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HomeMy WebLinkAboutWI0300104_Quarterly Progress_20061120Engineering for the Environment PlanningforPeople. 1055 ive, Suite A E. West Chester, ew rPA19380-42 3 te1610.840.9100 fax 610.840.9199 www.advancedgeoservices.com i March 7, 2006 2004-1292-00 Mr. Kim Caulk North Carolina Department of Environment and Natural Resources AQUIFFR-RECEIVED / DENR / DWQPROTFCVON S Division of Waste Management ECTION 1646 Mail Service Center NOV 2 02006 Raleigh, NC 27699-1646 RE: Remedial Action Quarterly Progress Report "90 Day Report" REC Program — DWM No. 99-SF-188 Former Pelton and Crane Facility, Charlotte, North Carolina _ Dear Mr. Caulk: ` In accordance with 15A NCAC 13C.0306(o) Advanced GeoServices Corp. (AGC), on behalf of v~ ya Siemens Medical Solutions USA Inc. (SMS), submits this Remedial Action Quarterly Progress Report. This report describes the activities at the Former Pelton and Crane Site (Figure 1) between November 1, 2005 and January 31, 2005, and the activities scheduled for the upcoming three months. This report is being submitted within 90 days of the completion/submittal of the Groundwater Remedial Action Construction Completion Report (GRACCR), dated December 9, 2005 in accordance with the REC Program Implementation Guidance. A construction summary of the monitoring wells, injection wells, and piezometers are described in Table 1. Monitoring and injection well locations are shown on Figure 2. 1. Activities Performed Groundwater monitoring for boron in accordance ents of the Underground Injection Control (UIC) ermit (WI0300104) as performed in November 2005 (i.e., 90 days post- i ' The results f this event, and previous boron sampling events, are s le 2. • One interim process monitoring groundwater sampling event was completed in November 2005 (90 days post -injection). The sampling was performed in accordance with Table 6-4 in the Groundwater Remedial Action Engineering Design Report (GRAEDR) and the UIC permit. The results of this event, and previous interim events, are summarized on Table 3. a F:\OFICEAGC1FROJECTS\Files\2004-1292\Reports\Quanerly\FouA Quarterly Reporr2005.doc Mr. Kim Caulk i 2004-1201-00 March 7, 2006 Page 2of5 • The initial process monitoring groundwater sampling event was completed in December 2005 (120 days post -injection). The sampling was performed in accordance with Table 6-4 in the GRAEDR and the UIC permit. The results of this event are provided in Tables 4 and 5. A summary of all volatile organic compounds (VOCs) groundwater results are also presented on Plate 1. • Annual indoor air monitoring was conducted in December 2005 at the Site (see Attachment A). 2. Performance Evaluation • Boron groundwater concentrations In the up -gradient monitoring well (1\4W-39) continued to increase (currently 200 ug/L) with respect to the baseline sampling event (71.2 ug/L). However, the up -gradient concentrations are still below the NC 2L standard of 315 µg/L. Boron groundwater concentrations in monitoring wells MW-40 and MW-41, 35 feet and 50 feet down -gradient of the injection wells, respectively, continue to have concentrations approximately 1.5 orders -of -magnitude above the baseline concentrations (i.e., approximately 100 ug/L vs. approximately 4,000 ug/L). • Total organic carbon (TOC) is a key indicator for evaluating the extent of SRS'rm 1 distribution in the bedrock. The 120-day post -injection TOC results continue to show a 2 to 3 order -of -magnitude increase in TOC concentrations at the first down -gradient (approximately 25 ft.) monitoring well cluster (MW-1 and MW-40) in the shallow groundwater zone (i.e., upper 100 ft. No increase in TOC continues to be observed in the deep groundwater (MW-38) at the same distance down-gradient.2 The next down -gradient (approximately 50 ft) shallow groundwater monitoring well cluster, MW-18 and MW-41, have TOC concentrations 2X and 50X, respectively, above the baseline concentrations. Monitoring wells further down -gradient did not show any significant increases in TOC. • Dissolved oxygen (DO) levels remained below 1 mg/L3 in all the monitoring wells MW-1, MW-38, MW-40, MW-41, and MW-18 near (i.e., within 50- feet down -gradient) the Phase I injection zone, and were typically below 0.5 mg/L during the 90-day and 120-day post -injection I SRSTM is a vegetable oil emulsion. SRSTM was injected into the groundwater to help stimulate anaerobic biodegradation by providing a carbon food source for the naturally occurring microorganisms. 2 SRSTM injections were only made within the upper 100 ft. 3 Dissolved oxygen levels above 1 mg/L3 are generally considered not conducive to anaerobic biodegradation of chlorinated aliphatic hydrocarbons such as WE F:\OFICEAGC\PROJECTS\Files\20041292\Reports\Quarterly\Fourth Quarterly Report2005.doc Mr. Kim Caulk 2004-1201-00 March 7, 2006 Page 3 of 5 interim process monitoring events. The DO levels in monitoring wells 100 feet down -gradient of the Phase I injection zone (i.e., MW-42 and MW-43) remained below 0.5 mg/L during the 90-day post -injection event but increased to slightly above 1.0 mg/L during the 120-day post -injection event. Monitoring wells MW-44 and MW-45, approximately 130 feet down -gradient of the injection zone, had average DO levels of 0.7 mg/L and 1.1 mg/L during the 90-day and 120-day post -injection sampling events; this is a slight increase from the 30-day and 60-day post -injection sampling events and represents an upward trend from the baseline sampling event. The oxidation/reduction potential (ORP) in the first down -gradient well cluster (i.e., MW-1 and MW-40) in the shallow groundwater during the 90-day and 120-day post -injection sampling events decreased in comparison to the 30-day and 60-day post -injection sampling events, and were less than 50 millivolts (mv) in December 2005. The ORP increased in the deep groundwater well (MW-38) but remained well below -100 mv. The remaining down -gradient process monitoring wells were consistently below -100 mv. The pH results for the 90-day and 120-day post -injection events in monitoring wells MW-1 and MW-40 increased by 2 or 3 standard units as compared with the 30-day post -injection and 60-day post -injection results. The breakdown of the SRSTM can cause a lowering of the pH if the groundwater formation does not have sufficient buffering capacity. The formation appears to be slowly buffering this effect of the SRSTM. The remaining shallow groundwater wells typically had pH levels within the range of 5 to 95. Deep groundwater well MW-38 continues to have a pH greater than 12, which is consistent with the baseline sampling event. A comparison of the monitored natural attenuation (MNA) parameters in Table 4 and field parameters in Table 3 to the U.S Air Force Center for Environmental Excellence screening criteria for evidence of biodegradation of chlorinated organics indicates the following: Strong evidence for biodegradation occurring is present in the shallow groundwater within 50 feet down -gradient of the injection zone; 4 Oxidation/reduction potentials greater than 50 millivolts are generally considered not conducive to anaerobic biodegradtion of chlorinated aliphatic hydrocarbons such as TCE. 5 pH conditions within 5 to 9 standard units generally considered conducive to anaerobic biodegradtion of chlorinated aliphatic hydrocarbons such as TCE. F:\OFICEAGC\PROIECTS\Files\2004-1292\Reports\Quarterly\Fourth Quarterly Report2005.doc Mr. Kim Caulk 2004-1201-00 March 7, 2006 Page 4 of 5 Limited evidence for biodegradation occurring in the deep groundwater within 50 feet down -gradient of the injection zone. However, increases in dissolved gases (i.e., ethane, ethene and methane) may be an indication of some beneficial effects from the substrate injection in the shallow groundwater zone above this well; and, Adequate evidence for biodegradation in the shallow groundwater 75 to 100 feet down -gradient on the injection zone. • Trichloroethene (TCE), 1, 1 -Dichloroethene (IIDCE), 1,2-Dichloroethene (12DCE), and Vinyl