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WI0300136_Application_20090624
State of North Carolina Department of Environment and Natural Resources Division of Water Quality APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection • Do not use this form for remediation systems that extract contaminated groundwater, treat it, and reinject the treated groundwater. • Submit TWO copies of the completed application and all attachments to the address on the last page of this form. • Any changes made to this form will result in the application package being returned. Application Number (to be completed by DW& W ZO300�.� I. GENERAL INFORMATION: 1. Applicant's Name (generally the responsible party): Sunoco Inc 2. Signing Official's Name: Devon Watts Title: Environmental Specialist 3. Mailing address of applicant: 203 South Falkenburg Road City: T State: FL Zip: 33619 Telephone number: (813) 654-7789 Fax number: (813) 657-7608 4. Property Owner's Name (if different from Applicant): S Cashion LLC 5. Property Owner's mailing 322 E Fisher St City: Salisbury State: NC Zip: 28144 6. Name and address of contact person who can answer questions about the proposed injection project: Name: Scott Dunsmuir Title: Operations Manager Company: EnviroTrac Ltd Address: 375 Winkler Drive; Suite E City: Alpharetta State: GA Zip: 30004 Telephone number: (770) 777-1711 Fax number:(770) 777-1766 Email Address: scottd@envirotrac.com II. PERMIT INFORMATION: 1. Project is: ® New ❑ Modification of existing permit ❑ Renewal of existing permit without modification ❑ Renewal of existing permit with modification 2. If this application is being submitted for renewal or modification to an existing permit, provide: existing permit number and the issuance date For renewal without modifications, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). For all renewals, you must submit a status report including monitoring results of all injection activities to date. Revised 8/07 UIC-50T RECEIVED I DENR / DWQ page 1 of 7 Aquifer Prntection Section JUN 2 4 2009 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection III. INCIDENT & FACILITY DATA A. FACILITY INFORMATION 1. Facility name: Former Country Cupboard Sunoco Inc 2. Complete physical address of the facility: 2010 Statesville Blvd City: Salisbury County: Rowan State: NC Zip: 28144 B. INCIDENT DESCRIPTION 1. Describe the source of the contamination: The apparent source of contamination at the site was identified as a combination of a leak from a gasoline UST that occurred in October 1986 and an aboveground spill of approximately 146 gallons of unleaded gasoline that occurred during refilling operations in June 1997. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Gasoline. 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? ❑x Yes If yes, list maximum measured separate phase thickness 2.24 feet ❑ No If no, list maximum concentration of total VOCs observed at site: ppb 4. Agency managing the contamination incident: X UST Section ❑ Superfund Section (including REC Program and DSCA sites) ❑ DWQ Aquifer Protection Section ❑ Solid Waste Section ❑ Hazardous Waste Section ❑ Other: 5. Incident managers name Dan Graham and phone number (704) 663-1699 6. Incident number or other site number assigned by the agency managing the contamination incident: , NCDENR Groundwater Incident #3519 C. PERMITS List all permits or construction approvals that have been issued for the facility or incident, including those not directly related to the proposed injection operation: 1. Hazardous Waste Management program permits under RCRA: 2. DWQ Non -Discharge or NPDES permits: 3. County or DEH subsurface wastewater disposal permits: 4. Other environmental permits required by state or federal law: Revised 8/07 UIC-51(5T Page 2 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection IV. INJECTION DATA A. INJECTION FLUID DATA 1. List all proposed injectants. NOTE. Any substance to be injected as a tracer or to promote in situ remediation must be reviewed by the Occupational and Environmental Epidemiology Section (GEES) of the Division of Public Health, Department of Health and Human Services. Review the list ofapproved iniectantsT or contact the UIC Program to determine if the injectants you are proposing have been reviewed by OEES. Injectant: Regenox Concentration at point of injection: Five Percent Injectant: Concentration at point of injection: Concentration at point of inj Inj Concentration at point of injection: Injectant: Concentration at point of injection: 2. Source of fluids used to dilute or chase the injectants listed above: ❑ None ❑x Municipal water supply ❑ Groundwater from private well or any well within 1/4 mile of injection site ❑ Air ❑ Other: 3. If any well within 1/4 mile of injection site, a private well, or surface water is to be used as the fluid source, supply the following information: a. Location/ID number of b. Depth of source: c. Formation: d. Rock/Sediment type: e. In Attachment C, provide a current, complete chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site. NOTE.- If contaminated groundwater is to be used as the dilution or chase fluid, this is not the proper permit application form. You must apply for a closed -loop groundwater remediation permit using application form GWRS. Revised 8/07 UIC-5I/5T Page 3 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection B. PROPOSED OPERATING PARAMETERS 1. Duration of Injection: Maximum number of separate injection events: Three Expected duration of each injection event: Eight Hours Expected duration between events (if more than one event): 30 days 2. Injection rate per well: One gallons per minute (gpm) 3. Total Injection volume: 200 gallons per day (gpd); 200 gallons per event (if separate events) 4. Injection pressure: Less than 20 pounds/square inch (psi) 5. Temperature at point of injection: 72 OF 6. Brieflv describe how the above parameters will be measured and controlled: Volume and flow will be measured using an in -line flow meter/totalizer. Pressure will be monitored with a pressure gauge mounted on the injection manifold. Flow and pressure will be controlled via a gate valve downstream from the pump, which can restrict the flow, and thereby lower the pressure. 7. Estimated hydraulic capacity of the well: Three . gpm C. INJECTION WELL CONSTRUCTION DATA 1. Injection will be via: ❑x Existing well(s) proposed for use as an injection well. Provide the data in (2) through (6) below to the best of your knowledge. ❑ Proposed well(s) to be constructed for use as an injection well. Provide the data in (2) through (6) below as proposed construction specifications. 2. Well Drilling Contractor's Name: Bore and Core NC Well Contractor Certification number: 763 3. Date to be constructed: October 1989 Number of borings: Four Approximate depth of each boring (feet): 35 4. Screened interval/Injection interval of injection wells: Depth: 7 to 35 feet below ground surface (if multiple intervals, indicate shallowest and deepest depth). 5. Well casing (N/A if injection is through direct push rods): Type: ❑x PVC ❑ Stainless steel ❑ Other:, Casing depth: to ft. 6. Grout (N/A if injection is through direct push rods): Type: ❑x Cement ❑ Bentonite ❑ Other: Grout depth: 1 to 4 ft. Revised 8/07 UIC-5I/5T Page 4 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection V. ATTACHMENTS Provide the following items as attachments with the given headings: A.' SITE HISTORY Provide a brief description of the site history including: (1) site usage historically and present, (2) origin of the contamination, (3) previous remedial action(s). NOTE: G.S. 89E-18 requires that any geologic plans, reports, or documents in which the performance is related to the public welfare or safeguarding of the environment be prepared by a licensed geologist or subordinate under his or her direction. G.S. 89E-13 requires that all drawings, reports, or documents involving geologic work which shall have been prepared or approved by a licensed geologist or a subordinate under his or her direction be signed and sealed by him or her. B. HYDROGEOLOGIC DESCRIPTION Provide a hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The hydrogeologic description shall include: (1) the regional geologic setting; (2) significant changes in lithology; (3) the hydraulic conductivity, transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test(s) used to determine these parameters; and (4) the depth to the mean seasonal high water table. C. INJECTION FLUID COMPOSITION Describe the chemical, physical, biological and radiological characteristics of each injectant. Attach the Material Safety Data Sheet (MSDS) for each injectant. If a private well or a well within 1/4 mile of the injection site is used as the source well, include chemical analysis of source fluid here. D. INJECTION RATIONALE Attach a brief description of the rationale for selecting the injectants and concentrations proposed for injection, including: (1) goals of the injection project; (2) a description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; and (3) summary results of modeling or testing performed to investigate the injectant's potential or susceptibility to change (biological, chemical or physical) in the subsurface. E. INJECTION PROCEDURE AND EQUIPMENT Provide a detailed description of all planned activities related to the proposed injection including but not limited to: (1) construction plans and materials; (2) operation procedures; (3) a detailed diagram of the surface and subsurface portions of the system; and (4) a planned injection schedule. F. MONITORING PLAN Provide a plan for monitoring the results of the injection, including: (1) a list of existing and proposed monitoring wells to be used; (2) a list of monitoring parameters and analytical methods to be used; and (3) a schedule for sampling to monitor the proposed injection. NOTE: The selected monitoring wells must be located so as to