated residuals land application programs are ones in which land application sites meet the criteria in 15A NCAC 02T
.110202). Specifically, a residuals land application program is designated as dedicated if any of the following are
applicable:
El Any land application site certified for the residuals land application program that receives residuals at rates or frequencies
greater than agronomic rates.
El Any land application site certified for the residuals land application program that is used primarily for residuals disposal,
and agricultural crop production is of secondary importance.
El Any land application site certified for the residuals land application program that receives residuals through fixed
irrigation facilities or irrigation facilities fed through a fixed supply system.
Please contact the Non -Discharge Permitting Unit if you need any assistance in determining whether your residuals program
falls under the dedicated program definitions.
G. Program Information
El Provide an explanation of why a dedicated system is required instead of a conventional non -dedicated system.
El Provide an explanation of the dedicated system and its operation.
H. Detailed Site Maps (All New or Modification Application Packages) _
Submit three (3) sets of standard size plans and two (2) sets of I I" by 17" plans (electronic format is acceptable - Adobe PDF
only). For Modifications, submit plans specific to the modification(s) only.
Plans must include the following minimum items:
El A general location map, a vicinity map and a topographic map with contours not exceeding 10 feet or 25% of the total site
relief and showing all facility related structures and fences within the land application area.
_ The location of all wells (including usage and construction details if available), streams (ephemeral, intermittent, and
perennial), springs, lakes, ponds, and other surface drainage features within 500 feet of the land application site(s).
. Delineation of the review and compliance boundaries
Setbacks as required by 15A NCAC 02T .1108
Site property boundaries within 500 feet of all waste treatment, storage, and disposal site(s).
El A map showing the entire irrigation area with an overlay of the suitable irrigation area depicted by the soil scientist's
evaluation. The irrigation plans shall show each nozzle/emitter and wetted area (when applicable). Clearly label spray
irrigation zones as they will be operated.
El Plans must depict a completed design and not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT
FOR CONSTRUCTION, etc.) that indicate that they are anything other than final plans. However, the plans may be
labeled with the phrase: FINAL DESIGN - NOT RELEASED FOR CONSTRUCTION
INSTRUCTIONS FOR FORM: RLAP 11-13 Page 2 of 3

I. Project Evaluation and Receiver Site Management Plan (All New Application Packages or Modifications that include new
sites)
Submit a project evaluation and a receiver site management plan (if applicable) with recommendations concerning cover
crops and their ability to accept the proposed application rates.
- Hydrogeologic Report (All New Application Packages or Modifications involving increasing the total design capacity)
0 Submit a detailed hydrogeologic evaluation in accordance with 15A NCAC 02T .1104(d)(4) and current Division Policy
available at: hqp://portal.ncdenr.org/web/wq/aps/lau/policies. The document shall be signed, sealed and dated by a qualified
professional.
K. Engineering Design Documents (All New or Modification Application Packages with fixed irrigation facilities or irrigation
facilities fed through fixed supply system)
El Submit engineering design documents that have been signed, sealed, and dated by a NC licensed Professional Engineer
and/or Professional Land Surveyor in accordance with 15A NCAC 02T .1104(d)(2). For Modifications, submit an updated
site map specific to the modification(s) only.
El The design documents must include the following minimum items:
Engineering plans for the facility and equipment except those previously permitted unless they are directly tied into the
new units or are critical to the understanding of the complete process;
Specifications describing materials to be used, method of construction, and means for ensuring quality and integrity of the
finished product including leaking testing; and
Engineering calculations including hydraulic and pollutant loading, sizing criteria, hydraulic profile, total dynamic head
curve analysis for each pump, and irrigation design.
Soil mapping units shown on all disposal sites.
L. Water Balance (All New Application Packages or Modifications that include new sites utilizing fixed irrigation facilities or
irrigation facilities fed through fixed supply systems)
[] Submit a completed and accurate water balance in accordance with 15A NCAC 02T .I 104(d)(5) and current Division Policy
available at: btt.p://portal.ncdenr.org/web/wq/gps/Iqu/policies.
M. Property Ownership Documentation (All New or Modification Application Packages involving new and/or relocated treatment
or irrigation components)
Property ownership documentation shall consist of one of the following:
El Legal documentation of ownership (i.e., GIS, deed or article of incorporation), or
Written notarized intent to purchase agreement signed by both parties with a plat or survey map, or
EJ An easement running with the land specifically indicating the intended use of the property and meeting the requirements
of 15A NCAC 02L .0107(fl, or
El A written notarized lease agreement signed by both parties, indicating the intended use of the property, as well as a plat or
survey map.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
By U.S. Postal Service:
1636 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1636
TELEPHONE NUMBER: [phone]
By Courier/Special Delivery:
512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27604
FAX NUMBER: [phone]
INSTRUCTIONS FOR FORM: RLAP 11-13 Page 3 of 3

State of North Carolina
Department of Environment and Natural Resources
Y r:. Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
FORM: RLAP 11-13
I. APPLICANT INFORMATION:
1. Applicant's name: CNA Holdings, Inc. Celanese Shelby Plant
Applicant type 0 Individual Z. Corporation El General Partnership E Privately -Owned Public Utility
0 Federal 0 State El Municipal El County
Signature authority's name per 15A NCAC 02T .0106: Luis Mendoza Title: Site Leader
Applicant's mailing address: 2525 Blacksburg Road
City: Shelby State: NC Zip: 28073 x
Telephone number: 704 480-5728 Email Address: [e-mail]
2. Consultant's name: Roy Whitaker. License Number (for P.E.): NA
Affiliation: EjOn Staff M Retained (Firm: EMA Resources, Inc.)
Consultant's mailing address: 755 Yadkinville Road
City: Mocksville State: NC Zip: 27028
Telephone number:. 336 751-1441 Email Address: [e-mail]
3. Agronomist's name: Roy Whitaker
License Number: NA
Affiliation: 0; N/A 0' On Staff
E Retained (Firm: )
Agronomist's mailing address
City: State ;
Zip:
Telephone number: -'
Email Address
4. Soil Scientist's name. '
License Number.
Affiliation: . N/A 0 On Staff
0 Retained (Firm: )
Soil Scientist's mailing address.
City: `` State a
Zip OF& `
Telephone number:
Email Address _
5. Fee submitted: NA (See Instruction B)
H. PERMIT INFORMATION:
1. Application is for (check all that apply) 0 new, Eg modified, 0 renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: W00011038 �ECEIVEDIDENRIDW
Date of most -recently issued permit: May 3, 2006
Date of most -recently certified Attachment A (if different than the permit).'" 0 C T 2 8 2014
Date of most -recently certified Attachment B (if different than the permit). Wa$eiQUailty
FORM: RLAP 11-13 Page 1 of 5

M. RESIDUALS LAND APPLICATION PROGRAM INFORMATION:
1. Residuals Processing Facility's physical address: 2525 Blacksburg Road
City: Grover State: NC Zip: 28073
Coordinates: Latitude: 35' 12' 26.2" Longitude: 81' 31' 27.6"
Datum: NAD83 Level of accuracy:.01"
Method of measurement: GPS
2. County where residuals land application program is headquartered: Cleveland
3. List the Operator In Responsible Charge (ORC) and all Back -Up ORCs for the residuals land application program, their
certification numbers, and their affiliations in the following table:
Designation
Name
Affiliation
Certification Number
ORC
Roy Whitaker
EMA Resources, Inc.
LA13283
Back -Up ORC
Brent Collins
EMA Resources, Inc.
LA27651
Additional Back -Up
ORCs
(if applicable)
If an ORC and at least one Back -Up ORC are not currently designated for this residuals land application program, provide
the candidates' names, affiliations, and an estimated time schedule for each candidate's completion of the required training
school and certification test:
4. Complete the following tables regarding management of the residuals land application program:
a. Plant Available Nitrogen Summary: Determine the maximum plant available nitrogen (PAN) generated by all residuals
source -generating facilities as currently certified and proposed for certification with this application and list the results in
the following table:
Maximum amount of residuals to be certified: 334 dry tons per year.
PAN
Pounds of PAN per Dry Ton
(Weighted Average)
Pounds of PAN per Year
Surface
Incorporation
or Injection
Surface
Incorporation
or Injection
First -Year
16.5
21.1
5511
7047
Five -Year Maximum Adjusted
24.9
29.5
8317
9853
b. Land Application Site Use Summary: Summarize information regarding the land application sites as currently certified
and proposed for certification with this application:
Category
Use
Acres
Comments
Crops
Forest or Plantation
0
t
Row Crops
0
_ v
Hay
51.6
r
Pasture
135.2
y
Total:
186.8
Methods
Surface
186.8
Incorporation or Injection
0
Total:
186.8
FORM: RLAP 11-13 Page 2 of 5

c. Residuals Land Application Summary: Determine the minimum acreage required to land apply the residuals as currently
certified and proposed for certification assuming the scenarios listed in the following table:
Assumed
Application Rate
(lbs PAN/ac-),r)
Acres Required Using
First -Year PAN Concentrations
Acres Required Using
Five -Year Maximum Adjusted PAN
Concentrations
Surface
Incorporation or
Injection
Surface
Incorporation or
Injection
50
110
141
166
197
100
55
70.5
83
98.5
150
37
47
55
66
200
27.5
35
41.5
49
6. If applicable, provide a plan and a schedule to resolve any known issues that would prevent land application of the proposed
residuals due to the violation of North Carolina Administrative Code (e.g. not enough storage, not enough land, vector
reduction practices not in place, etc.).
7. Specify type of residuals program (See Instruction F): E Non -dedicated El Dedicated
If Dedicated, specify the following (check all that apply):
Residuals program contains any land application site(s) that receives residuals at rates or frequencies greater than
r�
agronomic rates, explain; t R
0 Residuals program contains any land application site(s) that is used primarily for residuals disposal, and agricultural crop
production is of secondary importance, explain;
Residuals program contains any land application site(s) that receives residuals through fixed irrigation facilities or
irrigation facilities fed through a fixed supply system, explain; :.,:r,,:r..:::.:
IV. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the following Residuals Source Certification and all associated documentation.
I � nal I
Residuals Source
Certification
V. LAND APPLICATION SITE INFORMATION: (Required for all new, renewed, or modified land application site)
Complete and submit the following Land Applications Site Certification and all associated documentation.
%R;
Land Application Site
Certification.doc
FORM: RLAP 11-13 Page 3 of 5

Note: Item VI. Applicable to Dedicated Program with fixed irrigation system on .
7,-T. DESIGN INFORMATION FOR FIXED IRRIGATION SYSTEM
1. The irrigation system is: E]. Spray Drip
2. Disposal system is: E] existing El proposed.
3. Minimum depth to mean seasonal high water table (SHWT) within irrigation sites(s) per Soil Scientist's Evaluation:
feet below ground surface. Rules 15A NCAC 02T .0505(p) requires at least one -foot vertical separation between SHWT and
ground surface.
4. Are there any artificial drainage or water movement structures within 200 feet of any irrigation area?
E3 Yes or E3 No If Yes, please explain if the soil scientist report addresses artificial structures and please indicate if
structures are to be maintained or modified:,
5. Loading rates recommended by the Soil Scientist Evaluation:
Recommended
Recommended
Soil Series
Fields within Soil Area
Loading Rate
Loading Rate
(in/hr)
(inlyr)
El
6. Design loading rates are equal or less than the loading rates recommended by Soil Scientist?
- - -1
[I. Yes or El No If No, explain why 15A NCAC 02T .0505(n) is not met:
7. Non -dedicated System Design (fill in the appropriate information for either a spray or drip irrigation system):
Design Area
Number of
Maximum Application
Design Annual Loading
Field Zone
(fe)
Nozzles
Rate (gallons/hr)
Rate (gallons/yr)
Total
Plan Sheet
Specification
Spray Irrigation Design Element
I
Number
Page Number
Wetted diameter of nozzles
ft
1Z
Wetted area of nozzles
fe
-V
Nozzle capacity
gpm
Nozzle manufacturer / model
Elevation of highest nozzle
ft
FORM: RLAP 11-13 Page 4 of 5

Applicant's Certification (signing authority must be in compliance with 15A NCAC 02T .0106):
:se applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without
proper closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with
any active compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
M Yes El No, Explain; ;
I, Luis Mendoza, Site Leader
(Signature Authority's Name — PLEASE PRINT) (Title)
attest that this application for CNA Holding, Inc. Celanese Shelby Plant
(Facility Name)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water
Resources may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes
unless specifically granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate
enforcement action, which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the
Division of Water Resources should a condition of this permit be violated. I also understand that if all required parts of this
application are not completed and that if all required supporting information and attachments are not included, this application
package will be returned to me as incomplete.
Note: In accordance with North Carolina General Statutes § 143-215.6A and § 143-215.6B, any person who knowingly makes any
-
--`:else statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine
it to exceed $10,000 as well as civil penalties up to $25,000 per violation.
Z;w
Signature: Date:01 /0/113 /v x
OCT 2 8 2014
oiVVatarQuality
FORM: RLAP 11-13 Page 5 of 5

i
OF \�� �,T�R Michael F. Easley, Governor
Q William G. Ross Jr., Secretary
O.° •. G
Gj y North Carolina Department ofEnvironment and Natural Resources
•r
—i Alan W. Klimek, P.E., Director
Division of Water Quality
µ—�
I
j May 3, 2006
MR. DARRELL FISHER, INTERIM PLANT MANAGER
CNA HOLDINGS, INC.
PO BOX 87
SHELBY, NORTH CAROLINA 28152
Subject: Permit No. WQ0011038
CNA Holdings, Inc.
Residuals Land Application Program
Land Application of Residual Solids (503 Exempt)
Cleveland County
Dear Mr. Fisher:
In accordance with your permit modification and renewal application package received on
January 18, 2005, we are forwarding herewith a modified and renewed Permit No.. WQ0011038 dated
May 3, 2006, .to CNA Holdings, Inc. for the subject residuals land application program.
This permit shall be efective from the date of issuance until April 28, 2011; shall void Permit
No. WQ0011038, issued on August 4, 2000; and shall be subject to the conditions and limitations as
specified therein. Make note of this permit's expiration date and the fact that a permit renewal
_ application is due to the Division of Water Quality (Division) no later than six months prior to that date
(i.e., see Condition VI.7.), as the Division does not send reminders to apply for permit renewal.
This permit is being issued to approve the continued operation of the residuals land application
program for another five-year cycle with the following modifications:
a. This permit is issued to reflect corrected acreages of renewed fields and change the numbering
system for the renewed fields.
b. A number of land application sites approved in the previous issuance of this permit have been
deleted and, hence, the total land area has decreased from 468.7 acres to 278.3 acres in this
issuance.
As always, remember to take the time to review this permit thoroughly, as some of the
conditions contained therein may have been added, changed, or deleted since the last issuance. Pay
particular attention to the monitoring requirements in this permit. Failure to establish an adequate system
for collecting and maintaining the required operational information will result in future compliance
problems.
If any parts, requirements, and/or limitations contained in this permit are unacceptable, you have
the right to request an adjudicatory hearing upon written request within 30 days following receipt of this
permit. This request shall be in the from of a written petition, conforming to Chapter 150B of the North
Carolina General Statutes and filed with the Office of Administrative Hearings at 6714 Mail Service
Center, Raleigh, North Caroline, 27699-6714. No `hCaro ina
atural�
Aquifer Protection Section 1636 Mail Service Center Raleigh. ATC 27699-1636 Phone [phone] Customer Senlce
Internet: Imn:'Al2o.cm•.2728 Capital Boulevard Raleigh. NC 27604 Fax [phone]
Fax [phone]
An Equal Opportunity/Affirmative Action Employer - 50% Recycled/10% Post Consumer Paper

Mr. Darrell Fisher
Page 2
May 3, 2006
Unless such demands are made, this permit shall be final and binding.
If you need any additional information concerning this matter, please contact Mr. J. R. Joshi by
telephone at [phone], or via e-mail at [e-mail]-
Sincerely,
1�
or Alan W. Klimek, P.E.
cc:. Mr. Eric Thompson, SYNAGRO
Cleveland County Health Department
Mooresville regional Office -Aquifer Protection Section
Technical Assistance and Certification Unit
APS Central Files
LAU Residuals Program Coordinator

NORTH CAROLINA '
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
RALEIGH
LAND APPLICATION OF RESIDUAL SOLIDS (503 EXEMPT) PERMIT
In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as
amended, and other applicable Laws, Rules, and Regulations
PERMISSION IS HEREBY GRANTED TO
CNA Holdings, Inc. (Tycona)
Cleveland County
FOR THE
continued operation of a residuals land application program for CNA Holdings, Inc. (Tycona) and
consisting of the land application of residuals generated by the residuals source -generating facilities listed
in the most recently -certified Attachment A to the land application sites listed in the most recently -
certified Attachment B with no discharge of wastes to surface waters, pursuant to the permit modification
and renewal application package received on January 18, 2005 and in conformity with the project plan,
specifications, and other supporting data subsequently filed and approved by the Department of
Environment and Natural Resources and considered apart of this permit.
i This permit shall be effective from the date of issuance until April 28, 2011; shall void Permit
No. WQ0011038, issued on August 4, 2000; and shall be subject to the following specified conditions and
limitations:
I. PERFORMANCE STANDARDS
I. The residuals land application program shall be effectively maintained and operated as a non -
discharge system to prevent the discharge of any wastes resulting from the operation of this
program.
2. This permit shall become voidable if the soils of the land application sites fail to assimilate
the residuals adequately and may be rescinded unless the land application sites are maintained
and operated in a manner that will protect the assigned water quality standards of the surface
waters and groundwater.
3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to
surface waters or groundwater resulting from the operation of this residuals land application
program.