Chloride (VC) continue to be the predominant VOCs detected at the Site. Order of magnitude reductions in TCE concentrations (from the original baseline sampling) occurred in shallow wells: MW-40, MW-18, MW-41, and MW-42. Significant reductions in TCE concentrations were also observed in shallow wells MW-1 and MW-43. Because the TCE concentration in MW-1 is still within the historic range of concentrations at that location, we are not able to yet reach any definitive conclusions regarding the efficacy of the remedial system at that location. A variety of concentration trends were observed at these wells for the biodegradation breakdown compounds (i.e., IIDCE, 12DCE and VC). For example: At MW-40 —1,1-DCE, 1,2-DCE and VC all significantly declined; At MW-41 — 1, 1 -DCE and 1,2-DCE both significantly declined but VC significantly increased; and, At MW-42 —1,2-DCE significantly increased but 1,1-DCE and VC remained stable. The increase in dissolved gases at the first down -gradient well cluster (MW-1, MW-40 and MW-38) is a good indication that complete biodegradation is occurring. In summary, based on an overall assessment of the field data and groundwater chemical data, the injection of the SRSTM is appears to be promoting the biodegradation of the chlorinated aliphatic hydrocarbons in the shallow groundwater within the vicinity of the injection wells. Continued monitoring will help determine the effectiveness of the remedial system outside of the initial injection area: • SMS and the current property owner initiated discussion regarding potential land use restrictions that would be used to re-evaluate the selected soil remedy for areas of concern in the building and the shipping/receiving area off of Pelton Street. F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Fourth Quarterly Repor=05.doc Mr. Kim Caulk 2004-1201-00 March 7, 2006 Page 5 of 5 • Samples of the borrow proposed for use as backfill during soil remediation were collected and sent for chemical testing to assure the fill source meets the REC Program Unrestricted Use Soil Remediation Goals. 3. Difficulties Encountered • None. 4. Activities Scheduled for Upcoming Three Months • Continue evaluation and performance of post -injection groundwater monitoring. • Continue discussions regarding land use restrictions. • Initiate soil removal activities for the Western Baghouse Area, Unnamed Tributary, and the North Parking Lot. • Perform annual indoor air monitoring. If you have any questions, please call me at 610-840-9122. The certification statements are included in Attachment B. Sincerely, ADVANC DE G -SERV'-- TES CORP.. �' e„ ram,,• � Paul G. Stratman, P.E., P.G. Registered Site Manager PGS:vm Enclosures cc: Stephen Kirschner, AGC Robert L. Friedman, Siemens Charles Case, Hunton and Williams Thomas McKittrick, Clanton Partners F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarrerly\Fourth Quarterly Report2005.doc TABLES F:\OFICEAGC\PROJECTS\Files\20041292\Reports\Quutuly\Fourth Quutaly Report2005.doc Table 1 Monitoring Well, Injection Well, and Piezometer Construction Summary Former Pelton and Crane Facility Charlotte, NC Well Identification Monitoring Well Type Date Installed Outer Casing Diameter/Depth Boring Depth (ft. bgs.') Ground Surface Elevation Elevation TOICZ Screen/Open Length (ft.) Monitored Interval Monitored Zone Northing Easting (ft. bgs.) Elevation (ft.) Phase I PZ-1 ** 1-inch diameter PVC Jun-00 NA 15 724.1 723.86 10 5-15 709.1 - 719.1 Soils 531517.66 1440011.88 PZ-2 ** 1-inch diameter PVC Jun-00 NA 18 726.89 728.07 15 3 - 18 708.89 - 723.89 Soils 531792.17 1440055.54 PZ-3 ** 1-inch diameter PVC Jun-00 NA 28 726.27 727.05 20 8-28 698.27 - 718.27 Soils 531884.85 1439942.07 PZ-4 ** 1-inch diameter PVC Jun-00 NA 23 726.25 727.33 20 3-23 703.25 - 723.25 Soils 531862.73 1439850.17 PZ-5 ** 1-inch diameter PVC Jun-00 NA 23 724.8 725.4 20 3-23 702.17 - 722.17 Soils 531657.23 1439789.37 PZ-7 ** 1-inch diameter PVC Jun-00 NA 20 724.51 725.62 15 5 - 20 704.51 - 719.51 Soils 531372.81 1439837.70 PZ-8 ** 1-inch diameter PVC Jun-00 NA 22 726.61 728.06 20. 2'- 22 704.61 - 724.61 Soils 531387.89 1440108.99 MW-1 2-inch diameter PVC Sep-00 10"/15-ft. 35 724.1 723.86 10 25 - 35 689.15 - 699.15 Bedrock 531517.66 1440011.88 MW-2 2-inch diameter PVC Sep-00 10"/20-ft. 40 726.46 726.19 10 30 - 40 686.46 - 696.46 Soils 531850.05 1439863.12 NW-3 2-inch diameter PVC Sep-00 10"/20-ft. 32 725.15 ..724.83 8 24 - 32 693.15 - 701.15 Soils 531646.98 1439781.66 NM-4 2-inch diameter PVC Sp-00 10"/20-ft. 39 725.53 725.3 10 29 - 39 686.53 - 696.53 Soils 531529.34 1439724.79 NM-5 2-inch diameter PVC Sep-00 10"/20-ft. 27 726.58 728.96 5 22-27 699.58 - 704.58 Soils 531399.24 1440117.60 MW-6 2-inch diameter PVC -0010"/10-ft. 15 726.44 726.18 2 13-15 711.44 - 713.44 Soils 531556.05 1439897.42 MW-7 2-inch diameter PVC je -00 10"/28-ft. 34 727.04 726.78 3 31-34 693.04 - 696.04 Soils 531890.37 1439949.97 NW-8 2-inch diameter PVC Sep-00 10"/20-ft. 26 724.01 726.44 4 22 - 2 698.01 - 702.01 Soils 531389.381 1439806.50 PHASE II MW-9 2-inch diameter PVC A r-01 NA 27 725.45 725.16 10 17 - 27 698.45 - 708.45 Soils 531244.98 1439914.40 NW-10 2-inch diameter PVC A r-01 NA 36 721.96 721.77 10 26 - 36 685.87 - 695.87 Soils 531343.67 1439720.97 MW-11 2-inch diameter PVC A r-01 NA 35 726.93 726.24 10 25 - 35 691.93 - 701.93 Soils 531797.97 1440049.22 MW-12 2-inch diameter PVC A r-01 NA 28 727.26 727.09 10 18 - 28 699.26 - 709.26 Soils 531963.71 1439854.66 MW-15 o en borehole A r-01 6"/77-ft. 97 727.34 726.89 20* 77 - 97 630.34 - 650.34 S. bedrock 531899.10 1439941.71 MW-16 open borehole . A r-01 6"/43-ft. 58 724.19 723.96 15* 43 - 58 666.19 = 681.19 S. bedrock 531548.76 1439732.31 MW-17 open borehole A r-01 6"/39-ft. 59 721.87 721.61 20* 39 - 59 662.96 - 682.96 S. bedrock 531336.52 1439713.11 MW-18 2-inch diameter PVC A r-01 10"/21-ft. & 6"/55-ft. 85 723.26 722.91 20 65.-85 638.26 - 658.26 S. bedrock 531540.25 1439989.07 MW-19 2-inch diameter PVC A r-01 NA 23 729.79 729.09 10 13-23 707.79 - 717.79 Soils 532003.08 1439947.96 NM-20 open borehole Aug-01 10"/47-ft. & 6"/100-ft. 162 725.95 725.45 62* 100 - 162 625.95 - 563.95 D. bedrock 531775.61 1439843.54 MW-21 open borehole Aug-01 10"/59-ft. & 6"/100-ft. 122 724.20 724.03 22* 100 - 122 624.20 - 602.20 D. bedrock 531564.36 1439737.96 MW-22 open borehole Au -01 10"/42-ft. & 6"/100-ft. 162 722.24 722.06 62* 100 - 162 622.24 - 560.24 D. bedrock 531360.74 1439725.22 MW-23 open borehole Au -01 6"/45-ft. 59 725.82 725.40 14* 45 - 59 680.82 - 666.82 S. bedrock 531754.08 1439833.56 MW-24 2-inch diameter PVC Au -01 NA 43 732.71 734.77 10 33 - 43 699.71 - 689.71 Soils 531986.80 1440060.38 MW-32 open borehole Ma -03 6"/80-ft. 100 729.63 729.33 20* 807100 649.63 - 629.63 S. bedrock 531998.02 1439955.21 MW-33 open borehole May-03 6"/40-ft. 60 720.90 720.58 20* 40-60 680.90 - 660.90 S. bedrock 532045.68 1439653.12 MW-36 open borehole Ma -03 10"/8.5-ft. & 6"/100-ft. 140 720.79 720.44 40* 100-140 620.79 - 580.79 D. bedrock 532051.76 1439644.88 MW-37 open borehole Ma -03 10"/60-ft. & 6"/200-ft. 240 724.28 723.47 40* 200-240 524.28 - 484.28 D. bedrock 531542.24 1439733.28 MW-38 open borehole May-03 10"/25-ft. & 6"/160-ft. 200 723.67 723.39 40* 1 160-200 563.67 - 523.67 D. bedrock 531532.90 1440007.51 F.