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HomeMy WebLinkAboutWI0100142_Monitoring (Report)_20120330WITHERS &—RAVENEL ENGINEERS I PLANNERS I SURVEYORS KLOZUR® ACTIVATED PERSULFATE INJECTION PILOT TEST Report of Pre and Post I& Injection Groundwater Monitoring RECEIVEDIDENRIDWQ S" 4e� Reeves Brothers Henson Landfill MAR 30 2012 Forest City, North Carolina Prepared for.• Environmental Liability Transfer 165o Des Peres Road Suite 303 St. Louis, Missouri Prepared by. Withers & Ravenel, Inc. 1410 Commonwealth Drive Wilmington, NC 28403 Aquifer Protection Section �f o :J Christopher Fay Brian J. Bettis, P.G. March 2012 iii MacKenan Drive 1 Cary, NC 27511 1 tel:919.469.3340 1 fax:919.238.2099 I www-withersravenel.com 1410 Commonwealth Drive 1 Suite ioi 1 Wilmington, NC 28403 1 tel: 910.256.9277 1 fax: 910.256.2584 416 D Gallimore Dairy Road I Greensboro, NC 27409 1 tel: 336-993-5504 TABLE OF CONTENTS 1.0 INTRODUCTION ........................................................................................................................................... 2 2.0 SUMMARY OF RESULTS............................................................................................................................3 2.1 VOLATILE ORGANIC COMPOUNDS.................................................................................................................3 2.2 METALS.........................................................................................................................................................5 2.3 CHLORIDE AND SULFATE............................................................................................................................... 7 2.4 TOTAL ORGANIC CARBON..............................................................................................................................7 2.5 SEMI -VOLATILE ORGANIC COMPOUNDS........................................................................................................ 7 2.6 INDICATOR PARAMETERS..............................................................................................................._...............7 4.0 CONCLUSIONS AND RECOMMENDATIONS........................................................................................ 8 TABLES APPENDICES WITHERS & RAVENEL ENGINEERS I PLANNERS I SGRVEYGRS 1 .O INTRODUCTION On May 4, 2011 Withers & Ravenel and ELT were authorized through issuance of Permit No. W10100142 by the NCDENR Division of Water Quality Underground Injection Control (UIC) Program to conduct a pilot study to evaluate the effectiveness of injecting an aqueous solution of persulfate and sodium hydroxide to reduce concentrations of volatile organic compounds (VOCs) in groundwater beneath a site known as the Henson landfill in Forest City, NC. The injectant is also known as "activated persulfate" and was developed by FMC- Klozur of Philadelphia, PA. The injectant is a mixture of powdered persulfate and a 25% - solution of sodium hydroxide, which is mixed with water and injected into the saturated zone to create highly oxidizing conditions, that promote the destruction of VOCs through oxidation. The pilot study involved injection of activated persulfate at six locations to the north and northeast of Cell 3 of the Henson landfill and monitoring of groundwater quality conditions at monitoring wells MW-2 and MW-3 located just downgradient of the area were waste was disposed, and at wells MW-2o and MW-2oA located downgradient of the disposal area and near a perennial stream. Groundwater samples were collected from these wells prior to the injection, and for a three month period thereafter. The approximate injection point locations and positions of above reference monitoring wells are shown in the figure below. a DL \ CE+DLr+^iAIM SIAr AEM uaK 43M 4l -Q LI ® 1A-MMF NG WELL VigLNfl RATE FENIcs ■ ND.thl R 2009 ---- PRCtl3ERTY BMJrMA.4Y 0 DECEWBER 2037 +•9— MGMT-CF-WAY ® d1NE 2CO7 — — CREEs: ® DECENEER 2CO8 ML - BELOW DETECTON vwiT fQ""W A w9. M MM"M EY81 ® 4AWARY 2006 wA - NOT ANALYZED I11 DECENDER 25 • ACTIVATED PamvATE wxcnm Paw TEE9r'E.4 BROTHERS. MrHENSON SITE - NOTE: ALL CCNCEMTtRAUnS REPORTED M uQA G14PH';C SCALE it 934 5.w mu 1 6,ch - ALI' fh. Fw^iIP.ES I� WITMRRO & RAVCNCL PROPL]�£d A�1P'R TED PERSl1LEA7f P1L37 7E5T I� JICi 3� L2K�13Q`S a»nun I ►Euitw l atrmu -_I WITHERS RAVENEL ENGINEERS I PLANNERS I SURVEYORS Page 2 The injections were performed on August 29, 2011 through September 1, 2o11 by Vironex, Inc. and a report that describes the services they provided is included in Appenidx A. In summary, approximately 6,9oo gallons of activated persulfate solution were injected at the six locations shown above. Injection pressures varied between 4o and 120 PSI and the average injectant flow rate was 3.7 gallons per minute. Pre injection samples were collected from wells MW-2, MW-3, MW-2o and MW-2oA on August 26, 2011. Post injection samples were collected from those four monitoring wells on September 2, 2011, October 7, 2o11, November 9, 2o11 and December 6, 2011. The pre -injection samples were analyzed for VOCs by EPA Method 826o, semi-VOCs by EPA Method 8270, chloride, sulfate, arsenic, cadmium, chromium, copper, lead, mercury, selenium, silver and zinc. The post injection samples were analyzed for the same VOCs and metals as the pre -injection samples, however they were not analyzed for semi-VOCs. Field measurements of dissolved oxygen, pH, specific conductance, turbidity and oxidation reduction potential (ORP) were recorded during the well purging process that preceded sample collection. 2.0 SUMMARY OF RESULTS This section provides discussion of the laboratory analytical results and field data obtained for the pre and post injection monitoring events. 2.1 VOLATILE ORGANIC COMPOUNDS The attached Table 1 summarizes the results of EPA Method 826o analyses performed on the pre and post injection groundwater samples. Substantial increases in VOC concentrations were observed in the post injection samples from wells MW-2 and MW-3. However, VOC concentrations at downgradient wells MW-2o and MW-2oA remained relatively consistent during the pre and post injection monitoring period. Graphs of the concentrations of acetone, chloromethane, methy iso butyl ketone (MIBI) and toluene versus time for wells MW-2 and MW-3 illustrate the overall concentration increases. Henson Landfill VOCs: MW-2 50000 - -, 45000 J 40000 35000 c 30000 + Acetone 0 Chloromethane 25000 MIBK 20000 - Toluene c 15000 — 10000 5000 0 07/26/11 09/14/ 11 11:'031' 1 1 12123/ 11 Date WITHERS RAVENEL Page 3 Henson Landfill VOCs: MW-3 70000 60000 J a, 50000 _'. Acetone 0 40000 Chloromethane 30000 MIBK m - Toluene c 20000 U 10000 m 0 1 Y::�, 07/26/11 09/14/11 11/03/11 12/23i 11 Date Concentrations of methyl ethyl ketone (MEK) in the samples from MW-2 and MW-3 increased the most dramatically as illustrated in the following charts. 500000 450000 J 400000 350000 300000 0 250000 LO 200000 150000 100000 50000 0 07126111 Henson Landfill VOCs: MW-2 09/ 14/ 11 11 /03/11 12/23/11 Date WITHERS & RAVENEL Page 4 EIr,IHEEA5 1 PLINN EAS I S U A � E I I A S Henson Landfill VOCs: MW-3 350000 --- _. 300000 J a1 250000 ? Acetone 0 200000 f Chloromethane MIBK LG 150000 - Toluene - MEK (2-Butanone) tg 100000 1 50000 0 07/26/ 11 09/ 14/ 11 11 /03/ 11 12/23/ 11 Date The increased concentrations of VOCs within samples from wells MW-2 and MW-3 over the post injection monitoring period imply that the mass of activated persulfate injected was not sufficient to oxidize the mass of VOCs within the groundwater in the vicinity of MW-2 and MW-3 and immediately upgradient beneath Cell 3. We suspect that the activated persulfate initially oxidized a portion of the VOCs in groundwater near wells MW-2 and MW- 3, which would have created a concentration gradient that caused higher concentrations of VOCs beneath Cell 3 to move towards wells MW-2 and MW-3. The VOC concentrations for the December 2011 samples are similar to those detected in 2oo8 and previously. 2.2 METALS According to the post injection analysis results for metals the activated persulfate injection caused increases in the concentrations of arsenic, chromium, copper, lead and zinc at locations MW-2 and MW-3. Initial concentration increases were followed by concentration decreases at these locations. Post injection metals concentrations at the downgradient locations MW-2o and MW-2oA did not change noticeably in comparison to pre -injection concentrations. The analytical results are summarized in the attached Table 2, and graphs of the metals concentrations versus time for locations MW-2 and MW-3 are provided on the following page. WITHERSo NNF RAVENEL Page 5 J _y S 400C 0 300C V U 2000 10CC 0 815/11 45CC 40CC 35CC 300C 250C 1i 200C a V 150C 100C 500 0 Pre and Post Injection Metals Concentrations: MW-2 8/25111 i = 11 1 C = ` 1 1 C: 111 11/13/11 12/3111 12/23/11 Data Pre and Post Injection Metals Concentrations: MW-3 8;25111 5 1 1 1 C:4" 1 10:2-1:11 11, 1 3r' 1 11311 12/23/11 Date Arsenic Chromium Chromium Copper Lead —N—Zinc WITHERS C- RAVEWEL Page 6 ENGINEERS I PLANNERS I SURVEYORS 2.3 CHLORIDE AND SULFATE The pre and post injection groundwater samples were also tested for chloride and sulfate. The analytical results are summarized in the attached Table 3. The elevated concentrations of sulfate in the post injection samples from locations MW-2 and MW-3 indicate that the injection contractor successfully delivered the activated persulfate injectant to the targeted depth. The increases in chloride concentrations in the post injection samples from MW-2 and MW-3 suggest that oxidation of chlorinated compounds may have occurred. Chloride and sulfate concentrations at downgradient wells MW-2o and MW-2oA remained stable throughout the monitoring period, which implies that the injection did not affect groundwater conditions in this area. 2.4 TOTAL ORGANIC CARBON The pre and post injection groundwater samples were also tested for total organic carbon (TOC) and the analytical results are summarized in Table 4. Concentrations of TOC at downgradient locations MW-2o and MW-2oA remained consistent throughout the monitoring period, which implies that the injection did not affect groundwater conditions in this area. TOC concentrations locations MW-2 and MW-3 increased by a factor of about eight following the injection. This is appears to be related to the rise of VOC concentrations at these locations after the injection. 2.5 SEMI -VOLATILE ❑R13ANIC COMPOUNDS Low concentrations of three semi-VOCs (2-methylphen0l, 3,4-methylphenol and benzyl alcohol) were detected in the pre -injection groundwater sample from MW-2, and two of these semi-VOCs where also identified in the sample from MW-3 (see Table 5). Three of the five reported concentrations were below the method reporting limit but above the method detection limit and therefore are accompanied by a "J" flag in the laboratory report. An estimated concentration of 3,4-methylphenol was also identified in the sample from MW-20 and no semi-VOCs were identified in the sample from MW-2oA. The very low concentrations of only three semi-VOCs imply that they are minor contaminants of concern in comparison to the identified VOCs. 2.6 INDICATOR PARAMETERS Table 6 summarizes the results of field testing for various indicator parameters for each of the pre and post injection groundwater samples. Initial pre -injection measurements of dissolved oxygen and oxidation-reduction potential (ORP) at shallow well locations MW-2, MW-3 and MW-20 indicated the presence of low oxygen conditions and negative ORP, which implies chemically reducing conditions. As expected, oxygen concentrations and ORP increased dramatically at locations MW-2 and MW-3 following the injection, while no substantial change in either was observed at downgradient locations MW-20 or MW-2oA. WITHERS & RAVENEL Page 7 ENGINEERS I PLANNERS I SURVEYORS The pH of the groundwater in the vicinity of the activated persulfate injection area initially increased to give rise to alkaline conditions from near neutral starting conditions. This was expected due to the inclusion of sodium hydroxide as part of the injectant. However, by the end of the first month of post injection monitoring, pH levels had dropped and indicated the presence of acidic conditions. This was most likely due to the generation of sulfuric acid (H2SO4) after the sodium hydroxide had been consumed in reactions, and is an additional indication that the mass of activated persulfate injected was insufficient to oxidize the mass of VOCs present in the area and immediately upgradient in the vicinity of Cell 3 of the landfill. Well purge forms that show the indicator parameter readings are included in Appendix B. Laboratory reports for all of the pre and post injection sampling events are attached as Appendix C. 3.13 CONCLUSIONS AND RECOMMENDATIONS The post injection groundwater monitoring results imply that injection of even a strong oxidant like activated persulfate will not be effective at reducing VOC concentrations downgradient of Cell 3 until the concentrations of the VOCs in the soil and groundwater below Cell 3 are reduced. The soil vapor extraction pilot test conducted within Cell 3 and documented in the Remedial Action Plan (RAP) for this site demonstrated that soil vapor extraction (SVE) will be effective at removing VOCs from the buried waste and soils beneath Cell 3. SVE may also be effective at reducing VOC concentrations in underlying groundwater after the majority of VOCs are removed from the overlying unsaturated zone. !) Withers & Ravenel is in the process of preparing the Remedial Action Preconstruction Report, which will contain the plans and specifications for the recommended SVE system within Cell 3. According to the schedule of remedial activities contained in the RAP, a larger scale injection of activated persulfate was to occur during the period of time that the SVE system was in operation. However, based on the results of the activated persulfate injection pilot test, Withers & Ravenel now recommends postponement of future in -situ groundwater remediation activities until after the SVE system has operated long enough to remove the majority of VOCs from beneath Cell 3. At that point, additional evaluation of the magnitude and extent of VOCs within groundwater in the vicinity of Cell 3 will be conducted. Such an evaluation would allow for better estimation of the mass of VOCs remaining in the _ groundwater for subsequent treatment via injection. Alternatively, if operation of the SVE system results in lowering of VOC concentrations in groundwater sufficiently, the additional groundwater evaluation may be used to justify a monitored natural attenuation approach to groundwater remediation. Because the results of the injection pilot test have caused us to revise the remedial approach presented in the RAP, Withers & Ravenel will prepare a RAP Addendum that describes the revised remedial approach briefly described above. The RAP Addendum will be a part of the forthcoming Remedial Action Preconstruction Report that will be submitted to the NCDENR Division of Waste Management - Inactive Hazardous Sites Branch, which administers the Registered Environmental Consultant Program. WITHERS & RAVENEL ENGINEERS I PLANNERS I SURVEYORS Page 8 5 CN sN W CO OCONC�C V N N �CO�N�CC OCON `a(O O(O V NOCC n7 CN-�O\V `656 CON N OCC 0 N N N N WC N N Cl) N N N N N c - y N N N N N c y N N N N N C v 0 0 0 0 0 p D O O O O O O Np v 0 0 0 0 0 W O O O O O O jV z R1LnL,u,v,0 o 0 0 0 0 1,1,2-Trichloroethan Z m00000 1 1 2-Trichloroethan " Z 0 1,1,2-Trichloroethan Z m00000 N N N N N 1 1,2-Trichloroethan ' Im000 o�00000 n n n n n 1,1 Dichloroethane as ^� "� ^� 1,1 Dichloroethane w w" i rn 1 1,1 Dichloroethane cn w N N 1,1 Dichloroethane i"� C, 01 i 01 v, CA o 0 0 0 0 0 0 IA 0 1,2 Dichloroethane a o 0 0 0 0 1,2 Dichloroethane op o 0 04F11,2 Dichloroethane A w '�' 0 1,2 Dichloroethane C1 o^^^ ocncncncncn A A Acetone M o 000000 A A A A A Acetone Cf o o N 0 N 0 V �' V m Acetone cn o 0 A 0 W" 0 o C7 p N "Acetone 0 000000 o0Oop0 Oo 000CD 00 o 0 0 0 o Benzene -► w c Benzene -► .�i o 'N -n' o Benzene -► o 0 i 0 c N a Benzene Cn Cn u, in 0 o m 6 6 N 6 Bromochloromethan m o o o o o Bromochloromethan m N 0 CO iv o Bromochloromethan m o 0 0 0 o Bromochloromethan z o 0 0 0 o Bromomethane Z Bromomethane Z a i v, N Bromomethane Z �1O0pp0 o W w m a Bromomethane m<nCn01CYTM m00000 m 0000 o A A A A n c" Ca pCn 0 V ° V O cc iT Chlorobenzene a m ^p nC Chlorobenzene 00 a0 Chlorobenzene000ooChlorobenzene in n n Cn 0000 o n 00000 n n n Chloroethane o ^� ^� Chloroethane cD 0 0 0- Chloroethane o 0 0 0 N Chloroethane o Cn in Cn(n IA Cn p00000 000000 000000 w o 0 0 o Chloromethane w s 8 8 8 Chloromethane w 0 0 0 0 8 Chloromethane w o 0 0 r i Chloromethane CA V, Ip U, U, CA 0 0 0 0 0 IA 0000 0 0 0 j"D 0 0 n ^ n n n 2 DCE ` Q' cis-1,2 DCE AIM�0 cis-1,2 DCE O -0000cis-1, 00w0 i c' A cis-1,2 DCE O 0 O N V IIICA 00000 a 000000oU,L,",C,L, n n n n A Ethylbenzene o ^� -n• ylbenzene o m cN„ A A No Ethylbenzene o n) r i r i �v�Ethylbenzene 00000IlEth 0 00 00000 o^ ^^^^ x X lenes �P- Y c a-�rn ^' 8 x, X lanes P- Y o a r N N" x X lenes �P- Y o 41 A 4 a� x, X lenes P- Y o- orn� pco00C)C) o0000cO O0 n 0 n 0 n 0 n 0 n 0 o-Xylenes W o A 0 A 0 A 0 A 0 A 0 o-Xylenes Gf o cn „ 0 n 0 n 0 w o-Xylenes CA O A o A o A No n No A No o-Xylenes Cn Cn Cn Cn Cn Rj �An in c^n to c^„ MBK (2-Hexanone) m n o n 0 n 0 n 0 n o MBK (2-Hexanone) m n o n 0 n 0 n 0 n o MBK (2-Hexanone) m A o n 0 n 0 A 0 n o MBK (2-Hexanone) 00000 00000 00000 is o^^ ^^^ MEK 2-Butanone ( ) is o A 8 A A A A�� A n MEK 2-Butanone ( ) 4, o CI 0 W IV 0 10 O 0 W O— o w MEK (2-Butanone) 4 0 A W 0 W V 0 .a V 0 W CO o V cS MEK (2-Butanone) oOiUi°'�"�' 000000 000000 0o op0000 pop Z^ ^ ^ ^MIBK ZA Z0oo00MIBK zo0`1O^'MIBK mcnCALncncn m0000 m00000 mCDcm00 IA IA�-'1�IMIBK 000 00 ^� Methylene Chloride a AAAAA o 0 0 0 o Methylene Chloride cn i o 0 N o Methylene Chloride w ;° c 0 a o Methylene Chloride TAAA� Cf 0 A 0 A 0 n 0 A 0 A o Toluene Cf o N o w W O 0 W 0 W o Toluene Cf o o00o A 0 o p A A o Toluene Cf o o00000 10 p O o O o N p Toluene oininininin ooOOpp p rv' m 2 0 U) y O 7 r m 3 a v m O U) 7 ID n 0 3 O 0 0 to v d m C O N m 0 Co m O 0 n O a 0 c a W C fO AinOJaw000O000� NNNN AJnOJaW00000� NNNNN AinoJaW000Oo�- NNNNN tinOJaW00000�- NNNNN v v v v v v v v v v v v v v v v v v v v O Or 10 0O O0 CO N0 Z OoONNO Oco ZCO MO N�NpQUIO W CO) N x- N e- ��O !� WnlUa a SN1n0 d o co NN O wnlUa a I STIV C1 cn V T O C4 wmua a I STCOTToN `' `° `r "' O wn1Ua a I SOT V V T T v N peal°c°T.-cnw"� ui pea���-woT,� rTNMnjLn ea p ,CV �coCDMrn� O�TIO� ea p ,O� Loce) ')cow 000`' �`y� Jaddo�°ommo � Jaddo��`°�� oJaddoJaddooN��rn �N�`° O � le cm T To nlwoJ y�Ch4 MOc00��0 nIWOJ y��tON NCp��00 V T� nIWOJ 4�C)r-04 oD 1�T�c00 ,: nIWOJ ��cY T�I�N1-0 �� V-T-�� N wnlWpe'J T V Lo V w r Lq CD u) W N wnlwpe'J T V M N M T" V N N wnlWco pe'J T V T V T V T V N WnlWpe� T V T V T V r V r V N OIUBSJ d cl 10 M 1- !O [Y OD 0 �IUaSJ d m O w 60 co V 00 r 0 !� OIUaSJ d O 0 me 0 LO M a1 !f N IA 0 OIUaSJ d T N O N ti r O T CD T N T T 0 T T 0 T r 0 T T 0 T T 0 O C) T T 0 T T 0 T T 0 T T 0 T T 0 O 0 N T T 0 r T 0 T T 0 T T 0 T T 0 O Q 0 T r 0 T T 0 T T 0 T T 0 T T 0 O N N N N N co N N N N N N N N N CA N N N N N N N Cfl N N r- O O CO N CO N N f- O LA O N O N N W f- O CO N N C O N T T T 00 T r T Q) OD T T T 0 00 T T T .O U O X N a)O O J N N �U Q �U .. Z m L¢ L T 23) C CO) C N O L N � N C ina)N C � U � U) O Ur Z I I I Table 3: Henson Landfill Pre & Post Injection Monitoring Data Chloride & Sulfate (mg/L) MW-2 Chloride Sulfate 8/26/2011 26 <1 9/2/2011 86 9200 10/7/2011 120 14000 11 /9/2011 200 12000 12/6/2011 200 9200 GW STD 250 250 MW-3 Chloride Sulfate 8/26/2011 60 <1 9/2/20111 280 20000 10/7/2011 89 5700 11 /9/2011 140 7300 12/6/2011 110 4300 GW STD 250 250 MW-20 Chloride Sulfate 8/26/2011 46 <1 9/2/2011 48 <1 10/7/2011 49 2.4 11/9/2011 49 0.64 12/6/2011 52 <1 GW STD 250 250 MW-20A Chloride Sulfate 8/26/2011 1.4 26 9/2/2011 1.5 54 10/7/2011 1.6 30 11 /9/2011 1.6 39 12/6/2011 1.8 34 GIN STD 250 250 Note: Concentrations highlighted in red exceed the North Carolina Groundwater Standard (GW STD) established in 15A NCAC 2L .0202 Table 4: Henson Landfill Pre & Post Injection Monitoring Data Total Organic Carbon (mg/L) MW-2 TOC 8/26/2011 109 9/2/2011 168 10/7/2011 439 11 /9/2011 800 12/6/2011 707 MW-3 TOC 8/26/2011 73.5 9/2/2011 520 10/7/2011 379 11 /9/2011 602 12/6/2011 MW-20 392 TOC 8/26/2011 29.3 9/2/2011 32.9 10/7/2011 26.3 11 /9/2011 26.3 12/6/2011 MW-20A 33.2 TOC 8/26/2011 3.4 9/2/2011 4.3 10/7/2011 3.6 11/9/2011 2.3 12/6/2011 2 Table 5: Henson Landfill Pre Injection Monitoring Data Semi -Volatile Organic Compounds (ug/L) 0 o = = a 0 >, r r � 0 w � � c MW-2 I N m 8/26/2011 28 9.1 J 11 GW STD NE 40 NE 0 o = r a � y� s 0 u MW-3 N M In 8/26/2011 5.0 J 8.5 J <10 GW STD NE 40 NE 0 o = = r °D t a o c CL r o � W � c MW-20 I N M m 8/26/2011 <10 5.2 J <10 GW STD NE 40 NE 0 o _ = � a o r a 0 U � � c W-20AN M26/2011<10 L <10 <10 W STD NE 40 NE Table 6: Henson Landfill Pre & Post Injection Monitoring Data Field Parameter Measurements U a� in d z Well ID Sample Date d c. c c r > E N o �_ _ y a C m � O MW-2 8/26/2011 0.28 19.81 0.504 7.2 -140.4 4.2 Injection 9/1 /2011 9/2/2011 12.51 20.37 75.83 12.02 100.1 8.20 10/7/2011 1.61 20.03 18.71 1.90. 460.2 9.30 11 /9/2011 0.47 18.09 16.59 1.88 417.3 9.10 12/6/2011 0.38 17.22 12.69 2.03 399.3 6.20 MW-3 8/26/2011 0.31 16.54 0.642 7.29 -154 5.20 Injection 9/1 /2011 9/2/2011 23.71 20.25 13.95 4.04 453.8 8.70 10/7/2011 14.78 1 19.86 7.039 3.28 440.8 9.80 11 /9/2011 4.30 17.71 7.475 1.85 384 6.62 12/6/2011 4.35 17.32 7.532 2.09 392.1 4.30 MW-20 8/26/2011 0.24 16.84 0.381 8.43 -139.7 4.60 Injection 9/1 /2011 9/2/2011 0.17 6.21 0.378 7.62 -162.5 6.10 10/7/2011 0.74 15.68 0.351 8.17 -138.3 8.50 11 /9/2011 0.48 15.11 Ll 0.345 7.77 -138.2 5.60 12/6/2011 0.47 15.10 0.346 7.69 -138.5 4.20 MW-20A 8/26/2011 6.96 15.93 0.254 9.95 -137.9 0.75 Injection 9/1 /2011 9/2/2011 8.34 18.24 0.262 7.91 -159.1 0.50 10/7/2011 7.30 15.83 0.258 10.24 -142.0 0.86 11/9/2011 7.03 15.35 0.252 9.30 -131.5 3.78 12/6/2011 7.02 15.37 0.255 9.18 -122.6 3.99 APPENDIX A Injection Services Report Prepared for: WITHERS 6xORAVENEL ENGINEERS I PLANNERS I SURVEYORS Prepared by: I.ROI�T E Henson Landfill 4119 US Hwy 221 South Forest City, NC August 30, 2011 through September 1, 2011 Reproduction and distribution of this document without the express written consent of Vironex is strictly prohibited. The methodology and approaches presented herein are proprietary to Vironex. Wilmington, DE . Washington, DC . Denver, CO . Los Angeles, CA . San Francisco, CA www.vironex.com IRONEX Search and Destroy® Contents ProjectSummary...........................................................................................................................................1 Sitemap.........................................................................................................................................................2 InjectionSummary ........................................................................................................................................3 Project Photographs ProjectPhotographs .....................................................................................................................................5 ProjectPhotographs ..................................................................................................................................... 6 InjectionLogs............................................................................................................................... Appendix A Withers & Ravenel - Henson Landfill - Forest City, NC Page i -- I RONEX i Search and Destroy® Project Summary Project Name: Henson Landfill Project Dates: Aug 29, 2011 On -Site: 8:00 AM Off -Site: 8:30 PM Hours on Site: 12.5 Aug 30, 2011 On -Site: 7:30 AM Off -Site: 7:00 PM Hours on Site: 11.5 Aug 31, 2011 On -Site: 7:30 AM Off -Site: 9:30 PM Hours on Site: 14 Sept 1, 2011 On -Site: 7:30 AM Off -Site: 4:00 PM Hours on Site: 9 Manpower: David Wiley (Remediation Specialist); Jake Haldiman (Field Tech); David George (Field Tech) Equipment: Vironex specialized injection rig. This rig combines mixing capabilities with integrated safety features such as built in secondary containment and a safety shower/eyewash station. Vironex utilized two (2), one hundred and fifty (150) gallon mixing tanks to combine Sodium Persulfate and Sodium Hydroxide into a 20% solution. For this project Vironex utilized two (2) foot bottom up injection tools while using pre -strung drive rods. For drilling purposes Vironex utilized a Geoprobe 7822 track unit. Proposed SOW: Vironex proposed to inject 13,059 Ibs of Klozur activated by 25% NaOH. Given the silt lithology, Vironex recommended assuming a 20% (w/w) solution (6,889 gal). Vironex also provided a forklift and water truck rentals. Water Source: Water was provided by the city of Forest City, NC. Vironex utilized a water truck to transport the water from a designated hydrant located at the town hall (10 miles from the site). Project Summary: Injection services for this pilot test were initiated on Monday August 29, 2011. There were a couple of challenges on this site. The first challenge was the distance Vironex was injecting from an approved water source (10 miles). The water truck had to be re -filled twice per day. In the first injection area (MW3) Vironex hit numerous refusals and lost tooling trying to reach the proposed injection depth. Vironex utilized a pre -probe to attempt to achieve the desired depth before advancing the injection tooling. The acceptable depths reached in this area were 49', 47' and 47' respectfully. Once these depths were reached Vironex injected on three simultaneous locations. Flow was established in this area (MW3) between 100 psi and 120 psi. Once flow was achieved the average pressures were 50 psi while sustaining flow rates between 3 gpm and 4 gpm. There was no surfacing encountered in this area. In the second area (MW2) reaching the desired injection depth was not as difficult while still hitting refusal at 45 feet bgs. As in the other area (MW3) the injection locations were cut back from 5 to 3 while adding extra volume to the three simultaneous locations that Vironex injected on. The pressures needed to establish flow in this area were considerably lower (80 psi). Once flow was established the average pressure for each location was 60 psi while sustaining flow rates at 4 gpm throughout the injection locations. There was minimal surfacing on one location in this area around the rods (MW2-IP2). Injection services for this pilot test were completed without incident on Thursday September 1, 2011. -- Withers & Ravenel - Henson Landfill - Forest City, NC Page 1 16RO NE X Sitemap Search and Destroy® APasa Gzxar / AY',iC-2i u 0.3H l - � - - 64A•- ® A4 L-17 �'' A114.➢1 f eui = j ' Aev.� 1331 L9 �s� 6 nn}.�Tr br.f LH L ANV-i S di caa � H.99 j 4 H L 0 A1Lae \+-\ /l BIH1 \ \ HMIECiHON Hx01Ni LOCA710N [ETAIL MN-3 �L;� • � laturumATEa eyatmARo H mci, - 409H. Z030-,'LiiU 4j� NCNITOFdMG MEIL CANAUk DA � k' FOCCE • NOTE ALL CGtCENTRATI0N3 REPORTED IN up/H_ ® NOvD9m 2008 ---- P90PERTY SUMMARY IN DEC MBIER 2007 -'�'- 1WHT-CK-WAY ■ A1NE 2007 - - CREEK GRAPHIC SCALE 0 13ECMER 2OW 01HL - REL01T DETECTION L MHT (ffi'- A vat ata o[9&Hai uai>7 me 0 e96 3)¢Kkil i JAWARY 20DU NA - KOT ANALYM 9 DECEWBER 2005 • ACTIVATED POWLFATE INZCTION POINT IEEVESBROTHERS, IN MURE5 WITH IM &-RAVCHEL I-6E GOINI SITE PMFCSED ACTIVATED PER ULFATE MOTTST LNIEC-Mll LDCATI111I5 uau�an noun i uwnw Withers & Ravenel - Henson Landfill - Forest City, NC Page 2 16O= Search and Destroy® Injection Summary Sodium Sodium Total Date Persulfate Hydroxide Volume Points (Ibs) (gal) Injected Completed (Gal) Monday 8/29/2011 Tuesday 8/30/2011 2,177.7 293 1,149 Wednesday 8/31/2011 6,315.5 852 3,332 3 Thursday 9/1/2011 4,565.5 615 2,408 3 Design 13,058.7 1,760 6,889 6 Injected 13,058.7 1,760 6,889 6 Balance - - - - Daily Average 4,353 587 2,296 2 Withers & Ravenel - Henson Landfill - Forest City, NC Page 3 I RONEX Project Photographs Injection set up Area MW2 Injection set up Area MW2 Customized 5 Point Manifold Search and Destroy® Remediation Platform Customized Mixing Tanks Distribution Pump Withers & Ravenel - Henson Landfill - Forest City, NC Page 4 1 RONEX Search and Destroy® Project Photographs AW OIPLAY � Tracking Sodium Hydroxide Transfer Monitoring Flow Rates Monitoring Pressures Monitoring Temperature on Mixing Tanks Injection Locations around MW3 Withers & Ravenel — Henson Landfill — Forest City, NC Page 5 I RONEX Project Photographs F Search and Destroy® Injection Locations around MW2 Access Road to MW3 Mazur —Sodium Persulfate Klozur —Sodium Hydroxide Sodium Hydroxide Transfer Access Road Withers & Ravenel — Henson Landfill — Forest City, NC Page 6 IRONEX Search and Destroy® Appendix A - Injection Logs Withers & Ravenel - Henson Landfill - Forest City, NC Page 7 Vironex Field Data Sheet Injection Point ID Start Date Start Time End Date End Time Depth k Neragc pSl Highest I'Sl Average Flow Rate Sodium Persulfate (Ibs) SodiumAmended Hydroxide (Gal) Total (;al Mute. 8/30/2011 12.35 PM 8/30/2011 1:10 PM 49'-44' 60 110 4.0 363.9 49.0 192.0 Hit refusal at 49'. Achieved 110 psi before sustaining flow. IP1 8/30/2011 1:10 PM 8/30/2011 1:59 PM 49'-44' 50 60 4.0 362.0 48.8 191.0 Stopped injecting, had to fill the water truck, flushed with 20 gal H2O 8/31/2011 8:25 AM 8/31/2011 9 35 AM 44'-39' 45 50 3.5 409.4 55.2 216.0 Fill Water. MW3 8/31/2011 11:00 AM 8/31/2011 12:03 PM 44'-39' 40 40 3.0 1 316.5 1 42.7 167.0 1,149 8/31/2011 1:50 PM 8/31/2011 2:55 PM 39'-34' 40 50 3.0 363.9 49.0 192.0 Total Volume 8/31/2011 2:55 PM 8/31/2011 3:45 PM 39'-34' 40 40 3.5 362.0 48.8 191.0 8/30/2011 12:35 PM 8/30/2011 1:10 PM 47'-42' 70 100 3.5 363.9 49.0 192.0 Hit refusal at 47'. Achieved 100 psi before sustainingflow. IP2 6/30/2011 1:10 PM 1 8/30/2011 1:59 PM 47'42' 60 70 4.0 362.0 48.8 191.0 Stopped injecting, had to fill the water truck, flushed with 20 gal H2O 8/31/2011 8:25 AM 8/31/2011 9:35 AM 42'-37' 55 65 3.5 409.4 55.2 216.0 Fill Water. MW3 8/31/2011 11:00 AM 8/31/2011 12:03 PM 42'-37' 40 40 3.0 316.5 42.7 167.0 1,149 8/31/2011 1:50 PM 8/31/2011 2:55 PM 37'-32' 40 45 1 3.0 362.0 48.8 191.0 Total Volume 8/31/2011 2:55 PM 8/31/2011 3:45 PM 37'-32' 40 40 3.5 1 363.9 1 49.0 192.0 8/30/2011 12:35 PM 8/30/2011 1:10 PM 47'-42' 70 120 4.0 363.9 49.0 192.0 Hit refusal at 47'. Achieved 120 psi before sustainingflow. IP3 8/30/2011 1:10 PM 8/30/2011 1:59 PM 47'-42' 50 70 4.0 362.0 48.8 191.0 Stopped injecting, had to fill the water truck, flushed with 20 gal H2O 8/31/2011 8:25 AM 8/31/2011 9:35 AM 42'-37' 60 70 3.5 409.4 55.2 216.0 Fill Water. MW3 8/31/2011 11:00 AM 8/31/2011 12:03 PM 42'-37' 50 50 3.0 316.5 42.7 167.0 1,149 8/31/2011 1:50 PM 8/31/2011 2:55 PM 37'-32' 45 50 3.0 362.0 48.8 191.0 Total Volume 8/31/2011 2:55 PM 8/31/2011 3:45 PM 37'-32' 1 45 50 3.5 363.9 49.0 192.0 8/31/2011 820 PM 8/31/2011 900 PM 45'-40' 60 85 4.5 326.0 43.9 172.0 IP3 8/31/2011 9:00 PM 8/31/2011 9:40 PM 45'-40' 60 60 4.5 327.9 44.2 173.0 Finished for the day. 9/1/2011 8:25 AM 9/1/2011 9:10 AM 40'-35' 60 60 3.0 326.0 43.9 172.0 9/1/2011 9:10 AM 9/1/2011 9 50 AM 40'-35' 60 65 4.5 327.9 44.2 173.0 MW2 9/1/2011 11:30 AM 9/l/2011 12:05 PM 45-40' 55 60 3.0 216.1 29.1 114.0 Two locations in this area will not be completed. 9/1/2011 12:05 PM 9/l/2011 12:40 PM 45'40' 50 50 3.0 218.0 29.4 115.0 The remaining volume will be distributed between 3 locations. 1,148 9/1/2011 12:40 PM 9/1/2011 1:05 PM 40'-35' 50 50 4.5 218.0 29.4 115.0 Total Volume 9/1/2011 1:05 PM 9/1/2011 1:35 PM 40'-35' 50 50 4.0 216.1 29.1 1 114.0 Successfully completed location. 8/31/2011 8:20 PM 8/31/2011 9:00 PM 70 80 4.5 326.0 43.9 172.0 IP2 8/31/2011 9:00 PM 8/31/2011 9:40 PM 70 70 4.5 326.0 43.9 172.0 Finished for the day. 9/1/2011 8:25 AM 9/1/2011 9:10 AM 70 70 3.0 326.0 43.9 172.0 Surfaced around the rods. Packed bentonite around the rods and 9/1/2011 9:10 AM 9/1/2011 9:50 AM K454 60 70 4.5 327.9 44.2 173.0 continued. MW2 9/1/2011 11:30 AM 9/1/2011 12:05 PM 60 60 3.0 218.0 29.4 115.0 Two locations in this area will not be com leted. 9/1/2011 12:05 PM 9/l/2011 12:40 PM 60 60 3.0 216.1 29.1 114.0 The remainin volume will be distributed between 3 locations. 1,147 9/l/2011 12:40 PM 9/1/2011 1:05 PM 60 65 4.5 216.1 29.1 114.0 Total Volume 9/l/2011 1:05 PM 9/1/2011 1:35 PM 40'-35' 11 60 60 1 4.0 1 218.0 29.4 115.0 Successfully completed location. 8/31/2011 8:20 PM 8/31/2011 9:00 PM 45'40' 60 80 4.5 327.9 44.7 173.0 1P1 8/31/2011 9:00 PM 8/31/2011 9:40 PM 45'-40' 60 60 4.0 326.0 43.9 172.0 Finished for the day. 9/1/2011 8:25 AM 9/1/2011 9:10 AM 40'-35' 60 70 3.0 327.9 44.2 173.0 9/1/2011 9:10 AM 9/1/2011 9:50 AM 40'-35' 60 65 4.5 326.0 43.9 172.0 MW2 9/1/2011 11:30 AM 9/1/2011 12:05 PM 45'-40' 60 60 3.0 216.1 29.1 1 114.0 Two locations in this area will not be completed. 9/1/2011 12:05 PM 9/1/2011 12:40 PM 45'-40' 60 60 3.5 216.1 29.1 114.0 The remaining volume will be distributed between 3 locations. 1,147 9/1/2011 12:40 PM 9/1/2011 1:05 PM 40'-35' 65 70 4.5 1 216.1 1 29.1 1 114.0 Total Volume 9/1/2011 1:05 PM 9/1/2011 1:35 PM 40'-35' 65 65 1 4.5 1 219.3 29.4 T 1-15-07-1 Successfully completed location. Avg Avg Avg I SP NaOH Points Completed 56 63 3.7 1 13,058.7 1 1,760.0 6,889.0 6.0 Search and Destroy Withers Ravenel Injection Logs Vironex Inc. MI6-1NNSC;_000 WITHERS &- R AV E N E L Page of L� ENGINEERS I PLANNERS I SURVEYORS Job Number oi 3,rct03.g1.00 Groundwater Sampling Form State ID - _ Well ID / U—Z.Oh Site Name ljCw5oo LAOFILL Date Z4 Aij( 2011 Well Depth _ —7y-s __ _ Depth to Water 712'1f Well Diameter 2" Casing Material _. fkf t . Screen Length. 4_ Well Water Volume � Sampling Crew IC. t'aArlZD , Pump Type P.efis#altis-S�ts - Tubing Type Poly Intake set at Weather Conditions Oue /tx 7 , 16 H- So'_r, - Notes (eg. odor or color) No, _ _ I - � 1 Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (9AHr-1 (frnrhthr)fmnlll (°c) (uSlcm) ,(standard) (mV) (NTU) utner F arameters _ Sampled at 0V `{g, Parameters taken with YSI 556, LaMontte 2020 Samples delivered to Pi2t5M by-7, 6oui(1gai at 11*6 Analysis Preservative Bottle ware Number of Bottles Hold`Time, VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic _ ! 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass _ 7 Days Other su t 'l'rtuil,� I 5 A/C rf6 s` r weu volume t;alculatlon 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS & RAVENEL Page of L/ ENGINEERS I PLANNERS I SURVEYORS --�— Job Number 03o`io,38i•0o Groundwater Sampling Form State ID - Well ID 7,6 Site Name NcNs;,j _LM ORLL Date 21r, 4_V4 Z0 r{ Well Depth kp Depth to Water Z7r7o Well Diameter , 2" Casing Material P✓C! Screen Length /s Well Water Volume Ly -7 Sampling Crew tL- Q%AtL§6o Pump Type Ver� $%)(� Tubing Type Poly Intake set at Weather Conditions C)V0fU /l i Higkl Ro's Notes (eg. odor or color) Ara,46 Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 17A Hr.1 lfrnm Tr)r;N, fhale 1 1mn1l. (°(1l (uSlem) (standardl (mVl (WTU1 �!3ttr7� � - � L•�Z•lA��� Other Parameters Sampled at pq q,S Parameters taken with YSI 556, LaMontte 2020 Samples delivered to P(uSM by 1�_ &� at —No r, Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass Z 7 Days Metals Nitric Acid 250 ml plastic I 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other to(- HLL 4D,1 PJ)4r 1l iu 3 ,jr TLS G t G, Am PI Of,� 4ie `r well volume Laicuiatlon 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settin9 s\kbaarson\Desktop\GW Sampling Form PIS- IIJ36u nor) WITHERS & RAVENEL ENE3INEERS I PLANNERS i SURVEYORS Page 3 of 7 Job Number 030y 6 3 A 1, 00 Groundwater Sampling Form State ID Well ID ftLi-3 _ Site Name HGA)SoN L.14,NbF-1LLL -_ Date 2,6 A-)G Zod Well Depth 40 Depth to Water 3S S-2 Well Diameter 2" Casing Material PVC Screen Length _(S Well V1Jatpr Volume 0, 73 Sampling Crew V_ GAAfLC,! N Pump Type Peristat#� Sup Tubing Type Poly Intake set at Weather Conditions 1 ,1-1 20'5 Notes (eg. odor or color) LIGHT "o Wwcr TIN i Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 10A W,.l M-__ T11M i(I-10 N Jmnfl 1 10F11 hcglrml (:standnrdl (MVl (NTttl Other Parameters Sampled at L6% Parameters taken with YSI 556, LaMontte 2020 Samples delivered to _ Q;� ISM by 14. 6AAg&fj at / `100 Analysis VOCs Preservative HCL Bottle ware Number of Bottles 40 ml VOAs glass 3 Hold Time 14 Days SVOCs None 1 Liter glass Z 7 Days Metals Nitric Acid 250 ml plastic 1 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other l c K� A� rc Vm-> k n. I�' B�L1. t G No &DO Allu well volume calculation 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons_ C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form P(LF,-1&)36c; of, WITHERS &- RAVENEL Page "7 of ENGINEERS i PLANNERS i SURVEYORS Job Number__ u,3 , 2631q/, oo Groundwater Sampling Form State ID Well ID W - Z Site Name __ HFNsw-) LANDFILL Date U /4UG Zola Well Depth �o Depth to Water 3� Well Diameter 2" Casing Material pv;, Screen Length (5 Well Water Volume 0' ig Sampling Crew .�. BJ h 6ri Pump Type P.ecis"c s,)t, Tubing Type Poly; __. Intake set at Weather Conditions 1wG&x 6T, 1-1I (,H S6'5 Notes (eg. odor or color) (t GN'r R-M oA A AtAjE TrNT Time Water Level Volume Purged DO Temp EC pH ORP Turbidity PDA I-Ir 1 /frnm Tr)() 1ralc 1 1rr5n11.t 10C1 IuSlcml (standard) (mV1 (NTU1 �offAM ' �® �® Other Parameters Sampled at !Iyss Parameters taken with YSI 556, LaMontte 2020 Samples delivered to P2rSM by It, 6AAR-SoN at jypn Analysis VOCs Preservative HCL Bottle ware 40 ml VOAs glass Number of Bottles 3 Hold Time 14 Days SVOCs_ None 1 Liter glass Z. 7 Days Metals Nitric Acid 250 ml plastic I. 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other 1 r7 C G 4o I &Mlaer upu ia. 3 S,)LF Ct: t, fUbt, A1orJ_G Soo t pjk6d I _ ,- Well volume Gaicuiation 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons CADocuments and Settings\kbaarson\Desktop\GW Sampling Form P'd5i (nllLUtlonj WITHERS &— RAV E N E L Page �_ of (,I ENGINEERS I PLANNERS i SURVEYORS Job Number 63090381, oo Groundwater Sampling Form State ID Well ID dt%1W-zoA. Site Name ljGNS.or! Date 6L Sep zo tt Well Depth Mrs- Depth to Water 7.7Zik Well Diameter 2" _ Casing Material PV G Screen Length _ Ejo Well Water Volumey� Sampling Crew Pump Type RQ4&ta4c So ¢. Tubing Type Poly Intake set at Weather Conditions Gl,out)d .MICR Ro's Notes (eg. odor or color) AttNe. Time Water Level Volume Purged DO Temp EC pH ORP Turbidity .19A Hr.1 ffrrim Tr)i'_.1 MMIC 1 fmn/I1 fam fnSfcml, (standard) fmVl fNT1.1) • !►®WRIMM� Other Parameters Sampled at 0660 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to �41&cjA by1C, RA�d t.N at \?U Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic i 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other lor- i s u. ATCI . - - lutmid 9•66 l' c t G U ' NOA16 Z (? rn 1.& J' Well volume Gaicuiation 1" well [well depth -depth to water] " 0.0408 gallons 2" well [well depth -depth to water] ' 0.163 gallons 4" well [well depth -depth to water] ' 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form P66T 103, b - WN WITHERS &- RAV E N E L Page Z of _ C: ENGINEERS i PLANNERS i SURVEYORS Job Number 07__010,�_RI,od Groundwater Sampling Form State ID Well ID _MW-710 Site Name H NSan► LgNpFlt-(. Date pZ s6p U11 Well Depth 14' ), Depth to Water Z7,$ Well Diameter 2" Casing Material PUC. Screen Length Well Water Volume Sampling Crew IG. �hR�► Pump Type Peg&tam% SV(6 Tubing Type Poly Intake set at Weather Conditions CWU6Y 1-(IGH Ro's Notes (eg..odor orcolor) n1� vL Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr_) Cfrnrii T(1C1 (Gals 1 rrimnll 1 7°i^1 hiSlaml Istandardl (Myl lNTl1% WIWI No Other Parameters Sampled at 0700 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to p;Ll by V_ Vy"f-scw at Vao Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic I 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Loc. _ �► ya„ Ml is 3 5-u�Fh i s 0 JL &hYfie, — Well Volume Gaiculation 1"well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons CADocuments and Settings\kbaarson\Desktop\GW Sampling Form ?05 11, 36c lord WITHERS &' RAVENEL Page 3 of / ENGINEERS I PLANNERS i SURVEYORS Job Number 630g03gj,6o Groundwater Sampling Form State ID Well ID M4f - 3_ Site Name Hbmscm L ADF-IU. Date oz SSP roll Well Depth qn Depth to Water 15,48 Well Diameter 2" _ Casing Material P\)c Screen Length [.0 Well Water Volume p. j Sampling Crew IL, 64A4 6om Pump Type P-s4e6ttia 5,4 (y Tubing Type Poly Intake set at Weather Conditions G1-ov D Y, -wls Notes (eg. odor or color) FAW T Sot.FUR ap,,e UGH-T 9" cAU(,6 ctu& Time Water Level Volume Purged DO Temp EC pH ORP Turbidity MA I-Ir \ Ifrnm Tnr\ /(-nIc 1 1 r;iifl I fam hoRh-ml (Gtanriardl trnv) fNTltl other parameters Sampled at agao Parameters taken with YSI 556, LaMontte 2020 Samples delivered to ?a_kr.NA by V WA-(L' at M o Analysis Preservative Bottle ware Number of Bottles Hold Time VOCS HCL 40 ml VOAs glass 'X. _ 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic i 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass - 7 days Pesticides None 1 Liter glass 7 Days Other - - - � V; a 3 - Ct r Well Volume ualculatlon 1"well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS &- RAV E N E L Page of IV ENGINEERS i PLANNERS i SURVEYORS Job Number p3pg03�1. Oy Groundwater Sampling Form State ID Well ID /ALj.-2 Site Name HCN_SL; .L,IIA}bPy4_ Date o7- sep 2011 Well Depth _ yp _ _ Depth to Water 3%e7$ Well Diameter 2" Casing Material 4'y� Screen Length /&;7 Well Water Volume Sampling Crew , &AAAL, t-j. Pump Type Rerista+fic 5U,D, Tubing Type Poly Intake set at. Weather Conditions C'L-60 1. 1, 16H 80s Notes (eg. odor or color) Fe4r.oJT SukFutt ap-,1Z NM1 Mw -3 Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 02A Hr ) lknrn Tnrn male i (mnlb l (0C1 (uStem:) (standard) '(mV) (NTUt� Other Parameters Sampled at 0400 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to Mum by V.. 6AhR8aN at jg30 Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic j 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other H(_J, °( Al Vd .4JV, +s 3 50 I n 1 %.` Well volume c:aiculatlon 1" well [well depth -depth to water] ' 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] '' 0.653 gallons C:\Documents and Settingslkbaarson\Desktop\GW Sampling Form I S � MA �"C t�V VO5A 1 t 6,cx%0 s' WITHERS &— RAV E N E L Page f of - — ENGINEERS i PLANNERS I SURVEYORS Job Number 6 3o 110 3g/,00 Groundwater Sampling Form State ID _ Well ID Site Name I16,kso,j L"ZF1Q, Date a> vc, 2�) q __ Well Depth 2$;- Depth to Water. Z.11 f D Well Diameter 2"_ Casing Material eZ Screen Length 4y Well Water Volume Sampling Crew h M/hZ5,A) Pump Type "'—, SV Tubing Type Poly Intake set at Weather Conditions wni y C ? o q. _ Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hn). (from TOC1' (Gals.). (mo/Ll. tool (uS/cin) (standard) (mV) (NTU) Uther parameters Sampled at 0600 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to QhIs M by IL. l4M(Cs n1 at / yap Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic (- 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other SbC GL �� I v4?s T ,W n lass 3 Well volume calculation 1 " well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] ' 0.163 gallons 4" well [well depth -depth to water] ' 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS & RAV E N E L Page 2 of ENGINEERS i PLANNERS I SURVEYORS Job Number_ 89 03a� 0381, s u Groundwater Sampling Form State ID Well ID M,w -10 Site Name klis..,a LAW11*161* Date 0-7 , 0&T Z,61 Well Depth tic) Depth to Water zg , r z Well Diameter 2" Casing Material_ PUG Screen Length I Well Water Volume Sampling Crew _V, 6A+u,,rj Pump Type Re4atffltl"c Sme Tubing Type Poly Intake set at Weather Conditions .SuNAIY 70'5 Notes (eq. odororcolor) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 HrA (froth TOO) fGals_) (mn(I 1 tor.) (IiS(cml (.-,tqnrlPrrft tMVI INITI 11 uuler rarameters Sampled at 0706 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to ARasm by tic e6giks�,� at ) `! 