_ 4. In the event that the residuals land application program is not operated satisfactorily,
including the creation of nuisance conditions, the Permittee shall cease land applying
residuals to the site, contact the Aquifer Protection Section of the appropriate Division of
Water Quality's (Division) regional office, and take any immediate corrective actions as may
be required by the Division.
5. No residuals other than those generated by the residuals source -generating facilities listed in
the most recently -certified Attachment A of this permit shall be approved for land application
in accordance with this permit.
6. Only the land application sites listed in the most recently -certified Attachment B of this
permit are approved for residuals land application.
7. This permit shall become voidable unless the agreements between the Permittee and the
landowners and lessees or operators of any land application sites listed in the most recently -
certified Attachment B of this permit not owned by the Permittee are in full force and effect.
These agreements shall be considered expired concurrent with the expiration date of the
permit and shall be renewed at the same time the permit is renewed.
8. The appropriate local governmental official (Le., county manager, city manager, etc.) shall be
notified at least 24 hours prior to the initial residuals land application event to any new land
application site. In addition, the appropriate county manager's office shall be notified prior to
the initial residuals land application event on any new site so that they will be aware that
residuals land application activities have commenced on the site.
9. The Aquifer Protection Section of the appropriate Division's regional office shall be notified
at least 24 hours prior to the initial residuals land application event on any new land
application site. Such notification to the Regional Aquifer Protection Supervisor shall be
made during normal office hours (i.e., from 8:00 a.m. until 5:00 p.m.) between Monday and
Friday, but excluding State Holidays. A list of the Division's regional offices, their county
coverage, and their contact information may be downloaded from the web site at
http://h2o.enr.state.nc.us/ndpu/.
10. When residuals are land applied under the conditions of this permit, the Class B pathogen
requirements and site restrictions in 40 CFR Part 503.32(b) shall be met. Additionally, an
evaluation shall be performed that demonstrates the residuals' ability to comply with this
requirement. Upon request, a copy of this evaluation, including all test results and
calculations, shall be submitted. Only residuals that are generated by the residuals source -
generating facilities that are identified as being exempt from this condition in the most
recently -certified Attachment A shall not be required to comply with the specified pathogen
reduction requirements.
IL OPERATION AND MAINTENANCE REQUIREMENTS
The facilities and land application sites shall be properly maintained and operated at all
times.
2. Upon classification of the residuals land application program by the Water Pollution Control
System Operators Certification Commission (WPCSOCC), the Permittee shall designate a
certified land application/residuals operator to be in responsible charge (ORC) of the
2

program. The operator shall hold a certificate of the type classification assigned to the
program by the WPCSOCC. The Permittee shall also designate a certified back-up operator
' I of the appropriate type to comply with the conditions of 15A NCAC 8G .0202.
No residuals shall be stored at any land application site at any time, unless written approval
has first been requested and obtained from the Division.
4. A copy of this permit shall be maintained in all manned equipment at the land application
sites when residuals are being land applied during the life of this permit. A spill prevention
and control plan shall be maintained in all residuals transport and application vehicles.
5. When land applying residuals to any land application site, the following buffer zones shall be
maintained at all times:
a. 400 feet from residences or places of public assembly under separate ownership for
surface application methods; however, the buffer zone requirement may be reduced to a
minimum of 100 feet upon written consent of the owner and approval from the Aquifer
Protection Section of the appropriate Division's regional office in Attachment B of this
emit;
b. 200 feet from residences or places of public assembly under separate ownership for
subsurface application methods; however, the buffer zone requirement may be reduced to
a minimum of 100 feet upon written consent of the owner and approval from the Aquifer
Protection Section of the appropriate Division's regional office in Attachment B of this
permit;
c. 100 feet from any public or private water supply source, waters classified as SA or SB,
ar.ad any Class I or Class II impounded reservoir used as a source of drinking water for
both methods;
d. 100 feet from any streams classified as WS or B, any other stream, canal, marsh or
coastal waters and any other lake or impoundment for surface application;
e. 50 feet from any streams classified as WS or B, any other stream, canal, marsh or coastal
waters and any other lake or impoundment for subsurface application;
f. 50 feet from property lines for both surface and subsurface application methods;
g. 50 feet from public right of ways for both surface and subsurface application methods;
h. 10 feet from upslope interceptor drains and surface water diversions for both surface and
subsurface application methods; and
i. 25 feet from downslope interceptor drains, surface water diversions, . groundwater
drainage systems, and surface drainage ditches for both surface and subsurface
application methods.
Some of the buffers specified above may not have been included in previous permits for this
residuals land application program. However, any land application sites that are listed in the
most recently -certified Attachment B of this permit, but were approved with different buffers
shall be reflagged to comply with these buffers.
6. Maximum slope for land application of residuals shall be 10 percent for surface application
methods and 18 percent for subsurface application methods.
3

7. Specific residuals land application area boundaries shall be clearly marked on each land
application site prior to and during a residuals land application event.
8. The lifetime loading rates (LLRs) of heavy metal loadings rates on any land application site
shall not exceed the following for the corresponding soil cation exchange capacities (CEC):
Parameter
LLR for a Site
with CECs <5
(pounds per acre)
LLR for a Site
with CECs 5 to 15
ounds per acre)(pounds
LLR for a Site
with CECs >15
per acre
Cadmium
4.5
9
18
Copper
125
250
500
Lead
500
1,000
2,000
Nickel
125
250
500
Zinc
250
500
1,000
9. An acceptable pH shall be maintained in the soil, residuals, and lime mixture, greater than
6.0, on all land application sites onto which residuals are land applied to ensure optimum
yield for the crops specified in Condition 11. 13. The agronomist shall provide information
on the pH best suited for the specified. crop and the soil type.
10. Should any of the residuals generated by the residuals source -generating facilities listed in
the most recently -certified Attachment A of this permit contain a high salt. content (i.e., high
sodium adsorption ratio (SAR) of five or higherl the exchangeable sodium percentage (ESP)
or other method as approved by the Division, using the results from the annual soils analysis
as required by this permit, shall be monitored on all of the land application sites. The local
Cooperative Extension Office, the Department of Agriculture and Consumer Services, the
Natural Resource Conservation Service, a North Carolina -licensed Soil Scientist, or other
agronomist shall review the results and make recommendations regarding soil amendments
(e.g., gypsum, etc.) or other ameliorative mechanism for maintaining the integrity of the site
in terms of suitability for land application of residuals and maintaining conditions conducive
to crop growth. The Permittee shall implement such recommendations accordingly and shall
maintain written records of each monitoring event that includes details of the sites covered
and rate of soil amendment application.
11. Prior to land applying residuals to any land application site that has previously received or is
intended to receive animal waste (e.g., poultry litter, etc.) or other source of nutrients (e.g.,
fertilizer, etc.) in the future, the Permittee shall obtain information pertaining to the volume
and analysis of the applied waste/nutrients from the landowner and/or lesseeloperator of the
site. The Permittee shall be responsible for verifying the volume of residuals that may be
land applied to the site such that the plant available nitrogen (PAN) loading rate for the
specified crop (i.e., see Condition II. 13.) shall not be exceeded by all of the sources of PAN
applied. Should the maximum PAN loading rate be met or exceeded, then no additional
residuals shall be land applied to the site. .
12. A suitable vegetative cover, as listed in Condition H. 13., shall be. maintained on land
application sites onto which residuals are land applied in accordance with the crop
management plan outlined by the local Cooperative Extension Office, the Department of
Agriculture and Consumer Services, the Natural Resource Conservation Service, or other
agronomist and as approved by the Division..
4

13. Residuals and other sources of PAN shall be land applied to all land application sites at
agronomic rates in accordance with the crop management plan outlined by the local
Cooperative Extension Office, the North Carolina Department of Agriculture and Consumer
Services, the Natural Resource Conservation Service, or other agronomist. Under no
circumstances shall the following PAN loading rates land applied to any site exceed the
following for the specified crops:
PAN
PAN
Crop
(pounds per
Crop
(pounds per
acre per ear
acre per year
Alfalfa
200
Forest
(Hardwood or Softwood)
75
Bermuda Grass
220
Milo
100
(Hay- or Pasture
Blue Grass
B
120
Small Grain
(Wheat, Barley, or Oats
100
Corn
160
Sorghum or Sudex
180
Grain(Pasture)
Corn
200
Sorghum or Sudex
220
(Silage)
(Silage)
Cotton
70
Soybeans
200
Fescue
250
Timothy, Orchard, or
200
Rye Grasses
The Permittee shall apply for and receive a modification of this permit before land applying
residuals on any land application site that is to be established in a crop other than those listed
above. A maximum PAN loading rate for the desired crop shall.be approved with the permit
modification.
If the land application sites are to be overseeded (e.g., bermuda grass in the summer and rye
grass in the winter with BOTH crops to receive residuals), then the second crop shall receive
an application of PAN at a rate of no greater than 50 pounds per acre per year. This practice
shall be allowed as long as the second crop is to be harvested. If the second crop is to be
planted for erosions control only and is to be tilled into the soil, then no residuals shall be land
applied to these sites because the PAN will essentially be returned to the soil.
Residuals shall not be land applied at rates greater than agronomic rates, unless authorized by
the Division
14. Animals shall not be grazed on any land application site for 30 days after any residuals land
application event. Sites that are to be used for grazing shall have fencing that will be used to
prevent access after each event.
15. Food crops, feed crops, and fiber crops that do not come in contact with the residuals shall
not be harvested for 30 days after any residuals land application event.
16. Food crops with harvested parts that touch the residual/soil mixture and are totally above the
land surface (e.g., tobacco, melons, cucumbers, squash, etc.) shall not be harvested for 14
months after any residuals land application event.
17. Food crops with harvested parts below the surface of the land (i.e., root crops such as
potatoes, carrots, radishes, etc.) shall not be harvested for 20 months after any residuals land

application event when the residuals remain on the land surface for four months or longer
prior to incorporation into the soil.
j
18. Food crops with harvested parts below the surface of the land shall not be harvested for 38
months after any residuals land application event when the residuals remain on the land
surface for less than four months prior to incorporation into the soil.
19. Turf shall not be harvested for one year after any residuals land application event.
20. Adequate provisions shall be taken to prevent wind erosion and surface runoff from
conveying residuals from the land application sites onto adjacent properties or into any
surface waters.
21. Adequate procedures shall be provided to prevent surface runoff from carrying any land
applied or stored residuals into any surface waters.
22. Surface -applied residuals shall be plowed or disced within 24 hours after land application on
land application sites with no cover crop established.
23. For land application sites that are prone to flooding or within the 100-year flood elevation,
residuals shall be land applied only during periods of dry weather. The residuals shall be
incorporated into the soil within 24 hours after land application.
24. Residuals shall not be land applied during inclement weather or until 24 hours following a
rainfall event of 0.5-inch or greater in 24 hours. Any emergency residuals land application
measures shall first be approved in writing by the Division.
25. Residuals shall not be land applied to any land application site that is flooded, frozen, or
snow-covered
26. Appropriate measures shall be taken to control public access to the land application sites
during active site use and for the 12-month period following the last residuals land
application event. Such controls may include the posting of signs indicating the activities
being conducted at each site.
III. MONITORING AND REPORTING_ REOUIREMENTS
1. Any monitoring (i.e., including groundwater, surface water, residuals, soil, or plant tissue
analyses) deemed necessary by the Division to ensure protection of the environment shall be
established, and an acceptable sampling and *reporting schedule shall be followed.
j 2. Residuals generated by each residuals source -generating facility listed in the most -recently -
certified Attachment A of this permit shall be analyzed to demonstrate that they are non-
hazardous under the Resource Conservation and Recovery Act (RCRA). A corrosivity,
ignitability, and reactivity analysis as well as a Toxicity Characteristics Leaching Procedure
(TCLP) analysis shall be conducted on residuals generated by each residuals source -
generating facility listed in the most recently -certified Attachment A of this permit. The
analyses shall be performed at the frequency specified in the most recently -certified
Attachment A of this permit, and the results shall be maintained on file by the Permittee for a
minimum of five years. If residuals generated by a particular residuals source -generating
0

facility are lard applied at a frequency less than that which is specified in the most recently -
certified Attar-hment A of this permit, the analyses shall be required for each residuals land
application event. The TCLP analysis shall include the following parameters (i.e., note the
regulatory level in milligrams per liter in parentheses):
Arsenic (5.0)
Barium (100.0)
Benzene (0.5)
Cadmium (1.0)
Carbon tetrachloride (0.5)
Chlordane (0.03)
Chlorobenzene (100.0)
Chloroform (6.0)
Chromium (5.0)
m-Cresol (200.0)
o-Cresol (200.0)
p-Cresol (200.0)
Cresol (200.0)
2,4-D (10.0)
1,4-Dichlorobenzene (7.5) Nitrobenzene (2.0)
1,2-Dichloroethane (0.5)
Pentachlorophenol (100.0)
1, 1 -Dichloroethylene (0.7)
Pyridine (5.0)
2,4-Dinitrotoluene (0.13)
Selenium (1.0)
Endrin (0.02)
Silver (5.0)
Hexachlorobenzene (0.13)
Tetrachloroethylene (0.7)
Heptachlor (and its hydroxide) (0.008)
Toxaphene (0.5)
Hexachloro-1,3-butadiene (0.5)
Trichloroethylene (0.5)
Hexachloroethane (3.0)
2,4,5-Trichlorophenol (400.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
Lindane (0.4)
2,4,5-TP (Silvex) (1.0)
Mercury (0.2)
Vinyl chloride (0.2)
Methoxychlor (10.0)
Methyl ethyl ketone (200.0)
After the residuals have been monitored as specified above for two years at the frequency
specified in the most recently -certified Attachment A of this permit, the Permittee may
submit a request to the Division for a permit modification to request a reduction of this
monitoring requirement. In no case, however, shall the frequency of monitoring be less than
once per permit cycle.
3. An analysis shall be conducted on residuals generated by each residuals source -generating
facility listed. in the most recently -certified Attachment A of this permit. The analysis shall
be performed at the frequency specified in the most recently -certified Attachment A of this
permit, and the results shall be maintained on file by the Permittee for a minimum of five
years. If residuals generated by a particular residuals source -generating facility are land
applied at a frequency less than that which is specified in the most recently -certified
Attachment A of this permit, an analysis shall be required for each residuals land application
event. The analysis shall include, but shall not necessarily be limited to, the following
parameters:
Aluminum
Ammonia -Nitrogen
Cadmium
Calcium
Copper.
Lead
Magnesium
Nickel
Nitrate -Nitrite Nitrogen
Percent Total Solids
pH
Phosphorus
Potassium
Sodium
Total Kjeldahl Nitrogen
Zinc
Plant Available Nitrogen
(by calculation)
After die residuals generated by a particular residuals source -generating facility have
been monitored for two years at the frequency specified in the most recently -certified
Attachment A of this permit, the Permittee may submit a request to the Division for a
permit modification to reduce the frequency of this monitoring requirement. In no case,
however., shall the frequency of this monitoring be less than once per year when a
residuals land application event of residuals generated by the residuals source -generating
facility occurs during that year,
7