\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quartedy\Table 1 4th Quarter 2005ads Page 1 of 2 1 Table 1 Monitoring Well, Injection Well, and Piezometer Construction Summary Former Pelton and Crane Facility Charlotte, NC Well Identification Monitoring Well Type Date Installed Outer Casing Diameter/Depth Boring Depth (ft. bgs.') Ground Surface Elevation Elevation TOICZ I Screen/Open Length (ft-) Monitored Interval Monitored Zone Northing Easting (ft. bgs.) Elevation (ft.) PHASE H OFF -SITE MW-13 2-inch diameter PVC A `r-01 NA 11 720.43 720.2 5 6 - 11 709.43 - 714.43 Soils 531969.73 1439626.01 MW-14 2-inch diameter PVC A r-01 NA 36 718.15 717.58 10 26 - 36 682.15 - 692.15 Soils 531679.22 1439540.08 MW-25 2-inch diameter PVC Jun-02 NA 35 713.79 713.40 10 25-35 688.4-678.4 Soils 531616.09 1439502.58 MW-26 2-inch diameter PVC Jun-02 NA 35 722.49 722.02 10 25-35 697.02-687.02 Soils 531353.74 1439462.28 MW-27 2-inch diameter PVC Jun-02 6"/42-ft. 62 713.74 .713.41 15 47-62 666.41-651.41 S. bedrock 531610.12 1439511.16 MW-28 open borehole Jun-02 6"/40-ft. 60 722.17 721.91 20* 40-60 681.91-661.91 S. bedrock 531346.51 1439475.52 MW-29 2-inch diameter PVC Jun-02 6"/50-ft. 66 723.04 722.76 15 51-66 671.76-656.76 S. bedrock 531161.33 1439609.86 MW-30 open borehole Jun-02 8"/50-ft. & 6"/110-ft. 140 713.73 7i3.34 30* 110-140 603.34-573.34 D. bedrock 531606.11 1439517.01 MW-31 open borehole Jun-02 10 735-ft. & 6"/95-ft. 115 722.35 722.07 21 * 95-115 627.07-606.07 D. bedrock 531350.82 1439467.47 MW-34 open borehole May-03 6"/50-ft. 70 719.55 119.05 20* 50-70 669.55 - 649.55 S. bedrock 531911.93 1439542.98 MW-35 open borehole May-03 10"/35-ft. & 6"/100-ft. 140 719.18+-'718.98 40* 100-140 619.18 - 579.18 D. bedrock 531907.89 1439546.68 SUPPLEMENTAL PHASE H OFF SITE MW-46 o en borehole Feb-05 4"/80-ft. 100 716.40 716.08 20* 80-100 636.40-616.40 S. bedrock 532343.19 1440084.35 MW-47 open borehole Jan-05 8"/84-ft. & 4"/150-ft 170 716.16 715.84 20* 150-170 566.16-546.16 D. bedrock 532349.16 1440082.91 MW-48 open borehole A r-05 8"/16-ft. & 4"/80-ft 100 717.98 716.61 20* 80-100 637.98-617.98 S. bedrock 532249.50 1439763.66 MW-49 2-inch diameter PVC Apr-05 10"/18-ft & 2"-170' 170 717.68 717.40 20 15070 567.68-547.68 D. bedrock 532257.73 1439769.36 GROUNDWATER REMEDIAL ACTION MW-39 open borehole Dec-04 8"/25-ft. & 4"/50-ft. 75 727.71 727.32 25* 50-75 677.70-652.71 S. bedrock 531438.05 1440144.36 MW-40 open borehole Dec-04 8"/25-ft. & 4"/65-ft. 95 723.80 723.56 30* 65-95 658.80-628.80 S. bedrock. 531527.17 1440005.28 MW-41 open borehole Dec-04 4"/25-ft. 55 723.41 723.05 30* 25-55 698.41-668.41 S. bedrock 531535.92 1439987.27 MW-42 o enborehole Ma -05 4"/25-ft. 55.3 726.57 726.45 30.3* 25-55.3 701.57-671.27 S. bedrock 531554.07 1439943.70 MW-43 open borehole May-05 8"/20.5-ft & 4"/65-ft 95 726.51 726.08 30* 65-95 661.51-631.51 S. bedrock 531557.17 1439938.07 MW-44 open borehole May-05 8"/14.2-ft & 4"/65-ft 95.5 726.43 725.82 30.5* 65-95.5 661.43-630.93 S. bedrock 531559.89 1439898.63 MW-45 open borehole A r-05 8"/35-ft & 4"/65-ft 95 726.38 725.89 30* 65-95 661.38-631.38 S. bedrock 531686.86 1439960.52 IW-IS open borehole A r-05 4"/25.5-ft 55 725.13 724.76 29.5* 25.5-55 699.63-670.13 S. bedrock 531519.33 1440038.81 IW-lI open borehole A r-05 4"/64-ft 93 1 724.60 724.33 29* 64-93 660.60-631.60 S. bedrock 531523.57 1440030.36 IW-2S open borehole A r-05 4"/27-ft 56.4 726.43 726.23 29.4* 27-56.4 699.43-670.03 S. bedrock 531497.10 1440027.94 IW-2I open borehole Apr-05 4"/65-ft 95 726.40 726.06 30* 65-95 661.40-631.40 1 S. bedrock 1 531500.411 1440020.66 Notes: 1. bgs. - Below ground surface 2. TOIC - Top of inner casing 3. PVC - Poly -vinyl chloride well casing 4. NA - Not Applicable 6. Elevation Datum is North American Vertical Datum (NAVD 88) 7. * Indicates length of open borehole 8. Filter pack goes from 21 to 26 feet. 9. PZ-6 not installed in boring SB-22 because water was not encountered before equipment refusal was met. 10. Filter pack goes from 148 to 170 feet ** - Abandoned in accordance with state regulations., F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Table 1 4th Quarter 2005.)ds Page 2 of 2 TABLE 2 SUMMARY OF GROUNDWATER BORON (µg/L) RESULTS Former Pelton and Crane Facility Charlotte, NC Up -Gradient of 25' Down -Gradient 50' Down -Gradient of Sampling Event Injection Wells of Injection Wells Injection Wells MW-39 MW-40 MW-41 Baseline 71.2 117 102 June 2005 30-Day Post -Injection 165 3,970 4,040 September 2005 90-Day Post -Injection 200 4,140 3,830 November 2005 F:IOFICEAGCIPROJECTS1Files120D4-12921ReportslQuarlerlylTable 2 4th Quarter 2005.)ds E3 SUMMARY OF INTERIM PROCESS MONITORING FIELD PARAMETERS AND TOTAL ORGANIC CARBON (TOC) RESULTS Former Pelton and Crane Facility Charlotte, NC -el- I of 2 Location Monitored Interval (ft b sl) Distance Down Gradient (ft) Date Time Since Initial Injection (days) pH SPC (ms) ORP (mv) Temp (°C) DO ( m) Turb (ntu) TOC (m MW-39 50-75 -135 June, 2005 baseline 12.23 2.26 177 22.58 4.76 1.96 2.3 September, 2005 30 13.07 1.99 78 24.71 0.65 7.8 0.63 October, 2005 60 12.27 1.92 91 20.53 0.81 25.9 1.3 November, 2005 90 12.6 2.33 -75 19.53 1.55 8.64 2 December, 2005 120 10.92 2.48 -58 11.06 1.27 8.15 2 MW-1 25-35 25 June, 2005 baseline 12.23 2.54 -69 16.17 0.68 5.05 8.1 September, 2005 30 4.79 2.329 62 24.8 0.77 237.5 4230 October, 2005 60 4.81 1.95 151 20.7 0.14 ** 3000 November, 2005 90 3.88 2.36 118 22.17 0.08 ** 3770 December, 2005 120 6.29 2.42 46 17.39 0.13 ** 8,560 MW-40 65-95 35 June, 2005 baseline 7.26 0.339 -106 27.03 0.52 15.6 0.98 September, 2005 30 5.28 2.08 -1 27.22 0.66 273.8 14400 October, 2005 60 5.35 1.86 79 21.14 0.25 ** 2860 November, 2005 90 4.36 2.92 2 21.46 0.23 ** 9870 December, 2005 120 7.73 2.91 -41 11.68 0.60 ** 8,950 MW-38 160-200 35 June, 2005 baseline 12.73 4.05 -598 25.52 0.48 3.55 15.8 September, 2005 30 13.96 3.67 -551 25.03 0.46 4.23 13.9 October, 2005 60 12.49 3.2 -575 21.84 0.30 7.2 14.2 November, 2005 90 12.85 3.75 -334 21.31 0.47 2.34 14.4 December, 2005 120 13.49 3.89 -237 17.45 0.73 3.77 13.6 MW-41 25-55 50 June, 2005 baseline 6.58 0.436 15 18.43 0.16 23.4 1.4 September, 2005 30 6.65 0.5516 -168 22.97 0.56 50 79.9 October, 2005 60 6.79 0.403 -104 20.75 0.15 17.9 60.4 November, 2005 90 6.25 0.570 -96 20.77 0.40 14.39 76.4 December, 2005 120 8.28 0.688 -152 18.18 0.13 10.30 80.5 MW-18 65-85 50 June, 2005 baseline 6.57 0.452 -9 21.73 0.24 9.04 2.7 September, 2005 30 6.71 0.3305 -108 22.11 0.76 8.00 9.6 October, 2005 60 7.08 0.312 -303 21.56 0.07 8.79 5.3 November, 2005 90 6.95 0.357 -202 20.38 0.31 6.11 6.7 December, 2005 1 120 9.72 0.364 -153 15.83 0.45 2.50 4.7 F:\OFICEAGC\PROJECfS\Files\2004-1292\Reports\Quarterly\Table 3 4th Quarter 2005.x1s 3 SUMMARY OF INTERIM PROCESS MONITORING FIELD PARAMETERS AND TOTAL ORGANIC CARBON (TOC) RESULTS Former Pelton and Crane Facility Charlotte, NC -_a-2of2 Location Monitored Interval (ft b sl) Distance Down Gradient (ft) Date Time Since Initial Injection (days) pli SPC (ms) ORP (mv) Temp (°C) DO ( m) Turb (ntu) TOC (m L MW-42 25-55 96 June, 2005 baseline 6.69 0.413 -420 19.80 0.22 91.4 2.2 September, 2005 30 6.62 0.4577 -119 1 24.88 0.54 379 1.8 October, 2005 60 6.98 0.339 -160 21.04 0.39 27 2.1 November, 2005 90 6.65 0.418 -114 21.11 0.29 16.85 2.5 December, 2005 120 9.09 0.446 -129 18.98 1.03 4.01 2.2 MW-43 65-95 102 June, 2005 baseline 7.69 0.371 -519 31.17 0.03 197 1.3 September, 2005 30 7.98 0.3527 -219 21.64 0.49 24 0.67 October, 2005 60 7.75 0.29 -322 21.17 0.07 12.9 1.2 November, 2005 90 7.91 0.359 -193 21.18 0.27 15.83 8.7 December, 2005 120 10.51 0.349 -172 17.41 1.15 9.49 1.9 MW-44 65-95 137 June, 2005 baseline 7.49 0.336 -386 20.72 0.28 * 1.4 September, 2005 30 7.03 0.3709 -111 22.37 0.72 11.7 1.4 October, 2005 60 7 0.289 -234 21.31 0.26 21.7 1.1 November, 2005 90 7.06 0.352 -143 21.06 0.27 4.38 1.8 December, 2005 120 9.3 0.369 -120 18.48 1.05 4.71 1.4 MW-45 65-95 130 4 June, 2005 baseline 8.75 0.236 -372 22.65 0.31 932 1.9 September, 2005 30 9.21 0.285 42 22.77 0.67 336 ND October, 2005 60 7.57 0.239 72 22.93 0.59 79.1 0.86 J November, 2005 90 6.83 0.278 -12 21.95 1.3 57.39 1.2 December, 2005 120 9.5 0.249 -124 20.61 1 0.87 22.4 1.4 1: ft bgs - Feet Below Ground Surface 2: NC 2L Standard for Boron is 315 µg/L 3: NT - Well was not tested for this parameter 4: MW-45 also approximately 145 feet north from line connecting all other wells *: Turbidity was too high for the instrument to read correctly **: Turbidity was too high for the instrument to read correctly due to opaque water from the injection of the vegetable oil emulsion Denotes baseline reading F:\OFICEAGC\PROIECTS\Files\2004-1292\Reporb\Quarterly\Table 3 4th Quarter 2005.xls TABLE 4 COMPARISON OF BASELINE AND 120 DAY POST -INJECTION MNA SAMPLING RESULTS Former Pelton and Crane Facility Charlotte, North Carolina Page 1 of 2 LOCATION 150' Upgradient