detect any movement of injection fluids, process by- products, or formation fluids outside the injection area or zone. The monitoring parameters should include the target contaminants as well as secondary or intermediate contaminants which may result from the injection and other parameters which may serve to indicate the progress of the intended reactions, such as pH, ORP, dissolved oxygen, and Revised 8/07 UIC-5I/5T Page 5 of 7 APPLICATION FOR PERNHT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells — In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection other electron acceptors and donors. The monitoring schedule should be consistent with the pace of the anticipated reactions and rate of transport of the injectants and contaminants. G. WELL DATA Provide a tabulation of data on all existing or abandoned wells within '/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's use (water supply, monitoring, etc), total depth, screened or open borehole depth interval, and well construction or abandonment record, if available. H. MAPS Attach the following scaled, site -specific maps: (1) Area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site. (2) Site map including: a. all property boundaries; b. all buildings within the property boundary; c. existing and proposed injection wells or well field(s) d. any existing sources of potential or known groundwater contamination, including waste storage, treatment or disposal systems within '/4 mile of the injection well or well system; e. all surface water bodies within'/4 mile of the injection well or. well system; and f. all existing or abandoned wells within'/4 mile of the injection well(s) which penetrate the proposed injection zone, including, but not limited to, monitoring wells and wells proposed for use as injection wells. (3) Potentiometric surface map(s) including: a. direction of groundwater movement b. existing and proposed monitoring wells c. existing and proposed injection wells (4) Contaminant plume map(s) including: a. the horizontal extent of the contaminant plume, including isoconcentration lines b. existing and proposed monitoring wells c. existing and proposed injection wells (5) Cross-section(s) to the known or projected depth of contamination, including: a. horizontal and vertical extent of the contaminant plume, including isoconcentration lines b. major changes in lithology Revised 8/07 UIC-5U5T Page 6 of 7 APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Type 5I Wells —In Situ Groundwater Remediation / Type 5T Wells — Tracer Injection VI, CERTIFICATION I, (printed name of sienine official) , hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit. Signature: Date: (o g 'O9 Title: Environmental Specialist, Southeast If authorized agent is acting on behayof the applicant, supply a letter signed by the applicant authorizing the above agent. VII. CONSENT OF PROPERTY OWNER (if the property is not owned by the applicant) ("Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the landowner, in the absence of contrary //agreement in writing.) LLC r �c(rcira . k , Oa-5GI;o,�'1 I, (printed name of oropem mvner) , as owner of the property on which the injection well(s) are to be constructed and operated, hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (Title 15A NCAC 2C .0200) Signature: ja (� _ Date: Title: I'm 6 f Revised 8/07 Submit TWO copies of the completed application package, including all attachments, to: UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone (919) 733-3221 RECEIVED I DENR / DWQ UIC-51/5T Aquifer Protection Section JUN 2 4 2009 Page 7 of 7 Sunoco, Inc. Assistant Secretary's Certificate In Lieu Of A Resolution 1, Michael L. Preston, the duly elected and qualified Assistant Secretary of Sunoco, Inc., a corporation organized under the laws of the Commonwealth of Pennsylvania ("Sunoco" or the "Company"), do hereby certify that- Sunoco's Management Control, Process Policy ("Policy") was duly adopted by a resolution of the Company's Board of Directors ("Board"), at a meeting duly called and held on March 2, 2006, at which a quorum was present and acting 'throughout; such resolution has not been amended, modified or revoked and remains in full force and effect. 2. Pursuant to the Delegation, of Authority provisions of said Policy, the Board has delegated to the Chief Executive Officer (the "CEO") the authority for stewardship responsibilities with respect . to the execution of access agreements, discharge monitoring reports, NPOES permits, notifications of release, deed notices, and permits on behalf of Sunocc, and/or any of its subsidiaries including but not limited to Sunoco, Inc. (R&M). 3. Further pursuant to the Delegation of Authority provisions of said Policy, at the discretion of the CEO, the CEO may delegate in writing all or portions of the authority granted to the CEO. 4, Under said Delegations of Authority, the CEO has delegated to Robert W. Owens, Senior Vice President, Marketing, the authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, deed notices, and permits on behalf of Sunoco and/or any of its subsidiaries including but not limited to Sunoco, Inc. (R&M), Further under said Delegations w.' Authority, Mr. Owens has delegated to Cynthia A. Archer, Vice President, Marketing and Development the authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, deed notices,, and permits on behalf of Sunoco and/or any of its subsidiaries including but not limited to Sunoco, Inc. ( R&M). 6. Further under said Delegations of Authority, ivIs. Archer has delegated to Richard E. Oswald, Director, Technical Services the authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, deed notices, and permits on behalf 04 Sunocc and/or any of its subsidiaries including but not limited to Sunoco, Inc. (R&Mj). 7, Further under said Delegations of Authority, Mr, Oswald has delegated to Joseph W, Roberts, Manager, Environmental Services, the authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, dead notices, and permits on behalf of Sunoco and/or any of its subsidiaries including but not limited to Sunoco, Inc. (R&M). 8- Further Linder said Delegations offAuthority, Joseph W. Roberts has delegated to Daniel T,'WPDAT,A,',PresioiilDele(-,aticjii AO-,�] -Wails 10.22.07.docc �0 P_ Shine, Senior Environmental Consultant the authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, deed notices, and permits on behalf of, Sunoco and/or any of its subsidiaries including but not limited to Sunoco, Inc. (R&N7). 9, Further under said Delegations of Authority, Daniel P. Shine has delegated to Devon Watts, Environmental Specialist the limited authority for stewardship responsibilities with respect to the execution of access agreements, discharge monitoring reports, NPDES permits, notifications of release, deed notices, and permits, on behalf of, Sunoco and/or any of its subsidiaries including but not limited to Sunoco, Inc, (R&M), 10. No action has been taken to amend or rescind the above Delegation of Authority to the CEO, Mr. Owens, Ms. Archer, Mr- Oswal4-,,Mr. Roberts, fkr:\Shine or Ms.,�hatts, Michael L. Preston, Assistaifit Secretary October 7"), 2007 Philadelphia, PA [Corporate Seal! T:'�WPDAI'-A%PretL-itnI)eleaatioji A%D_-) -Waus, I 0=,07.doc ATTACHMENTS A. SITE HISTORY Site Usage Historically and Present: The Country Cupboard Sunoco is a retail gasoline and convenience store located at the intersection of Jake Alexander Boulevard (Highway 601) and Statesville Boulevard (Highway 70) in Salisbury, North Carolina. The site is triangular in shape and approximately one-half acre in size. The 2,000 square foot convenience store occupies the western half of the property. The site has been occupied by a retail gasoline station for at least 47 years. The site is currently operating as a British Petroleum (BP) retail petroleum and convenience store. Origin of the Contamination: The apparent source of groundwater contamination at the site was identified as a combination of a leak from a gasoline UST that occurred in October 1986 and an aboveground spill of approximately 146 gallons of unleaded gasoline that occurred during refilling activities in June 1987. Previous Remedial Action(s): IT Corporation submitted a Corrective Action Plan (CAP) in August 1993. The CAP proposed the use of soil vapor extraction (SVE) to remediate the hydrocarbon compounds at the subject site. Following approval of the CAP, the SVE system was activated in April 1994. A CAP Addendum, submitted in October 1996, proposed the use of air sparging technology to address dissolved -phase petroleum hydrocarbons in groundwater. Following approval of the CAP Addendum, the air sparge system was activated on June 11, 1997. The AS/VE system is located at the rear of the convenience store building. The system consists of an air sparge compressor that injects compressed air beneath the zone of groundwater contamination through 10 air sparge wells (SP-1, SP-2, SP-3, SP-4, SP-5, SP-6, SP-7, SP-8, SP-9, and SP-10). The system also includes a vacuum extraction blower for recovering petroleum hydrocarbon vapors through nine vapor extraction wells (VP-1, VP-2, VP-3, VP4, VP-4, VP-5, MW-1, MW- 4, MW-7, and RW-1). The extracted vapors are discharged to the atmosphere. Through the end of August 2002, the AS/VE system was managed and operated by Groundwater & Environmental Services (GES). ATC acquired the. AS/VE system in September 2002. In October 2002, ATC personnel visited the site and noted that the system was not operating. ATC personnel were able to troubleshoot and restart the SVE blower; however, the air sparge unit required more extensive repair work. After replacing several parts and hiring a vendor to perform additional maintenance, ATC personnel restarted the air sparge unit in February 2003. The ASNE system has been shut down since June 2007 while remedial alternatives are being reviewed. B. HYDROGEOLOGIC DESCRIPTION Regional Geologic Setting: The