_ 4. Residuals generated by each residuals source-gencrating. facility listed in the most recently -
certified Attachment A of this permit shall be monitored .for compliance with Condition I. 10.
The monitoring shall be performed at the frequency specified in the most recently -certified
Attachment A of this permit, and data to verify pathogen reduction of the residuals shall be
maintained on file by the Permittee for a minimum of five years. The required data shall be
specific to the stabilization process utilized, but also shall be sufficient to demonstrate clear
compliance with the Class B pathogen reduction requirements and site restrictions in 40 CFR
Part 503.32(b). In addition, the Environmental Protection Agency (EPA) certification
statements concerning compliance with pathogen reduction requirements, and management
practices shall be completed at the frequency specified in the most recently -certified
Attachment A of this permit by the proper authority or authorities, if more than one is
involved (i.e., either the person who prepares the residuals, the person who derives the
material, or the person who applies the residuals). Only residuals that are generated by the
residuals source -generating facilities that are identified as being exempt from Condition I. 10.
in the most recently -certified Attachment. A of this permit shall not be required to comply
with this monitoring requirement.
5. Laboratory analyses as required by Condition III. 2., Condition III. 3., and Condition III. 4.
shall be performed/gathered on the residuals as they are to be land applied. Furthermore,
analytical determinations made pursuant to the monitoring and reporting requirements of this
permit shall be made by a laboratory certified by the Division for the required parameter(s)
under 15A NCAC 2H .0800 or 15A NCAC 2H .1100.
6. Proper records shall be maintained by the Permittee tracking all residuals land application
events. These records shall include, but are not necessarily limited to, the following
information:
a. Source of residuals;
b. Date of land application;
c. Location of land application (i.e,, site, field, or zone number);
d. Method of land application;
e. Weather conditions (i.e., sunny, cloudy, raining, etc.);
f. Soil conditions (i.e., dry, wet, frozen, etc.);
g. Type of crop or crops to be grown on field;
h. Volume of residuals land applied in gallons per acre, dry tons per acre, or kilograms per
hectare;
i. Volume of animal waste or other nutrient source applied in gallons per acre, dry ton per
acre, or kilograms per hectare (if applicable);
j. Volume of soil amendments (i.e., lime, gypsum, etc.)'applied in gallons per acre, dry ton
per acre, or kilograms per hectare (if applicable); and'
. k. Annual and cumulative totals of dry tons per acre of residuals as well as animal waste and
other sources of nutrients (i.e., if applicable); annual`and cumulative pounds per acre of
each heavy metal (i.e., shall include, but shall not be limited to, arsenic, copper, lead,
mercury, molybdenum, nickel, selenium, and zinc), annual pounds per acre of PAN, and
annual pounds per acre of phosphorus applied to each field.
8

7. A representative annual soils analysis (i.e., Standard Soil Fertility Analysis) shall be
conducted on each land application site on which a residuals land application event in the
respective calendar year has occurred, and the results shall be maintained on file by the
Permittee for a minimum of five years. The Standard Soil Fertility Analysis shall include,
but is not necessarily limited to, the following parameters:
Acidity Exchangeable Sodium Percentage (by calculation)
Calcium Magnesium Phosphorus
Cation Exchange Capacity Manganese Potassium
Copper Percent Humic Matter Sodium
Base Saturation (by calculation) pH Zinc
8. Three copies of all required monitoring and reporting requirements as specified in Condition
III. 1., Condition III.2., Condition M. 3., Condition III.4., Condition III, S., Condition III.6.,
and Condition III, 7. shall be submitted annually on or before March 1 st of the year following
the residuals land application event to the following address:
NCDENR-DWQ
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
9. Noncompliance Notification:
The Permittee shall report by telephone to the Aquifer Protection Section of the Division's
Mooresville regional Office at telephone number [phone], as soon as possible, but in
no case more than 24 hours or on the next working day following the occurrence or first
knowledge of the occurrence of any of the following:
a. Any occurrence with the residuals land application program that results in the land
application of significant amounts of residuals that are abnormal in quantity, or
characteristic.
b. Any failure of the residuals land application program resulting in a release of material to
receiving waters.
c. Any time that self -monitoring information indicates that the residuals land application
program has gone out of compliance with the conditions and limitations of this permit or
the parameters on which the program system was designed.
d. Any process unit failure, due to known or unknown reasons, that render the residuals land
application program incapable of adequate residuals treatment.
e. Any spillage or discharge from a vehicle or piping system transporting residuals to the
application site.
Persons reporting such occurrences by telephone shall also file a written report in letter form
within five days following first knowledge of the occurrence. This report shall outline the
actions taken or proposed to be taken to ensure that the problem does not recur.

IV. GROUNDWATER REOUIREMENTS
I. Land Application Site Requirements:
_ a. Each land application site identified with a GW-A in the most recently -certified
At
tachment B of this permit is dominated b soils with a me
an ean seasonal high gh water table
greater than three feet below the land surface. Residuals land application events may
occur on these sites throughout the year.
b. Each land application site identified with a GW-B in the most recently -certified
Attachment B of this permit is dominated by soils with a mean seasonal high water table
between one and three feet below the land surface. Residual land application events on
these sites shall be prohibited from December through March, inclusive. No residuals
shall be land applied to these sites when the vertical separation between the depth of
residuals land application and the water table is less than three feet. The actual water
table depth for seasonally -restricted soils shall be verified by soil borings within 24 hours
prior to any residuals land application event that occurs from April through November,
inclusive. The number of borings advanced shall be sufficient to characterize water table
conditions across the land application site adequately. Any open borings shall be
properly filled with native soil, prior to the residuals land application event, to decrease
the chance of any residuals contaminating the groundwater.
2. Applicable Boundary Requirements:
a. The COMPLIANCE BOUNDARY for residuals land application programs is specified
by regulations in 15A NCAC 2L (i.e., "Groundwater Classifications and Standards").
The Compliance Boundary for each land application site is established at either 250 feet
from the residuals land application area or 50 feet within the property boundary,
whichever is closest to the residuals land application area. An exceedance of
Groundwater Quality Standards at or beyond the Compliance Boundary is subject to
immediate remediation action according to 15A NCAC 2L .0106 (d)(2).
b. The REVIEW BOUNDARY shall be established around each land application site
midway between the Compliance Boundary and the perimeter of the residuals land
application area. Any exceedance of Groundwater Quality Standards at the Review
Boundary shall require action in accordance with 15A NCAC 2L .0106 (d)(2).
I Additional Requirements:
a. Any groundwater quality monitoring, as deemed necessary by the Division, shall be
provided.
V. INSPECTIONS
I. Prior to each residuals land application event, the Permittee or his designee shall inspect the
residuals storage, transport, and application facilities to prevent malfunctions and
deterioration, operator errors, and discharges that may cause or lead to the release of wastes
to the environment, a threat to human health, or a nuisance. The Permittee shall maintain an
inspection log or summary including at least the date and time of inspection, observations
made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of
inspections shall be maintained by the Permittee for a period of five years from the date of the.
inspection and shall be made available to the Division or other permitting authority, upon
request.
10

ATTACHMENT A - Approved Residual Sources
Permit Number: WQ001 10.38
CNA Holdings Inc Tycona
CNA Holdings Inc- Sludge land application
Max D/T
Monitoring
Frequency
Monitoring Frequency
Cohdition Ill. 3 (metals &
Approved
Permit
Per
Condition Ill. 2.
nutdOhts)..& Ill. 4.(503
Mineralization
owner County . -Number
-is 603? year
TUP
pathogen & "R)
Rate
CNA Holdings. Inc Cleveland NCO004952
non 503 570.
Annually
Quarterly*
.30
Total
570.
*This permit is exempt from 503 pathogen and vector attraction requirements.
WQOO1 1038
Certified May 11, 2006

ATTACHMENT S - Approved Land Application Sites
Permit Number: WQ0011038
CNA Holdings Inc
CNA Holdings,lnc-A Sludge/Ho
FleldlZone .Jd
Owner lessee
County
NC-CL-1-01-01
Crawford, .Bobby
Cleveland
NC-CL-101-02
Crawford, Bobby
Cleveland
NC-CL-101-03
Crawford., Bobby
Cleveland
NC-CL-101-04
Crawford, Bobby
Cleveland
NC-CL-101-05
Crawford, Bobby
Cleveland
NC-CL-101-06
Crawford, Bobby
Cleveland
NC-CL-101-07
Crawford, Bobby
Cleveland
NC-CL-103-01
Austreli, Patricia Patterson, Ben
Cleveland
NC-CL-103A02
Austrell, Patricia 'Patterson, Ben
Cleveland
NC-CL-104-01
Ellis, Buford
Cleveland
NC-CL-109-01
Serratt, Victor
Cleveland
NC-CL-109-02
Sarratt, Victor
Cleveland
35011'09"
81 °34'32"
3501 WSW
81 °3412"
3501 V53"
81 °3432"
35010'42"
8103413"
35010'51"
81 °34'13"
35*10'43"
81 "34'02"
35°10'35"
81°3415"
35012'31"
8103225"
35012'31"
81032-34"
35011'19"
81034-31"
.35°1231"
8103225"
35°10'45"
81 035'20"
Dominant
Pacolet
Pacolet
Pacolet
Cecil
Pacolet
Pacolet
Pacolet
Pacolet
Pacolet
Pacolet
Pacolet
Net
crew
29.00
12.60
14,50
8.50
5.60
4.50
10.00
28.50
8.50
23.00
56.50
34.60
GWA- is dominated by soils with a mean seasonal high water table greater than three feet below the land surface. Residuals land application events may
occur on these sites year round.
Applioable
W Restrioti
GWA
GWA
GWA
GWA
GWA
GWA
GWA
GWA
GWA
GWA
GWA
GWA
W00011038 certified 05/01/2006 Page 1 of 1

Standard Operating Procedure and Operation and
Maintenance Plan for the Celanese Shelby Plant
WWTP Land Application Program
1. Purpose
a. Ensure 'the requirements of the Celanese Shelby Plant Land Application of
Residuals Permit# WQ0011038 are met.
2. Personnel
a. The following is a list of personnel in order they are to be contacted when
information needs to be shared.
i. EMA Resources inc.
1. Jeff Thompson - Project Manager
2. Boger Hartsell - Project Manager
3. Roy Whitaker - Director of Business Development
4. Brent Collins - Director of Technical Services
ii. Celanese Shelby Plant
1. Luis Mendoza - Site Leader
2. Pem Carter - EHS Lead
3. Mike Queen - ORC WWTP
3. Operational Functions
a. The operational function of this project it going to involve mixing the lagoon
with a tractor powered Houle pump to achieve a well -mixed and consistent
material that is suitable for land application. It is going to be spread at
agronomic rates that are determined using the Realistic Yield Expectations
(RYE) as outlined in the permit, the amount of other nutrient sources the
landowner and operator has applied, and the residuals nutrient and metal
sample that is current for that monitoring period. It is going to be spread
with a liquid applicator that will use pressure to spread the material in such a
( way as to achieve a consistent spread pattern. The material is going to be

land applied on fields that have a crop growing on them that are going to
either be grazed or cut for animal feed. Application rates will be reduced by
25% on fields that are primarily used for grazing in accordance with USDA-
NRCS 590. Grazed fields will be determined by the farmers and EMA
project managers.
4. Maintenance Schedule
a. EMA Resources Inc. will follow the maintenance schedule as recommended
by the EMA Resources Operations Manager (Mike Collins) for the equipment
necessary to complete the job.
5. Safety Measures
a. Celanese Shelby Plant and EMA Resources Inc. believe in operating in a
safety conscious manner and all employees participate in safety training that
is designed to help employees recognize safety issues and take steps to
prevent accidents from occurring. In addition, EMA Resources employees
have the authority to stop operations if they think any aspect of the operation
is going to cause environmental or personal harm.
6. Spill Response Plan
a. In the unlikely event of a spill, the following action shall be taken
immediately.
i. Management of Spill Clean-up Activities: The EMA Resources Project
Manager shall take immediate charge and initiate clean-up activities.
EMA Resources labor and equipment is to be utilized. In the event
additional labor and equipment is required, assistance may be
requested from Celanese Shelby Plant, The NC Department of
Transportation, and other private contractors as necessary.
ii. Halt the Source of the Spill: Such as a ruptured container or damaged
transport unit.
iii. Contain the Spill: Form a barrier. Sufficient quantities of straw shall
be used for such purposes. Earthen barriers may be constructed to
augment the straw bale containment area of the spill. The
Operations Manager or the person in charge on the spill site will be
advise the clean-up personnel where to get the straw, lime, and other

items necessary to complete the clean-up operation. le. local
farmers, farm supply centers, nurseries.
iv. Initial Clean -Up: Employ front-end loaders, vacuum equipment,
sludge application vehicles, and/or local septic tank service to
remove as much of the spilled material as possible. Straw and/or
sand should be scattered in the spill area to soak up the remaining
material. The straw and sand soaked material will be collected and
removed to a disposal area approved by representatives of the state
regulatory agency.
v. Final Clean -Up: Employ rotary brush sweeper if needed and apply
lime to the spill area upon the approval of the clean-up efforts by the
state regulatory representative. If the event occurs on private
property, the clean-up will be completed to the satisfactory of the
property owner and state regulatory representatives. The ultimate
goal will be restore the spill area to its original condition if possible.
vi. Notification: As soon as possible after the spill occurs, the EMA
Resources Project Manager or designee will notify the Davie County
and the EMA Resources main office. EMA Resources office staff are
then responsible for notifying other key EMA Resources personnel.
vii. Reporting: EMA Resources staff will notify the Mooresville regional
office of the NCDENR by telephone [phone] as soon as
possible, but not more than 24 hours after, or on the next working day
following the occurrence. The EMA Project Manager shall provide a
written report with 48 hours of the spill to the EMA Resources Director
of Technical Services and Celanese Shelby Plant staff. The report
shall list all relative information and actions taken. With the
assistance of EMA Resources personnel, and the Celanese Shelby
Plant personnel, a written report will be filed with the Mooresville
regional office within 5 days of the occurrence. For after hours
reporting, the Division's emergency number shall be called to report
all incidences [phone].

7. Inspection Plan
a. Inspection for the land application of residuals will conducted on a minimum
of a weekly basis at the land application site during land application
activities. The inspection frequency is based on the time frame that it is going
to take to complete the project and the amount of dry tons to be land
applied from this facility. The inspections will consist of inspecting a current
field that is being applied as well as inspecting random fields that have been
completed. Inspections will be conducted by Jeff Thompson - Project
Manager, and Boger Hartsell - Project Manager. These inspections will
consist of the following:
i. Verifying the application rates for each field that plan on receiving
material.
ii. Checking the calculated loads to ensure the correct amount of
residuals are being land applied.
iii. Ensure that all manned equipment has a copy of the permit and the
operation and maintenance plan.
iv. Ensure that the field has been flagged properly and that all buffers
are being adhered to.
v. Ensure proper signage has been posted
vi. Verify that the proper number of samples of the residuals have been
taken and that it meets the criteria for land application.
vii. The records will be kept in the EMA Resources project files in the main
office. Copies of all analyses and records will be forwarded to
Celanese Shelby Plant and kept on file.
viii. EMA Resources and Celanese Shelby Plant staff will immediately
inform the other part if any of the following conditions are noted.
1. Any occurrence with the distribution program resulting in the
land application of significant amounts of material that is
abnormal in quantity or characteristics.
2. Any failure of the distribution system that results in the release
to surface waters.
3. Any time that self -monitoring indicates that the facility has
gone out of compliance with the permit.
4. Any process failure that results in the system not adequately
treating the residuals.

5. Any spill or discharge from a vehicle or piping system during
residuals transportation.
6. Any release that requires immediate reporting outside normal
business hours shall be called in by EMA Resources staff to
DENR at [phone]. This number is to be called in the
event of a release to surface waters or imminent failure of a
storage system when the event occurs outside of normal
business hours.
8. Sampling and Monitoring Plan
a. Sampling for this project consists of sampling the residuals prior to land
application occurring in order to ensure that the residuals are suitable for
land application.
b. The samples will be collected from the storage lagoon that holds the
residuals
c. Jeff Thompson, Boger Hartsell, Brent Collins, Roy Whitaker or other designee
will be responsible for sample collection for nutrient and metal, TCLP, and
fecal coliform.
d. Nutrient, metal and TCLP sample aliquots will be collected randomly and
consist of at least 7 individual aliquots mixed together in order to get the
composite sample for these parameters.
e. The residuals will be sampled annually for TCLP including the RClls.
f. Metal and nutrient parameters will be collected and analyzed based on the
requested dry ton numbers in the permit application.
g. Residuals will be sampled for fecal coliform to demonstrate pathogen
requirements have been met. Seven separate samples will be collected and
analyzed.
9. Environmental Impacts
a. The environmental impacts for residuals may be affected by this procedure.
b. This procedure helps assure that land application is conducted in a safe and
efficient manner while ensuring compliance with the laws and regulations
and to minimize exposure, negative environmental impacts and public
relation concerns.