of Original Plating Area Original Plating/Process Line Discharge Break Areas 25' Down Gradient of Injection Wells 50' Down Gradient of Injection Wells WELL MW-39 MW-1 MW40 MW-38 MW41 MW-18 TYPE Shallow Bedrock Shallow Bedrock Shallow Bedrock Deep Bedrock Shallow Bedrock Shallow Bedrock DEPTH (ft. bgs) 50-75 25-35 65-95 160-200 25-55 65-85 SAMPLE DATE 6/21/2005 12/12/2005 6/1/2005 12/14/2005 6/22/2005 12/14/2005 5/27/2005 12/12/2005 6/l/2005 = 12/14/2005 5/31/2005 12/13/2005 PARAMETER UNITS RESULT Q I DL RESULT DL RESULT I Q I DL I RESULT I Q I DL RESULT I Q I DO RESULT Q DL RESULT I Q I DL I RESULT I DL RESULT 10 1 DL I RESULT DL RESULT I Q DL RESULT Q DL Field Parameter pH 12.23 10.92 12.23 6.29 7.26 7.73 12.73 13.49 6.58 8.28 6.69 9.72 Specific Conductivity mS 2.26 2.48 2.54 2.42 0.339 2.91 4.05 3.89 0.436 0.688 0.455 0.364 Redox Potential mV 177 -58 -69 46 -106 41 -598 -237 15 -152 -11 -153 Temperature °C 22.58 11.06 16.17 17.39 27.03 11.68 25.52 17.45 18.43 18.18 21.11 15.83 Dissolved Oxygen ppm 4.76 1.27 0.68 0.13 0.52 0.6 0.48 0.73 0.16 0.13 0.24 0.45 Turbidity NTU 1.96 8.15 5.05 NR 15.6 NR 3.55 3.77 23.4 10.3 10.48 2.5 Conventionals Bicarbonate Alkalinity mg/L U 5 U 5 U 5 651 5 147 5 916 5 U 5 U 5 173 5 236 5 191 5 145 5 Carbonate Alkalinity mg/L 140 5 76 5 272 5 U 5 U 5 U 5 143 5 103 5 U 5 U. 5 U 5 U 5 Chloride mg/L 5.4 3 4.7 3 11.6 3 25.6 J 3 12.4 3 21.7 3 4.9 J 6 5.9 J 6 12.2 3 13.7 3 15.5 3 15.8 3 Ferrous Iron mg/L U 0.2 U 0.2 0.097 J 0.2 66 10 UJ 0.2 445 40 0.05 J 0.2 U 0.2 9.6 1 10.1 10 1 0.97 J 0.2 0.06 J 0.2 Nitrate mg/L 1.1 0.5 0.27 J 0.5 0.18 J 0.5 0.25 J 0.5 U 0.5 ' 0.21 J 0.5 U 1 0.24 J 1 0.046 J 0.5 0.2 J 0.5 0.051 J 0.5 0.19 J 0.5 Nitrite mg/L U 0.5 0.98 0.5 0.12 J 0.5 0.65 J 2.5 U 0.5 1.3 J 5 1 Ul 1 1 0.14 J 1 0.1 J 0.5 1 0.14 J 0.5 0.14 J 0.5 0.14 J 0.5 Sulfate mg/L 15 5 10.5 5 13.8 1 J 5 1 5 U 1 5 1 10.9 5 5 U 5 10.7 J 10 8.2 J 10 14.4 J 5 5 U 5 11.3 J 5 5.4 5 Total Organic Carbon mg/L 2.3 1 2 U 1 8.1 1 8,560 100 0.98 J 1 8,950 500 15.8 J 1 13.6 1 1.4 1 80.5 2.1 2.7 1 4.7 1 Total Sulfide mg/L 0.6 U 1 U 1 U 1 3 U 1 0.6 U 1 32 J 40 U 1 1 EU 1 U 1 1 U 1 U1 1 I 1 U 1 Dissolved Gases Carbon dioxide 1g/L 100 J 160 U 170 94,000 E 160 530,000 170 3,300 160 310,000 170 U 160 U 170 130,000 E 160 45,000 170 16,000 160 9,400 170 Ethane µg/L U 0.5 U 2 11 R 25 5.9 2 9.3 3 6.3 2 0.32 J 0.5 1 J 2 0.39 J 0.5 4.6 2 0.67 0.5 3.1 2 Ethene µg/L U 0.5 U 1 8,600 R 25 2.8 1 14 ' 3 U 1 1.6 0.5 4.1 1 48 0.5 57 1 2.8 0.5 80 1 Methane 99/L 0.52 0.5 U 1 150 R 25 7,000 1 640 3 12,000 1 17 0.5 230 1 3 0.5 14,000ji 1 429 0.5 3,100 1 Notes: Q = Qualifier Detection Limit (DL) - The lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. U = Undetected at or below the detection limit J = Estimated UJ = Undetected, detection limit is qualified as estimated E = Concentration exceeded the instrument's calibration range, concentration reported is estimated R = The value reported has been rejected due to the laboratory exceeding the method holding time mg/L = milligrams per liter µg/L= micrograms per liter NR = not recorded due to instrument malfunction 1. VOE injection was performed in early August 2005 F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Table 4 41h Quarter 2005.xls TABLE 4 COMPARISON OF BASELINE AND 120 DAY POST -INJECTION MNA SAMPLING RESULTS Former Pelton and Crane Facility Charlotte, North Carolina LOCATION Truck Well - 75 to 100' Downgradient of Original Plating Area Northern Warehouse WELL MW-42 MW-43 MW-44 MW-45 TYPE Shallow Bedrock Shallow Bedrock Shallow Bedrock Shallow Bedrock DEPTH (ft. bgs). 25-55.3 65-95 65-95.5 65-95 SAMPLE DATE,' 6/l/2005 12/13/2005 6/22/2005 12/13/2005 6/21/2005 12/13/2005 6/21/2005 12/12/2005 PARAMETER UNITS RESULT DL RESULT DL RESULT DL RESULT Q DL RESULT Q DL RESULT Q DL RESULT DL RESULT Q DL Field Parameter pH 6.69 9.09 7.69 10.91 7.49 9.3 8.74 9.5 Specific Conductivity mS 0.413 0.446 0.371 0.349 0.336 0.369 0.236 0.249 Redox Potential mV -420 -129 -519 -172 -386 -120 -372 -124 Temperature °C 19.8 18.98 21.17 17.41 20.72 18.48 22.65 20.61 Dissolved Oxygen ppm 0.22 1.03 0.03 1.15 0.28 1.05 0.31 0.87 Turbidity NTU 91.4 4.01 I97 9.49 NR 4.71 1 932 1 f 22.4 Conventionals Bicarbonate Alkalinity mg/L 157 5 179 5 142 5 153 5 U 5 148 5 U 5 105 5 Carbonate Alkalinity mg/L U 5 U 5 U 5f123 5 380 5 U 5 270 5 U 5 Chloride mg/L 16.3 3 13.9 3 14.1 3 ki 3 9 3 13 3 13.8 3 8.2 3 Ferrous Iron mg/L 0.79 0.2 8.2 1 UJ 0.2 0.2 U 0.2 U 0.2 U 0.2 1.9 0.2 Nitrate mg/L 0.035 J 0.5 0.2 J 0.5 0.23 J 0.5 0.2 0.5 0.04 J 0.5 0.2 J 0.5 0.052 J 0.5 0.11 J 0.5 Nitrite mg/L 0.12 J 0.5 0.14 J 0.5 0.14 J 0.5 0.14 J 0.5 0.1 J 0.5 0.14 J 0.5 0.13 J 0.5 U 0.5 Sulfate mg/L 19.9 J 5 1.9 U 5 18.6 5 9 5 21.3 5 5 15.4 5 1.9 J 5 Total Organic Carbon mg/L 2.2 1 2.2 U 1 1.3 1 1.9 U 1 1.4 1 nlu 1 1.9 1 1.4 U 1 Total Sulfide mg/L U 1 U 1 U 1 1 U 1 0.6 U 1_ 1 0.6 U 1 1 U 1 Dissolved Gases Carbon dioxide µg/L 100,000 E 160 45,000 170 3,100 1601 12100 170 2,200 160 9,300 170 220 160 26,000 1 00 Ethane µg/L 530 R 25 4.4 2 14 1.5 7.5 2 5.6 0.5 4.3 2 4.6 0.5 0.56 J 2 Ethene µg/L 12,000 R 25 2.2 1 37 1.5 1 14 1 6.4 0.5 3.7 1 1 U 0.5 U 1 Methane µg/L 4,300 R 25 630 1 400 1.5 320 1 32 0.5 120 1 32 0.5-, 10 1 Notes: Q = Qualifier Detection Limit (DL) - The lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. U = Undetected at or below the detection limit J = Estimated UJ = Undetected, detection limit is qualified as estimated E = Concentration exceeded the instruments calibration range, concentration reported is estimated R= The value reported has been rejected due to the laboratory exceeding the method holding time mg/L = milligrams per liter µg/L = micrograms per liter NR = not recorded due to instrument malfunction 1. VOE injection was performed in early August 2005 Page 2 of 2 F:\OFICEAGCTROJECTS\Files\2004-1292\Reports\Quarrerly\Table 4 4th Quarter 2005.xls TABLE 5 COMPARISON OF BASELINE AND 120 DAY POST -INJECTION VOLATILE SAMPLING RESULTS Former Pelton and Crane Facility Charlotte, North Carolina Page 1 of 2 LOCATION 150' Upgradient of Original Plating Area Original Plating/Process Line Discharge Break Areas 25' Down Gradient of Injection Wells 50' Down Gradient of Injection Wells WELL MW-39 MW-1 MW-40 MW-38 MW-41 MW-18 TYPE Shallow Bedrock Shallow Bedrock Shallow Bedrock Deep Bedrock Shallow Bedrock Shallow Bedrock DEPTH (ft. bgs) 50-75 25-35 65-95 160-200 25-55 65-85 SAMPLE DATE 6/21/2005 12/12/2005 6/l/2005 12/14/2005 6/22/2005 = 12/14/2005 5/27/2005 12/12/2005 6/l/2005 12/14/2005 5/31/2005 12/13/2005 PARAMETER UNITS RESULT Q I DL I RESULT IDL RESULT I Q I DL I RESULT I Q DL I DL I RESULT Q DL RESULT I Q I DL I RESULT 0 DL RESULT 10 DL I RESULT I Q I DL RESULT I Q I DL I RESULT I Q I DL Field Parameter 1,1,1-Trichloroethane µg/L U 1 U 1 U 50 U 100 U1 50 U 10 U 201 U 1 10 U 501 U 100 U 20 U 10 1,1,2,2-Tetrachloroethane µg/L U 1 U 1 U 50 U 100 U 50 UJ 10 U 20 U 10 U 50 U 100 U 20 U 10 1,1,2-Trichloroethane µg/L UJ 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 UJ 20 U 10 11-Dichloroethane µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 1.6 J 10 U 50 U 100 4.8 J 20 3.8 J 10 11-Dichloroethee µg/L U 1 U 1 19 J 50 U 100 12 J `50 U 10 U 20 1.9 J 10 16 J 50 U 100 41 20 3.8 J 10 1,2-Dichloroethane µg/L U 1 U 1 U 50 1 U 1 100 U 50` U 10 U 20 U 10 U 50 U 100 U 20 U 10 1,2-Dichloroethee (total) µg/L U 1 U 1 2700 50 4,000 100 1000 50 260 10 130 20 190 J 10 1900 50 650 100 1300 20 650 D 30 1,2-Dichloropropane µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 2-Butanone µg/L 4.3 J 5 1.8 J 5 R 250 400 J 500 R 250 560 J 50 R 100 R 50 R 250 R 500 R 100 R 50 2-Hexanone µg/L UJ 5 U 5 U 250 U 500 UJ 250 U 50 UJ 100 U 50 U 250 U 500 UJ 100 U 50 4-Methyl-2-pentanone µg/L UJ 5 U 5 U 250 U 500 U 25.0 5.7 J 50 R 100 U 50 U 250 U 500 R 100 U 50 Acetone µg/L 65 J 10 39 J 10 76 J 500 430 J 1000 84 J 500 62 J 100 65 J 200 190 J 100 R 500 250 J 1000 R 200 31 J 100 Benzene µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 1.7 J 10 Bromodichloromethane µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Bromoform µg/L U 1 UJ 1 UJ 50 U 100 U 50 U 10 U 20 UJ 10 UJ 50 U 100 UJj 20 U 10 Bromomethane µg/L U 2 U 2 U 100 U 200 U 100 U 20 U 40 U 20 UJ 100 U 200 U 40 U 20 Carbon disulfide µg/L U 1 U I 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Carbon tetrachloride µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Chlorobenzene µg/L U 1 U 1 U 50 U 100 U. 