Loading...
HomeMy WebLinkAboutNC0072664_Regional Office Historical File Pre 2018 (15)DIVISION OF WATER QUALITY December 2, 1996 MEMORANDUM To: Susan Robson Through: Matt Matthews 0""' ,` From: Melissa Rosebrockviz Subject: Shurtape Technologies, Inc. Boiler/Cooling Tower Chemical Additives NPDES No. NCG500323 -Gaga C� ounty ar �4i�iT�pit DEC -�' 1996 kI71S101d OF EiiV11FINI HiTAL P,"tiNi Ef&iEfi� R100ESWILE REOt.0#;AL OFFICE In July of 1996 we received a request from Shurtape Technologies, Inc. to review and evaluate several chemicals for proposed boiler and cooling tower use. Since this time we have spoken by telephone with the facility to request additional documentation and clarification of numerous issues. Our most recent conversation was 11/4/96 when I spoke with Mr. Bill Little. To this date, we have not received the requested information and are returning the request to your office with the following recommendations: 1) Biosperse 261T microbiocide - facility needs to supply half-life documentation 2) Biosperse 250 microbiocide - facility needs to complete Metals Worksheet 3) Advantage Plus 1423 deposit/corrosion inhibitor - does not appear to be used as a biocide and active ingredients are not commonly considered biocidal in nature (recommend that product be approved for use) 4) Advantage Plus 6445 deposit inhibitor - appears to be non-biocidal but we need clarification of the 0- 4% active ingredient listed as "trade secret" on the MSDS 5) Valugard 250 D cooling water treatment - cannot evaluate product in that three of the five active ingredients (1-10%) are listed as "trade secret" on the MSDS 6) Drewsperse 751 antifoulant - product appears to contain a biocidal active ingredient (10-25% quaternary ammonium compound polyethoxylate) but we need a more specific description and a Biocide 101 Worksheet would need to be completed I have also spoken with Mr. Little regarding the "trade secret" issue. I suggested that the chemical supplier could submit the information to our office directly with the appropriate pages marked "proprietary." This has worked well in the past with suppliers that were uncomfortable with this type of information being accessible. If there are questions concerning this review please contact me at (919)733- 2136. Attachments cc1V� Gleason' �1VIRO= Central files State of North Carolina % Department of Environment, Health and Natural Resources Division of Water Quality James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director F f, A-- C)•• low E July 24, 1996 ,N,c, DEPT. OF r,,.i` VIP_ONT,' , HEALT I,' MEMORANDUM NATURAL -RE60URcV DEC 4 1996 To: Melissa Rosebrock, Aquatic Toxicology nlvlelq;a of EtFt MOLNESYUE REGRIIAl OFFICE From: Susan Robson, Permits and Engineering Subject: Request,for Biocide Review Shurtape Technologies, Inc. Catawba County NPDES: NCG500323 Attached please find Biocide 101 Worksheets and supporting information for the subject facility. We are requesting that you review and comment on these worksheets. Thank you for your help in this matter. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-9919 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper • State of North Carolina Department of Environment, Health and Natural Resources - Division of Environmental Management 512 North Salisbury St=t i Raleigh, North Carolina 27611 ,.p r ; James G. Martin. Governor A. Preston Howard, Jr., n. = ~; William W. Cobey, Jr., Secretary Acting I)irc r NOTICE OF. INTENT " _~ National PolIumnt Discharz- Miminnrioh System ? Application for Coverage under General Permit NCG500000-, Non -comet cooling. warn, boiler blowdoVA—I*, cooling_ tower blowdcwn, condeasaw, and similar point source discharges. '•C 1. Name, Address, locarion, and mlenhme atmtber of facility requesting Permit & NATII z�souRcr<4 . A_ Official Name' S k rtq p e Te c t, n o t o.g i e s, Tr c. B. Mailing Address: sto ,. po l n i- Tg e DEC '�9�► (I)S tr= Address: _ ttozo Hi9�la� Ave. NE . (2)City; Hi c kot OF EfdYkF"Qki#iE (3)Stsic; N o r.t k c g e o t q NTAL FgRMEtd� (4)Zip; Z 8 (00 3 ?ESYfiIE fiEpkdAt OFFICE (5)C«mry; c ai-a w, 6 q C. Location. (Anach map delineating general facility location) (I)Str= Address: k j , (2)Ciry, Stony Po...+ (3)SmLe; K o r-t- � e 4 r o l i N q (4)Cotinry; A I e xg r% 01 e r D. Telephone Number; (toy 1 585 _ (.1511 2. Facility Contact: A_ Name; C L, i 15 Fl v il e r B. Title; Crv1ro.,►..,e.,tal Ev.gt�t'_er C. Company Name; S r t Q p e Te c h h o 1 o g t e s , -E n c D. Phone Numb=; ( 0 4 1 o a .tL 4 5'L t A. New or Proposed; ✓ B. Existing If previously permitted, provide permit nttmbcr and issue date C. Madificatioa: (Describe the nature of the modificatioaL• 4. Description of discharge A. Please state the number of separate discharge points 1.( I ; 2.(1 ; IN : 4,( ) ; _.( 7• B. Please d=nbe the amount of wastewater being discharged per each separate discharge poinc 1: gallons per day (Spd) 2�— (sFd) 3: (gpd) 4: (914 t, 32.1`t �Pd Z. G44 3Pd 3. 1z48 3p4 Page 1 1. Continuous:_., QIntermittent (please desrrlpe): All dtscl•,ar2ses art 61eac1owr, 3. Seasonal (check month(s) the discharge occurs): January (1; February (]; Mph [ ]: April j May ( ];June (1; July ( ]; .August ( j; September (1; Ocmber ( ]:.November ( ]; December [ 1. 4. Now many days per week is there a discharge?(check the days the discharge ocmtrs) Monday N. Tuesday K Wainesday W. 'Thursday H,Fhday N. Sanuday fQ, Sunday 5. Now much of the volume discharged is trtated? (stare in percent) 100 % D. What type of wastewater is discharged, per scparate a sdmrge point. (Fl= cheek next to cm=t type): 1. Non -contact cooling water; 2. Boiler blowdown: 3 3. Cooling tower blowdown; ► 2 4; Catdei>sate _.. S. Other(please describe): Please at any mown pollutants that are present in the discharge, per each separate discharge point (if applicable): E. Please d=,-fDe the type of process the cooling water is being discharged from, per scpa ate discharge point (Le. compressor, boiler blowdown, cooling tower blowdown, air conditioning unit, 1. coolineJ -tower Z.-C-ootln3 -rower 3. 13011er <gll blo..+dow-) F. Pica se check the type of chemical added to the wastewater for treatment or other, per separate discharge Point: 1. Bic cid= 1 2 2. Corrosion iahibitars; 3 3. Chlorine; 4. Algae control: 5. Other(plcase dcscipe); 6. None; If 1.2,3,4, or 5 was checked. please state the name and manufacturer of the chemical additive. Also include a completed Biocide 101 form, and mamriac:urers' information on the additive with the application for the Division's review, See a+-r q c % rh a Y.T's G. Is there any type of treatment being provided to the wasmwater before discharge (i.e. retention ponds, settling ponds, etc.): if yes, please describe. Give design specifics (i.e. design volume, retention time, surf= area, etc.). Existing treatment facilities should be described in detail and design criteria or Operational data should be provided(including calculations) to ensure that: the facility can comply with requirements of the General PC nip No NO"IE: Construction of any wastewater treatment facilities require submission of three (3) sets of plans and specifications along with their application. Design of treament facilities must comply with requitement 15A NCAC 21-1 .0138. If construction applies to the discharge, include the there sets of plans and gxrincadons with the application. 5_ Whatis •thc.n==zf the Ix-i-zs applying for this permit?. Tq P e *' a •, f q ci re 6.-Nameofreceivingwa= T6«d Creek-'lodki., Pee Dee Classific2 om (Attach a USGS topographical map with all discharge point(s) cieariy marl Page 2 7. Is the di. -.barge dh=dy to the riving wa=" (YAN) N o If no, state- tate spu3ca11y the disch-urge point t�iaz clearly tie patf:way to the potencia! rx� ving warms on the site map. (this includes tracing the pathway of the storm xwer to its discharge point. if a rcrm sewer is the only viable means of discharge.) - .. 8. PSease sddress Possible nan-dischage al=r.Wves. for the following opdcns: A. Connearon to a Regional Sewer Collection Systrm; 13. Subsurfak~ Disposal; C Spray Irrigation; \ 'eY.e is ho re9"ongl SC,,,gge- CalItC{,o, 3'1IteV.