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HomeMy WebLinkAboutWQ0016247_Residual Annual Report 2014_20150302CITY OF STATESVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0016247 2014 ANNUAL REPORT City of Statesville, NC Residuals Land Application Program 2014 Annual Report TABLE OF CONTENTS 1. Certification Form, Annual Operations Summary, Facility and Land Applier Contact Information 2. Annual Residual Sampling Summary Forms, Residuals Analyses, & SAR Calculation Pages 3. Annual Land Application Field Summary Forms 4. TCLP Analyses 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00016247 County Iredell Year 2014 Facility Name (as shown on permit) City of Statesville, Third Creek WWTP & Fourth Creek WWTP NPDES No. NCO020591 & NCO031836 Land Application Operator Svnagro Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 31 Total number of fields utilized for land application during the year: 11 Total amount of dry tons applied during the year for all application sites: 639.01 Total number of acres utilized for land application during the year: 225.8 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2014 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T. I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of m_ y kno led e and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false i i g nes and imprisonment for knowing violations." Todd ar n O erations Director L�I Per itte 'Iameamd Tit9e pe or print) na r o i Date 'Signaturf of Preparer* Date SYgnature of Land Applier Date (if differbrit from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T. 1102 (26) DENR FORM ACF (12/2006) 2014 ANNUAL OPERATIONS SUMMARY - LAND APPLICATION STATESVILLE, NC STATESVILLE, NC FOURTH CREEK CAKE DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS February 2014 704.00 Y 87.93 D 79.76 March 2014 384.00 Y 47.97 D 43.50 June 2014 1,056.00 Y 126.03 D 114.30 October 2014 325.00 Y 40.89 D 37.09 YEARLY TOTAL 2,469.00 Y 302.82 D 274.65 STATESVILLE, NC THIRD CREEK CAKE DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS January 2014 640.00 Y 76.49 D 69.37 February 2014 544.00 Y 65.02 D 58.96 March 2014 160.00 Y 19.12 D 17.34 June 2014 928.00 Y 120.21 D 109.03 October 2014 400.00 'Y 55.35 D 50.21 YEARLY TOTAL 2,672.00 Y 336.19 D 304.91 1 /26/2015 2014 ANNUAL REPORT PROJECT: FACILITY: NPDES PERMIT NUMBER: RESPONSIBLE OFFICIAL: FACILITY OPERATOR: LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: City of Statesville, NC Third Creek WWTP NCO020591 Todd Norman, Residuals Superintendent Town of Statesville P.O. Box 1111 Statesville, NC 28677 (704) 878-3438 Todd Norman, Third Creek WWTP Supt. Town of Statesville P.O. Box 1111 Statesville, NC 28677 (704) 878-3438 Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 2014 ANNUAL REPORT PROJECT: FACILITY: NPDES PERMIT NUMBER: RESPONSIBLE OFFICIAL: FACILITY OPERATOR: LAND APPLIER AND PREPARER OF LAND APPLICATION ANNUAL REPORT: City of Statesville, NC Fourth Creek WWTP NCO031836 Andy Smith, Residuals Superintendent Town of Statesville P.O. Box 1111 Statesville, NC 28677 (704) 878-3438 Andy Smith, Fourth Creek WWTP Supt. Town of Statesville P.O. Box 1111 Statesville, NC 28677 (704) 878-3438 Synagro Central, LLC Contact: Marshall Puryear (336) 998-7150 ext. 17 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0016247 Facility Name: STATESVILLE, NC NPDES# : NCO031836 or WQ# (residual only) WWTP Name: FOURTH CREEK Residuals Analysis Data Product Type CAx CAx CAx Date Sampled (grab) or 01/09/14 05/11/14 09/26/14 Date Composited Percent Solids 14.83 14.17 14.94 PARAMETERS (mg/kg dry weight) Arsenic 5 5 4 Cadmium 5 5 4 Mercury 1.3 0.5 <0.4 Chromium 48 56 42 Copper 364 308 370 Lead 36 32 30 'Molybdenum 14 12 11 Nickel 34 46 22 Selenium 5 <5 <5 Zinc 709 704 458 Total Phosphorus 25800 23300 29600 TKN 54600 59600 50500 Ammonia -Nitrogen 9510 15100 7760 Nitrate and Nitrite 12.1 <2 <2 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed o assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significl pralties for submjtting false information, including the possibility of fines and imprisonment for knowing violations." X PREPARER) Date Dom- DENR FORM RSSF (5/2003) Printed: Tuesday - January 27, 2015 at 11:03:55 for: 2084 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0016247 Facility Name: STATESVILLE, NC NPDES# : NCO031836 