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Chloroethane µg/L U 2 U 2 UJ 100 U 200 U 100 U 20 U 40 U 20 U 100 U 200 U 40 U 1 20 Chloroform µg/L 0.84 J 1 U 1 U 50 U 100 6.2 J 50 U 10 U 20 U 10 U 50 U 100 Ul 20 1 U 1 10 Chloromethane µg/L 0.21 J 2 0.17 J 2 UJ 100 U 200 U 100 U 20 Ul 40 U 20 U 100 U 200 Ul 40 1 U 20 cis-1,3-Dichloropropene µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Dibromochloromethane µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Ethylbenzene µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Methylene chloride µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Styrene µg/L U 1 U 1 U 50 U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Tetrachloroethene µg/L U 1 0.11 J 1 U 50 U 100 U 50 U 10 U 20 1.6 J 10 U 50 U 100 U 20 U 10 Toluene µg/L 0.76 J 1 0.15 J 1 5.4 Jr U 100 U 50 U 10 4.8 J 20 4.5 J 10 U 50 U 100 U 20 1.2 J 10- trans- 1,3-Dichloropropene µg/L UJ 1 U 1 U U 100 . UJ 50 U 10 U 20 U 10 U 50 U 100 UJ 20 U 10 Trichloroethene µg/L 0.16 J 1 U 1 840 420 100 1500 50- 23 10 400 20 310 J 10 610 50 U 100 670 20 9.8 J 10 Vinyl chloride µg/L U 2 U 2 940 360 200 440 100 46 20 50 40 120 J 20 600 100 3,800 200 980 40 680 D 60 Xylenes (total) µg/L 0.53 J 1 U 1 U U 100 U 50 U 10 U 20 U 10 U 50 U 100 U 20 U 10 Q = Qualifier Detection Limit (DL) - The lowest concentration that can be reliably achieved within specified limits of precision and accuracy during routine laboratory operating conditions. U = Undetected at or below the detection limit. J = Estimated UJ = Undetected, detection limit is qualified as estimated R = The value reported has been rejected due to the laboratory exceeding the method holding times. pg/L = micrograms per liter 1. VOE injection was performed in early August 2005 F:\OFICEAGOPROJECTS\Files\2oo4-I292Uteports\QoarterlylTable5 4th Quarter 2005.xls TABLE 5 COMPARISON OF BASELINE AND 120 DAY POST -INJECTION VOLATILE SAMPLING RESULTS Former Pelton and Crane Facility Charlotte, North Carolina LOCATION Truck Well - 75 to 100' Downgradient of Original Plating Area Northern Warehouse WELL MW42 MW43 MW-44 MW-45 TYPE Shallow Bedrock Shallow Bedrock Shallow Bedrock Shallow Bedrock DEPTH (fL bgs) 25-55.3 65-95 65-95.5 65-95 SAMPLE DATE 6/l/2005 12/13/2005 6/22/2005 12/13/2005 6/21/2005 12/13/2005 6/21/2005 12/12/2005 PARAMETER UNITS RESULT DL RESULT DL RESULT DL RESULT DL RESULT DL RESULT DL RESULT DL RESULT DL Field Parameter 1, 1, 1-Trichloroethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 1,1,2,2-Tetrachloroethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 1,1,2-Trichloroethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 1,1-Dichloroethane µg/L 4 J 20 5.3 J 20 6.3 J 50 U 100 9.9 J 50 11 J 33 5.9 2 9.5 1 1,1-Dichloroethene µg/L 8.6 J 20 10 J 20 10 J 50 13 J 100 11 J 50 15 J 33 4.4 2 6.4 1 1,2-Dichloroethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 1,2-Dichloroethene (total) µg/L 1000 20 1600 20 920 50 1900 100 770 50 2200 J 33 84 2 110 DJ 2 1,2-Dichloropropane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 2-Butanone µg/L R 100 R 100 R 250 R 500 R 250 R 170 R 10 R 5 2-Hexanone µg/L U 100 U 100 UJ 250 U 500 UJ 250 U 170 UJ 10 U 5 4-Methyl-2-pentanone µg/L U 100 U 100 U 250 U 500 U 250 U 170 U 10 U 5 Acetone µg/L R 200 U 200 85 J 500 290 J 1000 89 J 500 100 J 330 12 U 20 10 R 10 Benzene µg/L U 20 U 20 U 50 U 100 U 50 U 33 0.35 J 2 0.39 J 1 Bromodichloromethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Bromoform µg/L UJ 20 U 20 U 50 U 100 U 50 U 33 U 2 UJ 1 Bromomethane µg/L UJ 40 U 40 U 100 U 200 U 100 U 67 U 4 U 2 Carbon disulfide µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Carbon tetrachloride µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Chlorobenzene µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 0.1 J 1 Chloroethane µg/L U 40 U 40 U 100 U 200 U 100 U 67 U 4 U 2 Chloroform µg/L 2.7 J 20 U 20 U 50 U 100 U 50 U 33 0.66 J 2 0.54 J 1 Chloromethane µg/L U 40 U 40 U 100 U 200 U 100 U 67 0.45 J 4 U 2 cis-1,3-Dichloropropene µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Dibromochloromethane µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Ethylbenzene µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Methylene chloride µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Styrene µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U 1 Tetrachloroethee µg/L U 20 U 20 U 50 U 100 U 50 U 33 1.7 J 2 2.7 1 Toluene µg/L U 20 U 20 U 50 U 100 U 50 U 33 U 2 U I trans-1,3-Dichloropropene µg/L U 20 U 20 UJ 50 U 100 UJ 50 U 33 UJ 2 U 1 Trichloroethee µg/L 410 20 16 J 20 1700 50 710 100 2100 50 950 J 33 35 2 33 J 1 Vinyl chloride µg/L 340 40 380 40 350 100 320 200 83 J 100 210 J 67 7 4 6.1 J 2 Xylenes (total) µg/L U 20 U 1 20 U 50 U 100 U -501 U 33 U 2 U 1 Notes: Q = Qualifier Detection Limit (DL) - The lowest concentration that can be reliably achieved within specified limits of precision and accuracy dining routine laboratory operating conditions. U = Undetected at or below the detection limit. J = Estimated UJ = Undetected, detection limit is qualified as estimated R = The value reported has been rejected due to the laboratory exceeding the method holding times. pg/L = micrograms per liter 1. VOE injection was performed in early August 2005 Page 2 of 2 F:\OFICEAGC\PROJECT'S\Files\2004-1292\Reports\Quarlerly\TableS 4th Quarter 2005.xts FIGURES F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Fourth Quarterly Report2005,doc Revision I Description Date I BY edgef �• y A }l v�J C4 j 1 INS..'�� - P. r > t ✓ t `c ll;t Bwoex i 1 � `,�1 � k. '''Y�`� � f � if �.tt ���.+//��►—• Basemap Source: U.S.G.S. 7.5 minute quadrangles of East and West Charlotte, North Carolina, dated 1967 and 1993 respectively. Notes: 1. One —quarter and one—half mile radius FORMER PEL TON & CRANE FACILITY shown. 200 CLANTON kO AD, CHARL U TTL, NO H 1H CAROLINA 2. Latitude: 35' 11' 45" c11e=1400• Longitude: 80' 52' 30" Originated i inat d By. SITE LOCATION MAP row, By S.M.F. Necked By. Advanced GeoServices Corp. B.B.B. 1055 Andrew Drive, Suite A roject Mgr. West Chester, Pennsylvania 19380 S.W.K. (610) 840-9100 0 1400 wg No. /G. FAX: (610) 840-9199 99596-39-03 R.)c Nu J:\CLANTDN\DRAWINGS\99596-39\99596-39-03 SCALE: FEET 2004-1292-03 FIGURE: 1 Revision Description Date T By I IW-11S IW-I 11 1 MW-f8 1 ' —1 fit J 18 iw— s IW-40 W-41 INSERT No. 1 SCALE: 1 "=50' MW-46 MW-47,0 MW-49 I I ' I I I I I I SEE INSERT lo. 1 I , i I I I W11 11 1 1 I MVjI-24* 1 I ; 1 i ' MW 7 W— 5 1 L�.W_MW-32 jg MW-12tji� I 1 I I I1 I 1 I 1 I 1 I I I 1 1 MW-33 1 W-36 I I �I MW-35 SO UT11 'rRtr0 MW-34 NOTES- 1 L tY . BASEMAP FROM R.B. PHARR & ASSOCIATES, PA. STREET BOUNDARY SURVEY FOR 200 CLANTON ROAD, CHARLOTTE, NC, MAY 18, 1999. 2. LOCATION OF UNDERGROUND UTILITIES ARE NOT SHOWN. 4. PROPERTY BOUNDARIES FOR LOTS ON THE SOUTH SIDE OF CLANTON ROAD AND NORTH SIDE OF CLANTON ROAD, WEST OF SITE, ARE 3. MONITORING WELL AND INJECTION WELL LOCATIONS SURVEYED BY APPROXIMATE AND ARE BASED ON TAX PARCEL MAPS OBTAINED R.B.PHARR & ASSOCIATES, PA. HORIZONTAL DATUM WAS NORTH FROM THE MECKLENBURG COUNTY INTERNET GIS SYSTEM. CAROLINA PLANE COORDINATES, NORTH AMERICAN DATUM (NAD83) AND THE VERTICAL DATUM WAS NATIONAL VERTICAL GEODETIC 5. OFF —SITE BUILDING LOCATIONS ARE APPROXIMATE. DATUM (NVGD29). 201— 07 \2004-1201— 07— 29 PELTON STREET I Ilj 114 I II IrE I I IE_ S —�1 ' N 1W AIW 11 IW� I I I� MW-18 — IrMW-4o W-41 —18 II Do-, _ 2 I �IMW-43 I I I — ASPHALT I W MW PARKING ® Ili MW-22 I MW 21A �♦ MW-4 1 MAW-16 / / /MW 7p.