NC0000396_Hg Field Blank Didn't Meet Criteria_20201123

Action History (UTC-05:00) Eastern Time (US & Canada)
Subrrit by Anonymous User 11/23/2020 9:03:01 AM (Supplemental Submittal)
Submit by Thedford, Wren 11/23/2020 1:36:17 PM (Supplemental Info Submittal)
• Thedford, Wren assigned the task to Thedford, Wren 11/23/2020 1:35 PM
• The task was assigned to Thedford, Wren, Bennett, Bradley 11/23/2020 9:03 AM

Initial Review Information
Updated ID#:* IWORTANf:FEVIBAERSl-IOLLDVERFYand revise here ifnecessary.
NC0000396
How should this project be handled?*
r File r Discard
Information Submitted on 11/23/2020
Submitter Information
Name: Teresa Williams
Who is subrritting the inforrretion?
Email Address:* [e-mail]
Submittal Information
The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental
information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted
electronically through the eDMR system and should not be submitted here. Division staff will reviewall
uploaded documents and will only maintain required information. Documents such as laboratory reports are not required
to be submitted and will not be maintained in the system.
Project Information:
Rease SUDDly the Dernit nun ber for this
Existing ID#* PerrritNurrber
NC0000396
Exarrples: NOKxxxxxx or NO&xxxxx
Facility Name:* Asheville Steam Electric Generating Plant
County: Buncombe
Please upload all files that need to be
submited. *
dick the upload button or drag and drop files here to attach docurrent
Asheville NC0000396 DMR Upload Cover Memo
1.26M6
10.2020.pdf
Only pdf files are accepted.
Comments about the attachments:
With regard to Hg field blank detection.
* V By checking the box and signing box below, I certify that:
I L... - ..4..... + - ......� �...+.. .....J .........I..+.. �..F...w...+�.... .... +L. �.. f......

- I IICIVC IY.IVCII II UC, Cll.l.UI CIIC, CII IU I.VI I IF/ICLC II IIVI I I ICIIIVI I VII LI IIJ IVI II I,
• I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the
NC General Statutes (the "Uniform Electronic Transactions Act)
• I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
(the "Uniform Electronic Transactions Act');
• I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
signature; AND
• I intend to electronically sign and submit the Supplemental Information form."
Full Name: Teresa L. Williams
Signature:
,-Irlg 6e WCWdrd---
Date Submitted: 11/23/2020

Antonio D. Price, PE
Plant General Manager
Asheville Combined Cycle Station

Duke Energy Progress
ASVL PLT | 46 Duke Energy Lane
Arden, NC 28704

o: 828-650-0620
f: 828-650-0701
[e-mail]

Submitted Electronically

File No.: 12520B

November 18, 2020
Memo
To: Central Files
NCDEQ, Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
From: Duke Energy Progress
Asheville Combined Cycle Station
46 Duke Energy Lane
Arden, NC 28704

RE: Asheville Steam Electric Generating Plant
Buncombe County
NPDES Number NC0000396
Discharge Monitoring Report (DMR)

In accordance with condition I.A. (18) 1., replaced by electronic signature and submission
guidelines, the October 2020 NPDES eDMR for Duke Energy Progress’s Asheville Steam
Electric Plant – NPDES Permit Number NC0000396 has been submitted.

The Outfall 001 low-level mercury field blank sample collected October 26, 2020 did not meet
quality control criteria in accordance with EPA Method 1631E. Per Division guidance ("NPDES
Mercury Requirement- EPA Method 1631 Additional Information"), the mercury field blank
samples have been noted in the eDMR comments section, and the associated analytical reports
are attached to this memo and uploaded electronically to the eDMR Supplement Data Upload
server.

Please contact Ms. Teresa Williams at [phone] or Ms. Mariea Keezel at [phone]
with any questions concerning the data in this submittal.

