NCG500323_Regional Office Historical File Pre 2018 (9)

1 - - --_
DIVISION OF WATER QUALITY
December 29, 1998
MEMORANDUM
To: Dave Goodrich
From: Matt Matthews
Subject: Shurtape Technologies
Biocide/Chemical Treatment Use
NPDES No. NCG500323
Alexander County
JAN 8 1999
a @" 01 sl MID 1'0
sedwak EMU 091
Consolidated Water Conditioners has submitted on behalf of Shurtape Technologies the biocides
Purobrom and Dow Antimicrobial CT Tablets for approval. Data submitted by the facility
concerning the dosage rates of the biocides, degradation, system volume, average daily discharge, toxicity
of the active ingredient(s) and/or breakdown products, and minimum stream flow have also been reviewed
and evaluated.
Please note:that the LC50 data for the Bluegill sunfish was incorrectly utilized by the facility in the
worksheet. We have used the lower LC50 value of 1.24 mg/L for daphnids with which to calculate the
regulated limitation. This revision, however, did not change the final analysis portion of the worksheet
(part IV, page 3).
Calculations summarized on the accompanying worksheet predict that the use of these products at the
stated dosage rates and discharge conditions will not result in toxic impact to aquatic life in the receiving
stream. Therefore, the use of this product as a biocide at Shurtape Technologies is acceptable.
If there are questions concerning this review please contact me at (919) 73372136.
Attachments .
cc: Melissa Rosebrock
Rex= Gleason-MRO-- '
Central files

Shurtape, Inc. BIOCIDE WORKSHEET
PERMIT* NCG500323
RECEIVING STREAM: Third Creek
7Q10. (cfs): 0.20
I.W.C.%: 1.60
PRODUCT: Purobrom
ACTIVE INGREDIENT: 1-bromo-3-chloro-5,5-dimethylyhydantoin
HALF LIFE (DAYS):
0.10
LC50 OF SELECTED TOX DATA (MG/L):
0.46
DECAY RATE:
6.6346
DOSAGE RATE (GRAMS/DAY):
170
AVG DAILY DISCHARGE (MGD):
0.0021
VOLUME OF SYSTEM (MIL. GAL'S):
0.0125
7Q10 (cfs): 0.20
I.W.C.%: 1.60
STEADY STATE DISC CONC: 0.5282
DEGRADATION FACTOR: 6.803
APPLICATION FACTOR: 0.050
INSTREAM BIOCIDE CONC:. 0.0084
REGULATED LIMITATION: 0.023
PASS/FAIL: PASS
PRODUCT: Antimicrobial CT Tablets
ACTIVE INGREDIENT: 2,2-dibromo-3-nitrilopropionamide (DBNPA)
HALF LIFE (DAYS):
0.04
LC50 OF SELECTED TOX DATA (MG/L):
1.24
DECAY RATE:
16.8293
DOSAGE RATE (GRAMS/DAY):
867
AVG DAILY DISCHARGE (MGD):
0.0021
VOLUME OF SYSTEM (MIL. GAL'S):
0.0125
STEADY STATE DISC CONC: 1.0781
DEGRADATION FACTOR: 16.997
APPLICATION FACTOR: 0.050
INSTREAM BIOCIDE CONC:- 0.0172
REGULATED LIMITATION: 0.062
PASS/FAIL: PASS

Subject: CT tabs
Date:"Wed, 11 Nov 1998 13:40:45 -0400
From: [e-mail]
To: [e-mail]
hello,
the reference to lasting 3 weeks is on page 2
the hand writing on page 1 was some notes i took from the sales rep
if any of it is unclear i can re -scan at a higher resolution
i am working on a location with a small tower about 1000 gal. volume
and a large tower about 2000 gal. voume.
the 7Q10 is 0.20
the ADD is .0014 d(i w t to carry 15 cycles in the towers) -"'•
the lowest LC50 is .1
i was figuring 3 tablets for the 3000 gal volume
each tablet is 200 grams
thank you for you time on your "day off"
i was supposed to be off with my kids today also, but being self employed
has kept me working on this project today.
i got your phone message that the e-mail didn't go through so i tried it
again with a slight modification to your address.
ed spencer
Name: CT_Tabs_page_Lgif
RCT Tabs page 1.gif Type: GIF Image (image/gif)
Encoding: base64
.Name: CT_Tabs_page_2.gif
h CT Tabs page 2.gif Type: GIF Image (image/gif)
Encoding: base64
E

Copsolidated Water Conditioners V 1-704-873-5413 R1 112311998 (D 2:10 PM L] 1/2
F I
................................................................................ .............
DATE: Monday, November 23, 1998
:.MEMC
TO: Melissa Rosebrock
................................................................
ATT: Melissa Rosebrock
FAX: [phone] Thisis one of 11 pages I just received. It
shows a tablet dissolving in 13 days at
high flow, and 21 days at lower flow. Call
me if you need more info.
FROM: Consolidated Water Conditioners Ed Spencer C.W.C.
PAGES: 2
............................................................................................. ..................................................................

Consolidated Water Conditioners Ir1-704-873-5413 R11/23/1998 (92:11 PM L12/2
11/23/98 MON 13:15 FAX [phone] DOW CIMMICAL CIG II
0
Tablet placement precautions
Use the bag provided, or a similar
receptacle made of nylon or plastic.
Suspend this in the tower basin in a
manner that avoids direct contact
with basin sidewalls or floor. Note
that DBNPA at -use concentrations
do NOT contribute appreciably to the
corrosivity of tower water.
• Avoid incomplete immersion
• -Do not allow contact with basin
walls or floor
• Avoid areas of high velocity
water flow
• Avoid sunlight
Monitoring tablets in use
SUMP BUDDY WT Tune -Release
tablets release active DBNPA by
gradual dissolution and erosion of
the outer tablet surface. The outer
dissolving layer remains thin;
DBNPA in the core remains dry.
During the first few days in a
system, the appearance of a tablet
will not change dramatically. Within
one week, the sharp edges will lose
definition, then round off and appear
translucent. This marshmallow -like
appearance will then remain essen-
tially the same and the tablet will
decrease in size. until completely
dissolved. During initial location
trials, monitor tablet dissolution to
verify that it follows the typical
three-week schedule.
by uniform dissolution. The expected
tablet lifetime was calculated at
21 clays at a flow rage of 0.058 ft/sec,
and 13 days at 0.26 ft/sec.
Compatibility cautions
Previous tests have shown that
DBNPA, the active ingredient in
nissouth-r-ratee vTr _yt►1 1;._-- _ _---
SIUMP RI1T)T1Y�S%j 11t71� Fie1P8se. .
water flow rates
tablets, is compatible with cooling
Figure 5 shows average tablet dis-
tower water and various components
solution profiles obtained in a study
of most water treatment programs.
that modeled water flow rates
However, mercaptobenzothiazoles
bracketing the range typical of
and their sodium salts will rapidly
bypass feeders. Two tablets were
degrade DBNPA, as will strong
studied at each flow rate and the
reducing agents such as oxygen
results were averaged.
scavengers or hydrogen sulfide.
The data indicate initial weight
gains as the tablets hydrated, followed
Figure 5 - Average tablet dissolutlon profiles at two water flow rates
nto+,; rrii
weigh[. Tlie tnblel9 quickly refiyvlrnfed when the experiment was reatnrled. Note that this upset h3d Wary e cum
on
dieeulution rut-j.
O

CWC. DEC0 6 1998
ENVIRONIVIENIALOGMULMATED
i BRANCH
INDUSTRIAL / COMMERCIAL
WATER TREATMENT
Division of Water Quality
4401 Reedy' Creek Road
Raleigh, NC 27607
ATT: Melissa Rosebrock
233 BEECHBR i10 K'LANE
WATER CONDITIONERS
STATESVILLE, N.C. 28625
[7041-873-5413
The following is a list of chemicals,., that ,I, plan to use at the Shurtape
facility. The MSDS contains a full list of ingredients for all products.
B I OC I DES : - total of two.
------------ ----------------------- ---------------------------------------
PUROBROM 1-Bromo-3-chloro=5,5=dimethyl-hydantoin
------------------------------------------------------ -----------------
DOW Time Release RNTI M I CROB I RL, CT TRBLETS
also called SUMP BUDDY WT tablets DBNPR {2,2-dibromo-3-nitrilopropionamide}
------------------------------=--------------------------------=--------
NON-BIOCIDES : total of eight
BOILER COMPLETE 200.0 , MULTI -BLEND STEAM BOILER TRERTMENT
-------------=----'-----------------=----=----------------------=-------
LIQUID ORRWAY l supplement to B.C. 2000 {if necessary}
BOILER DISPERSANT PLUS supplement to B.C. 2000 Of necessary}
SUPER RLKRLINITY BOOSTER t/ supplement to B.C. 2000'{if necessary}
------------------- ---- =----------------------------------------------
8000-N-1 COOLING TOWER TRERTMENT{scale/corrosion}
------------------ ----------------- -----------------=------------------
MOLYTRERT 300 supplement to. B.C. 2000 boiler treatment
---supplement to 8000-N-1 tower treatment
------------------- I-------- ----=----------------------------------
ULTRR KLERN supplement to 8000-N-1 tower treatment
Of necessary}
AIR WRSH TRERTMENT air.wash unit treatment {scale/corrosion}

CONSOLIDATED WATER CONDITIONERS
233 BEECHBROOK LANE STATESVILLE, N.C. 28625
INDUSTRIAL / COMMERCIAL
WATER TREATMENT
--------------------------------------------------------------
FORMULRS FOR FIGURING SYSTEM UOLUME
* all measurements expressed .in feet
17841-873-5413
Rectangular Tower System Uolume in.approx gallons =
TOWER SUMP Length x Width x auerage Depth x 7.5 plus 10% for piping
23.5 x 19 x 1.25 x 7.5 x 1.1 = approx. 4600 gallons
(1) big air wash 15 x 15 x 1.25 x 7.5 x 1.1 = approx. 2300 gallons
(3) small air wash 13 x 10.5 x 1.25 x 7.5 x 1.1 x 3 = approx. 4200 gallons
{smRW} 4200 + {Big RW} 2300 =approx. 6500 gallons in air wash
************************************************************************
Round Tower System Uolume in gallons =
Tower Basin Diameter x Diameter x auerage Depth x 5.9 plus 10% for piping
12 x 12 x 1.5 x 5.9 x 1.1 = approx. 1400 gallons
Rect. Tower gallons plus Round Tower gallons plus Rir Wash gallons = total gallons
4600, plus 1400 _plus. 6500 = 12,500 . total approx. system gallons.
DOSAGE RRTE FOR CT TRBLETS:
1 TRBLET PER 500 - 1000.GRLLONS OF SYSTEM VOLUME.
RM US I NG 1 TRBLET PER 1000 GRLLONS OF SYSTEM UOLUME.
• note.- even when using 1 tablet per 500 gallons, the calculations still pass with a receiving
stream concentration of 0.033 and reg. limitation of 0.065
ERCH TRBLET WEIGHS 200, GRRMS. THE TRBLETS LRST FROM 13 TO 21 DRYS. TO BE MORE
CONSERURTIUE, HOWEUER, IF THE HIGHEST DISSOLUTION OCCURS IN THE 1st 3 DRYS, I HRUE
DIVIDED THE 200 GRRMS BY 3 DRYS {as per Melissa Rosebrock} INSTERD OF 13 OR 21 DRYS
TO FIGURE THE MRxIMUM DOSRGE IN 24 HOURS. THIS 61DES 66.67 GRRMS PER TRBLET USED
Rs D.R. Rect. Tower 5 tablets + Round Tower 2 tablets + Rir Wash 6 tablets = total 13 tablets
DOSAGE RRTE FOR PUROBROM 3 Ihs. per 1.00,000 gal. or 3 .00003 x gallons
100,000
.00003 x 12,500 = 0.375 lbs. x 453.59 = 170 grams {this will be done once per week}

11/09/98 13:57 T2704 322 3535 SHUFORD HLS R&D 9 001
Facility Name: 61 U -T-A-0G G�.�4lQol�CC11 NPOES #: NCC2500323
BIOCIDEICHEMICAL TREATMENT
WORKSHEET-FORM 1 of
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worksheet must be completed separately for each biocida! product In use. This worksheet Is to be
returned with all appropriate data entered into the designated areas with carculations performed as, indicated.
t_ Facility Name S:E44f2a I
NPDI:S # NG Qgbcc> --3Z3 _ GuTfaTl # O�
County —A trEkA" D�i2
Receiving Stream Y' 7Q14 0 2 (cfs)
(All above information supplied by the Division of Ernvironmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handling systems to the receiving water body?
(in M.G.O.)
P!ease calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
PNC = — (A.D_D.) X 100 _ (,00zy) x 100
(7Q10)(0.646)+(A,.D.D) (,a 7(0.646) T (,o6z1)
This value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
IL What is the name of the whole product chemical treatment proposed for use in the discharge identified in Part I?
bow fglVT-/ M1C%ZU BiAL GT TA6LET$ - acsc 'cR,.cco E0 (1'tP
Please list the active ingredients and percent composition:
o0r"aPicrl 01(K Je D o�
0
W1lrat feed or dosage rate'(D.fi.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
d•R•= 6`7 grams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 gal, water X 8.34 lbs. X specific gravity of product X 453.59 % .
128 fl. oz. i gal. water 1 lb.
D.E.M. Form 101 (2/95) 1

11/09/98 13:57 %Y704 322 3535 SHUFORD MLS R&D
10002
Facility Name: S N L/r, l F` _ NPDES 4: NC G 5-o o 3 a 3
Estimate total volume of the water handling system between entry of biocidal product and N-PDES discharge
point. On an attached sheer please provide justificstIon for this estimate (system volurne, average rycics per
blowdown, holding lagoon size, etc.)
Volume= 6 1 a S million gallons
is
What is the pH of the handling system prior to biocide addition? If unknown, enter N/A -
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The
degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half
Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H.L. = D . D K I Days
The decay rate is equal to 1• I X o.s9 -Decay Rate (D.K.)
Calculate degradation factor (D.F.). This is the first order loss coefficient
aD.e. f , vtya. f �6 `t R 7
D... - (Volume) f (D.K.) _ ( . 0tZS ) (i6,8a��)
Calculate Steady State Discharge Concentration.
Dischg Conc. a D.S.) , 9 6 `7 � e � .7 (D.5.)(Volume)(3785) - (16. 9 ' ) ( t o I Z s ) (3 7 s s) _ M94
Calculate concentration of triocide instrearn during low flaw Conditions.
(Receiving Stream Concentration)
Disch . Conc. x IWC%
100 a 100 = mgR
Receiving Stream Concentration
Calculate regulated limitation.
List all LCSO data available for the whole product according to the following columns. (Mote that units should 69 in
TngM-- Please provide copies of the sources of this data.
Te t Mrd6on LC50 (ttxyq
our
V A
NV
u l� TV
N v gA l Al go uJ -r{Z o f t nJ V
D.E.M. Form 101 (2/95) 2
P se- c-oc

11/09/98 13:58 %2704 322 3535 SHUFORD MLS R&D 10003
Facility Name:. S tiUr7WaF NPDES G Soo 33
Choose the lowest LC50 fisted above:
Enter the LCSo: /. 3
If the half life (H.L) is less than 4 days, perform the following calculation. (� Z
Regulated Limitarlon = 0.05 x LCSo = G • 6 S mg/l J '�
If the half. fife (H.L.) is greater, than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation ; 0.01 x LC50 - mGA
Choose the appropriate regulated limitation from the calculations immediately above and place In this blank;
° G 6 mg/liter
From Part Il enter the receiving stream concentration:
' (I—mg/liter
IV. Analysis.
If the receiving stream concentration is greater than the •calculated regulated limitation, then this biocide is
unacceptable for use.
OF Eit/Vlj2O,L1,VEV-T 4�/
Name (Prhf)
Signature Date
Person in Responsible Charge
P913 CanVJedng ifil3W'oriQh Dad
(if Different From Above) .
D.E,M. Form 101 (2/95) 3

11/09/98 .13:58 %9704 322 3535 SHUFORD NLS R&D 4 004
Facility Name: 5P VP —r0f r- NPDES 9: NC
uoalemental Metal-Anafvsis
if copper, zinc, or chromium are present in'the proposed biocidal compound, complete this worksheet. A separate form
must be used for each metal and/or metal cotnpourtd pres"bnt in the biocide. List the metal, its chemical formula, molecular
weight (MVO, for weight (FM, and the concentration of the metal compound in the biocide (MCC). Complete a.
separate form for eery metal present in the biocide.
Metal Chemical Formula Molecular WeightWaight of Mctal Formula weight Concentration in Di aide
EXAMPLE
Copper Cuso4.6N20 63.546g(mcle 249.680 g/mole 0.2 %
Dosage rate of Biocide (DR) (from page 1):
DR = -- grams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallons/day
Discharge Concentration (DC) of Bfoofde:
DC = DR _ ( grams/day) gramslmilliongallons
ADD — ( million gallans/day)
Convert nC to mlcrograms/Ifter (ppb)_
DC rams/mAllon I x 1 x 106 Ica/a _
��) _ —___PC (9) 3.785 x 1,06 liters/million gal. ttg/I
Calculate the fraction of metal In the metal -containing compound (MF):
MF;grams/mole)
FW — ( grams/mole)-
Calculate the fraction of metal in the blocfdal compound (BF):
SF=MFx11ACOC�° _ x
(100)
Calculate the concentration of metal In the discharge (M):
• r
M DC x BF ugA x
••Cailcubs a the instream, mate(-= ncentratio n (IMC)-'at low -flow conditions:
IWC NO
IMC = M x . 100 ugn x 100 = ugll
Regulated Ilmitatlon of metal (from below): µgll
N eneral tatutes �8A N 02i1 a Ina: .
Copper- 7 µSA water quality action level' Zinc- 50 µgA water quality action level-
Chromium- 50 µg/I water quality standard
('Values which exceed action lavels must be addrassad directly by aquatic texicity lesting,)
D.E.M. Form 101(2195) 4

11/11/98 SPED 16:46 FAY 5178321439 D01f CHEMICAL CIG
lih 602
Fish and wildlife toxicology
Table 20 provides information about the
toxicity of DOW DBNPA to aquatic, marine,
and avian wildlife.
Table 20 — Evaluation of Hazards of
2,2-dibromo-3-
nitrilopropionamide (DBNPA)
to Wildlife
Aquatic Life
Bluegill sunfish, 96•hour LCo
1.31 (1 A-i.6), mg/t
' 1
Rainbow trout, 96-hour LC,,,
1.0 (0.6.1.5) mg/l
Fatimad minnow, 96-hour LCm 1.36 (1.24-1.481 mg/1
Daphnids,48-hourL.C�
1.24 (1 -0& 1,94) mo
Largemouth bass fingerling,%,
Whour I.Q.
1.63 (1.54-i,73) mg/1
Marine Life
Eastern oyster'(larvae),
48-hour LC.
a0.56, c1.0 mg/l
Fiddler crab, 9irhour LC„
14 (5-1-361 mg/)
Pink shrimp, 96•hour LC,,
-
>l.ti, C1.? moll
Glass shrimp, 96•hour LC„
116 (8.69-1522) mg/l -
Asiatic darn, 96-hour LC.
>W mg1l
Brackish Ovate clam,
24-hour LC„,
20 mg/l
Shccpshcud minnow,
96-hour LCb
mgrl
Avian Life
Mallard duck, oral LD„,
'All values based on aclive `
DBNPA
Male
Femalc
205 mg/kg
216 mg/kg
=9,�X nun/idrnce interval
'Pat rntaAe af'abnnnmath,
&)b White quail, oral LDS
delvloped larvao (trot
morraJlh'1
Malt
Female,
166 mg/kg
150 till;/kg
Toxicity hazard to fish
Based on the Several degradation path•
ways of DBNPA and its intermediate degradates,
the proper use of DBNPA in industrial water
Systems results only in traces of the compound
in discharge water. Chemical and biological
decomposition, and dilution of the effluent
water, result in rapid disappearance of these
traces. Therefore, DBNPA does not present a
Serious fish toxicity hazard when used properly.
However, all discharges of D13NPA into lakes,
streams, ponds, or public waters roust be in
accordancewithaNational Pollutant Discharge
Elimination System (NPDES) permit. The cur-
rent data indicate thatDBNPA has the potential
for localized fish kill only if a large amount
of biocide is discharged into a lake or river.
Far further guidance, contact your local BPA
regional office.
33

Recirculating water
cooling towers
Recirculating water systems am com-
monly contaminated with fungal and bacterial
organisms, and occasionally with algae. In
addition, their spores and reproductive cells
are continuously present in the air, so the likc-
lihood of repeated innoculation is extremely
high from a biological standpoint.
With their extremely fast killing action,
DOW Antimicrobials 7287 and 9536 effectively
control entering microorganisms before they -
can create problems. Because most microorgan-
isms are killed verysoon after exposure, there
usually isn't time for daughter generations to
develop. Fast kill means first generation kill,
which goes a long way toward preventing adap-
tation to the biocide or defense through secre-
tion of biofilm.
Kill rate outpaces degradation rate
DOW DBNPA typically yields a 99.999
percent kill before it degrades sufficiently to
lose effectiveness. Figure 1 shows the degrada-
tion profile of DOW DBNPA for various tem-
perature and pH combinations.
At neutral pH and normal system oper-
ating temperatures, DOW DBNPA exhibits a
half-life of about nine hours. As pH increases,
the rate of degradation of DOW DBNPA in-
creases, but virtually complete microbial kill
is achieved well before significant degradation
occurs. As shown in Figure 2. DOW DBNPA
easily achieves 99.999% kill in under three
hours even in alkaline systems.
Figure 1 — Half-life of DOW DBNPA vs.
pil (Hydrolysis)
100
f 10 VC
zs1C
s
\5(r
C
s 9 to 11
t,n
Figure 2 - Rate of Microorganism Kill by
2.5 ppm DOW DBNPA in
High pH (8.5) System
100
10
l
.n1
.001
T Viable nroanistns remaining
25 ppm DBNPA
.0001U 40 80 12) 160
Time minutcsj
100ppm.elWinin pH=8.5
500 ppm fla dnrV ? ?Fil fntriatC UAnt
Compatible and synergistic ►*ith
chlorine treatment
DOW Antimicrobial 7287 and DOW
Antimicrobial 8536 provide excellent results
in co -treatment programs with chlorine.
Neither substance reacts with, degrades, or
inhibits the antimicrobial acdvity of the other.
In combined treatment programs in
larger systems, DOW DBNPA antimicrobials
help control a broader variety of microorgan-
isms than chlorine treatment alone.

