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HomeMy WebLinkAboutNC0025135_PERMIT ISSUANCE_19950619NPDES DOCUMENT SCANNING COVER SNEET NPDES Permit: NC0025135 Huffman Finishing WWTP Permit Issuance Document Type: Wasteload Allocation Authorization to Construct (AtC) Permit Modification Complete File - Historical Compliance Speculative Limits Instream Assessment (67b) Environmental Assessment (EA) Permit History Document Date: June 19, 1995 This document is printed oa reuse papter - ignore any coatwmt on the reverse side State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director June 19, 1995 Mr. Lee T. Huffman Huffman Finishing Company P.O. Box 170 Granite Falls, North Carolina 28630 Subject: Permit Issuance NPDES Permit NCO025135 Huffman Finishing WWTP Caldwell County Dear Mr. Huffman: In accordance with your application for discharge permit received on September 27, 1994, we are forwarding herewith the subject State - NPDES permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the US Environmental Protection Agency dated December 6, 1983. Based on the draft permit comment letter received May 30, 1995, the following modifications and/or comments are offered: Discharge to Unnamed Tributary to Catawba River - • Deadline for Relocation - As requested, the date for relocation to the Catawba River is no longer specified on the effluent sheets. • Reduction in Monitoring Frequencies - The frequencies for all parameters except chromium have been reduced to monthly as requested. Since chromium is limited, the monitoring frequency will be weekly. • Change in toxicity test - The acute toxicity test that was originally placed in the permit on December 6, 1993, has been reinstated for discharge to the unnamed tributary to the Catawba River. Discharge to Catawba River - • Reduction in Monitoring Frequencies - The frequency for all parameters except chromium and antimony has been reduced to monthly as requested. Since chromium and antimony are limited, the monitoring frequencies will be weekly. • Deletion of Antimony limit - This limit cannot be removed at this time. Evaluation of existing monitoring data predicted a maximum value that would violate water quality standards. After monitoring for one year, data can be reevaluated by the Division at the facility's request. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-9919 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10 % post -consumer paper • Increase in Phenols limit - The Division of Environmental Health (DEH) has expressed concern about the location of Huffman's future outfall being upstream of the water intakes for the towns of Hickory and Long View. DEH would have preferred that Huffman relocate the outfall below these intakes. As a compromise, Huffman agreed to maintain the existing permitted limits at the Catawba River discharge location to minimize the relocation distance. For this reason, the phenols limit cannot be increased. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicative hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings, Post Office Drawer 27447, Raleigh, North Carolina 27611-7447. Unless such demand is made, this decision shall be final and binding. Please take notice this permit is not transferable. Part II, EA. addresses the requirements to be followed in case of change in ownership or control of this discharge. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Environmental Management or permits required by the Division of Land Resources, Coastal Area Management Act or any other Federal or Local governmental permit that may be required. If you have any questions concerning this permit, please contact Mr. Greg Nizich at telephone number 919n33-5083, ext. 541. Sincerely, Original Signed By David A, Goodrich A. Preston Howard, Jr., P.E. cc: Central Files Asheville Regional Office, Water Quality Section Mr. Roosevelt Childress, EPA Permits and Engineering Unit Facilities Assessment Unit (No BP) Aquatic Survey & Toxicology Unit Operator Training & Certification Unit Permit No. NCO025135 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES DIVISION OF ENVIRONMENTAL MANAGEMENT PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Huffman Finishing Company, Inc. is hereby authorized to discharge wastewater from a facility located at a site on US Highway 321 southeast of Granite Falls Caldwell County to receiving waters designated as an unnamed tributary to the Catawba River (Lake Hickory), and upon outfall relocation, to the Catawba River (Lake Hickory) in the Catawba River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, and III hereof. The permit shall become effective August 1, 1995 This permit and the authorization to discharge shall expire at midnight on May 31, 2000 Signed this day June 19, 1995 Original Signed By David A. Goodrich A. Preston Howard, Jr., P.E., Director Division of Environmental Management By Authority of the Environmental Management Commission Permit No. NC0025135 SUPPLEMENT TO PERMIT COVER SHEET Huffman Finishing Company, Inc. is hereby authorized to: Continue to operate the existing 0.250 MGD wastewater treatment facility consisting of a manuai lint screen, manual trash screen, a flow equalization basin with four floating aerators, lift pumps, an oxidation ditch, a circular clarifier, sludge recirculating pumps, a chlorine contact tank, ultrasonic flow measurement, chemical dechlorination, cascade post aeration, aerobic sludge digestor, sludge holding lagoon, sludge thickener, sludge drying beds and auxilary power located at Huffman Finishing Company WWTP, a site on US Highway 321, southeast of Granite Falls, Caldwell County (See Part III of this Permit), and 2 In accordance with the Authorization to Construct from the Division of Environmental Management, relocate the discharge from an unnamed tributary to the Catawba River to the Catawba River (Lake Hickory), and 3 Discharge from said treatment works at the location specified on the attached map into the Catawba River which is classified Class WS-IV CA waters in the Catawba River Basin. A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning upon the effective date of the permit and lasting until relocation of the discharge to the Catawba River, the Permittee is authorized to discharge from outfall(s) serial number 001 into an unnamed tributary to the Catawba River. Such discharges shall be limited and monitored by the permittee as specified below: Effluent Characterlstic Discharge LlmitatIoni Lbs/day Units (specify Mon. Avg. Daily Max Mon, Ava. Daily Max. Flow 0.250 MMC3D BOD, 5 Day, 20 °C COD TSS Sulfides Chromium Phenols Fecal Coliform (geometric mean) 68.5 135.8 790.0 1581.8 290.0 578.7 2.6 5.3 1.3 2.6 Monitorin9 Reaulrementa Measurement Sample •Sample Frequency Tvpe Locatlon Continuous Recorder I.or E 3/Week Composite E 3/Week Composite E 3/Week Weekly Weekly 20.0 µg/I Weekly 200 /100 ml 400 /100 ml 3/Week Grab E Grab E Composite E Grab E Grab E Arsenic Monthly Composite E Barium Monthly Composite E Cadmium Monthly Composite E * Sample locations: E - Effluent, I - Influent. ** Acute Toxicity (Ceriodaphnia) Monitoring; March, June, September and December, See Part III, Condition F. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored 3/week at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning upon the effective date of the permit and lasting until relocation of the discharge to the Catawba River, the Permittee is authorized to discharge from outfall(s) serial number 001 into an unnamed tributary to the Catawba River. (Continued) Effluent Characteristic. Discharge Lim it anon: Monitoring Requirements Lbs/day Other Units (speclfv) Measurement Samole •Samole Mon. Ava. Daily Max Mon, Ava. Daily Max. Frequency Tvoe Location Chloride Monthly Composite E Antimony Monthly Composite E Nickel Monthly Composite E Copper Monthly Composite E Cyanide Monthly Grab E Fluoride Monthly Composite E Load Monthly Composita F NH3 as N Monthly Composite E Silver Monthly Composite E Temperature 3/Week Grab E Total Nitrogen (NO2+NO3+TKN) Monthly Composite E Total Phosphorus Monthly Composite E Total Residual Chlorine 2/Month Grab E Zinc Monthly Composite E Acute Toxicity" Quarterly Composite E A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning upon relocation of the discharge to the Catawba River and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 001 into the Catawba River (Lake Hickory). Such discharges shall be limited and monitored by the permittee as specified below: Effluent Characterlstic. Flow BOD, 5 Day, 20 °C COD TSS Sulfides Chromium Phenols Fecal Coliform (geometric mean) Antimony Arsenic Barium Discharge Limltatloni Lbs/day Units (specify Mon. Ava. Daily Max Mon, Ava. Daily Max. 0.250 MGD 68.5 135.8 790.0 1581.8 290.0 578.7 2.6 5.3 1.3 2.6 200.0 /100 ml 20.0 µg/l 400.0 /100 ml 1.46 mg/I Monitoring Requirements Measurement Sample •Sample Frequency Tvpe, Location Continuous Recorder I or E 3/Week Composite E 3/Week Composite E 3/Week Grab E Weekly Grab E Weekly Composite E Weekly Grab E 3/Week Grab E Weekly Composite E Quarterly+ Composite E Quarterly+ Composite E * Sample locations: E - Effluent, I - Influent **Acute Toxicity (Daphnid 48 Hour) LC50 90%; March, June, September and December, See Part III, Condition G. + Once toxicity problems are remedied, the Permittee may request that the Division remove monitoring requirements for these parameters. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored 3/week at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. A. (). EFFLUENT LIMPI'ATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning upon relocation of the discharge to the Catawba River and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 001 into the Catawba River (Lake Hickory). (Continued) Effluent Characterlstic. Discharge LlmItatloLit Monitoring Requirements Lbs/dav Other Units (sgecifv) Measurement Samole 'Samole Mon. Ava. Dally Max Mon. Ava. Dolly Max., Frequent: v ZVae Location Cadmium Quarterly+ Composite E Chloride Quarterly+ Grab E Copper Quarterly+ Composite E Cyanide Quarterly+ Grab E Fluoride Quarterly+ Composite E Lead Quarterly+ Composite E NH3 as N Monthly Composite E Nickel Monthly Composite E Silver Monthly Composite E Total Nitrogen (NO2+NO3+TKN) Monthly Composite E Total Phosphorus Monthly Composite E Total Residual Chlorine 2/Month Grab E Zinc Quarterly+ Composite E Acute Toxicity Quarterly Composite E Part III Permit No. NC0025135 E. Nutrient Condition for Permits Without Phosphorus Limits This permit may be modified, or revoked and reissued to include an effluent limitation on nutrients for this discharge depending upon the following: 1. The findings of a study by the Division of Environmental Management determine nutrient control is necessary. 