Salisbury area is underlain by Paleozoic rocks of the Carolina Slate Belt, which consist of granite, granodiorite, quartz monzonite, and a mixture of granite and diorite. These rocks are generally fine to medium -grained and are easily weathered producing a sandy, clayey saprolite. The saprolite may range in thickness from a few feet to 50 feet. Significant changes in lithology: None observed. Hydraulic Conductivity, Transmissivity, and specific yield of the aquifer to be used for injection, including a description of the test used to determine these parameters: A rising head bail test was performed on well MW-3 in lieu of a groundwater pumping test to assess aquifer characteristics of the saprolite. The bail test was performed on well MW-3 by quickly bailing water from the well until the well was nearly dry. Bailing was stopped and rising water levels measured with an electric water level probe until the water level in the well had recovered to near static conditions. A log drawdown versus time recovery plot of water level data was prepared and evaluated using the Hvorslev method. The hydraulic conductivity (K) of the saprolite in the vicinity of well MW-3 determined from the bail test is approximately 1.34 gpd/ft3. This value is within the range for silt, i sandy silts, and clayey . silts, and clayey sands presented in the literature. Assuming a minimum saturated thickness (b) of the saprolite to be 50 feet, then by the relationship T = Kb, the minimum aquifer transmissivity (T) is approximately 67 gpd/ft. Depth to the Mean Seasonal High Water Table: Water levels have been measured at the site for several years, and it is apparent that he mean water level is approximately 32 feet below land surface. C. INJECTION FLUID COMPOSITION See attached RegenoxTm Brochure. MSDS Sheets for RegenoxTm Part A and Regenox Part B are also attached. D. INJECTION RATIONALE Based on review of historical groundwater analytical data and current site conditions, it appears that dissolved -phase constituents of concern are isolated to four monitoring well locations (MW-3, MW-5, MW-6, and VMW-7). Remediation of these areas via active mechanical remediation may not reduce the current concentrations to the groundwater governing standards applicable to this site (NCDENR Groundwater Quality 2L Standards) in an acceptable timeframe. As such, an advanced chemical oxidation technology is proposed to more rapidly and effectively destroy the targeted groundwater constituents. The chemical -oxidizing agent (RegenoxTM, which is on the NCDENR approved -chemical list) will be introduced to the subsurface as a slurry solution via direct -injection (geoprobe grout pump) using the above -referenced monitoring wells as injection points. Once introduced to the subsurface, efficient oxidation reactions will occur as a result of three mechanisms including surface mediated oxidation, direct oxidation, and free radical oxidation. RegenoXTM, which produces minimal heat, will continue to affect the oxidation process for up to 30 days on a single injection. E. INJECTION PROCEDURE AND EQUIPMENT Construction Plans and Materials: There will be no construction in order to complete the proposed injections. All necessary equipment will be mobilized to the site, the injection will take place, then all equipment will be removed from the site. Operation Procedures: The proposed injection wells, MW-3, MW-5, MW-6, and VMW- 7, will be measured for Depth to Water, Temperature, pH, Oxidation -Reduction Potential (ORP), Dissolved Oxygen (DO), Conductivity, and Alkalinity, then will be hooked up to a pumping system that will be used to inject the RegenoxTM compound. See diagram below: • ZEBRA CNAM ME n � Selected [L_ . __M °Vwft..:.t- R:.....».. Pumps •Rod String Is advanced by percussion Injection Probe Assembly Injection Chemical The pumping system will include a gate valve downstream from the pump for restricting the flow, which will, in turn, allow the operator to control the pressure. There will be a pressure gauge mounted on the injection manifold for monitoring pressure. The flow rate and total flow volume will be measured with an in -line flowmeter, similar to the type used for residential water supply lines. Water quality parameters (pH, Temp, Conductivity, DO, ORP, and Alkalinity) will be measured continuously throughout the injection, as well as at the conclusion of each event. Planned Injection Schedule: The first injection event will take place upon approval of this permit application, and the second and third injection events will take place at 30 day intervals afterward. F. MONITORING PLAN Monitoring of monitoring wells MW-3, MW-5, MW-6, and VMW-7 is proposed on a quarterly basis to assess the effectiveness of the application of Regeno)Jm. The first quarterly post -injection monitoring event will be conducted approximately 30 days subsequent to the date of injection. Data collected during the post -injection monitoring will be summarized and presented in a quarterly groundwater monitoring letter report. Groundwater samples will be analyzed by EPA Method 624 including BTEX, MTBE, DIPE, EDB, and Naphthalene. Additionally, pH, DO, temperature, ORP, and alkalinity measurements will be collected from the above -referenced monitoring wells during monitoring events subsequent to the injection. G. WELL DATA 2010 Statesville Boulevard Salisbury, North Carolina 28144 Sunoco Facility DUNS #0275-7383 NCDENR Groundwater Incident No. 3519 Well ID Total Depth (feet) Screened Interval (feet) Casing Diameter (inches) Well Type Notes MW-1 33.80 7-34 2 Typell MW-2 35.75 7-36 2 TypeII MW-3 37.10 7-37 2 Typell MW-4 34.65 7-35 2 Typell MW-5 35.65 7-36 2 Type II MW-6 33.80 3-34 2 Typell MW-7 35.40 7-35 2 Typell VMW-7 54.05 51-54 2 Type III MW-8 33.65 22-34 2 Typell MW-9 38.48 23-38 2 Typell MW-10 33.40 23-33 2 Ty e II VMW-11 80.00 75-80 2 Type III MW-13 45.00 20-45 2 Typell RW-12 40.00 10-40 6 Type II Harris Well 25.58 1 15-26 1 2 Type II Notes: 1. * Monitoring well MW-8 may have been destroyed by property construction. Potable Wells: Distance from Site Hydraulic City Water Potable Well Pro rt Owner feet Position Connection 1920 Statesville Blvd. Anger Family Properties 276 Upgradient No 170 Frances Street Salisbury, NC 28147- 9009 1924 Statesville Blvd. Susan Barber 360 Upgradient No 8965 Sherrils Ford Road Salisbury, NC 28147 2021 Woodleaf Road Dockins 224 Downgradient Yes 2029 Woodleaf Road Ann Miller Kieth 348 Downgradient Yes 810 Duckview Court Winston-Salem, NC 2740??? 2034 Woodleaf Road Harry L. Hipp, Jr. 360 Downgradient No 2035 Woodleaf Road Belle Realty Development 408 Downgradient No 301 N. Main Street P.O. Box 102 Salisbury, NC 28145 2036 Woodleaf Road John H. Hipp 432 Downgradient No 2036 Woodleaf Road Salisbury, NC 2037 Woodleaf Road Pinkston 480 Downgradient No 2101 Woodleaf Road Holly Leaf LLC 600 Downgradient No 407 Riverbend Drive Advance, NC 27006 2102 Woodleaf Road Harry L. Hipp, Jr. 504 Downgradient No 2104 Woodleaf Road George L. Hipp 516 Downgradient No 7. genm CHEMICAL OXIDATION REDEFINED... RegenOx'" is an advanced in situ chemical oxidation technology* designed to treat organic contaminants including high concentration source areas in the saturated and vadose zones PRODUCT FEATURES: Rapid and sustained oxidation of target compounds Easily applied with readily available equipment Destroys a broad range of contaminants More efficient than other solid oxidants Enhances subsequent bioremediation Avoids detrimental impacts to groundwater aquifers RegenOx product application HOW IT WORKS: RegenOx maximizes in situ performance using a solid alkaline oxidant that employs a sodium percarbonate complex with a multi -part catalytic formula. The product is delivered as two parts that are combined and injected into the subsurface using common drilling or direct -push equipment. Once in the subsurface, the combined product produces an effective oxidation reaction comparable to that of Fenton's Reagent without a violent exothermic reaction. RegenOx safely, effectively and rapidly destroys a wide range of contaminants in both soil and groundwater (Table 1). ACHIEVES RAPID OXIDATION VIA A NUMBER OF MECHANISMS RegenOx directly oxidizes contaminants while its unique catalytic complex generates a suite of highly charged, oxidative free radicals that are responsible for the rapid destruction of contaminants. The mechanisms by which RegenOx operates are: Surface- Mediated Oxidation: (see Figure 1 and description below) Direct Oxidation: C,Cl, + 2 Na,CO, • 3 H2O, + 2 H2O 2CO, + 4 NaCl + 4 H2O + 2 H,CO, Free Radical Oxidation: Figure 1. RegenOx" Surface -Mediated Oxidation — Perhydroxyl Radical (H0, •) — Hydroxyl Radical (OH-) — Superoxide Radical (0,•) Figure 1. Surface -Mediated Oxidation is responsible for the majority of RegenOx contaminant destruction. This process takes place in two stages. First, the RegenOx activator complex coats the subsurface. Second, the oxidizer complex and contaminant react with the activator complex surface destroying the contaminant. • Patent applied for Contaminai breakdown CO, and H,i Activator Complex (Surface) Cc, n:prfe,x ntaminant TV Regen From Mass Reduction to Bioremediation: RegenOx" is an effective and rapid contaminant mass reduction technology. A single injection will remove significant amounts of target contaminants from the subsurface. Strategies employing multiple Regenox injections coupled with follow-on accelerated bioremediation can be used to treat highly contaminated sites to regulatory closure. In fact, RegenOx was designed specifically to allow for a seamless transition to low-cost accelerated bioremediation using any of Regenesis controlled release compounds. Significant Longevity: RegenOx has been shown to destroy contaminants for periods of up to one month. Product Application Made Safe and Easy: RegenOx produces minimal heat and as with all oxidants proper health and safety procedures must be followed. The