#=CL#
November 09, 2020
LIMS USE: FR - MARIEA KEEZEL
LIMS OBJECT ID: 92502166
92502166
Project:
Pace Project No.:
RE:
Ms. Mariea Keezel
Duke Energy
,
OUTFALL 001 102620
Dear Ms. Keezel:
Enclosed are the analytical results for sample(s) received by the laboratory on October 26, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
Project Manager
1(828)254-7176
Enclosures
cc:Program Manager, Duke Energy
Christian Patterson, Duke Energy Progress, Inc.
Jennifer Verde, Anchor QEA
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 1 of 18
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 2 of 18
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92502166001 FIELD BLANK EPA 1631E 1 PASI-ANMP
92502166002 OUTFALL 001_2020/10/26_1050_N EPA 1664B 1 PASI-CCJM
EPA 200.7 Rev 4.4 1994 11 PASI-ARDT
EPA 1631E 1 PASI-ARDT
SM 2540C-2011 1 PASI-ARED
SM 2540D-2011 1 PASI-ARED
EPA 300.0 Rev 2.1 1993 2 PASI-ACDC
SM 4500-Cl-E-2011 1 PASI-ADMN
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 3 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Sample:FIELD BLANK Lab ID:92502166001 Collected:10/26/20 10:50 Received:10/26/20 15:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 0.575 ng/L 11/03/20 13:14 7439-97-6 1g,C010/28/20 17:400.50 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 4 of 18
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Sample:OUTFALL
001_2020/10/26_1050_N
Lab ID:92502166002 Collected:10/26/20 10:50 Received:10/26/20 15:24 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: EPA 1664B
Pace Analytical Services - Charlotte
HEM, Oil and Grease
Oil and Grease ND mg/L 10/29/20 13:175.0 1
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services - Asheville
200.7 MET ICP
Arsenic ND ug/L 11/02/20 05:52 7440-38-210/29/20 01:3510.0 1
Beryllium ND ug/L 11/02/20 05:52 7440-41-710/29/20 01:351.0 1
Cadmium ND ug/L 11/02/20 05:52 7440-43-910/29/20 01:351.0 1
Chromium ND ug/L 11/02/20 05:52 7440-47-310/29/20 01:355.0 1
Copper ND ug/L 11/02/20 05:52 7440-50-810/29/20 01:355.0 1
Lead ND ug/L 11/02/20 05:52 7439-92-110/29/20 01:355.0 1
Nickel 11.0 ug/L 11/02/20 05:52 7440-02-010/29/20 01:355.0 1
Selenium ND ug/L 11/02/20 05:52 7782-49-210/29/20 01:3510.0 1
Silver ND ug/L 11/02/20 05:52 7440-22-410/29/20 01:355.0 1
Hardness, Total(SM 2340B)121000 ug/L 11/02/20 05:5210/29/20 01:356621
Zinc 17.9 ug/L 11/02/20 05:52 7440-66-610/29/20 01:3510.0 1
Analytical Method: EPA 1631E Preparation Method: EPA 1631E
Pace Analytical Services - Asheville
1631E Mercury,Low Level
Mercury 2.63 ng/L 10/30/20 17:34 7439-97-610/28/20 17:400.50 1
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
2540C Total Dissolved Solids
Total Dissolved Solids 299 mg/L 10/29/20 21:5825.0 1
Analytical Method: SM 2540D-2011
Pace Analytical Services - Asheville
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 10/29/20 20:552.5 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services - Asheville
300.0 IC Anions 28 Days
Bromide 0.68 mg/L 10/27/20 16:46 24959-67-90.10 1
Fluoride 0.29 mg/L 10/27/20 16:46 16984-48-80.10 1
Analytical Method: SM 4500-Cl-E-2011
Pace Analytical Services - Asheville
4500 Chloride
Chloride 64.2 mg/L 11/02/20 11:16 16887-00-65.0 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 5 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
576579
EPA 1664B
EPA 1664B
1664 HEM, Oil and Grease
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3051312
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Oil and Grease mg/L ND 5.0 10/29/20 13:17
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3051313LABORATORY CONTROL SAMPLE:
LCSSpike
Oil and Grease mg/L 34.640 86 78-114
Parameter Units
MS
Result
% Rec
Limits Qualifiers% RecConc.
3051314MATRIX SPIKE SAMPLE:
MSSpike
Result
92501489002
Oil and Grease mg/L 13.5 M1403478-114ND
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 6 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
576488
EPA 1631E
EPA 1631E
1631E Mercury,Low Level
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166001, 92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3051019
Associated Lab Samples:92502166001, 92502166002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 11/03/20 14:31
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3051020
