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164 Bostian Bridge Road
Statesville, North Carolina
H&H Job No. DOT-504
September 4, 2015
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SMARTER ENVIRONMENTAL SOLUTIONS
#C-1269 Engineering
#-245 Geology
2923 South Tryon Street, Suite 100 3334 Hillsborough Street
Charlotte, NC 28203 Raleigh, NC 27607 I www.harthickman.com
704.586.0007 main 919.847.4241 main
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Via Email
September 4, 2015
NC DOT — Roadside Environmental
4809 Beryl Road
Raleigh, NC 27606
Attention: Mr. Ethan Caldwell, LG and PE
Re: Semi -Annual Monitoring Report
NC DOT Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Dear Ethan:
Per your request, please find the attached EOS®
Monitoring Report for the above -referenced site.
information, please do not hesitate to contact me.
Sincerely,
Hart & Hickman, PC
//XY
Matt Bramblett, PE
Principal
Attachment
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SMARTER ENVIRONMENTAL SOLUTIONS
SEA' 2 2 2015
All
REDEIVEDIDENRIDWR
SEP 2 3 2015
Water Quality Regionai
Ooerations Sect:cr.
Injection and Semi -Annual Groundwater
If you have any questions or need further
cc: Ms. Debra Watts, DWR UIC Program (via certified mail and email)
Mr. Andrew Pitner, Mooresville DWR (via certified mail)
Mr. Allen Johnson, Property Owner (via certified mail)
Ms. Jane Murray, Iredell County Health Department (via certified mail)
2923 South Tryon Street, Suite 100 3334 Hillsborough Street
Charlotte, NC 28203 Raleigh, NC 27607 www.harthickman.com
704.586.0007 main 919.847.4241 main

EOSO Injection and Semi -Annual
Groundwater Monitoring Report
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Table of Contents
Section Pate No.
1.0 Introduction..................................................................................................................................1
2.0 Potential Receptor Survey Update.............................................................................................3
2.1 Water Supply Wells....................................................................................................................3
2.2 Surface Water..............................................................................................................................4
3.0 Groundwater/Surface Water Monitoring.................................................................................
.5
3.1 Data Collection Procedures........................................................................................................
Is
3.2 Groundwater Levels and Flow Direction...................................................................................
6
3.3 Surface Water Measurements and Analytical Data....................................................................
6
3.4 Groundwater Analytical Data.....................................................................................................
7
4.0 Evaluation of Natural Attenuation Parameters........................................................................9
4.1 Competing Electron Acceptors...................................................................................................9
4.2 Geochemical Indicator Parameters...........................................................................................12
4.3 Electron Donor..........................................................................................................................14
4.4 Presence of Degradation Daughter Products............................................................................14
5.0 Summary and Conclusions.......................................................................................................16
3ECEIVEDIDENRIDWR
SAP 2 3 2015
Water Quality Regiona•
Ooeratiols Sector,
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List of Tables
Table 1
Water Supply Well Inventory
Table 2
Water Supply Well Analytical Data Summary
Table 3
Water Level Data Summary
Table 4
Surface Water Analytical Data Summary
Table 5
Saprolite Monitoring Well Analytical Data Summary
Table 6
Shallow Bedrock Monitoring Well Analytical Data Summary
Table 7
Summary of Natural Attenuation Indicator Data
Table 8
Surface Water Parameters
List of Figures
Figure 1 Site Location Map
Figure 2 Site Map
Figure 3 Water Supply Well Location Map
Figure 4 EOS® Injection Point Locations
Figure 5 Estimated Shallow Groundwater Potentiometric Map (February 2015)
Figure 6 Target VOC Concentrations in Saprolite Groundwater
Figure 7 Target VOC Concentrations in Bedrock Groundwater
List of Appendices
Appendix A Laboratory Analytical Data
Appendix B TCE Concentration Trends
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EOS® Injection and Semi -Annual
Groundwater Monitoring Report
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
1.0 Introduction
On behalf of the North Carolina Department of Transportation (DOT), Hart & Hickman, PC
(H&H) has prepared this report to present post -injection groundwater monitoring data for the
former Asphalt Testing Laboratory Site No. 2-66. The site is located at 164 Bostian Bridge
Road, which is near Buffalo Shoals Road (State Road 1004) in Statesville, North Carolina
(Figure 1). A site map is provided as Figure 2.
Soil and groundwater impacts from former asphalt testing operations were previously identified
at the site. The asphalt testing utilized trichloroethene (TCE), 1, 1, 1 -trichloroethane (1,1,1-TCA),
and/or carbon tetrachloride (CTC). The approved CAP included excavation for source area soil
and monitored natural attenuation (MNA) for groundwater impacts. Approximately 162 tons of
impacted soils were removed from the source area in September 2001 as reported in H&H's
Semi -Annual Monitoring and Soil Remediation Report dated February 19, 2002. Confirmation
soil samples indicated that soils were adequately removed. Monitored natural attenuation,
consisting of semi-annual or annual groundwater monitoring, was conducted at the site from
2002 until prior to the bioenhancement injection in December 2012.
Because TCE concentrations remained more than two orders of magnitude above the
groundwater standard, a stream is located near the plume, and there is no public water available
in the area of the site, H&H recommended that the bioenhancement event be conducted in
shallow groundwater where TCE concentrations were the highest. Bioenhancement improves
subsurface conditions for more efficient natural attenuation by reductive dechlorination.
On behalf of DOT, H&H prepared an Underground Injection Control (UIC) Permit Application
dated August 24, 2012 to conduct a bioenhancement injection at the site. The injectant selected
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for the bioenhancement injection event was Emulsified Oil Substrate (EOS®). DENR issued the
UIC permit on November 9, 2012. The bioenhancement injection activities were conducted in
December 2012.
The injection event included 36 temporary direct push technology (DPT) injection points and
injecting the EOS® into the upper 20 ft of the saturated zone. The 36 temporary DPT injection
wells were installed approximately 20 ft apart perpendicular to groundwater flow and
approximately 35 ft apart parallel to groundwater flow within the target treatment area. The DPT
temporary injection wells were advanced to depths ranging from approximately 27 ft to 42 ft
below ground surface (bgs). The injection area and injection well locations are depicted on
Figure 4.
The EOS® concentrate was mixed with water prior to injection using an approximate mixing
ratio of 1:6 (EOS® to water). For the project, a total of approximately 1,618 gallons of EOS®
concentrate were mixed with approximately 10,666 gallons of potable water and injected into the
subsurface. The quantity of EOS® was determined using EOS Remediation, LLC's EOS®
Design Tool (Version 3.0) software. Approximately 323 to 508 gallons of diluted EOSO mixture
were injected into each injection well.
This post -injection semi-annual groundwater monitoring report includes a summary of post -
injection groundwater monitoring between July 2014 and February 2015.
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2.0 Potential Receptor Survey Update
A summary of area receptors is described below and was updated in November 2014. The next
annual receptor survey update will be conducted in the second half of 2015.
2.1 Water Supply Wells
The November 2014 receptor survey update was performed by reconnaissance within 1,500 ft of
the former asphalt -testing laboratory and by contacting the local utility department to confirm
that no municipal wells are in the area. During the November 2014 receptor update, no
additional water supply wells were identified within 1,500 ft of the site.
A total of 18 water supply wells (active, inactive, or abandoned) are located within a 1,500-ft
radius of the former asphalt -testing laboratory. The locations of the water supply wells are
indicated on Figure 3, and a summary of water supply well information is provided in Table 1.
Of the 18 water supply wells, four wells are located on -site and are designated as WSW -I,
WSW-2, WSW-4, and WSW-4A. In accordance with the approved CAP, H&H abandoned water
supply wells WSW-1 and WSW-2 in September 2001. Water supply wells WSW-4 (deeper) and
WSW-4A (shallow) are located approximately 500 ft southeast and upgradient of the source area.
WSW-4 serves the entire subject property and WSW-4A is inactive. Target volatile organic
compounds (VOCs) have not been detected in WSW-4 including during the most recent
sampling event in February 2015 (Table 2).
No off -site water supply wells are located downgradient of the former asphalt -testing laboratory.
Each of the 14 off -site water supply wells is located upgradient or cross -gradient of the former
asphalt laboratory. The closest off -site water supply well (WSW-5) is situated cross -gradient of
the site approximately 650 ft southwest of the former asphalt laboratory.
One of the 14 off -site water supply wells (WSW-3) is located cross -gradient of the former
asphalt -testing laboratory on the Dorothy Davis property (across an unnamed tributary of
Third Creek and approximately 1,200 ft northeast of the former laboratory). WSW-3 was
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sampled in September 1997 and again in October 1998. No target compounds were identified in
either sample. Further, a deep saprolite monitoring well (DMW-8), located on the same side of
the tributary as WSW-3, is not impacted. The lack of impacts in DMW-8 indicates that the
tributary acts as an effective hydraulic barrier.
Based on the distance from the former laboratory, the known extent of the contaminant plume,
and topographic and hydraulic gradient considerations, the potential for site groundwater impacts
to affect the off -site water supply wells is considered to be low.
2.2 Surface Water
Two surface water bodies are located within a 0.25-mile radius of the subject site (Figures 1
and 3). An unnamed tributary to Third Creek is located approximately 400 ft north of the former
laboratory and borders the northern property boundary. In addition, Third Creek is located
approximately 600 ft west of the former laboratory and borders the western property boundary.
Both of these surface water bodies appear to be discharge locations for site groundwater.
In February 1999, surface water samples were collected from both the unnamed tributary and
Third Creek at locations along the northern and western property boundaries of the site. In
addition, H&H collected a surface water sample (labeled SS-2) in June 2015 from the unnamed
tributary of Third Creek (Table 4 and Figure 2). The surface water sample was analyzed for
purgeable halocarbons by EPA Method 6200B. Target compounds were not detected in the
surface water sample. In addition, groundwater modeling conducted as part of the CAP indicates
that target compounds will not be present in these surface waters above surface water quality
standards in the future. Recent surface water sampling activities are discussed further in
Section 3.
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3.0 Groundwater/Surface Water Monitoring
As outlined in the UIC permit, H&H conducted a pre -injection groundwater monitoring events on
February 2 and 3, 2012 and December 7, 2012 to establish a baseline for comparison with post -
injection monitoring data. Additionally, H&H performed quarterly post -injection monitoring
events in February 2013, April 2013, June 2013, October 2013, January 2014, May 2014, July
2014, November 2014, and February 2015 to assess the performance of the implemented enhanced
bioremediation remedy. The April 2013, October 2013, May 2014, and November 2014 quarterly
sampling events were comprehensive events as outlined in the UIC permit application. The
groundwater sampling procedures and monitoring results for the most recent monitoring event in
February 2015 are discussed below. The locations of the monitoring and temporary injection
wells are indicated on Figure 4, and monitoring well construction information is provided in
Table 3.
3.1 Data Collection Procedures
H&H sampled deeper saprolite monitoring wells DMW-1, DMW-2, DMW-6, DMW-8, DMW-9,
DMW-10, and DMW-11 and bedrock monitoring well DMW-7. Additionally, bedrock
monitoring well DMW-3, which could not be located during the November 2014 sampling event,
was located with a metal detector and sampled. Samples from these wells were submitted for
laboratory analysis of VOCs by Environmental Protection Agency (EPA) Method 6200B
(reporting the EPA Method 601 list), nitrate, sulfate, sulfide, methane, ethane, ethee, Resource
Conservation and Recovery Act (RCRA) metals (arsenic, barium, cadmium, chromium, lead,
selenium, silver, and mercury), and total organic carbon (TOC). Field measurements were also
collected from these wells and the unnamed tributaryof Third Creek for dissolved oxygen DO
Yg ( ),
oxidation-reduction potential (ORP), specific conductivity, ferrous iron, pH, and temperature. In
addition, one surface water sample was collected from the unnamed tributary of Third Creek
located north of the site for laboratory analysis of VOCs by EPA Method 6200B (reporting the
EPA Method 601 list) on June 2, 2015.
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The sampling event was conducted using the following procedures. After monitoring well water
levels were gauged, DO concentrations were measured using a downhole probe. Following DO
measurements and prior to collection of groundwater samples, the target wells were purged using
dedicated disposable bailers until pH, temperature, and specific conductivity levels stabilized. If
a well went dry during purging, the purging process was considered to be complete.
Groundwater samples were collected with dedicated disposable bailers.
Groundwater samples were submitted for laboratory analyses of VOCs using methods listed
above. Pace Analytical Laboratories, Inc., a North Carolina -certified laboratory, conducted the
laboratory analyses. Dedicated laboratory -supplied sample bottles were used for sample
collection. A chain -of -custody record was completed for samples collected and included sample
description, date collected, time collected, matrix, sample container information, and analyses
required. The chain -of -custody was signed by H&H and placed along with the samples in a
chilled cooler for hand delivery to the laboratory by H&H. Copies of the laboratory analytical
data sheets and chain -of -custody records are provided in Appendix A.
3.2 Groundwater Levels and Flow Direction
Water levels in site monitoring wells were gauged using an electronic water level meter on
February 3, 2015 (Table 3). The estimated saprolite potentiometric map constructed from the
February 2015 groundwater elevation data is presented as Figure 5. The potentiometric map was
constructed using both shallow and deeper saprolite water levels. Consistent with previous data,
groundwater flow in the saprolite aquifer is generally to the northwest in the direction of
Third Creek and its tributary. The shallow groundwater has a calculated horizontal hydraulic
gradient of approximately 0.04 ft/ft.
3.3 Surface Water Measurements and Analytical Data
As required in the UIC permit, quarterly surface water measurements were collected from the
unnamed tributary of Third Creek at locations upstream (SS-1) and downstream (SS-2) of the
injection area to determine if the bioenhancement injection activities are adversely impacting the
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creek. The locations of SS-1 and SS-2 are depicted on Figure 2. Based on similar data between
the two locations during each sampling event, the bioenhancment injection has not adversely
impacted the tributary (Table 8).
H&H will continue to collect surface water field measurements at locations upstream and
downstream of the injection area on a quarterly basis. Should field measurements indicate
impacts to the tributary, surface water samples would be collected from the tributary and
analyzed for various parameters as outlined in the UIC permit.
As outlined in the UIC permit application, a surface water sample was collected from the
unnamed tributary of Third Creek at a location (SS-2) downgradient of the injection area on June
2, 2015. The sample was collected by lowering a bailer into the flowing stream. No VOCs were
detected in the surface water sample (Table 4).
3.4 Groundwater Analytical Data
Deeper Saprolite
Analytical results from the February 2015 sampling event indicate groundwater impacts above
groundwater standards in deeper saprolite monitoring wells DMW-6 and DMW-11 (Table 5 and
Figure 6). TCE and 1,1-dichloroethane were the only two compounds detected above groundwater
standards. The most elevated concentrations were detected in DMW-6. TCE was detected in
monitoring well DMW-6 at a concentration of 41.8 µg/l, which is above the groundwater standard
for TCE of 3 1. 1,1-DCA was detected in monitoring g well DMW-6 at a concentration of 42.3
µg/l, which is above the groundwater standard for of 6 µgll
Consistent with previous sampling events, target compounds were not detected in deeper
saprolite well DMW-8. Monitoring well DMW-8 is situated on the northern side of the unnamed
tributary of Third Creek. The absence of groundwater impacts in DMW-8 indicates that the
tributary is acting as an effective hydraulic barrier.
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Bedrock
In February 2015, target compounds were not detected above laboratory reporting limits in bedrock
wells DMW-3 and DMW-7 (Table 6 and Figure 7), or in the on -site water supply well WSW4
(Table 2). Additionally, target compounds were not detected above laboratory reporting limits in
bedrock well DMW-4 that was last sampled in November 2014. Bedrock well DMW-7 is located
adjacent to deep saprolite well DMW-6, which is the monitoring well with the highest target
compound concentrations. Although only approximately 25 ft separates the DMW-6 and DMW-7
well screens, the concentrations decrease with depth to non -detectable levels in DMW-7.
Concentration Trends
TCE is the most widespread target VOC detected above standards. Post -injection February 2015
data indicate that TCE levels have decreased from 68.5 µg/1 to 41.8 µg/1 in DMW-6, 3.3 µg/1 to 3
µg/l .in DMW-9, and 10.8 µg/1 to 7 µg/1 in DMW-11 since the injection in 2012. These trends
indicate that the EOS® injection has resulted in enhanced bioremediation within portions of the
groundwater plume area. Concentration trends will continue to be evaluated n t d dun future
g p g
sampling events. Concentrations of key VOCs in saprolite and bedrock groundwater are depicted
on Figures 6 and 7. A graph showing the showing the TCE concentration trend in monitoring
well DMW-6 is provided in Appendix B.
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4.0 Evaluation of Natural Attenuation Parameters
Natural attenuation of groundwater contaminants occurs by physical, chemical, and biological
processes. Biodegradation by reductive dechlorination is a primary degradation pathway for the
type of constituents present at the site. Additional data on reductive dechlorination including
indicator parameter data and daughter product concentrations are discussed below.
The target potential DOT compounds at the site are amenable to natural attenuation. 1,1,1-TCA
and TCE predominantly biodegrade under anaerobic conditions by a process known as reductive
dechlorination. 1,1,1-TCA also degrades abiotically to 1,1-DCE. Historically, there was some
evidence of natural degradation of these compounds based on the presence of potential daughter
products: 1,1-DCE, l,l-DCA, and cis-1,2-DCE. However, natural site conditions were not
highly favorable for reductive dechlorination.
The EOSO injection was designed to enhance conditions for biodegradation of the constituents of
concern, and general favorable results in concentrations trends are being observed since the
injection of EOS® in December 2012. Recent and historical biodegradation data are presented in
Table 7. A discussion of the recent indicator parameter data from February 2015 is provided
below.
4.1 Competing Electron Acceptors
Various electron acceptors can potentially compete with reductive dechlorination, including DO,
nitrate, sulfate, iron (III), and carbon dioxide (methanogenesis). Each sequential reaction reduces
the ORP of the groundwater into the range within which anaerobic reductive dechlorination can
occur most efficiently. These parameters or their byproducts (e.g., Fe(11) and methane) were
measured to assess the prevailing redox conditions at the site. A brief discussion of each
parameter is provided below.
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Dissolved Oxygen
DO is used by microbes as an electron acceptor for the biodegradation of organic carbon.
Reductive dechlorination occurs under anaerobic or low DO conditions. DO concentrations
close to or less than 1 mg/l are favorable.
Dissolved oxygen measurements ranged from 0.97 mg/l (DMW-1) to 3.51 mg/1 (DMW-8) in
February 2015. Monitoring wells with dissolved oxygen levels close to or less than 1.0 mg/1
included monitoring wells DMW-1, DMW-2, and DMW-6. The measured dissolved oxygen
concentrations in most impacted monitoring wells indicate conditions conducive for reductive
dechlorination to occur.
Nitrate/Nitrite
Nitrate may be used as an electron acceptor for anaerobic biodegradation via denitrification. In
this process, nitrate is reduced and nitrite is produced. In general, nitrate concentrations in the
plume less than background are considered indicative of anaerobic biodegradation. At
concentrations greater than 1 mg/l, nitrate may compete with the reductive dechlorination
process.
Nitrate was detected at concentrations which ranged from <0.020 mg/l (DMW-6, DMW-10 and
DMW-11) to 2.70 mg/1 (DMW-2) in February 2015. These data suggest that nitrate reduction
may be occurring in the plume, indicating the presence of anaerobic conditions favorable for
reductive dechlorination. Most nitrate levels were less than 1 mg/l, and the potential for
significant competition with reductive dechlorination is low.
Sulfate/Sulfide
Sulfate also may be used as an electron acceptor for anaerobic biodegradation. This process is
known as sulfate reduction and results in the depletion of sulfate and production of sulfide in the
aquifer. Sulfate concentrations within the plume below background concentrations and sulfide
concentrations within the plume above background concentrations are indicative of anaerobic
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degradation by sulfate reduction. In addition, sulfate at concentrations greater than 20 mg/1 may
compete with reductive dechlorination processes.
Sulfate was detected at concentrations that ranged from 4.3 mg/l (DMW-1) to 118 mg/l (DMW-
7) in February 2015. Sulfate concentrations in the plume wells were generally greater than the
concentration (<20 mg/1) considered most favorable for reductive dechlorination. In general,
sulfate concentrations in the plume wells appear to indicate the potential for competition with
reductive dechlorination.
Sulfide was detected at concentrations which ranged from <0.10 mg/1 (DMW-1, DMW-2,
DMW-3, DMW-6, DMW-9, and DMW-7) to 0.25 mg/1 (DMW-2) in February 2015. The low
levels of sulfide concentrations in the plume wells appear to indicate that sulfate reduction is not
significant anaerobic process at the site.
Iron
Iron reduction is an anaerobic process in which Fe" is reduced to Fe". The reduced form of iron
is soluble. The presence of ferrous iron in groundwater greater than 1.0 mg/l is typically
considered an indication of iron -reducing conditions. In February 2015, ferrous iron was
generally not detected (<0.2 mg/1), other than 2 mg/l in DMW-10 and 8.5 mg/l in 'MW-11.
Therefore, iron reduction appears to be occurring in some portions of the groundwater plume.
Methane
The presence of methane above background conditions indicates microbial degradation
(methanogenesis) is occurring and strongly reducing conditions have been established. The
fastest rates of anaerobic dechlorination typically occur under methanogenic conditions.
Methane was detected at concentrations which ranged from <6.6 µg/l (DMW-2, DMW-7, and
DMW-8) to 4,560 µg/l (DMW-11) in February 2015. These results indicate that strongly
reducing conditions are present in portions of the plume.
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4.2 Geochemical Indicator Parameters
Parameters that are indicators of conditions favorable for anaerobic biodegradation of chlorinated
solvents include ORP, pH, and temperature. Ethene/ethane (end products) can also serve as
indicators of complete reductive dechlorination. At the request of DENR, site wells also were
sampled for eight RCRA (metals arsenic, barium, cadmium, chromium, lead, selenium, silver,
and mercury). A summary of these data and recent previous natural attenuation indicator and
target COC data are provided in Table 7. These parameters (February 2015 data) were evaluated
to assess biodegradation processes at the site, and the results are discussed below.
Redox Conditions QRP)
The ORP of groundwater is a measure of electron activity and is an indicator of "the relative
tendency of a solution to accept or transfer electrons. ORP of a groundwater system affects
biodegradation rates. Reductive dechlorination is most efficient in the ORP range corresponding
to sulfate reduction and methanogenesis (<-100 mV), but reductive dechlorination also occurs in
the ORP range associated with nitrate, manganese, and iron reduction (-50 mV to 740 mV).
ORP ranged from -32 mV (DMW-11) to 225 mV (DMW-1) in February 2015. ORP data are
generally lower in impacted wells and are within the range in which reductive dechlorination
may occur.
PH and Temperature
Groundwater pH values ranging from six to eight standard units are generally preferable for
anaerobic biodegradation. The pH of groundwater affects the presence and activity of microbial
populations. Acid generated during reductive dechlorination can decrease pH levels after a
bioenhancement injection. Groundwater pH ranged from 5.79 to 11.72 in February 2015. The
site pH values are within or close to the range, which is considered favorable for reductive
dechlorination.
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Temperature does notgreatly influence reductive dechlorination, but temperatures greater than
n
20°C may accelerate biochemical processes. In February 2015, temperatures ranged from 12YC
to 18.4°C. The average groundwater temperature for the site is approximately 14.4°C. These
temperatures are in the range, which is considered satisfactory for biodegradation.
Ethene and Ethane
The dissolved gases ethene and ethane are non -toxic end products of reductive dechlorination of
chlorinated solvents. Apart from ethane in DMW-6, DMW-10, and DMW-11, dissolved ethene
and ethane were not detected in the site wells in the pre -injection or post -injection monitoring
events. Ethane was detected in DMW-11 during pre -injection sampling in February 2012 and
post -injection sampling in February and April 2013. Additionally, ethane was detected in DMW-
6 during the post -injection sampling in October 2013, January 2014, and February 2015, and in
DMW-10 in February 2015. These results indicate that reductive dechlorination may be
occurring in the vicinity of DMW-6, DMW-10, and DMW-11. Because ethene and ethane are
highly volatile, it is not usual that these compounds were not detected in the remaining plume
groundwater samples even if they may have been present in groundwater at low levels.
RCRA Metals
In February 2015, the RCRA metals barium, cadmium, chromium, and lead were detected in
select site wells above pre -injection metals concentrations detected in December 2012. At the
request of H&H, the metal concentrations were subsequently confirmed by the analytical
laboratory. The RCRA metal concentration increases may be associated with elevated turbidities
noted in the monitoring wells. Additionally, because RCRA metal concentration increases were
also noted in monitoring wells located greater than 100 ft upgradient of the injection area, the
increases do not appear to be related to the 2012 bioenhancement injection. RCRA metals will
continue to be evaluated during future sampling events.
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4.3 Electron Donor
TOC
TOC is utilized as an electron donor in the reductive dechlorination process and, therefore, is
needed to drive the process. Organic carbon can be either naturally occurring or introduced
artificially. The goal of the EOS injection was to provide a carbon source to drive the reductive
dechlorination process.
The presence of TOC at concentrations greater than 20 mg/L is considered ideal
for biodegradation of chlorinated solvents. In February 2015, TOC levels ranged from 3.2 mg/l
(DMW-9) to 20.9 mg/1(DMW-11). The TOC levels near the injection area appear to have been
enhanced by the injection. H&H will continue to will monitor for the presence of TOC in other
portions of the plume during future monitoring events.
Metabolic Acids
In groundwater, fermentation of EOS produces metabolic acids including lactic, pyruvic, acetic,
propionic, and butyric acids. The production of these acids releases hydrogen into groundwater,
which is then utilized by indigenous microbes in reductive dechlorination. In January 2014,
groundwater samples were analyzed for metabolic acids to evaluate the presence of EOS
breakdown products. The metabolic acid results are summarized in Tables 8. Metabolic acids
were generally not detected in plume wells in January 2014. In accordance with the UIC
monitoring plan, the first year of post -injection sampling has been completed; therefore,
metabolic acids are no longer monitored.
4.4 Presence of Degradation Daughter Products
Degradation or daughter products have been detected in site groundwater. The presence of the
1,1,1-TCA daughter product 1,1-DCA and TCE daughter product cis-1,2-dicholoroethene (cis-
1,2-DCE) provide direct evidence that biodegradation by reductive dechlorination of the parent
VOCs has occurred. In general, daughter product concentrations continue to be present in higher
14 hart hickman
SAAAA-Master Projects`NC DOT-DOT\DOT-500s ContracV.DOT-504 Staten Ue 66\May 2015 Report4Semi-AmwI GNVbi Report.doc
SMARTER ENVIRONMENTAL SOWNONS

concentrations relative to parent products. The continued presence of these daughter products
indicates that reductive dechlorination is occurring.
In addition to reductive dechlorination, 1,1,1-TCA also undergoes significant degradation by
abiotic processes in which it is transformed to 1,1-DCE or acetate in the presence of water. The
presence of significant 1,1-DCE concentrations compared to TCA in well DMW-6 indicates that
abiotic degradation of TCA is also occurring in the plume area.
15 hart hickman
SAAAA-'Master Projects�NC DOT-DOTIDOT-500s ContracttDOT-504 Statesville 66\May 2015 RepoitSemi-Annual GNVM Report.doc
SMARTER EWRONMENTAt. SOUMONS

5.0 Summary and Conclusions
H&H has implemented an enhanced bioremediation remedy and completed the pre -injection
baseline and quarterly post -injection performance monitoring events at the former Asphalt
Testing Laboratory Site No. 2-66 in Statesville, NC. The purpose of the remedial action was to
address chlorinated solvents in groundwater. The pre -injection baseline monitoring event was
completed in February/December 2012 and post -injection performance monitoring events are
being conducted. The following summarizes the results of the sampling events and performance
of the bioenhancement injection activities:
0 Groundwater impacts, including TCE, l,l,l-TCA, and their daughter products, are
present near and downgradient of the former asphalt testing laboratory. Groundwater
impacts exceed groundwater standards in two deeper saprolite monitoring wells. No
impacts above standards were detected in bedrock monitoring wells.
• No ground water impacts were detected in monitoring well DMW-8 located on the opposite
side of the unnamed tributary of Third Creek from the former asphalt -testing laboratory.
The absence of ground water impacts in DMW-8 indicates that the tributary is acting as an
effective hydraulic barrier.
0 Target compounds were not detected in the active, upgradient on -site water supply well or
in the unnamed tributary of Third Creek in February 2015 or June 2015, respectively.
• A bioenhancement agent (EOS®) was injected into 36 injection wells in December 2012.
Post -injection data collected most recently in February 2015 indicate that TCE
concentrations are decreasing in plume wells DMW-6, DMW-9, and DMW-11. These
trends indicate that the EOS' injection has resulted in enhanced bioremediation within
portions of the groundwater plume area. Concentration trends will continue to be
evaluated during future sampling events.
16 hart ► hickman
S:1AAA-Duster ProjectA C DOT-DOTIDOT-500s Contract'DOT-503 StatenUe 66Way 2015 ReportLSenri-Annual GNDf Report.doc
SMARTER ENVIRONMENTAL SOLUTIONS

In accordance with the UIC permit, H&H has completed two years of post -injection quarterly
performance monitoring. The EOS® injection has been effective at reducing groundwater parent
COC concentrations and continued reduction in parent COCs is expected in the future. As a
result, H&H is reducing the ground water monitoring schedule from quarterly to semi-annually.
The next ground water monitoring event will be conducted in August 2015 with a monitoring
report submitted to DOT in Fall 2015. During the sampling event, groundwater samples will be
collected from deeper saprolite monitoring wells DMW-1, DMW-2, DMW-6, DMW-8, DMW-9,
DMW-10, and DMW-11; and bedrock monitoring wells DMW-3, DMW-4, and DMW-7.
Groundwater samples will be submitted to a North Carolina certified laboratory for analysis of
VOCs by EPA Method 6200B, reporting only the EPA Method 601 halogenated VOC list and
RCRA metals. Due to the extensive amount of natural attenuation data collected during the post -
injection quarterly performance monitoring, natural attenuation parameter sampling will be
reduced to select measurements including TOC, DO, pH, ORP, and temperature.
H&H also will collect a groundwater sample from the active on -site water supply well WSW-4
and the creek located on the northern portion of the site during the August 2015 sampling event.
The water supply well will be purged for approximately 15 minutes prior to sample collection.
The samples will also be analyzed for EPA Method 601 halogenated VOCs by EPA
Method 6200B.
17,
SAAAA-Mfaster Projects\NC DOT-DOMOT-500s Contract\DOT-504 Statesville WAlay 2015 Report%enu-Avoail GWbi Report.doc
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

Table 1
Water Supply Well Inventory
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Map ID
Well Owner & Address
Well Status
Distance and Direction from Former Asphalt
Testing Laboratory
WSW-1
Maymead, Inc., 164 Bostian Bridge Drive, Statesville
Abandoned
On -site, near former asphalt laboratory
WSW-2
Maymead, Inc., 164 Bostian Bridge Drive, Statesville
Abandoned
On -site, near former asphalt laboratory
WSW-3
Dorothy Davis, 124 Bostian Bridge Drive, Statesville
Active
--1,200 ft, cross -gradient
WSW-4
Maymead, Inc., 164 Bostian Bridge Drive, Statesville
Active
On -site, —500 ft, upgradient
WSW-4A
Maymead, Inc., 164 Bostian Bridge Drive, Statesville
Inactive
On -site, —500 ft, upgradient
WSW-5
Lance & Melissa Lingle, 913 Buffalo Shoals Road, Statesville
Active
—650 ft, cross -gradient
WSW-6
Fred Davis, Buffalo Shoals Road, Statesville
Active
—800 ft, upgradient
WSW-7
Fred Davis Estate, Buffalo Shoals Road, Statesville
Active
—1,000 ft, upgradient
WSW-8
Dorothy Davis, 868 Buffalo Shoals Road, Statesville
Active
—1,100 ft, upgradient
WSW-9
Dorothy Davis, 868 Buffalo Shoals Road, Statesville
Active
—1,100 ft, upgradient
WSW-10
Jerry Hinson, 917 Buffalo Shoals Road, Statesville
Active
—900 ft, upgradient
WSW-11
Jack & Betty Wooten, 897 Buffalo Shoals Road, Statesville
Active
—1,000 ft, upgradient
WSWA2
Margaret Cloer, 881 Buffalo Shoals Road, Statesville
Active
—1,200 ft, upgradient
WSW-13
Jack & Betty Wooten, 871 Buffalo Shoals Road, Statesville
Active
—1,200 ft, upgradient
WSW-14
Jack & Betty Wooten, 865 Buffalo Shoals Road, Statesville
Active
—1,400 ft upgradient
WSW-15
Jerry Hinson, 911 Buffalo Shoals Road, Statesville
Active
—900 ft, upgradient
WSW-16
Wooten Family of NC, 847 Buffalo Shoals Road, Statesville
Active
—1,200 ft, upgradient
WSW-17
Garland Cloer, 889 Buffalo Shoals Road, Statesville
Active
—1,200 ft, upgradient
Notes:
Owner and address information based on Iredell County GIS Database and recent H&H windshield survey.
WSW-15 and WSW-16 were located during the updated receptor survey in August 2006.
WSW-17 was located during the updated receptor survey in August 2010.
Water supply well locations are provided on Figure 3.
Table 1 (Page 1 of 1)
File: S*.~-MasterProjectsWCDOT -DOTDOT-500sContractlDOT-504Statesville 66Way2015RepoMTables\TablesM-WSWinventory Hart &Hickman PC
Date: 9*12015