necessary safety guidance accompanies all shipments of RegenOx and additional resources are available on request. Through the use of readily available, highly mobile, direct -push equipment and an array of pumps, RegenOx has been designed to be as easy to install as other Regenesis products like ORC® and HRC•. Effective on a Wide Range of Contaminants: RegenOx has been rigorously tested in both the laboratory and the field on petroleum hydrocarbons (aliphatics and aromatics), gasoline oxygenates (e.g., MTBE and TAME), polyaromatic hydrocarbons (e.g., naphthalene and phenanthrene) and chlorinated hydrocarbons (e.g., PCE, TCE, TCA). Oxidant Effectiveness vs. Contaminant Type: Based on laboratory kinetic data, thermodynamic calculations, and literature reports. Oxidant Effectiveness Key: A = Short half life, low free energy (most energetically favored), most complete B = Intermediate half life, low free energy, intermediate degree of completion C = Intermediate half life, intermediate free energy, low degree of completion D = Long half life, high free energy (least favored), very low degree of completion RE+GENESIS Advanced Technologies for Groundwater Resources 1011 Calle Sombre: San Clemente %California 92673-6244 Tel: 949.,366-8000; Fax: 949366-8090. ww .regenesis.com Regen OX — Part A (Oxidizer Complex) Material Safety Data Sheet (MSDS) Last Revised: October 1, 2007 Section 1 — Supplier Information and Material Identification Supplier: PIN REGENESiS 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8000 Fax: 949.366.8090 E-mail: info@regenesis.com Chemical Description: A mixture of sodium percarbonate [2Na-)CO3.3H20f]1 sodium carbonate [Na,)C031, sodium silicate and silica gel. Chemical Family: Inorganic Chemicals Trade Name: Regen Ox — Part A (Oxidizer Complex) Product Use: Used to remediate contaminated soil and groundwater (environmental applications) Section 2 — Chemical Information/Other Designations CAS No. Chemical Percenta6e 15630-89-4 Sodium Percarbonate 60 -100 % 5968-11-6 Sodium Carbonate Monohydrate 10 — 30 % 7699-11-6 Silicic Acid < 1 % 63231-67-4 Silica Gel < 1 % Section 3 — Physical Data Form: Powder Color: White Odor: Odorless Melting Point: NA Boiling Point: NA RegenOx — Part A Section 3 — Physical Data (cont) Flammability/Flash Point: NA Vapor Pressure: NA Bulk Density: 0.9 — 1.2 g/cm3 Solubility: Min 14.5g/100g water @ 20 °C Viscosity: NA pH (3% solution): 10.5 Decomposition Self -accelerating decomposition with oxygen release starts Temperature: at 50 °C. Section 4 — Reactivity Data Stability: Stable under normal conditions Conditions to Acids, bases, salts of heavy metals, reducing agents, and Avoid/Incompatibility: flammable substances Hazardous Decomposition Oxygen. Contamination with many substances will cause Products: decomposition. The rate of decomposition increases with increasing temperature and may be very vigorous with rapid generation of oxygen and steam. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: No Unlisted Substance: Yes SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: WHMIS Classification: C, D2B Canadian Domestic Appears Substance List: J:\Operations\MSDS\Regenox Page 2 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Oxidizer. Store in a cool, well ventilated area away from all sources of ignition and out of the direct sunlight. Store in a dry location away from heat and in temperatures less than 40 *C. Keep away from incompatible materials and keep lids tightly closed. Do not store in improperly labeled containers. Protect from moisture. Do not store near combustible materials. Keep containers well sealed. Store separately from reducing materials. Avoid contamination which may lead to decomposition. Handling: Avoid contact with eyes, skin and clothing. Use with adequate ventilation. Do not swallow. Avoid breathing vapors, mists or dust. Do not eat, drink or smoke in the work area. Label containers and keep them tightly closed when not in use. Wash hands thoroughly after handling. Personal Protective Equipment (PPE) Engineering Controls: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Avoid creating dust or mists. Maintain adequate ventilation at all times. Do not use in confined areas. Keep levels below recommended exposure limits. To determine actual exposure limits, monitoring should be performed on a routine basis. Respiratory Protection: For many conditions, no respiratory protection is necessary; however, in dusty or unknown conditions or when exposures exceed limit values a NIOSH approved respirator should be used. Hand Protection: Wear chemical resistant gloves (neoprene, rubber, or PVC). J:\Operations\MSDS\Regenox Page 3 RegenOx — Part A Section 6 — Protective Measures, Storage and Handling (cont) Eye Protection: Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Skin Protection: Try to avoid skin contact with this product. Chemical resistant gloves (neoprene, PVC or rubber) and protective clothing should be worn during use. Other: Eye wash station. Protection Against Fire & Product is non -explosive. In case of fire, evacuate all non - Explosion: essential personnel, wear protective clothing and a self- contained breathing apparatus, stay upwind of fire, and use water to spray cool fire -exposed containers. Section 7 — Hazards Identification Potential Health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Eye Contact: Causes irritation, redness and pain. Skin Contact: Causes slight irritation. Ingestion: May be harmful if swallowed (vomiting and diarrhea). Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage: Eliminate all ignition sources. Evacuate unprotected personnel and never exceed any occupational exposure limit. Shovel or sweep spilt material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to the inventory. Extinguishing Media: Water First Aid Eye Contact: Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Inhalation: Remove affected person to fresh air. Seek medical attention if the effects persist. Ingestion: If the individual is conscious and not convulsing, give two- four cups of water to dilute the chemical and seek medical attention immediately. Do Not induce vomiting. J:\Operations\MSDS\Regenox Page 4 RegenOx — Part A Section 8 — Measures in Case of Accidents and Fire (cont) Skin Contact: Wash affected areas with soap and a mild detergent and large amounts of water. Section 9 — Accidental Release Measures Precautions: Cleanup Methods: Shovel or sweep spilt material into plastic bags or vented containers for disposal. Do not return spilled or contaminated material to the inventory. Section 10 — Information on Toxicology Toxicity Data LD50 Oral (rat): 2,400 mg/kg LD50 Dermal (rabbit): Min 2,000 mg/kg LD50 Inhalation (rat): Min 4,580 mg/kg Section 11— Information on Ecology Ecology Data Ecotoxicological NA Information: Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Dispose of in an approved waste facility operated by an authorized contactor in compliance with local regulations. Package (Pail) Treatment: The empty and clean containers are to be recycled or disposed of in conformity with local regulations. J:\Operations\MSDS\Regenox Page 5 r Section 13 — Shipping/Transport Information RegenOx — Part A D.O.T. Shipping Name: Oxidizing Solid, N.O.S. [A mixture of sodium percarbonate [2Na-)CO3-3H2O-], sodium carbonate [Na2CO3], sodium silicate and silica gel.] UN Number: 1479 Hazard Class: 5.1 Labels: 5.1 (Oxidizer) Packaging Group: III HMIS® Rating Section 14 — Other Information Health — 1 (slight) Flammability — 0 (none) Reactivity — 1 (slight) Lab PPE — goggles, gloves, and lab coat HMIS® is a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but -is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. J:\Operations\MSDS\Regenox Page 6 Regen OX — Part B (Activator Complex) Material Safety Data Sheet (MSDS) Last Revised: November 7, 2005 Section I — Supplier Information and Material Identification Supplier: REGENESIS 1011 Calle Sombra San Clemente, CA 92673 Telephone: 949.366.8 000 Fax: 949.366.8090 E-mail: info@regenesis.com Chemical Description: A mixture of sodium silicate solution, silica gel and ferrous sulfate Chemical Family: Inorganic Chemicals Trade Name: Regen Ox — Part B (Activator Complex) Product Use: Used for environmental remediation of contaminated soils and.groundwater Section 2 — Chemical Information/Other Designations CAS No. Chemical 1344-09-8 Silicic Acid, Sodium Salt, Sodium Silicate 63231-67-4 Silica Gel 7720-78-7 Ferrous Sulfate 7732-18-5 Water Section 3 — Physical Data Form: Liquid Color: Blue/Green Odor: Odorless Melting Point: NA Boiling Point: NA Flammability/Flash Point: - NA Vapor Pressure: NA RegenOx — Part B Section 3 — Physical Data ( cont) Specific Gravity Solubility: Viscosity: pH (3% solution): Hazardous Decomposition .Products: 1.39 g/cm3 Miscible NA 11 Oxides of carbon and silicon may be formed when heated to decomposition. Section 4 — Reactivity Data Stability: Stable under normal conditions. Conditions to Avoid: None. Incompatibility: Avoid hydrogen fluoride, fluorine, oxygen difluoride, chlorine trifluoride, strong acids, strong bases, oxidizers, aluminum, fiberglass, copper, brass, zinc, and galvanized containers. Section 5 — Regulations TSCA Inventory Listed: Yes CERCLA Hazardous Substance (40 CFR Part 302) Listed Substance: No Unlisted Substance: Yes SARA, Title III, Sections 302/303 (40 CFR Part 355) — Emergency Planning and Notification Extremely Hazardous No Substance: SARA, Title III, Sections 311/312 (40 CFR Part 370) — Hazardous Chemical Reporting: Community Right -To -Know Hazard Category: Acute SARA, Title III, Sections 313 (40 CFR Part 372) — Toxic Chemical Release Reporting: Community Right -To -Know Extremely Hazardous No Substance: Page 2 RegenOx — Part B Section 6 — Protective Measures, Storage and Handling Technical Protective Measures Storage: Keep in a tightly closed container (steel or plastic) and store in a cool, well ventilated