State of North Carolina
Department of Environment and Natural Resources
fs=x Division of Water Resources
�.,_ - W
`� s �^
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 11-13
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit website at:
http:/1portal. ncdenr. org/web/wg/aps/1au
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-13, FORM: DCAR 11-13, or FORM: SDR 11-13).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-13):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-13) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
® For new or renewed permits, submit a separate certification for each source facility.
❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
® Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 11-13 Page 1 of 1

RESID L A:LS SOURCE FACILITY SUMMARY
Applicant's name: CNA Holdings, Inc. Celanese Shelby Plant
Status
o
Code
Facility Permit Holder
Facility Name
County
Permit Number
Maximum Dry Tons Per Year
Current b
Proposed
R
CNA Holdings, Inc.
Celanese Shelby Plant
Cleveland
NC0004952
570
334
'Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted)
b The amount of residuals currently permitted for distribution, land application, or disposal (Le, not applicable to new facility).
SUMMARY FOR FORM: RSC 11-13 Page 1

State of North Carolina
Department of Environment and Natural Resources
�f Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
FORM: RSC 11-13
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: CNA Holdings, Inc. Celanese Shelby Plant
2. Facility permit holder is: Q Federal, E; State, 0: Local Government, or M. Private.
Facility permit issued by: Div. of Water Resources, 0 Div. of Environmental Health,
or 0 Other (explain ).
3. Facility contact person and title: Luis Mendoza, Site Leader
Complete mailing address: 2525 Blacksburg Road
City: Grover State: NC Zip: 28073
Telephone number: 704 480-5728 E-mail address: [e-mail]
4. Facility physical address: 2525 Blacksburg Road
City: Grover State: NC Zip: 28073 w
Coordinates: Latitude: 35' 12' 26.2" Longitude: 81' 31' 27.6"
Datum: NAD83 Level of accuracy:.01"
Method of measurement: GPS
5. Purpose of the facility:
0 treatment of municipal wastewater, E] treatment of 100% domestic wastewater,
. treatment of potable water, 0 treatment of 100% industrial wastewater,
treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: 98.6 % industrial and 1_4 % domestic)
0 other (explain E rt' ).
6. Does the facility have an approved pretreatment program: Ej Yes E No
7. Facility permitted/design flow MGD and facility average daily flow:.422 MGD
8. Average amount of residuals being generated at this facility � 334 Wdry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Aerobic Digester: 490,000 gallons
Type and volume of residuals storage (i.e., outside of residuals treatment units): Two Earthen Lagoons: South Lagoon:
2.23 million gallons, North Lagoon:1.66 million gallons
H. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
Ej 40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
-- 2. Specify if residuals are defined under 15A NCAC 02T.1102(6) as:
Biological Non -Biological
FORM: RSC 11-13 Page 1 of 5

Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: El yes E no.
If yes, list the number(s)
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: E: yes M. no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: ESC Lab Sciences and Date of analysis: September 30, 2014
Passed corrosivity test: E, yes Ej no. pH: s.u. (2 < pH < 12.5)
Passed ignitability test: Z yes no. Flashpoint: > 170 T (> 140°F)
Passed reactivity test: yes Ono. HCN: <0.125 mg/kg (<250) & HZS: <25 mg/kg (<500)
TCLP Parameter
Limit
(mg/1)
Result
(mg/1)
TCLP Parameter
Limit
(mg/1)
Result
(mg/1)
Arsenic
5.0
<0.45
Hexachlorobenzene
0.13
<0.10
Barium
100.0
<1.4
Hexachloro-1,3-Butadiene
0.5
<0.10
Benzene
0.5
<0.050
Hexachloroethane
3.0
<0.10
Cadmium
1.0
<0.45
Lead
5.0
<0.45
Carbon Tetrachloride
0.5
<0.050
Lindane
0.4
<0.0050
Chlordane
0.03
<0.0050
Mercury
0.2
<0.010
Chlorobenzene
100.0
<0.050
Methoxychlor
10.0
<0.0050
Chloroform
6.0
<0.25
Methyl Ethyl Ketone
200.0
<0.50
Chromium
5.0
<0.45
Nitrobenzene
2.0
<0.10
m-Cresol
200.0
<0.10
Pentachlorophenol
100.0
<0.10
o-Cresol
200.0
<0.10
Pyridine
5.0
<0.10
p-Cresol
200.0
<0.10
Selenium
1.0
<0.45
Cresol
200.0
<0.10
Silver
5.0
<0.45
2,4-D
10.0
<0.0020
Tetrachloroethylene
0.7
<0.050
1,4-Dichlorobenzene
7.5
<0.10
Toxaphene
0.5
<0.010
1,2-Dichloroethane
0.5
<0.050
Trichloroethylene
0.5
<0.050
1,1-Dichloroethylene
0.7
<0.050
2,4,5-Trichlorophenol
400.0
<0.10
2,4-Dinitrotoluene
0.13
<0.10
2,4,6-Trichlorophenol
2.0
<0.10
Endrin
0.02
<0.0050
2,4,5-TP (Silvex)
1.0
<0.0020
Heptachlor and its Hydroxide
0.008
<0.0050
Vinyl Chloride
0.2
<0.050
FORM: RSC 11-13 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For Distribution/Land Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: A&L Eastern Laboratories, Inc. and Date of analysis: 9/26/14
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(mg/kg)
Monthly Average
Concentration Limits
(Class A Only)
(mg/kg)
Result
(mg/kg)
Arsenic
75
41
10
Cadmium
85
39
<2
Copper
4,300
1,500
271
Lead
840
300
45
Mercury
57
17
1
Molybdenum
75
n/a
14
Nickel
420
420
99
Selenium
100
100
<5
Zinc
7,500
2,800
592
b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory `'. and Date of analysis:
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic
(mg/kg)
Chromium
(mg/kg)
Nickel
(mg/kg)
> 0 but < 25
30
200
210
> 25 but < 50
34
220
240
> 50 but < 75
39
260
270
> 75 but < 100
46
300
320
> 100 but < 125
53
360
390
> 125
62
450
420
Result (mgV
FORM: RSC 11-13 Page 3 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For Distribudon/Land Application of Class A or Equivalent.
A fecal coliform density that is demonstrated to be less than 1,000 NUN per gram of total dry solids,
or
A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
Alternative 1 [15A NCAC 02T.I 106(b)(3)(A)] - Time/Temperature Compliance.
El Alternative 2 [15A NCAC 02T. I 106(b)(3)(B)] - Alkaline Treatment.
Alternative 3 [15A NCAC 02T. 1 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 4 [15A NCAC 02T.1106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: 0 composting, 0 heat drying, El heat treatment,
[3 thermophilic aerobic digestion, El beta ray irradiation,
0 gamma ray irradiation, or 0 pasteurization.
b. For Land Application of Class B:
. Alternative 1 [15A NCAC 02T.1106(c)(1)] -Fecal Coliform Density Demonstration.
Alternative 2 [15A NCAC 02T.1106(c)(2)] -Process to Significantly Reduce Pathogens (PSRP).
Specify one: 0aerobic digestion, 0, air drying, El anaerobic digestion,
Q composting, or 0 lime stabilization.
c. For Surface Disposal:
ED
Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item 11.7a. above.
Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II.7b. above.
Exempt - If Daily Cover Alternative is chosen in Item 11.8. below [15A NCAC 02T. 1 106(a)(2)].
' Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
Alternative 1 [15A NCAC 02T.1107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
EJ Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization.
Alternative 7 [15A NCAC 02T. 1 107(a)(7)] - Drying of Stabilized Residuals.
Alternative 8 [15A NCAC 02T. 1 107(a)(8)] - Drying of Unstabilized Residuals.
0 Alternative 9 [15A NCAC 02T. 1 107(a)(9)] - Injection.
EJ Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
EJ Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.1107(b)(2)].
Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 11-13 Page 5 of 5

Data use subject to license. TN Scale 1 : 20,800
0 fi00 12M I— zCW 3000 m © DeLorme. Topo USA® 8. MN o.0-M a iw - sw no M
www.delorme.com V = 1,733.3 ft Data Zoom 13-3

Groundwater j Evaporative Public
and Other LWater Storm
Losses Water
-�-_— 0.480 MGD
0.003 MGD 0.120 MGD 0.025 MGD
Process Potable
i Water Water
utility Performance Vectra Compounding Sanitary
Wastewater Fibers Process Wastewater
0.029 MGD 0.212 MGD 0.017 MGD 0.158 MGD 0.006 MGD
Headworks Equalization Equalization Equalization Mixing Box
Box Basin A I Basin B Basin C
South Aeration
Basin
[Tertiar�yFilter Polishing Polishing —Polishing RAS
Pond C Pond B Pond A
0.450 MGD North Aeration ;
i Basin
Outfa11001 to ,Y,--RAS"-
Buffalo Creek
Waste Activated Sludge (WAS)
cLL END North Sludge South Sludge Sludge Figui
Basin — Basin Digestion Water Balance
—� Gt Service ! i_ i CNA Hold
Standby Mode —� - � Waste Sludge Cicona Fa
- - ' ► Land Application (Off -Site) Grove

Celanese Shelby Plant WWTP
Quantitative Justification for Residuals Production Rate
The production at the manufacturing plant is at only a minimum of it capacity.
Tile=fftow=-into the WWTP is minimum compare to capacity. The two residuals
storage'lagoons have the ability to hold 5+ years residuals production. Residuals
were last removed in 2009. Celanese Shelby Plant is projecting to budget a land
application event in 2015. It is estimated that 1.5 to 2.0 million gallons of
residuals currently are in the lagoons.
The annual dry ton calculation is based on the percent solids of the analysis and the
removal of 2,000,000 gallons per event and a projected percent solids of 4%.
Gallons lbs/Gal. %Solids Dribs. lbs/ton Dry Tons
2,000,000 x 8.34 x 0.04 = 6675200 - 2000 = 333.6

t.•A-B S-C•!•E-N-C•E•S
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Mr. Brent Collins
EMA Resources
755 Yadkinville Road
Mocksville, NC 27028
Report Summary
Tuesday September 30, 2014
Report Number: L72299O
Samples Received: 09/20/14
Client Project:
Description: Celanese - Shelby Plant
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Entire Report Reviewed By:
Terrie Fudg ESC resentative
La bora tory Certifica tion Numbers
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BIO041, ND - R-140. NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
This report may not be reproduced, except in full, without written approval from Esc Lab sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 3

_AOESC
L-A-6 S•C•!•E•N-C•E•5
Mr. Brent Collins
EMA Resources
755 Yadkinville Road
Mocksville, NC 27028
Date Received
Description
Sample ID
Collected By
Collection Date
September 20, 2014
Celanese - Shelby Plant
CELANESE - SHELBY PLANT
Roy Whitaker
09/19/14 13:30
REPORT OF ANALYSIS
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
September 30,2014
ESC Sample # : L722990-01
Site ID
Project
Parameter
Result Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Corrosivity
Non-Corrosiv
9045D
09/24/14
0900
KBC
1
Ignitability
See Footnote
Deg. F
D93/101
09/26/14
1554
AS
1
Reactive CN (SW846 7.3.3.2)
BDL
0.125
mg/kg
9012B
09/24/14
1539
JAL
1
Reactive Sulf.(SW846 7.3.4.1)
BDL
25.
mg/kg
9034/90
09/24/14
1448
DR
1
TCLP Extraction
-
1311
09/24/14
0744
BG
1
Mercury
BDL
0.010
mg/l
0.20
7470A
09/25/14
0842
BRJ
1
Arsenic
BDL
0.45
mg/l
5.0
6010C
09/24/14
2039
JDG
1
Barium
BDL
1.4
mg/l
100
6010C
09/24/14
2039
JDG
1
Cadmium
BDL
0.45
mg/l
1.0
6010C
09/24/14
2039
JDG
1
Chromium
BDL
0.45
mg/1
5.0
6010C
09/24/14
2039
JDG
1
Lead
BDL
0.45
mg/1
5.0
6010C
09/25/14
1051
JDG
1
Selenium
BDL
0.45
mg/l
1.0
6010C
09/24/14
2039
JDG
1
Silver
BDL
0.45
mg/l
5.0
6010C
09/24/14
2039
JDG
1
TCLP ZHE Extraction
-
1311
09/23/14
0754
LJN
1
TCLP Volatiles
Benzene
BDL
0.050
mg/1
0.50
8260B
09/23/14
1757
JC
1
Carbon tetrachloride
BDL
0.050
mg/l
0.50
8260B
09/23/14
1757
JC
1
Chlorobenzene
BDL
0.050
mg/1
100
8260B
09/23/14
1757
JC
1
Chloroform
BDL
0.25
mg/1
6.0
8260B
09/23/14
1757
JC
1
1,2-Dichloroethane
BDL
0.050
mg/l
0.50
8260B
09/23/14
1757
JC
1
1,1-Dichloroethene
BDL
0.050
mg/1
0.70
8260B
09/23/14
1757
JC
1
2-Butanone (MEK)
BDL
0.50
mg/1
200
8260B
09/25/14
0539
JC
1
Tetrachloroethene
BDL
0.050
mg/l
0.70
8260B
09/23/14
1757
JC
1
Trichloroethene
BDL
0.050
mg/l
0.50
8260B
09/23/14
1757
JC
1
Vinyl chloride
BDL
0.050
mg/1
0.20
8260B
09/23/14
1757
JC
1
1,4-Dioxane
BDL
5.0
mg/1
8260B
09/23/14
1757
JC
1
Surrogate Recovery
Toluene-d8
96.1
% Rec.
114.
8260B
09/23/14
1757
JC
1
Dibromofluoromethane
94.1
% Rec.
125.
8260B
09/23/14
1757
JC
1
a,a,a-Trifluorotoluene
113.
% Rec.
114.
8260B
09/23/14
1757
JC
1
4-Bromofluorobenzene
109.
% Rec.
128.
8260B
09/23/14
1757
JC
1
TCLP Pesticides
Chlordane
BDL
0.0050
mg/l
0.030
8081
09/26/14
0849
LKD
1
Endrin
BDL
0.0050
mg/1
0.020
8081
09/26/14
0849
LKD
1
L722990-01 (IGNITABILITY) - Did
Not Ignite @ 170
F
Page 2 of 3

L•A•B S-C•I,E•N•C•E•S
REPORT OF ANALYSIS
Mr. Brent Collins
EMA Resources
755 Yadkinville Road
Mocksville, NC 27028
Date Received September 20, 2014
Description Celanese - Shelby Plant
Sample ID CELANESE - SHELBY PLANT
Collected By Roy Whitaker
Collection Date 09/19/14 13:30
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
September
30,2014
ESC Sample
# L722990-01
Site ID
Project
Parameter
Result
Det. Limit
Units
Limit
Method
Date/Time
By
Dil
Heptachlor
BDL
0.0050
mg/l
0.0080
8081
09/26/14
0849
LKD
1
Lindane
BDL
0.0050
mg/l
0.40
8081
09/26/14
0849
LKD
1
Methoxychlor
BDL
0.0050
mg/l
10.
8081
09/26/14
0649
LKD
1
Toxaphene
BDL
0.010
mg/l
0.50
8081
09/26/14
0849
LKD
1
Surrogate Recovery
Decachlorobiphenyl
85.8
% Rec.
123.
8081
09/26/14
0849
LKD
1
Tetrachloro-m-xylene
48.9
% Rec.
114.
8081
09/26/14
0849
LKD
1
TCLP Herbicides
2,4,5-TP (Silvex)
2,4-D
Surrogate Recovery
2,4-Dichlorophenyl Acetic Acid
TCLP Semi-Volatiles
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3-butadiene
Hexachloroethane
Nitrobenzene
Pyridine
3&4-Methyl Phenol
2-Methylphenol
Pentachlorophenol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogate Recovery
2-Fluorophenol
Phenol-d5
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
p-Terphenyl-d14
BDL
0.0020
mg/l
1.0
8151A
09/26/14
1845 KLM 1
BDL
0.0020
mg/l
10.
8151A
09/26/14
1845 KLM 1
64.8
% Rec.
8151A
09/26/14
1845 KLM 1
BDL
0.10
mg/l
7.5
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
0.13
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
0.13
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/1
0.50
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
3.0
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
2.0
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
5.0
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
400
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
200
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
100
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/1
400
8270D
09/27/14
1436 KMF 1
BDL
0.10
mg/l
2.0
8270D
09/27/14
1436 KMF 1
34.7
% Rec.
87.0
8270D
09/27/14
1436 KMF 1
23.7
% Rec.
67.0
8270D
09/27/14
1436 KMF 1
62.1
% Rec.
120.
8270D
09/27/14
1436 KMF 1
67.2
% Rec.
122.
8270D
09/27/14
1436 KMF 1
77.7
% Rec.
148.
8270D
09/27/14
1436 KMF 1
59.2
% Rec.
149.
8270D
09/27/14
1436 KMF 1
BDL - Below Detection Limit
Det. Limit - Estimated Quantitation Limit(EQL)
Limit - Maximum Contaminant Level as established by the US EPA
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 09/30/14 12:21 Printed: 09/30/14 15:21
L722990-01 (IGNITABILITY) - Did Not Ignite @ 170 F
r , Page 3 of 3

