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HomeMy WebLinkAboutNCG500210_Regional Office Historical File Pre 2018 F ILE ROY COOPER Governor MICHAEL S. REGAN Secretary : nviranmental � S. JAY ZIMMERMAN Quality Director February 14, 2017 Mr. Joe Parkulo, Regional HSE Manager Lubrizol Advanced Materials, Inc. 207 Telegraph Drive Gastonia,NC 28056 Subject: Compliance Evaluation Inspection 207 Telegraph Drive Certificate of Coverage No. NCG500210 Gaston County Dear Mr. Parkulo: Enclosed is a copy of the Compliance Evaluation Inspection for the inspection conducted at the subject facility on January 31, 2017, by Ori Tuvia. Your cooperation during the site visit was much appreciated. As discussed on the phone,the facility must change the sampling location and conduct sampling once the discharge comes out of the basins. If you have any questions, please contact Ori Tuvia at(704) 235-2190, or via email at ori.tuvia@ncdenr.gov. Sincerely, Ori Tuvia, Environmental Engineer Mooresville Regional Office Division of Water Resources, DEQ Mooresville Regional Office Location:610 East Center Ave.,Suite 301 Mooresville,NC 28115 Phone:(704)663-16991 Fax (704)663-60401 Customer Service:1-877-623-6748 Internet:www.ncwateroualitv.om United States Environmental Protection Agency Form Approved. EPA Washington,D.C.20460 OMB No.2040-0057 Water Compliance Inspection.RePort Approval expires 8-31-98 Section A:National Data System Coding(i.e.,PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 u 2 l5 l 3 I NCG500210 111 12 I 17/01/31 117 18[ j 19 I c I 201 1 211 I I I I I 1 1 1 1 11 I I I I I I I I I 1 1 1 1 1 1 1 1 1 1 1 I 1 1 11 1 I I I 1 l66 Inspection Work Days Facility Self-Monitoring Evaluation Rating B1 QA Reserved ` 67I1.0 1 701d 1 71 1it N 1 72 1 N 1 731 I 174 75� l 1 1 1 1 1 I 180 LJ Section B:Facility Data Name and Location of Facility Inspected(For Industrial Users discharging to POTW,also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 01:50PM 17/01/31 15/11/04 Lubrizol Advanced Materials 207 Telegraph Dr Exit Time/Date Permit Expiration Date Gastonia NC 280561306 03:45PM 17/01/31 20/07/31 Name(s)of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data /// Joe Parkulo//704-865-7451/7048654919 Name,Address of Responsible Official/Title/Phone and Fax Number Contacted Joe Parkulo,207 Telegraph Dr Gastonia NC 280561306/Managerl704-865-7451/7048654919 No Section C:Areas Evaluated During Inspection(Check only those areas evaluated) IIIII Permit • Flow Measurement Operations&Maintenance Records/Reports I♦ Self-Monitoring Program Facility Site Review Effluent/Receiving Waters Laboratory Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s)and Signature(s)of Inspector(s) Agency/Office/Phone and Fax Numbers Date Ori A Tuvia MRO WQ//704-663-1699/ / Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date W.Corey Basinger MRO WQ//704-235-2194/ EPA Form 3560-3(Rev 9-94)Previous editions are obsolete. 1 3 Q 2 Page# 1 NPDES yr/mo/day Inspection Type 1 31 NCG500210 111 12i 17/01/31 I17 Lcj Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) Page# 2 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/31/2017 inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new 0 0 0 application? Is the facility as described in the permit? • 0 0 0 #Are there any special conditions for the permit? ❑ • 0 0 Is access to the plant site restricted to the general public? • ❑ ❑ 0 Is the inspector granted access to all areas for inspection? • ❑ ❑ ❑ Comment: The subject permit expires on 7/31/2020. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? • ❑ 0 ❑ Is all required information readily available,complete and current? • 0 ❑ ❑ Are all records maintained for 3 years(lab. reg.required 5 years)? • ❑ 0 0 Are analytical results consistent with data reported on DMRs? • ❑ 0 0 Is the chain-of-custody complete? • 0 0 ❑ Dates,times and location of sampling • Name of individual performing the sampling Results of analysis and calibration • Dates of analysis • Name of person performing analyses • Transported COCs • Are DMRs complete:do they include all permit parameters? • ❑ 0 ❑ Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ • ❑ (If the facility is=or>5 MGD permitted flow)Do they operate 24/7 with a certified operator 0 ❑ 0 on each shift? Is the ORC visitation log available and current? ❑ 0 • ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ ❑ • ❑ Is the backup operator certified at one grade less or greater than the facility classification? ❑ ❑ El ❑ Is a copy of the current NPDES permit available on site? • ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ❑ ❑ • ❑ Comment: The permittee's records were very organized and well maintained. Chlorine results sampled on 11/17/2016 were 360 ug/L higher than permitted value.The facility was instructed to resample in order to verify results. Sampling done on 2/2/2017 resulted in below detection for chlorine. Page# 3 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/31/2017 Inspection Type: Compliance Evaluation Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? 0 0 0 Does the facility analyze process control parameters,for ex:MLSS,MCRT,Settleable 0 0 • 0 Solids,pH,DO,Sludge Judge,and other that are applicable? Comment: Non-contact cooling water, boiler blowdown, and stormwater are directed to two on-site concrete basins (operated in series)before discharge to surface waters. Process control measurements are taken before the wastewater is discharged to the unnamed tributary to South Crowders Creek via a pumping system.The Facilty must conduct sampling once the discharge comes out of the basins. The approved biocide (Biosperse 261T)is used in the cooling tower systems. Flow Measurement-Effluent Yes No NA NE #Is flow meter used for reporting? 0 0 0 Is flow meter calibrated annually? 0 0 IN 0 Is the flow meter operational? 0 0 0 (If units are separated)Does the chart recorder match the flow meter? 0 0 I ❑ Comment: Flow is estimated. Equalization Basins Yes No NA NE Is the basin aerated? 0 0 • 0 Is the basin free of bypass lines or structures to the natural environment? 0 0 11 0 Is the basin free of excessive grease? 0 0 • ❑ Are all pumps present? 0 0 • 0 Are all pumps operable? ❑ ❑ ❑ Are float controls operable? 00 . 0 Are audible and visual alarms operable? 0 0 • 0 #Is basin size/volume adequate? ❑ 0 • 0 Comment: Non-contact cooling water, boiler blowdown, and stormwater are directed to two on-site concrete basins(operated in series)before discharge to surface waters.chemicals are added as needed in order to get the pH 6-9 prior to discharge. Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? U 0 0 0 Are all other parameters(excluding field parameters)performed by a certified lab? • ODD #Is the facility using a contract lab? • ❑ ❑ ❑ #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees I000 Celsius)? Incubator(Fecal Coliform)set to 44.5 degrees Celsius+/-0.2 degrees? 0 0 IN 0 Page# 4 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/31/2017 Inspection Type: Compliance Evaluation Laboratory Yes No NA NE Incubator(BOD)set to 20.0 degrees Celsius+/-1.0 degrees? 0 0 • ❑ Comment: Prism Laboratories, Inc. (certification#402)has been contracted to provide analytical support. The permittee also uses an on-site laboratory to perform temperature and pH analyses. Biota Lab and Shealy Environmental have been contracted to sample the chlorine.A new NIST traceable thermometer ispurchased yearly and the pH meter is calibrated before use: pH buffers were within expiration dates. Effluent Sampling Yes No NA NE Is composite sampling flow proportional? ❑ 0 • 0 Is sample collected below all treatment units? 0 IN ❑ 0 Is proper volume collected? U 0 0 ❑ Is the tubing clean? 0 ❑ II ❑ #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees • 0 ❑ 0 Celsius)? Is the facility sampling performed as required by the permit(frequency,sampling type • ❑ ❑ 0 representative)? Comment: The permit requires grab samples for all samples. The Facilty must conduct sampling once the discharge comes out of the basins. Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? • 0 0 0 Are the receiving water free of foam other than trace amounts and other debris? • ❑ ❑ 0 If effluent (diffuser pipes are required) are they operating properly? 0 ❑ • ❑ Comment: The permittee was not discharging at the time of the inspection. Upstream /Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit(frequency,sampling type, and • ❑ 110 sampling location)? Comment: The permittee met the temperature requirements noted in NCG500000(<2.8 degrees C above the natural water temperature of the receiving stream) Page# 5 NCDENR A • A. FILE North Carolina Department of Environment and Natural Resources Pat McCrory John E. Skvarla, Ill Governor Secretary December 11, 2014 Mr. Joe Parkulo, Regional HSE Manager Lubrizol Advanced Materials, Inc. 207 Telegraph Drive Gastonia, North Carolina 28056 Subject: Notice of Violation Compliance Evaluation Inspection Tracking Number: NOV-2014-PC-0270 Lubrizol Advanced Materials, Inc. NPDES Certificate of Coverage No. NCG500210 Gaston County Dear Mr. Parkulo: Enclosed please find a copy of the Compliance Evaluation Inspection report for the inspection conducted at the subject facility on December 3, 2014, by Ms. Marcia Allocco of this office. Thank you for your assistance during the inspection. This report is being issued as a Notice of Violation (NOV) because the inspection revealed monitoring violations for chemical oxygen demand (COD) and deficiencies with regard to the testing procedures used to monitor the effluent of the subject NPDES permit and North Carolina General Statute(G.S.) 143-215.1, as described in the Effluent Sampling and Laboratory sections of the enclosed report. Pursuant to G.S. 143-215.6A, a civil penalty of not more than twenty-five thousand dollars ($25,000.00) per violation, per day, may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of any permit issued pursuant to G.S. 143-215.1. It is requested that a written response be submitted to this office by January 9, 2015, detailing your corrective actions to the violations in the enclosed report. Please address your response to the attention of your inspector, Ms. Marcia Allocco. The inspection report should be self-explanatory; however, should you have any questions, please do not hesitate to contact Ms. Allocco at(704) 235-2204 or marcia.allocco@ncdenr.gov. Sin rely, VtZ-Mr. Michael Parker, Regional Supervisor Water Quality Regional Operations Section Division of Water Resources, NCDENR Enclosures: Inspection Report cc: Wastewater Branch MSC 1617—Central files basement Mooresville Regional Office Location:610 East Center Ave.,Suite 301 Mooresville,NC 28115 Phone:(704)663-16991 Fax:(704)663-60401 Customer Service:1-877-623-6748 Internet http:llportal.ncdenr.orglweblwq An Equal Opportunity\Affirmative Action Employer—30%Recycledil0%Post Consumer paper United States Environmental Protection Agency Form Approved. EPA Washington,D.C.20460 OMB No.2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A:National Data System Coding(i.e.,PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 �N 2 �5 I 3 NCG500210 111 12 1 14/12/03 117 18 Lc.] 19' C i 20 I 211 1 1 1 1 L_1 J 1 1 1 1 1 1 1 I 1 I 1 I I 1 1 1 I I I I I I I I I I I I I I I i I I I I i66 Inspection Work Days Facility Self-Monitoring Evaluation Rating B1 QA ---------Reserved--- 6711.0 1 701,Li it I 71 Iry LJ I 72 I rJ I 7311 1" 751 I I I I 1 1 180 Section B:Facility Data Name and Location of Facility Inspected(For Industrial Users discharging to POTW,also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 10:04AM 14/12/03 12/08/01 Lubrizol Advanced Materials 207 Telegraph Dr Exit Time/Date Permit Expiration Date 11:00AM 14/12/03 15/07/31 Gastonia NC 280561306 Name(s)of Onsite Representative(s)/Titles(s)/Phone and Fax Number(s) Other Facility Data Name,Address of Responsible Official/Title/Phone and Fax Number Contacted James P Nelli,207 Telegraph Dr Gastonia