area away from all incompatible materials (acids, reactive metals, and ammonium salts). Store in a dry location away from heat and in temperatures less than 242C. Do not store in aluminum, fiberglass, copper, brass, zinc or galvanized containers. Handling: Avoid contact with eyes, skin and clothing. Avoid breathing spray mist. Use with adequate ventilation. Do not use product if it is brownish -yellow in color. Personal Protective Equipment (PPE) Engineering Controls: General room ventilation is required if used indoors. Local exhaust ventilation, process enclosures or other engineering controls may be needed to maintain airborne levels below recommended exposure limits. Safety shower and eyewash station should be within direct access. Respiratory Protection: Use NIOSH-approved dust and mist respirator where spray mist exists. Respirators should be used in accordance with 29 CFR 1910.134. Hand Protection: Wear chemical resistant gloves. Eye Protection:. Wear chemical safety goggles. A full face shield may be worn in lieu of safety goggles. Skin Protection: Try to avoid skin contact with this product. Gloves and protective clothing should be worn during use. Other: Protection Against Fire & Product is non -explosive and non-combustible. Explosion: Page 3 RegenOx — Part B Section 7 — hazards Identification Potential health Effects Inhalation: Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath, and irritations to mucous membranes, nose and throat. Eye Contact: Causes irritation, redness and pain. Skin Contact: Causes irritation. Symptoms include redness, itching and pain. Ingestion: May cause irritation to mouth, esophagus, and stomach. Section 8 — Measures in Case of Accidents and Fire After Spillage/Leakage Mop up and neutralize liquid, then discharge to sewer in (small): accordance with local, state and federal regulations. After Spillage/Leakage Keep unnecessary personnel away; isolate hazard area (large): and do not allow entrance into the affected area. Do not touch or walk through spilled material. Stop leak if possible without risking injury. Prevent runoff from entering into storm sewers and ditches that lead to natural waterways. Isolate the material if at all possible. Sand or earth may be used to contain the spill. If containment is not possible, neutralize the contaminated area and flush with large quantities of water. Extinguishing Media: Material is compatible with all extinguishing media. Further Information: First Aid Eye Contact: Flush eyes with running water for at least 15 minutes with eyelids held open. Seek a specialist. Inhalation: Remove affected person to fresh air. Give artificial respiration if individual is not breathing. If breathing is difficult, give oxygen. Seek medical attention if the effects persist. Ingestion: If the individual is conscious and not convulsing, give two-four cups of water to dilute the chemical and seek medical attention immediately. DO NOT induce vomiting. Skin Contact: Wash affected areas with soap and a mild detergent and large amounts of water. Remove contaminated clothing and shoes. Page 4 Section 9 — Accidental Release Measures Precautions: RegenOx — Part B PPE: Wear chemical goggles, body -covering protective clothing, chemical resistant gloves, and rubber boots (see Section 6). Environmental hazards: Sinks and mixes with water. High pH of this material may be harmful to aquatic life. Only water will evaporate from a spill of this material. Cleanup Methods: Pick-up and place in an appropriate container for reclamation or disposal. US regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. Section 10 — Information on Toxicology Toxicity Data Sodium Silicate: When tested for primary eye irritation potential according to OECD Guidelines, Section 405, a similar sodium silicate solution produced corneal, iridal and conjunctival irritation. Some eye irritation was still present 14 days after treatment, although the average primary irritation score has declined from 29.7 after 1 day to 4.0 after 14 days. When tested for primary skin irritation potential, a similar sodium silicate solution produced irritation with a primary irritation index of 3 to abraded skin and 0 to intact skin. Human experience confirms that irritation occurs when sodium silicates get on clothes at the collar, cuffs, or other areas where abrasion may exist. The acute oral toxicity of this product has not been tested. Ferrous Sulfate: LD50 Oral (rat): 319 mg/kg not.a suspected carcinogen. Page 5 RegenOx — Part B Section 11— Information on Ecology Ecology Data Ecotoxicological Based on 100% solid sodium silicate, a 96 hour median Information: tolerance for fish of 2,320 mg/l; a 96 hour median tolerance for water fleas of 247 mg/L; a 96 hour median tolerance for snail eggs of 632 mg/L; and a 96 hour median tolerance for Amphipoda of 160 mg/L. Section 12 — Disposal Considerations Waste Disposal Method Waste Treatment: Neutralize and landfill solids in an approved waste facility operated by an authorized contactor in compliance with local regulations. Package (Pail) Treatment: The empty and clean containers are to be recycled or disposed of in conformity with local regulations. Section 13 — Shipping/Transport Information D.O.T. This product is not regulated as a hazardous material so there are no restrictions. Section 14 — Other Information HMIS® Rating Health — 2 (moderate) Reactivity — 0 (none) Flammability — 0 (none) Lab PPE — goggles, Contact — 1 (slight) gloves, and lab coat HMIS® is a registered trademark of the National Painting and Coating Association. Section 15 — Further Information The information contained in this document is the best available to the supplier at the time of writing, but is provided without warranty of any kind. Some possible hazards have been determined by analogy to similar classes of material. The items. in this document are subject to change and clarification as more information become available. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Page 6 MW-9 MW-8 (DESTROYED) STRIP RESIDENTIAL MALL U7 GRASS lot, SP-9 0 °M— VP-3 O PORKEY'S OSP-10 arm a, HARRIS 8BQ \ KEROSENE '4S/J RESTAOD UORANT WELL DISPENSER EXXON MW 7 STATION � MW-4 Sp-1 . W-7 VP-4 � OSP-7 ®UST MW-11 0 AREA O SP-6 S MW MW-3� � MW-13 ®VP— —5 SP-2 O RW-12® GRASS SP-3 SP-4 O O CANOPY P ®MW-1 nTELEPHONE & SP-5 ASP-8 d - SIGN GRASS STATESVILLE BOULEVARD LEGEND: O CATCH BASIN 0 UTILITY POLE MONITORING WELL (TYPE 1) MONITORING WELL (TYPE 2) FORMER MONITORING WELL O AIR SPARGE WELL ® SOIL VAPOR EXTRACTION WELL = .hjaf,-n we47 'HALT RKING THEA 0 1s Fr. FORMER COUNTRY CUPBOARD SUNOCO FIGURE # "� srrxaea 2010 STATESVILLE BOULEVARD SITE PLAN 2 a7s wu«�n surtE E;� r»i�c nacv 3000� REVISION DATE rt�nseo BY: es SALISBURY NORTH CAROLINA PHONE: �777-171 Fi11f: 777-17" DUNE 22, 2009 1' � 15 FEET , STRIP MALL MW-9 MW-8 (DESTROYED) RESIDENTIAL GRASS rn � rn Q, 01 SP-9. ®VP-3 POBBQ .S GSP-10� �04 HARRIS °r KEROSENE AS// RESTAFOOD URANT WELL p DISPENSER EXXON 66.6s MW 7 , kW-44 ` STATION SP-1 W-7 VP-4 1 A7.42 % MW-11 665.66* UST AR ' SP-7 \ SP-6 �667.2'1 VP- s MW-3� MW-13 W 04 667.20 667.43 GRASS SP-2 SOP-3 RW-12 ® ' V 5 \ SP-4 O O CANOPY ®W-1 PHOi4E SP-5 . SP-8 \ S STATESVILLE LEGEND: Eq CATCH BASIN 0 UTILITY POLE MONITORING WELL (TYPE 1) MONITORING WELL (TYPE 2) FORMER MONITORING WELL AIR SPARGE WELL ® SOIL VAPOR EXTRACTION WELL INFERRED GROUNDWATER FLOW DIRECTION WATER —TABLE ELEVATION (feet) WELL NOT USED FOR CONTOURING CONTOUR INTERVAL = 0.25 FT. BOULEVARD 'HALT RKING THEA SIGN GRASS �� me �a 1rIt.aex _ DM wEE.mI S�NCE� GEOFM �4 Man LC/�7OT/_T7_-1711 FA% 0 777-1768 a 15 FT. FORMER COUNTRY CUPBOARD SUNOCO suaraco 2010 STATESVILLE BOULEVARD SALISBURY NORTH CAROLINA GROUNDWATER ELEVATION CONTOUR MAP NOVEMBER 24, 2008 FIGURE # 3 REVISION DATE: DUNE 22, 2009 SCALE: 1' 75 FEET R�� gy_ � MW-9 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 EDB ug/L <1 SEAFOOD RESTAURANT HARRIS WELL Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 EDB ug/L <1 LEGEND: EMI CATCH BASIN 0 UTILITY POLE MONITORING WELL (TYPE 1) MONITORING WELL (TYPE 2) FORMER MONITORING WELL E) AIR SPARGE WELL ® SOIL VAPOR EXTRACTION WELL VM1 Ber Toll Eth Tot, Toti MTE EDE VMW-7 Benzene ug/L 1,200 Toluene ug/L 1,100 ra6..i6------ A -70n MW-9 MW-8 MW-7 Benzene ug/L <5 Toluene ug/L <5 Ethylbenzene ug/L <5 MTBE ug/L <1 EDB ug/L <1 <0.9 <0.8 ig/L <0.8 ug/L <0.9 /L NO <1 <1 <5 24 I/L <5 g/L 35 L 59 5 <5 <0.9 <0.8 g/L <0.8 ig/L <0.9 L ND <1 <1 MW-3 Benzene ug/L 440 Toluene ug/L 6,500 Ethylbenzene ug/L 1,600 Total Xylenes ug/L 9,600 Total BTEX ug/L 18,140 MTBE ug/L 280 EDB ug/L 28 ° 15FT. FORMER COUNTRY CUPBOARD SUNOCO CHEMICALS OF CONCERN IN GROUNDWATER FIGURE # E 4�rOimc REVISION DATE SCALE: 2010 STATESVILLE BOULEVARD /) 375 wINIQER �� urNastr` coRCU 30004 REVISED BY: es MAY 28, 2009 T FIIONE (no777-1711 Fix: cn�7n-1788 JULY 22, 2009 1• - 15 FEET SALISBURY, NORTH CAROLINA MW-9 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 HARR Benz, Tolue Ethyll Total Total MTBE 1,2 EDB Terto LEGEND: ® MONITORING WELL LOCATION (TYPE 1) $ MONITORING WELL LOCATION (TYPE 2) ®SOIL VAPOR EXTRACTION WELL o AIR SPARGE WELL o POWER POLE — — OVERHEAD ELECTRICAL LINE -- — UNDERGROUND ELECTRIC LINE — — NATURAL GAS LINE — UNDERGROUND TELEPHONE LINE PHONE., VMW-7 Benzene ug/L 1,600 Toluene ug/L 1.600 Ethylbenzene ug/L 740 Total Xylenes ug/L 4.300 I Tertachloroethene ug/L I <1 0 10 Fr. 20 REVISION DATE SCALE: REVISED BY: TB JANUARY 9, 2009 ,• _ 20 FEET MW-7 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDS ug/L <1 Tertachloroethene ug/L <1 MW-5 Benzene ug/L 39 Toluene ug/L 1 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L 40 MTBE ug/L 310 1,2—Dichloroethane ug/L 24 EDB ug/L <1 Tertachloroethene ug/L <1 MYr- I u Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEY ug/L ND MTBE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L <1 FORMER COUNTRY CUPBOARD SUNOCO 2010 STATESVILLE BOULEVARD SALISBURY, NORTH CA.ROLINA MW-4 Benzene ug/L <0.9 Toluene ug/L <0.8 Ethylbenzene ug/L <0.8 Total Xylenes ug/L <0.9 Total BTEX ug/L NO MTHE ug/L <1 1,2—Dichloroethane ug/L <1 EDB ug/L <1 Tertachloroethene ug/L <1 ug/L <0.9 ug/L <0.8 e ug/L <0.8 rs ug/L <0.9 ug/L ND /L <1 oethane ug/L <1 'L <1 ethene ug/L 110 CHEMICALS OF CONCERN IN GROUNDWATER Nov. :7-O-OF RGURE # 4 RESTAURANT S � . �G G HARRIS 0J� ASPHALT WELL r PARKING A vMv rDRAW-/ dWf � STORAGE r' TANK AREA \r \ STORE \\ � 11 TMW-4 \ MW-13 _2 A' MW-3 MW-1 STATESVILLE I BLVD. ASPH PARK MW-10 B' �1 RW-12 AREA T MW-6 0 r&-MJ LEGEND + MONITORING WELL o VERTICAL DEFINITION - MONITORING WELL RECOVERY WELL tN 100 0 SCALE FEET SOURCE: JAMES L. HAINES - 6/3/93 SURVEY 1000 PERIMETER PARK DR 0019 GROUNDWATER SUITE I yORRISNLLE. NC 27560 00 TECHNOLOGY (919) 161-2227 REV. NO.: ORAMN DATE: ACAD FILE: 86931 5398-SIT LINES OF GEOLOGIC CROSS -SECTIONS A -A' & B-B' CLIENT: PM: SUN COMPANY, INC. LOCATION: PE RG: 2001 WOODLEAF RD. SALISBURY, NC DESIGNED: DETAILED: PROJECT NO.: FIGURE: TLW DKP 053245398 4 . - . j � i.