Celanese Shelby Plan
TKN
34300
mg/kg
NH3
4590
mg/kg
Organic N
29710
mg/kg
NO2NO3
2
mg/kg
1st yr min. rate
0.2
%
2nd yr min. rate
3rd yr min. rate
4th yr min. rate
5th yr min. rate
1st year PAN Calculation (Surface)
Lbs/DT PAN = [min. rate x (TKN - NH3) + (.5NH3) + NO2NO31 x .002
Lbs/DT = 0.2 29710 2295 2 x .002
Lbs/DT = 16.478
2nd year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 2 x 1 st yr organ ic N - 2nd yr mineralized organic N)] x .002
Lbs/DT =1 0.10 29710 6942 x .002
Lbs/DT = 1 4.76
3rd year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 3 x (2nd yr organic N - 3rd yr mineralized organic N)] x .002
Lbs/DT = 0.06 23768 2376.8 x .002
Lbs/DT = 2.14
4th year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 4 x (3rd yr organic N - 4th yr mineralized organic N)] x .002
Lbs/DT =1 0.026 21391.2 1070 1 x .002
Lbs/DT =1 1.02
5th year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 5 x 4th yr organic N - 5th yr mineralized organic N)] x .002
Lbs/DT = 0.0125 20322 508 x .002
Lbs/DT =1 0.50
Five Year Maximum Adjusted PAN = 24.88 Lbs/DT
Five Year Maximum Adjusted PAN = 12441 mg/kg
0.1
0.05
0.025
0.0125

Celanese Shelby Plan
TKN
34300
mg/kg
NH3
4590
mg/kg
Organic N
29710
mg/kg
NO2NO3
2
mg/kg
1st yr min. rate
0.2
%
2nd yr min. rate
3rd yr min. rate
4th yr min. rate
5th yr min. rate
1st year PAN Calculation (injection)
Lbs/DT PAN = [min. rate x (TKN - NH3) + NH3 + NO2NO31 x .002
Lbs/DT = 0.2 29710 4590 2 x .002
Lbs/DT =1 21.07
2nd year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 2 x 1st yr organic N - 2nd yr mineralized organic N)] x .002
Lbs/DT =1 0.10 29710 5942 x .002
Lbs/DT =1 4.75
3rd year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 3 x (2nd yr organic N - 3rd yr mineralized organic N)] x .002
Lbs/DT =1 0.05 23768 2376.8 x .002
Lbs/DT =1 2.14
4th year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 4 x 3rd yr organic N - 4th yr mineralized organic N)] x .002
Lbs/DT =1 0.025 21391.2 1070 1 x .002
Lbs/DT =1 1.02
5th year Residual PAN Calculation
Lbs/DT PAN = [min. rate yr 5 x 4th yr organic N - 5th yr mineralized organic N)] x .002
Lbs/DT = 0.0125 20322 508 1 x .002
Lbs/DT = 0.50
Five Year Maximum Adjusted PAN = 29.47 Lbs/DT
Five Year Maximum Adjusted PAN = 14736 mg/kg
0.1
0.05
0.025
0.0125

SAR Calculation
Na mg/l
Ca mg/I
Mg mg/l
106.929
389.13
181.812
Na
Ca
Mg
SAR
4.649
19.457
15.151
1.118
Na mil eq
Ca mil eq
Mg mil eq
4.649
19.457
15.151
Enter .% TS 3.27
Na mg/kg 3270
Ca mg/kg 11900
Mg mg/kg 5560
Enter
Data
Job Name:
Celanese Shelby Plant
Page 1

i
Page: 1 of 2
Report Number: 14-265-0202
Account Number: 46245
Submitted By: ROY WHITAKER
Send To: EMA RESOURCES INC
755 YADKINVILLE RD
MOCKSVILLE , NC 27028
Lab Number: 57682
Sample Id : CELAN ESE SHELBY PLANT WWTP
A&L Eastern Laboratories, Inc.
7621 Whitepine Road Richmond, Virginia 23237 (804) 743-Mi Fak [phone]
wwwaleaste.m.com
Project: CELANESE SHELBY PLANT
NC CERT # 257
REPORT OF ANALYSIS Date Sampled: 9/19/2014 13:30:00
Date Received: 09/22/2014 00:00
Date Reported: 09/26/2014
Total Solids *
3.27
32700
100.0
MW
09/23/2014 07:59
SM-2540G
Moisture "
96.73
100.0
MW
09/23/2014 07:59
SM-254OG
Total Kjeldahl Nitrogen
3.43
34300
10.0
JM
09/23/2014 08:05
SM-4500-NH3C-TKN
Total Phosphorus
0.38
3830
100
KM
09/23/2014 10:47
SW 6010C
Total Potassium
0.32
3180
100
KM
09/23/2014 10:47
SW 6010C
Total Sulfur
0.91
9110
100
KM
09/23/2014 10:47
SW 6010C
Total Calcium
1.19
11900
100
KM
09/23/2014 10:47
SW 6010C
Total Magnesium
0.56
5560
100
KM
09/23/2014 10:47
SW 6010C
Total Sodium
0.33
3270
100
KM
09/23/2014 10:47
SW 6010C
Total Iron
42000
100
KM
09/23/2014 10:47
SW 6010C
Total Aluminum
53600
100
KM
09/23/2014 10:47
SW 6010C
Total Manganese
1220
5
KM
09/23/2014 10:47
SW 6010C
Total Copper
271
5
KM
09/23/2014 10:47
SW 6010C
Total Zinc
592
5
KM
09/23/2014 10:47
SW 6010C
Ammonia Nitrogen
0.46
4590
10.0
JM
09/23/2014 08:05
SM-4500-NH3C
Organic N
2.97
29710
10.0
09/23/2014 08:05
CALCULATION
Nitrate+Nitrite-N
<2.00
2.00
JM
09/24/201411:30
SM-450ONO3F
Total Cadmium
<2.0
2.0
KM
09/23/2014 10:47
SW 6010C
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made 6wm4�/w
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
Debbie Holt

� I
Page: 2 of 2
Report Number: 14-265-0202
Account Number: 46245
Submitted By: ROY WHITAKER
Send To: EMA RESOURCES INC
755 YADKINVILLE RD
MOCKSVILLE , NC 27028
A&L Eastern Laboratories, Inc.
7621 ftitepine Road Richmond, Wginia.23237 (804)743-W1 fax [phone]
wvpw.aleastern.com
Project: CELANESE SHELBY PLANT
NC CERT # 257
REPORT OF ANALYSIS
Date Sampled: 9/19/2014 13:30:00
Lab Number: 57682
Date Received: 09/22/2014 00:00
Sample Id : CELANESE SHELBY PLANT WWTP
Date Reported: 09/26/2014
RESULT
RESULT
QUANTITATION
PARAMETER
..
Total Chromium
371
5
KM
09/23/2014 10:47 SW 6010C
Total Nickel
99
5
KM
09/23/2014 10:47 SW 6010C
Total Lead
45
5
KM
09/23/2014 10:47 SW 6010C
Total Arsenic
10.0
3.0
KM
09/23/2014 10:47 SW 6010C
Total Mercury
1.0
0.4
KM
09/24/2014 10:50 SW-7471 B
Total Selenium
<5.0
5.0
KM
09/23/2014 10:47 SW 6010C
pH (Standard Units) * 7.58
2.00
JM
09/23/2014 08:05 SW-9045D
Total Volatile Solids 29.55
295500
100.0
MW
09/23/2014 07:59 SM-2540G
Total Molybdenum
14
5
KM
09/23/2014 10:47 SW 6010C
Comments:
SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES.
QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Al". ALL OTHER QC DATA IS ACCEPTABLE.
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization.
i
Debbie Holt

Analytical Results
EMA Resources, Inc.
755 Yadkinville. Rd.
Mocksville, NC 27028
Receive Dater 09/18/2014
Reported: 09124%2014`
For.: Celeanese.Shelby Plant
Comments: Geometric Mean = 308 MPN/g
Sample Number
Parameter
Sample ID
Result
Unit
Method
Analyzed
Anal
140918-13='01
Fecal Coliforms
1
519
MPN/g
SM92210E-2006
09/19/2014
WL
140918-13-01
Percent Solids
1
7.70
%
SM254013-1997
09/19/2014:
WL
14091-8-13-02
Fecal Coliforms
2
329
MPN/g
SM92210E-2006
.0911912014
WL
140918-13-02
Percent Solids.
2
6.08'
6/0
SM254013-1997
09/19/2014
WL
14om-13-03
Fecal. Coliforms:
3
280
MPN/g.
SM92210E-2006
09I191201.4.
WL
140918-13-03
Percent Solids
3:
7..14
%;
SM2540B-1997
09/19/2014
WL
140918A 3-04
Fecal Coliforms:
4
<274..
MPNIg
SM9221 CE-2006
09/19/2014
WL
,40918-13-04
Percent Solids
4
T31
%
SM254OB-19.97
09/19/2014
WL
1:40918-13-05
Fecal Califorms
5.
<270
MPN/g
SM92210E-2006
09/19/2014
WL
140918-13-05
Percent Solids.
5
7.4
0%
SM25408-.1997
09/19/2014
WL
140918-13-06
Fecal. Coliforms
6
<285
MPNIg:
SM9221 CE-2006
09/1,912014
WL
140918-&13-06
Percent Solids
6
7.56:
%a
SM.2540B-1997
.09119/2014
WL
140418-1.3-07
Fecal Coliforms;
7
<283
MPNIg
SM92210E-2006
09/19/2014
WL
140918-13707
Percent Solids
7
7.07
%
SM254OB-1997
09/19/2014
WL
Respectfully
submitted,.
Dena Myers
NC Cert #440;
NCDW..Cert #37755,
EPA #NC00909
PO Box..228 • Statesville, NC`28687.704%872/4697
Page 1 of 3

9.
Client: -
p't j {J at? CIc
I STATESVIL., A LYTICA&'
Acidres&:,
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k,x 4 V T*C '+% 1-7
j
Court Street O • P... Bo 8'
122 x 22
Statesville'1VC 286$7
C.
0
(704) 872�tG97.
Contact Person.
Phone-#
FAX#:
_
Chaim:af
Po #
- Requisitioned by....(lime
Date)
Custody,Recor.d
Customer
sample too
'Lab #
Time $arripled.
(Grab'.Only)
Date.Sampied
(Grab Only)
o
a'.
Matrix
ww'
Parameters requested for analysis
s+
w
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Relinquished.by:
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Sampled by:
Time, ° -
ann,;&
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Transported by: jA/&j;
Relinquished by:
Time
am, pm
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Holding times- met: J
Received by:
Time,
am, pm
Date
Compliance work: t
Composite.Sampling #i:
Time begin am, pm
Date.,_J J
Non-compliance work:
Time end am, pm
Date ^1_ /
Lab Comments:
Composite Sampling:#2•
i
-
Time begin am, pm
Date
Time_end am, pm
Date

State of North Carolina
Department of Environment and Natural Resources
Division of Water Resources
�Division of Water Resources LAND APPLICATION SITE CERTIFICATION
INSTRUCTIONS FOR FORM: LASC 11-13
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit website at.
hp://ancdnr.org/web1wgas/laup/p
General — This certification provides detailed information of receiving sites for land application of Class B residuals (may include
water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this certification for review
without a corresponding application form (FORM: RLAP 11-13 or FORM: SDR 11-13).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Application Site Certification (FORM: LASC 11-13):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 11-13) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
® For new or renewed permits, submit the requested information for all land application sites.
❑ For modified permits, submit the requested information for only those sites that are new, transferred or affected by the
proposed modification.
Land Application Site Information:
® The status of the land application site with respect to this residuals land application program must be provided in table I. The
status categories and their corresponding codes are as follows:
♦ New (N) ♦ Renewed (R) ♦ Modified (M) ♦ Transferred (T) ♦ Deleted (D)
® Attach the following in accordance with each status code:
Status Code
Required Item
N
R
T
M
County Board
✓
Notification. doc
w
Land Owner
Agreement
(If applicable)
Setback Waiver
Agreement
An updated vicinity/setback map in accordance with the "Map Guidance
for Residuals Land Application Permits"
✓
✓
✓
A soils and agronomic evaluation in accordance with the "Soil Scientist
✓
Evaluation Policy"
An updated accounting of the land application site's cumulative
✓
✓
pollutant loading rates (CPLRs)
INSTRUCTIONS FOR FORM: LASC 11-13 Pagel of 3

Required Item Status Code
N R T M
For previously permitted sites without a soil series name indicated in the
Attachment B, submit County Soil Survey Map (or equivalent) clearly ✓
indicate the location of the land application site and in accordance with
the soil map requirements in the "Soil Scientist Evaluation Policy"
Acknowledgement of field transfer from Land Owner (Fields may not
be permitted to multiple Permittees over the same timeperiod)
* This item may be required for land application site with a status code "M", please contact the Division if you need assistant in
determining attachment requirements.
® Crop Type should include the most likely crop types for the life of the permit (five years).
® Predominant Soils Series Name must be either the name of the soil indicated in Attachment `B" of the existing permit, or
name of the soil series as provided by the licensed soil scientist.
® Predominant Soil Mapping Unit or Representative Slope: Either the Soil Mapping Unit or the representative slope of each
site must be provided. The predominant soil -mapping unit must be consistent with the predominant soil series name. Please
note that the soil mapping units are variable between Counties, so care should be taken in properly identifying the correct
mapping unit. If a representative slope is provided, it must be determined accordingly:
❑ For sites previously permitted for use, but do not have an established soil mapping unit (the mapping unit provides
information on both the soil series name and the slope of the soil), the Applicant may determine the representative slope
by using the average slope provided in the County Soil Survey (or equivalent). A soil type with a slope range of 4 - 8%
would have a representative slope of 6%.
❑ New Sites to be permitted must have slopes determined as part of the soils report prepared by a licensed soil scientist.
® Acceptable methods for determining location coordinates (i.e., latitude and longitude) and their corresponding codes are as
follows:
• Address Matching (ADD) • Digital or Raw Photo Extraction (EXT)
• Aerial Photography with Ground Control (AER) • Geodetic Quality GPS Survey (GEO)
• Cadastral Survey (SUR) • LORAN-C Navigation Device (LOR)
• Conversion from Coordinate Plane (CP) • Navigation Quality GPS (GPS)
• Conversion from Township -Section -Range (TSR) • Remote Sensing (RS)
• Conversion from Universal Trans Mere (UTM) • Zip Code Centroid (ZIP)
• Map Interpretation by Digital or Manual Extraction (MAP)
C. Waterbody and Classifications Information: (new sites only)
❑ Use an 8.5 by 11-inch copy of the portion of a 7.5-minute USGS Topographic Map to identify the location where the
residuals program activities are planned to occur as well as the closest downslope surface waters as clearly as possible. Each
map portion must be labeled with the map name and number, the identified location, and be of clear and reproducible quality.
❑ Surface water body classifications information may be found at: http://portal.ncdenr.or web/w / sp /csu
❑ Any questions concerning the waterbody and its classification, please contact the Division's regional offices.
❑ A list of the Division's regional offices, their county coverage, and their contact information may be downloaded at:
b=://portal.ncdenr.orp-/web/wq/home/ro
❑ General Instructions: There are 17 river basins in North Carolina. Each basin has associated waterbodies with assigned
subbasins, location descriptions, stream index numbers and established classifications.
1. Identify the project area on a 7.5 minute USGS topographical map (an 8.5 x 11-inch sheet showing the project area
should be submitted with the permit application regardless of whether a Stream classification was completed).
2. Determine the names of all the closest down slope surface waters from the project site. For unnamed tributaries,. see
Table 1: Unnamed Tributaries Entering Other States or for Specific Basin Areas. Label any unnamed tributaries as
"UT to stream name" as the waterbody name.
Open the link hM://h2o.enr.state.nc.us/bims/reports/reportsWB.html. If this link does not work, open
http://portal.ncdenr.or web/wq/ps/csu/classifications and download weekly -updated classification lists for named
waterbodies.
❑ Stream Classification Process: One of the options below may be used depending on the known initial project information.
❑ KNOWN BASIN WBERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Select roper basin from the List all Waterbodies in Neuse Basin sorted
Hydrologically
report. Sort hydrologically as this will provide the proper location descriptions if multiple
runs.
INSTRUCTIONS FOR FORM: LASC 11-13 Page 2 of 3