11/23/98RON 13:16 FAX[phone] DOW CHEMICAL CIG M009
Tablet placement precautions
Use the bag provided, or a similar
receptacle made of nylon or plastic.
Suspend this in the tower basin in a
manner that avoids direct contact
with basin sidewalls or floor. Note
that DBNPA at -use concentrations
do NOT contribute appreciably to the
corrosivity of tower water.
• Avoid incomplete immersion
• -Do not allow contact with basin
walls or floor
• Avoid areas of high velocity
water flow
Avoid sunlight .
Monitoring tablets In use
SUMP BUDDY WT Time -Release
tablets release active DBNPA by
gradual dissolution and erosion of
the outer tablet surface. The outer
dissolving layer remains thin;
DBNPA in the core remains dry.
During the first few days in a
system, the appearance of a tablet
will not change dramatically. Within
one week, the sharp edges will lose
definition, then round off and appear
translucent This marshmallow -like
appearance will then remain essen-
tially the same and the tablet will
decrease in size until completely
dissolved. During initial location
trials, monitor tablet dissolution to
by uniform dissolution. The expected
tablet lifetime was calculated at
21 days at a flow rate of 0.058 ft/sec,
and 13 days at 0.26 ft/sec.
verify that it follows the typical . Compatibility cautions
three-week schedule.
Previous bests have shown that,
DBNPA, the active ingredient in
f71.ssglutlin-rates van}-yYbtls-_-- - __--
SUMP BUDDY W..T.Mmt:-ReleaRp _ ..._... _
water flow rates
tablets, is compatible with cooling
Figure 5 shows average tablet dis-
tower water and various components .
solution profiles obtained in a study
of most water treatment programs.
that modeled water flow rates
However, mercaptobenzothiazoles
bracketing the range typical of
and their sodium salts will rapidly
bypass feeders. Two tablets were
degrade DBNPA, as will strong
studied at each flow rate and the
reducing agents such as oxygen
results. were averaged.
scavengers'or hydrogen sulfide.
The data indicate initial weight
gains as the tablets hydrated, followed
5 - Average tablet dissolution profiles at two water flow rates
temperature: 31t2°C [89t5.771)
300
See Note
zao >0.058
ft/seC
�-
m '
0
A 100 ` %
0.26 ft/sec
0
0 2 4 6 8 10 12 14 16, 18 20
Time (Days)
Note: in the study at 0.058 ft/sec, the experiment was shut down for a weekend; the tablets were allowed to dry and lost
weight The tablets quicW rehydrated when the experiment was restarted. Note that this upset had very little effect on
dis6olotion rate.
7

12/BZ/98 87:55:56- kightFhX UT-> Page 881
Bib
r iN.i'Mi,:.l v;ael�:wiA-toslA.t+:r!n
Comnserq�t 8 Speclalt(es al#1s1�t
FACSIMILE COVER SHEET
*"CONFIDENTIAL —
DATE: December Z, 1998 TEME: 8:01 AM
TO: Ed Spencer PHONE:
COMPANY: Consolidated Water Conditioners FAX: [phone]
FROM: AlanD. Harrison
RE: Half Life.ofHalogen from BromiCideo
CC: Leisa Corbett, Michelle Harrison
Number of pages including cover sheet: 1
Dear Mr. Spencer:
Going back into archives of work that was done in the late 1980's we were able to find some work
that was done on half-life of halogen from BCDMH in natural outdoor conditions. Please note that
this information is not from simulated UV light, it is actual use information collected from BCDMH
being used in an outdoor environment. T of halogen from BCDMH in an actual outdoor
environment ranges from'
I hope this helps you with your permitting question. Please let me know if there is anything else I
can do to help. Thank you for your support of our products.
Sincerely:
Alan D. Harrison
Manager, Applications Technology
(This message wes transmitted ele&cnicdly and,contains an electronic signature).
BioLab Inc., Commercial and Specialties Division, Industrial Water
P.O. Box 1489 • Decatur, GA 300314489
Phone (404) 378-W85 or [phone], Ext.1284 • Fax [phone] E-Mail aharrison@biolabinc-com

11/23/1998 12:49 99999999999999 HOUGHTON CHEMICAL PAGE 01
e
MATERIAL SAFETY DATA SHEET
MSDS pow: 1 017
Dattlsaued: 17A ilr497
NODS ftf. No: MC=025
Dale -Revised: 17nVt997
Revision NOG t
Purobrom Tabl4br
1. CHEWCAL PRODUCT AND COMPANY IDENTIFICATION
PRQDUCT NAME: Purobrorn Tablets
GENERAL USE: Industrial watWtreatment•
CHEMICAL FAMILY: Halogewded hydantoin
MANUFACTURER 24 HR. EMERGENCY TELEPHONE
Houghton Chemical Corporation NUMNE S
52 Cambridge Street CHEMTREC (Transpartatlon) [phone]
Allston, MA 02134
Cusb4mer SERVICE: [phone]
2. COMPOSITION I INFORMATION ON INGREDIENTS
Chemical Name
1-bromoZ-cNond•5,5-dimefthydentoin
COMMENTS:
(BCDMH)
3. HAZARDS IDENTIFICATION
EMERGENCY OVERUIIi W
PHYSICAL APPEARANCE:
White tablets with halogen odor.
Wt.% CAS Registry 0 EINECS #
92.5 1607"8.2 240 230-0
IMMEDIATE CONCERNS:
QANGER: Corrosive. Causes skin end eye damage. Harmful or fatal if swallowed. Do not get
in eyes, on skin or an clothing. Wear goggles or face shield and rubber gloves when handling.
Irritating to nose and throat Avoid breathing dust. Remove and wash contaminated clothing
before use. Wash throrougtily with soap and water after handling.
POTENTIAL HEALTH EFFECTS
EYES:
DANGER: Corrosive. Causes eye damage. Do not get in eyes.
SKIN:
DANGER: Corrosive. Causes skin damage. Do not get on skin.
INGESTION:
HanT ful Of fatal If swagawQd.
Paa4t' Fax Note 7671
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gof
pages► $
TO
FMM
CaJoept.
Co.
Phone 4
Phone #
Fax # 2
Fax 0

11/23/1998 12:49
99999999999999
HOUGHTON CHEMICAL
PAGE 02
MATERIAL SAFETY DATA SHEET
MSDS Pape: 201),
Dole-b mod: IZMI11997
NISDS W. No: PHCC22025
Dats�llssv$nd: LMV19W
Rcvlslan Nw 1
Pufobrom Tablets
INHALATION:.
Irritating to nose and throat Avoid breathing dust or tunes.
MEDICAL CONDITIONS AGGRA W111 .
Existing dery wtltls may be aggravated by exposure.
ROUTES OF ENTRY.
Skin Contact, Inhalation, Ingestion. Eye Contact.
COIMiIIENTS HEALTH:
There are no known chronic hourds.
4. FIRST All] MEASURES
EYES:
Eye Contact: Irrigate eyes with large volumes of room temperature water for at least 15 minutes,
then seek medical attention promptly.
SIGN:
If on Skin: Remove contaminated clothing immediately. Brush aR excess chemical and wash
akin with large volumes of soap and water, flushing the skin with water for at least 10 minutes. If
sidn irritation develop*, a wk rnscticgI attention.
INGESTION:
If Swallowed: Seek medical attention promptly. Do not Induce vomiting. Do not drink alcohol.
Drink at least 9 ounces of. water (not to exceed 0.23 oz. per pound In a child).
INHALATION:
If inhaled: Relmove to fresh air. It breathing is difficult, have trained parson adadnister oxygen.
If not breathing, give artificial respiration. Call a physician immediately.
NOTES TO PHYSICIAN:
Probable mucosal damage may contraindicate the use of gastric lavage.
5. FIRE FIGHTING MEASURES
GENERAL HAZARD:
In large fires fueled by other materials. this product may smolder for prolonged periods emitting
a dense black smoke.
Any spilled material should be considered contaminated. Neutralize to a non-0xidlzing material
for saEa disposal. Material which appears undamaged except for being damp' on the outside,
should ber opened and Inspected Immediaeely. If the material is damp, it should be neutralized
to a non -oxidizing material for sate disposal. .

11/23/1998 12:49 99999999999999 HOUGHTON CHEMICAL PAGE 03
MATERIAL SAFETY DATA SHEET
NISDS ate: i or T
Drro-haed: 1N'G11t947
MSDS Ref. rro: HiCCsz025
DecAwLed: 12j=1947
Rnv4roR No: t
Purobrom Tablefe
EXTINGUISHING MEDIA:
In case of fire or smoke, call the fire department. Do not attempt to extingu ish the flre without a
self-contained breathing eppamtus (SCBA). Do not let the Are burn. Flood with capioUS amounts
. of water. DO NOT use ABC or attter dry chemical extinguishers since there Is the potential for a
violent reaction.
EXPLOSION HAZARDS:
A dust expicaion severity determination was perfofined using the Hartmann Dust Exploslbiaty
Bomb designed at the U.S. Bureau of Mines. The product was determined not to be ignitable.
RRE FIGHTING PROCEDURES:
Fires fueled by other material! may release hydrogen bromide, bromine. hydrogen chloride or
chlorine. vaar sell -contained breathing apparatus. Ammonium phosphate (ABC) fires extira-
guishem should not be used.
S. ACCIDENTAL RELEASE MEASURES
GENERAL PROCEDUIRES:
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED : Spilled Material should
be considered contaminated and not used. Using appropriate protective clothing and safely equip-
ment, owlsin spilled material. Do not add water to spilied material. Using clean dedicated equip-
ment, sweep and lm=p all spilled material, contaminated soil, and other contaminated material
and place into clean dry containers for disposal. Do not use floor sweeping comppounds to dean
up spills. Do not close containers containing wat or damp material. They should be leftopen to dis-
perse any hazardous genes that may farm, Do not. transport wet or damp material. Keep product
out of sewers. watersheds and water s9yste ns. Do not contaminate water, food, or food by storage,
disposal or dean Ing of equiprrwnt Dispose of according to locai, state and fardand replations.
7. HANDLING AND STORAGE
HANDLING:
STRONG OXIDIZING AGENT Do not nag with other chemicals. Mix arty with water Never
add water to product. Always add product to large quantities of water. Do not add any other
chemical to dispensing device t;ontaining this product. Use clean dry utensils. Do not add this
product to any dispensing device dining remnants of any other product. Such use may cause
a violent reaction leading to fire or explosion. Contamination with moisture, organic matter or
other chemicals may start chemical reactions and generate heat, hazardous gas, possible fire
and explosion. In case of contemination or decomposition, de not reseal canminar if possible.
isolate container in .open air or well ventilated area. Flood area with large volumes of water.
STORAGE:
Keep this product In original dosed container when not in use. Store Ina cool, dry, weilve ndlated
area sway from heat or open flame. Do not contaminate water, food ar feed by storage or disposal
or cleaning of equipment Do not store above 125 F (52 C).

11/23/1998 12:49 99999999999999 HOUGHTON CHEMICAL PAGE 04
MATERIAL -SAFETY DATA SHEET
MSDS
Dun-Isiwe& 12MIA097
MSDS ME No: PHCC=W3
V=AzvhW; L7 VIM
Acvi:iaa No: 1
Purobrorn Tablets
S. EXPOSURE CONTROLS 1 PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA HAZARDOUS COMPONE14TS (29 CFR 1910.1200)
EXPOSURE LIMITS
OSHA PEL ACGIH TLV SUPPLIER CEL
ppm Mghn3 ppm rnglm3 Apra mg1m9
1-brom0-3-Chloro_�5,54methylhydr• TM N1Et11 NIE
ntdn
OSHA TABLE COMMENTS:
1. NIE = Not Established
ENGINEERING CONTROLS:
General room ventilation plus local exhaust should be used to minimize exposure to dusttvapors.
.PERSONAL PROTECTIVE EGUIPMENI!
MS'AND FACE.,
V*ar goggles or safely gia66eswith side shields whom mandling.this product.
SKIN:
Weir rubber gloves when handling this product. Avoid contactwith skin.
RESPIRATORY:
A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must
be followed WheneverworkpiaCe oonditions warrant a respirator's use.
WORK HYGIENIC PRACTICES:
Remeve and wash contaminated clothing before reuse.
OTHER USE PRECAUTIONS:
Facilities storing or utiltzing this material should be equipped with an eyewash and safety shower
9.- PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE: S0 d
ODOR: Faint halogen odes
APPEARANCE: Tablet
COLOR: White
'pH: 3.5(0.1% solution in DI water)
THERMAL DECOMPOSITION: 145•C to 1509C
SOLUBILITY IN WATER: 0.15g11oog water
DENSITY: 60.1 Ib1tt3

11/23/1998 12:49 99999999999999 HOUGHTON CHEMICAL PAGE 05
MATERML SAFETY DATA SHEET
MSDS
Purobrom Tablets
10. STABILITY AND REACTIIY "
Pa is a of 7
UWA-Umd: tM111g97
WrA IZof. No: PM(.X=5.
pr>nRsvleed: 17= 1997
hvisim No: I .
CONDITIONS TO Arola
High temperature. Poor ventilation. Contamination. Moisturelhigh humiditK
STABILITY:
This product is stable under normal conditions.
POLYMERIZATION:
Hazardous polymeftMIon will not occur under normal conditions.
HAZARDOUS DECOMPOSITION PRODUCTS:
Hydrogen brorMrk, bromine; hydrogen chloride, chlorine.
INCOMP9TIBLE MATERIALS:
Avoid contact with water.an cancentrated material in the container. Avoid contact with see -
ay oxidizable material; ammonia, urea!, or similar nitrogen containing compounds: inorganic re-
ducing compounds; floor aw*Vfng compounds; cyanurtc acid containing compounds; calcium
hypochlorite; alkalis. Avoid contact with all other chemicals.
11. TOXICOLOGICAL INFORMATION
ACUTE
EYES: Wdcoiogiaai study Indicate this product to be corrosive to eyes.
DERMAL I.Dca: 'The dermal L030 Is greater then 2.0 glkg (rabbit). The primary skin Irritation
Index is G.1 and the product is considered corrosive to skin.
ORAL LDv: 572 mglkp (1a4.
CARCINOGENICITY
This product Is riot listed as a carcinogen by IARC-
This product Is not lislied as a c n;inopen by NTP.
This product Is not listed as a carcinag" by OSHA.
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION;
This pesticide is taxis 10 fish and aquatic organisms. Do not disharge.effluent containing this
product into lakes, 'streams. ponds or estuaries, oceans, or they watem unlaw in accordance
,with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit
and the permitting authority has been notitled in writing prior to discharge. Do not discharge
effluent containing this product to sewer systems without previously natifying the local sewage
ireratment plant authority. For guidance contact your State Water Board or Regional Office of the
EPA.

11/23/1998 12:49 99999999999999 HOUGHTON CHEMICAL PAGE 06
MATERIAL SAFETY DATA SHEET
MSDS Psi. aof7
Dateutwd: 12/01/1997
MSM Ref. Nu: PHCC 22025
Dal-Mvin& 12=1M
Revision No: I
Purabrom Tablets
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD:
Pesticide wastes are tom Improper disposal of excess pesticide or rinsate is a vlotation of
Federal Law. If these warms cannot be disposed of by use according to label instructions, contact
your State Pestipde or Environmental Control Agency or they Hazardous Waste Rept"entadve
at the nearest EPA Regional Cfflce for guidance. Do not contaminate water, food, or feed by
storage or disposal or cleaning of equipment. Do not put product, spilled product, or ffkw or
partially filled containers Into the trash or waste compactor Canted with incompatible materials
Could csuse a macdon or fire.
EMPTY CONTAINER:
Do not reuse containac Rinse throughly before discarding In trash.
14. TRANSPORT INFORMATION
DOT (DEPORTMENT OF TRANSPOMTION)
PROPER SHIPPING NAME: Oxidlafng Solid. N.O.S. (Sromachloro-dimethyihydantoin)
PRIMARY HAZARD CLASSlDiVf$ION: 5.1
UN/NA NUMBER: 1479
PACKING GROUP: 11
16. REGULATORY INFORMATION
UNITM STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
313 REPORTABLE INGREDIENTS: This product or its components acre not listed.
CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)
CERCLA REGULATORY`. This product or its components are not listed.
TSCA (TOXIC SUBSTANCE CONTROL ACT)
TSCA REGULATORY: This product or its components are not subject to export notification.
TSCA STATUS: This product or Its components are listed on the TSCA Inventory.
OSHA HAZARD CC MM.' RULE:
Product is hazardous by deflnMen of the Hazardous Communication Standard,
CLEAN'AlATER ACT:
Not Listed.
FiFRA (FEDERAL INSECTICIDE. FUNGICIDE. AND RODENTICIDE ACT):
This product is a regimred pesticide.

11/23/1998 12:49 9999999§999999 HOUGHTON CHEMICAL PAGE 07
MATERIAL SAFETY DATA SHEET
MSDS pvc 7 er7
DqC-Inut 12MVI"7
NISIDS Ater. No: FHC.(.WO23
Die-AwiAd� 1217]I1907
Revision NO: I
Purobrom Tablets .
soy% (SAFE ORINKIN(3 WATER ACT):
Not listed.
CLEAN AIR ACT
40 CFR PART 68—RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVEW
TION: Not listed.
STA-M REGULATIONS
PROPOSITION 65 STATEMENT
This product or Its components are not listed on any Proposition 65 lists of carcinogens or repro-
ductrm toxicants.
is. OTHER INFORMATION
REVISION SUMMARY
Revision #: 1
This MSDS repmees the Decsmber 01,1997 MSDS. Any changes in information are as follows:
In Section 14
DOT Proper Shipping Name -DOT Imhnlcal Name
NFPA COQES
HEALTH: 3 FIRE: 1 REACTNITY: 1 SPECIAL: 8-
NFPA STORAGE CLASSIFICATION:
NFPA Oxidizer Class 2
HMIS Cd06S
HEALTH: 3 FIRE: 1 REACTIVITY i' PROTECTION: S
MANUFACTURER DISCLAIMER:
IMPORTANT. This Inforrmtion is given withouta warranty or guarantee. No suggestions for use are.,
intended or shall be coristrued as a mconlmendatlon to Infringe any e:dsdng patents at violate any
Federal, State orlocal laws. Salt handling and use isthe responsibility of the customelr. Read the
label before using this product This irdvrmadon is true and accurate to the best of our knowledge.

BromiCide
PRODUCT INFORMATION
June 13, 1997
Granules
BromiCide GRANULES ARE THE
INTERMEDIATE FORM OF BromiCide'. Thev
are the product of choice where you want to quickly attain a
halogen residulal, but desire the simplicity of control of a
Brominator.
• SAFER HANDLING. Because of its solid form.
BromiCide is easier to handle than most common gas and liquid
oxidizing biocides, thereby reducing the likely risk and impact of
environmental exposure.
• ENHANCED ENVIRONMENTAL
ACCEPTABILITY. BromiCidego decays rapidly allowing
for safe discharge into most waste water systems.
DESCRIPTION AND USE
BromiCide Granules (1-bromo-3-chloro-5,5-dimethylhvdantoin) offers
a safer, more effective altemative to chlorine based oxidizing biocides
and non -oxidizing biocides for microbiological control in industrial
cooling waters. When dissolved in water, BromiCide' Granules generate
hypobromous acid.
BromiCide° Granules are registered with the United States
Environmental Protection Agency for use in once -through and
recirculating cooling waters, heat exchange water systems, air washers
equipped with mist eliminators, industrial water scrubbers, influent
water systems, brewery pasteurizers, cooling ponds, and wastewater
treatment systems.
TREATMENT AND DOSING REQUIREMENTS
BromiCide' Granules effectively controls bacterial, algal, and fungal
slimes that can cause costly reductions in heat transfer efficiencv.
BromiCide' Granules can either be dosed on a continuous or
intermittent shock basis using a specially engineered dosing system
For noticeable fouling, add 0.2 - 0.5 ppm as Cl, for continuous dosing,
or 1 - 2 ppm as Cl_ for intermittent shock dosing. Typically, in well
managed systems, successful control has been demonstrated with
dosages in the range of 0.1 - 0.3 ppm total halogen as Cl_. For more
information, contact Great Lakes Water Treatment technical support at
the above number.
TYPICAL PROPERTIES
BromiCide Granules are white to off-white in color and have a faint
halogen odor.
IH, ,9
Structural Formula:
B��CI
0
BioLab
A Subsidiary of Great Lakes Chemical Corp.
Active Ingredient
1-bronmo-3-chloro-5,5-dimethylltydantoin
Abbreviation
BCDMH
Empirical Formula
C5H6BrCIN_0_
Molecular Weight
241.5
Bulk Density
57 lbsift3
Solubility @ 25 ° C
0.2 % as BCDMH
4'o Active Ingredient
96
Melting Point (° C)
145 - 150 Decomposes
STORAGE AND HANDLING PRECAUTIONS
Keep BromiCide Granules dry in a tightly closed container. Avoid
contamination with moisture, chemicals or any other foreign materials due to risk
of explosion, fire and release of hazardous gases. Store in a cool, dry, well -
ventilated area away From heat sunlight, open flames and organic materials such
as greases, oils, and solvents.
BromiCide Granules are corrosive in solution, and may be fatal if swallowed.
Inhalation of dust may cause irritation of the nose and throat, and irritation to
skin. Always wear a dust mask approved by the appropriate national authority,
impact -resistant safety goggles or safety glasses, and a full -face plastic shield
with forehead protection. To avoid contact with skin, wear rubber or plastic
gloves, long pants, and long shirt sleeves. Always tuck gloves under shirt
sleeves and leave pant legs outside of boots. Wash contaminated clothing and
equipment before reuse.
SAFETY PRECAUTIONS
Do not leave wet BromiCide° exposed to air inside a Brominator teed system.
,after adding BromiCide° but before replacing the top closure, refill the tank with
water. Failure to do so may allow for product decomposition leading to pressure
build-up in the feeder. High pressures may lead to rupture of the feeder causing
serious bodily injury or property damage by explosion, fire or release of
hazardous gases.
Contact of BromiCide Granules with organic materials such as alcohols,
aldehydes, and ketones, or strong reducing agents may cause a chemical reaction
leading to a pressure build-up in the feeder. High pressure may lead to'rupture
of the feeder causing serious bodily injury or property damage.
Before handling BromiCide Granules, all persons must be thoroughly aware of
the hazardous properties and have reviewed a ;Material Safety Data Sheet
(1vISDS). A NISDS may be obtained from Great Lakes Water Treatment.
PACKAGING INFORMATION
BromiCide Granules are available in 25 and 50 pound pails, and 500 pound
bulk bags.
Hou~ghton�Chernical Corpora_tion_, � ,
P.O. BOX-3d7-4 52 CAMBRIDGE STREET
ALLSTON (BOSTON), MA 02134
TEL: [phone] FAX: [phone]
CON MERCIAL & SPECIALTIES DIVISION * INDUSTRIAL WATER TREATMENT
P.O. Box 1489, Decatur GA. USA 30031-1489 or 627 East College Ave.. Decatur GA. USA 30030
Tel: [phone] or [phone] / Fax: [phone]