NC 280561306//704-865-7451/7048657090 No Section C:Areas Evaluated During Inspection(Check only those areas evaluated) II Permit Flow Measurement Operations&Maintenance II Records/Reports Self-Monitoring Program II Facility Site Review II Effluent/Receiving Waters II Laboratory Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s)and Signature(s)of Inspector(s) Agency/Office/Phone and Fax Numbers 11 1 Date ���, Marcia Allocco MRO 4-663-1699 Ext.2204/ 1�1 I O Signature of Management Q A Reviewer Agency/Office/Phone and Fax Numbers Date EPA Form 3560-3(Rev 9-94)Previous editions are obsolete. Page# 1 NPDES yr/mo/day Inspection Type 1 31 NCG500210 111 121 14/12/03 117 18 Section D:Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) Page# 2 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 12/03/2014 Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ ❑ • ❑ application? Is the facility as described in the permit? • ❑ El 0 #Are there any special conditions for the permit? ❑ • ❑ ❑ Is access to the plant site restricted to the general public? • El 0 0 Is the inspector granted access to all areas for inspection? • 0 ❑ 0 Comment: The general permit was reissued on August 1, 2012, and expires on July 31, 2015. The permittee has maintained permit coverage since September 30, 1993.The last compliance evaluation inspection was conducted on January 26, 2010. Operations & Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? • 0 0 ❑ Does the facility analyze process control parameters, for ex: MLSS, MCRT,Settleable ❑ ❑ II 0 Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Non-contact cooling water, boiler blowdown, and stormwater are directed to two on-site concrete basins(operated in series) before discharge to surface waters. Process control measurements are taken before the wastewater is discharged to the unnamed tributary to South Crowders Creek via a pumping system. The approved biocide (Biosperse 261T) is used in the cooling tower systems. Flow Measurement- Effluent Yes No NA NE #Is flow meter used for reporting? El I ❑ ❑ Is flow meter calibrated annually? ❑ ❑ • ❑ Is the flow meter operational? ❑ ❑ • ❑ (If units are separated)Does the chart recorder match the flow meter'? El ❑ � ❑ Comment: The permittee monitored the wastewater discharges on February 18th and August 14th in 2014. On the discharge monitoring reports(DMRs) prepared for each discharge event flow was estimated in units of inches. Please convert the flow reported on the DMR from inches to units of discharge volume/rate such as gallons per day. This allows the Division to compare flow estimates noted on your permit application to those notes for discharge events during compliance inspections. Effluent Sampling Yes No NA NE Is composite sampling flow proportional? ❑ ❑ IN ❑ Is sample collected below all treatment units? • ❑ 0 0 Is proper volume collected? • ❑ El ❑ Is the tubing clean? El 0 • El Page# 3 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 12/03/2014 Inspection Type: Compliance Evaluation Effluent Sampling Yes No NA NE #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees ❑ ❑ ❑ Celsius)? Is the facility sampling performed as required by the permit(frequency,sampling type ❑ � ❑ ❑ representative)? Comment: The permit requires grab samples for all samples. The 2012 permit added chemical oxygen demand (COD) as a required monitoring parameter if water treatment and/or chemical additives are added to the system. Because the permittee uses an approved biocide. COD monitoring should be conducted when monitoring the wastewater effluent discharges. Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? • ❑ ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? • ❑ ❑ ❑ If effluent (diffuser pipes are required) are they operating properly? ❑ ❑ � ❑ Comment: The permittee was not discharging at the time of the inspection. Upstream I Downstream Sampling Yes No NA NE Is the facility sampling performed as required by the permit(frequency,sampling type, and INOOD sampling location)? Comment: The permittee met the temperature requirements noted in NCG500000 (<2.8 degrees C above the natural water temperature of the receiving stream)on both occasions the wastewater effluent was monitored in 2014. Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? ME1EIEJ Are all other parameters(excluding field parameters)performed by a certified lab? • ❑ ❑ ❑ #Is the facility using a contract lab? MODEI #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees MEHEIE1 Celsius)? Incubator(Fecal Coliform)set to 44.5 degrees Celsius+/-0.2 degrees? 00110 Incubator(BOD)set to 20.0 degrees Celsius+/-1.0 degrees? EIC1110 Page# 4 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 12/03/2014 Inspection Type: Compliance Evaluation Laboratory Yes No NA NE Comment: Prism Laboratories, Inc. (certification#402) has been contracted to provide analytical support. The permittee also uses an on-site laboratory to perform temperature and pH analyses. A new NIST traceable thermometer is purchased yearly and the pH meter is calibrated before use; pH buffers were within expiration dates. However,the results of the meter calibration have not been documented. Guidance was provided for temperature and pH monitoring procedures as well as an example lab benchsheet. Please ensure the pH meter is calibrated before use on the same day effluent pH monitoring is completed. Prism Laboratories, Inc. is conducting total residual chlorine(TRC) analyses but the holding time (15 minutes)and minimum detection limits(permit requires documentation that discharges are< 17 ug/L; lab PQL was noted as 0.100 mq/L)were not met. If the effluent contains chlorine please ensure the analyses meet these requirements. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? • ❑ ❑ ❑ Is all required information readily available;complete and current? • 0 0 0 Are all records maintained for 3 years(lab. reg. required 5 years)? 11 ❑ 0 0 Are analytical results consistent with data reported on DMRs? • 0 0 0 Is the chain-of-custody complete? • 0 0 0 Dates,times and location of sampling • Name of individual performing the sampling • Results of analysis and calibration Dates of analysis • Name of person performing analyses • Transported COCs � Are DMRs complete:do they include all permit parameters? • 0 0 0 Has the facility submitted its annual compliance report to users and DWQ? ❑ ❑ U ❑ (If the facility is=or>5 MGD permitted flow)Do they operate 24/7 with a certified operator 0 0 11 ❑ on each shift? Is the ORC visitation log available and current? 0 0 � ❑ Is the ORC certified at grade equal to or higher than the facility classification? 0 ❑ • 0 Is the backup operator certified at one grade less or greater than the facility classification? ❑ ❑ • ❑ Is a copy of the current NPDES permit available on site? 11 0 0 0 Facility has copy of previous year's Annual Report on file for review? 0 0 • ❑ Comment: The permittee's records were very organized and well maintained. No permit limit violations were noted for the February 18th and August 14th 2014 discharge events. The permittee developed discharge monitoring reports(DMRs)for each sampling event. Please ensure that the DMRs note<PQL or<MDL such as<5.0 mq/L instead of<BRL to add the inspector in verifying compliance with the permit limit requirements. Page# 5 Lubrizol J 207 Telegraph Drive Gastonia,NC 28056 (704)865-7451 January 6, 2015 Ms. Marcia Allocco NCDENR Mooresville Regional Office Division of Water Resources Water Quality Regional Operations Section 610 East Center Avenue, Suite 301 Mooresville,NC 28115 Dear Ms. Allocco: This letter is in response to the Notice of Violation dated December 11, 2014 for violations regarding chemical oxygen demand (COD) and deficiencies with regard to the testing procedures used to monitor the effluent of the subject NPDES permit NCG500210. To address findings of the compliance inspection, the following corrective actions have been implemented: • Future monitoring will include COD monitoring for the effluent. • Flow estimates on DMR reports will be recorded in gallons per minute. • pH calibration will be documented on the same day effluent pH monitoring is completed. • If chlorine is contained in our effluent,monitoring will be conducted in compliance with NCDENR guidelines. As always,we continue to investigate ways to improve our environmental compliance efforts and appreciate your input. Please feel free to Joe Parkulo, HSES Manager at (704) 915-4165 if you have any questions concerning this response. Sincerely,04,20 Joe Marcsik Plant Manager Allocco, Marcia From: Parkulo, Joe <Joe.Parkulo@lubrizol.com> Sent: Wednesday, December 10, 2014 2:35 PM To: Allocco, Marcia Subject: RE: Example laboratory benchsheets Ms. Allocco, Thanks for the information. I have used it to develop a bench sheet to confirm documentation of the pH meter calibration. Regards, rTe Pv-410 HSES Manager Lubrizol Advanced Materials 207 Telegraph Drive Gastonia, NC 28056 (704) 915-4165 From: Allocco, Marcia[maiIto: marcia.allocco(a)ncdenr.govj Sent: Wednesday, December 10, 2014 2:00 PM To: Parkulo, Joe Subject: Example laboratory benchsheets Mr. Parkulo, When I visited your facility last week I noted I would follow-up with you regarding laboratory benchsheets to document your pH meter calibrations on the days it is used to monitor the pH of your effluent. The Division's Laboratory Certification group provides technical assistance documents on their website for field laboratory certified facilities. Although your facility is not required to obtain laboratory certification we recommend facilities covered by our general wastewater permits follow this guidance to assist in generating legally defensible monitoring data. The guidance documents I provided during my inspection (pH and temperature) can be found at the top of the website. If you scroll down to the "Tools for Laboratories" section of the page the first entry in the table is an example benchsheet you can use to document your pH meter calibrations. If you have any questions regarding the guidance provided or the benchsheet please let me know. Regards, Marcia Allocco Dhbbn of Wow Resources Marcia Allocco, MS — Senior Environmental Specialist Weaver, Charles /V f�o From: Weaver, Charles G c, Sent: Wednesday, November 04, 2015 10:25 AM To: 'joe.parkulo@lubrizol.com' Cc: 'james.neill@lubrizol.com' Subject: renewal of NCG500210 / Lubrizol - Gastonia Attachments: NCG50 Final 093015.pdf, Technical Bulletin - NCG500000 2015.doc Importance: High Attached you will find the updated version of NPDES General Permit NCG500000, effective 10/1/2015. Discard any previous versions of the General Permit and use this version until further notice. You do not need a reprinted Certificate of Coverage, as the one issued to you in 2007 is still applicable. Thank you for your patience during the longer -than -expected renewal period. If you have any questions about this matter, simply reply to this message. Charles H. Weaver Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919-807-6391 charles.weaver(a)ncdenr.gov (physical address) 512 North Salisbury Street, Raleigh, NC 27604 (mailing address) 1617 Mail Service Center, Raleigh, NC 27699-1617 ^Nothing Compares Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. RECEIVEDlNCDENR/DWR MAY 12 ZU16 WQROS MOORESVILLE REGIONAL OFFICE Weaver, Charles From: Microsoft Outlook To: joe.parkulo@lubrizol.com Sent: Wednesday, November 04, 2015 10:25 AM Subject: Relayed: renewal of NCG500210/ Lubrizol - Gastonia Delivery to these recipients or groups is complete, but no delivery notification was sent by the destination server: ioe.parkulo@ lubrizol.com (joe.parkuloCa�lubrizol.com) Subject: renewal of NCG500210/ Lubrizol -Gastonia renewal of NCG500210/Lu.,. 