•, r., *r%%e 4req T%,c Q19n't �%QI Its O•Jr% Srir<,II p4ckg3e t'r-Ca1-M�ht. 1>14nt- wr„c1, wovIA r'(It be abte,-to K9 ndte- T►,�s addif-renal 104 d,n3 . 9. I rsafy that I am fami.Iiar with the information coniained in the application and that to the best of my knowledge and belief such information is true, complete, and nenrrarr• Printed Name of ?--son Signing Title Date A.pplk=on Signed w r N L i77rZj-J,e vp 5-8'-96 Signatur of Applicant 6j• lOF • : to • : ' : • tr Any person who knowingly makes any false stamm=. representadon, or certification in any applicarion, record, report, plan or other document filed or rrquirod to be maintained under Article 21 or rcguLarions of the Environmental Ma nagetnent Commission implementing that Ardcle, or who falsifies, tampers with or knowingly renders inaccurate any mcading or monitoring device c r method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed S10,000, or by imprisonment not to exceed six months; or by both_ (18 U.S.C. Section 1001 provides a punishment by a fine of not morn than S10,000 or imprisonment not more than 5 years, or both, for a similar offense.) Notice of -Intent must be w..=mpanied by a check or money order for S400.00 made payable to the North Carolina Department of Environment. health, and Nan=I Resources. Mai thrt~ (3) copies of entire pac3mge to: Division of Environmcnral Mangy tncnt NPDES Permits Grotro Post Officc Box 29535 Raleigh, Norrh Carolina 27626-0535 —Page 3 Facility Name: S%t�rtq�e Teckalo.5tes� SJ-on NPDES #: NC 00-12(0(, BiOCIDE/CHEMICAL TREATMENT WORKSHEET•FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface North Carolina. This worksheet must be compieted separately for each biocidal product in use. This worksh etters is tobereturned with all appropriate data entered into the designated areas with calculations performed as indicated. I- Facility Name S �I"r t 5 P e T e C L% ►%o 10 NPDES n NC 0 01 2lo6 County A F e X a„d-e , OutfaII T 001 Receiving Stream76ird C►-ee{< Y"kil_Tee Dee Rrver .2 7Q10 (cfs) (All above information supplied by the Division of Environmental Management) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D. = . 00055(fl (in M.G.D.) P!ease calculate the Instream Waste Concentration (1WC in percent) of this discharge using the data entered above. IWC = (_4.D.D-) X 100 _ (.000556) X 100 (/Q10)(0.646)+(.A,.D.5) - ( .z )(0.646) ss6T 00p () This value (IWC) represents the Waste concentration to the receiving stream during low flow conditions. IL What is the name of the whole product chemical treatment ro p posed for use in the discharge identified in Part I? • Btosperse Z61 T Mrc,o61oclae Please list the active ingredients and percent composition: Brp�-^e)Ck10ro d,�.etL, �w+i da�oltdtnedtone °i 0 What feed or dosage -ram (D:R;j.}S used in this application? The units must be converted to maximum grams Of whole product used in a 24hr period. ' D.R.= 3y 0 , i 9 grams/24hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 aal, water XIbs X specific gravity of product X 49 cl, 128 fl. oz. 1 gal. water 1 lb. D.E.M. Form 101 (2/95) 1 Facility Name: Si,vrt9 Dt Tecl�r,ojo ies Stor, NPDES x: NC Ob`1 Z -64 Estimate total volume of the water handling system between entry of biocidal product and NPDES d' point. On an attached sheet please provide justxf catiomaverage cc �s n for this estimate (system volue, averach�o blowdown, holding lagoon size, etc.) b cycles per volumes • 03(0 303 million gallons TvSTI-f:rc -i+ on Systevn Volume What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. 8 •O What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) an d roceedegradation must be stated at pH level within 1/2 pH standard unit within handling system P Enterdthe half lire to asterisk.the Life is the time required for the initial product to degrade to half of its original concentration). The copies of the sources of this data. ) Please provide i H.L. = 003,}'1Z2 pays r ..�'•F-'� :. The decay rate is equal to 1 X Q_o9 = ► 9 8 . Z Ff.L. =Decay Rate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. j 3 i D.F. (,00055(. (Volume) + (D.K.) _ �• 0 3 ` 30`3 ) + ( l9 S -t z) = t 5 8 . -I3 Calculate Steady State Discharge Concentration: 3 o , Dischg Conc. `� f 9 ) (D.F.)(Volume)(3785) (19S--1 )(.o3(- o3 )(3785) - •otz�}5g mg/I Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischg_ Conc) x (IWC%1 .otzysg ' 100 r 100x — •.00a05-33 mg/I Ill.Calculate regulated limitation. Receiving Stream Concentration List all LC5o data available for the whole product according to the following columns. JP-94 : - Please fro, de.=cPies of the sources of this data. (Note that units should be in Organism D g F �, h, q M g Tesi Duration , LC50 (rncyl) g h q Rq in 6Uw Tt•-ov-r 96 l,ourS . � M�h�or,.) 9 L Viou rs (�L hours Z ZS S�eePI CLc1+ MrnV%0Lj 9L- `iL 1-,ourS ►3 , 00 ours Zo , 00 9t„ kotjrS (,.40 . 00 D.E.M. Form 101 (2/95) 2 Facility Name: S G"'-f a e Te c� h o► o c1 S1on NPDES #: NC 0 O, Z to G Choose the lowest LC50 listed above: Enter the LC50: If the half life (H.L) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LCSo . OZ 3 mg/l If the half life (H.L.) is greater than or aqua[ to 4 days or unknown, perform the following calculation_ Regulated Limitation = 0.01 x LCSSO _ mg/l Choose the appropriate regulated limhation from the calculations immediately above and place in this blan k, Oz3 mg/liter From Part [I enter the receiving stream concentration: .0000 553 mg/liter IV. Analysis. If the receiving stream concentrations greater than the calculated regulated limitat ion, den this biocide is unacceptable for use. • e--1 7� r.E, ,7-AV Name (Pant) Si3rrature . Person in Responsible Charge Dam "-s —�— t6 °rsan Catnple�rsg This WQ*shast Dad (If Different From Above) s a. D.E-M- Fozm 101 (2/95) 3 FacilityName: Shvr- -pe Techholo qjles, Stonl NPDES #: NC 00--1 2(-(-`4 BIOCIDE/CHEMICAL TREATMENT WORKSHEET-FORM 101 The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of North Carolina. This worksheet must be completed separately for each biocidal product In use. This worksheet is to be returned with all appropriate data entered into the designated areas with calculations performed as indicated. I. Facility Name S- e r t• q p e Te c k r, o l p I e s -L h e NPDES#NC 00-126(0�} 0utfaII # 00 1 County �� ex ar•oAe r' Receiving Stream Thircl Cv,eek Ir Yaddkl'n - Pee Dee P%iver- 7Q10 • 2- (cfs) (All above information supplied by the Division of Environmental Management) What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body? A.D.D. _ •000556 (in M.G.D.) Please calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered above_ IWC = - (A.D.D_) X 1�00 _ (000s56) X 10 0 (7010)(0.646) + (A.D.D) — ( 2. ) (0.6 =i_ 6) (oC0ss6) = . ' k Z.B�}8 �o . T This value (IWC) represents the waste concentration to the receiving stream during low flow conditions. IL What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I? gIo$perc 250 Mrcro' 10c10le. Please list the active ingredients and percent composition: reSIU Nt'Irgt� <<j S - C(.loco - 2. - N1 eth� — I'sai-kIaj 01% 3-one % Mg5'�e. vr-% CL,1oridl� 2 N+etr,yl 4 'LSp�hl9�oln - 3 - o►.e 35. °/c° cupric N r'tr-q*e . 1 '/c What feed or dosage -rate(D.Rj Is used in this application? The units must be converted to maximum grams Of whole product used in a 24hr period. ' D.R.= 2 9 4 .8 3 grams/24hr period Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is: Grams of product = fluid oz. of product X 1 aal, watgr X g,34 lbs_ X specific gravity of product X 45�,�c 128 fl. oz. 1 gal. water 1 lb. D.E.M. Form 101 (2/95) 1 Facility Name: S�"'rt q p e Te c >, hot og � e S Srt-o., %l NPDES ;#: NO 0012(o Estimate total volume of the water handling system between entry of biocidai product and NPDES dischazQ, point. On an attached sheet please provide justification for this estimate (system volume, average cycles per b blowdown, holding lagoon size, etc.) Volume .03(.303 million gallons :rust, C'ft o ►. S ys+e „, v of ,„ e What is the pH of the handling system prior to biocide addition? If unknown, enter N/A. g • Z What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half Life is the time required for the initial product to degrade to half of its original concentration). Please provide copies of the sources of this data. H.L. = Z . Sq Days The decay rate is equal to 1 X o.69 = Z6(.4 =Deca H.L. y Rate (D.K.) Calculate degradation factor (D.F.). This is the first order loss coefficient. D = (V D.D- + Dlume).K. — (•00055t.) ( '{ } = z811 1 Calculate Steady State Discharge Concentration: Dischg Conc. = (D. R_•) . _ ( 29(} . $ 3 ) 1 `—j (D.F.)