11/09/98 13:57 %Y704 322 3535 SHUFORD MLS R&D 19001
' Facility Name: C �l U
�~ t��`C-,IEs NPOES #: NCgg5 p523
BIOCIDE/CHEMICAL TREATMENT
WORKSHEI_ f -FOAM 10i
The following calculations are to be performed on any biocidal products ultimately discharged to the surface waters of
North Carolina. This worlcsheet must be completed separately for each biocidal product In use. This worksheet Is to be
returned with all appropriate data entered into the designated areas with calculations performed as indicated.
i- Facility Name RT + t tv+�c�c ins �Z>►`l� P
-•�. PLC-rt-r-
NPDES # NG Ce2ce:, 23 _ tDutfaTl # ��
County —AL- 5w-�
Receiving Stream -- - l ►2iE::, C2C 7Q140 2
(, fS)
(Alf above information supplied by the Division of Environmental Management)
What is the Average Daily Discharge (A.D.D.) volume of the water handfing systems to the receiving water body?
A.D.D. _ • 00 otk (in M.G.D.)
P!ease calculate the Instream Waste Concentration (IWC in percent) of this discharge using the data entered
above.
,? 1
(A.D_D.) X 1D0 _ (,ceZI) X 140
(7Q10)(0.646) + (A.D.D) - ( , a )(0.646) T (. �czt) /. S�9 176
This Value (IWC) represents the waste concentration to the receiving stream during low flow conditions.
IL What is the name of the whole product chemical treatment proposed. for use in the discharge identified in Part I?
U KQ Gg o ry)
Please list the active ingredients and percent composition:
os>10 — 3 c.% i o r a — S t m t? �' o
What feed or dosage rate -(Ali.) is used in this application? The units must be converted to maximum grams
of whole product used in a 24hr period.
D.R.= 170 grams/24hr period
Please note, fluid ounces (a volume) must be converted to grams (a mass). The formula for this conversion is:
Grams of product = fluid oz. of product X 1 cal. water X 8.34 lbs. X specflic gravity of product X 4 3.5
128 fl. oz. 1 gal. water 1 lb.
D.E.M. Form 101 (2/95) 1

11/09/98 13:57 %9704 322 3535 SEUFORD AILS R&D 19002
Facility Name: 514 u R TAPE
NPp1=S #: NC G Sv o 3 a 3
Estirnate total volume of the water handling system between entry of biocidal product and N-P DES discharge
point On an attached sheet please provide justification for this estimate (system volume, average eycics per
blowdown, holding lagoon size, etc.)
Volume • D t a S million gallons
What is the pH of the handling system prior to biocide addition? If unknown enter NIA 8 • ?
What is the decay rate (D.K.) of the product? If unknown, assume no decay (D.K.=O) and proceed to asterisk. The
degradation must be stated at pH level within 1/2 pH standard unit within handling system. Enter the half life (Half
Life is the time required for the initial product to degrade to half of its original concentration). Please provide
copies of the sources of this data.
H.L. _ %0� Days .
The decay rate is equal to -I--X 0_09 ; b • 63 �{ =Decay Pate (D.K.)
Calculate degradation factor (D.F.). This Is the first order toss coefficient
a aDf a K - � o°z( I /
(Volume) ( ) - ( o CtZ-S ) +
Calculate Steady State Discharge Concentration:
Dischg Conc.: __ 1 70 d �� 0
(D.F.)(Volume)(3785) (6 , U ) ( , D lZ S- ) (3 7 t3 5) mgA
Calculate concentration of biocide instrearn during lowflow conditions.
(Receiving Stream Concentration)
aisch _ Conc. x Mc% o. 5-Z9 1
100 a 100 = mgli
Receiving Stream Concentration
Calculate regulated limitation.
List all LC50 data available for the whole product according to the following columns. (Mote that units should be in
mgtl): Please provide copies of the sources of this data.
o� Testpuration C (mo)
a � ,
(N
D.H.M. Form 101 (2/95) 2

11/09/98 13:58 . U704 322 3535 SHUFORD MLS R&D A 003
Facility Name: 5Ef URTjq
NPDES #: NC G sov 3 a.3
Choose the lowest LCSO fisted above:
Enter the LC50: C7 • `-( (7 -
If the half life (H.L) is less than 4 days, perform the following calculation.
Regulated Limitarjon = 0.05 x LCso
mg/t
If the half rife (H.L.) is greater Than or equal to 4 days or unknown, perform the following calculation.
Regulated Limitation 0.01 x LCM = to
m
Choose the appropriate regulated limitation from the calculations immediately above and place in this blank:
C7� 00-1.3
—mg/liter
From Part 11 enter the receiving stream concentration:
O e 0 0 o mg/liter
IV. Analysis.
If the receiving stream concentration i; greatertf= die calculated regulated limitation, then this biocide is
unacceptable for use.
Name (Print)
Date
Person in Responsible Charge
n Cvrr*dng 1t fth Date
(if Different From Above)
D.B.M. Form 101 (2195) 3

11/09/98 13:58 %9704 322 3535 SHUFORD MLS R&D 19 004
Facility Name: { H (JA TOC NPOES #: NC G Scv 3 9-3
uanlemental Metals Artalvsis
If copper, zinc, or chromium are present in the proposed biocidal compound, complete this worksheet. A separate Farm
must be used for each metal and/or metal compound presbrtt in the biocide_ List the metal, its chemical formula, molecular
weight (MW), formula weight (FYI), and the concentration of the metal compound in the biocide (MCC). Complete a
separate form for every metal present in the biocide.
Metal Chemical Formula Molecular Weight of Nietal Fnmula Weight Conoea ration in Biocide
EXAMPLE
Copper Cu50¢ SH 0 63.546g/mcle 249.680g/mcle 0.2
Dosage rate of Biocide (DR) (from page 1):
OR = rams/day
Average Daily Discharge (ADD) (from page 1):
ADD = million gallons/day
Discharge Concentration (DC) of Biocrda:
DC DR _ grams/day) aramslmilliongalions
— ADD — ( _ _million gallans/day)
Convert DC to micrograms/litQr (ppb):
DC (µcgfl) = --_—PC (grams/million gat) x 1 x 106 Lca/a = u /l
3.785 x 106 literstmillion gal. g
Calculate the fraction of metal In the metal -containing compound (MF):
! — ( grams/mole)
MF =FW — ( grams/mofe)
Calculate the fraction of metal in the biocidai compound (BF);
BF = MF x MCC NO = x %
O
(100)
Calculate the concentration of metal in the discharge (M):
M = 00 x BF ng1l x
•'Citicutate the instrearnt metal•zvtrcentratioh (iMC) at low -flow conditions:
iMC = M x WC .0% — ug/l x % _ u,gA
100 100
Regulated limitation of meta[ (from below): gg/l
N eneral tatutes 1 A tv .02 t 1 aline: ,
Copper- 7 µg/t water quality action level- Ztnc- So µgill water quality action level-
Chromium- 50 µgill water quality standard
("Values which exceed action IaveLs must be addrassod directly by aquatic tonicity te6ting,)
D.E.M. Fotnn 101 (2195) 4

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ySlytied0Vd VI
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•40014pd BK� 3p aa°'�aae$x
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•s.zea '910plquV *TjTaedc ctE •m:og'alul"saIIoaap ssai�
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ETZZ-DSZ QT9l ® TO IM IN3NO HUIRMOH :WUJJ

. Additional controlled copy: Packager's MSDS notebook
M A T E R I A L S A F E T Y D A T A S H E E T
1. CHEMICAL PRODUCT & COMPANY IDENTIFICATION
24-HOUR EMERGENCY PHONE NUMBER: 517-636-4400
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date Printed: 06/11/97
The Dow Chemical Company, Midland, MI 48674
Customer Information Center: 800-258-2436
2. COMPOSITION/INFORMATION ON INGREDIENTS
Active ingredient:
2,2-Dibromo-3-nitrilopropionamide
Inert ingredients:
Hydroxypropyl
methylcellulose
Lactose
Stearic acid
3. HAZARDS IDENTIFICATION
Vu
IPage: 1
CAS# 010222-01-2
CAS# 009004-65-3
CAS# 000063-42-3
CAS# 000057-11-4
MSD: 002968
40%
60%
EMERGENCY OVERVIEW
************************************************************************
* Off-white solid. Mild, disinfectant odor. Causes severe eye burns.
* Avoid temperatures above 158F, 70C. Highly toxic to fish and/or
* aquatic organisms.
************************************************************************
POTENTIAL HEALTH EFFECTS (See Section 11 for toxicological data.)
EYE: Broken or crushed product may cause severe irritation with
corneal injury which may result in permanent impairment,
of vision, even blindness.
SKIN: Prolonged or repeated exposure may cause skin irritation,
even a burn. May cause allergic skin reaction in susceptible
individuals. A single prolonged exposure is not likely to
result in the material being absorbed through skin in harmful
amounts.
INGESTION: Single dose oral toxicity is considered to be moder-
ate. Small amounts swallowed incidental to normal handling
operations are not likely to cause injury; however, swallowing
(Continued on Page 2)
(R) Indicates a Trademark of The Dow Chemical Company
0/D #

M A T E R I A L S A F E T Y D A T A S H E E T Page: 2
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date Printed: 06/11/97 MSD: 002968
--------------------------------------------=---------------------------
3. HAZARDS IDENTIFICATION (CONTINUED)
amounts larger than that may cause serious injury, even death.
INHALATION: Single exposure to dust is not likely to be
hazardous.
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Excessive exposure may
increase the blood and tissue levels of bromine. observa-
tions in animals include kidney effects following repeated
ingestion, but no evidence of systemic. toxicity following
repeated dermal exposure at maximum attainable doses (data
on active ingredient). Ingestion of extremely large amounts
of stearic acid may lower blood clotting time.
4. FIRST AID
EYE: Irrigate with flowing water immediately and continuously for
15 minutes. Consult medical personnel.
SKIN: Wash off in flowing water or shower.
INGESTION: If swallowed, induce vomiting immediately as directed
by medical personnel. Never give anything by mouth to an un-
conscious person." Consult medical personnel. Seek medical
attention immediately.
INHALATION: Remove to fresh air if effects occur. Consult a
physician.
NOTE TO PHYSICIAN: If burn is present, treat as any thermal burn, -
after decontamination. No specific antidote. Supportive care.
Treatment based on judgment of the physician in response to
reactions of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: Not applicable.
METHOD USED: Not applicable.
AUTOIGNITION TEMPERATURE: Not applicable.
FLAMMABILITY LIMITS
(Continued on Page 3)
(R) Indicates a Trademark of The Dow Chemical Company

M A T E R I A L S A F E T Y D A T A S H E E T Page: 3
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date Printed: 06/11/97 MSD: 002968
------------------------------------------------------------------------
5. FIRE FIGHTING MEASURES (CONTINUED)
LFL: Not applicable.
UFL: Not applicable.
HAZARDOUS COMBUSTION PRODUCTS: Under fire conditions some
components of this product may decompose. The smoke may
contain unidentified toxic and/or irritating compounds.
EXTINGUISHING MEDIA: This material does not burn. If exposed
to fire from another source, use suitable extinguishing
agent for that fire.
FIRE FIGHTING INSTRUCTIONS: This material does not burn. Fight
fire for other material that is burning.
PROTECTIVE EQUIPMENT FOR FIRE FIGHTERS: Wear positive -pressure
self-contained breathing,appara�_-•7s (SCBA) and protective .fire
fighting.clothing.(ihcludes firs: fighting helmet, coat, pants,'
boots, and gloves).
6. ACCIDENTAL RELEASE MEASURES (See Section 15 for Regulatory
Information)
PROTECT PEOPLE: Use appropriate safety equipment. For additional
information, refer to "Exposure Controls/Personal Protection",
MSDS Section 8. Avoid any contact.
PROTECT THE ENVIRONMENT: Contain material to prevent
contamination of soil, surface water or ground water.
CLEANUP: Sweep up. Collect material in suitable and properly
labeled open containers. Contact the Dow Chemical Company
at 517-636-4400.
7. HANDLING AND STORAGE
HANDLING: Avoid contact with dusts from head space of containers.
Refer to "Exposure Controls/Personal Protection", Section 8,
of the MSDS.
STORAGE: Store below 95F/35C. Storage must only be in original
container. Keep container tightly closed when not in use.
(Continued on Page 4)
(R) Indicates a Trademark of The Dow Chemical Company

C
13
M A T E R I A L S A F E T Y D A T A S H E E T
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97
Date Printed: 06/11/97
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Page: 4
MSD: 002968
ENGINEERING CONTROLS: Provide general and/or local exhaust
ventilation to control airborne levels below the exposure guide-
lines.
PERSONAL PROTECTIVE EQUIPMENT
EYE/FACE PROTECTION: Use chemical goggles. Eye wash fountain
should be located in immediate work area.
SKIN PROTECTION: When prolonged or frequently repeated contact
could occur, use protective clothing impervious to this
material. Selection of specific items such as faceshield,
gloves, boots, apron, or full -body suit will depend on opera-
tion.
RESPIRATORY PROTECTION: Atmospheric levels should be maintained
below the exposure•guideline. In dusty•,atmospheres, use an
approved dust respirator.
EXPOSURE GUIDELINES:
Dibromonitrilopropionamide: Dow IHG is 2 mg/m3 Ceiling.
Stearic acid: Dow IHG is 10 mg/m3.
Methocel: Dow IHG for cellulose ethers is 10 mg/m3.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE/PHYSICAL STATE: Off-white solid.
ODOR: Mild, disinfectant odor.
VAPOR PRESSURE: 4x10 (-5) mmHg @ 25C
VAPOR DENSITY: <1
BOILING POINT: Not applicable.
SOLUBILITY IN WATER/MISCIBILITY: Slowly soluble in more than
10 times its own volume. '
SPECIFIC GRAVITY OR DENSITY: 1.3-1.4 g/cc
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: Stable under recommended storage conditions.
See storage section.
CONDITIONS TO AVOID: Avoid temperatures above 158F/70C.
(Continued on Page 5)
(R) Indicates a Trademark of The Dow Chemical Company

A F E T Y D A T A S H E E T Page: 5
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date Printed: 06/11/97 MSD: 002968
------------------------------------------------------------------------
10. STABILITY AND REACTIVITY (CONTINUED)
INCOMPATIBILITY WITH OTHER MATERIALS: Avoid contact with strong
bases.
HAZARDOUS DECOMPOSITION PRODUCTS: Gases are released during
decomposition. Hazardous decomposition products may include
and are not limited to bromine (Br2), cyanogen bromide, dibro-
moacetonitrile, carbon dioxide.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION (See Section 3 for Potential Health
Effects. For detailed toxicological data, write or call the
address or non -emergency number shown in Section 1)
SKIN: The LD50 for skin absorption in rabbits is >2000 mg/kg.
INGESTION: The oral LD50 for rats is 224 mg/kg.
MUTAGENICITY: In vitro mutagenicity studies were negative.
(active ingredient, DBNPA). No relevant information found.
(other ingredients).
12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call
the address or non -emergency number shown in Section 1)
ENVIRONMENTAL FATE:
MOVEMENT & PARTITIONING: Based on information for stearic acid.
Bioconcentration potential is low (BCF less than 100 or Log
Pow greater than 7). Based on information for remaining com-
ponents. Bioconcentration potential is low (BCF less than
100 or Log Pow less than 3).
DEGRADATION & PERSISTENCE: Based on information for DBNPA.
Chemical degradation (hydrolysis) is expected in the environ-
ment within minutes to hours. Degradation is expected in the
soil environment within minutes to hours. Based on informa-
tion for stearic acid and methylcellulose. Biodegradation
may occur under aerobic conditions (in the presence of oxy-
gen).
(Continued on Page 6)
(R) Indicates a Trademark of The Dow Chemical Company

M A T E R I A L S A F E T Y D A T A. S H E E T Page: 6
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 , Date Printed: 06/11/97 MSD: 002968
------------- ------------------------------------- ----------------------
12. ECOLOGICAL INFORMATION (For detailed Ecological data, write or call
ECOTOXICITY: Based'on information for DBNPA. Material is highly
toxic to aquatic organisms on an acute basis (LC50 between 0.1
and 1.0 mg/L in most sensitive species). Material is practic-
ally non -toxic to birds on a dietary basis (LC50 greater than
5000 ppm). Based on information for stearic acid. Material is
practically non -toxic to fish on an acute basis (LC50 greater
than 100 mg/L). Based on information for methylcellulose.
Not expected to be acutely toxic.
13. DISPOSAL CONSIDERATIONS (See Section 15 for Regulatory Information)
DISPOSAL: DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY
BODY OF WATER. All disposal methods must be in compliance with
all Federal, State/Provincial and local laws and regulations.
Regulations may vary in different locations. Waste characteriz-
ations and compliance with applicable laws are the responsi-
bility solely of the waste generator.* THE DOW CHEMICAL COMPANY
HAS NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING
PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE
INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS
SHIPPED IN ITS INTENDED CONDITION AS DESCRIBED IN MSDS SECTION
2 (Composition/Information On Ingredients).
FOR UNUSED & UNCONTAMINATED PRODUCT, the preferred option is to
contact your State Pesticide or Environmental Control Agency,
or the Hazardous Waste representative at the nearest EPA
Regional Office for guidance. The preferred option in other
jurisdictions is to contact the regulatory authority for this
product for guidance.
As a service to its customers, Dow can provide lists of com-
panies which recycle, reprocess or manage chemicals or plas-
tics, and companies that manage used drums. Telephone Dow's
Customer Information Center at 800-258-2436 or 517-832-1556
for further details.
14. TRANSPORT INFORMATION
For DOT regulatory information, if required, consult transporta-
tion regulations, product shipping papers or contact your Dow
representative.
(Continued on Page 7)
(R) Indicates a Trademark,of-The Dow Chemical Company

M A T E R I A L S A F E T Y D A T A S H E E T Page: 7
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date Printed: 06/11/97 MSD: 002968
------------------------------------------------------------------------
15. REGULATORY INFORMATION (Not meant to be all -inclusive --selected.
regulations represented)
NOTICE: The information herein is presented in good faith and
believed to be accurate as of the effective date shown above. However,
no warranty, express or implied is given. Regulatory requirements
are subject to change and may differ from one location to another;
it is the buyer's responsibility to ensure that its activities comply
with federal, state or provincial, and local laws. The following
specific information is made for the purpose of complying with
numerous federal, state or provincial, and local laws and regulations.
See other sections for health and safety information.
U.S. REGULATIONS
-----------------
-----------------
SARA 313 INFORMATION: This product contains the following substances
subjectrto the reporting requirements of Section 313 of Title III of
the Superfund Amendments and- Reauthorization Act of 1986'and 40 CFR
Part 372:
CHEMICAL NAME CAS NUMBER CONCENTRATION
-----------------------------------------------------=------------------
DIBROMONITRILOPROPIONAMIDE 010222-01-2 40 %
SARA HAZARD CATEGORY: This product has been reviewed according to the
EPA "Hazard Categories" promulgated under Sections 311 and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and
is considered, under applicable definitions, to meet the following
categories:
An immediate health hazard
A delayed health hazard
STATE RIGHT -TO -KNOW: This product is not known to contain any
substances subject to the disclosure requirements of
New Jersey
(Continued on Page 8)
(R) Indicates a Trademark of The Dow Chemical Company

M A T E R I A L S A F E T Y D A T A S H E E T Page: 8
Product: DOW TIME -RELEASE ANTIMICROBIAL CT
Product Code: 06263
Effective Date: 01/15/97 Date.'Printed: 06/11/97 MSD: 002968
------------------------------------------------------------------------
REGULATORY INFORMATION:(CONTINUED)
Pennsylvania
OSHA HAZARD COMMUNICATION STANDARD:.
This product is a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT
(CERCLA, or SUPERFUND):
To the -best of -our knowledge,. this product contains no chemical subject
&.to reporting under CERCLA.
16. OTHER INFORMATION
MSDS STATUS:- Revised entire MSDS. EPA Registration No. 464=624.
(R) Indicates a Trademark of The.Dow Chemical Company
The Information Herein Is Given In Good Faith, But No -Warranty,
Express Or Implied, Is Made. Consult The Dow Chemical Company For
Further Information.