2. Local actions do not successfully reduce the nutrient loading on the receiving waters. 3. The onset of problem conditions in the receiving waters. F. ACUTE TOXICITY MONITORING (QUARTERLY) The permittee shall conduct acute toxicity tests on a quarterly basis using protocols defined as definitive in E.P.A. Document 600/4-85/013 entitled "The Acute Toxicity of Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a Daphnia pulex or Ceriodaphnia 48 hour static test, using effluent collected as a 24 hour composite. Effluent samples for self -monitoring purposes must be obtained during representative effluent discharge below all waste treatment. The first test will be performed within thirty days from the effective.date of this permit during the months of March, June, September and December. The parameter code for this test if using Daphnia pulex is TAA3D. The parameter code for this test if using Ceriodaphnia is TAA313. All toxicity testing results required as part of this permit condition will be entered on'the Effluent Discharge Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and wrill require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. G. ACUTE TOXICITY PERMIT LIMIT (QRTRLY) The permittee shall conduct acute toxicity tests on a quarterly basis using protocols defined as definitive in E.P.A. Document 600/4-85/013 entitled "The Acute Toxicity of Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a Daphnia pulex or Ceriodaphnia 48 hour static test, using effluent collected as a 24 hour composite. The LC50 of this effluent using the previously stated methodology may at no time in any toxicity test be less than 90%. Effluent samples for self -monitoring purposes must be obtained during representative effluent discharge below all waste treatment. The first test will be performed after thirty days from the effective date of this permit during the months of March, June, September, and December. The parameter code for this test if using Daphnia pulex is TAA3D. The parameter code for this test if using Ceriodaphnia is TAA3B. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. June 6, 1995 To: Greg Nizich From: Farrell Keough-N Through: Carla Sanderson Ruth Swanek .. () Subject: Huffman Finishing Company WWTP NCO025135 Caldwell County Response to Comments to DRAFT NPDES Permit A wasteload allocation, was completed for this facility in March, 1995. A letter questioning the various Permit requirements was sent in May, 1995. This memorandum represents the Instream Assessment Unit response. Request to extend period of relocation due to "unforeseen" difficulties. IAU has no comment regarding this request and will concur with the recommendation(s) made by the Permits and Engineering unit. Request to have monitoring frequencies changed to once per month. It is the understanding of IAU that current operating procedure for monitoring frequency recommendations is based on the classification of the plant and type of limit recommended, (i.e. whether a numeric limit or a monitoring requirement). IAU concurs with those requirements currently required by this draft permit. Request to change toxicity test from Chronic, (P / F at 84%) to Acute, (type not specified). IAU does not recommend this requirement be changed. Toxicity Testing is based, among other things, upon the instream waste concentration (IWC). For this discharge to the unnamed tributary to the Catawba River, this ratio is 84%, which far exceeds the threshold of less than 1 % for most Acute Toxicity testing requirements. Request to have monitoring frequencies changed to once per month. As stated in number 2 above, IAU concurs with the current monitoring frequencies as established by the Permits and Engineering unit. We would also point out that this facility may petition to have these metals, (Cr, Sb, Ni, and Ag) re-evaluated. They would need to monitor for at least one year with at lest twelve data points representing their effluent after relocation. Request to have Antimony limit deleted.. IAU does not recommend this requirement be changed. As stated on our Fact Sheet, this limit was based on twelve data points and a predicted maximum value which exceeded the allowable maximum value. As stated above, the facility may petition for re-evaluation after one years data at the relocated site. Request to have Phenols limit be increased. This limit was based on an agreement made with the Division of Environmental Health and the IAU has no comment regarding this phenols limit. Please let us know if we can be of more assistance. INFANTS', CHILDREN'S, MISSES' AND MEN'S HOSIERY May 22, 1995 Mr. Dave A. Goodrich, Supervisor NPDES Permit Group N. C. Division of Environmental Management P.O. Box 29535 Raleigh, NC 27626-0535 RE: Draft NPDES Permit Nc. iC0025135 Huffman Finishing Company, Inc. Granite Falls, North Carolina Dear Mr. Goodrich Reference is made to the subject Draft Permit No. NCO025135 which is scheduled to be issued on June 10, 1995. Based upon our review of the Draft Permit we request that the following modifications be made in the Effluent Limitations and Monitoring Requirements of the Permit. For Discharge To Unnamed Tributary to the Catawba River: "During the period beginning upon the effective date of the permit and lasting until October 30, 1995, the Permittee is authorized to discharge from outfall(s) serial number 001 into an unnamed tributary to the Catawba River" be modified to read as follows: "During the period beginning upon the effective date of the permit and lasting until the installation of outfall sewer to Catawba River, the permittee is authorized to discharge from outfall(s) serial number 001 into the unnamed tributary to the Catzv:bz River". The above change is requested in consideration of any unforeseen delay of approval of the Duke Power Company's Shore Line Management Plan (SNIP) by the Federal Energy Regulatory Commission (FERC). P.O. Box 170 • Granite Falls, North Carolina 28630 Telephone: (704) 396-1741 • Fax: (704) 396-4235 2. The monitoring frequency requirements for the following characteristics be modified as follows: Lrr Effluent Characteristics Chromium Antimony Arsenic Barium Cadmium Chloride Copper Cyanide Fluoride Lead NH3-N Nickel Silver Zinc Monitoring Frequency ,,vakl6k Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly " Monthly Monthly Monthly Monthly Monthly M The Chronic Toxicity Testing requirements be modified to Acute Toxicity F,, 6n $"'/" , /yD The modifications requested in Items I and 2 above are primarily due to the cost concerns associated with the increased monitoring frequency and short period associated with the Permit issuance date and relocation of the discharge to the Catawba River. For Discharge To The Catawba River: The monitoring frequency requirements for the following effluent characteristics be modified as follows: Effluent Characteristics Chromium(i,„ tedO Antimony�arWt�( ) NH3-N Nickel [wo,� N at-rm , f Silver Cpt mn �xht, club Monitoring Frequency Monthly t r� Monthly Monthly Monthly P�r,r,,,,,i •Paq- u-euAl roharJ Monthly 2. The discharge limitation on Antimony of 1.46 mg/L be deleted because our existing permit did not have an effluent limit for Antimony. It is requested that Antimony be kept for monthly monitoring only. 3. The discharge limitation on Phenols be raised to a concentration that a waste load allocation model will allow for discharge to the Catawba River. We will appreciate your consideration in this matter. Should you have any questions, please call me (704-396-1741), Mr. Shuford Wise (704-396-7111), or Mr. Shankar Mistry (919-828-0531) Sincerely, Huffman Finishing Company, Inc. Lee T. Huffman c: James R. Reid, NCDEM - Asheville Mr. Shankar Mistry, The Wooten Company Mr. Shuford Wise, Huffman Finishing Company State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Health James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary May 10, 1995 MEMORANDUM [DEHNR TO: Coleen H. Sullins, Supervisor NPDES Permits Group Division of Environmental Management FROM: Linda C. Sewallol. sting Director Division of Environmental Health SUBJECT: Draft National Pollutant Discharge Elimination System Permit Huffman Finishing Company, Inc. Caldwell County Permit No. NCO025135 Reference is made to the above mentioned Pollutant Discharge Elimination System Permit. this permit application very carefully due to the proposed discharge to the Town of Longview and g1Z1.e:4 Draft National'' We have reviewed;- proximity of the: City of Hickory water supply intakes. We feel that special consideration is.; warranted due to the complex hydraulics of Lake Hickory during various flow conditions and the uncertain impacts this may have on the two downstream intakes. We concur with the issuance of this permit provided the effluent limitations reflect the wastewater plant's treatment capability rather than the maximum allowable loading rate for Lake Hickory. This should significantly reduce the amount of contaminants which might be allowed in the lake, while establishing effluent limitations which can be achieved by Huffman Finishing. Our concurrence is also contingent upon proper operation and maintenance of the facility and compliance with the toxicity limit. If we can be of further assistance, please contact us. LCS/JPA/bbr CC: Richard Durham Harold Saylor P.O. Box 27687. Raleigh, North Carolina 27611-7587 Telephone 919-733-2870 FAX 919-715-3242 An. Equal Opportunry Affirmative Action Fmployer 50% recycled/ 10% post -consumer paper Note for Farrell Keough I Page 1 From: Greg Nizich Date: Apr 5, 1995 10:54 AM Subject: Huffman Finishing To: Farrell Keough FYI. The phenols limit in the existing permit is 20 ug/l. This was based on a negotiated settlement with DER Coleen has told the that figure is to remain in the permit after relocation. 