Table 2
Water Supply Well Analytical Data Summary (pg/L)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
WSW-1 (-213')
WSW-2
WSW-3 (100')
WSW-4 (-165')
WSW-4
(-100'
Abandoned Site Well
Abandoned
Site Well
Davis Residential Well
Site Well (potable)
Inactive Site Well
6230D
6230D
601
601(Dup)
601
6230D
601
6230D
601
601
1 601
601
601
601 1
601
601
601
601
601
601
601
601
601
601
601
6200E
6200B
6200B
6200E
62006
6200E
601
COMPOUNDS
NC GIN
Oct-96
Sep-97
Oct-98
Oct-98
Oct-98
Sep-97
Oct-98
Jan-99
Aug-01
Feb-02
Aug-02
Feb-03
Aug-03
Feb-04
Aug-04
Feb-05
Aug-05
Feb-06
Aug-06
Feb-07
Aug-07
Feb-08
Aug-08
Aug-09
Aug-10
Aug -II
Apr-13
Oct-13
May-14
Nov-14
Feb-15
Feb-M
Standard
1,1,1-Trichloroethane
200
2
<0.5
<1
<i
<1
<0.5
<1
<0.5
<1
<1
<t
<1
<1
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
Trichloroethene
3
0.7
<0.5
<1
<1
<1
<0.5
<1
<0.5
<1
<1
< 1
<t
<1
<1
<1
<1
<t
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<7.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
1,1-Dichlorcethane
6
0.9
<0.5
<1
<1
<7
<0.5
<1
<0.5
<1
<t
<7
<1
<1
<t
<t
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
1,1-Dichloroethene
7
0.8
<0.5
<1
<1
<1
<0.5
<1
<0.5
<1
<1
<1
<1
<7
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
Methyl-tert butyl ether
20
1
0.7
NA
NA
NA
<0.5
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
m/p-xylenes
500
0.5
<0.5
NA
NA
NA
<0.5
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1,2,4-Tdmethylbenzene
400
1
<0.5
NA
NA
NA
<0.5
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
n-Propylbenzene
70
0.9
<0.5
NA
NA
NA
<0.5
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Naphthalene
6
0.7
<0.5
NA
NA
NA
<0.5
NA
40.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1,4-Dioxane
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1,2-Dichloroethane
0.4
0.9
<0.5
<1<1<1<1
<0.5
<t
<1
<1
<t
<1
<1
<t
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
'1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
Diisopropyl ether
70
0.8
<0.5
NA
NA
NA
dNANA
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ethylbenzene
600
0.5
<0.5
NA
NA
NA
NA
<0.5
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
I NA
Notes:
Analytical method numbers are shown below sample IDs.
NA - Not Analyzed for this parameter.
Bold indicates concentration exceeds standard.
Dup - Duplicate sample
GW - Ground Water
Well depth is shown in parenthesis
1,4-Dioxane was analyzed by Method SW846-8260B/SIM
Table 2 (Page 1 of 1)
File: S:\AAA-Master Projects\NC DOT-DOTIDOT-500s ContractlDOT-504 Statesville 66\May 2015 Report\Tables\Tables\T2-WSW data Hart & Hickman, PC
Date: 9/3/2015

Table 3
Water Level Data Summary
Former ATL Site No. 2-66
Statesville, North Carolina
H& Job No. DOT-504
t,. oc only I 77#r N-TA )niA 1anr-07'7rn1e I KA-A 951d I Miv3n 9014 I Nnvpmhpr5.2014 1 February 3. 2015
Well I.D.
Depth (ft)
Screen (ft)
Screened
Aquifer
Zone
Latitude
Longitude
ElevationVb
TOC (ft)
(100 ft DatumOC)
ble
Water Table
Elevation (ft)
(100 ft Datum)
Static
Water Table
(ft below TOC
Water Table
Elevation (ft)
100 ft Datum
Static
Water Table
ft below TOC)
Water Table
Elevation (ft)
100 ft Datum)
Static
Water Table
ft below TOC
Water Table
Elevation (ft)
100 ft Datum
Static
Water Table
(ft below TOC
Water Table
Elevation (ft)
100 ft Datum
Static
Water Table
ft below TOC)
Water Table
Elevation (ft)
100 ft Datum)
Static
Water Table
ft below TOC
Water Table
Elevation (ft)
100 ft Datum
SMW-1
30
20-30
Shallow Saprolite
N35.765483
W80.920233
90.73
64.44
26.70
64.03
27.02
63.71
25.95
64.78
26.87
63.86
27.16
63.57
26.75
63.98
SMW-2
35
25-35
Shallow Saprolite
N35.765483
W80.920233
93.92
65.22
29.09
64.83
29.30
64.62
28.30
65.62
29.22
64.70
29.58
64.34
29.22
64.70
SMW-3
40
30-40
Shallow Saprolite
N35.765704
W80.919861
98.79
32.05
66.74
32.39
66.40
29.74
69.05
31.29
67.50
32A4
66.35
32.97
65.82
32.68
66.11
SMW-4
35
25 - 35
Shallow Saprolite
NA
NA
100.52
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
SMW-5A
30
20 - 30
Shallow Saprolite
NA
NA
95.14
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
DMW-1
50
45 - 50
Deep Saprolite
N35.765396
W80.919907
98.11
32.13
65.98
32.64
65.47
29.91
68.20
31.62
66.49
32.77
65.34
33.23
64.88
32.85
65.26
DMW-2
40
35-40
Deep Saprolite
N35.765705
W80.919922
92.72
27.98
64.74
28.39
64.33
28.79
63.93
27.68
65.04
28.55
64.17
28.83
63.89
29.51
63.21
DMW-3
60
55 - 60
Shallow Bedrock
NA
NA
101.15
28.70
72.45
26.90
74.25
24.16
76.99
24.73
76.42
NM
NA
NM
NA
28.19
72.96
DMW-4
70
65 - 70
Shallow Bedrock
N35.765276
W80.919932
98.08
32.13
65.95
32.60
65.48
29.85
68.23
31.66
66.42
32.64
.65.44
33.08
65.00
32.89
65.19
DMW-5
38.5
28.6 - 38.5
Deep Saprolite
NA
NA
78.57
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
NM
NA
DMW-6
36.25
26.25 - 36.25
Deep Saprolite
N35.765961
W80.920820
79.60
18.48
61.12
18.75
60.85
18.42
61.18
18.54
61.06
18.88
60.72
18.84
60.76
18.68
60.92
DMW-7
65
60 - 65
Shallow Bedrock
N35-765950
W80.920806
81.85
17.66
61.34
17.92
61.08
17.57
61.43
NM
NA
NM
NA
NM
NA
22.04
59.81
DMW-8
24
14 - 24
Deep Saprolite
N35.766168
W80.921506
68.34
7.76
60.58
8.00
60.34
7.70
60.64
7.77
60.57
8.20
.60.14
8.15
60.19
7.86
60.48
DMW-9
40
3040
Deep Saprolite
N35.765726
W80.920251
88.72
25.53
63.19
25.84
62.88
25.38
63-34
25.42
63.30
NM
INA
NM
NA
27-33
61.39
DMW-10
38
28-38
Deep Saprolite
N35.765725
W80.920812
86.24
25.32
60.92
25.68
60.56
25.36
60.88
25.61
60.63
25.86
60.38
25.81
60.43
25.61
60.63
DMW-11
40
30-40
Deep Saprolite
N35.766114
W80.920408
85.13
23.30
61.83
23A9
61.64
23.21
61.92
23.99
61.84
23.47
81.66
26.65
58.48
23-44
61.69
noies:
TOC = Top of PVC well casing.
All wells referenced to an assumed datum of 100 feet.
NA - Not Available/Not Applicable
NM - Not Measured
SMW-5A was abandoned March 21, 2002
DMW-3, DMW4 and DMW-7 are Type III double -cased wells.
DMW-1, DMW-3 and DMW4 were repaired on 7/24/06 and re -surveyed for TOC elevations on 8/17/06
DMW-5 discovered damaged in August 2008 and could not be sampled.
SMW4 could not be located since December 2012.
DMW-7 was repaired on 9/16/14 and re -surveyed for TOC elevation on 11/6/14
Table 3 (Page 1 of 1)
Fle: S?AAA-Mier PrcjmMWC DOT-DOTDOT-500s Ca WMOT-504Sta-ft WlMy2015RpW:Tab1%Ueb1es\T3-Weta Tale Hart & Hickman, PC
Data 93MIS

Table 4
Surface Water Analytical Data Summary
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Compound
SS-1
Upgradient
Tributary
SS-2
Downgradient
Tributary
SS-3
Upgradient
Third Creek
SSA
Mid -Point
ThirdCreek
SS-5
Downgradient
Third Creek
Feb-99
Feb-99
Au -01
Au -02
Au -03
Au -04
Au -05
Au -06
Au -07
Au -08
Feb-09
Au -09
Au -10
Au -11
A r-13
Oct-13
Ma -14
Jun-15
Feb-99
Feb-99
Feb-99
14-Dioxane
NA
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
111-Tdchloroethane
<0.5
<0.5
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.5
<0.5
<0.5
Trichloroethene
<0.5
<0.5
<1
<1
<t
<1
<1
<11.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.5
<0.5
1 <0.5
1 1-Dichloroethane
<0.5
<0.5
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<0.5
<0.5
<0.5
cis-1 2-Dichloroethene
<0.5
<0.5
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
41.0
<1.0
<1.0
<1.0
<1.0-
<1.0
<1.0
<0.5
<0.5
<0.5
1 1-Dichloroethene
<0.5
<0.5
<1
<1
<1
<1
<1
<1.0
<1.0
<1.0
<1.0
I <1.0
<1.0
<1.0
<t.o
<1.0
I <1.0
<1.0
-0.5
<0.5
<0.5
Chloroform
<0.5
<0.5
1 <1
<1
<1
<1
<1
I <1.0
<1.0
<1.0
1 11.0
1 <1.0
<1.0
<1.0
<1.0
<1.0
I <1.0
<1.0
<0.5
<0.5
<0.5
N Ies:
Results are in pgll
"<" indicates compound was not detected above the analytical detection limit
NA - Not Analyzed for this parameter.
Table 4 (Page 1 of 1)
File: S:1AAA-Master Projects\NC DOT-DOTDOT500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T4-Surface Water Summary Hart &Hickman PC
Date: 9/3/2015

Table 5 (Page 1 of 6)
Saprolite Monitoring Well Analytical Data Summary (lag/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trichloroethane
Trichloroethene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
Chlorobenzene
WELL
SCREEN
INTERVAL
Well ID
Analysts
Sample Date
601
Dec-96
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Oct-98
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -01
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-03
<1
<1
<1
<1
<l
<1
NA
<5
<1
601
Au -D3
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-04
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -04
<1
<1
<1
<1
<1
<1
<5.0
<5
<1
NS
Feb-06
NS
NS
NS
NS
NS
NS
NS
NS
NS
601
Au -06
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
SMW-1
601
Feb-07
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA i
<2.0
<1.0
SS (15'-25')
601
Au -07
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
601
Feb-08
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -08
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Feb-09
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -09
-1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -10
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<5.0
<1.0
6200E
Au -11
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
A r-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Oct-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Ma -14
<1.0
<1.0
<1.0
<1.0
-1.0
<1.0
NA
<2.0
<1.0
6200E
Nov-14
<1.0
<1.0
<1.0
<1.0
<1.0
-1.0
NA
<2.0
<1.0
601
Dec-96
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Oct-98
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -01
<1
<1
4.3
<1
1.9
<1
NA
<5
<1
601
Feb-02
<1
<1
3.7
<1
<1
<t
NA
<5
<1
601
Au -02
<1
<1
4.8
<1
1.8
<1
NA
<5
<1
601
Feb-03
<1
<1
8.1
<1
2.7
<1
NA
<5
<1
601
Au 03
<1
<1
11
<1
<1
<1
NA
<5
<1
601
Feb-04
<1
<1
8.9
<1
1A
<1
NA
<5
<1
601
Aug-0
<1
<1
8.2
<1
0.961
<1
<5.0
<5
<1
601
Feb-05
<1.0
<1.0
5.9
<1.0
<1.0
<1
NA
<1.0
<1.0
601
Au -05
<1
<1
8.8
<1
<1
<1
NA
<2
<1
601
Feb-06
<1
<1
6.7
<1
<t
<1
NA
<2
<1
SMW-2
601
Au -06
<1.0
<1.0
5.6
<1.0
<1.0
<1.0
NA
<2.0
<1.0
SS (20'-3D')
601
Feb-07
<1.0
<1.0
4.7
<1.0
<1.0
<1.0
NA
<2.0
1 <1.0
601
Au -07-
<1.0
<1.0
3.5
<1.0
<1.0
<1.0
NA
<2.0
<1.0
601
Feb-08
<1.0
<1.0
3.8
<1.0
-1.0
<1.0
NA
<1.0
<1.0
601
Au -08
<1.0
<1.0
3.1
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Feb-09
<1.0
<1.0
3.5
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -09
<1.0
<1.0
1.9
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -10
<1.0
<1.0
5.8
<1.0
<1.0
<1.0
NA
<5.0
<1.0
601
Au -10
<1.0
<1.0
5.8
<1.0
<1.0
<1.0
NA
<5.0
<1.0
6200E
Au -11
<1.0
-1.0
2.1
<1A
<1.0
-1.0
NA
<2.0
<1.0
6200E
Apr-1 3
<1.0
<1.0
2.2
<1.0
<1.0
<1.0
NA
<2.0
<1.0
62008
Oct-13
<1.0
<1.0
2.0
<1.0
<1.0
<1.0
NA
-2.0
<1.0
8200B
Ma -14
<1.0
<1.0
3.1
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Nov-14
<1.0
<1.0
2.2
<1.0
<1.0
<1.0
NA
<2.0
<1.0
NC GW Standard
200
3
6
0.4
350
70
3
5
50
rvares:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs. 1,4-Dioxane was analyzed by Select ton Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater; NA = Not Analyzed for this parameter; NS = Well not sampled
J= The analyte was positively identified but the value is estimated below the reporting limit
SMW-5A was abandoned March 21, 2002
SMW4 is damaged and could not be sampled, August 2004; SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78J µgA, August 2004
Vinyl chloride (1.7 ug/1) and 1,1,2-trichloroethane (1.8 ug/1) were detected in DMW-6 in February 2005
Chloroform (3 ugA), and ,1,1,2-trichloroethane (3.5 ug/1) were detected in DMW-6 in February 2006
1,1,2,2-Trichloroethane (2.2 ug/1) was detected in DMW-6 in February 2008
Chloroform (3.5 ugA), and ,1,1,2-tichloroethane (2.5 ug/I) were detected in DMW-6 in August 2009
1,1,2-trichloroethane (1.2 ugA) was detected in DMW-6 in August 2011
Table 5 (Page 1 of 6)
File: S:\AW-Master Projects\NC DOT-DOT\DOT-500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T5-New sap data
Date: 9/3/2015 Hatt & Hickman, PC

Table 5 (Page 2 of 6)
Saprolite Monitoring Well Analytical Data Summary (Ng/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trichloroethane
Trichloroethene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
Chlorobenzene
WELL
SCREEN
INTERVAL
Well ID
Analysis
Sample Date
601
Dec96
4
1
1
<1
2
6
NA
<5
<1
601
Oct-98
3
<1
10
<1
<1
7
NA
<5
<1
601
Au -01
4.4
<1
6.2
<1
<1
<1
NA
<5
<1
801
Feb-02
2.3
1.5
8.3
<1
<1
<1
NA
<5
<1
801
Au -02
1.8
2.1
11
<1
1.5
2.8
NA
<5
<1
801
Feb-03
4.0
1.6
11
<1
<1
1.3
NA
<5
<1
801
Au -03
1.1
<1
12
<1
<1
<1
NA
<5
<1
601
Feb-04
<1
<1
7.1
<1
<1
2.9
NA
<5
<1
601
Au -04
<1
<1
4.7
<1
<1
1.7
<5.0
<5
<1
601
Feb-05
<1.0
<1.0
3.1
<1.0
<1.0
1.9
NA
<1.0
<1.0
601
Au -05
<1
<1
5.7
<1
<1
2.8
NA
<2
<1
601
Feb-06
<1
<1
7.7
<1
<1
3.0
NA
<2
<1
SMW3
601
Au -06
<1.0
<1.0
6.9
<1.0
<1.0
2.8
NA
<2.0
<1,0
SS (30'-40')
601
Feb-07
41.0
<1.0
7.7
<1.0
-1.0
2.7
NA
<2.0
<1.0
601
Au -07
<1.0
<1.0
6.7
<1.0
<1.0
3A
NA
<2.0
<1.0
601
Feb-08
<1.0
<1.0
8.7
<1.0
<1.0
2.3
NA
<1.0
<1.0
601
Au -08
<1.0
1.5
7.9
<1.0
<1.0
1.9
NA
<1.0
<1.0
Fet>09
<1.0
<1.0
8.8
<1.0
-1.0
3.7
NA
<1.0
<1.0
Au -09
<1.0
<1.0
4.5
<1.0
<1.0
2.8
NA
<1.0
<1.0
L2O
Au -10
<1.0
<1.0
4.7
<1.0
<1.0
2.1
NA
<5.0
<1.0
Au -11
<1.0
<1.0
3.7
<1.0
<1.0
1A
NA
<2.0
<1.0
Apr-1 3
<1.0
<1.0
4.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Oct-13
<1.0
0.0
4.3
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Ma -14
<1.0
<1.0
2.1
<1.0
<1.0
<1.0
NA
<2.0
<1.0
62008
Nov-14
<1.0
<1.0
2.3
<1.0
<1.0
<1.0
NA
<2.0
<1.0
SMW 4
601
Deo-96
<1
<1
<1
<t
<1
<1
NA
<5
<1
SS (25'35')
601
Oct-98
<1
<1
<1
<1
<1
<1
NA
<5
<1
SMW-5A
601
Dec-96
1
<1
<1
<1
6
<1
NA
<5
<1
SS (20'30')
NC GW Standard
200
3
1 6
1 0.4
350
70
1 3
5
50 11
Notes:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs. 1,4-Dioxane was analyzed by Select Ion Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater; NA = Not Analyzed for this parameter; NS = Well not sampled
J= The analyte was positively identified but the value is estimated below the reporting limit
SMW-5A was abandoned March 21, 2002
SMW4 is damaged and could not be sampled, August 2004; SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78.1 µg/I, August 2004
Vinyl chloride (1.7 ugn) and 1,1,2-trichloroethane (1.8 ug/1) were detected in DMW-6 in February 2005
Chloroform (3 ug/1), and ,1,1,2-trichloroethane (3.5 ug/1) were detected in DMW-6 in February 2006
1,1,2,2-Trichloroethane (2.2 ug/1) was detected in DMW-6 in February 2008
Chloroform (3.5 ugA), and ,1,1,2-trichloroethane (2.5 ug/1) were detected in DMW-6 in August 2009
1,1,2-trichloroethane (1.2 ug/1) was detected in DMW-6 in August 2011
Table 5 (Page 2 of 6)
File: S:\AW-Master Projects\NC DOT-DOT\DOT-500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T5-New sap data
Date: 9/3/2015 Hart & Hickman, PC

Table 5 (Page 3 of 6)
Saprolite Monitoring Well Analytical Data Summary (Ng/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-604
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trichloroethane
Trichloroethene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
I
Chlorobenzene
WELL
SCREEN
INTERVAL
Well ID
Analysis
Sample Datc
601
Dec-96
53
47
26
<1
37
53
NA
<5
1
8260B
Jan-97
59
54
28
<5
51
59
NA
<5
<5
601
Oct-98
30
41
28
<1
40
59
NA
<5
<1
801
Au -01
110
110
61
<1
51
56
NA
<5
<1
601
Feb-02
88
84
31
<1
64
58
NA
<5
<1
601
Au -02
42
51
23
<1
36
30
NA
<5
<1
601
Feb-03
17
28
16
<1
17
21
NA
<5
<1
601
Au -03
27
49
30
<1
27
39
NA
<5
<1
601
Feb-04
4.2
8.9
9.1
<1
8.8
10
NA
<5
<1
601
Au -04
2.8
5.8
5.3
<1
4.5
7.4
<5.0
<5
<1
601
Feb-05
2.7
7.4
6.1
<1.0
6.3
9.7
NA
<2.0
<1.0
NS
Au -OS
I NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
Feb-06
NS
NS
NS
NS
NS
NS
NS
NS
NS
601
Au -06
1.5
5.8
4.9
<1.0
2.4
4.9
NA
<2.0
<1.0
601
Feb-07
1.8
5.3
4.9
<1.0
3.0
7.2
NA
<2.0
<1.0
601
Au -07
11.0
1.4
2.0
<1.0
1.2
2.7
NA
<2.0
<1.0
DS (45'-50')
DMW-1
601
Feb-08
<1.0
2.1
1.7
<1.0
1.2
2.7
NA
-1.0
<1.0
801
Aug- 8
<1.0
2.4
1.2
<1.0
2.0
1.8
NA
<1.0
<1.0
601
Feb-09
1.2
3.8
4.7
<1.0
3.2
4.4
NA
<1.0
<1.0
601
Au -09
<1.0
2.9
1.9
<1.0
1.8
2.5
NA
<1.0
<1.0
601
Au -10
4.0
3.5
4.7
<1.0
3.8
4.8
NA
<5.0
<1.0
62008
Aug-1 1
<1.0
2.4
3.7
<1.0
1.7
3.5
NA
<2.0
<1.0
62009
Feb-12
<1.0
1.3
1.8
<1.0
<1.0
1.6
NA
<2.0
<1.0
8200E
Feb-13
<1.0
1.0
1.3
<1.0
-1.0
1.1
NA
<2.0
<1.0
6200E
A r-13
<1.0
1.0
1.8
<1.0
<1.0
1.1
NA
<2.0
<1.0
62008
JunA3
<1.0
1.0
2.8
<1.0
<1.0
2.0
NA
<2.0
<1.0
62006
Oct-13
<1.0
1.9
3.7
<1.0
1.3
2.8
NA
<2.0
<1.0
6200B
Jan-14
<1.0
3.0
4.5
<1.0
<1.0
3.3
NA
<2.0
<1.0
62008
Ma -14
<1.0
1.6
2.9
<1.0
<1.0
2.0
NA
<2.0
<1.0
8200B
Jul-14
<1.0
2.1
4.2
<1.0
1.3
3.5
NA
<2.0
<1.0
6200E
Nov-14
<1.0
1.0
2.4
<1.0
<1.0
1.9
NA
<2.0
<1.0
6200B
Feb-15
<1.0
1.2
2.5
<1.0
<1.0
2.0
NA
<2.0
<1.0
NC GW Standard
1 200
1 3
6
0.4
350
70
3
5
1 50
Notes:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs. 1,4-Dioxane was analyzed by Select Ion Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater; NA = Not Analyzed for this parameter; NS = Well not sampled
J= The ahalyte was positively identified but the value is estimated below the reporting limit
SMW-5Awas abandoned March 21, 2002
SMW-4 is damaged and could not be sampled, August 2004; SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78J µgA, August 2004
Vinyl chloride (1.7 ugA) and 1,1,2-trichloroethane (1.8 ugA) were detected in DMW-6 in February 2005
Chloroform (3 ugA), and ,1,1,2-trichloroethane (3.5 ugA) were detected in DMW-6 in February 2006
1,1,2,2-Trichloroethane (2.2 ug/1) was detected in DMW-6 in February 2008
Chloroform (3.5 ug/1), and ,1,1,2-trichloroethane (2.5 ug/1) were detected in DMW-6 in August 2009
1,1,24richloroethane (1.2 ugA) was detected in DMW-6 in August 2011
Table 5 (Page 3 of 6)
File: S:kW-Master Projects\NC DOT-DOT\DOT-500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T5-New sap data
Date: 9/3/2015 Hart & Hickman, PC

Table 5 (Page 4 of 6)
Saprolite Monitoring Well Analytical Data Summary (Ng/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trtchloroethane
Triehloroethene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene .
cls-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
Chlorobenzene
WELL
SCREEN
INTERVAL
Well ID
Analysis
Sample Dat
601
Mar-97
210
120
72
<2.5
130
<2.5
NA
<12.5
<2.5
601
Oct-98
29
18
48
<1
39
<1
NA
<5
<1
601
Au -01
9.9
11
43
<1
17
1.7
NA
<5
<1
601
Feb-02
23
18
49
<1
32
<1
NA
<5
<1
601
Au -02
21
22
55
<1
32
5.1
NA
<5
<1
601
Feb-03
12
17
23
<1
13
2.8
NA
<5
<1
601
Au -03
21
37
94
<1
23
<1
NA
<5
<1
601
Feb-04
13
28
73
<1
18
6.6
NA
<5
<1
601
Au -04
27
48
86
<1
38
15
<5.0
<5
<1
601
Feb-05
18
38
40
<1.0
32
12
NA
<2.0
<1.0
601
Au -OS
20
38
67
<1
19
12
NA
<2
<1
601
Feb-06
15
42
59
<1
19
9.1
NA
<2
<1
601
Au -06
13
29
58
<1.0
14
12
NA
<2.0
<1.0
601
Feb-07
8.2
19
40
<1.0
11
8.3
NA
<2.0
<1.0
601
Au -07
4.3
10
37.8
<1.0
6.2
4.2
NA
<2.0
<1.0
DMW-2
601
Feb-08
2.1
6.6
22
<1.0
3.0
2.8
NA
<1.0
<1.0
DS (35'-40')
601
Au -08
1.4
5.0
17
<1.0
3.2
2.1
NA
<1.0
<1.0
601
Feb-09
2.1
5.8
16
<1.0
4.5
3.0
NA
<1.0
<1.0
601
Au -09
1.6
5.8
9.2
<1.0
3.2
1.9
NA
<1.0
<1.0
601
Au -10
4.8
4.3
8.9
<1.0
3.5
1.9
NA
<5.0
<1.0
6200B
I Aug-1 1
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Feb-12
<1.0
<1.0
2.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Feb-13
<1.0
<1.0
1.6
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Apr-13
<1.0
<1.0
2.1
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Jun-13
<1.0
<1.0
1.8
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Oct-13
<1.0
<1.0
1.8
<1.0
-1.0
<1.0
NA
<2.0
<1.0
6200E
Jan-14
I <1.0
<1.0
1.3
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Ma -14
<1.0
<1.0
1.3
<1.0
<1.0
<1.0
NA
-2.0
<1.0
6200B
Jul-14
<1.0
-1.0
1.1
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Nov-14
<1.0
<1.0
1.2
<1.0
-1.0
<1.0
NA
<2.0
-1.0
62006
Feb-15
<1.0
<1.0
1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6230D
Jan-99
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
NA
<5
<0.5
601
Au-01
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-03
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -03
<1
<1
<1
<1
<1
<1
NA
<5
<1
DS (28.5'-
DMW-5
601
Feb-04
<1
<1
<1
<1
<1
<1
NA
<5
<1
38.5')
601
Au -04
<1
<1
<1
<1
<1
<1
<5.0
<5
<1
601
Feb-05
<1.0
<1.0
<1.0
<1.0
<1.0
<1
NA
<2.0
<1.0
601
Au -05
<1
<1
<1
<1
<1
<1
NA
<2
<1
601
Feb-06
<1
<1
<1
<1
<1
<1
NA
<2
<1
601
Au -06
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
NECW Standard
200
3
6
1 0.4
350
70
3
5
50
Notes:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs.1,4-Dioxane was analyzed by Select Ion Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater, NA = Not Analyzed for this parameter, NS = Well not sampled
J= The analyte was positively identified but the value is estimated below the reporting limit
SMW-5A was abandoned March 21, 2002
SMW-4 is damaged and could not be sampled, August 2004; SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78J µgA, August 2004
Vinyl chloride (1.7 ugA) and 1,1,2-trichloroethane (1.8 ugA) were detected in DMW-6 in February 2005
Chloroform (3 ugA), and ,1,1,2-trichloroethane (3.5 ug/l) were detected in DMW-6 in February 2006
1,1,2,2-Trichloroethane (2.2 ugA) was detected in DMW-6 in February 2008
Chloroform (3.5 ugA), and ,1,1,2-trichloroethane (2.5 ugA) were detected in DMW-6 in August 2009
1,1,2-trichloroethane (1.2 ug/I) was detected in DMW-6 in August 2011
Table 5 (Page 4 of 6)
File: S:\AAA-Master Projects\NC DOT-DOT\DOT-500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T5-New sap data
Date: 9/3/2015 Hart & Hickman, PC

Table 5 (Page 5 of 6)
Saprolite Monitoring Well Analytical Data Summary (Ng/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trichloroethane
Trichloroethene
14-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
Chlorobenzene
WELL
SCREEN
INTERVAL
Well iD
I Analysis
SampleDate
6230D
Jan-99
74
67
42
<0.5
160
1.5
NA
<5
<0.5
601
Au -01
95
57
60
<1
93
4.5
NA
<5
<1
601
Feb-02
140
170
89
<1
500
<10
NA
<5
<10
801
Au -02
140
190
120
<1
590
18
NA
<5
<10
801
Feb-03
100
160
77
<1
430
<10
NA
<5
<10
Au -03
97
170
80
4.3
420
14
NA
8.5
<1
Feb-04
63
140
74
<1
350
10
NA
<5
<1
K
Au -04
61
150
74<10
380
8.1J
180
<50
<10
Feb-05
49
150
69
7.8
250
10
NA
5.6
<1.0
Au -05
65
170
83
<5
290
12
NA
<10 1
<5
601
Feb-06
44
220
98
1.8
390
9.2
180
5.8
<1
601
Au -06
19
190
83
<5
270
9.0
NA
-10
<5.0
601
Feb-07
39
170
81
<5
330
12.0
180
<10
<5.0
601
Au -07
40.3
157
100
<10.0
290
<10.0
NA
<20.0
<10.0
601
Feb•08
33
130
77
<1.0
200
6.9
170
<1.0
<1.0
DS (26.25'-
DMW-6
601
Au -08
24
100
77
3.6
180
6.1
NA
<1.0
<1.0
36.25')
601
Feb-09
18
96
67
<1.0
220
6.7
NA
<1.0
<1.0
601
Au -09
23
120
83
4.9
220
6.6
NA
<1.0
<1.0
601
Aug-10
16
100
79
<1.0
200
8.6
NA
<5.0
<1.0
6200E
I Au -11
10.6
100
75.9
1.3
147
3.9
NA
<2.0
<1.0
6200E
I Feb-12
5.9
68.5
53.1
<1.0
90.5
3.0
NA
<2.0
<1.0
62008
Feb-13
5.2
71.8
61.6
<1.0
92.1
3.7
NA
<2.0
<1.0
6200B
A r-13
5.5
71.4
65.0
1.1
99.2
3.8
NA
<2.0
<1.0
6200E
Jun-13
5.1
67.1
67.8
<1.0
92.7
3.0
NA
<2.0
<1.0
6200B
Oct-13
5.0
69.9
71.1
1.1
97.7
4.3
NA
<2.0
<1.0
6200B
Jan-14
3.6
62.5
50.9
1.2
73.2
3.5
NA
<2.0
<1.0
6200B
Ma -14
3.1
64.9
57.2
<1.0
67.7
1.9
NA
<2.0
<1.0
6200E
Jul-14
1.9
43.2
40.6
<1.0
52.0
2.5
NA
<2.0
<1.0
6200B
Nov-14
2.0
46.7
47.5
<1.0
59.7
3.3
NA
<2.0
<1.0
6200B
Feb-15
1.5
41.8
42.3
<1.0
55.0
2.7
NA
<2.0
<1.0
601
Au -01
<7
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -02
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-03
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -03
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Feb-04
<1
<1
<1
<1
<1
<1
NA
<5
<1
601
Au -04
<1
<1
<1
<1
<1
<1
<5.0
<5
<1
601
Feb-05
<1
<1
<1
<1
<1
<1
NA
<1.0
<1
801
Au -05
<1
<1
<1
<1
<1
<1
NA
<2
<1
601
Feb-06
<1
<1
<1
<1
<1
<1
NA
<2
<1
601
Au -06
<1.0
<1.0
<1.0
<1.0
<1.0
-1.0
NA
<2.0
<2.0
601
Feb-07
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<2.0
601
Au -07
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
601
Feb-08
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
DMW-8
801
Au -08
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
DS (14'-24')
601
Feb-09
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -09
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
601
Au -10
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<5.0
<1.0
8200B
Au -11
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Feb-12
<1.0
<1.0
<1.0
<11.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Feb-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
62008
A r-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
62008
Jun-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
-2.0
<1.0
8200E
Oct-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Jan-14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Ma -14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Jul-14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
-2.0
<1.0
62008
I Nov-14
<1.0
I <1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
620013
1 Feb-15
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
NC GW Standard
200
3
6
0.4
350
70
3
5
50
Notes:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs. 1,4-Dioxane was analyzed by Select Ion Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater, NA = Not Analyzed for this parameter, NS = Well not sampled
J= The analyte was positively identified but the value is estimated below the reporting limit
SMW-5A was abandoned March 21, 2002
SMW-4 is damaged and could not be sampled, August 2004: SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78J jig/I, August 2004
Vinyl chloride (1.7 ug/1) and 1,1,2-trichloroethane (1.8 ugh) were detected in DMW-6 in February 2005
Chloroform (3 ug/I), and ,1,1,2-trichloroethane (3.5 ug/1) were detected in DMW-6 in February 2006
1,1,2;2-Trichloroethane (2.2 ugA) was detected in DMW4b in February200B
Chloroform (3.5 ug/l), and ,1,1,2-trichloroethane (2.5 ug/l) were detected in DMW-6 in August 2009
1,1,24richloroethane (1.2 ug/1) was detected in DMW-6 in August 2010
Vinyl chloride (1.5 ug/I) was detected in DMW-6 in November 2014
Table 5 (Page 5 of 6)
File: S:\AAA-Master Projects\NC DOT-DOT\DOT-500s Contract\DOT-504 Statesville 66\May 2015 ReporhTables\Tables\T5-New sap data
Date: 9/3/2015 Hart & Hickman, PC