NYPA/HMI::; HEALTH - 1
F'LAMMABJ.1,ITY - 0
REACT I:V LTY - 0
PAGE; I OF 5
MATERIAL SAE'E;'L'Y. DATA SHEET U.S. DE,PAaTME,NT OFL'A80R
COMPI-J ES WITH USDL SA1'E TY AND HEALTH REGULATIONS, (`l.9 CvR 1910.1200)
•k**•t��r*•kk�kie**�r�r�r�e*�r;k�l••k�e�r�t��r�r�t�e*k•k�r•k�r*�e�c�•k�r�t�e�eye*�r*;t�1r*�e�k�e•k�e*kk�e�;*�e�*�e�r*�kye�t�e*
SECTJA.)N I CHEMIC.A.T, PRODUCT AND COMPANY 1Dl',N'.C'J t ICA'1'J UN
--PRODUCT NAME: BOILER COMPLE,`C'E, 2000
PRODUCIT USE;: BOJ LER TREATMENT
PRODUC'.l' CODE,: 4939
MSDS NUMBER: KOS . 655
MSDS TYPE: CAS VS
CONSOLIDATED WATE R COND
233 BEECH BROOK LANE
STA'L')~ SV LL• LE,, NC 2,86.7.7
EM]J,RGN,NCJ ES: (704)-873-5413
REVISION DATE,: 040198 (1 )
SECTION 11 C()MP()S:C'1'ION/J.NVOMA'2J:()N IN COMPONENTS
CAS NUMBER CHEMICAL NAMES
7'731-18-5 WA'IT,R (D1 IONIZE,D)
131.0 -S13 -3 45%, AQUEOUS POTASS I'UM HYDIWXIDL
7757-83-7 S0D'LUM I;UJ:,9ITE:
- MAY.O(.)UE,ST 1500
'71050-62-9 POLY (ACRYLIC ACID-CO-HY.POPHOSPHA'1'L,)
- POL' YCOI; 90 (D C SPE RSANT )
68512-•34--5 SODIUM TaGNOSULFONATE
110-91-13 M()RpHOI; I:NL, 9B%,
100-37-8 D:(.LeTHYLETHAN0:I',AM1NL
311313-65--5 SODJ:CJM GLUCOHE:PTONA`.C'L, 50%
TLV (UNITS)
< 65.00
n/e
< 18.00
2 MG/CU M
< 7.00
n/e
< 2.00
n/e
< 4.00
n/e
< 0.50
n/e
< 4.00
n/e
< 1.50
20- (PPM)
< 1.50
10 (PPM)
< 2.00
n/e
n/e = none established
* * * it e l * * * **lk****•k•k****•k*****•k******fir**-k***

MA'. ERI:AL', S.Ar'r;`L'Y DA`i'A SHraE'L' F3UIT�ER COMPLETE 2000
F?AGr: '). U r' 5
SECTION' 11 :(. HAZARDS 1.DENTJ V-.LCA.'1'IUN
Primary Route of l3nt.ry
Skin contact/absorption and inhalation
(-'arcinogeni.c information :(A}tC , N'i'Y, or OSHA.
This material.. is not li..sted as a carcinogen by
SEC'1':LUIV I r'IItS'1' All) MEASURES
EYES
>y'lush with plenty of water for. at .least 15 minutes, holding eye] j_ s
open.
SKIN
Immediately f_l_ush affected area with water and wash with vinegar.
I:NIIE1lA`J.' I:UN
Move to well. ventilated area for clean fresh air.
I:NGES`L I ON
or fruit juj.re . Seek medical_ assistance.
Drink plenty of water and/
SEC`1':LUN V VJ RE )?7 GHTJ NG MEASURE
Yl.ash Point
No plash at boil. (C.C. Method)
Expl.osive Limits
Not Applicable
Aut.oj.gni.ti.on 'i'emperature
Not Applicable
Hazardous Products of combustion
Not Applicable
Hxtj.ngui.sh'j_ng Media
Not A.pplj.cable
NVPA/HMI:S Ratings Reactivity: U
Health: 1, h,lammabil.i.ty: U,
�fr*�r�r�k�r�c�c�rir�k�r•k�k�k�kic�r**�r�c'Fr�c�r-k*�k**uric k�t�c�c**�c�k�k•k-kir*�c�c�c�k*�r�r�r�lt�c�k�c*****�c�r�t�k**fit**'

MA'J'ERYAL SAYETY 1)A'1'A SHEET BOILER COMPLETE, 2000 PAGE 4 UY 5
SECT.I.ON X S'1'AL• IL:I-'1'Y AND R AC'J'1 VVJ'Y
Chemical- Stability
Stable
Conditions To Avoid
Avoid temperature extremes
f ncompat. i-b it ity
Acidic conditions
Hazardous Decomposition
None
Hazardous Polymerization
Will not occur
*******•k************�e•k*•k*�crt�c�k�e-k�r•k�k*�kye�e�e•k�c•k�e7tie•k•k*�e*�e*i;'k*-k�e•k*�e•kdeik�e�k�e�e•k�c�r�e�e•k�;
SECTEON XI ` OXICOLOG.WA.L 1NYORMATION
No Data Available
******************�r�r�c•k�c•k***�c*�c*dc�c•k�r*Atycic�c�t•k*fir**Fr�c*fir**kdc�r�: �cAr^k�kyc�Irk•kikAr*�1r*•k�tk•k�c
S) CTfON XI1 13COLOGICAL INFORMATION.
No Data Available
�k�k•k�k�e*�c�e�c•k�c�e�k�:�c•k-k�r**�k�c*dc•k�c•k•k�c�e�c*�e•k�c•k�Ar*•k�Ac�e•k�e�kyYye�e�c•k�k�k•k•�e•k�k•k�c�r���e�e•k*�r�r�k�e�c�e�lr�cdc�c
SECIVION XL.I:J. DESPOSAL CUNSJ:DERATION
Waste Disposal Information
Dispose of in accordance with all applicable Yederal, State, and
Local r- ecrulat.i-ons .
k�c******d **'k•k* **-k*•k•k
S'EC`L KON XIV 'URANSPOI. T I:lVF'URMA'C J:UN
DOT Information -- 49 CYR 172.101
DOT Description:
COMPOUNDS, BOILER CLEANSING, PRESERVING SCA14E ]'1Z}�,VENTJ NG OR
REMOV.L•NG LIQUID - ITEM 50093 Sub 2 (Class 55)
,- Packaged in plastic containers
Reportable Quantity (RQ) -- 49 CVR 1.12.101
Not applicable
***-k*****•k**-k,k**************************-k*********•k*** k****-k.**************

MA` 9R CAL GAYETY DATA SHEET BOILER CUMF?]: E'.I'L 2000 PAGE 5 OF 5
SECT'C UN XV REGULATORY LNV O MATI ON
US Feder. al iZegul.ations
TSCA (Toxic_. Substances Control Act)) Status
The intentional_ ingredients of this product are listed.
CERCLA RQ - 40 C;~ R 355 Appendix A
None
SARA 302 Components - 40 CFR 35S Appendix A
None
SAhA 313 Components - 40 Cb'h 372.65
None
State And Local Regulations
California Proposition 65
None
North Carolina Administrative Code "1.1). 1104 and 2H. 0610
None
South Carolina Regulation 62.5 Standard Number. S
None
�c�1rk•k*Ye�ek�e�r�e�eik�e•k�e•k�e�eYr�e�c•h.*•**�c•k•kit•k�e�:�•k�e*k�e�e�eie�e�e�c�;*�cYe**•k�1r*�eYc*yc•k�c�eYe•k•k**�e��e�e*k**
SLCIIIION XV1: OTHER CNYORMA'1'XON
The information accumulated. herein is believed to be accurate but
is not warranted to be whether originat.i.ng with the company or
not. Recipients are advised to confirm i.n advance of need that the.
information is . current, applicable, and suitable to their
circumstances.
This inf.ormatlon was comp:i led from current manufacturer's MSI)S' for
the component parts of the product.. As well as'ot.her sources, such as:
Code of Yederal_ Regulations 29, Revised as of. :luly 1, 1994.
Code of. Federal. Regulations 40, Revised as of July 1, 1994.
ACGI H, Guide to Uccupat.ional Exposure Values, '1996..
ANSI 'L129.1-1994, Precautionary Labeling for Hazardous Industrial
Chemicals.
Hazard Communication Handbook, A Right. to Know Compliance Guide,
Craig A. Moyer u Michael Francis. Clark Broadman Company, LTD.
New York, New York. 1996.
RChA. Regu.latoins and. Keyword Index, Compiled and Published by McCoy
and Associates, I:nc. Lakewood, Colorado. 1992.

NYPA/HM:I. S : HEA.:1. TI.I — '1
YLAMMAB I L' I `L' Y — 0
c REACTIVITY — 0
PAGE 1 OY S
MA`L'I RJ'AJ'� SAP'J;TY. DATA SHEET U.S. DEPAf.:TMIENT OY LABOR
COMY7,:f ES WITH USDL• SAFETY AND HEALTH REGU•LAT) ONS, (2.9 CYR 1910. '1:,'OU )
:l•ir*•k:+c:t k•k•k* k'k:k:k•k�c�k*�c:k•k•k*•k*fie k�c:+:**;k*•k�c�r��c�c:k'k•k h�l; :it•k�c�c�; k•kk•/:•k kk k•k*�k�r**ic k�t•kk k�c*•k k
SECTION 1 CH} M:I_CAL PRODUCT AND COMPANY 7.DHN` I FICATION
---� PRc)DU(.'U NAME:: LIQUL•D OXAWAY
Pj.' CODUC'1' USI : BO'J LER TREATMXN`I'
PRODUCT' CODE: 4134
MSDS NUMBER: KOO . 638
MSUS TYPE: CAS #IS
CONSULLDA'1'ED WA'l'l;R COND
233 BERCH BROOK: ].SANK
STATESVI:LLE, NC 2,86.7.7
EMERG1 NC120: ('704)-8'73-5413
REVISION DATE: 040.798 (1 )
�k�c�ic**•k�c•k•k•k** k�c�c•k�c•k k�r•k*Erik*�c�c*•kic�lr*�rik�ir�c�k*�r�c�c•k�r•k�k�k•k*�1t�t�c*�r*�c�r-k�t•kik�lr�r�r�r*ic�r•k*yc�r•k*
SECTI ON '11
CUML'C:S7.7'I UN/:f 1N1� U}ZMA'1.'7 C)N IN COMPONEN'1•'S
CAS NUMBER
CHEMICAL JSfAMES
`.C'L' V (UNITS)
773A--18-5
WATE" R
<
'78.00
n/e
7757--83-7
SOl)I:IJM SU.LYIT
<
13.00
n/e
1310-58-3
45 AQUEOUS POTASSIUM HYDROXIDE'
<
9.00
2 MG/CU M
68S12-34 -5
SODI:UM 1-11c73NOSUL• YONA'I E
<
2.00
n/e
=
1L1A1,0
<
1.003113i-65
n/e
n/e = none
established
•k•k•k*•kk�c�c•k�r•k*�:*•k�c*�c*•k�e•k�c�r•kkk•k*�c�c•k*�:�:•k*k�c•k•k�cYe•k•kdc*�c•k�c*�r*�e•k�rdc•k•k•k�r•k�e•k�:•k•k*�r•k�cik�:

MA7'LIt1:A1:, SAYETY. DATA SHEE:'J' LIQUCD UXAWAY PAGE '? OF 5
SECTION 1.1. I HAlAkDS IDENTIFICATION
Primary Route of Entry
Skin contact/absorption
Carcinogenic .I*nf.ormati.on
This material is not listed as a carcinogen by 'I ARC, NTP, or. OSHA.
************,k***** ***-k**-k**-k******** k*************•k*************,+r•k****•k***
SECTION 'IV L '( RS`.0 AID MLA5U}.tES
E,YL;:;
Flush immediately with clean water. cell physician immedi.atel.y.
SKIN
Wash with generous amounts of water..
CNEIALA'[ T0&
Remove to fresh air.. Consult physician if breathing is difficult.
I:NGES7'.I ON
Drink large quantities of fruit juice or water. Call physician
imme d i_at e l.y .
BE-.'C1'1:0N V YXR'3 FI:GTITJ:NG MEASURES
Fl.ash Point
No ]?lash at boil (C.C. Method)
Explosive Limits
Not Appl.icabl.e
Autoi.gn:i.ti.on Temperature
Not Appl.:i_cabl.e
Hazardous Products of. Combustion
If liquid comes in contact with aluminum -or other soft metal.s,
Hydrogen can be generated which is f.l.ammabl.e,.
Extinguishing Media
Not A.ppl.icable
NYY. A/HM1 S, - Ratings
Health: 1, Flammability: 0, Reactivity: 0

MATERIAL SAl E'PY DATA SH)1 M" LIQUID OXAWAY
SEC'-C 1:UN V1: ACC1:1)>+;N`VAL RELEASE MEASURES
PAGE 3 Ulu _`i
Small Spill
Absorb with an inert solid and scoop up for disposal, then rinse
soiled area with water_ down the drain.
Large Spill
Stop leak at the source and collect into a suitable container,
then treat as a small spill.
•******loft**-k**********************,k*-k**.k•k*•k*rt*Yc****************yl•*dc***,****
SEC`I'LOM V1:1: HANDL• I"NG AND STORAGE
Store in a cool, dry place. Keep original container closed when not in
use. Shelf life - 2 years minimum.
*******•k**********•k•k**-k** ** k***********•k*•k*-k******************************
SECPION VIA'.J: E:XPOSIR.-ZE CONTROLS/PERSONAl'.1 PROTECTION
Safety glasses and rubber gloves are recommended when using this product.
SLCTION:IX PHYSICAL ANI) CBEMJCAL• Y}.tU);L}'h' ILeS
Appearance and Odor
Dark brown liquid; odorless
pH Concentrate
:12.-5 -- 13.5
Vapor Pressure
Unknown
'Vapor Density
Unknown
lioi-l-i.nq Point.
217 degrees Yahr.enhei.t
Solubility in Water
Comp.l..ete
Evaporation Rate
(Water-=1) < 1
Percent. Volatil_es
66%
Specific Gravity
(H20=1) 1.06 +/- 0.02
*•k*•k**************•k**•k•k**********•k********-k***************'k***************

MATERIAL L SAb'ETY DATA SHEET Ll:c U ED OXAWAY
SECTION X S'1'H.):371:,ITY AND REACTIVITY
Chemical. St.abil.i.ty
Stable
Conditions To :Avoid
Avoid temperature extremes
.L ncompat- i.b i.l. i.t.y
None
Hazardous Decomposition
None
Hazardous PoJ.ymer_ization
Will not occur
PAGE' 4 OF S
***�:•k�r�c*•k�k�c*�r-k*�r•k-k*•k•kk�c*�c��c�c�c**�r�t*•k�r*•k*�r•k�c•kic-k��c�c•kyk•k�c�c�c�c•k�r•k*-kYc•k�c�t�c*•kic k�c�c�c�ck
SECTION X1 TOXECOLOGICAL 1NVORMATION
No Data Available
*******k•I;�ck•k�r�e�e�t^kic�c�c*�:•k*•k*�c�r*�r�e•k*•k•k�c�c�c*�e•k�c•k�k•k•kk•k�e•k•k�e�e�l•iek�t�cYc�e•k**•kkFrk*•k•kdc�F�c•k
SECTION X C C ECOL• OG CCAL• INFORMATION
No Data Available
***********•k**•k****�rk•kde�e�e*�r•k��k•k•k•k�1c�e•k*�e�ek�e�e*•k�r��t�e�:/t�e��eYrk�e�e�e•kyF�r�c�e•k�lr•k•k*ik•k�c�e•k�N
SLC'1 YON Xl• L I: DESPOSAL CONS LI)EM'1'.I:ON
Waste Disposal. Information
Dispose of in accordance with all. applicable Yederal, State, and
Local reaulations.
•k******-** **,k*******•k*dc•k-k•k•k*,k-k***-k* *,k*****-k•k**************,Ic*
SECTION XIV 'URANSPORT I:NYORMATION
DOT :Lnformati.on -- 49 CFR 1.12.101
1)U`I' I)escr. i.pt.i.on:
COMPOUNDS, BOILER CLEANSING, YRLSERVMG SCALE PR VBN'1'7 NG OR
k.-EMOV.I_NG, l:, I:QU1ll .i:`-['EM 50093 Sub 2 (CJ.ass SS )
- Packaged in plastic containers
Reportab)_e Quantity (.[ Q) -- 49 CJ~ R 172.101
Not appli.cabl.e
* k******** k k**********•k•k k k******* k•k****•k**** k******** k****'k***-k*****•k*** k*

MA` EIZIAL SAFE'.CY DATA , SH)i:ET L' -QU.I D UXAWAY PAGE .5 OF 5
SECTION XV REGULATORY INFORMATION
US Yede r. al V.egii lat ions
TSCA ('Toxic Substances Control Act)) Statics
The int.ent.ional ingredients of this product are listed.
CERCLA XQ - 40 C YR 355 Appendix A
None
SARA 30'Components -- 40 C YR 355 Appendix A
None
SAPA 313 Components - 40 CyR
None
State And Local. Regulations
California Proposition 65
None
North Carolina Administrative Code 2D. 1104 and 2.H. 0610
None
South Carolina Regulation 61.5 Standard Number. S
None
*******************•k•kYc**********lost•k******-k•k******-k*******k**************Yc***
SECT10N XV'C OTHER fltlUOI) MATION
The information accumulated herein i.s .bel.ieved to be accurate but
is not warranted to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
i.nformati-on is cur. -rent, applicable, and suitable to their
circumstances.
This information was compiled from current manufacturer's MSJS' for
the component parts of the product. As well as other sources, such as:
Code of Federal Rec;ulati-ons 2.9, Revised as of. July 1, 1994.
Code of Federal Regu.l_at.i.ons 40, R.evised as of J'ul.y 1, 1994.
ACG7 H, Guide to Occ.u.pational. Exposure Valises, .1996.
ANS1' I,1.'Z9.1--1.994, Precautionary Labeling for Hazardous Industrial
Chemicals.
Hazard Communication Handbook, A Right to Know Compliance Guide,
Craig A. Moyer & .Mi.chael. Francis. Clark Broadman. company, LTD.
New York, ' New York. 1996.
RCkA Regulatoi-ns and Keyword Index, Compiled and Published by McCoy
and Associates, Inc. Lakewood, Colorado. 1992.

NVI?A/IJMI S HEALTH - 1
Y LAMMA.R I L L' `L' Y— 0
REAC'1'7:V7'l'Y — 0
PAGE 1 OY 5
MATER.1:AL SAVE'VY DATA SHEH'`l' - U.S. DEPAR'l.'MEN`L' OV LABOR
COMPLIES WITH USDI, SAFETY AND HEALTIJ REGULATIONS, (29 CYR 1910.1200)
�c:��c�c�lr�k**•�r*•k•k•k•k*�:*yt**�c�r*•k�k**�k�k*:kk*�Ir�c*•k�k�•k-k•k•�r�k•k•k*�c�e^k�e-k�r*�,k�c�r*•k*�k*fir*�c*•k*�r�r•k�e*
SECTION I CHEMICA•1., PRODUCT AND COMPANY I DEN'.C'1D':ICATT.ON
-- PRODUCT NAME: BO1:LL(Z D 1:SPE[ZSAN`.0 PLUS
PRODUCT US}•,: BO1•I.ER TREATMENT
PRODUCT DUCT CODE: : 41.0 9
MSDS NUMBER: KOS . 633
MSDU TY PH,: CAS #' S
Cc)NSOT .I:DATLD WATER Cc 61D
233 BEECH. BROC)K L•ANX
S`L'A`VESV LT,LL, NC 286'7'1
EMERGENCIES: ('704)-8 73-5413
R.I,eV'[S.J'ON DATE* 0506911 (1 )
SECTION 11 COMPC)SI'J':LON/7ND'C)RMA'.VS..C)N IN COMPONENTS
CAS NUMBER
1.300—'72•-'7
7'1050-62..-- 9
68512-34-5
77—y2—y
31138 -65 -5
Ci11's'M1:CAL• NAMES
96 TLV (UNl"'1'S )
WATER (DE:LON:I ZED) < 85.00
4-L3 AQUEOUS POTASSIUM HYDL20XlJ)E < 4.00
POLY(ACRYLIC ACID CO--HYPO>>Hc:)SPH:LTY.) < 3.00
MAYOQUEOT 1500 (CHELA'.CES CAL' CJ TUM) < 1.50
SOI.)1UM 1,7 GNO:iUT,I+'UNA.`f% < 3.00
POLYCOL 43 (J) -SPE[tSAN1') < 2.00
ClTRTC' ACID < 1.50
00D l:1JM GLUCOf49P9'ONA'.V9, 50` < 2. SO
n/e
2 MG/CU M
n/e
n/e
n/e
n/e
n/e
n/e
n/e = none established.
Nt�c�l*�c*�klrk*�c�c*Eck*ft/t�c�ck�c�k�ckf�r�c*�c�c*ik*lock*k•kkk•k•k-k�c�k

c MA OR1:AL SAFETY DAr 1.' A SHEET OJ.'LER DISPI- 2SAN1 PLU
S PAGE 2 OF S
SECTION 1111 HAZARDS J DEN'-1'IF I-CA`J-':1.CN
Primary .[-route of Entry
Skin contact/absorption
Carci.noaenic Enf-ormation
'i'his material is not listed as a carcinogen by 1 A]2C, N'1'N, or OSHA.
h•k�fr•k�e-k�•�r�F�e�1r*-k*k�1rk�r•kk�r•k•k�r•k-k**�e�e�e�r*�e�e**•k�e�r**-k�r•k�e•k�r-k•k�e•k�r•k�e•k•k�e•k*•k�r*•k*�k*�1r*fie*ie�;
SF,CT.TON IV F TRST AJ D M);,A:;U].:N;S
I�'YES
Flush immediately with clean water. Call physician immediately.
SKI,. N
Wash with generous amounts of. water.
INHALATION
Remove to fresh air. Consult physician if breathing is difficult.
ENGESTION
Drink large quantities of fruit juice or water. Call physician
i-mmedi.atel.v.
�r�cic�t-k*�c•k�r�r�:dr•kikk*k�:�r,k�r•k�r�c•k�c�rYr�c*•k�c•klrlc•k***lrk�r�c-k•k�r�:•k�dr�c•k�c•k•k•k�c�c•k�c-k-kYr-k�c�t•k7t��c-k�k-k
SECT I'ON V Y ]:RE Y I:Gf1T'.I: NG MEASURES
Flash Point
No Flash at boil (C. C. Method)
Explosive Limits
Not Applicable
Autoigni.tion 'I'emperat-ure
Not Applicable
Hazardous Products of. Combustion
Not. Applicable
Extinguishing Media
Not Applicable
i_NYP'A/HM1:S Ratings
Health: 1, Flammability: U, Reactivity: U
•k•k*•k•k1rklr�r•kk*-k•k*•k*•k�r�c�r*•k*•k•k�r•k�c kirk•k**1r7t**�t�c•k*�c*•k•k*•�t•k*•k*•k�r•k*�r•k*•k•k�c*Vr�c•k*****•k*.