Associated Lab Samples:92502166001, 92502166002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 11/03/20 13:21
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3051021
Associated Lab Samples:92502166001, 92502166002
Matrix:Water
Analyzed
Mercury ng/L ND 0.50 11/03/20 14:39
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3051022LABORATORY CONTROL SAMPLE:
LCSSpike
Mercury ng/L 5.725 114 80-120
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3051023MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92499904002
3051024
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 250 78 71-12588 1125017.8 214 239
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3051025MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92501678001
3051026
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Mercury ng/L 25 98 71-12596 225ND24.5 24.0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 7 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
576513
EPA 200.7 Rev 4.4 1994
EPA 200.7 Rev 4.4 1994
200.7 MET
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3051190
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Arsenic ug/L ND 10.0 11/02/20 05:45
Beryllium ug/L ND 1.0 11/02/20 05:45
Cadmium ug/L ND 1.0 11/02/20 05:45
Chromium ug/L ND 5.0 11/02/20 05:45
Copper ug/L ND 5.0 11/02/20 05:45
Hardness, Total(SM 2340B)ug/L ND 662 11/02/20 05:45
Lead ug/L ND 5.0 11/02/20 05:45
Nickel ug/L ND 5.0 11/02/20 05:45
Selenium ug/L ND 10.0 11/02/20 05:45
Silver ug/L ND 5.0 11/02/20 05:45
Zinc ug/L ND 10.0 11/02/20 05:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3051191LABORATORY CONTROL SAMPLE:
LCSSpike
Arsenic ug/L 503500 101 85-115
Beryllium ug/L 482500 96 85-115
Cadmium ug/L 482500 96 85-115
Chromium ug/L 475500 95 85-115
Copper ug/L 507500 101 85-115
Hardness, Total(SM 2340B)ug/L 3120033100 94 85-115
Lead ug/L 486500 97 85-115
Nickel ug/L 484500 97 85-115
Selenium ug/L 479500 96 85-115
Silver ug/L 237250 95 85-115
Zinc ug/L 480500 96 85-115
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3051192MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502166002
3051193
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 108 70-130110 1500ND547554
Beryllium ug/L 500 103 70-130102 1500ND514511
Cadmium ug/L 500 105 70-130105 0500ND525524
Chromium ug/L 500 101 70-130101 0500ND507505
Copper ug/L 500 108 70-130108 0500ND546544
Hardness, Total(SM 2340B)ug/L 33100 108 70-13099 233100121000157000154000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 8 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3051192MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502166002
3051193
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Lead ug/L 500 104 70-130104 0500ND518519
Nickel ug/L 500 102 70-130102 050011.0 522 520
Selenium ug/L 500 110 70-130110 0500ND552550
Silver ug/L 250 101 70-130101 0250ND253253
Zinc ug/L 500 101 70-130101 050017.9 522 523
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3051194MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502197008
3051195
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Arsenic ug/L 500 110 70-130110 0500ND552553
Beryllium ug/L 500 100 70-130102 2500ND500512
Cadmium ug/L 500 104 70-130105 1500ND518525
Chromium ug/L 500 99 70-130101 2500ND495503
Copper ug/L 500 106 70-130109 2500ND533546
Hardness, Total(SM 2340B)ug/L 33100 96 70-130102 333100461007800080000
Lead ug/L 500 103 70-130104 2500ND514522
Nickel ug/L 500 101 70-130103 1500ND509516
Selenium ug/L 500 107 70-130109 2500ND536546
Silver ug/L 250 99 70-130101 1250ND249252
Zinc ug/L 500 101 70-130102 1500ND506509
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 9 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
576778
SM 2540C-2011
SM 2540C-2011
2540C Total Dissolved Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3052284
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Total Dissolved Solids mg/L ND 25.0 10/29/20 21:58
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3052285LABORATORY CONTROL SAMPLE:
LCSSpike
Total Dissolved Solids mg/L 256250 102 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92502066014
3052286SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 207 3214
Parameter Units
Dup
Result QualifiersRPDResult
92502197002
3052287SAMPLE DUPLICATE:
Total Dissolved Solids mg/L 248 0248
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 10 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
576773
SM 2540D-2011
SM 2540D-2011
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3052262
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 10/29/20 20:48
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3052263LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 240250 96 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92502479001
3052264SAMPLE DUPLICATE:
Total Suspended Solids mg/L 184 5194
Parameter Units
Dup
Result QualifiersRPDResult
92501999002
3052731SAMPLE DUPLICATE:
Total Suspended Solids mg/L 650 2660
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 11 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
575921
EPA 300.0 Rev 2.1 1993
EPA 300.0 Rev 2.1 1993
300.0 IC Anions
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3048181
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Bromide mg/L ND 0.10 10/27/20 15:34
Fluoride mg/L ND 0.10 10/27/20 15:34
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3048182LABORATORY CONTROL SAMPLE:
LCSSpike
Bromide mg/L 2.32.5 92 90-110
Fluoride mg/L 2.42.5 97 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3048183MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502122001
3048184
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 105 90-110107 12.52.0 4.6 4.6
Fluoride mg/L 2.5 100 90-110102 22.50.86 3.4 3.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3048185MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502066007
3048186
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Bromide mg/L 2.5 91 90-11091 02.50.15 2.4 2.4
Fluoride mg/L 2.5 93 90-11093 02.5ND 2.4 2.4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 12 of 18
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
577224
SM 4500-Cl-E-2011
SM 4500-Cl-E-2011
4500 Chloride
Laboratory:Pace Analytical Services - Asheville
Associated Lab Samples:92502166002
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:3054350
Associated Lab Samples:92502166002
Matrix:Water
Analyzed
Chloride mg/L ND 1.0 11/02/20 11:14
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
3054351LABORATORY CONTROL SAMPLE:
LCSSpike
Chloride mg/L 20.620 103 90-110
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3054352MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92502166002
3054353
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L 10 95 90-11092 01064.2 73.8 73.4
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
3054354MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92503093021
3054355
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Chloride mg/L M6109390-110150 110494503509
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 13 of 18
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
The mercury concentrations in the field blanks may be subtracted from the associated sample per EPA method 1631E
section 12.5.2., “… field blanks associated with the sample may be subtracted from the results for that sample, or must
be subtracted if requested or required by a regulatory authority or in a permit.”
1g
Result confirmed by second analysis.C0
Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.M1
Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.M6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Page 14 of 18
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92502166
OUTFALL 001 102620
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92502166002 576579OUTFALL
001_2020/10/26_1050_N
EPA 1664B
92502166002 576513 576544OUTFALL
001_2020/10/26_1050_N
EPA 200.7 Rev 4.4 1994 EPA 200.7 Rev 4.4 1994
92502166001 576488 576704FIELD BLANK EPA 1631E EPA 1631E
92502166002 576488 576704OUTFALL
001_2020/10/26_1050_N
EPA 1631E EPA 1631E
92502166002 576778OUTFALL
001_2020/10/26_1050_N
SM 2540C-2011
92502166002 576773OUTFALL
001_2020/10/26_1050_N
SM 2540D-2011
92502166002 575921OUTFALL
001_2020/10/26_1050_N
EPA 300.0 Rev 2.1 1993
92502166002 577224OUTFALL
001_2020/10/26_1050_N
SM 4500-Cl-E-2011
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 11/09/2020 11:48 AM
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
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