or WQ# (residual only) WWTP Name: FOURTH CREEK Residuals Analysis Data Product Type CAK CAK CAK Date Sampled (grab) or 01/09/14 05/11/14 09/26/14 Date Composited Percent Solids 14.83 14.17 14.94 PARAMETERS (mg/kg dry weight) Aluminum 26200 20900 30100 Calcium 10600 29200 6750 Magnesium 2590 3970 1620 pH 6.42 7.98 5.67 Potassium 2960 4130 2260 Sodium 843 862 881 Laboratory A&L Eastern Laboratories Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are nalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." significa�it PA *4 (SIGNATRE OF-PREPARER) NR - Data Not Reported or Data Not Required Date o� l s ( — DENR FORM RSSF-B (7/2002) Printed: Tuesday - January 27, 2015 at 11:04:28 for: 2084 01 Page: 1 of 2 Report Number: 14-010-0201 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97420 Sample Id : 4TH CK 99A&L Eastern Laboratories, Inc. . 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www,aleastem.com Project: STATESVILLE 4TH CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/9/2014 09:20:00 Date Received: 01/10/2014 00:00 Date Reported: 01/15/2014 Total Solids * 14.83 148300 100.0 JM 01/10/2014 14:19 SM-2540G Moisture * 85.17 100.0 JM 01/10/2014 14:19 SM-2540G Total Kjeldahl Nitrogen 5.46 54600 10.0 JM 01/13/2014 08:30 SM-4500-NH3C-TKN Total Phosphorus 2.58 25800 100 KM 01/13/2014 11:35 SW 6010C Total Potassium 0.30 2960 100 KM 01/13/2014 11:35 SW 6010C Total Sulfur 0.88 8800 100 KM 01/13/2014 11:35 SW 6010C Total Calcium 1.06 10600 100 KM 01/13/2014 11:35 SW 6010C Total Magnesium 0.26 2590 100 KM 01/13/2014 11:35 SW 6010C Total Sodium 0.08 843 100 KM 01/18/2014 11:35 SW 6010C Total Iron 25300 100 KM 01/13/2014 11:35 SW 6010C Total Aluminum 26200 100 KM 01/13/2014 11:35 SW 6010C Total Manganese 1580 5 KM ..,01/13/2014 1.1:35 SW 6010C Total Copper 364 5 KM 01/13/2014 11:35 SW 6010C Total Zinc 709 5 KM 01/13/2014 11:35 SW 6010C Ammonia Nitrogen 0.95 9510 10.0 JM 01/13/2014 08:30 SM-4500-NH3C Organic N 4.51 45090 10.0 01/13/2014 08:30 CALCULATION Nitrate+Nitrite-N 12.1 2.00 JM 01/13/2014 08:30 SM-450ONO3F Total Cadmium 5.0 2.0 KM 01/13/2014 11:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made ,CcT to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-010-0201 Account Number: 46493 Submitted By: ERIC THOMPSON , Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97420 Sample Id : 4TH CK �yyL A&L Eastern Laboratories, Inca 7621 Whitepine Road Richmond, Virginia 23237' (804) 743-9401 Fax (804) 271-6446 Wwwaleastern.cOm Project: STATESVILLE 4TH CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/9/2014 09:20:00 Date Received: 01/10/2014 00:00 Date Reported: 01/15/2014 Total Chromium 48 5 KM 01/13/2014 11:35 SW 6010C Total Nickel 34 5 KM 01/13/2014 11:35 SW 6010C Total Lead 36 5 KM 01/13/2014 11:35 SW 6010C Total Arsenic 5.0 3.0 KM 01/13/2014 11:35 SW 6010C Total Mercury 1.3 0.4 KM 01/13/2014 09:00 SW-7471 B Total Selenium 5.0 5.0 KM 01/13/2014 11:35 SW 6010C pH (Standard Units) * 6.42 2.00 JM 01/13/2014 08:30 SW-9045D Total Molybdenum 14 5 KM 01/13/2014 11:35 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MSD WAS OUT OF LIMITS FOR "NO3/NO2-N" AND "Se". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "As" AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. 9n- 01IT .1relH SAMPLING LOG tf ® 'I u �— '^ ^•••'�"'"' � tiQc Mr. ■ ■L ��Il� ��� 11� ����� ,'n I 464 10-0201 CUSTOMER: SYNAGRO SOUTHEAST SYNAGROCENTRAL I�I ,STA ESVLo,- E�II�II�I 93 1a2o14 STATESWLLE 4TH CK 12:57 06 PROJECT MANAGER: ! G 4 -izl Phone:( 3 3� 0 % 6 S w�31d Ed CHAIN OF CUSTODY RECORD & ANALYSIS RECORD per field sampling procedures he collection of these samples. A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED o�P r o 1" 1141 01 s ()G�) LlPS t( / cI ML41 Relinquished by Sampler: Date �Lr Time Recieved by: REMARKS: 61W1 C :, P(4;,7 e! 9 /lod Relinquished by: Dat Time Recieved ,� �' ZC )7,21 CID 2 0 ; � Relinquished by. D e Time Recieved b . SPECIAL INSTRUCTIONS: PO#: For --monitoring purposes. (STATE) ANALYSIS REQUEST SAMPLE I.D. SL1 SL2 NH4 N NO3 N Organic Cd Cr Ni Pb As H 9 Se p H CaCO3 equiv. Vol atile Solids Mo Cl NO -N z P1/YOPOO, too tskoo1/'140ort0009 1009 kdo 1000 1/Ir SL1: Total Solids (Moisture), Total Kjeldahl Nitrogen. Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc White — A & L Canary — MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2084-01-CAK-NC STATESVILLE, NC FOURTH CREEK CAKE ' 1/9/2014 1/1/2014-3/31/2014 0.7309 Na mg/I = (Na mg/kg x % Solids) = 100 = (843 x 14.8300) : 100 = 125.017 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (10600 x 14.8300) = 100 = 1571.98 Mg mg/I = (mg mg/kg x % Solids) + 100 = (2590 x 14.8300) = 100 = 384.097 Na meq = Na mg/I _ Molec.Wgt.Na = 125.017 + 23 = 5.43552 Ca meq = Ca mg/I = Molec.Wgt.Ca = 1571.98 + 20 = 78.599 Mg meq = Mg mg/I + Molec.Wgt.Mg = 384.097 = 12 = 32.0081 SAR = Na meq =`SgrRoot[0.5 x (Ca meq + Mg meq)] = 5.43552 = SgrRoot[0.5(78.599+32.0081)] = 0.730911 Printed: 1/27/2015 Page 1 11:11 Page: 1 of 2 Report Number: 14-133-0206 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 55320 Sample Id : STATESVILLE 4TH CK 99,A&L EasternLaboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-WG wwwaleastern.com Project: STATESVILLE 4TH CK/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 5/11/2014 11:15:00 Date Received: 05/13/2014 00:00 Date Reported: 05/16/2014 Total Solids " 14.17 141700 100.0 JM 05/13/2014 13:59 SM-2540G Moisture * 85.83 100.0 JM 05/13/2014 13:59 SM-2540G Total Kjeldahl Nitrogen 5.96 59600 10.0 JM 05/14/2014 08:24 SM-4500-NH3C-TKN Total Phosphorus 2.33 23300 100 KM 05/14/2014 12:42 SW 6010C Total Potassium 0.41 4130 100 KM 05/14/2014 12:42 SW 6610C Total Sulfur 0.76 7610 100 KM 05/14/2014 12:42 SW 6010C Total Calcium 2.92 29200 100 KM 05/14/2014 12:42 SW 6010C Total Magnesium 0.40 3970 100 KM 05/14/2014 12:42 SW 6010C Total Sodium 0.09 862 100 KM 05/14/2014 12:42 SW 6010C Total Iron 20300 100 KM 05/14/2014 12:42 SW 6010C Total Aluminum 20900 100 KM 05/14/2014 12:42 SW 6010C Total Manganese 1490 5 KM 05/14/2014 12:42 SW 6010C Total Copper 308 5 KM 05/14/2014 12:42 SW 6010C Total Zinc 704 5 KM 05/14/2014 12:42 SW 6010C Ammonia Nitrogen 1.51 15100 10.0 JM -'05/14/2014 08:24 SM-4500-NI3C Organic N 4.45 44500 10.0 05/14/2014 08:24 CALCULATION Nitrate+Nitrite-N Q.00 2.00 JM 05/14/2014 08:25 SM-450ONO3F Total Cadmium 5.0 2.0 KM 05/14/2014 12:42 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-133-0206 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 55320 Sample Id: STATESVILLE 4TH CK �L A&L Eastern Laboratories, Inc:, 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwW aleastern.com Project: STATESVILLE 4TH CK/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 5/11/2014 11:15:00 Date Received: 05/13/2014 00:00 Date Reported: 05/16/2014 Total Chromium 56 5 KM 05/14/2014 12:42 SW 6010C Total Nickel 46 5 KM 05/14/2014 12:42 SW 6010C Total Lead 32 5 KM 05/14/2014 12:42 SW 6010C Total Arsenic 5.0 3.0 KM 05/14/2014 12:42 SW 6010C Total Mercury 0.5 0.4 KM 05/14/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 05/14/2014 12:42 SW 6010C pH (Standard Units) * 7.98 2.00 JM 05/14/2014 08:30 SW-9045D Total Molybdenum 12 5 KM 05/14/2014 12:42 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Cr", "Fe", "Ni", AND "Se". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2084-01-CAK-NC STATESVILLE, NC FOURTH CREEK CAKE 5/11/2014 4/1/2014-6/30/2014 0.4715 Na mg/I = (Na mg/kg x % Solids) _ 100 = (862 x 14.1700) =100 = 122.145 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (29200 x 14.1700) = 100 = 4137.64 Mg mg/I = (mg mg/kg x % Solids) = 100 = (3970 x 14.1700) = 100 = 562.549 Na meq = Na mg/I = Molec.Wgt.Na = 122.145 = 23 = 5.31067 Ca meq = Ca mg/I + Molec.Wgt.Ca = 4137.64 + 20 = 206.882 Mg meq = Mg mg/I = Molec.Wgt.Mg = 562.549 = 12 = 46.8791 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 5.31067 = SgrRoot[0.5(206.882+46.8791)] = 0.471468 ` ` Printed: 1 /27/2015 Page 1 11:12 Page: 1 of 2 Report Number: 14-273-0211 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57857 Sample Id : STATESVILLE 4TH CK A&L_Eastern Laboratories, Inc. .7621 Whitepine Road Richmond, Virginia,23237 (804) 743.9401 Fax (804) 271-6446 wwwaleasterh.com Project: STATESVILLE 4TH CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/26/2014 13:25:00 Date Received: 09/30/2014 00:00 Date Reported: 10/06/2014 Total Solids 14.94 149400 100.0 BW 09/30/2014 14:15 SM-2540G Moisture ` 85.06 100.0 BW 09/30/2014 14:15 SM-2540G Total Kjeldahl Nitrogen 5.05 50500 10.0 JM 10/01/2014 08:44 SM-4500-NH3C-TKN Total Phosphorus 2.96 29600 100 KM 10/01/2014 12:04 SW 6010C Total Potassium 0.23 2260 100 KM 10/01/2014 12:04 SW 6010C Total Sulfur 0.83 8250 100 KM 