7
MA7.'HX:LAI� SAI,'2 'Y DA'1'A. SH1sL'.l' BOILER DISPERSANT PJ;,US PAGE. :3 OF 'i
Sl C7'.I:ULN VI' ACC I I)LN'1'AL RELEASE MEASU[t1:'�'S
Small Spi.J J_
Absorb with an inert solid and scoop up f_"or disposal, then rinse
soiled area with water down the drain.
Large SpilJ.
Stop leak at the source and collect into a. suitable container,
then treat. as .a small. spill.
**-k*******yc*******,k*-k***•k*•t:*******-k•k*•k*****dc**********-k**.k*•ic*****-.k** r***
SI,C'L'.1:ON V 1: I: HANDLING AND :.STORAGE
Store in a cool, dry place. Keep original conta.i ner cl osed when not i..n
use. Shelf. J.i.fe 2 years minimum.
SECI1'1:ON VL"CJ: ExPoa"CJm CON`I'ROL•S/PERGONA% PR0'l-'9C'1'l"ON
Safety glasses and rubber_ gloves are recommended when using this product.
ONC`J'YUN J X PHY-S7 CAT, AND CI-18M.TC;AL PRO 1'L.'R' I1,1 S
Appearance and Odor
Thin, dark--brown/blank liquid with earthy odor.
pH Concentrate
11.5 - 13.5
Vapor pressure
Unknown
Vapor Density
Unknown
Boiling Point
21`1. degrees Fahrenheit
Solubility in Water
Complete
Evaporation Rate
(Water=l) : < 1
Percent. Vol-at-i.les
89.1%,
Speci..f-i_c Gravity
(H.2'0=1) 1.14 � /- O. 0:.
-k**•k*•k***************•k**********•k*•k-k********•k*****************************

MATERIAL SAFETY DATA SHEET BOILER DISPERSANT PLUS PAGE 4 OY S
SECTION X S'.I'ABI LI `I'Y AND REACTIVITY
Chemi.ca.l. Stab:i_li.t.y
Stable
Condi.t.i.ons To Avoid
Avoid temperature extremes
J. nc omp at. i. b i. J. i.t.y
None
I.iazardous Decompositi-on
None
Hazardous Polymerization
Wj.J.1 not occur
•k�e�e�c•k�e•k•k�r�lr�e•k�e�t�r�ek^k�e•k�r��c�r•k•k�c�c•k•k�rk�e�ek�r�c•Ack�eAr*•k*�tk�ek�e�ek�e�c**•isle•k•k•kk�r•k�ck•k•k•k•k•k*k*�:
SECT ION X1: `VOXTCOLOGYCA.L• I:NYO MA`V f.ON
No Data Available
*********•k****-k****•k*****-k•k*•k******** **'k*********-k•k*******•k***************
SECT I:ON X 1: 1: 1KC0L0GI CAI, I NY ORM.A` ION
No Data Available
SLCTJ N XJ: I: I: DISPOSAL CONS CDERA`C' KON
Waste Disposal. Information
Di.spose of i.n accordance with al.l applArable Federal, State, and
Local. regulations.
*****•k***********•k******•k***-k*•k******************•k*************•k**********
SLC`i' I:ON XIV TRANSPORT r.NI OTc MAT I'ON
DOT :I n£ormat:i on - 49 CF12 172.101
DO7' Descr. i.pt.i.on:
COMPOUNDS, BOILER ER CLEANSING, L-"RESERVING SCAT,E PREVENT-T.NG,
Olt REMOVING, LI-QUID
!.'1EM 50093 Sub 2 (Class .55)
- Packaged i.n p.l.ast.i.c containers
Reportable quantity (RQ) -- 49- CYR 1*71.101
Not. appli-cable
•k•k•k****•k***********•k**•k•k*•k**•k******'k**'k**•k•k************•k****************'k*

MA`l'ERCAL GAYETY DATA St{ERR BOILER DL'SPERSANT PLUS PAGE S OF S
SECTION XV REGULATORY INV ORMAT I UN
US Federal. Regulations
TSCA (Toxic Substances Control Act)) Status
The intentional_ ingredients of this product are listed.
CERCLA RQ - 40 CYR 355 Appendix A
None
SARA 302. Components - 40 C?R 355 Appendix A.
None
SARA 313 Components - 40 CVR 372.65
None
State And Local Regulations
California Proposition 65
None
North Carolina Administrative Code KD.1104 and 2H.06:10
None
south Carolina Regulation 62.5 Standard Number It
None
SECTION XVI: OTHER VNrc)RMAtION
The information accumulated herein is believed to be accurate but
is .not warranted to be whether originating with the company or
not. 'Recipients are advised to confirm in advance of need that the
information is current., applicable, and suitable to their
circumstances.
This information was compiled from current manufacturer's MSDS' for
the component parts of the product. As well as other sources, such as:
Code of Federal. Regulations 29, Revised as of Curly 1, :1994.
Code of. Federal. Regulations 40, Revised as of. July 1, 1994.
ACGJH, Guide to Occupational hxposur.e Values, 1996.
ANSI: Z129.1. -1.994, Precautionary Labeling for Hazardous industrial_
Chemicals.
Hazard Communication Dand.book, A Right to Know Compliance Guide,
Craig A. Moyer. & Michael. Yr_ ancis . Clark fir_ oadman Company, LTD.
New York, New York. 199b._
RCRA Regulatoins and Keyword :Index, Compiled and Published by McCoy
and Associates, Inc. Lakewood, Colorado. 1992.

NVPA/HM*( HEALTH 3
YLAMMAB I'LITY 0
RE ACT *1 VJ T Y
PAGIE I OF 6
MA'J%.fk1'.Ar, OAFETY DATA SHEET U.S. DEPARJ.'MEN'J.' 0V LA1301Z
COM)?L:LXS WITH USDL SAFETY AND fflsALT11 )-,J�!GULATIONS, (29 CFR 1910.1200)
* ****** *** * *** * *** * * * * * * * * * * * * ** * * *lk* lk *** * **-k-Af ****** ** * **** ** *** ** *
SECTION I CHEMICAL PRODUCT AND CUM) --')ANY J.DENT'LVICATION
PRODG01 NAME: SUPER ALKAI�INVVY BOOSTER CONSOLIDATED WATER. COND
PRODUCT Uc,,Le: BOILER WATER TREATMl,*,NJ`
CODE: 4 1.4 *7
MSDS NUMBXR: KOS : '704
233 BEXCH BROOK LANE
STATESVILLEO, NC 286-7.7
MSDS TYPE: CA,"; #IS EME�RGENCIRS,: ('704)- 671-5413
R.EVESYON DATE: wslaqB (1)
CC)MP(,)',',ITION/'LNFOI.ZW�TION ON INGRED'I'liINTS,
CAS NUMBER CIIEMJ'CAL NAMES % 'VW(UNITS)
1310-73-2 SODIUM HYDROXIDE, 25.9b AQUEWUS < 100.00 2 MG/CU M
SOI)3:UM LIGNOSULVONATE < i.so n/e
n/e = none established
** *-k-k * * ** ** * ** -k *-k * **** * **-k * *-k-k* * ** *** * *** * * * * ** * * ***-k* -k-k* * *-k* *-k *-k

MATERIAL SA1 E"f.'Y DATA SHEET SUPER A]'.,'KALMI'TY BOOSTER PAGE 2 OY 6
SECT'fON '11-1. HAZARDS IDENTIFICATION
Primary Route (s) of Entry
Skin contact/absorption
Effects of Overexposure
Corrosive to all body tissu.es by al] routes of exposure. The effect
of. Local. derma]. exposure may consist of multiple areas of
superficial destruction of the skin or of primary irritant
dermati.ti.s. Similarly, inhalation of dust, spray, or mist may
result in varying degrees of irritation or damage to the respiratory
tract tissues and an increased susceptibility to respiratory
i.]. lness .
Immediate Health Effects
EYES
Exposure may result in severe damage or blindness. Exposure to
surrounding tissues may cause severe burns. Symptoms may include
burning, redness, tearing, and blurry vision.
SKIN
Exposure causes immediate skin irritation. Contact may produce
severe skin blarns and destruction of tissue.
1. NGFE::,TI ON
Causes burns to mucous membranes of the mouth, throat, esophagus,
and stomach.
7 NHA.LA'J I ON
Breathing dust, mist or spray may cause damage to the upper
respiratory tract and lung tissue which could produce chemical
pneumonia, depending on severity of exposure.
Carcinogenic ):nf.ormati.on
This material is not listed as a ca.rci nogen by IAFtC, NTP or OSHA.
)-jonq Term Effects
No data
*********-k***•**•k,k•k****-********•*****•k******•k**********-Ar *ic^k*yc*ik**-k*********
:i);'(:TrON CV YIRS'.1.' AID Mf3ASURES
EYES
Flush thoroughly with low pressure wat.er for at least 15 minutes
with special. attention to area under. eyelids.
SKI N
Wash with water for at least 15 minutes. If irritation persists,
get medical. attention .immediately.
l NGESTTON
Drink milk or other liquid to dilute substance. Get immediate
medical. attention.
? NHA:I"JAT:L ON
If symptoms of overexposure develop, remove victim to fresh air.
Get medical. attention immediately.
***************•k***•k*•k**•k*-k*****-k***•k****-k*******************************

MA1ERI'AL SAb'I?:'I Y DATA SHEET SUPER ALKAI',INl''J.'V- BOOS` EP,
SEC'J'I UN V b'I GHT_CNG MEASURES
Flash Point
No flash at boil (C . C. Method)
Explosive Limit
No data
Autoi-gnition "Vemperat.ure
Non-flammable
PAGE 3 09 h
Yir. e and Explosion Hazards
Direct contact with water can cause an exothermic reaction.
Exti-ngui.shing Media
This product is not. combustible. Foam, carbon dioxide or dry
chemical may be used where this product is stored.
Fire Fighting Instructions
Wear full protective clothing. Avoid direct ocntact with water
as this can generate a lar- cie amount of heat
NI?PA/HM't S Ratings,
Health: 3, Yl-ammabi.lity: 0, Reactivity: 1
-k•k•kic�r***�r*�c�k*•k•kdc•k*•!r**�Iric*�k*******•k**'k**�k***�r�c:lr*�c�r•k�c�r�c***�Ir�c**•k�c•k•k�c�1r•k�r�c�c�c�r*•k�c
SECTION VI ACCIDENTAL RELEASE MEASURES
All leaks should be stopped. Gpi.l.Ts should be contained and cleaned up
immediately. Neutralize ize remaining traces of material with any di -lute
inorganic acid such as hydrochloric, sulfuric, ni.t.ri.c, phosphoric, and
acetic acid. 'Then spill. area should then be flushed with water followed
by liberal covering of sodium bicarbonate. All. clean-up material should
be removed and planed in approved containers, labeled and stored in a
safe place to await proper treatment. or disposal. Persons performing
clean-up work should wear adequate personal protective equipment and
clothing.
•k*•k�c�r�k•k�c•k•k�c•k�c•k•!c•k•k��c*�:•k�c•k•I:•k�c�c*^k�;•k•k•k•k*�c-k-kyc•k�r•k•k•kdc�:�cdc�r•k�r�c*�c�;��k•k*�:•k*�c*�c�c�r�c�c�c�c
SECT LON V Y T HANDL I'NG AND S' OIc AG>
Handling and Storage Precautions
Do not get into eyes, on skin, or on clothing. Avoid breathing dust,
mists, or spray. Igo not take internally. Use with adequate ventilation
and wear respiratory protection when exposure to dust, mist or spray is
possible. When handling, wear- chemical splash goggles, fare shield,
rubber gloves and pr-ntect.i.ve clothing. Wash thoroughly after handling
or contact - exposure can cause burns which are not immediately painful
or vi.sibl.e. Keep container- closed when not in use.

MA'1.BRIAT. SALit'TY llA'1.'A SH81:-:'1' SUPER ALKAT.I.N 9' Y BOOSTER PAGIi, 4 OF 6
Product is corrosive to tin, a.lizmi.num, zinc and alloys containing these
meta -Is, and will react violent..l_y with these metals in powder. form. Keep
i.n a cool, dry place.
�c•k�r�c�k�k�cdt*k•k*k*�k�cik**�r�r�c�c•k�r*•k*�c�c�c**�c�c�c*�t*k�k�l•dc•k�r�c�c�c�c�cik•k�c�c�c�c�c�k•k•k�c�c•k�Ar�ir-kic�c*�k�c�c�t�r
SLC'1'1:0N V.1il LXF'osul.ZL CUN`1'[20LS/I?1],[RS0NAT, PROTECTION
Eye Protection
Wear chemical safety goggles plus full face shield to protect
against splashing.
Skin Protection
Wear chemical resistant gloves such as natuar_ al. or buty] rubber. .
Gloves my be decontaminated by washing with mild soap and water.
Impervious clothing and chemically resistant safety shoes should be
worn to minimize contact..
Respiratory Protection
Respiratory protection is not required under normal use. Use
NEOSH/MSHA approved respirators where dust, mist, or spray may be
generated.
Engineering Controls
Provide sufficient mechanical (general and local exhaust)
ventilation.
^k*de�c�c�e*�c*�•k�ArYcik�r*�e�e**�/e•k•kk•k^k*•k•kdc•kdt•k�k�*�ic�e^k�c�c•/r�c�k�r•k�c�c�k�:*�r•k**�k�r�e�r*�r�e�k�e�k�k�k�:•k�c�e�r•k
SEM."FON EX PHYSICAL AND C14EMICAL PROPERTIES
Appearance and Odor.
Clear l.i_quid; odorless
PH
13.0
Vapor. Pressure
Unknown
Vapor. Density
Unknown
Boiling Po:i.nt.
240 degrees I:ahrenheit
Solubility in Water
Complete
Evaporation Rate
(Water=l) < .'1
Percent Volatiles
Specific Gravity
(H20=1) 1.2B +/- 0.02

MA'I'LI. CAJJ SAFEVVY I)A'I'A SHEET SUPER ALXALJ:NJ:'1'Y. BOOSTER PAGE S OY 6
SEC'1'J ON X STA1_i:I:1:ITY AND REACTIVITY
Chemical Stability
Stable
Conditions To Avoid
Temperature extremes
I:ncompati.bil.ity
When handling this product, avoid contact with aluminum, tin, zinc,
and alloys containing these metals. Do not mix with strong acids
without dilution and agi tati.on ' to slow reaction. Avoid contact
with leather, wool, acids, organic halogen compounds and organic
nitro compounds.
Hazardous Decomposition
None
Hazardous Polymerization
Will not occur..
*****•k•k* **-k*****'k******-k****•k*• **-k****-k*-k**•k*Yr* **-k•k•k^ **-k*-k*****ic*^ **-k*****
SECTION XI'. 7'OX I:CQ1'.UG I.CAL I:NFORMA'V I OM
No Data
k*********************** Ar***•k******* k* k k k**•k*******-k*******•k******•k•k***•k**
SECTION X I:I: ECOLOGICAL MF'()RMAT EON
No Data
*** k* k k******•k•k******•k******•k*****'***********.************************•k****
;C'1'1:(.)N XXII DISPOSAL CONSIDERATION
Waste Di posal Information
Dipose of in accordance with all applicable Federal, State, and
Local. regulations.
*****************•k*-k*************,k************•k**•k**•k•k*-k*****'k************
SEC` I:ON X1:V TR2ANSPOR'.1' IN1{ORMATION
DOT :Information -- cif) CYR 172-101
DOT Description:
SODIUM IiYDROX:CU2, SOLUTION, S , CORR.C)SJ VL, UN1824., J J ,
ITEM 4BS130 Sub 3 ( Class SS)
CLEANING CUMPoliki), NO]'-
- Packaged in steel,containers
RQ (Reportable chzant:ity) ny CYR 171 . 101
Not. applicable
•k******k****•k*******•k•k**•k**•*•k*****•k*******k*********•k*•k******k************

MA`J.'E-R.CAL SAF1+TY. DATA SHl '!s"V SUL)ER ALXAL'L'NJ:'1'Y BOOSTER PAGE 6 Ub' 6
SECT) ON XV REGULATORY INFOIRMATI UN
US Veder. al. Regul.at.ions
`1'SCA (Toxic Substances Control Act)) Status
`1'SCA (UN.U..I'LI) STATES) The intentional. ingredients of this
product are listed.
C'EJ.d.CLA RQ -- 40 CYR 355 Appendix A.
None
SARA 302 Components - 40 CFIZ Appendix A
None
Section 311/312, hazard Class -- 40 CFR 370.2
Cmmedi ate (X) I)el.ayed (X) Fire(X) Reactive( ) Sudden
Release of Pressure( )
SARA 313 Components - 40 CYJt 372.65
None
State and Local- Regul•at.i.ons
California Proposition 65
None
North Carolina Administrative Code 21). 1104 and 2H. 06:10
None
South Carolina Regulation 62.5 Standard. Number It
None
SECT 1:0N XV.I: OTHER- I:NFORM.A`L' I:UN
The information accumulated herein 'i-s believed to be' accurate but
is not warranted to be whether originating with the company or
not. I2eci_pi.ents are advised to confirm i.n advance of need that the
i.nf.ormat.i-on is current, applicable, and sui.tabl.e to their
circumstances.
This information was compi.l.ed from current manufacture's MSI)Ss of
the component parts of the product. As wel1 as other sources, such as:
Code of Federal Regulations 29, Revised as of July 1., 1994.
Code of Federal Regulations 40, Revised as of July 1, 1.994.
ANS:I. I,17.9. 1 1994, Precautionary Labeling of Hazardous :I ndust:r. i.al
Chemi.cal.s .
Hazard Communication Handbook, A Right to Know Compliance Guide,
Craig A, Moyer & Michael grancis. Clark Broadman Company, LTD.
New York, New_York. 1996.
R('RA I:egul ations and Kevword Index. Compi l.ed and publ-i shed by McCoy
and Associates, Inc. Lakewood, Col.orado. 1.992,

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(OOZI.'OThT XAD 6Z) H.I,':( TH (INV F'x',gays '.C(ISf1 H,T,7:M 52fl(CWO7
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MA`I'GJ..ZJ:AL• SA!♦ EVVY. DA'J'A :3HEE T 13000 -N--1. TOWER TREATMENT PAGE 2 UP' 5
SL''CT'7.UN III. HAZARDS IDEN'TIV1CATION
Pr. i.mary Route of Entry
Skin contact./absorption
Carcinogenic- Information
Thi-s material is not listed as a carcinogen by I.ARC, NTP, or U':;HA.
*k1r�r�ik�ck•k**�r*Ir•k9c•kirk*�c�c:k*�ck�c•kk*�c�c*�r•k•k**�r�c*•k*•*�c*�c*1cic�r�t�;*�r•k*�c•k7k*�c•k•k*•k*•k��r�c�cx�r�c
SXCTION I.V FIRST AID ML;ASURI S
LYFS
Flush immediately with clean water.. Call physician immediately.
SKXN
Wash with generous amounts of water and mild soap.
r NHAL' AT T 0 N
D'or excessive inhalation remove to fresh air and get medical
attention.
J.NGE'ISI'L ON
Drink large amounts of. water. Call. a physician or local Poison
Control. Center immediately.
�ck�c�c•k*dc•k-k*�c�t�c7k�r�c�rkkk•k•k�c*k�r�ck�r•k�c•k�:k�c�fr*�c•k^k�r�•kk**�c**�t•k�l•�c*�k�k�kkAc�r�c•kycYc•k•k�c�c�4rk�k*�rdr
SECTION V r'J:RS YWHIUNG MEASURES
Flash Point
No Flash at boil (C.C. Method)
h;xpl_osive Limits
Not Applicable
Aatoignition 'Temperature
Not Applicable
Hazardous Hazardous Products of. Combustion
Not Applicable
*Extinguishing Media
Not Applicable
NYPA/IIMJ:S .Ratings
Health: 1, Vlamma.bil.ity: U, Reactivity: U
***********k*�rk�r*�t•k*�***•k*fir* :t***�e�e�rkY�e**-k*fie*�c�r�e7kk k/r*•kde�e�r**�c�e�e•k*�c*�c•�e***fir*fie*

MI.1'1'LRLAI:, SA1 B.TY DATA SHEET f0000-N--'1 TOWER '1'Y' EATML'; T PAGIs 3 OF S
SC!.CTJ.(.)N V 1: ACC.I:Df.;M.'AL REYj ;ASE MEASURES
Small Spill
Absorb with an inert solid and scoop up for disposal; then rinse
soiled area with water down the drain.
Large Spill
Stop leak at the source and collect.into a suitable container,
then treat.,as a small spill.
*****•k********************************•k*•k****•k***********'*************•k•k
SECTION VTI HANDLING AND ST0,RAGE'
Store in a cool, dry place. Keep original container closed when not in
use. Shelf. life >, years mi.ni.mum.
*******•k************•k****•k*******•k***************k*****fir******************
SHC`CLUN VLLI EXPOSURE CUN'1'RULG/PERSUNAIJ PROTEC'LYON
Safety glasses and rubber gloves are recommended when using this product.
**************************************************************************
SECTION 1X PHYS:I:CA:L, AND CHEMICAL Pl. UOP+JZTIES
Appearance and Odor
Clear, straw-colored liquid; odorless
pH Concentrate
11.5 -- 12.
Vapor Pressure
Unknown
Vapor_ Density.
Unknown
Boi.li.ng Point.
213 degrees lea.hrenheit.
Solubility i.n Water
Complete
Evaporation Rate
(Water=l) : 1
Percent Vol.atiles
'70%
Specific Gravi.ty. .
(H' 1 . 0.7 +/- 0.02
***************•k********-k*******•k*********•k***•k•k**************************