�-- / ���•-.,ram-.�%�rr«r►��io%��o� tea•-•��•o�Oc' �i E► . ri of ei ri ri of .:. -- rI`.I F•a� r%=•��ri�'�•rl� ���ir�roi��r�ir�roioi rl�.j r`, WWI'IO�OIOI ��OI�.� IOI��OII� rIp;•�0I0I: t OIOI •IOI:` Ip� •��OI '� a�: �' gIArw -W'V � e�i'r�rIIJ���iI0I0Iw�. IAV.t„VI.di Wd Iw a�I.►. r l ,rIJ�rI Iw rI.►.. a% io�oir��i��or.Ioioi .�� s► - l�' rC1' r,�ri�►.roirio�o�,,o���`ro�,e1oio�o • ► �0��'Ijjs'IE�OIrI .cll • ��I�ojO�I�• IMId1U-14w, OI`w'�OI�J�Is'�I��J� - ;OQj��I�jOI Ov�jr'�Oj101�j�OI���O ... O�>,�OIrI rIOI irr �ir�ai�rr�r�oi��: r�rl I''6J rI�.I`��yOI�yO;.IOIpIO��.IOI�.,GOI�. �,.��.r�i�.re►soreiorrio�rior riri ♦ `'JI `IOI r�r� �O IIrI �'IOI `' `ri j� • rta� vIO1rI01 I rIO �a;I•�j�OI����a' . PWAP _s�Iw� ry � Olwi �!I..i a��..i �I..i..Iwi s�I�►i �I.�� �I�.� s�I�►� �!I.�� �� 645 640 635 630 625 620 GRAVEL (DGA) ® CLAY ® CLAYEY SILT PSH PHASE —SEPARATED HYDROCARBONS 0 SILTY SAND (FILL) 1171, SILT ® SAPROLITE BDL BELOW DETECTION LIMI NS NOT SAMPLED IWELL SCREEN (18,540) TOTAL DISSOLVED BTEX CONCENTRATION (ug/L) TOTAL DISSOLVED OCONCENTRATIONBTEX CONTOUR (ug/L) T WATER —TABLE ELEVATION (feet) VERTICAL SCALE AS SHOWN 100 0 100 ti HORIZONTAL SCALE IN FEET SOURCE: WELL LOO INFORMATION 1000 PERIMETER PART( DI :101 GROUNDWATER SUITE IAlE, NC 27sso 3E TECNHNOgLOGY (919) 4B7-2 NC Ev. No.: DRAB/ 11 /9 ACAD FILE: 5398-XAA GEOLOGIC CROSS-SECTION A -A' UENT: Pi SUN COMPANY, INC. 2001 WOODLEAF DR. SALISBURY, NC IGNED: DETAILED: PROJEC NO.: FIGURE TLW FKP 053245398 . s 2104 2161 \ 2102 j HOLLY AVENUE 2036 2037 / \ 2034 2035 2029 \ �\ R04D \ 2021 \ /' 2012 > �O srgr � SITE � ESttk, BCV C l p (Nwy 70) i� i O WATER TOWER 1924 / 1920 I LEGEND PREVAILING GROUNDWATER FLOW DIRECTION (JUNE 1996) NOTE: THE BOLD NUMBERS SHOWN ON THE PROPERTY PLOTS INDICATE PROPERTIES WITH PRIVATE POTABLE WATER WELLS. TABLE 3 PRESENTS THE NAMES AND ADDRESSES OF THE TWELVE (12) PROPERTY OWNERS LOCATED WITHIN 1500 FEET OF THE SITE. 100 200 SCALE FEET SOURCE: WITHERS h RAVENEL ENGINEERING, INC. (I HCDENR North Carolina Department of Environment and Beverly Eaves Perdue Governor Division of Water Quality Coleen H. Sullins Director October 12, 2009 Devon Watts Sunoco, Inc. 203 South Falkenburg Road Tampa, FL 33619 Ref: Issuance of Injection Permit WI0300136 Country Cupboard Salisbury, Rowan County, NC Dear Ms. Watts: Natural Resources Dee Freeman Secretary In accordance with the application received on June 24, 2009, and the supporting data received October 2, 2009, we are forwarding permit number WI0300136. This permit is to inject RegenOx to remediate groundwater contaminated with gasoline at the facility referenced above. This permit shall be effective from the date of issuance until September 30, 2011, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VH = MONITORING AND REPORTING REQUIREMENTS. Please note that some of the monitoring requirements have changed from your application Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at 919-715-6164 or thomas.slusser@ncdenr.Szov if you have any questions about your permit. cc: Andrew Pitner, Mooresville Regional Office Scott Dunsmuir, EnviroTrac, Ltd. WI030.0136 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 Phone: 919-733-3221 1 FAX 1: 919-715-0588; FAX 2: 919-715-60481 Customer Service: 1-877-623-6748 Internet: www.ncwaterouality.org An Equal Opportunity \ Affirmative Action Employer Be4wr-vz t Regards, Thomas Slusser, L.G. Program Manager Underground Injection Control Program One Nortb Carolina Na'rally Slusser, Thomas From: John Coyne Dohnc@envirotrac.com] Sent: Friday, October 02, 2009 4:01 PM To: Slusser, Thomas; Schutte, Maria Subject: Salisbury UIC permit application Attachments: Water Supply Well Data —Updated 2009.xis; ET Salisbury -Area Map 1 to 150.pdf Hello Maria and Thomas, Over the last several weeks we have been conducting investigations, interviews, research, and collecting data about the properties surrounding 2100 Statesville Boulevard in Salisbury, NC. Specifically, yesterday I completed.a door-to-door survey of residents. I have attached an updated Water Supply Well Table which shows all of the Potable Wells around the site. I have also attached an updated Water Supply Well Location Map. You will note that there are only three wells inside_ of the 1000' radius that are being used for drinking water (or being used at all for that matter).' The nearest of which being on the David Tod Hipp property located at 2034 Woodleaf Road. That property is 722' from our site. The results of our investigations revealed that there have been no changes since the last Receptor Survey was conducted by the previous consultant in July 2005. All of the properties which were on city water then are still on city water, and all of the properties that were on private wells are still on private wells. All of the properties that are cross -gradient or up -gradient within the 1000' radius are commercial in nature, and are all believed to be on city water. There were no wells found in any other area of the 1000' radius of the site. It should be noted that the seven properties that still use wells as their water source do have access to city water. There is a water main that runs down Woodleaf Road; those property owners simply choose not to be connected to the city water lines. None of the property owners interviewed knew exactly how old or how deep their wells were. We included the years that the homes were built on our table of information, however, because it stands to reason that the homes all had water after they were built, and conversely, it's unlikely that the wells were installed long before the homes were built, as there would be no rationale for that. As for the depths, we heard guesses from property owners ranging from 50 feet to 150 feet, but none of that is known or can be proved. Similarly, there was no knowledge of screen depths or screened intervals. Hope this information helps with the issuance of the UIC permit. Please let us know if there's any other information needed, or if you have any more questions or concerns. John Coyne EnviroTrac Ltd 375 Winkler Drive; Suite E Alpharetta, GA 30004 (770) 777-1711 1 TABLE 1 Water Supply Well Data Former County Cupboard Sunoco, Inc. Facility 2010 Statesville Boulevard Salisbury, North Carolina Sunoco Facility DUNS #0275-7383 NCDENR Groundwater Incident No. 3519 Distancefrom 'Hydraulic City Water Year Home Potable --Well Property Owner Site feet Position Connection Built 2021 Woodleaf Road James E. Dockins Jr. Yes 2021 Woodleaf Road 372 Downgradient Water supply well 1948 Salisbury, NC 28147 is inactive (does not produce water 2029 Woodleaf Road Ann Miller Keith Yes 3331 E. Kingsfield Road 590 Downgradient Water line for 1949 Pensacola, FL 32514 supply well has been disconnected 2034 Woodleaf Road David Tod Hipp 2034 Woodleaf Road 722 Downgradient No 1971 Salisbury, NC 28147 704 278-3253 2035 Woodleaf Road Michael T. and Rhonda B. Hollowa 2035 Woodleaf Road 737 Downgradient No 1949 Salisbury, NC 28147 704 637-2099 2036 Woodleaf Road John H. Hipp 2036 Woodleaf Road 876 Downgradient No 1965 Salisbury, NC 28147 704 636-2509 2037 Woodleaf Road Piedmont Land Developers, LLC 854 Valley Road 857 Downgradient No 1949 Mocksville, NC 27028 336 751-7007 2101 Woodleaf Road Holly Leaf LLC 407 Riverbend Drive 1194 Downgradient No 1940 Advance, NC 27006 336 998-2787 2102 Woodleaf Road Harry L. Hipp, Jr. 2102 Woodleaf Road 1035 Downgradient No 1973 Salisbury, NC 28147 704 633-2958 2104 Woodleaf Road George L. Hipp 2104 Woodleaf Road 1184 Downgradient No 1973 Salisbury, NC 28147 704 636-0256 "All of the above information was verified on October 1, 2009 by conducting a door-to-door survey"" I i I I i i i r / I r I II r / I HOLLY LEAF. LLC (2101) WATER LINE FROM THE WATER SUPPLY WELL TO THE HOUSE HAS BEEN DISCONNECTED ANN MILLER P \\ KEITH \ ` (2029) HARRY L HIPP JR. ` (2102) , \ \\\ (VAMM,/HILDA H. `\ \� SHAVER (2012) /> / I SITE ` EXXON _JE GLARIA I�N' STATE IUHEI CHURCH' FIDELITY BANK PROPERTIES << cvs (908) PHARMACY LEGEND: �IBA�RBEHR AI iI PHAR I ® ---- PROPERTY BOUNDARY ', 1�-- �- _ KELLY & I © WATER SUPPLY WELL �� ` APPLIANCES. / SAMCo I ® CITY WATER INC. PROPERTIES / / I � McDONALD'S / RESTAURANT / / \ / / `\ / • BANK o ,so Fr. FORMER COUNTRY CUPBOARD SUNOCO FIGURE # �virO rac REVISION DATE: SCALE :®� 2010 STATESVILLE BOULEVARD WATER SUPPLY WELL LOCATION MAP 3 375 PHONE: (77o m ii i A`F,v" no'�m 1786� s/e/os 1 • = 1 so FEET REVISED e�` Bs - SALI S B U RY, NORTH CAR O LI N A Slusser, Thomas , From: John Coyne Bohnc@envirotrac.com] Sent: Tuesday, July 21, 2009 2:05 PM To: Schutte, Maria Cc: Slusser, Thomas Subject: RE: W10300136 - Former Country Cupboard Sunoco, Inc. Attachments: Salisbury Potable well table.pdf Hi Maria, I've attached the table that should've accompanied our Figure 10 in the UIC Permit application. This is the most recent well survey that we have and it is correct to the best of our knowledge. Let us know if there's anything else we can provide you in order to get this application approved. Thanks! John From: Schutte, Maria [mailto:maria.schutte@ncdenr.gov] Sent: Monday, July 20, 2009 4:42 PM To: John Coyne Cc: Pitner, Andrew; Slusser, Thomas Subject: RE: WI0300136 - Former Country Cupboard .Sunoco, Inc. John, We will need a current 1/4mile survey and well table. You mail email them and please copy Thomas.Slusser@ncdenr.gov. Thank You! Maria From: John Coyne [mailto:johnc@envirotrac.com] Sent: Monday, July 20, 2009 2:43 PM To: Schutte, Maria Cc: Scott Dunsmuir Subject: RE: WI0300136 - Former Country Cupboard Sunoco, Inc. Hello Maria, Here's what I could find out about the above referenced site: Apparently during the Comprehensive Site Assessment conducted in 1992, the potable well located at 2012 Woodleaf Road aka the McBride property, was overlooked. The environmental consultant at the time, Withers and Ravenel Environmental Engineering, received a letter from a Staff Engineer from the City of Salisbury which listed all of the wells in the area, and that well was not listed. When the Corrective Action Plan Addendum was prepared in 1996 by the next consultant, Fluor Daniel GTI, the well at 2012 Woodleaf was identified. It is not known if that well is still in existence and use currently. TABLE 3 Summary of Private Wells Mid-State/Sun .2010 Statesville Boulevard, Salisbury, NC ---------- - - -- ----- '. N .......... . . . . . . . . . . . . . . . 