10/01/2014 12:04 SW 6010C Total Calcium 0.68 6750 100 KM 10/01/2014 12:04 SW 6010C Total Magnesium 0.16 1620 100 KM .10/01/2014 12:04 SW 6010C Total Sodium 0.09 881 100 KM 10/01/2014 12:04 SW 6010C Total Iron 27100 100. KM 10/01/2014 12:04 SW 6010C Total Aluminum 30100 100 KM 10/01/2014 12:04 SW 6010C Total Manganese 853 5 KM 10/01/2014 12:04 SW 6010C Total Copper 370 5 KM 10/01/2014 12:04 SW 6010C Total Zinc 458 5 KM 10/01/2014 12:04 SW 6010C Ammonia Nitrogen 0.78 7760 10.0 JM 10/01/2014 08:44 SM-4500-NH3C Organic N 4.27 42740 10.0 10/01/2014 08:44 CALCULATION Nitrate+Nitrite-N <2.00 2.00 JM 10/01/2014 08:45 SM-450ONO3F Total Cadmium 4.0 2.0 KM 10/01/2014 12:04 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series. is on a, wet basis. 4 Our d reports and letters are for the exclusive aconfidential- , ft-'66, p n use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-273-0211 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57857 Sample Id : STATESVILLE 4TH CK @P A&L Eastern Laboratories, Inc._ 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 wwlwaleastern.com Project: STATESVILLE 4TH CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/26/2014 13:25:00 Date Received: 09/30/2014 00:00 Date Reported: 10/06/2014 Total Chromium 42 5 KM 10/01/2014 12:04 SW 6010C Total Nickel 22 5 KM 10/01/2014 12:04 SW 6010C Total Lead 30 5 KM 10/01/2014 12:04 SW 6010C Total Arsenic 4.0 3.0 KM 10/01/2014 12:04 SW 6010C Total Mercury <0.4 0.4 KM 09/30/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 10/01/2014 12:04 SW 6010C pH (Standard Units) * 5.67 2.00 JM 10/01/2014 08:50 SW-9045D Total Molybdenum 11 5 KM 10/01/2014 12:04 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE AND MSD WERE OUT OF LIMITS FOR "Mg". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2084-01-CAK-NC STATESVILLE, NC FOURTH CREEK CAKE 9/26/2014 9/1/2014-10/31/2014 0.9632 Na mg/1= (Na mg/kg x % Solids) + 100 = (881 x 14.9400) + 100 = 131.621 Ca mg/1= (Ca mg/kg x % Solids) = 100 = (6750 x 14.9400) = 100 = 1008.45 Mg mg/I = (mg mg/kg x % Solids) = 1'00 = (1620 x 14.9400) - 100 = 242.028 Na meq = Na mg/I = Molec.Wgt.Na = 131.621 + 23 = 5.72267 Ca meq = Ca mg/I = Molec.Wgt.Ca = 1008.45 = 20 = 50.4225 Mg meq = Mg mg/I _ Molec,Wgt.Mg = 242.028 _ 12 = 20.169 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] 5.72267 = SgrRoot[0.5(50.4225+20.169)] = 0.963247 Printed: 1 /27/2015 Page 1 11:12 i ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0016247 Laboratory Facility Name: STATESVILLE, NC A&L Eastern Laboratories Inc. NPDES# : NCO020591 or WQ# (residual only) WWTP Name: THIRD CREEK Residuals Analysis Data Product Type CAx CAx CAx CAx Date Sampled (grab) or 01/09/14 05/11/14 09/26/14 01/29/15 Date Composited Percent Solids 14.19 15.38 16.43 15.49 PARAMETERS (mg/kg dry weight) Arsenic 5 3 3 4 Cadmium 12 11 15 17 Mercury 0.4 <0.4 <0.4 0.6 Chromium 88 85 101 109 Copper 438 369 453 417 Lead 99 82 127 107 Molybdenum 23 16 19 20 Nickel 55 54 47 52 Selenium <5 <5 <5 <5 Zinc 1090 1230 965 1150 Total Phosphorus 19300 18100 20400 17300 TKN 49300 53400 39700 34100 Ammonia -Nitrogen 4580 5330 4020 1940 Nitrate and Nitrite 14.8 7.15 21.9 444 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed assure that qualiii.ed pers nnel properly gathered and evaluated the information submitted. I am aware that there are significa pe hies for submitting fa & information, including the possibility of fines and imprisonment for knowing violations." X Date (SIGNATURA OF PREPARER) DENR FORM RSSF (5/2003) Printed: Tuesday - February 10, 2015 at 13:55:28 for. 2084 02 I ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0016247 Laboratory Facility Name: STATESVILLE, NC A&L Eastern Laboratories Inc. NPDES# : NCO020591 or WQ# (residual only) WWTP Name: THIRD CREEK Residuals Analysis Data Product Type CAK CAI{ CAK CAK Date Sampled (grab) or 01/09/14 05/11/14 09/26/14 01/29/15 Date Composited Percent Solids 14.19 15.38 16.43 15.49 PARAMETERS (mglkg dry weight) Aluminum 15800 15800 19900 16800 Calcium 10600 10700 12200 16300 Magnesium 2460 3300 2150 2180 pH 5.96 8.09 6.07 5.10 Potassium 2940 3770 2050 2180 Sodium 1140 1450 1440 568 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to ss a that qualified per onnel properly gathered and evaluated the information submitted. I am aware that there are significant en es for su