MATERIAL SAIFEVY I)A'['A SH21,02 8000•-N- J. '1.'OWER. 'VREA'1'ME;N'1' PAGE 4 OF 5
Sk;C'J':[ ON X S`1'AL411aJ.TY AND RMACTI VTTY
Chemical Stabi.l_i.ty
Stable
Conditions 'I'o Avoid
Avoid temperature extremes
Incompatibility
None
Hazardous Decomposition
None
Hazardous Polymerization
Will not occur .
*�l:�F-k�c*�k-k*�t•k*�/t•k•k*dc*�c•k�r•k•k�c�c•k•k*�c*•k•k*•k•k*�k�c�c^k�r•k�cdc•k�c�k-k**�c•k•k�c�c-k�;�cYc�c�c•k-k*•kdc�k•k•k�k-k�c�r�c
SECTION XI* TOX-CCOL" OG1:CAL LNYORMATION
No Data Available
�r�r•k**•k�c�r�c•k��c•k•k•k:rkMr�c*•k*ic�t•k�c�c*�t�c**•k�c�r•k�cik�rk�ryc�r�r*�c**ic*�•k�c�c�k�c*�l•�c��c�k�c*�c*�fr•k�:•k�ck�c k
SECT CON Xl'7 LCOLOG COAL INFORMATION,
Data Available
�:�:�;****•k*�c�t�F�c•kk�c*-k�c�lr�c**�t•k�c*^k*-k�c*•k�r*Fr•Jc�ci;�r�kl:��c*y:�;�c-k�c-�-kk•k,kk*�c�c**�c*-k�t�c�c*k•k•k•k*ir
S14:C'J'.CON XI:II DISPOSAL CONSIDERATION
Waste Disposal Information
Dispose of in accordance with all applicable Federal., State, and
Local r. eau-lations .
•k^k**Yc�r�c*�r**�c�c�:*�ck�ir�c�c•kyck•k�r•k�ckAr•k*k�c�c•k�c*Yc�cArYc•k•k�r�c-k�c�t-k•k�c�:•k�cyF�rk•k�c�:�c�:•k•k•kk�r�c��c*�c*
SECT I:ON Xl•V TRANSPORT .UIVORMA` TOR
DU'J' 7.nformat.i on -- 49 CFR 1 72- 1.01
D0'V Description:
COMPOUNDS, :CNDU:;'. RI A1, PROCESS WA -PER 7'hk;A'J':I NG LIQUID
ITEM 50227 Sub 1 (Class 60)
- Packaged in plastic containers
Reportable Quantity (KQ) - 49 CFR 172.101
Not applicable
-A,******-k7k***k*yc•k******•k•k*Yr•k** **'k****-k*****yY•k****•k**•Ac*•kic**-k*•k*yc*yc* ******dc***

MA'['t;R1AL' SAYETY DATA SHEET 8000--N'-1 TOWKR '.LR ATM1 qv PAGE 5 Ul±' 5
SXC'PION XV REGULATORY INFORMATION
US Federal. Regulations
TSCA ('Poxi.c Substances Control. Act)) Status
11'he intentional ingredients of this product are I.ist.ed.
CERCLA RQ -- 40 CYR. 355 Appendix A
Norte
SA}.:A 302. Components -• 40 CYR 355 Appendix A
None
SARA 333 Components - 40 CVR 377.. 65
None
State And Local Regulations
California Proposition 65
None
North Carolina Administrative Code 2D. 1104 and 2H. 0610
None
South Carolina ina Regulation 62.5 Standard Number B
None
SECTION XV.r 09'HER INFORMATION
The information accumulated herei-n is believed to be accurate but
is not warranted to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
information i-s current, applicable, and suitable to their
circumstances.
This information was compiled from current manufacturer's M SUS' for
the component parts of the produ<<t. As well as ' other sources, such as:
Code of. Federal Regulations 29, Revised as of duly 1, 1994.
Code of Federal Regulations 40, Revi-sed as of July 1, 1994.
ACG1H, Guide to Occupational -Exposure Values, 199.6.
ANSI 'L129. 1-1994, Precautionary Labeling for Hazardous L'ndust.r- ia.l
Chemicals.
Hazard Communication Handbook, A Right to.Know Compliance Guide,
Craig A: Moyer & Michael.Yrancis Clark Broadman Company, LTD.
New York, New York. 1996.
RCi:A Regulatoins and keyword :Index, Compiled and l'ubl.:i_shed by McCoy
and Associates, 1:nc. Lakewood, Colorado. 1992.

Nl?pA/RM1.,17; : HEALTH I
FLAMMAB11-41'12Y - 0
REACTIVITY - 0
PAGE 1 OY 5
MA9.'ER1'AT, SAYU,'I.'Y DATA StTEET U.S. DEPARTMENT' OY LABOR
COMY11JES W]"J'll 7.,AYETY AND HEALTH REGULATIONS, (29 CYK� 1910.12,00)
* * * * * * * * * * -k * * * * * -k * * * * * * * * * * * * * -k * * * * * * * * * * * * * * * * * * * lk * * -Ar * * * * * * * * * -k * * * * * * * * *
SECTJ.0N J. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: MOLYT.REAT 300 CONSOLEDATED WATER COND
PRODUCT USE: WAJ*'L,',k TXli.ATMXNT
2.33 BEECH BROOK LANE
PIZODUCT CODE: 4102 SJ.'A'J.ESVILLE, NC 2,86-7-7
MSDS NUMBER: KOS : 24
CAS # '.) EMLRGXN(-!:J1i5: (704)-873-5413
REVISION DATE: 021098 (2)
SECTION 11
COMPO',i:['I!'10)\[/INFORMAT:L()N IN COMPONENI'S
CAS NUMBER
CHEMICAL NAMES
%
TLV (UNITS)
77 3 2 - 18- 5
WATER
<
96.00
n/e
1.0102--40--6
.130J) (UM MOLYBDATE CRYS'J.'ALS
<
21.00
n/e
6 4 6 6 5 --,57 -2.
SOD:! UM TOLYTRIAZOLE, 50%. AQUEOUS
<
0.50
n/e
110-91--f3
MOJ.ZPHOLr.NE, 98%
<
0.50
20 (PPM).
121'79-04-3
BORAX, s MOLE-;
1.50
1 M('V,/CU M
9003-04-7
POLYACRYLYC ACID, GODI'UM SALT
<
1.00
n/e
31130-65-5
SODIUM. GLUCOREPTONATE, 5096
<
1.00
n/e
-SPIv
POLYCOL go (D]. 0.SANT)
<
0.50
n/e
n/e = none established
* * * * * * * * -k * * * 'k * * * * * * * * -k -k -k -k -k -k -k -k

MATERIAL SAVE- TY DATA SF{E'E'1' MUL• Y42RHA`C 300 PAGE 2 OF 5
SECTION III HAZARDS IDENTIFICATION
Primary Route of Entry
Skin contact/absorption
Carcinogenic Enf.ormat.ion
This material is not listed as a carcinogen by, J ARC, NTP, or OSHA.
•k•k�r**kk*•k:kk*�1r�k�r�c*k�r�c**ir•k*�r•k•k�ck**it�r*•k***:�**�r•k*�c�c*•kk�r�c*�k**•k•kYcic�lr�r***irk�r•k�r�r�t**
Sh'C'1'J UN 'IV F I..hS'.I' AID MLA.SIJRhS
EYES
Ylush with low pressure water for,at least 15 minutes.
SKIN
Wash thoroughly with soap and water.
I: NHAL• A`C E' ON
Igor.excessive inhalation, remove to fresh air and get medical
attention.
INGESTS ON
Give S to 16 ounces of water to dilute substance. Cal] a physician
or. Local. Poison Control Center immediately.'
de�c,k*�t*�k^k•k^k�c•k*�c�ede•k�e�k*•k*�c•k•k•Ac�r•k�e•k�c*•kit�Ar•kd;•k•kYe•k•k•kie•k•k�fr�e�e�kk�k�c•k�e*Ic�r�e�E•k�e�c�k�c�cYc�k�k�c�r*•k�c
SEC` ION V F ]:IZL Y I:GH'l',I:NG MEASURES
Plash Point
No Flash at boil (C.C. Method)
Explosive Limits
Not Applicable
Autt.oi_gni.ti.on ':Temperature
Not Applicable
Hazardous Products of Combustion
Not Applicable
t;'xti_ngui.shi.ng Media
Not Applicable
WPA/HMUS .I•tati.ngs
Health: 1, Flammability: 0, keactivity : 0
•k�rkJc�c*�c-k•k�c�r•k*•k�r�1r•k•k*�c*•k�k�t�k k�c^k*�r�t�rrlr**�r*�t�c•k*•k'k**�r•k�r�k*�r�r.*�Ir�k�t�k•k�rk�t�r•k�c�c�**•k�rir�r�r*

MATLeRIAL SAFETY DATA SHEY-,I' M.OLY'.C'REAT 300 PAM-', 3 OY S
SEC` YON V.I: A.C:CI:DEM'AL RELEASE MEASURES
Small Spill
Absorb with an inert solid and scoop up for disposal, then rinse
soiled area with water down the drain.
Large Spill
Stop leak. at the source and collect into a suitable container,
then treat as a small spill.
****************,kY **-k*-k-k*,k******,kit*****-k*-k*********•k*****•k**************
SLC'.L'.I:ON V E. J.' HANDL• L• NG AND STORAGE
Store in a cool, dry place. Keep original container closed when not. inuse. Shelf life - 2, vears minimum.
************•k***.k**********•k******•k********************************-k*•k**-k*
SLC'I'1"OLV V1 LI EXPOSURE COMR.ZOLS/PERSONA:IL PROTECTION
Safety glasses and rubber gloves are recommended when using this product.
•k•k�r•k************•k*******•k****************k*********�Ir•k**•k*****fir****�r�t*•k****
SHCTION IX PHYSICA.la AND CHEMICAL PRO]-IRR'J"TE5
Appearance and Odor
Thin, straw --colored liquid with bland/mild odor
pH Concentrate
8.5 - 9.5
Vapor. Pressure
Unknown
Vapor Density
Unknown
Boi.li.ng Point.
206 degrees Fahr.enhe:i_t.
Solubility in Water.
Complete
Evaporation Rate
(Water=l) 1
Percent. Vol-ati.l.es
92%
Speci.f. ic_ Gravity
(I-12()=l) L. 005 I-/ 0.0`?

MATT' VR1AL SAY&I.'Y DATA SHEET MULYTR2AT 300
SECTION X STABILITY AND REACTIVITY
Chemical. Stability
Stable
Conditions `1'o Avoid
Avoid temperature extremes
Cncompatibility
None
Hazardous Decomposi.ti.on
None
Hazardous Polymerization
Will not occur
PAGE 4 OV 5
***•k•k****•k*Y****•k******•k**•k*ic****•k•k•k*•k******•k•k****•k**•kk*•k•k*•k****** t•k******
S; C7.'J:C)N X1 `I'UXTCUL•UGfCAL 1:NYORMA`1'TON
No Data Available
SEICTI:UN X1:J: U-COLUGiCAL 1NVORM.A'1'.TUN
No Data Available
*****•k*•k****•�t*•k�c•k•�r*•kk***•k**•k***********�c•k*•k****•k********************•k****�c
SECTION X111 DISPOSAL CONS 1.1))±;12AT 1*ON
Waste Disposal Information
Dispose of in accordance with all applicable >±ederal, State, end
Local regulations.
***********•k***:k********•k•k******•k******•k*****************•k*******•k**•k•k•k•k**
SEC'1':I:UN XJ:V TRANSPORT 1:NVORMATION
DOT Information -• 49 CFR 1.71:.101
DOT Description:
COMPOUNDS, }3U:C•1•,ER CLEANSING, YRRSERVING SCAJ: Le PREVENTING OR
REMOV•I:NG, LIQUID
7'J'1-;M. 50093 .Sub 7. (Class 55 )
- Packaged in plastic containers
Reportable Quantity ()ZQ) - 49 CFR 1.72.101
Not applicable
***•k****************•k****•k**•k******'k***************•k******•k***************

MATERIAL SAF137'Y" DA'VA SHEET MOLY't'•T.ZEW).' 300 PAGE 5 OF 5
SECTTON XV REGULATORY INFORMATION
US Federal. Regulations
TSCA (Toxic Substances Control Act.)) Status
The i.nt.enti.onal ingredients of this product are listed.
CX'RCLA RQ -• 40 CFI . 355 Appendix A
None
SARA 302 Components - 40 Crk 355 Appendix A.
None
SARA 313 Components •- 40 CYR 372.65
None
State And Local Regulations
California Proposition 65
None
North Carolina Administrative Code 2ll.1104 and 2H.0610
None
South 'Carolina }Regulation 62.5 Standard Number B
None
SECTION XVI OTHER INFORMATION
The information accumulated herein is believed to be accurate but
is not warranted to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and sui.table to their
circumstances.
This information was compiled from current manufacturer's MS DS 1 for
the component parts of the product..'_ As well as other sources, such as:
Code of Federal Regulations 29, Revised as of July 1, 1994.
Code of Federal Regulations 40, Revised as of J"uly 1, 1994.
ACGl"H, Guide to Occupational. Exposure Values, 1996.
ANSI Z1:29.1 -1994, Precautionary Labeling for Hazardous 1_ndustrial
Chemicals.
Hazard Communication Handbook, A night to Know Compliance Guide,
Craig A. Moyer & Michael Francis. Clark Broadman company, LTD.
New York, New York. 1996.
RCRA Regulatoins and Keyword Index, Compiled and Published by McCoy
and Associates, I'nc. Lakewood, Colorado. 1992.

NYPA/HMIS HEA'l'.,TH — I
FLAMMAS'll'i.1"VY - 0
REACTIVITY - 0
PAGE 1 Oy -S
MA"1.'EJ.\Z.l'A)j SAFVVY DATA SIREET U. S. DE PAR'l.'MENT OF LABOR
COMPLIES WJTH USDI, SAFE'VY AND HEALTH RXGULATIONs, (29 C'I?R 1910.1%00)
SEC".VION I CHEMICAL
I.-'RODUCT AND CQMPANY
'[DENTIVICATION
--"�0PRODUCT NAME:
ULTRA
KLEZAN
CONSOLIDATED WATER COND
PRODUCT USE:
WATER
TOWER' TREATMENT
233 BEECH BXOOK LANE
PRODUCT CODE:
4961
STATESVILLE, NC 2,8677
MSDS NUMBER:
KOS :
672.
MSDS TYPE:
CAS VS,
EMERGhNCJ.ES: ('704)-873-5413-
REVl:SJ:ON DATE: 050598 (1)
SECTION 11 CC)MPOS'C'J.'I.C)N/'.LNF(.)I�MA'J"IC)N JN COMPONENTS)
CAS NUMBER C If IsM r CAL., NAMES
').'YV (UNITS)
7 7 3' - 18 - - S WATER (DA-10N)'ZED) '79.00 n/e
9003-04-7 POLVACRYLl.'C ACID, SoDXUM,SAKAT < 10.00 n/e
SODIUM METHYL NAP HT HALIMA' S ULF0NA;U.,-. < 1.00 n/e
03-11 -6 POLYOXYPJ.:.oPYLEJIE-2-LILYoXYI-:,--�-�e < 10.50 n/e
BLOCK C(.POLYMER
ji.mU)'S:(oN < 0. 50 n/e
-92--9 C'I'TRI.0 ACID < 1.00 n/e
64665-57-2 -SODIUM 1110INTRIA7,C)LE, 50%, AQUEOUS < 1.00 n/e
n/e = none established'.,
*-k* *-k*-k *-k

MA7.'L.RTAL SAFE'J'Y DA'VA SHEL'1' ULTRA K:J',>;'1'AN
SECTION TII HAZARDS J-DEN'J':f VICA`1':I.UN
Pri.mar. y Route of. Entry
Skin contact/absorption
PAGE 2 OY 5
c ar. ci.nogeni.c rnf.ormati-on
`Phis material_ i.s not listed as a carcinogen by 1.ARC, NTT, or OSHA.
**k***k****�e*k�r�ckkkk�ck*kkkkJe*k�rk�rk*k�e**k�t�r� kk**�kk�ekk�c�c'k*kkk**•k**it�rkkk�e�4r�kk�
SECT10N TV I?J11ST AID Mk�,ASURES
EYES
):lush immediately with clean water. Call physician immediately.
SK.i:N
Wash w:i.th generous amounts of. water..
I: N HALA`i.' C U N
Remove to fresh ai-r. Consult physician if breathing is difficult.
isNGh',. T I:UN
Drink Large quantities of f_rui_t juice or water. Call phvs:i ci.an
i.mme d i. at e l.y .
*********•k*•k*•k*********•k**********•k*•k**•k**•k************-k*•k************-k***
SI;'C't'J:UN V FtRE YT.GHTJ:NG MEASURES
Flash Point
No Flash at boil (C.C. Method)
Explosive J-,i.mi.ts
Not. Appli_r_abl.e
Autoi.gni.ti.on Temper_ azure
Not Applicable
Hazardous Products of. Combustion
Not A.ppl:i..cable
Lxtingui.shing .Media
Not Appl-i..cabl.e
Nl:PA/HMIS A.Zati_ngs
Health: 1, plammabili.ty: o, Reacti-vity: 0
********•k****•k•k**•k•k•Jc**k*********•k*********-k•k*.ter***•k•k*****•k*•k*-k*************

MA'J Hk1.A:l. SAFETY DATA SH);RT ULTRA K•L• ZAN
SLC'1'J'.0N VT ACC.I:llLN'I'A% RELEASE MEASURES
PAGE 3 OF 5
Small Spill.
Absorb with an inert solid and scoop up for disposal-, then rinse
soi_Ied area with water down the drain.
Large Spill
Stop J_eak at the source and collect into a suitable container,
then treat as a smal_1 spill.
***** **-k****•k*** k****,k**************-k**-k***-k***yc•k**-k**-k•k****************
SLUE' r ON VT I HANDJ° T NG AND S'i'U RAGE
Store in a cool., dry place. Keep origi.na..1 container closed when not in
use. Shelf_ life - 2 years minimum.
*********•k******•k*•k**•k*****�c*****************•k*-k�c*�c******•k********•k-k******
SECICT. )N VJ_J"E EXPOSURE' COM'EROLS/PERSONAL PROTECTION
Safety glasses and rubber gloves are recommended when using this product.
**•k***�c******�c•k•k***•k�r*•k**************ir*****it**********'**•k*********•k****fir**
SECTION IX PHYSICAL AND CHEMICAL PIZO?L;127':f ES
Appearance and Odor.
Thin, amber. -brown J.iqu.id with characteristic odor_
pH Concentrate
3.5 •- 4.5
Vapor Pressure
Unknown
Vapor Density
Unknown
Boi..1ing Point.
211 degree Fahrenheit
So l.ia.b i.l. i.ty in Water
Comp l.e to
Evaporation [fate
(Water=1) : < 1
Percent Vol.atil.es
6 _`i %
Speci.f i.c Gravity
(H2..O=-t) 1.03 +/- 0.02
**********•k*k***•k*•k******•k**-k*•k***•k*******•k�c*�c*k*-k*-k******•k***-k•k*-kk•k*****•k

4,F%f.*,F**%f.* ***M*aI•***************,1.***,f•*aF**,Y•***********y.***k-*-'.,f'.**
a lgeat �dde .�oN
T 0 T ' Z. Z. T '8,q,) 617 - ( ()2T) L4'l4uenO a-1 cje-4aoda2t
s..iau Le-.uoo o-c-4seTd ' uT paf3e-{ot-c[ -
(o9 T qnc L.Z<OS h]:T,l.a:
CIT..C1brT. X'ilTH.M SMIDO) (c{ rCEl1:�fJ;SCtQlu.l: 'S(INC)C)c{Tr]()7
:uoT-4d-iaosa(I ,T,o(j
TOT'Z/.T. Cat? - uoT-4e41-TO-4uT ,ToQ
No:t•,l`d.W 0-gN:C A'IX
suo-L P'[l:lCaa -reoo�
Put'; "a4R-45 `•lx'.zapa,I aTgeoTTdde r-le u•4-rm oouepz000e u•c go asodsT(l
uo•T'4eu1,[o4UT Tesods cQ agseM
S Ao I? I.qcl)va
NU:1.�1.��7.2);Tt[:IrNC)7 rrFZrC.)cir:CC► 1:l:fX NO:C;I,;.?'�T:�
a'Cge-CT'RAV e4eQ ON
No:CJ,VWfo.TN7. rr�17 I �U.rU7 T :I TX NC>1,T,7�:)
a lqe Tpnd e4PCI ON
N0:f,T,HW27t),gNa : X NU:l,l, 70
-in000 -4ou "CT"�M
uo-14L-Z-f.xauix-loa sn0p.xezel9
auoN
uo1_}'Csodulooa(j sLlUp (e"Lefj
auoj\j
k44 T_[q•i.-4edwoou.t-
sauua..(qXa a.zngr-ua.dulaq pTOAV
p1onV 0;1, suo-[q•fpuU7
aTgp-,4S
A'41T.�ge=FS -j-eo-piagj )
x,r, I:nT,T,7Ktq2T (INV ?,�L 1:r[ L�[V.T,S
NFI. grrN. W'1,6rlfl IMAT;IMS VI'll ICf A111RAVS r1V:l 2IgIl,F1.W

MA.`I ERIAL SA1?1*s'.11Y DATA SHEN'T U)-1jTRA. XLLAN PAGE .5 OF 5
SECTION XV R1 GUl',A'I!ORY :1:Nb'0W111r)' UN
US Veder. al Regulations
`1'SCA ('Toxic Substances Control Act)) Status
The intentional ingredients of this product are listed.
Ci✓RULA RQ - 40 CVR 355 Appendix A.
None
SARA 302 Components - 40 CFR 35 Appendix A
None
SARA. 313 Components - 40 CYR 37.2.65
None
State And. Local Regulations
California Proposi.ti_on 6.5
None
North Carolina Administrative Code 2D.1104 and 2H.0610
None
South Carolina Regulation 62.5 Standard Number 8
None
SLC1I'1*0N �,Wl: OTHER I1:NFORMATION
The information accumulated herein is believed to be' accur. ate but
is not warranted to be whether originating with the company or
not. Recipients are advised to confirm in advance of need that the
information is current., applicable, and suitable to their
circumstances.
This information was compiled from current manufacturer's M:,Dc3' for
the component parts of the product. As well as other sources, such as:
Code of Federal. Regulations 2..9, Revised as of. July 1, 1994.
Code of. Yederal. Regul.at.i.ons 40, Revised as of J'ul_y 1, 1994.
ACGI.H, Guide to Occupational. Exposure Values, 1996.
ANSI 7129.1-1994, Precautionary Labeling for liazar_dous Tndustrial
Chemicals
Hazard Communication Handbook, Alight to Know Compliance Guide,
Craig A. Moyer. & Michael. Francis. Clark 13roadman Company, LTD.
New York, New York. 1996.
RC 111', Regul.ato:i_ns and Keyword Index, Compiled and Published by McCoy
and Associates, Inc. Lakewood, Colorado. 1992.