1920 Statesville Blvd. Larry Bums 276 Upgradien t 1924 Statesville Blvd Mrs. Barber 360 Upgradlent 2012 Woodleaf Ave. Mrs. McBride 240 Downgradieni 2021 Woodleaf Ave. Unknown 2.24 Downgradieni 2029 Woodleaf Ave. Wesley Kieth 348 Downgradieni 2034 Woodleaf Ave. Unknown 360 Downgradie 2035 Woodleaf Ave. Mike Holloway 408 Downgradient 2036 Woodleaf Ave. John H. Hipp 432 Downgradieni 2037 Woodleaf Ave. Cecil Pinkston 480 Downgradient 210I Woodleaf Ave. Ron Arey 600 Downgradieni 2102 Woodleaf Ave. H.L. Hipp Jr. 504 Downgradieni 2104 Woodleaf Ave. H.L. Hipp Sr. 516 Downgradieni aA027573831Tbl3.Wk4 HCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Governor Director June 26. 2009 Devon Watts Sunoco, Inc 203 South Falkenburg Road Tampa. FL 33619 Subject: Acknowledgement of Application No. WI0300136 Former Country Cupboard Sunoco Inc Injection In situ Groundwater Remediation Well (5I) Rowan Dear Devon: Dee Freeman Secretary The Aquifer Protection Section of the Division of Water Quality (Division) acknowledges receipt of your permit application and supporting materials on June 26, 2009. This application package has been assigned the number listed above and will be reviewed by Thomas Slusser. The reviewer will perform a detailed review and contact you with a request for additional information if necessary. To ensure the maximum efficiency in processing permit applications, the Division requests your assistance in providing a timely and complete response to any additional information requests. Please be aware that the Division's Regional Office, copied below, must provide recommendations prior to final action by the Division. Please also note at this time, processing permit applications can take as long as 60 - 90 days after receipt of a complete application. If you have any questions, please contact Thomas Slusser at 919-715-6164, or via e-mail at thomas.slusser@ncdenr.gov. If the reviewer is unavailable, you may leave a message, and they will respond promptly. Also note that the Division has reorganized. To review our new organizational chart, go to http://h2o.enr.state.ne.us/documents/dwq_orQchart.pdf. PLEASE REFER TO THE ABOVE APPLICATION NUMBER WHEN MAKING INQUIRIES ON THIS PROJECT. Sincerely, 0 W�L kp�. for Debra J. Watts Supervisor cc: Mooresville Regional Office, Aquifer Protection Section Scott Dunsmuir (EnviroTrac Ltd - 375 Winkler Drive, Ste E, Alpharetta, GA 30004) Permit Application File W10300136 AQUIFER PROTECTION SECTION 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard. Ralegh, North Carolina 27604 One Phone: 919-733-3221 l FAX 1: 919-715-0588; FAX 2: 919-715-60481 Customer Service: 1-877-623-6748 NorthCarolina Internet: ,nrww.ncwateroualitv.ora Naturally Equal Opportunity � Affirmative Action Employer • rol Environmental Services 375 Winkler Drive; Suite E, Alpharetta, GA 30004 PH: (770) 777-1711 FAX: (770) 777-1766 June 22, 2009 Thomas Slusser, L.G. UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Re: Former Country Cupboard Sunoco, Inc. 2010 Statesville Boulevard Salisbury, Rowan County, North Carolina 28114 Sunoco Facility DUNS# 02757383 NCDENR Groundwater Incident # 3519 Dear Mr. Slusser, Enclosed please find two copies of revised Applications for Permit to Construct and/or use a Well(s) for Injection. EnviroTrac Ltd. has revised these applications on behalf of Sunoco Inc., per your request for the site referenced above. The following corrections have been made: 1. The permit application has been completed in the name of Sunoco Inc, who is the responsible party, instead of EnviroTrac, who is the consultant currently conducting remediation activities on their behalf. 2. The permit application has been signed by Devon Watts from Sunoco Inc. 3. The proposed injection wells are shown on Figure 2 as MW-3, MW-5, MW-6, and VMW-7. We propose injecting Regenox directly into the specified monitoring wells. 4. Item B.3 on Page 4 of the permit application has been filled in to show that we will be injecting 200 gallons per day, which is 200 gallons per eight -hour event. There will be three events, spaced thirty days apart, so after roughly 90 days, we will have injected 600 gallons, but each individual event is one day/eight hours. 5. Item B.6 has been edited to discuss how the injection rate, volume, and pressure will be measured and controlled. There is a limited amount of space available on the form, so in the attachment under letter E, Operation Procedures, we go into greater detail about flow, pressure, and rate controls. 6. The groundwater elevation contour map has been redrawn to correct errors. If you have any questions or comments regarding this submittal, please contact me at (770) 777-1711 or (770) 527-1063, or email me at scottd@envirotrac.com. Thank you. Sincerely, EnviroTrac Ltd. '7"�"' V A).. - Scott Dunsmuir Senior Project Manager Attachment(s): Two revised Applications to Construct and /or Use a Well(s) for Injection and all attachments. RECEIVED / DENR / DWQ Aquifer PrntPrtinn Ser..tion JUN 2 4 2009 �CDENR North Carolina Department of Environment and Natural Resources Beverly Eaves Perdue Governor Scott Dunsmuir EnviroTrac Environmental Services 375 Winkler Drive, Suite E Alpharetta, GA 30004 Division of Water Quality Coleen H. Sullins Director June 1, 2009 RE: Return of Incomplete Application for a Type 5I Injection Well Permit Former Country Cupboard Sunoco Salisbury, Rowan- County, NC Dear Mr. Dunsmuir: Dee Freeman Secretary The Underground Injection Control (UIC) Program is returning two copies of the subject application package for an injection well permit since it is incomplete as submitted. Please resubmit the application with the following corrections and/or missing information: 1. The permit application should be completed in the name of whoever is responsible for the remediation activity, not in the name of the consultant currently scheduled to conduct the remediation activity on their behalf. 2. The permit application should be signed by a responsible corporate officer or other such person as described in the North Carolina Administrative Code, Title 15A, Subchapter 2C .0211(b). If an authorized agent signs the permit application, then include a letter from the signing official authorizing the selected agent to sign the permit application on their behalf. 3. The proposed injection wells were not indicated on any of the maps submitted. 4. Item 13.3 on Page 4 of the permit application form does not specify the volume of Regenox to be injected for each of the three injection events. 5. Item B.6 does not describe how the proposed injection rate, volume, and pressure will be measured and controlled. 6. The groundwater elevation contour map is not conducive for calculating the site hydraulic gradient. Plus, there seems to be a discrepancy with groundwater elevation data for MW-2, 669.26 feet, and the adjacent groundwater elevation contour line of 667.25 feet. RECEIVED / DENR / DWQ , Aquifer Protection Section REC D J UN 4 - 2009 AQUIFER PROTECTION SECTION JUN 2 4 2009 1636 Mail Service Center, Raleigh, North Carolina 27699-1636 Location: 2728 Capital Boulevard, Raleigh, North Carolina 27604 �71 Phone: 919-733-3221 1 FAX 1: 919-715-0588: FAX 2: 919-715-60481 Customer Service: 1-877-623-6748 ne 1 O13e 1 CcliO1111S Internet: www.ncwaterouali�.o� An Equal Opportunity 1 Affirmative Action Employer att1auflff Scott Dunsmuir Return Incomplete Application Former Country Cupboard Sunoco June 1, 2009 Page 2 of 2. Please contact me at thomas.slusser(a)ncdenr.gov or 919-715-6164 if you have any questions. Best Reg ds, Thomas Slusser, L.G. Hydrogeologist Underground Injection Control Program cc: UIC Program files Dan Graham, DWM UST Section • enviroirac Environmental Services 375 Winkler Drive; Suite E, Alpharetta, GA 30004 PH: (770) 777-1711 FAX: (770) 777-1766 May 18, 2009 UIC Program Aquifer Protection Section North Carolina DENR-DWQ 1636 Mail Service Center Raleigh, NC 27699-1636 Re: Former Country Cupboard Sunoco, Inc. 2010 Statesville Boulevard Salisbury, Rowan County, North Carolina 28114 Sunoco Facility DUNS# 02757383 NCDENR Groundwater Incident # 3519 Dear Sir or Madam, Enclosed please find two completed Applications for Permit to Construct and/or use a Well(s) for Injection. EnviroTrac Ltd. has prepared these applications on behalf of Sunoco Inc. for the site referenced above. If you have any questions or comments regarding this submittal, please contact me at (770) 777-1711 or (770) 527-1063. Thank you. Sincerely, EnviroTrac Ltd. Scott Dunsmuir Senior Project Manager