mitting Ise information, including the possibility of fines and imprisonment for knowing violations." X Date O< j (SIGNATUI� OF PREPARER) NR - Data Not Reported or Data Not Required DENR FORM RSSF-B (7/2002) Printed: Tuesday - February 10, 2015 at 13:55:57 for: 2084 02 Page: 1 of 2 Report Number: 14-010-0200 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97419 Sample Id: 3RD CK @P, A&L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271-6446 www.aleastern.com Project: STATESVILLE 3RD CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/9/2014.09:15:00 Date Received: 01/10/2014 00:00 Date Reported: 01/15/2014 Total Solids ` 14.19 141900 100.0 JM 01/10/2014 14:19 SM-2540G Moisture * 85.81 100.0 JM =01/10/2014 14:19 SM-2540G Total Kjeldahl Nitrogen 4.93 49300 10.0 JM 01/13/2014 08:30 SM-4500-NH3C-TKN Total Phosphorus 1.93 19300 100 KM 01/13/2014 11:35 SW 6010C Total Potassium 0.29 2940 100 KM 01/13/2014 11:35 SW 6010C Total Sulfur 0.91 9070 100 KM 01/13/2014 11:35 SW 6010C Total Calcium 1.06 10600 100 KM 01/13/2014 11:35 SW 6010C Total Magnesium 0.25 2460 100 KM 01/13/2014 11:35 SW 6010C Total Sodium 0.11 1140 100 KM 01/13/2014 11:35 SW 6010C Total Iron 24000 100 KM 01/13/2014 11:35 SW 6010C Total Aluminum 15800 100 KM 01/13/2014 11:35 SW 6010C Total Manganese 531 5 KM 01/13/2014 11:35 SW 6010C Total Copper 438 5 KM 01/13/2014 11:35 SW 6010C Total Zinc 1090 5 KM 01/13/2014 11:35 SW 6010C Ammonia Nitrogen 0.46 4580 10.0 JM 01/13/2014 08:30 SM-4500-NH3C Organic N 4.47 44720 10.0 01/13/2014 08:30 CALCULATION Nitrate+ N itrite-N 14.8 2.00 JM 01/13/2014 08:30 SM-450ONO3F Total Cadmium 12.0 2.0 KM 01/13/2014 11:35 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt --1 Page: 2 of 2 Report Number: 14-010-0200 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 97419 Sample Id : 3RD CK �L A&L Eastern Laboratories, Inc., .7621 Whitepine Road Richmond, Virginia 23237 (804) 743-9401 Fax (804) 271.6446 www,aleastem.com Project: STATESVILLE 3RD CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 1/9/2014 09:15:00 Date Received: 01/10/201.4 00:00 Date Reported: 01/15/2014 Total Chromium 88 5 KM 01/13/2014 11:35 SW 6010C Total Nickel 55 5 KM 01/13/2014 11:35 SW 6010C Total Lead 99 5 KM 01/13/2014 11:35 SW 6010C Total Arsenic 5.0 3.0 KM 01/13/2014 11:35 SW 6010C Total Mercury 0.4 0.4 KM 01/13/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 01/13/2014 11:35 SW 6010C pH (Standard Units) * 5.96 2.00 JM 01/13/2014 08:30 SW-9045D Total Molybdenum 23 5 KM 01/13/2014 11:35 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MSD WAS OUT OF LIMITS FOR "NO3/NO2-N'' AND "Se". THE MATRIX SPIKE WAS OUT OF LIMITS FOR "As" AND "S". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt SAMPLING LOG # A & ° I IN OF CUSTODY 997E2 ���+��III �InN�lllll�++�l l .4M oo ,RD & ANALYSIS NT RICE SYNAGROCERAL LLGSTATESVILLE 2014 RECORD CUSTOMER: SYNAGRO SOUTHEAST M 804 STATESVILLE3RDCK f2:49:31 .� !sampling procedures PROJECT MANAGER: f=t L /�s� were use., U..,,..J .. ction of these samples. Phone: ( 33� 0% j 1 D p S SA P R A & L CUSTOMER SAMPLING SAMPLE # OF SAMPLING METHOD METHOD LAB # SAMPLE I.D. LOCATION TYPE CONTAINERS DATE TIME PRESERVED SHIPPED 54i C /<' /M Coif' i cl fo�i� 015 () 41�) BPS l-T,/ (�(1' l /�I �1 i1 j �i MLo " f' Z 1, Relinquished by Sampler: Date %Lj Time Recieved by: REMARKS: C `� fW of d 9 iSvo Relinquished by: Dat Time Recieved l PS c 14D 2 0 '/Icl1' Relinquished by: D e Time Recieved b . SPECIAL INSTRUCTIONS: For 1� monitoring purposes. SAMPLE ANALYSIS REQUEST I.D. SLi SL2 NHa N NO3 N Organic N Cd Cr Ni Pb As Hg Se pH CaUl 3 equiv. Volatile Solids Mo CI NOZ N SL1: Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SLY: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium. Iron, Aluminum, Manganese, Copper and Zinc White —A & L Canary — MANAGER COPY Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2084-02-CAK-NC' STATESVILLE, NC THIRD CREEK CAKE 1/9/2014 1/1/2014-3/31/2014 0.9740 Na mg/I = (Na mg/kg x % Solids) _ 100 = (1140 x 14.1900) + 100 = 161.766 Ca mg/I = (Ca mg/kg x % Solids) = 100 = (10600 x 14.1900) + 100 = 1504.14 Mg mg/1 = (mg mg/kg x % Solids) = 100 = (2460 x 14.1900) = 100 = 349.074 Na meq = Na rrig/I + Molec.Wgt.Na = 161.766 - 23 = 7.0333 Ca meq = Ca mg/I - Molec.Wgt.Ca = 1504.14 _ 20 = 75.207 Mg meq = Mg mg/I.