30 Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCS None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic t 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other H U, 3 VVel1 volume:e CJaIGUlatlon 1" well [well depth -depth to water] " 0.0408 gallons 2" well [well depth -depth to water] ` 0.163 gallons 4" well [well depth -depth to water] 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS &- RAVENEL Page 3 of !I_ ENGINEERS i PLANNERS i SURVEYORS 03�'ip3gl,b� Job Number 8&7e499-49 Groundwater Sampling Form State ID Well ID Mu -.3 Site Name HF,Nso�AmCp)L,6 NG&PA- Date 67 0 I Sol,/ Well Depth yd.._ Depth to Water _ ?6,2,1 Well Diameter _ 2" Casing Material ivG Screen Length Well Water Volume Sampling Crew IL, GA/4(Z$6n) Pump Type Ee6stattie Tubing Type Poly Intake set at Weather Conditions SUN OY . -2 o's Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from.TOb (Gals.) (ma/L) VC) (A/cm) (standard) (mV) (NTU) ®ITOEM. M Other Parameters Sampled at pgoo Parameters taken with YSI 556, LaMontte 2020 Samples delivered to P2►SM by (L, 6WSar1 at j 4 30 Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic j 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other 6C - (1 Nahr�r Well Volume Calculation 1" well [well depth -depth to water] ' 0.0408 gallons 2" well [well depth -depth to water] ` 0.163 gallons 4" well [well depth -depth to water] " 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS I- RAV E N E L Page G1 of ENGINEERS I PLANNERS I SURVEYORS 03C�a3i. �ij Job Number .307 8t4 "g-- Groundwater Sampling Form State ID N�Ns Well ID r1gW_1z Site Name UAaFIGL., lgesPk _ _ Date 07 O G7 Well Depth !,p Depth to Water Well Diameter 2".- Casing Material p,rC, Screen Length (_ Well Water Volume Sampling Crew L. �AAX S6,-3 Pump Type Porna4tir S.� (� Tubing Type Poly Intake set at Weather Conditions SuN r1Y 7o's Notes (eg. odor or color) Time Water Level Volume Purged DO TI Temp P EC P H ORP Turbidity t24 Hr_1 Ornm TO i tGAls_l (ma/L) t°c) (u4/aril (standard) (rriVI (NTU) Other Parameters Sampled at oyoo Parameters taken with YSI 556,, LaMontte 2020 Samples delivered to PR-15M by It. 64/1'&66/13 at 1 `130 Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs, HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic .( 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other E, (. .—.6 'ofv l Well Volume Calculation 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form I�,vG,t [ors WITHERS & RAV E N E L Page ( of !J ENGINEERS i PLANNERS i SURVEYORS —L— Job Number z; 0-clo Groundwater Sampling Form State ID Well ID M, , ' 74 Site Name LAN()Fl(, Date p Nov 7,01) Well Depth Z.-S Depth to Water Well Diameter 2" Casing Material Pic--- Screen Length yp Well Water Volume Sampling Crew )t:,. 6 4ru&N Pump Type Pie 5,)3 Tubing Type Poly Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (2-4 Hr.) (from TOC1 (G21s.1 (ma/L) ('C) (uS/cm) "(standard) (mW (NTU) Uther Parameters Sampled at p 8p Parameters taken with YSI 556,_LaMontte_2020 Samples delivered to p2tSM by ►L, 6A4RSoa at - Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 mI VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other 1 `tD,J V one } .wu h-'6:'' i,i} Nofir, well volume Calcination 1" well [well depth -depth to water] ; 0.0408 gallons 2" well [well depth -depth to water] " 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS &- RAV E N E L Page -Z, of ENGINEERS i PLANNERS i SURVEYORS Job Number o3oy.0 z?t,,o0 Groundwater Sampling Form State ID -' Well ID Site Name HGNsor7 LAriDPIU, Date o$A;ov U&I Well Depth AiRr `to Depth to Water i/rl Well Diameter 2" Casing Material PVG Screen Length IS- Well Water Volume Sampling Crew Pump Type Peristakic 306 Tubing Type Poly Intake set at Weather Conditions _ Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) 1from TbCl (Gals-1 (mo/L) (°Cl (uS/cm) (standard) (mV1 (NTO) 06zo !',S_o 7s./S �yl g.31 —(37, 61 27,9 o6Zs 4�.03 CD, 3q $-.j6 --137_•,g— ZZ-6 0 00 i.S iy O. 3V5 /7 Z 0 1 .1 o,y �•�l —i37• G JZ,-- OGLrs o,s3 IS-41 O,3yy 7,gr -138,J 7,'7 t56- D c�„ [S ,tl O 95 7.9) 3 ,L 6•S-_ 6SS b, yq 1.—,(1 -0.ifs. 7, 7q •-/39, S,. 0700 Y fs-, 11 0 .3yY .7,77 - 338',Z S•6 Other Parameters Sampled at o700. Parameters taken with YSI 556,_LaMontte_2020 Samples delivered to FA -Ism by r—, 9A49.sc, at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic j 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other -CoC LL L10,h ( V C . ,,a,b_(r61,51 3 SQL .iF, 1N( 7 A1�rJ G Y. Well Volume Calculation 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS &- RAV E N E L Page 3 of C4 ENGINEERS i PLANNERS i SURVEYORS Job Number c53o9biPl.oe Groundwater Sampling Form State ID Well ID mwj— X Site Name ktGNSesr)n1b.tUt,, Date (3l Ai0V Zo i( Well Depth _ _�i o _. Depth.to Water 361 q3 Well Diameter 2" _ Casing Material pV�. Screen Length I Well Water Volume Sampling Crew N XA-gA any_ Pump Type Regetattfz S�)Q, Tubing Type Poly Intake set at Weather Conditions _ Notes (eg. odor or color) 5U - T o2ANGLr_-c"oLvA Time Water Level Volume Purged DO Temp EC pH ORP Turbidity Me ur I lire.., rnrN rrz.f. t fmnli t 1�P1 hokirml istandardl fmVl INTUI v7 Zo _ _ 1 .6 : _ - 6.qV 2, 60_ _ 39�; v 23 y o'7z 7, qo 17,0() 4 Z, bo 3S" ..3 . __ / d 3. 07 30 7,13 17,69 - Z, V- ?S 71.4, z . 6 _ o73s - -- - 17, I - -7• 5_ z,36 376. Z /7. q 0710 S 75- 17• q .., i 15 z.2, _ 3 9.E l y• 0-745' - o7s"a 4.3" 17. 77 _ , i _ v7ss °t. .7,7 1., 60'. 1-87 379, 9 BLS 0$00 41_30 17.7 7.LiZS_ 11 S 3g9.0 6.6Z Other Parameters Sampled at 0100 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to by K. 9ft Sant at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic j .180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other -TOC- Ii X/OAC QAV 1Ass 3 s.,Lf A- i ci 5- U . zw r s, _L10A well Volume upicuaanon 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form i WITHERS & RAV E N E L Page t of -. ENGINEERS i PLANNERS i SURVEYORS Job Number D 3oq .o q 1, c Groundwater Sampling Form State ID _ Well ID /AW-7, Site Name HGniScrl L AntDPU- Date pq nNoy u_ i! Well Depth Li 0 Depth to Water .3.9. 7Z. Well Diameter 2" Casing Material _�V(,_ Screen Length �_ Well Water Volume Sampling Crew y.,. S,AAI&prj_ , Pump Type Tubing Type Poly Intake set at _ Weather Conditions Notes (eg. odor or color) S7 -94 N c __suz_r_aC r o02 OiZ11,My fs G._Lc !L Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 1-10 (from TOCI (Gnis_1 fmnIt tom (uSlrml (standardl (mV1 (NTI11 Other Parameters Sampled at 01100 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to tt -ksm by !L, 6A,+Psc.nQ at Analysis Preservative Bottle ware Number of Bottles Hold Time VOCS HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic t 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other t 1 t. FI GL t D U ..S 3 Weil Volume Gaicuiation 1" well [well depth -depth to water] ` 0.0408 gallons 2" well [well depth -depth to water] ` 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form r 5 R.� Mo��Nt✓� Posi 1rJJLC.(t0rJ WITHERS & RAVENEL Page 1 of �( ENGINEERS i PLANNERS i SURVEYORS -t- Job Number 03 0c103 g I,00 Groundwater Sampling Form State ID Well ID A'ov-To A. Site Name K(;,Ns(,,4 LAobFll 1, Date ce, pee_ Z011 Well Depth 2, <, Depth to Water L`1 ,..{ Well Diameter 2" Casing Material V\i-G Screen Length 4 0 Well Water Volume Sampling Crew V_ %AR(tc�N Pump Type Pmistatttd S;tj& Tubing Type Poly Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity MA ur.1 6frnr„ Trlr71 Irnic 1 Imnll 1 torn (HR/cml (standard) (mv (.NTUI utner Parameters Sampled at boo Parameters taken with YSI 556, LaMontte 2020 Samples delivered to Pa.\Snn by y-, �>AAaso.N at 11 39 Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs. HCL 40 ml VOAs glass 14 Days SVOCs None 1 -Liter glass 7 Days Metals Nitric Acid 250 ml plastic { 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other i-'6 L c. Ho�►� V� x . tvN• weir volume ualcuauon 1" well [well depth -depth to water] " 0.0408 gallons 2" well [well depth -depth to water] ' 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form of WITHERS &- RAV E N E L Page Z (.� ENGINEERS i PLANNERS t SURVEYORS Job Number o3or1 o" qj. ,30 Groundwater Sampling Form State ID Well ID 1 %i,,,) -' Site Name HEN500 L+AbN -IGL, Date o6 Dt_TC. Zo, l Well Depth _ __ 4 o _ . Depth to Water 27. `iZ, Well Diameter 2" _ Casing Material PK Screen Length 1S' Well Water Volume Sampling Crew If, . ( AAA S-d Pump Type Perietelt7s. 5i,,-& Tubing Type _Poly Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from TOC) (Gals_1 (ma/L) ('C). (uS/cm) (standard) (mV): (NTLI) Other Parameters Sampled at 000 Parameters taken with YSI 556, LaMontte 2020 Samples delivered to M3rA by 4. 5A.,l-Iz-svN at 113`1 Analysis Preservative Bottle ware Number,of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic I 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Su( =lr cllLv - Ncn►C ALL Well Volume Calculation 1" well [well depth -depth to water] " 0.0408 gallons 2" well [well depth -depth to water] ` 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS &- RAVENEL Page 3 of �1 1 ENGINEERS I PLANNERS I SURVEYORS Job Number o� oryr 38(,ao Groundwater Sampling Form State ID Well ID Mw-� Site Name RCAISc-N L," DP10- Date _0b DlrG Zoir Well Depth y h Depth to Wafer 36,31 Well Diameter 2" Casing Material P J C Screen Length 15 Well Water Volume Sampling Crew \(-. Q MgsorJ Pump Type Ro4sta4ie g,Jd Tubing Type Poly Intake set at Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity hd Hr ) Urnm ThC'1 rr,alg 1 imnll 1 7°Cl (uShmil (standard) (mV1 (NT111 other Parameters Sampled at p-706 Parameters taken with _ _ YSI 556, LaMontte 2020 Samples delivered to M sm by V, J AAf-Sony_ at 113c) Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic ( 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other To L -H F.L. ,w 04, insr 3 su h �D - oNt i 'c well volume calculation 1" well [well depth -depth to water] " 0.0408 gallons 2" well [well depth -depth to water] ' 0.163 gallons 4" well [well depth -depth to water] " 0.653 gallons C:\Documents and Settings\kbaarson\Desktop\GW Sampling Form WITHERS & RAVENEL Page LA of ENGINEERS i PLANNERS I SURVEYORS Job Number o 3 cei o 3 S 1,c)() Groundwater Sampling Form State ID Well ID . .Mw Site Name MCNS,,N j-"DPILL Date o6- ,c- - _eo it Well Depth tto Depth to Water 1, q 3. Well Diameter 2" Casing Material PJC Screen Length ) s Well Water Volume Sampling Crew k. 6 AA ti50,1 Pump Type Rec Svc Tubing Type Poly Intake set at - Weather Conditions Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 19d I-Ir 1 ffrnm Tr)(1 Malc 1 lmia/1 1 (96 (t.iS/rm) (standardl (mV) (Mn m Other Parameters Sampled at b$aa Parameters taken with YSI 556, LaMontte 2020 Samples delivered to R- sM. ___ by K, at )f3: Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 3 14 Days SVOCs None 1 Liter glass __ _ 7 Days Metals Nitric Acid 250 ml plastic 1 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other c, cL q0A VOAs Am iw (a 3 L l Well Volume Calculation 1" well [well depth -depth to water] * 0.0408 gallons 2" well [well depth -depth to water] * 0.163 gallons 4" well [well depth -depth to water] * 0.653 gallons CADocuments and Settings\kbaarson\Desktop\GW Sampling Form %PRISM ,a lA RMATORIES INC. Full -Service Analytical & Environmental Solutions Withers & Ravenel-Wilmington Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cert No. 37735 Project: Henson Landfill Lab Submittal Date: 08/26/2011 Prism Work Order: 1080715 Case Narrative 09/07/2011 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: TOC analysis was subcontracted to GCAL. Laboratory report is attached. Analysis note for 3030C Chromium: Chromium was detected in the Method Blank at 3.98 ug/L. SWS Limit is 10 ug/L. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. 6 /1 �'J VP Laboratory Services Reviewed By This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/526-0409 Page 1 of 52 Data Qualifiers Key Reference: B Analyte is found in the associated blank as well as in the sample (CLP B-flag). J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L1 LCS recovery outside of the QC limits. LCSD recovery within the limits. No further action taken. L2 LCSD recovery outside of the QC limits. LCS recovery within the limits. No further action taken. M Matrix spike outside of the control limits. P Recovery outside of the QC limits due to inconsistency during extraction and chromatographic performance of this compound. SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041625-0409 Page 2 of 52 Full -Service Analytical 8PRISM I Evironmentaf Solutions Ln1 AT0111- ING Sample Receipt Summary 09/07/2011 Prism Work Order: 1080715 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW-20A 1080715-01 Water 08/26/11 08/26/11 MW-20 1080715-02 Water 08/26/11 08/26/11 MW-3 1080715-03 Water 08/26/11 08/26/11 MW-2 1080715-04 Water 08/26/11 08/26/11 Samples received in good condition at 5.3 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 3 of 52 P R I SqM Laboratory Report Full -Service Analytical & ps Environmental Solutions 09/07/2011 LwBOi1A O ES N Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1080715-01 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 08:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 3030C Metals Arsenic 2.1 ug/L 1.0 0.12 1 6020A 8/31/11 13:10 DWR P110001 Cadmium BRL ug/L 1.0 0.20 1 6020A 8/31/11 13:10 DWR P110001 Chromium 4.1 B ug/L 1.0 0.12 1 6020A 8/31/11 13:10 DWR P110001 Copper 1.0 J ug/L 5.0 0.53 1 6020A 8/31111 13:10 DWR P110001 Lead 0.15 J ug/L 1.0 0.13 1 6020A 8/31111 13:10 DWR P110001 Selenium 0.79 J ug/L 1.0 0.44 1 6020A 8/31/11 13:10 DWR P110001 Silver BRL ug/L 1.0 0.059 1 6020A 8/31/11 1310 DWR P110001 Zinc 3.8 J ug/L 10 0.58 1 6020A 8/31/11 13:10 DWR P110001 Anions by Ion Chromatography Chloride 1400 Sulfate 26000 Semivolatile Organic Compounds by GC/MS ug/L ug/L 1000 10000 8.6 120 1 10 9056A 9056A 8/29111 17:02 8/30/11 10:47 RSL RSL PlHO642 PlH0642 1,2,4-Trichlorobenzene BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PIH0677 1,2-Dichlorobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 1,3-Dichlorobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 1,4-Dichlorobenzene BRL ug/L 10 2.0 1 8270D 9/6/11 18:55 KC PlH0677 2,4,5-Tnchlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 18:55 KC PlH0677 2,4,6-Trichlorophenol BRL ug/L 10 2.3 1 8270D 9/6/11 18:55 KC PlH0677 2,4-Dichlorophenol BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlH0677 2,4-Dimethylphenol BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlHO677 2,4-Dinitrophenol BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlH0677 2,4-Dinitrotoluene BRL ug/L 10 0.95 1 8270D 9/6/11 18:55 KC PlH0677 2,6-Dinitrotoluene BRL ug/L 10 1.6 1 8270D 9/6/11 1855 KC PlH0677 2-Chloronaphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 18:55 KC PlH0677 2-Chlorophenol BRL ug/L 10 2.1 1 8270D 9/6111 18:55 KC PlH0677 2-Methyl naphthalene BRL ug/L 10 2.6 1 8270D 9/6/11 18:55 KC PlH0677 2-Methylphenol BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlHO677 2-Nitroaniline BRL ug/L 10 1.9 1 8270D 9/6/11 18:55 KC PlH0677 2-Nitrophenol BRL ug/L 10 2.5 1 8270D 9/6/11 18:55 KC PlH0677 3,3'-Dichlorobenzidine BRL ug/L 10 0.96 1 8270D 9/6/11 18:55 KC PlH0677 3/4-M ethyl phenol BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlH0677 3-Nitroaniline BRL ug/L 10 1.3 1 8270D 9/6/11 18:55 KC PlH0677 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.7 1 8270D 9/6/11 18:55 KC PlH0677 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 4-Chloro-3-methylphenol BRL ug/L 10 2.3 1 8270D 916/11 18:55 KC PlH0677 4-Chloroaniline BRL ug/L 10 2.5 1 8270D 9/6/11 18:55 KC PlH0677 4-Chlorophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 4-Nitroaniline BRL ug/L 10 0.91 1 8270D 916/11 18:55 KC PIH0677 4-Nitrophenol BRL ug/L 10 2.6 1 8270D 9/6/11 1855 KC PIH0677 Acenaphthene BRL ug/L 10 2.1 1 8270D 9/6/11 18:55 KC PlH0677 Acenaphthylene BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PlH0677 This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 4 of 52 ZR I aR I S M I Fullmee Analytical 8 Environironmental Solutions ine;numwies Luc Laboratory Report 09/07/2011 Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Sample Matrix: Water Client Sample ID: MW-20A Prism Sample ID: 1080715-01 Prism Work Order: 1080715 Time Collected: 08/26/11 08:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Aniline BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PlHO677 Anthracene BRL ug/L 10 1.2 1 8270D 9/6/11 18:55 KC PlH0677 Azobenzene BRL ug/L 10 1.8 1 82700 9/6/11 18:55 KC PlH0677 Benzo(a)anthracene BRL ug/L 10 0.95 1 8270D 9/6/11 18:55 KC PlH0677 Benzo(a)pyrene BRL ug/L 10 1.1 1 8270D 9/6/11 18:55 KC PlH0677 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 9/6/11 18:55 KC PlH0677 Benzo(g,h,i)perylene BRL ug/L 10 2.1 1 8270D 9/6/11 18:55 KC P1H0677 Benzo(k)fluoranthene BRL ug/L 10 1.1 1 8270D 9/6/11 18:55 KC PlH0677 Benzoic Acid BRL ug/L 100 50 1 8270D 9/6/11 18:55 KC PlH0677 Benzyl alcohol BRL ug/L 10 2.1 1 8270D 9/6/11 18:55 KC PlH0677 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PlH0677 Bis(2-Chloroethyl)ether BRL ug/L 10 1.9 1 8270D 9/6/11 18:55 KC P1H0677 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.3 1 8270D 9/6/11 18:55 KC PlH0677 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 Butyl benzyl phthalate BRL ug/L 10 1.5 1 8270D 9/6/11 18:55 KC PlH0677 Chrysene BRL ug/L 10 1.2 1 8270D 9/6/11 18:55 KC PlH0677 Dibenzo(a,h)anthracene BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 Dibenzofuran BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PlH0677 Diethyl phthalate BRL ug/L 10 1.4 1 8270D 9/6/11 18:55 KC PlH0677 Dimethyl phthalate BRL ug/L 10 1.6 1 8270D 9/6/11 18:55 KC PlH0677 Di-n-butyl phthalate BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 Di-n-octyl phthalate BRL ug/L 10 1.9 1 8270D 9/6/11 18:55 KC PlH0677 Fluoranthene BRL ug/L 10 0.94 1 8270D 9/6/11 18:55 KC PlH0677 Fluorene BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 Hexachlorobenzene BRL ug/L 10 1.4 1 8270D 9/6/11 18:55 KC PlH0677 Hexachlorobutadiene BRL ug/L 10 2.3 1 82700 9/6/11 18:55 KC PlH0677 Hexachlorocyclopentadiene BRL ug/L 10 1.8 1 8270D 9/6/11 18:55 KC PlH0677 Hexachloroethane BRL ug/L 10 1.9 1 8270D 9/6/11 18:55 KC PlH0677 Indeno(1,2,3-cd)pyrene BRL ug/L 10 1.6 1 8270D 9/6/11 18:55 KC PlH0677 Isophorone BRL ug/L 10 2.4 1 8270D 9/6/11 18:55 KC PlH0677 Naphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 18:55 KC PlH0677 Nitrobenzene BRL ug/L 10 2.0 1 8270D 9/6/11 18:55 KC PlH0677 N-Nitroso-di-n-propylamine BRL ug/L 10 2.3 1 8270D 9/6/11 18:55 KC PlH0677 N-Nitrosodiphenylamine BRL ug/L 10 1.6 1 8270D 9/6/11 18:55 KC PlH0677 Pentachlorophenol BRL ug/L 10 1.6 1 8270D 9/6/11 18:55 KC PlH0677 Phenanthrene BRL ug/L 10 1.2 1 8270D 9/6/11 18:55 KC PlH0677 Phenol BRL ug/L 10 2.2 1 8270D 9/6/11 18:55 KC PlH0677 Pyrene BRL ug/L 10 1.4 1 8270D 9/6/11 18:55 KC PlH0677 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 106 % 26-139 2-Fluorobiphenyl 68 % 41-112 2-Fluorophenol 46 % 10-48 Nitrobenzene-d5 70 % 34-102 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041625-0409 Page 5 of 52 PRISMLaboratory Report Full -Service Analytical & ` Environmental Solutions 09/07/2011 � .ueonnroniEs inc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1080715-01 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 08:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Phenol-d5 32 % 10-34 Terphenyl-d14 101 % 31-165 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL ug/L 0.20 0.014 1 7470A 8/31/11 13:51 LTB PlH0666 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.15 1 8260B 8/30/11 16:18 MGB PlHO661 1,1,1-Trichooroethane BRL ug/L 0.50 0.063 1 8260B 8/30/11 16:18 MGB PlH0661 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.071 1 8260B 8/30/11 16:18 MGB PlH0661 1,1,2-Trichooroethane BRL ug/L 0.50 0.17 1 8260B 8/30/11 16:18 MGB PlH0661 1,1-Dichloroethane BRL ug/L 0.50 0.096 1 8260B 8/30/11 16:18 MGB PlH0661 1,1-Dichloroethylene BRL ug/L 0.50 0.078 1 8260B 8/30/11 16:18 MGB PlH0661 1,1-Dichloropropylene BRL ug/L 0.50 0.061 1 8260B 8/30/11 16:18 MGB PlH0661 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.20 1 8260B 8/30/11 16:18 MGB PlH0661 1,2,3-Trichooropropane BRL ug/L 1.0 0.081 1 8260B 8/30/11 16:18 MGB PIH0661 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.10 1 8260B 8130/11 16:18 MGB PlH0661 1,2,4-Trimethylbenzene BRL ug/L 0.50 0.048 1 8260B 8/30/11 16:18 MGB PIH0661 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.59 1 8260B 8/30/11 16:18 MGB PIH0661 1,2-Dibromoethane BRL ug/L 0.50 0.14 1 8260B 8/30/11 16:18 MGB PIH0661 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 8/30/11 16:18 MGB PlH0661 1,2-Dichloroethane BRL ug/L 0.50 0.14 1 8260B 8/30/11 16:18 MGB PlH0661 1,2-Dichloropropane BRL ug/L 0.50 0.13 1 8260B 8/30/11 16:18 MGB PlH0661 1,3,5-Trimethylbenzene BRL ug/L 0.50 0.057 1 8260B 8/30/11 16:18 MGB PIH0661 1,3-Dichlorobenzene BRL ug/L 0.50 0.074 1 8260B 8/30/11 16:18 MGB PIH0661 1,3-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 8/30/11 16:18 MGB PIH0661 1,4-Dichlorobenzene BRL ug/L 0.50 0.068 1 8260B 8/30/11 16:18 MGB PlH0661 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 8130/11 16:18 MGB PlH0661 2-Chloroethyl Vinyl Ether BRL ug/L 2.0 0.22 1 8260B 8/30/11 16:18 MGB PlH0661 2-Chlorotoluene BRL ug/L 0.50 0.038 1 8260B 8/30/11 16:18 MGB PlH0661 4-Chlorotoluene BRL ug/L 0.50 0.053 1 8260B 8/30/11 16:18 MGB PlH0661 4-Isopropyltoluene BRL ug/L 0.50 0.065 1 8260E 8/30/11 16:18 MGB PlH0661 Acetone BRL ug/L 5.0 0.62 1 8260B 8/30/11 16:18 MGB PlH0661 Acrolein BRL ug/L 20 1.1 1 8260B 8/30/11 16:18 MGB PlH0661 Acrylonitrile BRL ug/L 20 0.86 1 8260B 8/30/11 16:18 MGB PlH0661 Benzene BRL ug/L 0.50 0.072 1 8260B 8/30/11 1618 MGB PlH0661 Bromobenzene BRL ug/L 0.50 0.064 1 8260B 8/30/11 16:18 MGB PlH0661 Bromochloromethane BRL ug/L 0.50 0.13 1 8260B 8/30/11 1618 MGB PlH0661 Bromodichloromethane BRL ug/L 0.50 0,062 1 8260B 8130/11 16:18 MGB PlH0661 Bromoform BRL ug/L 1.0 0.27 1 8260B 8/30/11 16:18 MGB PlH0661 Bromomethane BRL ug/L 1.0 0.47 1 8260B 8/30/11 16:18 MGB PlH0661 Carbon disulfide BRL ug/L 5.0 1.4 1 8260B 8/30/11 16:18 MGB PlH0661 Carbon Tetrachloride BRL ug/L 0.50 0.12 1 8260B 8/30/11 1618 MGB PlH0661 Chlorobenzene BRL ug/L 0.50 0.061 1 8260B 8/30/11 16:18 MGB PlH0661 Chloroethane BRL ug/L 0.50 0.13 1 8260B 8/30/11 16:18 MGB PlH0661 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 704/525-0409 Page 6 Of 52 Laboratory Report PRISMFull-ServiceAnalocal8 -, Environmental Solutions 09/07/201 1 .lnB'.MPiOniES iNC � Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1080715-01 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 08:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Chloroform BRL ug/L 0.50 0.089 1 8260B B/30/11 16:18 MGB P1H0661 Chloromethane BRL ug/L 0.50 0.11 1 8260B 8/30/11 16:18 MGB PlH0661 cis- 1,2-Dichloroethylene BRL ug/L 0.50 0.076 1 8260B 8/30/11 16:18 MGB PlH0661 cis- 1, 3-Dichloropropylene BRL ug/L 0.50 0.10 1 8260B 8/30/11 16:18 MGB PlH0661 Dibromochloromethane BRL ug/L 0.50 0.30 1 8260B 8/30/11 16:18 MGB PlH0661 Dibromomethane BRL ug/L 0.50 0.13 1 8260B 8/30/11 16:18 MGB PlH0661 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 8260B 8/30/11 16:18 MGB P1H0661 Ethylbenzene BRL ug/L 0.50 0.067 1 8260B 8/30/11 16:18 MGB P1 H0661 Hexachlorobutadiene BRL ug/L 2.0 0.36 1 8260B 8/30/11 16:18 MGB P1H0661 Isopropyl Ether BRL ug/L 0.50 0.043 1 8260B 8/30/11 16:18 MGB PlH0661 Isopropylbenzene(Cumene) BRL ug/L 0.50 0.072 1 8260B 8/30/11 16:18 MGB PlH0661 m,p-Xylenes BRL ug/L 1.0 0.081 1 8260B 8/30/11 16:18 MGB PlH0661 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.19 1 82606 8/30/11 16:18 MGB PlH0661 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.90 1 8260B 8/30/11 16:18 MGB PlH0661 Methyl Isobutyl Ketone BRL ug/L 5.0 0.12 1 8260B 8/30/11 16:18 MGB PlH0661 Methylene Chloride BRL ug/L 1.0 0.44 1 8260B 8/30/11 16:18 MGB PlH0661 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.070 1 8260B 8/30/11 16:18 MGB P1H0661 Naphthalene BRL ug/L 1.0 0.098 1 8260B 8/30/11 16:18 MGB P1H0661 n-Butylbenzene BRL ug/L 1.0 0.11 1 8260B 8/30/11 16:18 MGB P1H0661 n-Propylbenzene BRL ug/L 0.50 0.060 1 8260B 8/30/11 16:18 MGB PlH0661 o-Xylene BRL ug/L 0.50 0.046 1 8260B 8/30/11 16:18 MGB PlH0661 sec-Butylbenzene BRL ug/L 0.50 0.087 1 8260B 8/30/11 16:18 MGB PlH0661 Styrene BRL ug/L 0.50 0.047 1 B260B 8/30/11 16:18 MGB PlH0661 tert-Butylbenzene BRL ug/L 0.50 0.080 1 8260B 8/30/11 16:18 MGB PlH0661 Tetrachloroethylene BRL ug/L 0.50 0.069 1 B260B 8/30/11 16:18 MGB P1H0661 Toluene BRL ug/L 0.50 0.042 1 8260B 8/30/11 16:18 MGB P1H0661 trans- 1,2-Dichloroethylene BRL ug/L 0.50 0.12 1 8260B 8/30/11 16:18 MGB P1H0661 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.043 1 8260B 8/30/11 16:18 MGB PlH0661 Trichloroethylene BRL ug/L 0.50 0.054 1 8260B 8/30/11 16:18 MGB PlH0661 Trichlorofluoromethane BRL ug/L 0.50 0.088 1 8260B 8/30/11 16:18 MGB PlH0661 Vinyl acetate BRL ug/L 2.0 0.10 1 8260B 8/30/11 16:18 MGB PlH0661 Vinyl chloride BRL ug/L 0.50 0.16 1 8260B 8/30/11 16:18 MGB PlH0661 Surrogate Recovery Control Limits 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 102 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529.6364 - Fax: 7041525-0409 Page 7 of 52 PRISM Laboratory Report Full -Service Analytical & /Environmental Solutions 09/07/2011 r'd 1 --.- Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1080715-02 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 09:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic Cadmium Chromium Copper Lead Selenium Silver Zinc Anions by Ion Chromatography 50 BRL 3.8 B 1.5 J 2.4 1.3 0.067 J 16 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 1.0 1.0 1.0 5.0 1.0 1.0 1.0 10 0.12 0.20 0.12 0.53 0.13 0." 0.059 0.58 1 1 1 1 1 1 1 1 6020A 6020A 6020A 6020A 6020A 6020A 6020A 6020A 8/31/11 13:15 8/31/11 13:15 8/31/11 13:15 8131/11 13:15 8/31/11 13:15 8/31111 13:15 8/31111 13:15 8/31111 13:15 DWR DWR DWR DWR DWR DWR DWR DWR P110001 P110001 P110001 P110001 P110001 P110001 P110001 P110001 Chloride 46000 ug/L 10000 86 10 9056A 8/30/11 11:06 RSL PIH0642 Sulfate BRL ug/L 1000 12 1 9056A 8/29/11 17:20 RSL PlH0642 Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.3 1 8270D 9/6/11 19:33 KC PlH0677 1,2-Dichlorobenzene BRL ug/L 10 1.9 1 8270D 9/6/11 19:33 KC PlH0677 1,3-Dichlorobenzene BRL ug/L 10 1.9 1 8270D 9/6/11 19:33 KC PlH0677 1,4-Dichlorobenzene BRL ug/L 10 2.1 1 8270D 9/6/11 19:33 KC PlH0677 2,4,5-Trichlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 19:33 KC PlHO677 2,4,6-Trichlorophenol BRL ug/L 10 2.4 1 82700 9/6111 19:33 KC PlH0677 2,4-Dichlorophenol BRL ug/L 10 2.5 1 8270D 9/6111 19:33 KC PlH0677 2,4-Dimethylphenol BRL ug/L 10 2.5 1 8270D 9/6/11 19:33 KC PlH0677 2,4-Dinitrophenol BRL ug/L 10 2.4 1 8270D 9/6/11 19:33 KC PlH0677 2,4-Dinitrotoluene BRL ug/L 10 0.98 1 8270D 9/6/11 19:33 KC PlH0677 2,6-Dinitrotoluene BRL ug/L 10 1.7 1 8270D 9/6/11 19:33 KC PlH0677 2-Chloronaphthalene BRL ug/L 10 2.4 1 8270D 9/6/11 19:33 KC PlH0677 2-Chlorophenol BRL ug/L 10 2.2 1 8270D 9/6/11 19:33 KC PlH0677 2-Methylnaphthalene BRL ug/L 10 2.7 1 8270D 9/6/11 19:33 KC PlH0677 2-Methylphenol BRL ug/L 10 2.5 1 8270D 9/6/11 19:33 KC PlH0677 2-Nitroaniline BRL ug/L 10 2.0 1 8270D 9/6/11 19:33 KC PlH0677 2-Nitrophenol BRL ug/L 10 2.5 1 8270D 9/6/11 19:33 KC PlH0677 3,3'-Dichlorobenzidine BRL ug/L 10 0.99 1 8270D 9/6/11 19:33 KC P1H0677 314-Methylphenol 5.2 J ug/L 10 2.4 1 8270D 916/11 19:33 KC PlH0677 3-Nitroaniline BRL ug/L 10 1.4 1 8270D 9/6/11 19:33 KC PlH0677 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.8 1 8270D 9/6/11 19:33 KC PlH0677 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 9/6/11 19:33 KC PlH0677 4-Chloro-3-methylphenol BRL ug/L 10 2.4 1 8270D 9/6/11 19:33 KC PlH0677 4-Chloroaniline BRL ug/L 10 2.6 1 8270D 9/6/11 19:33 KC PlH0677 4-Chlorophenyl phenyl ether BRL ug/L 10 1.9 1 8270D 9/6/11 19:33 KC PlH0677 4-Nitroaniline BRL ug/L 10 0.94 1 8270D 9/6/11 19:33 KC PlH0677 4-Nitrophenol BRL ug/L 10 2.6 1 8270D 9/6/11 19:33 KC PlH0677 Acenaphthene BRL ug/L 10 2.2 1 8270D 9/6/11 19:33 KC PlH0677 Acenaphthylene BRL ug/L 10 2.3 1 8270D 9/6/11 19:33 KC PlH0677 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 8 of 52 R ISn � I FWI-Service Analytical s �,`d ' V, Environmental Solutions Laboratory Report 09/07/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1080715-02 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 09:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Aniline BRL ug/L Anthracene BRL ug/L Azobenzene BRL ug/L Benzo(a)anthracene BRL ug/L Benzo(a)pyrene BRL ug/L Benzo(b)fluoranthene BRL ug/L Benzo(g,h,i)perylene BRL ug/L Benzo(k)fluoranthene BRL ug/L Benzoic Acid BRL ug/L Benzyl alcohol BRL ug/L bis(2-Chloroethoxy)methane BRL ug/L Bis(2-Chloroethyl)ether BRL ug/L Bis(2-chloroisopropyl)ether BRL ug/L Bis(2-Ethylhexyl)phthalate BRL ug/L Butyl benzyl phthalate BRL ug/L Chrysene BRL ug/L Dibenzo(a,h)anthracene BRL ug/L Dibenzofuran BRL ug/L Diethyl phthalate BRL ug/L Dimethyl phthalate BRL ug/L Di-n-butyl phthalate BRL ug/L Di-n-octyl phthalate BRL ug/L Fluoranthene BRL ug/L Fluorene BRL ug/L Hexachlorobenzene BRL ug/L Hexachlorobutadiene BRL ug/L Hexachlorocyclopentadiene BRL ug/L Hexachloroethane BRL ug/L Indeno(1,2,3-cd)pyrene BRL ug/L Isophorone BRL ug/L Naphthalene BRL ug/L Nitrobenzene BRL ug/L N-Nitroso-di-n-propylamine BRL ug/L N-Nitrosodiphenylamine BRL ug/L Pentachlorophenol BRL ug/L Phenanthrene BRL ug/L Phenol BRL ug/L Pyrene BRL ug/L 10 2.3 1 8270D 9/6/11 19:33 KC PlH0677 10 1.3 1 8270D 9/6/11 19:33 KC P1 H0677 10 1.8 1 8270D 9/6/11 19:33 KC PlH0677 10 0.98 1 8270D 9/6/11 19:33 KC PlH0677 10 1.1 1 8270D 9/6/11 19:33 KC PlH0677 10 1.4 1 8270D 9/6/11 19:33 KC PIH0677 10 2.2 1 8270D 9/6/11 19:33 KC P1 H0677 10 1.1 1 8270D 9/6/11 19:33 KC PlH0677 100 52 1 8270D 9/6/11 19:33 KC PlH0677 10 2.1 1 8270D 9/6/11 19:33 KC PlH0677 10 2.2 1 8270D 9/6/11 19:33 KC PlH0677 10 1.9 1 8270D 9/6/11 19:33 KC PlHO677 10 2.4 1 82700 9/6/11 19:33 KC PlH0677 10 1.8 1 8270D 9/6/11 19:33 KC PlH0677 10 1.6 1 8270D 9/6/11 19,33 KC PlH0677 10 1.2 1 8270D 9/6/11 19:33 KC PlH0677 10 1.8 1 8270D 9/6/11 19:33 KC PlH0677 10 2.3 1 8270D 9/6/11 19:33 KC PlH0677 10 1.4 1 8270D 9/6/11 19:33 KC PlH0677 10 1.7 1 8270D 9/6/11 19:33 KC PlH0677 10 1.9 1 8270D 9/6/11 19:33 KC P1 H0677 10 2.0 1 8270D 9/6/11 19:33 KC PlH0677 10 0.97 1 8270D 9/6/11 1933 KC PlH0677 10 1.9 1 8270D 9/6/11 19:33 KC PlH0677 10 1.5 1 8270D 9/6/11 19:33 KC PlH0677 10 2.4 1 8270D 9/6/11 1933 KC P1 H0677 10 1.9 1 8270D 9/6/11 19:33 KC PIH0677 10 2.0 1 8270D 9/6/11 1933 KC PlH0677 10 1.6 1 8270D 9/6/11 19:33 KC PlH0677 10 2.5 1 8270D 9/6/11 19:33 KC PlH0677 10 2.4 1 8270D 9/6/11 19:33 KC P1 H0677 10 2.0 1 8270D 9/6/11 19:33 KC PIH0677 10 2.4 1 8270D 9/6/11 19:33 KC PlH0677 10 1.6 1 8270D 9/6/11 19:33 KC PlH0677 10 1.7 1 8270D 9/6/11 19:33 KC PlH0677 10 1.2 1 8270D 9/6/11 19:33 KC P1 H0677 10 2.2 1 8270D 9/6/11 19:33 KC PlH0677 10 1.4 1 8270D 9/6/11 1933 KC PlH0677 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 119 % 26-139 2-Fluorobiphenyl 82 % 41-112 2-Fluorophenol 35 % 10-48 Nitrobenzene-d5 83 % 34-102 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 9 of 52 P R I S M Laboratory Report Full -Service Analytical & 3 Environmental Solutions 09/07/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1080715-02 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 09:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Phenol-d5 36 % 10-34 SR Terphenyl-d14 119 % 31-165 Total Metals Mercury BRL ug/L 0.20 0.014 1 7470A 8/31/11 13:55 LTB PlH0666 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 8/31/11 2:16 MGB P1H0661 1, 1, 1 -Trichloroethane BRL ug/L 10 1.3 20 8260B 8/31/11 2:16 MGB P1H0661 1, 1, 2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 8/31/11 2:16 MGB PlH0661 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 8/31/11 2:16 MGB PlH0661 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 8/31/11 2:16 MGB PlH0661 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 8/31/11 2:16 MGB PlH0661 1, 1 -Dichloropropylene BRL ug/L 10 1.2 20 8260B 8/31/11 2:16 MGB PlH0661 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 8/31/11 2:16 MGB PlHO661 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 8/31/11 2:16 MGB PlH0661 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 8/31/11 2:16 MGB PlH0661 1,2,4-Trimethyl benzene BRL ug/L 10 0.95 20 8260B 8/31/11 2:16 MGB PlH0661 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 8/31/11 2:16 MGB PlH0661 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 8/31/11 2:16 MGB PlH0661 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 8/31/11 2:16 MGB PlH0661 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 8/31/11 2:16 MGB P1H0661 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 8/31/11 2:16 MGB PlH0661 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 8/31/11 2:16 MGB PlH0661 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 8/31/11 2:16 MGB PlH0661 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 8/31/11 2:16 MGB PlH0661 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 8/31/11 2:16 MGB PlH0661 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 8/31/11 2:16 MGB PlH0661 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 82608 8/31111 2:16 MGB P1H0661 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 8/31/11 2:16 MGB PlH0661 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 8/31/11 2:16 MGB PlH0661 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 8/31/11 2:16 MGB PlH0661 Acetone BRL ug/L 100 12 20 8260B 8/31/11 2:16 MGB PlH0661 Acrolein BRL ug/L 400 22 20 8260B 8/31/11 2:16 MGB PlH0661 Acrylonithle BRL ug/L 400 17 20 8260B 8/31/11 2:16 MGB PlH0661 Benzene 28 ug/L 10 1.4 20 8260E 8/31/11 2:16 MGB PlH0661 Bromobenzene BRL ug/L 10 1.3 20 8260B 8/31/11 2:16 MGB PlH0661 Bromochloromethane BRL ug/L 10 2.5 20 8260B 8/31/11 2:16 MGB PlH0661 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 8/31/11 216 MGB PlH0661 Bromoform BRL ug/L 20 5.4 20 8260B 8/31/11 2:16 MGB PlH0661 Bromomethane BRL ug/L 20 9.3 20 8260B 8/31/11 2:16 MGB PlH0661 Carbon disulfide BRL ug/L 100 28 20 8260B 8/31/11 2:16 MGB PlH0661 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 8/31/11 2:16 MGB PlH0661 Chlorobenzene 95 ug/L 10 1.2 20 8260E 8/31/11 2:16 MGB PlH0661 Chloroethane BRL ug/L 10 2.6 20 8260B 8/31/11 2:16 MGB PlH0661 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041526.0409 Page 10 of 52 /�P R I S M I Full -Service Analytical a Laboratory Report �i Environmental Solutions 09/07/2011 � uecnnro M - Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1080715-02 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 09:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Chloroform BRL ug/L 10 1.8 20 8260B 8/31/11 2:16 MGB PlH0661 Chloromethane BRL ug/L 10 2.2 20 8260B 8/31/11 2:16 MGB PlH0661 cis-1,2-Dichloroethylene 64 ug/L 10 1.6 20 82608 8/31/11 2:16 MGB PlH0661 cis- 1,3-D ichloropropylene BRL ug/L 10 2.1 20 8260B 8/31/11 2:16 MGB P1H0661 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 8/31/11 2:16 MGB P1H0661 Dibromomethane BRL ug/L 10 2.6 20 8260B 8/31/11 2:16 MGB PlH0661 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 8/31/11 2:16 MGB PlH0661 Ethylbenzene BRL ug/L 10 1.3 20 8260B 8/31/11 2:16 MGB PlH0661 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 8/31/11 2:16 MGB P1H0661 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 8/31/11 2:16 MGB P1H0661 Isopropylbenzene(Cumene) BRL ug/L 10 1.4 20 8260B 8/31/11 2:16 MGB P1H0661 m,p-Xylenes 16 J ug/L 20 1.6 20 8260B 8/31/11 2:16 MGB P1H0661 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260E 8/31/11 2:16 MGB PlH0661 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 100 18 20 8260B 8/31/11 2:16 MGB PlH0661 Methyl Isobutyl Ketone 13 J ug/L 100 2.5 20 8260E 8/31/11 2:16 MGB PlH0661 Methylene Chloride BRL ug/L 20 8.9 20 8260B 8/31/11 2:16 MGB PlH0661 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 8/31/11 2:16 MGB P1H0661 Naphthalene BRL ug/L 20 2.0 20 8260B 8/31/11 2:16 MGB P1H0661 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 8/31/11 2:16 MGB P1H0661 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 8/31/11 2:16 MGB PlH0661 o-Xylene BRL ug/L 10 0.92 20 8260B 8/31/11 2:16 MGB PlH0661 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 8/31/11 2:16 MGB PlH0661 Styrene BRL ug/L 10 0.94 20 8260B 8/31/11 2:16 MGB PlH0661 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 8/31/11 2:16 MGB PlH0661 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 8/31/11 2:16 MGB PlH0661 Toluene 5000 ug/L 100 8.5 200 8260E 8/31111 11:21 MGB P1H0661 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 8/31/11 2:16 MGB PlH0661 trans- 1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 8/31/11 2:16 MGB PlH0661 Trichloroethylene BRL ug/L 10 1.1 20 8260B 8/31/11 2:16 MGB PlH0661 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 8/31/11 2:16 MGB PlH0661 Vinyl acetate BRL ug/L 40 2.0 20 8260B 8/31/11 2:16 MGB PlH0661 Vinyl chloride BRL ug/L 10 3.1 20 8260B 8/31/11 2:16 MGB PlH0661 Surrogate Recovery Control Limits 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041526-0409 Page 11 of 52 Z.0;R IS M Laboratory Report Full -Service AnalyLcal 8Enironmental Solutions 09/07/2011 , ueoA•.oaEs me Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1080715-03 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 10:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID 3030C Metals Arsenic 53 ug/L 1.0 0.12 1 6020A 8/31111 13:20 DWR P110001 Cadmium BRL ug/L 1.0 0.20 1 6020A 8/31/11 1320 DWR P110001 Chromium 4.2 B ug/L 1.0 0.12 1 6020A 8/31111 13:20 DWR P110001 Copper 4.9 J ug/L 5.0 0.53 1 6020A 8/31111 13:20 DWR P110001 Lead 1.8 ug/L 1.0 0.13 1 6020A 8/31/11 13:20 DWR P110001 Selenium 1.4 ug/L 1.0 0.44 1 6020A 8/31/11 13:20 DWR P110001 Silver 0.15 J ug/L 1.0 0.059 1 6020A 8/31/11 13:20 DWR P110001 Zinc 17 ug/L 10 0.58 1 6020A 8/31/11 13:20 DWR P110001 Anions by Ion Chromatography Chloride 60000 Sulfate BRL Semivolatile Organic Compounds by GC/MS ug/L ug/L 10000 1000 86 12 10 1 9056A 9056A 8/30/11 11:25 8/29/11 17:39 RSL RSL P1H0642 PlH0642 1,2,4-Trichlorobenzene BRL ug/L 10 2.3 1 8270D 9/6/11 20:11 KC PlH0677 1,2-Dichlorobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 20:11 KC PlH0677 1,3-Dichlorobenzene BRL ug/L 10 1.8 1 82700 9/6/11 20:11 KC PlH0677 1,4-Dichlarobenzene BRL ug/L 10 2.1 1 8270D 9/6/11 20:11 KC PlH0677 2,4,5-Trichlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:11 KC PlH0677 2,4,6-Trichlorophenol BRL ug/L 10 2.4 1 8270D 9/6/11 20:11 KC PlH0677 2,4-Dichlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:11 KC PIH0677 2,4-Dimethylphenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:11 KC PlH0677 2,4-Dinitrophenol BRL ug/L 10 2.4 1 8270D 9/6/11 20:11 KC PlH0677 2,4-Dinitrotoluene BRL ug/L 10 0.97 1 8270D 9/6/11 20:11 KC PlH0677 2,6-Dinitrotoluene BRL ug/L 10 1.7 1 8270D 9/6/11 20:11 KC PlHO677 2-Chloronaphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 20:11 KC PlH0677 2-Chlorophenol BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlH0677 2-Methylnaphthalene BRL ug/L 10 2.7 1 8270D 9/6/11 2011 KC PIH0677 2-Methylphenol 5.0 J ug/L 10 2.4 1 8270D 9/6111 20:11 KC PlH0677 2-Nitroaniline BRL ug/L 10 2.0 1 8270D 9/6/11 20:11 KC PlH0677 2-Nitrophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:11 KC PlH0677 3,3'-Dichlorobenzidine BRL ug/L 10 0.98 1 8270D 9/6/11 20:11 KC PlH0677 3/4-Methylphenol 8.6 J ug1L 10 2.4 1 8270D 9/6111 20:11 KC PIH0677 3-Nitroaniline BRL ug/L 10 1.4 1 8270D 9/6111 2011 KC PlH0677 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.7 1 8270D 9/6/11 2011 KC PlH0677 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 9/6/11 2011 KC PlH0677 4-Chloro-3-methylphenol BRL ug/L 10 2.3 1 8270D 9/6/11 2011 KC PlH0677 4-Chloroaniline BRL ug/L 10 2.6 1 8270D 9/6/11 20:11 KC PlH0677 4-Chlorophenyl phenyl ether BRL ug/L 10 1.9 1 8270D 9/6/11 20:11 KC PIH0677 4-Nitroaniline BRL ug/L 10 0.93 1 8270D 9/6/11 20:11 KC PIH0677 4-Nitrophenol BRL ug/L 10 2.6 1 8270D 9/6/11 20:11 KC PlH0677 Acenaphthene BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlHO677 Acenaphthylene BRL ug/L 10 2.3 1 8270D 9/6/11 20,11 KC PlH0677 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 12 of 52 Laboratory Report %P R I S M I Full -Service Analytical & iyt Environmental Solutions 09/07/201 1 .� ueonn�ones ,nc. Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1080715-03 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 10:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Limit Dilution Factor Method Analysis Date/Time Analyst Batch ID Aniline BRL ug/L 10 2.3 1 8270D 9/6/11 20:11 KC PlH0677 Anthracene BRL ug/L 10 1.3 1 8270D 9/6/11 20:11 KC PlH0677 Azobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 20:11 KC PlHO677 Benzo(a)anthracene BRL ug/L 10 0.97 1 8270D 9/6/11 20:11 KC PlHO677 Benzo(a)pyrene BRL ug/L 10 1.1 1 8270D 9/6/11 20:11 KC PlH0677 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 9/6/11 20:11 KC PIH0677 Benzo(g,h,i)perylene BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlH0677 Benzo(k)fluoranthene BRL ug/L 10 1.1 1 8270D 9/6/11 20:11 KC PlHO677 Benzoic Acid BRL ug/L 100 51 1 8270D 9/6/11 20:11 KC PlH0677 Benzyl alcohol BRL ug/L 10 2.1 1 8270D 9/6/11 20:11 KC PlH0677 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlH0677 Bis(2-Chloroethyl)ether BRL ug/L 10 1.9 1 8270D 9/6/11 20:11 KC PlH0677 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.4 1 8270D 9/6/11 20:11 KC PlH0677 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 1.8 1 8270D 9/6/11 20:11 KC PlH0677 Butyl benzyl phthalate BRL ug/L 10 1.6 1 8270D 9/6/11 20:11 KC PlH0677 Chrysene BRL ug/L 10 1.2 1 8270D 9/6/11 20:11 KC PlH0677 Dibenzo(a,h)anthracene BRL ug/L 10 1.8 1 8270D 9/6/11 20:11 KC PlH0677 Dibenzofuran BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlH0677 Diethyl phthalate BRL ug/L 10 1.4 1 8270D 9/6111 20:11 KC PlH0677 Dimethyl phthalate BRL ug/L 10 1.7 1 8270D 9/6/11 20:11 KC PIH0677 Di-n-butyl phthalate BRL ug/L 10 1.9 1 8270D 9/6/11 20:11 KC PlH0677 Di-n-octyl phthalate BRL ug/L 10 1.9 1 8270D 9/6/11 20:11 KC PlH0677 Fluoranthene BRL ug/L 10 0.96 1 8270D 9/6111 20:11 KC PlH0677 Fluorene BRL ug/L 10 1.9 1 8270D 9/6/11 20:11 KC PlH0677 Hexachlorobenzene BRL ug/L 10 1.4 1 8270D 9/6/11 20:11 KC PlH0677 Hexachlorobutadiene BRL ug/L 10 2.3 1 8270D 9/6/11 20:11 KC PlH0677 Hexachlorocyclopentadiene BRL ug/L 10 1.8 1 8270D 9/6/11 20:11 KC PlH0677 Hexachloroethane BRL ug/L 10 2.0 1 8270D 9/6/11 20:11 KC PlH0677 Indeno(1,2,3-cd)pyrene BRL ug/L 10 1.6 1 8270D 9/6/11 20:11 KC PlH0677 Isophorone BRL ug/L 10 2.5 1 8270D 9/6/11 20:11 KC PIH0677 Naphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 20:11 KC PlH0677 Nitrobenzene BRL ug/L 10 2.0 1 8270D 9/6/11 20:11 KC PlH0677 N-Nitroso-di-n-propylamine BRL ug/L 10 2.4 1 8270D 9/6/11 20:11 KC PlH0677 N-Nitrosodiphenylamine BRL ug/L 10 1.6 1 8270D 9/6/11 20:11 KC PlH0677 Pentachlorophenol BRL ug/L 10 1.7 1 8270D 9/6/11 20:11 KC PlH0677 Phenanthrene BRL ug/L 10 1.2 1 8270D 9/6/11 20:11 KC PlH0677 Phenol BRL ug/L 10 2.2 1 8270D 9/6/11 20:11 KC PlHO677 Pyrene BRL ug/L 10 1.4 1 8270D 9/6/11 20:11 KC PlH0677 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 133 % 26-139 2-Fluorobiphenyl 90 % 41-112 2-Fluorophenol 59 % 10-48 SR Nitrobenzene-d5 90 % 34-102 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041625-0409 Page 13 of 52 Laboratory Report Pull -Service Analytical & PRISM �. ueonn.oniEs Inc Environmental Solutions 09/07/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1080715-03 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 10:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Datefrime ID Phenol-d5 40 % 10-34 SR Terphenyl-d14 126 % 31-165 Total Metals Mercury BRL ug/L 0.20 0.014 1 7470A 8/31/11 1359 LTB PlHO666 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 8/31/11 2:48 MGB PlH0661 1,1,1-Tdchloroethane BRL ug/L 10 1.3 20 8260B 8/31/11 2:48 MGB PlH0661 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 8/31/11 2:48 MGB PlHO661 1,1,2-Tiichloroethane BRL ug/L 10 3.3 20 8260B 8/31/11 2:48 MGB PlH0661 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 8/31/11 248 MGB PlH0661 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 8/31/11 248 MGB PlH0661 1, 1 -Dichloropropylene BRL ug/L 10 1.2 20 8260B 8/31/11 2:48 MGB PlH0661 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 8/31/11 2:48 MGB PlH0661 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 8/31/11 2:48 MGB PlH0661 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 8/31/11 2:48 MGB PlH0661 1,2,4-Trimethyl benzene BRL ug/L 10 0.95 20 8260B 8/31/11 2:48 MGB PlHO661 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 8/31/11 2:48 MGB PlH0661 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 8/31/11 2:48 MGB PlH0661 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 8/31/11 2:48 MGB PIH0661 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 8/31/11 2:48 MGB PlH0661 1,2-Dichloropropane BRL ug/L 10 2.5 20 82606 8/31/11 2:48 MGB PlH0661 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 8/31/11 2:48 MGB PlH0661 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 8/31/11 248 MGB P1H0661 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 8/31/11 248 MGB P1H0661 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 8/31/11 2:48 MGB PlH0661 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 8/31/11 2:48 MGB PlH0661 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 8/31/11 2:48 MGB PlH0661 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 8131/11 2:48 MGB PIH0661 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 8/31/11 2:48 MGB PlH0661 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 8/31/11 2:48 MGB PlH0661 Acetone 250 ug/L 100 12 20 8260B 8/31111 2:48 MGB PIH0661 Acrolein BRL ug/L 400 22 20 8260B 8/31/11 2:48 MGB PlH0661 Acrylonitrile BRL ug/L 400 17 20 8260B 8/31/11 2:48 MGB PlH0661 Benzene 40 ug/L 10 1.4 20 8260E 8/31111 2:48 MGB PIH0661 Bromobenzene BRL ug/L 10 1.3 20 8260B 8/31/11 2:48 MGB PlH0661 Bromochloromethane BRL ug/L 10 2.5 20 8260B 8/31/11 2:48 MGB PlH0661 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 8/31/11 2:48 MGB PlH0661 Bromoform BRL ug/L 20 5.4 20 8260B 8/31/11 2:48 MGB PlH0661 Bromomethane BRL ug/L 20 9.3 20 8260B 8/31/11 2:48 MGB PIH0661 Carbon disulfide BRL ug/L 100 28 20 8260E 8/31/11 2:48 MGB PIH0661 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 8/31/11 2:48 MGB PIH0661 Chlorobenzene 150 ug/L 10 1.2 20 8260B 8/31/11 2:48 MGB PIH0661 Chloroethane BRL ug/L 10 2.6 20 8260B 8/31/11 2:48 MGB PlH0661 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 14 of 52 /rPRISM I Full -Service Analytical& Laboratory Report 1 ., Environmental Solutions 09/07/2011 ,� LwBgill�ON1E4 LNG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1080715-03 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 10:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Chloroform BRL ug/L 10 1.8 20 8260B 8/31/11 2:48 MGB PIH0661 Chloromethane BRL ug/L 10 2.2 20 8260B 8/31/11 2:48 MGB PlH0661 cis-1,2-Dichloroethylene 290 ug/L 10 1.5 20 8260B 8/31/11 2:48 MGB PlH0661 cis- 1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 8/31/11 2:48 MGB PlH0661 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 8/31/11 2:48 MGB PlH0661 Dibromomethane BRL ug/L 10 2.6 20 8260B 8/31/11 2:48 MGB P1H0661 Dichlorodifluoromethane BRL ug/L 20 2.1 20 82608 8/31/11 2:48 MGB P1H0661 Ethylbenzene 20 ug/L 10 1.3 20 8260B 8131111 2:48 MGB PIH0661 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 8/31/11 2:48 MGB PlH0661 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 8/31/11 2:48 MGB PlH0661 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 8/31/11 2:48 MGB PlH0661 m,p-Xylenes 46 ug/L 20 1.6 20 8260B 8131/11 2:48 MGB PlH0661 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260E 8/31/11 2:48 MGB PIH0661 Methyl Ethyl Ketone (2-Butanone) 130 ug/L 100 18 20 8260B 8131111 2:48 MGB PIH0661 Methyl Isobutyl Ketone 800 ug/L 100 2.5 20 8260E 8/31111 2:48 MGB PlH0661 Methylene Chloride BRL ug/L 20 8.9 20 8260B 8/31/11 2:48 MGB P1H0661 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 8/31/11 2:48 MGB PIH0661 Naphthalene BRL ug/L 20 2.0 20 8260B 8/31/11 2:48 MGB PlH0661 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 8/31/11 2:48 MGB PlH0661 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 8/31/11 2:48 MGB PlH0661 o-Xylene 13 ug/L 10 0.92 20 8260B 8/31111 2:48 MGB P1H0661 sec-Butylbenzene BRL ug/L 10 1.7 20 82606 8/31/11 2:48 MGB P1H0661 Styrene BRL ug/L 10 0.94 20 8260B 8/31/11 2:48 MGB P1H0661 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 8/31/11 2:48 MGB P1H0661 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 8/31/11 2:48 MGB P1H0661 Toluene 4100 ug/L 100 8.5 200 82608 8/31111 11:52 MGB PIH0661 trans- 1, 2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 8/31/11 2:48 MGB PlH0661 trans- 1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 8/31/11 2:48 MGB PlH0661 Trichloroethylene BRL ug/L 10 1.1 20 8260B 8/31/11 2:48 MGB PlH0661 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260E 8/31/11 2:48 MGB PlH0661 Vinyl acetate BRL ug/L 40 2.0 20 8260B 8/31/11 2:48 MGB PlH0661 Vinyl chloride BRL ug/L 10 3.1 20 8260B 8/31/11 2:48 MGB PlH0661 Surrogate Recovery Control Limits 4-Bromofluorobenzene 107 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene -dB 100 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1.8001529-6364 - Fax: 7041626-0409 Page 15 of 52 PRISM Full-Sernce tin 8 Z Environmental al Solutions ueoanTonics Inc Laboratory Report 09/07/2011 Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1080715-04 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 11:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 73 ug/L 1.0 0.12 1 6020A 8/31/11 13:25 DWR P110001 Cadmium BRL ug/L 1.0 0.20 1 6020A 8/31/11 13:25 DWR P110001 Chromium 3.3 B ug/L 1.0 0.12 1 6020A 8131/11 13:25 DWR P110001 Copper 2.0 J ug/L 5.0 0.53 1 6020A 8131111 13:26 DWR P110001 Lead 0.85 J ug/L 1.0 0.13 1 6020A 8131/11 13:25 DWR P1110001 Selenium 2.5 ug/L 1.0 0.44 1 6020A 8/31/11 13:25 DWR P110001 Silver BRL ug/L 1.0 0.059 1 6020A 8/31/11 13:25 DWR P110001 Zinc 9.5 J ug/L 10 0.68 1 6020A 8/31111 13:26 DWR P110001 Anions by Ion Chromatography Chloride 26000 ug/L 5000 43 5 9056A 8/30/11 11:44 RSL P1H0642 Sulfate BRL ug/L 1000 12 1 9056A 8/29/11 17:51 RSL PlH0642 Semivolatile Organic Compounds by GC/MS 1,2,4-Trichlorobenzene BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC PlH0677 1,2-Dichlorobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlH0677 1,3-Dichlorobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlH0677 1,4-Dichlarobenzene BRL ug/L 10 2.1 1 8270D 9/6/11 20:49 KC PlH0677 2,4,5-Trichlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:49 KC PIH0677 2,4,6-Trichlorophenol BRL ug/L 10 2.4 1 82700 9/6/11 20:49 KC PlH0677 2,4-Dichlorophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:49 KC PlH0677 2,4-Dimethylphenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:49 KC PlH0677 2,4-Dinitrophenol BRL ug/L 10 2.4 1 8270D 9/6/11 20:49 KC PlH0677 2,4-Dinitrotoluene BRL ug/L 10 0.97 1 8270D 9/6/11 20:49 KC PlH0677 2,6-Dinitrotoluene BRL ug/L 10 1.7 1 8270D 9/6/11 20:49 KC PlH0677 2-Chloronaphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC PlH0677 2-Chlorophenol BRL ug/L 10 2.2 1 8270D 9/6/11 20:49 KC PlH0677 2-Methylnaphthalene BRL ug/L 10 2.7 1 8270D 9/6/11 20:49 KC PlH0677 2-Methylphenol 28 ug/L 10 2.4 1 8270D 916111 20:49 KC PlH0677 2-Nitroaniline BRL ug/L 10 2.0 1 8270D 9/6/11 20:49 KC PlH0677 2-Nitrophenol BRL ug/L 10 2.5 1 8270D 9/6/11 20:49 KC PlH0677 3,3'-Dichlorobenzidine BRL ug/L 10 0.98 1 8270D 9/6/11 20:49 KC PIH0677 314-Methylphenol 9.1 J ug/L 10 2.4 1 8270D 916/11 20:49 KC PIH0677 3-Nitroaniline BRL ug/L 10 1.4 1 8270D 9/6/11 20:49 KC PlH0677 4,6-Dinitro-2-methylphenol BRL ug/L 10 2.7 1 8270D 9/6/11 20:49 KC PlHO677 4-Bromophenyl phenyl ether BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlH0677 4-Chloro-3-methylphenol BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC PlH0677 4-Chloroaniline BRL ug/L 10 2.6 1 8270D 9/6/11 20:49 KC PlH0677 4-Chlorophenyl phenyl ether BRL ug/L 10 1.9 1 8270D 9/6/11 20:49 KC PlH0677 4-Nitroaniline BRL ug/L 10 0.93 1 8270D 9/6/11 20:49 KC PlH0677 4-Nitrophenol BRL ug/L 10 2.6 1 8270D 9/6/11 20:49 KC PlH0677 Acenaphthene BRL ug/L 10 2.2 1 8270D 9/6/11 20:49 KC PlH0677 Acenaphthylene BRL ug/L 10 2.3 1 82700 9/6/11 20:49 KC PlHO677 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 Page 16 of 52 ZRRISM I Full -Service Analytical 8 Laboratory Report Environmental Solutions 09/07/2011 A L�H(%lAtt?RIES LNG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1080715-04 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 11:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Aniline BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC P1H0677 Anthracene BRL ug/L 10 1.3 1 8270D 9/6/11 20:49 KC PlH0677 Azobenzene BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlHO677 Benzo(a)anthracene BRL ug/L 10 0.97 1 8270D 9/6/11 20:49 KC PlH0677 Benzo(a)pyrene BRL ug/L 10 1.1 1 8270D 9/6/11 20:49 KC PlH0677 Benzo(b)fluoranthene BRL ug/L 10 1.4 1 8270D 9/6/11 20:49 KC PlH0677 Benzo(g,h,i)perylene BRL ug/L 10 2.2 1 8270D 9/6/11 20:49 KC PlH0677 Benzo(k)fluoranthene BRL ug/L 10 1.1 1 8270D 9/6/11 20:49 KC PlH0677 Benzoic Acid BRL ug/L 100 51 1 8270D 9/6/11 20:49 KC PlH0677 Benzyl alcohol 11 ug/L 10 2.1 1 8270D 916/11 20:49 KC PlHO677 bis(2-Chloroethoxy)methane BRL ug/L 10 2.2 1 8270D 9/6111 20:49 KC PlH0677 Bis(2-Chloroethyl)ether BRL ug/L 10 1.9 1 8270D 9/6/11 20:49 KC P1H0677 Bis(2-chloroisopropyl)ether BRL ug/L 10 2.4 1 8270D 9/6/11 20:49 KC PlHO677 Bis(2-Ethylhexyl)phthalate BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlHO677 Butyl benzyl phthalate BRL ug/L 10 1.6 1 8270D 9/6111 20:49 KC PlH0677 Chrysene BRL ug/L 10 1.2 1 8270D 9/6/11 20:49 KC PIH0677 Dibenzo(a,h)anthracene BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlH0677 Dibenzofuran BRL ug/L 10 2.2 1 8270D 9/6/11 20:49 KC PlH0677 Diethyl phthalate BRL ug/L 10 1.4 1 8270D 9/6/11 20:49 KC PlH0677 Dimethyl phthalate BRL ug/L 10 1.7 1 8270D 9/6/11 20:49 KC PlH0677 Di-n-butyl phthalate BRL ug/L 10 1.9 1 8270D 9/6/11 20:49 KC PlH0677 Di-n-octyl phthalate BRL ug/L 10 1.9 1 8270D 9/6/11 20:49 KC PlH0677 Fluoranthene BRL ug/L 10 0.96 1 8270D 9/6/11 20:49 KC P1H0677 Fluorene BRL ug/L 10 1.9 1 8270D 9/6/11 20:49 KC PlH0677 Hexachlorobenzene BRL ug/L 10 1.4 1 8270D 9/6/11 20:49 KC PlH0677 Hexachlorobutadiene BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC PlH0677 Hexachlorocyclopentadiene BRL ug/L 10 1.8 1 8270D 9/6/11 20:49 KC PlH0677 Hexachloroethane BRL ug/L 10 2.0 1 8270D 9/6/11 20:49 KC PlH0677 Indeno(1,2,3-cd)pyrene BRL ug/L 10 1.6 1 8270D 9/6/11 20:49 KC P1H0677 Isophorone BRL ug/L 10 2.5 1 8270D 9/6111 20:49 KC PlH0677 Naphthalene BRL ug/L 10 2.3 1 8270D 9/6/11 20:49 KC PlH0677 Nitrobenzene BRL ug/L 10 2.0 1 8270D 9/6/11 20:49 KC PlH0677 N-Nitroso-di-n-propylamine BRL ug/L 10 2.4 1 8270D 9/6/11 20:49 KC PlH0677 N-Nitrosodiphenylamine BRL ug/L 10 1.6 1 8270D 9/6/11 20:49 KC PlH0677 Pentachlorophenol BRL ug/L 10 1.7 1 8270D 9/6/11 20:49 KC PlH0677 Phenanthrene BRL ug/L 10 1.2 1 8270D 9/6/11 20:49 KC PlH0677 Phenol BRL ug/L 10 2.2 1 8270D 9/6/11 20:49 KC PlH0677 Pyrene BRL ug/L 10 1.4 1 8270D 9/6/11 20:49 KC PlH0677 Surrogate Recovery Control Limits 2,4,6-Tribromophenol 127 % 26-139 2-Fluorobiphenyl 83 % 41-112 2-Fluorophenol 51 % 10-48 SR Nitrobenzene-d5 79 % 34-102 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 17 of 52 F R I S M FullService Analytical 8 '. Environmental Solutions ueonnT-E me Laboratory Report 09/07/201 1 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1080715-04 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 11:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Phenol-d5 34 % 10-34 SR Terphenyl-d14 120 % 31-165 Total Metals Mercury BRL ug/L 0.20 0.014 1 7470A 8/31/11 14:10 LTB PlH0666 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane BRL ug/L 20 5.9 40 8260B 8/31/11 1:45 MGB PlH0661 1, 1, 1-Trichloroethane BRL ug/L 20 2.5 40 8260B 8/31/11 1:45 MGB PlH0661 1, 1, 2,2-Tetrachloroethane BRL ug/L 20 2.9 40 8260B 8/31/11 1:45 MGB PlH0661 1,1,2-Trichloroethane BRL ug/L 20 6.6 40 8260B 8/31/11 1:45 MGB PlH0661 1,1-Dichloroethane BRL ug/L 20 3.8 40 8260B 8/31/11 1:45 MGB PlH0661 1,1-Dichloroethylene BRL ug/L 20 3.1 40 8260B 8/31/11 1:45 MGB PlH0661 1, 1 -Dichloropropylene BRL ug/L 20 2.5 40 8260B 8/31/11 1:45 MGB PlH0661 1,2,3-Trichlorobenzene BRL ug/L 80 8.0 40 8260B 8/31/11 1:45 MGB PIH0661 1,2,3-Trichloropropane BRL ug/L 40 3.2 40 8260B 8/31/11 1:45 MGB PIH0661 1,2,4-Trichlorobenzene BRL ug/L 40 4.1 40 8260B 8/31/11 1:45 MGB PlH0661 1,2,4-Trimethylbenzene BRL ug/L 20 1.9 40 8260B 8/31/11 1:45 MGB PlH0661 1,2-Dibromo-3-chloropropane BRL ug/L 80 24 40 8260B 8/31/11 1:45 MGB PlH0661 1,2-Dibromoethane BRL ug/L 20 5.5 40 8260B 8/31/11 1:45 MGB PlH0661 1,2-Dichlorobenzene BRL ug/L 20 3.1 40 8260B 8/31/11 1:45 MGB PlH0661 1,2-Dichloroethane BRL ug/L 20 5.6 40 8260B 8/31/11 1:45 MGB PlH0661 1,2-Dichloropropane BRL ug/L 20 5.1 40 8260B 8/31/11 1:45 MGB PlH0661 1,3,5-Trimethylbenzene BRL ug/L 20 2.3 40 8260B 8/31/11 1:45 MGB PlH0661 1,3-Dichlorobenzene BRL ug/L 20 3.0 40 8260B 8/31/11 1:45 MGB PlH0661 1,3-Dichloropropane BRL ug/L 20 4.4 40 8260B 8/31/11 1:45 MGB PlH0661 1,4-Dichlorobenzene BRL ug/L 20 2.7 40 8260B 8/31/11 1:45 MGB PlH0661 2,2-Dichloropropane BRL ug/L 80 4.6 40 8260B 8/31/11 1:45 MGB PlH0661 2-Chloroethyl Vinyl Ether BRL ug/L 80 9.0 40 8260B 8/31/11 1:45 MGB PlH0661 2-Chlorotoluene BRL ug/L 20 1.5 40 8260B 8/31/11 1:45 MGB PlH0661 4-Chlorotoluene BRL ug/L 20 2.1 40 8260B 8/31/11 1:45 MGB PlH0661 4-Isopropyltoluene BRL ug/L 20 2.6 40 8260B 8/31/11 1:45 MGB PlH0661 Acetone 2400 uglL 200 25 40 8260E 8/31/11 1:46 MGB PlH0661 Acrolein BRL ug/L 800 44 40 8260E 8/31/11 1:45 MGB PlHO661 Acrylonithle BRL ug/L 800 34 40 8260B 8/31/11 1:45 MGB PIH0661 Benzene 84 ug/L 20 2.9 40 8260B 8/31/11 1:45 MGB PlH0661 Bromobenzene BRL ug/L 20 2.6 40 8260B 8/31/11 1:45 MGB PlH0661 Bromochloromethane BRL ug/L 20 5.0 40 8260B 8/31/11 1:45 MGB PlHO661 Bromodichloromethane BRL ug/L 20 2.5 40 8260B 8/31/11 1:45 MGB PlH0661 Bromoform BRL ug/L 40 11 40 8260B 8/31/11 1:45 MGB PlH0661 Bromomethane BRL ug/L 40 19 40 8260B 8/31/11 1:45 MGB PlH0661 Carbon disulfide BRL ug/L 200 55 40 8260B 8/31/11 1:45 MGB PlH0661 Carbon Tetrachloride BRL ug/L 20 4.7 40 8260B 8/31/11 1:45 MGB PlHO661 Chlorobenzene 240 ug/L 20 2.6 40 8260B 8131/11 1:46 MGB PIH0661 Chloroethane BRL ug/L 20 5.1 40 8260B 8/31/11 145 MGB PlH0661 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 18 of 52 /PRISM ( Full -Service Analytical & Laboratory Report Environmental Solutions 09/07/2011 iweonnrow¢s — Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1080715-04 1410 Commwealth Drive Prism Work Order: 1080715 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 08/26/11 11:45 Time Submitted: 08/26/11 14:25 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Chloroform BRL ug/L 20 3.5 40 8260B 8/31/11 1:45 MGB PlH0661 Chloromethane BRL ug/L 20 4.4 40 8260B 8/31/11 1:45 MGB PlH0661 cis-1,2-Dichloroethylene 140 ug/L 20 3.0 40 8260B 8131/11 1:46 MGB PlH0661 cis- 1,3-Dichloropropylene BRL ug/L 20 4.2 40 8260B 8/31/11 1:45 MGB PlH0661 Dibromochloromethane BRL ug/L 20 12 40 8260B 8/31/11 1:45 MGB PlH0661 Dibromomethane BRL ug/L 20 5.2 40 8260B 8/31/11 1:45 MGB PlH0661 Dichlorodifluoromethane BRL ug/L 40 4.3 40 8260B 8/31/11 1:45 MGB P1H0661 Ethylbenzene 24 ug/L 20 2.7 40 8260E 8/31/11 1:45 MGB PlH0661 Hexachlorobutadiene BRL ug/L 80 15 40 8260B 8/31/11 1:45 MGB PIH0661 Isopropyl Ether BRL ug/L 20 1.7 40 8260B 8/31/11 1:45 MGB PlH0661 Isopropylbenzene(Cumene) BRL ug/L 20 2.9 40 8260B 8/31/11 1:45 MGB PlH0661 m,p-Xylenes 49 ug/L 40 3.2 40 8260E 8/31111 1:45 MGB PIH0661 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 200 7.6 40 8260E 8/31/11 1:45 MGB PlH0661 Methyl Ethyl Ketone (2-Butanone) 17000 ug/L 2000 360 400 8260E 8131/11 10:48 MGB PlH0661 Methyl Isobutyl Ketone 1200 ug/L 200 5.0 40 8260B 8/31/11 1:45 MGB PIH0661 Methylene Chloride BRL ug/L 40 18 40 8260B 8/31/11 1:45 MGB PlH0661 Methyl-tert-Butyl Ether BRL ug/L 20 2.8 40 8260B 8/31/11 1:45 MGB PlH0661 Naphthalene BRL ug/L 40 3.9 40 8260B 8/31/11 1:45 MGB PlH0661 n-Butylbenzene BRL ug/L 40 4.5 40 8260B 8/31/11 1:45 MGB PlH0661 n-Propylbenzene BRL ug/L 20 2.4 40 8260B 8/31/11 1:45 MGB P1H0661 o-Xylene BRL ug/L 20 1.8 40 82606 8/31/11 1:45 MGB PIH0661 sec-Butylbenzene BRL ug/L 20 3.5 40 8260B 8/31/11 1:45 MGB PlH0661 Styrene BRL ug/L 20 1.9 40 8260B 8/31/11 1:45 MGB PlH0661 tert-Butylbenzene BRL ug/L 20 3.2 40 8260B 8/31/11 1:45 MGB PlH0661 Tetrachloroethylene BRL ug/L 20 2.8 40 8260B 8/31/11 1:45 MGB PlH0661 Toluene 15000 ug/L 200 17 400 8260E 8/31/11 10:48 MGB PlH0661 trans-1,2-Dichloroethylene BRL ug/L 20 4.6 40 8260B 8/31/11 1:45 MGB PlHO661 trans- 1,3-Dichloropropylene BRL ug/L 20 1.7 40 8260B 8/31/11 1:45 MGB PlHO661 Trichloroethylene BRL ug/L 20 2.2 40 8260B 8/31/11 1:45 MGB PlH0661 Trichlorofluoromethane BRL ug/L 20 3.5 40 8260B 8/31/11 1:45 MGB PlH0661 Vinyl acetate BRL ug/L 80 4.0 40 82608 8/31/11 1:45 MGB PIH0661 Vinyl chloride BRL ug/L 20 6.2 40 8260B 8/31/11 1:45 MGB PlH0661 Surrogate Recovery Control Limits 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 19 of 52 .ARR I S M I Fun -Service Analytical 8 ^"' Environmental Solutions g �q ue«+nrow�es wc Level II QC Report 9/7/11 Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:00PM 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1H0661 - 5030B Blank (PI H0661-BLK1) Prepared & Analyzed: 08/30/11 1, 1, 1,2-Tetrachloroethane BRL 0.50 ug/L 1, 1, 1 -Trichloroethane BRL 0.50 ug/L 1, 1, 2,2-Tetrachloroethane BRL 0.50 ug/L 1, 1, 2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1, 1 -Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Tichooropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethylbenzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethylbenzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 2.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone 1.20 5.0 ug/L J Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis- 1,2-Dichloroethylene BRL 0.50 ug/L cis- 1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 20 of 52 /'P.R I S M I FWI-Service Analytical Environmantelol Solutions lABO(U1nME1 -N Withers & Raven el -Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0661 - 5030B Blank (PI H0661-BLK1) Prepared & Analyzed: 08/30/11 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 26.8 ug/L 25.00 107 80-124 Surrogate: Dibromofluoromethane 25.7 ug/L 25.00 103 75-129 Surrogate: Toluene-d8 25.4 ug/L 25.00 102 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041525-0409 Page 21 of 52 qService Analytical /P R I SM I Environmental Solutions SIR' ueonwro iEs n�c Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0661 - 5030B LCS (P1H0661-BS1) Prepared & Analyzed: 08/30/11 1,1-Dichloroethylene 22.8 0.50 ug/L 20.00 114 70-154 Benzene 21.4 0.50 ug/L 20.00 107 77-128 Chlorobenzene 21.0 0.50 ug/L 20.00 105 78-119 Toluene 21.2 0.50 ug/L 20.00 106 76-131 Trichloroethylene 21.7 0.50 ug/L 20.00 109 77-133 Surrogate:4-Bromofluorobenzene 24.8 ug/L 25.00 99 80-124 Surrogate: Dibromofluoromethane 25.0 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 24.8 ug/L 25.00 99 77-123 LCS Dup (P1 H0661 -BSD1) Prepared & Analyzed: 08/30/11 1,1-Dichloroethylene 22.1 0.50 ug/L 20.00 ill 70-154 3 Benzene 20.9 0.50 ug/L 20.00 104 77-128 2 Chlorobenzene 20.9 0.50 ug/L 20.00 104 78-119 0.9 Toluene 20.7 0.50 ug/L 20.00 103 76-131 3 Trichloroethylene 21.5 0.50 ug/L 20.00 108 77-133 0.8 Surrogate:4-Bromofluorobenzene 25.0 ug/L 25.00 100 80-124 Surrogate: Dibromofluoromethane 24.6 ug/L 25.00 98 75-129 Surrogate. Toluene-d8 25.1 ug/L 25.00 101 77-123 200 200 200 200 200 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/526-0409 Page 22 of 52 7,2 R I S M I Full -Service Analytical & � Environmental Solutions .� LABORATOfl1ES INC Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Analyte Result Limit Units Level II QC Report 9/7/1 1 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351OC MS Blank (P1 H0677-BLK1) Prepared:08/30/11 Analyzed:09/06/11 1,2,4-Trichlorobenzene BRL 10 ug/L 1,2-Dichlorobenzene BRL 10 ug/L 1,3-Dichlorobenzene BRL 10 ug/L 1,4-Dichlorobenzene BRL 10 ug/L 2,4,5-Trichlorophenol BRL 10 ug/L 2,4,6-Trichlorophenol BRL 10 ug/L 2,4-Dichlorophenol BRL 10 ug/L 2,4-Dimethylphenol BRL 10 ug/L 2,4-Dinitrophenol BRL 10 ug/L 2.4-Dinitrotoluene BRL 10 ug/L 2,6-Dinitrotoluene BRL 10 ug/L 2-Chloronaphthalene BRL 10 ug/L 2-Chlorophenol BRL 10 ug/L 2-Methylnaphthalene BRL 10 ug/L 2-Methylphenol BRL 10 ug/L 2-Nitroaniline BRL 10 ug/L 2-Nitrophenol BRL 10 ug/L 3,3'-Dichlorobenzidine BRL 10 ug/L 3/4-Methylphenol BRL 10 ug/L 3-Nitroaniline BRL 10 ug/L 4,6-Dinitro-2-methylphenol BRL 10 ug/L 4-Bromophenyl phenyl ether BRL 10 ug/L 4-Chloro-3-methylphenol BRL 10 ug/L 4-Chloroaniline BRL 10 ug/L 4-Chlorophenyl phenyl ether BRL 10 ug/L 4-Nitroaniline BRL 10 ug/L 4-Nitrophenol BRL 10 ug/L Acenaphthene BRL 10 ug/L Acenaphthylene BRL 10 ug/L Aniline BRL 10 ug/L Anthracene BRL 10 ug/L Azobenzene BRL 10 ug/L Benzo(a)anthracene BRL 10 ug/L Benzo(a)pyrene BRL 10 ug/L Benzo(b)fluoranthene BRL 10 ug/L Benzo(g,h,i)perylene BRL 10 ug/L Benzo(k)fluoranthene BRL 10 ug/L Benzoic Acid BRL 100 ug/L Benzyl alcohol BRL 10 ug/L bis(2-Chloroethoxy)methane BRL 10 ug/L Bis(2-Chloroethyl)ether BRL 10 ug/L Bis(2-chloroisopropyl)ether BRL 10 ug/L Bis(2-Ethylhexyl)phthalate BRL 10 ug/L Butyl benzyl phthalate BRL 10 ug/L Chrysene BRL 10 ug/L Dibenzo(a,h)anthracene BRL 10 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 52 P R I S M Full -Service Analytical & Environmental Solutions Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351OC MS Blank (P1H0677-BLK7) Prepared: 08/30/11 Analyzed: 09/06/11 Dibenzofuran BRL 10 ug/L Diethyl phthalate BRL 10 ug/L Dimethyl phthalate BRL 10 ug/L Di-n-butyl phthalate BRL 10 ug/L Di-n-octyl phthalate BRL 10 ug/L Fluoranthene BRL 10 ug/L Fluorene BRL 10 ug/L Hexachlorobenzene BRL 10 ug/L Hexachlorobutadiene BRL 10 ug/L Hexachlorocyclopentadiene BRL 10 ug/L Hexachloroethane BRL 10 ug/L Indeno(1,2,3-cd)pyrene BRL 10 ug/L Isophorone BRL 10 ug/L Naphthalene BRL 10 ug/L Nitrobenzene BRL 10 ug/L N-Nitroso-di-n-propylamine BRL 10 ug/L N-Nitrosodiphenylamine BRL 10 ug/L Pentachlorophenol BRL 10 ug/L Phenanthrene BRL 10 ug/L Phenol BRL 10 ug/L Pyrene BRL 10 ug/L Surrogate: 2,4,6-Tribromophenol 115 ug/L 100.0 115 26-139 Surrogate:2-Fluorobiphenyl 42.2 ug/L 50.00 84 41-112 Surrogate:2-Fluorophenol 57.5 ug/L 100.0 58 10-48 SR Surrogate: Nitrobenzene-d5 44.2 ug/L 50.00 88 34-102 Surrogate: Phenol-d5 37.6 ug/L 100.0 38 10-34 SR Surrogate: Terphenyl-d14 64.2 ug/L 50.00 128 31-165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 24 of 52 %PAR ISM I Full -Service Mau Environmental Solutions ueonn-m - Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GCIMS - Quality Control Reporting Analyte Result Limit Units Batch P1 H0677 - 3510C MS Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25MPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (PlH0677-BS1) Prepared: 08/30/11 Analyzed: 09/06/11 1,2A-Trich ]arobenzene 31.5 10 ug/L 50.00 63 45-103 1,2-Dichlorobenzene 31.3 10 ug/L 50.00 63 43-100 1,3-Dichlorobenzene 28.9 10 ug/L 50.00 58 42-98 1,4-Dichlorobenzene 29.9 10 ug/L 50.00 60 42-100 2,4,5-Trichlorophenol 51.0 10 ug/L 50.00 102 66-120 2,4,6-Trichlorophenol 46.5 10 ug/L 50.00 93 62-121 2,4-Dichlorophenol 44.4 10 ug/L 50.00 89 58-113 2,4-Dimethylphenol 41.4 10 ug/L 50.00 83 42-120 2,4-Dinitrophenol 57.8 10 ug/L 50.00 116 27-129 2,4-Dinitrotoluene 60.8 10 ug/L 50.00 122 62-136 2,6-Dinitrotoluene 51.3 10 ug/L 50.00 103 64-129 2-Chloronaphthalene 49.0 10 ug/L 50.00 98 38-141 2-Chlorophenol 40.4 10 ug/L 50.00 81 49-107 2-Methylnaphthalene 40.4 10 ug/L 50.00 81 55-112 2-Methylphenol 41.2 10 ug/L 50.00 82 40-106 2-Nitroaniline 56.1 10 ug/L 50.00 112 65-122 2-Nitrophenol 44.1 10 ug/L 50.00 88 57-115 3,3'-Dichlorobenzidine 67.3 10 ug/L 50.00 135 58-139 3/4-M ethyl phenol 38.2 10 ug/L 50.00 76 34-101 3-Nitroaniline 64.0 10 ug/L 50.00 128 52-155 4,6-Dinitro-2-methylphenol 59.4 10 ug/L 50.00 119 49-138 4-Bromophenyl phenyl ether 49.3 10 ug/L 50.00 99 63-135 4-Chloro-3-methylphenol 45.8 10 ug/L 50.00 92 33-149 4-Chloroaniline 55.0 10 ug/L 50.00 110 44-163 4-Chlorophenyl phenyl ether 49.9 10 ug/L 50.00 100 63-129 4-Nitroaniline 72.8 10 ug/L 50.00 146 63-147 4-Nitrophenol 28.6 10 ug/L 50.00 57 10-77 Acenaphthene 44.5 10 ug/L 50.00 89 64-118 Acenaphthylene 43.9 10 ug/L 50.00 88 65-119 Aniline 56.7 10 ug/L 50.00 113 12-197 Anthracene 50.9 10 ug/L 50.00 102 69-134 Azobenzene 50.6 10 ug/L 50.00 101 56-129 Benzo(a)anthracene 51.5 10 ug/L 50.00 103 71-125 Benzo(a)pyrene 54.4 10 ug/L 50.00 109 67-135 Benzo(b)fluoranthene 49.2 10 ug/L 50.00 98 56-145 Benzo(g,h,i)perylene 54.6 10 ug/L 50.00 109 44-149 Benzo(k)fluoranthene 51.0 10 ug/L 50.00 102 65-138 Benzoic Acid BRL 100 ug/L 50.00 10-125 Benzyl alcohol 39.2 10 ug/L 50.00 78 35-111 bis(2-Chloroethoxy)methane 45.8 10 ug/L 50.00 92 49-126 Bis(2-Chloroethyl)ether 40.5 10 ug/L 50.00 81 47-124 Bis(2-chloroisopropyl)ether 41.2 10 ug/L 50.00 82 42-126 Bis(2-Ethylhexyl)phthalate 67.3 10 ug/L 50.00 135 59-139 Butyl benzyl phthalate 68.2 10 ug/L 50.00 136 67-133 Chrysene 49.1 10 ug/L 50.00 98 64-124 Dibenzo(a,h)anthracene 48.2 10 ug/L 50.00 96 49-144 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.8001529-6364 - Fax: 7041525-0409 P L1 Page 25 of 52 P R I S M FullServiceAnalytical 8 Environmental Solutions u.9onAtoNiEA �� Level II QC Report 9/7/11 Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351 OC MS LCS (P1H0677-BSI) Prepared: 08/30/11 Analyzed: 09/06/11 Dibenzofuran 46.0 10 ug/L 50.00 92 68-113 Diethyl phthalate 53.0 10 ug/L 50.00 106 70-124 Dimethyl phthalate 49.2 10 ug/L 50.00 98 71-117 Di-n-butyl phthalate 55.4 10 ug/L 50.00 ill 69-128 Di-n-octyl phthalate 64.2 10 ug/L 50.00 128 52-150 Fluoranthene 54.1 10 ug/L 50.00 108 66-135 Fluorene 50.5 10 ug/L 50.00 101 67-124 Hexachlorobenzene 51.0 10 ug/L 50.00 102 62-124 Hexachlorobutadiene 29.7 10 ug/L 50.00 59 42-105 Hexachlorocyclopentadiene 34.7 10 ug/L 50.00 69 32-117 Hexachloroethane 29.5 10 ug/L 50.00 59 40-99 Indeno(1,2,3-cd)pyrene 51.8 10 ug/L 50.00 104 40-150 Isophorone 41.7 10 ug/L 50.00 83 54-125 Naphthalene 38.4 10 ug/L 50.00 77 54-111 Nitrobenzene 33.4 10 ug/L 50.00 67 51-117 N-Nitroso-di-n-propylamine 52.0 10 ug/L 50.00 104 55-115 N-Nitrosodiphenylamine 50.4 10 ug/L 50.00 101 70-152 Pentachlorophenol 60.4 10 ug/L 50.00 121 23-139 Phenanthrene 49.9 10 ug/L 50.00 100 68-128 Phenol 18.4 10 ug/L 50.00 37 12-58 Pyrene 62.4 10 ug/L 50.00 125 62-139 Surrogate: 2,4,6-Tribromophenol 113 ug/L 100.0 113 26-139 Surrogate:2-Fluorobiphenyl 41.9 ug/L 50.00 84 41-112 Surrogate:2-Fluorophenol 57.5 ug/L 100.0 58 10-48 SR Surrogate: Nitrobenzene-d5 45.7 ug/L 50.00 91 34-102 Surrogate: Phenol-d5 39.2 ug/L 100.0 39 10-34 SR Surrogate: Terphenyl-dM 63.3 ug/L 50.00 127 31-165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 26 of 52 �P R ISM I Fullironmca Analytical s q �*^�, ',gyp Enviro�mentel Solutions � ueon�Towics �Nc Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Semivolatile Organic Compounds by GC/MS - Quality Control Analyte Batch P1 H0677 - 351 OC MS Reporting Result Limit Units Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS Dup (PlH0677-BSD1) Prepared: 08/30/11 Analyzed: 09/06/11 1,2,4-Trichlorobenzene 37.8 10 ug/L 50.00 76 45-103 18 200 1,2-Dichlorobenzene 37.6 10 ug/L 50.00 75 43-100 18 200 1,3-Dichlorobenzene 35.9 10 ug/L 50.00 72 42-98 22 200 1,4-Dichlorobenzene 36.4 10 ug/L 50.00 73 42-100 20 200 2,4,5-Trichlorophenol 50.9 10 ug/L 50.00 102 66-120 0.3 200 2,4,6-Trichlorophenol 46.9 10 ug/L 50.00 94 62-121 0.9 200 2,4-Dichlorophenol 45.1 10 ug/L 50.00 90 58-113 1 200 2,4-Dimethylphenol 43.3 10 ug/L 50.00 87 42-120 4 200 2,4-Dinitrophenol 61.9 10 ug/L 50.00 124 27-129 7 200 2,4-Dinitrotoluene 61.0 10 ug/L 50.00 122 62-136 0.4 200 2,6-Dinitrotoluene 52.5 10 ug/L 50.00 105 64-129 2 200 2-Chloronaphthalene 57.0 10 ug/L 50.00 114 38-141 15 200 2-Chlorophenol 41.6 10 ug/L 50.00 83 49-107 3 200 2-Methylnaphthalene 44.2 10 ug/L 50.00 88 55-112 9 200 2-Methylphenol 42.8 10 ug/L 50.00 86 40-106 4 200 2-Nitroaniline 54.8 10 ug/L 50.00 110 65-122 2 200 2-Nitrophenol 45.6 10 ug/L 50.00 91 57-115 3 200 3,3'-Dichlorobenzidine 70.0 10 ug/L 50.00 140 58-139 4 200 L2 3/4-Methyl phenol 39.9 10 ug/L 50.00 80 34-101 4 200 3-Nitroaniline 63.9 10 ug/L 50.00 128 52-155 0.05 200 4,6-Dinitro-2-methylphenol 59.0 10 ug/L 50.00 118 49-138 0.7 200 4-Bromophenyl phenyl ether 48.2 10 ug/L 50.00 96 63-135 2 200 4-Chloro-3-methylphenol 46.8 10 ug/L 50.00 94 33-149 2 200 4-Chloroaniline 56.7 10 ug/L 50.00 113 44-163 3 200 4-Chlorophenyl phenyl ether 52.2 10 ug/L 50.00 104 63-129 5 200 4-Nitroaniline 73.6 10 ug/L 50.00 147 63-147 1 200 L2 4-Nitrophenol 30.1 10 ug/L 50.00 60 10-77 5 200 Acenaphthene 45.6 10 ug/L 50.00 91 64-118 2 200 Acenaphthylene 46.5 10 ug/L 50,00 93 65-119 6 200 Aniline 57.8 10 ug/L 50.00 116 12-197 2 200 Anthracene 52.6 10 ug/L 50.00 105 69-134 3 200 Azobenzene 48.2 10 ug/L 50.00 96 56-129 5 200 Benzo(a)anthracene 50.9 10 ug/L 50.00 102 71-125 1 200 Benzo(a)pyrene 53.9 10 ug/L 50.00 108 67-135 0.8 200 Benzo(b)fluoranthene 52.9 10 ug/L 50.00 106 56-145 7 200 Benzo(g,h,i)perylene 55.0 10 ug/L 50.00 110 44-149 0.7 200 Benzo(k)fluoranthene 47.8 10 ug/L 50.00 96 65-138 7 200 Benzoic Acid BRL 100 ug/L 50.00 10-125 200 P Benzyl alcohol 41.2 10 ug/L 50.00 82 35-111 5 200 bis(2-Chloroethoxy)methane 47.0 10 ug/L 50.00 94 49-126 3 200 Bis(2-Chloroethyl)ether 41.6 10 ug/L 50.00 83 47-124 3 200 Bis(2-chloroisopropyl)ether 42.6 10 ug/L 50.00 85 42-126 3 200 Bis(2-Ethylhexyl)phthalate 66.7 10 ug/L 50.00 133 59-139 0.9 200 Butyl benzyl phthalate 64.4 10 ug/L 50.00 129 67-133 6 200 Chrysene 49.3 10 ug/L 50.00 99 64-124 0.4 200 Dibenzo(a,h)anthracene 48.0 10 ug/L 50.00 96 49-144 0.5 200 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 27 of 52 P R I S M Environmental Service Analytical 8 ': Environmental Solutions � uecwn*owics Inc Level II QC Report 9/7/11 Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GCIMS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351 OC MS LCS Dup (P1H0677-BSD1) Prepared: 08/30/11 Analyzed: 09/06/11 Dibenzofuran 48.8 10 ug/L 50.00 98 68-113 6 200 Diethyl phthalate 53.5 10 ug/L 50.00 107 70-124 1 200 Dimethyl phthalate 50.1 10 ug/L 50.00 100 71-117 2 200 Di-n-butyl phthalate 53.8 10 ug/L 50.00 108 69-128 3 200 Di-n-octyl phthalate 65.0 10 ug/L 50.00 130 52-150 1 200 Fluoranthene 52.9 10 ug/L 50.00 106 66-135 2 200 Fluorene 50.9 10 ug/L 50.00 102 67-124 0.8 200 Hexachlorobenzene 49.7 10 ug/L 50.00 99 62-124 3 200 Hexachlorobutadiene 36.8 10 ug/L 50.00 74 42-105 21 200 Hexachlorocyclopentadiene 40.2 10 ug/L 50.00 80 32-117 15 200 Hexachloroethane 36.3 10 ug/L 50.00 73 40-99 21 200 Indeno(1,2,3-cd)pyrene 51.9 10 ug/L 50.00 104 40-150 0.2 200 Isophorone 43.5 10 ug/L 50.00 87 54-125 4 200 Naphthalene 42.1 10 ug/L 50.00 84 54-111 9 200 Nitrobenzene 34.5 10 ug/L 50.00 69 51-117 3 200 N-Nitroso-di-n-propylamine 53.5 10 ug/L 50.00 107 55-115 3 200 N-Nitrosodiphenylamine 48.5 10 ug/L 50.00 97 70-152 4 200 Pentachlorophenol 57.2 10 ug/L 50.00 114 23-139 5 200 Phenanthrene 49.1 10 ug/L 50.00 98 68-128 2 200 Phenol 20.0 10 ug/L 50.00 40 12-58 8 200 Pyrene 58.9 10 ug/L 50.00 118 62-139 6 200 Surrogate: 2,4,6-Tribromophenol 119 ug/L 100.0 119 26-139 Surrogate:2-Fluorobiphenyl 45.2 ug/L 50.00 90 41-112 Surrogate:2-Fluorophenol 60.8 ug/L 100.0 61 10-48 SR Surrogate: Nitrobenzene-d5 46.0 ug/L 50.00 92 34-102 Surrogate: Phenol-d5 41.1 ug/L 100.0 41 10-34 SR Surrogate: Terphenyl-d14 59.3 ug/L 50.00 119 31-165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 28 of 52 zp�,RISM I Full -Service al Solutions 8 Environmental Solutions .�F�'., ineownrowies, n�c. Withers & Raven el-Wilm i ngton Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Semivolatile Organic Compounds by GUMS - Quality Control Analyte Batch P1 H0677 - 3510C MS Reporting Result Limit Units Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Matrix Spike (P1H0677-MS1) Source: 1080715-01 Prepared: 08/30/11 Analyzed: 09/06/11 1,2,4-Trichlorobenzene 69.7 20 ug/L 100.0 BRL 70 44-100 1,2-Dichlorobenzene 68.7 20 ug/L 100.0 BRL 69 42-99 1,3-Dichlorobenzene 66.1 20 ug/L 100.0 BRL 66 35-101 1,4-Dichlorobenzene 66.8 20 ug/L 100.0 BRL 67 43-97 2,4,5-Trichlorophenol 94.7 20 ug/L 100.0 BRL 95 51-122 2,4,6-Trichlorophenol 84.7 20 ug/L 100.0 BRL 85 46-117 2,4-Dichlorophenol 79.5 20 ug/L 100.0 BRL 80 42-108 2,4-Dimethylphenol 75.3 20 ug/L 100.0 BRL 75 13-122 2,4-Dinitrophenol 133 20 ug/L 100.0 BRL 133 10-166 2,4-Dinitrotoluene 130 20 ug/L 100.0 BRL 130 64-135 2,6-Dinitrotoluene 109 20 ug/L 100.0 BRL 109 50-146 2-Chloronaphthalene 92.5 20 ug/L 100.0 BRL 92 46-114 2-Chlorophenol 72.0 20 ug/L 100.0 BRL 72 36-94 2-Methylnaphthalene 81.2 20 ug/L 100.0 BRL 81 36-115 2-Methylphenol 77.9 20 ug/L 100.0 BRL 78 27-92 2-Nitroaniline 112 20 ug/L 100.0 BRL 112 51-139 2-Nitrophenol 79.4 20 ug/L 100.0 BRL 79 43-108 3,3'-Dichlorobenzidine 123 20 ug/L 100.0 BRL 123 10-214 3/4-Methylphenol 75.6 20 ug/L 100.0 BRL 76 22-84 3-Nitroaniline 130 20 ug/L 100.0 BRL 130 50-145 4,6-Dinitro-2-methylphenol 125 20 ug/L 100.0 BRL 125 25-152 4-Bromophenyl phenyl ether 99.9 20 ug/L 100.0 BRL 100 52-128 4-Chloro-3-methyl phenol 91.6 20 ug/L 100.0 BRL 92 44-110 4-Chloroaniline 99.0 20 ug/L 100.0 BRL 99 10-156 4-Chlorophenyl phenyl ether 101 20 ug/L 100.0 BRL 101 55-125 4-Nitroaniline 154 20 ug/L 100.0 BRL 154 39-159 4-Nitrophenol 99.4 20 ug/L 100.0 BRL 99 10-105 Acenaphthene 88.6 20 ug/L 100.0 BRL 89 55-117 Acenaphthylene 88.5 20 ug/L 100.0 BRL 89 52-121 Aniline 96.7 20 ug/L 100.0 BRL 97 11-124 Anthracene 110 20 ug/L 100.0 BRL 110 60-136 Azobenzene 99.3 20 ug/L 100.0 BRL 99 50-135 Benzo(a)anthracene 105 20 ug/L 100.0 BRL 105 64-135 Benzo(a)pyrene 112 20 ug/L 100.0 BRL 112 68-136 Benzo(b)fluoranthene 108 20 ug/L 100.0 BRL 108 61-149 Benzo(g,h,i)perylene 97.7 20 ug/L 100.0 BRL 98 47-151 Benzo(k)fluoranthene 112 20 ug/L 100.0 BRL 112 45-148 Benzoic Acid BRL 200 ug/L 100.0 BRL 10-125 Benzyl alcohol 74.5 20 ug/L 100.0 BRL 75 30-97 bis(2-C hloroethoxy) methane 81.1 20 ug/L 100.0 BRL 81 43-119 Bis(2-Chloroethyl)ether 73.7 20 ug/L 100.0 BRL 74 36-115 Bis(2-chloroisopropyl)ether 73.5 20 ug/L 100.0 BRL 74 36-113 Bis(2-Ethylhexyl)phthalate 140 20 ug/L 100.0 BRL 140 50-168 Butyl benzyl phthalate 144 20 ug/L 100.0 BRL 144 52-166 Chrysene 100 20 ug/L 100.0 BRL 100 62-135 Dibenzo(a,h)anthracene 88.5 20 ug/L 100.0 BRL 88 45-155 P This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 29 of 52 /�'..P:R ISM I Full -Service Analytical 8 Environmental Solutions LAepU,TO %- Level II QC Report 9/7111 Withers & Raven el -Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351OC MS Matrix Spike (P1H0677-MS1) Source: 1080715-01 Prepared: 08/30/11 Analyzed: 09/06/11 Dibenzofuran 96.0 20 ug/L 100.0 BRL 96 58-119 Diethyl phthalate 112 20 ug/L 100.0 BRL 112 55-137 Dimethyl phthalate 102 20 ug/L 100.0 BRL 102 46-135 Di-n-butyl phthalate 114 20 ug/L 100.0 BRL 114 53-141 Di-n-octyl phthalate 157 20 ug/L 100.0 BRL 157 48-166 Fluoranthene 115 20 ug/L 100.0 BRL 115 51-136 Fluorene 100 20 ug/L 100.0 BRL 100 57-121 Hexachlorobenzene 106 20 ug/L 100.0 BRL 106 55-131 Hexachlorobutadiene 68.2 20 ug/L 100.0 BRL 68 39-110 Hexachlorocyclopentadiene 73.3 20 ug/L 100.0 BRL 73 26-122 Hexachloroethane 68.4 20 ug/L 100.0 BRL 68 37-98 Indeno(1,2,3-cd)pyrene 95.2 20 ug/L 100.0 BRL 95 14-177 Isophorone 73.9 20 ug/L 100.0 BRL 74 49-113 Naphthalene 74.5 20 ug/L 100.0 BRL 75 38-109 Nitrobenzene 60.5 20 ug/L 100.0 BRL 60 34-117 N-Nitroso-di-n-propylamine 92.0 20 ug/L 100.0 BRL 92 44-115 N-Nitrosodiphenylamine 100 20 ug/L 100.0 BRL 100 57-156 Pentachlorophenol 124 20 ug/L 100.0 BRL 124 17-167 Phenanthrene 100 20 ug/L 100.0 BRL 100 62-131 Phenol 49.3 20 ug/L 100.0 BRL 49 10-68 Pyrene 130 20 ug/L 100.0 BRL 130 46-156 Surrogate:2,4,6-Tribromophenol 250 ug/L 200.0 125 26-139 Surrogate:2-Fluorobiphenyl 79.7 ug/L 100.0 80 41-112 Surrogate:2-Fluorophenol 127 ug/L 200.0 64 10-48 SR Surrogate: Nitrobenzene-d5 79.4 ug/L 100.0 79 34-102 Surrogate: Phenol-d5 105 ug/L 200.0 52 10-34 SR Surrogate. Terphenyl-d14 130 ug/L 100.0 130 31-165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 30 of 52 P R ISM I Fua-Service Analytical s � Environmental Solutions .. LAB0�IATORIES iNG Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Semivolatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351OC MS Matrix Spike Dup (P1H0677-MSD1) Source: 1080715-01 Prepared: 08/30/11 Analyzed: 09/06/11 1,2.4-Trichlorobenzene 79.6 20 ug/L 100.0 BRL 80 44-100 13 30 1,2-Dichlarobenzene 78.8 20 ug/L 100.0 BRL 79 42-99 14 34 1,3-Dichlarobenzene 74.7 20 ug/L 100.0 BRL 75 35-101 12 36 1,4-Dichlarobenzene 76.4 20 ug/L 100.0 BRL 76 43-97 13 35 2,4,5-Trichlorophenol 105 20 ug/L 100.0 BRL 105 51-122 10 22 2,4,6-Trichlorophenol 92.4 20 ug/L 100.0 BRL 92 46-117 9 30 2,4-Dichlorophenol 89.3 20 ug/L 100.0 BRL 89 42-108 12 33 2,4-Dimethylphenol 85.0 20 ug/L 100.0 BRL 85 13-122 12 36 2,4-Dinitrophenol 134 20 ug/L 100.0 BRL 134 10-166 0.5 41 2,4-Dinitrotoluene 131 20 ug/L 100.0 BRL 131 64-135 1 24 2,6-Dinitrotoluene 109 20 ug/L 100.0 BRL 109 50-146 0.2 28 2-Chloronaphthalene 106 20 ug/L 100.0 BRL 106 46-114 14 30 2-Chlorophenol 81.6 20 ug/L 100.0 BRL 82 36-94 13 37 2-Methyl naphthalene 90.1 20 ug/L 100.0 BRL 90 36-115 10 33 2-Methylphenol 87.9 20 ug/L 100.0 BRL 88 27-92 12 36 2-Nitroaniline 112 20 ug/L 100.0 BRL 112 51-139 0.4 24 2-Nitrophenol 93.0 20 ug/L 100.0 BRL 93 43-108 16 33 3.3'-Dichlorobenzidine 132 20 ug/L 100.0 BRL 132 10-214 7 34 3/4-Methyl phenol 84.9 20 ug/L 100.0 BRL 85 22-84 12 30 M 3-Nitroaniline 131 20 ug/L 100.0 BRL 131 50-145 1 24 4,6-Dinitro-2-methylphenol 128 20 ug/L 100.0 BRL 128 25-152 2 35 4-Bromophenyl phenyl ether 104 20 ug/L 100.0 BRL 104 52-128 4 21 4-Chloro-3-methyl phenol 93.3 20 ug/L 100.0 BRL 93 44-110 2 25 4-Chloroaniline 109 20 ug/L 100.0 BRL 109 10-156 10 38 4-Chlorophenyl phenyl ether 107 20 ug/L 100.0 BRL 107 55-125 6 29 4-Nitroaniline 149 20 ug/L 100.0 BRL 149 39-159 3 29 4-Nitrophenol 90.8 20 ug/L 100.0 BRL 91 10-105 9 40 Acenaphthene 93.7 20 ug/L 100.0 BRL 94 55-117 6 33 Acenaphthylene 92.6 20 ug/L 100.0 BRL 93 52-121 4 30 Aniline 108 20 ug/L 100.0 BRL 108 11-124 11 35 Anthracene 105 20 ug/L 100.0 BRL 105 60-136 4 27 Azobenzene 99.6 20 ug/L 100.0 BRL 100 50-135 0.3 34 Benzo(a)anthracene 104 20 ug/L 100.0 BRL 104 64-135 0.9 18 Benzo(a)pyrene 107 20 ug/L 100.0 BRL 107 68-136 5 21 Benzo(b)fluoranthene 110 20 ug/L 100.0 BRL 110 61-149 2 34 Benzo(g,h,i)perylene 104 20 ug/L 100.0 BRL 104 47-151 7 27 Benzo(k)fluoranthene 99.0 20 ug/L 100.0 BRL 99 45-148 12 39 Benzoic Acid BRL 200 ug/L 100.0 BRL 10-125 51 P Benzyl alcohol 86.0 20 ug/L 100.0 BRL 86 30-97 14 37 bis(2-Chloroethoxy)methane 92.7 20 ug/L 100.0 BRL 93 43-119 13 30 Bis(2-Chloroethyl)ether 82.4 20 ug/L 100.0 BRL 82 36-115 11 33 Bis(2-chloroisopropyl)ether 82.3 20 ug/L 100.0 BRL 82 36-113 11 34 Bis(2-Ethylhexyl)phthalate 130 20 ug/L 100.0 BRL 130 50-168 7 21 Butyl benzyl phthalate 131 20 ug/L 100.0 BRL 131 52-166 9 23 Chrysene 97.7 20 ug/L 100.0 BRL 98 62-135 3 22 Dibenzo(a,h)anthracene 94.9 20 ug/L 100.0 BRL 95 45-155 7 28 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704I529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 31 of 52 R ISM I Full -Service Analytical s ,t ;� Environmental Solutions Level II QC Report 9/7/11 Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Semivolatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0677 - 351 OC MS Matrix Spike Dup (P1H0677-MSD1) Source: 1080715-01 Prepared: 08/30/11 Analyzed: 09/06/11 Dibenzofuran 100 20 ug/L 100.0 BRL 100 58-119 4 23 Diethyl phthalate 112 20 ug/L 100.0 BRL 112 55-137 0.6 22 Dimethyl phthalate 103 20 ug/L 100.0 BRL 103 46-135 1 25 Di-n-butyl phthalate 110 20 ug/L 100.0 BRL 110 53-141 3 24 Di-n-octyl phthalate 136 20 ug/L 100.0 BRL 136 48-166 15 21 Fluoranthene 112 20 ug/L 100.0 BRL 112 51-136 2 26 Fluorene 104 20 ug/L 100.0 BRL 104 57-121 4 30 Hexachlorobenzene 107 20 ug/L 100.0 BRL 107 55-131 1 29 Hexachlorobutadiene 81.2 20 ug/L 100.0 BRL 81 39-110 17 35 Hexachlorocyclopentadiene 88.5 20 ug/L 100.0 BRL 88 26-122 19 36 Hexachloroethane 77.5 20 ug/L 100.0 BRL 78 37-98 12 37 Indeno(1,2,3-cd)pyrene 104 20 ug/L 100.0 BRL 104 14-177 9 34 Isophorone 85.6 20 ug/L 100.0 BRL 86 49-113 15 27 Naphthalene 85.1 20 ug/L 100.0 BRL 85 38-109 13 35 Nitrobenzene 68.8 20 ug/L 100.0 BRL 69 34-117 13 34 N-Nitroso-di-n-propylamine 91.2 20 ug/L 100.0 BRL 91 44-115 0.9 33 N-Nitrosodiphenylamine 103 20 ug/L 100.0 BRL 103 57-156 3 26 Pentachlorophenol 123 20 ug/L 100.0 BRL 123 17-167 0.5 36 Phenanthrene 102 20 ug/L 100.0 BRL 102 62-131 2 23 Phenol 51.2 20 ug/L 100.0 BRL 51 10-68 4 43 Pyrene 123 20 ug/L 100.0 BRL 123 46-156 6 31 Surrogate: 2,4,6-Tribromophenol 249 ug/L 200.0 124 26-139 Surrogate. 2-Fluorobiphenyl 89.5 ug/L 100.0 90 41-112 Surrogate:2-Fluorophenol 135 ug/L 200.0 67 10-48 SR Surrogate: Nitrobenzene-d5 92.4 ug/L 100.0 92 34-102 Surrogate: Phenol-d5 109 ug/L 200.0 54 10-34 SR Surrogate: Terphenyl-d14 123 ug/L 100.0 123 31-165 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 32 of 52 /�P R I S M I FullironmService Analytical s y;;; �,� Environmental Solutions �.. L/tlO�ATpiIEA ANC: Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Total Metals - Quality Control Project: Henson Landfill Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 H0666 - 7470A Blank (P1H0666-BLK1) Prepared: 08/30/11 Analyzed: 08/31/11 Mercury BRL 0.20 ug/L LCS (P1H0666-BS1) Prepared: 08/30/11 Analyzed: 08/31/11 Mercury 8.80 0.20 ug/L 9.375 94 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041526-0409 Page 33 of 52 'j.1 �R I S M I Fun -Service Analytical s r Environmental Solutions �AEgNAT0RIES LNG Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 9/7/11 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110001 - SM3030 C Blank (P110001-BLK1) Prepared: 08/26/11 Analyzed: 08/31/11 Arsenic BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium 3.98 1.0 ug/L B Copper BRL 5.0 ug/L Lead 0.194 1.0 ug/L J Selenium 0.441 1.0 ug/L J Silver BRL 1.0 ug/L Zinc 1.42 10 ug/L J LCS (P110001-13SI) Prepared: 08/26/11 Analyzed: 08/31/11 Arsenic 272 1.0 ug/L 250.0 109 80-120 Cadmium 265 1.0 ug/L 250.0 106 80-120 Chromium 287 1.0 ug/L 250.0 115 80-120 B Copper 278 5.0 ug/L 250.0 111 80-120 Lead 257 1.0 ug/L 250.0 103 80-120 Selenium 280 1.0 ug/L 250.0 112 80-120 Silver 264 1.0 ug/L 250.0 106 80-120 Zinc 283 10 ug/L 250.0 113 80-120 Matrix Spike (P110001-MS1) Source: 1080715-04 Prepared: 08/26/11 Analyzed: 08/31/11 Arsenic 293 1.0 ug/L 250.0 72.7 88 75-125 Cadmium 234 1.0 ug/L 250.0 BRL 94 75-125 Chromium 241 1.0 ug/L 250.0 3.32 95 75-125 B Copper 232 5.0 ug/L 250.0 1.96 92 75-125 Lead 232 1.0 ug/L 250.0 0.845 92 75-125 Selenium 221 1.0 ug/L 250.0 2.47 88 75-125 Silver 227 1.0 ug/L 250.0 BRL 91 75-125 Zinc 231 10 ug/L 250.0 9.54 88 75-125 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/626-0409 Page 34 of 52 ZPFull-Service Analytical & xR I S M I Environmental Solutions �k uecwnrowcs we Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 9/7/1 1 Prism Work Order: 1080715 Time Submitted: 8/26/11 2:25:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110001 - SM3030 C Matrix Spike Dup (P110001-11VISD1) Source: 1080715-04 Prepared: 08/26/11 Analyzed: 08/31/11 Arsenic 296 1.0 ug/L 250.0 72.7 89 75-125 0.8 20 Cadmium 234 1.0 ug/L 250.0 BRL 94 75-125 0.1 20 Chromium 242 1.0 ug/L 250.0 3.32 96 75-125 0.6 20 B Copper 235 5.0 ug/L 250.0 1.96 93 75-125 1 20 Lead 230 1.0 ug/L 250.0 0.845 92 75-125 0.9 20 Selenium 224 1.0 ug/L 250.0 2.47 89 75-125 1 20 Silver 228 1.0 ug/L 250.0 BRL 91 75-125 0.1 20 Zinc 230 10 ug/L 250.0 9.54 88 75-125 0.4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041625-0409 Page 35 of 52 Level II QC Report P. R I S M I Fun -Service Analytical 9,7,11 Environmental Solutions � ueowntowEs iwc Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1080715 Attn: Brian Bellis Time Submitted: 8/26/11 2:25:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch PIH0642 - NO PREP Blank (P1H0642-BLK1) Prepared & Analyzed: 08/29/11 Chloride BRL 1000 ug/L Sulfate BRL 1000 ug/L LCS (PIH0642-BSI) Prepared & Analyzed: 08/29/11 Chloride 1980 1000 ug/L 2000 99 80-120 Sulfate 2050 1000 ug/L 2000 103 80-120 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final Date/Time 1080715-01 P110001 50 mL 50 mL 08/26/11 15:00 1080715-02 P110001 50 mL 50 mL 08/26/11 15:00 1080715-03 P110001 50 mL 50 mL 08/26/11 15:00 1080715-04 P110001 50 mL 50 mL 08/26/11 15:00 Prep Method: 3510C MS Lab Number Batch Initial Final Date/Time 1080715-01 PlH0677 1000 mL 1 mL 08/30/11 9:30 1080715-02 PlH0677 970 mL 1 mL 08/30/11 9:30 1080715-03 PlH0677 980 mL 1 mL 08/30/11 9:30 1080715-04 P1 H0677 980 mL 1 mL 08/30/11 9:30 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 1080715-01 P1 H0666 20 mL 30 mL 08/30/11 13:15 1080715-02 PlH0666 20 mL 30 mL 08/30/11 13:15 1080715-03 PlH0666 20 mL 30 mL 08/30/11 13:15 1080715-04 PlH0666 20 mL 30 mL 08/30/11 13:15 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 1080715-01 PlH0661 10 mL 10 mL 08/30/11 11:48 1080715-02 PlH0661 10 mL 10 mL 08/30/11 11:48 1080715-02 PlH0661 10 mL 10 mL 08/30/11 11:48 1080715-03 PlHO661 10 mL 10 mL 08/30/11 11:48 1080715-03 P1H0661 10 mL 10 mL 08/30/11 11:48 1080715-04 P1H0661 10 mL 10 mL 08/30/11 11:48 1080715-04 PlHC661 10 mL 10 mL 08/30/11 11:48 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 36 of 52 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 1080715-01 TOC (Sub) 1080715-02 TOC (Sub) 1080715-03 TOC (Sub) 1080715-04 TOC (Sub) This report should not be reproduced, except in its entirely, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041525-0409 Page 37 of 52 CHAIN OF CUSTODY RECORD 1AMEJ ,;Full -Service Analytical &'} s;'F: ism Environmental Solutions PAGE 1— OF_1f_ Ol70Tk? it TO ENSURE PROPER BILLING: V" IABORATORIFA ING HCN 5.0 N i AW p r-, L.. 449 Springbrook Road • P.O. Box 240543 • Charlotte, NO 28224-0543 Project Name: Phone: 704/529-6364 • Fax: 704/525-0409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) Client Company Name: W I-Ct-tins-Rh>iiN�L "Please ATTACH any project specific reporting (QC LEVEL 111 111 IV) provisions and/or QC Requirements Report To/Contact Name: IDIXA N S��U'lS Invoice To: Reporting Address: 190 CoMMWE;&AH k&\y6 Address: Snit 16 1,6\ Zggil Phone: q lD Fax (Yes) (No): Purchase Order NoJBilling Reference TO BE FILLED IN BY CLIENT/SAMPLINGi PERSONNEL f Email [Q (No) Email Address Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC EDD Type: PDF_ Excel —Other "Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ p ash p WorkMust Be N�Ns°N SjT'(, l..q,NOFt1,,1. SC_ OTHER N/A Site Location Name: Samples received after 15:00 will be processed next business day. Site i (q VS t {V i ZZ� S Turnaround time is based on business days, excluding weekends and holidays ChIOCinated: YES_ NO — Site Location Physical Address: (SEE REVERSE FOR TERMS & REGARDING SERVICES O r jb pie Iced Upon Collection: YES �NO cl r� /QRENDERED BY PRISM LABORATORIES, INC. TO CLIENT)NDITIONS sES• CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- AN REQU@STED Q �/ DL (/ �,➢\` % (� REMARKS PRISM LAB 'TYPE SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR NO. SIZE TIVES ��\� y V ID NO. HOURS SLUDGE) SEE BELOW /� (,��_ 1-I C,L A- G C Z_ I L mow_ in k CL Pik c 9r; r% Ogg Nab J - rJ - - - / GP ( ieoM Nay c c Sampler's Signature Sampled By (Print Name) r✓ d Affiliatlon Upon relinquishing, this Chain of Custody Is your authorization for Prism to proceed with the analyses as requested above. Any changes must be • - • IZIIWM Manager. There will be charges for any changes after analyses have been initialized. „ : . ..,;;; submitted In writing to the Prism Project Received By: (Signature) Date Military/Hours Additional Comments: '.Si(e'Ait'N' aliTimi3°_ Relinquished By: (Signature) Sit9DepattuieiTliiie Relinquished By: (Signature) Received By: (Signature) Data g;% , , qulshed.By: (Signature) eived F bcrawnes By: Date 4rZ(s, f( lNzS 7i+lifage od of S pment: NOTE: ALL SAMP E COOLERS SHOU D BE TAPED SHUT WIT CUSTODY SEALS ORTATION TO THE LABORATORY. COC Group No. N SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC NTIL RECEIVED AT THE ORATORY. W OD d Ex ❑UPS ❑ Hand -delivered ❑ Prism Field Service O Other 'SEE REVERSE o ES: usT: GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: . �. N C ❑ SC ❑ NC ❑ SC I IRNC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC D NC ❑ SC ❑ NC ❑ SC I ❑ NC ❑ SC I ❑ NC ❑ SC I ❑ _...