104 is gone! ►I• � �l.`Ik.7;i.��lrrtl7 PERMIT NO.: NCO025135 PERMITTEE NAME: Huffman Finishing Company, Inc. FACILITY NAME: Huffman Finishing Company WWTP Facility Status: Existing Permit Status: Renewal Major q Minor Pipe No.: 001 Design Capacity: 0.250 MGD Domestic (% of Flow): Industrial (% of Flow): 4.24 % 95.76 % Comments: 0.2394 MGD industrial. 0.0106 MGD domestic. RECEIVING STREAM: the Catawba River WS-IV CA Sub -Basin: 03-08-32 Reference USGS Quad: D 13 SW (please attach) County: Caldwell Regional Office: Asheville Regional Office Previous Exp. Date: 5/31/95 Treatment Plant Class: Class 3 Classification changes within three miles: PLOTTED Requested by: Prepared b ," Reviewed by: 3 Date: 10/4/94 Datc: Date: Modular FK Date Rec'd g 10/4/94 8028 . ul Catawba River Drainage Area (mi2): Catawba River 0.3 Drainage Area (mi2): 1,090 Average Streamflow (cis): 0.5 Average Streamflow (cis): n/a s7010 (cfs): 0.075 s7010 (cfs): 40 w7010 (cfs): 0.1 w7Q10 (cfs): Minimum Instantaneous 3002 (cfs): 0.2 3002 (cis): Release IWC: 84% IWC 0.96% Toxicity Limits (during Chronic (Ceriodaphnia) P / F 84 % relocation interim): March, June, September, and December Toxicity Limits (after Acute (Daphnid 48 tour) LC50 90% relocation of discharge): March, June, September, and December Indream Monitanm Not Reo sired During Relocation After Ret=ion Ibs / day : other (specified) Ibs / day : other (specified) Monthly Average Daly Mexlnwtm I Monthly Average Daily Maxxnum Wasteflow (MGD): 0.250 0.250 1301>5 (#/d): 68.5 135.8 68.5 135.8 COD (#/d): 790 1581.8 790 1581.8 NH3N (rrV): monitor monitor TSS (#/d): 290 578.7 290 578.7 Fecal Col. (/100 ml): 200 400 200 400 pH (SU): 6-9 6-9 Residual Chlorine (µg/I): monitor monitor Total Phosphorus (mg/1): monitor monitor Total Nitrogen (mg/1): monitor monitor Antimony (µg/l): monitor 1,459 Arsenic (µg/l): monitor monitor' Barium (µW): monitor monitor' Cadmium (µg/1): monitor monitor' Chloride (µg/l): monitor mowhor.* Copper (µg/I): monitor monitor Chromium (#/d): 1.3 2.6 1.3 2.6 Cyanide (µg/I): monitor monitor' Fluoride (µg/I): monitor monitor' Lead (µg/I): monitor monitor' Nickel (µg/I): monitor monitor Phenols (µg/I): 20 104 Silver ()tg/I): monitor monitor Sulfides (#/d): 2.6 5.3 2.6 53 Zinc (µg/I): monitor monitor monitor' There shall be no discharge of floating solids or visible foam in other than trace amounts. The Permittee may also be required to monitor for other parameters as deemed necessary by the Director in future Permits or by Administrative Letters Recommend Quarterly monitoring due to continued problems with toxicity - Permittee should be made aware that once toxicity problems are remedied, petition for dropping these requirements will be an option. October 4, 1994 Huffman Finishing, NCO025135 Effluent Guideline Limitations Effluent Characteristics Monthly Average (Ib/da) Daily Maximum (Ib/da) Comments BOD5 68.5 135.8 BOD5 and TSS have an additional allocation for COD 790.Q 1581.8 0.0106 m d of domestic waste. TSS /-290.0 578.7 Sulfide 2.6 5.3 Phenols L2.6/ Total Chromium 1.3 2.6 H 6-to 9 6 to 9 BoD ' 3arnA/V w 0.z = Qz. Type of Product Produced Lbs/Day Produced Effluent Guideline Reference Knit Dyeing and Finishing 26,363 40 CFR 410.52 (Subpart E, Knit Fabric) A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the riod beginning on the effective date of the permit an ting until the relocation of the discharge into the Catawba Rive (Lake Hickory) r expansion of the treatment system, the Permittee is authonzelc to disc arge rom out a s sen number mto an unnamed tributary of the Catawba Kiver. Such discharges shall be limited and monitored by the permittee as specified below: Flow BOD, 5 Day, 20 °C 00D TSS Sulfides Chromium Phenols Fecal Coliform (geonetric mean) Antimony Arsenic Barium Discharcle Llimitatlo Units ., Ava. Daily Ma Mon.Daily 0.250 MGD 68.5 135.8 790.0 1581.8 290.0 578.7 2.6 5.3 1.3 2.6 D.6x35 20.0 µg/I 200.0 /100 ml 400.0 /100 ml to •Sample Continuous Recorder I or E Daily Composite E Weekly Composite E Daily Grab E Weekly Grab E Monthly Composite E Weekly Grab E Daily Grab E Monthly Composite E Monthly Composite E Monthly Composite E * Sample locations: E - Effluent, I - Influent **Chronic Toxicity (Ceriodaphnia) Phase H Monitoring; March, June, September and December, See Part III, condition H. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored weekly at the effluent by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. The pernttee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. A. O. EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning on the effective date of the permit and lasting until the relocation of the discharge into the Catawba River (Lake Hickory) or expansion of the treatment system, the Permittee is authorized to discharge from outfall(s) serial number 001 into an unnamed tributary of the Catawba River. (Continued) Effluent Characterlstic Discharge Llmltatlont Monitoring Requirements Lbs/dav Other Units (speclf}r) Measurement Sample 'Sample Mon. Ava. pally Max Mon. Avg. Daily Max. Frequency Tvoe Location Cadmium Monthly Composite E Chloride Monthly Grab E Copper Monthly Composite E Cyanide Monthly Grab E Fluoride Monthly Composite E Lead Monthly Composite E NH3 as N Monthly Composite E Nickel Monthly Composite E Silver Monthly Composite E Total Nitrogen (NO2+NO3+TKN) Monthly Composite E Total Phosphorus Monthly Composite E Total Residual Chlorine Monthly Grab E Zinc Monthly Composite E Chronic Toxicity Quarterly Composite E A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning(af�sion but without the relocation of the outfall and lasting discharge from outfall(s) serial number 001 into an unnamed tributary to the Catawba River. the pernnittee as specified below: Effluent Characteristic Discharge Limitatloni Lbs/dav Units (specify Mon. Ava. Daily Max Mon. Avg. Daily Max. Flow 0.250 MGD BOD, 5 Day, 20 'C 031) TSS Sulfides Dissolved Oxygen t, the Permittee is authorized to shall be limited and monitored by Monitoring ReaulrementE Measurement S8n1Dl2 *$ample Freauencv TvDe Locatlon Continuous Recorder I or E 68.5 • 135.8 Daily 790.0- 1518.8 Weekly 290.0' 578.7 Daily 2.6i 5.3 Weekly Daily Composite Composite 'Grab Grab Grab E E E E E,U,D + Fecal Coliform (geometric mean) 200.0 /100 ml , - 400.0 /100 ml Daily Grab E,U,D + Antimony 17.0 ug/I Weekly Composite E ✓60.0 µg/I Weekly Composite E [Arsenic arium �.2 mg/I Weekly Composite E dmium / �.4 µg/I Weekly Composite E * Sample locations: E - Effluent, I - Influent, U - Upstream 50 feet from the ( utfall, D - Downstream (1) 100 feet below the effluent and (2) 0.6 miles below the effluent. **The daily average dissolved oxygen effluent concentration shalt not be less than 5.0 mg/l. **'Chronic Toxicity (Ceriodaphnia) P/F at 84%; March, June, September and December, See Part III, condition G. + Daily upstream and downstream monitoring may be reduced at each sampling station to one time per week except during the months of June, July, August and September when the frequency must be no less than three times per week at each station. The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored weekly at the effluent, upstream and downstream by grab sample. There shall be no discharge of floating solids or visible foam in other than trace amounts. The pem- ittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning after expansion but without the relocation of the outfall and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 001 into an unnamed tributary to the Catawba River. (Continued) Effluent Characteristic plscharge Limltatlona Monitoring Requirements Lbs/dav Other Units (specify) Measurement m 1 ��� 'Sa m iZ Mon. Avg. Daily Max Mon, Avg. Daily Max. Frequencv Is-" Location Chloride . 296.0 mg/I Weekly Composite E Chromium �60.0 µg/1' Weekly Composite E Nickel ✓30.0 µg/I Weekly Composite E Phenols �20.0 µg/I Weekly Grab E Conductivity Monthly Grab U,D Copper Monthly Composite E Cyanide Monthly Grab E Fluoride Monthly Composite E Lead Monthly Composite E NH3 as N Monthly Composite E Silver Monthly Composite E Temperature Monthly Grab U,D Total Nitrogen (NO2+NO3+TKN) Monthly Composite E Total Phosphorus Monthly Composite E Total Residual Chlorine Monthly Grab E Zinc Monthly Composite E Chronic toxicity "' Quarterly Composite E A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning on the relocation of the discharge into the Catawba River (Lake Hickory) and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 001 into the Catawba River (Lake Hickory). Such discharges shall be limited and monitored by the permittee as specified below: Flow BOD, 5 Day, 20 °C CCD TSS 'Sulfides "Chromium Phenols - - '-Fecal Coliform (geometric mean) "Antimony ✓Arsenic - Barium 68.5 135.8 790.0 1581.8 290.0 578.7 , 2.6 ✓ 5.3 --`1 .3 ✓26 — * Sample locations: E - Effluent, I - Influent r �• --2070 µg/I 200.0 /100 ml 400.0 /100 ml Monitoring Requirements_ Measurement Sample •Sample Fregs ei ncv Tvoe Location Continuous Recorder I or E Daily Composite E Weekly Composite E Daily Grab E Weekly Grab E Monthly Composite E Weekly Grab E Daily Grab E Monthly Composite E Monthly Composite E Monthly Composite E ✓ *" Acute Toxicity (Daphnid 48 Hour) LC50 90%; March, June, September and December, See Part III, condition F. ✓ The pH shall not be less than 6.0 standard units nor greater than 9.0 standard units and shall be monitored weekly at the effluent by grab sample. ✓There shall be no discharge of floating solids or visible foam in other than trace amounts. ✓Tile permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. A. (). EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS FINAL Permit No. NCO025135 During the period beginning on the relocation of the discharge into the Catawba River (Lake Hickory) and lasting until expiration, the Permittee is authorized to discharge from outfall(s) serial number 001 into the Catawba River (Lake Hickory). (Continued) Effluent Characteristic Discharge Limitations Monitoring Requirements Lbs/day Other Units (specify) Measurement sampf am I Mon. Ava. Daily Max Mon, Avg. Dally