- Molec.Wgt.Mg = 349.074 _ 12 = 29.0895 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 7.0333 = SgrRoot[0.5(75.207+29.0895)] = 0.973956 Printed: 1 /27/2015 Page 1 11:12 , Page: 1 of 2 Report Number: 14-133-0205 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 55319 Sample Id: STATESVILLE 3RD CK LA &L Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804)'743-9401 Fax (804) 271-6446 wwwaleastern.0m Project: STATESVILLE 3RD CK/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 5/11/2014 11:10:00 Date Received: 05/13/2014 00:00 Date Reported: 05/16/2014 Total Solids * 15.38 153600 100.0 JM 05/13/2014 13:59 SM-2540G Moisture * 84.62 100.0 JM 05/13/2014 13:59 SM-2540G Total Kjeldahl Nitrogen 5.34 53400 10.0 JM 05/14/2014 08:24 SM-4500-NH3C-TKN Total Phosphorus 1.81 18100 100 KM 05/14/2014 12:42 SW 6010C Total Potassium 0.38 3770 100 KM 05/14/2014 12:42 SW 6010C Total Sulfur 0.80 7950 100 KM 05/14/2014 12:42 SW 6010C Total Calcium 1.07 10700 100 KM 05/14/2014 12:42 SW 6010C Total Magnesium 0.33 3300 100 KM 05/14/2014 12:42 SW 6010C Total Sodium 0.15 1450 100 KM 05/14/2014 12:42 SW 6010C Total Iron 20400 100 KM 05/14/2014 12:42 SW 6010C Total Aluminum 15800 100 KM 05/14/2014 12:42 SW 6010C Total Manganese 592 5 KM 05/14/2014 12:42 SW 6010C Total Copper 369 5 KM 05/14/2014 12:42 SW 60106 Total Zinc 1230 5 KM 05/14/2014 12:42 SW 6010C Ammonia Nitrogen 0.53 5330 10.0 JM 05/14/2014 08:24 SM-4500-NH3C Organic N 4.81 48070 10.0 05/14/2014 08:24 CALCULATION Nitrate+Nitrite-N 7.15 2.00 JM 05/14/2014 08:25 SM-450ONO3F Total Cadmium 11.0 10 KM 05/14/2014 12:42 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-133-0205 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 55319 Sample Id : STATESVILLE 3RD CK A&L Eastern Laboratories, Inc: .7621.Whitepine Road Richmond, Virginia 23237 (804)743-8401 Fax (804) 271.6446 W W W 2leastern.com Project: STATESVILLE 3RD CK/NC CERT#257 REPORT OF ANALYSIS Date Sampled: 5/11/2014 11:10:00 Date Received: 05/13/2014 00:00 Date Reported: 05/16/2014 Total Chromium 85 5 KM 05/14/2014 12:42 SW 6010C Total Nickel 54 5 KM 05/14/2014 12:42 SW 6010C Total Lead 82 5 KM 05/14/2014 12:42 SW 6010C Total Arsenic 3.0 3.0 KM 05/14/2014 12:42 SW 6010C Total Mercury <0.4 0.4 KM 05/14/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 05/14/2014 12:42 SW 6010C pH (Standard Units) * 8.09 2.00 JM 05/14/2014 08:30 SW-9045D Total Molybdenum 16 5 KM 05/14/2014 12:42 SW 6010C Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "Cr", "Fe", "Ni", AND "Se". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. / Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date ReportRange Ratio 2084-02-CAK-NC STATESVILLE, NC THIRD CREEK CAKE 6/11/2014 4/1/2014-6/30/2014 1.2285 Na mg/1= (Na mg/kg x % Solids) = 100 = (1450 x 15.3800) = 100 = 223.01 Ca mg/1= (Ca mg/kg x % Solids) _ 100 = (10700 x 15.3800) = 100 = 1645.66 Mg mg/1 = (mg mg/kg x % Solids) = 100 = (3300 x 15.3800) = 100 = 507.54 Na meq = Na mg/I _ Molec.Wgt.Na = 223.01 _ 23 = 9.69609 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 1645.66 = 20 = 82.283 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 507.54 = 12 = 42.295 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 9.69609 _ SgrRoot[0.5(82.283+42.295)] = 1.22854 Printed: 1/27/2015 Page 1 11:13 Page: 1 of 2 ReportNumber: 14-273-0210 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57856 Sample Id : STATESVILLE 3RD CK 9A&L� Eastern Laboratories, Inc. 7621 Whitepine Road Richmond, Virginia 23237 (804),743-9401 Fax (804) 271-6446 „' o www,aleastern.com Project: STATESVILLE 3RD CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/26/2014 13:35:00 Date Received: 09/30/2014 00:00 Date Reported: 10/06/2014 Total Solids " 16.43 164300 100.0 BW 09/30/2014 14:15 SM-2540G Moisture * 83.57 100.0 BW 09/30/2014 14:15 SM-2540G Total Kjeldahl Nitrogen 3.97 39700 10.0 JM 10/01/2014 08:44 SM-4500-NH3C-TKN Total Phosphorus 2.04 20400 100 KM 10/01/2014 12:04 SW 6010C Total Potassium 0.21 2050 100 KM 10/01/2014 12:04 SW 6010C Total Sulfur 0.89 8920 100 KM 10/01/2014 12:04 SW 6010C Total Calcium 1.22 12200 100 KM 10/01/2014 12:04 SW 6010C Total Magnesium 0.22 2150 100 KM 10/01/2014 12:04 SW 6010C Total Sodium 0.14 1440 100 KM 10/01/2014 12:04 SW 6010C Total Iron 29000 100 KM 10/01/2014 12:04 SW 6010C Total Aluminum 19900 100 KM 10/01/2014 12:04 SW 6010C Total Manganese 420 5 KM 10/01/2014 12:04 SW 6010C Total Copper 453 5 KM 10/01/2014 12:04 SW 6010C Total Zinc 965 5 KM 10/01/2014 12:04 SW 6010C Ammonia Nitrogen 0.40 4020 10.0 JM 10/01/2014 08:44 SM-4500-NH3C Organic N 3.57 35680 10.0 10/01/2014 08:44 CALCULATION Nitrate+Nitrite-N 21.9 2.00 JM 10/01/2014 08:45 SM-450ONO3F Total Cadmium 15.0 2.0 KM 10/01/2014 12:04 SW 6010C All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. 