__, �MW-14 WIN-2 / I I I I 9 LEGEND — — SITE PROPERTY BOUNDARIES — — — — PROPERTY BOUNDARIES — - — . — . — EASEMENT BOUNDARY — — — — — SETBACK BOUNDARY ?VW-28 SHALLOW BEDROCK MONITORING WELL ♦MW-22 DEEP BEDROCK MONITORING WELL OVERBURDEN *MW-9 MONITORING WELL *W-1S INJECTION WELL CLUSTER SAW-29 t t 3TW-28 W-26 FORMER PELTON & CRANE FACILITY / I 200 CLANTON ROAD, CHARLOTTE, NORTH CAROLINA t Scale: MONITORING AND INJECTION 1' =100' riginoted By. WELL LOCATION PLAN C.P. Drawn By. P.S.G. Checked By. B.B.B. Project Mgr: S.W.K. 0 25 50 100 D2 No. gg2004-1201—G7-29 SCALE: FEET IdWI( Q 4 2006 0 Advanced GeoServices Corp. 1055 Andrew Drive Suite A West Chester, Pennsylvania 19380 (610) 840-9100 • FAX: (610) 840-9199 ject No. 2004-1292-03 FIGURE: 2 PLATE F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Fourth Quarterly Rq*rt2O05.doc ATTACHMENT A F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarrerly\Fourrh Quarterly Report2O05.doc February 17, 2006 (Revised March 1, 2006) Mr. Robert L. Friedman Siemens Medical Solutions USA, Inc. 51 Valley Stream Parkway Malvern, PA 19355 RE: Former Pelton and Crane Facility REC Program -Indoor Air Sampling Dear Mr. Friedman: ADV . CED. eoSenrices Engineerrn8 for the Fitduoxmmt P><aming farPmpfe 1055 Andrew Drive, Suite A West Chester, PA 19380-4293 te1610.840.9100 fax 610.840.9199 www.advancedgeoservices.com 2004-1292-02 This letter provides a summary of the field activities and results regarding the indoor air sampling activities conducted at the Former Pelton and Crane Facility (Facility) by Advanced GeoServices Corp. (AGC) during November 2005. Field Activities The air sampling was performed overnight while the building was closed to reduce the potential for sample concentration dilution. The samples were collected using SUMMATm canisters (6- liter, evacuated, stainless steel spheres equipped with a pre -calibrated 12-hour flow controllers). Six SUMMATm canisters were set in place inside the Facility after the employees left for the day (approximately 4:30 p.m. to 5:30 p.m.). The interior canisters were placed 3 to 5 feet above the floor level. A seventh SUMMATm canister was placed outside the building on the ground surface near Pelton Street. This location was selected since it is upgradient of the known extent of VOC-impacted groundwater. Figure 1 shows the air monitoring locations. Below are the air sample numbers and location descriptions of the seven SUMMATm canisters. Sample Location IAS-01-01 1972 Building Expansion IAS-01-02 Former Second Plating/Cleaning Area IAS-01-03 Former Paint Room IAS-01-04 Former Machine Shop IAS-01-05 Former Fabrication Area IAS-01-06 Former Original Plating Room IAS-01-07 Outside the Facility, East side near Pelton Street The locations were consistent with previous indoor air sampling locations. F:\OFICEAGC\PROJECTS\Files\20041292\Communications\ll Og Oiairsampling.doc Mr. Robert L. Friedman 2004-1292-02 February 17, 2006 (Revised March 1, 2006) Page 2 of 4 AGC returned to the Facility at 5:30 a.m. on November 13, 2005 to turn off and collect the SUMMAT'm canisters. All SUM1WATm canisters were turned off between 6:00 a.m. and 6:30 a.m. The ending SUMMATm canister pressure was also documented. The SUMMATM canisters were relinquished and shipped to Pace Analytical Services, Inc. in Minneapolis, Minnesota for Volatile Organic Compound (VOC) analysis utilizing EPA Methods TO-14 and TO-15 with Select Ion Monitoring. Site Constituents of Concern The VOC Constituents of Concern (COCs) in soil and/or groundwater associated with the Facility are as follows: • Tetrachloroethene (PCE); • Trichloroethene (TCE); • 1,2-Dichloroethene (1,2-DCE); • 1, 1 -Dichloroethene (1,1-DCE); • Vinyl chloride; • Bromomethane; • 1,2-Dichloropropane; • Chloromethane; and, • Methylene chloride. Air Quality Sample Results The validated air sampling analytical results are included in Attachment A. Table 1 provides a summary of the results for the aforementioned nine site VOC COCs. Table 2 provides a summary of the results for the non -site VOCs detected in at least one sample at/or above the respective laboratory reporting limit (RL). The REC Implementation Guidance Manual, Appendix DA suggested the most current U.S. Environmental Protection Agency Subsurface Vapor Intrusion Guidance be used to evaluate indoor air exposure due to vapor intrusion from impacted soil and groundwater. As such, AGC developed screening level air concentration values for the site COCs based on the current industrial use of the Site. Screening values were developed for both a target hazard quotient (THQ) ' of 1 and target carcinogenic risk (TCR) of 1.0 x 104 (i.e., the upper limit of the acceptable risk range) for each COC. The lower of the two screening values was used to compare to the indoor air concentrations measured at the Site. Toxicity values for each COC were selected based on USEPA developed information in the Integrated Risk Information System (IRIS) database or Health Effects Assessment Summary Tables (BEAST). The Pennsylvania Land Recycling Program Technical Guidance Manual was used as a third source for cis 1,2-DCE since toxicity values were not provided in either IRIS or BEAST for this COC. Exposure factors were selected from USEPA's Risk Assessment Guidance and based on F:\OFICEAGCTR07ECTSWilu120041292\Communications\I l 08 05av sampling doe Mr. Robert L. Friedman 2004-1292-02 February 17, 2006 (Revised March 1, 2006) Page 3 of 4 industrial land use. Attachment B includes the screening level air concentration calculations. In addition, the Occupational Safety and Health Administration's (OSHA) Permissible Exposure Limits (PELs) for general industry based on the current use of the Facility are shown on Tables 1 and 2. All of the VOC COCs were below the OSHA PELs. All the November 2005 sample results were below the calculated screening level indoor air concentrations, except one sample (IAS-0304). This sample was located in the Former Machine Shop, and exceeded the screening level indoor air concentration for TCE (5.03 ug/m3 vs 4.0 ug/m3). Twelve non-COC VOCs were detected during this event. All of the VOCs were well below the PELs. No screening level indoor air concentrations were developed for.these constituents since they are not Site COCs. Therefore, the OSHA PELs are the appropriate standards to use for comparison. Conclusion and Recommendation All of the air concentration results for the site VOC COCs and non -site VOCs were significantly below the OSHA PELs. All of the COCs, with one exception, were also below the calculated screening level indoor air concentration developed using the USEPA's current Subsurface Vapor Intrusion Guidance. Three sampling rounds have been completed at the Site (two fall and one winter event). Only two exceedances of the calculated indoor air screening levels have occurred during these three events. Each exceedance was at a different location and were both for TCE. Current technical guidance on indoor air sampling recommends the sampling program be designed to account for temporal, meteorological and seasonal effects, or to try to simulate a worst -case scenario by sealing the building for 24 to 48 hours. Ultimately, the best approach is to characterize variability by conducting multiple sampling events 1.2. AGC believes no remedial action is necessary at this time due to the marginal and limited exceedance of the screening values. However, AGC recommends the sampling be repeated in the early spring 2006 to account for seasonal variability. This next recommended sampling event will complete two data sets two years apart for the same two seasons. IU.S. Environmental Protection Agency (USEPA, 2003b), Draft Guidance for Evaluting the Vapor Intrusion to Indoor Air Pathway from Groundwater and Soils, EPA 530-F-02-052, November 2002. 