2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ KNOWN COUNTY WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
ance
1. Select the proper county from the List all Waterbodies in Alam--- county, hydrologically report.
2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ UNKNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Use the Clickable basin map to hydrologically sorted list report.
2. Click on the approximate project location to bring -up the hydrologically sorted list.
3. Locate the name of the identified waterbody (from General Directions) on the list.
4. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
5. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ Notes on index number and unnamed streams:
Unnamed Streams 15A NCAC 02B .0301M.
❑ Any stream which is not named in the schedule of stream classifications carries the same classification as that assigned
to the stream segment to which it is tributary (at the point of entry) except:
(A) unnamed streams specifically described in the schedule of classifications;
(B) unnamed freshwaters tributary to tidal saltwaters will be classified "C"; or
(C) after November 1, 1986, any newly created areas of tidal saltwater which are connected to Class SA waters by
approved dredging projects will be classified "SC" unless case -by -case reclassification proceedings are conducted.
❑ The following river basins have different policies for unnamed streams entering other states or for specific areas of the
basin:
Unnamed Tributaries Entering Other States or for Specific Basin Areas
Hiwassee River Basin
Streams entering Georgia or Tennessee shall be classified "C Tr."
Little Tennesse River
Basin And Savannah
River Drainage Area
Streams entering Georgia or Tennessee shall be classified "C Tr." Such streams in the Savannah
River drainage area entering South Carolina shall be classified "B Tr."
French Broad River
Basin
Streams entering Tennessee will be classified "B."
Watauga River Basin
Streams entering the State of Tennessee are classified "C."
Broad River Basin
Streams entering South Carolina are classified "C."
New River Basin
Streams entering the State of Tennessee are classified "C."
Catawba River Basin
Streams entering South Carolina are classified "C."
Yadkin -Pee Dee River
Basin
Streams entering Virginia are classified "C," and such streams entering South Carolina are
classified "C."
Lumber River Basin
Streams entering South Carolina are classified "C Sw."
Roanoke River Basin
Streams entering Virginia are classified "C." Except that all backwaters of John H. Kerr
Reservoir and the North Carolina portion of streams tributary thereto not otherwise named or
described shall carry the classification "B," and all backwaters of Lake Gaston and the North
Carolina portion of streams tributary thereto not otherwise named or described shall carry the
classification "C and B."
Chowan River Basin
Streams entering Virginia are classified "C."
Tar -Pamlico River
Basin
All drainage canals not noted in the schedule are classified "C Sw." except the main drainage
canals to Pamlico Sound and its bays which shall be classified "SC."
Pas uotank River Basin
All drainage canals not noted in the schedule are classified "C."
INSTRUCTIONS FOR FORM: LASC 11-13 Page 3 of 3

LAND .bvrPLICATION SITE CERTIFICATION
Applicant's name: CNA Holdings, Inc. Celanese Shelby Plant
Land application sites currently certified: 252.80 net acres and Total to be certified: 186.80 net acres.
I. LAND APPLICATION SITE INFORMATION (See Instruction B):
Status
Codes
Site/Field
Landowner(s)
Lessee(s) or Operator(s)
Net Acres
County
Crop(s)
Predominant Soil
b
Series Name
Mapping Unit
or Rep. Slope'
R
101-02
Bobby Crawford
12.6
Cleveland
Fescue
Pacolet
PaC2
R
101-03
Bobby Crawford
14.5
Cleveland
Fescue
Pacolet
PaC2
R
101-04
Bobby Crawford
8.5
Cleveland
Fescue
Pacolet
PaC2
R
101-05
Bobby Crawford
5.6
Cleveland
Fescue
Cecil
CaB2
R
101-06
Bobby Crawford
4.5
Cleveland
Fescue
Pacolet
PaC2
R
101-07
Bobby Crawford
10.0
Cleveland
Fescue
Pacolet
PaC2
R
104-01
Buford Ellis
23.0
Cleveland
Fescue
Pacolet
PaC2
R09
O1
Victorarratf
55 5
Jok
Iescue
pacoet
1'aC2
R
109 02
Vtctor SaXrait
34 G.
Cleveland
fescue
Pacolef
PaC2
R
t 03;
;victor Sarrat
18 0
Cleveland
Fescue.
acolet
1?aC2
D
C101 07
Bobby Grawwford
29 0
Cleveland
D
v103 01
Patrlcia`Austrel'j
28 5
Cleelarid
D
103-02
Patricia Austrell
8.5
Cleveland
a Status Code for land application sites are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ T (Transferred) ♦ D (Deleted)
b Soil Series Name (i.e. Appling, Cecil, etc.)
'Mapping Unit must be consistent with those used in the County Soil Survey (i.e, for a 2-8% slope Cecil in Anson County the mapping unit is CeB2)
FORM: LASC 11-13 Page 1

LAND i-it'PLICATION SITE CERTIFICATION
H. WATERBODY AND CLASSIFICATIONS INFORMATION (See Instruction Q:
Site/Field ID
Latitude
Longitude
Location
Location Method Code
Location Accuracy
Waterbody Subbasin and
Current and Proposed
Datum
Stream Index No.
Class
NAD 83
ADD
Nearest Second
7
E
NAD 83
ADD
Nearest Second
0
NAD 83
ADD
Nearest Second
I
NAD 83
ADD
Nearest Second
NAD 83
ADD
Nearest Second
V�710
NAD 83
ADD
Nearest Second
NAD 83
ADD
Nearest Second
ft 04
NAD 83
ADD
Nearest Second
Note: Please keep the site information (I.) and wateibody intormation (11.) of the same field on the same page.
FORM: LASC 11-13 Page 2

SITE SUMMARY
CNA Holdings, Inc. Celanese Shelby Plant
WQ0011038
Site ID: NC-CL-101
Owner: Bobby Crawford ItO
Address: 118 E. John Crawford Road
Shelby, NC 28152-8427
Phone: [phone]
Operator: Same
Field#
Total Acres
Net Acres
Crop(s)
Soil Series
Latitude &
Longitude
2
30.0
12.6
Fescue
Pacolet
35010'56" N
81034'22" W
3
17.0
14.5
Fescue
Pacolet
35010'53" N
81034'32" W
4
12.0
8.5
Fescue
Pacolet
35010'42" N
81034'13" W
5
7.5
5.6
Fescue
Cecil
35010'51" N
81034'13" W
6
7.8
4.5
Fescue
Pacolet
35010'43" N
81034'02" W
7
17.3
10.0
Fescue
Pacolet
35°10'35" N
81034' 15" W
TOTALS
91.6
55.7

SITE MONITORING REPORT
In pounds per acre
Project:
Ticona
Owner:
Bobby Crawford
Permit #:
W00011038
Crop:
Fescue
Weather Code
2
Operator:
Same
Field #:
CL101-04
Acres:
8.5
Site Code
2
Application Method
Surface
Date
Gallons
% Solids
Gal/Ac
DUAc
PAN
NO3-1\102
NH3
P
K
Pb
Zn
Cu
Ni
Cd
As
Hg
Se
Mo
06/05/07
65,000
3.67
7647.059
1.1703
38.1541
0.0023
16.6182
35.3430
7.0218
0.1381
1.3271
0.8894
0.1361
0.0047
0.0489
0.0028
0.0019
0.0421
06/06/07
71,500
3.67
8411.765
1.2873
41.9695
0.0026
18.2801
38.8773
7.7240
0.1519
1.4598
0.9784
0.1519
0.0051
0.0538
0.0031
0.0021
0.0463
06/07/07
58,500
3.67
6882.353
1.0533
34.3387
0.0021
14.9564
31.8087
6.3196
0.1243
1.1944
0.8005
0.1243
0.0042
0.0440
0.0025
0.0017
0.0379
06/08/07
84,500
3.67
9941.176
1.5214
49.6003
0.0030
21.6037
45.9459
9.1283
0.1795
1.7253
1.1563
0.1795
0.0061
0.0636
0.0037
0.0024
0.0548
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Totals:
Annual:
279,500
32882.35
5.0323
164.0625
0.0101
71.4584
151.9749
30.1937
0.5938
5.7066
3.8245
0.5938
0.0201
0.2103
0.0121
0.0081
0.1812
Total Cumulatives:
0.5938
5.7066
3.8245
0.5938
0.0201
0.2103
0.0121
0.0081
0.1812
Prior Years Cumulatives:
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Annual Dry
Tons
42.7744
267.00 1 2498.00
Permit Limits)
SOIL MONITORING
Soil pH
Lime Appl. Ton/AC
5.5
1 T/acre
Weather Code: 1) >90F 2) 70-90F 3)32-70F "' A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3 Moist 4) Wet
representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0011038
Hg I Se I Mo
500 89_nn -

SITE MONITORING REPORT
In pounds per acre
Project:
Ticona
Owner:
Bobby Crawford
Permit #:
WQ0011038
Crop:
Fescue
Weather Code
2
Operator:
Same
Field #:
CL101-05
Acres:
5.6
Site Code
2
Application Method
Surface
Date
Gallons % Solids
Gal/Ac
Dt/Ac
PAN
NO3-NO2
NH3
P
K
Pb
Zn
Cu
Ni
Cd
As
Hg
Se
Mo
09/03/09
26,000 2.59
4642.857
0.5014
13.6683
0.0692
9.3268
10.3297
2.3066
0.0532
0.5024
0.3109
0.0391
0.0010
0.0231
0.0011
0.0021
0.0431
09/04/09
26,000 2.59
4642.857
0.5014
13.6683
0.0692
9.3268
10.3297
2.3066
0.0532
0.5024
0.3109
0.0391
0.0010
0.0231
0.0011
0.0021
0.0431
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0,0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Totals:
Annual:
52,000
9285.714
1.0029
27.3366
0.1384
18.6537
20.6594
4.6133
0.1063
1.0049
0.6218
0.0782
0.0020
0.0461
0.0022
0.0042
0.0862
Total Cumulatives:
0.9622
9.1041
6.2259
0.9468
0.0281
0.3369
0.0203
0.0179
0.3921
Prior Years Cumulatives:
0.8559
8.0992
5.6041
0.8686
0.0261
0.2908
0.0181
0.0137
0.3059
Annual Dry
Tons
5.6162
Cu I Ni I Cd I As I Hg
89.00
SOIL MONITORING
Soil pH Lime App. Ton/AC
Weather Code: 1) >90F 2) 70-90F 3)32-70F -A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
I, . representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0011038

SITE MONITORING REPORT
In pounds per acre
Project:
Ticona
Owner:
Bobby Crawford
Permit #:
WQ0011038
Crop:
Fescue
Weather Code
2
Operator:
Same
Field #:
CL101-06
Acres:
4.5
Site Code
2
Application
Method
Surface
Date
Gallons % Solids
Gal/Ac
Dt/Ac
PAN
NO3-NO2
NH3
P
K
Pb
Zn
Cu
Ni
Cd
As
Hg
Se
Mo
06/12/07
52,000 3.67
11555.56
1.7685
57.6550
0.0035
25.1120
53.4072
10.6107
0.2087
2.0054
1.3440
0.2087
0.0071
0.0739
0.0042
0.0028
0.0637
06/13/07
39,000 3.67
8666.667
1.3263
43.2413
0.0027
18.8340
40.0554
7.9580
0.1565
1.5041
1.0080
0.1565
0.0053
0.0554
0.0032
0.0021
0.0477
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Totals:
Annual:
91,000
20222.22
3.0948
100.8963
0.0062
43.9460
93.4626
18.5687
0.3652
3.5095
2.3520
0.3652
0.0124
0.1294
0.0074
0.0050
0.1114
Total Cumulatives:
0.3652
3.5095
2.3520
0.3652
0.0124
0.1294
0.0074
0.0050
0.1114
Prior Years Cumulatives:
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Annual Dry
Tons
13.9265
SOIL MONITORING
Soil pH
Lime Appl. Ton/AC
5.7
1 T/acre
Weather Code: 1) >90F 2) 70-90F 3)32-70F -.A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00011038

SITE MONITORING REPORT
In pounds per acre
Project: Ticona
Owner: Bobby Crawford Permit #: W00011038 Crop: Fescue Weather Code 2
Operator: Same Field #: CL101-07 Acres: 10.0 Site Code 2
Application Method Surface
Date Gallons % Solids Gal/Ac Dt/Ac PAN NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo
09/03/09 136,500 2.59 13650 1.4742 40.1849 0.2034 27.4209 30.3694 6.7815 0.1563 1.4772 0.9140 0.1150 0.0029 0.0678 0.0032 0.0062 0.1268
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Totals:
Annual: 136,500 13650 1.4742 1 40.1849 0.2034 27.4209 30.3694 6.7815 1 0.1563 1.4772 0.9140 0.1150 0.0029 0.0678 0.0032 0.0062 0.1268
Total Cumulatives: 0.9503 8.9995 6.1059 0.9198 0.0273 0.3384 0.0199 0.0188 0.4073
Prior Years Cumulatives: 0.7940 7.5223 5.1919 0.8048 0.0244 0.2706 0.0167 0.0126 0.2805
Annual Dry Tons 14.7424
38.001 374..00 I 34.00 I 36.00 I 15.00 I 89.00 I -
SOIL MONITORING
Soil pH Lime Appl. Ton/AC
Weather Code: 1) >90F 2) 70-90F 3)32-70F --*A) Less than 1/2 inch rainfall B) Greater than 112 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
I, , representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. W00011038

State of North Carolina
Department of Environment and Natural Resources
Division of Water Resources
15A NCAC 02T .1100 — LAND OWNER AGREEMENT
Dtviston of Water Resources
FORM: LOA 11-13
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit we site at.
http://
portal. ncdenr.or /wg eb/wg/aps/lau
General — This document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of
Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not
submit this agreement for review without a corresponding application form (FORM: RLAP 11-13).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Owner Agreement (FORM: LOA 11-13):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 11-13) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ Prepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the
Applicant.
❑ A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator.
AGREEMENT FOR THE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND
.,)e undersigned landowner or his representative hereby permits:
Applicant's name: CNA Holdings, Inc., Celanese Shelby Plant
hereinafter referred to as the Permittee, to land apply residuals from the following facility(ies) onto the following land
application site(s) (i.e., see attached setback maps) in accordance with the stipulations and restrictions. as given in this
Agreement:
Site/Field.ID
Lease
(yes/no)
Land Use or
Cropping Patterns
Intended Use of Crops
Residuals Source
(optional)
Special note
(no-till/over-seed/
pasture)
we -ct - 1 o t - o -L
oat t= 0f#ZrW6
NC -C%- - 10 1 - 03
1�llS�c�cc%
Clt7rCov G zr+J
C -CL - 101 -0L4
afl'jre "!:�rvly s
IJG-CL - 101 -oS
/�f�`%
cwrnrf,69/166
tiJC-CL- 10t-p(�
l
Cf�I�GcJ0 /"6,
NC-Ct,-101 -0%
C/1lre, rG/Z/"6$
The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the
Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals.
leis Agreement shall remain in effect for the length of the Division's permit for the residuals land application program and
-all be renewed each time this permit is renewed.
The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and
stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement.
FORM: LOA 11-13 Pagel of 3