Max. Frequency Tv�oe Location ✓Cadmium Monthly Composite E ✓Chloride Monthly Grab E ' Copper Monthly Composite E Cyanide Monthly Grab E ✓Fluoride Monthly Composite E ✓Lead Monthly Composite E ✓NH3 as N Monthly Composite E ✓Nickel Monthly Composite E ✓Silver Monthly Composite E ✓Total Nitrogen (NO2+NO3+TKN) Monthly Composite E - Total Phosphorus Monthly Composite E j/Total Residual Chlorine Monthly Grab E ✓Zinc Monthly Composite E Acute Toxicity Quarterly Composite E v i-rJc7 � li FACT SHEET FOR WASTELOAD ALLOCATION Request # Facility Name: Huffman Finishing Company, Inc. NPDES No.: NCO025135 Type of Waste: Industrial - 4.24 % Domestic - 95.76% Facility Status: Existing Permit Status: Renewal Stream Characteristic: Receiving Stream: Catawba River USGS # Stream Classification: WS - IV CA Date: Subbasin: 03-08-32 Drainage Area (mi2): County: Caldwell Summer 7Q10 (cfs): Regional Office: Asheville Winter 7Q10 (cfs): Requestor: Nizich Average Flow (cfs): Date of Request: 10 / 4 / 94 30Q2 (cfs): Topo Quad: D 13 SW IWC (%): Wasteload Allocation Summary (approach taken, correspondence with region, EPA, etc.) fi"M ut Catawba River Catawba River 0.3 1,090 0.075 40 0.1 Minimum 0.5 Instantaneous 0.2 Release 84 % 0.96 % Facility discharges approximately one mile above intakes for Towns of Longview and Hickory. Facility has poor toxicity record. High levels of antimony present in effluent. Source may be from adhesives and polymers or from flame retardents. Facility should review their process products for reducing this pollutant as it exhibits high levels of toxicity. Per Staff Report: "Relocation of the outfall [from UT CTB River to CIB River (Lake Hickory)) is pending (awaiting FERC's approval)." These recommendations include both interim and„axl br�" relocation to Catawba River mainstem limits. K �bS I �� Limits based upon 40 CFR 410.52 (Subppart E, Knit Fabric); w/ 26.363 I d y production. onlytu0.5e�s e! (i rn� i mud N� apPFo✓ i e �i rncf rcnu i r/ ments�and addition co ent m Reviewers* 1 / y 1/ % /TR/%1/J"UNY �ii)'1/f �f �Jt�.�. �f /�G/l Si i/f/J T�// r; IN Reviewed by Instream Assessment: Regional Su r: Petnuts & E gineerin c, m , /1eq 40% O/ i . ".� fit, RETURN TO TECHNICAL SUPPORT BY: rL3 24 WZct 5 pdaz:-h e4 1 i yha i vad ✓vt.c, bus + c- sLi�r( i it 1+vt"11(17� he fly die. S . cie 5 GiJIt//w"&tdS d/ �i1tG�G1dPN?D. Ci /J T38 h (11u.77``tl/ sc i✓Ifc 17 / r!1- nw, -„s %s P",,,,c 1'SB tncve�l .,fie Imo. Fk a,4y",4 6 I4'4wie.-y CONVENTIONAL PARAMETERS Existing Limits [during relocation interim]: wG%Y q, in*k o qtw 4i4imi9r) (adc"Q �1.2(or�) Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Wasteflow (MGD): 0.250 BODS (#/d): 68.5 135.8 COD (#/d): 790 1581.8 NH3-N (mg/1): monitor TSS (#/d): 290 578.7 Fecal Coliform (/100 mL): 200 400 pH (SU): 6-9 Residual Chlorine (µg/1): monitor Total Phosphorus (mg/1): monitor Total Nitrogen (mg/1): monitor [ NO2 + NO3 + TKN 1 There shall be no discharge of floating solids or visible foam in other than trace amounts. The pernuttee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. Recommended Limits [during relocation interim]: bl'X1'1A V 1J/ ask✓ ns�erl c�d F a Gn�awF) Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Wasteflow (MGD): 0.250 BOD5 (#/d): 68.5- 135.8 - COD (#/d): 790 1581.8 -- NH3-N (mg/1): monitor. TSS (#/d): 290— 578.7' Fecal Coliform (/100 mQ: 200 400" pH (SU): 6 - 9. Residual Chlorine (µg/1): monitor, Total Phosphorus (mg/1): monitor, Total Nitrogen (mg/1): monitor [ NO2 + NO3 + TKN ] There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the �, Director in future pemuts or Administrative letters. 1300, Coo, T�6 &V ItiAf'4 Rto] il►y 510111R)zI1A71M .Iyj isting Limits [after relocation]: W thA l �l i P,4 JX4 U)bti F. Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Wasteflow (MGD): 0.250 BOD5 (#/d): 68.5 135.8 COD (#/d): 790.0 1581.8 NH3-N (mg/1): monitor TSS (#/d): 290 578.7 Fecal Coliform V100 mL): 200 400 pH (SU): 6-9 Residual Chlorine (µg/1): monitor Total Phosphorus (mg/1): monitor Total Nitrogen (mg/1): monitor [ NO2 + NO3 + TKN ] There shall be no discharge of floating solids or visible foam in other than trace amounts. The petmittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. Recommended Limits [after relocationl: JOA& .ha4u ( i f& CaAAAba. F Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Wasteflow (MGD): 0.250 BOD5 (#/d): 68.5 135.8 COD (#/d): 790 1581.8 NH3-N (mg(1): monitor TSS (#/d): 290 578.7 Fecal Coliform (/100 mL): 200 400 pH (SU): 6-9 Residual Chlorine (µg/l): monitor Total Phosphorus (mg/1): monitor Total Nitrogen (mg/1): monitor [ NO2 + NO3 + TKN ] There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. TOXICSA ETALS Existing_ Limits [during relocation interim]: "chmj i& OT cq bn it " v U' mlV) Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Antimony (µg/l): 1 ' 17 . Arsenic (µg/1): Barium (mg/1): 60 t 1 u 1.2 Cadmium (µg/1): Chloride (mg/1): 2.4 298 Copper (µg/1): Chromium (µg/1): monitor r 60 M /Cyanide (µg/l): Fluoride (mg/l): monitor monitor n �j ✓Lead (µg/l): monitor I "I •-Nickel (µg/l): 30 Phenols (µg/1): 20 ✓Silver (µg/l): monitor Sulfides (#/d): 2.6 5.3 ✓Zinc (}tg/l): monitor There shall be no discharge of floating solids or visible foam in other than trace amounts. The petmittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. Recommended Limits [during relocation interim]: 9L'6(Aa/)�e LI4 Ul q&) .PNga'r6l'r"dd 'k�a��� Arsenic (µl Barium (m, Cadmium ( Chloride (r Copper(µI Chromium Cyanide (p Fluoride (n Lead (ul:/Jil Phenols Silver (1 Sulfides Zinc fur Lbs / day Monthly Average Daily Maximum Other (specify units) Monthly Average Daily Maximum 'r7 M..X 60 1.2 2.4 298 b'tA4 monitor ee monitor S. monitor monitor �pphy we---r 30 20 2.6 5.3 monitor monitor (�. �a �y h' There shall be no discharge of floating solids or visible foam in other than trace amounts. The pemrittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. * SOP for requirement under review. TOXICS/METALS Existing Limits [after relocation]: Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Antimony (µgll): monitor * Arsenic (µg/1): monitor * Barium (mg/1): monitor * Cadmium (µg/1): monitor * Chloride (mg/1): monitor * Copper (µg/1): monitor * Chromium (#/d): 1.3 2.6 Cyanide (µg/l): monitor * Fluoride (mg/1): monitor * Lead (µg/l): monitor * Nickel (µg/1): monitor * Phenols (µg/1): 20 Silver (µg/1): monitor * Sulfides (#/d): 2.6 5.3 Zinc (ttE/1): monitor * There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. * Monitoring recommendation(s) based on verifying previously used theoretical toxics analysis. Lbs / day Other (specify units) Monthly Average Daily Maximum Monthly Average Daily Maximum Antimony (µg/1): Arsenic (µg/l): Barium (mg/1): Cadmium (µg/1): Chloride (mg/1): Copper (µg/1): Chromium (#/d): 1.3 2.6 Cyanide (µg/1): Fluoride (mg/1): Lead (tieft Phenols (µg/l): Silver (µgh): Sulfides (#/d): 2.6 5.3 Zinc (µg/l): 1,459 - T r not required- r ✓not required monitor * not required monitor - not required not required not required monitor 104 ** monitor monitor * There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. * SOP for requirement under review; current toxics analysis methods based on actual data. ** State Water Quality Standard overrides Federal Guidelines TOXICITY TESTING Type of Toxicity Test: Chronic (Ceriodaphnia) P/F Existing Limit: 84 % Recommended Limit: 84 % Monitoring Schedule: March, June, September, and December After Relocation of Discharge; Type of Toxicity Test: Acute (Daphnid 48 hour) LC50 Existing Limit: 90 % Recommended Lin -tit: 90 % Monitoring Schedule: March, June, September, and December Arsenic: Max. Pred Cw 84 12 values used for analysis; no values below detection level Allowable Cw 5,211.3 not required per NPDES Permit Cadmium: Max. Pred Cw 62.4 12 values used for analysis; 2 values below detection level Allowable Cw 208.5 monitor - SOP for requirement to be developed Chromium: Max. Pred Cw 22,877.5 12 values used for analysis; 2 values below detection level Allowable Cw 5,211.3 Limit per NPDES Permit [Federal Guidelines] values converted to µg/I for analysis Copper. Max. Pred Cw 448 12 values used for analysis; no values below detection level Allowable Cw 729.6 monitor - SOP for requirement to be developed Cyanide: Max. Pred Cw 0.0 12 values used for analysis; all values below detection level Allowable Cw 521.1 of 5.0 µg/l not required per NPDES Permit Lead: Max. Pred Cw 64 12 values used for analysis; 6 values below detection level Allowable Cw 2,605.6 not required per NPDES Permit Antimony: Max. Pred Cw 1,508 12 values used for analysis; 5 values below detection level Allowable Cw 1,459.2 *refer note above Limit per NPDES Permit [Federal Guidelines: EPA Human Health limit 14 µg/11 Nickel: Max. Pred Cw 80 12 values used for analysis; one value below detection level Allowable Cw 2,605.6 Outlier in data set, (3,830 µgp) when discounted, yielded very low Maximum Predicted value [Max. Pred. determined w/out outlier] monitor recommended as precaution Silver: Max. Pred Cw 16.8 12 values used for analysis; 8 values below detection level Allowable Cw 6.25 of 5.0 µg/I Monitor per NPDES Permit Zinc: Max. Pred Cw 1,064 12 values used for analysis; no values below detection level Allowable Cw 5,211.3 monitor - SOP for requirement to be developed Barium: Max. Pred Cw 0.3 12 values used for analysis; I values below detection level Allowable Cw 104.2 of 0.1 mg/l not required per NPDES Permit Chloride: Max. Pred Cw 1,810 12 values used for analysis; no values below detection level Allowable Cw 26,065.5 not required per NPDES Permit Fluoride: Max. Pred Cw 1.5 12 values used for analysis; no values below detection level Allowable Cw 187.6 not required per NPDES Permit _ Parameter(s) are water quality limited. For some parameters, the available load capacity of the immediate receiving water will be consumed. This may affect future water quality based effluent limitations for additional dischargers within this portion of the watershed. OR No parameters are water quality limited, but this discharge may affect future allocations. INSTREAM MONITORING REQUIREMENTS Upstream Location: not required Downstream Location: not required Parameters: Special