2Massachusetts Department of Environmental Protection (PADEP 2002), Indoor Air Sampling and Evaluation Guide, WSC Policy #02-430, April 2002. \O; F:\OF[CEAGWROJECTS\Files\2004-1292\Communications\l1-08 05a'u sampling doe Mr. Robert L. Friedman 2004-1292-02 February 17, 2006 (Revised March 1, 2006) Page 4 of 4 Please contact Steve Kirschner at 610-840-9117 if you have any questions regarding this data. Sincerely, ADVANCED GEOSERVICES CORP. d- s /17— Stephen schner, P.E. Project Consultant aul G. Stra an, eSM Senior Project Consultant SWK:PGS:vm Enclosures cc: C. Case - T. McKittrik F:\OECEAGC\PROJECTS\Files\20041292\Communications\l l 08 05au samplin&doc TABLES F:\OFiCEAGMROJEC7S\Fila\2004-1292\CommuniatiomV l OB 05air wnPlin&dm TABLE 1 INDOOR AM MONTTORING SUMMARY OF STTE SPECIFIC COC VOLATILE ORGANIC COMPOUND ANALYTICAL RESULTS Former Pelton and Crane Site Charlotte, North Carolina Sample Location USEPADraft Subsurface Vapor Intrusion Guidance (11-2002) TCR 10-4, THQ=1 200 4 5.1 90 35 90 136 4 46 OSHA Permissable Exposure - UntieIndoor (PEL) NA4 350,000 77,800' 207,000 794,000' 86,750 678,000 537,000 2,560 IAS-01-01 1081127-001 IIIIV03 Air Result Q RL U 2 9 U 2.63 U 3 U LS I 1 U 2.9 U 2.68 U 4.96 U 3.39 U 1.97 IAS-02-01 105480818 0329/04 Indoor Air Result Q RL U 0.04 U 3.4 U 3.9 0.0987 0.021 0.121 0.04 U 0.11 1.86 0.069 0.546 0.055 0.0961 0.026 IAS-03-01 1023805001 11/18/05 Indoor Air Result Q RL 0.133 0.037 U 3.1 U 2.6 0.798 0.073 U 0.028 0.219 0.071 2.21 0.24 .1.37 0.023 0.0702 0.018 IAS-01-02 1081127-002 11/12/03 Indoor Air Result Qr2.49 U U U U .5 U 2.78 U 2.54 U 4.76 U 3.22. U 1.87 IAS-02-02 105480826 0329/04 Indoor Air Result Q RL U 0.028 U 23 U 2.6 0.336 0.015 0.0766 0.028 U 0.071 0.965 0.048 . 0.393 0.037 0.0286 0.018 IAS-03-02 1023805002 11/18/05 Indoor Air Result Q RL U 0.039 U 3.4 U 2.8 0.882 0.31 0.169 0.03 0.286 0.074 1.65 0.051 1.42 0.025 0.0252 0.019 IAS-01-03 1081127-003 11/12/03 Indoor Air Result Q RL U 2.78 U 2.49 U 2.84 U 1 1.45 U 2.78 U 2.54 U 4.76 U 3.22 U 1.87 LkS-02-03 IOS480834 0329/04 It Result Q RL U 0.028 U 2.3 U 2.6 0.462 0.015 0.153 0.028 1.41 0.71 2.72 E 0.048 ' 0.71 0.037 U 0.018 IAS-03-03 1023805003 11/18/OS It Q Air Result Q RL U 0.04 U 3.5 U 2.9 0.693 0.016 0.443 0.031 07166 0.078 9.65 0.53 3 0.26 U 0.019 IAS-01-04 1081127-004 11/12/03 Indoor Air Result Q RL U 2.78 U 2.49 U 2.84 U 1.45 U 2.78 U 2.54 U 4.76 U 3.22 U 1.87 IAS-02-04 105480842 0329/04 Indoor An Result Q RL U 0.028 U 2.3 U 2.6 0.861 D 0.29 0.306 0.028 0.0883 0.071 1.1 0.048 1.15 0.037 U 0.037 IAS-03-04 1023805004 I1/18/OS Indoor Air Result Q RI, U 0.037 U 3.1 U 2.6 0.609 0.015 U 0.028 0.219 0.071 1.65 0.048' -:•° ;S! � 0.23 U 0..23 Lab ID Sample Date Matrix Parameter 1,1-Dichloroethene 1,2-Dichloropropane romomethane Chloromethane cis-1,2 Dichloroethene Methylene chloride Tetracbloroethene Trichloroethene Vinyl chloride Units µg/m, 99/m3 µ8/m' µElm 1191m3 991m3 9962 µ8IM µFA Sample Location USEPA Draft Subsurface •Vapor Intrusion ' Guidance(11-2002) TCR=10-4, THQ=1 200 4 5.1 90 35 .90 136 4 46 OSHA Permissable Exposure Limle (PEL) NA4 350,000 77,80e 207,000 794,0003 86,750 678,000 537,000 2,560 IAS-01-05 1081127-005 11/12/03 Indoor Air Result Q RL U 2.86 U 2.58 U 2.92 1.57 1.49 ' U 2.86 U 2.61 U 4.9 U 3.33 U 1.92 IAS-02-05 105480859 0329/04 Indoor Air Result Q RL U 0.052 U 4.2 U 4.7 1.28 D 0.27 0.806 0.052 0.191 0.13 1.38 0.09 2.08 0.066 U 0.031 IAS43-05 1023805005 11/19/05 Indoor Air Result Q RL U 0.039 U 17 U 15 1.57 0.16 0.685 0.03 0.293 0.074 1.32 0.051 3.11 0.25 0.148 0.019 IAS41-06 1081127-006 11/12/03 Indoor Air Result Q RL U 1 2.74 U 2.44 U 2.76 1.47 1.43 U 2.74 3.04 . 2.47 U 4.69 U 3.17 U 1.82 IAS-02-06 105480867 0329/04 Indoor Air Result Q RL IT 0.031 U 16 U 2.9 1.3 D 0.31 1.01 D 1 0.6 0.706 0.078 2.76 E 0.053 g�' "'ry 0.82 U 0.019 IAS-03-06 1023805006 11/18/05 Indoor Air Result Q RL U 0.037 U 3.1 U 2.6 0.588 0.015 U 1 0.028 0.201 0.071 0.896 0.048 2.51 0.23 U 0.018 iAS-01-07 1081127-007 I IIIV03 Outdoor Air Result Q RL U 2.58 U Z35 U 2.64 U 1.41 U 2.58 U 2.37 U 4.41 U 3 U 1.74 IAS42-07 105480875 0329/04 Outdoor Air Result Q RL U 1 0.027 U . 2.3 U • 2.6 0.0357 0.014 U 0.027 U 0.071 3.38 D 0.47 0.0546 0.036 1 U 1 0.017 IAS-03-07 1023805007 11/18/05 Outdoor Air Result Q RL U 0.034 U 15 U 12 0S46 0.014 U 0.026 0.145 0.067 0.414 0.045 0.0874 0.022 U 0.017 Lab M Sample Date Matrix Parameter 1,1-Dichloroethene 1,2 Dichloropropane Bromomethane 'hloromethaae '1,2 Dichloroethene Methylene chloride Tetrachloroethwe Trichioroethene Vinyl chloride Units µ91m3 µ9/m3 µgin3 µg/m3 µg/m3 µg/m3 µ!/m3 µ911n3 µ-- Notes: 4. NA -None available. 5. Ceiling limit, no PEL U The analyte was not detected at the given reporting limit. D The value was obtained from a analysis of a diluted sample. E Concentration exceeded the instrumenfs calibration range and should be considered as estimated The sample should be diluted. F:IOFICEAGLVR07EC1'S1FilesVOD4-12921CommL6rauons%Table 1 airsamp9n&xls TABLE 2 • INDOOR AIR MONITORING SUMMARY OF NON-COC VOLATILE ORGANIC COMPOUND ANALYTICAL RESULTS Former Pelton and Crane Site Charlotte, North Carolina ziampk Location OSHA Permissable Exposure Line (PEL) NA 35,000 400,000 NA 120,000 120,000 3,247 159.885 240,000s 4,950,000 435,000 435,000 435,000 420,006s 765,995 790,0006 IAS-01-01 1081127-001 11/12/03 Indoor Air Result Q RL U 3.55 U 4.12 U 2.91 U 2.43 U 3.54 5 3.6 2.66 2.11 U 3.96 U 3.57 U 3.82 3.75 2.78 4.9 2.52 4.9 .5 U 2.6 t23-'36 2.76 NR IAS-02-01 105480818 .03/29/04 Indoor Air Result Q RL 0.388 0.055 0216 0.07 U 0.091 U 0.041 U 4.7 7 4.7 8.77 D 0.65 U 0.064 0.0794 0.05 U 4.9 6.62 3.7 2.5 7.1 7.5 33 80.4 3.6 U 0.04 IAS-03-01 1023805001 11/18/05 Indoor Air Result Q RL 0.105 0.038 U 0.049 U 0.062 9.99 3.3 0.202 0.029 U 3.3 2.7 0.11 0.512 0.045 0.298 0.035 U 3.4 2.65 0.15 13.7 5.7 4.86 3 U 2.9 62.8 2.6 U 0.028 IAS-01-02 1081127-002 11/12/03 Indoor Air Result Q RL U 3.33 U 3.91 U 2.79 U 2.31 U' 3.39 U 3.45 2.11• 1.98 3.78 U 3.42 U 3.62 2.91 2.65 10.15 4.85 3.05 2.38 U 2.47 14.55 2.64 NR IAS-02:02 105480826. 03/29/04 Indoor Air Result Q RL 0.311 0.038 U 0.049 U 0.062 U 0.029 U: �3-20.0741 U 4.55 D 0.45 0.0601 0.045 0.0432 0.035 U 3.4 4.15 2.5 15.4 4.9 3.97 2.3 372 2.5 • HU 0-028 IAS-03-02 1023805002 11/18/05 Indoor Air Result Q RL 0.183 0.04 U 0.052 U 0.066 9.49 3.6 0.03 5.5 3.6 7.79 0.49 0.831 0.047 1.09 .0.037 U 3.6 4.86 0.66 24.7 6.2 4.86 3.2 U' 3.1 162 14 U 0.03 IAS-01-03 1081127-003 11/12/03 Indoor Air Result Q RL U 333 U 3.91 U 2.79 U 2.31 U 3.39 U 3.45 U 1.98 3.78 U 3.42 U 3.62 U 2.65 8.83 4.85 2.47 2.38 U 2.47 9.96 2.64 NR IAS-02-03 105480834 03/29/04 Indoor Air Result Q RL 0.322 0.038 0.286 0.049 U 0.062 U 0.029 U 3.2 7.5 3.2 3.15 D 022 0.064 0.045 0 243 0.035 3.47 3.4 6.62 2.5 22.5 4.9 6.18 2.3 53.6 2.5 0.0399 0.028 IAS-03-03 1023805003 11/18/05 Indoor Air Result Q RL 0.0887 0.042 U 0.054 U 0.066 13.5- 3.7 0.0453 0.032 5.5 3.7 5.52 0.24 0.416. 0.049 3.37 0.38 U 3.7 6.18 0.34 37.1 M6.12.8 10.2 U 456 57 IAS-01-04 1081127-004 11/12/03 Indoor Air Result Q RL U 333 U 3.91 U 2.79 U 231 U 339 U 3.45 U 1.98 3.78 U 3.42 3.97 3.62 3.44 2.65 4.85 3.13 2.38 U 2.47 13.02 2.64 IAS-02-04 105480842 03/29/04 Indoor Air Result Q RL 0.133 0.038 U 0.049 0.0864 0.062 U 0.029 U 3 2 3.45 3.2 422 D 0.45 0.0633 0.045 0.0633 0.035 U 3.4 3 2.5 11.5 4.9 3.05 23 29.1 2.5 IAS-03-04 1023805004 11/18/05 Indoor Air Result Q RL 8.32 0.38 U 0.049 U 0.062 U 3.3 0.494 0.029 U 3.3 224 0,22 0.448 0.045 .44 00 5 U 3.4 7.06. 