1 yotyki,-e2 Lubrizol February 26, 2010 MAR - 32010. Ms. Maria Allocco Mooresville Regional Office North Carolina Division of Water Quality 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Re: Notice of Violation NPDES#NCG500210 Dear Ms. Allocco: This letter is in response to the recent NOV dated 2/10/2010 from your agency. Actions taken specific to the compliance inspection include: 1. Reverse osmosis reject water has been diverted to now enter the site wastewater pretreatment system. 2. Changes to the site self-monitoring procedures will include upstream and downstream temperatures as specified in the current permit. 3. Self-monitoring requirements of the two NPDES permits have been reviewed and future monitoring events will meet the requirements as specified. If you have any questions, please give Joe Parkulo a call at (704) 915-4165. Sincerely, crv3,o6ep.z____ James P. Nelli Plant Manager '�1rU-- NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary February 10, 2010 Mr. James P.Nelli Lubrizol Advanced Materials, Inc. 207 Telegraph Drive Gastonia,North Carolina 28056 Subject: Notice of Violation Compliance Evaluation Inspection Lubrizol Advanced Materials, Inc. NPDES Permit No.NCG500210 Gaston County,N.C. •Tracking#: NOV-2010-PC-0138 Dear Mr.Nelli: Enclosed is a copy of the Compliance Evaluation Inspection Report for the inspection conducted at the subject facility on January 26, 2010 by Mr. Wes Bell of this Office. This report is being issued as a Notice of Violation (NOV) due to the inclusion of an unpermitted discharge (reverse osmosis reject water) in the facility's drainage system/effluent discharge and the facility's failure to monitor upstream and downstream temperatures and collect representative effluent samples (prior to comingling with stormwater). The unpermitted discharge and failures to monitor upstream/downstream temperatures and collect representative effluent samples are violations of the subject NPDES Permit and North Carolina General Statute (G.S.) 143-215.1, as detailed in the Permit and Effluent Sampling Sections of the attached report. Pursuant to G.S. 143-215.6A, a civil penalty of not more than twenty-five thousand dollars ($25,000.00) per violation, per day, may be assessed against any person who violates or fails to act in accordance with the terms, conditions, or requirements of any permit issued pursuant to G.S. 143-215.1. It is requested that a written response be submitted to this Office by March 3, 2010, addressing the above-noted violations and the discrepancies noted in the Laboratory and Flow Measurement Sections of the attached report. In responding to the violations, please address your comments to the attention of Mrs. Marcia Allocco. Mooresville Regional Office Location:610 East Center Ave.,Suite 301 Mooresville,NC 28115 One Phone:(704)663-1699\Fax:(704)663.60401 Customer Service:1-877-623-6748 NorthCarolina Internet http://portal.ncdenr.org/weblwq An Equal Opportunity l Affirmative Action Employer—50%Recycled/10%Post Consumer paper Naturally Mr. James P. Nelli February 10, 2010 Page Two The report should be self-explanatory; however, should you have questions concerning this report,please do not hesitate to contact Mr. Bell at (704) 663-1699. Sincerely, ` Robert B. Krebs Surface Water Protection Regional Supervisor Enclosures: Inspection Report pH Technical Assistance Document cc: Gaston County Health Department WB United States Environmental Protection Agency Form Approved. E PA Washington,D.C.20460 OMB No.2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCS) Transaction Code NPDES yr/mo/day Inspection Type Inspector Fac Type 1 INI 2 I51 31 NCG500210 111 121 10/01/26 117 181c1 191s1 20I 11 Remarks 211 III 11 I I 1 I l l 1 I I I I 1 1 1 I I I I I 1 1 I III 1 1 1 1 I III 1 III 1 . 1 1 166 Inspection Work Days Facility Self-Monitoring Evaluation Rating B1 QA - 671 1.5 169 701 3 I 71 I N I 721 NI 731 I 174 751 1 1 1 I 1 I 1 80 Section B: Facility Data Name and Location of Facility Inspected(For Industrial Users discharging to POTW,also include Entry Time/Date Permit Effective Date POTW name and NPDES permit Number) 11:10 AM 10/01/26 07/08/01 Lubrizol Advanced Materials 207 Telegraph Dr Exit Time/Date Permit Expiration Date Gastonia NC 28056 02:00 PM 10/01/26 12/07/31 Name(s)of Onsite Representative(s)Ttles(s)/Phone and Fax Number(s) Other Facility Data • /// Joe Parkulo//704-865-7451 /7048654919 Name,Address of Responsible Official/Title/Phone and Fax Number Contacted James P Ne11i,207 Telegrapph % Gastonia NC 28056//704-865 7451/7048657090 Yes Section C: Areas Evaluated During Inspection(Check only those areas evaluated) 1.1 Permit Flow Measurement •Operations&Maintenance •Records/Reports II Self-Monitoring Program 111 Facility Site Review III Effluent/Receiving Waters III Laboratory Section D: Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Name(s)and Signature(s)of Inspector(s Agency/Office/Phone and Fax Numbers Date`� Wesley N Bell <V / -c MRO WQ//704-663-1699 Ext.2192/ / �-t //.Q Signat+yt(e q.[Management Q A Reviewer • ency/Office/Phone and Fax Numbers Qate • Marcia Allocco MRO WQ//704-663-1699 Ext.2204/ EPA Form 3560-3(Rev 9-94)Previous editions are obsolete. Page# 1 NPDES yr/mo/day Inspection Type 1 3I NCG500210 I11 12I 10/01/26 117 18ICI Section D: Summary of Finding/Comments(Attach additional sheets of narrative and checklists as necessary) • Page# 2 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/26/2010 Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new application? nnion Is the facility as described in the permit? ■ n n n #Are there any special conditions for the permit? n n ■ n Is access to the plant site restricted to the general public? ■ n n n Is the inspector granted access to all areas for inspection? ■ n n n Comment: The subject permit expires on 7/31/12. The facility discharged an unpermitted wastestream (reverse osmosis reject water) into the on-site drainage system. The reverse osmosis reject water is not covered under the NCG500210 permit. The facility will have to either connect this wastestream to the on-site pretreatment system or submit an application for an individual NPDES Permit. Record Keeping Yes No NA NE Are records kept and maintained as required by the permit? ■ n n n Is all required information readily available,complete and current? ■ n n n Are all records maintained for 3 years(lab. reg. required 5 years)? n n n ■ Are analytical results consistent with data reported on DMRs? n n n U Is the chain-of-custody complete? ■ n n n Dates,times and location of sampling ■ Name of individual performing the sampling ■ Results of analysis and calibration U Dates of analysis N Name of person performing analyses ■ Transported COCs ■ Are DMRs complete: do they include all permit parameters? n n n U Has the facility submitted its annual compliance report to users and DWQ? n n • n (If the facility is=or>5 MGD permitted flow) Do they operate 24/7 with a certified operator on each shift? n ❑ ■ Is the ORC visitation log available and current? n ❑ ■ n Is the ORC certified at grade equal to or higher than the facility classification? n n ■ n Is the backup operator certified at one grade less or greater than the facility classification? n n ■ n Is a copy of the current NPDES permit available on site? ■ n .n n Facility has copy of previous year's Annual Report on file for review? nnmin Page# 3 Permit: NCG500210 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/26/2010 Inspection Type: Compliance Evaluation Record Keeping Yes No NA NE Comment: The facility's records were organized and accessible. No effluent limit violations were noted in the review of the 6/09 and 9/09 sampling events. The facility staff must ensure the collection and analysis times for the pH measurements are documented to verify compliance with the 15-minute holding time requirement(40 CFR 136.3, Table II). • Laboratory Yes No NA NE Are field parameters performed by certified personnel or laboratory? n n U n Are all other parameters(excluding field parameters)performed by a certified lab? ■ n n n #Is the facility using a contract lab? ■ n n n #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees Celsius)? ■ ❑ ❑ ❑ Incubator(Fecal Coliform)set to 44.5 degrees Celsius+/-0.2 degrees? n n ■ n Incubator(BOD)set to 20.0 degrees Celsius+/- 1.0 degrees? n n ■ n Comment: Prism Laboratories, Inc. (Certification#402) has been contracted to provide analytical support. The facility also uses the on-site laboratory to perform pH and temperature analyses. Note: The temperatures are also reported from the pH meter. The pH meter calibrations had not been documented and one of the pH buffers had expired. A second buffer may have also expired; however, the expiration date was not found on the container. In addition, the temperature measuring device on the pH meter had not been verified against a NIST certified or NIST traceable thermometer. Please review the technical guidance document regarding the calibration (and documentation) of the pH meter and the meter's temperature compensating device that has been attached to this report. Effluent Sampling Yes No NA NE Is composite sampling flow proportional? n n U n Is sample collected below all treatment units? ■ n n n Is proper volume collected? ■ n n n Is the tubing clean? n n U n #Is proper temperature set for sample storage(kept at less than or equal to 6.0 degrees Celsius)? n n ■ ❑ Is the facility sampling performed as required by the permit(frequency,sampling type representative)? n ■ n n Comment: No upstream and downstream temperature monitoring had been performed as required by the subject permit. In addition, representative effluent samples had not been collected prior to comingling with the stormwater. Operations&Maintenance Yes No NA NE Is the plant generally clean with acceptable housekeeping? ■ n n n Does the facility analyze process control parameters, for ex: MLSS, MCRT,Settleable Solids, pH, DO,Sludge 0 ❑ ■ ❑ Judge,and other that are applicable? Page# 4 • Permit: NCG50021 0 Owner-Facility: Lubrizol Advanced Materials Inspection Date: 01/26/2010 Inspection Type: Compliance Evaluation Operations &Maintenance Yes No NA NE Comment: The wastestreams flow into two concrete basins that are operated in series. The accumulated water in the second basin is recirculated (via pump system) and process control measurements are performed by the on-site laboratory. The water is then pumped to the receiving stream by this same pump system. An approved biocide (Biosperse 261T) is used in the cooling tower systems. Flow Measurement- Effluent Yes No NA NE #Is flow meter used for reporting? n ❑ • n Is flow meter calibrated annually? n ❑ • ❑ Is the flow meter operational? ❑ n ■ ❑ (If units are separated)Does the chart recorder match the flow meter? 