9 Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made , ML4 to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Debbie Holt Page: 2 of 2 Report Number: 14-273-0210 Account Number: 46493 Submitted By: ERIC THOMPSON Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE , NC 27028 Lab Number: 57856 Sample Id : STATESVILLE 3RD CK �L A&L Eastern, Laboratories, Inc-.._ -7621 Whitepine Road Richmond, Virginia 23237 (804) 709401, Fax (804) 271-6446 wwwaleastem.cotn Project: STATESVILLE 3RD CK NC CERT#257 REPORT OF ANALYSIS Date Sampled: 9/26/2014 13:35:00 Date Received: 09/30/2014 00:00 Date Reported: 10/06/2014 Total Chromium 101 5 KM 10/01/2014 12:04 SW 6010C Total Nickel 47 5 KM 10/01/2014 12:04 SW 6010C Total Lead 127 5 KM 10/01/2014 12:04 SW 6010C Total Arsenic 3.0 3.0 KM 10/01/2014 12:04 SW 6010C Total Mercury <0.4 0.4 KM 09/30/2014 09:00 SW-7471 B Total Selenium <5.0 5.0 KM 10/01/2014 12:04 SW 6010C pH (Standard Units) * 6.07 2.00 JM 10/01/2014 08:50 SW-9045D Total Molybdenum 19 5 KM 10/01/2014 12:04 SW 60100 Comments: SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES. QUALIFIER: THE MATRIX SPIKE AND MSD WERE OUT OF LIMITS FOR "Mg". ALL OTHER QC DATA IS ACCEPTABLE. All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written,authorization. on- 77i7a:711 Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range Ratio 2084-02-CAK-NC STATESVILLE, NC THIRD CREEK CAKE 9/26/2014 911/2014-10/3112014 1.2776 Na mg/I = (Na mg/kg x % Solids) = 100 = (1440 x 16.4300) _ 100 = 236.592 Ca mg/I = (Ca mg/kg x % Solids) + 100 = (12200 x 16A300) = 100 = 2004.46 Mg mg/I = (mg mg/kg x % Solids) _ 100 = (2150 x 16.4300) = 100 = 353.245 Na meq = Na mg/1 = Molec.Wgt.Na = 236.592 _ 23 = 10.2866 Ca meq = Ca mg/I _ Molec.Wgt.Ca = 2004.46 = 20 = 100.223 Mg meq = Mg mg/1 _ Molec.Wgt.Mg = 353.245 = 12 = 29.4371 SAR = Na meq _ SgrRoot[0.5 x (Ca`meq + Mg meq)] = 10.2866 = SgrRoot[0.5(100.223+29.4371)] = 1.27757 Printed: 1/27/2015 Page 1 11:13 ------ - _ -- ...: _ r_ �— A&L Eastern Laboratories, Inc. - 7621 Whttepine Road Richmond, Virginia 23237 - (804) 743.9401 Fax (804)271-446 . +,I h . Project: 3RD CHECK/NC CERT#257 . . iRTOFANALYSI$.. DateSampled:.1/29/2015:09:30:00 Date Received: 01/30/2015 00:00 ;s Date Reported: 02/05/2015 PARAMETER P-11-PA I I IAI 12. ANALYST DATE/TIME METHOD .. Total Solids *:... 15.49..: 154900 100.0 RD 01/30/2015.14:19' SM-2540G Moisture *- 84.51 100.0 RD- 01/301201514:19 SM-2540G `N Total Kjeldahl Nitrogen 3.41 341.00 10.0 JM 02/02/2015 08:24 SM-4500=NH3C-TKN Total Phosphorus 1.73 . 17300 100 .. KM 02/02/201513:08 SW 6010C. Total Potassium 0.22 2180 100 KM 02/02/201618:08 ... SW 6010C' Total Sulfur 0.76 7630. 100 _. . KM 02102/201513:08 SW 6010C Total Calcium 1.63 16300 100 - KM 02/02/2015.13:08 SW 6010C- ::.:. Total=Magnesium - 0.22 : 2180 100 KM 02/02/201513:08 SW 601OG t Total Sodium 0.06 568 : 100 KM 02/021201513:08 SW 6010C ! i Total Iron 22700 100 :. KM 02/02/2015 13.08: SW 6010C l >: Total Aluminum 1-6800 100 ..KM 02/02/201513:08 SW 6010C . . Total Manganese 509 5 KM.: = 02/02/2015 13:08. $VU 010C .6. Total Copper :.. 417 5 KM : 02102/901513:08 : SW 6010C Total Zinc 1150 5 KM 02102/201513:08 SW 6010C Ammonia Nitrogen _ '0.19 1940 10.0 JM 02/02I2015 08:24 SM4500-NH3C:' . Organic N 5.22 32160 10.0 02/02/2015 08:24 CALCULATION Nitrate+Nitrite-N 444 2.00 JM - 02/02/2015 08:25 SM-4500NOV.: y . Total Cadmium 17.0 2.0 KM 02102/2015-13:08 SW 6010C ?sa All values are on a dry weight basis except as noted by asterisk. 'Detection limit on all N series is on a wet basis. k' Our reports and letters are for the exclusive and confidential use of our clients, and'may not be reproduced in whole or part; nor may any reference be made to the work, the results, 'or the company in any advertising, news release, orother public announcements without obtaining our prior written'authodzation., I'. Debbie Holt i Page: 2 of 2,,1 A& { Report Number: 15-030-0200; L Eastern Laboratories, Inc, .. Account Number. '46493 A 76iiWhitepin©Road Richmond; Virginia23237 '(804)7434401-Fax(804)271.6446 i; Submitted By: ERIC THOMPSON wwwaleastem.com i:i. Send To:, SYNAGRO CENTRAL LLC/STATESVILLE Project : 3RD CHECK/NC CERT#257 Mary.Brewer. : 284 ROGER RD MOCKSVILLE�, NC '27028 1„ PEPORTALYS Date Sampled. 