I. STIPULATIONS:
1. The landowner or his representative shall not enter into any additional residuals application contracts or agreements with another permitted
entity for the site(s) specified by this Agreement.
2. Should the landowner or his representative lease or otherwise permit the use of the land application site(s) to a third party, the landowner shall
be responsible to ensure that the third party agrees and complies with the terms and conditions of this Agreement.
3. The landowner or his representative shall adhere to the provisions of this Agreement until all of the site restrictions (under Section II) are met.
4. Notification of cancellation of this Agreement shall be immediately forwarded to NCDENR-DWR, Non -Discharge Permitting Unit, 1636
Mail Service Center, Raleigh, NC 27699-1636.
5. The Permittee must request and obtain a permit modification from the Division prior to a transfer of the land application site(s) to a new
landowner. In addition, the current landowner shall give a notice to the new landowner that gives full details of the residuals applied at the
land application site(s).
6. The Permittee has provided the landowner or his representative with information and data concerning the residuals land application program,
including an analysis of constituents of the residuals, residuals application methods, schedules for typical cropping patterns, a description of
the equipment used by the Permittee.
7. The Permittee will provide the landowner or his representative with a copy of the residuals permit prior to commencement of any residuals
land application event and a copy of the results of each soil analysis.
8. If the soil pH of the land application site(s) is not maintained at 6.0 or greater, sufficient amounts of lime shall be applied to achieve a final
soil pH of at least 6.0, unless an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for
the specified crop.
9. The landowner or his representative and the Permittee will agree on residuals application rates and schedules based on crop patterns, results of
soil samples, and the permitted application limits.
10. The landowner or his representative will provide the Permittee with information regarding the amount and analysis of other sources of
nutrients (e.g., fertilizer, unregulated animal waste, etc.) that have been applied to the land application site(s).
11. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns for
the land application site(s) prior to each planting season to enable the Permittee to amend this Agreement and schedule residuals land
application events at appropriate periods.
12. Specific residuals land application area boundaries shall be clearly marked on the land application site(s) by the Permittee, the landowner, or
his representative prior to and during a residuals land application event.
13. The landowner or his representative hereby authorizes the Permittee, local officials, and State officials or their representatives to; enter and
inspect any property, premises, or place on or related to the land application site(s) at any reasonable time for the purpose of determining
compliance with the permit; establish monitoring facilities on or near the land application site(s) as required by the permit; copy any records
that must be kept under the terms and conditions of the permit; take necessary leachate, surface water, groundwater, or soil samples during the
term of, and 12 months after termination of, this Agreement.
RESTRICTIONS:
1. Appropriate measures must be taken by the Permittee and/or the landowner or his representative to control public access to the land
application site(s) during active use and for the 12-month period following a residuals land application event. Such controls may include the
posting of signs that indicate the activities being conducted at the land application site(s).
2. Animals shall not be grazed on the land application site(s) for a 30-day period following a residuals land application event. Land application
sites that are to be used for grazing shall have fencing that will be used to prevent access during these periods after such residuals land
application events.
3. Food crops, feed crops, and fiber crops shall not be harvested for a 30-day period following a residuals land application event.
4. Food crops with harvested parts that touch the residuals/soil mixture and are totally above the land surface shall not be harvested for a 14-
month period following a residuals land application event.
5. Food crops with harvested parts below the surface of the land shall not be harvested for a 20-month period following a residuals land
application event when the residuals remain on the land surface for four months or longer prior to incorporation into the soil.
6. Food crops with harvested parts below the surface of the land shall not be harvested for a 38-month period following a residuals land
application event when the residuals remain on the land surface for less than four months prior to incorporation into the soil.
7. Turf grown on land where residuals are applied shall not be harvested for a 12-month period following a residuals land application event.
HI.ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY: (please check one)
15A NCAC 02L .0107(d) prohibits water supply wells within the compliance boundary. However, 15A NCAC 02T .0105(h) allows the
compliance boundary to be placed closer to the waste disposal area, such that the water supply well is situated outside of the compliance
boundary provided the groundwater standards can be met at the newly -established compliance boundary. Please mark one of the following;
❑ A re -defined compliance boundary is needed for field(s) ID:
(Please include the rationale for the requested re -location of the compliance boundary and attach a map showing the newly proposed
compliance boundary to the application package)
❑ A re -defined compliance boundary is not needed for this site.
IV. ACKNOWLEDGEMENT OF FIELD TRANSFER: (if needed)
❑ The land application field(s) ID: . is currently permitted under another
residuals land application program; Permit Number WQ: The land owner hereby acknowledge that by signing this
agreement, he/she is requesting that the field(s) be removed from the previously permitted residuals land application program and transferred
into the new program;
(Name of the new program)
FORM: LOA 11-13 Page 2 of 3

Landowner's Certification:
I certify that I am a deeded landowner of the above -referenced land application site(s) and am authorized to make decisions
regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through
a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of the
deeded landowners. I certify that the above -referenced land application site(s) are not included in any waste disposal contract or
agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement,
understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of
field transfer, and do hereby grant permission to the Permittee to land apply residuals to the land application site(s) as specified
herein.
Landowner name:o
Address: & �i �H.J CRC "J.oei-�)
City: vim/ $ V State: Al C Zip:
Phone: o 9, '�/ �l �3 E-mail address: p Z�
Signature: Date:
NORTH CAROLINA, _�GL�/G�/trr� COUNTY
I, the undersigned Notary Public do hereby certify that B0 3 a h'
personally appeared before me this day and acknowledged the due execution of the forgoing instrument.
n , i 7f./
WITNESS my hand and official seal this the
day of
Signature and seal:
My commission expires:
Lessee's/Operator's Certification:
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Lessee/operator name:
Address:
City:
Phone:
Signature:
Permittee's Certification:
State:
E-mail
Date:
Zip:
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Signing official name. CNA Hold' In elanese Shelby Plant Luis Mendoza Site Leader
Signature: Date: AIX3hy
FORM: LOA 11-13 Page 3 of 3

VICINITY MAP
COUNTY OWNER

Bobby Crawford
MNO-0-M
Site: N C-CL-101 1" = 2,083.3 ft Data Zoom 14-0

Bobby Crawford m l
MN V.0-M 0 100 M 000 a00 500
Site: NC-CL-101 1"=1,0W7ft Data Zoom14-0
Fields: 2-7

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.1 0, ON
il
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ki
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-now
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A
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MON
oil IEN% 1,
JI,
. . . . . . . . . . . . . .
..........

III
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.J:,,v 'n'� Sr' d J r. j;— ;•, $• �,,, $ r y, J 5 AFL ,
'�3' i J�y�.yY .L 1, 22 •J � t. p-� .•
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! sntp +� r

APPLICATION AREA MAP
m
Scale: 1" = . (oLd �' Field # 1—
Total
Acres sm
et Acres at
. > STREAM CID
APPLICATION AREA
- - - - - -
PRIVATE ROAD
. > DRAIN
HOUSE
FORESTED AREA
CDSURFACE WATER
❑
OUTBUILDING
UNSUITABLE
FENCE
WELL
STORAGE AREA
O
SOIL DESCRIPTION
SUITABLE FOR
®
INCORPORATION,
PROPERTY LINE
8-12% SLOPE
L i vvu gi60- -,)U !bl�
6t:�neL st o pe oP n a. p a:�-+k.s,c r-, of vAr.

DELORME
W I MI
420010,T

APPLICATION
Owner b bye!-�,cuFa, Scale: 1Field # 1-i- -
Total Acres Seems et Acres fee
• -> STREAM APPLICATION AREA - - - - - - PRIVATE ROAD
• - > DRAIN HOUSE FORESTE
C, SURFACE WATER
X FENCE
OSTORAGE AREA
PROPERTY LINE
D AREA
❑ OUTBUILDING UNSUITABLE
0 WELL (5
O SOIL DESCRIPTION ® SUITABLE FOR
INCORPORATION,
8-12% SLOPE

i

SITE SUMMARY
CNA Holdings, Inc. Celanese Shelby Plant
WQ0011038
Site ID: NC-CL-104
Owner: John Buford Ellis
Address: 1507 Wesson Road
Shelby, NC 28152
Phone: H: 704-487-6809 W: 704-482-9591 Ext. 250 M: 704-472-2010
Operator: Same (Farm Manger: Ronnie Hamrick: M: 704-418-1744)
Field#
Total Acres
Net Acres
Crop(s)
Soil Series
Latitude &
Longitude
1
30.5
23.0
Fescue
Pacolet
35011'19" N
81°34'31" W
TOTALS
30.5
23.0

SITE MONITORING REPORT
In pounds per acre
Project: Ticona
Owner: Buford Ellis Permit #: WQ0011038 Crop: Fescue Weather Code 2
Operator: Same Field #: CL104-01 Acres: 23.0 Site Code 2
Application Method Surface
Date Gallons % Solids Gal/Ac Dt/Ac PAN NO3-NO2 NH3 P K Pb Zn Cu Ni Cd As Hg Se Mo
08/28/09 117,000 2.59 5086.957 0.5494 14.9757 0.0758 10.2190 11.3178 2.5273 0.0582 0.5505 0.3406 0.0429 0.0011 0.0253 0.0012 0.0023 0.0472
08/29/09 130,000 2.59 5652.174 0.6105 16.6397 0.0842 11.3544 12.5753 2.8081 0.0647 0.6117 0.3785 0.0476 0.0012 0.0281 0.0013 0.0026 0.0525
08/31/09 104,000 2.59 4521.739 0.4884 13.3118 0.0674 9.0835 10.0602 2.2465 0.0518 0.4893 0.3028 0.0381 0.0010 0.0225 0.0011 0.0021 0.0420
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0,0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
0 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Totals:
Annual: 351.000 15260.87 1.6482 1 44.9272 0.2275 30.6569 33.9533 7.5818 0.1747 1.6515 1.0219 0.1286 0.0033 0.0758 0.0036 0.0069 0.1417
Total Cumulatives: 0.6391 6.1147 4.0131 0.5930 0.0190 0.2403 0.0130 0.0132 0.2834
Prior Years Cumulatives: 0.4644 4.4632 2.9912 0.4644 0.0157 0.1645 0.0094 0.0063 0.1417
Annual Dry Tons 37.9091
(Lifetime
SOIL MONITORING
Soil pH Lime Appl. Ton/AC
Weather Code: 1) >90F 2) 70-90F 3)32-70F """ A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0011038

State of North Carolina
Department of Environment and Natural Resources
_ Division of Water Resources
Dlvislon of Water Resources 15A NCAC 02T .1100 — LAND OWNER AGREEMENT
FORM: LOA 11-13
rlease use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit we site at:
httv.•//portal.ncdenr org/web/wa/a s/laar
General — This document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of
Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not
submit this agreement for review without a corresponding application form (FORM: RLAP 11-13).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Owner Agreement (FORM: LOA 11-13):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 11-13) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ Prepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the
Applicant.
❑ A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator.
AGREEMENT FOR THE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND
'ie undersigned landowner or his representative hereby permits:
Applicant's name: CNA Holdings, Inc. Celanese Shelby Plant
hereinafter referred to as the Permittee, to land apply residuals from the following facility(ies) onto the following land
application site(s) (i.e., see attached setback maps) in accordance with the stipulations and restrictions as given in this
Agreement:
Site/Field ID
Lease
(yes/no)
Land Use or
Cropping Patterns
Intended Use of Crops
Residuals Source
(optional)
Special note
(no-till/over-seed/
pasture)
At-CLP4 - f
�y �ts7�,eF
�7GF /ol1R6C
The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the
Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals.
;s Agreement shall remain in effect for the length of the Division's permit for the residuals land application program and
:11 be renewed each time this permit is renewed.
The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and
stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement.
FORM: LOA 11-13
Page 1 of 3

I. STIPULATIONS:
1. The landowner or his representative shall not enter into any additional residuals application contracts or agreements with another permitted
entity for the site(s) specified by this Agreement.
2. Should the landowner or his representative lease or otherwise permit the use of the land application site(s) to a third party, the landowner shall
be responsible to ensure that the third party agrees and complies with the terms and conditions of this Agreement.
3. The landowner or his representative shall adhere to the provisions of this Agreement until all of the site restrictions (under Section 11) are met.
4. Notification of cancellation of this Agreement shall be immediately forwarded to NCDENR-DWR, Non -Discharge Permitting Unit, 1636
Mail Service Center, Raleigh, NC 27699-1636.
5. The Permittee must request and obtain a permit modification from the Division prior to a transfer of the land application site(s) to a new
landowner. In addition, the current landowner shall give a notice to the new landowner that gives full details of the residuals applied at the
land application site(s).
6. The Permittee has provided the landowner or his representative with information and data concerning the residuals land application program,
including an analysis of constituents of the residuals, residuals application methods, schedules for typical cropping patterns, a description of
the equipment used by the Permittee.
7. The Permittee will provide the landowner or his representative with a copy of the residuals permit prior to commencement of any residuals
land application event and a copy of the results of each soil analysis.
8. If the soil pH of the land application site(s) is not maintained at 6.0 or greater, sufficient amounts of lime shall be applied to achieve a final
soil pH of at least 6.0, unless an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for
the specified crop.
9. The Iandowner or his representative and the Permittee will agree on residuals application rates and schedules based on crop patterns, results of
soil samples, and the permitted application limits.
10. The landowner or his representative will provide the Permittee with information regarding the amount and analysis of other sources of
nutrients (e.g., fertilizer, unregulated animal waste, etc.) that have been applied to the land application site(s).
11. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns for
the land application site(s) prior to each planting season to enable the Permittee to amend this Agreement and schedule residuals land
application events at appropriate periods.
12. Specific residuals land application area boundaries shall be clearly marked on the land application site(s) by the Permittee, the landowner, or
his representative prior to and during a residuals land application event.
13. The landowner or his representative hereby authorizes the Permittee, local officials, and State officials or their representatives to; enter and
inspect any property, premises, or place on or related to the land application site(s) at any reasonable time for the purpose of determining
compliance with the permit; establish monitoring facilities on or near the land application site(s) as required by the permit; copy any records
that must be kept under the terms and conditions of the permit, take necessary leachate, surface water, groundwater, or soil samples during the
term of, and 12 months after termination of, this Agreement.
RESTRICTIONS:
1. Appropriate measures must be taken by the Permittee and/or the landowner or his representative to control public access to the land
application site(s) during active use and for the 12-month period following a residuals land application event. Such controls may include the
posting of signs that indicate the activities being conducted at the land application site(s).
2. Animals shall not be grazed on the land application site(s) for a 30-day period following a residuals land application event. Land application
sites that are to be used for grazing shall have fencing that will be used to prevent access during these periods after such residuals land
application events.
3. Food crops, feed crops, and fiber crops shall not be harvested for a 30-day period following a residuals land application event.
4. Food crops with harvested parts that touch the residuals/soil mixture and are totally above the land surface shall not be harvested for a ]4-
month period following a residuals land application event.
5. Food crops with harvested parts below the surface of the land shall not be harvested for a 20-month period following a residuals land
application event when the residuals remain on the land surface for four months or longer prior to incorporation into the soil.
6. Food crops with harvested parts below the surface of the land shall not be harvested for a 38-month period following a residuals land
application event when the residuals remain on the land surface for less than four months prior to incorporation into the soil.
7. Turf grown on land where residuals are applied shall not be harvested for a 12-month period following a residuals land application event.
III. ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY: (please check one)
15A NCAC 02L .0107(d) prohibits water supply wells within the compliance boundary. However, 15A NCAC 02T 0105(h) allows the
compliance boundary to be placed closer to the waste disposal area, such that the water supply well is situated outside of the compliance
boundary provided the groundwater standards can be met at the newly -established compliance boundary. Please mark one of the following;
A re -defined compliance boundary is needed for field(s) ID: _
(Please include the rationale for the requested re -location of
compliance boundary to the application package)
❑ A re -defined compliance boundary is not needed for this site.
me compliance boundary and attach a map showing the newly proposed
IV. ACKNOWLEDGEMENT OF FIELD TRANSFER: (if needed)
❑ The land application field(s) ID: is currently permitted under another
residuals land application program; Permit Number WQ: The land owner hereby acknowledge that by signing this
agreement, he/she is requesting that the field(s) be removed from the previously permitted residuals land application program and transferred
into the new Droeram,
(Name of the new program)
FORM: LOA 11-13
Page 2 of 3

Landowner's Certification:
I certify that I am a deeded landowner of the above -referenced land application site(s) and am authorized to make decisions
regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through
a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of the
deeded landowners. I certify that the above -referenced land application site(s) are not included in any waste disposal contract or
agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement,
understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of
field transfer, and do hereby grant permission to the Permittee to land apply residuals to the land application site(s) as specified
herein.
Landowner name:
Address: �t
CState: jV Zip: / S
Phone: t) L� 4 / -- ` -1-6 10 E-mail address: , 4. ri
Signature: Date: 16 1if
NORTH CAROLINA, C t a,.J r� COUNTY
1, the undersigned Notary Public do hereby certify that c, 14-rQ [C z S
personally appeared before me this day and acknowledged the due execution of the forgoing instrument.
WITNESS my hand and official seal this the /y ;�91/
day of
Signature and seal:
My commission expires:
Lessee's/Operator's Certification:
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Lessee/operator name:
Address:
City:
Phone:
Signature:
Permittee's Certification:
State:
E-mail
Date:
Zip:
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Signing official name• A Holdin c. elanese ShelbyPlant Luis Mendoza Site Leader
Signature: Date: AIZ511Y
FORM: LOA 11-13 Page 3 of 3

VICINITY MAP
11 COUNT -I f, - OWNER - Bz�v' ,,L ous

Site: NC-CL-104 MNM.-M
0 oaa aoo oao eao 1" = 2,083.3 ft Data Zoomloco 14-0

J.;Buford Ellis ,m -
MN (7.0-M .I m
ryV 0 100 200 300 A00 S00
Site: NC-CL-104 1 = 1,066.7ft Data Zoom 14-0
Field: 1

0Ind

i
APPLICATION AREA MAP
Owner`��,t`fai-d� _ r
Scale: I« ��- Field # 1
• • -- > STREAM
• -
DRAIN
C�
SURFACE
WATER
--�--'-
FENCE
l
STORAGE AREA
PROPERTY LINE
Total ACreS .be2suau JNet Acres Se.e
APPLICATION AREA — —
HOUSE
❑ OUTBUILDING
0 WELL
O SOIL DESCRIPTION
— — — "
PRIVATE ROAD
FORESTED
AREA
UNSUITABLE
FOR
®SUITABLE
INCORPORATION,
8-12% SLOPE