instream monitoring locations or monitoring frequencies: MISCELLANEOUS INFORMATION & SPECIAL CONDITIONS AAdd guacy of Existing Treatment Has the facility deynonstrated the ability to meet the proposed new limits with existing treatment facilities? Yes _ No / If no, which parameters cannot be met? t4T(�� NOD IVl� 11n O Would a "phasing in" of the new limits be appropriate? Yes _ No If yes, please provide a schedule (and basis for that schedule) with the regional office recommendations: If no, why not? �:. Wasteload sent to EPA? (Major) _ (Y or N) (If yes, then attach updated evaluation of facility, including toxics spreadsheet, modeling analysisif modeled at renewal, and description of how it fits into basinwide plan) Additional Information attached? (Y or N) If yes, explain with attachments. Facility Name Huffman Finishing Company Permit # NC0025135 Pipe # 001 CHRONIC TOXICITY PASS/FAIL PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit chronic toxicity using test procedures outlined in: 1.) The North Carolina Ceriodaphnia chronic effluent bioassay procedure (North Carolina Chronic Bioassay Procedure - Revised *September 1989) or subsequent versions. The effluent concentration at which there may be no observable inhibition of reproduction or significant mortality is 84 % (defined as treatment two in the North Carolina procedure document). The permit holder shall perform quarterly monitoring using this procedure to establish compliance with the permit condition. The fast test will be performed after thirty days from the effective date of this permit during the months of Mar., Jun., Sep., and Dec. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the parameter code TGP3B. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Fai a to submit suitable test results will constitute noncompliance with monitoring requirements. it 7Q10 0.075 cfs Permitted Flow 0.250 MGD Recommended by-- — lWC 84 % Farrell Basin & Sub -basin 03-08-32 Receiving Stream ut Catawba River [re ovation to mainstem County Catawba Date rA 6%&,me... QCL P/F Version 9191 Page 1 Note for Jackie Nowell From: Farrell Keough Date: Wed, Dec 28, 1994 11:37 AM Subject: FYI: Huffman Finishing To: Matt Mathews Cc: Greg Nizich; Jackie Nowell NC0025135 I've been reviewing this facility in preparation of a Fact Sheet. They have a crummy Toxicity Testing record for their Chronic Test at 84%. They've relocated to the Catawba River and will now have an Acute Toxicity Test at 0.96% IWC. What is of interest, (and may explain some of the toxicity failures) is the level of antimony in their effluent. Our current toxics spreadsheet review indicates they would need a limit, even at the Catawba River discharge location, (7Q10 is 40 cfs, minimum instantaneous release). I haven't been able to contact the facility, (probably closed for Holiday break) but James Reid of the Asheville RO is checking into this. I can't figure out what they would use antimony for; everything I found indicates that battery manufacturing, (and occassionally iron ore and coal powered plants) is the primary user. If you are aware of any further info., please let me know. Thanks. Facility Name Huffman Finishing Company Permit # NC0025135 Pipe # 001 ACUTE TOXICITY PERMIT LIMIT (QRTRLY) The permittee shall conduct acute toxicity tests on a Wrter basis using protocols defined as definitive in E.P.A. Document 600/4-85/013 entitled "The Acute Toxicity of Effluents to Freshwater and Marine Organisms." The monitoring shall be performed as a Daphnia Rulgx or Ceriodaphnia 48 hour static test, using effluent collected as a 24 hour composite. The LC50 of this effluent using the previously stated methodology may at no time in any toxicity test be less than 90 %. Effluent samples for self - monitoring purposes must be obtained during representative effluent discharge below all waste treatment. The first test will be performed after thirty days from the effective date of this permit during the months of Mar., Jun., Sep., and Dec. The parameter code for this test if using Daphnia puki is TAA3D. The parameter code for this test if using Ceriodaphnia is TAA3B. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR-1) for the month in which it was performed, using the appropriate parameter code. Additionally, DEM Form AT-1 (original) is to be sent to the following address: Attention: Environmental Sciences Branch North Carolina Division of Environmental Management 4401 Reedy Creek Road Raleigh, N.C. 27607 Test data shall be complete and accurate and include all supporting chemical/physical measurements performed in association with the toxicity tests, as well as all dose/response data. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should any single quarterly monitoring indicate a failure to meet specified limits, then monthly monitoring will begin immediately until such time that a single test is passed. Upon passing, this monthly test requirement will revert to quarterly in the months specified above. Should any test data from either these monitoring requirements or tests performed by the North Carolina Division of Environmental Management indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival and appropriate environmental controls, shall constitute an invalid test and will require immediate retesting(within 30 days of initial monitoring event). Failure to submit suitable test results will constitute noncompliance with monitoring requirements. 7Q10 40 cfs Permitted Flow 0.250 MGD I W C 0.96 % Basin & Sub -basin 03 - 08 - 32 Receiving Stream Catawba River County Caldwell i QAL Daphnid 48 Version 10191 Recommended Date ARO Comments 1/26/95 Fact Sheet for Huffman Finishing Company NPDES NC0025135 Limits do not exist in Huffman's current permit for Sb (antimony), Ba, Cd, chloride, Cu, Ni, As, as stated on the first "Toxics/Metals" page of the Fact Sheet. See attached copies of "Effluent Limits" pages from current permit. Since the above listed parameters are not currently limited, do not issue interim limits for them in the renewal permit. Facility cannot consistently meet the proposed interim Sb and Cd limits. Facility cannot meet the proposed interim limit of 298 for chlorides. The current Cr limit is 1.3 lb/da (mo av); the proposed interim limit of 60 ug/1 for Cr would make the limit 0.125 lb/da (1/10 its current value); is this correct? The renewal permit will require relocation of the outfall. After relocation, the permittee will be able to meet the proposed limitations appearing on the fact sheet. Since the current permit does not contain Sb, Ba, Cd, chloride, Cu, Ni and As limitations and since relocation of the outfall will occur under a construction schedule, no benefit would be derived by implementation of interim limits for the above listed parameters. Relocation of the outfall (beyond the February 24, 1995 deadline in the current permit) has been delayed as a result of FERC's control of Lake Hickory. Luke Kwong (Wooten Company), the facility's engineer, contacted the ARO by phone within the past couple of days and said that FERC had given the permittee a date on which relocation could begin. Mr. Kwong will be requesting adjustment of the 2/24/95 construction deadline as part of renewal of Huffman's NPDES Permit. OJ ge%pho" T,vet li icl, -rc-L,; cl,'d 4t Plan b,)f Ca�lvchd� x�d�4 Cvas Yz�V , Ay �a She-VV a mo Facility Name: Huffman Finishing Company, Inc. NPDES No.: NC0025135 Type of Waste: 4.24 % Domestic 95.76 Facility Status: Existing Permit Status: Renewal Receiving Stream: Catawba River Stream Classification: WS - IV CA Subbasin: 03-08-32 County: Caldwell Regional Off ice: Asheville Requestor. Nizich Date of Request: 10 / 4 / 94 TopoOuad: D 13 SW Existing WLA checked: Staff Report: Topo checked: USGS Flows confirmed: IWC Spreadsheet: Stream Classification: Nutrient Sensitivity: Instream Data: x nr Federal Guidelines x Water Supply Request # 8028 % Industrial Stream Characteristic: USGS # Date: Drainage Area (miz): Summer 7010 (cfs): Winter 7010 (cfs): Average Flow (cfs): 3002 (cfs): IWC (%): 1991 1090 40 Minimum Instantaneous Release 0.96 % Car�a� P03D (9201 00'6 (L � x Instream data for ut discharge, but not to Catawbaq River 1977: Void Level B modeling evaluation on u.t., "Note - tried to get BPT from field office but they would not provide it" 1979: Level B modeling evaluation on u.t., with Secondary Limits recommended. 1980: re-evaluation yielded limits of: 28 mg/I BOD5 , 13 mg/I NH3-N 6 mg/I dissolved oxygen, 0.05 mg/I Total Chromium, 0.001 mg/I Phenols, 0.002 mg/I Sulfide, 1,000 / 100mL fecal collform, 123 mg/I TSS', 338 mg/I COD' [' BPT limited] for 0.070 mgd discharge. 40 CFR 410 subpart E 1982: modeling analysis for possible discharge to Catawba River. 1984: On -site flow -through Toxicological examination [plant process is bleaching and dying operation of cotton and cotton/synthetic socks]. The LC50 value for the daphnia pulex was determined to be approximately 330%, (i.e. at 33% effluent concentration, approximately 50% of the test specimens will die in a 96 hr time frame). Acute, ceriodaphnia reproduction results are on an attached schematic, [acute tests had no dilution]. Both copper and zinc were at excessive levels. Benthic survey indicated little variety and predominance of anaerobic species. 1984 arsenic article attached. 1985: Model run and WLA for existing u.t. discharge location and proposed relocation to Catawba River. Major differences between two discharge locations were no dissolved oxygen limit and less stringent phenols, total chromium, and toxicity limits for discharge to Catawba River. Letter attached requesting limits for proposed expansion(s). 1987: Plant expansion and respective increase in effluent limits, (Federal Guidelines). Modeling was run. 1988: SOC request for expansion, with another subsequent flow increase due to production, which shorty followed. 