--_ I o --_... --- ❑ .... ❑ _ ❑ -_.— ❑ - , ❑ —...— o ORIGINAL ..�....�., �...,� ...,.,r �. _ n tie. r _ rto�. r rta�� v - plastic- TL = Teflon -Lined CaD VOA = Volatile Organics Analysis (Zero Head Space) - -- I � I lip - CHAIN OF CUSTODY RECORD #g -i�. Full -Service Analytical & A ;J IS M Environmental Solutions PAGE OF QUOTE �9T0 ENSURE PROPER BILLING: LABORATORIES, W. 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Project Name: Phone: 704/529-6364 % Fax: 704/525-0409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) Client Company Name, *Please ATTACH any project specific reporting (QC LEVEL 111111 IV) provisions and/or QC Requirements Report To/Contact Name: Invoice To: Reporting Address: Address: Phone: Fax (Yes) (No): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email (Yes) (No) Email Address Requested Due Date ❑ i Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC EDD Type: PDF._ Excel Other 'Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ Rushdust Be SC____ OTHER N/A Site Location Name: Samples received after 15.00 will be processed next business day. Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES— NO_ Site Location Physical Address: (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES _ NO — RENDERED BY PRISM LABORATORIES, INC. TO CLIENT] TIME MATRIX SAMPLE CONTAINER ANALYSES RE UESTED ��� PRISM LAB CLIENT DATE COLLECTED (SOIL, PRESERVA- TIVES �'� �N� �, REMARKS ID NO. "TYPE SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR, NO' SIZE�)b(` HOURS SLUDGE) SEE BELOW Mor C, C G 3 3i4M . -R (, J - fL a � 1-_ 290 ! r P 1 flSr� 3 G e 1 JIS-00M I N a Sampled By (Print Name) K. Q. k,56Z � Affiliation 1J °/t this Chain of Custody is your authorization for Prism to proceed with the analyses as requested. above. Any changes must be i to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. ^ By: nquished By: (Signature) • ", ' — " _.__..-- -' S 2r, / ( 1-Iz5 Iy to CD hod of Sh pment: NOTE: ALL SA PLE COOLERS SHO D E TAPED SHUT wi H C STORY SEALS FOR TR PORTATION TO THE LABORATORY. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COO UNTIL RECEIVED AT THE LABORATORY. COC Group o. J lJ ��JJ Y � ed Ex ❑ UPS ❑ Hand -delivered ❑ Prism Field Service ❑ Other I WAYER: i L❑ SOLID 5C E Q ILL I OTHER: F❑ ❑ NC ❑ SC ❑ NC ❑ SCTER: OD NCKI❑SNG ❑NC ❑ ❑❑ NCA ❑ SC ❑❑ NC SC j 0 NC SC O NC ❑ SC ❑ ❑ O ENTA1:NEjR TYPE CODES: A = Amber C = Clear G = Glass II I P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Comments: PRISM -USE ONLY '$ifeDepaRu'rQ?Tihiet% �.? SEE REVERSE FOR TERMS & CONDITIONS 0. a a ACCESS ANAL'flT1CAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 ATTENTION Angie Overcash PROJECTiD 1080715 LABORATORY REPORT NUMBER 211082914 DATE 08/31 /2011 Primary Data Review By ln(e* 'gn Curtis Ekker Data Validation Manager, GCAL Secondary Data Review By Ashley a Amick Project Manager, Access Analytical, Inc. aamick@accessanalyUcalinc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 GSRI Avenue, Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Page 40 of 52 NELAP CERTIFICATE NUMBER 01955 DOD FLAP CERTIFICATE NUMBER ADE - 1482 ANALYTICAL RESULTS PERFORMED BY GULF COAST ANALYTICAL LABORATORIES, INC. 7979 GSRI Avenue Baton Rouge, LA 70820 Report Date 08/31/2011 "uiuReport Miudi110iiiiiii1m Deliver To Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 706-529-6364 Attn Angie Overcash Project 1080715 Page 41 of 52 CASE NARRATIVE Client: Prism Laboratories, Inc. Report: 211082914 GulfCoastCoast Analytical Laboratories received and analyzed the sample(s) listed on the sample cross-reference page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. CONVENTIONALS In the SM 5310B analysis, samples 21108291403 (MW-3) and 21108291404 (MW-2) had to be diluted in order to bracket the Total Carbon and/or Total Inorganic Carbon concentrations within the calibration range of the instrument. The Total Organic Carbon is based on the difference between the Total Carbon and the Inorganic Carbon. The dilution is reflected in the elevated reporting limit. Page 42 of 52 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations Utilized in this Report ND Indicates the result was Not Detected at the specified RDL DO Indicates the result was Diluted Out Mi Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field PQL Practical Quantitation Limit MDL Method Detection Limit RDL Reporting Detection Limit 00:00 Reported as a time equivalent to 12:00 AM Reporting Flags Utilized In this Report J Indicates an estimated value U Indicates the compound was analyzed for but not detected B (ORGANICS) Indicates the analyte was detected in the associated Method Blank B (INORGANICS) Indicates the result is between the RDL and MDL Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with the NELAC standard and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer -readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Robyn Migues Technical Director GCAL REPORT 2110829141nt Sig I THIS REPORT CONTAINS PAGES. Page 43 of 52 Report Sample Summary GCAL ID Client ID Matrix Collect Date/Time Receive Date/rime 21108291401 MW-20A Water 08/261201108:45 08/27/201109:00 21108291402 MW-20 Water 08/26/201109:45 08/27/201109:00 21108291403 MW-3 Water 08/261201110:46 08127/201109:00 21108291404 MW-2 Water 08/261201111:45 08/27/201109:00 GCAL Report 211082914 Page 44 of 52 Summary of Compounds Detected :;GCALIQ �_::-::.::=-:=�Clianfll);:'::;;,�•::M__�.:_�:.:::::.:::.:::--,_.;_;•.._.:�;:?Matrix CollectDatel'itme.-z,�:_< , Recetve,Dateltime .�.1.....<_ -, ..;. •• c'.. } . ...... _«..... ,::�:..... ....._..:_ „-:. ., . •..: c: •: •s 5f :2:i3::: i.iS".''C F3:�:: =:-`'t::: .:. � s» ::=3=tr•:3:-:.: � s;.r'•'a..._.'�s._:.. _•_-:::�::.:-;::. ;•:.u_,, .,.. ......:....->..._....» .; . .-' • :�::::::: n:cc:::n. ;..tom......... •....,.,:rc..e:_ :fx�:::rr.;:.'i?:c:^v}: ::: t G'•.a>:,m;:? :=::08126120. 08 5=.:::.::,. :.= =:aa::;::z.08/27/2 1 J• 0 :•w -.._.._......_....M.:..._.._....._.._.:::.,:,.: :,..,.Wa.e.._......., -- - l..,..,4...._t.._..._._..._... ,._...._.:....._.......__0:. _.0.9..0 aY: ?s-,.:::::::::........ SM 5310B TOC CAN Parameter Result RDL MDL Units C-012 Total Organic Carbon 3.4 1.0 0.20 mg/L -- ::G AC1D •-_ M:-»_,:� Clietttla ...._..:: _. ••--•rr» =-.-._..:=�:- •-:.=�-=:-:::=~`�Mafn , .::t=-_ =:- allect„DateTGime - Rece,ue ISate c :Ime.: _4����n;=-_;:;>ri?�. w:x- .:::: �: =w :=.,:<::� •._ _.....- .. __.__._..._... _._........ _...tom: M: t._ ... t ......._..... _...; : ,:::.. :..........r_.. ems.......,.... "-«- >::::::::::-<:< ,:.::: .,..._.�, •-- :,._._....._._ :-;-; ; „s: ::'b),»tom ..-._.. ..».�._.,. _ _. .......:..... ...,.. 2:t.. _3 S� .o.�..,__.[..._._..._ t0829t40 :s::: ,•MW-20: -: ::..:.. _ Uiiater :?•...- -Q k 2D11.09.45__ •:• :_:-.:- :::•:::-08t2:72 : 1 00 _., SM 5310B TOC CAN Parameter Result RDL MDL Units C-012 Total Organic Carbon 29.3 1.0 0.20 mg/L :�:,,.,,;�,,,::�_-_.---:-::::_.,-•.,._ ::.>;:,:,.._......._-<r;r-.:,--1t.._..__ __.•,.::ram.-:-----.�::-••-. _:,..fi.t :GCAi-w:•-= x1D��:.->,�::Gllent7��-r.._:�..,;:a.,�:::=�:,a4.� t •_-----MatrSy 3_:�_-:,�GolTect-D3itakiltn+i :?,;i?eCe,veDaf�l_T:imem...:2t� _�.,+�-r..- .t:f1..ns..._............. _....._- __ ....tt �.::...:F-:..� :=tC::"•v..........•... .'MM^.«_....-._� ...<... _ -- fI:.L......L..s_._.W't.::::::: - '• :try:±� ..._.,...««.. �..5� ._..t.. .. r_c.:.::......... ,.......�r:m� :-.._..,.r,,'^.r.�.•N .,.. __.qa:-......._ �.=..:?_:1_.- .G:Cr-::'_� ••: — - + 't:a'._ ..rth�yi?;Y=c:p,:..,..._........«„c.::-;rer:'. .:-.,...._......-.;c:;.::s..;:.u,::._rn:xr..:;n,.«..:.::m_•-._...._.:._..=.. ;.:.me•rc:r.•w-. rx..:...:»..,..:-.:63r-.;.:.r... _.._..__.._...__r. .. r .:_ t r SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 73.5 5.0 1.0 mglL N. ..,:r.:........ ....... _ ,. tom.,.:...,.:..:.._. r . � r : __ - :3•.;::r_c-..c ..,?rr.:n :c .r.,.. __._. s g3•..v..__......t..-....__._... -; - .., _,. GALsID __:..:. I L}�:,,:7•: �� :•;�= � :.._, .,�' :.._.. "Ail .ix ... _... C ,me.... _..............__ ..._.. ec iv --• ------•--�-------.. telT......._,T•.:,........_.... Ji a-.e.-atl7lme ,: _.._..._....._.._�....3:..-»:::::.:_.. �._,...rw,..a�•:•��r.i: ... . .......::::rsf_. __...._.. �3.., ., .__m..a,....._.....:__.,.......---..:...._..__....... _.�.._g., � 3...:1^:[: _��_:::�•�:; .....« f_..................u.__a_co•:3r.:;s:: ; %yr.,:4..;GfS:.r�s::.:�� m�._.-3:_. mt .:�:..,...5... .:: �::saa .. __..........&.. ......._......._......_._.... -.._, ,-.._,pu-�_v± ;.,,�.,�...;�c-'::M.,;�•;:..�; ..i:."'::�:":5_:;..:-_..- s. ..._....... ...�t.e3.:rr�.::::c ,�.. c.; 3:::��::.::••:-::n?I:r_::c:: - ... ....,}..-....._.....:..._.-,<:a:a:- 1:404 .... :. rt;:__ ::s~_ :u•=a_:_-::::: _.:.....:0872612011 1' :: _2.f.1.D.._9......._...------=-]V11Nr�,,:r.=�:: ..:_t....._.._..:.�:_::,::::Watgl'�,-x, _-_-.�......__..__:..r,..,45<:._�.,-,:�,:•:.-- _•2._/2. _'�U9..00;�. SM 5310B TOC CAS# Parameter C-012 Total Organic Carbon l � GCAL Report 211082914 Result RDL MDL Units 109 5.0 1.0 mglL Page 45 of 52 SM 531 OB TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 08130/201123:06 AEL 464369 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 3.4 1.0 0.20 mglL GCAL Report 211082914 77-71 Page 46 of 52 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch t OB1301201123:26 AEL 464369 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 29.3 1.0 0.20 mg/L GCAL Report 211082914 i Page 47 of 52 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 5 081311201110:08 AEL 464369 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 73.5 5.0 1.0 mg1L GCAL Report 211082914 I I Page 48 of 52 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 5 081311201110:27 AEL 464368 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211082914 Result RDL MDL Units 109 5.0 1.0 mglL Page 49 of 52 General Chemistry Quality Control Summary Analytical Batch 464369 Client ID MB464369 LCS464369 LCSD464369 Prep Batch NIA GCAL ID 983458 983459 983460 Sample Type Method Blank LCS LCSD Analytical Date 08/30/2011 11:52 08/30/2011 12:27 08130/2011 12:49 Matrix Water Water Water SM 5310B TOC Units mg/L. Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 0.20U 0.20 50.0 51.8 104 80 - 120 52.0 0.4 25 Analytical Batch 464369 ClientlD U31DB201G 983238MS 98323SMSD Prep Batch N/A GCAL ID 21108270501 983463 983464 Sample Type SAMPLE MS MSD Analytical Date 08/30/2011 20-.36 08130/2011 22:13 08/30/2011 22:38 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control I Result RPD Result RDL Added % R Limits % R % R 1 RPD Limit C-012 Total Organic Carbon 178 1.0 250 410 1 75 - 1251 404 90 7 1 25 GCAL Report 211082914 5�3 - Full -Service Analytical & Environmental Solutions LAgO}!g70R1E$1NG SUBCONTRACT ORDER Certification: NELAC_ USACE Prism Laboratories, Inc. SC_ Other R� IIn 1 1080715 N/A SENDWGLABORATORY: RECEWLNG LABORATORY: Prism Laboratories, Inc. Gulf Coast Analytical Labs, Inc. P. O. Box 240543 7979 GSRI Avenue Charlotte, NC 28224-0543 Baton Rouge, LA 70820 t Phone: 800-529-6364 Phone :(225) 7694900 Fax: 704-525-0409 Fax: (225) 767-5717 Project Manager. Angela D. Overcash Analysis Due Expires Laboratory ID Comments Sample ID: 1030715-01 Water Sampled:08/26/1108.45 10-11WIN"�!'•.-^e� TOC (Sub) 09/23/11 08:45 Containers Supplied: Sample ID: 1080715-02 Water Sampled:08/26/1109:45 TOC (Sub) 09/23/11 09:45 Containers Supplied; - _ M _ J Sample ID: 1080715-03 Water Sampled:08/26/11 10:45 • :tt�. a�. TOC (Sub) Containers Supplied: 09/23/11 I0:45 Sample ID:1080715-04 Water Sampled:08/26/1i 11:45 ! - = �" . _'r TOC (Sub) --Containers Supplied, 09/23/11 11:45 Released By Date Received By Date i Released By Date Received By Date Page 1 of 1 Page 51 of 52 Login Checklist Page I of I GCALE® CAI F CO\STANALYMALIABORATOM" WC SAMPLE RECEIVING CHECKLIST Workorder 211082914 Client: 4565 - Access Analytical Profile: 80435 - Prism Lab- Line Item: 1 -Water BTHX/Naoh MTBE Received by: Saucier. Charlotte Received Datefrime: 8/2712011 9:00:00 AM Samples Received via: FEDEXX Number of Coolers Received: — r� C ' �7 Cooler tracking numbers(s): I( d� r9 - 1 Cooler temperature(s): Were all coolers received at a temperature of 0 - 6° C? l✓j Yes F. No r NIA Were all custody seals intact? F Yes r No r NIA Were all samples received in proper containers? F. Yes r• No r NIA Were all samples property preserved? r Yes r No r NIA Was preservative added to any container at the lab? r Yes r No r NIA Were all containers received in good condition? 1✓ Yes r No r NIA Were all VOA vials received with no head space? r Yes (' No NIA Do all sample labels match the Chain of Custody? r Yes �" No r WA Was the client notified about any discrepancies? r Yes r No NIA Notes/Comments: http://webserverl/REX/Secure/LoginChecklist.aspx 8/29/20II Page 52 of 52 ZPRISM� I Full -Service Analytical & yy Environmental solutions :�.. LABORATORIES ING Withers & Rave nel-Wilmington Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cent No. 37735 Project: Henson Landfill Project No.: none Lab Submittal Date: 09/02/2011 Prism Work Order: 1090044 Case Narrative 09/15/2011 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: TOC analysis was subcontracted to GCAL. Laboratory report is attached. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. 6 /1 �'J VP Laboratory Services Data Qualifiers Key Reference: Reviewed By A Final CCV recovery (111 %) is outside the control limits (90-110%). Results might be biased high. Aa Sample diluted due to high Internal Standard recoveries. Internal Standard elements appear to be present in the samples. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). MC Sample concentration too high for recovery evaluation. MI Matrix spike outside of the control limits. Matrix interference suspected. SR Surrogate recovery outside the QC limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/625-0409 Page 1 of 37 P_,R I S M I Fun -Service Analytical s -• Environmental Solutions � �.eown.owics wc Sample Receipt Summary 09/15/2011 Prism Work Order: 1090044 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW-20A 1090044-01 Water 09/02/11 09/02/11 MW-20 1090044-02 Water 09/02/11 09/02/11 MW-3 1090044-03 Water 09/02/11 09/02/11 MW-2 1090044-04 Water 09/02/11 09/02/11 Samples received in good condition at 0.7 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 2 of 37 Z�E',RI S M I Full-ServiceService Analytical 8 Environmental Solutions L nBgiAlOeIES - Laboratory Report 09/15/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1090044-01 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 06:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 2.9 ug/L 2.0 0.12 1 6020A 916111 13:09 DWR P110062 Cadmium BRL ug/L 1.0 0.20 1 6020A 9/6/11 13:09 DWR P110062 Chromium 5.0 ug/L 1.0 0.12 1 6020A 916/11 13:09 DWR P110062 Copper 1.2 J ug/L 5.0 0.53 1 6020A 916/11 13:09 DWR P110062 Lead 0.30 J ug/L 1.0 0.13 1 6020A 9/6111 13:09 DWR P110062 Selenium 1.6 J ug/L 2.0 0.44 1 6020A 9/6/11 13:09 DWR P110062 Zinc 8.7 J ug/L 10 0.58 1 6020A 9/6111 13:09 DWR P110062 Anions by Ion Chromatography Chloride 1500 ug/L 1000 8.6 1 9056A 9/8111 0:35 CDE P110146 Sulfate 54000 ug/L 10000 120 10 9056A 919/11 16:53 CDE P110164 Total Metals Mercury BRL ug/L 0.20 0.014 1 7470A 9/7/11 15:25 BGM P110099 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.15 1 B260B 9/6/11 13:35 MGB P110061 1,1,1-Trichloroethane BRL ug/L 0.50 0.063 1 8260B 9/6/11 13:35 MGB P110061 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.071 1 8260B 9/6/11 13:35 MGB P110061 1,1,2-Trichloroethane BRL ug/L 0.50 0.17 1 8260B 9/6/11 13:35 MGB P110061 1,1-Dichloroethane BRL ug/L 0.50 0.096 1 8260B 9/6/11 13:35 MGB P110061 1,1-Dichloroethylene BRL ug/L 0.50 0.078 1 8260B 9/6/11 13:35 MGB P110061 1, 1 -Dichloropropylene BRL ug/L 0.50 0.061 1 8260B 9/6/11 13:35 MGB P110061 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.20 1 8260B 9/6/11 13:35 MGB P110061 1,2,3-Trichloropropane BRL ug/L 1.0 0.081 1 8260B 9/6/11 13:35 MGB P110061 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.10 1 8260B 9/6/11 13:35 MGB P110061 1,2,4-Trimethyl benzene BRL ug/L 0.50 0.048 1 8260B 9/6/11 13:35 MGB P110061 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.59 1 8260B 9/6/11 13:35 MGB P110061 1,2-Dibromoethane BRL ug/L 0.50 0.14 1 8260B 9/6/11 13:35 MGB P110061 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 9/6/11 13:35 MGB P110061 1,2-Dichloroethane BRL ug/L 0.50 0.14 1 8260B 9/6/11 13:35 MGB P110061 1,2-Dichloropropane BRL ug/L 0.50 0.13 1 8260B 9/6/11 13:35 MGB P110061 1,3,5-Trimethylbenzene BRL ug/L 0.50 0.057 1 8260B 9/6/11 13:35 MGB P110061 1,3-Dichlorobenzene BRL ug/L 0.50 0.074 1 8260B 9/6/11 13:35 MGB P110061 1,3-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 9/6/11 13:35 MGB P110061 1,4-Dichlorobenzene BRL ug/L 0.50 0.068 1 8260B 9/6/11 13:35 MGB P110061 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 9/6/11 13:35 MGB P110061 2-Chloroethyl Vinyl Ether BRL ug/L 2.0 0.22 1 8260B 9/6/11 13:35 MGB P110061 2-Chlorotoluene BRL ug/L 0.50 0.038 1 8260B 9/6/11 13:35 MGB P110061 4-Chlorotoluene BRL ug/L 0.50 0.053 1 8260B 9/6/11 13:35 MGB P110061 4-Isopropyltoluene BRL ug/L 0.50 0.065 1 8260B 9/6/11 13:35 MGB P110061 Acetone BRL ug/L 5.0 0.62 1 8260B 9/6/11 13:35 MGB P110061 Acrolein BRL ug/L 20 1.1 1 8260B 9/6/11 13:35 MGB P110061 Acrylonitrile BRL ug/L 20 0.86 1 8260B 9/6/11 13:35 MGB P110061 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 3 of 37 /F P R I S M i Full-Service� ce Analytical Environmental Solutions ueownronres Inc Laboratory Report 09/15/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1090044-01 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 06:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene BRL ug/L Bromobenzene BRL ug/L Bromochloromethane BRL ug/L Bromodichloromethane BRL ug/L Bromoform BRL ug/L Bromomethane BRL ug/L Carbon disulfide BRL ug/L Carbon Tetrachloride BRL ug/L Chlorobenzene BRL ug/L Chloroethane BRL ug/L Chloroform BRL ug/L Chloromethane BRL ug/L cis- 1,2-Dichloroethylene BRL ug/L cis- 1,3-Dichloropropylene BRL ug/L Dibromochloromethane BRL ug/L Dibromomethane BRL ug/L Dichlorodifluoromethane BRL ug/L Ethylbenzene BRL ug/L Hexachlorobutadiene BRL ug/L Isopropyl Ether BRL ug/L Isopropylbenzene (Cumene) BRL ug/L m,p-Xylenes BRL ug/L Methyl Butyl Ketone (2-Hexanone) BRL ug/L Methyl Ethyl Ketone (2-Butanone) BRL ug/L Methyl Isobutyl Ketone BRL ug/L Methylene Chloride BRL ug/L Methyl-tert-Butyl Ether BRL ug/L Naphthalene BRL ug/L n-Butylbenzene BRL ug/L n-Propylbenzene BRL ug/L o-Xylene BRL ug/L secButylbenzene BRL ug/L Styrene BRL ug/L tert-Butylbenzene BRL ug/L Tetrachloroethylene BRL ug/L Toluene BRL ug/L trans- 1,2-Dichloroethylene BRL ug/L trans- 1,3-Dichloropropylene BRL ug/L Trichloroethylene BRL ug/L Trichlorofluoromethane BRL ug/L Vinyl acetate BRL ug/L Vinyl chloride BRL ug/L 0.50 0.072 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.064 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.13 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.062 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.27 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.47 1 8260B 9/6/11 13:35 MGB P110061 5.0 1.4 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.12 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.061 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.13 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.089 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.11 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.076 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.10 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.30 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.13 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.11 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.067 1 8260B 9/6/11 13:35 MGB P110061 2.0 0.36 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.043 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.072 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.081 1 8260B 9/6/11 13:35 MGB P110061 5.0 0.19 1 8260B 9/6/11 13:35 MGB P110061 5.0 0.90 1 8260B 9/6/11 13:35 MGB P110061 5.0 0.12 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.44 1 82606 9/6/11 13:35 MGB P110061 0.50 0.070 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.098 1 8260B 9/6/11 13:35 MGB P110061 1.0 0.11 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.060 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.046 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.087 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.047 1 8260B 9/6/11 1335 MGB P110061 0.50 0.080 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.069 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.042 1 B260B 9/6/11 13:35 MGB P110061 0.50 0.12 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.043 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.054 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.088 1 8260B 9/6/11 1335 MGB P110061 2.0 0.10 1 8260B 9/6/11 13:35 MGB P110061 0.50 0.16 1 8260B 9/6111 13:35 MGB P110061 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041625-0409 Page 4 Of 37 � I Full -Service Analytical & Laboratory Report �P„ I S M Environmental Solutions 09/15/2011 ineorwra — wn Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1090044-01 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 06:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 106 % 75-129 Toluene-d8 100 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529.6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 5 of 37 /gIRR I S M I Fun -Service Analytical 8 Laboratory Report Environmental Solutions 09/15/2011 � i�eonnrowres inc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1090044-02 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 07:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 54 ug/L 2.0 0.12 1 6020A 916111 13:01 DWR P110062 Cadmium BRL ug/L 1.0 0.20 1 6020A 9/6/11 13,01 DWR P110062 Chromium 7.7 ug/L 1.0 0.12 1 6020A 9/6111 13:01 DWR P110062 Copper 1.6 J ug/L 5.0 0.53 1 6020A 9/6111 13:01 DWR P110062 Lead 0.60 J ug/L 1.0 0.13 1 6020A 9/6111 13:01 DWR P110062 Selenium 6.6 ug/L 2.0 0.44 1 6020A 916/11 13:01 DWR P110062 Zinc 18 ug1L 10 0.58 1 6020A 9/6/11 13:01 DWR P110062 Anions by Ion Chromatography Chloride 48000 ug1L 10000 86 10 9056A 9/9/11 16:18 CDE P110164 Sulfate BRL ug/L 1000 12 1 9056A 9/8/11 0:53 CDE P110146 Total Metals Mercury Volatile Organic Compounds by GUMS BRL ug/L 0.20 0.014 1 7470A 9/7/11 15:41 BGM P110099 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 9/3/11 16:23 MGB P110061 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 9/3/11 16:23 MGB P110061 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 9/3/11 1623 MGB P110061 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 9/3/11 16:23 MGB P110061 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 9/3/11 16:23 MGB P110061 1, 1 -Dichloropropylene BRL ug/L 10 1.2 20 8260B 9/3/11 1623 MGB P110061 1,2,3-Thchlorobenzene BRL ug/L 40 4.0 20 8260B 9/3/11 16:23 MGB P110061 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 9/3/11 16:23 MGB P110061 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 9/3/11 16:23 MGB P110061 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 9/3/11 16:23 MGB P110061 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 9/3/11 16:23 MGB P110061 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 9/3/11 16:23 MGB P110061 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 9/3/11 16:23 MGB P110061 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 9/3/11 1623 MGB P110061 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 9/3/11 1623 MGB P110061 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 9/3/11 16:23 MGB P110061 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 9/3/11 16:23 MGB P110061 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 9/3/11 16:23 MGB P110061 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 9/3/11 16:23 MGB P110061 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 9/3/11 16:23 MGB P110061 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 9/3/11 16:23 MGB P110061 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 9/3/11 16:23 MGB P110061 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 9/3/11 16:23 MGB P110061 Acetone BRL ug/L 100 12 20 8260E 9/3/11 16:23 MGB P110061 Acrolein BRL ug/L 400 22 20 8260E 9/3/11 16:23 MGB P110061 Acrylonitrile BRL ug/L 400 17 20 8260B 9/3111 1623 MGB P110061 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 6 of 37 PRISM Full-ServiceAnalyticalLaboratory Report Environmental Solutions 09/15/2011 /�. ueonnrowres nc Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1090044-02 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 07:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Benzene 30 ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 Bromobenzene BRL ug/L 10 1.3 20 8260B 9/3/11 16:23 MGB P110061 Bromochloromethane BRL ug/L 10 2.5 20 8260B 9/3/11 16:23 MGB P110061 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 9/3/11 16:23 MGB P110061 Bromoform BRL ug/L 20 5.4 20 8260B 913/11 16:23 MGB P110061 Bromomethane BRL ug/L 20 9.3 20 8260B 9/3/11 16:23 MGB P110061 Carbon disulfide BRL ug/L 100 28 20 8260E 9/3/11 16:23 MGB P110061 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 9/3/11 16:23 MGB P110061 Chlorobenzene 91 ug/L 10 1.2 20 8260B 913111 16:23 MGB P110061 Chloroethane BRL ug/L 10 2.6 20 8260B 9/3/11 16:23 MGB P110061 Chloroform BRL ug/L 10 1.8 20 8260B 9/3/11 16:23 MGB P110061 Chloromethane BRL ug/L 10 2.2 20 8260B 9/3/11 16:23 MGB P110061 cis-1,2-Dichloroethylene 71 ug/L 10 1.6 20 8260B 913/11 16:23 MGB P110061 cis- 1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 9/3/11 16:23 MGB P110061 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 9/3/11 16:23 MGB P110061 Dibromomethane BRL ug/L 10 2.6 20 8260B 9/3/11 16:23 MGB P110061 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 9/3/11 16:23 MGB P110061 Ethylbenzene BRL ug/L 10 1.3 20 8260B 9/3/11 16:23 MGB P110061 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 9/3/11 16:23 MGB P110061 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 9/3/11 16:23 MGB P110061 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 m,p-Xylenes 21 ug/L 20 1.6 20 8260B 913/11 16:23 MGB P110061 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260E 9/3/11 16:23 MGB P110061 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 100 18 20 82606 9/3/11 16:23 MGB P110061 Methyl Isobutyl Ketone 16 J ug/L 100 2.5 20 8260E 9/3111 16:23 MGB P110061 Methylene Chloride BRL ug/L 20 8.9 20 8260B 9/3/11 16:23 MGB P110061 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 Naphthalene BRL ug/L 20 2.0 20 8260B 9/3/11 16:23 MGB P110061 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 9/3/11 16:23 MGB P110061 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 9/3/11 16:23 MGB P110061 o-Xylene BRL ug/L 10 0.92 20 8260B 9/3/11 16:23 MGB P110061 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 9/3/11 16:23 MGB P110061 Styrene BRL ug/L 10 0.94 20 8260B 9/3/11 16:23 MGB P110061 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 9/3/11 16:23 MGB P110061 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 9/3/11 16:23 MGB P110061 Toluene 3500 ug/L 100 8.5 200 8260E 913/11 16:50 MGB P110061 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 9/3111 16:23 MGB P110061 trans- 1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 9/3/11 16:23 MGB P110061 Tiichloroethylene BRL ug/L 10 1.1 20 8260B 9/3/11 16:23 MGB P110061 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 9/3/11 16:23 MGB P110061 Vinyl acetate BRL ug/L 40 2.0 20 8260B 9/3111 16:23 MGB P110061 Vinyl chloride BRL ug/L 10 3.1 20 8260B 9/3/11 16:23 MGB P110061 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, Phone: 704/529-6364 Toll Free Number: 1-800/529-6364 NC 28224-0643 Fax: 704/625-0409 Page 7 of 37 - - I S M I Full -Service Analytical 8 Environmental Solutions ,SIR uern�romes,r�c. Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Project No.: none Sample Matrix: Water Laboratory Report 09/15/2011 Client Sample ID: MW-20 Prism Sample ID: 1090044-02 Prism Work Order: 1090044 Time Collected: 09/02/11 07:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 Of 37 Laboratory Report �s P R I S M I Full -Service Analytical s /yj¢ Environmenta� Solutions 09/15/2011 ueownr".m'NG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1090044-03 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 08:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 68 Aa ug/L 30 3.5 30 6020A 9/8111 13:05 DWR P110062 Cadmium 23 Aa, J ug/L 30 6.0 30 6020A 9/8111 13:06 DWR P110062 Chromium 66 Aa ug/L 30 3.5 30 6020A 918/11 13:05 DWR P110062 Copper 4100 Aa ug/L 150 16 30 6020A 9/8/11 13:05 DWR P110062 Lead 91 Aa ug/L 30 3.8 30 6020A 918/11 13:05 DWR P110062 Selenium 49 Aa ug/L 30 13 30 6020A 9/8/11 13:05 DWR P110062 Zinc 2100 Aa ug/L 300 17 30 6020A 9/8111 13:05 DWR P110062 Anions by Ion Chromatography Chloride 280000 ug/L 50000 430 50 9056A 9113/11 16:19 RSL P110210 Sulfate 20000000 A ug/L 5000000 60000 5000 9056A 9/14111 15:53 RSL P110189 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL ug/L 0.20 0.014 1 7470A 917/11 15:45 BGM P110099 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 9/3/11 17:16 MGB P110061 1, 1, 1-Trichloroethane BRL ug/L 10 1.3 20 8260B 9/3/11 17:16 MGB P110061 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 9/3/11 17:16 MGB P110061 1,1,2-Trichloroethane 11 uglL 10 3.3 20 8260B 9/3/11 17:16 MGB P110061 1,1-Dichloroethane 26 ug/L 10 1.9 20 8260B 9l3/11 17:16 MGB P110061 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 9/3/11 17:16 MGB P110061 1,1-Dichloropropylene BRL ug/L 10 1.2 20 8260B 9/3/11 17:16 MGB P110061 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 9/3/11 17:16 MGB P110061 1,2,3-Trichooropropane BRL ug/L 20 1.6 20 8260B 9/3/11 17:16 MGB P110061 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 9/3/11 17A6 MGB P110061 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 9/3/11 17:16 MGB P110061 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 9/3/11 17:16 MGB P110061 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 9/3/11 17:16 MGB P110061 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 9/3/11 17:16 MGB P110061 1,2-Dichloroethane 170 ug/L 10 2.8 20 8260B 913/11 17:16 MGB P110061 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 9/3/11 17:16 MGB P110061 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 9/3/11 17:16 MGB P110061 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 9/3/11 17:16 MGB P110061 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 9/3/11 17:16 MGB P110061 1,4-Dichlorobenzene BRL ug/L 10 1A 20 8260B 9/3/11 17:16 MGB P110061 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 9/3/11 17:16 MGB P110061 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 9/3/11 17:16 MGB P110061 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 9/3/11 17:16 MGB P110061 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 9/3/11 17:16 MGB P110061 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 9/3/11 17:16 MGB P110061 Acetone 7900 ug/L 1000 120 200 8260E 9/3111 17:42 MGB P110061 Acrolein BRL ug/L 400 22 20 8260E 913/11 17:16 MGB P110061 Acrylonitrile BRL ug/L 400 17 20 8260E 9/3/11 17:16 MGB P110061 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529.6364 - Fax: 7041525-0409 Page 9 of 37 /P R I S M I Fun -Service Analytical 8 Environmental Solutions �k. ueonwrowics me Laboratory Report 09/15/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1090044-03 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 08:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene BRL ug/L Bromobenzene BRL ug/L Bromochlorom ethane 42 ug/L Bromodichloromethane BRL ug/L Bromoform BRL ug/L Bromomethane 150 ug/L Carbon disulfide BRL ug/L Carbon Tetrachloride BRL ug/L Chlorobenzene BRL ug/L Chloroethane 390 ug/L Chloroform BRL ug/L Chloromethane 1800 ug/L cis- 1,2-Dichloroethylene BRL ug/L cis- 1,3-Dichloropropylene BRL ug/L Dibromochloromethane BRL ug/L Dibromomethane BRL ug/L Dichlorodifluoromethane BRL ug/L Ethylbenzene BRL ug/L Hexachlorobutadiene BRL ug/L Isopropyl Ether BRL ug/L Isopropylbenzene (Cumene) BRL ug/L m,p-Xylenes BRL ug/L Methyl Butyl Ketone (2-Hexanone) BRL ug/L Methyl Ethyl Ketone (2-Butanone) 36000 ug/L Methyl Isobutyl Ketone 3000 ug/L Methylene Chloride 72 ug/L Methyl-tert-Butyl Ether BRL ug/L Naphthalene BRL ug/L n-Butylbenzene BRL ug/L n-Propylbenzene BRL ug/L o-Xylene BRL ug/L sec-Butylbenzene BRL ug/L Styrene BRL ug/L tert-Butylbenzene BRL ug/L Tetrachloroethylene BRL ug/L Toluene 34 ug/L trans- 1,2-Dichloroethylene BRL ug/L trans- 1,3-Dichloropropylene BRL ug/L Trichloroethylene BRL ug/L Trichlorofluoromethane BRL ug/L Vinyl acetate BRL ug/L Vinyl chloride BRL ug/L 10 1.4 20 8260B 9/3/11 17:16 MGB P110061 10 1.3 20 B260B 9/3/11 17:16 MGB P110061 10 2.5 20 8260B 9/3111 17:16 MGB P110061 10 1.2 20 B260B 9/3/11 17:16 MGB P110061 20 5.4 20 B260B 9/3/11 17:16 MGB P110061 20 9.3 20 8260B 9/3/11 17:16 MGB P110061 100 28 20 8260B 9/3/11 17:16 MGB P110061 10 2.4 20 B260B 9/3/11 17:16 MGB P110061 10 1.2 20 8260B 9/3/11 17:16 MGB P110061 10 2.6 20 8260B 913111 17:16 MGB P110061 10 1.8 20 8260B 9/3/11 17:16 MGB P110061 10 2.2 20 8260B 913111 17:16 MGB P110061 10 1.5 20 8260B 9/3/11 17:16 MGB P110061 10 2.1 20 8260B 9/3/11 17:16 MGB P110061 10 6.0 20 8260B 9/3/11 17:16 MGB P110061 10 2.6 20 8260B 9/3/11 17:16 MGB P110061 20 2.1 20 8260B 9/3/11 17:16 MGB P110061 10 1.3 20 8260B 9/3/11 17:16 MGB P110061 40 7.3 20 8260B 9/3/11 17:16 MGB P110061 10 0.87 20 8260B 9/3/11 17:16 MGB P110061 10 1.4 20 8260B 9/3/11 17:16 MGB P110061 20 1.6 20 8260B 9/3/11 17:16 MGB P110061 100 3.8 20 8260E 9/3/11 17:16 MGB P110061 2000 360 400 8260B 916111 14:28 MGB P110061 1000 25 200 8260B 9/3111 17:42 MGB P110061 20 8.9 20 8260B 913111 17:16 MGB P110061 10 1.4 20 8260B 9/3/11 17:16 MGB P110061 20 2.0 20 8260B 9/3/11 1716 MGB P110061 20 2.3 20 8260B 9/3/11 17:16 MGB P110061 10 1.2 20 8260B 9/3/11 17:16 MGB P110061 10 0.92 20 8260B 9/3/11 17:16 MGB P110061 10 1.7 20 8260B 9/3/11 17:16 MGB P110061 10 0.94 20 8260B 9/3/11 17:16 MGB P110061 10 1.6 20 8260B 9/3/11 17:16 MGB P110061 10 1.4 20 8260B 9/3/11 1716 MGB P110061 10 0.85 20 8260B 913111 17:16 MGB P110061 10 2.3 20 8260B 9/3/11 17:16 MGB P110061 10 0.87 20 8260B 9/3/11 17:16 MGB P110061 10 1.1 20 8260B 9/3/11 17:16 MGB P110061 10 1.8 20 8260B 9/3/11 17:16 MGB P110061 40 2.0 20 8260B 9/3/11 17:16 MGB P110061 10 3.1 20 8260B 9/3/11 17:16 MGB P110061 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1.8001629-6364 - Fax: 7041525-0409 Page 10 of 37 %1RISM I Full -Service Analytical& Laboratory Report Environmental Solutions 09/15/2011 .ems,. �>r,waton,es Hc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1090044-03 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 08:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 109 % 75-129 Toluene-d8 100 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 11 of 37 ZPRISM Laboratory Report Full-Serwce Analytical & Environmental Solutions 09/15/2011 �R1. ue�aoniEs nc. Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1090044-04 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 09:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 1300 Aa ug/L 5.0 0.58 5 6020A 918/11 12:56 DWR P110062 Cadmium BRL Aa ug/L 5.0 1.0 5 6020A 9/8/11 12:56 DWR P110062 Chromium 2600 Aa ug/L 5.0 0.58 5 6020A 9/8111 12:56 DWR P110062 Copper 650 Aa ug/L 25 2.6 5 6020A 9/8111 12:56 DWR P110062 Lead 210 Aa ug/L 5.0 0.64 5 6020A 918/11 12:56 DWR P110062 Selenium 54 Aa ug/L 5.0 2.2 5 6020A 918111 12:56 DWR P110062 Zinc 190 Aa ug/L 50 2.9 5 6020A 9/8/11 12:56 DWR P110062 Anions by Ion Chromatography Chloride 86000 ug/L 10000 86 10 9056A 9/9111 20:21 CDE P110164 Sulfate 9200000 A ug/L 2000000 24000 2000 9056A 9114111 16:11 RSL P110189 Total Metals Mercury BRL ug/L 0.80 0.054 1 7470A 9/7/11 15A8 BGM P110099 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 20 5.9 40 8260B 9/3/11 18:10 MGB P110061 1,1,1-Trichloroethane BRL ug/L 20 2.5 40 8260B 9/3/11 18:10 MGB P110061 1,1,2,2-Tetrachloroethane BRL ug/L 20 2.9 40 8260B 9/3/11 18:10 MGB P110061 1,1,2-Trichloroethane BRL ug/L 20 6.6 40 8260B 9/3/11 18:10 MGB P110061 1,1-Dichloroethane BRL ug/L 20 3.8 40 8260B 9/3/11 18:10 MGB P110061 1,1-Dichloroethylene BRL ug/L 20 3.1 40 8260B 9/3/11 18:10 MGB P110061 1,1-Dichloropropylene BRL ug/L 20 2.5 40 8260B 9/3/11 18:10 MGB P110061 1,2,3-Trichlorobenzene BRL ug/L 80 8.0 40 8260B 9/3/11 18:10 MGB P110061 1,2,3-Trichloropropane BRL ug/L 40 3.2 40 8260B 9/3/11 1810 MGB P110061 1,2,4-Trichlorobenzene BRL ug/L 40 4.1 40 8260B 9/3/11 18:10 MGB P110061 1,2,4-Trimethylbenzene BRL ug/L 20 1.9 40 8260B 9/3/11 18:10 MGB P110061 1,2-Dibromo-3-chloropropane BRL ug/L 80 24 40 8260B 9/3/11 18:10 MGB P110061 1,2-Dibromoethane BRL ug/L 20 5.5 40 8260B 9/3/11 18:10 MGB P110061 1,2-Dichlorobenzene BRL ug/L 20 3.1 40 8260B 9/3/11 18:10 MGB P110061 1,2-Dichloroethane 34 ug/L 20 5.6 40 8260B 9/3111 18:10 MGB P110061 1,2-Dichloropropane BRL ug/L 20 5.1 40 8260B 9/3/11 18:10 MGB P110061 1,3,5-Trimethylbenzene BRL ug/L 20 2.3 40 82608 9/3/11 18:10 MGB P110061 1,3-Dichlorobenzene BRL ug/L 20 3.0 40 8260B 9/3/11 18:10 MGB P110061 1,3-Dichloropropane BRL ug/L 20 4.4 40 8260B 9/3/11 18:10 MGB P110061 1,4-Dichlorobenzene BRL ug/L 20 2.7 40 8260B 9/3/11 18:10 MGB PlID061 2,2-Dichloropropane BRL ug/L 80 4.6 40 8260B 9/3/11 18:10 MGB P110061 2-Chloroethyl Vinyl Ether BRL ug/L 80 9.0 40 8260B 9/3/11 18,10 MGB P110061 2-Chlorotoluene BRL ug/L 20 1.5 40 8260B 9/3/11 18:10 MGB P110061 4-Chlorotoluene BRL ug/L 20 2.1 40 8260B 9/3/11 18:10 MGB P110061 4-Isopropyltoluene BRL ug/L 20 2.6 40 8260B 9/3/11 18:10 MGB P110061 Acetone 9000 ug/L 2000 250 400 8260E 9/3/11 18:36 MGB P110061 Acrolein BRL ug/L 800 44 40 8260B 9/3/11 18:10 MGB P110061 Acrylonitrile BRL ug/L 800 34 40 8260E 9/3/11 18:10 MGB P110061 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 12 of 37 PRISMI Full -Service Analytical & Laboratory Report Environmental Solutions 09/15/2011 LABORAlON1ES �Nc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1090044-04 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 09:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Benzene 92 ug/L 20 2.9 40 8260B 913111 18:10 MGB P110061 Bromobenzene BRL ug/L 20 2.6 40 8260B 9/3/11 18:10 MGB P110061 Bromochloromethane BRL ug/L 20 5.0 40 8260B 9/3/11 18:10 MGB P110061 Bromodichloromethane BRL ug/L 20 2.5 40 8260B 9/3/11 18:10 MGB P110061 Bromoform BRL ug/L 40 11 40 8260B 9/3/11 18:10 MGB P110061 Bromomethane 190 ug/L 40 19 40 8260B 913/11 18:10 MGB P110061 Carbon disulfide BRL ug/L 200 55 40 8260B 9/3/11 18:10 MGB P110061 Carbon Tetrachloride BRL ug/L 20 4.7 40 8260B 9/3/11 18:10 MGB P110061 Chlorobenzene 44 ug/L 20 2.5 40 8260E 9/3111 18:10 MGB P110061 Chloroethane 560 ug/L 20 5.1 40 8260B 9l3/11 18:10 MGB P110061 Chloroform BRL ug/L 20 3.5 40 8260B 9/3/11 18:10 MGB P110061 Chloromethane 1600 ug/L 20 4.4 40 8260B 9/3/11 18:10 MGB P110061 cis-1,2-Dichloroethylene 46 ug/L 20 3.0 40 8260E 913111 18:10 MGB P110061 cis- 1,3-Dichloropropylene BRL ug/L 20 4.2 40 8260B 9/3/11 18:10 MGB P110061 Dibromochloromethane BRL ug/L 20 12 40 8260B 9/3/11 18:10 MGB P110061 Dibromomethane BRL ug/L 20 5.2 40 8260B 9/3/11 18:10 MGB P110061 Dichlorodifluoromethane BRL ug/L 40 4.3 40 8260B 9/3/11 18:10 MGB P110061 Ethylbenzene BRL ug/L 20 2.7 40 8260B 9/3/11 18:10 MGB P110061 Hexachlorobutadiene BRL ug/L 80 15 40 8260B 9/3/11 18:10 MGB P110061 Isopropyl Ether BRL ug/L 20 1.7 40 8260B 9/3/11 18:10 MGB P110061 Isopropylbenzene (Cumene) BRL ug/L 20 2.9 40 8260B 9/3111 18:10 MGB P110061 m,p-Xylenes BRL ug/L 40 3.2 40 8260B 9/3111 18:10 MGB P110061 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 200 7.6 40 8260E 9/3/11 18:10 MGB P110061 Methyl Ethyl Ketone (2-Butanone) 38000 ug/L 5000 900 1000 8260B 9/6111 14:02 MGB P110061 Methyl Isobutyl Ketone 2000 ug/L 200 5.0 40 8260E 9/3111 18:10 MGB P110061 Methylene Chloride 34 J ug/L 40 18 40 8260B 9/3111 18:10 MGB P110061 Methyl-tert-Butyl Ether BRL ug/L 20 2.8 40 8260B 9/3/11 18:10 MGB P110061 Naphthalene BRL ug/L 40 3.9 40 8260B 9/3/11 18:10 MGB P110061 n-Butylbenzene BRL ug/L 40 4.5 40 8260B 9/3/11 18:10 MGB P110061 n-Propylbenzene BRL ug/L 20 2.4 40 8260B 9/3/11 18:10 MGB P110061 o-Xylene BRL ug/L 20 1.8 40 82606 9/3/11 18:10 MGB P110061 sec-Butylbenzene BRL ug/L 20 3.5 40 8260B 9/3/11 18:10 MGB P110061 Styrene BRL ug/L 20 1.9 40 8260B 9/3/11 18:10 MGB P110061 tert-Butylbenzene BRL ug/L 20 3.2 40 8260B 9/3/11 18:10 MGB P110061 Tetrachloroethylene BRL ug/L 20 2.8 40 8260B 9/3/11 18:10 MGB P110061 Toluene 6900 ug/L 200 17 400 8260E 913/11 18:36 MGB P110061 trans- 1,2-Dichloroethylene BRL ug/L 20 4.6 40 8260B 9/3/11 18:10 MGB P110061 trans- 1,3-Dichloropropylene BRL ug/L 20 1.7 40 8260B 9/3/11 18:10 MGB P110061 Trichloroethylene BRL ug/L 20 2.2 40 8260B 9/3/11 18:10 MGB P110061 Trichlorofluoromethane BRL ug/L 20 3.5 40 8260B 9/3/11 18:10 MGB P110061 Vinyl acetate BRL ug/L 80 4.0 40 8260B 9/3/11 18:10 MGB P110061 Vinyl chloride BRL ug/L 20 6.2 40 8260B 9/3111 18:10 MGB P110061 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 13 of 37 ISM Laboratory Report Full -Service Analytical & /,..;,,IP.REnvironmental Solutions 09/15/2011 � .wewuowiEs nc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1090044-04 1410 Commwealth Drive Project No.: none Prism Work Order: 1090044 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 09/02/11 09:00 Time Submitted: 09/02/11 10:23 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 73 % 75-129 SR Toluene-d8 104 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 Full -Service Analytical & LMF� Environmental Solutions uDOHwtOwiES iMG Withers & Ravenel-Wilmington Project: Henson Landfill Attm Brian Bellis 1410 Commwealth Drive Project No: none Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110061 - 5030B Blank (P110061-BLK1) Prepared: 09/02/11 Analyzed: 09/03/11 1,1.1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Tiichooropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethylbenzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethylbenzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 2.