0 0 ■ 0 Comment: Flow calculations were based on combined flows (stormwater, wastewater, etc.). All future flows must be based on the flow rates/discharges of the permitted wastestreams (covered under the NCG500210 Permit) prior to comingling with stormwater. Effluent Pipe Yes No NA NE Is right of way to the outfall properly maintained? ■ n ❑ ❑ Are the receiving water free of foam other than trace amounts and other debris? ■ ❑ n ❑ If effluent (diffuser pipes are required) are they operating properly? n n U ❑ Comment: The facility was not discharging at the time of the inspection. Page# 5 TECHNICAL ASSISTANCE FOR FIELD ANALYSIS OF pH This document is intended to provide technical assistance and guidance for the measurement of pH. This is not meant to be a substitute for the method,but is offered as a guide to the method. • HOLDING TIME: • Samples must be analyzed within 15 minutes of collection. METER CALIBRATION: • The meter must be calibrated prior to the analysis of samples. • If compliance samples are analyzed throughout the day, a post calibration check(e.g.,7 buffer)must be analyzed mid-day and at the end of the run(i.e., roughly every 4 hours based on an eight hour day). • For routine work, use a pH meter accurate and reproducible to 0.1 pH unit with a range of 0 to 14, equipped with a temperature compensation device. Follow all manufacturers' recommendations for the calibration of the meter each analysis day. In all cases, the meter must be calibrated with at least two buffers. Calibrating with the pH 4 and pH 10 buffers meets standard methods requirements and brackets the pH range for most monitoring (with the exception of sludge) scenarios. The calibration; however, must bracket the range of the samples being analyzed. In addition to the calibration standards, the meter • must be verified with a third calibration standard (e.g., pH 7 buffer). • In order to meet the above-specified criteria,the standard must read within a range of pH 6.9 to 7.1 to be acceptable. General Information: • Samples shall be gently stirred during measurement. • The electrode must be rinsed and blotted dry between measurements. • All thermometers and temperature measuring devices must be checked every 12 months against a NIST certified or NIST traceable thermometer and the process documented even if the instrument is not used for reporting temperature results. To check a thermometer or the temperature sensor of a meter, read the temperature of the thermometer/meter against a NIST certified or NIST traceable thermometer and record the two temperatures. The thermometer/meter readings must be less than or equal to 1°C from the NIST certified or NIST traceable thermometer reading. The documentation must include the serial number of the NIST certified thermometer or NIST traceable thermometer that was used in the comparison. Also document any correction that applies on both the thermometer/meter and on a separate sheet to be filed. (NOTE: Other certified laboratories may provide assistance in meeting this requirement.) DOCUMENTATION: The following must be documented whenever sample analysis is performed. 1. Time and date of sample collection 2. Time of calibration 3. Time and date of analysis(to verify 15 minute holding time is met) 4. Collector's/analyst's name 5. Value of buffers used for calibration 6. Value obtained for check buffer(e.g., pH 7 buffer) 7. Sample location/site 8. Post calibration checks(if applicable) 9. Report all data values to the nearest 0.1 pH unit. 10. The temperature correction (even if it is zero) must be posted on the meter as well as in hard copy format(to be retained for 5 years). • Page 2 of 2 Recommendation: Maintain a log of all chemicals, reagents and standards to include vendor, lot numbers, and expiration date. Ref: Standard Methods, 18th Edition - Method 4500-H+ B. Ref: Standard Methods, 18th Edition - Method 2550 B. Rev.02/2009 ,7i17 /111 6'0 .4 3 NCDENR North Carolina Department of Environment and Natural Resources 2 2007 Division of Water Quality Michael F. Easley, Governor William G. Ross,Jr., Secretary Alan W. Klimek, P.E., Director NOTICE OF RENEWAL INTENT _ Jeri.03- _:7,1k0:':71It •ND NATU , RZCOURC Application for renewal of existing coverage under General Permit NCG501 I 010 �+`' >!AL 0 , r MILL: r _,:,C ry Existing Certificate of Coverage (CoC): NCG500 a t 0 i■ (Please print or type) FEB 1 6 2007 1) Mailing address' of facility owner/operator: Company Name 1i 0 v e ov\ Owner Name 0 cfl) j:n C. WEER +t' ? a• „'� T i y � v Street Address ' 0 rl -T-ele��F&ph 1l tr'1"- City Gc-54 i' State AJC-- ZIP Code ' 056 Telephone Number I C q S L 5 "0 Li51 Fax: '7 o'4 Roy r1 o 0 Email address �z. r rsrltut. o (1rL C w, *Address to which all permit correspondence should be mailed 2) Location of facility producing discharge: Facility Name IQ \I:c rnn1 T hiC . Facility Contact 3 e_ i'c r1C w t o 4 5 E tk Poky ir Street Address C ri 1 �1e5r4ph Dr. City G 4 S'Co r<; State PC_ ZIP Code --X o 5 County C c ko r. Telephone Number rtl?4 ctz 5- I L/6 1 Fax: 'r]tj`F `� 5-'7oi'o Email address J C�- • e GAL \c () f\O'v' .(.o vn 3) Description of Discharge: a) Is the discharge directly to the receiving stream? ErYes ❑ No (If no,submit a site map with the pathway to the potential receiving waters clearly marked.This includes tracing the pathway of the storm sewer to the discharge point,if the storm sewer is the only viable means of discharge.) b) Number of discharge outfalls(ditches, pipes, channels, etc. that convey wastewater from the property): c) What type of wastewater is discharged? Indicate which discharge points,if more than one. I "Non-contact cooling water Outfall(s)#: 0 02. Boiler Blowdown Outfall(s) #: CO-2— Page 1 of 3 NCG500000 renewal application Additional Application Requirements: The following information must be included in triplicate [original+2 copies] with this application or it will be returned as incomplete. ➢ Site map. If the discharge is not directly to a stream,the pathway to the receiving stream must be clearly indicated. This includes tracing the pathway of a storm sewer to its discharge point. > Authorization for representatives. If this application will be submitted by a consulting engineer(or engineering firm),include documentation from the Permittee showing that the consultant submitting the application has been designated an Authorized Representative of the applicant. Certification I certify that I am familiar with the information contained in this application and that to the best of my knowledge and belief such information is true, complete, and accurate. Printed Name of Person Signing: 3 ck vn e.S ?• L'.l 1 ► Title: P1(x _ a.y1c..s2� ,f21) //a CA 7 (Signature of Applicant) (Date Signed) North Carolina General Statute 143-215.6 b (i)provides that: Any person who knowingly makes any false statement, representation, or certification in any application, record, report, plan or other document filed or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article,or who falsifies,tampers with or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article,shall be guilty of a misdemeanor punishable by a fine not to exceed$25,000,or by imprisonment not to exceed six months,or by both.(18 U.S.C.Section 1001 provides a punishment by a fine of not more than$25,000 or imprisonment not more than 5 years,or both,for a similar offense.) This Notice of Renewal Intent does NOT require a separate fee. The permitted facility already pays an annual fee for coverage under NCG500000. Mail the original and two copies of the entire package to: Mr. Charles H. Weaver NC DENR/DWQ/NPDES 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Page 3 of 3 Noveon, Inc. 207 Telegraph Drive Gastonia,NC 28056 (704) 865-7451 Stormwater Site Flows As shown on Figure 2, there are four watersheds at this site. Watershed 1: There are no production, shipping, receiving, or loading activities occurring in this watershed. Watershed 1 includes non-contact cooling water from the Acrylic Polymer Plant cooling tower overflow and a small.amount of stormwater from the Acrylic Polymer Plant production area. In order to direct the flow from this watershed to the spill control basin, additional piping was added in this area in 1996. As a result of the piping change, this watershed drains through Outfall 02 at the discharge of the spill control basin. Watershed 2: The majority of the production, shipping, receiving, and loading activities occur within this watershed. The Acrylic Polymer Plant, the Latex Compounding Plant, and the SBR Plant are included in this watershed. This watershed drains through Outfall 02 at the discharge of the spill control basin. Watershed 3: The only activity occurring in this watershed is the "bone yard" storage area. The bone yard consists of scrap metal, scrap equipment and other miscellaneous items. This watershed drains through Outfall 03, a small, channelized discharge point. Watershed 4: There are no production, shipping, receiving or loading activities occurring in this watershed. Stormwater runoff from Watershed 4 does not have a central discharge point. All industrial activity at the Noveon Gastonia site is contained in watershed 1 or watershed 2. All stormwater from these two areas drains to the stormwater basins before being discharged to surface waters. Stormwater retention basins consist of two concrete basins piped in series. Stormwater from watershed 1 and 2 combine to enter the west basin which has a capacity of 221,228 gallons. If the west basin fills, it will automatically overflow to the east basin which has a capacity of 418,160 gallons. When the west basin fills, it will overflow to the stream running through Noveon property. Under normal operating conditions, all stormwater enters the west basin and is pumped to the east basin after operators perform visual observation of the water. When the east basin level reaches about half full, a visual observation is recorded along with the pH and temperature and the water is discharged to the stream exiting the property. This stream is a tributary to Crowders Creek. Retention times vary depending on rainfall but the average retention is several days. During dry periods, retention time may exceed one week. Storm Water Basin (West) Capacity Bottom Width 35 feet Bottom Length 26 feet Depth 10 feet Wall Slope 0.5 rise/run Length of Basin Wall 22.4 feet Basin Volume 272,290 gals Density (22.5C) 8.35 lb/gal Equivalent Liquid Head 120.0 in WC Level Xmtr Physical Offset 0.0 in Level Xmtr Zero Offset 0.0 in WC Level Xmtr Span 120.0 in WC Level Xmtr 0% Reading 0 gals Level Xmtr 100% Reading 272,290 gals Level Display 0% Reading 0 gals Level Display 100% Reading 272,290 gals Hi Alarm (90%) 245,061 gals HiHI Alarm (95%) 258,676 gals Storm Water Basin (East) Capacity Bottom Width 35 feet Bottom Length 56 feet Depth 10 feet Wall Slope 0.5 rise/run Length of Basin Wall 22.4 feet Basin Volume 418,160 gals Density (22.5C) 8.35 lb/gal Equivalent Liquid Head 120.0 in WC Level Xmtr Physical Offset 0.0 in Level Xmtr Zero Offset 0.0 in WC Level Xmtr Span. 120.0 in WC Level Xmtr 0% Reading 0 gals Level Xmtr 100% Reading ' 418,160 gals - - • Level Display 0% Reading 0 gals Level Display 100% Reading , 418,160 gals Hi Alarm (90%) 376,344 gals HiHIAlarm (95%) 397,252 gals Storm Water Basin (West) Capacity Air Space Depth (linear feet Volume (ft) down wall) (Gals) (lbs) 0.0 22.4 0 0 0.5 21.2 3,754 31,329 1.0 20.1 8,244 68,792 1.5 19.0 13,518 112,809 2.0 17.9 19,629 163,803 2.5 16.8 26,626 222,193 3.0 15.7 34,560 288,402 3.5 14.5 43,481 362,852 4.0 13.4 53,441 445,963 Bottom of inlet pipe 4.5 12.3 64,488 538,156 5.0 11.2 76,675 639,854 5.5 10.1 90,051 751,477 6.0 8.9 104,667 873,447 6.5 7.8 120,574 1,006,186 7.0 6.7 137,821 1,150,114 7.5 5.6 156,459 1,305,653 Top of inlet pipe 8.0 4.5 176,540 1,473,225 8.5 3.4 198,113 1,653,250 9.0 2.2 221,228 1,846,150 Overflow to East Basin 9.5 1.1 245,937 2,052,347 10.0 0.0 272,290 2,272,262 Storm Water Basin (East) Capacity Air Space Depth (linear feet Volume (ft) down wall) (Gals) (lbs) 0.0 22.4 0 0 0.5 21.2 7,850 65,507 1.0 20.1 16,771 139,956 1.5 19.0 ' 26,815 223,769 2.0 17.9 38,031 . 317,368 2.5 16.8 50,470 421,172 3.0 15.7 64,183 , 535,605 3.5 14.5 79,219 661,086 4.0 13.4 ._.95,631 ' 798,038 4.5 12.3 113,467 946,882 5.0 11.2 132,779 . 1,108,040 . 5.5 10.1 153,617 1,281,932 6.0 8.9 176,031 1,468,980 6.5 ' .. 7.8 200,073 1,669,605 7.0 6.7 225,791 '1,884,229 7.5 5.6 253,238 2,113,274 8.0 _ 4.5 282,464 .2,357,1`59 8.5 3.4 • 313,518 2,616,308 9.0 2.2 . 346,452 2,891,141 -- - 9.5 1.1 381,316 3,182,079 10.0 0.0 418,160 3,489,545 Noveon,Inc. Gastonia,NC STORMWATER FLOW DIAGRAM To Wastewater Plant • Incoming Stormwater X 4 ► ♦ V5 . East Basin X \West Basin #2 #1 Valve 4 pValve 3 Stormwater Valve 1 Overflow or Valve 2 Ins ideSump Inside Sump Pumped to Creek 4 p Valve 6 Inside Sump Stormwater Discharge Procedure 1. For Quick Transfer— Open valves 1 & 2 and allow the basins to equalize. Pump may be used to assist by opening valve #3 to 40% mark and valve #5 full open. 2. Make sure that valve 6 is fully closed to prevent from pumping stormwater to the creek. 