1990: WLA notes; "In 1989, facility was asked to look into toxicity problems (outside of SOC). They have hired 2 consultants to improve plant design and isolate toxicity problem(s)." Facility had failed toxicity tests since January, 1989. Engineers determined that increased aeration and retention times should reduce toxicity. New WLA was for increased flow to 0.250 mgd and included limits for most metals, (including chloride, fluoride, and antimony). Facility sent response letter regarding Draft; it requested the deletion of the metals and chloride, fluoride and antimony limits. TSB response recommended continuation of these limits for the discharge to the u.t. 1991: Re-evaluation of relocation of discharge pipe to Catawba River proper. Many limits changed to monitor, [chromium and phenols limits remained] and addition of Acute Toxicity Test LC50 at 90%, [ 0.960% IWC]. This relocation is approximately one - mile above intake(s) for Towns of Longview and Hickory. Staff Report; facility has not regularly passed toxicity test, nor met their phenols limit, (which is thought by their consultants to be related to their raw material). This Report reviewed many of the aspects of this discharge and its proposed relocation and requested limits for current and proposed site and interim limits for relocation process. An Alternatives Analysis yielded findings that proposals other than relocation to Catawba River above the Towns of Longview and Hickory were too expensive to pursue. Dye Study memorandum included in WLA file. Finalized WLA for that year re -issued with the same previous limits and for the situations requested in Staff Report. 1992: Request for review and changes to Draft Permit by Huffman Finishing; reply letter in WLA file, [many, many letters and memo's about this Draft Permit have gone back and fourth]. Comments report on Draft Permit in WLA file; good review of contracted studies, (including instream conductivity and TIE studies) are presented in this document. IDMfla facility well w/in limits for conventional parameters. Total phosphorus levels are excessive, (especially in 1992 - 1993), as well as total nitrogen values. Toxic Spreadsheet attached Facility has relocated outfall to the Catawba River mainstem. ToxfcRv Facility has very poor record. A 1992 "Comments in Response to Draft NPDES Permit No. NC0025135" has near the back a section entitled THE Status Report. Numerous issues are addressed in this section; 'The mixing zone issue was resolved by testing performed by BRI, Huffman Finishing, NCDEM, and The Wooten Company representatives. It is reported in a summary report prepared by Mr. B. Kennedy of The Wooten Company and presented to the NCDEM and Huffman on August 1, 1991. It is our understanding that the NCDEM believed that the plume or mixing zone affects are very small and should not be a problem in the Catawba River." Memo in the 1991 section of the WLA does not substantiate this claim; dispersion was very slow and the dye held to the south side of the Catawba River for at least three hours, (somewhere around 3/4 of a mile) and then moved to the central part of the waterbody body for another hour or so, (about 1/2 mile) at which point it could only be detected by fluorometer for the last few hundred feet until the Longview WTP Intake, (taking approximately four hours to reach this intake from the confluence of the ut w/ the Catawba River). September 19, 1991 Memorandum Re: Lake Hickory Dye Study. "...@ is believed that the Sodium Perchlorate, it it truly exists, is produced due to the large amount of Sodium Hypochlorite used at the plant. Even though S02 is used to de -chlorinate prior to biological treatment, it is also quite possible that additional dechlorination before discharge may be necessary." The Toxic monitored per the NPDES Permit also indicate that Chromium and Silver are predicted to have maximum values, (using current Toxics Spreadsheet) exceeding the limit, (nickel seems to have an outlier which over -predicts the maximum). Another constituent in high quantities is Antimony. A fax, (attached) from ESB indicates that the source may be waste adhesives and polymers and waste flame retardants. This substances, (more commonly found in battery production) can be highly toxic; I have informed both the Region and the facility as to its existence and probable limit placed in the NPDES Permit. Existing Llmlts: Lbs / day Other (specify units) Mon. Ave. Daily Max. Mon. Ave. Daily Max. Wasteflow (MGD): 0.250 BODE (#/d): 68.5 135.8 COD (#/d): 790 1581.8 NH3-N (mg/1): monitor TSS (#/d): 290 578.7 Sulfides (#/d): 2.6 5.3 Chromium (#/d): 1.3 2.6 Phenols(µgft 1,3 2.6 mom_ colmotoo, Fecal Coliform (/100 mL): mw 200 400 pH (SU): s1w•r�1 6-9 Total Residual Chlorine (µg/I): monitor Antimony (µgA): monitor Arsenic (µg/1): monitor Barium (mgA): monitor Cadmium (µgA): monitor Chloride (mgA): monitor Copper (µg/I): monitor Cyanide (µgA): monitor Fluoride (mg/1): monitor Lead (µgA): monitor Nickel (µg/I): monitor Silver (µg/1): monitor Zinc (µg/1): monitor Total Phosphorus (mgA): monitor Total Nitrogen (m /I): monitor IN02+NO3+T N� Toxicity Test: Acute Toxicity (Daphnid 48 hour) LC50 at 90%: March, June, September, and December There shall be no discharge of floating solids or visible foam in other than trace amounts. The permittee may also be required to monitor for other parameters as deemed necessary by the Director in future permits or Administrative letters. Upstream Location: not required Downstream Location: not required Parameters: Huffman Finishing NCO025135 Arsenic: Max. Prod Cw 84 12 values used for analysis; no values below detection level Allowable Cw 5,211.3 not required per NPDES Permit Cadmium: Max. Pred Cw 62.4 12 values used for analysis; 2 values below detection level Allowable Cw 208.5 monitor -SOP for requirement to be developed Chromium: Max. Pred Cw 22,877.5 12 values used for analysis; 2 values below detection level Allowable Cw 5.211.3 Limit per NPDES Permit [Federal Guidelines] values converted to µg/I for analysis Copper: Max. Pred Cw 448 12 values used for analysis; no values below detection level Allowable Cw 729.6 monitor -SOP for requirement to be developed Cyanide: Max. Pred Cw 0.0 12 values used for analysis; all values below detection level of 5.0 µg/I Allowable Cw 521.1 not required per NPDES Permit Lead: Max. Pred Cw 64 12 values used for analysis; 6 values below detection level Allowable Cw 2,605.6 not required per NPDES Permit Antimony: Max. Pred Cw 1,508 12 values used for analysis; 5 values below detection level 'refer note above Allowable Cw 1,459.2 Limit per NPDES Permit [Federal Guidelines: EPA Human Health limit 14 µg/I] Nickel: Max. Pred Cw 80 12 values used for analysis; one value below detection level Allowable Cw 2,605.6 if outlier in data set is discounted, no w,�l aeg�Qc. �aoAow �usr to be 60mvo Silver: Max. Pred Cw 16.8 12 values used for analysis; 8 values below detection level of 5.0 µg/I�S uq1 PQpC65S Allowable Cw 6.25 Monitor per NPDES Permit D' - otc�1 uwa Pv_nc"Lw_a �S Zinc: Max. Pred Cw 1,064 12 values used for analysis; no values below detection level usod•• . Allowable Cw 5,211.3 monitor -SOP for requirement to be developed Barium: Max. Pred Cw 0.3 12 values used for analysis; 11 values below detection level of 0.1 mg/I Allowable Cw 104.2 not required per NPDES Permit Chloride: Max. Pred Cw 1,810 12 values used for analysis; no values below detection level Allowable Cw 26,065.5 not required per NPDES Permit Fluoride: Max. Pred Cw 1.5 12 values used for analysis; no values below detection level Allowable Cw 187.6 not required.per NPDES Permit Huffman Finishing NC0025135 Faeulry Nanw= manses= 0w (MGn) = 7010a (Cls)-- Avc (%) = Huffman Finishing N0002613 0.25 m d 40.00 Cfs 0.96 % Arsenic Maximum Value 20.0 Max. Prod Cw 84.0 Allowable Cw 5211.3 Nor �n�a�1 Cadmium Maximum Value 12.0 Max. Prod Cw r 62.4 Allowable Cw ✓ 208.5 wr � - 0U'eE'1 Chromium Maximum Value 193e.8 Max. Prod Cw v22877.5 Lnir Allowable Cw 5211.3 Copper [Al] Maximum Value 140.0 Max. Prod Cw 448.0 Allowable Cw 729.6 ND1 ec�ur Cyanide Maximum Value 2.5 Max. Prod Cw 0.0 N,r Or6ii Allowable Cw 521.1 Lead Maximum Value 20.0 Max. Prod Cw r 64•0 NOT Wavleca Allowable Cw r 2605.6 Antimony 5b Maximum Value 290.0 Max. Prod Cw 1508.00 '�'"~0 1+e1rr Allowable Cw ✓1459.16 (ePA r' w%,,i 4 Nickel Maximum Value 3830.0 "e- Wr1M,Q, Max. Prod Cw �70855.0 v Aw--, _ Allowable Cw i �04- 3q6 • r141 t6o6.6 3hv4ead 4hac Silver [AL] Maximum Value 7.0 �R Max. Prod Cw -16.80 F1pRayy Allowable Cw ,� 6.25 00"rt ot. Zinc [AL] Maximum Value 380.0 Max. Prod Cw ✓1064.0 Allowable Cw i5211.3 vat ClaUe Barium Maximum Value 0.1 Max. Prod Cw �0.3 Allowable Cw "104.2 ,uOr D Chloride Maximum Value 905.0 Max. Prod Cw ✓1810.0 NdrT Otura�-4 Allowable Cw 26056.5 Fluoride Maximum Value 0.9 Max. Prod Cw � 1.5 AiOT P*?W Allowable Cw -187.6 E.a . MO%) h u5ed io "U L 44%11b0t� lW sul[•,de. VQfi-• 401ublE 3"l 9pG t�a1c * rift % '44*P.6 Gaw(�P4�1.! i1�4 J,5"ft r1,4UCd ". A,/r to -fauc.r4 F Standard - n 1 2 3 4 5 e 7 a 9 10 11 Arsenic 50 µv BDL-12DL 'if 12 DL RESULTS 5 Sid Dev. 5.1 2 Mean 5.5 3 C.V. 0.9 8 8 20 Mutt Factor= 42 7 Max. Value 20.0 µgA 3 Max. Pred Cv 84.0 µgo 2 Allowable Cw 5211.3 µgel 4 2 A`rdusl, 1993 though October, 1994 Cadmium 2 µW BDL-112DL 'if 12 DL RESULTS 1 Sat Dev. 3.2 2 Mean 2.9 2 C.V. 1.1 3 2 xaraneter- Chromium sanded- 50 µg/l -(wt6.3VMQd))'tb00 n BDL-1/2DL 'if l/2 DL RESULTS 1 31.70 Sod Dev. 581.6 2 16.25 Mean 267.0 3 1938.77 C.V. 2.2 4 2.34 5 13.84 2 Mul7Factor- 5.2 6 37.24 Mutt Factor- 11.8 2 Max. Value 12.0 µgrl 7 883.91 Max. Value 1938.8 µgn 12 Max. Pred Cv 62.4 µyl 6 9.91 Max. Pred Cy 22877.5 µy1 2 Allowable C% 208.5 µgn 9 5.25 Allowable Cw 5211.3 µy1 0.5 10 154.16 6 11 99.33 0.5 12 11.77 122854 Au�tW,-1493`' though October, 1994 emnsler- Capper [Al] _ PoarMar- Cyanide Panmetm- Lead Slrxierd- 7 W Sferxf d- 5 pyl Slandard- 25 pga n BDL-112DL 'ifl/2DL RESULTS n BDL-1/2DL 'ifl/2DL RESULTS n BDL-112DL Y1/2131- RESULTS t 140 Sol Dev. 33.9 1 2.5 Std Dev. 0.0 1 2.5 Sod Dev. 6.6 2 29 Mean 45.9 2 2.5 Mean 2.5 2 5 Mean 9.6 3 23 C.V. 0.7 3 2.5 C.V. 0.0 3 5 C.V. 0.7 4 20 4 2.5 4 20 5 21 5 2.5 5 10 6 42 Mu/t Factor- 3.2 6 2.5 Mull Facor= 0.0 a 10 Mull Facor- 3.2 7 22 Max. Value 140.0 pg/I 7 2.5 Max. Value 2.5 pga 7 5 Max. Value 20.0 pert e 59 Max. Pred Cv 448.0 pg/I 6 2.5 Max. Pred Cw 0.0 pgrl 6 5 Max. Pred Cw 64.0 pert e 29 Allowable Cw 729.6 pga 9 2.5 Allowable Cw 521.1 pg4 9 5 Allowable Cw 2605.6 pgrl 10 60 10 2.5 10 10 11 66 11 2.5 11 20 12 40 12 2.5 12 20 A%em, FAS tlwugh October, 1994 o r.nerr. Andmony .unra . Hickol - Silver [ALI Swewd. 