Table 5 (Page 6 of 6)
Saprolite Monitoring Well Analytical Data Summary (jig/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
DOT Target Compounds
Non -Target
COMPOUND
1,1,1-Trichloroethane
Trichloroethene
1,1-Dichloroethane
1,2-Dfchloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
Methylene
Chloride
Chlorobenzene
WELL
SCREEN
Well ID
at sis
Sample DateINTERVAL
6200E
Feb-12
<1.0
3.3
4.5
<1.0
2.1
<1.0
NA
<2.0
<1.0
6200B
Feb-13
11.0
5.8
8.5
<1.0
3.6
<1.0
NA
<2.0
<1.0
6200E
Apr-13
<1.0
6.4
7.7
<1.0
4A
1.1
NA
<2.0
<1.0
6200E
Jun-13
<1.0
5.5
6.7
<1.0
3.6
1.2
NA
<2.0
1 <1.0
DMW-9
6200B
Oct-13
<1.0
4.9
4.9
<1.0
3A
1.2
NA
<2.0
<1.0
DS (30'-40')
6200E
Jan-14
<1.0
2A
2.6
-1.0
1.9
<1.0
NA
<2.0
<1.0
6200B
Ma -14
<1.0
2.9
2.3
<1.0
1.9
<1.0
NA
<2.0
<1.0
6200B
Nov-14
<1.0
2.6
2.3
<1.0
1.6
<1.0
NA
<2.0
<1.0
62008
Feb-15
1
<.0
3.0
2.2
<1.0
1.3
<1.0
NA
<2.0
<1.0
6200E
Feb-12
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Feb-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
A r-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Jun-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Oct-13
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
DS
DMW-10
6200E
Jan-14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
(30'40')
6200B
Ma -14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200E
Jul-14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Nov-14
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Feb-15
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<2.0
<1.0
6200B
Feb-12
<1.0
10.8
10.9
<1.0
15.0
<1.0
NA
<2.0
<1.0
6200B
Feb-13
<1.0
8.0
7.0
<1.0
10.5
<1.0
NA
<2.0
<1.0
6200B
Apr-1 3
<1.0
9.0
7.6
<1.0
11.9
<1.0
NA
<2.0
<1.0
6200B
Jun-13
<1.0
5.7
4.9
<1.0
7.4
1.4
NA
<2.0
<1.0
6200B
Oct-13
<1.0
6.3
6.6
<1.0
9.0
<1.0
NA
<2.0
<1.0
DS
DMW-11
6200B
Jan-14
<1.0
8.1
6.8
<1.0
9.5
<1.0
NA
<2.0
<1.0
(30'-40')
6200B
May-14
<1.0
6.3
5.4
<1.0
7.5
<1.0
NA
<2.0
<1.0
6200E
Jul-14 I
<1.0
7.9
8.6
<1.0
11.0
<1.0
NA
<2.0
<1.0
62008
Nov-14
-1.0
9.8
10
<1.0
13.2
<1.0
NA
<2.0
<1.0
6200B
Feb-15
<1.0
7.0
%7
<1.0
9.5
<1.0
NA
<2.0
<1.0
NC GW Standard
200
3
6
0.4
350
70
3
5
50
Notes:
Bold indicates concentration exceeds standard
Analytical method numbers are shown beside sample IDs. 1,4-Dioxane was analyzed by Select Ion Monitoring
SS - Shallow Saprolite; DS - Deep Saprolite; GW - Groundwater; NA = Not Analyzed for this parameter; NS = Well not sampled
J= The analyte was positively identified but the value is estimated below the reporting limit
SMW-5A was abandoned March 21, 2002
SMW-4 is damaged and could not be sampled, August 2004; SMW-4 repaired July 2006
DMW-2 reported Chloroform at an estimated value = 0.78J µg/1, August 2004
Vinyl chloride (1.7 ug/1) and 1,1,2-trichloroethane (1.8 ugA) were detected in DMW-6 in February 2005
Chloroform (3 ug/I), and ,1,1,2-trichloroethane (3.5 ug/I) were detected in DMW-6 in February 2006
1,1,2,2-Trichloroethane (2.2 ug/1) was detected in DMW-6 in February 2008
Chloroform (3.5 ugA), and ,1,1,2-trichloroethane (2.5 ug/1) were detected in DMW-6 in August 2009
1,1,2-trichloroethane (1.2 ug/1) was detected in DMW-6 in August 2011
Table 5 (Page 6 of 6)
File: S:~-Master Projects\NC DOT-DOT0OT-500s Contract\DOT-504 Statesville 66\May 2015 Report\Tables\Tables\T5-New sap data
Date: 9/3/2015 Hart & Hickman, PC

Table 6
Shallow Bedrock Monitoring Well Analytical Data Summary (mg/1)
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
COMPOUND
1,1,1-
Trichloroethane
Trichloroethene
1,1-
Dlchloroethane
1,1-
Dichlomethene
cis-1,2-
Dichla1,2- a
1,4-Dioxane
Chlorobenzene
WELL
SCREEN
INTERVAL
Well ID
Analysis
Sample Dale
601
Mar-97
<1
<1
<7
<1
<1
NA
<1
601
Oct-98
<1
<1
<1
<1
<1
NA
<1
601
Feb-03
<7
<t
<1
<1
<1
NA
<1
601
Au 3
<1
<i
<1
<1
41
NA
<1
601
Feb-04
<1
<1
41
<1
<1
NA
<1
60118260
Au
<1
<1
<1
<1
<1 1
-5.0
<1
601
Feb-05
<1
<1
<1
<1
<1
NA
<1
601
Au 5
<1
<1
<1
<1
<1
NA
<1
601
Feb-06
<1
41
<1
<1
<1
NA
<1
601
Au 6
<1.0
-1.0
<1.0
-1.0
<1.0
NA
<1.0
DMW-3
601
Feb-07
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
(55'-601
601
Au
<1.0
<1.0
<7.0
<1.0
<7.0
NA
<1.0
601
Feb-08
-1.0
<1.0
<1.0
<7.0
<1.0
NA
-1.0
601
Au -08
<1.0
<1.0
<1.0
-1.0 1<1.0
NA
<1.0
601
Feb-09
<1.0
<1.0
-1.0
<1.0
<1.0
NA
<1.0
601
Au 10
<1.0
-1.0
<1.0
<1.0
<1.0
NA
<1.o
6200B
Aug-1 1
<1.O
<1.0
-1.0
<1.0
<1.0
NA
-1.0
62008
r-13
<1.0
<7.0
<1.0
<1.0
<1.0
NA
<1.0
6200B
Oct-13
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
6200E
Ma -14
<1.0
<7.0
<1.0
<1.0
<1.0
NA
<1-0
6200B
Feb-15
<7.o
<1.0
<1.0
<1.0
<1.0
NA
<1.0
601
Mar-97
<1
<1
<1
<1
<1
NA
<t
601
Oct-98
<1
<1
<t
<1
<1
NA
<1
601 1
Au 1
<1
<7
<1
<1
<1
NA
<1
601
Feb-02
<1
<1
41
<1
<1
NA
<1
601
Au -02
<1
<1
<1
<1
<1
NA
<i
601
Feb-03
<1
<1
<1
<1
<i
NA
<1
601
3
<1
<1
<1
<1
<1
NA
<1
601
Feb-04
<1
<1
<1
<1
<1
NA
<1
601/8260
Au
<1
<1
<1
<1
<1
<5.0
<1
601
Feb-05
<1
<1 1
1
<1
<1
NA
<1
601
Au 05
<1
<1
<1
<1
<1
NA
<1
601
1 Feb-06
<1
<1
<1
<1
<1
NA
`1
(65'-70')
DMW-0
601
Au
-1.0
<100
<1.0
<1.0
<1.0
NA
<1.0
601
Feb-07
<1.0
<1.0
<1.0
<100
<1.0
NA
<1.0
601
Au 07
<1.0
-1.0
<1.0
<1.0
<1.0
NA
-1.0
601
Feb-08
-1.0
<1.0
<1.0
<1.0
I <1.0
NA
<1.0
601
Au -08
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
601
Au -09
<t.o
<7.0
<1.O
<1.0
<1.0
NA
<1.0
601
Au -10
<1.0
<1.0
<1.0
<7.0
<1.0
NA
<1.0
62003
Au 11
<1.0
<1.0
<1.0
<7.0
<1.0
NA
<1.0
62006
r-13
<1.0
<1.0
<7.0
<1.0
<1.0
NA
<1.0
6200E
Oct-13
<1.0
<1.0
<7.0
<1.0
<1.0
NA
<1.0
6200B
Ma -14
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<11.0
6200E
Nov-14
<1.0
<7.0
<1.0
<1.0
<1.0
NA
<7.0
601
Au 1
<1
<1
<1
<1
I <1
NA
<1
601
Feb-02
<1
<1
<1
1.9
<1
NA
<1
601
Au 2
2.4
6.3
1.6
14
<1
NA
<7
601
Feb-03
2.1
2.4
<t
2.8
<1
NA
<1
601
Au 3
3.8
7.0
1.5
12
<1
NA
<1
601
Feb-04
<1
1.5
<1
2.6
<1
NA
<1
601/8260
Au -04
O.B1J
2.2
0.70J
3.6
<i
45.0
<7
601
Feb-05
<1
2.1
<7.0
3.9
41
NA
<1
601
Au o5
<1
1.6
<1
1.9
<1
NA
<1
601
Feb-06
<1
3.7
1.5
3
<1
NA
<7
601
Au -06
<1.0
4.6
1.3
3.3
<1.0
NA
<1.0
601
Feb-07
<1.0
2.2
1.8
2.5
<1.0
NA
<1.0
601
1 Au -07
<1.0
2.7
1.2
3.5
<1.0
NA
<11.0
601
Feb-08
-1.0
2.2
<1.0
1.6
<1.0
NA
<1.0
DMW-7
601
Au 8
<1.0
3.1
<1.0
2.6
<11.0
NA
<1.0
(60'-651
601
Feb-09
-1.0
2.3
IA
2.6
<1.0
NA
<1.0
601
Au
<1.0
2.1
<1.0
1.3
1 <1.0
NA
<1.0
601
Au -10
<1.0
3.2
1.1
2.8
<1.0
NA
<7.0
6200B
Au 11
<1.0
-1.0
<1.0
<1.0
<1.0
NA
e1.0
6200E
Feb-12
<7.0
<1.0
<1.0
<1.0
<1.o
NA
<1.0
6200E
Feb-13'
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
62008
I A r-13
<1.0
<1.0
<1.0
<1.0
<1.0
NA
-1.0
6200E
Jun-13
<1.0
<1.0
-1.0
<1.0
<7.0
NA
<1.0
6200E
Oct-13
<1.0
<1.0
<7.0
<1.0
<1.0
I NA
<1.0
8200E
Jan-14
<1.O
<1.0
<1.0
<1.0
<1.0
I NA
I <1.0
6200B
Ma -14
<1.0
<7.0
<1.0
<1.0
<1.0
NA
<1.0
8200B
Jul-14
<7.0
<1.0
<1.0
-1.0
-1.0
NA
-1.0
6200E
Nov-15
<7.0
<1.0
e1.0
<1.0
<1.0
NA
<7.0
6200B
Feb15
<1.0
<1.0
<1.0
<1.o
<1.0
NA
<7.0
NC GW STANDARD
200
1 3
6
350
70
13
50
Analytical method numbers are shown beside sample IDs.
Bold indicates concentration exceeds standard
GW -Ground Water
J= The analyte was positively identified but the value is estimated below the reporting limit
NA = Not Analyzed for this parameter
- 1,4-Dioxane was analyzed by Method SW 846-8260B(SIM
= Methylene chloride detected at a concentration of 2.7 (pg0) in February 2013
Table 6 (Page 1 of 1)
rr: swwmmr+genwc oormrmr�osraa..rmraw snes�esxyans wwmrmmrmmre«..eaan
Harr & Hickman, PC

Table 7 (Page 1 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring Weil ED
SMW-1
SMW-2
Sampling Date
Au -10
Au -11
A r-13
Oct-13
Ma 44
Nov-14
Aug-10
Au -11
A r-13
Oct-13
Ma 44
Nov-14
Field Measurements
Dissolved Oxygen (mg/1)
1.83
3.13
3.50
1.35
1.61
1.23
0.34
0.98
3.20
1.17
1.04
1.88
Ferrous Iron (mg/1)
NA
NA
<0.2
<0.2
<0.2
<0.2
NA
NA
<0.2
<0.2
1.0
2.0
Redox (mV)
277
278
144.2
320
368.1
313
384
521
280
406
370
398
Conductivity (µS/cm)
130.0
160.0
123.0
157.8
298.0
386.4
288.0
220.0
263.0
270.1
344.9
401.7
pH (standard units)
5.27
5.21
5.13
5.39
5.76
5.86
5.31
5.03
5.22
5.29
5.55
5.86
Temperature (°C)
18.0
18.1
19.3
17.5
18.0
18.4
18.6
19.0
19.6
17.3
18.0
17.7
Labortaory Analytical Parameters
NA
NA
NA
NA
NA
2.9
NA
NA
NA
NA
NA
<0.020
Nitrate (mg/1)
Sulfate (mg/1)
NA
NA
NA
NA
NA
20.8
NA
NA
NA
NA
NA
54.8
Sulfide (mg/l)
NA
NA
NA
NA
NA
<0.10
NA
NA
NA
NA
NA
<0.10
TOC (mg/1)
NA
NA
NA
NA
NA
30.9
NA
NA
NA
NA
NA
31.2
Methane (µg/1)
NA
NA
NA
NA
NA
<6.6
NA
NA
NA
NA
NA
136
Ethane (µg/l)
NA
NA
NA
NA
NA
<6.2
NA
NA
NA
NA
NA
<6.2
Ethene (µg/1)
NA
NA
NA
NA
NA
<6.2
NA
NA
NA
NA
NA
<6.2
Metals 601017470 /ue/D
Arsenic
NA
NA
NA
NA
NA
<10.0
NA
NA
NA
NA
NA
<10.0
Barium
NA
NA
NA
NA
NA
122
NA
NA
NA
NA
NA
34.7
Cadmium
NA
NA
NA
NA
NA
<1.0
NA
NA
NA
NA
NA
<1.0
Chromium
NA
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
<5.0
Lead
NA
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
<5.0
Selenium
NA
NA
NA
NA
NA
<10.0
NA
NA
NA
NA
NA
<10.0
Silver
NA
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
<5.0
Mercury
NA
NA
NA
NA
NA
<0.20
NA
NA
NA
NA
NA
<0.20
Metabolic.4cids ftzlb
Acetic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Butyric Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Lactic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Propionic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Pyruvie Acid
NA
NA
NA I
NA I
NA I
NA I
NA I
NA
NA I
NA I
NA
NA
Notes:
TOC = Total Organic Carbon; DO = Dissolved Oxygen; NA = Not Analyzed
t = Sulfide and metals samples collected on July 17, 2013.
File: S.WN Mmtm Pt jmtsWC DOT-0OTXDOTSWs CwnMDOTS04 Ste+esve 66M W2D15 Repro eblm Td*e U7-Nat Atlen. riev Table 7 (Page 1 of 6)
Dates 9=15
Half &Hickman, PC

Table 7 (Page 2 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring WellID
SMW-3
DMW-1
Sampling Date
Aug-10
Aug-11
Apr-13
Oct-13
May44
Nov-14
Feb-12
Dec-12
Feb-13
Apr-13
Jun-13t
Oct-13
Jan-14
May44
Jul-14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (mg/1)
0.31
0.97
2.22
1.70
1.22
1.68
0.68
NA
2.40
2.48
0.86
1.20
1.11
1.37
1.61
2.11
0.97
Ferrous Iron (mg/1)
NA
NA
<0.2
<0.2
<0.2
<0.2
<0.2
NA
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
Redox(mV)
121
84
107
106
124
176.1
310
NA
296
116
414
320
206
300
319
290
225
Conductivity (µS/cm)
128.0
110.0
123.0
127.1
196.7
298.1
96.4
NA
106.3
73.0
71.4
157.8
70.0
125.5
302.7
361.1
79.4
pH (standard units)
5.34
5.70
5.51
5.58
5.98
5.62
5.64
NA
5.63
5.50
5.56
5.39
5.57
5.25
4.99
5.57
6.03
Temperature (°C)
18.6
19.0
18.2
16.4
16.4
16.3
18.3
NA
18.3
18.2
19.8
17.5
15.7
16.0
15.7
15.2
15.4
Labortaory Analytical Parameters
0.28
NA
NA
NA
NA
0.079
<0.20
NA
0.076
0.079
0.07
0.11
0.23
0.32
0.24
0.041
0.059
Nitrate (mg/1)
Sulfate (mg/1)
48
NA
NA
NA
NA
6.4
<5.0
NA
5.2
4.2
4.6
4.2
4.5
3.9
3.6
4.2
4.3
Sulfide (mg/1)
NA
NA
NA
NA
NA
<0.10
NA
<0.10
<0.10
NA
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
TOC (mg/1)
2.5
NA
NA
NA
NA
28.8
4.9
NA
26.7
4.9
5.7
4.5
5.5
4.4
6.1
17.4
4.2
Methane (µg/1)
NA
NA
NA
NA
NA
18.7
15.7
NA
12.8
7.3
8.2
9.3
15.4
14.2
10.2
10.4
13.8
Ethane (µg/1)
NA
NA
NA
NA
NA
<6.2
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Ethene (µg/1)
NA
NA
NA
NA
NA
<6.2
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Metals 601017470 6w11)
Arsenic
NA
NA
NA
NA
NA
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
Barium
NA
NA
NA
NA
NA
107
NA
56.7
58.1
NA
57.5
56.8
60.2
59.8
61.8
54.3
502
Cadmium
NA
NA
NA
NA
NA
<1.0
NA
<1.0
<1.0
NA
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
1.2
Chromium
NA
NA
NA
NA
NA
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
86.4
Lead
NA
NA
NA
NA
NA
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
27.9
Selenium
NA
NA
NA
NA
NA
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<I0.0
<10.0
<10.0
<10.0
Silver
NA
NA
NA
NA
NA
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
Mercury
NA
NA
NA
NA
NA
<0.20
NA
<0.20
<0.20
NA
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Metabolic Acids (me/b
Acetic Acid
NA
NA
NA
NA
NA
NA
<5.0
NA
<1.8
1.91
<0.67
<0.67
<0.67
NA
NA
NA
NA
Butyric Acid
NA
NA
NA
NA
NA
NA
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
Lactic Acid
NA
NA
NA
NA
NA
NA
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
Propionic Acid
NA
NA
NA
NA
NA
NA
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
Pyruvic Acid
NA
NA I
NA I
NA I
NA I
NA 1
<10 1
NA i
<2.0 1
<2.0
<0.53 i
<0.53
<0.53 1
NA I
NA I
NA I
NA
Notes:
TOC = Total Organic Carbon; DO = Dissolved Oxygen; NA =Not Analyzed
t = Sulfide and metals samples collected on hay 17, 2013.
Table 7 (Page 2 of 6)
Fft S:WAFAbWPrgwftWCDOT -DOTXD0T5aasCmtadCOT567Stdt UoWNW 2015RepaaTableskTables1T7444Aftm.re (2) Hart &Hickman, PC
Data. 9=15

Table 7 (Page 3 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring WellED
DMW-2
DMW-6
Sampling Date
Feb-12
Dec-12
Feb-13
A r-13
Jun-13n
Oct-13
Jan-14
Ma -14
Jul-14
Nov-14
Feb-15
Feb-12
Dec-12
Feb-13
A r-13
Jun-13n
Oct-13
Jan-14
May-14
Jul-14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (nng/1)
0.41
NA
2.83
3.08
0.83
1.17
1.16
1.66
0.82
0.67
1.41
1.24
NA
3.23
3.32
0.76
1.17
1.06
0.41
1.44
0.76
1.11
Ferrous Iron (ing/1)
<0.2
NA
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
NA
<0.2
<0.2
<0.2
<0.2
<02
<0.2
<0.2
<0.2
<0.2
Redox(utV)
207
NA
324
242
372
286
197
210
195
191
141
174
NA
91
131
410
136
49
87
106
69
68
Conductivity (ItS/can)
281.6
NA
243.6
263.0
253.9
282.3
234.0
445.6
490.9
578.1
259.8
418.9
NA
363.3
385.0
364.7
410.9
330.0
409.7
425.8
493.7
288.4
pH (standard units)
5.18
NA
5.06
4.84
5.02
5.06
4.94
5.30
5.31
5.00
6.20
6.11
NA
6.26
5.33
6.11
6.15
6.16
6.61
6.97
7.01
6.28
Temperature (°C)
18.6
NA
18.3
18.6
19.6
16.2
15.7
17.1
17.0
16.6
13.0
16.4
NA
16.3
16.7
16.3
15.6
16.0
16.4
17.0
16.4
12.3
Labortaory Analvdcal Parameters
4.50
NA
3.20
5.40
2.90
3.50
3.70
2.40
2.30
2.5
2.7
<0.20
NA
0.59
0.74
0.33
0.86
0.54
<0.020
<0.020
<0.020
<0.020
Nitrate (mg/1)
Sulfate (mg/1)
66.8
NA
79.1
60.6
79.5
72.7
79.1
83.3
81.8
69.3
77.2
81.3
NA
62.7
86.9
70.3
54.3
58.2
59.5
45.9
39.8
45.3
Sulfide (mgd)
NA
<0.10
<0.10
NA
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
NA
<0.10
<0.10
NA
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
TOC (mgn)
6.0
NA
5.4
11.4
42.6
5.8
7.0
5.3
5.8
23.6
3.6
10.3
NA
11.8
11.8
11.0
46.0
17.1
11.1
14.2
45.0
8.7
Methane (Itgn)
76.4
NA
105
124
110
62.8
61.9
30.3
<6.6
42.2
58.7
22.2
NA
192
18.9
<6.6
93.8
49.4
17.4
<6.6
766
674
Ethane (Itg/1)
<I0.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<10.0
NA
<6.2
<6.2
<6.2
7.0
7.0
<6.2
<6.2
7.0
<6.2
Ethene (µgd)
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<62
<6.2
<6.2
<6.2
<6.2
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
61.6
Motnis 601017470 (ye/7)
Arsenic
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
Barium
NA
32.3
27.6
NA
28.4
28.3
28.2
27.2
28.2
26.3
91.0
NA
117
216
NA
114
ill
195
109
108
126
172
Cadnniumn
NA
<1.0
<1.0
NA
<1.0
<1.0
1.0
<I.0
<I.0
<1.0
<1.0
NA
<1.0
<I.0
NA
<1.0
<1.0
<I.0
<1.0
<1.0
<I.0
<1.0
Chronnitmn
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
212
NA
<5.0
37.9
NA
<5.0
<5.0
35.7
<5.0
<5.0
<5.0
20.3
Lead
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
5.8
NA
<5.0
10.3
NA
<5.0
<5.0
10.6
<5.0
<5.0
<5.0
8.9
Selenium
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
Silver
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
Mercury
NA
<0.20
<0.20
NA
<020
0.22
<0.20
<0.20
<0.20
<0.20
<0.20
NA
<0.20
<0.20
NA
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<020
Metabolic Acids (ma
Acetic Acid
<5.0
NA
<1.8
<1.8
<0.67
<0.67
<0.67
NA
NA
NA
NA
<5.0
NA
<1.8
LK
<0.67
<0.67
<0.67
NA
NA
NA
NA
Butyric Acid
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
Lactic Acid
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
Propionic Acid
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
jPyruvic Acid I
<10 I
NA 1
<2.0 1
<2.0
<0.53 1
<0.53 1
<0.53 1
NA I
NA
NA I
NA I
<10 I
NA
<2.0
<2.0 1
<0.53 1
<0.53 1
<0.53 1
NA I
NA I
NA I
NA
Notes:
TOC = Total Organic Carbon; DO = Dissolved Oeygeu: NA = Not Analyzed
t = Sulfide and metals samples collected on Ady 17, 2013.
Table 7 (Page 3 of 6)
o a:WIAM.nta PropcbWC WT-0OTDOTi00�CanVacl�DOT-sal SlabrnYe 66\May]DIS �pw(�TebbalTffiIn\T)N0.Reen.new (3)
o- srnma Hart & Hickman, PC

Table 7 (Page 4 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring Well JD
DMW-8
DMW-9
Sampling Date
Feb-12
Dec-12
Feb-13
A r-13
Jun-131
Oct-13
Jan-14
Ma -14
Jul-14
Nov-14
Feb-15
Feb-12
Dec-12
Feb-13
A r-13
Jun-131
Oct-13
Jan-14
Ma -14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (mg/1)
4.44
NA
4.86
4.98
4.76
3.55
3.10
2.86
2.04
3.01
3.51
0.95
NA
1.01
1.09
1.11
2.45
2.32
2.07
1.71
2.36
Ferrous Hon (mg/1)
<0.2
NA
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
0.5
NA
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<02
Redox(mV)
258
NA
94
101
103
116
237
220
197
297
199
ill
NA
293
139
314
184
116
112
135
132
Conductivity (pS/cm)
159.8
NA
147.3
150.0
146.0
168.7
142.0
162.8
170.9
198.2
155.3
290.1
NA
245.4
268.0
249.8
283.0
240.0
270.6
313.0
260.2
pH (standard units)
6.51
NA
6.78
6.16
6.10
6.54
6.51
6.62
6.44
6.80
6.61
5.70
NA
5.62
5.40
5.88
5.47
5.53
5.69
5.88
5.79
Temperature (°C)
14.6
NA
16.1
15.0
17.6
16.2
12.6
14.5
15.0
13.9
13.5
182
NA
18.6
18.6
18.4
18.4
17.9
17.8
17.0
14.4
Labortaory Analytical Parameters
0.76
NA
0.77
0.56
0.73
0.72
0.88
0.80
0.79
0.87
0.81
2.1
NA
1.7
1.6
1.5
1.5
1.4
1.5
1.4
1.4
Nitrate (mg/1)
Sulfate (mg/1)
<5.0
NA
2.6
2.2
2.4
2.3
3.0
2.1
<2.0
2.2
27
61.5
NA
66.7
65.6
85.1
65.8
76.3
71.3
69.3
71.9
Sulfide (ing/1)
NA
<0.10
<0.10
NA
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
0.20
NA
<0.10
<0.10
NA
<0.10
<0.50
<0.50
<0.50
<0.10
<0.20
TOC (nig/1)
22.2
NA
2.2
22.1
3.0
2.5
2.1
3.4
24.4
10.8
20.6
7.1
NA
5.7
7.2
5.5
5.5
8.1
5.6
30.6
3.2
Methane (µg/l)
<10.0
NA
<6.6
<6.6
<6.6
8.3
<6.6
<6.6
<6.6
<6.6
<6.6
147
NA
151
153
24.6
40.6
175
116
707
1,010
Ethane (jig/1)
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<I0.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Ethene (jig/1)
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Meals 601017470 (ae/!)
Arsenic
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<I0.0
<10.0
<10.0
Barium
NA
60.4
33.8
NA
36.1
35.9
33.6
28.9
30.7
32.3
846
NA
100
91.0
NA
84.3
86.2
85.0
82.0
76.0
896
Cadmium
NA
<1.0
<1.0
NA
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<I.0
NA
<1.0
<1.0
NA
<1.0
<1.0
<I.0
<1.0
<1.0
1.1
Chromium
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
81.2
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
209
Lead
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
14.6
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
32.0
Selenium
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<10.0
NA
<I0.0
<10.0
<I0.0
<10.0
<10.0
10.0
Silver
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
Mercury
NA
<0.20
<0.20
NA
<0.20
<0.20
<020
<0.20
<0.20
<0.20
<0.20
NA
<0.20
<0.20
NA
<0.20
<0.20
<0.20
<0.20
<020
0.47
Metabolic Acids (mn/1)
Acetic Acid
<5.0
NA
<1.8
<1.8
<0.67
<0.67
<0.67
NA
NA
NA
NA
<5.0
NA
<1.8
<1.8
<0.67
<0.67
NA
NA
NA
NA
Butyric Acid
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
<5.0
NA
<0.87
<0.87
<0.10
<0.10
NA
NA
NA
NA
Lactic Acid
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
<25
NA
<2.3
<2.3
<2.0
<2,0
NA
NA
NA
NA
Propionic Acid
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
<5.0
NA
<1.0
<1.0
<0,25
<0.25
NA
NA
NA
NA
,Pynivic Acid
<10 I
NA 1
<2.0 1
<2.0 1
<0.53 1
<0.53 1
<0.53 1
NA I
NA I
NA I
NA I
<10 I
NA 1
<2.0 1
<2.0 1
<0.53 1
<0.53
NA I
NA
NA I
NA
Notes:
TOC = Total Organic Carbon: DO = Dissolved Oxygen; NA = Not Analyzed
'= Sulfide and metals samples collected on July 17, 2013.
J = estimated concemmtion greater than the method detetion limit. but below the reporting limit.
Table 7 (Page 4 of 6)
s:-vmwc ooToonoor3aa. c�o-arnmr-sa sw® n, seia=ymts aewmTm�nubm+�. nm,. �.Iq Har! Se Hickman, PC
wm smots

Table 7 (Page 5 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring WelliD
DMW-10
DMW-11
Sampling Date
Feb-12
Dec-12
Feb-13
A r-13
Jun-13r
Oct-13
Jan-14
Ma -14
Jul-14
Nov-14
Feb-15
Feb-12
Dec-12
Feb-13
A r-13
Jun-13r
Oct-13
Jan-14
Ma -14
Jul-14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (mg/l)
2.25
NA
0.88
0.92
0.52
0.82
0.80
1.11
2.01
1.93
2.04
1.03
NA
1.13
1.20
0.83
2.24
2.19
1.99
2.16
2.32
1.70
Ferrous Iron (mg/1)
<0.2
NA
5.0
5.0
4.5
5.0
5.0
6.0
5.4
2.5
2.0
0.5
NA
7.5
8.0
8.0
8.5
9.0
10.0
9.0
8.5
8.5
Redox (mV)
22
NA
-58
-27
4
-37
-34
-17
-17
-42
-17
18
NA
54
76
116
12
66.4
71.4
93
105
-32
Conductivity (1tS/cm)
463.2
NA
440.0
440.0
428.4
490.6
400.0
381.2
480.1
398.9
423.6
666.8
NA
500.3
556.0
490.4
576.1
492.0
448.9
502.3
427.9
428.3
pH (standard units)
6.51
NA
6.47
6.24
6.34
6.35
6.39
6.61
6.71
6.46
6.50
6.67
NA
6.32
5.70
6.23
6.30
6.15
6.20
6.29
6.13
6.69
Temperature (DC)
18.3
NA
18.9
18.6
18.4
17.6
17.3
17.9
17.0
16.3
13.3
17.3
NA
18.3
17.1
17.3
17.6
16.6
16.8
16.4
16.2
14.6
Labortaory Analvtical Parameters
<0.20
NA
<0.020
<0.020
<0.020
0.12
<0.020
<0.020
<0.020
<0.020
<0.020
<0.20
NA
<0.020
<0.020
<0.020
<0.020
<0.020
<0.020
<0.020
<0.020
<0.020
Nitrate (rng/1)
Sulfate (mg/1)
19.0
NA
27.4
22.4
24.9
35.3
20.8
20.2
17.6
18.3
19
114
NA
99.7
106
103
75
108
47.9
80.3
39.2
79.6
Sulfide (mg/1)
NA
<0.10
0.15
NA
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
0.25
NA
<0.10
<0.10
NA
<0.10
<0.50
<0.10
<0.10
<0.10
<0.10
0.14
TOC (mg/I)
21.4
NA
24.9
26.0
22.8
18.3
21.6
23.6
27.9
46.1
18.5
23.9
NA
24.2
26.9
25.0
18.4
23.4
23.8
21.9
45.0
20.9
Methane(lig/1)
945
NA
1,040
839
389
701
<6.6
555
1,160
1,200
654
1,640
NA
347
260
65.3
663
3,790
2,140
4,070
4,840
4,560
Ethane (jig/1)
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
14.5
NA
6.5
7.7
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Ethene (µgll)
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
33.6
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Metals 601017470 (ae/1)
Arsenic
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
Barium
NA
140
707
NA
1"
136
141
252
143
122
282
NA
88.3
89.7
NA
70.0
69.8
66.5
58.9
69.5
56.1
789.0
Cadmium
NA
<I.0
8.2
NA
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
NA
<1.0
<1.0
NA
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
Chromium
NA
<5.0
224
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
4.5.7
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
85.0
Lead
NA
<5.0
92.7
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
22.1
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
110
Selenium
NA
<10.0
10.8
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
NA
<10.0
<I0.0
NA
<10.0
<10.0
<10.0
<I0.0
<10.0
<10.0
<10.0
Silver
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
Mercury
NA
<0.20
<0.20
NA
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
NA
<0.20
<0.20
NA
<0.20
<0,20
<0.20
<0.20
<0.20
<0.20
<0.20
Meraboltc Acids /m e/D
Acetic Acid
<5.0
NA
<1.8
1.91
<0.67
<0.67
0.67J
NA
NA
NA
NA
<5.0
NA
<1.8
<1.8
<0.67
<0.67
<0.67
NA
NA
NA
NA
Butyric Acid
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
Lactic Acid
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
Propionic Acid
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
jPyruvic Acid
<10 I
NA 1
<2.0 1
<2.0 1
<0.53 1
<0.53 1
<0.53 1
NA I
NA I
NA I
NA I
<10 I
NA 1
<2.0 1
<2.0 1
<0.53 1
<0.53 1
<0.53 1
NA I
NA I
NA I
NA
Notes:
TOC = Total Organic Carbon; DO = Dissolved Oxygen; NA = Not Analyzed
= Sulfide and metals samples collected on July 17. 2013.
J = estimated concentration greater than the method detetion limit. but below the reporting lnnit.
Table 7 (Page 5 of 6)
D.e S+AA9aaD15 DIs PmptlaWGDDT-0011WTii00, CDnbxADai�501 akttaa➢e 6TMry]015 RepvM1TeDleeRabbalTiWx ADm. mst5) Hart &Hickrnan, PC
Dat