3. On control panel press the pump start button, if it does not start, try the other pump start button. • ASHLJWC). Ashland Water Technologies Stan Mauldin Division of Ashland Inc. Senior Account Executive 3930 Glenwood Drive,Charlotte,NC 28208 USA Office: 704.391.5932 Fax:704.391.5934 Cell:704-905-2399 gsmauldin@ashland.com www.ashland.com January 22, 2007 Mr. Joe Parkulo NOVEON 207 Telegraph Road Gastonia, NC 28056 Subject: Biocide Worksheets Joe, Please find attached the information regarding the Biocide Worksheet Form 101 for Biosperse 261T that is used in the cooling towers at Noveon. Outlined below are some of the parameters used in these calculations. • Bleed off from the SBR Tower of - 3,500 gallons a day and the bleed off from the Acrylic Tower of 3,000 gallons a day. • The maximum dosage of Biosperse 261T to the Towers is 4 pounds per day. This equates to 1,680 grams a day using 92.5 % active BCDMH. • The total basin volume is 0.740 gallons, 272,290 gallons in the west basin and 0.418,160 gallons in the west basin • Biosperse 261T half life of 1 hour(0.0417 days) • The Environmental profile sheet for Biosperse 261T. • pH of the basin water discharge is -- 7.5. This provides Noveon with the information used for the attached worksheets. Should you have additional questions or comments, please feel free to give me a call at(704) 905-2399. Cordially, ASHLAND WATER TECHNOLOGIES Drew Industrial Division tvic24,46.:„ Stan Mauldin Senior Account Executive Cc: Durwood McDaniel, John Dudek Drew Business Groups S3 1 avJer BIOCIDE/CHEMICAL TREATMENT WORKSHEET-FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use. This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name Noveon NPDES# NC 50e)-lO Outfall # a County Gaston Receiving Stream Unnamed stream 7Q10 0 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.)volume of the water handling systems to the receiving water body? A.D.D.=_0.0035 (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above. IWC = (A.D.D.) X 100 ( ) X 100 (7010)(0.646) + (A.D.D) - ( )(0.646) + ( ) = 100 0/0 This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? Biosperse 261 T Please list the active ingredients and percent composition: 1-bromo-3-chlor-5,5-dymethylhydation 92.5 % What feed or dosage rate (D.R.) is used in this application?The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= _1,680 grams/24hr period Please note,fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product= fluid oz. of product X 1 gal. water X 8.34 lbs. X specific gravity of product X 453.59g. 128 fl. oz. 1 gal. water 1 lb. 5e, Facility Name: Ai"V0c n) -(rc• NPDES#: NC 4 50M.1 t3 Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown, holding lagoon size, etc.) Volume= 0.740 million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. -7.5 What is the decay rate (D.K.) of the product? If unknown, assume no decay(D.K.=0) and proceed to asterisk. The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. =0.0417 Days The decay rate is equal to FIT X 0.69 = 16.5 =Decay Rate (D.K.) Calculate degradation factor(D.F.). This is the first order loss coefficient. * D.F. = (Volume) + (D.K.) = ( ) + ( ) = 16.5 Calculate Steady State Discharge Concentration: Dischg Conc. = (D.F.)(Vollume)(3785) = ( )( )(3785) = 0.036 mg/I Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischg. Conc.) x (IWC%) ( ) x ( ) _ 0.036 mg/I 100 = 100 - Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mg/I). Please provide copies of the sources of this data. Organism Test Duration LC50/EC50 (ma/I) SEE ATTACHMENT • D.W.Q. Form 101 (62000) 2 SP Facility Name: t+/?ch, Irc_, NPDES#: NC C?ScO)-lO Choose the lowest LC50/EC50 listed above: Enter the LC50/EC50: 0.46 If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = 0.23 mg/I If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 = mg/I Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: 0.23 mg/liter From Part II enter the receiving stream concentration: 0.036_mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation,then this biocide is unacceptable for use. Person in Responsible Charge ,Name (Print) ryc /3.3/o'7 Signature Date Person Completing This Worksheet (If different from above) Name (Print) Signature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 27699-1621 Attn: Todd Christenson D.W.Q. Form 101 (6/2000) 3 5.34 Facility Name: �' Vleo f‘) . , NPDES#: NC Supplemental Metals Analysis If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A separate form must be used for each metal and/or metal compound present in the biocide. List the metal, its chemical formula, molecular weight (MW), formula weight (FW), and the concentration of the metal compound in the biocide (MCC). Complete a separate form for every metal present in the biocide. Metal Chemical Formula Molecular Weight of Metal Formula Weight Concentration in Biocide EXAMPLE Copper CuSO4.5H20 63.546 g/mole 249.680 g/mole 0.2 % Dosage rate of Biocide(DR) (from page 1): DR = 1260 grams/day Average Daily Discharge(ADD)(from page 1): ADD = 0.003_million gallons/day Discharge Concentration (DC) of Biocide: DC = =DR ( grams/day) _ 420,000_grams/million gallons ADD ( million gallons/day) Convert DC to micrograms/liter(ppb): x DC (pg/I) = DC (grams/million gal) x 1 106 s/mi _ pg/I 3.785 x 106liters/million gal. Calculate the fraction of metal in the metal-containing compound (MF): MW ( grams/mole) MF = FW = grams/mole) _ Calculate the fraction of metal in the biocidal compound (BF): BMCC (%) F = MFx _ x 100 (100) Calculate the concentration of metal in the discharge(M): M = DC x BF = pg/I x = pg/I Calculate the instream metal concentration (IMC)at low-flow conditions: IMC = M x IWC (%) _ _ 100 _pg/I x 100 pg/I Regulated limitation of metal (from below): Ng/I • NC General Statutes 15A NCAC 2B.0211 define: Copper-7 pg/I water quality action level* Zinc-50 pg/I water quality action level* Chromium-50 pg/I water quality standard (*Values which exceed action levels must be addressed directly by aquatic toxicity testing.) D.W.Q. Form 101 (6/2000) 4 • cry1; I 0 vaer BIOCIDE/CHEMICAL TREATMENT WORKSHEET-FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product in use.This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. Facility Name Noveon NPDES # NC G 50 o 0 Outfall # t�2 County Gaston Receiving Stream Unnamed stream 7Q10 0 (cfs) (All above information supplied by the Division of Water Quality) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D.=_0.003 (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above. (A.D.D.) X 100 ( ) X 100 IWC = (7Q10)(0.646) + (A.D.D) _ ( )(0.646) + ( ) = 100 /0 This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. II. What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? Biosperse 261 T Please list the active ingredients and percent composition: 1-bromo-3-chlor-5,5-dymethylhydation 92.5 % 0/0 What feed or dosage rate (D.R.) is used in this application?The units must be converted to maximum grams of whole product used in a 24hr period. D.R.= _1,680 grams/24hr period Please note,fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product= fluid oz. of product X 1 dal. water X 8.34 lbs. X specific gravity of product X 453.59d. 128 fl. oz. 1 gal. water 1 lb. Po- Facility Name: dv ‘/P2 vr�l ! � NPDES #: NC C7 ? O Estimate total volume of the water handling system between entry of biocidal product and NPDES discharge point. On an attached sheet please provide justification for this estimate (system volume, average cycles per blowdown, holding lagoon size, etc.) Volume= 0.740 million gallons What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. - 7.5 What is the decay rate (D.K.) of the product? If unknown, assume no decay(D.K.=0) and proceed to asterisk. The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. =0.0417 Days The decay rate is equal to 1L X 0.69 = 16.5 =Decay Rate (D.K.) Calculate degradation factor(D.F.). This is the first order loss coefficient. * D.F. _ (VolDume) + (D.K.) _ + ( ) = 16.5 Calculate Steady State Discharge Concentration: Dischg Conc. = (D.F.)(Vollume)(3785) = ( )( )(3785) = 0.036 mg/I Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischg. Conc.) x (IWC%) ( ) x ( ) _100 100 0.036 mg/1 = Receiving Stream Concentration III. Calculate regulated limitation. List all LC50 and EC50 data available for the whole product according to the following columns. (Note that units should be in mg/I). Please provide copies of the sources of this data. Organism Test Duration LC50/EC50 (moil) SEE ATTACHMENT D.W.Q. Form 101 (6/2000) 2 1;3 Facility Name: Wifflo, 'yo^ NPDES#: NC CI 503310 Choose the lowest LC50/EC50 listed above: Enter the LC50/EC50: 0.46 If the half life (H.L.) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC50 = 0.23 mg/I If the half life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LC50 = mg/I Choose the appropriate regulated limitation from the calculations immediately above and place in this blank: 0.23 mg/liter From Part II enter the receiving stream concentration: 0.036_mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use. Person in Responsible Charge 3� `�pc -•��o Name (Print) 9e.e„Q4,4,6 1/a3ie 7 Signature Date Person Completing This Worksheet (If different from above) Name (Print) Signature Date Please submit to: Division of Water Quality Aquatic Toxicology Unit 1621 Mail Service Center Raleigh, NC 2 7699-1 62 1 Attn: Todd Christenson D.W.Q. Form 101 (6/2000) 3 u Facility Name: 1V dv cr-1 n4 NPDES #: NC C 500?-u' Supplemental Metals Analysis If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A separate form must be used for each metal and/or metal compound present in the biocide. List the metal, its chemical formula, molecular weight (MW), formula weight (FW), and the concentration of the metal compound in the biocide (MCC). Complete a separate form for every metal present in the biocide. Metal Chemical Formula Molecular Weight of Metal Formula Weight Concentration in Biocide EXAMPLE Copper CuSO4.5H2O 63.546 g/mole 249.680 g/mole 0.2% Dosage rate of Biocide(DR)(from page 1): DR = 1260_grams/day Average Daily Discharge(ADD) (from page 1): ADD = 0.003_million gallons/day Discharge Concentration (DC) of Biocide: DR ( grams/day) DC = ADD = ( million gallons/day) = 420,000_grams/million gallons Convert DC to micrograms/liter(ppb): 1 x 106 pg/g DC (pg/I) = DC (grams/million gal) x = pg/I 3.785 x 106 liters/million gal. Calculate the fraction of metal in the metal-containing compound (MF): MW ( grams/mole) MF = FW = ( grams/mole) _ Calculate the fraction of metal in the biocidal compound(BF): BMCC (%) F = MFx _ x 100 (100) Calculate the concentration of metal in the discharge(M): M = DC x BF = pg/I x = pg/I Calculate the instream metal concentration (IMC)at low-flow conditions: IMC = MxIWC (%) = N9/Ix 100 =100pg/I Regulated limitation of metal (from below): Ng/I NC General Statutes 15A NCAC 2B.0211 define: Copper-7 pg/I water quality action level* Zinc-50 pg/I water quality action level* Chromium-50 pg/I water quality standard (*Values which exceed action levels must be addressed directly by aquatic toxicity testing.) D.W.Q. Form 101 (6/2000) 4 DREW INDUSTRIAL DIVISION OXIDATIVE CHEMICALS BIOSPERSE® 261T Microbiocide Environmental Profile General Degradation Data BIOSPERSE 261T microbiocide is a broad-spectrum The non-toxic dehalogenated by-product of BIOSPERSE 261T antimicrobial product designed specifically for control of microbiocide, 5,5-dimethylhydantoin, is biodegradable as bacterial, fungal and algal slimes in industrial recirculating determined by carbon-14 radiolabeling of sewage sludge. cooling water systems. BIOSPERSE 261T microbiocide is a After 19 days,94 percent of the carbon-14 had been recovered solid microbiocide which liberates hypobromous acid, as carbon dioxide. Under the test conditions, the hypochlorous acid and 5,5-dimethylhydantoin when dehalogenated by-product of BIOSPERSE 261T microbiocide dissolved in water.This environmental profile is designed to degraded rapidly with no obvious toxic effects upon the test address common questions about the impact of BIOSPERSE organisms. 