14 NW St.ndw- ®2.5 IOW - 0.06 xW EPA:Munrn n BDL.1/2DL 'if 1/2 DL RESULTS n BDL.1/2DL 'if 1/2 DL RESULTS BDL.1/20L 'if 1/2 DL RESULTS 1 50 SW Dev. 78.9 t 2.5 Std Dev. 1099.6 (1. 5 Std Dev. 1.8 2 140 Meen 69.2 2 20 Mean 337.7 (2e 2.5 Mean 3.7 3 25 C.V. 1.1 3 20 C.V. 3.3 (oq 2.5 C.V. 0.5 4 20 4 20 2.6 ' 5 290 5 20 F12 2.5 ' a 100 MWt FACA1r. 5.2 a 20 MO Facror= 18.5 (:. 2.5 Mu/t Factor- 2.4 7 50 Max. Value 200.0 µW 7 ® Feb, 54 Max. Value 3830.0 µ 7 Max. Value 7.0 µW a 50 Max. Prod Ow 1508.00 PW a 20 Max. Pred Cv 7'OB55.0 µ 2.5 Max. Pred Cw 16.8 µgn 9 5 ' Allowable Cw 145IL16 µW 9 20 Allowable Cw�a47Y.6� µ 7 Allowable Cw 6.3 µW 10 20 10 20 24.ps.6 2.5 ' 11 40 11 20 (FO) 5 12 40 12 40 2.5 ' 1f *W5 v/9IUE is Well to 10, -fi,6,}E ( ) eko� CAIC4AfttVd . 1W.Nm 140�,v5Tr OM3 Itrouph Water. 1994 Pwwrmw, 23m IAy P.W. Berbun Pw iw. Chloride P ft,. Fluoride Sr xYd- 50 IV sneev. 1 , met s d. 250 ✓ m91 saute. 1.8 m91 n BDL-12DL *1 12 DL RESULTS n BOL-121DL '112 DL RESULTS n BDL-12DL '112 DL RESULTS n BDL-12DL'112 DL RESULTS 1 140 SW Dev. 97.5 1 0.125 SId Dev. 0.0 1 420 Sid Dev. 196.4 1 0.808 Std Dev. 0.2 2 50 Mean 165.8 2 0.05 Mean 0.1 2 263 Mean 519.1 2 0.463 Mean 0.6 3 90 C.V. OA 3 0.05 C.V. OA 3 396 C.V. 0.4 3 0.9 CV. 0.3 4 100 4 0.05 4 415 4 0.596 5 120 5 0.05 5 390 5 0.625 6 190 Mu0 Fedor- 2.8 6 0.05 MuO Fsc - 2.0 6 825 A4u0Fac*w- 2.0 6 0.656 AAdf Factor- 1.7 7 100 Max. Value 380.0 up1 7 0.05 Max. Value 0.1 m9t 905 Max. Value 905.0 m01 7 0.9 Max. Value OA m94 a 380 Max. Prod Cv 1064.a µp1 a 0.05 Max. Prod Ow 08 m,A a 325 Max. Prod Ca 1810.0 men 8 0.348 Max. Prod Co 15 m96 9 150 Allowable Cm 5211.3 µyt 9 0.05 Allowable Ow 1042 myt 9 480 Allowable Cw 260563 m99 9 0.55 Allowable C% 187.6 m96 10 300 10 0.05 10 640 10 0.717 11 120 11 0.05 11 610 11 0.58 12 250 12 0.05 12 560 12 0.57 Finishing Company 35 Catawba River 03-M32 0.25 mgd 40.0 7010 40 Qave 40 3002 Parameter Standard Allowable Concentration Detected Ago µgA µgA Arsenic 50.0 5221 < 100 Cadmium 2.0 209 <5 Chromium 50.0 5221 <5 Copper 7.0 731 Cyanide 5.0 522 Lead 25.0 2611 < 100 Mercury 0.012 1 < 0.2 Nickel 88.0 9189 Selenium 5.0 522 < 100 Silver 0.1 6 < 100 31� Zinc 50.0 rha� 5221 .69ML4Mr7,3Ov Pheols 1.0 1�0 Water Supply: 30Q2 Chlordane 0.575 ngA 60 ng/I < 5000 µgA ' 0.3 No [Total Chlordane] Endrin 2.0 ng/I 209 ng/I < 5 µg,4 - 0.03 µo Heptachlor 0.280 ng/I 29 ng/I < 5000 µgA • 0.02 µV Heptachlor Epoxide < 5 µgA Lindane 10.0 ngA 1044 ng/I <5 µgA Methoxychlor 30.0 ngA 3133 ng/I < 5 µgA Toxaphene 0.2 ngA 21 ng/I 400 -1.5 MO o - Cresol 13.4 1399 < 10 m, p - Cresol < 10 2,4 - Dinitrotoluene 0.11 11 < 10 Hexachlorobenzene 0.00075 0 < 10 -0.01 µo Hexachlorobutadiene 0.445. 46 < 10 Hexachloroethane 1.9 198 < 10 Nitrobenzene 17 1775 < 10 Pentachlorophenol 0.28 29 < 10 Pyridine < 10 2,4,5 - Trichlorophenol 1 104 < 10 2,4,6 - Trichlorophenol 2.1 219 < 10 Benzene 1.19 124 < 5 Carbon Tetrachloride 0.254 27 < 5 Chlorobenzene 488 50960 <5 chlorinated benzenes Chloroform 5.7 595 <5 1,4 - Dichlorobenzene 2700 281960 < 5 1,2 - Dichloroethane 0.38 40 < 5 1,1-Dichloroethane 0.057 6 <5 Dichloroethylene Tetrachloroethene 0.8 84 < 5 Tetrachloroethylene Trichloroethene 2.7 282 <5 Trichloroethylene Vinyl Chloride 2 209 < 10 Methyl Ethyl Ketone - <100 2,4 - D 100 10443 < 1.0 Silvex 10 1044 < 1.0 Calcium, Total 100 10443 19900 calcium carbonate Magnesium, Total - - 8150 Sodium, Total - 7400 Barium 100 10443 300 Federal Federal c Federal c Federal c Federal Federal c Federal Federal c Federal c Federal Federal Federal c Federal c Federal c N. C. DEPARTMENT OF ENVIRONMENT, HEALTH, AND NATURAL RESOURCES ASHEVILLE REGIONAL OFFICE DIVISION OF ENVIRONMENTAL, MANAGEMENT WATER QUALITY SECTION TO: FAX #: FROM: Trv, ICED v FAX #: 704/251-6098 DATE: o # OF PAGES INCLUDING THIS COVER: T MESSAGE: 51- .8. a TO'd J AlI--Pdm J31bn 01 U+Ba 08 ail!AaH5d WM:U OT:LT S66T-ST-Ndf JAM-18-95 WED 15:44 TOWN OF GRANITE FALLS FAX NO. 7043963133 P.02 CLIENT: DATE RECEIVED: DATE REPORTED: SAMPLE NUMBER 402-0220A 402-0220B 402-0220C 402-02200 402-0220E r is Y�J G !i t�yR rr.-•............... Biological & Chemical Laboratories, Inc. P.O. Box 40 Granite Falls, N.C. 28630 Attention: Ms. C. Gragg February 02, 1994 February 22, 1994 SAMPLE DESCRIPTION Waste Water; Huffman for Phenol. Waste Water; Huffman for CN. Waste Water, Huffman for Total N. ( NZ N3, TKN), T. Phosphorus, Waste Water; Huffman for F. Waste Water; Huffman for C%Sb, Ba, As, Cd, Cu, Pb, Ni, Ag, Zn, PARAMETER RESULTS MQ • DATE STARTED 402-0220A - Phenol * 0.001 mg/I 2/03/94 40Z-02ZOS - CN * 0.005 mg/I 2/03/94 402-0220C - Total Nitrogen N2 N3 6.39 0,02 mg/l 2/08/94 TKN 1.46 0.50 mg/I 2/08/94 Total Phosphorus 5.69 0.05 mg/I 2109/94 402-0220D - F 0.9 0.01 mg/I 2/09/94 " Concentrations are below Minimum Quantification Limit except where noted. NC Labvrator�ertificate No. 275. 20'd a 1,.LI-k1m N31w Ol d+9a ON alITha45G WOd=l OT:LT S%T-ST-Wf JAN-18-95 WED 15:44 TOWN OF GRANITE FALLS FAX NO, 7043963133 P. 03 PARAMETER RE. M.Q.L DATE V—kLTFQ 402-0220E - Cr 0.883 O-OOS mg/l 2/04/94 Sb 0.01 Mg/l 2/04/94 Ba 0.10 M'9/1 2/04/94 As 0.007 0.001 mg/1 2/04/94 Cd 0.002 0.001 mg/l 2/04/94 Cu 0.022 0,001 mg/l 2/04/94 Pb 0.01 Mg/1 2/04/94 Ni 3.83 0.01 ' rng1l 2/04/94 Ag 0.007 0,005 mg/l 2/04/94 Zn 0.10 0.01 mg/1 2/04/94 i REPORTED BY: D. R. )singer - General Manager Concentrations are below Minimum Quantification Limit except where noted, NC Laboratory Certificate No. 275. 20' d N hd I -�-M a3iUM 01 H+ea Od a 111 AGHSU woaA oT:GT sGeT-eT-Ndf 70'd �H101 - JAN-18-95 WED 15:46 TOWN OF GRANITE FALLS FAX NO. 7043963133 P.04 I .dh9y •I O,O�. Hi���, th1�e ,l;dyf Od'yy 3.53 io< A ay — 43-9Y 0 6 G16-?5 a•o 2 47-9y b z RSA .;d,o,Z %/Xi e /2e�oorf*W 4,e r.v 7'�.,',1 F/,;A .4 r Za6, 2 14-c -eg Ae 0.74a.7' rq4,>� l% a.�ty t eo.4 lea c74 /I/P.r moo'" Td Page 1 Note for Farrell Keough From: Matt Mathews Date: Jan 9, 1995 9:43 AM Subject: RE: FYI: Huffman Finishing To: Farrell Keough I have located information which indicates that antimony may be found in textile waste streams. The source would be waste adhesives and polymers and waste flame retardants. What did the facility have to say? From: Farrell Keough on Wed, Dec 28, 1994 11:37 AM Subject: FYI: Huffman Finishing To: Matt Mathews Cc: Greg Nizich; Jackie Nowell NC0025135 I've been reviewing this facility in preparation of a Fact Sheet. They have a crummy Toxicity Testing record for their Chronic Test at 84%. They've relocated to the Catawba River and will now have an Acute Toxicity Test at 0.96% IWC. What is of interest, (and may explain some of the toxicity failures) is the level of antimony in their effluent. Our current toxics spreadsheet review indicates they would need a limit, even at the Catawba River discharge location, (7Q10 is 40 cfs, minimum instantaneous release). I haven't been able to contact the facility, (probably closed for Holiday break) but James Reid of the Asheville RO is checking into this. I can't figure out what they would use antimony for, everything I found indicates that battery manufacturing, (and occassionally iron ore and coal powered plants) is the primary user. If you are aware of any further info., please let me know. Thanks. 0'1/09/95 10:44 $919 733 9959 NC DEM WQ ENVSCI �,y WQ HQ AT #6 (-V 1 - Post-V brand tax transmittal memo 7671 1 g or pages . /13 prom A a,. hcw a.Co. Dept. Pnoneg 33 -v3 G Paag Faxg AQUATIC TOXICITY OF ANTIMONY IN FRESHWATER AND SALTWATER 'A Research Paper (HII) Presented To Dr. James,Robertson East Carolina University Environmental Toxicology Environmental Health 5010 by Deborah A. Sawyer April 17, 1987 VAN 9 01/09/95 10:44 1&919 733 9959 NC DEM WQ ENVSCI +++ WQ IIQ Q002 TABLE 2 POTENTIALLY HAZARDOUS WASTE STREAMS FOR INDUSTRIAL SOURCES Industry Textiles Plastic Materials and Synthetics Inorganic Chemicals Primary Metals Organic Chemicals Paint and Allied Products Wastes 011 Refining Waste Streams - waste adhesives and polymers - waste .flame retardants -polyester production catalyst waste -synthetic rubber industry waste -filter cakes and sludges from wastewater treatment from the production of chrome colors and other pigments -contaminated antimony pentafluoride -waste from production of sulfur oxychlorides -primary smelting and electrolytic refining of copper -blast furnace slag from the pyrometallurgical processes in the secondary smelting and refining of copper -arsenic trioxide from smelting industry wastes -antimony-and antimony trioxide waste from smelting industry -contaminated antimony trifluoride -contaminated antimony pentafluoride -waste from the manufacture of perchloroethylene -waste from the manufacture of fluorocarbons -cleanings and wastewater treatment sludges from the production of solvent thinned trade sales paints (house Paint) -cleaning and wastewater treatment sludges from the production of lacquers -cleanings and wastewater sludges from the production of factory -applied coatings -cleanings and wastewater treatment sludges from the production of putty and miscellaneous paint products -reclaimer's residues -4A- [4) FA 01/09/95 10:45 V919 733 9959 NC DBI NQ ENVSCI -+, WQ IIQ � :01 antimony trichloride, and antimony trioxide. The "available data indicates that acute and chronic toxicity to freshwater aquatic life occurs at concentrations as low as 1.600 and 9,000 ug/l, respectively, and would occur at lower concentrations among species that are more sensitive than those tested" [9). Antimony potassium tartrate and antimony trichloride were both tested on Daphnis ma na. The freshwater toxicity results were approximately the same for both compounds (see table 4). The Pimeahales promelas (fathead minnow) had an acute toxicity of 21,900 ug/1 for antimony trichloride (see table 4). [91 Chronic exposure to antimony trichoride showed a freshwater lethal concentration of 5,400 ug/l for the Daphnia manna and an effective concentration of 1,600 ug/l for the fathead minnow. Antimony trioxide showed no chronic effect on the fathead minnow (see table 5). (91 Toxicity for freshwater plants was also evaluated. An alga, Selenastrum CaPri2aERRIUm was the tested species. Antimony trioxide had an EC50 (effective concentration) of 610 ug/1 in the 96 hour test for