(Volume)(3785) (, 2$ t I I ) (. o3(• 3o 3 ) (3 7 8 5) Calculate concentration of biocide instream during low flow conditions. (Receiving Stream Concentration) (Dischq_ Conc.) x (IWC%) 100x..03Z(o3 100 m n g Receiving Stream Concentration Ill. Calculate regulated limitation. List all LC50 data available for the whole product according to the following columns. (Note that units should be in Please provide :copies of the sources of this data. Organism Test Duration LC50 EgSieOys+e,.. 48 t.rs 19 ChQ..nel Cot -Cf's k (o day., L F-'o'egd Mrr%now Rgrn bow ►►-out D4p1,►,rg Ma9r,g S6,eeps►,ead Mrnno',J � dQ� `� 8 t•+ r s .1 g.0 9.3 10.0 Z0.0 D.E.M. Form 101 (2/95) 2 Facility Name: Si urtaPe Tecl"O\o31eS Ston� NPDE0�.,,Z��S #: NC � Choose the lowest LC50 listed above: Enter the LC50: If the half life (H.L) is less than 4 days, perform the following calculation. Regulated Limitation = 0.05 x LC5o = • 095 mg/I If the halt life (H.L.) is greater than or equal to 4 days or unknown, perform the following calculation. Regulated Limitation = 0.01 x LCM = mg/I Choose the appropriate regulated limitation from the calculations immediately above and place in this blank; 09 S mg/liter From Part 11 enter the receiving stream concentration: .03.z63 mg/liter IV. Analysis. If the receiving stream concentration is greater than the calculated regulated limitation, then this biocide is unacceptable for use. Name (Print) A)*/Av S,grrrmre Date Person in Responsible Charge C>%ri.T ,udeY- 5--1— at PecSnn Catnpleft.Thm Workshest Date (If Different From Above) D-�.M. Form 101 (2/95) 3 Attachment; 1. 500 ton cooling tower 2. 100 ton cooling tower 3. Boiler Chemical Advantage Plus 1423 Advantage Plus 6445 Valugard 250D Drewsperse 751 Biosperse 250 Biosperse 261-T Enclosures; Added to 3 3 1,2 1 1,2 1,2 MSDS for all the above chemicals. Environmental Profiles for the biocides Biosperse 250 and 261-T. USGS map showing plant location. Drawing of plant showing location of discharge point sources. 11 MATERIAL SAFETY DATA SHEET Ashland Chemical Co. Page 001 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0275696-003.001 ADVANTAGE PLUS 1423 DEPOSIT &CORRSN INH 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: ADVANTAGE PLUS 1423 DEPOSIT &CORRSN INH General orGeneric ID: DEPOSIT &.CORROSION INHIBITOR Company Emergency Telephone Numbe-r":.-"- ..." Ashland Chemical Co. 1-800-ASHLAND (1-800-274-5263) P.O. Box 2219 24 hours everyday Columbus, OH 43216 614-790-3333 Regulatory Information Number: 1-800-325-3751 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) CAS -------------------------------------------------- Number % (by weight) ------------- DIETHYLETHANOLAMINE ------------- 100-37-8 1.0- 10.0 ETHYLENEDIAMINE TETRAACETIC ACID NA SALT 64-02-8 1.0- 10.0 SODIUM SULFITE 7757-83-7 1.0- 10.0 SODIUM LIGNOSULFONATE 8061-51-6 1.0- 10.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Exposure causes irreversible eye damage. Symptoms may include stinging, tearing, redness, swelling, corneal damage, and blindness. Additional symptoms of eye exposure may include: blurred vision halo vision (characterized by blurring vision around bright objects) Skin Exposure causes severe skin irritation. Symptoms may include redness, burning, and severe skin damage. Skin absorption is possible, and may contribute to symptoms of toxicity from other routes of exposure. Swallowing Single dose oral toxicity is low. Swallowing small amounts during normal handling is not likely to cause harmful effects; swallowing large amounts may be harmful. Inhalation Exposure to vapor or mist is possible. Symptoms of Exposure gastrointestinal irritation (nausea, vomiting, diarrhea), irritation (nose, throat, respiratory tract), headache, muscle weakness. Target Organ Effects Overexposure to this material (or its components) has been suggested as a cause of the following effects in laboratory animals, and may aggravate pre-existing disorders of these organs in humans: liver abnormalities, eye damage, kidney damage. Continued on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. z ADVANTAGE PLUS 1423 DEPOSIT &CORRSN INH Page 003 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0275696-003.001 Hazardous Products of Combustion May form:, carbon dioxide and carbon monoxide, nitrogen compounds, sulfur compounds, various hydrocarbons. Fire and Explosion Hazards No special fire hazards are known to be associated with this product. Extinguishing Media regular foam, water fog, carbon dioxide, dry chemical. Fire Fighting Instructions Wear a self-contained breathinga - pparatus with a full facepiece operated in the _.._...positive. pressure demand. mode with.. appropriate.. turn -out resistant gear. and.. •.chemical personal protective equipment. Refer to the.personal�protectiye-•-" equipment section of this MSDS. NFPA Rating Health - 3, Flammability - 0, Reactivity - 1 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. - Large Spill Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand,.clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7.. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. :Since emptied. containers retain product residues (vapor, liquid, and/or solid)., precautions given in the data sheet must be. observed. all hazard Storage - _.__.Keep _.from -..freezing.. ..... 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) Skin Protection Wear resistant gloves such as:, neoprene, To prevent repeated or prolonged skin contact, wear impervious clothing and boots.. Continued on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. ADVANTAGE PLUS 1423 DEPOSIT &CORRSN INH - Appearance No data State LIQUID Physical Form HOMOGENEOUS SOLUTION Color DARK BROWN Odor No data pH 13.0 Freezing Point 20.0 F (-6.6 C) Solubility in Water SOLUBLE Page 005 Date Prepared: C1/05/96 Date Printed: 02/16/96 MSDS No: 0275696-003.001 10. STABILITY AND REACTIVITY i Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition May form:, carbon dioxide and carbon monoxide, nitrogen compounds, sulfur compounds, various hydrocarbons. Chemical Stability Stable. Incompatibility Avoid contact with:, copper, reactive metals such as aluminum and magnesium, strong mineral acids, strong organic acids, strong oxidizing. agents.. 11. TOXICOLOGICAL INFORMATION No data 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state 1. and federal regulations. Continued on next page u MATERIAL SAFETY DATA SHEET - Ashland Chemical Co. Page 007 I Date Prepared: 01/05/96 Date Printed: 02/16/96 ,ADVANTAGE PLUS 1.423 DEPOSIT &CORRSN INH MSDS No: 0275696-003.001 New Jersey RTK Label Information DIETHYLAMINOETHANOL 100-37-8 Pennsylvania RTK Label Information ETHANOL, 2-(DIETHYLAMINO)- 100-37-8 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is'not warranted to be whether originating., with the company or_ not. Recipients. -are advised to confirm in advance of need that the information is -current., applicable, and suitable to their circumstances. Last page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. ADVANTAGE PLUS 6445 DEPOSIT INHIBITOR -1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Material Identity Product Name: ADVANTAGE PLUS 6445 DEPOSIT INHIBITOR General or Generic ID: DEPOSIT INHIBITOR Page 001 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0275693-002.001 Company Ashland Chemical Co. Emergency Teleph-one� �Number-:'- 1-800-ASHLAND P.O. Box 2219 24 hours everyday-800-274-5263) Columbus, OH 43216 614-790-3333 Regulatory Information Number: 1-800-325-3751 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients) CAS Number --------------------------------------------- =- (by -weight) WATER ----- ------------- SODIUM HEXAMETAPHOSPHATE 79.0- 83.0 E TETRAACETIC ACID NA SALT 10124-56-8 8.0'- 12.0 TRADE SECRET 64-02-8 2.