261T microbiocide on the environment. Hypobromous and hypochlorous acid can degrade by reacting with organics to form halogenated by-products. Active Ingredient These by-products can be carcinogenic and acutely toxic to aquatic organisms. Hypobromous acid differs from 1-Bromo-3-chloro-5,5-dimethyl-hydantoin 92.5% hypochlorous acid in that brominated organics degrade much quicker than chlorinated organics. For example, Fish & Wildlife Studies bromoform has a half-life of 15 days compared with 50 days . for chloroform.A seeded,anaerobic culture with 160 ppb of LD50 and LC50,96-Hour Data for brominated trihalomethane degraded to less than 0.1 ppb in 1-Bromo-3-chloro-5,5-dimethyl-hydantoin less than two weeks. When 157 ppb of chlorinated Organism Test Result trihalomethane was run using the same method, 117 ppb Daphnia Magna LC50 0.46 mg/1 remained after two weeks. Bromobenzene degrades in Rainbow Trout LC50 0.87 mg/1 1/100 of the time of chlorobenzene. Fathead Minnow LC50 2.25 mg/1 Grass Shrimp LCSo 13.0 mg/1 Sheepshead Minnow LC50 20.0 mg/1 Detoxification American Oyster LC50 640 mg/1 If a spill of the tablets occurs, dry tablets can simply be Rat LDS5 1390 mg/kg collected and used. If a solution of BIOSPERSE 261T LC50,96-Hour Data for 5,5 dimethylhydantoin microbiocide is spilled,the hypobromous and hypochlorous acid can be detoxified by carefully adding a dilute solution Organism LC 50 • of a reducing agent such as sodium metabisulfite or sodium Daphnia Magna 1300 mg/1 Rainbow Trout 6100 mg/1 bisttlfite. Fathead Minnow 8100 mg/1 Grass Shrimp 12700 mg/1 Important information Sheepshead Minnow 13300 mg/1 American Oyster 14200 mg/1 This Environmental Profile is designed to address common questions about the impact of BIOSPERSE 261TMicrobiocide on LCS5 Data for Hypobromous Acid the environment and is not a substitute for the product's Material Organism Test Result Safety Data Sheet. Daphnia Magna LC50,24-Hour 1.05 mg/I LC50,48-hour 0.71 mg/1 Ashland maintains Material Safety Data Sheets on all of its Bluegill Sunfish LC50,96-Hour 0.52 mg/1 products.Material Safety Data Sheets contain health and safety Rainbow Trout LC50,96-Hour 0.23 mg/1 information for your development of appropriate product Sheepshead Minnow LC50,96-Hour 0.19 mg/1 handling procedures to protect your employees and customers. Mysid Shrimp LCso,96-Hour 0.17 mg/1 Continued on page 2. ®Registered trademark of Ashland Inc. "Registered service mark of the American Chemistry Council. °1991,2001 Ashland Inc.All Rights Reserved.Created in USA.•OX-EP-005 Rev.1 All statements,information and data presented herein are believed to be accurate and reliable but are not to be taken as a guarantee,express warranty or t OPoatid1atriai implied warranty of merchantability or fitness for a particular purpose,or representation,express or implied,for which seller assumes legal responsibility,and �f is Division they are offered solely for your consideration,investigation and verification.Statements or suggestions concerning possible use of this product are made - without representation or warranty that any such use is free of patent infringement and are not recommendations to infringe on any patent. Ashland* For more information on Ashland Specialty Chemical Company and its divisions,visit our Internet web site at http://www.ashspec.com A ar Ashland Specialty Chemical Cornpany DREW INDUSTRIAL DIVISION •One Drew Plaza,Boonton,New Jersey 07005 •Tel:(973)263-7600• Fax:(973)263-4483 •a„' Division of Ashland Inc . . . ..., . . . ... ... .. , 1„..._. 1,•• . .... \ • . ..„, .:lr'.r • • . . . • C t .,, . • . . . . .• . .. • • .. .. .. .. . .. . . • . ... . . . . . • ‘: . . . . . • • . .. ..... • .:i4 .. - _ ._ ....: ... • .. ... ..., ; , • r • • 4 Li•. . .1 .. a • • F. •f,}A'. �.a. • • • t 9'`� •. • . ;• 14, • • • • • -L • ''. • .S • . • . , • k 4 2 r' k • • • C. • t'i NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Michael F. Easley, Governor William G. Ross, Jr., Secretary Coleen H. Sullins, Director July 23, 2007 Joe Parkulo Noveon, Inc. 207 Telegraph Drive Gastonia, NC 28056 Subject: Renewal of coverage / General Permit NCG500000 Noveon Certificate of Coverage NCG500210 Gaston County Dear Permittee: In accordance with your renewal application [received on January 29, 20071, the Division is renewing Certificate of Coverage (CoC) NCG500210 to discharge under NCG500000. This CoC is issued pursuant to the requirements of North Carolina General Statue 143-215.1 and the Memorandum of Agreement between North Carolina and the US Environmental Protection agency dated May 9, 1994 for as subsequently amended]. If any parts, measurement frequencies or sampling requirements contained in this General Permit are unacceptable to you, you have the right to request an individual permit by submitting an individual permit application. Unless such demand is made, the certificate of coverage shall be final and binding. Please take notice that this Certificate of Coverage is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the certificate of coverage. Contact the Mooresville Regional Office prior to any sale or transfer of the permitted facility. Regional Office staff will assist you in documenting the transfer of this CoC. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning the requirements of the General Permit, please contact Jim McKay [919 733-5083, extension 595 or james.mckay@ncmail.netl. Sincerely, for Coleen H. Sullins cc: Central Files NPDES file 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 512 North Salisbury Street, Raleigh, North Carolina 27604 Phone: 919 733-5083 / FAX 919 733-0719 / Internet: www,ncwaterquality.org An Equal Opportunity/Affirmative Action Employer — 50% Recycled/10% Post Consumer Paper vorthCarolina Naturally STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY GENERAL PERMIT NCG500000 CERTIFICATE OF COVERAGE NCG500210 TO DISCHARGE NON-CONTACT COOLING WATER, COOLING TOWER AND BOILER BLOWDOWN, CONDENSATE AND SIMILAR WASTEWATERS UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1,other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission,and the Federal Water Pollution Control Act, as amended, Noveon, Inc. is hereby authorized to discharge Non-contact Cooling Water, Boiler Blowdown, Cooling Tower Blowdown & Condensate from a facility located at Noveon 207 Telegraph Drive Gastonia Gaston County to receiving waters designated as an unnamed tributary to Crowders Creek in subbasin 30837 of the Catawba River Basin in accordance with the effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This certificate of coverage shall become effective August 1, 2007. This Certificate of Coverage shall remain in effect for the duration of the General Permit. Signed this day July 23, 2007. U(-1 for Coleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission A • es, f NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Michael F. Easley, Governor William G. Ross,Jr.,Secretary Alan W. Klimek, P.E., Director November 15, 2006 Joe Parkulo Noveon Incorporated 207 Telegraph Drive Gastonia,NC 28056 Subject: NPDES Permit NCG500000 renewal Certificate of Coverage(CoC)NCG500210 Noveon Gaston County Dear Permittee: The facility listed above is covered under NPDES General Permit NCG500000. NCG500000 expires on July 31, 2007. Federal(40 CFR 122.41) and North Carolina(15A NCAC 2H.0105(e))regulations require that permit renewal applications must be filed at least 180 days prior to expiration of the current permit. If you have already mailed a renewal request,you may disregard this notice. To satisfy this requirement,the Division must receive a renewal request postmarked no later than February 1,2007. Failure to request renewal by this date may result in a civil penalty assessment. Larger penalties may be assessed depending upon the delinquency of the request. This renewal notice is being sent well in advance of the due date so that you have adequate time to prepare your application. If any discharge previously covered under NCG500000 will occur after July 31,2007, the CoC must be renewed. Discharge of wastewater without a valid permit would violate North Carolina General Statute 143-215.1;unpermitted discharges of wastewater may be assessed civil penalties of up to $25,000 per day. If all discharge has ceased at your facility and you wish to rescind this CoC [or if you have other questions],contact me at the telephone number or e-mail address listed below. Sincerely, -TES V " `.:7FFICE Charles H. Weaver,Jr. NPDES Unit NOV 1 6 200( cc: Central Files NPDES File J4 TEP t. fir ! !Ty cErT! 1617 Mail Service Center,Raleigh,North Carolina 27699-1617 One 512 North Salisbury Street,Raleigh,North Carolina 27604 NorthCarolina Phone: 919 733-5083,extension 511/FAX 919 733-0719/charles.weaver@ncmail.net Naturally An Equal Opportunity/Affirmative Action Employer—50%Recycled/10%Post Consumer Paper 33 Old aaDM a°°Jin s-OMa� MichhaellF.Easley,Governor W 61. 15s 1e N ] r North Carolina Department of Environment and Natural Resources N� msAlctor Urvision of�ater uality September 5,2007 JOE PARKULO LUBRIZOL ADVANCED MATERIALS, INC G3A1303e1 207 TELEGRAPH DR GASTONIA NC 28056 Subject: NPDES No. NCG500210 Lubrizol Advanced Material, Inc. Formerly: Noveon Gaston County Dear Mr. Parkulo: In accordance with your request dated August 29, 2007, we are forwarding herewith the modified Certificate of Coverage page for the subject facility. The only change is in name. This Certificate of Coverage is issued pursuant to the requirements of North Carolina General Statue 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated May 9, 1994. This permit expires in July 31, 2012 The following information is included with your permit package: • A copy of the Certificate of Coverage for your treatment facility • A copy of General Wastewater Discharge Permit NCG500000 • A copy of a Technical Bulletin for General Wastewater Discharge Permit NCG500000 If any parts, measurement frequencies or sampling requirements contained in this general permit are unacceptable to you, you have the right to request an individual permit by submitting an individual permit application. Unless such demand is made, the certificate of coverage shall be final and binding. This CoC is not transferable except after notice to the Division of Water Quality. The Division may require modification or revocation and re-issuance of the CoC. Contact the Mooresville Regional Office prior to any sale or transfer of the permitted facility. Regional Office staff will assist you in documenting the transfer of this CoC. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources,Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit,please contact Jim McKay at fT,Amhontrffinfiber 19/733 083; I extension 595 or james.mckay@ncmail.net . • Sincerely, i c..72ks oleen H. Sullins cc: Central Files NPDES General Permit Files Npon�e tCarolina ,Naturally North Carolina Division of Water Quality 1617 Mail Service Center Raleigh,NC 27699-1617 Phone(919)733-5083 Customer Service Internet: www.ncwaterqualitv.org Location: 512 N.Salisbury St. Raleigh,NC 27604 Fax (919)733-0719 1-877-623-6748 An Equal Opportunity/Affirmative Action Employer—50%Recycled/10%Post Consumer Paper Permit NCG500210 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY General Permit NCG500000 Certificate of Coverage NCG500210 TO DISCHARGE NON-CONTACT COOLING WATER, COOLING TOWER AND BOILER BLOWDOWN, CONDENSATE AND SIMILAR WASTEWATERS UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amencL-d, Lubrizol Advanced Materials, Inc is hereby authorized to discharge COOLING TOWER BLOWDOWN to receiving waters designated as a ut to Crowder's Creek, a class C water, in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV of the General Permit NCG 500000, as attached. This certificate of coverage shall become effective September 7, 2007. This Certificate of Coverage shall remain in effect for the duration of the General Permit. Signed this day September 7, 2007. oit/4.Y'Zh H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission SOC PRIORITY PROJECT: Yes_No x If Yes, SOC No. To: Permits and Engineering Unit Water Quality Section Attention: Charles Weaver Date: April 26, 2007 NPDES STAFF REPORT AND RECOMMENDATION County: Gaston MRO# 07-13 Permit No. NCG5500210 PART I - GENERAL INFORMATION 1. Facility and Address: Noveon, Inc., Formerly B.F. Goodrich 207 Telegraph Drive Gastonia,North Carolina 28056 2. Date of Investigation: April 19, 2007 3. Report Prepared By: Samar Bou-Ghazale, Env. Engineer I 4. Persons Contacted and Telephone Number: Mr. Joe Parkulo, Tel # (704) 865-7451. 