chlorophyll a inhibition. The effective concentration of 630 ug/1 caused a reduction in cell numbers (see table 7. [91 A saltwater plant species was also evaluated in the testing. The alga, Skeletonema costatum was tested in antimony trioxide. There was chlorophyll a inhibition at greater than 4,200 ug/l and a reduction in cell numbers at .the same concentration see table 7. [9] -11- Q 003 WHOLE EFFLUENT TOXICITY TESTING 0(SELF-MONITORING SUMMARY) Mon, Nov 21, 1994 FACILITY RG UIREMITlT YEAR JAN FIT MAR APR MAY RUN An. AIIO SFP O(-T NOV DO IIOECIISIC19ANISE/NIZDMRERD PERM: 4911R LCM AC LIM 42%CERIO OR DAPH 90 - - - - - - - - - - - - NCW7989MI Bcgln:9/IM4 FmluemY:Q A JAN APRJUL<RR N..Cnv.p:SINGW 01 - - - - - - - - -- -- - - County:ROWAN Region: MRO Subbuin: YAIXJ6 92 N N N N - - N - - - - 9.50 PF: 0.298 SMciel 90 H - - H - - >90.0' - - >90.0' - - 7QI0:106 MC(%):042 Crdee 94 >90.0' HOI:CHSTCELANESE CORP. PERM CUR LIM:6.5% 90 - - - - - - - - - - - - NC0004952N01 BeginWIN3 Ftegoercy: Q JW A MAR JUN SEP DEC N..C.W:SINGLE 91 - - - - - - - - - - - - County:C1EVEAND Region: MRO Subbuin: BRD05 92 - - - - - - - - - - - - PF:0.55 Specie) W - - - - - BI LATE PASS PASS - - PASS 2Q10:20.0 DVC(%):4.47 Ordee W - - PASS - - PASS - - PASS IIOLLY RIDGE V WfP PERM CUR LU1:90`.G 90 NONE - - M NONE - NONE - - 50.9 - - NCW25895/001 Begm:2JIN3 Fn unlcy: Q P/F A MAR JUN SE' DEC NmCamp:SPIGLE 91 LATE PASS - PASS - - FAIL Nil I'll FAIL FAIL AH COYnty:ONSLOW Region:WIRO Subbein:CPF24 02 LATE PASS - - FAIL,PASS - NR - - N3 FAIL PASS PF:0.1 Sprcin 93 - - NWPASS - - FAIL NRAR Bt FAIL PASS - ]QIO: 0.0 IWC(%)A0oo BI FAIL NIP FAIL FAIL FAIL FAIL FAIL LATE BI,>W 67.1 IIOMELI3E TEXTRON WI PERM CHR LIM:99% 90 PASS - - PASS - - PASS - - PASS - - NC000523I1001 Begin:I0O189 Flapmcy: Q P/F A JAN APR JUL OCT N..C.Wo 01 PASS - - PASS - - FAIL FAIL FAIL FAIL FAR PASS C..Iy:GASTON Region: MRO Subbuin: CTB37 92 FAIL PASS PASS PASS - - PASS - - PASS.PASS - - Pr: 0.40 Speeiel W PASS - - FAIL PASS - FAIL PASS - FAIL PASS(s) - TQIO:O.W R3'C(%):IW.W ONe' W W PASS - FAIL PASS - PASS - - FAIL 110MELITETFiMON002 PERM CHR LIM:99%(GRAB) 90 PASS - - PASS - - PASS - - FAIL LATE lot NC000523I/W2 Bcgin:I UL89 Fmqucncy: Q P/F JAN APR JUL OCT N..Cornp: 01 PASS - - PASS - - PASS - - PASS - - County:GASTON Region: MRO Subbuin: CI 037 92 FAIL PASS PASS FAIL PASS PASS PASS - - M NT M PF: 0.06 Specie) 03 PASS - - FAIL PASS - H - - PASS - - 2QIO:O00 PXC(%):IW.W Cole' 04 W FAIL FAIL PASS - - PASS - - FAIL IIUIIMAN IINISUING PERM: 4811R LC50 AC MONK 90%(DAPII OR CERIO) V W - - FAIL - - FAIL - - FF - - FAIL NC0025135=1 Regin:7/IN3 Frapvay: Q MAR JUN SEP DEC NonComp: 91 - FAIL FAIL FAIL FAR FAIL FAIL FAIL FALL FAIL - FAIL C-oty: CALDWI'11. Rep. n: ARu 4d.Lndm CII,Q 02 FAII FAR FAIT, FAIL - ]]0 2 1 a 07.0 37.0 070 21.0 02.0 19E0,250 51'en•1 OJ /go So /o.0 boo -- 10,0,21.0 >00.0' -- IAIL -- - NIVM0.0- ]010:0.0]5 PXC(%L84.0 Gm6 W - - 86.6' 98.4' >100' >90- - - >100' INGIRSOLL-RAND/SCILAGE CORP. PERM CUR LIM:90%(GRAB) W - - - - - - - - - - - - NCW]922]A01 BeginAW136I2 Pnquency:Q PM A FEB MAY AUG NOV NonComp:SWG1E 91 - - -- - - - - - - - - - Counly:NASH Region: RRO Suhbasin: TAR02 92 - - - - - - - - -- - N - PF:0.1236 Spea'ul 90 - H - - H - PASS FAIL FAIL - PASS - 7QI0.0.0 IWC(%):IWO° 94 - PASS - - PASS - - PENDING(e) - IRA D I F UJL CHASE PFAM CIIR LIM:90%; NO TOX WIMN1 .05MGD 90 - - - - - - - -- NC0063146N01 Bcgm:&IM3 FmPercy: Q P/F A JAN APR JUL OCT NonComp: 91 PASS - - LATE LATE LATE] M - PASS FAIL PASS - County:WAKE Region: RHO Subbuin: NE -UM 92 PASS - - PASS - - FAIL FAIL FAIL PASS - - PF:0.05 specie) 93 PASS - - PASS - - FAIL PASS - PASS - - 7QI0:0.0 IWC(11:90 Qder W PASS PASS - N"ASS - - PASS - J.P. STEVENS-WAGRAM PERM CHR LIM:6%: UPON FXP CHR LIM 9% V W PASS - - PASS - - M PASS PASS NR,P,P - - NC0005762A01 Begio:9/IN4 Fmluene,; Q P/F A FEBMAY AUG NOV N..Comp:SINGLE 91 M PASS PASS PASS PASS,P1 PASS( PASS,Pf NR,PASSI >1001 P,NONEI NR,>lM NR.NONEI Counry:SCOTLAND Region: FRO Subbuin: LUM51 92 M PASSLP N3 - PASSI,PASS - - PASS,PASSI - - PASS,PASSI - PF:4.5 Spaiel 93 - N(LPASSf - - PASS.PASSI - - PASSI,PASS - - PASS,PASSf - ]QIO: 117 IWC(%): 5.6 Uaee 94 - PASSRASSI - - PASS,PASSI - - FAIL LATE LATE JACKSON COUNTY W WIP PERM CUR LIM:1.4% Y W - Ni PASS - PASS - - PASS - - LATE b1 NC003957BIWI Regin:8/1/93 Fnquercy: Q P/F A NOV ITR MAY AUG NonComp:SINGIE 91 PASS PASS - - PASS - - PASS - - PASS - Coumy:JACKSON Region: ARO Subbuin: LT1,402 92 - PASS - - PASS - - PASS - - PASS - PF:1.50 5peciel 93 - PASS - - PASS - - PASS - - PASS - TQIO:165.0 IWC(%)A39 nnler: " -- PASS - --- PASS - - PASS - O 2.... ...live fnilum. =aignili• ml n..nronq.li.uve Y lore I`M IMI., Avnilnhle IILEND: PERM=Permit Requirement L.ET=Adminis0azivel<Oer-Tnrg0 Frequency=Monitoring fregrene,:Q.Quanerly:M-Momh1Y; BM- Bimunddy: SA- Sonmmnaually;A-Annuelly;OWD- Only when lischazing;D- Discontinued monitoring lequiremenl: IS. Conducting indepeodc'ot uWy Bean = Fog manrh rcauirN ]QIO=Receiving sueam low Rnw cntenon (c(s) A = quanedy monitoring ircruus Ib monrNY upon single (ailurt Month+ slut rating muz occur - ex. IANAPRJIR..00T NonComp = Curren, CmnpJinn a Requimmml PF= Pem.itted naw(MGD) IWC%=lnstmem waste cansenuatim PT- P.4-ail ehmvie test AC=Acme CIIR=Chronic Der Noution: f - FaO.ead Minnow: • - CenodephNa s..: my - Mvsid shnma: ChV - Chonic value: P- MonAi1Y of stand aen,en,ane et Mahn mnccmntion: a - Pcdom by DENI Tox Eval Grouo: bt - Bed test Reporting Nowion:--= Der ow required: NR - Not reponed;O- Beginning of Quota I'ecRlry Activity Sums: I - Imeilve, N - Newly lssued(.mrtnrm); II - Aeive but not disc!urging:}-Mom don ava0able for.0t in question SIG =ORCai,,mai erwedcd 28 IIL20 A. S. T. 06.4 R=24.7 A.S.T.— Average Survival Time (Days) R= Number of young/adult N R=0 300 Complete Mortality A. S. T. =2.7 2C R=0 60% Mortality 0 3 A.S. T. 03. 4 R=0 80% Mortality `400 A. S. T->S. B 3A R=o 20% Mortality 1 200 1 Catawba River Io iApproximate Distance Between Stations -in Meters `20 a SOC PRIORITY PROJECT: NO TO: PERMITS AND ENGINEERI WATER QUALITY SECTION UNIT DATE: October 14, 1994 NPDES STAFF REPORT AND RECOMMENDATION COUNTY Caldwell PERMIT NUMBER N000.25135 PART I - GENERAL INFORMATION 1. Facility and Address: Huffman Finishing Company P. 0. Box 170 Granite Falls, N. C. 28630 2. Date of Investigation: September 1, 1994 3. Report Prepared By: James R. Rei j 4. Persons Contacted and Telephone Number: Shuford Wise and Lee Huffman 704-396-1741 5. Directions to Site: Huffman Finishing Company is located on the west side of Highway 321 approximately 1.0 miles north of where Highway 321 crosses the Catawba River in southern Caldwell County. 6. Discharge Point(s), List for all discharge points: EXISTING PROPOSED Latitude: 350 46' 05" 350 4.5' 34" Longitude: 810 23' 49" 810 23' 48" Attach a USGS map extract and indicate treatment facility site and discharge point on map. U.S.G.S. Quad No. D 13 SW U.S.G.S. Quad Name Granite Falls 7. Size (land available for expansion and upgrading): Huffman Finishing owns the land behind the existing WWTP which would be available for expansion. 8. Topography (relationship to flood plain included): Hilly, slopes to 40%, not in flood plain. 9. Location of nearest dwelling: None within 500 feet of the WWTP. -1- Receiving stream or affected surface waters: The existing discharge point is on an unnamed tributary to the Catawba River (Lake Hickory). The facility is operating under a schedule which mandates that the outfall be relocated to the Catawba River (Lake Hickory) on or before February 24, 1995. a. Classification: WS-IV CA b. River Basin and Subbasin No.: Catawba - 030832 C. Describe receiving stream features and pertinent downstream uses: Lake Hickory is used for primary and secondary recreation, as well as water supply. The City of Hickory's water supply intake is approximately 6000 feet downstream from the proposed discharge point. PART II - DESCRIPTION OF DISCHARGE AND TREATMENT WORKS 1. Type of wastewater: 4 % Domestic 96 % Industrial a. Volume of Wastewater: 0.250 MGD (Design Capacity) 2 3 b. Types and quantities of industrial wastewater: Approximately 239,400 gpd of industrial wastewater from the bleaching and dyeing of cotton and cotton/synthetic socks. C. Prevalent toxic constituents in wastewater: d. Pretreatment Program (POTWs only): n/a in development approved should be required not needed Production rates (industrial discharges only) in pounds per day; 26,363 lbs/day. a. Highest month in the past 12 months: 26,363 lbs/day. b. Highest year in the past 5 years: lbs/day Description of industrial process (for industries only) and applicable CFR Part and Subpart: Sic 22 - Bleaching and dyeing of cotton and cotton/synthetic socks. 40 CFR Part 410 Subpart E. 4. Type of treatment (specify whether proposed or existing): Existing - vibrating mechanical lint screen, a manual trash screen, a flow equalization basin with 4 floating aerators, lift pumps, an oxidation ditch, a circular clarifier, sludge recirculation pumps, a chlorine contact tank, ultrasonic flow measurement, cascade aeration, chemical dechlorination, aerobic sludge digester, holding lagoon, sludge thickener, and auxiliary generator. 5. Sludge handling and disposal scheme: Sludge is removed by a contracted disposal firm and land applied to permitted sites under Permit No. WQ0002431. 6. Treatment plant classification: Less than 5 points; no rating (include rating sheet, if appropriate). Class III -2- 7.- SIC Codes(s): 2252 Wastewater Code(s): Primary 55 Secondary 02 i MTU Code: 1003 PART III - OTHER PERTINENT INFORMATION 1. Is this facility being constructed with Construction Grant funds (municipals only)? no 2. Special monitoring requests: none 3. Additional effluent limits requests: none 4. Other: none PART IV - EVALUATION AND RECOMMENDATIONS Renew the permit with interim and final limitations page. Interim and final limitations should be calculated in accordance with current production information (26,363 lbs/day). The date for "completion of construction and compliance with final limits" should be February 24, 1995. Facility is well operated: Relocation of the outfall (from UT CTB River to CTB River (Lake Hickory)) is pending (awaiting FERC's approval). to -3-