�4. L LFONATE, SULFOMETHYLATED 68512-34-5 1. I q. .'�r>r.• T!'1 i.•.�T i Tn�. 7.7 nil 3. iIN''T 1LL V- i tarft, stJi4 Potential Health Effects Eye Exposure may cause mild eye irritation. Symptoms may include stinging, tearing, and redness. Skin Exposure may cause mild skin irritation. Symp burning. toms may include redness and Swallowing Single dose oral toxicity is low. Swallowing small amounts during normal handling is not likely to cause harmful effects; swallowing large amounts may be harmful. Inhalation Exposure to vapor or mist is possible. Symptoms of Exposure gastrointestinal irritation (nausea, vomiting, diarrhea), irritation (nose, throat, respiratory tract). Target Organ Effects No data Developmental Information No data Continued.,on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. Page 003 Date Prepared: 01/05/96 Date Printed: 02/16/96 ADVANTAGE PLUS 6445 DEPOSIT INHIBITOR MSDS No: 0275693-002.001 Fire and Explosion Hazards No special fire hazards are known to be associated with this product. Extinguishing Media regular foam, water fog, carbon dioxide, dry chemical. Fire Fighting Instructions Water may be used to keep fire -exposed containers cool until fire is out. Wear a self-contained breathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn -out gear and chemical resistant personal protective'equipment.. Refer to the personal 'protective equipment section of this MSDS. NFPA Rating Health - 1,:Flammability•= Or, Reactivity.- 0 . 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. Flush area with water. Large Spill Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area of spill to prevent spi eadiii9 puwp iiyU'*(! `to' salvage tank-: itelilairl iiiy -liquid may 'be 'taken up on sand, clay, earth, floor absorbent, or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard ....precautions given in the. data sheet..must. be „observed. Storage. Keep from freezing. 8. EXPOSURE CONTROLS/PERSONAL.PROTECTION Eye Protection Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are -advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) ,Skin Protection Wear resistant gloves such as:, polyvinyl chloride, To prevent skin contact, wear impervious clothing and boots.. Continued on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. ~ ADVANTAGE PLUS 6445 DEPOSIT INHIBITOR - Appearance No data State LIQUID Physical Form HOMOGENEOUS SOLUTION Color CLEAR TO HAZY BROWN Odor No data M 7.0 Page 005 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0275693-002.001 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will not undergo hazardous polymerization. Hazardous Decomposition May form:, carbon dioxide and carbon monoxide, nitrogen. oxides, various hyurocar bolis. Chemical Stability Stable. Incompatibility Avoid contact with:, strong mineral acids, strong organic acids. 11. TOXICOLOGICAL INFORMATION No data - 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations. Continued on next page MATERIAL -SAFETY DATA SHEET Ashland Chemical Co. Page 007 } Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0275693-002.001 ADVANTAGE PLUS 6445 DEPOSIT INHIBITOR New Jersey RTK Label Information SODIUM PHOSPHATE, TRIBASIC 10124-56-8 Pennsylvania RTK Label Information METAPHOSPHORIC ACID (H6P6018), HEXASODIU 10124-56-8 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is•not warranted to be whether originating with the company or not. Recipients are . advised -to confirm in advance of'need that.the information is current,: applicable,- and suitable to their circumstances. Last page PAGE 000 ASHLA`D CHEMICAL COMPANY - 24—HOUR MATERIAL SAFETY Drew Divisions Emergency DATA SHEET' (20 Ashland One: Drew Plaza; Boonton, NJ 07005 Telephone ' Phone 1) 263-7600,. (800)•274-5263 or 9 Telex 13644 FAX (201) 263-4482 (800) ASHLAND 000145 `' VALUGA IS 250 COOLING WATER TREAT Page: 1 THIS MSDS COMPLIES WITH 29 C 10.1200 (THE HAZARD COMMUNICATION STANDARD) s:sasasassssssasasasssssassss::sssassasssas:sassaa:ssasaasaaasaasssssssssssasssasasasssss:ssassaassssassasssasaa Product Name: VALUGARD 250 D COOLING WATER .TREAT F Data Sheet No: 0300131-001.000 DREW INDUSTRIAL DIVISION OD 10 92.2 - Prepared: 03/16/95 9407-8 SOUTHERN PINE BLVD. Supersedes: ( N/A )Print Date: 04/29/95 PRODUCT: 4307 CHARLOTTE INVOICE: NC 28273 INVOICE DATEo- TO: DREW INDUSTRIAL DIVISION 9401-8 SOUTHERN PINE BLVD. DISTRICT MANAGER CHARLOTTE NC 28273 SECT I ON OD General or Generic ID: COOLING WATER TREATMENT DOT Hazard Classification: NOT APPLICABLE SE CT I ON I I -COMPONENTS IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA-TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION IN DIENT % (by WT) PEL - TLV Note DE SECRET 1-10 ( 1) DE SE s 1-10 ( 2) DE SECRET 1-10 ( 3) TRIAZOLE a 1-10 ( 4) SODIUM MOLYBDATE• "' 1=10 5 MG/M3 5 MG/M3 CAS #: 7631-95-0 Notes: ( 1) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL ( 2) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL ( 3) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL ( 4) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL = THE SPECIFIC CHEMICAL NAME OF THIS COMPONENT. IS BEING WITHHELD AS A TRADE SECRET. SECTI ON III-PHYSI CAL DATA Boiling Point for COMPONENT( 70-85%) 212.00 Deg F ( 100.00 Deg C) @ 760.00 mm Hg Vapor Pressure for COMPONENT( 70-85%) 17.50 mm Fig @ 68.00.Deg F ( 20.00 Deg C). Specific Vapor Density AIR = 1 > 1.00 Specific Gravity 1.113 @ 77.00 Deg F ( 25.00 Deg C) Percent Volatiles 70-85% Evaporation Rate SLOWER THAN ETHER pH 12.5 Appearance YELLOW State LIQUID Form HOMOG SOLN FLASH POINT NOT APPLICABLE EXPLOSIVE LIMIT (LOWEST VALUE OF COMPONENT) LOWER .9% EXTINGUISHING MEDIA: REGULAR FOAM OR WATER FOG OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM:, VARIOUS HYDROCARBONS, NITROGEN OXIDES, CARBON DIOXIDE AND CARBON MONOXIDE CONTINUED ON PAGE: 2 aSt1la:�ll' ReAL LU_ WAIN Y . 24—HUUlt ►- Drew Divisions:-" Emergency MATERIAL SAFETY Ashland .one'.Drew Plaza, Boonton, NJ 07005- Telephone ;.DATA SHEET t. Phone (201) 263-7600 (800) -' 274-5263 "or ® °Telex 13644 FAX (20.1) 263-4482 (800) ASHLAND 000145 VALUGARD 250 D` COOLING WATER TREAT Page: 2 FIREFIGHTING PROCEDURES: WEAR A SELF—CONTAINED BREATHING APPARATUS WITH A FULL"FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH APPROPRIATE TURN —OUT GEAR -AND CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT. REFER TO THE PERSONAL PROTECTIVE EQUIPMENT SECTION OF THIS MSDS: SPECIAL COPPERFIRE ETC. TO RELEASE�HYDROGENCAN GAS WHICH CAN FORM EXPLOSIVE REACTIVE MIXTURESMETALS SUCH AS ALUMINUM. ZINC, MAGNESIUM, WITH AIR NFPA CODES: HEALTH— 3 FLAMMABILITY— 0 REACTIVITY-1 PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. a :i EFFECTS OF ACUTE OVEREXPOSURE: EYES CORNEAL DAMAGE CAUSES IRREVERSIBLE EYE DAMAGE. SYMPTOMS MAY INCLUDE.STINGING, TEARING, REDNESS— SWELL.ING, — SKIN — EXPOSURE CAUSES IRREVERSIBLE SKIN DAMAGE. SYMPTOMS MAY INCLUDE REDNESS SWELLING BURNS, AND SEVERE SKIN DAMAGE. PRE—EXISTING SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE % THIS MAi:LRIAL. y BREATHING — EXPOSURE TO VAPOR OR MIST IS POSSIBLE. EXPOSURE MAY BE HARMFUL OR FATAL. SYMPTOMS MAY INCLUDE SEVERE IRRITATION AND BURNS TO THE NOSE, THROAT; AND RESPIRATORY TRACT. PRE—EXISTING LUNG DISORDERS (E.G. ASTHMA —LIKE CONDITIONS) MAY BE AGGRAVATED By - EXPOSURE TO THIS MATERIAL. SWALLOWING — MAY BE HARMFUL OR FATAL. SYMPTOMS MAY INCLUDE SEVERE IRRITATION AND BURNS OF THE MOUTH, THROAT, AND DIGESTIVE TRACT. i FIRST AID: IF ON SKIN: IMMEDIATELY FLUSH SKIN WITH WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. SEEK IMMEDIATE MEDICAL ATTENTION. ASH CLOTHING BEFORE REUSE AND DECONTAMINATE OR DISCARD CONTAMINATED SHOES. IF INWILE:HOLDING EYELIDS APART IF SYMPTOMS DEVELOPIMMEDIATELY ASFLUSH A RESULT 0OF APORWITH EXPOSURE, IMMEDIATELY MOVE15 MINUTES INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR BEFORE FLUSHING AS RECOMMENDED ABOVE. .SEEK IMMEDIATE MEDICAL ATTENTION. TO IF THE MOUTHSEEK IMMEDIATE MEDICAL AND THROAT. IF INDIVIDUAL IISOCONSCIOUSTINDUCE AND ALERT ITMMEDIATELY RINSEVOMITING LMOUTHSWITHRTHER WATER AND GIVE MILK OR WATER TO DRINK. IF POSSIBLE, DO NOT LEAVE INDIVIDUAL UNATTENDED. IF BREATHED: IF SYMPTOMS DEVELOP., MOVE INDIVIDUAL AWAY FROM EXPOSURE AND INTO FRESH AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ATTENTION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. KEEP PERSON ARM AND QUIET; SEEK IMMEDIATE MEDICAL ATTENTION. PRIMARY ROUTE(S) OF ENTRY: INHALATION, SKIN CONTACT HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT WITH: STRONG ORGANIC ACIDS, STRONG MINERAL ACIDS., REACTIVE METALS SUCH AS ALUMINUM AND MAGNESIUM, COPPER, ORGANIC MATERIALS STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE BEEN SPILL: PERSONS STOPWSPILLGATRSOU PROTECTIVE DIKKEEIA� EQUIPMENT SSHOPILL TO PREVENT SPREADING,OPUMPILIQUDITOCLEAN—UPSALVAGE HAS TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELER INTO CONTAINERS. :•=.WASTE "DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE•AND FEDERAL REGULATIONS. • . RESPIRATORY PROTECTION: IF WORKPLACE EXPOSURE LIMITS) OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION II), A NIOSH/MSHA•APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS (SEE YOUR INDUSTRIAL HYGIENIST). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. VENTILATION: PROVIDE'SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S): PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NEOPRENE, NITRILE RUBBER EYE PROTECTION: CHEMICAL SPLASH GOGGLES AND FACE SHIELD (8" MIN.) IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED• HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR INDUSTRIAL HYGIENIST). OTHER PROTECTIVE EQUIPMENT: TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING.AND BOOTS. CONTINUED -ON PAGE: 3 MATERIAL SAFETY DATA SHEEET Ashland ASHLAND` CHEMICAL COMPANY ..Drew Divisions. One, Drew 1"Boonton 3 760 J 07005 Phone f)2tdt Telex 13644 FAX (201) 263-4482 24-HOUR Emergency Telephone �800� 274-5263 800 ASHLAND DEFINITIONS This definition page is intended for use with Material Safety Data Sheets supplied by the Ashland Chemical Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G — Occupational Health and Environmental Control, and subpart I — Personal Protective Equipment, for aeneral quidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAL OR GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1% in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC, or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in. the product Negative conclusions concerning carcinogenicity are not reported. Additional health information may be found in Section V. Components subject to the reporting requirements of Section 313 of SARA Title III are identified in the footnotes in this section, along with typical percentages. Other components may be listed if deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELS) and American Conference of Governmental Industrial Hygienists (ACGIH) Threshold limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is,listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If the Specific Vapor Density of a product is not known, the value is expressed as lighter or greater than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value. is expressed as less than or greater than water. pH: If applicable. .-PERCENT - -VOLATILES: Percentage . of . material with initial -boiling point below. 425• degrees :Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. ,SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowset value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heating, burning or other reactions. SECTION IV (cont.) EXTINGUISHING MEDIA: 'Following National Fire Protection Association criteria FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporization. combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product THRESHOLD LIMIT VALUE For product EFFECTS OF ACUTE OVEREXPOSURE Potential local and systemic effects due to single or short term overexposure to the eyes and skin or through inhalation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or .long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. , STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and .methods of containment, clean—up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION Vill PROTECTIVE EQUIPMENT TO BE USED Protective equipment• which may be needed when handling the product SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. or. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. "EMPTY" drums should not be given to individuals. Serious accidents have resulted from the misuse of "EMPTIED" containers (drums,pails,etc.). Refer to Sections "I __J IV ' ASHLAND CHEMICAL COMPANY Drew Divisions. 24-HOUR MATERIAL SAFETY ?,: Emergency ASh1and -one Drew Plaza-;, Boonton,~ NJ 07005 Telephone 14 DATA SHEET Phone (201) 263.-7600 (800) 274-5263 or e Telex'13644 FAX (201)'263-4482 (800) ASHLAND 000�as VALUGARD 250 D COOLING WATER TREAT Page: 3 CONTAINERS -OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED.SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL .HAZARD PRECAUTIONS GIVEN IN THEE DATA SHEET MUST BE OBSERVED. KEEP FROM FREEZING. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE -BUT IS NOT WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE -TO -THEIR CIRCUMSTANCES. MATERIAL` SAFETY DATA SHEET Drew .Industrial Division ASHLAND CHEMICAL INC. - One Drew, Plaza, Boonton, New Jersey 07005 Phone (201) 263-7600/Telex' 136444 e 24-HOUR Emergency Telephone 1(800) 274-5263 or 1 (800) ASHLAND 005830 ..DREWSPERSE 751 ANTIFOULANT Page: I THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) sssaaasas:sszasssssasssa:ssaaazssasassssas::szaaassasasssaszsassaasazssasaassssssaszassasassasaazsasaasss:zassas Product Name: DREWSPERSE 751 ANTIFOULANT C Data Sheet No: 0188008-001 OD 10 .922 - Prepared: 11/22/85 DREW INDUSTRIAL DIVISION Supersedes: ( N/A ) 500 ARCHDALE DRIVE SUITE 115 PRODUCT: 1062 CHARLOTTE INVOICE: NC 28210 INVOICE DATE: DREW INDUSTRIAL DIVISION 500-ARCHDALE DRIVE DISTRICT MANAGER General or Generic ID: ANTIFOULANT DOT Hazard Classification: NOT APPLICABLE IF PRESENT, IARC. NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TI-LE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION INGREDIENT % (by WT) PEL TLV -Note - QUATERNARY AMMONIUM COMPD POLYETHOXYLATE 10-25 ( 1) r Notes: ( 1) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL SECTION III -PHYSICAL DATA Boiling Point for COMPONENT(- 70785%) 21200 Deg F 100:00 Deg C) @ 760.00 min Fig Vapor Pressure for COMPONENT( 70-85%) 175 @ .0 Deg ( 20.00 Deg C) Specific Vapor -Density LIGHTER THAN AIR Specific Gravity 1.030 - 1.060 @ .77.00 Deg F = ( 25.00 Deg C) Percent Volatiles 70-85% Evaporation Rate SLOWER THAN ETHER pH 4.5 - 7.0 Appearance CLEAR TO SLIGHTLY HAZY State LIQUID SECT I ON IV -FIRE AND EXPLOSION INFORMATION FLASH POINT >200 Deg F ( > 94 Deg C) EXPLOSIVE LIMIT :. NOT APPLICABLE EXTINGUISHING MEDIA: WATER FOG OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION OR COMBUSTION MAY PRODUCE:, CARBON DIOXIDE AND CARBON ..MDNOXIDE. OXIDES.OF NITROGEN, AMMONIA, AND/OR, HYDROGEN CHLORIDE FIREFIGHTING PROCEDURES: WATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF ' THE FIREFIGHTER, ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. SPECIAL FIRE & EXPLOSION HAZARDS: NOT APPLICABLE NFPA CODES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY- 2 SECTI ON V�- HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED: SEE SECTION VIII. EFFECTS OF ACUTE OVEREXPOSURE: SKIN - MAY CAUSE IRRITATION. EYES - CAN CAUSE MODERATE IRRITATION, REDNESS, TEARING. IF SWALLOWED - MAY CAUSE GASTROINTESTINAL IRRITATION AND LARGE AMOUNTS MAY CAUSE SERIOUS HARM. BREATHING - EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY IRRITATION. COPYRIGHT 1985 _ CONTINUED ON PAGE:•2 . 24—HOUR u. Drew .;.Industrial Division- Emergency MATERIAL SAFETY. ASHLAND CHEMICAL Or— Telephone VA One Drew Plaza, Boonton, New Jersey 07005 1(800).- 274-5263� or : DATA SHEET ;, Phone (201) 263-7600/Telex 136444 1(800) .ASHL?.ND 005830 DREWSPERSE 751 ANTIFOULANT Page: FIRST AID:. :F ON SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE -USE. IF IN EYES: FLUSH WITH LARGE AMOUNTS OF WATER, LIF-iNG UPPER AND LOWER LIDS OCCASIONALLY, GET MEDICAL ATTENTION. IF PHYSICIAN IS NOT IMMEDIATELY AVAILABLE, CONTINUE FLUSHING WITH WATER. :F SWALLOWED: DO NOT INDUCE VOMITING. DRINK PROMPTLY A LARGE QUANTITY OF MILK EGG WHITES, GELATIN SOLUTIONS -OR IF THESE ARE NOT AVAILABLE,. DRINK LARGE QUANTITIES OF WATER. AVOID ALCOF&. CALL A PHYSICIAN IMMEDIATELY. IF BREATHED: REMOVE INDIVIDUAL TO FRESH AIR. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE :NCOMPATIBILITY: AVOID CONTACT WITH:, STRONG MINERAL ACIDS., STRONG OXIDIZING AGENTS STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PERSONS WIPROTECTIVE EXCLUDED I OF SPILL UNTIL CHAS BEEN COMPLETED. STOPSPLL.ATSOUREDKEAREAOFSPILLL TO PREVENT SPREADG,PUMPLIQUDTOSALVAGE.NK. REMAINING LIQUID MAY BE TAKEN UP ON LAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REWIRED, THAT A SPILL HAS OCCURED. WASTE DISPOSAL METHOD: SHALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL.LOCAL, STATE AND FEDERAL REGULATIONS. team Elv=12111111 RESPIRATORY PROTECTION: IF OVEREXPOSURE HAS BEEN DETERMINED OR DOCUMENTED, A NIOSH/MSHA JOINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS.' (SEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE (FROM KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS).. PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NATURAL RUBBER EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED- HOWEVER, OSHA . REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR SAFETY EQUIPMENT.§UPPLIER) OTHER PROTECTIVE EQUIPMENT: TO, PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR IMPERVIOUS CLOTHING AND BOOTS. KEEP FROM FREEZING. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES ..v(VAPOR, LIQUID, AND/OR SOLID).'•ALL HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET MUST BE OBSERVED. -HE INFORMATION ACCUMULATED HEREIN IS BELIEVED'TO BE ACCURATE BUT IS NOT WARRANTED TO. BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. rnnvnTr_vm IQAr, TACT T)hrr -qRR ATTArHMPWT PAGE ENCLOSED --LAST PAGE MATERIAL SAFETY DATA SHEET Ashland Chemical Co. - BIOSPERSE 250 MICROBIOCIDE 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Page 001 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0137221-006.001 Material Identity Product Name: BIOSPERSE 250 MICROBIOCIDE General or Generic ID: MICROBIOCIDE Company Emergency Telephone Number: Ashland Chemical Co. 1-800-ASHLAND (1-800-274-5263) P.O. Box 2219 24 hours everyday Columbus, OH 43216 614-790-'3333 Regulatory Information Number: 1-800-325-3751 2. COMPOSITION/INFORMATION ON INGREDIENTS- Ingredient(s) CAS Number o (by weight) ---------------------------------------------------------------------------- MAGNESIUM NITRATE •10377-60-3 1.0- 7.0 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE 26172-55-4 1.0- 6.0 3. HAZARDS IDENTIFICATION Potential Health Effects Eye Exposure causes severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and eye damage. Skin Exposure causes severe skin irritation. Symptoms may include redness, burning, and severe skin damage. Additional symptoms of skin contact may include: allergic skin reaction Skin absorption is possible, and may contribute to Symptoms of toxicity from other routes of exposure. Swallowing Exposure may be harmful or fatal. Symptoms may include severe stomach and intestinal irritation (nausea, vomiting, diarrhea), abdominal pain, and vomiting of blood. Swallowing this material may cause burns and destroy tissue in the mouth, throat, and digestive tract. Low blood pressure and shock may occur as a result of severe tissue injury. Inhalation Exposure to vapor or mist is possible. Symptoms of Exposure irritation (nose, throat, respiratory tract). Target Organ Effects No data Developmental Information No data Continued on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. BIOSPERSE 250 MICROBIOCIDE Cancer Information No data Other Health Effects No data Primary Route(s) of Entry Inhalation, Skin absorption, Skin contact. Page 002 Date Prepared: 01/05/96 Date Printed: 02/16/96 t MSDS No: 0137221-006.001 4. FIRST AID MEASURES _._ Eyes If material gets into the eyes, immediately flush eyes gently with water for at _least 15 minutes while holding eyelids apart. If.symptoms develop as a.result of vapor exposure, immediately move individual away from exposure and into fresh air before flushing as recommended above. Seek immediate medical attention. Skin Immediately flush skin with water for at least 15 minutes while removing contaminated clothing and shoes. Seek immediate medical attention. Wash - clothing before reuse and decontaminate or discard•contaminated shoes. Swallowing Seek immediate medical attention. Do not induce vomiting. Vomiting will cause f ti to t' i a ­'- f ndi v i �dua n^�i �•�c� alert, LL1It:iitr dau«yc to mile Tivi.I�h aiiu �hrv�..:_. I '1 ..- 1 .1 ^� .� and •. - immediately rinse mouth with water and give milk or'water to drink. If possible, do not leave individual unattended. Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attention; keep person warm and quiet. If person is not breathing, begin artificial respiration. If breathing is difficult, administer oxygen. Note to Physicians Probable mucosal damage may contraindicate the use -of gastric lavage. Measures against circulatory•shock.,: respiratory.depression.and convulsions may, -be _ needed. •.:.:... _ 5. FIRE FIGHTING MEASURES Flash Point Not. applicable Explosive Limit Not applicable Autoignition Temperature No data Continued on next page I MATERIAL SAFETY DATA SHEET Ashland Chemical Co. BIOSPERSE 250 MICROBIOCIDE Page 003 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0137221-006.001 Hazardous Products of Combustion May form:, hydrogen chloride, nitrogen oxides, sulfur oxides. Fire and Explosion Hazards No data Extinguishing Media No data Fire Fighting Instructions Water may be used to keep fire -exposed containers cooluntil fire is out.. Wear a self-contained breathing apparatus with a full facepiece operated in -the Positive pressure demand mode with appropriate turn -out gear and chemical resistant personal protective equipment. Refer to the personal protective equipment -section of this'MSDS. No special precautions necessary -.when fighting fires involving this product. NFPA Rating Health - 3, Flammability - 0, Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large Still -- Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source. Dike tb.prevent spreaaterial. The depthdsufficientrttoing. bsobwremoveeallmmicrobiocide) issthennshoveledrinto aopailoor• drum and treated with enough decontaminant solution to wet the solid thoroughly. Let these containers stand open for 48 hours to avoid the'buiidup of.pressure, then seal and dispose of by burying as landfill. The decontaminated area is washed with additional decontaminant solution and then flushed into a chemical or municipal sewer. Do not discharge spills and cleaning runoffs into open bodies of water. Remove clothing promptly; launder before reuse. Wash skin with soap and water.. Decontaminant solution: bisulfite solutions (about 11% solids content) sodium decompose Biosperse 250 rapidly. Laboratory tests indicate that the microbiocide is almost completely__-* deactivated within 30 minutes when treated with at least 4 equivalents of decontaminating solution. A volume ratio of20/1 decontaminant/active.. .. microbiocide is recommended. The following solutions. are acceptable. decontaminants: Ingredient: sodium metabisulfite (weight = 1 pound) + water(weight = 8 pounds). Total 9 pounds. Solids content = 11.1%. pH = 4.2. Ingredient: sodium bisulfite (weight 1 pound + water (weight 8.3 pounds). -Total 9.3 pounds. Solids content = 10.70. pH = 4.2. Ingredient: sodium '-sulfite (weight = 1 pound) + water (weight = 7 pounds) + hydrochloric acid(37a) (weight = 0.67 pounds). Total 8.67 y 5-5.5. Note: Decontaminant solutionomust�have 1phsonothe nacid 9side; since it is much less effective when alkaline. In converting sodium sulfite to the bisulfite, dissolve the salt in water and slowly add the acid with good agitation to prevent liberation of sulfur dioxide caused by local excess of acid. Keep containers of decontaminant solution closed or covered to reduce accumulation of sulfur dioxide in the workplace(threshold limit value(ACGIH) 2 ppm). The solutions should be made fresh as needed. Personnel making up or handling decontaminant solutions should wear goggles or face shield and rubber gloves. Continued on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. Page 004 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0137221-006.001 BIOSPERSE 250 MICROBIOCIDE 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) Skin Protection Wear resistant gloves such as:, -neoprene, nitrile rubber, To prevent skin contact, wear impervious clothing and boots., Other protective equipment: eyewash station, emergency shower.. Respiratory Protections If overexposure has been determined or documented, a NIOSH/MSHA jointly approved air supplied.respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA res irators under specified conditions. (See your safety equipment supplier. Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure (from known, suspected or apparent adverse effects). Exposure Guidelines Component MAGNESIUM NITRATE (10377-60-3) No exposure limits established 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE (26172=55-4) No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES. - .Boiling .Point `(for` component) ` 217--0 (100.0 C) @ 760 mmHg Vapor Pressure (for component).17.500 mmHg @ 68.00 F Specific Vapor Density 1.000 @ AIR=1 1� Continued on next page L MATERIAL SAFETY. DATA SHEET Ashland Chemical Co. BIOSPERSE 250 MICROBIOCIDE Page- 004 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0137221-006.001 7. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection = Chemical splash goggles and face shield (8" min.) in compliance with OSHA regulations are advised; however, OSHA regulations also permit other type safety glasses. (Consult your industrial hygienist.) Skin Protection Wear resistant gloves such as:, -neoprene, nitrile rubber, To prevent skin contact, wear impervious clothing and boots., Other protective equipment: eyewash station, emergency shower.. Respiratory Protections If overexposure has been determined or documented, a NIOSH/MSHA jointly approved air supplied.respirator is advised in absence of proper environmental control. OSHA regulations also permit other NIOSH/MSHA respirators under specified conditions. (See your safety equipment supplier.) Engineering or administrative controls should be implemented to reduce exposure. Engineering Controls Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure (from known, suspected or apparent adverse effects). Exposure Guidelines Component MAGNESIUM NITRATE (10377-60-3) No exposure limits established 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE (26172-55-4)' No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES. = ,Bo.i.ling _Point (for' component') "'212':0 (100.0 C) @ 760 mmHg 0 Vapor Pressure (for component)•17.500 mmHg @ 68.00 F Specific Vapor Density 1.000 @ AIR=1 t Continued on next page N F. MATERIAL.- SAFETY DATA SHEET Ashland Chemical Co. Page 005 Date Prepared: 01/05/96 Date Printed: 02/16/96 BIOSPERSE 250 MICROBIOCIDE MSDS No: 0137221-006.001 Specific Gravity 1.010 - 1.030 @ 77.00 F Liquid Density 8.400 - 8.570 lbs/gal @ 77.00 F 1.010 - 1.030'kg/1 @ 25.00 C Percent Volatiles 85.0 - 100.0 %- Evaporation Rate SLOWER THAN ETHYL ETHER Appearance. CLEAR - State - - - LIQUID Physical Form HOMOGENEOUS SOLUTION Color LIGHT GREEN YELLOW Odor No data pH 2.0 - 5.0 10. STABILITY AND REACTIVITY Hazardous Polymerization will not undergo hazardous polymerization. Hazardous Decomposition May form:, hydrogen chloride, nitrogen oxides.,, sulfur oxides. - Chemical Stability =" Stable. Incompatibility Avoid contact with:, amines, reducing agents, strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION No , data I Continued.on next page MATERIAL SAFETY DATA SHEET Ashland Chemical Co. BIOSPERSE 250 MICROBIOCIDE 12. ECOLOGICAL INFORMATION No data Page 006 Date Prepared: 01/05/96 Date Printed: 02/16/96 f• MSDS No: 0137221-006.001 13. DISPOSAL CONSIDERATION Waste Management Information Deposit in a landfill in accordance with local, state and federal regulations. 14. TRANSPORT INFORMATION. DOT Information - 49 CFR 172.101 DOT Description: CORROSIVE LIQUIDS, N.O.S.,8 (CORROSIVE MATERIAL),UN1760,II Container/Mode: 55 GAL DRUM/TRUCK PACKAGE NOS Component: 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE RQ (Reportable Quantity) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION US Federal Re ulations CERCLA Ra = 40 CFR 302.4 None SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CFR 370.2 Immediate(X) Delayed( ) Fire( ) Reactive( ) Pressure( ) SARA 313 Components - 40 CFR 372:65 None Sudden Release of International Re ulations Inventory Status - ----Not determined State and Local Regulations California Proposition 65 The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains the following substance(s) known to the state of California to cause cancer. LEAD The following statement is made in order to comply with the California Safe Drinking Water and Toxic Enforcement Act of 1986: This product contains the following substance(s) known to the state of California to cause reproductive harm. t LEAD Continued on next page a P MATERIAL SAFETY DATA SHEET Ashland Chemical Co. Page 007 Date Prepared: 01/05/96 Date Printed: 02/16/96 MSDS No: 0137221-006.001 BIOSPERSE 250 MICROBIOCIDE New Jersey RTK Label Information MAGNESIUM NITRATE 10377-60-3 Pennsylvania RTK Label Information ' NITRIC ACID, MAGNESIUM SALT 10377-60-3 16. OTHER INFORMATION The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not: Recipients are advised to confirm in advance of need that the information is current.,. applicable, and suitable to their circumstances. 0 Last page PAGE 000 Drew Divisions . 24-HOUR ASHLANDCF=P C.,L.iNC. emergency ?elephonei f MATERIAL, SAFETY 2•�e Drew Plaza. Eoonicr•. Ne_wJersey 07005 1(606) . 324=11�33 or DATA SHEET•. = 20l elex . .,. _ 1263-7o"oO:T_ ' 3�G.�4 FAX (201) 203-4482 1(80.0) _ 274-5.26.3 000443 B I OSPERSE 2 61T MICROBIOCIDE. Page: 1 'HIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD)' :ss:sasas:ssasssassasasaasassasssaa:aaasaa:aaaaaa:sassaasssaasassaaaaa:ssassssssssasssaaassssassasasasasssssasaa Product Name: BIOSPERSE 261T MICROBIOCIDE CAS NUMBER: 126-06-7 Data Sheet No: 0196831-005.000 00 10 922 - Prepared: 04/05/93 DREW.INDUSTRIAL DIVISION Supersedes: 05/06/91 500 ARCHDALE DRIVE SUITE 115 PRODUCT: 4636 CHARLOTTE INVOICE - NC 28210 INVOICE DATE: T0: DREW INDUSTRIAL DIVISION 500 ARCIDALE DRIVE DISTRICT MANAGER CHARLOTTE_ General or Generic ID: MICROBIOCIDE DOT Hazard Classification: OXIDIZER (173.:51) SECTION I I -COMPONENTS IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA Ti-LE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION INGREDIENT BROMDCHLORODIMETHYLIMIDAZOLIDINEDIONE CAS 0: 126-06-7 Notes: ( 1) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL Boiling Point Vapor Pressure Specific Vapor Density Specific Gravity NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE % (by WT) PEL TLV Note 93 - 95 ( 1) @ 77.002Deg F ( 25.00 Deg C) Percent Volatiles NOT APPLICABLE Evaporation Rate NOT APPLICABLE Appearance WHITE . State SOLID Form TABLETS SECTION IV -FIRE AND EXPLOSION INFORMATION FLASH POINT NOT APPLICABLE EXPLOSIVE LIMIT NOT APPLICABLE EXTINGUISHING MEDIA: WATER FOG HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL CECOMPOSITION OR CCMBUSTION MAY PRODUCE:, BROMINE, HYDROGEN BROMIDE FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. SPECIAL FIRE & EXPLOSION HAZARDS: DECOMPOS7-:ON CAN RELEASE OXYGEN WHICH SUPPORTS COMBUSTION AND REDUCES THE EFFECTIVENESS OF SUFFOCATION TYPE FIRE EXTINGUISHERS. PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED: SEE SECTION VIII. EFFECTS OF ACUTE OVEREXPOSURE: EYES - CAUSES SEVERE IRRITATION AND CORNEAL :NJURY. SKIN - CAN CAUSE IRRITATION. BURNS CAN RESUL- FROM PROLONGED CONTAC BREATHING - OF DUST CAN CAUSE IRRITATION OF NASAL AND RESPIRATORY PASSAGES. SWALLOWING - CAN.CAUSE DEATH FIRST AID: IF ON SKIN: IMMEDIATELY FLUSH EXPOSED AREA Mi'H WATER FOR AT LEAST 'S MINUTES, GET MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE -USE. IF IN EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER LIDS. OCCASIONALLY. GET IMMEDIATE MEDICAL A -ELATION. IF 'SWALLOWED: IMMEDIATELY DRINK TWO GLASSES OF WATER AND INDUCE VOMITING BY EITHER GIVING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF THROAT.'NEVER'GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION IMMEDIATELY. ` r0NT T NTTTrn - om .PAGE. ...2 DrewpDhvisio...