5. Directions to Site: From the intersection of U.S. Highway 321 and Telegraph Drive, travel east on Telegraph Drive approximately 0.1 mile to facility on the right. 6. Discharge Point(s). List for all discharge points: Latitude: 35°12'00" Longitude: 80°12'25" Attach a U.S.G.S. map extract and indicate treatment facility site and discharge point on map. U.S.G.S. Quad No.: G 14 NW U.S.G.S. Name: Gastonia South,N.C. 7. Site size and expansion are consistent with application? Adequate land available for expansion if necessary. 8. Topography(relationship to flood plain included): Facility is not located in a flood plain. Slopes range from 5 to 12%. 9. Location of nearest dwelling: The nearest dwelling is approximately 200 feet from the discharge location. 10. Receiving stream or affected surface waters: U.T. to Crowders Creek. a. Classification: C b. River Basin and Subbasin No.: Catawba River Basin 03-08-37 c. Describe receiving stream features and pertinent downstream uses: Little flow was observed in the receiving stream. No detrimental effects were observed as a result of this discharge. PART II -DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. a. Volume of wastewater to be permitted: Flow is dependent on the amount of usage of the cooling towers. b. What is the current permitted capacity of the wastewater treatment facility? N/A c. Actual treatment capacity of the current facility(current design capacity)? N/A d. Date(s) and construction activities allowed by previous Authorizations to Construct issued in the previous two years: N/A e. Please provide a description of existing or substantially constructed wastewater treatment facilities: The wastewater treatment consists of two concrete basins piped in series. The first basin has a capacity of 221,228 gallons. The second basin has a capacity of 418,160 gallons. Flow enters the first basin and is pumped to the second basin after a visual observation of the water content. Wastewater is discharged from basin two after recording pH and temperature. f. Please provide a description of proposed wastewater treatment facilities: N/A g. Possible toxic impacts to surface waters: Biocide is used at the facilty. h. Pretreatment Program(POTWs only): N/A 2. Sludge Handling and Disposal Scheme: N/A 3. Treatment plant classification (attach completed rating sheet): no rating 4. SIC Code(s): 2821, 2899 Primary: 14 Secondary: PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grant Funds or are any public monies involved(municipals only)? N/A 2. Special monitoring or limitations (including toxicity) requests: N/A 3. Important SOC, JOC or Compliance Schedule dates: (please indicate): N/A 4. Air Quality and/or Groundwater concerns or hazardous materials utilized at this facility that may impact water quality, air quality, or groundwater: No AQ or GW concerns nor are hazardous materials utilized at this facility. PART IV- EVALUATION AND RECOMMENDATIONS The applicant has requested permit renewal to continue the discharge of non-contact cooling water containing biocide additives. A review of the self-monitoring data for the past two years did not reveal violations of the effluent limitations. Pending review and approval by P&E and the Aquatic Toxicology Group, it is recommended that the permit be reissued. 7,0 Signature of Report reparer Water Quality Regional Supervisor • Date /JITLI,11L JVLCVGI t<HLC,II.Jt"1, IN L!NCO LNTON I Aril. w,l I 478000m.E. '1 930000 FEET (S.C. 480 1 12'30" 4$2 2.5, 1. +O ;NT G.. r'i�. 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' _: I '.-% �P� d ` //. , a____ c .._,...,\ \' 2 11.,'\' 7.,,i, aL6''''./.1 :::/. 1.,,:,--, '____7',,',, : r .\ C 1 I { r / y \ \oo_J \l i \ 1 e • i r • i 11)i +J' )S /! ' •(, ),)._ II \,V• \ `l\�. `�1 1,,S-•.�'±���\''` '�,� 693`_ (\�\\' __ \�_ � _ • t)� Jt� p1•�E ` \\ , �\ /ill = �'� � \F\ .< \ I • J i � I In III 1 \.\. \ \ ., / 8 ` �=i1- 75` '( 4 \ 1 /. Th \ , \ ill CIl�\,L a� )�` , � 1 n�\\r /; ;4��;,,,\ ,i. . f � ' ik 10, To: Permits and Engineering Unit Water Quality Section Date: May 17, 1991 NPDES STAFF REPORT AND RECOMMENDATIONS . County: Gaston NPDES Permit No. : NC0049824 MRO No. 91-101 PART I - GENERAL INFORMATION 1. Facility and Address: Colloids, Inc. Walsh Division 207 Telegraph Drive Gastonia, N. C. 28056 2. Date of Investigation: 5/9/91 3 . Report Prepared By: Allen Hardy, Environmental Engineer I. 4. Person Contacted and Telephone Number: Warren Jones, Operations Manager, (704) 865-7451; Hans Hansen, Plant Manager, ( 704) 854-7451. 5. Directions to Site: From the intersection of U.S. Highway 321 and Telegraph Drive, travel east on Telegraph Drive approximately 0.1 mile. Walsh Chemical Company will be on the right. 6. Discharge Point(s) , List for all discharge Points: - 0 ,1 802 Latitude: 35 12 ' 00" 35 12 ' 06" Longitude: 81° 12 ' 25 81° 12 ' 26" Attach a USGS Map Extract and indicate treatment plant site and discharge point on map. USGS Quad No. : G14NW 7. Size ( land available for expansion and upgrading) : There appeared to be adequate land available for expansion and upgrading. 8 . Topography (relationship to flood plain included) : The site contained gently rolling terrain with slopes of 5-12%. The site did not appear to be in the flood plain. 9. Location of Nearest Dwelling: The nearest dwelling was approximately 150-200 feet from the discharge location. 10. Receiving Stream or Affected Surface, Waters: UT to Crowders Creek. a Page Two a. Classification: C b. River Basin and Subbasin No. : Catawba 03-08-37 c. Describe receiving stream features and pertinent downstream uses: The discharges appeared to be the headwaters of the receiving stream. There was very little flow in the receiving stream, possibly zero flow (7Q10=0) conditions. There are several discharges into the receiving stream - NC0005231 (Homelite-Gastonia) , NC0059366 (Kenneth Balsom Residence) , NC0032794 (Petty Machine) , and NC0063835 (A.B. Carter, Inc. ) . PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. Type of Wastewater: 0% Domestic 100% Industrial a. Volume of Wastewater: MGD (Design Capacity) b. Types and quantities of industrial wastewater: N/A. c. Prevalent toxic constituents in wastewater: Biocides are used in the cooling towers. The type of biocides used were submitted with the application. d. Pretreatment Program (POTWs only) : N/A. * Flow is dependent on the amount of usage of the cooling towers. Since flow is not required to be monitored, an average is not available from the self-monitoring data. 2. Production Rates (industrial discharges only) in Pounds: N/A. 3 . Description of Industrial Process (for industries only) and Applicable CFR Part and Subpart: CFR Part 414 Organic Chemicals. 4. Type of Treatment ( specify whether proposed or existing) : Effluent from discharge 001 empties into a small holding pond prior to discharging to the receiving stream. Pipe 002 discharges directly into the receiving stream. 5. Sludge Handling and Disposal Scheme: N/A. 6 . Treatment Plant Classification: Less than 5 points; no rating ( include rating sheet) . N/A. 7. SIC Code(s) : 2821, 2822, 2899 Wastewater Code(s) : Primary: 14 Secondary: t r Page Three PART III - OTHER PERTINENT INFORMATION , 1. Is this facility being constructed with Construction Grants Funds (municipals only) ? No. 2. Special monitoring requests: No. 3 . Additional effluent limits requests: No. 4. Air Quality and/or Groundwater concerns or hazardous waste utilized at this facility that may impact water quality, air quality or groundwater? No air quality concerns are expected from the discharges. Groundwater quality may be effected from an unlined holding pond which receives a non- contact cooling water that has biocide additives. No hazardous waste is utilized in the process for the NPDES discharges. 5. Other: No PART IV - EVALUATION AND RECOMMENDATIONS The applicant, Walsh Division - Colloids, Inc. , has requested renewal of their permit which allows them to discharge non-contact cooling water containing biocide additives. A review of the self-monitoring data from 4/90 through 3/91 reveals no violations of the effluent limitations. The facility plans to connect to an area wide sewer (Gastonia-Crowders Creek WWTP NC0074268) as soon as possible. It is recommended that the permit be renewed. w MIX � 4.-Jcw_} L 5 /itef9t Signature of Report $: arer Date ✓/ / D. "cam -0 0/ Water Quality egional Supervisor Date Y .,ice `O&'N''.,+����I \\L�. `�!' • 4 :i ( Jl i l •;''' ��: 1( '')„, t�/% \• _ of •L� Y 1 �,�it - R / - �� ' � 4,\, � '. I 1. ,,, • , ^I ,,, \____,--).)- - ' ! ).4:\*\. -----I 'c--- :-' -' /' r 7 7 - - - i ,y J !,u ` a Towerr K • lij. ., 100 \ •. _ �� • ! !/ram 1 ,#xdG_A; ,1 11 o - l 44. /(� �„ ___. ..) s , , 1 _ , _.,„ , ..,,,,,---t:-- -,.,.•_,,s,'L:, - ( V W--"1/.::-/ i f_ ; / 1. Li % V 1 J, _ � • Ccm. • \J 1� of 1 :•r ;vT\ •-- r \ ;I, ,r 1 I 1 e ., r )t)ir ..1,:---. .,',1,: ...\\c-.,:- ! �! '',1I "1• `l ` .*V 11 -__ /Q .-- - --- y 1 ' {j \'' t <• , \ .t 1 _ \ V\ (. o 1t V_--- 7 " -•--�- I;' `t11 ! /ter-- -. '7':,),.'':‘'.) ...:''\'•.irtY1 Y-. ( P 1. �i �sr _ 9'3 � , � "� ` 1 C7 � F95 • /. v �A .:t: '•,• tk r •':•'.. _ - , , I /, . . ;frt •',',..,-•:-,%'N .,.„.,C.•.::,t-2-.:.:_,''-' ---.%illti,t i l \ ` , / /// f,&,`,�„ _ ' L, �� \� f Crowder dip. i ('; ;. • 1 \\, (' t` `•--1 I I ! it fat 1.\ - /. t .- J I 'SUbs• ,( ..il" �► / �i'��,�•1 -.`.. - ._ �.. _�� .. ,•....:L•-' ( / • i / t y" Palk 4 0014 �' 6�" �ri.t, �� LAND CUB ,,, T10N V yr. , p 4(/' � .•�.,�, QPR 30 State of North Carolina ��/''�1991 De ent of Environment, Health, and Natural R a~ice �� ENVIROr{;oT Division of Environmental Management AND NATURAL RESgU 512 North Salisbury Street • Raleigh, North Carolina 27611 James G.Martin,Governor George T.Everett,Ph.D. William W.Cobey,Jr.,Secretary e „ ---- Director 4/29/91 .6c.c Warren Jones, Oper. Mgr. 6 Colloids, Inc. y7'r 1�, ���.; Subject : NPDES Permit Application 207 Telegraph Drive _- - . NPDES Permit No.NC0049824 Gastonia, NC 28056 sue __ Walsh Division Dear Mr. Jones Gaston County This is to acknowledge receipt of the following documents on March 7, 1991: Application Form _ Engineering Proposal (for proposed control facilities) , Request for permit renewal, Application Processing Fee of $200.00, Other , The items checked below are needed before review can begin : 4 Application Form , attached - Engineering proposal (see attachment) , - Application Processing Fee of , - Delegation of Authority (see attached) Biocide Sheet (see attached) Other Statement whether any change in biocide use from 1080 gm. /day of SELcide 401 has occured (see attached) If the application is not made complete within thirty (30) days, it will be returned to you and may be resubmitted when complete . This application has been assigned to Jule Shanklin (919/733-5083) of our Permits Unit for review. You will be advised of any comments recommendations, questions or other information necessary for the review of the application. I am, by copy of this letter, requesting that our Regional Office Supervisor prepare a staff report and recommendations regarding this discharge . If you have any questions regarding this applications, please contact the review person listed above . S ' cerel /',� ( . ' 01 , M Dale Overcash, P .E . CC : Mooresville Regional Office / Polilutlon Prevention Pays P.O.Box 27687,Raleigh,North Carolina 27611-7687 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer ... 47:04--, ..--.1 N ilAirt)..16V- u. "c450.0.