Table 7 (Page 6 of 6)
Summary of Natural Attenuation Indicator Data
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Monitoring We11ID
DMW-3
DMW-4
DMW-7
Sampling Date
Att -10
Att -11
Oct-13
Ma -14
Feb-15
Au -10
Au -11
I Oct-13
Ma -14
Nov-14
Feb-12
Dec-12
Feb-13
A r-13
Jim-131
Oct-13
Jan-14
Ma -14
Ju1-14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (mg/1)
0.51
0.99
3.58
3.14
3.62
0.24
0.56
1.01
0.99
2.88
1.16
NA
4.37
4.89
3.27
2.76
2.60
2.86
2.70
2.16
2.84
Ferrous Iron (mg/1)
NA
NA
<0.2
<0.2
<0.2
NA
NA
<0.2
<0.2
1.2
<0.2
NA
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
Redox (ml')
NA
NA
-104.3
-71.9
32.0
NA
NA
405.6
400
-46.9
286
NA
101
160
402
148
51
80
106
75
113
Conductivity (pS/cm)
649.0
394.0
300.1
428.9
1,455.0
216.0
203.0
270.1
250.0
288.1
228.6
NA
115.3
113.0
114.3
98.6
111.0
142.9
202.7
199.4
168.6
pH (standard units)
10.69
7.45
10.38
9.62
11.72
6.75
6.71
5.29
5.89
6.67
6.72
NA
6.96
6.28
6.62
6.16
6.96
7.58
7.46
7.58
6.23
Temperature (°C)
18.3
18.6
16.2
16.5
15.4
18.8
18.6
17.3
18.0
16.1
15.6
NA
15.9
17.4
18.0
15.4
15.7
18.4
18.7
18.0
18.4
LabortamT Analytical Parameters
NA
NA
NA
NA
0.29
NA
NA
NA
NA
NA
<0.20
NA
0.50
0.46
0.48
0.032
0.58
0.18
0.61
2.9
0.63
Nitrate (mg/1)
Sulfate (ing/1)
NA
NA
NA
NA
76.7
NA
NA
NA
NA
NA
<5.0
NA
4.7
7.4
4.8
10.9
3.8
4.4
5.2
24.9
118
Sulfide (mg/1)
NA
NA
NA
NA
<0.10
NA
NA
NA
NA
NA
NA
<0.10
<0.10
NA
<0.10
<0.10
<0.10
<0.10
<0.10
0.17
<0.10
TOC (mg/I)
NA
NA
NA
NA
17.8
NA
NA
NA
NA
NA
8.2
NA
1.6
2.8
2.1
6.7
2.4
17.2
2.7
13.6
3.4
Methane (µgd)
NA
NA
NA
NA
50.6
NA
NA
NA
NA
NA
<10.0
NA
<6.6
<6.6
<6.6
<6.6
<6.6
15.8
<6.6
<6.6
<6.6
Ethane (jig/1)
NA
NA
NA
NA
<6.2
NA
NA
NA
NA
NA
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
Ethane (jig/1)
NA
NA
NA
NA
<6.2
NA
NA
NA
NA
NA
<10.0
NA
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
<6.2
16.2
Metals 601017470 a A
Arsenic
NA
NA
NA
NA
<10.0
NA
NA
NA
NA
NA
NA
<10.0
<10.0
NA
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
<10.0
Baritmr
NA
NA
NA
NA
209
NA
NA
NA
NA
NA
NA
18.2
18.5
NA
41.1
28.2
21.2
52.4
37.4
84.2
42.7
Cadmimn
NA
NA
NA
NA
<I.0
NA
NA
NA
NA
NA
NA
<LO
<1.0
NA
<1.0
<1.0
<1.0
<I.0
<1.0
2.3
<1.0
Chromium
NA
NA
NA
NA
79.0
NA
NA
NA
NA
NA
NA
<5.0
<5.0
NA
5.4
<5.0
<5.0
6.9
<5.0
11.0
6.2
Lead
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
NA
<5.0
<5.0
NA
8.6
<5.0
<5.0
<5.0
<5.0
10.4
<5.0
Selenium
NA
NA
NA
NA
<10.0
NA
NA
NA
NA
NA
NA
<10.0
<10.0
NA
<10.0
<I0.0
<10.0
<10.0
<10.0
<10.0
<10.0
Silver
NA
NA
NA
NA
<5.0
NA
NA
NA
NA
NA
NA
<5.0
<5.0
NA
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
<5.0
Mercury
NA
NA
NA
NA
<0.20
NA
NA
NA
NA
NA
NA
<0.20
<0.20
NA
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
<0.20
Metabolic Acids (meA)
Acetic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<5.0
NA
<1.8
<1.8
<0.67
<0.67
<0.67
NA
NA
NA
NA
Butyric Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<5.0
NA
<0.87
<0.87
<0.10
<0.10
<0.10
NA
NA
NA
NA
Lactic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<25
NA
<2.3
<2.3
<2.0
<2.0
<2.0
NA
NA
NA
NA
Propionic Acid
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
<5.0
NA
<1.0
<1.0
<0.25
<0.25
<0.25
NA
NA
NA
NA
P nvic Acid I
NA I
NA I
NA I
NA I
NA I
NA I
NA I
NA I
NA I
NA I
<10 I
NA 1
<2.0 1
Q.0 1
<0.53 1
<0.53 1
<0.53 1
NA I
NA I
NA I
NA
Notes:
TOC = Total Organic Carbon: DO = Dissolvrd Oxygen; NA Not Analyzed
' = Sulfide and metals samples collected on July 17, 2013.
Table 7 (Page 6 of 6)
D S:WAAJAaIVRojecDlWC DOT-0DT1WTd00�DonbxM0T3(M aMmAe6hWry3111h Repv[�Trblva\Tebbe\T)Ne1.A¢m. rcs161 Hari &Hickman, PC
m 9aaalh

Table 8
Surface Water Parameters
Former ATL Site No. 2-66
Statesville, North Carolina
H&H Job No. DOT-504
Surface Water Location
SS-1 u stream
SS-2 downstream
Sampling Date
Dec-12
Feb-13
A r-13
Jun-13
Oct-13
Jan-14
Ma -14
Jul-14
Nov-14
Feb-15
Dec-12
Feb-13
A r-13
Jtut-13
Oct-13
Jan-14
May- 14
Jul-14
Nov-14
Feb-15
Field Measurements
Dissolved Oxygen (rngd)
10.83
10.10
9.86
6.45
8.66
9.30
9.00
9.70
9.50
8.20
10.96
10.40
10.06
6.79
9.50
10.20
9.68
10.00
9.40
8.80
Ferrous Iron (mg/1)
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
<0.2
Redox(mV)
190
174
168
43
66.6
70.4
98
182
164
111
194
163
170
34
69
69
108
277
209
161
Conductivity(µS/cm)
136.4
H6.6
121.4
33.5
123.6
131.3
120.1
118.1
116.9
110.7
128.9
115.5
133.9
43.4
130.3
136.1
85.4
135.4
121.7
115.7
pH (standard traits)
7.04
7.00
7.02
6.78
7.18
7.20
7.32
6.98
7.09
7.07
7.02
6.90
6.96
7.00
7.16
7.18
7.22
6.43
6.53
6.82
Temperature (°C)
10.6
12.0
13.3
16.4
14.2
13.0
20.4
22.9
13.4
20.9
10.9
11.1
14.0
16.1
14.2
13.1
22.4
24.0
13.4
20.9
Notes:
TOC = Total Organic Carbon; DO = Dissolved Oxygen; NA = Not Analyzed
i = Sulfide and metals samples collected on Judy 17. 2013.
Table 8 (Page 1 of 1)
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NOTES:
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•
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704-586-0007(p)704-586-0373(0
SNAKIER ENVIIt)NMENTAL SOLUTIONS
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DATE: 06-01-15
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ABANDONED WATER SUPPLY
WELL
SURFACE WATER SAMPLE
® MONITORING WELL SHALLOW
SAPROLITE
TEMPORARY MONITORING WELL
• SOIL BORING
(63.98) SAPROLITE GROUNDWATER
ELEVATION (FT) (FEBRUARY 2015)
64 GROUNDWATER
POTENTIOMETRIC CONTOUR (FT)
—► ESTIMATED FLOW DIRECTION
NM NM NOT MEASURED
B
1
1 APPROXIMATE
0 100 200
SCALE IN FEET
ME ESTIMATED SHALLOW GROUNDWATER
POTENTIOMETRIC MAP - FEBRUARY 2015
FORMER ATL SITE #2-66
STATESVILLE, NORTH CAROLINA
2923 South Tryon Street -Suite 100
had hickman Charlotte, North Catolina28203
704-586-0007(p) 704-586-0373(o
SMARTS11 ENVRONMENULL SOIUiIONS license # C-1269 / #C-245 Geolc
DATE: 06-01-15 REVISION NO. 0
JOB NO. DOT-504 FIGURE NO. 5

DMW-8 (DS
5/14
7/14
11/14
2/15
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
Iss2. � �- - ..-••-
DMW-10 (DS)
i/14 7/14 11/14 2/15
<1 <1 <1 <1 - -
<1 <1 <1 <1 TREES
<1 <1 <1 <1
<1 <1 <1 <1
<1 <1 <1 <1
DMW1(-1(-1(
AGGEGRATE
STOCK PILES
DMW-6 (DS)
5/14
7/14
11/14
2/15
64.9
43.2
46.7
41.8
3.1
1.9
2
1.5
67.7
52.0
59.7
55
57.2
40.6
47.5
42.3
1Q
1)S
v1W-1 SS
0/13
5/14
11/14
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
DMW-1 (DS)
5/14
7/14
11/14
2/15
1.6
2.1
1.0
1.2
<1
<1
<1
<1
<1
1.3
<1
<1
2.9
4.2
2.4
2.5
2
3.5
1.9
1 2
TREES
DMW-11 (DS)
5/14
7/14
11/14
2/15
6.3
7.9
9.8
1 7
<1
<1
<1
<1
7.5
11.0
13.2
9.5
5.4
8.6
10
6.7
<1.0
<1.0
<1.0
<1.0
LEGEND
SITE PROPERTY BOUNDARY
- - - STREAM
SHALLOW MONITORING WELL
Q DEEP MONITORING WELL
+ MONITORING WELL BEDROCK
® WATER SUPPLY WELL
ABANDONED WATER SUPPLY
1 WELL
I
I SURFACE WATER SAMPLE
TEMPORARY MONITORING WELL
I
ESTIMATED GROUNDWATER
FLOW DIRECTION
.ES I3 TCE ISOCONCENTRATION
CONTOUR (NgA)
'15
:1 I:1
:1 I
1 I
f I I
2/15 =DATE
<1=TRICHLOROETHENE (Ng/1)
I <1=1,1,1-TRICHLOROETHANE (pg/1)
<1 =1,1-DICHLOROETHENE (pg/1)
3.7 =1,1-DICHLOROETHANE (Ng/1)
1 1.4 =CIS-1,2-DICHLOROETHENE (pg/I)
I
PARKING
I
I
1
I
I
WSW-4 WSW-0A
(Acme) �(INACme) APPROXIMATE
)FFICE I o 100 200
SCALE IN FEET
TARGET VOC CONCENTRATIONS IN
SAPROLITE GROUNDWATER
PROJM7
TREES I FORMER ATL SITE #2-66
STATESVILLE, NORTH CAROLINA
SOUTHERN RAILROAD
• 2923 South Tryon Street -Suite 100
hart'"` hiekman Charlotte, North Carolina 28203
704-586-0007(p) 704-586-0373(f
SNU1RIHl ENVIROMJIQidL SOWIXW License # C-1269 / #C-245 Geolo
DATE: 06-01-15 REVISION NO. 0
JOB NO. DOT-504 FIGURE NO. 6

QDMW-8
-TRIBUTARY — —
� ss-z� • • � ' �— '
DMW-7 (SBR)
5/14
7/14
11/14
2/15
<1
I <1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
/
/ DMW-6-
_. DMW-11
TREES
/
/
u
LLI
• U
/
/
TREES -
I—
=7-,7 7,7 i i,,- -- — —
SOUTHERN RAILROAD
DMW-3 SBR
4/13
10/13
5/14
2/15
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
MAIN
iARAGE
I
I
TREES I
I
�I
WSW-4
V13
5/14
11/14
2/15
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
I <1
<1
<1
TREES
<1
<1
<1
OFFICE
I
I
I
1
I
I
I
I
4 WSW-4A
7 (INACTIVE)
I
I
r
LEGEND
SITE PROPERTY BOUNDARY
— — — STREAM
SHALLOW MONITORING WELL
Q DEEP MONITORING WELL
+ MONITORING WELL BEDROCK
® WATER SUPPLY WELL
ABANDONED WATER SUPPLY
WELL
SURFACE WATER SAMPLE
TEMPORARY MONITORING WELL
• SOIL BORING
2/15 =DATE
<1=TRICHLOROETHENE (Ng/1)
<1=1,1,1—TRICHLOROETHANE (Ng/1)
<1 =1,1—DICHLOROETHENE (Ng/1)
<1 =1,1—DICHLOROETHANE (pg/1)
<1 =CIS-1,2—DICHLOROETHENE (pg/1)
APPROXIMATE
0 100 200
SCALE IN FEET
TARGET VOC CONCENTRATIONS
IN BEDROCK GROUNDWATER
FORMER ATL SITE #2-66
STATESVILLE, NORTH CAROLINA
� 2923 Suth Tryonteet-Suite
hart hickman Charlottoe, North CStazolina 28203100
704-586-0007(p) 704-586-0373(f
SMARM! EtMotHAENM SOWIEONS License # C-1269 / #C-245 Geok
DATE: 06-01-15 REVISION NO. 0
JOB NO. DOT-504 FIGURE NO. 7

Appendix A
Laboratory Analytical Data
14
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

aceAnalytical
www.pacelabs.com
November 19, 2014
Chemical Testing Engineer
NCDOT
Materials & Tests Unit
1801 Blue Ridge Road
Raleigh, NC 27607
RE: Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Dear Chemical Engineer:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2014.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
�e pCCRF��
geORA,�pQ,
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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aceAnalytical
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Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
I
Minnesota Certification IDs
1700 Elm Street SE Suite 200, Minneapolis, MN 55414
A&A Certification M 2926.01
Alaska Certification M UST-078
Alaska Certification #MN00064
Alabama Certification #40770
Arizona Certification #: AZ-0014
Arkansas Certification #: 88-0680
California Certification M 01155CA
Colorado Certification #Pace
Connecticut Certification M PH-0256
EPA Region 8 Certification M 8TMS-L
Florida/NELAP Certification #: E87605
Guam Certification M14-008r
Georgia Certification M 959
Georgia EPD M Pace
Idaho Certification M MN00064
Hawaii Certification #MN00064
Illinois Certification M 200011
Indiana Certification#C-MN-01
Iowa Certification #: 368
Kansas Certification #: E-10167
Kentucky Dept of Envi. Protection - DW #90062
Kentucky Dept of Envi. Protection - WW #:90062
Louisiana DEQ Certification M 3086
Louisiana DHH #: LA140001
Maine Certification #: 2013011
Maryland Certification #: 322
Michigan DEPH Certification #: 9909
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #. 37706
North Carolina Field Services Certification M 5342
North Carolina Wastewater Certification M 12
South Carolina Certification M 99006001
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification P. M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Minnesota Certification M 027-053-137
Mississippi Certification M Pace
Montana Certification #: MT0092
Nevada Certification #: MN 00064
Nebraska Certification M Pace
New Jersey Certification #: MN-002
New York Certification #: 11647
North Carolina Certification M 530
North Carolina State Public Health * 27700
North Dakota Certification M R-036
Ohio EPA M 4150
Ohio VAP Certification #: CL101
Oklahoma Certification M 9507
Oregon Certification #: MN200001
Oregon Certification #: MN300001
Pennsylvania Certification #: 68-00563
Puerto Rico Certification
Saipan (CNMI) #:MP0003
South Carolina #:74003001
Texas Certification M T104704192
Tennessee Certification M 02818
Utah Certification M MN000642013-4
Virginia DGS Certification #. 251
Virginia/VELAP Certification #: Pace
Washington Certification M C486
West Virginia Certification M 382
West Virginia DHHR *9952C
Wisconsin Certification M 999407970
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
West Virginia Certification M 357
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
West Virginia Certification #. 356
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 51

i
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SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
HuntersAlle, NC 28078
[phone]
Project:
DOT-504 34613.3.26
Pace Project No.:
92224577
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92224577001
DMW-10
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577002
SMW-2
RSK 175
JRB
3
PASI-M
EPA 6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310E
AES2
1
PASI-A
92224577003
DMW-2
RSK 175
JRB
3
PASI-M
EPA 6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577004
DMW-11
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577005
SMW-1
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, Inc..
Page 3 of 51

7 ci
Analytical e
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
Kincey Ave. te 100
9800Hunte sville, NC1280778
[phone]
-.
jl
Analytes
Lab ID Sample ID
Method
Analysts
Reported Laboratory
EPA 300.0
AES2
1 PASI-A
EPA353.2
DMN
1 PASI-A
SM 5310B
AES2
1 PASI-A
92224577006 DMW-6
RSK 175
JRB
3 PASI-M
EPA6010
JMW
7 PASI-A
EPA 7470
HVK
1 PASI-A
_ SM 6200B
CAH
33 PASI-C
SM 4500-S21D
JTJ
1 PASI-A
EPA 300.0
AES2
1 PASI-A
EPA 353.2
DMN
1 PASI-A
SM 5310B
AES2
1 PASI-A
92224577007 DMW-9
RSK 175
JRB
3 PASI-M
EPA6010
JMW
7 PASI-A
EPA 7470
HVK
1 PASI-A
SM 6200B
CAH
33 PASI-C
SM 4500-S21)
JTJ
1 PASI-A
EPA 300.0
AES2
1 PASI-A —
EPA 353.2
DMN
1 PASI-A
SM 5310B
AES2
1 PASI-A
92224577008 DMW-8
RSK 175
JRB
3 PASI-M —�
EPA6010
JMW
7 PASI-A
EPA 7470
HVK
1 PASI-A
SM 6200B
CAH
33 PASI-C
SM 4500-S2D
JTJ
1 PASI-A
EPA 300.0
AES2
1 PASI-A
EPA353.2
DMN
1 PASI-A
SM 5310B
AES2
1 PASI-A
92224577009 SMW-3
RSK 176
JRB
3 PASI-M
EPA6010
JMW
7 PASI-A
EPA 7470
HVK
1 PASI-A
SM 6200B
CAH
33 PASI-C
SM 4500-S21)
JTJ
1 PASI-A
EPA 300.0
AES2
1 PASI-A
EPA353.2
DMN
1 PASI-A
SM 5310B
AES2
1 PASI-A
92224577010 DMW-7
RSK 175
JRB
3 PASI-M
i
EPA6010
JMW
7 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
J r
without the written consent of Pace Analytical Services, Inc..
Page 4 of 51

- 5acmnalytical
j www..pacelabs.com
f
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersviile, NC 28078
[phone]
Project:
Pace Project No.:
DOT-504 34613.3.26
92224577
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577011
DMW-1
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S213
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577012
DMW-4
RSK 176
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200E
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92224577013
WSW-4
SM 6200B
CAH
33
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 51

.0-1911
aceAnalytical
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i
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-10
Parameters
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577001 Collected: 11/05/14 10:45 Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 14:40
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 14:40
74-85-1
Methane
1200 ug/L
6.6
1
11/11/14 14:40
74-82-8
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 01:46
7440-38-2
Barium
122 ug/L
5.0
1
11/07/14 15:20
11/08/14 01:46
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 01:46
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/1415:20
11/08/14 01:46
7440-47-3
Lead
ND ug/L
5.0
1
11/07/1415:20
11/08/14 01:46
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/1415:20
11/08/14 01:46
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 01:46
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/0711412:00
11/07/1414:50
7439-97-6 M1
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
11/12/14 17:46
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/1417.46
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/1417.46
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 17:46
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11112/1417:46
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/1211417:46
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 17:46
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/1417A6
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/1417:46
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11112/1417:46
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 17:46
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 17:46
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 17:46
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 17:46
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 17:46
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 17:46
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 17:46
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 17:46
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 17:46
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 17:46
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 17:46
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 17:46
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 17A6
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 17:46
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 17:46
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/1417A6
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/1417A6
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 17:46
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 17:46
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 6 of 51

�- aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-10
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
I
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
6310B TOC
Total Organic Carbon
Date: 11/19/2014 05:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577001 Collected:
11/05/14 10:45
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/1417:46
106-93-4
95 %
70-130
1
11/12/1417:46
460-00-4
94 %
70-130
1
11/12/1417:46
17060-07-0
100 %
70-130
1
11/12/1417:46
2037-26-5
Analytical Method: SM 4500-S21)
ND mg/L
0.10
1
11/11/1414:20
18496-25-8
Analytical Method: EPA 300.0
18.3 mg/L
2.0
1
11/09/14 02:37
14808-79-8
Analytical Method: EPA 353.2
ND mg/L
0.020
1
11/07/14 01:23
Analytical Method: SM 5310B
46.1 mg/L
1.0
1
11/08/14 21:53
7440-44-0 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 7 of 51

55'cie Analytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: SMW-2
Parameters
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577002 Collected: 11/05/14 11:20 Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 14:51
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 14:51
74-85-1
Methane
136 ug/L
6.6
1
11/11/14 14:51
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1 11/07/14 15:20
11/08/14 01:56
7440-38-2
Barium
34.7 ug/L
5.0
1 11/07/14 15:20
11/08/14 01:56
7440-39-3
Cadmium
ND ug/L
1.0
1 11/07/14 15:20
11/08/14 01:56
7440-43-9
Chromium
ND ug/L
5.0
1 11/07/1415:20
11/08/14 01:56
7440-47-3
Lead
ND ug/L
5.0
1 11/07/1415:20
11/08/14 01:56
7439-92-1
Selenium
ND ug/L
10.0
1 11/07/1415:20
11/08/14 01:56
7782-49-2
Silver
ND ug/L
5.0
1 11/07/1415:20
11/08/14 01:56
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1 11/07/1412:00
11/07/14 14:58
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
2.2 ug/L
1.0
1
11/12/14 18:02
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/1211418:02
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 18:02
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 18:02
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 18:02
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:02
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 18:02
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 18:02
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:02
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:02
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 18:02
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 18:02
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 18:02
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 18:02
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 18:02
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 18:02
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 18:02
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 18:02
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 18:02
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 18:02
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11112/1418:02
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 18:02
75-71-8
Methylene Chloride .
ND ug/L
2.0
1
11/12/14 18:02
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11112/1418:02
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 18:02
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 18:02
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/14 18:02
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/1211418:02
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 18:02
75-01-4
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM
without the written consent of
Pace Analytical Services, Inc..
Page 8 of 51

aceAnalytical
mm..pacelabs.com
i
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: SMW-2
i
Parameters
601 Volatiles by SM 6200
1,2-Dibromoelhane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577002 Collected: 11/05/14 11:20
Results Units Report Limit DF
Received: 11/06/14 15:42 Matrix: Water
Prepared Analyzed CAS No. Qua[
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/1211418:02
106-93-4
96 %
70-130
1
11/12/14 18:02
460-00-4
99 %
70-130
1
11/12/1418:02
17060-07-0
100 %
70-130
1
11/12/1418:02
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
11/11/14 14:20
18496-25-8
Analytical Method: EPA 300.0
54.8 mg/L
4.0
2
11/12/14 11:47
14808-79-8
Analytical Method: EPA 353.2
ND mg/L
0.020
1
11/07/14 01:31
Analytical Method: SM 5310B
31.2 mg/L
1.0
1
11/08/14 22:28
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 51

_1�5a'neAnalydcal"
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-2
Parameters
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577003 Collected: 11/05/14 11:50 Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 15:02
74-84-0
Ethane
ND ug/L
6.2
1
11/11/14 15:02
74-85-1
Methane
42.2 ug/L
6.6
1
11/11/14 15:02
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 01:59
7440-38-2
Barium
26.3 ug/L
5.0
1
11/07/1415:20
11/08/14 01:59
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 01:59
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 01:59
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 01:59
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 01:59
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 01:59
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11107/1412:00
11/07/1415:01
7439-97-6
601 Volatiles by SM. 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
1.2 ug/L
1.0
1
11/12/14 18:19
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/14 18:19
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 18:19
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 18:19
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 18:19
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:19
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 18:19
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11112/1418:19
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:19
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 18:19
109-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 18:19
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 18:19
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 18:19
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 18:19
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1418:19
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 18:19
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 18:19
108-90-7
Chloroethane
ND ug/L
1.0
1
11112/1418:19
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 18:19
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 18:19
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 18:19
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 18:19
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 18:19
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 18:19
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 18:19
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 18:19
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/14 18:19
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 18:19
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 18:19
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 10 of 51

acieAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-2
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S21) Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577003 Collected:
11/05/14 11:50
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/1418:19
106-93-4
96 %
70-130
1
11/12/1418:19
460-00-4
97 %
70-130
1
11/12/1418:19
17060-07-0
100 %
70-130
1
11/12/1418:19
2037-26-5
Analytical Method: SM 4500-S213
ND mg/L
0.10
1
11/11/1414:20
18496-25-8
Analytical Method: EPA 300.0
69.3 mg/L
8.0
4
11/12/1412:01
14808-79-8 M1
Analytical Method: EPA 353.2
2.5 mg/L
0.020
1
11/07/14 01:32
Analytical Method: SM 5310B
23.6 mg/L
1.0
1
11/08/14 22:40
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11119/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 11 of 51

Pace Analytical Services, Inc.
i
Kincey Ave.
® 9800Huntersvlle, NCi28 78
_ te 100
aceAnalytical
www.pacelabs.com [phone]
ANALYTICAL RESULTS -,
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-11 Lab ID: 92224577004 Collected: 11/05/1412:25 Received: 11/06/14 15:42 Matrix: Water j
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 15:13
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 15:13
74-85-1
Methane
4840 ug/L
6.6
1
11/11/14 15:13
74-82-8
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3010'
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:02
7440-38-2
Barium
66.1 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:02
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:02
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:02
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:02
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:02
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:02
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11107/1415:03
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
10 ug/L
1.0
1
11/12/1418:36
75-34-3
1,1-Dichloroethene
13.2 ug/L
1.0
1
11/12/1418:36
75-35-4
1,1,1-Tdchloroethane
ND ug/L
1.0
1
11/12/1418:36
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/1418:36
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/1418:36
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:36
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/1418:36
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/1418:36
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:36
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:36
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 18:36
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/1418:36
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/1418:36
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/1418:36
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1418:36
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 18:36
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/1418:36
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/1418:36
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/1418:36
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 18:36
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/1211418:36
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/1418:36
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/1418:36
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/1418:36
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1418:36
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/1418:36
127-18-4
Trichloroethene
9.8 ug/L
1.0
1
11/12/1418:36
79-01-6
Tdchlorofluoromethane
ND ug/L
1.0
1
11/12/1418:36
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 18:36
75-01-4
Date: 11/19/2014 05:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 51

aceAnalytical
mvw.pecolabs.com
C
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-11
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-13romofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S21) Sulfide Water
c
Sulfide
300.0 IC Anions 28 Days
Sulfate
363.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Date: 11/19/2014 05:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224677004 Collected:
11/05/14 12:25
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/1418:36
106-93-4
96 %
70-130
1
11/12/14 18:36
460-00-4
96 %
70-130
1
11/12/1418:36
17060-07-0
100 %
70-130
1
11/12/1418:36
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
11/11/14 14:20
18496-25-8
Analytical Method: EPA 300.0
39.2 mg/L
4.0
2
11/12/14 12:42
14808-79-8
Analytical Method: EPA 353.2
ND mg/L
0.020
1
11/07/14 01:34
Analytical Method: SM 5310B
45.0 mg/L
2.0
2
11/11/1415:33
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 13 of 51

aceAnalytical
www.pace/ahs.com
I
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone] -�
� I
Sample: SMW-1
Parameters
Lab ID: 92224577005 Collected: 11/05/14 12:50
Results Units Report Limit DF
Received: 11/06/14 15:42 Matrix: Water
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 15:24
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 15:24
74-85-1
Methane
ND ug/L
6.6
1
11/11/1415:24
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/1415:20
11/08/14 02:05
7440-38-2
Barium
122 ug/L
5.0
1
11/07/1415:20
11/08/14 02:05
7440-39-3
Cadmium
ND ug/L
1.0
1
11/0711415:20
11/08/14 02:05
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:05
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:05
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:05
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:05
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:06
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
11/12/1418:52
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/1418:52
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/1211418:52
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/1418:52
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/1418:52
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:52
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11112/1418:52
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/1418:52
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:52
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/1418:52
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 18:52
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/1418:52
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/1418:52
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/1418:52
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1418:52
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 18:52
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 18:52
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/1418:52
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 18:52
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/1418:52
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/1418:52
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/1418:52
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 18:52
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11112/1418:52
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1418:52
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 18:52
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/1418:52
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 18:52
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 18:52
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 14 of 51

aceAnalXical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: SMW-1
Parameters
I
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
w Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Date: 11/19/2014 05:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577005 Collected: 11/05/14 12:50
Results Units Report Limit DF
Received: 11/06/14 15:42 Matrix: Water
Prepared Analyzed CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/14 18:52
106-93-4
96 %
70-130
1
11/12/14 18:52
460-00-4
98 %
70-130
1
11/12/14 18:52
17060-07-0
100 %
70-130
1
11/12/14 18:52
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
11/11/1414:20
18496-25-8
Analytical Method: EPA 300.0
20.8 mg/L
2.0
1
11/09/14 03:59
14808-79-8
Analytical Method: EPA 353.2
2.9 mg/L
0.020
1
11/07/14 01:35
Analytical Method: SM 5310B
30.9 mg/L
1.0
1
11/08/14 23:27
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 51

1�55'cmnalyticalo
www..pacelabs.com
r
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-6
Parameters
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577006 Collected: 11/05/14 14:20 Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
7.0 ug/L
6.2
1
11/11/14 16:34
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 16:34
74-85-1
Methane
766 ug/L
6.6
1
11/11/14 16:34
74-82-8
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:08
7440-38-2
Barium
126 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:08
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:08
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/1415:20
11/08/14 02:08
7440-47-3
Lead
ND ug/L
5.0
1
1110711415:20
11/08/14 02:08
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/1415:20
11/08/14 02:08
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:08
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:09
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
47.5 ug/L
1.0
1
11/12/14 19:09
75-34-3
1,1-Dichloroethene
59.7 ug/L
1.0
1
11/12/14 19:09
75-35-4
1,1,1-Trichloroethane
2.0 ug/L
1.0
1
11/12/14 19:09
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 19:09
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 19:09
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 19:09
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 19:09
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 19:09
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/1211419:09
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 19:09
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 19:09
75-27-4
Bromomethane
ND ug/L
5.0
1
11/1211419:09
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 19:09
75-25-2
cis-1,2-Dichloroethene
3.3 ug/L
1.0
1
11/12/14 19:09
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 19:09
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 19:09
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 19:09
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 19:09
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 19:09
67-66-3
Chloromethane
ND ug/L
1.0
1
11/1211419:09
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 19:09
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
.11/12/14 19:09
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 19:09
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/1211419:09
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 19:09
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 19:09
127-18-4
Trichloroethene
46.7 ug/L
1.0
1
11112/1419:09
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 19:09
75-69-4
Vinyl chloride
1.5 ug/L
1.0
1
11/12/14 19:09
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 16 of 51