0.31 37.1 5.7 7.5 3 U 2.9 774 51 Lab ID Sample Date Matrix Parameter 1,1,1-Trichloroethane 1,1,2,2-Tetrachlomethane 1,1-Dichloroethane 1,2-Dichloroethane 1,3,5-Trimethylbenzene 1,2,4=Trimethylbenzene Benzene Carbon tetrachloride Chloroform Dichlorodifluoromethane Units µg/m3 µg/m? µg/m3 99112 µg/m3 µgJm3 µg/m3 99hr3 µg/m3 µg/m3 3 µghr Ethylbenzene mXy1cneene µg�3 o-Xylene µg/m3 Styrene µg/m3 Toluene• µg/m3 Mans-1,2-Dichloroethene µghn3 U 0.031 NR U 0.028 0.0443 0.028 'ample L.ocauon ID 1.,a wle Date OSHA IAS-01-05. IAS-02-05 Permissable 1081127-005 105480859 Exposure I 11/12/M naMoind IAS-03-05 IAS-01-06 IAS-02-06• IAS-03-06 lAS-01-07 IAS-02-07 IAS-03-07 023805005 1081I27-006 105480867 1023805006 1081127-007 105480875 1023805007 11/18/05 11/12/03 03/29/04 Matrix Parameter 1,1,1-Trichloroethane Units µg%m3 Limie (PEL) NA Indoor Result Air Q U RL 3.49 Indoor Result 0.41 Q Air RL 0.067 Indoor Result 0.887 Q Air RL 0.04 Indoor Result Air Q U RL 3.33 Indoor Result 1.39 Q D Air RL 0.83 i1/18/OS Indoor Result 0.0832 Q Air RL 0.038 ILlLV03 Outdoor Result 9.43 4.21 Q U U U U U U U U U U U U U NR Air RL 03/29/04 Outdoor Result Q Air RL 11 Ou Result 3.16 3.71 2.59 2.19 3.15 3.2 1.88 3.52 3.18 3.37 2.47 4.85 2.25 2.34 2.45 0.061 1.23 2.68 U U U U U D U U U U U U U 0.037 0.047 0.058 0.028 3.1 3.1 0.21 0.043 0.034 3.3 2.4 4.4 2.2 2.4 0.027 0.0887 0.0407 1.33 0.492 0.109 2.69 132 1,1,2,2-Tetachloroethane 1,1. Dichlomethane 1,2-Dichloroethane µglms µg/m3 µg/m3 35,000 400,000 NA U U U 4.05 2.87 2.39 0.174 U U 0.091 0.11 0.053 U U U 0.052 0.066 18 U U U 3.84 2.75 2.27 0.148 U U 0.054 6.066 .0.032 U U U 0.049 0.062 3.3 1,3,5-Trimethylbenzene 1,2,4-Trimethylbenzene Benzene Carbon tetrachloride Chloroform Dichiorodifluoromethane Ethylbenzene m+p-Xylene o-Xylene Styrene Toluene trans-1,2-Dichloroethene µg/m3 µg/m3 11a µg/m3 µg/m3 µg/m3 µa Agin? µg/m3 99/m3 µg/m3 99IM3 120,000 120,000 3,247 159.88' 240,0004 4,950,000 435,000 435,000 435,000 420,0004 765,995 790,0005 4.45 2.63 5.53 5.3 13.68 4.41 .3.59 18.77 U U U NR 3.49 3.55 2.08 3.90 3.52 3.72 2.74 53 2.47 2.55 2.72 2.96 18.8 0.0887 U U D U U U U U U 6.0 6.0 0.39 0.083 0.065 6.0 4.4 8.4 4.1 4.6 0.052 0.0617 5.85 0.556 1.24 1.68 278 0.0484 U U U U U 0.03 18 0.24 0.047 0.037 19 0.33 33 16 16 14 0.03 4.88 3.53 9.71 3.00 3.03 16.09 U U U U U NR 3.34 3.4 1.98 3.71 3.37• 3.52 2.6 4.85 238 2.42 2.6 1.69 0.0588. 7.95 23 U U D U; U U U U 3.5 3.5. 0.49 0.049 0.038 3.7 2.7 5.3 2.5 2.7 0.031 0.0354 7.47 0.486 0.744 1.06 90.4 U U U U U U 0.029 3.3 0.22 0.045 0.035 3.4 0.031 5.7 3.0 2.9 2.6 0.028 s: -. OSHA General Industry Air Contaminants Standard (29 CFR 1910.1000). 2. PEL criteria for m+p-Xylene and o-Xylene expressed as total Xylenes. 3. NA - None available. 4. Ceiling limit, no PEL 5. PEL criteria expressed as total 1,2-dichloroethene. U The analyte was not detected at the given reporting limit. D The value was obtained from an analysis of a diluted sample. NR The analyte was not reported. /18105 tdoor Air Q RL 0.035 U ' 0.045 U 0.058 Ul 15 0.027 U 15 0.1 '0.042 0.032 U 16 0.14 U 27 U 14 U 13 12 1I 0.026 R\0FICEAMPROJECI•Mcs\2004-1292\Communieadons\Table 2 Nov 05Indoor Air Data- NonCOC_s.xls FIGURE F:1OFICEAG(,VROlECTS1Fi1a12004-12921Communications\I l OS 05air samplingdoc PRPrERT{ M.W. LEMMOND I W.D. CORNWELL LLC DEED 4555-05 DEED 9042-73E I 5 24' 55' 27" W 341.49' Kul S 24. �"9.7T' Is PELTOINTSTREET I� (60. F/w) . 1 EASTEPJJ GAG PDSS"IX .1 12 DE 1. ICES CORPORATION mI I DEED ;571-4%.t lr N W L 1 ra O C 4•' ri!•}6�—• un POWER y Ono ZAKSAV ,n PAVED FDPJP_F n.FUMAME •V SYD.2AGE ApEA � _ W - YIDRA7'dK 3 FT°S7tYr6 1AS-03-0i rIASSLQZ— ZMp�'1C stw!a MOORAGE Vl Af6w k F POUS/ m F4FMER � Ll CorI�ETE .� :r t v Waflm.* r.,r ' FppOAG Y�vTWt BAG HWSE fppMER WASH WATER FlkMER 441P 61M5. AaD t TREATMENT NA,.rAJS WASTE H.J. FRIDELL ST(RADE A4EA SOLOMON SHAP[RO DEED 6509-344� =+/ - DEED 6575-474 .q� z ti •N r fi h f, E. IJ N y' un 3 .ZC .3bxrnaR F! SOUTH TRY01V S rREET G.7949 AL. � Pr= I I t -10 osFTrra � I I II Ila GT�.a2 I I Q d� ,S-03-0B .AFTces "� 11 u AP.EA GUT OF PIW: I 262.634 SG.FT. rACRhr � � iK I • �C ASPHALT D P PARKINGPUftAr I I I,l &gw II sxa I I MINC l ' .9,Oro% �£9:btV 3-yt ,rb .£Z•Yir oy •lS .I awY l,Df- r FARM $1'ACE � � I J.W. HOPIGNS !/ DEED 5321-430 AAnes�' AOp„yy D.Pgak.Nl,n ' LEGEND PROPERTY BOUNDARIES EASEMENT BOUNDARY - - - - - SETBACK BOUNDARY AIR MONITORING LOCATION n r -? NOTES: �C5 1). BASEMAP FROM R.B. PHARR & ASSOCIATES, PA. BOUNDARY SURVEY FOR 200 CLANTON ROAD, CHARLOTTE, NC, MAY 18. 1999. 0 d 2). LOCATION OF UNDERGROUND UTILITIES ARE NOT SHOWN. 11SLS tl9Att91f [sse•rut : 1l3i]itM i s � ncwsr-Tat.o i FORMER PELTON & CRANE FACILITY I 200 CLANTON ROAD, CHARLOTT& NORTH CAROLINA 0 25 50 100 -0131 SCALE: FEET ATTACHMENT A FAOFICEAGOPROJECrWila\2004-1292\Communiatimu\il OB 05,irsempling.doc mrowNRIq ATTACHMENT B F.\OFICEAGC\PROJECTS\Files\2004-1292\Communiatiom\l l 08 05av sampling.doc Industrial Scenario Target Indoor Air Concentrations based on USEPA Subsurface VI Guidance (USEPA 2002) For Carcinogens- C... (ug/m') = [(TCR*ATc)/(EF*ED*URF)] For Non -Carcinogens: ,C ..Ka... (ug/m3) (THQ*RfC* 1000 ug/mg) .where: Cw as = target indoor air concentrations, carcinogen, (ug/m') C„...... =target indoor air concentration, non -carcinogen, (ug/m') TCR = target cancer risk (e.g., 1.Ox10'5) THQ = target hazard quotient (e.g., 1.0) URF = unit risk factor (ug/m')" RIC = reference concentration (mg/m') At, = averaging time, carcinogens (70 years * 365 days/year = 25,550 days) EF = exposure frequency (days/year) ED = exposure duration (years) INPUT PARAMETERS VALUE SOURCE TCR 0.0001 Site -Specific THQ 1 Site -Specific URF Chemical Specific See Below RfC Chemical Specific See Below At, 25550 USEPA - RAGS EF 250 USEPA - RAGS ED 25 USEPA-RAGS CHEMICAL URF SOURCE Tetrachloroethene 0.000003 USEPA NCEA provisional value Trichloroethene 0.00011 USEPA-NCEA provisional value Methylene Chloride 0.000001 USEPA-NCEA provisional value l,l-Dichloroethene NA NA 1,2-Dichloropropane 0.000019 HEAST Vinyl chloride 0.0000098 IRIS Bromomethane NA NA Chloromethane 0.000001 USEPA-NCEA provisional value cis-1,2-Dichloroethene NA NA CHEMICAL SPECIFIC TARGET INDOOR AIR CONCENTRATION CHEMICAL Ccancer C'non-cancer Tetrachloroethene 136 NA Trichloroethene 4 40 Methylene Chloride 409 90 1,1-Dichloroethene . NA 200 1,2-Dichloropropane 22 4 Vinyl chloride 46 100 Bromomethane NA 5.1 Chloromethane 409 90 cis-1,2-Dichoroethene NA 35 RfC SOURCE NA NA 0.04 USEPA-NCEA provisional value 0.09 IRIS 0.2 USEPA NCEA provisional value 0.604 IRIS 0.1 IRIS 0.0051 IRIS 0.09 IRIS 0.035 PA Act 2 State -Wide Health Standard, LRP Tech Manual As a comparison, the TCE Region 9 PRG for a residential scenario (i.e., TCR = 0.000001; ED = 30; EF = 350) is 0.017 ug/m?. ATTACHMENT B F:\OFICEAGC\PROJECTS\Files\2004-1292\Reports\Quarterly\Fourth Quarterly Report2005.doc REMEDIATING PARTY CERTIFICATION STATEMENT (.0306(b)(2)): "I certify under penalty of law that I have personally examined and am familiar with the information contained in this submittal, including any and all documents accompanying this certification, and that, based on my inquiry of those individuals immediately responsible for obtaining the information, the material and information contained herein is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for willfully submitting false, inaccurate or incomplete information." L (Name 1 f Remediatin Party Official) (Signature of Remediating Party Official) 3 z 2cc � Date * NOTE. -The RSM certifies all documents LAST. Failure to do so is a violation of I5A NCAC 13C.0306(b) (2) of the REC Rules and subject to possible enforcement actionnagainst the RECand/or RSM. PC 11) ru 4 )ya q t a (Enter State) l iL.1de,- COUNTY I, _ffZ i.ssv- A, VaLt!a � , a Notary Public of said County and State, do hereby certify that Ro be rt L-- {=r R d ^a vi did personally appear and sign before me this the o? day of i(YM6 f C11 �(migmtum) Notary bli (OFFICML SEAL) My commission expires: NOTARtAL SF------�'•,w MELM A VAUMNt !t{ V. 2ipQ G - 2 REGISTERED SITE MANAGER CERTIFICATION STATEMENT (.0306(b)(1)): "I certify under penalty of law that I am personally familiar with the information contained in this submittal, including any and all supporting documents accompanying this certification, and that the material and information contained herein is, to the best of my knowledge and belief, true, accurate and complete and complies with the Inactive Hazardous Sites Response Act G.S. 130A-310, et seq, and the voluntary remedial action program Rules 15A NCAC 13C .0300. I am aware that there are significant penalties for willfully submitting false, inaccurate or incomplete information." (Name of Registered Sitc'Marfager) IX (Signature of Registered Site Manager) Da * NOTE: The RSM certifies all documents LAST. Failure to do so is a violation of 15A NCAC 13C.0306(b)(2) of the REC Rules and - subject to possible enforcement action against the REC and/or RSM. Ril il-'21 V JI Ok-(Enter State) COUNTY a Notary Public of said County and State, do hereby certify that _- Irl,U� I S- C I l`�}'� Cjt r1 did personally appear and sign before me this the day of Notary Public (signature) (OFFICIAL SEAL) My coNOARW Ptdft IDU G - 3