`11414" • �5 .tea 3G°3� State of North Carolina �� Department of Environment, Health, and Natural Resources Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27611 ,q • k James G. Martin, Governor Gorge T.Everett,Ph. D. William W. Cobey,Jr., Secretary '' `4 •= a February 18, 1991 Mr. Warren Jones MAR )991 Operations Manager Walsh Division - Colloids, Inc. <r ;; t. .�. : -, , 207 Telegraph Drive j 1 Gastonia, NC 28056 Subject: NPDES Permit Application NPDES Permit No. NC0049824 Walsh Division - Colloids, Inc. Gaston County Dear Mr. Jones: On February 15, 1991, the Division of Environmental Management received a NPDES Permit Application for the subject facility. The application is considered incomplete. Therefore, the Division of Environmental Management is returning the application. The returned i • ust be resubmitted with the following to complete the application: / 1 . A the k for $200.00 ma e1payable to the NC Department of EHNR (see attached fee regula • ns . eck for $400.00 is enclosed. The Division of Environmental Management will initiate the permit review process upon receipt of the above requested information. The receipt of the above information does not preclude this Division from requesting additional information at a future date. If you have any questions, please contact me at (919) 733-5083. Sincerely, 1.(e N915t.c. M. Dale Overcash, PE------ Supervisor, NPDES Permits cc: Mooresville Regional Office Pollution Prevention Pays P.O.Box 27687,Raleigh,North Carolina 27611-7687 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer s° . =tip;\�� 1'\' ,t-. 1•••.,� �: �-,�.�-�� �•� . State of North Carolina Department of Environment, Health and Natural Resources AIT'llYgrA Mooresville Regional Office James B. Hunt, Jr., Governor p E H MFR. / DIVISION OF LAND RESOURCES LAND QUALITY SECTION August 15, 1997 Mr. James P. Nelli, Plant Manager B. F. Goodrich 207 Telegraph Drive Gastonia, North Carolina 28056 Dear Mr. Nelli: This office has received a soil erosion and sediment control plan for the project listed on page two which was submitted as required by the North Carolina Sedimentation Pollution Control Act (G. S. 113A-57) . Please be advised that the Act requires that all persons disturbing an area of one or more acres of land must obtain approval of a soil erosion control plan prior to the commencement of the land-disturbing activity. The Act further states that this plan must be filed a minimum of 30 days prior to the activity and the approving authority must approve or disapprove the submitted plan within 30 days of receipt. Failure of the approving authority to approve or disapprove the submitted plan within the 30 days period will be deemed approval of the plan if the submitted plan is complete. Commencement or continuation of a land-disturbing activity under the jurisdiction of this Act prior to the approval of an erosion and sediment control plan is a violation of the Act. We have performed a preliminary review of your submitted plan and have determined that additional information will be necessary before a final review can be completed. Enclosed is a checklist of items that must be submitted before we can complete the review process. Failure to provide the additional information may result in disapproval of your plan. 919 North Main Street, N Pi* FAX 704 663 6040 Mooresville,North Carolina 28115 An Equal Opportunity/Affirmative Action Employer Voice 704-663-1699 unizr=ms 50%recycled/10%post-consumer paper Page Two If you have questions please do not hesitate to contact Jonathan Hartwig of this office. Your cooperation in this matter is appreciated and we look forward to working with you on this project. Sincerely, ILAKI Steve Allred Asst. Regional Engineer Land Quality Section Project Name: B. F. Goodrich Location: US 321 - Gaston County Submitted By: B. F. Goodrich Date Received by Land Quality Section: August 13, 1997 cc: ERM-Southeast, Inc. SEA/ae tate of North Carolina A Department of Environment, 1:11910re A Health and Natural Resources Mooresville Regional Office p a I---i Ni FR Division of Land Resources Land Quality Section PROJECT NAME: gjc- (1 cccr, 1 COUNTY: Cj/},51-Z,0 DATE: g f 41 7 EROSION AND SEDIMENTATION CONTROL PLAN CHECKLIST To expedite the approval process, a cursory review of your submitted Erosion Control Plan has been made and has shown the need for additional information as specified below. To meet our review schedule ny additional information should be received by this Office no later than V..21147 . Failure to meet this schedule may result in disapproval of your plan. LOCATION OF PROJECT: 704-663-1699. Including roads, streets, watercourses and other major DESIGN CALCULATIONS: landmarks or features Preconstruction runoff calculations, GENERAL SITE FEATURES: for each outlet from the site (at each peak discharge location) Legend; north arrow, plan s c a le , erosion control measures, etc. Culverts and storm sewers Property lines and boundaries of total Open channels; existing and planned tract (include temporary linings) Existing and proposed contours Energy dissipators, (include stone size and dimensions) Limit and acreage of disturbed area Sediment basins, pits, check dams Planned & existing buildings and elevations FINANCIAL RESPONSIBILITY/OWNERSHIP FORM Planned & existing road locations and elevations Completed, notarized Financial Responsibility/Ownership Form Lot and/or building numbers Accurate application fee Geographic features; rock outcrops, seeps, springs, wetlands, streams, Certificate of assumed name, if the lakes, dams, etc. owner is a Partnership Easements & adjoining property uses VEGETATIVE STABILIZATION: Profiles; streets, utilities, lateral ditchlines, etc. Methods of soil preparation Stockpile locations Seed type and rates (temporary & X permanent) Plan proposes 150 feet or more stream disturbance, 401 Water Quality Fertilizer type and rate certification may be necessary for this project. Please contact Rex Gleason Mulch type and rate with the Water Quality Section at //11 NTINUED ON SACK- -2- SITE DRAINAGE FEATURES: Drainage features; existing and planned (including off-site areas EROSION CONTROL MEASURES: that drain through the project) Location of measures, temporary and Size of sub-watersheds (Acres) permanent erosion control measures Culverts & sewers; size and location Construction drawings, details for temporary and permanent erosion control Soils information (type, special measures characteristics) Maintenance requirements of measures Name and classification of receiving watercourse or name of municipal _ Contact persons for maintenance of operator (where stormwater measures discharges) BORROW AND/OR WASTE AREAS: NARRATIVE AND CONSTRUCTION SEQUENCE: If the same person conducts the land- Nature and purpose of project disturbing activity and any related borrow or waste activity, that Construction sequence as it relates borrow/waste activity shall constitute to sedimentation and erosion control part of the land-disturbing activity, including provisions for the unless the borrow/waste activity is installation of critical measures regulated under the Mining Act of 1971, prior to the initiation of the land- or is a landfill regulated by the disturbing activity; all maintenance Division of Solid Waste Management. If of measures; and the removal of the land-disturbing activity and the measures after areas they serve have related borrow/waste activity are not been permanently stabilized. conducted by the same financially responsible party, they shall be considered separate land-disturbing activities. OTHER INFORMATION: • Project Name: BF Gc, oiLA County: 4A4Dh Reviewed by: JUnr]/- Rn f•I Ark',"i C.) Date: gjl'f/17 Alas Rex Gleason - Water Quality DIVISION OF ENVIRONMENTAL MANAGEMENT December 7, 1995 N.C. DEPT. OF ENVIRONMENT, HEALTH, &NATURAL RESOURCES MEMORANDUM: DEC 13 1995 To: Susan Robson DIVISION OF ENVIRONMENTAL MANAGEMENT MOORESVILLE REGIONAL OFFICE Through: Matt Matthews ti`1 From: Melissa RosebrockN`'� Subject: BF Goodrich Use of Biocides NPDES No. NC0049824 Gaston County BF Goodrich-Gastonia has submitted microbiocides Biosperse 261T and Biosperse 240 for approval. Data submitted by the subject facility concerning the dosage rate of the compounds, system volume, average daily discharge, toxicity of the active ingredient and/or breakdown products, and minimum stream flow have also been reviewed and evaluated. Biosperse 240 toxicity data supplied by the facility was for rainbow trout (whole product LC50= 20.0 mg/1). Given the geographical location of the facility, the more appropriate toxicity data would be for the Daphnia magna (whole product LC50=24.8 mg/1). This revision did not alter the final analysis portion of the worksheet (part IV, page three). Calculations summarized on the accompanying worksheet predict that the use of Biosperse 261T and Biosperse 240 at the stated dosage rate, retention time(6.0 hours), and discharge conditions will not result in toxic impact to aquatic life in the receiving stream. Therefore, the use of this product as a biocide at BF Goodrich-Gastonia is deemed acceptable. If there are questions regarding this review please contact me at (919)733-2136. Attachments cc: l sori=^l R3 "1 Central files BF Goodrich/GastoniaBIOCIDE WORKSHEET PERMIT#: NC0049824 RECEIVING STREAM: UT to Crowders Creek 7010 (cfs): 0.00 I.W.C.%: 100.00 PRODUCT: Biosperse 261-T ACTIVE INGREDIENT: 92.5% 1 BROMO-3-CHLORO-5,5-DIMETHYLHYDANTOIN HALF LIFE (DAYS): 0.042 STEADY STATE DISC GONG: 0.0080 LC50 OF SELECTED TOX DATA(MG/L): 0.46 DEGRADATION FACTOR: 16.558 DECAY RATE: 16.4286 APPLICATION FACTOR: 0.050 DOSAGE RATE(GRAMS/DAY): 42.52 AVG DAILY DISCHARGE(MGD): 0.011 INSTREAM BIOCIDE CONC: 0.008 VOLUME OF SYSTEM(MIL.GAL'S): 0.085 REGULATED LIMITATION: 0.023 PASS/FAIL: PASS • 7010 (cfs): 0.00 I.W.C.%: 100.00 PRODUCT: Biosperse 240 ACTIVE INGREDIENT: 5% 2,2-Dibromo-3-nitrilopropionamide HALF LIFE (DAYS): 0.08 STEADY STATE DISC CONC: 0.6262 LC50 OF SELECTED TOX DATA (MG/L): 24.8 DEGRADATION FACTOR: 8.443 DECAY RATE: 8.3133 APPLICATION FACTOR: 0.050 DOSAGE RATE(GRAMS/DAY): 1701.00 AVG DAILY DISCHARGE(MGD): 0.011 INSTREAM BIOCIDE CONC: 0.626 VOLUME OF SYSTEM(MIL.GAL'S): 0.085 REGULATED LIMITATION: 1.240 PASS/FAIL: PASS Half-life Determination 261-T Half-life (hours) 1 Shut off time (hours) 6 Initial Amount (grams) 2721 .552 (6.0 pounds) Final Amount (grams) 42.56 240 Half-life (hours) 2 Shut off time (hours) 6 Initial Amount (grams) 13607.76 (30.0 pounds) Final Amount (grams) 1701 .72 Page 1 ,--4 e__Z (2_ il State of North Carolina Department of Environment, Health and Natural Resources Aff iCir A Mooresville Regional Office James B. Hunt, Jr., Governor CO H N FR. B. Howes, Secretary Linda Diane Long, Regional Manager Division of Environmental Management October 27, 1994 Mr. B. Edgar Longstreet, Jr. , Manager Environmental Affairs - The BF Goodrich Company 207 Telegraph Drive Gastonia, North Carolina 28056 Subject: Request for Permit Name Change NPDES Permit No. NC0049824 Walsh Division of Colloids Inc . __ Gaston County, NC Dear Mr. Longstreet: This is to advise you that the subject request should be sent to our Raleigh Office for review and approval . The Raleigh Office's mailing address is as follows : DEHER/DIVISION OF ENVIRONMENTAL MANAGEMENT Post Office Box 29535 Raleigh, North Caroline 27626-0535 In submitting your request, please include copies of documents of property transactions for both parties (i.e. the buyer and the seller) plus a processing fee of $100.00. We are returning your letter of request and the check for $25 . 00 . If you have any questions regarding this matter, please contact Mr. G. T. Chen or me at (704) 663-1699 . Sincerel , DRi. J(24c44,4, D. Rex Gleason, P. E. Water Quality Regional Supervisor Enclosures gtc 919 North Main Street,Mooresville,North Carolina 28115 Telephone 704-663-1699 FAX 704-663-6040 An Equal Opportunity Affirmative Action Employer 50%recycled/ 10%post-consumer paper