Attachment(s): Two completed Applications to Construct and /or Use a Well(s) for Injection and all attachments. RECEIVED I DENR I DWQ RECEIVED / DENR / DWQ AQUIFFR PROTFPTm SFUION Aquifer Prntectinn Section MAY 2 U 2009 JUN 2 4 Z009 AQUIFER PROTECTION REGIONAL STAFF REPORT Date: 07/20/09 County: Rowan To: Aquifer Protection Central Office Permittee: Sunoco Inc Central Office Reviewer: Thomas Slusser Project Name: Former Country Cupboard Regional Login No: Application No.: WI0300136 L GENERAL -INFORMATION 1. This application is (check an that apply): ® New ❑ Renewal ❑ Minor Modification ❑ Major Modification Surface Irrigation ❑ Reuse ❑ Recycle ❑ High Rate Infiltration ❑ Evaporation/Infiltration Lagoon ❑ Land Application of Residuals ❑ Attachment B included ❑ 503 regulated ❑ 503 exempt ❑ Distribution of Residuals ❑ Surface -Disposal ❑ Closed -loop Groundwater Remediation ® Other Injection Wells (including in situ remediation) Was a site visit conducted in order to prepare this report? ® Yes or ❑ No. a. Date of site visit: 07/16/09 b. Person contacted and contact information: Scott Dunsmuir, Operations Manager w/ Enviro Trac Ltd., Alpharetta, GA (770) 77771711. Call returned by John Coyne w/Enviro Trac Ltd. They did not have anyone local to meet me, but he provided the store manager information, so I could introduce myself upon arrival. Country Cupboard Store Manager : Chrissy Cain (704) 636-0022. c. Site visit conducted by: Maria Schutte d. Inspection Report Attached: ❑ Yes or ® No. 2. Is the following information entered into the RIMS record; for this application correct? N Yes or ❑ No. If no, please complete the following or indicate that it is correct on the current application. For Treatment Facilities: info in BIMS for the facility was undated by MRO a. Location: b. Driving Directions: c. ; USGS Quadrangle Map name and number: d. Latitude: Longitude: e. Regulated Activities / Type of Wastes (e.g., subdivision, food processing, municipal wastewater): For Disposal and Iniection Sites: info in BIMS for the facilitv was undated by MRO (If multiple sites either indicate which sites the information annlies to. conv and haste a new section into the document for each site, or attach additional pages for each site a. Location(s): see above b. Driving Directions: c. USGS Quadrangle Map name and number: d. Latitude: Longitude: IL NEWAND MAJOR MODIFICATIONAPPLICATIONS (this section not needed for renewals or minor modifications, skin to next section) Section 11 is not applicable to this UIC project. FORM: APRSR040929-UIC review Country Cupboard - July 2009 AQUIFER PROTECTION REGIONAL STAFF REPORT III. RENEWAL AND MODIFICATIONAPPLICATIONS (use previous section for new or major modification stems Section III is not applicable to this project. IV. INJECTION WELL PERMIT APPLICATIONS (Complete these two sections for all systems that use injection wells, including closed -loop groundwater remediation effluent injection wells, in situ remediation injection wells, and heat pump injection wells.) Description Of Well(S) And Facilities — New, Renewal, And Modification 1. Type of injection system: ❑ Heating/cooling water return flow (5A7) ❑ Closed -loop heat pump system (5QM/5QW) ® In situ remediation (5I) ❑ Closed -loop groundwater remediation effluent injection (51,/"Non-Discharge") ❑ Other (Specify: 2. Does system use same well for water source and injection? - ❑ Yes ® No 3. Are there any potential pollution sources that may affect injection? ® Yes ❑ No What is/are the pollution source(s)? This is a small scale infection at an active convenience store / gas station. The contamination.plume is near the current USTs and above ground Kerosene dispenser. What is the distance of the injection well(s) from the pollution source(s)? 5 —15 ft from USTs and Kerosene Dispenser. 4. What is the minimum distance of proposed injection wells from the property boundary? —5ft. from Statesville Boulevard right-o -way. 5. Quality of drainage at site: ❑ Good ®Adequate ❑ Poor 6: Flooding potential of site: ® Low ❑ Moderate ❑ High 7. For groundwater remediation systems, is the proposed and/or existing groundwater monitoring program (number of wells, frequency of monitoring, monitoring parameters, etc.) adequate? ❑ Yes ® No. Attach map of existing monitoring well network if applicable. If No, explain and recommend any changes to the groundwater -monitoring program: Proposal uses exiting, monitoring wells as the injection wells and then plans to sample them over time. Recommend installation.ofini ction wells and monitor progress via existing MWs. 8.. Does the map presented represent the actual site (property lines, wells, surface drainage)? ® Yes or ❑ No. If no or no map, please attach a sketch of the site. Show property boundaries, buildings, wells, potential pollution sources, roads, approximate scale, and north arrow. Iniection Well Permit Renewal And Modification Only: This section not applicable to this project. FORM: APRSR040929-UIC revi -� �'ountry Cupboard - July 2009 -- 2 AQUIFER PROTECTION REGIONAL STAFF REPORT V. EVALUATIONAND RECOMMENDATIONS 1. Provide any additional narrative regarding your review of the application: The injection proposal is for a 5% RegenOx solution (diluted with a municipal water source) intended to remediate petroleum products from a 1986 UST leak and a 1987 above ground unleaded gasoline spill. (Typing error in application for spill says June 1997; clarified with consultant should be June 1987.) The injection site is an active convenience store / gas station. The Country Cupboard still exists but now offers BP products. Due to concerns about the current status of nearby wells, the MRO has requested a current '/ mile survey / table / map of water supply wells. Noted under section IV #7: The project proposes injecting and sampling from same wells (MW-3, MW-5, MW- 6 & VMW-7). The MRO recommends separate injection / monitoring wells. Should the CO agree and the consultant opt to install injection wells note this site is riddled with drilling obstacles: There are overhead and underground utilities, AST's and USTs, a gaspump canopy and this is a fairly busy - high traffic volume store. 2. Attach Well Construction Data Sheet - if needed information is available 3. Do you foresee any problems with issuance/renewal of this permit? ® Yes ❑ No. If yes, please explain briefly. Injecting and sampling from same well is not an accurate measure ofplume response_ 4. List any items that you would like APS Central Office to obtain through an additional information request. Make sure that you provide a reason for each item: Item Reason 5. List specific Permit conditions that you recommend to be removed from the permit when issued. Make sure that you provide a reason for each condition: Condition Reason 6. List specific special conditions or compliance schedules that you recommend to be included in the permit when issued. Make sure that you provide a reason for each special condition: Condition Reason Install separate injection wells Injecting and sampling from same well is not an accurate measure of plume. 7. Recommendation: ® Hold, pending receipt and review of additional information by regional office; ❑ Hold, pending review of draft permit by regional office; ❑ Issue upon receipt of needed additional information; ❑ Issue; ❑ Deny. If deny, please state reasons: 8. Signature of report preparer(s): Maria Schutte Digitally signed by Andrew Pitney N: ZAntlrew y, 0, ou=DWD�A Andrew PitnereOmaikandrew.pitnerPitnetmn<dencgov. r-PS,US Signature of APS regional supervisor: Andrew Pitner Date:2009.0I21085107-04'00' Date: July 21, 2009 FORM: APRSR040929-UIC review Country Cupboard - July 2009 3 North Carolina Department of Health and Human Services Division of Public Health • Epidemiology Section 1912 Mail Service Center • Raleigh, North Carolina 27699-1912 Tel 919-707-5900 • Fax 919-870-4810 Michael F. Easley, Governor September 5, 2007 MEMORANDUM TO: Qu Qi .. Underground hij ection Control Program. Aquifer Protection Section FROM: Luanne K. Williams, Pharm.D., Toxicologist Medical Evaluation and Risk Assessment Unit Occupational and Environmental Epidemiology Branch North Carolina Department of Health and Hunan Services Carmen Hooker Odom, Secretary SUBJECT: Use of Non -Biological Products RegenOxTm to Enhance Biodegradation of Contaminated Groundwater I am writing in response to a request for a health risk evaluation regarding the use of non - biological product R.egenOxTM to enhance biodegradation of contaminated groundwater. Based upon my review of the information submitted, I offer the following health risk evaluation: Some effects or hazards reported to be associated with the chemicals proposed for use are as follows: • Exposure can cause severe irritation and possibly burns to the skin, eyes, nose, throat, lungs, and gastrointestinal tract (Micromedex TOMES Plus System CD-ROM Database, Volume 73, 2007) 2. If the products are released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. Persons working with this product should at least wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 4. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should never be permitted in the application area during or iminediately following application. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. e Location: 5505 Six Forks Road, 2nd F16or, Room D7 • Raleigh, N.C. 27609 An Equal Opportunity Employer The Material Safety Data Sheets should be followed to prevent adverse reactions and injuries. C. Access to the area of application should be limited to the workers applying the product. Fri order to minimize exposure to unprotected individuals, measures should be taken to prevent access to the area of application. 7. Efforts should be made to prevent contamination of existing or future wells and surface waters that may be located near the application area. Please do not hesitate to call me if you have any questions at (919) 707-5912. r