- 5acieAnalydcal
www.pacelabs.com
i
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
s Sample: DIVIW-6
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310E TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577006 Collected:
11/05/14 14:20
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/1419:09
106-93-4
96 %
70-130
1
11/12/1419:09
460-00-4
97 %
70-130
1
11/12/14 19:09
17060-07-C
98 %
70-130
1
11/12/1419:09
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
11/11/1414:20
18496-25-6
Analytical Method: EPA 300.0
39.8 mg/L
4.0
2
11/09/14 03:59
14808-79-8
Analytical Method: EPA 353.2
ND mg/L
0.020
1
11/07/14 01:36
Analytical Method: SM 5310B
45.0 mg/L
1.0
1
11/08/14 23:39
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Qua[
Page 17 of 51

_ aceAnalytica(
www.pacelabs.com
r
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-9 Lab ID: 92224577007 Collected: 11/05/14 15:00 Received: 11/06/14 15:42 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 16:56
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 16:56
74-85-1
Methane
707 ug/L
6.6
1
11/11/14 16:56
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method:
EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/1415:20
11/08/14 02:11
7440-38-2
Barium
76.0 ug/L
5.0
1
11/07/1415:20
11/08/14 02:11
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:11
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:11
7440-47-3
Lead
ND ug/L
5.0
1
11/07/1415:20
11/08/14 02:11
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/1415:20
11/08/14 02:11
7782-49-2
Silver
ND ug/L
5.0
1
11107/1415:20
11/08/14 02:11
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:17
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
2.6 ug/L
1.0
1
11/12/1419:26
75-34-3
1,1-Dichloroethene
1.6 ug/L
1.0
1
11/12/1419:26
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/1419:26
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/1419:26
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/1419:26
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/1419:26
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/1419:26
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/1419:26
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11112/1419:26
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/1419:26
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/1419:26
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/1419:26
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/1419:26
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/1419:26
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1419:26
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 19:26
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/1419:26
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/1419:26
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/1419:26
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/1419:26
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/1419:26
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/1419:26
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 19:26
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11112/1419:26
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/1419:26
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/1419:26
127-18-4
Trichloroethene
2.3 ug/L
1.0
1
11/12/1419:26
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/1419:26
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 19:26
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 18 of 51

aceAnalytical
www..pacelabs.com
,I
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-9
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577007 Collected:
11/05/1415:00
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qua[
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/1419:26
106-93-4
97 %
70-130
1
11/12/1419:26
460-00-4
100 %
70-130
1
11/12/1419:26
17060-07-0
100 %
70-130
1
11/12/1419:26
2037-26-5
Analytical Method: SM 4500-S21)
ND mg/L
0.10
1
11/11/14 14:20
18496-25-8
Analytical Method: EPA 300.0
69.3 mg/L
4.0
2
11/09/14 04:26
14808-79-8
Analytical Method: EPA 353.2
1.4 mg/L
0.020
1
11/07/14 01:37
.
Analytical Method: SM 5310B
30.6 mg/L
1.0
1
11/08/14 23:54
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 61

aceAnalytical
1 www.pacelabs.com
I
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-8 Lab ID: 92224577008 Collected: 11/05/14 15:50 Received: 11/06/14 15:42 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 17:07
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 17:07
74-85-1
Methane
ND ug/L
6.6
1
11/11/14 17:07
74-82-8
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:24
7440-38-2
Barium
32.3 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:24
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/1415:20
11/08/14 02:24
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/1415:20
11/08/14 02:24
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:24
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/1415:20
11/08/14 02:24
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:24
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:19
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
11/12/14 19:43
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/14 19:43
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 19:43
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/1211419:43
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 19:43
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/1211419:43
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 19:43
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 19:43
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/1211419:43
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 19:43
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 19:43
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 19:43
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 19:43
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 19:43
156-59-2
cis- 1, 3-Dichloropropene
ND ug/L
1.0
1
11/12/14 19:43
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 19:43
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 19:43
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 19:43
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 19:43
67-66-3
Chloromethane
ND ug/L
1.0
1
11112/1419:43
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 19:43
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 19:43
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 19:43
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11112/1419:43
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 19:43
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 19:43
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/1419:43
79-01-6
Tdchlorofluoromethane
ND ug/L
1.0
1
11/12/14 19:43
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 19:43
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 20 of 51

ii
aceAnaljftal
rmvw.pacelabs.com
i
ANALYTICAL RESULTS
J Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-8
Parameters
Lab ID: 92224577008 Collected: 11/05/14 15:50
Results Units Report Limit DF
Received: 11/06/1415:42 Matrix: Water
Prepared Analyzed CAS No.
601 Volatiles by SM 6200
Analytical Method: SM 6200B
-
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
11/12/14 19:43
106-93-4
Surrogates
4-Bromofluorobenzene (S)
95 %
70-130
1
11/12/14 19:43
460-00-4
1,2-Dichloroethane-d4 (S)
98 %
70-130
1
11/12/14 19:43
17060-07-0
Toluene-d8 (S)
101 %
70-130
1
11/12/14 19:43
2037-26-5
4500S213 Sulfide Water
Analytical Method: SM 4500-S2D
' Sulfide
ND mg/L
0.10
1
11/11/14 14:20
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
2.2 mg/L
2.0
1
11/12/14 12:55
14808-79-8
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
0.87 mg/L
0.020
1
11/07/14 01:38
5310B TOC
Analytical Method: SM 5310B
Total Organic Carbon
10.8 mg/L
1.0
1
11/09/14 00:06
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Qual
Page 21 of 51

IeAnalytical"
J www.pacelab&com
I
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 _
Huntersville, NC 28078
[phone]
Sample: SMW-3
Parameters
Lab ID: 92224577009 Collected: 11/06/14 08:50
Results Units Report Limit DF
Received: 11/06/14 15:42 Matrix: Water
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 17:18
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 17:18
74-85-1
Methane
18.7 ug/L
6.6
1
11/11/14 17:18
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:27
7440-38-2
Barium
107 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:27
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:27
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:27
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:27
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:27
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:27
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
_11/07/1415:22
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
2.3 ug/L
1.0
1
11/12/14 20:00
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:00
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:00
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:00
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 20:00
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:00
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 20:00
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 20:00
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:00
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:00
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 20:00
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 20:00
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 20:00
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:00
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:00
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 20:00
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 20:00
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 20:00
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 20:00
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 20:00
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 20:00
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 20:00
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 20:00
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:00
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:00
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 20:00
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/14 20:00
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 20:00
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 20:00
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 22 of 51
I

aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: SMW-3
' Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
-, 4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
_ 4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
I
Date: 11/19/2014 05:39 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577009 Collected:
Analytical
Analytical
Analytical
Analytical
Analytical
11/06/14 08:50
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. ' Qual
Method: SM 6200B
ND ug/L
1.0
1
11/12/14 20:00
106-93-4
96 %
70-130
1
11/12/14 20:00
460-00-4
101 %
70-130
1
11/12/14 20:00
17060-07-0
100 %
70-130
1
11/12/14 20:00
2037-26-5
Method: SM 4500-S2D
ND mg/L
0.10
1
11/12/1415:20
18496-25-8
Method: EPA 300.0
6.4 mg/L
2.0
1
11/12/1413:09
14808-79-8
Method: EPA 353.2
0.079 mg/L
0.020
1
11/07/14 01:45
Method: SM 5310B
28.8 mg/L
1.0
1
11/09/14 00:25
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 23 of 51

laneAnalyticalo
mvw.pacelabs.com
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-7
Parameters
Lab ID: 92224577010 Collected: 11/06/14 09:45
Results Units Report Limit DF
Received: 11/06/14 15:42 Matrix: Water
Prepared Analyzed _ CAS No. Qual
RSK 176 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/1417:29
74-84-0
Ethene
ND ug/L
6.2
1
11111/1417:29
74-85-1
Methane
ND ug/L
6.6
1
11/11/1417:29
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:30
7440-38-2
Barium
84.2 ug/L
5.0
1
11/07/1415:20
11/08/14 02:30
7440-39-3
Cadmium
2.3 ug/L
1.0
1
11/07/14 15:20
11/08/14 02:30
7440-43-9
Chromium
11.0 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:30
7440-47-3
Lead
10.4 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:30
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:30
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:30
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:24
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
11/12/14 20:17
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/1420:17
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11112/1420:17
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:17
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 20:17
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:17
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 20:17
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 20:17
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:17
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:17
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 20:17
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 20:17
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 20:17
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:17
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:17
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 20:17
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 20:17
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 20:17
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 20:17
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 20:17
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 20:17
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 20:17
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 20:17
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:17
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:17
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 20:17
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/14 20:17
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 20:17
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 20:17
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 24 of 51

aceAnalyfical
www.pacelabs.com
I
i I
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-7
Lab ID: 92224577010 Collected:
11/06/14 09:45
Received: 11/06/14 15:42 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
11/12/14 20:17
106-93-4
Surrogates
4-Bromofluorobenzene (S)
95 %
70-130
1
11/12/14 20:17
460-00-4
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
11/12/14 20:17
17060-07-0
Toluene-d8 (S)
100 %
70-130
1
11/12/14 20:17
2037-26-5
4500S2D Sulfide Water
Analytical Method: SM 4500-S21)
Sulfide
0.17 mg/L
0.10
1
11/12/1415:20
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
24.9 mg/L
2.0
1
11/1211413:50
14808-79-8
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
2.9 mg/L
0.020
1
11/07/14 01:49
5310B TOC
Analytical Method: SM 531013
Total Organic Carbon
13.6 mg/L
1.0
1
11/09/14 00:38
7440-44-0
Date: 11/19/2014 05:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qua[
Page 25 of 51

aceAnaiXical
www.pacelabs.com
1
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-1
Parameters
Lab ID: 92224577011 Collected: 11/06/14 11:30
Results Units Report Limit DF
Received: 11/0611415:42 Matrix: Water
Prepared Analyzed CAS No. Qual
RSK 176 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 17:41
74-84-0
Ethene
ND ug/L
6.2
1
11/11/14 17:41
74-85-1
Methane
10.4 ug/L
6.6
1
11/11/14 17:41
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:33
7440-38-2
Barium
54.3 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:33
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:33
7440-43-9
Chromium
. ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:33
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:33
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:33
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:33
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:27
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
2.4 ug/L
1.0
1
11/12/14 20:33
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11112/1420:33
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:33
71-65-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11112/1420:33
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11112/1420:33
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:33
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
1111211420:33
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/1211420:33
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:33
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:33
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 20:33
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 20:33
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 20:33
75-25-2
cis-1,2-Dichloroethene
1.9 ug/L
1.0
1
11/12/14 20:33
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:33
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 20:33
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 20:33
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 20:33
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 20:33
67-66-3
Chloromethane
ND ug/L
1.0
1
11/12/14 20:33
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 20:33
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 20:33
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 20:33
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:33
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:33
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 20:33
127-18-4
Trichloroethene
1.0 ug/L
1.0
1
11/12/14 20:33
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 20:33
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 20:33
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 26 of 51
i

1�5acieAnalytical
www..pacelabs.com
1
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-1
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S21) Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577011 Collected:
11/06/14 11:30
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
1.0
1
11/12/14 20:33
106-93-4
95 %
70-130
1
11/12/14 20:33
460-00-4
100 %
70-130
1
11/12/14 20:33
17060-07-0
100 %
70-130
1
11/12/14 20:33
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
11/12/1415:20
18496-25-8
Analytical Method: EPA 300.0
4.2 mg/L
2.0
1
11/12/1414:03
14808-79-8
Analytical Method: EPA 353.2
0.041 mg/L
0.020
1
11/07/1415:40
Analytical Method: SM 5310B
17.4 mg/L
1.0
1
11/11/14 19:42
7440-44-0 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 27 of 51

I�AceAnalydca(
www.pacelabs.com
f
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-4
Parameters
Lab ID: 92224577012 Collected: 11/06/14 13:10
Results Units Report Limit DF
Received: 11/06/1415:42 Matrix: Water
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
11/11/14 17:52
74-84-0
Ethene
ND ug/L
6.2
1
11/11/1417:52
74-85-1
Methane
189 ug/L
6.6
1
11/11/1417:52
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:36
7440-38-2
Barium
17.3 ug/L
5.0
1
11/07/14 15:20
11/08/14 02:36
7440-39-3
Cadmium
ND ug/L
1.0
1
11/07/14 15:20
11/08/14 02:36
7440-43-9
Chromium
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:36
7440-47-3
Lead
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:36
7439-92-1
Selenium
ND ug/L
10.0
1
11/07/14 15:20
11/08/14 02:36
7782-49-2
Silver
ND ug/L
5.0
1
11/07/14 15:20
11/08/14 02:36
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
11/07/1412:00
11/07/1415:30
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
11/12/14 20:50
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:50
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:50
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
11/12/14 20:50
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
11/12/14 20:50
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:50
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
11/12/14 20:50
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
11/12/14 20:50
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:50
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
11/12/14 20:50
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
11/12/14 20:50
75-27-4
Bromomethane
ND ug/L
5.0
1
11/12/14 20:50
74-83-9
Bromoform
ND ug/L
1.0
1
11/12/14 20:50
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:50
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:50
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
11/12/14 20:50
56-23-5
Chlorobenzene
ND ug/L
1.0
1
11/12/14 20:50
108-90-7
Chloroethane
ND ug/L
1.0
1
11/12/14 20:50
75-00-3
Chloroform
ND ug/L
1.0
1
11/12/14 20:50
67-66-3 -
Chloromethane
ND ug/L
1.0
1
11/12/14 20:50
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
11/12/14 20:50
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
11/12/14 20:50
75-71-8
Methylene Chloride
ND ug/L
2.0
1
11/12/14 20:50
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
11/12/14 20:50
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
11/12/14 20:50
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
11/12/14 20:50
127-18-4
Trichloroethene
ND ug/L
1.0
1
11/12/14 20:50
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
11/12/14 20:50
75-69-4
Vinyl chloride
ND ug/L
1.0
1
11/12/14 20:50
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 28 of 51

- aceAnal
Yl
ical
1 www..pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Sample: DMW-4
Parameters
i
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310E TOC
Total Organic Carbon
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92224577012 Collected:
Analytical
Analytical
Analytical
Analytical
Analytical
11/06/14 13:10
Received: 11/06/14 15:42 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No.
Method: SM 6200B
ND ug/L
1.0
1
11/12/14 20:50
106-93-4
96 %
70-130
1
11/12/14 20:50
460-00-4
100 %
70-130
1
11/12/14 20:50
17060-07-0
99 %
70-130
1
11/12/14 20:50
2037-26-5
Method: SM 4500-S2D
0.11 mg/L
0.10
1
11/12/1415:20
18496-25-8
Method: EPA 300.0
5.0 mg/L
2.0
1
11/12/1414:17
14808-79-8
Method: EPA 353.2
ND mg/L
0.020
1
11/07/1415:59
Method: SM 5310B
27.0 mg/L
1.0
1
11/11/14 20:15
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Qual
Page 29 of 51

aceAnalytical
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r
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 KinceyAve. Suite too
Hunlersville, NC 28078
[phone]
Sample: WSW-4 Lab ID: 92224577013 Collected: 11/06/1413:30 Received: 11/06/14 15:42 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 11/19/2014 05:39 PM
Analytical Method: SM 6200B
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
ND ug/L
96 %
96 %
99 %
1.0
1
11/12/14 21:07
75-34-3
1.0
1
11/12/14 21:07
75-35-4
1.0
1
11/12/14 21:07
71-55-6
1.0
1
11/12/14 21:07
79-00-5
1.0
1
11/12/14 21:07
79-34-5
1.0
1
11/12/14 21:07
95-50-1
1.0
1
11/12/14 21:07
107-06-2
1.0
1
11/12/14 21:07
78-87-5
1.0
1
11/12/14 21:07
541-73-1
1.0
1
11/12/14 21:07
106-46-7
1.0
1
11/12/14 21:07
75-27-4
5.0
1
11/12/14 21:07
74-83-9
1.0
1
11/12/14 21:07
75-25-2
1.0
1
11/12/14 21:07
156-59-2
1.0
1
11/12/14 21:07
10061-01-5
1.0
1
11/12/14 21:07
56-23-5
1.0
1
11/12/14 21:07
108-90-7
1.0
1
11/12/14 21:07
75-00-3
1.0
1
11/12/14 21:07
67-66-3
1.0
1
11/12/14 21:07
74-87-3
1.0
1
11/12/14 21:07
124-48-1
1.0
1
11/12/14 21:07
75-71-8
2.0
1
11/12/14 21:07
75-09-2
1.0
1
11/12/14 21:07
156-60-5
1.0
1
11/12/14 21:07
10061-02-6
1.0
1
11/12/14 21:07
127-18-4
1.0
1
11/12/14 21:07
79-01-6
1.0
1
11/12/14 21:07
75-69-4
1.0
1
11/12/14 21:07
75-01-4
1.0
1
11/12/14 21:07
106-93-4
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
11/12/14 21:07 460-00-4
11/12/14 21:07 17060-07-0
11/12/14 21:07 2037-26-5
Page 30 of 51

Pace Analytical Services, Inc.
® 9800 Kincey Ave. Suite 100
aceAnalytical Huntersville, NC 28078
www..pacelabs.com [phone]
I
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: AIR/21799 Analysis Method: RSK 175
QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012
METHOD BLANK: 1841320 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
- 92224577008,92224577009,92224577010,92224577011,92224577012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Ethane ug/L ND 6.2 11/11/1410:26
Ethene ug/L ND 6.2 11/11/1410:26
Methane ug/L NO 6.6 11/11/1410:26
LABORATORY CONTROL SAMPLE & LCSD: 1841321
1841322
-'
Spike
LCS
LCSD
LCS LCSD
% Rec Max
Parameter Units
Conc.
Result
Result
% Rec % Rec
Limits RPD RPD Qualifiers
Ethane ug/L
114
117
106
103 93
85-115 10 20
Ethene ug/L
106
108
97.4
102 92
85-115 11 20
Methane ug/L
60.7
61.5
54.7
101 90
85-115 12 20
SAMPLE DUPLICATE: 1841323
60181936012 Dup
Parameter Units Result Result RPD Qualifiers
Ethane ug/L 56.0 64.2 14
Ethene ug/L <3.1 ND
Methane ug/L 390 434 10
SAMPLE DUPLICATE: 1841324
92224577006 Dup
Parameter Units Result Result RPD Qualifiers
Ethane ug/L 7.0 7.4 6
Ethene ug/L ND ND
Methane ug/L 766 859 11
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 31 of 51

aceAnalytical
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r
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] '
I
QC Batch: MERP/7277 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007, --
92224577008,92224577009,92224577010,92224577011,92224577012
METHOD BLANK: 1324927 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008, 92224577009, 92224577010, 92224577011, 92224577012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 11/07/1414:45
I I
LABORATORY CONTROL SAMPLE: 1324928
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.3 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1324929 1324930 _
MS MSD
92224577001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 1.5 1.4 61 58 75-125 5 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
it
Page 32 of 51

JaceAnalyticale
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1
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
DOT-504 34613.3.26
Pace Project No.:
92224577
QC Batch:
MPRP/17298
Analysis Method: EPA 6010
— QC Batch Method:
EPA3010
Analysis Description: 6010 MET
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012
METHOD BLANK:
1325309
Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Arsenic
ug/L
ND 10.0 11/08/14 01:31
Barium
ug/L
ND 5.0 11/08/14 01:31
Cadmium
ug/L
ND 1.0 11/08/14 01:31
Chromium
ug/L
ND 5.0 11/08/14 01:31
Lead
ug/L
ND 5.0 11/08/14 01:31
Selenium
ug/L
ND 10.0 11/08/14 01:31
Silver
ug/L
ND 5.0 11/08/14 01:31
LABORATORY CONTROL SAMPLE:
1325310
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Arsenic
ug/L
500
487
97
80-120
Barium
ug/L
500
496
99
80-120
Cadmium
ug/L
500
493
99
80-120
Chromium
ug/L
500
474
95
80-120
Lead
ug/L
500
498
100
80-120
Selenium
ug/L
500
509
102
80-120
Silver
ug/L
250
239
96
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1325311
1325313
MS
MSD
92224577001
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec % Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
500
498
100
100
75-125
0
Barium
ug/L
122
500
500
617
618
99
99
75-125
0
Cadmium
ug/L
ND
500
500
494
495
99
99
75-125
0
Chromium
ug/L
ND
500
500
474
478
95
96
75-125
1
Lead
ug/L
ND
500
500
489
488
98
97
75-125
0
Selenium
ug/L
ND
500
500
503
506
100
101
75-125
1
Silver
ug/L
ND
250
250
240
242
96
97
75-125
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 33 of 51

aceAnalytical
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f
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MSV/29222 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 601 by 6200B
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008, 92224577009, 92224577010, 92224577011, 92224577012, 92224577013
METHOD BLANK: 1328260 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012,92224577013
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane
ug/L
ND
1.0
1111211417:29
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
11/12/14 17:29
1,1,2-Trichloroethane
ug/L
ND
1.0
11/12/14 17:29
1,1-Dichloroethane
ug/L
ND
1.0
11/12/14 17:29
1,1-Dichloroethene
ug/L
ND
1.0
11/12/14 17:29
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
11/12/14 17:29
1,2-Dichlorobenzene
ug/L
ND
1.0
11/1211417:29
1,2-Dichloroethane
ug/L
ND
1.0
11112/1417:29
1,2-Dichloropropane
ug/L
ND
1.0
11/12/14 17:29
1,3-Dichlorobenzene
ug/L
ND
1.0
11112/1417:29
1,4-Dichlorobenzene
ug/L
ND
1.0
11112/1417:29
Bromodichloromethane
ug/L
ND
1.0
11/12/14 17:29
Bromoform
ug/L
ND
1.0
11/12/1417:29
Bromomethane
ug/L
ND
5.0
11/12/14 17:29
Carbon tetrachloride
ug/L
ND
1.0
11/12/14 17:29
Chlorobenzene
ug/L
ND
1.0
11/12/14 17:29
Chloroethane
ug/L
ND
1.0
11/12/14 17:29
Chloroform
ug/L
ND
1.0
11/12/14 17:29
Chloromethane
ug/L
ND
1.0
11/12/14 17:29
cis-1,2-Dichloroethene
ug/L
ND
1.0
11/1211417:29
cis-1,3-Dichloropropene
ug/L
ND
1.0
11/1211417:29
Dibromochloromethane
ug/L
ND
1.0
11/1211417:29
Dichlorodifluoromethane
ug/L
ND
1.0
11/12/14 17:29
Methylene Chloride
ug/L
ND
2.0
11/12/14 17:29
Tetrachloroethene
ug/L
ND
1.0
11/12/14 17:29
trans-1,2-Dichloroethene
ug/L
ND
1.0
11/12/14 17:29
trans-1,3-Dichloropropene
ug/L
ND
1.0
11/12/14 17:29
Trichloroethene
ug/L
ND
1.0
11/12/14 17:29
Trichlorofluoromethane
ug/L
ND
1.0
11/12/14 17:29
Vinyl chloride
ug/L
ND
1.0
11/12114 17:29
1,2-Dichloroethane-d4 (S)
%
97
70-130
11/12/14 17:29
4-Bromofluorobenzene (S)
%
95
70-130
11/12/14 17:29
Toluene-d8 (S)
%
100
70-130
11/12/14 17:29
LABORATORY CONTROL SAMPLE: 1328261
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 50 54.8 110 60-140
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 34 of 51

aceAnalyiical
www.pacelabs.com
_I
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
LABORATORY CONTROL SAMPLE: 1328261
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,2,2-Tetrachloroethane
ug/L
50
53.7
107
60-140
1,1,2-Trichloroethane
ug/L
50
54.4
109
60-140
1,1-Dichloroethane
ug/L
50
55.2
110
60-140
1,1-Dichloroethene
ug/L
50
48.3
97
60-140
1,2-Dibromoethane (EDB)
ug/L
50
56.4
113
60-140
1,2-Dichlorobenzene
ug/L
50
53.3
107
60A40
1,2-Dichloroethane
ug/L
50
47.5
95
60-140
1,2-Dichloropropane
ug/L
50
53.8
108
60-140
1,3-Dichlorobenzene
ug/L
50
54.1
108
60-140
1,4-Dichlorobenzene
ug/L
50
53.0
106
60-140
Bromodichloromethane
ug/L
50
51.2
102
60-140
Bromoform
ug/L
50
46:2
92
60-140
Bromomethane
ug/L
50
30.8
62
60-140
Carbon tetrachloride
ug/L
50
58.2
116
60-140
Chlorobenzene
ug/L
50
54.7
109
60-140
Chloroethane
ug/L
50
43.9
88
60-140
Chloroform
ug/L
50
49.8
100
60-140
Chloromethane
ug/L
50
38.5
77
60-140
c7is-1,2-Dichloroethene
ug/L
50
55.5
111
60-140
c7is-1,3-Dichloropropene
ug/L
50
57.1
114
60-140
Dibromochloromethane
ug/L
50
48.4
97
60-140
Dichlorodifluoromethane
ug/L
50
38.5
77
60-140
Methylene Chloride
ug/L
50
50.0
100
60-140
Tetrachloroethene
ug/L
50
52.1
104
60-140
trans-1,2-Dichloroethene
ug/L
50
48.7
97
60-140
trans-1,3-Dichloropropene
ug/L
50
58.7
117
60-140
Trichloroethene
ug/L
50
53.2
106
60-140
Trichlorofluoromethane
ug/L
50
37.3
75
60-140
Vinyl chloride
ug/L
50
45.6
91
60-140
1,2-Dichloroethane-d4 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1329104
1329105
MS
MSD
92224577013
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
1,1,1-Trichloroethane
ug/L
ND
20
20
21.7
22.3
109
111
60-140
2
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20
20.5
21.0
103
105
60-140
2
1,1,2-Trichloroethane
ug/L
ND
20
20
20.6
21.2
103
106
60-140
3
1,1-Dichloroethane
ug/L
ND
20
20
21.9
22.6
109
113
60-140
3
1,1-Dichloroethene
ug/L
ND
20
20
20.6
20.8
103
104
60-140
1
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
20.9
21.4
105
107
60-140
2
1,2-Dichlorobenzene
ug/L
ND
20
20
21.1
21.3
105
107
60-140
1
1,2-Dichloroethane
ug/L
ND
20
20
18.4
18.8
92
94
60-140
2
Results presented on this page are In
the units Indicated by the
"Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Qual
Page 35 of 51

aceAnalytical
www..pacelabs.com
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1329104
MS
92224577013
Spike
Parameter
Units Result
Conc.
1,2-Dichloropropane
ug/L
ND
20
1,3-Dichlorobenzene
ug/L
ND
20
1,4-Dichlorobenzene
ug/L
ND
20
Bromodichloromethane
ug/L
ND
20
Bromoform
ug/L
ND
20
Bromomethane
ug/L
ND
20
Carbon tetrachloride
ug/L
ND
20
Chlorobenzene
ug/L
ND
20
Chloroethane
ug/L
ND
20
Chloroform
ug/L
ND
20
Chloromethane
ug/L
ND
20
cis-1,2-Dichloroethene
ug/L
ND
20
cis-1,3-Dichloropropene
ug/L
ND
20
Dibromochloromethane
ug/L
ND
20
Dichlorodifluoromethane
ug/L
ND
20
Methylene Chloride
ug/L
ND
20
Tetrachloroethene
ug/L
ND
20
trans-1,2-Dichloroethene
ug/L
ND
20
trans-1,3-Dichloropropene
ug/L
ND
20
Tiichloroethene
ug/L
ND
20
Trichlorofluoromethane
ug/L
ND
20
Vinyl chloride
ug/L
ND
20
1,2-Dichloroethane-d4 (S)
%
4-Bromofluorobenzene (S)
%
Toluene-d8 (S)
%
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100 -
Huntersville, NC 28078
[phone]
MSD
Spike
Conc.
1329105
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
20
20.8
20.8
104
104
60-140
0
20
21.4
22.0
107
110
60-140
2
20
21.3
21.6
106
108
60-140
2
20
18.7
19.3
93
97.
60-140
4
20
16.4
16.6
82
83
60-140
1
20
14.1
14.3
70
72
60-140
2
20
22.5
22.9
113
114
60-140
2
20
21.4
21.8
107
109
60-140
2
20
18.7
18.9
94
95
60-140
1
20
19.5
20.0
97
100
60-140
3
20
15.4
16.6
77
83
60-140
8
20
21.7
22.5
108
112
60-140
4
20
20.7
20.9
103
105
60-140
1
20
17.4
17.9
87
89
60-140
3
20
17.1
17.8
85
89
60-140
4
20
16.0
17.2
80
86
60-140
8
20
20.7
21.1
103
105
60-140
2
20
19.4
20.2
97
101
60-140
4
20
21.1
21.4
105
107
60-140
1
20
20.8
21.2
104
106
60-140
2
20
16.8
17.3
84
87
60-140
3
20
19.1
19.9
95
99
60-140
4
92
92
70-130
100
99
70-130
99
98
70-130
Qual
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 36 of 51

1�5acmnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WET/34204 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008
METHOD BLANK: 1326942 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 11/11/1414:20
LABORATORY CONTROL SAMPLE: 1326943
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.49 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1326944 1326945
MS MSD
92224134002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Sulfide mg/L ND .5 .5 0.48 0.48 95 95 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1326946
MS
92224598013 Spike
Parameter Units Result Conc.
Sulfide mg/L ND .5
1326947
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qual
5 0.48 0.48 95 95 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result
Date: 11/19/2014 05:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
withoutthe written consent of Pace Analytical Services, Inc..
Page 37 of 51

aceAnalytical
www.pacerabs.coin
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WET/34233 Analysis Method: SM 4500-S213
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92224577009, 92224577010, 92224577011, 92224577012
METHOD BLANK: 1327952 Matrix: Water
Associated Lab Samples: 92224577009, 92224577010, 92224577011, 92224577012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 11112/1416:20
Pace Analytical Services, Inc.
i
9800 KinceyAve. Suite 100 _
Hunlersville, NC 28078
[phone] ti
1 '
LABORATORY CONTROL SAMPLE: 1327953
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.52 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1327954
MS
92224577009 Spike
Parameter Units Result Conc.
Sulfide mg/L ND .5
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1327956
MS
92224598019 Spike
Parameter Units Result Conc.
Sulfide mg/L ND .5
1327955
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD
.5 0.48 0.48 93 93 90-110 0
1327957
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD
.5 0.46 0.46 92 92 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Qual
Qual
� I
I
!
Page 38 of 51

Pace Analytical Services, Inc.
ane /i na'yrna/ 9800 uncey Ave. Suite 100
078
vli/if! !V 1 Huntersville, NC 28078
www.pacelabs.com
i
_ [phone]
i
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WETA/20850 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012
I.
METHOD BLANK: 1325952 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010,92224577011,92224577012
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 2.0 11/08/14 23:00
LABORATORY CONTROL SAMPLE: 1325953
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 20 18.8 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325954
MS MSD
92223050002 Spike Spike
Parameter Units Result Conc. Conc.
Sulfate mg/L 172 20 20
1325955
MS MSD MS MSD % Rec
Result Result % Rec % Rec Limits RPD Qual
182 180 48 39 90-110 1 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325956 1325957
MS MSD
92224577003 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 69.3 20 20 84.7 84.8 77 78 90-110 0 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 39 of 51

aceAnalytical
www.pacelabs.com
I
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] --;
I I
QC Batch: WETA/20820 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010
METHOD BLANK: 1324737 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.020 11/07/14 01:15
LABORATORY CONTROL SAMPLE: 1324738
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 2.5 2.6 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1324739 1324740
MS MSD
92224461002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Nitrate mg/L 22.9 2.5 2.5 23.4 23.4 19 19 90-110 0 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1324741 1324742
MS MSD
92224577001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.4 2.4 97 97 90-110 0
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 40 of 51

Pace Analytical Services, Inc.
® 9800 Kincey Ave. Suite 100
acie 'nal! `ical Huntersville, NC 28078
www.pacelabs.com
_ [phone]
I
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WETA/20832 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92224577011
METHOD BLANK: 1325285 Matrix: Water
Associated Lab Samples: 92224577011
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.020 11/07/14 15:12
LABORATORY CONTROL SAMPLE: 1325286
Spike
LCS
LCS
% Rec
Parameter Units
Conc..
Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate mg/L
2.5
2.5
102
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325287
1325288
MS
MSD
92224526006
Spike
Spike MS
MSD
MS MSD % Rec
Parameter Units Result
Conc.
Conc. Result
Result
% Rec % Rec Limits RPD
Nitrogen, Nitrate mg/L 0.12
2.5
2.5 2.7
2.7
103 103 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325289
MS
92224526002 Spike
Parameter Units Result Conc.
Nitrogen, Nitrate mg/L 0.31 2.5
Qual
1325290
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qual
2.5 3.0 3.0 107 107 90-110 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 41 of 51

aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WETA/20833
QC Batch Method: EPA 353.2
Associated Lab Samples: 92224577012
METHOD BLANK: 1325298
Associated Lab Samples: 92224577012
Parameter Units
Nitrogen, Nitrate mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 353.2
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.020 11/07/1415:55
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 L _'
Huntersville, NC 28078
[phone]
I
1'
1 i
i
LABORATORY CONTROL SAMPLE: 1325299
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Nitrate mg/L 2.5 2.5 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325300 1325301
MS MSD
92224577012 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Nitrate mg/L ND 2.5 2.5 2.5 2.5 99 99 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
Page 42 of 51