NVYA/HM:(.'� : HEALTH - 1
FLAMMABILITY - 0
REACT:1 VI TY - 0
PAGE 1 OV S
MA'.I.'E1.2J:AL SAYE'l.'Y. DA'.VA. SHEIET U.S. Dt F?AR'(.'MLNT car' LABOR
COMP)"J.ES WITH USDL SAH)O.VY AND H)",ALTH XEGU:I,A.TJ ONS, (2.9 CYR. 1910. 1200 )
*********•k****************************•k*****• **-k*****:k* **,k******,k***** kic k
SECTION I CHEMICAL PRODUCT AND COMPANY IDEN'1'J V ICA.TION
F)RODUC T NAME: A.I*k WASH 'I' REA7.'MEN'C'
PRODUCT USE: WA'I,Ex '1'OWN,h '.Vi,,EA7'MEN'1'
PRODUCT CODE: 4957
MSDS NUMBED: K()S.: 635
MSDS TYPE: CAS #' S
CONSOY IDA`l'ED WA.'I'Ex C OND
233 BEECH BROOK LANE
STA`.IESV.CLLS1 NC 286.77
EMEk.GBN(:;71s,S: ('704)-8'13-5413
REVISIOIN DATE: 050698. (1 )
E;);'C'i'iC)1V IJ CUMPOS:f.7'7.ON/I.NFO)ZMA'1'IC)N IN COMPONhN"7.'S
CAS NUMBER C:HEM1:CAL NAMES
'7732--18- W,
(' )]:M> '1'HY]", SIA"i_CoNE LMULS I:oN
003-11--•6 YULYUXY_PItC)PY1',N')V)i, }'U'L"YUXY.E'].'T1Y1�1�;NE
BflOCK COPOLYMER
1310-58-3 454'6 AQUI.OUS POTASSIUM HYDROXIDE
6466S-57-2 SOD] -UM TOLY'IRIA/,ULE, S096 AQUEOUS
10102-40-6 SODIUM MOLYBDATE
1.344--09 -8 SOD I:UM S I'LICATE SOLUTION 46/16
31075-2.4--B MAYOQUESrJ' 60 (CATIO)NJC POLYMER)
Qa
T].V . (UN•I'L'S )
< 92.00
ri/e
< 0.50
n/e
?.. 00
n/e
1.00
. MG/CU M
< 0.50
n/e
< 1.00
n/e
< 5.00
n/e
< 2.00
n/e
n/e = none established
•k**k*****•k*****k*****�ck*****•%r•k***�:****k*•�**�c***�k�c�tdc*fir***k�c***•k•,k�c*********

MATERIAL SAL E'VY DATA SHEET A I'R. WASH 'TRLA'VME;NT NAVE; 2 Ur' 5
SECTION JJI HAZARDS I.DENTI ICA'J.ION
Primary Route of Entry
Skin contact/absorpti.on
Carc:i.nogeni.c Enformation
This material is not listed as a carcinogen by 1_A.1tC, N'J'1', or C)StiA.
**-k�c�*;r�r�'it�:�r�c�r�Ir��r �l•*�k•k�c�r**-k•k�r**�r•k�r�c k�c***�c�r•k�1r�r•kit•k�c�c�c**�r�c•k�c�k•k•k�c*•k•k�c•k*•k*•k�c�r�c*�1r
SHC7'I UN IV FIRST All) MEASURES
Ile YLS
Flush immediately with clean water. Call physician immediately.
SKIN
wash with generous amounts of water.
Remove to fresh air. Consii.j.t physician if breathing is difficult.,
J: NGIE''ST YON
Drink large quanti.t:ies of fruit juice or water.. Call physician
immediately.
�c***�*�***•k•k**�l••k*•k�F**•k*•k•k*�ck�k�c�c�c•k�r^k*�c�c�rdc•k*.�c*�r*ik�c�c�c•k�r�c�1r�;�c�c��c•k�:�c�;-k�c•k-kic�c�c�r�c*�k
SL'CTVON tr YIRE Y(GH'TENG MEASURES
Flash 1?oi.nt
No Ylash at boil (C.C. Method)
Explosive Limits
Not Applicable
Autoi.gni.tion 'Temperature
Not. Applicable
Hazardous Products of. Combustion
Not. Applicab) e
Extinguishing Media
Not A.pp] :i..cabl e
NYPA/HMJ:S Ratings
Health: 1, rilammability: 0, Reactivity- o
�Ir•k**•k�c*�1r�k•k�r�t�k*�It•kit•k•k**�r�k**•k***�k•k�r**�1r•k**�c�c�lr�c•k•k-k�1r**�r�r*�k�lr•k�c•k•k�1r*•k�c•k•k**�c�t•k*•k*�k•k*

MATERIAL SAFl,']'Y. DATA SH1,) '.1' AT1Z WASH '1'REATMLN`.L' PAGE 3 OF 5
:3Ei C'' ):On! V E ACC.I:I)LN`C'P,L RELE.,:ASL MEASURES
Small Spill
Absorb with an inert solid and scoop tip for disposal, then rinse
soiled area with water down the drain.
Large Spill_
Stop leak at the source and collect into a suitable container.
then treat as a small spi.11.
****-k*-k-k•k***-k*******-k*-k***-k•k-k**** *•k•k***'k**'k**** **-k***k***•k*****
SCC'I.' I:ON V.0 C I•IANT)1.1:NG AND STORAGE
Store in a cool, dry place. Keep original container closed when not in
use. Shelf. life - 2 years minimum.
**************-k*'k***•k**-k**********•k***************************-k-k*****•k****
'C'1'1:ON Vl: 1: I: I XI-10SUREi CONTROLS/ PEIRSOMAL PGtOTEC`f CON
Safety glasses and rubber gloves are recommended when using this product.
*******•k******•k*•k*•k********•k********•k*****•k*•k*****************************
ShCTION 7_X PHYSICAL AND CHEMICAL PROPE,E2'1IMS
Appearance and Odor
Clear, colorless licluid ; odorless
pH Concentrate
11.5 - 12.5
Vapor- Pressure
Unknown
Vapor. Density
Unknown
Boiling Point.
211 degrees 1j'ahrenheit.
Solubility in Water
Complete.
Evaporation Rate
(Water=l) : 1
Percent Vol.ati_.les
95`•Y,
Speci.fi.c Gravity
(H20=1) 1.03 +/- 0.02.
*************•k**•k******************-k**-k******•k*•k**** k-k***********•k***•k****

MA`1.'LItI:A'L SAVIIKOVY DATA SHEL'1' AI:R WASH '1'REA`.L'MV.4T PAGE 4 014' 5
SB'CT:I.UN X STABILITY AND REACTIVITY
Chemical. Stability
Stab] e
Conditions 11'o Avoid
Avoid temperature extremes
J: ncompat i.b i 1. i.t.y
None
Hazardous Decomposition
None
'Nazar. doug Polymerization
Will not occur
-icy;*•k**•k•k****.k-k* **.k*-***k***k*******•k*****.k•k**********************i;*-k***'k-k•k*
S13CT1:c)N XI_ '1'c)XJ:CULc)GI:(-'AL• ):NFORMATJ:c)N
No Data Available
*-k***ie** k* k*•k;k* k** k****'k****-k*******'k*ik***,k*
SH'C'J ION X1:1: ECOLOGICAL INFO MA' IOV
No Data Available
*-k******•k•k*dc*�c***�c**ic*******•k**�:�c-k*******�k***�k�c**�r*•k^k�c�c*********�c*********
SEC'L'I:UN X.I_ I is DISPOSAL CONSIDERATION
Waste Disposal Information
Dispose of in accordance with al.l applicable Federa.l, State, and
Local remal.ations.
**************** k k k*****************************•k-k***fie**'********•k******-k**
SE0C'I')-c)N XIV 'I.'1.2AN:3I ORT 1NFOL1 MA'l'.1ULV
DOT :Information - 49 CFRI 1.7`'?.101
))OT Description:
COMPOUNDS, INDUSTRIAL PROC'MSS WATER '.I'REATIN-G I.I.(Q1311)
I.'1.'LM S022.7 Gnb 1 (Class 60) .
Packaged in plastic containers
Reportable Quant .ty (RQ) - ..49 CFR 1*72. 107_
Not applicable
*********-k*****************•k-k***-k-k********************-k********-k**********

MA'L'E[.ZJ:AL SA1'EVVY DATA SHECK'T A11Z WASH `I'[tZA`['MLNT PAGE S Oh' 5
SECTION XV REGULA'!ORY. INb'ORM1',PION
US Yederal Regulations
TSCA. (Toxic Substances Control Act.)) Status
The i.nt.enti.onal. ingredients of this product are listed.
CERCLA RQ --- 40 C'FR 355 Appendix A
None
SARA 302.. Components -- 40 C'FR 3S>5 Appendix. A
None
SARA 313 Components -• 40 CFR 372.65
None
State And ]:vocal_ ].regulations
California Pr_otaosi.t.i.on 6.15
None
North Carolina Administrative Code 2,D.1104. and 2H.0610
None
South Carolina Regulation 62. 5 Standard lvumber S
None
SLC:1!J'OU XVJ: ()'['({ER INYORMA`l' I:UiV
The information accumulated herein is believed to be accurate but
j.s not warranted to be whether originati-ng with the company or
not. Recipients are advised to confirm. in advance of need that the
i.nformati.on is current., applicable, . and suitable to their
circumstances.
.This i.nformati.on was compiled from current manufacturer's M.SDS' for
the component parts of the product. As well as other sources, such as:
Code of Federal I.:egul_ati.ons Revised as of 'July 1, 1994.
Code of Yederal. Regulations 40, Revised as of July 1, 1.994.
ACGIR, Guide to Occupat.ional. Exposure Values, 1996.
AN:. T '7,129. 1-1.994, Precautionary Labeling for Hazardous Industrial
Chemicals.
Hazard Communication Handbook, A ]tight to Know Compliance Guide,
Craig A. Moyer & Mi.chael Yr. anci-s . Clark Br. oadman Company, LTD.
New York, New York. 1996.
RCRA Regul.atoi.ns and Keyword 'Index, Compiled and t:Dubl i shed by McCoy
and Associates, J:nc. Lakewood, Colorado. 1992.

NOV. -25' 98 (WED) 1.5:01
TEL:[phone] P"001
..,,RBioLab,
A9Wit►�/tf01�11 LYYIYIGiYv.Yal C7Alo�(a
malwomfu & 511dikla fJMlaa
FA4CSIMILE COVER SHEET
** CONFEDENTIAL***
DATE. November
S, 1998 TEAR 1:53 PM
TO: Ed Spencer
PRONE: 704-973-5413
COWANY; ConsolidaW
Water Conditioners FAX [phone]
FROM. M the fle Ramson
RE: $romiCide
ox data
CC:
Number of pages imcludir
g cover sheet: 13
Dear Mr. Spencer,
I am sending the toxicity chta
that you requested: If you need anymore information, please do not
hesitate to ca U me.
Thank you far your suppor.
of our products.
$in rely,
1llichellc Harrison
Senior Applications Chemi
t
{Tills mcssege was tranemind ele=
ifcally and contains an electronic: sbadurm) ..
BioLab Inr,, Commere
al and Specialties DivisionIndustrial Water
P.O. Box 1429 • Decatur, GA
31-1489
Phone [phone]-Mi or (300)
6004523, ExL 401 • Fa= (404) 337&7455 E-Mail [e-mail]

NOV. -25' 9B (WED) 15:01 TEL:[phone] P. 002
IVR
I-ERROMO--3-OHLORO-5, 5-DIt+ETHYLMANTOIN
(BROMICIDEO)
TY DATA
Background: l-Ero-3-chloro-5, 5-dimethylhydantoin (ACME) is a
biocide. When dissolved in water, scmi hydrolyzes immediately to
hypobromous acid, hypochlorous acid (the active biocides), and 5,5-
dimethylhydantoin (). Toxicity data are available for either
SCDMH or DMH, but not necessarily for both. Summaries of toxicity
data which are from the Federal EPA registration files are so
indicated.
I. Microbial Mute enici.tY: 2=NN wag tested for potential
mutagenic effects using a series of in nitro micrQbial assays
employing Salmonella and SacchAZWRyces indicator organisms in the
absence and presence of liver microsomal enzyme preparations ,from
Arochlor (39) induced rats. The results of the tests were all
negative. 3CDMH teas not mutagenic under the conditions tested.
MO was tested for potential mutagenic effects using a series of in
vitro microbial assays employing Salmonella and Saccharomyces
indicator organisms in the absence and presence of liver microsomal
enzyme preparations from Arochlor (S9) induced rats: The results of
the tests were all negative. DMH was not mutagenic under the
confli.tions tested.
2. Mam=lian Cell Mutageni,bity: MM wa.s eValuated in rats for the
potential to induce zhromosome aberrations in bone marrow cells when
administered by oral gavage to male and female rats, Dose levels of
200, 660 or 2000 mg/kg resulted in no statistically significant
increases in the fro uency of chromosomal aberrations when comparecl
to control values.
DME was evaluated fo the potential to induce gene mutations in
cultured L517F,Y mousa lymphoma cells in the absence and presence of a
metabolic activation system. Under tha test conditions, DMH, at
concentrations up to and including 1000 }gg/mL, did not cause an
increase in forward mutations in L5178Y mouse ly=homa cells.
DMA at concentratjQn3 up to and including 1000 µg/ML was tested for
the potential to tra sform cultured C8H 10T 1/2 cells in the absence,
and presence of a me abolic activation system. In the absence of a
metabolic activation no dose related cytotoxicity and no Type ITT
foci (transformed oe 15) were produced. In the presence of a
metabolic activation no dose related cytotoxicity resulted, but one
Type Iz2 focus was p oduced at each concentration of 10, 30 and 300

NOV. -25' 98 (WED) 15 : 02 TEL: [phone] P. 003
µg/mL. The results
neoplastic cell tray
3. Acute Toxicity
via gastric intubat:
dose levels of 500,
LDsa in rats was calf
The acute dermal t
2.0 g/kg for both
toxicity were obse
Inhalation toxicity
only, exposure in m
air -milled dust wit
Airborne concentrat
and 0.29 mg/L. The
mg/L of air.
of the study indicated that DMH did not produce
sformations.
BCDMH was administered as a sir4gle oral dose
on to groups of five male and five female -rats at
370, 650, 741 and 845 mg/kg. The combined oral
ulated to be 578 mg/kg.
Lty of BC,DM8 was determined to be greater than
and female, rabbits. No signs of systemic
f BCMM was evaluated in.a 4-hour, single, nose-
s and female rats. BCDMH was administered as an
the 1-2 AD ranging from 1.5 to 1.7 microns.
ns (gravimetrically determined) were 0.11, 0.16
ombined..LCsa of BCDMH was calculated to be 0.168
In one study the ac to oral LDgo for DM in rats was reported as being
>4000 mq/kg.
MM was administered as a single oral dose via gastric intubation to
groups Qf five male and five rats. on the day of dosing two .females
were observed to be slightly to moderately lethargic with slight
lacrimation; they were normal for the remaining 14 days. The acuto
oral LDso was calculated to be >5000 mg/kg.
The acute dermal to ia�ty of Db'i was determined to be greater than 3
g/kg for both ma-,e and female rabbits. No signs of systemic toxicity
were.observed. 5,5-Dimethy1hydantoiri is practically non -toxic by the
dermal route of'expasure.
4. Irritation (Skin and Eye): The primary skin irritation index
for SCmm was calculated to be 6.1 according to the method. of Dtaize.
Eschar and necrosis of the skin were observed through day 7. On day
14, the irritation score was zero and eschar and necrosis were no
longer observed. BCDMH was considered corrosive to the skin.
Prolonged or repeated skin contact with solid BcDj4n resulted in minor
reddening of the skin and superficial necrosis with the development
Of excessive exfoliation. Contact with dilute solutions of 0.1$ or
less (1000 ppm or less) was not irritating to the skin (Federal EPA
registration tiles).
Eye contact with the powdered ErDMH resulted :Ln persistent severe
conjunctival irritation and slow development.of corneal damage in
rabbits. Washing the eyes promptly (within 30 seconds) resulted in a
significant reduc-tiou of adverse effects. Dilute soiutions of 0.1-t
(1000 ppm) or less ware essentially non -irritating to the eyes
(Federal EPA registr tion files).
DMH was tested for S in irritation. Slight irritation and edema were
observed at 24 hours in the majority of the rabbits for both intact

NOV. -25' 98(WED) 15:02 TEL:[phone] P. D04
i
and abraded sites. IAt 72 hours, two abraded sites showed slight
erythema; there wer no other reactions. The primary jRjj% irritation
index was calculate to be 0.8 according to the method of Draize.
5,5-Dimethylhydanto�n is classified as minimally irritating to the
skin.
tye contact with po dered DbIIi resulted in slight to moderate erythema
and slight to marked ahemosis and discharge at the 17hour reading in
all rinsed and unri sod. eyes. All irritations had completely
subsided at the 7 d y reading. The primary irritation index,
according to the method of Draize, was calculated to be 12.8 for
unrinsed and 10.0 f x rinsed. DMH is classified as mildly irritating
to eyes. Aqueous s lutions of DMH (10t or leas) Were found to be
essentially nary -irritating to the eye.
S. skin Sensitization: The Buehler method was used to determine if
DME.induced delayed contact hypersensitivity in albino guinea pigs.
No reactions were' o served in the toot ar naive control groups
following either the initial nbaZlenge or the re -challenge insults -
Based on the data, DMH was found to be non -sensitizing in the albino
quinea pigs.
The Guinea pig Maximization Test was used to determine if DM induced
contact hypersensitivity. DMH was termed to be a mild skin -
Sensitizer when three of twenty animals responded at challenge to the
Application of a 10 'aqueous solution.
6. 4-Weep Oral: BM was offered on a continuous basis in the diet
to groups of five male and five female mice for a period of four
weeku. Dosage levels of 0, 1000, 5000, 10,000 and 50,000 ppm were.
used. Systemic toxicity was not apparent at any dose level. The
only potential effect of DMH when administered to mice for 28 day$
was increased serum alkaline phnaphatase (50,000 ppm females).
DIE, suspended in 0
daily for 4 weeks b
0, 2.5, 5.0, 9.0, a
low incidence of le
g/kg. The No-bbsery
g/kg.
DM in capsules was
males and 2 females;
administered DMH at
weights. Potential
one 2000 mg/kg/day c
mg/kg/day were cons:
systemic toxicitty WI
respectively.
5$ aqueous methyl --cellulose, was administered
oral gavage to groups of male and female rats at
d 12.5 g/kg. Two females died at 12.5 g/kg. A
hargy and salivation was noted at 9.0 and 12.5
isle -Effect -Level (NOEL) was considered to be 5.0
administered daily for 28.days to Beagle dogs (2
at 0, 250, 500, 1000 and 2000 mg/kg/day. Males
2000 mg/kg/day had lower testes/epididymides
treatment -related clinical signs were noted in
roup male. A dosage level of 1000 and'2000
dered the No-OHservahle-Effect-Level (NOEL) for
en administered orally to male and female dogs,

NOV. -25' 98 (WED) 15 : 03 TEL, 4043707485 P. 005
7. 6-Week Feeding, Three 5-month old female rats were used in
week feeding study. Dry DM8 was admixed daily in the rats diet.
rat raneived 10 mg/ a.y during the first week; 13 mg/day during the
a 6-
One
second week; 25 mg/ay during weeks three through five; and 60 mg/day
diiring the sixth we k. The other two rats received 10 mg/day
throughout the 6-we k test period. Evidence of gross tox pity was
not
observed during the test. There was no apparent effect on blood
parameters, and no videnve of intestinal disturbances. Autopsy
examination, with p rticular attention given to the heart, lungs,
gastro-intestinal t act, and kidneys, showed no treatment -related
lesions.
Three adult guinea I igs were used in a 6-week feeding. study. one
male received 30 mg day during the first week; 40 mg/day during the
second week; 50 mg/ay during the third week; 60 mg/day during the
fourth week; 75 mg/ay during the fifth week; and 90 mg/day during
the sixth week. The other male and the female received 30 mg/day for
the sips week period Evidence of gross toxicity was' not observed.
There was no apparent effect on blood parameters, and no evidence of
intestinal disturbances. Autopsy examination, with particular
attention given to the heart, lungs, gastro-intestinal tract, and
kidneys, showed no reatment-related lesions.
8. 90-Day Oral: Ibffl was administered orally by gavage to rats for
at least 90 days at 2000, 5000 or 10,000 mg/kg. Four mortalities
were noted: one male and one female at 10,000 mg/kg; one female at
5000; and one control female. Histopathologia changes were noted in
the kidney of all is le treated groups and in the 5000 and 10,000
mg/kg group females. These histopathologic changes were accompanied
by a dose related i crease in kidney weights in males and the mid and
high dose females. Clinical changes consistent with the
histopathology were noted. Clinical observations included a dose
related incidence of white.granular material in the urogenital area
and/or urine stains which were related to the high dose levels,of
material and the kidney pathologic changes. There was a slight
decrease (7-10%-) in mean body weights in high dose males from week 7
throughout the study. Mean food consumption was increased in,high
dose females from w ek 5 through the end of the study with the
exception of week 9 Food consumption was also sporadically
increased in mid do a females throughout the study. A No-Obsarvable-
EtfeGt-Level (NOEL) was not determined in this study.
was dissolved ir water and administered by gavage to groups of 5
male and. 5 female r is at 0, 250, 500, 1000 and 2000 mg/kg/day for 90
days. No effects were noted in the study that could be attributed to
treatment. The No-0 servable-Effect-Level. (NOEL) was aonaidered to be
2000 mg/kg/day in t is study.
D4ff was offered on 4continuous basis in the diet to groups of 20
male and 20-fema.Le ice for a period of 13 weeks. Dosage levels were .