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone 0.900 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis- 1,2-Dichloroethylene BRL 0.50 ug/L cis- 1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041526-0409 J Page 15 of 37 Full-S �P R I S M I Environmental Analytical 8 Environmental Solutions "uea+wlonIM me Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Project No: none Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110061 - 5030B Blank (P110061-BLK1) Prepared: 09/02/11 Analyzed: 09/03/11 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 60.7 ug/L 50.00 121 80-124 Surrogate: Dibromofluoromethane 62.1 ug/L 50.00 124 75-129 Surrogate: Toluene -dB 60.0 ug/L 50.00 120 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041525-0409 Page 16 of 37 I � j,'tR I `- M I Environmental Analytical s r J Environmental Solutions LAflONATORIES LNG Withers & Raven el -Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Project No: none Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110061 - 5030B LCS (P110061-BS1) Prepared: 09/02/11 Analyzed: 09/03/11 1,1-Dichloroethylene 20.7 0.50 ug/L 20.00 103 70-154 Benzene 22.3 0.50 ug/L 20.00 112 77-128 Chlorobenzene 22.7 0.50 ug/L 20.00 114 78-119 Toluene 22.5 0.50 ug/L 20.00 112 76-131 Trichloroethylene 25.5 0.50 ug/L 20.00 128 77-133 Surrogate:4-Bromofluorobenzene 51.8 ug/L 50.00 104 80-124 Surrogate: Dibromofluoromethane 53.4 ug/L 50.00 107 75-129 Surrogate: Toluene-d8 53.1 ug/L 50.00 106 77-123 LCS Dup (P110061-BSD1) Prepared: 09/02111 Analyzed: 09/03/11 1,1-Dichloroethylene 21.1 0.50 ug/L 20.00 105 70-154 2 200 Benzene 23.0 0.50 ug/L 20.00 115 77-128 3 200 Chlorobenzene 23.5 0.50 ug/L 20.00 117 78-119 3 200 Toluene 23.3 0.50 ug/L 20.00 117 76-131 4 200 Trichloroethylene 26.3 0.50 ug/L 20.00 131 77-133 3 200 Surrogate:4-Bromofluorobenzene 52.4 ug/L 50.00 105 80-124 Surrogate: Dibromofluoromethane 53.0 ug/L 50.00 106 75-129 Surrogate: Toluene-d8 53.5 ug/L 50.00 107 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/625-0409 Page 17 of r Full -Service Analytical PR I S M I Environmental Solutions � I.ea+•*oases — Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Total Metals - Quality Control Analyte Project: Henson Landfill Project No: none Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110099 - 7470A Blank (P110099-BLK1) Prepared: 09/06/11 Analyzed: 09/07/11 Mercury BRL 0.20 ug/L LCS (P110099-13S1) Prepared: 09/06/11 Analyzed: 09/07/11 Mercury 9.23 0.20 ug/L 9.375 98 80-120 Matrix Spike (P110099-MS1) Source: 1090044-01 Prepared: 09/06/11 Analyzed: 09/07/11 Mercury 9.31 0.20 ug/L 9.375 BRL 99 80-120 Matrix Spike Dup (P110099-MSD1) Source: 1090044-01 Prepared: 09/06/11 Analyzed: 09/07/11 Mercury 9.17 0.20 ug/L 9.375 BRL 98 80-120 1 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 18 of 37 /'P4R ISM I Environmental Analytical & Environmental Solutions �1. ueoanroaEx �.x: Level II QC Report 9/15/11 Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1090044 Attn: Brian Bellis Time Submitted: 9/2/2011 10:23:OOAM 1410 Commwealth Drive Project No: none Wilmington, NC 28411 3030C Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110062 - SM3030 C Blank (P110062-BLK1) Prepared: 09/02/11 Analyzed: 09/06/11 Arsenic BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 1.0 ug/L Zinc 1.26 10 ug/L J LCS (P110062-BS1) Prepared: 09/02/11 Analyzed: 09/06/11 Arsenic 257 1.0 ug/L 250.0 103 80-120 Cadmium 247 1.0 ug/L 250.0 99 80-120 Chromium 267 1.0 ug/L 250.0 107 80-120 Copper 253 5.0 ug/L 250.0 101 80-120 Lead 234 1.0 ug/L 250.0 94 80-120 Selenium 271 1.0 ug/L 250.0 108 80-120 Zinc 268 10 ug/L 250.0 107 80-120 Matrix Spike (P110062-MS1) Source: 1090044-03 Prepared: 09/02/11 Analyzed: 09/06/11 Arsenic 319 25 ug/L 250.0 68.1 100 75-125 Cadmium 262 25 ug/L 250.0 23.1 95 75-125 Chromium 316 25 ug/L 250.0 65.8 100 75-125 Copper 4090 120 ug/L 250.0 4060 14 75-125 MC Lead 244 25 ug/L 250.0 91.4 61 75-125 MI Selenium 336 25 ug/L 250.0 49.3 115 75-125 Zinc 2270 250 ug/L 250.0 2060 82 75-125 Matrix Spike Dup (P110062-MSD1) Source: 1090044-03 Prepared: 09/02/11 Analyzed: 09/06/11 Arsenic 312 25 ug/L 250.0 68.1 97 75-125 2 20 Cadmium 261 25 ug/L 250.0 23.1 95 75-125 0.3 20 Chromium 304 25 ug/L 250.0 65.8 95 75-125 4 20 Copper 4050 120 ug/L 250.0 4060 NR 75-125 1 20 MC Lead 248 25 ug/L 250.0 91.4 63 75-125 2 20 MI Selenium 331 25 ug/L 250.0 49.3 113 75-125 2 20 Zinc 2260 250 ug/L 250.0 2060 80 75-125 0.2 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/626-0409 Page 19 of 37 &P R I S M I Full -Service Analytical Environmental Solutions � usonn —s we Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Project No: none Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P110146 - NO PREP Blank (P110146-BLK1) Prepared & Analyzed: 09/07/11 Chloride BRL 1000 ug/L Sulfate BRL 1000 ug/L LCS (P110146-BSI) Prepared & Analyzed: 09/07/11 Chloride 1900 1000 ug/L 2000 95 80-120 Sulfate 1930 1000 ug/L 2000 96 80-120 Batch P110164 - NO PREP Blank (13110164-BLK1) Prepared & Analyzed: 09/09/11 Chloride BRL 1000 ug/L Sulfate BRL 1000 ug/L LCS (13110164-13SI) Prepared & Analyzed: 09/09/11 Chloride 1980 1000 ug/L 2000 99 80-120 Sulfate 1900 1000 ug/L 2000 95 80-120 Batch P110189 - NO PREP Blank (13110189-BLK1) Prepared & Analyzed: 09/14/11 Sulfate BRL 1000 ug/L LCS (P110189-BS1) Prepared & Analyzed: 09/14/11 Sulfate 2010 1000 ug/L 2000 101 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 7041525-0409 Page 20 of 37 I Fu117Servlce Analytical & Environmental solutions Ala-�ieonn�onies,lrc - Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Project No: none Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Level II QC Report 9/15/11 Prism Work Order: 1090044 Time Submitted: 9/2/2011 10:23:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch PI10210 - NO PREP Blank (13110210-BLK1) Prepared & Analyzed: 09/13/11 Chloride BRL 1000 ug/L LCS (P110210-BSI) Prepared & Analyzed: 09/13/11 Chloride 1960 1000 ug/L 2000 98 80-120 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final Date/Time 1090044-01 P110062 50 mL 50 mL 09/02/11 12:00 1090044-02 P110062 50 mL 50 mL 09/02/11 12:00 1090044-03 P110062 50 mL 50 mL 09/02/11 12:00 1090044-04 P110062 50 mL 50 mL 09/02/11 12:00 Prep Method: 7470A j Lab Number Batch Initial Final Date/Time 1090044-01 13110099 20 mL 30 mL 09/06/11 10:00 1090044-02 P110099 20 mL 30 mL 09/06/11 10:00 1090044-03 P110099 20 mL 30 mL 09/06/11 10:00 1090044-04 P110099 5 mL 30 mL 09/06/11 10:00 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 1090044-01 P110061 10 mL 10 mL 09/02/11 14:51 1090044-02 P110061 10 mL 10 mL 09/02/11 14:51 1090044-02 P110061 10 mL 10 mL 09/02/11 14:51 s 1090044-03 P110061 10 mL 10 mL 09/02/11 14:51 1090044-03 P110061 10 mL 10 mL 09/02/11 14:51 1090044-03 P110061 10 mL 10 mL 09/02/11 14:51 1090044-04 P110061 10 mL 10 mL 09/02/11 14:51 _J 1090044-04 P110061 10 mL 10 mL 09/02/11 14:51 1090044-04 P110061 10 mL 10 mL 09/02/11 14:51 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 1090044-01 TOC (Sub) 1090044-02 TOC (Sub) 1090044-03 TOC (Sub) — 1090044-04 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 - Phone: 7041529-6364 - Toll Free Number: 1-800/629.6364 - Fax: 7041525-0409 Page 21 of 37 rr MAR ISM I Full -Service Analytical & Environmental Solutions -tl"LABORATORIES, INQ 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Phone:704/529-6364 • Fax:704/625-0409 Client Company Name: tst-1:1,16AS q flAv�L Report To/Contact Name: Reporting Address: 1ul0 c�..,«v�uC/N�f►t d1MV� su►id xo% wtid►1/N6conl AlG U1103 CHAIN OF CUSTODY RECORD PAGE —1 OF QUOTE as TO ENSURE BILLING: Samples INTACT upon arrival? fN �PRROPERR Project Name: H�saN LNM r! GL- Received ON WET ICE? Temp U1 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) PROPER PRESERVATIVES indicated? *Please ATTACH any project specific reporting (QC LEVEL 1 II III IV) Received WITHIN HOLDING TIMES? provisions and/or QC Requirements CUSTODY SEALS INTACT? Invoice To: _ VOLATILES rec'd W/OUT HEADSPACE? PROPER CONTAINERS used? Address: YESy NO N/A co ✓ o N —_ N 0 o li Phone: 0110 - 7S6 -9ZiJkax (Yes) (Rb): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email (No) Email Address 6 &CU.65 )vti 4aP_�l F�eq(iested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC EDD Type: PDF Excel _Other "Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ Rush Work Must Be NOV-56,a i'mmi , Site Location Name: ' Pre -Approved Samples received after 15:00 will be processed next business day. SC OTHER N/A — Site Location Physical Address: 41IR V5 HWY 2,21 Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO-4-4 A1 C (SEE REVERSE FOR TERMS 8 CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES AO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- �p VNALYSES REOUESSTED PRISM SAMPLE DESCRIPTION COLLECTED MILITARY TIVES `4t °V-e�P4�-)REMARKS ,� LAB ID NO. NO. SIZE HOURS SLUDGE) SEE BELOW �� y t✓� PY -UA ozsBP T.11 0600 ulk(g12 c6 %N* 3 q011 i'LCZ -- - j v*A Q ► z b^% HfJ6 f S� tM3 bbww Voh 3 404 Hu. J 0 1 sooMt 0646 J _ cP 1 % o"I Norlg v Mrw� 70 fell 0300 W416A C& VbA_ 3 4 µ cP _ IUy.1 No sic M_Law Aw V 0A 40 �/ ctP l Soo oN ------- - - - Gt za , Alor165 f Sampler's Signature kl, -. Sampled By (Print Name) 13wA! Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished y: (Signature) Received By: (Signature) Date Military/Hours Comments: Site Arrival Time: Relinquished Received By: (signature) Date [Additional 116—IM.S %AIC.<VDC ; Site Departure Time: PA495N IC Field Tech Fee: Relinquished By: (Signature) Rec ' ed For Pris b ones By: Date ib CA-bA 1;U M 10Z3 Mileage: / GHI�p►lo� et oShipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SJALS FOR TRANSPORTATION TO THE LABORATORY. COC Group No. SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECRIVED AT THE LABORATORY. CbPTp J;k {} ❑ Fad Ex ❑ UPS 2r.,ndlwiverecl ❑ Prism Field Service j� ❑ Other " `r Li,-• rV NPDES: UST: G OUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: I'1�i►iL�S ' NC ❑SCI El NC ❑SCI 7NC ❑ SC I NC ❑ SC I U NC ❑ SC I ORIN ❑SCI NC ❑ SCI 00 NC ❑ SCI ❑O NC ❑ SC Wit. C I\IA o El o o nRlr_Inlel *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) Ile RAR I S M ( Full -Service Analytical Environmental Solutions -LABORATORIES II 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Phone: 704/529-6364 • Fax:704/525-0409 Client Company Name: W 11W5 k R Ay SAL Report To/Contact Name: (3iRvwJ AGLLAS Reporting Address: CHAIN OF CUSTODY RECORD PAGE 2nOF -'I— QUOTE # TO ENSURE PROPER BILLING: Project Name: HfiNs^t L.Awbff u, Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) *Please ATTACH any project specific reporting (QC LEVEL 1 11 III IV) provisions and/or QC Requirements Invoice To: Address: Samples INTACT upon arrival? O' Received ON WET ICE? Temp PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES rec'd W/OUT HEADSPACE? PROPER CONTAINERS used? r` YESS NO N/A M �C— O N a T Phone: 9I0*2"' yZ7% Fax (Yes) (No): purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email (Yes) (No) Email Address (S LIS 4e uested Due Date ❑ 1 Da O 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days q Y Y Y Y Y Certification: NELAC USACE FL lI h Work Must Be EDD Type: PDF_ Excel —Other "Working Days" ❑ 6-9 Days ❑ Standard 10 days ❑ Rush re Site Location Name: HP,�N S-y4 L/l�JrD�IU. y. Samples received after 15:00 will be processed next business day. SC_ OTHER N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NOZ' (SEE REVERSE FOR TERMS 8 CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) CLIENT DATE TIME COLLECTED MATRIX (SOIL, SAMPLE CONTAINER PRESERVA- D ANALYSES ��fiL REQUESTED cl PRISM SAMPLE DESCRIPTION COLLECTED MILITARY WATER OR TIVES oa��10v ��� REMARKS LAS ID NO. *TYPE NO. SIZE HOURS SLUDGE) SEE BELOW J njJ y AkW, a-l-WZotl G8o0 VKl Cr- VOA 3 4olI 1-- f --— �63 c-LP 1 2avMj �N6 , iwctrws 41fiILcw ft \Ich 3 k0,4 1-tU. J CAP SbAM1 A3606 -- -- CIP Nof,E ._- .------- - ---. _. -- •- '-Z ' ce 07iSG� �/1 o A0 Q1V UAr � Rom. W - -� --'-I `TOMI CP r 3 zsoM1 "I 5_0DM1 yea J ��7it>✓s 4�a(,ow ft \IlbA HCL - CY 1 Noda J C ' Z.SO,J Sampler's Signature Sampled By (Print Name) r, Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be PRISM USE ONLY submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. Relinquished B : (Signature) Received By: (Signature) Date Military/Hours Additional Comments: Site Arrival Time: Relinquished By: (Signature) Received By: (Signature) Date 3l t L Site Departure Time: A �M tUN� Field Tech Fee: Relinquished By: (Signature) Re ived For Pn boratories By: D�tt 9 10Z,3 CAtUA t'J^ Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTO EALS FOR TRANSPORTATION TO THE LABORATORY. COG Group No. C. r k SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. L&/lb Ar ❑ Fed Ex ❑ UPS H.nd•clellvered ❑ Prism Field Service O Other A""04 - NPDES: S GROUNDWATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: 5�l.�NWM SEI: REVERSE ', NS ❑ NC ❑ SC ❑ NC ❑ SC I Q(NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC (❑ NC ❑ SC n n ❑ ❑ n ❑ ❑ - ❑ ❑ Zlntf 11�I/�INI Ar *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ANALYTICAL REPORT CLIENT Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 ATTENTION Angie Overcash PROJECTID 1090044 LABORATORY REPORT NUMBER 211090616 DATE 09/09/2011 Primary Data Review By Int ign Curtis Ekker Data Validation Manager, GCAL Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 GSRI Avenue, Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Page 24 of 37 i NELAP CERTIFICATE NUMBER 01955 DOD FLAP CERTIFICATE NUMBER ADE -1482 ANALYTICAL RESULTS PERFORMED BY GULF COAST ANALYTICAL LABORATORIES, INC. 7979 GSRI Avenue Baton Rouge, LA 70820 Report Date 09/09/2011 Deliver To Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 706-529-6364 Attn Angie Overcash Project 1090044 i Page 25 of 37 CASE NARRATIVE Client: Prism Laboratories, Inc. Report: 211090616 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the sample cross-reference page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. CONVENTIONALS In the SM 5310B analysis, samples 21109061603 (MW-3) and 21109061604 (MW-2) had to be diluted in order to bracket the Total Carbon and/or Total Inorganic Carbon concentrations within the calibration range of the instrument. The Total Organic Carbon is based on the difference between the Total Carbon and the Inorganic Carbon. The dilution is reflected in the elevated reporting limit. 7757 Page 26 of 37 . Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations Utilized in this Report ND Indicates the result was Not Detected at the specified RDL DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field PQL Practical Quantitation Limit MDL Method Detection Limit RDL Reporting Detection Limit 00:00 Reported as a time equivalent to 12:00 AM Reporting Flags Utilized in this Report J Indicates an estimated value U Indicates the compound was analyzed for but not detected B (ORGANICS) Indicates the analyte was detected in the associated Method Blank B (INORGANICS) Indicates the result is between the RDL and MDL Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with the NELAC standard and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer -readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Inte Robyn Migues Technical Director GCAL REPORT 21109061ilnt riS - THIS REPORT CONTAINS PAGES. Page 27 of 37 Report Sample Summary GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21109061601 MW-20A Water 09/02/201106:00 09/03/201109:45 - 21109061602 MW-20 Water 09102/201107:00 09/03/201109:45 _ 21109061603 MW-3 Water 09/02/201108:00 09/03/201109:45 21109061604 MW-2 Water 09/02/201109:00 09/03/201109:45 GCAL Report 211090616 Page 28 of 37 Summary of Compounds Detected GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21109061601 MW-20A Water 091021201106:00 09/03/201109:45 SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 4.3 1.0 0.20 mg/L GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21109061602. MW-20 — Water 09/02/2011 07:00 09/03/2011 09:45 SM 5310B TOC CAS# Parameter C-012 Total Organic Carbon Result RDL MDL Units 32.9 1.0 0.20 mg/L GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21109061603 MW-3 Water 09/021201108:00 09103/201109:45 SM 5310B TOC CAS# Parameter C-012 Total Organic Carbon Result RDL MOL Units 520 20.0 4.1 mg/L GCAL ID Client ID Matrix Collect Date(Time Receive Date/Time 21109061604 MW 2 Water 09/02/2011 09:00 09/03/2011 09:45 SM 5310B TOC CAS# Parameter C-012 Total Organic Carbon GCAL Report 211090616 Result RDL MDL Units 168 5.0 1.0 mg/L Page 29 of 37 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 09/06/201119:11 AEL 464769 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 4.3 1.0 0.20 mg/L GCAL Report 211090616 Page 30 of 37 GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21109061602 MW-20 Water 09/02/201107:00 09/03/201109:45 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 09/06/201119:35 AEL 464769 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211090616 Result RDL MDL Units 32.9 1.0 0.20 mg/L Page 31 of 37 GCALID Client ID Matrix Collect Date/Time Receive Date/Time 21109061603 MW-3 Water 09/02/201108:00 09103/201109:45 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 20 09/07/201111:41 AEL 464769 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211090616 Result RDL 520 20.0 MDL Units 4.1 mg/L Page 32 of 37 10B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 5 09/07/201112:05 AEL 464769 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211090616 Result RDL MDL Units 168 5.0 1.0 mgtL General Chemistry Quality Control Summary Analytical Batch 464769 Client ID MB464769 LCS464769 LCSD464769 Prep Batch N/A GCAL ID 985171 985172 985173 Sample Type Method Blank LCS LCSD Analytical Date 09/06/2011 12:40 09/06/2011 14:12 09/06/2011 14:36 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result "�a RPD Limit Result RDL Added % R Limits % R R RPD C-012 Total Organic Carbon 0.20U 0.20 50.01 49.8 100 80 - 120 49.9 100 0.2 1 25 Analytical Batch 464769 ClientlD U31EPAC 985154MS 985154MSD Prep Batch N/A GCAL ID 21109062402 985174 985175 Sample Type SAMPLE MS MSD Analytical Date 09/06/2011 13:01 09/06/2011 13:27 09/06/2011 13:48 Matrix Water Water Water SM 5310E TOC Units mg/L Spike Result % R Control I Limits % R Result % R RPD RPD I Limit Result RDL Added C-012 Total Organic Carbon 8.1 0.20 50.0 60.0 104 75 - 1251 1 25 N c= GCAL Report 211090616 CD w .A 0 W SUBCONTRACT ORDER Prism Laboratories, Inc. 1090044 SENDING LABORATORY: RECEIMG LABORATORY: Prism Laboratories, Inc. Gulf Coast Analytical Labs, Inc. P. O. Box 240543 7979 GSRI Avenue Charlotte, NC 28224-0543 Baton Rouge, LA 70820 Phone: 800-529-6364 Phone :(225) 769-4900 Fax:704-525-0409 Fax: (225) 767-5717 Project Manager: Angela D. Overcash Analysis Due Expires Laboratory 1D Comments Sample ID: 1090044-01 Water Sampled:09/02/1106:00 TOC (Sub) 09/30/11 06:00 Containers Supplied: Z x g U m t PAI M V(7A g e,L Sample ID: 1090044-02 TOC (Sub) Containers Supplied: Water Sampled:09102/1107:00 09/30/11 07:00 Sample ID: 1090044-03 1 Water Sampled:09/02/1108:00 TOC (Sub) 09/30/11 08:00 Containers Supplied. Sample ID: 1090044-04 + Water Sampled:09/02/1109:00 TOC (Sub) 09/30/I 1 09:00 Containers Supplied: 'L .2, q 17gl7zl 8/50 17s"io -r- �. . Login Checklist Page 1 of 1 QCALEU BEN L SAMPLE RECEIVING CHECKLIST Workorder: 211090616 Client 4565 - Access Analytical Profile: 80251 - Prism Lab Line Item: 1- Water BTEX/Naah/MTBE Received by: Saucier. Charlotte Received Datetrime: 9/3/2011 9:45:00 AM Samples Received via: FEDEX Number of Coolers Received: 'u57/0 Cooler trackingnumbers(s): J, /7 Cooler temperature(s): Were all coolers received at a temperature of 0 - 60 C? r Yes r No F N/A Were all custody seals Intact? )✓ Yes F No F WA Were all samples received in proper containers? Yes l" No NIA Were all samples properly preserved? F* Yes r No r NIA Was preservative added to any container at the lab? r Yes r No r NIA Were all containers received in good condition? )✓ Yes r No r WA Were all VOA vials received with no head space? (✓ Yes r No r WA Do all sample labels match the Chain of Custody? r Yes F No r WA Was the client notified about any discrepancies? r— Yes F No r WA Notes/Comments: http://webserverl/REX/Secure/LoginChecklist.aspx I 9/6/2011 Page 36 of 37 SENDING LABORATORY: Prism Laboratories, Inc. P. O. Box 240543 Charlotte, NC 28224-0543 Phone: 800-529-6364 Fax: 704-525-0409 Project Manager: Angela D. SUBCONTRACT ORDER Prism Laboratories, Inc. 1090044 RECEIVING LABORATORY: Gulf Coast Analytical Labs, Inc. 7979 GSRI Avenue Baton Rouge, LA 70820 Phone :(225) 769-4900 Fax: (225) 767-5717 Analysis Due' Expires Laboratory ID Comments Sample ID :1090044-01 Wa r Sampled:09/02/1106:00 TOC (Sub) 09/30/1106:00 Containers Supplied: 2 X U P AU It- Vc?A Sample ID: 1090044-02 Wat r Sampled:09/02/1107:00 TOC (Sub) 09/30/11 07:00 Containers Supplied: Sample ID: 1090044-03 WO TOC (Sub) Containers Supplied: Sample ID: 1090044-04 TOC (Sub) Containers Supplied: Sa m pled:09/02/11 08:00 09/30/ 11 08:00 Sampled:09/02/11 09:00 09/30/11 09:00 Fell) EY Eb 6X A By Date Received By G (A Page 37 of 37 n C n Full -Service Analytical Environmental Environmental Solutions �ABOgATORIES INC. Withers & Ravenel-Wilmington Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cent No. 37735 Project: Henson Landfill Lab Submittal Date: 10/07/2011 Prism Work Order: 1100199 Case Narrative 10/18/2011 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. r��'J VP Laboratory Services Data Qualifiers Key Reference: Reviewed By A LCS recovery is outside the control limits. Sample results might have high bias. Aa Sample batch run without ending LLCCV due to instrument malfunction. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). MC Sample concentration too high for recovery evaluation. MI Matrix spike outside of the control limits. Matrix interference suspected. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 1 of 36 /'PRISM I Fullironmee Analytical s Environmental Solutions .�i lAaO1UTOw�E3, iwG Sample Receipt Summary 10/18/2011 Prism Work Order: 1100199 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW-20A 1100199-01 Water 10/07/11 10/07/11 MW-20 1100199-02 Water 10/07/11 10/07/11 MW-3 1100199-03 Water 10/07/11 10/07/11 MW-2 1100199-04 Water 10/07/11 10/07/11 Samples received in good condition at 5.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 2 of 36 /`P R I S M I Full -Service Analytical 8 Environmental Solutions �. usonnroaiea �Hc Summary of Detections 10/18/2011 Prism Work Order: 1100199 Prism ID Client ID Parameter Method Result Units 1100199-01 MW-20A Arsenic 6020A 1.7 Aa ug/L 1100199-01 MW-20A Chromium 6020A 2.7 Aa ug/L 1100199-01 MW-20A Copper 6020A 2.2 Aa, J ug/L 1100199-01 MW-20A Lead 6020A 0.83 Aa, J ug/L 1100199-01 MW-20A Zinc 6020A 22 Aa ug/L 1100199-01 MW-20A Chloride '9056A 1.6 mg/L 1100199-01 MW-20A Sulfate '9056A 30 mg/L 1100199-02 MW-20 Arsenic 6020A 35 Aa ug/L 1100199-02 MW-20 Chromium 6020A 2.1 Aa ug/L 1100199-02 MW-20 Copper 6020A 4.0 Aa, J ug/L 1100199-02 MW-20 Lead 6020A 0.76 Aa, J ug/L 1100199-02 MW-20 Selenium 6020A 1.4 Aa ug/L 1100199-02 MW-20 Zinc 6020A 20 Aa ug/L 1100199-02 MW-20 Chloride '9056A 49 mg/L 1100199-02 MW-20 Sulfate '9056A 2.4 mg/L 1100199-02 MW-20 Benzene 8260E 21 ug/L 1100199-02 MW-20 Chlorobenzene 82606 67 ug/L 1100199-02 MW-20 cis-1,2-Dichloroethylene 8260B 56 ug/L 1100199-02 MW-20 m,p-Xylenes 8260E 14 J ug/L 1100199-02 MW-20 Toluene 8260E 800 ug/L 1100199-03 MW-3 Arsenic 6010C 0.058 mg/L 1100199-03 MW-3 Cadmium 6010C 0.0037 mg/L 1100199-03 MW-3 Chromium 6010C 0.021 mg/L 1100199-03 MW-3 Copper 6010C 2.0 mg/L 1100199-03 MW-3 Lead 6010C 0.029 mg/L 1100199-03 MW-3 Selenium 6010C 0.049 A mg/L 1100199-03 MW-3 Zinc 6010C 1.3 mg/L 1100199-03 MW-3 Chloride '9056A 89 mg/L 1100199-03 MW-3 Sulfate '9056A 5700 mg/L 1100199-03 MW-3 1,1-Dichloroethane 8260E 21 ug/L 1100199-03 MW-3 1,2-Dichloroethane 8260B 110 ug/L 1100199-03 MW-3 Acetone 8260E 7600 ug/L 1100199-03 MW-3 Benzene 8260B 32 ug/L 1100199-03 MW-3 Bromochloromethane 8260E 18 ug/L 1100199-03 MW-3 Bromomethane 8260E 150 ug/L 1100199-03 MW-3 Chlorobenzene 8260E 52 ug/L 1100199-03 MW-3 Chloroethane 8260E 690 ug/L 1100199-03 MW-3 Chloromethane 8260E 3000 ug/L 1100199-03 MW-3 cis- 1,2-Dichloroethylene 8260E 120 ug/L 1100199-03 MW-3 Methyl Ethyl Ketone (2-Butanone) 8260B 96000 ug/L 1100199-03 MW-3 Methyl Isobutyl Ketone 8260B 11000 ug/L 1100199-03 MW-3 Methylene Chloride 8260E 68 ug/L 1100199-03 MW-3 Toluene 8260E 11000 ug/L 1100199-04 MW-2 Arsenic 6010C 0.067 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 3 of 36 m P R ISM I Full -Service al Solutions 8 �^ Environmental Solutions � ueoanr —% 1— Summary of Detections 10/18/2011 Prism Work Order: 1100199 Prism ID Client ID Parameter Method Result Units 1100199-04 MW-2 Cadmium 601CC 0.016 mg/L 1100199-04 MW-2 Chromium 601CC 0.16 mg/L 1100199-04 MW-2 Copper 6010C 1.4 mg/L 1100199-04 MW-2 Lead 6010C 0.19 mg/L 1100199-04 MW-2 Selenium 6010C 0.050 A mg/L 1100199-04 MW-2 Zinc 6010C 6.0 mg/L 1100199-04 MW-2 Chloride '9056A 120 mg/L 1100199-04 MW-2 Sulfate `9056A 14000 mg/L 1100199-04 MW-2 1,1-Dichloroethane 8260E 22 ug/L 1100199-04 MW-2 1,2-Dichloroethane 82606 63 ug/L 1100199-04 MW-2 Acetone 8260E 10000 ug/L 1100199-04 MW-2 Benzene 8260E 40 ug/L 1100199-04 MW-2 Bromomethane 8260E 530 ug/L 1100199-04 MW-2 Chlorobenzene 8260B 20 ug/L 1100199-04 MW-2 Chloroethane 8260E 2300 ug/L 1100199-04 MW-2 Chloromethane 8260E 6700 ug/L 1100199-04 MW-2 Methyl Butyl Ketone (2-Hexanone) 8260E 20 1 ug/L 1100199-04 MW-2 Methyl Ethyl Ketone (2-Butanone) 8260E 170000 ug/L 1100199-04 MW-2 Methyl Isobutyl Ketone 8260E 5700 ug/L 1100199-04 MW-2 Methylene Chloride 8260B 58 ug/L 1100199-04 MW-2 Toluene 8260E 1900 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525.0409 Page 4 of 36 Laboratory Report Full -Service Analytical 8 /PRISM Environmental Solutions 10/18/2011 �3li+. unuA c Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1100199-01 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 06:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Daterrime ID 3030C Metals Arsenic 1.7 Aa ug/L 1.0 0.12 1 6020A 10/13111 15:42 DWR P1J0147 Cadmium BRL Aa ug/L 1.0 0.20 1 6020A 10/13/11 15:42 DWR PlJO147 Chromium 2.7 Aa ug/L 1.0 0.12 1 6020A 10/13/11 15:42 DWR PlJO147 Copper 2.2 Aa, J ug/L 5.0 0.53 1 6020A 10/13111 15:42 DWR P1J0147 Lead 0.83 Aa, J ug/L 1.0 0.13 1 6020A 10/13111 15:42 DWR PlJO147 Selenium BRL Aa ug/L 1.0 0.44 1 6020A 10/13/11 15:42 DWR PlJO147 Zinc 22 Aa ug/L 10 0.68 1 6020A 10/13111 15:42 DWR P1J0147 Anions by Ion Chromatography Chloride 1.6 mg/L 1.0 0.0050 1 *9056A 10/11/11 19:57 cde PlJ0247 Sulfate 30 mglL 10 0.039 10 *9056A 10/11/11 20:14 cde PlJ0247 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 10/12/11 12:19 BGM PlJO190 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.15 1 82608 10/12/11 20:56 MGB P1J0218 1.1,1-Trichloroethane BRL ug/L 0.50 0.063 1 8260B 10/12/11 20:56 MGB P1J0218 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.071 1 8260B 10/12/11 20:56 MGB P1J0218 1,1,2-Trichloroethane BRL ug/L 0.50 0.17 1 8260B 10/12/11 20:56 MGB P1J0218 1,1-Dichloroethane BRL ug/L 0.50 0.096 1 8260B 10/12/11 20:56 MGB P1J0218 1,1-Dichloroethylene BRL ug/L 0.50 0.078 1 8260B 10/12/11 20:56 MGB P1J0218 1,1-Dichloropropylene BRL ug/L 0.50 0.061 1 8260B 10/12/11 20:56 MGB P1J0218 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.20 1 8260B 10/12/11 20:56 MGB P1J0218 1,2,3-Trichooropropane BRL ug/L 1.0 0.081 1 8260B 10/12/11 2056 MGB P1J0218 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.10 1 8260B 10/12/11 2056 MGB P1J0218 1,2,4-Trimethylbenzene BRL ug/L 0.50 0.048 1 8260B 10/12/11 20:56 MGB P1J0218 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.59 1 8260B 10/12/11 20i56 MGB P1J0218 1,2-Dibromoethane BRL ug/L 0.50 0.14 1 8260B 10/12/11 20:56 MGB P1J0218 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 10/12/11 20:56 MGB P1J0218 1,2-Dichloroethane BRL ug/L 0.50 0.14 1 8260B 10/12/11 20:56 MGB P1J0218 1,2-Dichloropropane BRL ug/L 0.50 0.13 1 8260B 10/12/11 20:56 MGB P1J0218 1,3,5-Trimethylbenzene BRL ug/L 0.50 0.057 1 8260B 10/12/11 2056 MGB PIJ0218 1,3-Dichlorobenzene BRL ug/L 0.50 0.074 1 8260B 10/12/11 20:56 MGB P1J0218 1,3-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 10/12/11 20:56 MGB P1J0218 1,4-Dichlorobenzene BRL ug/L 0.50 0.068 1 8260B 10/12/11 20:56 MGB P1J0218 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 10/12/11 20:56 MGB P1J0218 2-Chloroethyl Vinyl Ether BRL ug/L 2.0 0.22 1 8260B 10/12/11 20:56 MGB P1J0218 2-Chlorotoluene BRL ug/L 0.50 0.038 1 8260B 10/12/11 20:56 MGB P1J0218 4-Chlorotoluene BRL ug/L 0.50 0.053 1 8260B 10/12/11 20:56 MGB P1J0218 4-Isopropyltoluene BRL ug/L 0.50 0.065 1 8260B 10/12/11 20:56 MGB PIJ0218 Acetone BRL ug/L 5.0 0.62 1 8260B 10/12/11 20:56 MGB P1J0218 Acrolein BRL ug/L 20 1.1 1 8260B 10/12/11 20:56 MGB P1J0218 Acrylonitrile BRL ug/L 20 0.86 1 8260B 10/12/11 20:56 MGB P1J0218 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 5 Of 36 I `- n � ( Full -Service Analytical /vz,rPAR J'v' Environmental Solutions LABOHRTg1�E5 ANC Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Sample Matrix: Water Laboratory Report 10118/2011 Client Sample ID: MW-20A Prism Sample ID: 1100199-01 Prism Work Order: 1100199 Time Collected: 10/07/11 06:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene BRL ug/L Bromobenzene BRL ug/L Bromochloromethane BRL ug/L Bromodichloromethane BRL ug/L Bromoforrn BRL ug/L Bromomethane BRL ug/L Carbon disulfide BRL ug/L Carbon Tetrachloride BRL ug/L Chlorobenzene BRL ug/L Chloroethane BRL ug/L Chloroform BRL ug/L Chloromethane BRL ug/L cis-1,2-Dichloroethylene BRL ug/L cis-1,3-Dichloropropylene BRL ug/L Dibromochloromethane BRL ug/L Dibromomethane BRL ug/L Dichlorodifluoromethane BRL ug/L Ethylbenzene BRL ug/L Hexachlorobutadiene BRL ug/L Isopropyl Ether BRL ug/L Isopropylbenzene (Cumene) BRL ug/L m,p-Xylenes BRL ug/L Methyl Butyl Ketone (2-Hexanone) BRL ug/L Methyl Ethyl Ketone (2-Butanone) BRL ug/L Methyl Isobutyl Ketone BRL ug/L Methylene Chloride BRL ug/L Methyl-tert-Butyl Ether BRL ug/L Naphthalene BRL ug/L n-Butylbenzene BRL ug/L n-Propylbenzene BRL ug/L o-Xylene BRL ug/L sec-Butylbenzene BRL ug/L Styrene BRL ug/L tert-Burylbenzene BRL ug/L Tetrachloroethylene BRL ug/L Toluene BRL ug/L trans-1,2-Dichloroethylene BRL ug/L trans-1,3-Dichloropropylene BRL ug/L Trichloroethylene BRL ug/L Trichlorofluoromethane BRL ug/L Vinyl acetate BRL ug/L Vinyl chloride BRL ug/L 0.50 0.072 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.064 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.13 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.062 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.27 1 8260B 10/12/11 20:56 MGB PlJ0218 1.0 0.47 1 8260B 10/12/11 20:56 MGB PlJ0218 5.0 1.4 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.12 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.061 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.13 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.089 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.11 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.076 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.10 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.30 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.13 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.11 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.067 1 8260B 10/12/11 20:56 MGB P1J0218 2.0 0.36 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.043 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.072 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.081 1 8260B 10/12/11 20:56 MGB P1J0218 5.0 0.19 1 8260B 10/12/11 20:56 MGB P1J0218 5.0 0.90 1 8260B 10/12/11 20:56 MGB P1J0218 5.0 0.12 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.44 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.070 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.098 1 8260B 10/12/11 20:56 MGB P1J0218 1.0 0.11 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.060 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.046 1 8260B 10/12/11 20:56 MGB PIJ0218 0.50 0.087 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.047 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.080 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.069 1 8260B 10/12/11 20:56 MGB PIJ0218 0.50 0.042 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.12 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.043 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.054 1 8260B 10/12/11 20:56 MGB P1J0218 0.50 0.088 1 8260B 10/12/11 20:56 MGB PlJ0218 2.0 0.10 1 8260B 10/12/11 20:56 MGB PlJ0218 0.50 0.16 1 8260B 10/12/11 20:56 MGB PlJ0218 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 7041525-0409 Page 6 of 36 P R I S M I Funiro mAnalytical s Environmenen tal Solutions 1 L�eORInOR�E3 — Laboratory Report 10/18/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1100199-01 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 06:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 107 % 80-124 Dibromofluoromethane 106 % 75-129 Toluene-d8 107 % 77-123 This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 7 of 36 %PRISM Full -Service Analytical & Laboratory Report Environmental Solutions 10/18/2011 LAPORATON,ES INL Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1100199-02 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 07:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Daterrime ID 3030C Metals Arsenic 35 Aa ug/L 1.0 0.12 1 6020A 10113/11 15:33 DWR PlJO147 Cadmium BRL Aa ug/L 1.0 0.20 1 6020A 10/13/11 15:33 DWR P1J0147 Chromium 2.1 Aa ug/L 1.0 0.12 1 6020A 10113/11 15:33 DWR P1J0147 Copper 4.0 Aa, J ug/L 5.0 0.53 1 6020A 10113/11 15:33 DWR P1J0147 Lead 0.76 Aa, J ug/L 1.0 0.13 1 6020A 10/13111 15:33 DWR PlJO147 Selenium 1.4 Aa ug/L 1.0 0.44 1 6020A 10/13/11 15:33 DWR PlJO147 Zinc 20 Aa ug/L 10 0.58 1 6020A 10/13/11 15:33 DWR PlJO147 Anions by Ion Chromatography Chloride 49 mg/L 10 0.050 10 `9056A 10/11/11 20:49 cde P1J0247 Sulfate 2.4 mg/L 1.0 0.0039 1 '9056A 10/11/11 20:32 cde P1J0247 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL mg/L 0.00020 0.000014 1 7470A 10/12/11 12:30 BGM PlJO190 1, 1, 1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 10/12/11 22:15 MGB P1J0218 1.1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 10/12/11 22:15 MGB P1J0218 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 10/12/11 22:15 MGB PlJ0218 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 10/12/11 22:15 MGB P1J0218 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 10/12/11 22:15 MGB P1J0218 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 10/12/11 22:15 MGB PlJ0218 1, 1 -Dichloropropylene BRL ug/L 10 1.2 20 8260B 10/12/11 22:15 MGB P1J0218 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 10/12/11 22:15 MGB PlJ0218 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 10/12/11 22:15 MGB P1J0218 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 10/12/11 22:15 MGB P1J0218 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 10/12/11 22:15 MGB P1J0218 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 10/12/11 22:15 MGB P1J0218 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 10/12/11 22:15 MGB P1J0218 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 10/12/11 22:15 MGB P1J0218 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 10/12/11 22:15 MGB PIJ0218 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 10/12/11 22:15 MGB PlJC218 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 10/12/11 22:15 MGB PlJ0218 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 10/12/11 22:15 MGB PIJ0218 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 10/12/11 22:15 MGB P1J0218 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 10/12/11 22:15 MGB P1J0218 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 10/12/11 22:15 MGB PIJ0218 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 10/12/11 22A5 MGB P1J0218 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 10/12/11 22:15 MGB PlJ0218 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 10/12/11 22:15 MGB PlJ0218 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 10/12/11 22:15 MGB PlJ0218 Acetone BRL ug/L 100 12 20 8260B 10/12/11 22:15 MGB P1J0218 Acrolein BRL ug/L 400 22 20 8260E 10/12/11 22:15 MGB P1J0218 Acrylonitrile BRL ug/L 400 17 20 8260B 10/12/11 22:15 MGB P1J0218 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 8 of 36 Full -Service Analytical 8 PRISM Environmental Solutions LAB011gTOelES ANC. Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Sample Matrix: Water Laboratory Report 10/18/2011 Client Sample ID: MW-20 Prism Sample ID: 1100199-02 Prism Work Order: 1100199 Time Collected: 10/07/11 07:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene 21 ug/L 10 1.4 20 8260B 10/12111 22:15 MGB PlJ0218 Bromobenzene BRL ug/L 10 1.3 20 8260B 10/12/11 22:15 MGB PlJ0218 Bromochloromethane BRL ug/L 10 2.5 20 8260B 10/12/11 22:15 MGB PlJ0218 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 10/12/11 2215 MGB PlJ0218 Bromoform BRL ug/L 20 5.4 20 8260B 10/12/11 22:15 MGB PlJ0218 Bromomethane BRL ug/L 20 9.3 20 8260B 10/12/11 22:15 MGB PlJ0218 Carbon disulfide BRL ug/L 100 28 20 8260E 10/12/11 22:15 MGB PlJ0218 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 10/12/11 22:15 MGB PlJ0218 Chlorobenzene 67 ug/L 10 1.2 20 8260E 10/12111 22:15 MGB PlJ0218 Chloroethane BRL ug/L 10 2.6 20 82606 10/12/11 22:15 MGB PlJ0218 Chloroform BRL ug/L 10 1.8 20 8260B 10/12/11 22:15 MGB P1J0218 Chloromethane BRL ug/L 10 2.2 20 8260B 10/12/11 22:15 MGB PlJ0218 cis-1,2-Dichloroethylene 56 ug/L 10 1.6 20 8260E 10112/11 22:15 MGB P1J0218 cis-1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 10/12/11 22:15 MGB PlJ0218 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 10/12/11 2215 MGB PlJ0218 Dibromomethane BRL ug/L 10 2.6 20 8260B 10/12/11 22:15 MGB PlJ0218 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 10/12/11 22:15 MGB PlJ0218 Ethylbenzene BRL ug/L 10 1.3 20 8260B 10/12/11 22:15 MGB PlJ0218 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 10/12/11 22:15 MGB PlJ0218 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 10/12/11 22:15 MGB PlJ0218 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 10/12/11 22:15 MGB PlJ0218 m,p-Xylenes 14 J ug/L 20 1.6 20 8260B 10/12111 22:15 MGB PIJ0218 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260E 10/12/11 22:15 MGB PlJ0218 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 100 18 20 8260E 10/12/11 22:15 MGB P1J0218 Methyl Isobutyl Ketone BRL ug/L 100 2.5 20 8260E 10/12/11 22:15 MGB PlJ0218 Methylene Chloride BRL ug/L 20 8.9 20 8260B 10/12/11 22:15 MGB PlJ0218 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 10/12/11 22:15 MGB PlJ0218 Naphthalene BRL ug/L 20 2.0 20 8260B 10/12/11 22:15 MGB PlJ0218 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 10/12/11 22:15 MGB PlJ0218 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 10/12/11 22:15 MGB PlJ0218 o-Xylene BRL ug/L 10 0.92 20 8260B 10/12/11 22:15 MGB PlJ0218 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 10/12/11 22:15 MGB PlJ0218 Styrene BRL ug/L 10 0.94 20 8260B 10/12/11 22:15 MGB PlJ0218 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 10/12/11 22:15 MGB PlJ0218 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 10/12/11 22:15 MGB P1J0218 Toluene 800 ug/L 10 0.85 20 8260B 10/12/11 22:15 MGB P1J0218 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 10/12/11 22:15 MGB PlJ0218 trans-1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 10/12/11 22:15 MGB PlJ0218 Trichloroethylene BRL ug/L 10 1.1 20 8260B 10/12/11 22:15 MGB PlJ0218 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 10/12/11 2215 MGB PlJ0218 Vinyl acetate BRL ug/L 40 2.0 20 8260B 10/12/11 22:15 MGB PlJ0218 Vinyl chloride BRL ug/L 10 3.1 20 8260B 10/12/11 22:15 MGB PlJ0218 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 9 of 36 I S M IFu0-Service Analytical&Laboratory Report Environmental Solutions 10/18/2011 ZPR �- iwmnntomEs me Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1100199-02 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 07:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 105 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 10 of 36 P R I S M Full -Service Analytical & Laboratory Report Environmental Solutions 10/18/2011 ueonatwies me Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1100199-03 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 08:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 0.058 mg/L 0.010 0.0018 1 6010C 10110/11 12:22 LTB PlJ0271 Cadmium 0.0037 mg/L 0.0010 0.00017 1 6010C 10/10/11 12:22 LTB PlJ0271 Chromium 0.021 mg/L 0.0050 0.00070 1 6010C 10/10/11 12:22 LTB P1J0271 Copper 2.0 mg/L 0.010 0.00022 1 6010C 10/10/11 12:22 LTB PlJ0271 Lead 0.029 mg/L 0.0050 0.00073 1 6010C 10/10/11 12:22 LTB PlJ0271 Selenium 0.049 A mg/L 0.020 0.0035 1 6010C 10/10/11 12:22 LTB PlJ0271 Zinc 1.3 mg/L 0.030 0.027 1 6010C 10/10/11 12:22 LTB PlJ0271 Anions by Ion Chromatography Chloride 89 mg/L 10 0.050 10 *9056A 10/11/11 21:24 cde PlJC247 Sulfate 6700 mg/L 1000 3.9 1000 *9056A 10/14111 18:31 cde P1J0297 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL mg/L 0.00020 0.000014 1 7470A 10/12/11 12:34 BGM PlJO190 1, 1, 1, 2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 10/12/11 23:08 MGB P1J0218 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 10/12/11 23:08 MGB P1J0218 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 10/12/11 23:08 MGB P1J0218 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 10/12/11 23:08 MGB PlJ0218 1,1-Dichloroethane 21 ug/L 10 1.9 20 8260B 10/12/11 23:08 MGB PlJ0218 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 10/12/11 23:08 MGB P1J0218 1,1-Dichloropropylene BRL ug/L 10 1.2 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 10/12/11 23:08 MGB PIJ0218 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 10/12/11 23:08 MGB PlJ0218 1,2-Dichloroethane 110 ug/L 10 2.8 20 8260B 10112/11 23:08 MGB PlJ0218 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 10/12/11 23:08 MGB PlJ0218 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 10/12/11 23:08 MGB P1J0218 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 10/12/11 23:08 MGB PIJ0218 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 10/12/11 23:08 MGB PIJ0218 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 10/12/11 23:08 MGB PlJ0218 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 10/12/11 23:08 MGB PlJ0218 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 10/12/11 23:08 MGB PlJ0218 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 10/12/11 23:08 MGB PlJ0218 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 10/12/11 23:08 MGB P1J0218 4-Isopropyltoluene BRL ug/L 10 1.3 20 82606 10/12/11 23:08 MGB P1J0218 Acetone 7600 ug/L 1000 120 200 8260B 10/12111 23:34 MGB PlJ0218 Acrolein BRL ug/L 400 22 20 8260B 10/12/11 23:08 MGB PlJ0218 Acrylonitrile BRL ug/L 400 17 20 8260B 10/12/11 23:08 MGB PlJ0218 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 11 of 36 PRISM I Full-ServiceAnalytical 8 . Environmental Solutions �If� �.ewurow�Ea Inc Laboratory Report 10/18/2011 Withers & Raven el -Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1100199-03 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 08:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene 32 ug/L 10 1.4 20 Bromobenzene BRL ug/L 10 1.3 20 Bromochloromethane 18 ug/L 10 2.5 20 Bromodichloromethane BRL ug/L 10 1.2 20 Bromoform BRL ug/L 20 5.4 20 Bromomethane 150 ug/L 20 9.3 20 Carbon disulfide BRL ug/L 100 28 20 Carbon Tetrachloride BRL ug/L 10 2.4 20 Chlorobenzene 52 ug/L 10 1.2 20 Chloroethane 690 ug/L 10 2.6 20 Chloroform BRL ug/L 10 1.8 20 Chloromethane 3000 ug/L 100 22 200 cis-1,2-Dichloroethylene 120 ug/L 10 1.5 20 cis-1,3-Dichloropropylene BRL ug/L 10 2.1 20 Dibromochloromethane BRL ug/L 10 6.0 20 Dibromomethane BRL ug/L 10 2.6 20 Dichlorodifluoromethane BRL ug/L 20 2.1 20 Ethylbenzene BRL ug/L 10 1.3 20 Hexachlorobutadiene BRL ug/L 40 7.3 20 Isopropyl Ether BRL ug/L 10 0.87 20 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 m,p-Xylenes BRL ug/L 20 1.6 20 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 Methyl Ethyl Ketone (2-Butanone) 96000 ug/L 10000 1800 2000 Methyllsobutyl Ketone 11000 ug/L 1000 25 200 Methylene Chloride 68 ug/L 20 8.9 20 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 Naphthalene BRL ug/L 20 2.0 20 n-Butylbenzene BRL ug/L 20 2.3 20 n-Propylbenzene BRL ug/L 10 1.2 20 o-Xylene BRL ug/L 10 0.92 20 sec-Butylbenzene BRL ug/L 10 1.7 20 Styrene BRL ug/L 10 0.94 20 tert-Butylbenzene BRL ug/L 10 1.6 20 Tetrachloroethylene BRL ug/L 10 1.4 20 Toluene 11000 ug/L 100 8.5 200 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 trans-1,3-Dichloropropylene BRL ug/L 10 0.87 20 Trichloroethylene BRL ug/L 10 1.1 20 Trichlorofluoromethane BRL ug/L 10 1.8 20 Vinyl acetate BRL ug/L 40 2.0 20 Vinyl chloride BRL ug/L 10 3.1 20 Surrogate 8260B 10112/11 23:08 MGB PlJ0218 8260E 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB PIJ0218 8260E 10/12/11 2108 MGB P1J0218 8260B 10/12/11 23:08 MGB PlJ0218 8260E 10/12/11 23:08 MGB PIJ0218 8260B 10/12/11 2108 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB PIJ0218 8260E 10/12/11 23:08 MGB PIJ0218 8260E 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:34 MGB PlJ0218 8260E 10/12/11 23:08 MGB PlJ0218 8260E 10/12/11 2108 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB PlJ0218 8260E 10/12/11 2108 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB PIJ0218 8260B 10/12/11 23:08 MGB PIJ0218 8260E 10/13/11 8:11 MGB PlJ0218 8260B 10/12/11 23:34 MGB PIJ0218 8260E 10/12/11 23:08 MGB PIJ0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB PIJ0218 8260E 10/12/11 23:08 MGB PlJ0218 8260E 10/12/11 2108 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB PlJ0218 8260E 10/12/11 23:08 MGB P1J0218 8260E 10/12111 23:34 MGB PIJ0218 8260B 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB P1J0218 82606 10/12/11 23:08 MGB PlJ0218 8260B 10/12/11 23:08 MGB PlJ0218 8260B 10/12/11 23:08 MGB P1J0218 8260B 10/12/11 23:08 MGB P1J0218 Recovery Control Limits This report should not be reproduced.. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 12 Of 36 R ISM I Environmental Full -Service Analytical 8 / Environmental Solutions �' 1 AR01UTORiES LNG Laboratory Report 10/18/2011 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1100199-03 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 08:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 108 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 107 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 36 Laboratory Report R S M I Full -Service Analytical 8 ;P Environmental . � -A..M sac Solutions 10/18/201 1 Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1100199-04 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 09:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 0.067 mg/L 0.010 0.0018 1 601CC 10/10/11 11:59 LTB PlJ0271 Cadmium 0.016 mg/L 0.0010 0.00017 1 6010C 10/10/11 11:59 LTB P1J0271 Chromium 0.16 mg/L 0.0050 0.00070 1 6010C 10/10111 11:59 LTB PlJ0271 Copper 1.4 mg/L 0.010 0.00022 1 6010C 10/10/11 11:59 LTB P1J0271 Lead 0.19 mg/L 0.0050 0.00073 1 6010C 10110/11 11:59 LTB PlJ0271 Selenium 0.050 A mg1L 0.020 0.0035 1 6010C 10/10111 11:59 LTB PlJ0271 Zinc 6.0 mg/L 0.060 0.054 2 6010C 10/10111 13:59 LTB P1J0271 Anions by Ion Chromatography Chloride 120 mg/L 20 0.10 20 '9056A 10/13/11 21:09 cde PIJ0297 Sulfate 14000 mg/L 2000 7.8 2000 '9056A 10/14/11 18:48 cde PlJ0297 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 10/12/11 12:38 BGM P1J0190 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 20 5.9 40 8260B 10/13/11 0:27 MGB P1J0218 1,1,1-Trichloroethane BRL ug/L 20 2.5 40 8260B 10/13/11 0:27 MGB P1J0218 1,1,2,2-Tetrachloroethane BRL ug/L 20 2.9 40 8260B 10/13/11 0:27 MGB P1J0218 1,1,2-Trichloroethane BRL ug/L 20 6.6 40 8260B 10/13/11 0:27 MGB P1J0218 1,1-Dichloroethane 22 ug/L 20 3.8 40 8260B 10/13111 0:27 MGB P1J0218 1,1-Dichloroethylene BRL ug/L 20 3.1 40 8260B 10/13/11 0:27 MGB P1J0218 1,1-Dichloropropylene BRL ug/L 20 2.5 40 8260B 10/13/11 0:27 MGB P1J0218 1,2,3-Trichlorobenzene BRL ug/L 80 8.0 40 8260B 10/13/11 0:27 MGB P1J0218 1,2,3-Trichloropropane BRL ug/L 40 3.2 40 8260B 10/13/11 0:27 MGB P1J0218 1,2,4-Trichlorobenzene BRL ug/L 40 4.1 40 8260B 10/13/11 0:27 MGB PIJ0218 1,2,4-Trimethylbenzene BRL ug/L 20 1.9 40 8260B 10/13/11 0:27 MGB P1J0218 1,2-Dibromo-3-chloropropane BRL ug/L 80 24 40 8260B 10/13/11 0:27 MGB P1J0218 1,2-Dibromoethane BRL ug/L 20 5.5 40 8260B 10/13/11 0:27 MGB PIJ0218 1,2-Dichlorobenzene BRL ug/L 20 3.1 40 8260B 10/13/11 0:27 MGB P1J0218 1,2-Dichloroethane 63 ug/L 20 5.6 40 8260E 10/13/11 0:27 MGB P1J0218 1,2-Dichloropropane BRL ug/L 20 5.1 40 8260B 10/13/11 0:27 MGB PlJ0218 1,3,5-Trimethylbenzene BRL ug/L 20 2.3 40 8260B 1D/13/11 0:27 MGB P1J0218 1,3-Dichlorobenzene BRL ug/L 20 3.0 40 8260B 10/13/11 0:27 MGB P1J0218 1,3-Dichloropropane BRL ug/L 20 4.4 40 82606 10/13/11 0:27 MGB PIJ0218 1,4-Dichlorobenzene BRL ug/L 20 2.7 40 8260B 10/13/11 0:27 MGB PlJ0218 2,2-Dichloropropane BRL ug/L 80 4.6 40 8260B 10/13/11 0:27 MGB PlJ0218 2-Chloroethyl Vinyl Ether BRL ug/L 80 9.0 40 8260B 10/13/11 0:27 MGB PlJ0218 2-Chlorotoluene BRL ug/L 20 1.5 40 8260B 10/13/11 0:27 MGB PlJ0218 4-Chlorotoluene BRL ug/L 20 2.1 40 8260B 10/13/11 0:27 MGB P1J0218 4-Isopropyltoluene BRL ug/L 20 2.6 40 82606 10/13/11 0:27 MGB P1J0218 Acetone 10000 ug/L 2000 250 400 8260E 10113/11 0:53 MGB P1J0218 Acrolein BRL ug/L 800 44 40 8260B 10/13/11 0:27 MGB PlJ0218 Acrylonitrile BRL ug/L Boo 34 40 8260E 10/13/11 0:27 MGB P1J0218 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 36 /P R I S M I Full -Service Analytical & ,, Environmental Solutions LABOMTORIES ENO Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Sample Matrix: Water Laboratory Report 10/18/2011 Client Sample ID: MW-2 Prism Sample ID: 1100199-04 Prism Work Order: 1100199 Time Collected: 10/07/11 09:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene 40 ug/L 20 2.9 40 8260B 10/13/11 0:27 MGB PlJ0218 Bromobenzene BRL ug/L 20 2.6 40 8260B 10/13/11 0:27 MGB PIJ0218 Bromochloromethane BRL ug/L 20 5.0 40 8260B 10/13/11 0:27 MGB PlJ0218 Bromodichloromethane BRL ug/L 20 2.5 40 8260B 10/13/11 0:27 MGB PlJ0218 Bromoform BRL ug/L 40 11 40 8260B 10/13/11 0:27 MGB PlJ0218 Bromomethane 530 ug/L 40 19 40 8260B 10/13/11 0:27 MGB PIJ0218 Carbon disulfide BRL ug/L 200 55 40 8260E 10/13/11 0:27 MGB PlJ0218 Carbon Tetrachloride BRL ug/L 20 4.7 40 8260B 10/13/11 0:27 MGB PlJ0218 Chlorobenzene 20 ug/L 20 2.5 40 8260B 10/13/11 0:27 MGB PIJ0218 Chloroethane 2300 ug/L 20 6.1 40 8260B 10/13/11 0:27 MGB P1J0218 Chloroform BRL ug/L 20 3.5 40 8260B 10/13/11 0:27 MGB PlJ0218 Chloromethane 6700 ug/L 200 44 400 8260E 10113111 0:53 MGB PIJ0218 cis-1,2-Dichloroethylene BRL ug/L 20 3.0 40 8260B 10/13/11 0:27 MGB PlJ0218 cis-1,3-Dichloropropylene BRL ug/L 20 4.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Dibromochloromethane BRL ug/L 20 12 40 8260B 10/13/11 0:27 MGB PIJ0218 Dibromomethane BRL ug/L 20 5.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Dichlorodifluoromethane BRL ug/L 40 4.3 40 8260B 10/13/11 0:27 MGB PlJ0218 Ethylbenzene BRL ug/L 20 2.7 40 8260B 10/13/11 0:27 MGB PlJ0218 Hexachlorobutadiene BRL ug/L 80 15 40 8260B 10/13/11 0:27 MGB PlJ0218 Isopropyl Ether BRL ug/L 20 1.7 40 8260B 10/13/11 0:27 MGB PIJ0218 Isopropylbenzene (Cumene) BRL ug/L 20 2.9 40 8260B 10/13/11 0:27 MGB PlJ0218 m,p-Xylenes BRL ug/L 40 3.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Methyl Butyl Ketone (2-Hexanone) 20 J ug/L 200 7.6 40 8260E 10/13/11 0:27 MGB PlJ0218 Methyl Ethyl Ketone (2-Butanone) 170000 ug/L 10000 1800 2000 8260E 10/13/11 8:38 MGB PlJ0218 Methyl Isobutyl Ketone 5700 ug/L 2000 50 400 8260B 10/13/11 0:63 MGB PlJ0218 Methylene Chloride 58 ug/L 40 18 40 8260E 10/13/11 0:27 MGB PlJ0218 Methyl-tert-Butyl Ether BRL ug/L 20 2.8 40 8260B 10/13/11 0:27 MGB PlJ0218 Naphthalene BRL ug/L 40 3.9 40 8260B 10/13/11 0:27 MGB PlJ0218 n-Butylbenzene BRL ug/L 40 4.5 40 8260B 10/13/11 0:27 MGB PlJ0218 n-Propylbenzene BRL ug/L 20 2.4 40 8260B 10/13/11 0:27 MGB PIJ0218 o-Xylene BRL ug/L 20 1.8 40 8260B 10/13/11 0:27 MGB PlJ0218 sec-Butylbenzene BRL ug/L 20 3.5 40 8260B 10/13/11 0:27 MGB PlJ0218 Styrene BRL ug/L 20 1.9 40 8260B 10/13/11 0:27 MGB PlJ0218 tert-Butylbenzene BRL ug/L 20 3.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Tetrachloroethylene BRL ug/L 20 2.8 40 8260B 10/13/11 0:27 MGB PIJ0218 Toluene 1900 ug/L 20 1.7 40 8260B 10113/11 0:27 MGB PlJ0218 trans-1,2-Dichloroethylene BRL ug/L 20 4.6 40 8260B 10/13/11 0:27 MGB PlJ0218 trans-1,3-Dichloropropylene BRL ug/L 20 1.7 40 8260B 10/13/11 0:27 MGB PlJ0218 Trichloroethylene BRL ug/L 20 2.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Trichlorofluoromethane BRL ug/L 20 3.5 40 8260B 10/13/11 0:27 MGB PlJ0218 Vinyl acetate BRL ug/L 80 4.0 40 8260B 10/13/11 0:27 MGB PlJ0218 Vinyl chloride BRL ug/L 20 6.2 40 8260B 10/13/11 0:27 MGB PlJ0218 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 15 of 36 R I S Full -Service Analytical S Environmental Solutions LABLWAlOP1E5 AMC. Laboratory Report 10/18/2011 Withers & Raven el-Wilm ington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1100199-04 1410 Commwealth Drive Prism Work Order: 1100199 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 10/07/11 09:00 Time Submitted: 10/07/11 14:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 109 % 80-124 Dibromofluoromethane 105 % 75-129 Toluene-d8 105 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 16 of 36 Level II QC Report /P R I S M I Fun -Service Analytical s t FuVif ervice A solutions 10/18/11 IAI-ATOA Withers & Rave nel-Wilmington Project: Henson Landfill Prism Work Order: 1100199 Attn: Brian Bellis Time Submitted: 10/7/2011 2:40:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1J0218 - 5030B Blank (P1J0218-BLK1) Prepared & Analyzed: 10/12/11 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,1-Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichooropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethyl benzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethylbenzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 2.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced., except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/526-0409 Page 17 of 36 o R I S n � I Full -Service al Solutions 8 r 'v' Environmental Solutions Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 10/18/11 Prism Work Order: 1100199 Time Submitted: 10/7/2011 2:40:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1J0218 - 5030B Blank (P1J0218-BLK1) Prepared & Analyzed: 10/12/11 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,l-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 52.5 ug/L 50.00 105 80-124 Surrogate: Dibromofluoromethane 51.8 ug/L 50.00 104 75-129 Surrogate: Toluene-d8 52.3 ug/L 50.00 105 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 7041525-0409 Page 18 of 36 P R I S M Full -Service Analytical �, .�"� Environmental Solutions LABOfiPTOR1ES ANC Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 10/18/11 Prism Work Order: 1100199 Time Submitted: 10/7/2011 2:40:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1J0218 - 5030B LCS (PlJ0218-BSI) 1,1-Dichloroethylene Benzene Chlorobenzene Toluene Trichloroethylene Surrogate: 4-Bromofl uorob enz ene Surrogate: Dibromofluoromethane Surrogate: Toluene-d8 LCS Dup (PIJ0218-BSD1) 1,1-Dichloroethylene Benzene Chlorobenzene Toluene Trichloroethylene Surrogate: 4-Bromofluorob enz ene Surrogate: Dibromofluoromethane Surrogate: Toluene-d8 Prepared & Analyzed:10/12/11 20.9 0.50 ug/L 20.00 104 70-154 19.8 0.50 ug/L 20.00 99 77-128 20.9 0.50 ug/L 20.00 105 78-119 20.5 0.50 ug/L 20.00 103 76-131 19.6 0.50 ug/L 20.00 98 77-133 52.2 ug/L 50.00 104 80-124 52.0 ug/L 50.00 104 75-129 53.0 ug/L 50.00 106 77-123 Prepared & Analyzed: 10/12/11 19.5 0.50 ug/L 20.00 98 70-154 7 200 19.2 0.50 ug/L 20.00 96 77-128 3 200 20.1 0.50 ug/L 20.00 100 78-119 4 200 19.9 0.50 ug/L 20.00 99 76-131 3 200 19.1 0.50 ug/L 20.00 96 77-133 2 200 51.4 ug/L 50.00 103 80-124 51.6 ug/L 50.00 103 75-129 52.2 ug/L 50.00 104 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041625-0409 Page 19 of 36 ZRIR ISM I Full -Service tin S Environmentalal Solutions Analytical UFaCWATpNES ING Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Total Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 10/18/11 Prism Work Order: 1100199 Time Submitted: 10/7/2011 2:40:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1J0190 - 7470A Blank (P1J0190-BLK1) Prepared: 10/11/11 Analyzed: 10/12/11 Mercury BRL 0.00020 mg/L LCS (P1J0190-BSI) Prepared: 10/11/11 Analyzed: 10/12/11 Mercury 0.00945 0.00020 mg/L 0.009375 101 80-120 Matrix Spike (P1J0190-MSI) Source: 1100199-01 Prepared: 10/11/11 Analyzed: 10/12/11 Mercury 0.00942 0.00020 mg/L 0.009375 BRL 100 80-120 Matrix Spike Dup (P1J0190-MSD1) Source: 1100199-01 Prepared: 10/11/11 Analyzed: 10/12/11 Mercury 0.00974 0.00020 mg/L 0.009375 BRL 104 80-120 3 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525.0409 Page 20 of 36 PRISM Fun -Service Analytical 8 Environmental Solutions �iP4 ueow�mwies �wc Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 10/18/11 Prism Work Order: 1100199 Time Submitted: 10/7/2011 2:40:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1JO147 - SM3030 C Blank (P1J0147-BLK1) Prepared: 10/07/11 Analyzed: 10/13/11 Arsenic BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 1.0 ug/L Zinc BRL 10 ug/L LCS (P1J0147-BSI) Prepared: 10/07/11 Analyzed_: 10/13/11 Arsenic 254 1.0 ug/L 250.0 102 80-120 Cadmium 253 1.0 ug/L 250.0 101 80-120 Chromium 261 1.0 ug/L 250.0 104 80-120 Copper 258 5.0 ug/L 250.0 103 80-120 Lead 252 1.0 ug/L 250.0 101 80-120 Selenium 268 1.0 ug/L 250.0 107 80-120 Zinc 267 10 ug/L 250.0 107 80-120 Batch P1J0271 - SM3030 C Blank (PlJ0271-BLK1) Prepared. 10/07/11 Analyzed: 10/10/11 Arsenic BRL 0.010 mg/L Cadmium BRL 0.0010 mg/L Chromium BRL 0.0050 mg/L Copper 0.000302 0.010 mg/L J Lead BRL 0.0050 mg/L Selenium BRL 0.020 mg/L Zinc BRL 0.030 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 21 of 36 Level II QC Report vice Analytical 8RISM I Environmental Solutions 10/18/11 LABWiAT0-%-- Withers & Rave nel-Wilmington Project: Henson Landfill Prism Work Order: 1100199 Attn: Brian Bellis Time Submitted: 10/7/2011 2:40:OOPM 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Result Reporting Limit Units Spike Level Source Result %REC %REC Limits RPD RPD Limit Notes Batch P1J0271 - SM3030 C LCS (PlJ0271-BSI) Prepared: 10/07/11 Analyzed: 10/10/11 Arsenic 0.270 0.010 mg/L 0.2500 108 80-120 Cadmium 0.271 0.0010 mg/L 0.2500 108 80-120 Chromium 0.260 0.0050 mg/L 0.2500 104 80-120 Copper 0.260 0.010 mg/L 0.2500 104 80-120 Lead 0.273 0.0050 mg/L 0.2500 109 80-120 Selenium 0.301 0.020 mg/L 0.2500 121 80-120 A Zinc 0.282 0.030 mg/L 0.2500 113 80-120 Matrix Spike (PlJ0271-MSI) Source: 1100199-04 Prepared: 10/07/11 Analyzed: 10/10/11 Arsenic 0.283 0.010 mg/L 0.2500 0.0667 87 75-125 Cadmium 0.187 0.0010 mg/L 0.2500 0.0163 68 75-125 MI Chromium 0.329 0.0050 mg/L 0.2500 0.159 68 75-125 MI Copper 1.57 0.010 mg/L 0.2500 1.39 73 75-125 MI Lead 0.352 0.0050 mg/L 0.2500 0.190 65 75-125 MI Selenium 0.308 0.020 mg/L 0.2500 0.0502 103 75-125 Zinc 1.00E9 0.030 mg/L 0.2500 6.01 NR 75-125 MC Matrix Spike Dup (PlJ0271-MSD1) Source: 1100199-04 Prepared: 10/07/11 Analyzed: 10/10/11 Arsenic 0.287 0.010 mg/L 0.2500 0.0667 88 75-125 1 20 Cadmium 0.189 0.0010 mg/L 0.2500 0.0163 69 75-125 1 20 MI Chromium 0.335 0.0050 mg/L 0.2500 0.159 70 75-125 2 20 MI Copper 1.59 0.010 mg/L 0.2500 1.39 81 75-125 1 20 Lead 0.358 0.0050 mg/L 0.2500 0.190 67 75-125 1 20 MI Selenium 0.306 0.020 mg/L 0.2500 0.0502 102 75-125 0.7 20 Zinc 1.00E9 0.030 mg/L 0.2500 6.01 NR 75-125 0 20 MC This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529.6364 - Fax: 7041525.0409 Page 22 Of 36 Level II QC Report PRISM Full -Service Analytical 10(18/1 Environmental Solutions � ueoan.oaies sac Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1100199 Attn: Brian Bellis Time Submitted: 10/7/2011 2:40:OOPM 1410 Commwealth Drive Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch PIJ0247 - NO PREP Blank (PlJ0247-BLKI) Prepared &Analyzed: 10/11/11 Chloride BRL 1.0 mg(L Sulfate BRL 1.0 mg/L LCS (PlJ0247-BSI) Prepared & Analyzed: 10/11/11 - Chloride 1.88 1.0 mg/L 2.000 94 80-120 Sulfate 1.86 1.0 mg/L 2.000 93 80-120 Batch P1J0297 - NO PREP Blank (PlJ0297-BLK1) Chloride Sulfate LCS (PlJ0297-BS1) Chloride Sulfate Prep Method: SM3030 C Lab Number Prepared & Analyzed: 10/13/11 BRL 1.0 mg/L BRL 1.0 mg/L Prepared & Analyzed: 10/13/11 2.05 1.0 mg/L 2.000 103 80-120 2.02 1.0 mg/L 2.000 101 80-120 Sample Extraction Data Batch Initial Final Date/Time 1100199-01 PlJO147 50 mL 50 mL 10/07/11 15:15 1100199-02 PlJO147 50 mL 50 mL 10/07/11 15:15 1100199-03 PlJ0271 50 mL 50 mL 10/07/11 15:15 1100199-04 PlJ0271 50 mL 50 mL 10/07/11 15:15 1100199-04 PlJ0271 50 mL 50 mL 10/07/11 15:15 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 1100199-01 P1J0190 20 mL 30 mL 10/11/11 12:05 1100199-02 P1J0190 20 mL 30 mL 10/11/11 12:05 1100199-03 P1J0190 20 mL 30 mL 10/11/11 12:05 1100199-04 P1J0190 20 mL 30 mL 10/11/11 12:05 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 1100199-01 PlJ0218 10 mL 10 mL 10/12/11 14:08 1100190-02 P1J0218 10 mL 10 mL 10/12/11 14:08 1100199-03 P1J0218 10 mL 10 mL 10/12/11 14:08 1100199-03 P1J0218 10 mL 10 mL 10/12/11 14:08 1100199-03 P1J0218 10 mL 10 mL 10/12/11 14:08 1100199-04 P1J0218 10 mL 10 mL 10/12/11 14:08 1100199-04 P1J0218 10 mL 10 mL 10/12/11 14,08 1100199-04 P1J0218 10 mL 10 mL 10/12/11 14:08 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 23 of 36 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 1100199-01 TOC (Sub) 1100199-02 TOC (Sub) l 100199-03 TOC (Sub) 1100199-04 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525.0409 Page 24 of 36 I ' i If LRD I� Environmental SolutionsFull-Service Analytical & ABORATORfE& INC. 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Phone:704/529-6364 • Fax:704/525-0409 Client Company Name: 1^J` Report To/Contact Name: Reporting Address: CHAIN OF CUSTODY RECORD PAGE 7,— OF ` QUOTE 8 To ENSURE PROPER BILLING: Project Name: ����a n) (--/4 p�l Lim Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) *Please ATTACH any project specific reporting (QC LEVEL 1 II III IV) provisions and/or OC Requirements Invoice To: Address: Samples INTACT upon arrival? Received ON WET ICE? Temp 5•� PROPER PRESERVATIVES indicated? Received WITHIN HOLDING TIMES? CUSTODY SEALS INTACT? VOLATILES rec'd WlOUT HEADSPACE? PROPER CONTAINERS used? YES NO N/A M 0 N tmone: t-ax (ies) (NO): Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email (Yes) (No) Email Address Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NCV/ EDD Type: PDF_ Excel _Other yP "Working Days" ❑ 6-9 Days ❑Standard 10 days Rush Be Site Location Name: Samples received after 15:00 will be processed next business day. Sc OTHER_ N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES— NOS (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) _ CLIENT TIME COLLECTED MATRIXSAMPLE CONTAINER AhkALYSES REQUES ED Q� PRISM SAMPLE DESCRIPTION DATE COLLECTED MILITARY (SOIL, WATER OR PRESERVA- TIVES bb �A� / J`�CN S( REMARKS ID LA B *TYPE NO SIZE HOURS SLUDGE) SEE BELOW . 3/� y t (�` 0-7 0L1 Loll O %b-o W ATU2 GG Val} ZSoM 14G VaA 3 4.O,M RcL _ k 5-00 LAI Noti J W 2 01100 c.G )VoA 3 L(OM) 4 r-L a _ 1 ZsoM 1 fiml-xV A_ - - — ft VDA He -- - Cp t 500M' AJOr►6_ 1/ lrl Z,6 O-o _ Al0(J(i Sampler's Signature , a d1n- Sampled By (Print Name) �3A�t/LSd,411 Affiliation W ��- Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be I submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. • Relinquished By: (Signature) Received By: (Signature) Date ilitary/Hours Additional Comments: Site Arrival Time: Relinquished By: (Signature) Received By: (Signature) Date Site Departure Time: R linquished By: (Signature) Received For sm Laboratories By: Date Ln`` A#&A)1G Field Tech fee: / n ! FAO �J ar I -W o C�M1UM Mileage: Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WI CUSTODY SEALS R TRANSPORTATION TO THE LABORATORY. COG Group No. Gi11tO n1UM SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COC UNTIL RECEIVED AT THE LABORATORY. c*f r&0 ❑ Fed Ex ❑ UPS and -delivered ❑ Prism Field Service ❑ Other _ LZA­•' NPDES: U T.WATER: DRINKING WATER: SOLID WASTE: RCRA: CERCLA LANDFILL OTHER: M6A..WILj . ' �GPOUND ❑NC ❑SC ❑NC ❑SC NC ❑SC LINC ❑SC ❑NC ❑SC ❑NC ❑SC LNG ❑SC ❑NC ❑SCI ❑NC ❑SC I 5"1JIU,n . ❑ - ❑ - - ❑---- ❑ ❑ ❑ — ❑ ❑ *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) f'`n' `' vr1IUII1Jt%L- Primary Data Review By I n kr *-19 n Curtis Ekker Data Validation Manager, GCAL ANALYTICAL REPORT CLIENT Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 ATTENTION Angie Overcash PROJECTID 1100199 LABORATORY REPORT NUMBER 211101022 DATE 10/12/2011 Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 GSRI Avenue, Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Page 26 of 36 al NELAP CERTIFICATE NUMBER 01955 DOD FLAP CERTIFICATE NUMBER ADE -1482 ANALYTICAL RESULTS PERFORMED BY GULF COAST ANALYTICAL LABORATORIES, INC. 7979 GSRI Avenue Baton Rouge, LA 70820 Report Date 10/12/2011 GiiReport uu2sii10ii22i Deliver To Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 706-529-6364 Attn Angie Overcash Project 1100199 Page 27 of 36 CASE NARRATIVE Client: Access Analytical Report: 211101022 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the sample cross-reference page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. CONVENTIONALS In the SM 5310B analysis, samples 21110102203 (MW-3) and 21110102204 (1VIW-2) had to be diluted in order to bracket the Total Carbon and/or Total Inorganic Carbon concentrations within the calibration range of the instrument. The Total Organic Carbon is based on the difference between the Total Carbon and the Inorganic Carbon. The dilution is reflected in the elevated reporting limit. Page 28 of 36 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations Utilized in this Report ND Indicates the result was Not Detected at the specified RDL DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field PQL Practical Quantitation Limit MDL Method Detection Limit RDL Reporting Detection Limit 00:00 Reported as a time equivalent to 12:00 AM Reporting Flags Utilized in this Report J Indicates an estimated value U Indicates the compound was analyzed for but not detected B (ORGANICS) Indicates the analyte was detected in the associated Method Blank B (INORGANICS) Indicates the result is between the RDL and MDL Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with the NELAC standard and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer -readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Int i n g Robyn Migues Technical Director GCAL REPORT 2111010221nt isi THIS REPORT CONTAINS PAGES. Page 29 of 36 Report Sample Summary GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21110102201 MW-20A Water 10/07/201106:00 10/08/201109:15 21110102202 MW-20 Water 10/07/201107:00 10/08/201109:15 21110102203 MW-3 Water 10/07/201108:00 10/08/201109:15 21110102204 MW-2 Water 10/07/201109:00 10108/201109:15 GCAL Report 211101022 Page 30 of 36 Summary of Compounds Detected GCAL ID Client ID Matrix Collect Date/Time Receive Date(Time 21110102201 MW-20A Water 10/07/201106:00 10/08/201109:15 SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 3.6 1.0 0.25 mg/L GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21110102202 MW-20 Water 10/07/201107:00 10108/201109:15 SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 26.3 1.0 0.25 mg/L 'GCAL ID Client 1D Matrix Collect DateMme Receive Date/Time 21110102203 MW-3 Water 10107/201108:00 10Q8/201109:15 SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 379 20.0 5.1 mg/L ' [GCAL ID Client ID Matrix ' Collect Date/Time Receive Date/Time 2 11 10102204 MW-2 Water 10/07/201109:00 10/08/201109:15 SM 5310B TOC CAS# Parameter C-012 Total Organic Carbon GCAL Report 211101022 Result RDL MDL Units 439 5.0 1.3 mg/L Page 31 of 36 GCAL ID Client ID Matrix Collect DateiTime Receive Date/Time 21110102201 MW-20A Water 10/07/201106:00 10/081201109:15 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 10/11/201123:15 AEL 466928 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211101022 Result RDL MDL Units 3.6 1.0 0.25 mg/L Page 32 of 36 GOAL ID Client 1D Matrix Collect Date/Time Receive Date/Time 21110102202 MW-20 Water 10/071201107:00 10108/201109:15 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 10/11/201123:37 AEL 466928 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 26.3 1.0 0.25 mg/L GCAL Report 211101022 Page 33 of 36 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 20 10/11/201123:57 AEL 466928 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 379 20.0 5.1 mg/L GCAL Report 211101022 Page 34 of 36 GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21110102204 MW-2 Water 10107/201109:00 10108/201109:15 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 5 10/12/201100:20 AEL 466928 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211101022 Result RDL MDL 439 5.0 1.3 Units mg/L r Page 35 of 36 General Chemistry Quality Control Summary Analytical Batch 466928 Client ID MB466928 LCS466928 LCSD466928 Prep Batch N/A GCAL ID 995201 995202 995203 Sample Type Method Blank LCS LCSD Analytical Date 10/11/2011 17:27 10/11/2011 17:47 10/11/2011 18:04 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 0.251.1 0.25 50.01 49.9 100 80 - 1201 50.5 101 1 25 Analytical Batch 466928 Client ID 002 OUTFALL 994498MS 994498MSD Prep Batch N/A GCAL ID 21110072701 995204 995205 Sample Type SAMPLE MS MSD Analytical Date 10/11/2011 19:06 10/11/2011 19:29 10/11/2011 19:45 Matrix Water Water Water SM 5310B TOC Units mglL Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 2.3 0.25 50.0 56.0 107 75 - 125 55.5 106 0.9 25 Analytical Batch 466928 Client ID U31D201G 99508OMS 99508OMSD Prep Batch NIA GCAL ID 21110112201 995206 995207 Sample Type SAMPLE MS MSD Analytical Date 10/12/2011 03:10 10/12/2011 03:28 10/12/2011 03*47 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R 1 1 Limits % R % R RPD Limit C-012 Total Organic Carbon i 127 1.3 2501 380 101 75 - 1251 372 98 2 1 25 GCAL Report 211101022 i ��RISM �'�`'"ueoruTorues, iNc Full -Service Analytical & Environmental Solutions Withers & Ravenel-Wilmington Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cent No. 37735 Project: Henson Landfill Lab Submittal Date: 11/09/2011 Prism Work Order: 1110283 Case Narrative 11 /29/2011 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. VP Laboratory Services Data Qualifiers Key Reference: Reviewed By A LCS recovery is outside the control limits. H Compound reported with possible high bias. LCS recovery above the QC limit. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 1 of 37 P R I S M Full -Service Analytical 8 Environmental Solutions Sample Receipt Summary 11 /29/2011 Prism Work Order: 1110283 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW-20A 1110283-01 Water 11/09/11 11/09/11 MW-20 1110283-02 Water 11/09/11 11/09/11 MW-3 1110283-03 Water 11/09/11 11/09/11 MW-2 1110283-04 Water 11/09/11 11/09/11 Samples received in good condition at 2.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/526-0409 Page 2 of 37 RISM Laboratory Report Full -Service Analytical & Environmental Solutions 11/29/2011 /�Awpd BOHATO l iHG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1110283-01 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 06:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 1.9 ug/L 1.0 0.12 1 6020A 11/16/11 19:26 DWR PlK0255 Cadmium BRL ug/L 1.0 0.20 1 6020A 11/16/11 1926 DWR PlK0255 Chromium 2.0 J ug/L 5.0 0.12 1 6020A 11/16/11 19:26 DWR PlK0255 Copper 1.4 J ug/L 5.0 0.53 1 6020A 11/16/11 19:26 DWR PlK0255 Lead 0.23 J ug/L 1.0 0.13 1 6020A 11/16/11 19:26 DWR PlK0255 Selenium 1.0 ug/L 1.0 0.44 1 6020A 11116/11 19:26 DWR PIK0255 Zinc 15 ug/L 10 0.58 1 6020A 11/19/11 0:50 DWR PlK0255 Anions by Ion Chromatography Chloride 1.6 J mg/L 2.0 0.010 2 9056A 11122/11 18:08 cde PIK0608 Sulfate 39 mg/L 2.0 0.0078 2 9056A 11/22/11 18:08 cde PlKO508 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL mg/L 0.00020 0.000014 1 7470A 11/17/11 12:08 BGM PlK0346 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.15 1 8260B 11/14/11 16:31 MGB P1K0284 1,1,1-Trichloroethane BRL ug/L 0.50 0.063 1 8260B 11/14/11 16:31 MGB P1K0284 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.071 1 8260B 11/14/11 16:31 MGB P1K0284 1.1,2-Trichloroethane BRL ug/L 0.50 0.17 1 8260B 11/14/11 16:31 MGB P1K0284 1,1-Dichloroethane BRL ug/L 0.50 0.096 1 8260B 11/14/11 16:31 MGB P1K0284 1,1-Dichloroethylene BRL ug/L 0.50 0.078 1 8260B 11/14/11 16:31 MGB P1K0284 1,1-Dichloropropylene BRL ug/L 0.50 0.061 1 8260B 11/14/11 16:31 MGB P1K0284 1,2,3-Tdchlorobenzene BRL ug/L 2.0 0.20 1 8260B 11/14/11 16:31 MGB P1K0284 1,2,3-Trichloropropane BRL ug/L 1.0 0.081 1 8260B 11/14/11 16:31 MGB P1K0284 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.10 1 8260B 11/14/11 16:31 MGB P1K0284 1,2,4-Trimethylbenzene BRL ug/L 0.50 0.048 1 8260B 11/14/11 16:31 MGB P1K0284 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.59 1 8260B 11/14/11 16:31 MGB P1K0284 1,2-Dibromoethane BRL ug/L 0.50 0.14 1 8260B 11/14/11 16:31 MGB P1K0284 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 11/14/11 16:31 MGB P1K0284 1,2-Dichloroethane BRL ug/L 0.50 0.14 1 8260B 11/14/11 16:31 MGB P1K0284 1,2-Dichloropropane BRL ug/L 0.50 0.13 1 82606 11/14/11 16:31 MGB PIK0284 1,3,5-Trimethylbenzene BRL ug/L 0.50 0.057 1 8260B 11/14/11 16:31 MGB PIK0284 1,3-Dichlorobenzene BRL ug/L 0.50 0.074 1 8260B 11/14/11 16:31 MGB PIK0284 1,3-Dichloropropane BRL ug/L 0.50 0.11 1 8260E 11/14/11 16:31 MGB PIK0284 1,4-Dichlorobenzene BRL ug/L 0.50 0.068 1 8260B 11/14/11 16:31 MGB PIK0284 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 11/14/11 16:31 MGB PlK0284 2-Chloroethyl Vinyl Ether BRL ug/L 2.0 0.22 1 8260B 11/14/11 16:31 MGB PlK0284 2-Chlorotoluene BRL ug/L 0.50 0.038 1 8260B 11/14/11 16:31 MGB PlK0284 4-Chlorotoluene BRL ug/L 0.50 0.053 1 8260B 11/14/11 16:31 MGB PlK0284 4-Isopropyltoluene BRL ug/L 0.50 0.065 1 8260B 11/14/11 16:31 MGB PlK0284 Acetone BRL ug/L 5.0 0.62 1 8260B 11/14/11 16:31 MGB PlK0284 Acrolein BRL ug/L 20 1.1 1 8260B 11/14/11 16:31 MGB PlK0284 Acrylonitrile BRL ug/L 20 0.86 1 8260B 11/14/11 16:31 MGB PlK0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 7041525-0409 Page 3 of 37 /WR I S M I full -Service Analytical Environmental Solutions 1n8011ATOH1E4 LNG Laboratory Report 11 /29/2011 Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1110283-01 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 06:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene BRL ug/L 0.50 0.072 1 Bromobenzene BRL ug/L 0.50 0.064 1 Bromochloromethane BRL ug/L 0.50 0.13 1 Bromodichloromethane BRL ug/L 0.50 0.062 1 Bromoform BRL ug/L 1.0 0.27 1 Bromomethane BRL ug/L 1.0 0.47 1 Carbon disulfide BRL ug/L 5.0 1.4 1 Carbon Tetrachloride BRL ug/L 0.50 0.12 1 Chlorobenzene BRL ug/L 0.50 0.061 1 Chloroethane BRL ug/L 0.50 0.13 1 Chloroform BRL ug/L 0.50 0.089 1 Chloromethane BRL ug/L 0.50 0.11 1 cis- 1,2-Dichloroethylene BRL ug/L 0.50 0.076 1 cis- 1,3-Dichloropropylene BRL ug/L 0.50 0.10 1 Dibromochloromethane BRL ug/L 0.50 0.30 1 Dibromomethane BRL ug/L 0.50 0.13 1 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 Ethylbenzene BRL ug/L 0.50 0.067 1 Hexachlorobutadiene BRL ug/L 2.0 0.36 1 Isopropyl Ether BRL ug/L 0.50 0.043 1 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.072 1 m,p-Xylenes BRL ug/L 1.0 0.081 1 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.19 1 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.90 1 Methyl Isobutyl Ketone BRL ug/L 5.0 0.12 1 Methylene Chloride BRL ug/L 1.0 0.44 1 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.070 1 Naphthalene BRL ug/L 1.0 0.098 1 n-Butylbenzene BRL ug/L 1.0 0.11 1 n-Propylbenzene BRL ug/L 0.50 0.060 1 o-Xylene BRL ug/L 0.50 0.046 1 sec-Butylbenzene BRL ug/L 0.50 0.087 1 Styrene BRL ug/L 0.50 0.047 1 tert-Butylbenzene BRL ug/L 0.50 0.080 1 Tetrachloroethylene BRL ug/L 0.50 0.069 1 Toluene BRL ug/L 0.50 0.042 1 trans- 1,2-Dichloroethylene BRL ug/L 0.50 0.12 1 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.043 1 Trichloroethylene BRL ug/L 0.50 0.054 1 Trichlorofluoromethane BRL ug/L 0.50 0.088 1 Vinyl acetate BRL ug/L 2.0 0.10 1 Vinyl chloride BRL ug/L 0.50 0.16 1 Surrogate 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB PlK0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB PI K0284 8260B 11/14/11 16:31 MGB PI K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB PI K0284 8260E 11/14/11 16:31 MGB PI K0284 8260B 11/14/11 16:31 MGB PI K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB PI K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB Fill K0284 8260B 11/14/11 16:31 MGB PI K0284 8260B 11/14/11 16:31 MGB P1 K0284 8260E 11/14/11 16:31 MGB P1 K0284 Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1.8001629-6364 - Fax: 7041525-0409 Page 4 of 37 Full -Service Analyticals&RR ISM I Environmental Solutions �N uwonnruwres we Laboratory Report 11 /29/2011 Withers & Rave nel-Wilmi ngton Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1110283-01 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 06:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 4-Bromofluorobenzene 106 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 5 of 37 Laboratory Report Funee Analytical 8 %P R I S M I Environmironmental Solutions 11 /29/201 1 1Xt .. LA-1- Inc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1110283-02 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 07:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 49 ug/L 1.0 0.12 1 6020A 11/16/11 19:51 DWR P1K0255 Cadmium BRL ug/L 1.0 0.20 1 6020A 11/16/11 1951 DWR PIK0255 Chromium 0.74 J ug/L 5.0 0.12 1 6020A 11116/11 19:51 DWR PlK0255 Copper 1.2 J ug1L 5.0 0.53 1 6020A 11/16/11 19:51 DWR PlK0255 Lead 1.3 ug/L 1.0 0.13 1 6020A 11116111 19:51 DWR PlK0265 Selenium 1.5 ug/L 1.0 0.44 1 6020A 11116111 19:51 DWR P1K0255 Zinc 13 ug/L 10 0.58 1 6020A 11/19111 0:69 DWR PlK0255 Anions by Ion Chromatography Chloride 49 mg/L 10 0.050 10 9056A 11/22/11 18:42 cde P1K0508 Sulfate 0.64 J mg/L 1.0 0.0039 1 9066A 11122/11 18:25 cde PIK0508 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 11/17/11 12:19 BGM PlK0346 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 11/14/11 17:12 MGB P1K0284 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 11/14/11 17:12 MGB P1K0284 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 11/14/11 17:12 MGB P1K0284 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 11/14/11 17:12 MGB P1K0284 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 11/14/11 17:12 MGB P1K0284 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 11/14/11 17:12 MGB P1K0284 1,1-Dichloropropylene BRL ug/L 10 1.2 20 8260B 11/14/11 17:12 MGB P1K0284 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 11/14/11 17:12 MGB PIK0284 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 11/14/11 17:12 MGB PlK0284 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 11/14/11 17:12 MGB P1K0284 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 11/14/11 17:12 MGB PIK0284 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 82606 11/14/11 17:12 MGB P1K0284 1,2-Dibromoethane BRL ug/L 10 2.7 20 B260B 11/14/11 17:12 MGB P1K0284 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 11/14/11 17:12 MGB P1K0284 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 11/14/11 17:12 MGB P1K0284 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 11/14/11 17:12 MGB PIK0284 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 11/14/11 17:12 MGB PlK0284 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 11/14/11 17:12 MGB PlK0284 1,3-Dichloropropane BRL ug/L 10 2.2 20 82606 11/14/11 17:12 MGB P1K0284 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 11/14/11 17:12 MGB P1K0284 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 11/14/11 17:12 MGB P1K0284 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 11/14/11 17:12 MGB P1K0284 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 11/14/11 17:12 MGB P1K0284 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 11/14/11 17:12 MGB PIK0284 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 11/14/11 17:12 MGB P1K0284 Acetone BRL ug/L 100 12 20 8260B 11/14/11 17:12 MGB P1K0284 Acrolein BRL ug/L 400 22 20 8260B 11/14/11 17:12 MGB P1K0284 Acrylonithle BRL ug/L 400 17 20 8260B 11/14/11 17:12 MGB P1K0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1.8001529-6364 - Fax: 704/525-0409 Page 6 of 37 /0 Full -Service Analytical & PRISM Environmental Solutions Lwa011ATON,ES ANC. Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Sample Matrix: Water Laboratory Report 11/29/2011 Client Sample ID: MW-20 Prism Sample ID: 1110283-02 Prism Work Order: 1110283 Time Collected: 11/09/11 07:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Benzene 27 ug/L 10 1.4 20 8260E 11114/11 17:12 MGB PlK0284 Bromobenzene BRL ug/L 10 1.3 20 8260B 11/14/11 17:12 MGB PlK0284 Bromochloromethane BRL ug/L 10 2.5 20 8260B 11/14/11 17:12 MGB PlK0284 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 11/14/11 17:12 MGB PlK0284 Bromoform BRL ug/L 20 5.4 20 8260B 11/14/11 17:12 MGB PlK0284 Bromomethane BRL ug/L 20 9.3 20 8260B 11/14/11 17:12 MGB PlK0284 Carbon disulfide BRL ug/L 100 28 20 8260E 11/14/11 17:12 MGB PlK0284 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 11/14/11 17:12 MGB PlK0284 Chlorobenzene 87 ug/L 10 1.2 20 8260B 11/14111 17:12 MGB PlK0284 Chloroethane BRL ug/L 10 2.6 20 8260B 11/14/11 17:12 MGB PlK0284 Chloroform BRL ug/L 10 1.8 20 8260B 11/14/11 17:12 MGB PlK0284 Chloromethane BRL ug/L 10 2.2 20 8260B 11/14/11 17:12 MGB PlK0284 cis-1,2-Dichloroethylene 72 ug/L 10 1.6 20 8260B 11/14/11 17:12 MGB P1K0284 cis-1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 11/14/11 17:12 MGB PlK0284 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 11/14/11 17:12 MGB PlK0284 Dibromomethane BRL ug/L 10 2.6 20 8260B 11/14/11 17:12 MGB PlK0284 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 11/14/11 17:12 MGB PlK0284 Ethylbenzene BRL ug/L 10 1.3 20 8260B 11/14/11 17:12 MGB PlK0284 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 11/14/11 17:12 MGB PlK0284 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 11/14/11 17:12 MGB PlK0284 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 11/14/11 17:12 MGB PlK0284 m,p-Xylenes 17 J ug/L 20 1.6 20 8260B 11114/11 17:12 MGB PlK0284 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260B 11/14/11 17:12 MGB PlK0284 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 100 18 20 8260B 11/14/11 17:12 MGB PlK0284 Methyl lsobutylKetone BRL ug/L 100 2.5 20 8260B 11/14/11 17:12 MGB PlK0284 Methylene Chloride BRL ug/L 20 8.9 20 B260B 11/14/11 17:12 MGB PlK0284 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 11/14/11 17:12 MGB PlK0284 Naphthalene BRL ug/L 20 2.0 20 8260B 11/14/11 17:12 MGB PlK0284 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 11/14/11 17:12 MGB PlK0284 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 11/14/11 17:12 MGB PIK0284 o-Xylene BRL ug/L 10 0.92 20 8260B 11/14/11 17:12 MGB PlK0284 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 11/14/11 17:12 MGB PlK0284 Styrene BRL ug/L 10 0.94 20 8260B 11/14/11 17:12 MGB PlK0284 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 11/14/11 17:12 MGB PlK0284 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 11/14/11 17:12 MGB PlK0284 Toluene 930 ug/L 10 0.85 20 8260B 11114/11 17:12 MGB PlK0284 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 11/14/11 17:12 MGB PlK0284 trans- 1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 11/14/11 17:12 MGB PlK0284 Trichloroethylene BRL ug/L 10 1.1 20 8260B 11/14/11 17:12 MGB PlK0284 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 11/14/11 17:12 MGB PlK0284 Vinyl acetate BRL ug/L 40 2.0 20 8260B 11/14/11 17:12 MGB PlK0284 Vinyl chloride BRL ug/L 10 3.1 20 8260B 11/14/11 17:12 MGB PlK0284 Surrogate Recovery Control Limits This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 7 of 37 ZP R I S M I Full -Service Analytical 8 Envirottmental Solutions �'h ueuanrowies urc. Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Sample Matrix: Water Laboratory Report 11 /29/2011 Client Sample ID: MW-20 Prism Sample ID: 1110283-02 Prism Work Order: 1110283 Time Collected: 11 /09/11 07:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DatelTime ID 4-Bromofluorobenzene 105 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 99 % 77-123 This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1.800/529-6364 - Fax: 704/525-0409 Page 8 of 37 PRISM Laboratory Report Full -Service Analytical 6 Environmental Solutions 11/29/2011 �!. usonnroeies Inc. Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1110283-03 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 08:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic BRL mg/L 0.010 0.0018 1 6010C 11/16/11 14:42 LTB PlK0349 Cadmium BRL mg/L 0.0010 0.00017 1 6010C 11/16/11 14:42 LTB PlK0349 Chromium BRL mg/L 0.0050 0.00070 1 6010C 11/16/11 14:42 LTB PlK0349 Copper 0.46 mg/L 0.010 0.00022 1 6010C 11/16/11 14:42 LTB PlK0349 Lead 0.030 mg/L 0.0050 0.00073 1 6010C 11/17/11 10:48 LTB P1K0349 Selenium 0.044 H mg/L 0.020 0.0035 1 6010C 11116/11 14:42 LTB P1K0349 Silver BRL mg/L 0.0050 0.00017 1 6010C 11/16/11 14:42 LTB P1K0349 Zinc 0.56 mg/L 0.030 0.027 1 6010C 11/16/11 14:42 LTB PlK0349 Anions by Ion Chromatography Chloride 140 mg/L 20 0.10 20 9056A 11/22/11 19:17 cde PlKO508 Sulfate 7300 mg/L 1000 3.9 1000 9056A 11/28/11 19:02 CDE P1K0565 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 11/17/11 12:23 BGM PlKO346 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 11/14/11 17:39 MGB PIK0284 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 11/14/11 17:39 MGB PlK0284 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 11/14/11 17:39 MGB PlK0284 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 11/14/11 17:39 MGB P1K0284 1,1-Dichloroethane 28 ug/L 10 1.9 20 8260E 11114/11 17:39 MGB PIK0284 1.1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 11/14/11 17:39 MGB P1K0284 1,1-Dichloropropylene BRL ug/L 10 1.2 20 8260B 11/14/11 17:39 MGB PIK0284 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 11/14/11 17:39 MGB PlK0284 1,2,3-Trichooropropane BRL ug/L 20 1.6 20 8260B 11/14/11 17:39 MGB PlK0284 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 11/14/11 17:39 MGB P1K0284 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 11/14/11 17:39 MGB P1K0284 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 11/14/11 17:39 MGB P1K0284 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 11/14/11 17:39 MGB PIK0284 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 11/14/11 17:39 MGB PlK0284 1,2-Dichloroethane 130 ug/L 10 2.8 20 8260B 11/14/11 17:39 MGB PIK0284 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 11/14/11 17:39 MGB P1K0284 1.3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 11/14/11 17:39 MGB P1K0284 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 11/14/11 17:39 MGB P1K0284 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 11/14/11 17:39 MGB P1K0284 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 11/14/11 17:39 MGB PIK0284 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 11/14/11 17:39 MGB PlK0284 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 11/14/11 17:39 MGB PlK0284 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 11/14/11 17:39 MGB PlK0284 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 11/14/11 17:39 MGB P1K0284 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 11/14/11 17:39 MGB P1K0284 Acetone 23000 ug/L 10000 1200 2000 8260B 11/15111 9:28 MGB PlK0284 Acrolein BRL ug/L 400 22 20 8260B 11/14/11 17:39 MGB PIK0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041526-0409 Page 9 of 37 ZRRISM I Full -Service Analytical a Laboratory Report Environmental Solutions 1 1 /29/2011 L-... -- Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1110283-03 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 08:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acrylonitrile BRL ug/L 400 17 20 8260B 11/14/11 17:39 MGB PIK0284 Benzene 80 ug/L 10 1.4 20 8260E 11/14/11 17:39 MGB PlK0284 Bromobenzene BRL ug/L 10 1.3 20 8260B 11/14/11 17:39 MGB P1K0284 Bromochloromethane 30 ug/L 10 2.6 20 8260B 11114/11 17:39 MGB PIK0284 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 11/14/11 17:39 MGB PlK0284 Bromoform BRL ug/L 20 5.4 20 8260B 11/14/11 17:39 MGB PlK0284 Bromomethane 340 ug/L 20 9.3 20 8260B 11/14111 17:39 MGB PIK0284 Carbon disulfide BRL ug/L 100 28 20 8260B 11/14/11 17:39 MGB PlK0284 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 11/14/11 17:39 MGB PIK0284 Chlorobenzene 190 ug/L 10 1.2 20 8260B 11/14/11 17:39 MGB PIK0284 Chloroethane 1000 ug1L 10 2.6 20 8260B 11/14/11 17:39 MGB PlK0284 Chloroform BRL ug/L 10 1.8 20 8260B 11/14/11 17:39 MGB PlK0284 Chloromethane 1800 ug/L 100 22 200 8260B 11114/11 18:05 MGB PlK0284 cis-1,2-Dichloroethylene 330 ug/L 10 1.5 20 8260B 11114/11 17:39 MGB PIK0284 cis- 1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 11/14/11 17:39 MGB PlK0284 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 11/14/11 17:39 MGB PlK0284 Dibromomethane BRL ug/L 10 2.6 20 8260B 11/14/11 17:39 MGB PlK0284 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 11/14/11 17:39 MGB PlK0284 Ethylbenzene 25 ug1L 10 1.3 20 8260B 11/14/11 17:39 MGB PlK0284 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 11/14/11 17:39 MGB PlK0284 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 11/14/11 17:39 MGB PlK0284 Isopropylbenzene(Cumene) BRL ug/L 10 1.4 20 8260B 11/14/11 17:39 MGB PlK0284 m,p-Xylenes 58 ug/L 20 1.6 20 8260B 11/14/11 17:39 MGB PIK0284 Methyl Butyl Ketone (2-Hexanone) 19 J ug/L 100 3.8 20 8260B 11/14/11 17:39 MGB PIK0284 Methyl Ethyl Ketone (2-Butanone) 320000 ug/L 50000 9000 10000 8260E 11/17/11 16:43 MGB PIK0284 Methyllsobutyl Ketone 20000 ug/L 10000 250 2000 8260E 11/15111 9:28 MGB PIK0284 Methylene Chloride 100 ug/L 20 8.9 20 8260B 11114111 17:39 MGB PlK0284 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 11/14/11 17:39 MGB P1K0284 Naphthalene BRL ug/L 20 2.0 20 8260B 11/14/11 17:39 MGB PIK0284 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 11/14/11 17:39 MGB PlK0284 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 11/14/11 17:39 MGB PIK0284 o-Xylene 19 ug/L 10 0.92 20 8260B 11114/11 17:39 MGB PIK0284 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 11/14/11 17:39 MGB PlK0284 Styrene BRL ug/L 10 0.94 20 8260B 11/14/11 17:39 MGB P1K0284 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 11/14/11 17:39 MGB PlK0284 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 11/14/11 17:39 MGB PlK0284 Toluene 61000 ug/L 5000 420 10000 8260B 11/17111 16:43 MGB PIK0284 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 11/14/11 17:39 MGB PlK0284 trans- 1, 3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 11/14/11 17:39 MGB PIK0284 Trichloroethylene BRL ug/L 10 1.1 20 8260B 11/14/11 17:39 MGB PlK0284 Thchlorofluoromethane BRL ug/L 10 1.8 20 8260B 11/14/11 17:39 MGB PlK0284 Vinyl acetate BRL ug/L 40 2.0 20 8260B 11/14/11 17:39 MGB PlK0284 Vinyl chloride BRL ug/L 10 3.1 20 8260B 11/14/11 17:39 MGB PlK0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Page 10 of 37 Phone: 7041529-6364 -Toll Free Number: 1-8001529-6364 -Fax: 704/525-0409 %PRISM Laboratory Report Full -Service Analytical 8 � Environmental Solutions 11/29/2011 �i UBOHPTOn1ES LNG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1110283-03 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 08:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 103 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529.6364 - Fax: 7041525-0409 Page 11 of 37 Full -Service Analytical& Laboratory Report ZRRISM I Environmental Solutions 1 1 /29/201 1 tnBOnATON1Ei LNG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1110283-04 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 09:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 0.048 mg/L 0.010 0.0018 1 6010C 11/16/11 14:49 LTB PIK0349 Cadmium 0.0095 mg/L 0.0010 0.00017 1 6010C 11116/11 14:49 LTB PIK0349 Chromium 0.19 mg/L 0.0050 0.00070 1 6010C 11/16/11 14:49 LTB PIK0349 Copper 0.49 mg/L 0.010 0.00022 1 6010C 11116/11 14:49 LTB PlK0349 Lead 0.066 mg/L 0.0050 0.00073 1 6010C 11/16111 14:49 LTB PIK0349 Selenium 0.044 H mg/L 0.020 0.0035 1 6010C 11/16/11 14:49 LTB PlK0349 Silver BRL mg/L 0,0050 0.00017 1 6010C 11/16/11 14:49 LTB P1K0349 Zinc 3.6 mg/L 0.030 0.027 1 6010C 11116/11 14:49 LTB PIK0349 Anions by Ion Chromatography Chloride 200 mg/L 20 0.10 20 9056A 11/22/11 20:43 cde PlKO508 Sulfate 12000 mg/L 1000 3.9 1000 9066A 11/28111 19:20 CDE PIK0565 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 11/17/11 12:27 BGM P1K0346 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 20 5.9 40 8260B 11/14/11 18:31 MGB PlK0284 1,1,1-Trichloroethane BRL ug/L 20 2.5 40 8260B 11/14/11 18:31 MGB P1K0284 1,1,2,2-Tetrachloroethane BRL ug/L 20 2.9 40 8260B 11/14/11 18:31 MGB P1K0284 1,1,2-Trichloroethane BRL ug/L 20 6.6 40 8260B 11/14/11 18:31 MGB P1K0284 1,1-Dichloroethane 23 ug/L 20 3.8 40 8260E 11/14/11 18:31 MGB PlK0284 1,1-Dichloroethylene BRL ug/L 20 3.1 40 8260B 11/14/11 18:31 MGB P1K0284 1.1-Dichloropropylene BRL ug/L 20 2.5 40 8260B 11/14/11 18:31 MGB P1K0284 1,2,3-Trichlorobenzene BRL ug/L 80 8.0 40 8260B 11/14/11 18:31 MGB P1K0284 1,2,3-Trichooropropane BRL ug/L 40 3.2 40 8260B 11/14/11 18:31 MGB P1K0284 1,2,4-Trichlorobenzene BRL ug/L 40 4.1 40 8260B 11/14/11 18:31 MGB P1K0284 1,2,4-Trimethylbenzene BRL ug/L 20 1.9 40 8260B 11/14/11 18:31 MGB PIK0284 1,2-Dibromo-3-chloropropane BRL ug/L 80 24 40 8260B 11/14/11 18:31 MGB P1K0284 1,2-Dibromoethane BRL ug/L 20 5.5 40 8260B 11/14/11 18:31 MGB P1K0284 1,2-Dichlorobenzene BRL ug/L 20 3.1 40 8260B 11/14/11 18:31 MGB P1K0284 1,2-Dichloroethane 36 ug/L 20 5.6 40 8260B 11114/11 18:31 MGB P1K0284 1,2-Dichloropropane BRL ug/L 20 5.1 40 8260B 11/14/11 18:31 MGB PlK0284 1,3,5-Trimethylbenzene BRL ug/L 20 2.3 40 8260B 11/14/11 18:31 MGB P1K0284 1,3-Dichlorobenzene BRL ug/L 20 3.0 40 8260B 11/14/11 18:31 MGB PIK0284 1,3-Dichloropropane BRL ug/L 20 4.4 40 8260B 11/14/11 18:31 MGB P1K0284 1,4-Dichlorobenzene BRL ug/L 20 2.7 40 8260B 11/14/11 18:31 MGB P1K0284 2,2-Dichloropropane BRL ug/L 80 4.6 40 8260B 11/14/11 18:31 MGB P1K0284 2-Chloroethyl Vinyl Ether BRL ug/L 80 9.0 40 8260B 11/14/11 18:31 MGB P1K0284 2-Chlorotoluene BRL ug/L 20 1.5 40 8260B 11/14/11 18:31 MGB P1K0284 4-Chlorotoluene BRL ug/L 20 2.1 40 8260B 11/14/11 18:31 MGB P1K0284 4-Isopropyltoluene BRL ug/L 20 2.6 40 82608 11/14/11 18:31 MGB P1K0284 Acetone 33000 ug/L 2000 250 400 8260B 11/14111 18:58 MGB PlK0284 Acrolein BRL ug/L 800 44 40 8260B 11/14/11 18:31 MGB P1K0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001629-6364 - Fax: 704/625.0409 Page 12 of 37 �P R I S M I Full -Service Analytical & Laboratory Report Environmental Solutions 11/29/2011 �" PIABORMIOMEA ING Withers & Rave nel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1110283-04 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 09:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acrylonitrile BRL ug/L 800 34 40 8260E 11/14/11 18:31 MGB P1K0284 Benzene 110 ug/L 20 2.9 40 8260B 11/14/11 18:31 MGB PIK0284 Bromobenzene BRL ug/L 20 2.6 40 8260B 11/14/11 18:31 MGB PlK0284 Bromochloromethane BRL ug/L 20 5.0 40 8260B 11/14/11 18:31 MGB PlK0284 Bromodichloromethane BRL ug/L 20 2.5 40 8260B 11/14/11 18:31 MGB PIK0284 Bromoform BRL ug/L 40 11 40 8260B 11/14/11 18:31 MGB PlK0284 Bromomethane 1300 ug/L 40 19 40 8260B 11/14/11 18:31 MGB PIK0284 Carbon disulfide BRL ug/L 200 55 40 8260B 11/14/11 18:31 MGB PIK0284 Carbon Tetrachloride BRL ug/L 20 4.7 40 8260B 11/14/11 18:31 MGB PlK0284 Chlorobenzene 190 ug/L 20 2.5 40 8260B 11/14/11 18:31 MGB PIK0284 Chloroethane 2000 ug/L 20 6.1 40 8260B 11/14/11 18:31 MGB PlK0284 Chloroform BRL ug/L 20 3.5 40 8260B 11/14/11 18:31 MGB PlK0284 Chloromethane 8800 ug/L 200 44 400 8260B 11/14/11 18:58 MGB PIK0284 cis-1,2-Dichloroethylene 110 ug/L 20 3.0 40 8260B 11114/11 18:31 MGB PIK0284 cis- 1,3-Dichloropropylene BRL ug/L 20 4.2 40 8260B 11/14/11 18:31 MGB PlK0284 Dibromochloromethane BRL ug/L 20 12 40 8260B 11/14/11 18:31 MGB PlK0284 Dibromomethane BRL ug/L 20 5.2 40 8260B 11/14/11 18:31 MGB PlK0284 Dichlorodifluoromethane BRL ug/L 40 4.3 40 8260B 11/14/11 18:31 MGB PlK0284 Ethylbenzene BRL ug/L 20 2.7 40 8260B 11/14/11 18:31 MGB PlK0284 Hexachlorobutadiene BRL ug/L 80 15 40 8260B 11/14/11 18:31 MGB PlK0284 Isopropyl Ether BRL ug/L 20 1.7 40 8260B 11/14/11 18:31 MGB PlK0284 Isopropylbenzene (Cumene) BRL ug/L 20 2.9 40 8260B 11/14/11 18:31 MGB PlK0284 m,p-Xylenes BRL ug/L 40 3.2 40 8260B 11/14/11 18:31 MGB PlK0284 Methyl Butyl Ketone (2-Hexanone) 33 J ug/L 200 7.6 40 8260B 11114/11 18:31 MGB PIK0284 Methyl Ethyl Ketone (2-Butanone) 370000 ug/L 50000 9000 10000 8260E 11/17/11 17:09 MGB PIK0284 Methyl Isobutyl Ketone 16000 ug/L 2000 50 400 8260E 11/14/11 18:58 MGB PIK0284 Methylene Chloride 110 ug/L 40 18 40 8260B 11114/11 18:31 MGB PIK0284 Methyl-tert-Butyl Ether BRL ug/L 20 2.8 40 8260B 11/14/11 18:31 MGB PlK0284 Naphthalene BRL ug/L 40 3.9 40 8260B 11/14/11 18:31 MGB PIK0284 n-Butylbenzene BRL ug/L 40 4.5 40 8260B 11/14/11 18:31 MGB PIK0284 n-Propylbenzene BRL ug/L 20 2.4 40 8260B 11/14/11 18:31 MGB PlK0284 o-Xylene BRL ug/L 20 1.8 40 8260B 11/14/11 18:31 MGB PlK0284 sec-Butylbenzene BRL ug/L 20 3.5 40 8260B 11/14/11 18:31 MGB PlK0284 Styrene BRL ug/L 20 1.9 40 8260B 11/14/11 18:31 MGB PlK0284 tert-Butylbenzene BRL ug/L 20 3.2 40 8260B 11/14/11 18:31 MGB PlK0284 Tetrachloroethylene BRL ug/L 20 2.8 40 8260B 11/14/11 18:31 MGB PlK0284 Toluene 41000 ug/L 200 17 400 8260E 11/14111 18:58 MGB PlK0284 trans- 1,2-Dichloroethylene BRL ug/L 20 4.6 40 8260B 11/14/11 18:31 MGB PlK0284 trans- 1,3-Dichloropropylene BRL ug/L 20 1.7 40 8260B 11/14/11 18:31 MGB PlK0284 Trichloroethylene BRL ug/L 20 2.2 40 8260B 11/14/11 18:31 MGB PlK0284 Trichlorofluoromethane BRL ug/L 20 3.5 40 8260B 11/14/11 18:31 MGB PlK0284 Vinyl acetate BRL ug/L 80 4.0 40 8260B 11/14/11 18:31 MGB PlK0284 Vinyl chloride BRL ug/L 20 6.2 40 82606 11/14/11 18:31 MGB PlK0284 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 13 of 37 /P R I S M ( Full -Service Analytical & Laboratory Report Environmental Solutions 1 1 /29/201 1 .. ueonnrowics we Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1110283-04 1410 Commwealth Drive Prism Work Order: 1110283 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 11/09/11 09:00 Time Submitted: 11/09/11 13:40 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor DatelTime ID Surrogate Recovery Control Limits 4-Bromofluorobenzene 106 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 100 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 14 of 37 S M I Full- Service Analytical r Environmental Solutions wauioaea, xc Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11 /29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0284 - 5030B Blank (P1K0284-BLK1) 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1, 1, 1 -Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1, 1 -Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethylbenzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethylbenzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 2.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis- 1,2-Dichloroethylene BRL 0.50 ug/L cis- 1.3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L Prepared & Analyzed: 11/14/11 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041526.0409 Page 15 of 37 /`P R ISM I Fun -Service Analytical^� Environmental Solutions .+. uo;,nwnmies nc Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11/29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0284 - 5030B Blank (P1K0284-BLK1) Prepared & Analyzed: 11/14/11 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec -Butyl benzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butylbenzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate 4-Bromofluorohenzene 25.8 ug/L 25.00 103 80-124 Surrogate: Dibromofluoromethane 24.5 ug/L 25.00 98 75-129 Surrogate: Toluene-d8 24.8 ug/L 25.00 99 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 16 Of 37 b.R I S M I Full -Service Analytical 9 Environmental Solutions UBORPTORIES IHO Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 11/29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0284 - 5030B LCS (P1K0284-BS1) 1,1-Dichloroethylene Benzene Chlorobenzene Toluene Trichloroethylene Surrogate. 4-B romofluorob enzene Surrogate: Dibromofluoromethane Surrogate: Toluene-d8 LCS Dup (PlK0284-BSD1) 1,1-Dichloroethylene Benzene Chlorobenzene Toluene Trichloroethylene Surrogate: 4-B romofluorob enzen e Surrogate: Dibromofluoromethane Surrogate: Toluene -dB Prepared & Analyzed: 11/14/11 21.4 0.50 ug/L 20.00 107 70-154 21.2 0.50 ug/L 20.00 106 77-128 20.7 0.50 ug/L 20.00 104 78-119 20.4 0.50 ug/L 20.00 102 76-131 21.0 0.50 ug/L 20.00 105 77-133 25.1 ug/L 25.00 101 80-124 24.6 ug/L 25.00 98 75-129 24.7 ug/L 25.00 99 77-123 Prepared & Analyzed: 11/14/11 22.6 0.50 ug/L 20.00 113 70-154 5 200 22.3 0.50 ug/L 20.00 112 77-128 5 200 21.9 0.50 ug/L 20.00 109 78-119 5 200 21.6 0.50 ug/L 20.00 108 76-131 6 200 22.1 0.50 ug/L 20.00 110 77-133 5 200 25.2 ug/L 25.00 101 80-124 25.0 ug/L 25.00 100 75-129 24.7 ug/L 25.00 99 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 17 of 37 zPRI S M I Full -Service Analytical Environmental Solutions !21lmlmmwwk IAPORATORIm- Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Total Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 11/29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0346 - 7470A Blank (P1K0346-BLK1) Prepared:11/16/11 Analyzed: 11/17/11 Mercury 0.0000142 0.00020 mg/L J LCS (P1K0346-BS1) Prepared: 11/16/11 Analyzed: 11/17/11 Mercury 0.00866 0.00020 mg/L 0.009375 92 80-120 Matrix Spike (PlK0346-MS1) Source: 1110283-01 Prepared: 11/16/11 Analyzed: 11/17/11 Mercury 0.00867 0.00020 mg/L 0.009375 BRL 93 80-120 Matrix Spike Dup (P1K0346-MSD1) Source: 1110283-01 Prepared: 11/16/11 Analyzed: 11/17/11 Mercury 0.00870 0.00020 mg/L 0.009375 BRL 93 80-120 0.3 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 37 APgR I S M Full -Service Analytical�- Environmental Solutions A IABOPATONIES LNG Level II QC Report 11 /29/11 Withers & Raven el -Wilmington Project: Henson Landfill Prism Work Order: 1110283 Attn: Brian Bellis Time Submitted: 11/9/2011 1:40:OOPM 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Reporting Spike Source °/REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0255 - SM3030 C Blank (P1K0255-BLK1) Prepared: 11/11/11 Analyzed: 11/16/11 Arsenic BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium 0.143 1.0 ug/L J Copper BRL 5.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 1.0 ug/L Zinc BRL 10 ug/L LCS (P1K0255-BS1) Prepared: 11 /11 /11 Analyzed: 11/16/11 Arsenic 257 1.0 ug/L 250.0 103 80-120 Cadmium 260 1.0 ug/L 250.0 104 80-120 Chromium 273 1.0 ug/L 250.0 109 80-120 Copper 266 5.0 ug/L 250.0 107 80-120 Lead 265 1.0 ug/L 250.0 106 80-120 Selenium 282 1.0 ug/L 250.0 113 80-120 Zinc 292 10 ug/L 250.0 117 80-120 Matrix Spike (P1K0255-MS1) Source: 1110283-01 Prepared. 11/11/11 Analyzed: 11/16/11 Arsenic 257 1.0 ug/L 250.0 1.93 102 75-125 Cadmium 257 1.0 ug/L 250.0 BRL 103 75-125 Chromium 263 1.0 ug/L 250.0 1.99 104 75-125 Copper 255 5.0 ug/L 250.0 1.40 101 75-125 Lead 243 1.0 ug/L 250.0 0.231 97 75-125 Selenium 275 1.0 ug/L 250.0 1.03 110 75-125 Zinc 288 10 ug/L 250.0 15.4 109 75-125 Matrix Spike Dup (P1K0255-MSD1) Source: 1110283-01 Prepared: 11/11/11 Analyzed: 11/16/11 Arsenic 248 1.0 ug/L 250.0 1.93 99 75-125 3 20 Cadmium 251 1.0 ug/L 250.0 BRL 101 75-125 2 20 Chromium 259 1.0 ug/L 250.0 1.99 103 75-125 2 20 Copper 251 5.0 ug/L 250.0 1.40 100 75-125 2 20 Lead 247 1.0 ug/L 250.0 0.231 99 75-125 2 20 Selenium 270 1.0 ug/L 250.0 1.03 108 75-125 2 20 Zinc 286 10 ug/L 250.0 15.4 108 75-125 0.8 20 This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 19 of 37 . R ISM I Full -Service oll Solutions S Environmental Solutions IABOI'4T -& - Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Batch PI K0349 - SM3030 C Project: Henson Landfill Level II QC Report 11/29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:OOPM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (P1K0349-BLK1) Prepared: 11 /11 /11 Analyzed: 11/16/11 Arsenic BRL 0.010 mg/L Cadmium BRL 0.0010 mg/L Chromium BRL 0.0050 mg/L Copper BRL 0.010 mg/L Lead BRL 0.0050 mg/L Selenium BRL 0.020 mg/L Silver BRL 0.0050 mg/L Zinc BRL 0.030 mg/L LCS (PlK0349-BSI) Prepared: 11 /11 /11 Analyzed: 11/16/11 Arsenic 0.272 0.010 mg/L 0.2500 109 80-120 Cadmium 0.278 0.0010 mg/L 0.2500 111 80-120 Chromium 0.263 0.0050 mg/L 0.2500 105 80-120 Copper 0.266 0.010 mg/L 0.2500 106 80-120 Lead 0.263 0.0050 mg/L 0.2500 105 80-120 Selenium 0.312 0.020 mg/L 0.2500 125 80-120 Silver 0.279 0.0050 mg/L 0.2500 112 80-120 Zinc 0.288 0.030 mg/L 0.2500 115 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/629-6364 - Fax: 704/525-0409 A, H Page 20 of 37 P R I S M I EnvFull-Service Analytical & iro ,&jJ nmental Solutions LABCInATORIEI iNC Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Level II QC Report 11/29/11 Prism Work Order: 1110283 Time Submitted: 11/9/2011 1:40:00PM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 K0508 - NO PREP Blank (P1K0508-BLK1) Prepared & Analyzed: 11/22/11 Chloride BRL 1.0 mg/L Sulfate BRL 1.0 mg/L LCS (P1K0508-BS1) Prepared & Analyzed: 11/22/11 Chloride 1,91 1.0 mg/L 2.000 96 80-120 Sulfate 2.10 1.0 mg/L 2.000 105 80-120 Batch P1 K0565 - NO PREP Blank (P1K0565-BLK1) Prepared & Analyzed: 11/23/11 Sulfate 0.137 1.0 mg/L J LCS (P1K0565-BS1) Prepared: 11/23/11 Analyzed: 11/28/11 Sulfate 1.99 1.0 mg/L 2.000 100 80-120 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final Date/Time 1110283-01 PlK0255 50 mL 50 mL 11/11/11 14:30 1110283-01 P1K0255 50 mL 50 mL 11/11/11 14:30 1110283-02 P1K0255 50 mL 50 mL 11/11/11 14:30 1110283-02 PIK0255 50 mL 50 mL 11/11/11 1430 1110283-03 PlK0349 50 mL 50 mL 11/11/11 14:30 1110283-03 PlK0349 50 mL 50 mL 11/11/11 1430 1110283-04 PlK0349 50 mL 50 mL 11/11/11 1430 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 1110283-01 P1K0346 20 mL 30 mL 11/16/11 12:20 1110283-02 PlKO346 20 mL 30 mL 11/16/11 12:20 1110283-03 PlKO346 20 mL 30 mL 11/16/11 12:20 1110283-04 PlKO346 20 mL 30 mL 11/16/11 12:20 Prep Method: 5030E Lab Number Batch Initial Final DatelTime 1110283-01 P1K0284 10 mL 10 mL 11/14/11 9:36 1110283-02 P1K0284 10 mL 10 mL 11/14/11 9:36 1110283-03 P1K0284 10 mL 10 mL 11/14/11 9:36 1110283-03 PlK0284 10 mL 10 mL 11/14/11 9:36 1110283-03 PlK0284 10 mL 10 mL 11/14/11 9:36 1110283-03 PlK0284 10 mL 10 mL 11/14/11 936 1110283-04 PlK0284 10 mL 10 mL 11/14/11 9:36 1110283-04 PlK0284 10 mL 10 mL 11/14/11 936 1110283-04 PlK0284 10 mL 10 mL 11/14/11 9:36 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 21 of 37 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis - 1110283-01 TOC (Sub) 1110283-02 TOC (Sub) 1110283-03 TOC (Sub) 1110283-04 TOC (Sub) I This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number. 1-8001529.6364 - Fax: 7041525-0409 Page 22 of 37 Ism IFullService Analytical Environmental Solutions LABORATORIFA ING 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Phone:704/529-6364 • Fax:704/525-0409 Client Company Name: W VIHIrM *-AM6tJ ✓(. Report To/Contact Name: 9. G CW6 Reporting Address: 1_4110 C6MMcfJtu6&Ai4 J)P%/G SW Lt. f0i UILM/NGroa; AIG 74463 Phone: Fax (Yes) (�o CHAIN OF CUSTODY RECORD PAGE —A— oFM QUOTE # TO ENSURE PROPER BILLING: Project Name: R6t4JSo,J LA -A) D P!Ji fi Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) *Please ATTACH any project specific reporting (OC LEVEL 1 II III IV) provisions and/or OC Requirements Invoice To- Address - CG Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL Email (Yes) (No) Email Address 10, iS Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC� EDD Type: PDF�_ Excel _Other "Working Days" ❑ 6-9 Days XStandard 10 days ❑ Rush Work Must Be Site Location Name: 11 91JS0A LAAJDPJk,(1 Pre -Approved Samples received after 15:00 will be processed next business day. SC OTHER N/A Site Location Physical Address: 41 iq f)S li LJ Y S Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NOV r-og6.S "� C I 'T /J C� (SEE REVERSE FOR TERMS &CONDITIONS REGARDING SERVICES Upon Collection: YES NO U Iced le Sam Y� RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) P P CLIENT SAMPLE DESCRIPTION ATE COL ECTED TIME COLLECTED MATRIX WATER OR SAMPLE CONTAINER PR T VESVA ANALYSES REQUESTED r 17 �$�r��� �Q/�f(� / REMARKS PRISM �� NO. SIZE HOURSY SLUDGE) SEE*TYPE BELOW ���+O� Sampler's Signature - Sampled By (Print Name) V I /J A/R.S C/J Affiliation Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been Initialized. Heungmshed ev: (si nature) Received For Prism Labors ries By: Date / �� `/D I fit>�.C�M�� Ic l/ Additional Comments: *fit Mv"00 itiCLUDE: A00iIC. CA-0MIQM CK(L'0MWA4 SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECI 7 AT THE LABORATORY. I �� �� 9 ❑ ❑ Fed Ex UPS VHand-delivered ❑ Prism Field Service ❑ Other ( NPDES: I UST'_ G . OUNDWATER: I DRINKING WATER: SOLID WASTE: I RCRA: CERCLA LANDFILL OTHER: MAR OM ❑ NO ❑ SC ❑ NO Cl SC In NO ❑ SC ❑ NC ❑ SC ❑ NC El SO ❑ NO ❑ SCI ❑ NO ❑ SC ❑ NO ❑ SC El NO ❑ SC 5u`L40 iUM ❑ ❑...._.. ❑ . _....._.... ❑ ...__.... _....... ❑ .. __ . _. ❑ _. _..._: ❑ ..... ❑__..._.-...._. ❑ . .------- .. Z-Itic, *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) =FOR SEE REVETERMS & C •- Ism I Full -Service al Solutions s CHAIN OF CUSTODY RECORD Environmental Solutions PAGE OF QUOTE # TO ENSURE PROPER BILLING: � LABORATORIES ING 449 Springbrook Road * P.O. Box 240543 • Charlotte, NC 28224-0543 Project Name: }-I 6;/U S or) LAA)0 P) (,L Phone: 704/529-6364 * Fax: 704/525-,0/�409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) Client Company Name: W %' *Please ATTACH any project specific reporting (OC LEVEL 1 II III IV) Report? To/Contact Name: L GELL1.5 provisions and/or OC Requirements Invoice To: Reporting Address: Address: - - CV t.ed2. _..� . N 3? I N _ a 'ACE7 Phone: q1n-7-56-9277 Fax (Yes) (No): Email (Yes) (No) Email Address 6Q"- 5C&W tTH&2st2hy(.n Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL , Requested Due Date ❑ 1 Da ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days (bM y Certification: NELAC USACE FL NC ✓ EDD Type: PDF_A Excel -Other "Working Days" ❑ 6-9 Days *tandard 10 days ❑ RushMust Be re Apo Work Site Location Name: H6,NSe o Site uU D F1LA, Samples received after 15:00 will be processed next business day. ved OTHER N/A Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO',/ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES Sample Iced Upon Collection: YES NO RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) SAMPLE DESCRIPTION CO ELECTED ATE TIME CMI THOURSY MATRIX SAMPLE CONTAINER PRT VES A. ANALYSES REQUESTED �1,CLIENT / REMARKS ��r�p *�✓/ PRISM ID NO. TYPE SLUDGE) SEE BELOW NO. SIZE ����0 ,� /vl.W- j .. _a9iva� Zot 6a00.._. lilgi�/( C& VOA. 3 40M1 GP I 2—S-0M A-G voA_ 3 .. 4o,. ID 1 c 1 r~ C G VOA 3 4o,.,[ cP:_ - -.... A-& voA 40 CP f Signature Sampled By (Print Name) LSorJ Affiliation W quishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. neunquisneo oy: tatgnamrel rlecelvee rsy: t5lgnalure) Uate MIIIIarylHOWS Additional Comments: Relinquished By: (Signature) Received By: (Signature) Date kPI&VAt-5 IAIU-VOC Ap,%N,C Relinquished By, (Signature) Re ived For Pri ab ratori s By: Date 13 U CADM IUA It Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODYWLSFOR TRANSPORTATION TO THE LABORATORY. O Group No. CRItoMW /!I SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL REC ED AT THE LABORATORY. / ❑ Fed Ex ❑ UPS Hand•delivered ElPrism Field Service ❑ Other / LVAP NPDES: i UST: I GROUNDWATER: DRINKING WATER: I SOLID WASTE: RCRA: I CERCLA LANDFILL OTHER: A%UA ,gXJ ❑ NC ❑ SC ❑ NC ❑ SC I 9NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC; ❑ NC ❑ SC ❑ NC ❑ SC ! ❑ NC ❑ SC SB( G/V IUNI ❑ ❑ .__ ❑ ❑...._ ❑ ❑ ❑ ❑ ❑... .. *CONTAINER TYPE CODES: A = Amber C = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) ZIn1G ORIGINAL ACCESS ANALYTICAL, INC. Primary Data Review By Int( 00ign Curtis Ekker Data Validation Manager, GCAL CLIENT Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 ATTENTION Angie Overcash PROJECTID 1110283 LABORATORY REPORT NUMBER 211111125 DATE 11/17/2011 Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 GSRI Avenue, Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Page 25 of 37 NELAP CERTIFICATE NUMBER 01955 DOD FLAP CERTIFICATE NUMBER ADE -1482 ANALYTICAL RESULTS PERFORMED BY GULF COAST ANALYTICAL LABORATORIES, INC. 7979 GSRI Avenue Baton Rouge, LA 70820 Report Date 11/17/2011 Giimiiuiuiiiiiuiiui�2iiidid1niiiiiii Deliver To Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 706-529-6364 Attn Angie Overcash Project 1110283 Page 26 of 37 CASE NARRATIVE y Client: Access Analytical Report: 211111125 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the sample cross-reference page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. CONVENTIONALS In the SM 5310B analysis, samples 21111112503 (MW-3) and 21111112504 (MW-2) had to be diluted in order to bracket the Total Carbon and/or Total Inorganic Carbon concentrations within the calibration range of the instrument. The Total Organic Carbon is based on the difference between the Total Carbon and the Inorganic Carbon. The dilution is reflected in the elevated reporting limit. r Page 27 of 37 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention j period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations Utilized in this Report ND Indicates the result was Not Detected at the specified RDL DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field PQL Practical Quantitation Limit MDL Method Detection Limit RDL Reporting Detection Limit 00:00 Reported as a time equivalent to 12:00 AM Reporting Flags Utilized in this Report J Indicates the result is between the MDL and RDL U Indicates the compound was analyzed for but not detected B Indicates the analyte was detected in the associated Method Blank Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with the NELAC standard and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer -readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Int &i$ign_ Robyn Migues Technical Director GCAL REPORT 211111125 Int� riSi THIS REPORT CONTAINS 1 PAGES. Page 28 of 37 Report Sample Summary GCAL ID Client ID Matrix Collect Datefrime Receive Date/Time 21111112501 MW-20A Water 11/09/201106:00 11/11/201108:40 21111112502 MW-20 Water 11/09/201107:00 11/11/201108:40 21111112503 MW-3 Water 11/09/201108:00 11/11/201108:40 21111112504 MW-2 Water 11/09/201109:00 11/11/201108:40 GCAL Report 211111125 Page 29 of 37. Summary of Compounds Detected SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 2.3 1.0 0.25 mg/L SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 26.3 1.0 0.25 mg/L SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 602 10.0 2.5 mg/L SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 800 10.0 2.5 mg/L GCAL Report 211111125 Page 30 of 37 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 11/15/201120:49 AEL 469341 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 2.3 1.0 0.25 mg/L GCAL Report 211111125 Page 31 of 37 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 11 /15/2011 22:11 AEL 469341 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 26.3 1.0 0.25 mg1L GCAL Report 211111125 Page 32 of 37 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 10 11/161201109:44 AEL 469341 CAS# Parameter C-012 Total Organic Carbon GCAL Report 211111125 Result RDL MDL Units 602 10.0 2.5 mg/L i i i i I I Page 33 of 37 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 10 111161201110:01 AEL 469341 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 800 10.0 2.5 mg/L GCAL Report 211111125 Page 34 of 37 v O w CA O h U-4 General Chemistry Quality Control Summary Analytical Batch 469341 Client ID MB469341 LCS469341 LCSD469341 Prep Batch N/A GCAL ID 1007007 1007008 1007009 Sample Type Method Blank LCS LCSD Analytical Date 11/15/2011 17:42 11/15/2011 18:02 11/15/2011 18:22 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 0.25U 0.25 50.01 50.1 100 80 - 120 50.9 102 2 25 Analytical Batch 469341 Client ID U31D201G 1006346MS 1006346MSD Prep Batch N/A GCAL ID 21111120701 1007010 1007011 Sample Type SAMPLE MS MSD Analytical Date 11/16/2011 00:07 11/16/2011 00:32 11/16/2011 00:49 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 169 1.3 250 411 97 75 - 1251 418 99 2 25 GCAL Report 211111125 W/o Pcs RR Full -Service Analytical & Ca18l I M I Environmental Solutions IAB0RAT0RIFA IM SUBCONTRACT ORDER Certification: NELACUSACE_ Prism Laboratories, Inc. SC O—ther W G 1110283 N/A SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Gulf Coast Analytical Labs, Inc. P. O. Box 240543 7979 GSRI Avenue Charlotte, NC 28224-0543 Baton Rouge, LA 70820 Phone: 800-529-6364 Phone :(225) 769-4900 Fax: 704-525-0409 Fax: (225) 767-5717 Project Manager: Angela D. Overcash Analysis Due Expires Laboratory ID Comments Sample ID: 1110283-01 Water Sampled:1110911106:00 TOC (Sub) 12/07/11 06:00 Containers Supplied: 2 X "t a rh l VC>N a A M 3 e jL l i C.i -_ ' '_ fin} y Sample ID: 1110283-02 .a •��. Water Sampled:1110911107:00 r .- °=-M /' TOC (Sub) 12/07/11 07:00 ontainers Supplied: Sample ID: 1110283-03 Water Samp►ed;11/09/1108:00 -- TOC (Sub) 12/07/11 08:00 ontainers Supplied - Sample 1D: 1110283-04 Water Sampled, 11/09/1109:00 > m Tnrn ie..tii tIJm Jt t fl0•n(1 Containers Supplied: --I, /00/r c 6J CX r'--( P l.'x 1 ilia C-I 64 C, Released By Date Received By Date S. S' 4�0 Page I of I Login Checklist GCALM11 GULF COAST ^F"L";M L4MMTOfflE% w SAMPLE RECEIVING CHECKLIST Workorder: 211111125 Client: 4565 - Access Analytical Profile: 80435 - Prism Lab- Line Item: 1 - Water BTEXINaoh/1VITBE Received by: Saucier. Charlotte Received Date/rime: 11/11/2011 8:40:00 AM Samples Received via: FEDEX Number of Coolers Received:T- 2 Cooler tracking numbers(s): _'j 1 (�jS 3 —1 Cooler temperature(s): 5 .(?)— Were all coolers received at a temperature of 0 - 60 C? 1✓:_ Yes r No 17. NIA Were all custody seals intact? r Yes 1- No F: NIA Were all samples received in proper containers? F Yes r No F N/A Were all samples properly preserved? lY Yes (— No F NIA Was preservative added to any container at the tab? 1- Yes ff No r NIA Were all containers received in good condition? IT Yes r7' No r NIA Were all VOA vials received with no head space? i- Yes r No 1✓ N/A Do all sample labels match the Chain of Custody? F Yes r No r NIA Was the client notified about any discrepancies? F Yes r No IT NIA (Votes/Comments: Page 1 of 1 http://webserverl/REX/Secure/LoginChecklist.asnx 11/11/2011 6 PRIqm�'ue Full-Service Analytical & Environmental Solutions Withers & Ravenel-Wilmington Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 NC Certification No. 402 SC Certification No. 99012 NC Drinking Water Cent No. 37735 Project: Henson Landfill Lab Submittal Date: 12/06/2011 Prism Work Order: 1120146 Case Narrative 12/15/2011 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. 1-11 6<�J VP Laboratory Services Data Qualifiers Key Reference: Reviewed By A Internal standard area above the QC limit. Compound reported with possible low bias. Not diluted due to reporting limit requirements. Aa Internal standard recovery above the QC limit. Element reported with low bias. Not diluted due to reporting limit requirements. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). M Matrix spike outside of the control limits. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 40 PFull-Sere Analytical s Environmenn tal Solutions 'R ISM M swear AT —Es. INC Sample Receipt Summary 12/15/2011 Prism Work Order: 1120146 Client Sample ID Lab Sample ID Matrix Date Sampled Date Received MW-20A 1120146-01 Water 12/06/11 12/06/11 MW-20 1120146-02 Water 12/06/11 12/06/11 MW-3 1120146-03 Water 12/06/11 12/06/11 MW-2 1120146-04 Water 12/06/11 12/06/11 Samples received in good condition at 2.5 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 2 of 40 Full -Service AnalyticalsUR I S M I Environmental Solutions 1A­1 LNG Summary of Detections 12/15/2011 Prism Work Order: 1120146 Prism ID Client ID Parameter Method Result Units 1120146-01 MW-20A Arsenic 6020A 1.9 ug/L 1120146-01 MW-20A Chromium 6020A 5.7 ug/L 1120146-01 MW-20A Copper 6020A 1.6 J ug/L 1120146-01 MW-20A Lead 6020A 0.61 J ug/L 1120146-01 MW-20A Silver 6020A 0.066 J ug/L 1120146-01 MW-20A Zinc 6020A 12 ug/L 1120146-01 MW-20A Chloride '9056A 1.8 mg/L 1120146-01 MW-20A Sulfate '9056A 34 mg/L 1120146-02 MW-20 Arsenic 6020A 52 ug/L 1120146-02 MW-20 Cadmium 6020A 0.78 J ug/L 1120146-02 MW-20 Chromium 6020A 7.6 ug/L 1120146-02 MW-20 Copper 6020A 4.5 J ug/L 1120146-02 MW-20 Lead 6020A 5.9 ug/L 1120146-02 MW-20 Selenium 6020A 0.78 J ug/L 1120146-02 MW-20 Silver 6020A 0.090 J ug/L 1120146-02 MW-20 Zinc 6020A 26 ug/L 1120146-02 MW-20 Chloride '9056A 52 mg/L 1120146-02 MW-20 Benzene 8260E 23 ug/L 1120146-02 MW-20 Chlorobenzene 8260E 80 ug/L 1120146-02 MW-20 cis-1,2-Dichloroethylene 8260B 64 ug/L 1120146-02 MW-20 m,p-Xylenes 8260E 16 J ug/L 1120146-02 MW-20 Toluene 8260E 2100 ug/L 1120146-03 MW-3 Arsenic 6020A 18 ug/L 1120146-03 MW-3 Cadmium 6020A 2.4 ug/L 1120146-03 MW-3 Chromium 6020A 10 ug/L 1120146-03 MW-3 Copper 6020A 160 ug/L 1120146-03 MW-3 Lead 6020A 2.1 Aa ug/L 1120146-03 MW-3 Selenium 6020A 9.1 ug/L 1120146-03 MW-3 Silver 6020A 0.090 J ug/L 1120146-03 MW-3 Zinc 6020A 280 ug/L 1120146-03 MW-3 Chloride '9056A 110 mg/L 1120146-03 MW-3 Sulfate '9056A 4300 mg/L 1120146-03 MW-3 1,1-Dichloroethane 8260E 13 ug/L 1120146-03 MW-3 1,2-Dichloroethane 8260E 67 ug/L 1120146-03 MW-3 Acetone 8260B 29000 ug/L 1120146-03 MW-3 Benzene 82606 47 ug/L 1120146-03 MW-3 Bromochloromethane 8260E 12 ug/L 1120146-03 MW-3 Bromomethane 8260E 31 ug/L 1120146-03 MW-3 Chlorobenzene 8260B 140 ug/L 1120146-03 MW-3 Chloroethane 8260B 440 ug/L 1120146-03 MW-3 Chloromethane 8260E 1000 ug/L 1120146-03 MW-3 cis-1,2-Dichloroethylene 8260E 170 ug/L 1120146-03 MW-3 Ethylbenzene 8260E 19 ug/L 1120146-03 MW-3 m,p-Xylenes 8260B 49 ug/L This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 3 of 40 �PRI S M Full -Service Analytical 8 Environmental Solutions �:. uecmn+onres �� Summary of Detections 12/15/2011 Prism Work Order: 1120146 Prism ID Client ID Parameter Method Result Units 1120146-03 MW-3 Methyl Butyl Ketone (2-Hexanone) 8260E 11 J ug/L 1120146-03 MW-3 Methyl Ethyl Ketone (2-Butanone) 8260E 160000 ug/L 1120146-03 MW-3 Methyl Isobutyl Ketone 8260B 18000 ug/L 1120146-03 MW-3 Methylene Chloride 8260B 41 ug/L 1120146-03 MW-3 o-Xylene 8260E 15 ug/L 1120146-03 MW-3 Toluene 8260E 54000 ug/L 1120146-04 MW-2 Arsenic 6020A 8.5 Aa ug/L 1120146-04 MW-2 Cadmium 6020A 8.5 Aa ug/L 1120146-04 MW-2 Chromium 6020A 110 Aa ug/L 1120146-04 MW-2 Copper 6020A 190 Aa ug/L 1120146-04 MW-2 Lead 6020A 5.3 Aa ug/L 1120146-04 MW-2 Selenium 6020A 28 A ug/L 1120146-04 MW-2 Silver 6020A 0.12 Aa, J ug/L 1120146-04 MW-2 Zinc 601oC 2.9 mg/L 1120146-04 MW-2 Chloride '9056A 200 mg/L 1120146-04 MW-2 Sulfate '9056A 9200 mg/L 1120146-04 MW-2 1,1-Dichloroethane 82603 28 ug/L 1120146-04 MW-2 1,2-Dichloroethane 82606 58 ug/L 1120146-04 MW-2 Acetone 8260E 45000 J ug/L 1120146-04 MW-2 Benzene 8260B 100 ug/L 1120146-04 MW-2 Bromomethane 8260B 500 ug/L 1120146-04 MW-2 Chlorobenzene 8260E 110 ug/L 1120146-04 MW-2 Chloroethane 8260B 1600 ug/L 1120146-04 MW-2 Chloromethane 82606 8500 ug/L 1120146-04 MW-2 cis-1,2-Dichloroethylene 82606 70 ug/L 1120146-04 MW-2 Methyl Butyl Ketone (2-Hexanone) 8260E 44 J ug/L 1120146-04 MW-2 Methyl Ethyl Ketone (2-Butanone) 8260E 430000 ug/L 1120146-04 MW-2 Methyl Isobutyl Ketone 8260E 13000 ug/L 1120146-04 MW-2 Methylene Chloride 8260E 92 ug/L 1120146-04 MW-2 Toluene 8260B 19000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240643 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 4 of 40 Laboratory Report PR R I S M Fun -Service Analytical 8 ZEnvironmental Solutions 12/15/2011 .� L-M - Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1120146-01 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 05:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 1.9 ug/L 1.0 0.12 1 6020A 12/12/11 13:55 DWR PIL0251 Cadmium BRL ug/L 1.0 0.20 1 6020A 12/12/11 13:55 DWR P1L0251 Chromium 5.7 ug/L 1.0 0.12 1 6020A 12/12/11 13:55 DWR P1L0251 Copper 1.6 J ug/L 5.0 0.53 1 6020A 12/12/11 13:55 DWR P1L0251 Lead 0.61 J ug/L 1.0 0.13 1 6020A 12/12111 13:55 DWR P1L0251 Selenium BRL ug/L 1.0 0.44 1 6020A 12/12/11 1355 DWR P1L0251 Silver 0.066 J ug/L 1.0 0.059 1 6020A 12/12/11 13:55 DWR PlL0251 Zinc 12 ug/L 10 0.58 1 6020A 12/15111 13:35 DWR P1L0251 Anions by Ion Chromatography Chloride 1.8 mg/L 1.0 0.0050 1 '9056A 12/8/11 13:48 RSL P1L0192 Sulfate 34 mg/L 10 0.039 10 '9056A 12/9111 11:17 CDE PlL0246 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 12/12/11 17:22 LTB PlL0208 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 0.50 0.15 1 8260B 12/7/11 18:03 MGB PlLO139 1,1,1-Trichloroethane BRL ug/L 0.50 0.063 1 8260B 12/7/11 18:03 MGB PlLO139 1,1,2,2-Tetrachloroethane BRL ug/L 0.50 0.071 1 8260B 12/7/11 18:03 MGB PlLO139 1,1,2-Trichloroethane BRL ug/L 0.50 0.17 1 8260B 12/7/11 18:03 MGB PlLO139 1,1-Dichloroethane BRL ug/L 0.50 0.096 1 8260B 12/7/11 18:03 MGB PlLO139 1,1-Dichloroethylene BRL ug/L 0.50 0.078 1 8260B 12/7/11 18:03 MGB PlLO139 1,1-Dichloropropylene BRL ug/L 0.50 0.061 1 8260B 12/7/11 18:03 MGB PlLO139 1,2,3-Trichlorobenzene BRL ug/L 2.0 0.20 1 8260B 12/7/11 18:03 MGB PlLO139 1,2,3-Trichooropropane BRL ug/L 1.0 0.081 1 8260B 12/7/11 18:03 MGB PlLO139 1,2,4-Trichlorobenzene BRL ug/L 1.0 0.10 1 8260B 12/7/11 18:03 MGB P1L0139 1,2,4-Trimethylbenzene BRL ug/L 0.50 0.048 1 8260B 12/7/11 18:03 MGB P1L0139 1,2-Dibromo-3-chloropropane BRL ug/L 2.0 0.59 1 8260B 12/7/11 18:03 MGB P1L0139 1,2-Dibromoethane BRL ug/L 0.50 0.14 1 8260B 1217/11 18:03 MGB P1L0139 1,2-Dichlorobenzene BRL ug/L 0.50 0.076 1 8260B 12/7/11 18:03 MGB P1L0139 1,2-Dichloroethane BRL ug/L 0.50 0.14 1 8260B 12/7/11 18:03 MGB P1L0139 1,2-Dichloropropane BRL ug/L 0.50 0.13 1 8260B 1217/11 18:03 MGB P1L0139 1,3,5-Trimethylbenzene BRL ug/L 0.50 0.057 1 8260B 12/7/11 18:03 MGB PlLO139 1,3-Dichlorobenzene BRL ug/L 0.50 0.074 1 8260B 12/7/11 18:03 MGB P1L0139 1,3-Dichloropropane BRL ug/L 0.50 0.11 1 8260B 12/7/11 18:03 MGB PlLO139 1,4-Dichlorobenzene BRL ug/L 0.50 0.068 1 8260B 12/7/11 18:03 MGB PlLO139 2,2-Dichloropropane BRL ug/L 2.0 0.11 1 8260B 12/7/11 18:03 MGB PlLO139 2-Chloroethyl Vinyl Ether BRL ug/L 2.0 0.22 1 8260B 12f7/11 1B:03 MGB PlLO139 2-Chlorotoluene BRL ug/L 0.50 0.038 1 8260B 1217/11 18:03 MGB PlLO139 4-Chlorotoluene BRL ug/L 0.50 0.053 1 8260B 12/7/11 18:03 MGB PlLO139 4-Isopropyltoluene BRL ug/L 0.50 0.065 1 8260B 12/7/11 1803 MGB PlLO139 Acetone BRL ug/L 5.0 0.62 1 8260B 12/7/11 1803 MGB PlLO139 Acrolein BRL ug/L 20 1.1 1 8260B 1217/11 1803 MGB PlLO139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 40 Laboratory Report P R I S M Full -Service Analytical & Environmental Solutions 12/15/2011 �9lr ueonnronies wc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1120146-01 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 05:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst DateirTime Batch ID Acrylonitrile BRL ug/L 20 0.86 1 8260B 1217/11 18:03 MGB PlLO139 Benzene BRL ug/L 0.50 0.072 1 8260B 12/7/11 18:03 MGB PlLO139 Bromobenzene BRL ug/L 0.50 0.064 1 8260B 1217/11 18:03 MGB PlLO139 Bromochloromethane BRL ug/L 0.50 0.13 1 8260B 1217/11 18:03 MGB PlLO139 Bromodichloromethane BRL ug/L 0.50 0.062 1 8260B 12/7/11 18:03 MGB PlLO139 Bromoform BRL ug/L 1.0 0.27 1 8260B 1217/11 18:03 MGB PlLO139 Bromomethane BRL ug/L 1.0 0.47 1 8260B 12/7/11 18:03 MGB PlLO139 Carbon disulfide BRL ug/L 5.0 1.4 1 8260B 12/7/11 18:03 MGB PlLO139 Carbon Tetrachloride BRL ug/L 0.50 0.12 1 8260B 12/7/11 18:03 MGB PlLO139 Chlorobenzene BRL ug/L 0.50 0.061 1 8260B 1217/11 18:03 MGB PlLO139 Chloroethane BRL ug/L 0.50 0.13 1 8260B 1217111 18:03 MGB PlLO139 Chloroform BRL ug/L 0.50 0.089 1 8260B 12/7/11 18:03 MGB PlLO139 Chloromethane BRL ug/L 0.50 0.11 1 8260B 1217/11 18:03 MGB PlLO139 cis-1,2-Dichloroethylene BRL ug/L 0.50 0.076 1 82606 12/7/11 18:03 MGB PlLO139 cis-1,3-Dichloropropylene BRL ug/L 0.50 0.10 1 8260B 12/7/11 18:03 MGB PlLO139 Dibromochloromethane BRL ug/L 0.50 0.30 1 8260B 12/7/11 18:03 MGB PlLO139 Dibromomethane BRL ug/L 0.50 0.13 1 8260B 12/7/11 18:03 MGB PlLO139 Dichlorodifluoromethane BRL ug/L 1.0 0.11 1 8260B 1217/11 18:03 MGB PlLO139 Ethylbenzene BRL ug/L 0.50 0.067 1 8260B 1217/11 18:03 MGB PlLO139 Hexachlorobutadiene BRL ug/L 2.0 0.36 1 8260B 1217/11 18:03 MGB PlLO139 Isopropyl Ether BRL ug/L 0.50 0.043 1 8260B 12/7/11 18:03 MGB PlLO139 Isopropylbenzene (Cumene) BRL ug/L 0.50 0.072 1 8260B 1217/11 18:03 MGB PIL0139 m,p-Xylenes BRL ug/L 1.0 0.081 1 8260B 12/7/11 18:03 MGB PlLO139 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 5.0 0.19 1 8260B 12/7/11 18:03 MGB PlLO139 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 5.0 0.90 1 8260B 12/7/11 18:03 MGB PlLO139 Methyl Isobutyl Ketone BRL ug/L 5.0 0.12 1 8260B 1217/11 18:03 MGB P11-0139 Methylene Chloride BRL ug/L 1.0 0.44 1 8260B 12/7111 18:03 MGB P11-0139 Methyl-tert-Butyl Ether BRL ug/L 0.50 0.070 1 8260B 12/7/11 18:03 MGB PlLO139 Naphthalene BRL ug/L 1.0 0.098 1 8260B 12/7/11 18:03 MGB P1L0139 n-Butylbenzene BRL ug/L 1.0 0.11 1 8260B 12/7/11 18:03 MGB PlLO139 n-Propylbenzene BRL ug/L 0.50 0.060 1 8260B 12/7/11 18:03 MGB PlLO139 o-Xylene BRL ug/L 0.50 0.046 1 8260B 12/7/11 18:03 MGB PlLO139 sec-Butylbenzene BRL ug/L 0.50 0.087 1 8260B 12/7/11 18:03 MGB PlLO139 Styrene BRL ug/L 0.50 0.047 1 8260B 1217/11 18:03 MGB PlLO139 tert-Butylbenzene BRL ug/L 0.50 0.080 1 8260B 12/7/11 18:03 MGB P11-0139 Tetrachloroethylene BRL ug/L 0.50 0.069 1 8260B 1217111 18:03 MGB P1L0139 Toluene BRL ug/L 0.50 0.042 1 8260B 1217/11 18:03 MGB PlLO139 trans-1,2-Dichloroethylene BRL ug/L 0.50 0.12 1 8260B 12/7/11 18:03 MGB PlLO139 trans- 1,3-Dichloropropylene BRL ug/L 0.50 0.043 1 8260B 12/7/11 18:03 MGB PlLO139 Trichloroethylene BRL ug/L 0.50 0.054 1 8260B 12/7/11 18:03 MGB PlLO139 Trichlorofluoromethane BRL ug/L 0.50 0.088 1 8260B 12/7/11 18:03 MGB PlLO139 Vinyl acetate BRL ug/L 2.0 0.10 1 8260B 1217111 18:03 MGB PlLO139 Vinyl chloride BRL ug/L 0.50 0.16 1 8260B 1217/11 18:03 MGB PlLO139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 6 of 40 PRISMI Full -Service Analytical & Laboratory Report Environmental Solutions 12/15/2011 /// " lne[wnTGN�ES �HC Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20A Attn: Brian Bellis Prism Sample ID: 1120146-01 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 05:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Surrogate Recovery Control Limits 4-Bromofluorobenzene Dibromofluoromethane Toluene-d8 104 % 80-124 97 % 75-129 102 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 40 /'PRISM Laboratory Report Full -Service Analytical 8 Environmental Solutions 12/15/2011 �. uaonwrowies rc Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1120146-02 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 06:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 52 ug/L 1.0 0.12 1 6020A 12/12/11 14:21 DWR P1L0251 Cadmium 0.78 J ug/L 1.0 0.20 1 6020A 12/12/11 14:21 DWR P1L0251 Chromium 7.6 ug/L 1.0 0.12 1 6020A 12/12/11 14:21 DWR PlL0251 Copper 4.5 J ug/L 5.0 0.53 1 6020A 12112/11 14:21 DWR P1L0251 Lead 5.9 ug/L 1.0 0.13 1 6020A 12/12/11 14:21 DWR P1L0251 Selenium 0.78 J ug/L 1.0 0.44 1 6020A 12/12111 14:21 DWR P1L0251 Silver 0.090 J ug/L 1.0 0.059 1 6020A 12112/11 14:21 DWR Fill L0251 Zinc 26 ug/L 10 0.58 1 6020A 12/15/11 13:44 DWR P1L0251 Anions by Ion Chromatography Chloride 52 mg/L 10 0.050 10 *9056A 1219111 12:06 CDE PlL0246 Sulfate BRL mg/L 1.0 0.0039 1 *9056A 12/8/11 14:04 RSL PlLO192 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 12/12/11 17:25 LTB PlL0208 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 12/7/11 18:33 MGB PlLO139 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 1217/11 18:33 MGB P11-0139 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 1217/11 18:33 MGB P11-0139 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 12/7/11 18:33 MGB PlLO139 1,1-Dichloroethane BRL ug/L 10 1.9 20 8260B 1217/11 18:33 MGB P11-0139 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 12/7/11 18:33 MGB PlLO139 1, 1 -Dichloropropylene BRL ug/L 10 1.2 20 8260B 12/7/11 18:33 MGB P11-0139 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 12/7/11 18:33 MGB P11-0139 1,2,3-Trichloropropane BRL ug/L 20 1.6 20 8260B 1217/11 18:33 MGB PlLO139 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 12/7/11 18:33 MGB P1L0139 1,2,4-Trimethylbenzene BRL ug/L 10 0.95 20 8260B 12/7/11 18:33 MGB PlLO139 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 12/7/11 18:33 MGB PlLO139 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 12/7/11 18:33 MGB PlLO139 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 12/7/11 18:33 MGB P11-0139 1,2-Dichloroethane BRL ug/L 10 2.8 20 8260B 1217/11 18:33 MGB PlLO139 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 12/7/11 18:33 MGB PlLO139 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 12/7/11 18:33 MGB PlLO139 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 1217/11 18:33 MGB P1L0139 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 12/7/11 18:33 MGB P1L0139 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 12/7/11 18:33 MGB PlLO139 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 12/7/11 18:33 MGB P1L0139 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 1217/11 18:33 MGB P11-0139 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 1217/11 18:33 MGB PlLO139 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 12/7/11 18:33 MGB P11-0139 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 12/7/11 18:33 MGB P11-0139 Acetone BRL ug/L 100 12 20 8260B 1217/11 18:33 MGB P11-0139 Acrolein BRL ug/L 400 22 20 8260E 1217/11 18:33 MGB PlLO139 This report should not be reproduced. except in its entirety, without the written consent of Prism Laboratories, Inc 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529.6364 - Fax: 7041525-0409 1 Page 8 of 40 Full -Service Analytical & Laboratory Report P R 1 S M Environmental Solutions 12/15/201 1 l2MMMWiK9k uecuw ...E.'- Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-20 Attn: Brian Bellis Prism Sample ID: 1120146-02 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 06:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Acrylonitrile BRL ug/L 400 17 20 8260B 12/7/11 18:33 MGB PlLO139 Benzene 23 ug/L 10 1.4 20 8260B 1217/11 18:33 MGB PIL0139 Bromobenzene BRL ug/L 10 1.3 20 8260B 12/7/11 18:33 MGB PlLO139 Bromochloromethane BRL ug/L 10 2.5 20 8260B 1217/11 18:33 MGB PlL0139 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 12/7/11 18:33 MGB PlLO139 Bromoform BRL ug/L 20 5.4 20 8260B 12/7/11 18:33 MGB PlLO139 Bromomethane BRL ug/L 20 9.3 20 8260B 12/7111 18:33 MGB PlLO139 Carbon disulfide BRL ug/L 100 28 20 8260E 1217/11 18:33 MGB PlLO139 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 12/7/11 18:33 MGB PlLO139 Chlorobenzene 80 ug/L 10 1.2 20 8260E 12/7/11 18:33 MGB PlLO139 Chloroethane BRL ug/L 10 2.6 20 8260B 12/7/11 18:33 MGB PlLO139 Chloroform BRL ug/L 10 1.8 20 8260B 12/7/11 18:33 MGB P1L0139 Chloromethane BRL ug/L 10 2.2 20 8260B 12/7/11 18:33 MGB PlLO139 cis-1,2-Dichloroethylene 64 ug/L 10 1.5 20 8260E 1217/11 18:33 MGB P1L0139 cis-1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 12/7/11 18:33 MGB PlLO139 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 12/7/11 18:33 MGB PlLO139 Dibromomethane BRL ug/L 10 2.6 20 8260B 12/7/11 18:33 MGB PlLO139 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 12/7/11 18:33 MGB PlLO139 Ethylbenzene BRL ug/L 10 1.3 20 82606 1217/11 18:33 MGB PlLO139 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 1217/11 18:33 MGB PlL0139 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 12/7/11 18:33 MGB PlLO139 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 12/7/11 18:33 MGB PlLO139 m,p-Xylenes 16 J ug/L 20 1.6 20 8260B 1217111 18:33 MGB PlLO139 Methyl Butyl Ketone (2-Hexanone) BRL ug/L 100 3.8 20 8260B 12/7/11 18:33 MGB PlLO139 Methyl Ethyl Ketone (2-Butanone) BRL ug/L 100 18 20 8260B 12/7/11 18:33 MGB P1L0139 Methyl Isobutyl Ketone BRL ug/L 100 2.5 20 8260B 12/7/11 18:33 MGB PlLO139 Methylene Chloride BRL ug/L 20 8.9 20 8260B 12/7/11 18:33 MGB PlLO139 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 12/7111 18:33 MGB PlLO139 Naphthalene BRL ug/L 20 2.0 20 8260B 12/7/11 18:33 MGB PlLO139 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 1217/11 18:33 MGB PlLO139 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 1217/11 18:33 MGB PlLO139 o-Xylene BRL ug/L 10 0.92 20 8260B 1217/11 18:33 MGB PlLO139 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 1217/11 18:33 MGB PlLO139 Styrene BRL ug/L 10 0.94 20 8260B 12/7/11 18:33 MGB PlLO139 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 1217/11 18:33 MGB PlLO139 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 1217/11 18:33 MGB PlLO139 Toluene 2100 ug/L 10 0.85 20 8260B 12/7/11 18:33 MGB PlLO139 trans-1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 12/7/11 18:33 MGB PlLO139 trans-1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 12/7/11 18:33 MGB PlLO139 Trichloroethylene BRL ug/L 10 1.1 20 8260B 12/7/11 18:33 MGB PlLO139 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 12/7/11 18:33 MGB PlLO139 Vinyl acetate BRL ug/L 40 2.0 20 8260B 12/7/11 18:33 MGB PlLO139 Vinyl chloride BRL ug/L 10 3.1 20 8260B 12/7/11 18:33 MGB PlLO139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 9 of 40 /RgR I S M I Full -Service Analytical Environmental Solutions UBOf1ATORIES ANC Withers & Raven el -Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Project: Henson Landfill Sample Matrix: Water Laboratory Report 12/15/2011 Client Sample ID: MW-20 Prism Sample ID: 1120146-02 Prism Work Order: 1120146 Time Collected: 12/06/11 06:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Surrogate Recovery Control Limits 4-Bromofluorobenzene 104 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 101 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 10 of 40 /RR I S M I Full -Service Analytical Environmental Solutions �t11!s: umanraaEs inc Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Laboratory Report 12/15/2011 Project: Henson Landfill Client Sample ID: MW-3 Prism Sample ID: 1120146-03 Prism Work Order: 1120146 Sample Matrix: Water Time Collected: 12/06/11 07:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 18 ug/L 1.0 0.12 1 6020A 12/12/11 14:29 DWR Fill L0251 Cadmium 2.4 ug/L 1.0 0.20 1 6020A 12/12/11 14:29 DWR P1L0251 Chromium 10 ug/L 1.0 0.12 1 6020A 12/12/11 14:29 DWR P1L0251 Copper 160 ug/L 5.0 0.53 1 6020A 12/12/11 14:29 DWR Fill L0251 Lead 2.1 Aa ug/L 1.0 0.13 1 6020A 12/12/11 14:29 DWR P1L0261 Selenium 9.1 ug/L 1.0 0.44 1 6020A 12/12111 14:29 DWR P1L0251 Silver 0.090 J ug/L 1.0 0.059 1 6020A 12/12111 14:29 DWR P1L0251 Zinc 280 ug/L 10 0.58 1 6020A 12/12111 14:29 DWR P1L0251 Anions by Ion Chromatography Chloride 110 mg/L 20 0.10 20 *9056A 1219/11 12:22 CDE PIL0246 Sulfate 4300 mg/L 1000 3.9 1000 *9056A 12/11/11 23:40 CDE PlL0256 Total Metals Mercury BRL mg/L 0.00020 0.000014 1 7470A 12/12/11 17:29 LTB PlL0208 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane BRL ug/L 10 2.9 20 8260B 1217/11 22:07 MGB PlLO139 1,1,1-Trichloroethane BRL ug/L 10 1.3 20 8260B 12/7/11 22:07 MGB PIL0139 1,1,2,2-Tetrachloroethane BRL ug/L 10 1.4 20 8260B 12/7/11 22:07 MGB PIL0139 1,1,2-Trichloroethane BRL ug/L 10 3.3 20 8260B 12/7/11 22:07 MGB PlLO139 1,1-Dichloroethane 13 ug/L 10 1.9 20 8260B 1217/11 22:07 MGB PIL0139 1,1-Dichloroethylene BRL ug/L 10 1.6 20 8260B 12/7/11 22:07 MGB PlLO139 1,1-Dichloropropylene BRL ug/L 10 1.2 20 8260B 12/7/11 22:07 MGB PlLO139 1,2,3-Trichlorobenzene BRL ug/L 40 4.0 20 8260B 1217/11 22:07 MGB PlLO139 1,2,3-Trichooropropane BRL ug/L 20 1.6 20 8260B 12/7/11 22:07 MGB PlLO139 1,2,4-Trichlorobenzene BRL ug/L 20 2.0 20 8260B 12/7/11 22:07 MGB PlLO139 1.2,4-Trimethyl benzene BRL ug/L 10 0.95 20 8260B 1217/11 22:07 MGB PlLO139 1,2-Dibromo-3-chloropropane BRL ug/L 40 12 20 8260B 12/7/11 22:07 MGB PlLO139 1,2-Dibromoethane BRL ug/L 10 2.7 20 8260B 1217/11 22:07 MGB P1L0139 1,2-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 12/7/11 22:07 MGB PIL0139 1,2-Dichloroethane 67 ug/L 10 2.8 20 8260B 12/7111 22:07 MGB PIL0139 1,2-Dichloropropane BRL ug/L 10 2.5 20 8260B 12/7/11 22:07 MGB PlLO139 1,3,5-Trimethylbenzene BRL ug/L 10 1.1 20 8260B 12/7/11 22:07 MGB PlLO139 1,3-Dichlorobenzene BRL ug/L 10 1.5 20 8260B 12/7/11 22:07 MGB PlLO139 1,3-Dichloropropane BRL ug/L 10 2.2 20 8260B 1217/11 22:07 MGB PlLO139 1,4-Dichlorobenzene BRL ug/L 10 1.4 20 8260B 12r7/11 22:07 MGB PlLO139 2,2-Dichloropropane BRL ug/L 40 2.3 20 8260B 12/7/11 22:07 MGB PlLO139 2-Chloroethyl Vinyl Ether BRL ug/L 40 4.5 20 8260B 12/7/11 22:07 MGB PlLO139 2-Chlorotoluene BRL ug/L 10 0.76 20 8260B 12/7/11 22:07 MGB PIL0139 4-Chlorotoluene BRL ug/L 10 1.1 20 8260B 12/7/11 22:07 MGB PlLO139 4-Isopropyltoluene BRL ug/L 10 1.3 20 8260B 1217/11 2207 MGB PlLO139 Acetone 29000 ug/L 10000 1200 2000 8260B 12/7111 23:08 MGB PIL0139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 40 PRISMI Full -Service Analytical & ? Environmental Solutions ufS Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Sample Matrix: Water Laboratory Report 12/15/2011 Client Sample ID: MW-3 Prism Sample ID: 1120146-03 Prism Work Order: 1120146 Time Collected: 12/06/11 07:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Acrolein BRL ug/L 400 22 20 8260B 12/7/11 22:07 MGB PlLO139 Acrylonitrile BRL ug/L 400 17 20 8260B 12/7/11 22:07 MGB PlLO139 Benzene 47 ug/L 10 1.4 20 8260E 1217/11 22:07 MGB PIL0139 Bromobenzene BRL ug/L 10 1.3 20 8260B 1217/11 22:07 MGB PlLO139 Bromoch lorom ethane 12 ug/L 10 2.5 20 8260E 1217/11 22:07 MGB PlL0139 Bromodichloromethane BRL ug/L 10 1.2 20 8260B 12/7/11 22:07 MGB PlLO139 Bromoform BRL ug/L 20 5.4 20 8260B 1217/11 22:07 MGB PlLO139 Bromomethane 31 ug/L 20 9.3 20 8260E 12/7111 22:07 MGB PIL0139 Carbon disulfide BRL ug/L 100 28 20 8260E 12/7/11 22:07 MGB PlLO139 Carbon Tetrachloride BRL ug/L 10 2.4 20 8260B 1217/11 22:07 MGB PlLO139 Chlorobenzene 140 ug/L 10 1.2 20 8260B 1217/11 22:07 MGB PlLO139 Chloroethane 440 ug/L 10 2.6 20 8260B 1217/11 22:07 MGB PlL0139 Chloroform BRL ug/L 10 1.8 20 8260B 12/7/11 22:07 MGB PlLO139 Chloromethane 1000 ug/L 10 2.2 20 8260B 12/7/11 22:07 MGB PlLO139 cis-1,2-Dichloroethylene 170 ug/L 10 1.5 20 8260B 1217111 22:07 MGB PlLO139 cis-1,3-Dichloropropylene BRL ug/L 10 2.1 20 8260B 12/7111 22:07 MGB PlLO139 Dibromochloromethane BRL ug/L 10 6.0 20 8260B 12/7/11 22:07 MGB PIL0139 Dibromomethane BRL ug/L 10 2.6 20 8260B 12/7/11 22:07 MGB PlLO139 Dichlorodifluoromethane BRL ug/L 20 2.1 20 8260B 12/7/11 22:07 MGB PlLO139 Ethylbenzene 19 ug/L 10 1.3 20 8260E 12/7111 22:07 MGB PIL0139 Hexachlorobutadiene BRL ug/L 40 7.3 20 8260B 12/7/11 22:07 MGB PlLO139 Isopropyl Ether BRL ug/L 10 0.87 20 8260B 12/7/11 22:07 MGB PlLO139 Isopropylbenzene (Cumene) BRL ug/L 10 1.4 20 8260B 12/7/11 22:07 MGB PlLO139 m,p-Xylenes 49 ug/L 20 1.6 20 8260B 12/7/11 22:07 MGB PIL0139 Methyl Butyl Ketone (2-Hexanone) 11 J ug/L 100 3.8 20 8260E 12/7111 22:07 MGB PIL0139 Methyl Ethyl Ketone (2-Butanone) 160000 ug/L 10000 1800 2000 8260E 1217/11 23:08 MGB PIL0139 Methyl Isobutyl Ketone 18000 ug/L 1000 25 200 8260B 1217/11 22:37 MGB PIL0139 Methylene Chloride 41 ug/L 20 8.9 20 8260E 12/7111 22:07 MGB PIL0139 Methyl-tert-Butyl Ether BRL ug/L 10 1.4 20 8260B 12/7/11 22:07 MGB PlLO139 Naphthalene BRL ug/L 20 2.0 20 8260B 12/7/11 22:07 MGB PlLO139 n-Butylbenzene BRL ug/L 20 2.3 20 8260B 12/7/11 22:07 MGB PlLO139 n-Propylbenzene BRL ug/L 10 1.2 20 8260B 12/7/11 22:07 MGB PlLO139 o-Xylene 15 ug/L 10 0.92 20 8260B 12/7111 22:07 MGB PlLO139 sec-Butylbenzene BRL ug/L 10 1.7 20 8260B 12/7/11 22:07 MGB PlLO139 Styrene BRL ug/L 10 0.94 20 8260B 12/7/11 22:07 MGB PlLO139 tert-Butylbenzene BRL ug/L 10 1.6 20 8260B 12/7/11 22:07 MGB PlLO139 Tetrachloroethylene BRL ug/L 10 1.4 20 8260B 12/7/11 22:07 MGB PlLO139 Toluene 64000 ug/L 1000 85 2000 8260B 12/7/11 23:08 MGB PlLO139 trans- 1,2-Dichloroethylene BRL ug/L 10 2.3 20 8260B 1217111 22:07 MGB PlLO139 trans-1,3-Dichloropropylene BRL ug/L 10 0.87 20 8260B 12RIl1 22:07 MGB PlLO139 Trichloroethylene BRL ug/L 10 1.1 20 8260B 12/7/11 22:07 MGB PlLO139 Trichlorofluoromethane BRL ug/L 10 1.8 20 8260B 12/7/11 22:07 MGB PlLO139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 40 Laboratory Report Full -Service Analytical 8 P:R I S M Environmental Solutions -BONPT'JRIES ANC 12/15/2011 Withers & Raven el -Wilmington Project: Henson Landfill Client Sample ID: MW-3 Attn: Brian Bellis Prism Sample ID: 1120146-03 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 07:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Vinyl acetate BRL ug/L 40 2.0 20 8260B 12/7/11 22:07 MGB P1L0139 Vinyl chloride BRL ug/L 10 3.1 20 8260B 12/7/11 22:07 MGB PIL0139 Surrogate Recovery Control Limits 4-Bromofluorobenzene 103 % 80-124 Dibromofluoromethane 94 % 75-129 Toluene-d8 102 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/625-0409 Page 13 of 40 PRISM I Full -Service Analytical & Laboratory Report Environmental Solutions 12/15/2011 1AB011RTORIEi iNG Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1120146-04 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 08:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Arsenic 8.5 Aa ug/L 1.0 0.12 1 6020A 12/12111 14:38 DWR PIL0251 Cadmium 8.5 Aa ug/L 1.0 0.20 1 6020A 12/12/11 14:38 DWR P1L0251 Chromium 110 Aa ug/L 1.0 0.12 1 6020A 12/12/11 14:38 DWR PIL0261 Copper 190 Aa ug/L 5.0 0.53 1 6020A 12/12/11 14:38 DWR PIL0251 Lead 5.3 Aa ug/L 1.0 0.13 1 6020A 12112/11 14:38 DWR PlL0251 Selenium 28 A ug/L 1.0 0.44 1 6020A 12/12/11 14:38 DWR PlL0251 Silver 0.12 Aa, J ug/L 1.0 0.059 1 6020A 12/12/11 14:38 DWR PIL0251 Zinc 2.9 mg/L 0.030 0.027 1 601CC 12/14111 15:48 DWR PlLO188 Anions by Ion Chromatography Chloride 200 mg/L 50 0.25 50 '9056A 1219/11 12:64 CDE PlL0246 Sulfate 9200 mg/L 1000 3.9 1000 '9056A 12/11/11 23:66 CDE PlL0255 Total Metals Mercury Volatile Organic Compounds by GC/MS BRL mg/L 0.00020 0.000014 1 7470A 12/12/11 17:33 LTB PlL0208 1,1,1,2-Tetrachloroethane BRL ug/L 20 5.9 40 8260B 12/8/11 0:09 MGB PIL0139 1,1,1-Trichloroethane BRL ug/L 20 2.5 40 8260B 12/8/11 0:09 MGB PlLO139 1,1,2,2-Tetrachloroethane BRL ug/L 20 2.9 40 8260B 12/8/11 0:09 MGB PlLO139 1,1,2-Trichloroethane BRL ug/L 20 6.6 40 8260B 12/8/11 0:09 MGB PlLO139 1,1-Dichloroethane 28 ug/L 20 3.8 40 8260B 12/8111 0:09 MGB PlLO139 1,1-Dichloroethylene BRL ug/L 20 3.1 40 8260B 12/8/11 0:09 MGB PlLO139 1,1-Dichloropropylene BRL ug/L 20 2.5 40 8260B 12/8/11 0:09 MGB PlLO139 1,2,3-Trichlorobenzene BRL ug/L 80 8.0 40 8260B 12/8/11 0:09 MGB PlL0139 1,2,3-Trichloropropane BRL ug/L 40 3.2 40 8260B 12/8/11 0:09 MGB PlLO139 1,2,4-Trichlorobenzene BRL ug/L 40 4.1 40 8260B 12/8/11 0:09 MGB PlLO139 1,2,4-Trimethylbenzene BRL ug/L 20 1.9 40 8260B 12/8/11 0:09 MGB PlLO139 1,2-Dibromo-3-chloropropane BRL ug/L 80 24 40 8260B 12/8/11 0:09 MGB PIL0139 1,2-Dibromoethane BRL ug/L 20 5.5 40 8260B 12/8/11 0:09 MGB PlLO139 1,2-Dichlorobenzene BRL ug/L 20 3.1 40 8260B 12/8/11 0:09 MGB PlLO139 1,2-Dichloroethane 58 ug/L 20 5.6 40 8260E 12/8111 0:09 MGB PIL0139 1,2-Dichloropropane BRL ug/L 20 5.1 40 8260B 12/8/11 0:09 MGB PlLO139 1,3,5-Trimethylbenzene BRL ug/L 20 2.3 40 8260B 12/8/11 0:09 MGB PlLO139 1,3-Dichlorobenzene BRL ug/L 20 3.0 40 8260B 12/8/11 0:09 MGB PlL0139 1,3-Dichloropropane BRL ug/L 20 4.4 40 8260B 12/8/11 0:09 MGB PlL0139 1,4-Dichlorobenzene BRL ug/L 20 2.7 40 8260B 12/8/11 0:09 MGB PIL0139 2,2-Dichloropropane BRL ug/L 80 4.6 40 8260B 12/8/11 0:09 MGB PlLO139 2-Chloroethyl Vinyl Ether BRL ug/L 8o 9.0 40 8260B 12/8/11 0:09 MGB PlLO139 2-Chlorotoluene BRL ug/L 20 1.5 40 8260B 12/8/11 0:09 MGB PlLO139 4-Chlorotoluene BRL ug/L 20 2.1 40 8260B 12/8/11 0:09 MGB PIL0139 4-Isopropyltoluene BRL ug/L 20 2.6 40 8260B 12/8/11 0:09 MGB PlLO139 Acetone 45000 J ug/L 50000 6200 10000 8260B 12/8/11 1:10 MGB PIL0139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525.0409 Page 14 Of 40 /PRISM I Full -Service Analytical& Laboratory Report Environmental Solutions 12/15/2011 i uewwroaEi �t. Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1120146-04 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 08:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report Limit MDL Dilution Factor Method Analysis Date/Time Analyst Batch ID Acrolein BRL ug/L 800 44 40 8260E 12/8/11 0:09 MGB PlLO139 Acrylonitrile BRL ug/L 800 34 40 8260E 12/8/11 0:09 MGB PlLO139 Benzene 100 ug/L 20 2.9 40 8260B 12/8111 0:09 MGB PlLO139 Bromobenzene BRL ug/L 20 2.6 40 8260B 12/8/11 0:09 MGB PlLO139 Bromochloromethane BRL ug/L 20 5.0 40 8260B 12/8/11 0:09 MGB PlLO139 Bromodichloromethane BRL ug/L 20 2.5 40 8260B 12/8/11 0:09 MGB PlLO139 Bromoform BRL ug/L 40 11 40 8260B 12/8/11 0:09 MGB PlLO139 Bromomethane Soo ug/L 40 19 40 8260B 12/8111 0:09 MGB PlLO139 Carbon disulfide BRL ug/L 200 55 40 8260B 12/8/11 0:09 MGB PlLO139 Carbon Tetrachloride BRL ug/L 20 4.7 40 8260B 12/8/11 0:09 MGB PlLO139 Chlorobenzene 110 ug/L 20 2.5 40 8260B 1218111 0:09 MGB PlLO139 Chloroethane 1600 ug/L 20 5.1 40 8260B 1218/11 0:09 MGB PlLO139 Chloroform BRL ug/L 20 3.5 40 8260B 12/8/11 0:09 MGB PlLO139 Chloromethane 8500 ug/L 200 44 400 8260B 1218/11 0:40 MGB PlLO139 cis-1,2-Dichloroethylene 70 ug/L 20 3.0 40 8260E 1218/11 0:09 MGB PlLO139 cis-1,3-Dichloropropylene BRL ug/L 20 4.2 40 8260B 12/8/11 0:09 MGB PlLO139 Dibromochloromethane BRL ug/L 20 12 40 8260B 12/8/11 0:09 MGB P1L0139 Dibromomethane BRL ug/L 20 5.2 40 8260B 12/8/11 0:09 MGB P1L0139 Dichlorodifluoromethane BRL ug/L 40 4.3 40 8260B 12/8/11 0:09 MGB PlLO139 Ethylbenzene BRL ug/L 20 2.7 40 8260E 12/8/11 0:09 MGB P1L0139 Hexachlorobutadiene BRL ug/L 80 15 40 8260B 12/8/11 0:09 MGB PlLO139 Isopropyl Ether BRL ug/L 20 1.7 40 8260B 12/8/11 0:09 MGB PlLO139 Isopropylbenzene(Cumene) BRL ug/L 20 2.9 40 8260B 12/8/11 0:09 MGB PlLO139 m,p-Xylenes BRL ug/L 40 3.2 40 8260B 12/8/11 0:09 MGB PlLO139 Methyl Butyl Ketone (2-Hexanone) 44 J ug/L 200 7.6 40 8260B 12/8111 0:09 MGB PlLO139 Methyl Ethyl Ketone (2-Butanone) 430000 ug/L 50000 9000 10000 8260B 12/8/11 1:10 MGB PIL0139 Methyl Isobutyl Ketone 13000 ug/L 2000 5o 400 8260E 12/8/11 0:40 MGB PlLO139 Methylene Chloride 92 ug/L 40 18 40 8260B 12/8111 0:09 MGB P1L0139 Methyl-tert-Butyl Ether BRL ug/L 20 2.8 40 8260B 12/8/11 0:09 MGB PlLO139 Naphthalene BRL ug/L 40 3.9 40 8260B 12/8/11 0.09 MGB PlLO139 n-Butylbenzene BRL ug/L 40 4.5 40 8260B 12/8/11 0:09 MGB PlLO139 n-Propylbenzene BRL ug/L 20 2.4 40 8260B 12/8/11 0:09 MGB PlLO139 o-Xylene BRL ug/L 20 1.8 40 8260B 12/8/11 0:09 MGB PlLO139 sec-Butylbenzene BRL ug/L 20 3.5 40 8260B 12/8/11 0:09 MGB PlLO139 Styrene BRL ug/L 20 1.9 40 8260B 12/8/11 0:09 MGB PlLO139 tert-Butylbenzene BRL ug/L 20 3.2 40 8260B 12/8/11 0:09 MGB PlLO139 Tetrachloroethylene BRL ug/L 20 2.8 40 8260B 12/8/11 0:09 MGB P1 L0139 Toluene 19000 ug/L 200 17 400 8260E 1218/11 0:40 MGB Pi L0139 trans-1,2-Dichloroethylene BRL ug/L 20 4.6 40 8260B 12/8/11 0:09 MGB PlLO139 trans-1,3-Dichloropropylene BRL ug/L 20 1.7 40 8260B 12/8/11 0:09 MGB PlLO139 Trichloroethylene BRL ug/L 20 2.2 40 8260B 12/8/11 009 MGB P1L0139 Trichlorofluoromethane BRL ug/L 20 3.5 40 8260B 12/8/11 0:09 MGB P1L0139 Vinyl acetate BRL ug/L 80 4.0 40 8260B 12/8/11 009 MGB PlLO139 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 7041529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 40 T R I S M I En,iro men Analytical 8 Laboratory Report Environmental Solutions 12/15/2011 z�, 1-M.- Withers & Ravenel-Wilmington Project: Henson Landfill Client Sample ID: MW-2 Attn: Brian Bellis Prism Sample ID: 1120146-04 1410 Commwealth Drive Prism Work Order: 1120146 Wilmington, NC 28411 Sample Matrix: Water Time Collected: 12/06/11 08:00 Time Submitted: 12/06/11 11:39 Parameter Result Units Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Vinyl chloride BRL ug/L 20 6.2 40 82608 12/8/11 0:09 MGB PlLO139 Surrogate Recovery Control Limits 4-Bromofluorobenzene Dibromofluoromethane Toluene-d8 102 % 80-124 96 % 75-129 98 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 16 of 40 Full-Seniee /PR ISM I Evironmental Solutions �lnBonnlYJw�E3 �N(: Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P1 L0139 - 5030B Reporting Result Limit Units Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P1L0139-BLK1) Prepared & Analyzed: 12/07/11 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1. 1 -Dichloropropylene BRL 0.50 ug/L 1,2,3-Trichlorobenzene BRL 2.0 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2,4-Trichlorobenzene BRL 1.0 ug/L 1,2,4-Trimethylbenzene BRL 0.50 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,3,5-Trimethylbenzene BRL 0.50 ug/L 1,3-Dichlorobenzene BRL 0.50 ug/L 1,3-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L 2,2-Dichloropropane BRL 2.0 ug/L 2-Chloroethyl Vinyl Ether BRL 2.0 ug/L 2-Chlorotoluene BRL 0.50 ug/L 4-Chlorotoluene BRL 0.50 ug/L 4-Isopropyltoluene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrolein BRL 20 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromobenzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Dichlorodifluoromethane BRL 1.0 ug/L Ethylbenzene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224.0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 17 of 40 P R_ I S M EnFull-Service Analytical 8 vironmental Solutions ueauroa[a me Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Reporting Spike Source °/REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0139 - 5030B Blank (P1L0139-BLK1) Prepared & Analyzed: 12/07/11 Hexachlorobutadiene BRL 2.0 ug/L Isopropyl Ether BRL 0.50 ug/L Isopropylbenzene (Cumene) BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L Methyl-tert-Butyl Ether BRL 0.50 ug/L Naphthalene BRL 1.0 ug/L n-Butylbenzene BRL 1.0 ug/L n-Propylbenzene BRL 0.50 ug/L o-Xylene BRL 0.50 ug/L sec-Butylbenzene BRL 0.50 ug/L Styrene BRL 0.50 ug/L tert-Butyl benzene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Surrogate:4-Bromofluorobenzene 26.2 ug/L 25.00 105 80-124 Surrogate: Dibromofluoromethane 24.8 ug/L 25.00 99 75-129 Surrogate: Toluene-d8 25.4 ug/L 25.00 101 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1.800/529.6364 - Fax: 7041525-0409 Page 18 of 40 3 ZP:, I I Full -Service Analytical & M Environmental Solutions LTB7AFTD111E4, ING Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0139 - 5030B LCS (P1L0139-BSI) Prepared & Analyzed: 12/07/11 1,1-Dichloroethylene 20.6 0.50 ug/L 20.00 103 70-154 Benzene 20.6 0.50 ug/L 20.00 103 77-128 Chlorobenzene 20.1 0.50 ug/L 20.00 101 78-119 Toluene 20.8 0.50 ug/L 20.00 104 76-131 Trichloroethylene 20.8 0.50 ug/L 20.00 104 77-133 Surrogate:4-Bromofluorobenzene 24.8 ug/L 25.00 99 80-124 Surrogate: Dibromofluoromethane 25.1 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 24.7 ug/L 25.00 99 77-123 LCS Dup (P1L0139-BSD1) Prepared & Analyzed: 12/07/11 1,1-Dichloroethylene 19.5 0.50 ug/L 20.00 97 70-154 6 200 Benzene 20.1 0.50 ug/L 20.00 101 77-128 3 200 Chlorobenzene 19.8 0.50 ug/L 20.00 99 78-119 2 200 Toluene 20.2 0.50 ug/L 20.00 101 76-131 2 200 Trichloroethylene 20.5 0.50 ug/L 20.00 102 77-133 2 200 Surrogate:4-Bromofluorobenzene 24.8 ug/L 25.00 99 80-124 Surrogate: Dibromofluoromethane 24.7 ug/L 25.00 99 75-129 Surrogate: Toluene-d8 25.0 ug/L 25.00 100 77-123 Matrix Spike (P1L0139-MS1) Source: 1120146-01 Prepared & Analyzed: 12/07/11 1,1-Dichloroethylene 174 5.0 ug/L 200.0 BRL 87 65-162 Benzene 195 5.0 ug/L 200.0 BRL 97 73-131 Chlorobenzene 192 5.0 ug/L 200.0 BRL 96 76-119 Toluene 197 5.0 ug/L 200.0 BRL 98 72-135 Trichloroethylene 190 5.0 ug/L 200.0 BRL 95 72-133 Surrogate, 4-Bromofluorobenzene 24.5 ug/L 25.00 98 80-124 Surrogate. Dibromofluoromethane 25.0 ug/L 25.00 100 75-129 Surrogate: Toluene-d8 24.8 ug/L 25.00 99 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 19 of 40 &lP R I S M I Full -Service Analytical Environmental Solutions Withers & Ravenel-Wilmington Project: Henson Landfill Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0139 - 5030B Matrix Spike Dup (P1L0139-MSD1) Source: 1120146-01 Prepared & Analyzed: 12/07/11 1,1-Dichloroethylene 166 5.0 ug/L 200.0 BRL 83 65-162 5 20 Benzene 188 5.0 ug/L 200.0 BRL 94 73-131 4 17 Chlorobenzene 188 5.0 ug/L 200.0 BRL 94 76-119 2 20 Toluene 191 5.0 ug/L 200.0 BRL 95 72-135 3 18 Trichloroethylene 186 5.0 ug/L 200.0 BRL 93 72-133 2 17 Surrogate:4-Bromofluorobenzene 24.4 ug/L 25.00 98 80-124 Surrogate: Dibromofluoromethane 24.7 ug/L 25.00 99 75-129 Surrogate: Toluene-d8 24.8 ug/L 25.00 99 77-123 This report should not be reproduced.. except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 20 of 40 %P R I S M I Full -Serowe Analytical Environmental Solutions .� � umnn & me Withers & Rave nel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 Total Metals - Quality Control Project: Henson Landfill Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:00AM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0208 - 7470A Blank (PIL0208-BLKI) Prepared & Analyzed: 12/12/11 Mercury BRL 0.00020 mg/L LCS (P1L0208-BSI) Prepared & Analyzed: 12/12/11 Mercury 0.00984 0.00020 mg/L 0.009375 105 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 21 of 40 . R I S M I Full -Service Analytical 8 v Environmental Solutions - Ie Aeon M we Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Batch P1 L0251 - SM3030 C Project: Henson Landfill Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (1311-0251-BLKII) Prepared: 12/08/11 Analyzed: 12/12/11 Arsenic BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead BRL 1.0 ug/L Selenium BRL 1.0 ug/L Silver BRL 1.0 ug/L Zinc 3.95 10 ug/L J LCS (PlL0251-BS1) Prepared: 12/08/11 Analyzed: 12/12/11 Arsenic 96.7 1.0 ug/L 100.0 97 80-120 Cadmium 94.2 1.0 ug/L 100.0 94 80-120 Chromium 104 1.0 ug/L 100.0 104 80-120 Copper 102 5.0 ug/L 100.0 102 80-120 Lead 96.9 1.0 ug/L 100.0 97 80-120 Selenium 95.0 1.0 ug/L 100.0 95 80-120 Silver 97.4 1.0 ug/L 100.0 97 80-120 Zinc 102 10 ug/L 100.0 102 80-120 Matrix Spike (PlL0251-MS1) Source: 1120146-01 Prepared: 12/08/11 Analyzed: 12/12/11 Arsenic 97.3 1.0 ug/L 100.0 1.93 95 75-125 Cadmium 94.8 1.0 ug/L 100.0 BRL 95 75-125 Chromium 108 1.0 ug/L 100.0 5.68 102 75-125 Copper 100 5.0 ug/L 100.0 1.63 98 75-125 Lead 97.6 1.0 ug/L 100.0 0.613 97 75-125 Selenium 94.8 1.0 ug/L 100.0 BRL 95 75-125 Silver 96.8 1.0 ug/L 100.0 0.0660 97 75-125 Zinc 110 10 ug/L 100.0 12.0 98 75-125 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 7041529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 7041525-0409 Page 22 of 40 PRISM I EuService Analytical � Environmental Solutions .It vi ��eonn,anes me Withers & Ravenel-Wilmington Attn: Brian Bellis 1410 Commwealth Drive Wilmington, NC 28411 3030C Metals - Quality Control Analyte Project: Henson Landfill Level II QC Report 12/15/11 Prism Work Order: 1120146 Time Submitted: 12/6/2011 11:39:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1L0251-SM3030 C Matrix Spike Dup (PlL0251-MSD1) Source: 1120146-01 Prepared: 12/08/11 Analyzed: 12/12/11 Arsenic 101 1.0 ug/L 100.0 1.93 99 75-125 3 20 Cadmium 95.4 1.0 ug/L 100.0 BRL 95 75-125 0.6 20 Chromium 109 1.0 ug/L 100.0 5.68 103 75-125 0.6 20 Copper 101 5.0 ug/L 100.0 1.63 100 75-125 1 20 Lead 97.3 1.0 ug/L 100.0 0.613 97 75-125 0.3 20 Selenium 101 1.0 ug/L 100.0 BRL 101 75-125 6 20 Silver 97.3 1.0 ug/L 100.0 0.0660 97 75-125 0.4 20 Zinc 112 10 ug/L 100.0 12.0 100 75-125 2 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0643 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 23 of 40 Level II QC ReportP R I S M I Full -Service Analytical & 12/15/11 Environmental Solutions � �weonnra+res u�c Withers & Ravenel-Wilmington Project: Henson Landfill Prism Work Order: 1120146 Attn: Brian Bellis Time Submitted: 12/6/2011 11:39:OOAM 1410 Commwealth Drive Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0192 - NO PREP Blank (PI L0192-BLK1) Prepared & Analyzed: 12/08/11 Chloride BRL 1.0 mg/L Sulfate BRL 1.0 mg/L LCS (P1L0192-BS1) Prepared & Analyzed: 12/08/11 Chloride 1.98 1.0 mg/L 2.000 99 80-120 Sulfate 1.96 1.0 mg/L 2.000 98 80-120 Batch P1 L0246 - NO PREP Blank (P1L0246-BLK1) Prepared & Analyzed: 12/09/11 Chloride BRL 1.0 mg/L Sulfate BRL 1.0 mg/L LCS (P1L0246-BS1) Prepared & Analyzed: 12/09/11 Chloride 1.97 1.0 mg/L 2.000 98 80-120 Sulfate 2.14 1.0 mg/L 2.000 107 80-120 Matrix Spike (PlL0246-MS1) Source: 1120146-01 Prepared & Analyzed: 12/09/11 Chloride 6.69 10 mg/L 5.000 2.72 79 80-120 M Sulfate 37.5 10 mg/L 5.000 33.6 79 80-120 M Matrix Spike Dup (P1L0246-MSD1) Source: 1120146-01 Prepared & Analyzed: 12/09/11 Chloride 6.73 10 mg/L 5.000 2.72 80 80-120 0.6 15 Sulfate 37.9 10 mg/L 5.000 33.6 85 80-120 0.8 15 Batch P1L0255 - NO PREP Blank (P11-0255-BLK1) Prepared & Analyzed: 12/11/11 Sulfate BRL 1.0 mg/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/629-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 Page 24 of 40 Level II QC Report R ISM I Full -Service Analytical , 2„ 5„ , »��� Environmental Solutions ,,. �' uEx�nn*a+ies we Withers & Rave nel-Wilmington Project: Henson Landfill Prism Work Order: 1120146 Attn: Brian Bellis Time Submitted: 12/6/2011 11:39:OOAM 1410 Commwealth Drive Wilmington, NC 28411 Anions by Ion Chromatography - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P1 L0255 - NO PREP LCS (1311-0255-BS1) Prepared & Analyzed: 12/11/11 Sulfate 2.02 1.0 mg/L 2.000 101 80-120 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final DatelTime 1120146-01 P1 L0251 50 mL 50 mL 12/08/11 9:45 1120146-01 P1L0251 50 mL 50 mL 12/08/11 9:45 1120146-02 P1 L0251 50 mL 50 mL 12/08/11 9:45 1120146-02 PlL0251 50 mL 50 mL 12/08/11 9:45 1120146-03 P1 L0251 50 mL 50 mL 12/08/11 945 1120146-04 P1 L0251 50 mL 50 mL 12/08/11 9:45 1120146-04 P1 LO188 50 mL 50 mL 12/08/11 9:45 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 1120146-01 P1L0208 20 mL 30 mL 12/12/11 9:45 1120146-02 P1L0208 20 mL 30 mL 12/12/11 9:45 1120146-03 PlL0208 20 mL 30 mL 12/12/11 9:45 1120146-04 PlL0208 20 mL 30 mL 12/12/11 9:45 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 1120146-01 P1 L0139 10 mL 10 mL 12/07/11 11:17 1120146-02 P1L0139 10 mL 10 mL 12/07/11 11,17 1120146-03 P1L0139 10 mL 10 mL 12/07/11 11:17 1120146-03 P1L0139 10 mL 10 mL 12/07/11 11:17 1120146-03 P1L0139 10 mL 10 mL 12/07/11 11:17 1120146-04 PlLo139 10 mL 10 mL 12/07/11 11:17 1120146-04 PlLO139 10 mL 10 mL 12/07/11 11:17 1120146-04 P1 LO139 10 mL 10 mL 12/07/11 11:17 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 1120146-01 TOC (Sub) 1120146-02 TOC (Sub) 1120146-03 TOC (Sub) 1120146-04 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 Page 25 of 40 I n A I Full -Service Analytical CHAIN OF CUSTODY RECORD 7 'v' Environmental Solutions ppgE OF QUOTE M TO ENSURE PROPER BILLINq: � IABORATORIFA INC. 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Project Name: "CA) So(Q (,AND 9 0, Phone: 704/529-6364 • Fax: 704/525-0409 Short Hold Analysis: (Yes) (No) UST Project: (Yes) (No) Client Company Name: W t i"606 t-9414tN6t- "Please ATTACH any project specific reporting (QC LEVEL 1 II III IV) Report To/Contact Name: (3. B 65 LLIS provisions and/or QC Requirements Reporting Address: 1410 CoMMbr�lwiii Lil{ OfZIVrs� Invoice To: syac Lot W1LMWCs?Ort nl0 2gItO3 Address: Phone: qID-Za- g7,71 Fax (Yes) (No)• Email (No) Email AddressB{iF,Cl.►50� NIjHERsRAvC.IEt..csNlPurchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL EDD Type: PD172L Excel Requested Due Date ❑ 1 Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC� _Other °Working Days" ❑ 6.9 Days eStandard 10 days ❑ Rush Work Must Be Site Location Name: HCAJAo1J u#�VOPIt,I. Proved Samples received after 15:00 will be processed next businesss day. ay. SC OTHER N/A Site Location Physical Address: W 19 US HW Y S Turnaround time Is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO�� Go'If!45� ��•• ; 7 CAT Y (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES r. N C RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES /No CLIENT TIME COLLECTED MATRIX SAMPLE CONTAINER A LYSES REQUESTED PRISM SAMPLE DESCRIPTION DATE COLLECTED MILITARY (SOIL, WATER OR PRESERVA• TIVES �`p� /�" �fir� ��� / REMARKS LAB TYPE HOURS SLUDGE) SEE BELOW,4111.!4 NO. SIZE �,ypr`�� yJ` v ID NO. w4zi=ilk eG VOA 3 qo l VAU-__. - - . ---- - . CAP I L /Ud fJ Lt p0 ub l HNo 5ampier•s Signature 1 Sampled By (Print Name) J" 11 1 taN I Affiliation W L Upon relinquishing, this Chain of Custody is your authorization for Prism to proceed with the analyses as requested above. Any changes must be submitted in writing to the Prism Project Manager. There will be charges for any changes after analyses have been initialized. i� - +- ---,•. n...... .. oy.%..u........ uace munarymlours Additional Comments: 6 p6c� �( �"tLiM,S IntcwpL: Relinquished By: (Signature) Received By: (Signature) Date J44f✓ NlC Relinquished By: (Signature) Received For P ' ab rie By: Data CA-b M t U M Method of Shipment: NOTE: ALL SAMPLE COOLERS SHOULD BE TAPED SHUT WITH CUSTODY SEALS FO NSPORTATION TO THE LABORATORY. COC Group No, vi /1 SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST COO UNTIL RECEIVED AT THE LABORATORY. (' [ &( f6 - ❑ Fed Ex ❑ UPS Hand -delivered ❑ Prism Field Service ❑ Other �\QQ LISAb NPDES: UST: GROUNDWATER: DRINKING WATER: SOLID WASTE: I RCRA: j CERCLA LANDFILL ;OTHER: MCRcvttI ❑ NC El SC: ElNC ❑ SC XNC ❑ SC I ONC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC ❑ NC ❑ SC SL�(,6ti rn 'CONTAINER TYPE CODES: A = Amber C = Clear G. = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) 19 ORIGINAL .d a I I Full -Service Analytical & Environmental Solutions .�LABORATORIE$ INC. 449 Springbrook Road • P.O. Box 240543 • Charlotte, NC 28224-0543 Phone:704/529-M • Fax:704/525-040n9 Client Company Name: W *(2, Report To/Contact Name: 98'I,L.I S Reporting Address: CHAIN OF CUSTODY RECORD PAGE Z OF It QUOTE w TO ENSURE PROPER BILLING: Project Name: M&NSo_/J L4N fl FI t.L Short Hold Analysis. (Yes) (No) UST Project: (Yes) (No) `Please ATTACH any project specific reporting (OC LEVEL 1 II 1111V) provisions and/or OC Requirements Invoice To: Address: Phone: e40IS-6-1274Fax (Yes) (No): Email (Yes) (No) Email Address Purchase Order No./Billing Reference TO BE FILLED IN BY CLIENT/SAMPLING PERSONNEL EDD Type: PDF� Excel Requested Due Date CI Day ❑ 2 Days ❑ 3 Days ❑ 4 Days ❑ 5 Days Certification: NELAC USACE FL NC —Other Site Location Name: _ F{ �iNSa,.1 LJ4n1 GI L� . Working Days" ❑ 6-9 Days Standard 10 days ❑ Pre-Ap ork rov d Be Samples received after 15:00 will be processed next business day. SC_ OTHER N/A — Site Location Physical Address: Turnaround time is based on business days, excluding weekends and holidays. Water Chlorinated: YES_ NO�_ (SEE REVERSE FOR TERMS & CONDITIONS REGARDING SERVICES RENDERED BY PRISM LABORATORIES, INC. TO CLIENT) Sample Iced Upon Collection: YES _ NO _ CLIENT SAMPLE DESCRIPTION DATE COLLECTED TIME COLLECTED MILITARY MATRIX (SOIL, WATER OR SAMPLE CONTAINER PRESERVA- TIVESLAB A ALYSES REQUESTED b /(/ ON REMARKS PRISM 'TYPE HOURS SLUDGE) SEE BELOW NO. SIZE ��oSa j����� �b/v ID NO. �� Mw -3 ol`s �Za� 6 to a �RTGR CG ydq . _ 3 'toMl RcL J - c,P�Ml.. Kn�o3 _ f - SE L 4�Cola 3 Ito M1 NO N _ --- ----- If HCl- - __...._GP _ ._. �_.._.....� L NonX..... ----�....� .. ✓ -- - - Upon relinquishing, this Chain of submitted in writing to the Prism Relinquished By: (Signature) ,.. r Al fpl_� Sampled By (Print Name) ll S V) /J !9 6AI?JQ fJ Affiliation W your authorization for Prism to proceed with the analyses as requested above. Any changes must be nager. There will be charges for any changes after analyses have been initialized. occ_ 24, Additional Comments: .& MC A L 3 i}(CSEN lG • ' Ch�M1vA� C111t,oMN u M SAMPLES ARE NOT ACCEPTED AND VERIFIED AGAINST CDC UNTIL RECEIVED AT THE LABORATORY. I ,... I I ❑ Fed Ex ❑ UPS ❑ Hand -delivered ❑ Prism Field Service ❑ Other l ` `P " NPDES: j UST: ❑❑ NO ❑ SC ❑❑ NO ❑ SC �cupej G��I1OUNDWATER: J&NC ❑ SC DRINKING WATER: ❑ NC ❑ SC SOLID WASTE: ! RCRA: I CERCLA LANDFILL ❑ NO ❑ SC ICING ❑ Sd ❑ NC ❑ SC i ❑ NC ❑ SC OTHER: ❑ NC ❑ SC gN(UM Z`� G AA IS M USE ONLY t71'e fAal Time K _s+ 1r...i "SfteUepanureTjme Field -Tech Fee µ PCK +Mileage _.. ❑ . . _. _....__.._ ❑ .. . _...... --._.. __.. ❑ ....... _...... -_ ❑ . - _..1 ❑ - ... .. I ❑ _._ . _ ❑ - ---- ORIGINAL *CONTAINER TYPE CODES: A = Amber 0 = Clear G = Glass P = Plastic; TL = Teflon -Lined Cap VOA = Volatile Organics Analysis (Zero Head Space) AccEss ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 ATTENTION Angie Overcash PROJECTID 1120146 LABORATORY REPORT NUMBER 211120810 DATE 12/12/2011 Primary Data Review By Secondary Data Review By In i i n Ashley B. Amick Curtis Ekker Project Manager, Access Analytical, Inc. Data Validation Manager, GCAL aamick@accessanalybcalinc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 GSRI Avenue, Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Page 28 of 40 NELAP CERTIFICATE NUMBER 09955 DOD FLAP CERTIFICATE NUMBER ADE - 1482 ANALYTICAL RESULTS PERFORMED BY GULF COAST ANALYTICAL LABORATORIES, INC. 7979 GSRI Avenue Baton Rouge, LA 70820 Report Date 12/12/2011 G`iiiuu�Report iiiiiiduiiiiiiiiluii Deliver To Prism Laboratories, Inc. PO BOX 240543 Charlotte, NC 28224 706-529-6364 Attn Angie Overcash Project 1120146 Page 29 of 40 CASE NARRATIVE Client: Access Analytical Report: 211120810 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the sample cross-reference page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. CONVENTIONALS In the SM 5310B analysis, samples 21112081003 (MW-3) and 21112081004 (MW-2) had to be diluted in order to bracket the Total Carbon and/or Total Inorganic Carbon concentrations within the calibration range of the instrument. The Total Organic Carbon is based on the difference between the Total Carbon and the Inorganic Carbon. The dilution is reflected in the elevated reporting limit. Page 30 of 40 r- Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations Utilized in this Report ND Indicates the result was Not Detected at the specified RDL DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field PQL Practical Quantitation Limit MDL Method Detection Limit RDL Reporting Detection Limit 00:00 Reported as a time equivalent to 12:00 AM Reporting Flags Utilized in this Report J Indicates the result is between the MDL and RDL U Indicates the compound was analyzed for but not detected B Indicates the analyte was detected in the associated Method Blank Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with the NELAC standard and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer -readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. DOD QSM as specified in the contract if applicable. Inte4ritign Robyn Migues Technical Director GCAL REPORT 21112081 IntbihiriS THIS REPORT CONTAINS PAGES. This report is in compliance with the Page 31 of 40 Report Sample Summary GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21112081001 MW-20A Water 12/06/201105:00 12/081201109:25 21112081002 MW-20 Water 12/06/201106:00 12108/201109:25 21112081003 MW-3 Water 12/06/201107:00 12/08/201109:25 21112081004 MW-2 Water 12/06/201108:00 12/08/201109:25 GCAL Report 211120810 Page 32 of 40 Summary of Compounds Detected SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 2.0 1.0 0.25 mg/L SM 5310B TOC CAN Parameter Result RDL MDL Units C-012 Total Organic Carbon 33.2 1.0 0.25 mg/L SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 392 10.0 2.5 mg/L SM 5310B TOC CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 707 20.0 5.1 mg/L GCAL Report 211120810 Page 33 of 40 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 12109/201117:15 AEL 470759 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 2.0 1.0 0.25 mg/L _i GCAL Report 211120810 Page 34 of 40 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 1 12/09/201118:34 AEL 470759 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 33.2 1.0 0.25 mg/L GCAL Report 211120810 Page 35 of 40 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 10 12/10/201112:53 DJH 470759 CAN Parameter Result RDL MDL Units C-012 Total Organic Carbon 392 10.0 2.5 mglL I i I I �j I i I i I I GCAL Report 211120810 Page 36 of 40 SM 5310B TOC Prep Date Prep Batch Prep Method Dilution Analyzed By Analytical Batch 20 12/10/201113:10 DJH 470759 CAS# Parameter Result RDL MDL Units C-012 Total Organic Carbon 707 20.0 5.1 mg/L GCAL Report 211120810 Page 37.of 40 General Chemistry Quality Control Summary Analytical Batch 470769 Client ID MB470759 LCS470759 LCSD470759 Prep Batch N/A GCAL ID 1013509 1013510 1013511 Sample Type Method Blank LCS LCSD Analytical Date 12/09/2011 10:42 12/09/2011 11:01 12/09/2011 11:15 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 0.250 0.25 50.0 49.5 99 80 - 1201 49.0 98 1 25 Analytical Batch 470769 Client ID 004 OUTFALL 120611 1012978MS 1012978MSD Prep Batch N/A GCAL ID 21112074502 1013512 1013513 Sample Type SAMPLE MS MSD Analytical Date 12/09/2011 12:08 12/09/2011 12:25 12/09/2011 12:44 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R 1 RPD Limit C-012 Total Organic Carbon 1 6.3 0.25 50.0 53.9 95 75 - 125 56.4 100 5 25 Analytical Batch 470759 Client ID L131D201G 1013235MS 1013235MSD Prep Batch N/A GCAL ID 21112082001 1013514 1013515 Sample Type SAMPLE MS MSD Analytical Date 12/09/2011 20:41 12/09/2011 21:09 12/09/2011 21:28 Matrix Water Water Water SM 5310B TOC Units mg/L Spike Result Control Result RPD Result RDL Added % R Limits % R % R RPD Limit C-012 Total Organic Carbon 67.0 1.3 1 2501 326 104 75 - 1251 326 104 0 25 "D �p GCAL Report 211120810 (D W 00 O O G�� 4505 ZM2-0bk0Iad5-1 � SUBCONTRACT ORDER Prism Laboratories, Inc. 1120146 SENDING LABORATORY: RECEIVING LABORATORY: Prism Laboratories, Inc. Gulf Coast Analytical Labs, Inc. P. O. Box 240543 7979 GSRI Avenue Charlotte, NC 28224-0543 Baton Rouge, LA 70820 Phone: 800-529-6364 Phone :(225) 7694900 Fax:704-525-0409 Fax: (225) 767-5717 Project Manager. Angela D. Overcash Analysts Due Expires Laboratory ID Comments a / Sample ID: 1120146-01 Water Sampled:12/06/1105:00 TOC (Sub) 01/03/12 05:00 Containers Supplied: Z x q om [ A P!('"]Z 67L t jU Ac �� G Sample ID: 1120146-02 Water Sampled:12/06/11 06:00 TOC (Sub) 01/03/12 06:00 Containers Supplied: Sample ID:1120146-03 Water Sampled:12/06/1107:00 a' TOC (Sub) 01/03/12 07:00 Containers Supplied. - Sample ID: 1120146-04 1 Water Sampled:12106/1108:00 TOC (Sub) 01/03/12 08:00 Containers Supplied; 1Fej CK 1 tIlOC"l�a bgo�- Page 1 of I Page 39 of 40 Login Checklist GCALNIB SAMPLE RECEIVING CHECKLIST Workorder 211120810 Client: 4565 - Access Analytical Profile: 80251- Prism Lab Line Item: t -Water BTEX/NaohtWBE Received by: Saucier. Charlotte Received Daterrime: 12/8/2011 9:25:00 AM Samples Received via: FEDEX Number of Coolers Received: �//} /gyp Cooler tracking numbers(s): ".�/—i,'!%D 1 %2 5E 4,902 Cooler temperature(s): V . `-1 Were all coolers received at a temperature of 0 - 60 C? r Yes (� No r N/A Were all custody seals Intact? Yes No r N/A Were all samples received in proper containers? F Yes r No r NIA Were all samples properly preserved? r Yes r No r NIA Was preservative added to any container at the lab? r Yes F No r NIA Were all containers received In good condition? r Yes r No r NIA Were all VOA vials received with no head space? r Yes r No _ F N/A Do all sample labels match the Chain of Custody? r Yes r No f N/A Was the client notified about any discrepancies? r Yes r No F N/A Notes/Comments: http://webserverl/REX/Secure/LoginChecklist.aspx Page 1 of I 12/8/2411 -J Page 40 of 40