Pace Analytical Services, Inc.
® 9800 Kincey Ave. Suite 100
aceAnalyiical
Huntersville, NC 28078
www.pacelabs.com
_ [phone]
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WETA120849 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: 5310E TOC
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010
METHOD BLANK: 1325932 Matrix: Water
Associated Lab Samples: 92224577001, 92224577002, 92224577003, 92224577004, 92224577005, 92224577006, 92224577007,
92224577008,92224577009,92224577010
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 11/08/14 18*49
LABORATORY CONTROL SAMPLE: 1325933
-- Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Total Organic Carbon mg/L 25 24.6 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325934
1325935
MS
MSD
92224273001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Total Organic Carbon mg/L 3.8 25
25
27.7
27.5
96
95
90-110
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1325936
1325937
MS
MSD
92224577001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Total Organic Carbon mg/L 46.1 25
25
63.0
62.5
68
66
90-110
1 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 11/19/2014 05:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 43 of 51

1eAnalytical"
www..pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
QC Batch: WETA/20868
QC Batch Method: SM 5310B
Associated Lab Samples: 92224577011, 92224577012
METHOD BLANK: 1327747
Associated Lab Samples: 92224577011, 92224577012
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 1327748
Parameter Units
Total Organic Carbon mg/L
I
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
I
I
,I
1"
i
I
I
I
i
.. i
i
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1327749 1327750
MS MSD
92224577011 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L 17.4 25 25 31.5 31.0 56 55 90-110 1 M1
QUALITY CONTROL DATA
Analysis Method: SM 5310B
Analysis Description: . 5310B TOC
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 11/11/14 19:17
Spike LCS
Conc. Result
25 25.4
LCS % Rec
% Rec Limits
102 90-110
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc..
I
Page 44 of 51
i

Pace Analytical Services, Inc.
aceAnalytical ® 9800 Kincey Ave. Suite 100
_ Hunlersville, NC 28078
www.pacelabs.com [phone]
I�
QUALIFIERS
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
- 1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-M Pace Analytical Services - Minneapolis
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
Date: 11/19/2014 05:39 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 45 of 51

aceAnalytical
wvnvpacelabs.com
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92224577001
DMW-10
RSK 175
AIR/21799
92224577002
SMW-2
RSK 175
AIR/21799
92224577003
DMW-2
RSK 175
AIR/21799
92224577004
DMW-11
RSK 175
AIR/21799
92224577005
SMW-1
RSK 175
AIR/21799
92224577006
DMW-6
RSK 175
AIR/21799
92224577007
DMW-9
RSK 175
AIR/21799
92224577008
DMW-8
RSK 175
AIR/21799
92224577009
SMW-3
RSK 175
AIR/21799
92224577010
DMW-7
RSK 175
AIR/21799
92224577011
DMW-1
RSK 175
AIR/21799
92224577012
DMW-4
RSK 175
AIR/21799
92224577001
DMW-10
EPA 3010
MPRP/17298
EPA 6010
ICP/15590
92224577002
SMW-2
EPA 3010
MPRP/17298
EPA 6010
ICP/15590
92224577003
DMW-2
EPA 3010
MPRP/17298
EPA 6010
ICP/15590
92224577004
DMW-11
EPA 3010
MPRP/17298
EPA 6010
ICP/15590
92224577005
SMW-1
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224677006
DMW-6
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577007
DMW-9
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577008
DMW-8
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577009
SMW-3
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577010
DMW-7
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577011
DMW-1
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577012
DMW-4
EPA 3010
MPRP/17298
EPA6010
ICP/15590
92224577001
DMW-10
EPA7470
MERP/7277
EPA7470
MERC/6995
92224677002
SMW-2
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577003
DMW-2
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577004
DMW-11
EPA7470
MERP/7277
EPA7470
MERC/6995
92224677005
SMW-1
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577006
DMW-6
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577007
DMW-9
EPA 7470
MERP/7277
EPA 7470
MERC/6995
92224577008
DMW-8
EPA 7470
MERP/7277
EPA 7470
MERC/6995
92224577009
SMW-3
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577010
DMW-7
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577011
DMW-1
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577012
DMW-4
EPA7470
MERP/7277
EPA7470
MERC/6995
92224577001
DMW-10
SM 6200B
MSV/29222
92224577002
SMW-2
SM 6200B
MSV/29222
92224677003
DMW-2
SM 6200B
MSV/29222
92224577004
DMW-11
SM 6200B
MSV/29222
92224577005
SMW-1
SM 6200B
MSV/29222
92224577006
DMW-6
SM 6200B
MSV/29222
92224577007
DMW-9
SM 6200E
MSV/29222
92224577008
DMW-8
SM 6200B
MSV/29222
92224577009
SMW-3
SM 6200B
MSV/29222
92224577010
DMW-7
SM 6200B
MSV/29222
92224577011
DMW-1
SM 6200E
MSV/29222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 46 of 51

- 5acmnalydcal
www.pacelabs.com
Ir
i
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
Project:
Pace Project No.:
QUALITY
DOT-504 34613.3.26
92224577
CONTROL DATA CROSS REFERENCE TABLE
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92224577012
DMW-4
SM 6200B
MSV/29222
92224577013
WSW-4
SM 6200B
MSV/29222
92224577001
DMW-10
SM 4500-S2D
WET/34204
92224577002
SMW-2
SM 4500-S2D
WET/34204
92224577003
DMW-2
SM 4500-S2D
WET/34204
92224577004
DMW-11
SM 4500-S2D
WET/34204
92224677005
SMW-1
SM 4500-S2D
WET/34204
92224577006
DMW-6
SM 4500-S2D
WET/34204
92224577007
DMW-9
SM 4500-S2D
WET/34204
92224577008
DMW-8
SM 4500-S2D
WET/34204
92224577009
SMW-3
SM 4500-S2D
WET/34233
92224577010
92224577011
DMW-7
DMW-1
SM 4500-S2D
SM 4500-S2D
WET/34233
WET/34233
92224577012
DMW-4
SM 4500-S2D
WET/34233
92224577001
DMW-10
EPA 300.0
WETA120850
92224577002
SMW-2
EPA 300.0
WETA/20850
92224577003
DMW-2
EPA 300.0
WETA/20850
92224577004
DMW-11
EPA 300.0
WETA/20850
92224577006
SMW-1
EPA 300.0
WETA/20850
92224577006
DMW-6
EPA 300.0
WETA/20850
92224577007
DMW-9
EPA 300.0
WETA/20850
92224577008
DMW-8
EPA 300.0
WETA/20850
92224577009
SMW-3
EPA 300.0
WETA/20850
92224677010
DMW-7
EPA 300.0
WETA/20850
92224577011
DMW-1
EPA 300.0
WETA/20850
92224577012
DMW-4
EPA 300.0
WETA120850
92224577001
DMW-10
EPA 353.2
WETA120820
92224577002
SMW-2
EPA 353.2
WETA/20820
92224577003
DMW-2
EPA 353.2
WETA120820
92224577004
DMW-11
EPA 353.2
WETA120820
92224577005
SMW-1
EPA 353.2
WETA/20820
92224577006
DMW-6
EPA 353.2
WETA/20820
92224577007
DMW-9
EPA 353.2
WETA/20820
92224577008
DMW-8
EPA 353.2
WETA/20820
92224577009
SMW-3
EPA 353.2
WETA/20820
92224577010
DMW-7
EPA 353.2
WETA/20820
92224577011
DMW-1
EPA 353.2
WETA/20832
92224677012
DMW-4
EPA 353.2
WETA/20833
92224577001
DMW-10
SM 5310B
WETA/20849
92224577002
SMW-2
SM 5310B
WETA/20849
92224577003
DMW-2
SM 5310B
WETA/20849
92224677004
DMW-11
SM 5310B
WETA/20849
92224677005
SMW-1
SM 5310B
WETA/20849
92224577006
DMW-6
SM 5310E
WETA/20849
92224577007
DMW-9
SM 5310B
WETA/20849
j REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/19/2014 05:39 PM without the written consent of Pace Analytical Services, Inc.. Page 47 of 51

aceAnalytical
www.pacelabs.com
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: DOT-504 34613.3.26
Pace Project No.: 92224577
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 _
Huntersville, NC 28078
[phone]
I�
Analytical
Lab ID
Sample ID
QC Batch Method QC Batch Analytical Method
Batch
92224577008
DMW-8
SM 5310E WETA/20849
92224577009
SMW-3
SM 5310B WETA/20849
92224577010
DMW-7
SM 5310B WETA/20849
92224577011
DMW-1
SM 5310E WETA/20868
92224577012
DMW-4
SM 5310B WETA/20868
j
}
REPORT OF LABORATORY ANALYSIS
i I
I
This report shall not be reproduced, except in full,
—'
Date: 11/19/2014 05:39 PM
without the written consent of Pace Analytical Services, Inc..
Page 48 of 51
1 '

(1R56A1l,11y11C,?1*
wn rcecer r sc;U" Page 1 of 2
Number: Issuing Authority:
103-rev.15 _Pace Huntersvillp r)nnlii%
t
Client Name: [4url-
i�
Courier: . ❑ Fed Ex ❑ UPS❑ USPS❑ Client:, Co rfiercial❑ Other
Custody Seal on Cooler/Box Present: ❑ yes :: no Seals intact: El yes ❑ no
I.
Packing Material: a ubble V❑p ❑ Bubble Ba ffi; ❑ None ❑ Other
Office
Thermometer Used: IR Gun Type of Ice:�/II�V Blue None ©' aS�m les on ice, cooling g p y process has begun
Temp Correction Factor T1401 No Correction':<
Corrected Cooler Temp.: % •C
Biological Tissue is Frozen: Yes No NIA
Date and Initials of pQr�son examining
Temp should be above freezing to 6°C
i
. Comments:
contents: (iL/ UI ' 6 C�
Chain of Custody Present:
�. es ❑No
❑NIA
1,
Chain of Custody Filled Out:
C . os o
❑N►A
2.
Chain of Custody Relinquished:
E:fes too
❑NIA
3.
4,
5.
Sampler Name & Signature on COC:Yes ❑No
❑NIA
Samples Arrived within Hold Time: as No
❑N/A
Short Hold Time Analysis (<72hr):
.yes ❑No
❑N/A
6.
Rush Turn Around Time Requested:
lit es o . ❑N/A
7,
Sufficient Volume:
y"
.,Kes No [IN
All / xc
$, /
Correct Containers Used:
e
es No
❑N/A
g,
-Pace Containers Used:es
❑No
❑N/A
Containers Intact:
C9'es ❑No
❑N/A
10.
Filtered volume received for Dissolved tests
GvYes ❑No
[3 /A
11.
Sample Labels match COC:
❑No
❑NIA
12.
gyres
-includes date/time/ID/Analysis Matrix:
,
'
All containers needing preservation have been checked.
13.
C es ON,
❑NIA
All containers needing preservation are found to be in
r ❑No
compliance with EPA recommendation.
es
❑NIA
exceptions: VOA, coliform, TOG, 0&G, !fill-DRO (water)
iP- Ye�s .
Samples checked for dechlorination:
-❑1No
C� es1'r ❑No ❑wA
14.
Headspace in VOA Vials (>6mm):
QYes ©n . ❑N/A
15.
Trip Blank Present:
gYes ❑No
12 oft,
6,
Trip Blank Custody Seals Present
l,JYes ❑No
❑N/A
Pace Trip Blank Lot # (if purchased):
+�
Client Notification/ Resolution: I!
� Field Data Required? Y / N
Person Contacted: ° `
t; :Date/Time:
Comments/ Resolution:
SCURF Review:
Date:
SRF Review: AisadiEE]
Date: !;f. // 7Note: Whenever thscrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North C I•olina DEHNR
Certification Office (i.e out of hold, Incorrect preservadv'e, out of temp,
Incorrect containers)
i;
IV
n
W0#A:92224577
IIIAI�IINIV�
Page 49 of 51

— ----- -- --- ----
CHAIN -OF -CUSTODY ! Analytical Request Document
r/ '�eeAnalytleal The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
www.i)acelabs.com
Section A Section B Section C
Page: ofB
`
Required Client Information: Required Projcet Information: Invoice Information:
Company: • Report To: Attention:
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Address:
Copy To:
Company Name: '' t�
REGULATORY AGENCY
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Address:
j- NPDES GROUND WATER r- DRINKING WATER
UST j RCRA r OTHER
Email Te/��
3'LrlA�{-i ,�J. � �ticiClGtu,.et,L•C'-V
Purchase Order No.:
Paw Quote
Rotaronea: -
Phone:
-
0 : GG-%'s
Fax: Project
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Name:
Paw Project
Manager.
Site Location
STATE.,
/VC—
Requested Due DatelTAT: � Project
Number. ` 5 d 4
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P3004CM ` � . Q, 11,(p
Requested
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Filtered
(Y/N)
Section D Matrix Codes
E.
RoqulrodCtionl Information MATRIX I CODE
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COLLECTED
Preservatives
Y
Drinking Water OW
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waste Water WW
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CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Page: of 1
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1�5a'cmnalytical'
www.pacelabs.com
February 11, 2015
Chemical Testing Engineer
NCDOT
Materials & Tests Unit
1801 Blue Ridge Road
Raleigh, NC 27607
RE: Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Dear Chemical Engineer:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on February 04, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
�J,,,-- -
Kevin Godwin
[e-mail]
Project Manager
Enclosures
�Q NCCRFO�
lfge0 pS��1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 40

aceAnalytical
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Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Minnesota Certification IDs
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CERTIFICATIONS
55414 Minnesota Certification M 027-053-137
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REPORT'OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 2 of 40

aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
- Lab ID Sample ID
92236396001 DMW-10
92236396002 DMW-6
92236396003 DMW-7
92236396004 DMW-9
92236396005 DMW-8
SAMPLE ANALYTE COUNT
Method
RSK 175
EPA 6010
EPA 7470
SM 6200B
SM 4500-S2D
EPA 300.0
EPA 353.2
SM 5310B
RSK 175
EPA 6010
EPA 7470
SM 6200B
SM 4500-S21)
EPA 300.0
EPA 353.2
SM 5310E
RSK 175
EPA 6010
EPA 7470
SM 6200B
SM 4500-S2D
EPA 300.0
EPA 353.2
SM 5310E
RSK 175
EPA 6010
EPA 7470
SM 6200B
SM 4500-S2D
EPA 300.0
EPA 353.2
SM 5310B
RSK 175
EPA 6010
EPA 7470
SM 6200B
SM 4500-S21)
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analysts
Analytes
Reported
Laboratory
JRB
3
PASI-M
JMW
7
PASI-A
HVK
1
PASI-A
CAH
33
PASI-C
JTJ
1
PASI-A
AES2
1
PASI-A
DMN
1
PASI-A
AES2
1
PASI-A
JRB
3
PASI-M
JMW
7
PASI-A
HVK
1
PASI-A
CAH
33
PASI-C
JTJ
1
PASI-A
AES2
1
PASI-A
DMN
1
PASI-A
AES2
1
PASI-A
JRB
3
PASI-M
JMW
7
PASI-A
HVK
1
PASI-A
CAH
33
PASI-C
JTJ
1
PASI-A
AES2
1
PASI-A
DMN
1
PASI-A
AES2
1
PASI-A
JRB
3
PASI-M
JMW
7
PASI-A
HVK
1
PASI-A
CAH
33
PASI-C
JTJ
1
PASI-A
AES2
1
PASI-A
DMN
1
PASI-A
AES2
1
PASI-A
JRB
3
PASI-M
JMW
7
PASI-A
HVK
1
PASI-A
CAH
33
PASI-C
JTJ
1
PASI-A
Page 3 of 40

acmnalytical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92236396006
DMW-11
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S21D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92236396007
DMW-2
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S2D
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92236396008
DMW-1
RSK 175
JRB
3
PASI-M
EPA6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S21)
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92236396009
DMW-3
RSK 175
JRB
3
PASI-M
EPA 6010
JMW
7
PASI-A
EPA 7470
HVK
1
PASI-A
SM 6200B
CAH
33
PASI-C
SM 4500-S21)
JTJ
1
PASI-A
EPA 300.0
AES2
1
PASI-A
EPA 353.2
DMN
1
PASI-A
SM 5310B
AES2
1
PASI-A
92236396010
WSW-4
SM 6200B
CAH
33
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 40

i
1�5acmnalytical"
r www.pacelabs.com
L
_ Project: DOT 504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-10
Parameters
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396001 Collected: 02/03/15 11:50 Received: 02104/1516:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
RSK 175 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
02/06/15 17:53
74-84-0
Ethene
33.6 ug/L
6.2
1
02/06/15 17:53
74-85-1
Methane
664 ug/L
6.6
1
02/06/15 17:53
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
02/05/15 15:45
02/06/15 02:43
7440-38-2
Barium
282 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:43
7440-39-3
Cadmium
ND ug/L
1.0
1
02/05/15 15:45
02/06/15 02:43
7440-43-9
Chromium
45.7 ug/L
5.0
1
02/05/1515:45
02/06/15 02:43
7440-47-3
Lead
22.1 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:43
7439-92-1
Selenium
ND ug/L
10.0
1
02/05/15 15:45
02/06/15 02:43
7782-49-2
Silver
ND ug/L
5.0
1
02/05/15 15:45
02/06/15 02:43
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
02/06/15 12:45
02/06/15 16:40
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
-
1,1-Dichloroethane
ND ug/L
1.0
1
02/11/15 09:52
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
02/11/15 09:52
75-35-4
1,1,1-Tichloroethane
ND ug/L
1.0
1
02/11/15 09:52
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
02/11/15 09:52
79-00-5
- 1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
02111/1509:52
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
02/11/16 09:52
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
02/11/15 09:52
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
02/11/15 09:52
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 09:52
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 09:52
106-46-7
Bromodichloromethane
ND ug/L
1.0
1
02/11/15 09:52
75-27-4
Bromomethane
ND ug/L
5.0
1
02/11/15 09:52
74-83-9
Bromoform
ND ug/L
1.0
1
02/11/15 09:52
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 09:52
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 09:52
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
02/11115 09:52
56-23-5
Chlorobenzene
ND ug/L
1.0
1
02/11/15 09:52
108-90-7
Chloroethane
ND ug/L
1.0
1
02/11/15 09:52
75-00-3
Chloroform
ND ug/L
1.0
1
02/11/15 09:52
67-66-3
Chloromethane
ND ug/L
1.0
1
02/11/15 09:52
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
02/11/15 09:52
12448-1
Dichlorodifluoromethane
ND ug/L
1.0
1
02/11/15 09:52
75-71-8
Methylene Chloride
ND ug/L
2.0
1
02/11/15 09:52
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 09:52
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 09:52
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
02/11/15 09:52
127-18-4
Trichloroethene
ND ug/L
1.0
1
02/11/15 09:52
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
02/11/15 09:52
75-69-4
Vinyl chloride
ND ug/L
1.0
1
02/11/15 09:52
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 5 of 40

aceAnalytical
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Project: DOT 504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-10
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310E TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 _
Huntersville, NC 28078
[phone] -,
i
;I
Lab ID: 92236396001 Collected: 02/03/1511:50 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
Analytical
Analytical
Analytical
Analytical
1.0
1
02/11/15 09:52
106-93-4
105 %
70-130
1
02/11/15 09:52
460-00-4
106 %
70-130
1
02/11/15 09:52
17060-07-0
101 %
70-130
1
02/11/15 09:52
2037-26-5
Method: SM 4500-S2D
0.25 mg/L
0.10
1
02/06/15 16:45
18496-25-8
Method: EPA 300.0
19.0 mg/L
2.0
1
02/06/15 15:09
14808-79-8
Method: EPA 353.2
ND mg/L
0.020
1
02/05/15 00:17
Method: SM 5310B
18.6 mg/L
1.0
1
02/05/15 18:33
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 40

it I
1�5aneAnalytical
www.pacelabs.com
Ir
I
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-6
Parameters
RSK 175 AIR Headspace
Ethane
Ethene
Methane
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury
Mercury
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396002 Collected: 02/03/15 12:30 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: RSK 175
ND ug/L
6.2
1
02/06/15 18:00 74-84-0
61.6 ug/L
6.2
1
02/06/15 18:00
74-85-1
674 ug/L
6.6
1
02/06/15 18:00
74-82-8
Analytical Method: EPA 6010 Preparation Method: EPA 3010
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 02:46
7440-38-2
172 ug/L
5.0
1
02/05/15 15:45 02/06/15 02:46
7440-39-3
ND ug/L
1.0
1
02/05/15 15:45 02/06/15 02:46
7440-43-9
20.3 ug/L
5.0
1
02/05/15 15:45 02/06/15 02:46
7440-47-3
8.9 ug/L
5.0
1
02/05/15 15:45 02/06/15 02:46
7439-92-1
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 02:46
7782-49-2
ND ug/L
5.0
1
02/05/15 15:45 02/06/15 02:46
7440-22-4
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L
0.20
1
02106/1512:45 02/0611516:43
7439-97-6
Analytical Method: SM 6200B
42.3 ug/L
1.0
1
02111/1512:25
75-34-3
55.0 ug/L
1.0
1
02/11/15 12:25
75-35-4
1.5 ug/L
1.0
1
` 02/11/15 12:25
71-55-6
ND ug/L
1.0
1
02111/1512:25
79-00-5
ND ug/L
1.0
1
02/11/15 12:25
79-34-5
ND ug/L
1.0
1
02/11/15 12:25
95-50-1
ND ug/L
1.0
1
02/11/15 12:25
107-06-2
ND ug/L
1.0
1
02/11/15 12:25
78-87-5
ND ug/L
1.0
1
02/11/15 12:25
541-73-1
ND ug/L
1.0
1
02/11/15 12:25
106-46-7
ND ug/L
1.0
1
02/11/15 12:25
75-27-4
ND ug/L
5.0
1
02111/1512:25
74-83-9
ND ug/L
1.0
1
02/11/15 12:25
75-25-2
2.7 ug/L
1.0
1
02/11/15 12:25
156-59-2
ND ug/L
1.0
1
02/11/15 12:25
10061-01-5
ND ug/L
1.0
1
02/11/15 12:25
56-23-5
ND ug/L
1.0
1
02/11/15 12:25
108-90-7
ND ug/L
1.0
1
02/11/15 12:25
75-00-3
ND ug/L
1.0
1
02111 /15 12:25
67-66-3
ND ug/L
1.0
1
02/11/15 12:25
74-87-3
ND ug/L
1.0
1
02/11/15 12:25
124-48-1
ND ug/L
1.0
1
02/11/15 12:25
75-71-8
ND ug/L
2.0
1
02/11/15 12:25
75-09-2
ND ug/L
1.0
1
02111/1512:25
156-60-5
ND ug/L
1.0
1
02111/1512:25
10061-02-6
ND ug/L
1.0
1
02/11/15 12:25
127-18-4
41.8 ug/L
1.0
1
02/11/15 12:25
79-01-6
ND ug/L
1.0
1
02/11/15 12:25
75-69-4
ND ug/L
1.0
1
02/11/15 12:25
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qua[
Page 7 of 40

aceAnalytical
www.pacelabs.00m
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-6
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 —
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396002 Collected: 02/03/15 12:30
Received: 02/04/15 16:28 Matrix: Water
I
Results Units
Report Limit DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
ND ug/L
1.0 1
02/11/1512:25
106-93-4
105 %
70-130 1
02111/1512:25
460-00-4
110 %
70-130 1
02/11/15 12:25
17060-07-0
100 %
70-130
1
02111 /15 12:25 2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
02/05/15 11:00 18496-25-8
Analytical Method: EPA 300.0
45.3 mg/L
4.0
2
02/06/15 15:50 14808-79-8
Analytical Method: EPA 353.2
ND rrg/L
0.020
1
02/05/15 00:18
Analytical Method: SM 5310B
8.7 mg/L
1.0
1
02/05/15 18:44 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 40

i !
1�5aneAnalydcal
www..pacelabs.com
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-7
Parameters
Lab ID: 92236396003 Collected: 02/03/15 13:10
Results Units Report Limit DF
Received: 02/04/15 16:28 Matrix: Water
Prepared Analyzed CAS No. Qual
RSK 175 AIR Headspace
Analytical Method: RSK 175
Ethane
ND ug/L
6.2
1
02/06/1518:06
74-84-0
Ethene
ND ug/L
6.2
1
02/06/1518:06
74-85-1
Methane
ND ug/L
6.6
1
02106/1518:06
74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
02/05/15 15:45
02/06/15 02:50
7440-38-2
Barium
42.7 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:50
7440-39-3
Cadmium
ND ug/L
1.0
1
02105/1515:45
02/06/15 02:50
7440-43-9
Chromium
6.2 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:50
7440-47-3
Lead
ND ug/L
5.0
1
02/05/15 15:45
02/06/15 02:50
7439-92-1
Selenium
ND ug/L
10.0
1
02/05/15 15:45
02/06/15 02:50
7782-49-2
Silver
ND ug/L
5.0
1
02/05/15 15:45
02/06/15 02:50
7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
02/06/1512:45
02/0611516:51
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
02/11/15 10:09
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
02/11/15 10:09
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
02/11/15 10:09
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
02111/1510:09
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
02/11/15 10:09
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 10:09
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
02/11/15 10:09
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
02/11/15 10:09
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
02/1111510:09
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 10:09
106A6-7
Bromodichloromethane
ND ug/L
1.0
1
02/11/15 10:09
75-274
Bromomethane
ND ug/L
5.0
1
02/11/15 10:09
74-83-9
Bromoform
ND ug/L
1.0
1
02/11/15 10:09
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 10:09
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
02111/1510:09
10061-01-5
Carbon tetrachloride
ND uglL
1.0
1
02/11/15 10:09
56-23-5
Chlorobenzene
ND ug/L
1.0
1
02/11/15 10:09
108-90-7
Chloroethane
ND ug/L
1.0
1
02/11/15 10:09
75-00-3
Chloroform
ND ug/L
1.0
1
02/11/15 10:09
67-66-3
Chloromethane
ND ug/L
1.0
1
02/11/15 10:09
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
02/11/15 10:09
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
02/11/15 10:09
75-71-8
Methylene Chloride
ND ug/L
2.0
1
02/11/15 10:09
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 10:09
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
02111/1510:09
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
02/11/15 10:09
127-18-4
Trichloroethene
ND ug/L
1.0
1
02/11/15 10:09
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
02/11/15 10:09
75-69-4
Vinyl chloride
ND ug/L
1.0
1
02/11/15 10:09
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc.. Page 9 of 40

acmnalytical
www..pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-7
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
r-
Lab ID: 92236396003 Collected: 02/03/15 13:10 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit
Analytical
Analytical
Analytical
Analytical
Analytical
DF
Prepared Analyzed
CAS No. Qua[
Method: SM 6200B
ND ug/L
1.0
1
02/11/15 10:09
106-93-4
104 %
70-130
1
02/11/1510:09
460-00-4
108 %
70-130
1
02111/1510:09
17060-07-0
100 %
70-130
1
02/11/1510:09
2037-26-5
Method: SM 4500-S2D
ND mg/L
0.10
1
02106/1516:45
18496-25-8
Method: EPA 300.0
118 mg/L
10.0
5
02/07/15 01:34
14808-79-8
Method: EPA 353.2
0.63 mg/L
0.020
1
02/05/15 00:22
Method: SM 5310B
3.4 mg/L
1.0
1
02/05/15 18:57
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 40

laneAnalytical
www..pacelabs.com
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-9
Parameters
Lab ID: 92236396004 Collected: 02/03/15 13:50
Results Units Report Limit DF
Received: 02/04/15 16:28 Matrix: Water
Prepared Analyzed CAS No.
RSK 175 AIR Headspace
Analytical Method: RSK 175
- Ethane
ND ug/L
6.2
1
02/06/15 18:21
74-84-0
Ethene
ND ug/L
6.2
1
02/06/15 18:21
74-85-1
Methane
1010 ug/L
6.6
1
02/06/15 18:21
74-82-8
+ 6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
02/05/15 15:45
02/06/15 02:53
7440-38-2
Barium
896 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:53
7440-39-3
Cadmium
1.1 ug/L
1.0
1
02/05/1515:45
02/06/15 02:53
7440-43-9
Chromium
209 ug/L
5.0
1
02/05/15 15:45
02/06/15 02:53
7440-47-3
Lead
32.0 ug/L.
5.0
1
02/05/15 15:45
02/06/15 02:53
7439-92-1
Selenium
10.0 ug/L
10.0
1
02/05115 15:45
02/06/15 02:53
7782-49-2
Silver
ND ug/L
5.0
1
02/05/15 15:45
02/06/15 02:53
7440-22-4
7470 Mercury
Analytical Method: EPA7470 Preparation Method: EPA7470
Mercury
0.47 ug/L
0.20
1
02/06/15 12:45
02/06/15 16:54
7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
3.0 ug/L
1.0
1
02/11/15 10:26
75-34-3
1,1-Dichloroethene
1.5 ug/L
1.0
1
02/11/15 10:26
75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
02/11/15 10:26
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
02/1111510:26
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
02/11/15 10:26
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 10:26
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
02/11/15 10:26
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
02/11/15 10:26
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 10:26
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
02/1111510:26
106A6-7
Bromodichloromethane
ND ug/L
1.0
1
02/11/15 10:26
75-27A
Bromomethane
ND ug/L
5.0
1
02/11/15 10:26
74-83-9
Bromoform
ND ug/L
1.0
1
02/11/15 10:26
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 10:26
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 10:26
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
02/11/15 10:26
56-23-5
Chlorobenzene
ND ug/L
1.0
1
02/11/15 10:26
108-90-7
Chloroethane
ND ug/L
1.0
1
02/11/15 10:26
75-00-3
Chloroform
ND ug/L
1.0
1
02/11/15 10:26
67-66-3
Chloromethane
ND ug/L
1.0
1
02111/1510:26
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
02/11/15 10:26
124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
02/11/15 10:26
75-71-8
Methylene Chloride
ND ug/L
2.0
1
02/11/15 10:26
75-09-2
_ trans-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 10:26
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 10:26
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
02/11/15 10:26
127-18-4
Trichloroethene
2.2 ug/L
1.0
1
02111/1510:26
79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
02/11/15 10:26
75-69-4
Vinyl chloride
ND ug/L
1.0
1
02/11/15 10:26
75-01-4
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 11 of 40

5ac ie A na ly Acal
t www.pacelabs.com
I
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] -
Sample: DMW-9
Parameters
Lab ID: 92236396004 Collected: 02/03/1513:50
Results Units Report Limit DF
Received: 02/04/15 16:28 Matrix: Water
Prepared Analyzed CAS No. Qual
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
02/11/15 10:26
106-93-4
Surrogates
4-Bromofluorobenzene (S)
105 %
70-130
1
02/11/15 10:26
460-00-4
1,2-Dichloroethane-d4 (S)
110 %
70-130
1
02/11/15 10:26
17060-07-0
Toluene-d8 (S)
101 %
70-130
1
02/11/15 10:26
2037-26-5
4500S21) Sulfide Water
Analytical Method: SM 4500-S213
Sulfide
ND mg/L
0.20
2
02/06/15 16:45
18496-25-8
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
71.9 mg/L
4.0
2
02/06/15 16:17
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2
Nitrogen, Nitrate
1.4 mg/L
0.020
1
02/05/15 00:24
5310B TOC
Analytical Method: SM 5310B
Total Organic Carbon
3.2 mg/L
1.0
1
02/05/15 19:07
7440-44-0
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
I
i
Page 12 of 40