-'�DELORME
nj

Site ID:
Owner:
Address:
Phone:
Operator:
SITE SUMMARY
CNA Holdings, Inc. Celanese Shelby Plant
WQ0011038
NC-CL-109
Victor Saratt
120 North Petty Street
Gaffney, SC 29340
Gaffney, SC 29342
W: 864-489-2756 H: 864-487-9831 M:864-839-7220
Same
Field#
Total Acres
Net Acres
Crop(s)
Soil Series
Latitude &
Longitude
1
67.0
55.5
Fescue
Pacolet
35012'31" N
81032'25" W
2
43.0
34.6
Fescue
Pacolet
35012'31" N
81032'34" W
3
36.5
18.0
Fescue
Pacolet
35010'53" N
81034'32" W
TOTALS
146.5
108.1

SITE MONITORING REPORT
In pounds per acre
Project:
Ticona
Owner:
Victor Sarratt
Permit #:
W00011038
Crop:
Fescue
Weather Code
2
Operator:
Same
Field #:
CL109-02
Acres:
34.6
Site Code
2
Application Method
Surface
Date
Gallons
% Solids
Gal/Ac
Dt1Ac
PAN
NO3-NO2
NH3
P
K
Pb
Zn
Cu
Ni
Cd
As
Hg
Se
Mo
05/24/07
32,500
3.67
939.3064
0.1438
4.6866
0.0003
2.0413
4.3413
0.8625
0.0170
0.1630
0.1093
0.0170
0.0006
0.0060
0.0003
0.0002
0.0052
05/25/07
117,000
3.67
3381.503
0.5175
16.8716
0.0010
7.3485
15.6286
3.1050
0.0611
0.5868
0.3933
0.0611
0.0021
0,0216
0.0012
0.0008
0.0186
05/26/07
26,000
3.67
751.4451
0.1150
3.7492
0.0002
1.6330
3.4730
0.6900
0.0136
0.1304
0.0874
0.0136
0.0005
0,0048
0.0003
0.0002
0.0041
05/29/07
123,500
3.67
3569.364
0.5463
17.8089
0.0011
7.7568
16.4968
3.2775
0.0645
0.6194
0.4152
0.0645
0.0022
0.0228
0.0013
0.0009
0.0197
05/30/07
130,000
3.67
3757.225
0.5750
18.7462
0.0012
8.1650
17.3651
3.4500
0.0679
0.6521
0.4370
0.0679
0.0023
0.0240
0.0014
0.0009
0.0207
05/31/07
143,000
3.67
4132.948
0.6325
20.6208
0.0013
8.9815
19.1016
3.7950
0.0746
0.7173
0.4807
0.0746
0.0025
0.0264
0.0015
0.0010
0.0228
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Totals:
Annual:
572,000
16531.79
2.5300
1 82.4834
0.0051
35.9261
76.4063
15.1801
0.2985
2.8690
1.9228
0.2985
0.0101
0.1058
0.0061
0.0040
0.0911
Total Cumulatives:
0.2985
2.8690
1.9228
0.2985
0.0101
0.1058
0.0061
0.0040
0,0911
Prior Years Cumulatives:
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Annual Dry
Tons
87.5383
Pb I Zn
SOIL MONITORING
Soil pH
Lime Appl. Ton/AC
5.7
1 T/acre
1338.00
Weather Code: 1) >90F 2) 70-90F 3)32-70F -A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0011038
Mo

SITE MONITORING REPORT
In pounds per acre
Project:
Ticona
Owner:
Victor Sarratt
Permit #:
W00011038
Crop:
Fescue
Weather Code
2
Operator:
Same
Field #:
CL109-03
Acres:
18.0
Site Code
2
Application Method
Surface
Date
Gallons % Solids
Gal/Ac
Dt/Ac
PAN
NO3-NO2
NH3
P
K
Pb
Zn
Cu
Ni
Cd
As
Hg
Se
Mo
05/24/07
97,500 3.67
5416.667
0.8290
27.0258
0.0017
11.7712
25.0346
4.9738
0.0978
0.9400
0.6300
0.0978
0.0033
0.0347
0.0020
0.0013
0.0298
06/01/07
117,000 3.67
6500
0.9948
32.4310
0.0020
14.1255
30.0416
5.9685
0.1174
1.1281
0.7560
0.1174
0.0040
0.0416
0.0024
0.0016
0.0358
06/05/07
58,500 3.67
3250
0.4974
16.2155
0.0010
7.0627
15.0208
2.9843
0.0587
0.5640
0.3780
0.0587
0.0020
0,0208
0.0012
0.0008
0.0179
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Totals:
Annual:
273,000
15166.67
2.3211
75.6722
0,0046
32.9595
70.0970
13.9265
0.2739
2.6321
1.7640
0.2739
0.0093
0.0970
0.0056
0.0037
0.0836
Total Cumulatives:
0.2739
2.6321
1.7640
0.2739
0.0093
0.0970
0.0056
0.0037
0.0836
Prior Years Cumulatives:
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
Annual Dry
Tons
g1.7796
7 00 12498.00 11338.00 I 374..00 I 34.00 I 36.00 I 15.00 I 89.00 I -
Permit Limits)
SOIL MONITORING
Soil pH
Lime Appl. Ton/AC
6.1
0
Weather Code: 1) >90F 2) 70-90F 3)32-70F "'"** A) Less than 1/2 inch rainfall B) Greater than 1/2 inch rainfall in past 24 hours
Site Condition Code: 1) Excessively Dry 2) Dry 3) Moist 4) Wet
representative of EMA Resources, Inc., hereby certify that this site was operated in compliance with the conditions of Nondischarge Permit No. WQ0011038

State of North Carolina
Department of Environment and Natural Resources
- � Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 —LAND OWNER AGREEMENT
FORM: LOA 11-13
rlease use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two conies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit we site at.,
httn: //aortal. rzcdenr orb/web/wa/aps/lap
General — This document is an agreement between the Applicant and land owner(s) of residuals receiving sites for land application of
Class B residuals (may include water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not
submit this agreement for review without a corresponding application form (FORM: RLAP 11-13).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Owner Agreement (FORM: LOA 11-13):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: LASC 11-13) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ Prepare a separate agreement for each set of land application sites that are owned or operated by an entity other than the
Applicant.
❑ A copy of the completed and appropriately executed agreement must be provided to the landowner and the lessee/operator.
AGREEMENT FOR THE LAND APPLICATION OF RESIDUALS TO PRIVATELY OWNED LAND
e undersigned landowner or his representative hereby permits:
Applicant's name: CNA Holdings, Inc. Celanese Shelby Plant
hereinafter referred to as the Permittee, to land apply residuals from the following facility(ies) onto the following land
application site(s) (i.e., see attached setback maps) in accordance with the stipulations and restrictions as given in this
Agreement:
Site/Field ID
Lease
(yes/no)
Land Use or
Cropping Patterns
Intended Use of Crops
Residuals Source
(optional)
Special note
(no-till/over-seed/
pasture)
/IBC- ` - 1 a9 - b
C-cc-log -©Z_
PW5rctZ&,r
NC -CL-- 16q - 0 3
PAsT c�
C_"ree gmC,e-
The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the
Permittee receives, in consideration, the use of the land application site(s) described above for the disposal of the residuals.
s Agreement shall remain in effect for the length of the Division's permit for the residuals land application program and
11 be renewed each time this permit is renewed.
The undersigned landowner or his representative and the Permittee agree to abide with the following restrictions and
stipulations until such time as written notification, given 30 calendar days in advance, modifies or cancels this Agreement.
FORM: LOA 11-13 Page 1 of 3

I. STIPULATIONS:
L The landowner or his representative shall not enter into any additional residuals application contracts or agreements with another permitted
entity for the site(s) specified by this Agreement.
2. Should the landowner or his representative lease or otherwise permit the use of the land application site(s) to a third party, the landowner shall
be responsible to ensure that the third party agrees and complies with the terms and conditions of this Agreement.
3. The landowner or his representative shall adhere to the provisions of this Agreement until all of the site restrictions (under Section Il) are met.
4. Notification of cancellation of this Agreement shall be immediately forwarded to NCDENR-DWR, Non -Discharge Permitting Unit, 1636
Mail Service Center, Raleigh, NC 27699-1636.
5. The Permittee must request and obtain a permit modification from the Division prior to a transfer of the land application site(s) to a new
landowner. In addition, the current landowner shall give a notice to the new landowner that gives full details of the residuals applied at the
land application site(s).
6. The Permittee has provided the landowner or his representative with information and data concerning the residuals land application program,
including an analysis of constituents of the residuals, residuals application methods, schedules for typical cropping patterns, a description of
the equipment used by the Permittee.
7. The Permittee will provide the landowner or his representative with a copy of the residuals permit prior to commencement of any residuals
land application event and a copy of the results of each soil analysis.
8. If the soil pH of the land application site(s) is not maintained at 6.0 or greater, sufficient amounts of lime shall be applied to achieve a final
soil pH of at least 6.0, unless an agronomist provides information indicating that the pH of the soil, residuals and lime mixture is suitable for
the specified crop.
9. The landowner or his representative and the Permittee will agree on residuals application rates and schedules based on crop patterns, results of
soil samples, and the permitted application limits.
10. The landowner or his representative will provide the Permittee with information regarding the amount and analysis of other sources of
nutrients (e.g., fertilizer, unregulated animal waste, etc.) that have been applied to the land application site(s).
11. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns for
the land application site(s) prior to each planting season to enable the Permittee to amend this Agreement and schedule residuals land
application events at appropriate periods.
12. Specific residuals land application area boundaries shall be clearly marked on the land application site(s) by the Permittee, the landowner, or
his representative prior to and during a residuals land application event.
13. The landowner or his representative hereby authorizes the Permittee, local officials, and State officials or their representatives to; enter and
inspect any property, premises, or place on or related to the land application site(s) at any reasonable time for the purpose of determining
compliance with the permit; establish monitoring facilities on or near the land application site(s) as required by the permit; copy any records
that must be kept under the terns and conditions of the permit; take necessary leachate, surface water, groundwater, or soil samples during the
term of, and 12 months after tennination of, this Agreement.
RESTRICTIONS:
1. Appropriate measures must be taken by the Permittee and/or the landowner or his representative to control public access to the land
application site(s) during active use and for the 12-month period following a residuals land application event. Such controls may include the
posting of signs that indicate the activities being conducted at the land application site(s).
2. Animals shall not be grazed on the land application site(s) for a 30-day period following a residuals land application event. Land application
sites that are to be used for grazing shall have fencing that will be used to prevent access during these periods after such residuals land
application events.
3. Food crops, feed crops, and fiber crops shall not be harvested for a 30-day period following a residuals land application event.
4. Food crops with harvested parts that touch the residuals/soil mixture and are totally above the land surface shall not be harvested for a 14-
month period following a residuals land application event.
5. Food crops with harvested parts below the surface of the land shall not be harvested for a 20-month period following a residuals land
application event when the residuals remain on the land surface for four months or longer prior to incorporation into the soil.
6. Food crops with harvested parts below the surface of the land shall not be harvested for a 38-month period following a residuals land
application event when the residuals remain on the land surface for less than four months prior to incorporation into the soil.
7. Turf grown on land where residuals are applied shall not be harvested for a 12-month period following a residuals land application event.
III. ALTERNATIVES FOR WATER SUPPLY WELLS INSIDE THE COMPLIANCE BOUNDARY: (please check one)
15A NCAC 02L .0107(d) prohibits water supply wells within the compliance boundary. However, 15A NCAC 02T 0105(h) allows the
compliance boundary to be placed closer to the waste disposal area, such that the water supply well is situated outside of the compliance
boundary provided the groundwater standards can be met at the newly -established compliance boundary. Please mark one of the following;
❑ A re -defined compliance boundary is needed for field(s) ID:
(Please include the rationale for the requested re -location of the compliance boundary and attach a map showing the newly proposed
compliance boundary to the application package)
❑ A re -defined compliance boundary is not needed for this site.
IV. ACKNOWLEDGEMENT OF FIELD TRANSFER: (if needed)
n The land application field(s) ID: is currently permitted under another
residuals land application program; Permit Number WQ: The land owner hereby acknowledge that by signing this
agreement, he/she is requesting that the field(s) be removed from the previously permitted residuals land application program and transferred
into the new oroeram
(Name of the new program)
FORM: LOA 11-13
Page 2 of 3

Landowner's Certification:
I certify that I am a deeded landowner of the above -referenced land application site(s) and am authorized to make decisions
regarding the use of the land application site(s) on behalf of other deeded landowners OR that I am otherwise authorized, through
a power of attorney or other legal delegation, to make decisions regarding the use of the land application site(s) on behalf of _the
deeded landowners. I certify that the above -referenced land application site(s) are not included in any waste disposal contract or
agreement with another municipality, contractor, or other permitted entity. Furthermore, I certify that I have read this Agreement,
understand the stipulations, restrictions, alternatives for water supply wells inside the compliance boundary, acknowledgement of
field transfer, and do hereby grant permission to the Pennittee to land apply residuals to the land application site(s) as specified
herein. `
Landowner name:
Address: / 120 wakze{ j�FTTY S�
City: _(_,WO�/VG� State: , 5 Zip: o� %3 540
Phone g�� - 7220 E-mail address:
Signature:
NORTH CAROLINA, C�LG'`�/�C/g r�l COUNTY
I, the undersigned Notary Public do hereby certify that V ZG7ofZ
personally appeared before me this day and acknowledged the due execution of the forgoing instrument.
WITNESS my hand and official seal this the
liiHi ii
day of ,a Gs ,20 /,`.�,WH/Tq'�
Signature and seal: ! Q °� 4A90�
�ef3 l T o2 = 1N
My commission expires: o�lo � 20
16
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Lessee's/Operator's Certification: �''Vi1,'PV�.�`�
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Lessee/operator name:
Address:
City: State: Zip:
Phone: E-mail address:
Signature: Date:
Permittee's Certification:
I certify that I have read this Agreement and do hereby agree to abide by the stipulations and restrictions as specified herein.
Signing official na . NA Holdin c. elanese Shelby Plant Luis Mendoza Site Leader
Signature: Date:
FORM: LOA 11-13 Page 3 of 3

VICINITY MAP
COUNTY OWNER 1' r �ar'b

AERIAL REFERENCE MAP
OWNER /1�&

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Site: NC-CL-109
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WDENR
North Carolina Department of Environment and Natural Resources
Pat McCrory
Governor
CNA HOLDINGS INC
2525 BLACKSBURG RD
GROVER NC, 280739641
Dear CNA Holdings Inc:
Division of Water Resources
Water Quality Programs
Thomas A. Reeder
Director
October 3, 2014
�Johli_E LLSkvarla II I
Seca ta'
OCT 7 2014 ,
i
Subject: Notice of Expiration (NOE)
CNA Holdings Inc -A Sludge/Ho
Land Application of Residual
Solids (503) System
Pen -nit No: WQ0011038
Cleveland County
Our records indicate that the above referenced permit for the operation of a Land Application of Residual
Solids (503) system is soon due for renewal. The most recent permit was effective on 5/3/2006, and will
expire on 4/30/2015. Per administrative code, the renewal application must be submitted six (6) months
prior to the expiration of your permit. Therefore, according to our records, you must submit your permit
renewal by 10/30/2014.
As the permit owner, you are responsible for maintaining this permit. Failure to do so may result in
assessment of civil penalties in accordance with North Carolina General Statute § 143-215.6A.
Renewal Instructions
Please respond to this notice by taking one of the following actions:
1. APPLY FOR PERMIT RENEWAL. Forms for renewal are available on-line at the Division of Water
Resources website at http://portal.ncdenr.org/web/wq/aps/lau/applications.
2. APPLY FOR PERMIT RESCISSION. If the Land Application of Residual Solids (503) system is no
longer active, or a permit is no longer needed, you may request to rescind your permit by submitting a
letter requesting rescission signed by the permit owner, and documentation from the Division's
Regional office that the system has been properly closed. If your system has never been constructed
or does not include treatment and storage units, please indicate so in your rescission request letter.
WATER QUALITY PERMITTING SECTION
1617 Mail Service Center, Raleigh, North Carolina 27699-1636
Location: 512 N. Salisbury St., Raleigh, NC 27604
Phone: [phone] FAX: [phone]
Internet: http://Portal.ncdenr.org/web/wa
An Equal Opportunity 1 Affirmative Action Employer

Please submit the necessary documentation to the following address:
Division of Water Resources
Water Quality Non -Discharge Permitting Unit
1617 Mail Service Center
Raleigh, NC 27699-1636
Thank you in advance for your cooperation and timely response. If you have any questions regarding
renewal of your pennit, please contact our permitting staff by phone at [phone].
Sincerely,
Jon Risgaard, Supervisor
Division of Water Resources
, Mooresville Regional -Office, Water Quality Non -Discharge Permitting Unit
Permit Application File WQ0011038