NOV.-25'48(WED) 15:03 TEL:[phone]E5
P. 006
0, 5000, 20,000 and 50,000 ppm. The only potential effect of DYH,
when administered for a minimum of 90 days to mice, was a microscopic
change in the adren 1 glands in the 50,000 ppm females. The No-
Observable-Effect-L vel (NOEL) for systemic toxicity was considered
to be 20,000 ppm in this study.
DbM was evaluated f c r toxicity in a 13-week subchronic toxicity study
in beagle dogs. Dosages of 250, 500 ard.1000 mg/kg/day were
administered by capsule to groups of six males and six females.
There were no adver a effects on survival rate, clinical condition of
the animals, body Weight gain, food consumption data, clinical
pathologic paramete s or organ weight data. No macroscopic or
microscopic examina ions of selected tissues revealed lesions that
could be attributed to the test material. The No -observable -Effect -
Level (NOEL) was co sidered to be 1000 mg/kg/day in this study.
S. DevelopmentalToxicity: DMH was evaluated for potential
maternal and/or developmental toxicity in a range -finding study in
rabbits. DMH Suspended in 1$ aqueous methyl=cellulose was
administered orally to groups of seven inseminated does as a single
daily dose from day 6 through 16 of gestation. Dose levels were 0,
250, 500, 1000, 200C and 2500 mg/kg/day. No compound related deaths
or abortions occurred. Clinical signs (decreased defecation and
white to brownish c ystalline-like material in the feces) were
observed in the 250 mg/kg/day group. Body weight loss and
reductions in food consumption were dose -related in the 1000 mg/kg
and above groups. lo treatment -related gross necropsy findings were
observed at any dose level. Post -implantation losses were increased
and live litter size was decreased at dose levels of 2000 and 2500
mg/kg/day. A sgveri raduction. in mean fetal body weight was observed
in the 2500 mg/kg/d y group. EXternal fetal malformations, primarily
involving defects of the digits (adectyly and brachydactyly),.were
noted at dose levels of 1000, 2000 and 2500 mg/kg/day in 1, 7 and 10
fetuses, respectively- No external fetal variations were observed in
any close group. The (NOAEL) was
considered to be 500 mg/kg/day for maternal and developmental
toxicity.
DM was evaluated i rabbits for potential maternal and developmental
toxicity. Dose le v is of 0, 100, 500 and 100.0 mg/kg/day in 11%
aqueous methyl-celltLlose were administered to groups of 20
inseminated ra-bbitg as a single dose on days 6 through 16 of
gestation. A dose evel of 1000 mg/kg/day produced moderate maternal
toxicity that was a hibited by reductions in body weight gain and
food consumption, p imarily d"Tr_rich the initial six days of compound
administration. Potential developmental. toxini,'ty Was expressed by an
increase of one specific skeletal variant at dose levels of 500 and
1000 mg/kg/day and digital defects (forepaw digit #1) at a dose level
of 1000 mg/kd/day. The dose level of 500 mg/kg/day wag considered
the No -Observable -A verse-Effect-Level(NOAEL) for maternal tbxiQc ty
and a dose level of 100 mg/kg/day was considered the NOAEL for fetal
developmental toxicity.

NOV. -25' 98 (WED) 15 : 04 TEL: [phone] P. 007
10.. Teratology ,in
in 0.5t methyl -cells
rats as a single dai
mg/kg/day on days 6
(e.g.-r
ataxia, lethargy, d�
dried-erange. and rec
majority of the femt
group, and two in the
observable -Effect -Le
Rafts.:. In a range -finding study, DMR, suspended
lose, was administered t4 grOupo of-5.'bred female
ly dose at 0,. 1000, 2500" 5Q00, 7500 and 10,'000
through 19 of -gestation.. Signsof toxicity
creased body weight gain',. and the presence of
matter around the mouth} were noted in the.
lea in -each group. "One:female in the 7500 mg/kg
10,000 7/kg group died during treatment. A No-
vel (NOEL) was not determined in the study,
I7MH, suspended in.0.5%_aqueous methyl -cellulose was administered to
groups of 25 bred f male rats as a single .dose at.01 500, 2000 or
4500 mg/kgJday on days 6,through 19 of gestation. -Toxicity was not
apparent in the 500 mg/kg/day group. Maternal and fetal toxicity
were noted in the 2 00. and 4500 mg/kg/day groups. Reduced fetal
ossification Was assloclated with the reduced fetal body weight and
was considered to b a secondary response resulting from maternal
toxicity. There_we a no major malformations or.increased
developmental varies is expressed -in the` 500,or 2000'mg./kg/day groups.
No-Observable-Adverse-Effect-Level(NQAEL) for maternal tOXicity and
fetal developmental toxicity was considered.to be 500 mg/kg/day,in
tbis study
11. Reproduction: m n was evaluated for potential adverse effects
on the reproductive capabil]tics of 'the Fa and F, generations and
neonatal friability d growth. DE E, in 1% aqueous mothyl-ce11u�.4se,
was administered orally by.gavage.at dose levels of 0, 250, 500 and
1000 mg/kg/day,to the Fo and.Fl animals. Roproductive performance of
the Fo and F1-generations was not adversely affected at a dose of 1000
mg/kg/day. Neonatal body weight (F1 and Fa litters) and Fi madbody
weight. -and 96ad .consumption ,were suppressed bar DMH administraitian at
dose levals'of 500 and 1000 mg/kg/day. Reduced.F2 pup viability was
also apparent at 1000 mg/kg/day.. A, dose level of 250 mg/kg/day'did
not produce any apparent adverse_ results. Therefore, 1000 mg/kg/day,
was considered the o-Observable-Adverse-Effect-Level (NOAEL) for
reproductive toxicity and.500 mg/kg/day w'as considered the NOAEL.for
parental toxicitT. A, dose level of 250 mg'/kg/day was considered the
NOAEL for neonatal t xioity.
12. Metabolism: he absorption and elimination in rats was st adied
using Rats Rats were given a single oral dose of 20 or 100 mg/kg
C14-DMH and observed for 7 days. DMH was'absarbed rapldly and
eliminated primaril in the urine.. The average KeCovery of C14from
rats was 95%. Malef
d,fema.le rats. at both the high and low levels
snowed similar Cld dribution. Dosing'with unlabeled DMH daily for
at least 14 days bee"d6Sing.with radio -labeled DMH'cauPed no'
change ift the excreicy pattern. An average''of 91% was found to be..
excreted ire the- uriwitYs BB$ eliminated i t� the first. 24 hours':after
dosing: Only one mbolite was detected, which amounted to 2.5% of
the urinary Cie.. Noasuzable level of C1°-residues were obaerved in
tissues of rats recing -the low dose indicating levels of less than

NOV. -25' 98 (WED) 15 : 04 TEL: 40437D7485 P. 008
20 ppb. 2n rats re4eiving 'the high dose, low levels of C14 were
detected in kidney 4nd bone.
13. Chronic Mouse The oncogenic potential of ObS was evaluated in
an 18-month dietary study in mice. Doses levels of 0, 100, 320, and
1000 mg/kg/day were administered in diet to groups of 80 male and 80
female mice. Treatm nt with DMH resulted in slight decreases in mean
body weights for thE 320 and 1000 mg/kg/day group males and elevated
mean food consumpti n. values for the �000 mg/kg/day group males and
females. No treatment related e�fffe cats were seen, on any other
parameter evaluated during the study, including clinical signs of
toxicity and palpab a mass data. Tumor incidence Was similar between
the control and tre ted groups and did not reveal any changes related
to the administrate n of DMH. Based on the data obtained, the NO -
observable -Adverse -Effect -Level (NOAFL) for oncogenicity of DMH when
administered in the diet to mice was greater than 1000 mg/kg/day.
14. Chronic Pat:
effects of DM8 when
evaluated. Dose le'
administered in the
and 20 females were
60 females were ass
subgroups were necr
were necropsied fol
treat�qeat related e
condXtiQns (yellow
in the 320 and 1000
toxicologic signifi
were attributed to
which was noted occ,
frequently in the 1
effects were obsery
study. Tumor incid,
groups and did not .
adtttinistration of D!
Observable-Effect-L
administered in the
The NOEL for oncoge;
mg/kg/day.
15. Chronic (Dog) :
in a 1-year oral st
capsules t4 groups
500 and loco mg/kg/
necropsy. No DMH r
chemistry or urinal
a toxic effect were
related to test art
relative organ weig
systemic toxicity w
The p,essj.blt long term toXio and oncogenic
administered to rats for 24 months were
els of 0, 100, 320 and 1000 mg/kg/dray were
diet to 100 male and 100 female rats (20 males
assigned to a chronic subgroup and 80 males and
gned to an oncogenicity subgroup). The chronic
psied at 52 weeks and the oncogenicity subgroups
owing a minimum of 104 wee)Cs of dosing. Two
fects were noted: change in the clinical
atting in the urogenital region) of the animals
mg/kg/day groupso which was not considered of
a.nce; and elevated food conM=ptiQn means, which
he increased concentration of DMH in the diets,
sionally in the 320 mg/kg/day animals and
00 mg/kg/day animals. No treatment -related
d on any other parameter evaluated during the
nce was simi�.ar be'twQt n the control and treated
eveal any changes related to the dietary
H. Based on the data obtained, the No-
vel (NOEL) for systemic toxicity of DMH when
diet to rats was considered to be 100 mg/kg/day.
.icity*was considered to be greater than 1000
The toxicologic potential of DDT was evaluated
dy ire. heagle dogs. DMH was administered in
f four males and four females at doses of 0, 250,
ay. All animals survived to the scheduled
lated effects were observed on hematology, serum
sis parameters. No oc'ilar lesions indicative of
observed. NO maarescopic Qr microscopic lesions
cle administration were noted. Mean absolute and
is in the treated groups were unaffected. No
s observed at any dose level evaluated. The No-

NOV. -25' 98(WED) 15:05 TEL:[phone] P. 009
Obscrzrablc-Effect-L vel (NOEL) for chronic systemic toxicity in the
beagle was 1000,mg/ g/day.
3.9. Aquatie Uptake Depuration and Bioconcentration: A dynamic 42-
day study evaluated the bioconcentration of 14C-DMH using 511aegz].l
sunfish, Lepomis ma rochlrus. A.flaw-through proportional diluter
system was used to maintain a measured water concentration of 4.4
(± 0.33) ppm 14C-5,5 dimethylhydantoin for a 28 day exposure period.
Radio -analysis of fillet, whole fish and visceral portions were
performed throughout the exposure period. Daily bioconcentraton
factors were all less than the minimum quantifiable limits (OMD) for
viscera, fillet and whole fish throughout the exposure period.
Uptake tissue concelLtrations of 14C-DMH were less than the minimum
quantifiable limits for fillet, whole fish and viscera. Therefore,
5,5-DMH basically did not bioconcentrate after 28 days of exposure.
To measure the elim nation of laC-DMH, the test, fish were placed in
clean water for 14 ays. Radio -analysis throughout the depuration
period indicated less than minimum quantifiable limits for fillet,
whole fish and .viscera. .since neither an uptake rate constant (K1)
nor a depuration rate constant (K2) could be calculated or observed, a
non -linear two compartment kinetic modeling program (HIOTAAC) could
not be used for the analysis of the uptake/depuration data.
17. 96-Hour Stati Aquatic Toxicity: [Test protocols for fish and
crustacean bioassay were based on ``Registration of Pesticides in the
United States" in F deral Register Vol 43, No. 132, July 10, 1378.
Toxicity tests and general guidelines for the American oyster were
based on guidelines in "Methods for Acute Toxicity Tests with Fish,
Macroinvertebrates and Amphibians" (EPA-600/3-75-O09, April, 1975),
"sioassay Procedure for the Ocean Disposal Permit Program" (EPA-
600/9-76-010, March, 1978), `Methods for Measuring -the Acute Toxicity
of Effluents to Aqu tic Organisms" (EPA-600/4-78-012, Revised July,
1978), and "Standar Methods, 14"" Ed." (APHA, 1975.) .1
solutiQns were prep red in either synthetic saltwater medium or in
freshwater and were not renewed during the.tests. Six aquatic
species were tested, including three freshwater species; the Rainbow
trout, Sabo gairdn ri; the Fathead minnow,.Fsmephases promelas; and
the water flea, Daphnia -magma. The three saltwate_t species Were
sheepshead minnow, Cyprinodon variegatus; grass shrimp, Palaemonetes
pugio; and the American oyster, Crassostzea virginica.
lacThe 96 hour static LCoo, except where otherwise indicated, for
1-8rasno-3-chlorQ-5,-dimethylhydantoin were:.

NOV.-25'48(WE0) 15:05
TEL:[phone]
Organism
LC54 (mg/L)
NCEC (mg/L)_
Water flea (48
Hr. )
0.48
0.3
Rainbow trout
0.97
0.5
Fatl%ead minnow
2.25
117
Grass shrimp
13.0
6.4
Sheepshead mi
ow
20.0
11.2
American oyste
>640
11.2
DbM: The ,96 hour static LC50 or MC50 data, except where otherwise
indicated, for 5,5- imethylhydantoin (DMH), were:
organism I LC50(mg /L) NOEC(mg/L) ECso(mg/L)
Water flea (48 Hr) >1070 1070
Rainbow trout >972 972 ---
Fathead minnow >1085 1085 ---
Mysid shrimp >922 I.922924 hr.' ---
Sheepshead minnow >1006 1006' ---
Eastern oyster
(dynamic) --- 125 >125
5luegill sunfish >1017 1017
18. Aquatic Reproduction Toxicity (Daphnia Magna): Based on the
effect of EcDM on daphnid reproduntion, the Nc-observed-Effect
Concentration (NOEL) was considered to be 0.056 mg/L (nominal
concentration). No statistically significant 'differences were
determined between his test group concentration and the control
group in terms of t qe number of young produced per adult over a
per-cbd of 21 days.
19. ' Oct.anol/Waterj Partition Coefficient: Fvr DM, the average
value df P from fou4 replications at 25°C was 0.38.
20. Chemical Oxyg n Demand (COD): The COD for MM at the nominal
concentration of 50 mg/L'WMS determined to be 60 mg 02 per liter:
21. 5-Day Bioch ` cal Oxygen Demand (BODy) : The EOD5 . for DbM at
the nominal concent ation of 50 mg/L waa determined to be 6.25 mg Oz
per liter.
22. Hydrolysis: The half-life -of DM8 in water, using radio -labeled
techniques was faun to be:
PEI Half-life in bays
5 842
7 (orris hu fer) 760
7 (Pha�spha e buffer) 1070
9 182
' 9 of 30 dcad @ 96 hours.
P. 010

NOV. -25' 98 (WED) 15 : 05
,- 0
TEL:[phone] P.O11
23. Photolysis: The photolysis study was conducted with radio -
labeled Dt+m in water at pH 7. The half-life for DMH in the
sensitized exposed system was 2295 days. For the non -sensitized
system, the half-life was 2100 days. The half-lives calculated
represent the degradation rate based an little or no degradation.
24. Biodegradati.c ! The hi.odegradatjon of Dm, the dehalogenated
by-product of 1-bro o-3-chloro-5,5-dimethylhydantoin, was
investigated using ierated mixed cultures of microorganisms found in
activated sludge. Iludge was acclimated to 25 ppm unlabeled DMH over
a 2-week period. R dio-labeled DMH was added and levels of DMH and
radioactivity were monitoxed. Within 24 hours the level of DMH in
the incubation mixt re (measured by HPLC) decreased from about 20 ppm
to
an average of 5 ppm, a 75% lass. in tht same period, however,
radioactivity in the mixture showed only a 19% loss, this is
explained by the release of metabolites into solution and subsequent
absorption
by the particulate Matter. After 3 days, DMH concentration in the
mixture was <1ppm, and radioactivity had decreased to 491 of its
original level, showing that metabolites were ultimately leaving the
system as carbon di x1de. By 19 days, 94% of the radioactivity had
been recovered as c rbcn dioxide. Only tract amounts of
radioactivity were ound to be volatile other than oarbo7l dioxide,
and these
appeared to be due to aerosols from the incubation mixture. when the
results were correG ed for known leakage of carbon dioxide in the
apparatus, a carbon balance was maintained. Under the test
conditions, DMH deg cedes rapidly without obvious toxic effects upon
the organisms.
25. Avian Acute 4 al LDso (Bobwhite quail): Sixty 27-week-old
Bobwhite quail -Were administered a single oral dose of DMH at dose
levels of 0, 464, 6 1, 1000, 1470 or 2150 mg/kg of body weight. The
No -Observed -Effect- evel (NOEL) was considered to be greater than
2150 mg/kg of body weight. The acute oral LD5a of DMH in Bobwhite
quail, was detQrmineq to be greater than 2150 mg/kg of body weight.
26. Avian Diatary LC50: DME was administered in the diet to 5-day-
old Mallard ducklin s at dose levels of 0, 312, 625, 1250, 2500 or
3000 ppm for five consecutive days followed by a three'day recovery
period. The dietary levels employed in this study did not produce
any signs of toxicity, mortality, decreased body weight, decreased
diet consumption or gross pathological findings. The No-Observed-
Bffect- Level (NOEL) was considered to be in excess of 5000 ppm. The
D-day acete dietary LC5a of DMH in Mallard ducklings was determined to
be in exce$$ of 500 ppm.
DMa was administers in the diet to 11-day-old Bobwhite quail at close
levels of 0, 312, 6 5, 1250, 2500 or 5000 ppm for 5 consecutive days

NOV. -25' 98 (WED) 15 : 06
a y
TEL:[phone] P.012
followed by a 3-day
this study did not z
decreased body weigi
pathological findinc
considered to be in
of DMH in Bobwhite c
27. Aerobic Aquat
dark conditions usi
ppm at 25°C. EXtrat
for 12.3 and 37.4�
volatile residues r
represented a mean
residues, respectiv
the Water or extras
the estimation of a
28. Anaerobic Aqt
metabolism study wa
conducted under dar
DMH
concentration was 1
the distribution of
months. The highes
accounted for 82.4%
residues in soil
accounted for 17.2%
volatile residues e
re4oveXy pezicd. The dietary levels employed in
roduce any signs of toxicity, mortality,
t, decreased diet consumption, or gross
S. The No -Observed -Effect -Level (NOEL) was
excess of 5000 ppm. The 8-day acute dietary LCs,
uail was determined to be in excess of 5000 ppm.
.c Metabolism: The study was conducted under
g sandy loam soil at a Imn concentration of 10
table residues and test water residues accounted
f total residues, respectively. Bound and
mained low over the course of the study. DMH
f 96.2 and 96.4% of water and extractable
1y. No degradation products were found in either
S. The stability of radio -labeled DHH precluded
half-life.
tic Metabolism: A 1-year anaerobic aquatic
conducted with radio -labeled MW. The study was
conditions using sandy loam soil at 25°C. The
ppm. No significant changes were observed in
radio -labeled residues from day 0 through 12
levels of activity were water soluble and
of the total residue at 12 months. Extractable
of the total at 12 months. Non -extractable and
ch accounted for less than 1% of the total
residues at 12 months. After 12 months of anaerobic aquatic
incubation, radio-1 baled DMH was stable and accounted for 87.1W of
the water soluble residues and 93.5� of the radio -labeled residues
extractable from tht sediment. No degradation of the DMH was
observed. Due to the stability of DMH under anaerobic conditions, a
half-life could not be estimated.
29. Aquatic Orgar
to evaluate the bio
sunfish. Oai ly }:iiQ
minimum quantifiabl
labeled DMH were al
measure the elimina
placed in clean wat
depuration period i
Neither an uptake r
(K2) could be calcu:
30. Aerobia soil
study was conducted
under dark conditio
conditions at WC.
months of aerobic i
-am Aceumulati.Qn: A 28-day study was Conducted
oncentration of radio -labeled DMH by'Hluegill
oncentration factors were all less than the
limits. Uptake tissue concentrations of radio-
o less than the minimum quantifiable limits. To
ion of radio -labeled DMH the test fish were
r for 14 days. Radio -analysis throughout the
dictated less than minimum quantifiable limits.
to constant.(K1) nor a depuration rate constant
ited or observed.
setabolism: A year long aerobic soil metabolism
with radio -labeled DME. The study was conducted
s on sandy loam soil under microbial active.
The DMH concentration was 10 ppm. After 12
cubation, 97.4% of the extractable residues were'

NOV. -25'98(WED) 15:06 TEL:[phone] P.013
parent compound. N degradation products were observed in the
extracts. The persstence of radio -labeled DMH on soil under aerobic
conditions precludeithe estimation of a half-life.
31. Li�ta(Nhing: Rac io-labeled DMS was used in a laboratory leaching
study. The radio -labeled DMH reGovererd from the replicate columns of
four types of soil I sandy loam, silt loam, loam and clay loam) were
determined to be 90 1�1, 104.2*, 100.7%, and 95.2t of the total
applied DMH, respectively.
32. Adsarption/De orption: Aqueous solutions of radio -labeled DMB
were equilibrated with four soil types. Analysis demonstrated that
90 to 951 of the radio -labeled DMH was accounted for in the.aqueaus
phase. No significant adsorption of DMH onto any of the soil types
was observed. The soil adsorption coefficient, ECd and Ka, are as
follows:
Soil
K
Koe
Sandy joaM
0.0508
10.2
Silt 16ar
0.0766
6.4
Loam
0.0925
51.0
Clay loam
0.130
5.8
The information s above is preseated in good faith aad has been derived from
sa,•,e; hag a &Md to Be 0. HCW= E.r, no warranty, expr*ao or imPLied is
PXtQ ded regardix. its ==Rcg or the z0oults to be obtaia.ed from its use. 9iaoe
Lbndftti6tYb of Use are and our eoutrol.all risks axe assumed by the nsea.
Fzvi.sed, 6 Februaxy 199q MM