1�5acieAnalytical
r www.pacelabs.com
i
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-8
Parameters
RSK 175 AIR Headspace
Ethane
Ethene
Methane
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury
Mercury
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
c7is-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Hunlersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396005 Collected: 02/03/15 14:40 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: RSK 175
ND ug/L
6.2
1
02/06/1518:30
74-84-0
ND ug/L
6.2
1
02/06/15 18:30
74-85-1
ND ug/L
6.6
1
02/06/1518:30
74-82-8
Analytical Method: EPA 6010 Preparation Method: EPA 3010
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:05
7440-38-2
846 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:05
7440-39-3
ND ug/L
1.0
1
02/05/15 15:45 02/06/15 03:05
7440-43-9
81.2 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:05
7440-47-3
14.6 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:05
7439-92-1
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:05
7782-49-2
ND ug/L
5.0
1
02/05/15 15:45 02/06/15 03:05
7440-22-4
Analytical Method: EPA7470 Preparation Method: EPA7470
ND ug/L
0.20
1
02/06/1512:45 02/06/1516:56
7439-97-6
Analytical Method: SM 6200B
ND ug/L
1.0
1
02/11/15 10:43
75-34-3
ND ug/L
1.0
1
02/11/15 10:43
75-35-4
ND ug/L
1.0
1
02/11/15 10:43
71-55-6
ND ug/L
1.0
1
02111/1510:43
79-00-5
ND ug/L
1.0
1
02111/1510:43
79-34-5
ND ug/L
1.0
1
02/11/15 10:43
95-50-1
ND ug/L
1.0
1
02/11/15 10:43
107-06-2
ND ug/L
1.0
1
02/11/15 10:43
78-87-5
ND ug/L
1.0
1
02/11/15 10:43
541-73-1
ND ug/L
1.0
1
02/11/15 10:43
106-46-7
ND ug/L
1.0
1
02111/1510:43
75-27-4
ND ug/L
5.0
1
0211111510:43
74-83-9
ND ug/L
1.0
1
02111/1510:43
75-25-2
ND ug/L
1.0
1
02111/1510:43
156-59-2
ND ug/L
1.0
1
02/11/15 10:43
10061-01-5
ND ug/L
1.0
1
02111/1510:43
56-23-5
ND ug/L
1.0
1
02/11/15 10:43
108-90-7
ND ug/L
1.0
1
02/11/15 10:43
75-00-3
ND ug/L
1.0
1
02/11/15 10:43
67-66-3
ND ug/L
1.0
1
02/11/15 10:43
74-87-3
ND ug/L
1.0
1
02/11/15 10:43
124-48-1
ND ug/L
1.0
1
02/11/15 10:43
75-71-8
ND ug/L
2.0
1
02/11/15 10:43
75-09-2
ND ug/L
1.0
1
02/11/15 10:43
156-60-5
ND ug/L
1.0
1
02/11/15 10:43
10061-02-6
ND ug/L
1.0
1
02/11/15 10:43
127-18-4
ND ug/L
1.0
1
02/11/15 10:43
79-01-6
ND ug/L
1.0
1
02/11/15 10:43
75-69-4
ND ug/L
1.0
1
02/11/15 10:43
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 13 of 40 -

7;a'neAnalyticalo
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] _
i.
Sample: DMW-8 Lab ID: 92236396006 Collected: 02/03/15 14:40 Received: 02/04/15 16:28 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
601 Volatiles by SM 6200 Analytical Method: SM 6200B
ANALYTICAL RESULTS
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
02/11/15 10:43
106-93-4
Surrogates
4-Bromofluorobenzene (S)
103 %
70-130
1
02/11/15 10:43
460-00-4
1,2-Dichloroethane-d4 (S)
108 %
70-130
1
02/11/15 10:43
17060-07-C
Toluene-d8 (S)
101 %
70-130
1
02/11/15 10:43
2037-26-5
4500S2D Sulfide Water
Analytical Method: SM 4500-S213
Sulfide
0.20 mg/L
0.10
1
02/05/15 11:00
18496-25-E
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
27.0 mg/L
2.0
1
02/06/15 16:31
14808-79-6
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA353.2
Nitrogen, Nitrate
0.81 mg/L
0.020
1
02/05/15 00:25
5310B TOC
Analytical Method: SM 5310B
Total Organic Carbon
20.6 mg/L
1.0
1
02/05/15 19:33
7440-44-0
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 40

aceAnalytical
www..pacelabs.com
Project: DOT 504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-11
Parameters
RSK 175 AIR Headspace
Ethane
Ethene
Methane
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury
Mercury
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396006 Collected: 02/03/15 16:20 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: RSK 175
ND ug/L
6.2
1
02/06/15 18:38
74-84-0
ND ug/L
6.2
1
02/06/15 18:38
74-85-1
4560 ug/L
6.6
1
02/06/15 18:38
74-82-8
Analytical Method: EPA 6010 Preparation Method: EPA 3010
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:08
7440-38-2
789 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:08
7440-39-3
ND ug/L
1.0
1
02/05/15 15:45 02/06/15 03:08
7440-43-9
85.0 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:08
7440-47-3
.110 ug/L
5.0
1
02/05/15 15:45 .02/06/15 03:08
7439-92-1
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:08
7782-49-2
5.9 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:08
7440-22-4
Analytical Method: EPA 7470 Preparation Method:
EPA 7470
ND ug/L
0.20
1
02/06/15 12:45 02/06/15 16:59
7439-97-6
Analytical Method: SM 6200B
6.7 ug/L
1.0
1
02/11/15 11:00
75-34-3
9.5 ug/L
1.0
1
02111/1511:00
75-35-4
ND ug/L
1.0
1
02/11/1511:00
71-55-6
ND ug/L
1.0
1
02/11/1511:00
79-00-5
ND ug/L
1.0
1
02/11/1511:00
79-34-5
ND ug/L
1.0
1
02/11/1511:00
95-50-1
ND ug/L
1.0
1
02/11/1511:00
107-06-2
ND ug/L
1.0
1
02111/1511:00
78-87-5
ND ug/L
1.0
1
02/11/1511:00
541-73-1
ND ug/L
1.0
1
02/11/1511:00
106-46-7
ND ug/L
1.0
1
02111/1511:00
75-27-4
ND ug/L
5.0
1
02/11/1511:00
74-83-9
ND ug/L
1.0
1
02/11/1511:00
75-25-2
ND ug/L
1.0
1
02/11/1511:00
156-59-2
ND ug/L
1.0
1
02/11/1511:00
10061-01-5
ND ug/L
1.0
1
02/11/1511:00
56-23-5
ND ug/L
1.0
1
02/11/1511:00
108-90-7
ND ug/L
1.0
1
02/11/1511:00
75-00-3
ND ug/L
1.0
1
02/11/1511:00
67-66-3
ND ug/L
1.0
1
02/11/1511:00
74-87-3
ND ug/L
1.0
1
02/11/1511:00
124-48-1
ND ug/L
1.0
1
02/11/1511:00
75-71-8
ND ug/L
2.0
1
02/11/1511:00
75-09-2
ND ug/L
1.0
1
02/11/1511:00
156-60-5
ND ug/L
1.0
1
02/11/1511:00
10061-02-6
ND ug/L
1.0
1
02/11/1511:00
127-18-4
7.0 ug/L
1.0
1
02/11/1511:00
79-01-6
ND ug/L
1.0
1
02/11/1511:00
75-69-4
ND ug/L
1.0
1
02/11/1511:00
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 40

aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-11
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofiuorobenzene (S)
1,2-Dichloroethane-d4 (S) .
Toluene-d8 (S)
4500S21) Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5310B TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID: 92236396006 Collected: 02/03/15 16:20 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit
Analytical
Analytical
Analytical
Analytical
Analytical
DF
Prepared Analyzed
CAS No. Qual
Method: SM 6200B
ND ug/L
1.0
1
02111/1511:00
106-93-4
102 %
70-130
1
02/11/1511:00
460-00-4
106 %
70-130
1
02111/1511:00
17060-07-0
101 %
70-130
1
02/11/1511:00
2037-26-5
Method: SM 4500-S2D
0.14 mg/L
0.10
1
02/06/15 16:45
18496-25-8
Method: EPA 300.0
79.6 mg/L
8.0
4
02/07/15 01:48
14808-79-8
Method: EPA 353.2
ND mg/L
0.020
1
02/05/15 00:26
Method: SM 5310B
20.9 mg/L
1.0
1
02/05/15 19:44
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 40

�5acieAnalytical
www.pacelabs.com
Project: DOT 504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-2
Parameters
RSK 175 AIR Headspace
Ethane
Ethene
Methane
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury
Mercury
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichlo roeth ane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396007 Collected: 02/04/15 11:50 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: RSK 175
ND ug/L
6.2
1
02106/1519:19
74-84-0
ND ug/L
6.2
1
02/06/15 19:19
74-85-1
58.7 ug/L
6.6
1
02/06/15 19:19
74-82-8
Analytical Method: EPA6010 Preparation Method:
EPA3010
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:11
7440-38-2
91.0 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:11
7440-39-3
ND ug/L
1.0
1
02/05/15 15:45 02/06/15 03:11
7440-43-9
21.2 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:11
7440-47-3
5.8 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:11
7439-92-1
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:11
7782-49-2
ND ug/L
5.0
1
02/05/15 15:45 02/06/15 03:11
7440-22-4
Analytical Method: EPA 7470 Preparation Method: EPA 7470
ND ug/L
0.20
1
02/06/15 12:45 02/06/15 17:01
7439-97-6
Analytical Method: SM 6200B
1.0 ug/L
1.0
1
02/11/1511:16
75-34-3
ND ug/L
1.0
1
02/11/1511:16
75-35-4
ND ug/L
1.0
1
02111/1511:16
71-55-6
ND ug/L
1.0
1
02/11/1511:16
79-00-5
ND ug/L
1.0
1
02/11/1511:16
79-34-5
ND ug/L
1.0
1
02/11/1511:16
95-50-1
ND ug/L
1.0
1
02/11/1511:16
107-06-2
ND ug/L
1.0
1
02/11/1511:16
78-87-5
ND ug/L
1.0
1
02/11/1511:16
541-73-1
ND ug/L
1.0
1
02/11/1511:16
106-46-7
ND ug/L
1.0
1
02/11/1511:16
75-27-4
ND ug/L
5.0
1
02/11/1511:16
74-83-9
ND ug/L
1.0
1
02/11/1511:16
75-25-2
ND ug/L
1.0
1
02/11/1511:16
156-59-2
ND ug/L
1.0
1
02/11/1511:16
10061-01-5
ND ug/L
1.0
1
02/11/1511:16
56-23-5
ND ug/L
1.0
1
02/11/1511:16
108-90-7
ND ug/L
1.0
1
02/11/1511:16
75-00-3
ND ug/L
1.0
1
02/11/1511:16
67-66-3
ND ug/L
1.0
1
02/11/1511:16
74-87-3
ND ug/L
1.0
1
02/11/1511:16
124-48-1
ND ug/L
1.0
1
02/11/1511:16
75-71-8
ND ug/L
2.0
1
02/11/1511:16
75-09-2
ND ug/L
1.0
1
02111/1511:16
156-60-5
ND ug/L
1.0
1
02/11/1511:16
10061-02-6
ND ug/L
1.0
1
- 02/11/15 11:16
127-18-4
ND ug/L
1.0
1
02/11/1511:16
79-01-6
ND ug/L
1.0
1
02/11/1511:16
75-69-4
ND ug/L
1.0
1
02/11/15 11:16
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qual
Page 17 of 40

aceAnalytical
f vAmpacelabs.com
I
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-2
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310E TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
1-7
Lab ID: 92236396007 Collected:
02/04/15 11:50
Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
Analytical Method: SM 6200B
I i
ND ug/L
1.0
1
02/11/15 11:16
106-93-4
102 %
70-130
1
02/11/1511:16
460-00-4
107 %
70-130
1
02111/1511:16
17060-07-0
101 %
70-130
1
02/11/1511:16
2037-26-5
Analytical Method: SM 4500-S2D
ND mg/L
0.10
1
02/05/15 11:00
18496-25-8
Analytical Method: EPA 300.0
77.2 mg/L 4.0 2 02/10/15 14:06 14808-79-8
Analytical Method: EPA 353.2
2.7 mg/L 0.020 1 02/05/15 00:28
Analytical Method: SM 5310B
3.6 mg/L 1.0 1 02/05/15 19:54 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 40

aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-1
Parameters
RSK 175 AIR Headspace
Ethane
Ethene
i Methane
6010 MET ICP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury
Mercury
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trchloroethene
Trichlorofluoromethane
Vinyl chloride
Date: 02/11/2015 05:03 PM
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Lab ID: 92236396008 Collected: 02/04/1512:50 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: RSK 175
ND ug/L
6.2
1
02/06/15 19:28
74-84-0
ND ug/L
6.2
1
02/06/15 19:28
74-85-1
13.8 ug/L
6.6
1
02/06/15 19:28
74-82-8
Analytical Method: EPA6010 Preparation Method: EPA3010
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:14
7440-38-2
502 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:14
7440-39-3
1.2 ug/L
1.0
1
02/05/15 15:45 02/06/15 03:14
7440-43-9
86.4 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:14
7440-47-3
27.9 ug/L
5.0
1
02/05/15 15:45 02/06/15 03:14
7439-92-1
ND ug/L
10.0
1
02/05/15 15:45 02/06/15 03:14
7782-49-2
ND ug/L
5.0
1
02/05/15 15:45 02/06/15 03:14
7440-22-4
Analytical Method: EPA7470 Preparation Method: EPA7470
ND ug/L
0.20
1
02/06/1512:45 02/06/1517:04
7439-97-6
Analytical Method: SM 6200B
2.6 ug/L
1.0
1
02/11/1511:33
75-34-3
ND ug/L
1.0
1
02/11/1511:33
75-35-4
ND ug/L
1.0
1
02/11/1511:33
71-55-6
ND ug/L
1.0
1
02/11/15 11:33
79-00-5
ND ug/L
1.0
1
02/11/1511:33
79-34-5
ND ug/L
1.0
1
02/11/1511:33
95-50-1
ND ug/L
1.0
1
02/11/1511:33
107-06-2
ND ug/L
1.0
1
02/11/1511:33
78-87-5
ND ug/L
1.0
1
02/11/1511:33
541-73-1
ND ug/L
1.0
1
02/11/1511:33
106-46-7
ND ug/L
1.0
1
02/11/1511:33
75-27-4
ND ug/L
5.0
1
02/1111511:33
74-83-9
.ND ug/L
1.0
1
02/11/1511:33
75-25-2
2.0 ug/L
1.0
1
02/11/1511:33
156-59-2
ND ug/L
1.0
1
02/11/1511:33
10061-01-5
ND ug/L
1.0
1
02/11/1511:33
56-23-5
ND ug/L
1.0
1
02/11/1511:33
108-90-7
ND ug/L
1.0
1
02111/1511:33
75-00-3
ND ug/L
1.0
1
02/11/1511:33
67-66-3
ND ug/L
1.0
1
02111/1511:33
74-87-3
ND ug/L
1.0
1
02/11/1511:33
124A8-1
ND ug/L
1.0
1
02/11/1511:33
75-71-8
ND ug/L
2.0
1
02111/1511:33
75-09-2
ND ug/L
1.0
1
02/11/1511:33
156-60-5
ND ug/L
1.0
1
02/1111511:33
10061-02-6
ND ug/L
1.0
1
02/11/1511:33
127-18-4
1.2 ug/L
1.0
1
02/11/1511:33
79-01-6
ND ug/L
1.0
1
02/11/1511:33
75-69-4
ND ug/L
1.0
1
02/11/1511:33
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 40

acmnalytical
www..pacelabs.com
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
i
i
Sample: DMW-1
Lab ID: 92236396008 Collected:
02104/1512:50
Received: 02/04/16 16:28 Matrix: Water
Parameters
Results Units Report Limit
DF
Prepared Analyzed
CAS No. Qual
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
02/11/15 11:33
106-93-4
Surrogates
4-Bromofluorobenzene (S)
101 %
70-130
1
02/11/15 11:33
460-00-4
I
1,2-Dichloroethane-d4 (S)
106 %
70-130
1
02/11/15 11:33
17060-07-0
Toluene-d8 (S)
101 %
70-130
1
02/11/15 11:33
2037-26-5
4500S2D Sulfide Water
Analytical Method: SM 4500-S213
—
Sulfide
ND mg/L
0.10
1
02/06/15 16:45
18496-25-8
1
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0
Sulfate
4.3 mg/L
2.0
1
02/10/1514:23
14808-79-8
353.2 Nitrogen, N021NO3 unpres Analytical Method: EPA 353.2
Nitrogen, Nitrate 0.059 mg/L 0.020 1 02/05/15 00:29
5310E TOC Analytical Method: SM 5310B
Total Organic Carbon 4.2 mg/L 1.0 1 02/05/15 20:46 7440-44-0
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 40

1�;aceAnalytical
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ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: DMW-3
Parameters
Lab ID: 92236396009 Collected: 02/04/15 15:00
Results Units Report Limit DF
Received: 02/04/15 16:28 Matrix: Water
Prepared Analyzed CAS No.
RSK 175 AIR Headspace
Analytical Method: RSK 175
--- Ethane
ND ug/L
6.2
1
02/06/15 19:36 74-84-0
Ethene
ND ug/L
6.2
1
02/06/15 19:36 74-85-1
Methane
50.6 ug/L
6.6
1
02/06/15 19:36 74-82-8
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3010
Arsenic
ND ug/L
10.0
1
02106/1510:05
02/06/15 18:32 7440-38-2
Barium
209 ug/L
5.0
1
02/06/15 10:05
02/06/15 18:32 7440-39-3
Cadmium
ND ug/L
1.0
1
02/0611510:05
02/06/15 18:32 7440-43-9
Chromium
79.0 ug/L
5.0
1
02/06/15 10:05
02/06/15 18:32 7440-47-3
Lead
ND ug/L
5.0
1
02/06/15 10:05
02/06/15 18:32 7439-92-1
Selenium
ND ug/L
10.0
1
02/06/15 10:05
02106/1518:32 7782-49-2
Silver
ND ug/L
5.0
1
02/06/15 10:05
02106/1518:32 7440-22-4
7470 Mercury
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Mercury
ND ug/L
0.20
1
02/06/1512:45
02/06/1517:07 7439-97-6
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
02/11/15 11:50 75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
02/11/15 11:50 75-35-4
1,1,1-Trichloroethane
ND ug/L
1.0
1
02/11/15 11:50 71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
02/11/15 11:50 79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
02/11/15 11:50 79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
02/1111511:50 95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
02/11/15 11:50 107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
02/11/15 11:50 78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 11:50 541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 11:50 106-46-7
Bromodichloromethane
ND ug/L
1.0
1
02/11/15 11:50 75-27-4
Bromomethane
ND ug/L
5.0
1
02/11/15 11:50 74-83-9
Bromoform
ND ug/L
1.0
1
02/11/1511:60 75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 11:50 156-59-2
- cis-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 11:50 10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
02/11/15 11:50 56-23-5
Chlorobenzene
ND ug/L
1.0
1
02/11/15 11:50 108-90-7
Chloroethane
ND ug/L
1.0
1
02/11/15 11:50 75-00-3
Chloroform
ND ug/L
1.0
1
02/1111511:50 67-66-3
Chloromelhane
ND ug/L
1.0
1
02111/1511:50 74-87-3
Dibromochloromethane
ND ug/L
1.0
1
02/11/15 11:50 124-48-1
Dichlorodifluoromethane
ND ug/L
1.0
1
02/11/15 11:50 75-71-8
Methylene Chloride
ND ug/L
2.0
1
02/11/15 11:50 75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
02111/1511:50 156-60-5
r trans-1,3-Dichloropropene
ND ug/L
1.0
1
02111/1511:50 10061-02-6
Tetrachloroethene
ND uglL
1.0
1
02/11/15 11:50 127-18-4
Trichloroethene
ND uglL
1.0
1
02/11/15 11:50 79-01-6
Trichlorofluoromethane
ND ug/L
1.0
1
02/11/15 11:50 75-69-4
j Vinyl chloride
ND ug/L
1.0
1
02/11/15 11:50 75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Qual
Page 21 of 40

1�5a'cieAnalytica(
( www.pacelabs.com
I
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Sample: DMW-3
Parameters
601 Volatiles by SM 6200
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
300.0 IC Anions 28 Days
Sulfate
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
5310E TOC
Total Organic Carbon
Date: 02/11/2015 05:03 PM
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
�1
�I
Lab ID: 92236396009 Collected: 02/04/1515:00 Received: 02/04/15 16:28 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Analytical Method: SM 6200B j
NO ug/L 1.0 1 02/11/15 11:50 106-93-4
102 % 70-130 1 02/11/15 11:50 460-00-4
109 %
Analytical
Analytical
Analytical
Analytical
70-130
1
02/11/15 11:50
17060-07-0
100 %
70-130
1
02/11/16 11:50
2037-26-5
Method: SM 4500-S2D
NO mg/L
0.10
1
02/05/1511:00
18496-25-8
Method: EPA 300.0
76.7 mg/L
4.0
2
02107/1610:39
14808-79-8
Method: EPA 353.2
0.29 mg/L
0.020
1
02/05/15 00:30
Method: SM 5310B
17.8 mg/L
1.0
1
02/05/15 20:56
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
l
i
l
Page 22 of 40

d�
aceAnalytical
www.pacelabs.com
I g
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WSW-4
Parameters
Lab ID: 92236396010 Collected: 02/04/15 15:30
Results Units Report Limit DF
Received: 02/04/15 16:28 Matrix: Water
Prepared Analyzed CAS No.
601 Volatiles by SM 6200
Analytical Method: SM 6200B
1,1-Dichloroethane
ND ug/L
1.0
1
02/11/15 12:07
75-34-3
1,1-Dichloroethene
ND ug/L
1.0
1
02/11/15 12:07
75-35-4
- 1,1,1-Trichloroethane
ND ug/L
1.0
1
02111/1512:07
71-55-6
1,1,2-Trichloroethane
ND ug/L
1.0
1
02/11/15 12:07
79-00-5
1,1,2,2-Tetrachloroethane
ND ug/L
1.0
1
02/11/15 12:07
79-34-5
1,2-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 12:07
95-50-1
1,2-Dichloroethane
ND ug/L
1.0
1
02/11/15 12:07
107-06-2
1,2-Dichloropropane
ND ug/L
1.0
1
02/11/15 12:07
78-87-5
1,3-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 12:07
541-73-1
1,4-Dichlorobenzene
ND ug/L
1.0
1
02/11/15 12:07
10646-7
Bromodichloromethane
ND ug/L
1.0
1
02111/1512:07
75-274
Bromomethane
ND ug/L
5.0
1
02111/1512:07
74-83-9
Bromoform
ND ug/L
1.0
1
02/11/15 12:07
75-25-2
cis-1,2-Dichloroethene
ND ug/L
1.0
1
0211111512:07
156-59-2
cis-1,3-Dichloropropene
ND ug/L
1.0
1
02111/1512:07
10061-01-5
Carbon tetrachloride
ND ug/L
1.0
1
02/11/15 12:07
56-23-5
Chlorobenzene
ND ug/L
1.0
1
02/11/15 12:07
108-90-7
Chloroethane
ND ug/L
1.0
1
02/11/15 12:07
75-00-3
Chloroform
ND ug/L
1.0
1
02/11/15 12:07
67-66-3
Chloromethane
ND ug/L
1.0
1
02/11/15 12:07
74-87-3
Dibromochloromethane
ND ug/L
1.0
1
02/11/15 12:07
12448-1
Dichlorodifluoromethane
ND ug/L
1.0
1
02/11/15 12:07
75-71-8
Methylene Chloride
ND ug/L
2.0
1
02/11/15 12:07
75-09-2
trans-1,2-Dichloroethene
ND ug/L
1.0
1
02/11/15 12:07
156-60-5
trans-1,3-Dichloropropene
ND ug/L
1.0
1
02/11/15 12:07
10061-02-6
Tetrachloroethene
ND ug/L
1.0
1
02/11/15 12:07
127-18-4
Trichloroethene
ND ug/L
1.0
1
02/11/15 12:07
79-01-6
Tdchlorofluoromethane
ND ug/L
1.0
1
02/11/15 12:07
75-69-4
Vinyl chloride
ND ug/L
1.0
1
02/11/15 12:07
75-014
1,2-Dibromoethane (EDB)
ND ug/L
1.0
1
02/11/15 12:07
106-93-4
Surrogates
4-Bromofluorobenzene (S)
102 %
70-130
1
02/11/15 12:07
460-00-4
1,2-Dichloroethane-d4 (S)
110 %
70-130
1
02/11/15 12:07
17060-07-0
Toluene-d8 (S)
102 %
70-130
1
02/11/15 12:07
2037-26-5
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. _
Qual
Page 23 of 40

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc. '
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] ;
i
i
QUALITY CONTROL DATA -,
�I
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
QC Batch: AIR/22451 Analysis Method: RSK 175 i
QC Batch Method: RSK 175 Analysis Description: RSK 175 AIR HEADSPACE
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007, -
92236396008,92236396009
METHOD BLANK: 1895844 Matrix: Water
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Ethane ug/L ND 6.2 02106/1516:03
Ethene ug/L ND 6.2 02106/1516:03
Methane ug/L ND 6.6 02/06/1516:03
LABORATORY CONTROL SAMPLE
& LCSD:
1895845 1895846
Spike LCS LCSD LCS LCSD
% Rec Max
Parameter
Units Conc. Result Result % Rec % Rec
Limits RPD RPD Qualifiers
Ethane
ug/L
114 108 109 95 96
85-115 2 20
Ethene
ug/L
106 100 101 95 95
85-115 1 20
Methane
ug/L
60.7 56.2 56.4 93 93
85-115 0 20
SAMPLE DUPLICATE: 1895847
10296012001 Dup
Parameter
Units Result Result RPD
Qualifiers
Ethane
ug/L
ND ND
Ethene
ug/L
ND ND
Methane
ug/L
31.7 31.0 2
r
SAMPLE DUPLICATE: 1895848
10296012004 Dup
-
Parameter
Units Result Result RPD
Qualifiers
Ethane
ug/L
ND ND
I
Ethene
ug/L
ND ND
Methane
ug/L
9070 9830 8 E
i
Results presented on this page are
I
In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
—
Date: 02/11/2015 05:03 PM
without the written consent of Pace Analytical Services, Inc..
Page 24 of 40
I I

l
aceAnalytical
www..pacelabs.com
i
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MERP/7557 Analysis Method: EPA 7470
QC Batch Method: EPA 7470 Analysis Description: 7470 Mercury
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
r
METHOD BLANK: 1386127 Matrix: Water
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ug/L ND 0.20 02/0611516:19
_i
LABORATORY CONTROL SAMPLE: 1386128
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 2.5 2.4 94 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1386129 1386130
MS MSD
92236289001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury ug/L ND 2.5 2.5 2.4 2.4 98 98 75-125 0
— Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result.
r
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 25 of 40

acmnalytical
w m..pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
1
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100 -
Huntersville, NC 28078
[phone]
t
QC Batch: MPRP/17846 Analysis Method: EPA6010 j
QC Batch Method: EPA 3010 Analysis Description: 6010 MET
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008
QUALITY CONTROL DATA
METHOD BLANK: 1385562
Matrix: Water
Associated Lab Samples:
92236396001, 92236396002, 92236396003, 92236396004, 92236396005,
92236396006, 92236396007,
92236396008
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Arsenic
ug/L
ND
10.0
02/06/15 01:45
Barium
ug/L
ND
5.0
02/06/15 01:45
Cadmium
ug/L
ND
1.0
02/06/15 01:45
Chromium
ug/L
ND
5.0
02/06/15 01:45
Lead
ug/L
ND
5.0
02/06/15 01:45
Selenium
ug/L
ND
10.0
02/06/15 01:45
Silver
ug/L
ND
5.0
02/06/15 01:45
LABORATORY CONTROL SAMPLE:
Parameter
1385563
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Arsenic
ug/L
500
457
91
80-120
Barium
ug/L
500
463
93
80-120
Cadmium
ug/L
500
467
93
80-120
Chromium
ug/L
500
476
95
80-120
Lead
ug/L
500
467
93
80-120
Selenium
ug/L
500
462
92
80-120
Silver
ug/L
250
237
95
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1385564
1385565
MS
MSD
92235846002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
103
500
500
488
482
77
76
75-125
1
Barium
ug/L
113
500
500
870
849
151
147
75-125
3 M1
Cadmium
ug/L
1 A
500
500
408
403
81
80
75-125
1
Chromium
ug/L
255
500
500
666
659
82
81
75-125
1
Lead
ug/L
17.6
500
500
443
435
85
84
75-125
2
Selenium
ug/L
20.8
500
500
380
378
72
71
75-125
1 M1
Silver
ug/L
ND
250
250
204
201
81
80
75-125
1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 26 of 40

lacieAnalyficalo
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MPRP/17852
Analysis Method:
EPA6010
QC Batch Method: EPA3010
Analysis Description: 6010 MET
Associated Lab Samples: 92236396009
METHOD BLANK: 1386032
Matrix: Water
Associated Lab Samples: 92236396009
-
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
J Arsenic
ug/L
ND
10.0
02106/1518:26
Barium
ug/L
ND
5.0
02106/1518:26
Cadmium
ug/L
ND
1.0
02/06/1518:26
Chromium
ug/L
ND
5.0
02/06/1518:26
Lead
ug/L
ND
5.0
02/06/1518:26
Selenium
ug/L
ND
10.0
02106/1518:26
Silver
ug/L
ND
5.0
02106/1518:26
LABORATORY CONTROL SAMPLE:
1386033
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Arsenic
ug/L
500
485
97
80-120
1 Barium
ug/L
500
494
99
80-120
Cadmium
ug/L
500
495
99
80-120
Chromium
ug/L
500
474
95
80-120
Lead
ug/L
500
481
96
80-120
Selenium
ug/L
500
497
99
80-120
Silver
ug/L
250
248
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1386034
1386035
MS
MSD
92236396009
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result-
Result % Rec % Rec
Limits
RPD
Arsenic ug/L
ND
500
500
512
509
102 102
75-125
1
— Barium ug/L
209
500
500
721
718
102 102
75-125
0
Cadmium ug/L
ND
500
500
517
516
103 103
75-125
0
Chromium ug/L
79.0
500
500
555
555
95 95
75-125
0
i Lead ug/L
ND
500
500
496
495
98 98
75-125
0
— Selenium ug/L
ND
500
500
518
518
103 103
75-125
0
Silver ug/L
ND
250
250
257
256
103 102
75-125
0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
withoutthe written consent of Pace Analytical Services, Inc..
Qual
Page 27 of 40

Analytical o
www..pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
te loo
9800Huntersv Ile, NC'28078
[phone] --
QUALITY CONTROL DATA - -.
QC Batch: MSV/30281
Analysis Method: SM 6200B
QC Batch Method: SM 6200B
Analysis Description: 601 by 6200B
Associated Lab Samples:
92236396001, 92236396002,
92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009,92236396010
METHOD BLANK: 1388284
Matrix: Water
Associated Lab Samples:
92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009,92236396010
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,1,1-Trichloroethane
ug/L
ND
1.0
02/11/15 09:35
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
02/11/15 09:35
1,1,2-Trichloroethane
ug/L
ND
1.0
02/11/15 09:35
1,1-Dichloroethane
ug/L
ND
1.0
02/11/15 09:35
1,1-Dichloroethene
ug/L
ND
1.0
02/11/15 09:35
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
02/11/15 09:35
1,2-Dichlorobenzene
ug/L
ND
1.0
02/11/15 09:35
1,2-Dichloroethane
ug/L
ND
1.0
02/11/15 09:35 _
1,2-Dichloropropane
ug/L
ND
1.0
02/11/15 09:35
1,3-Dichlorobenzene
ug/L
ND
1.0
02/11/15 09:35
1,4-Dichlorobenzene
ug/L
ND
1.0
02/1111509:35
Bromodichloromethane
ug/L
ND
1.0
02/11/15 09:35
Bromoform
ug/L
ND
1.0
02/11/15 09:35
Bromomethane
ug/L
ND
5.0
02/11/15 09:35
Carbon tetrachloride
ug/L
ND
1.0
02M1/15 09:35
Chlorobenzene
ug/L
ND
1.0
02/11/15 09:35
Chloroethane
ug/L
ND
1.0
02/11/15 09:35
Chloroform
ug/L
ND
1.0
02/11/15 09:35
Chloromethane
ug/L
ND
1.0
02/11/15 09:35
cis-1,2-Dichloroethene
ug/L
ND
1.0
02/11/15 09:35
cis-1,3-Dichloropropene
ug/L
ND
1.0
02/11/15 09:35 -
Dibromochloromethane
ug/L
ND
1.0
02/11/15 09:35
Dichlorodifluoromethane
ug/L
ND
1.0
02/11/15 09:35
Methylene Chloride
ug/L
ND
2.0
02/11/15 09:35
Tetrachloroethene
ug/L
ND
1.0
02/11/15 09:35
trans-1,2-Dichloroethene
ug/L
ND
1.0
02/11/15 09:35
trans-1,3-Dichloropropene
ug/L
ND
1.0
02/11/15 09:35
Trichloroethene
ug/L
ND
1.0
02/11/15 09:35
Trichlorofluoromethane
ug/L
ND
1.0
02/11/15 09:35
Vinyl chloride
ug/L
ND
1.0
02/11/15 09:35
1,2-Dichloroethane-d4 (S)
%
104
70-130
02/11/15 09:35
4-Bromofluorobenzene (S)
%
104
70-130
02/11/15 09:35
Toluene-d8 (S)
%
100
70-130
02/11/15 09:35
as
LABORATORY CONTROL SAMPLE: 1388285
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 50 54.3 109 60-140
Results presented an this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
I
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc.. Page 28 of 40