�. _ 0700�_ ....__.- c o 324 1 ,� ns �•, nvu EACAL. Emergency Telephon :.VIATERIAC SAFETY t onq-Dr=w Plaza. Boonton, dew ers_y 1 6 6 — 133 0 DATA SHEET Phone (2ot:, 2c?-7000Telex 136444 FAX :201) 263-aa82 1(800) 274-5263 CCO44'. BIOSPERSE 261T,MICROBIOCIDE Page: 2 NG IS XYGEN. IF :F BREATHED:INGFHASFSTO PEDRGGIVEEARTIIFICIALLTO RESPIRA�ON. AIR. EEP PERSONIF IWARM, QUIETCAND,GET MEDICAL ATTENTION. PRIMARY ROUTE(S) OF ENTRY: INHALATION', SKIN CONTACT HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT WITH:,.STRONG ALKALIES, ORGANIC MATERIALS. REDUCING AGENTS STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: SWEEP UP MATERIAL FOR DISPOSAL OR RECOVERY. LARGEBEENLCOMPLETEDS NOT 9IOVELAMATERIARLTINTOVCONQTUAINT �iOROUGHLY SWESHOULD ZE EPEAREA OFASEILOFTOPCLEANtUPLACLEAN-UP I�RESIDUAL HS MATERIAL. WASTE DISPOSAL METHOD: - - SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. JOINTLYJA APPROVED RESPIRATORY IF OVEREXPOSURE 14AS BEEN DETERMINED NIRC10PEiAIT ROPER ENVIRONMENTAL CONTROL. REGUATIONNSAS SPLEDESPIRATORISAVISEDNABSENCE OF P OTHER NIOSH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS. (SEE YOUR SAFETY EQUIPMENT SUPPLIER)- ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE -EXPOSURE. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO, MAINTAIN EXPOSURE BELOW TLV(S). PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS:, NEOPRENE EYE PROTECTION: REGULATIONS�ALLSIO PERMIT OTHER ERGOGGLES SAFETY GLASSES. (CONSSLTRYOUR SAFNETYARE EQUIPMADVISED- ENT 1UPHPLIER)' OSHA OTHER PROTECTIVE EQUIPMENT: TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. CONTAINERS OF THIS MATERIAL MAY BE HgLLRF�ZARWEN D PREtA??DNS GIVEN EMPTIED PTHIS CONTAINERS DA AASI-EETSMUSTRETAIN BE OBSERVED.RESIDUES (VAPOR. LIQUID, AN SOLID), R ORIGINATING -HE INFORMATION ACCUMULATED OR NOT. RECIPIENTSLAREED TO BE A ADVISED ACCURATE0 ONRMUT IS NOT IN,ADVANCEWARRANTED O ANEED THATEWHiET TH FORMATION S CURRENT, APPLICABLE, AND SUITABLE TO THEIR C3RC0ASTANCES: Txrr.ncFn=—LAST PAGE • a 0 Drew industrial Dn►WM ASNLAND C'rEMICAL. INC_. SUBSIDIARY ASHLAND OIL, M. ° One Drew Plaza, Boonton. New Jersey 07MS BIOSPERSE@261T Microbiocide General BIOSPERSE' 261 T microbiocide is a broad- spec-trum antimicrobial product designed specifically for control of bacterial, fungal and algal slimes in fr4w trial recirculating cooling water systems. BIOSPERSE 261T Is a solid microbiocide which' iterates hypobrornous acid, hypochorous acid and . 5,S-dimethythydartfdn when dissolved in water. This environmental profile is designed to address common Questions about the irrgact of BIOSPERSE 261T microbiocide on the errvimnment. Active Ingredient 1-Bromo-3-chbm-6,5-dimethyt-hydantoin 92.S% Fish & Wildlife Studies LD„ and LC,, 9644our Data for 1-Bromo-3chiorc-b,5-dimethyl-hydantoin Daphnia Magna Rainbow Trout Fathead Minnow Grass Shrimp Sheepshead Minnow American.0yster Rat IW LCW LC„ LC LC„ LC50 LC„ LDW 6 0. 2.25 mgA 13.0 mgA 20.0 mgA 640 nVA 1390 mgAcg ENVIRONMENTAL PROFILE LC,p, 96-Hour Data for 5,54*n0ttylhydantoin Ornanis Daphnia Maqu 1300 mgA Rainbow Trout '6100 Mgt Fathead Mlnnotlr 8100 m04 Grass Shrimp 12700 mil Sheepshead Minnow 13300 mgA American Oyster 14200 mg4 . LC„ Data for Hypobnontrous Acid Ormanism Iasi fle;�Wi Daphnia Magna LC,, 24-Four 1.05 mgA LC,, 48-hour 0.71 z Bluegill Sunfish LCe, 96-Hour 0.52 Rainbow Trout LC:, 96-Four 0.23 mgA Sheepshead MMnow LCO, 96Four 0.19 mgA Mysid Shrimp LC,,, WHour 0.17 mo Degradation Data The non -toxic dehalogerudod by-product of SIOSPERSE 261T, 5,5<limethyihydantoin, is biode- gradable as detemtined by carbon-14 radiolabeling. of sewage 'sludge. After 19 days, 94 percent of the carbon-14 had been recovered as'rarbon dioxide. Under the lest candiions, Ow dehabgenated by- product of BIOSPERSE 261T degraded rapidly with no obvious toxic effects upon the test organisms. C BIGSPERSE Is a ngi - melemark of Ashdrem I.P., Inc., rand by Drew kWuBVW Division. All statements, information and data pas~ Herein are t0lleved to be accurate and nYOk but arc not to be taken as a gueranrra, Irarrar� off warranty of m rd%araabi* or 11b+ nor a particular Purpoau, or reweranl . ` Non, or b g implied, for which :olbr eaatrnaa 1s�1 r�ar�WtY, ma key are oeornd Solely for rwa warranty VW ao.ny hive use k fend wPMent [nf. Stenen�rs d 6Ul}pebewq ooncat ing posdbia Um of tlt� pes►rd wo auA��� mace wrteotrt representation or `rur+rM tHat arty sueH use i:n free d parent tniflrgerMot and are not reonnrmendatun, b iMNfP do a++)I paarrR. -r *1991 AtnNatW Chpn*mr, ki All Wt; Reserved. Prbh)d In U.aJL CWT EP-0B TOTAL P.01 „ DREW A HISTORY OF RESULTS ENVIRONMENTAL PROFILE BIOSPERSE® 250 Microbiocide j General Degradation Data SIOSPERSE 250 microbiocide is a broad-spectrum antimicrobial product designed specifically for control of bacteria, fungi and algae in industrial recirculating cooling water systems such as cooling towers, - pasteurizers, air washers and evaporative condens- ers as well as for use as a preservative in aqueous metal working fluids. This Environmental Profile is designed to address common questions about the impact of BIOSPERSE 250 tnicrobiocide on the environment. The degradation scheme for the active components of BIOSPERSE 250 is isothiazolinone to N-methyl- malonamic-acid to malonamic acid to malonic acid with the final products being acetic acid, formic acid and carbon dioxide. Degradation Half-life, minutes: �•T.111111e - 8.2 131,472 3,730 Active Ingredients 11.0 14,400 137 5-Chloro-2-methyl-4-isothiazolin-3-one 1.15% Photolytic Degradation: 2-Methyl-4-isothiazolin-3-one 0.35% Total 1.5% BIOSPERSE 250 Remaining Tme fhrs) 1tY QdlfS Fish & Wildlife Studies 0 78.8% 78.8% Orcanism IW Result 5 59.3% 77.Vo 48 31.2% 79.1 •% Bluegill Sunfish LC501 6-Day 36 mg/I 120 0% 78.60/6 Channel Catfish Fathead Minnow LCR„ 6-Day LC30; 6-Day 6.7 mgA 8.0 mg/I Detoxification Rainbow Trout LC., 6-Day 9.3 mg/I Daphnia Magna LC!V, 48 Hrs. 10 mgA In case of spillage, BIOSPERSE 250 is easily Bay Mussel LC501 96 Hrs. 130 mgA detoxified. A sodium bisulfate solution (about 11 % Sheepshead Minnow- LC.., 96 Hrs. 20 mgA solids content) decomposes BIOSPERSE 250 Fiddler Crab LCW, 96 Hrs. 3900 mg/l rapidly. Laboratory tests indicate that BIOSPERSE Pink Shrimp LCW, 96 Hrs. 150 mgA 250 is almost completely deactivated within 30 Eastern Oyster LCW, 48 Hrs. 1.9 mgA minutes when treated with at least 4 equivalents of Bobwhite Dual LD.., Acute Oral 6500 mg/I decontaminating solution. A volume ratio of 20/1 ` LCw 8-Day Diet. >37,000mg/1 d000ntaminant/cletivo microbixido it recommended. Pekin Dude LZ 8-Day Diet. >37,000mgA Acceptable decontaminants are 11.1 wt. % sodium Rat (male) LD , Acute Oral so 3810 mg/kg metabisulfite, 10.80/o wt. % sodium bisulfrte or a 7.7 wt. % concentrated hydrochloric acid/11.5 wt. °% sodium sulfite solution. BIOSPERSE s a registered trademark or Ashchem I.P., Inc., used by Drew Industrial Division. Ab sta mums. Information and data presented herein its believed to be accurate and reliable but are not to be taken as a guarantee, express warranty or — implied warranty Of merchantability or fulness for a particular purpose, or representation, express or implied. for which seller ausumes legal ndWzibility, Ashland Chemira! and they are offered solely for your consideration, investigation and veritiratoa. Statements or suggestions corxwrrng possible use of this OrDO= are "Imomw made without repreizenntion or warranty that any zmh use is free of patent infringement and are not recommendations to infringe on any patent. AtaMand Ctterrtical Compactly Draw Indtltltf)t♦I Dh4s1m • One Drew Plaza. Boonton, New Jersey 07005 e Phone: (201) 263.78M - Fax: (201) 263-4483 Diviaiort ot Asil'Jand Oil. Irr- 01991 Ashland Chetnl al. Inc. All Rights Reserved. Printed In U.S.A. Z0'd 01 I-1J40—M3Na/PuS1HSd WMI3 TZ:ST 966Ti02ib0 CWT EP-01 Drainage area