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i
QUALITY CONTROL DATA
- Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
1388285
-
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
1,1,2,2-Tetrachloroethane
ug/L
50
47.9
96
60-140
1,1,2-Trichloroethane
ug/L
50
54.6
109
60-140
1,1-Dichloroethane
ug/L
50
53.2
106
60-140
- 1,1-Dichloroethene
ug/L
50
52.8
106
60-140
1,2-Dibromoethane (EDB)
ug/L
50
49.7
99
60-140
1,2-Dichlorobenzene
ug/L
50
45.1
90
60-140
1,2-Dichloroethane
ug/L
50
57.3
115
60-140
1,2-Dichloropropane
ug/L
50
50.2
100
60-140
1,3-Dichlorobenzene
ug/L
50
44.0
88
60-140
1,4-Dichlorobenzene
ug/L
50
44.0
88
60-140
Bromodichloromethane
ug/L
50
51.9
104
60-140
Bromoform
ug/L
50
43.3
87
60-140
Bromomethane
ug/L
50
62.5
125
60-140
- Carbon tetrachloride
ug/L
50
51.4
103
60-140
Chlorobenzene
ug/L
50
46.1
92
60-140
Chloroethane
ug/L
50
58.0
116
60-140
Chloroform
ug/L
50
50.2
100
60-140
Chloromethane
ug/L
50
52.2
104
60-140
cis-1,2-Dichloroethene
ug/L
50
55.5
111
60-140
- cis-1,3-Dichloropropene
ug/L
50
53.6
107
60-140
Dibromochloromethane
ug/L
50
49.0
98
60-140
Dichlorodifluoromethane
ug/L
50
54.4
109
60-140
Methylene Chloride
ug/L
50
58.7
117
60-140
Tetrachloroethene
ug/L
50
44.8
90
60-140
trans-1,2-Dichloroethene
ug/L
50
53.4
107
60-140
trans-1,3-Dichloropropene
ug/L
50
56.6
113
60-140
Trchloroethene
ug/L
50
49.8
100
60-140
Trichlorofluoromethane
ug/L
-
50
58.2
116
60-140
Vinyl chloride
ug/L
50
51.3
103
60-140
1,2-Dichloroethane-d4 (S)
%
104
70-130
4-Bromofluorobenzene (S)
%
109
70-130
Toluene-d8 (S)
%
103
70-130
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 1388286
1388287
MS
MSD
92236396010
Spike
Spike
MS
MSD
MS MSD % Rec
Parameter
Units Result
Cone.
Cone.
Result
Result
% Rec % Rec Limits RPD
1,1,1-Trichloroethane
ug/L
ND
20
20
21.1
15.9
105
80 60-140 28
1,1,2,2-Tetrachloroelhane
ug/L
ND
20
20
17.2
14.1
86
71 60-140 19
1,1,2-Trichloroethane
ug/L
ND
20
20
19.9
15.4
100
77 60-140 25
1,1-Dichloroethane
ug/L
ND
20
20
21.0
16.0
105
80 60-140 27
-' 1,1-Dichloroethene
ug/L
ND
20
20
21.7
16.2
108
81 60-140 29
1,2-Dibromoethane (EDB)
ug/L
ND
20
20
17.2
14.0
86
70 60-140 20
1,2-Dichlorobenzene
ug/L
ND
20
20
16.5
12.7
82
64 60-140 26
1,2-Dichloroethane
ug/L
ND
20
20
21.5
16.3
108
81 60-140 28
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Qua[
Page 29 of 40

1�55'cmnalydca(
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I
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
i
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1388286
1388287
MS
MSD
92236396010
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qua[
1,2-Dichloropropane
ug/L
ND
20
20
19.0
14.3
95
72
60-140
28
1,3-Dichlorobenzene
ug/L
ND
20
20
16.3
12.4
82
62
60-140
27
1,4-Dichlorobenzene
ug/L
ND
20
20
16.6
12.7
83
64
60-140
26
Bromodichloromethane
ug/L
ND
20
20
18.4
13.8
92
69
60-140
29
Bromoform
ug/L
ND
20
20
14.9
12.3
74
62
60-140
19
Bromomethane
ug/L
ND
20
20
26.9
18.1
135
91
60-140
39 R1
Carbon tetrachloride
ug/L
ND
20
20
19.8
15.2
99
76
60-140
26
Chlorobenzene
ug/L
ND
20
20
17.3
13.7
87
68
60-140
24
Chloroethane
ug/L
ND
20
20
27.5
19.1
138
96
60-140
36 R1
Chloroform
ug/L
ND
20
20
19.4
14.8
97
74
60-140
27
Chloromethane
ug/L
ND
20
20
21.2
15.7
106
78
60-140
30
cis-1,2-Dichloroethene
ug/L
ND
20
20
21.7
16.3
108
82
60-140
28
cis-1,3-Dichloropropene
ug/L
ND
20
20
18.3
14.2
91
71
60-140
25
Dibromochloromethane
ug/L
ND
20
20
15.3
11.8
77
59
60-140
26 MO
Dichlorodifluoromethane
ug/L
ND
20
20
23.3
17.6
117
88
60-140
28
Methylene Chloride
ug/L
ND
20
20
21.0
15.2
105
76
60-140
32 R1
Tetrachloroethene
ug/L
ND
20
20
17.1
14.1
85
71
60-140
19
trans-1,2-Dichloroethene
ug/L
ND
20
20
21.2
16.2
106
81
60-140
27
trans-1,3-Dichloropropene
ug/L
ND
20
20
18.7
14.2
94
71
60-140
28
Trichloroethene
ug/L
ND
20
20
19.2
15.0
96
75
60-140
25
Trichlorofluoromethane
ug/L
ND
20
20
25.6
19.1
128
96
60-140
29
Vinyl chloride
ug/L
ND
20
20
21.3
15.7
106
78
60-140
30
1,2-Dichloroethane-d4 (S)
%
109
105
70-130
4-Bromofluorobenzene (S)
%
106
109
70-130
Toluene-d8 (S)
%
103
103
70-130
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 30 of 40

1
- 5aneAnalytical"
www.pacelabs.com
I !
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
QUALITY CONTROL DATA
QC Batch: WET/35567 Analysis Method: SM 4500-S2D
- QC Batch Method: SM 4500-S2D Analysis Description: 4500S213 Sulfide Water
Associated Lab Samples: 92236396002, 92236396005, 92236396007, 92236396009
METHOD BLANK: 1385059 Matrix: Water
Associated Lab Samples: 92236396002, 92236396005, 92236396007, 92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 0210511511:00
LABORATORY CONTROL SAMPLE: 1385060
Parameter Units
Sulfide mg/L
Spike LCS
Cone. Result
.5 0.49
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LCS % Rec
% Rec Limits Qualifiers
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1385061 1385062
MS MSD
92235628002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
I �
Sulfide mg/L ND .5 .5 0.48 0.48 90 90 90-110 0
Results presented on this page are to the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 31 of 40

acmnalytical
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QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
QC Batch: WET/35601 Analysis Method: SM 4500-S2D
QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water
Associated Lab Samples: 92236396001, 92236396003, 92236396004, 92236396006, 92236396008
METHOD BLANK: 1386390 Matrix: Water
Associated Lab Samples: 92236396001, 92236396003, 92236396004, 92236396006, 92236396008
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/L ND 0.10 02/06/1516:45
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone] l
LABORATORY CONTROL SAMPLE: 1386391
Spike LCS LCS % Rec
Parameter. Units Conc. Result % Rec Limits Qualifiers
Sulfide mg/L .5 0.50 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1386392 1386393
MS MSD
92236233001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfide mg/L NO .5 .5 0.48 0.49 97 97 90-110 0
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
I
Page 32 of 40
J,

Pace Analytical Services, Inc.
g n
® 9800 Kincey Ave. Suite 100
�ceAnal �/tical Huntersville, NC 28078
www.pacelabs.com [phone]
- -, QUALITY CONTROL DATA
Project: DOT 504 34613.3.26
Pace Project No.: 92236396
QC Batch: WETA/21832 Analysis Method: EPA 300.0
QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
METHOD BLANK: 1386068 Matrix: Water
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 2.0 02/06/1513:48
LABORATORY CONTROL SAMPLE: 1386069
Parameter Units
Sulfate mg/L
Spike
Cone.
20
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1386070
MS
92236396001 Spike.
Parameter Units Result Cone.
Sulfate mg/L 19.0 20
LCS LCS - % Rec
Result % Rec Limits Qualifiers
20.6 103 90-110
1386071
MSD
Spike MS MSD MS MSD % Rec
Cone. Result Result % Rec % Rec Limits RPD
20 39.0 40.2 100 106 90-110 3
Qual
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1386072 1386073
MS MSD
92236646002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 7810 20 20 7810 7780 -2 -155 90-110 0 M6
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 33 of 40

lacieAnalyticalo
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Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone] -
i
QC Batch: WETA/21813 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
METHOD BLANK: 1384756 Matrix: Water
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007, —,
92236396008,92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0.020 02/04/15 23:54
LABORATORY CONTROL SAMPLE: 1384757
Parameter Units
Nitrogen, Nitrate mg/L
QUALITY CONTROL DATA
Spike LCS
Cone. Result
2.5 2.5
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1384758
MS
92236183003 Spike
Parameter Units Result Cone.
Nitrogen, Nitrate mg/L 1.1 2.5
Qualifiers
1384759 --
MSD
Spike MS MSD MS MSD % Rec
Cone. Result Result % Rec % Rec Limits RPD Qua[
2.5 3.1 3.4 79 93 90-110 11 M1,R1
LCS % Rec
% Rec Limits
99 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1384760 1384761
MS MSD
92236230001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qua[
Nitrogen, Nitrate mg/L 10.1 2.5 2.5 13.7 13.9 141 149 90-110 1 M1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 34 of 40
j-i

aceAnalytical
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QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: WETA/21815 Analysis Method: SM 5310B
QC Batch Method: SM 5310B Analysis Description: 531013 TOC
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
METHOD BLANK: 1385102 Matrix: Water
Associated Lab Samples: 92236396001, 92236396002, 92236396003, 92236396004, 92236396005, 92236396006, 92236396007,
92236396008,92236396009
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Organic Carbon mg/L ND 1.0 02/05/15 16:06
LABORATORY CONTROL SAMPLE: 1385103
Parameter Units
Total Organic Carbon mg/L
Spike LCS LCS % Rec _
Conc. Result % Rec Limits Qualifiers
25 24.2 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1385104
MS
92236210001
Spike
Parameter
Units
Result
Conc.
Total Organic Carbon
mg/L
724
25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1385106
MS
92236396004
Spike
Parameter
Units
Result
Conc.
Total Organic Carbon
mg/L
3.2
25
1385105
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qual
25 700 688 -98 -147 90-110 2 M6
1385107
MSD
Spike MS MSD MS MSD % Rec
Conc. Result Result % Rec % Rec Limits RPD Qua[
25 28.2 28.0 100 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Page 35 of 40

aceAnalytical
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QUALIFIERS
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
DEFINITIONS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes toAzobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) -.Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TN - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services -Asheville
PAST-C Pace Analytical Services - Charlotte
PASI-M Pace Analytical Services - Minneapolis
ANALYTE QUALIFIERS
E Analyte concentration exceeded the calibration range. The reported result is estimated.
Mo Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
R1 RPD value was outside control limits.
Date: 02/11/2015 05:03 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 36 of 40

Z�;acmnalyfical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92236396001
DMW-10
RSK 175
AIR/22451
92236396002
DMW-6
RSK 175
AIR/22451
92236396003
DMW-7
RSK 175
AIR/22451
92236396004
DMW-9
RSK 175
AIR/22451
92236396005
DMW-8
RSK 175
AIR/22451
92236396006
DMW-11
RSK 175
AIR/22451
92236396007
DMW-2
RSK 175
AIR/22451
92236396008
DMW-1
RSK 175
AIR/22451
92236396009
DMW-3
RSK 175
AIR/22451
92236396001
DMW-10
EPA 3010
MPRP/17846
EPA 6010
ICP/16062
92236396002
DMW-6
EPA 3010
MPRP/17846
EPA 6010
ICP/16062
92236396003
DMW-7
EPA 3010
MPRP/17846
EPA6010
ICP/16062
92236396004
DMW-9
EPA 3010
MPRP/17846
EPA6010
ICP/16062
92236396005
DMW-8
EPA3010
MPRP/17846
EPA6010
ICP/16062
92236396006
DMW-11
EPA 3010
MPRP/17846
EPA6010
ICP/16062
92236396007
DMW-2
EPA 3010
MPRP/17846
EPA 6010
ICP/16062
92236396008
DMW-1
EPA 3010
MPRP/17846
EPA6010
ICP/16062
92236396009
DMW-3
EPA 3010
MPRP/17852
EPA 6010
ICP/16069
92236396001
DMW-10
EPA 7470
MERP/7557
EPA 7470
MERC/7251
92236396002
DMW-6
EPA 7470
MERP/7557
EPA 7470
MERC/7251
92236396003
DMW-7
EPA 7470
MERP/7557
EPA 7470
MERC/7251
92236396004
DMW-9
EPA 7470
MERP/7557
EPA 7470
MERC/7251
92236396005
DMW-8
EPA 7470
MERP/7557
EPA 7470
MERC17251
92236396006
DMW-11
EPA 7470
MERP/7557
EPA 7470
MERC17251
92236396007
DMW-2
EPA 7470
MERP/7557
EPA 7470
MERC17251
92236396008
DMW-1
EPA 7470
MERP/7557
EPA 7470
MERC17251
92236396009
DMW-3
EPA 7470
MERP/7557
EPA 7470
MERC/7251
92236396001
DMW-10
SM 6200B
MSV/30281
92236396002
DMW-6
SM 6200E
MSV/30281
92236396003
DMW-7
SM 6200B
MSV/30281
92236396004
DMW-9
SM 6200B
MSV/30281
92236396005
DMW-8
SM 6200E
MSV/30281
92236396006
DMW-11
SM 6200E
MSV/30281
92236396007
DMW-2
SM 6200B
MSV/30281
92236396008
DMW-1
SM 6200B
MSV/30281
92236396009
DMW-3
SM 6200E
MSV/30281
92236396010
WSW-4
SM 6200B
MSV/30281
92236396001
DMW-10
SM 4500-S2D
WET/35601
92236396002
DMW-6
SM 4500-S2D
WET/35567
92236396003
DMW-7
SM 4500-S2D
WET/35601
92236396004
DMW-9
SM 4500-S213
WET/35601
92236396005
DMW-8
SM 4500-S2D
WET/35567
92236396006
DMW-11
SM 4500-S213
WET/35601
92236396007
DMW-2
SM 4500-S213
WET/35567
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc.. Page 37 of 40

aceAnalXical
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I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: DOT-504 34613.3.26
Pace Project No.: 92236396
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92236396008
DMW-1
SM 4500-S2D
WET/35601
92236396009
DMW-3
SM 4500-S2D
WET/35567
92236396001
DMW-10
EPA 300.0
WETA/21832
92236396002
DMW-6
EPA 300.0
WETA/21832
92236396003
DMW-7
EPA 300.0
WETA121832
92236396004
DMW-9
EPA 300.0
WETA121832
92236396006
DMW-8
EPA 300.0
WETA/21832
92236396006
DMW-11
EPA 300.0
WETA/21832
92236396007
DMW-2
EPA 300.0
WETA/21832
92236396008
DMW-1
EPA 300.0
WETA121832
92236396009
DMW-3
EPA 300.0
WETA(21832
92236396001
DMW-10
EPA 353.2
WETA121813
92236396002
DMW-6
EPA 353.2
WETA/21813
92236396003
DMW-7
EPA 353.2
WETA121813
92236396004
DMW-9
EPA 353.2
WETA121813
92236396005
DMW-8
EPA 353.2
WETA121813
92236396006
DMW-11
EPA 353.2
WETA121813
92236396007
DMW-2
EPA 353.2
WETA/21813
92236396008
DMW-1
EPA 353.2
WETA121813
92236396009
DMW-3
EPA 353.2
WETA121813
92236396001
DMW-10
SM 5310B
WETA121815
92236396002
DMW-6
SM 5310E
WETA121815
92236396003
DMW-7
SM 5310E
WETA/21815
92236396004
DMW-9
SM 5310B
WETA121815
92236396005
DMW-8
SM 5310B
WETA121815
92236396006
DMW-11
SM 5310B
WETA121815
92236396007
DMW-2
SM 5310B
WETA121815
92236396008
DMW-1
SM 5310B
WETA121815
92236396009
DMW-3
SM 5310B
WETA121815
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/11/2015 05:03 PM without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
Page 38 of 40

or 1
05
acQAnaiyticai4 Sample Condition U on Recei t SCUR Page 1 of 2
Document Number: Issuing Authority:
- F-CHR-CS-003-rev.15 Pace Huntersvilie Quality Office
Client Name:_ Flu( �' -3 1-fidlMu,�
Courier: ❑ Fed Ex ElUPS❑ USPS❑ ` Co Client mercial❑ Pace Other b -fit ,
Custody Seal on Cooler/Box Present: Elyes no Seals Intact: ❑ yes ❑ no
Packing Material: ❑ Bubble VDp i Bubble Bags ❑ None ❑ Other
Thermometer Used: IR Gun 61�ofType of Ice: V lue None amples on Ice, cooling process has begun
Temp Correction Factor T1401 No Correction
Corrected Cooler Temp.: •C
Temp should be above freezing to VC
Biological Tissue is Frozen: Yes No A
Comments:
t
Date and In! Is -of person examiningcontents:
Chain of Custody Present:
No
❑NIA
1.
Chain of Custody Filled Out:
No
❑N►A
2.
Chain of Custody Relinquished:
00y's--6w
❑NIA
3.
Sampler Name & Signature on COC:
s o
❑NIA
4,
Samples Arrived within Hold Time:
es ON9,
❑NIA
5.
Short Hold Time Analysis (<72hr):
es ❑No
PNIA
6.
Rush Turn Around Time Requested:
❑Yes
NIA
7.
Sufficient Volume:
s ❑No
N/A
$.
Correct Containers Used:
-Pace Containers Used:
es ❑N NIA
es ❑N ❑NIA
9.
Containers Intact:
Bell --[]No
❑NIA
10.
Filtered volume received for Dissolved tests
❑Yes ❑No
fK
11.
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
es ❑No
❑NIA
12.
All containers needing preservation have been checked.
All containers needing preservation are found to be In
compliance with EPA recommendation.
exceptions: VOA, coliform, TOC, O&G, VVI-DRO pvater)
es ❑No !A
❑Yes ❑No NIA
❑ s ❑
13.
Samples checked for dechlorination:
es ❑No
❑NIA
4.
Headspace in VOA Vials ( >6mm):
❑Yes o
❑NIA
1
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
❑Yes ❑No
❑Yes ❑No
IA
IA
1
Client Notification/ Resolution:
Person Contacted: Daterrime:
Comments/ Resolution:
SCURF Review: jDate: 1 2 '( !S
SRF Review: Date: 2 S
Note: Whenever they . a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( Le out of hold, incorrect preservative, out of temp,
Incorrect containers)
Field Data Required? Y / N
----- 9226396 -- -
IAo#
`` ti11111�11�1
�1� ._...
g2231396 „o label available)
Page 39 of 40

r
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i
CHAIN -OF -CUSTODY / Analytical Request Document
w
,aceAna1Xica1'
The Chain -of -Custody is a LEGAL DOCUMENT, All relevant fields must be completed accurately.
°
• www.paeetabs.eem
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Section A
Section B
Section C Page. of
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Required Client Information:
Required Project Information:
Invoice Information:
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Company Name:
� REGULATORY AGENCY
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Address:
f NPDES .f GROUND WATER r DRINKING WATER
Email To:
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Purchase Order No.:
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Project Name:
Paco Project
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Site Location
STATE
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RequestedDue DatefiAT:
ProjectNumber.
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DD
Requested Analysis Filtered (YIN)
Section D Matrix Codes
Required Client Information MATRIX I CODE
Drinking Water DW
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•Important Note., By signing this form you are accepting pace's NET 30 day payment terns and agmoing to late charges of 1.5% per month forany invoices
(MMIDD/YY):
30
m days.
F-ALL-0-020rev.07,
15-May-2007

aceAnalXical
www.pacelabs.com
June 10, 2015
Chemical Testing Engineer
NCDOT
Materials & Tests Unit
1801 Blue Ridge Road
Raleigh, NC 27607
RE: Project: DOT-504 34613.3.26
Pace Project No.: 92252375
Dear Chemical Engineer:
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on June 02, 2015. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Godwin
[e-mail]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 11

aceAnaVical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Certification M 99006001
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
i
CERTIFICATIONS -
I
Florida/NELAP Certification #: E87627
Kentucky UST Certification M 84
West Virginia Certification M 357
vrginiaNELAP Certification M 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 11

- aceAnalytical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
Lab ID Sample ID
92252375001 SS-2
i
SAMPLE SUMMARY
Matrix Date Collected Date Received
Water 06/02/1514:00 06/02/1514:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 11

acmnalytical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92252375001 SS-2 SM 6200B CAH 33 PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 11

aceAnalytical
www.pecolabs.com
'1
ANALYTICAL RESULTS
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: SS-2 Lab ID: 92252375001 Collected: 06/02/15 14:00 Received: 06/02/15 14:44 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
601 Volatiles by SM 6200
1,1-Dichloroethane
1,1-Dichloroethene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1,2,2-Tetrachloroethane
1,2-Dichlorobenzene
-, 1,2-Dichloroethane
1,2-Dichloropropane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Bromodichloromethane
Bromomethane
Bromoform
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dichlorodifluoromethane
Methylene Chloride
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Tetrachloroethene
Trchloroethene
Trichlorofluoromethane
Vinyl chloride
1,2-Dibromoethane (EDB)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 06/10/2015 02:38 PM
Analytical Method: SM 6200B
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
102 %
92 %
100 %
1.0
1
06/10/15 06:36 75-34-3
1.0
1
06/10/15 06:36 75-35-4
1.0
1
06/10/15 06:36 71-55-6
1.0
1
06/10/15 06:36 79-00-5
1.0
1
06/10/15 06:36 79-34-5
1.0
1
06/10/15 06:36 95-50-1
1.0
1
06/10/15 06:36 107-06-2
1.0
1
06/10/15 06:36 78-87-5
1.0
1
06/10/15 06:36 541-73-1
1.0
1
06/10/15 06:36 106-46-7
1.0
1
06/10/15 06:36 75-27-4
5.0
1
06/10/15 06:36 74-83-9
1.0
1
06/10/15 06:36 75-25-2
1.0
1
06/10/15 06:36 156-59-2
1.0
1
06/10/15 06:36 10061-01-5
1.0
1
06/10/15 06:36 56-23-5
1.0
1
06/10/15 06:36 108-90-7
1.0
1
06/10/15 06:36 75-00-3
1.0
1
06/10/15 06:36 67-66-3
1.0
1
06/10/15 06:36 74-87-3
1.0
1
06/10/15 06:36 124-48-1
1.0
1
06/10/15 06:36 75-71-8
2.0
1
06/10/15 06:36 75-09-2
1.0
1
06/10/15 06:36 156-60-5
1.0
1
06/10/15 06:36 10061-02-6
1.0
1
06/10/15 06:36 127-18-4
1.0
1
06/10/15 06:36 79-01-6
1.0
1
06/10/15 06:36 75-69-4
1.0
1
06/10/15 06:36 75-01-4
1.0
1
06/10/15 06:36 106-93-4
70-130
1
06/10/15 06:36 460-00-4
70-130
1
06/10/15 06:36 17060-07-0
70-130
1
06/10/15 06:36 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 11

acmnalXical
www.pacelabs.com
Project: DOT-504 34613.3.26
Pace Project No.: 92262375
QC Batch: MSV/32056
QC Batch Method: SM 6200B
Associated Lab Samples: 92252375001
QUALITY CONTROL DATA
Analysis Method: SM 6200B
Analysis Description: 601 by 6200E
METHOD BLANK: 1479953
Associated Lab Samples: 92252375001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1,1-Trichloroethane
ug/L
ND
1.0
06/10/15 00:31
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
06/10/15 00:31
1,1,2-Trichloroethane
ug/L
ND
1.0
06/10/15 00:31
1,1-Dichloroethane
ug/L
ND
1.0
06/10/15 00:31
1,1-Dichloroethene
ug/L
ND
1.0
06/10/15 00:31
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
06/10/15 00:31
1,2-Dichlorobenzene
ug/L
ND
1.0
06/10/15 00:31
1,2-Dichloroethane
ug/L
ND
1.0
06/10/15 00:31
1,2-Dichloropropane
ug/L
ND
1.0
06/10/15 00:31
1,3-Dichlorobenzene
ug/L
ND
1.0
06/10/15 00:31
1,4-Dichlorobenzene
ug/L
ND
1.0
06/10/15 00:31
Bromodichloromethane
ug/L
ND
1.0
06/10/15 00:31
Bromoform
ug/L
ND
1.0
06/10/15 00:31
Bromomethane
ug/L
ND
5.0
06/10/15 00:31
Carbon tetrachloride
ug/L
ND
1.0
06/10/15 00:31
Chlorobenzene
ug/L
ND
1.0
06/10/15 00:31
Chloroethane
ug/L
ND
1.0
06/10/15 00:31
Chloroform
ug/L
ND
1.0
06/10/15 00:31
Chloromethane
ug/L
ND
1.0
06/10/15 00:31
cis-1,2-Dichloroethene
ug/L
ND
1.0
06/10/15 00:31
cis-1,3-Dichloropropene
ug/L
ND
1.0
06/10/15 00:31
Dibromochloromethane
ug/L
ND
1.0
06/10/15 00:31
Dichlorodifluoromethane
ug/L
ND
1.0
06/10/15 00:31
Methylene Chloride
ug/L
ND
2.0
06/10/15 00:31
Tetrachloroethene
ug/L
ND
1.0
06/10/15 00:31
trans-1,2-Dichloroethene
ug/L
ND
1.0
06/10/15 00:31
trans-1,3-Dichloropropene
ug/L
ND
1.0
06/10/15 00:31
Trichloroethene
ug/L
ND
1.0
06/10/15 00:31
Trichlorofluoromethane
ug/L
ND
1.0
06/10/15 00:31
Vinyl chloride
ug/L
ND
1.0
06/10/15 00:31
1,2-Dichloroethane-d4 (S)
%
90
70-130
06/10/15 00:31
4-Bromofluorobenzene (S)
%
101
70-130
06/10/15 00:31
Toluene-d8 (S)
%
98
70-130
06/10/15 00:31
LABORATORY CONTROL SAMPLE: 1479954
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Spike
LCS LCS % Rec
Parameter
Units
Conc.
Result % Rec Limits Qualifiers
1,1,1-Trichloroethane
ug/L
50
46.0 92 60-140
1,1,2,2-Tetrachloroethane
ug/L
50
48.3 97 60-140
1,1,2-Trichloroethane
ug/L
50
48.5 97 60-140
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 06/10/2015 02:38 PM without the written consent of Pace Analytical Services, Inc..
Page 6 of 11

aceAnalytical
www..pacelabs.com
QUALITY CONTROL DATA
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
LABORATORY CONTROL SAMPLE: 1479954
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethane
ug/L
50
47.0
94
60-140
1,1-Dichloroethene
ug/L
50
44.0
88
60-140
1,2-Dibromoethane (EDB)
ug/L
50
50.2
100
60-140
1,2-Dichlorobenzene
ug/L
50
51.1
102
60-140
1,2-Dichloroethane
ug/L
50
47.0
94
60-140
1,2-Dichloropropane
ug/L
50
49.0
98
60-140
1,3-Dichlorobenzene
ug/L
50
49.2
98
60-140
1,4-Dichlorobenzene
ug/L
50
50.0
100
60-140
Bromodichloromethane
ug/L
50
45.0
90
60-140
Bromoform
ug/L
50
45.6
91
60-140
Bromomethane
ug/L
50
42.1
84
60-140
Carbon tetrachloride
ug/L
50
48.9
98
60-140
Chlorobenzene
ug/L
50
51.3
103
60-140
Chloroethane
ug/L
50
43.5
87
60-140
Chloroform
ug/L
50
43.4
87
60-140
Chloromethane
ug/L
50
36.7
73
60-140
cis-1,2-Dichloroethene
ug/L
50
47.6
95
60-140
cis-1,3-Dichloropropene
ug/L
50
47.6
95
60-140
Dibromochloromethane
ug/L
50
45.2
90
60-140
Dichlorodifluoromethane
ug/L
50
37.8
76
60-140
Methylene Chloride
ug/L
50
47.6
95
60-140
Tetrachloroethene
ug/L
50
49.1
98
60-140
trans-1,2-Dichloroethene
ug/L
50
46.1
92
60-140
trans-1,3-Dichloropropene
ug/L
50
48.2
96
60-140
Trichloroethene
ug/L
50
49.3
99
60-140
Trichlorofluoromethane
ug/L
50
41.3
83
60-140
Vinyl chloride
ug/L
50
41.2
82
60-140
1,2-Dichloroethane-d4 (S)
%
91
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene -dB (S)
%
98
70-130
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 06110/2015 02:38 PM without the written consent of Pace Analytical Services, Inc..
Page 7 of 11

acmnalytical
www..pacelabs.com
QUALIFIERS
Project: DOT-504 34613.3.26
Pace Project No.: 92252375
DEFINITIONS
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL- Practical Quantitation Limit.
RL- Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
Date: 06/10/2015 02:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 8 of 11
r
� JI

(I�IacieAnalytkal
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: DOT 504 34613.3.26
Pace Project No.: 92252375
- Lab ID Sample ID
92252375001 SS-2
Date: 06/10/2015 02:38 PM
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QC Batch Method QC Batch Analytical Method
SM 6200B MSV/32056
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
Page 9 of 11

(--11'11100h1111X1081*
Condltion Upon Receil
Document Number:
F-CHR-CS-003-rev.16
Client iVame:_ 14 H / -� i tt � � 11 /"i U � * Page,2 of 2 is for Internal Use Only
Courier: ❑ Fed Ex ❑ UPS❑ LISPS❑ Client C merclal❑ ��—Other my'.
Custody Seal on Cooler/Box Present- ❑ yes no Seals intact:yes ❑ no Packing Material: ❑ Bubbie
�p ubble Bags ❑ None ❑ Other
Page 1 of 2*
Office
Thermometer Used: IR Gun 140 Type of Ice: Blue None Sm les on ice, cooling
process has begun
Temp Correction Factor T1401 No Correction
Corrected Cooler Temp.: I. •C
Temp should be above freezing to 6°C
Biological Tissue is Frozen: Yes NotC!:
Comments:
Initials7�7!rson exaaqq��I Inn
ts: C d
Chan'of Custody Present:
es 0
❑N/A
1.
2.
3,
Chain of Custody Filled Out: es o ❑N►A
Chain of Custody Relinquished: Yes (❑N/A
Sampler Name & Signature on COC:
es ❑
❑N/A
4.
Samples Arrived within Hold Time:
es ❑No
A
5.
Short Hold Time Analysis <72hr):
[]yes 13 0
❑ A
6.
Rush Turn Around Time Requested:
Dyes
❑N/A
7.
Sufficient Volume:
es o
❑NIA
8.
Correct Containers Used:
-Pace Containers Used:
Yes o
Yes o
❑N/A
❑N/A
9.
Containers Intact:
flYes ❑No
❑N/A
1
11.
Filtered volume received for Dissolved tests ❑Yes ❑ o•• rA
Sample Labels match COC:
-Includes date/time/ID/Analysis Matrix:
es' ❑No
Y
❑N/A
12.
All containers needing preservation have been checked.
All containers needing preservation are found to be in
compliance with EPA recommendation.
exceptlons: VOA, MUM. TOG, 0&G. WI-DRO (water)
❑Yes []No ❑ !A
[]Yes N/A
11Yes []No
1
Samples checked for dechlorination:
❑Yes ❑No
r
4,
t eadspace in VOA Vials (>6mm):
❑Yes o
❑N/A
16.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot #-(if purchased): - - -
❑Yes []No
❑Yes ❑No
-- -
❑ /A
/A
-. -_
c;ltent Notification/ Resolution:
Person Contacted:
Comments/ Resolution:
Date/Time:
SCURF Review: 6 c Date: to-/
SRF Review: ([ j Date: U L �L
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office ( i.e out of hold, Incorrect preservative, out of temp,
Incorrect containers)
Field Data Required? Y / N
woo: szasa375"
1111111111111111111111
92252375
Page 10 of 11

,. �FaceAnalytical"
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
6
Section A Section B Section C Page: of
Required Client Information: Required Project Information: Invoice Information:
Company. n Report To: . Attention:
1902170
Address: J , Copy To: J Company Name:
� 1 ` a„�.. �`• S.. ��' /r/G (��', j REGULATORY AGENCY
Address.
NPDES GROUND WATER r' DRINKING WATER
!- UST r RCRA r OTHER
Email To:3 �••� �
LS c.A {fit AGa.
Purchase Order No.:
Paw Ouoto p . n �+
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Phone: Fax
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Project Name: �G i / r�P
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Rataronw: �/ Q7-� Tt ,
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Requested Due DateITAT:✓ 1
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Project Number. U��ys `Y :
Manager
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STATE: �fCr
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Analysis
Filtered
{Y!N)
Section D Matrix Codes
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Appendix S
TCE Concentration Trends
hart hickman
SMARTER ENVIRONMENTAL SOLUTIONS

120
100
80
60
40
20
Oct-95
TCE Concentration Trend in Near Source Area Well DMW-1 (µg/L)
Jun-97 Feb-99 Oct-00 May-02 Jan-04 Sep-05 Apr-07 Dec-08 Aug-10 Apr-12 Nov-13
f—TCE —EOS Injection (Dec. 2012)
Jul-15

200
150
100
50
Jul-98
TCE Concentration Trend in Downgradient Well DMW-6 (µg/L)
Mar-00 Nov-01 Jun-03 Feb-05 Oct-06 Jun-08 Jan-10 Sep-11 May-13 Dec-14
tTCE -EOS Injection (Dec. 2012)