1/29/2015.09:30:00 Lab Number:; 59938 O FAN lS Date Received: 01/30/2015 00:00 3 Sample Id•r.3RD CK .... Date Reported: 02/05/2015 .. i s • j . •. .:.: . • . DATEITIMEF ... . n Total Chromium 109 5 : :.KM 02/02/201513:08 SW 601007i . . Total Nickel 52 5 KM 02/02/20151.3:08 SW 6010C Total Lead 1,07 5 KM 02/02/20-1513:08 SW 6010C . Total Arsenic . 4.0 3.0 .. KM 02/02/201513:08 SW 6010C . Total Mercury 0.6 . - 0.4 KM &,03%201513:35 8W-7471 B <5.0.. 5.0 KM . 02/02/201513:08 SW 6010G� .:.... Total Selenium ' pH (Standard Units) * 5A0 2.00 JM 02/02/2015 06:24 SW-9045D Total,Molybdenum 20 5 KM02/02/2015 13:0$ SW 6010C' Comments: . SULFUR AND ORGANIC NITROGEN NOT FOR COMPLIANCE PURPOSES: " r: QUALIFIER: THE MATRIX SPIKE WAS OUT OF LIMITS FOR "AI" AND "Se". ALL OTHER QC DATA IS ACCEPTABLE::?. - All valuesare on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.,lit Our repo'fts'end letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part nor may any reference be madea to the ivoilr, the results, or fhe company tn'any`advedfsirig, news release, orotherpublic announcements without obtaln4v ourprior written authorization. " Debbie Holt i; Sodium Absorption Ratio Calculation (SAR) Product Code Product Name Sample Date Report Range: Ratio 2084-02-CAK-NC STATESVILLE, NC THIRD CREEK CAKE 1/29/2015 / 1 - 1 V 0.4354 Na mg/l = (Na mg/kg x % Solids) = 100 = (568 x 15.4900) =100 = 87.9832 Ca mg/I = (Ca mg/kg x.% Solids) _ 100 = (16300 x 15.4900) =100 = 2524.87 . Mg mg/1= (mg mg/kg x % Solids) =100 = (2180 x 15.4900) = 100 = 337.682 Na meq = Na mg/I _ Molec.Wgt.Na = 87.9832 23 = 3.82536 Ca. meq = Ca mg/I + Molec.Wgt.Ca = 2524.87 = 20 = 126.244 Mg meq = Mg mg/1 + Molec.Wgt.Mg = 337.682 =12 = 28.1402 SAR = Na meq _ SgrRoot[0.5 x (Ca meq + Mg meq)] = 3.82536 _ SgrRdot[0.5(126.244+28.1402)] = 0.435398 SAMPLING LOG # A do L EASTEI 7621 Whitepin CUSTOMER: SYNAGRO Richmond, VA 8041743-9401 PROJECT MANAGER:j/� r �u Phone: A& L CUSTOMER SAMPUNG SAMPLE LAB # SAMPLE I.D. LOCATION TYPE 3 4 e4ed 1 11ll1AINII��III��I�u�I��III�II��IWII�IIw ozoo 46493 SYNAGRO CENTRAL LLG01.30-2015STATESVILLE 12'S6:28 3RD CHECKINC CERT0257 STODY A�'Y`S�S ►cedures were u$eo aunng me collection or mere samples. #OF SAMPLING CONTAINERS DATE TIME 1 Otlal if • 6g14 METHOD PRESERVED L' cS) elinqu' ed by am ler: ¢ate Time Recieved by: REMARKS_ elfin ed Da Time Redeved by: Relinquished by: Date I Ti de Recleved by: METHOD SHIPPED orG AM1 IN-D I HUU I IUNS: /� ry I4A-r&?Al For rltL monitoring purposes. PO#: So Lb v SAMPLE ANALYSIS REQUEST I.D. SL1 SL2 NH -N NO -N Organic a 3 N Cd Cr Ni Pb As Hg Se pH COCO, Volatile Mo CI NO -N equiv Solids s C 1� 1/t r� 'LIF 1% 1f !f jf Y'r �r 1/r 1f � 1! yr SL1: Total Solids (Moisture), Total Neldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: STATESVILLE, NC PREDOMINANT SOIL SERIES: RHODISS OWNER: TIMOTHY PAYNE PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 13.84 SITE #: NC AL 00014 FIELD# : AL 00014 0001 A OPERATOR: TIMOTHY PAYNE CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 19.20 ACRES PERMITTED: 19.20 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm), Crop MONTH Total FprAc,. Solids 10/9/14 100.00 (CY) 5.208 16.43 0.721 STTCC DRY 0-<1/2" SUR 0.5 0.30 39,700. p 4,020.00 p 1 21.90 p 12736 WHEAT Oct-14 100.00 (Cl) 5.208 1 1 r orai t;uoic x as/Hc: �).Z1 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.004 0.022 0.146 0.653 0.183 <.001 0.027 0.068 0.007 1.391 29.41 18 Cumulative Ibs/acre 0.004 0.022 0.146 0.653 1 0.183 1 <.001 0.027 1 0.068 0.007 1.391' 1 Permit PAN Limit (Ibs/acre) 1st Cro /2nd Crop u k x I. . FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0" ` 375.0 89.0 2500.0 a STTCC = STATESVILLE, NC THIRD CREEK CAKE X aL �3 � / :: �r (SIGNAT " OF L APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: TIMOTHY PAYNE SITE #: NC AL 00014 FIELD# : AL 00014 0001 B RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CLIFFORD PERMIT #: WQ0016247 ANNUAL DRY TONS APPLIED: 82.41 OPERATOR: TIMOTHY PAYNE CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 22.70 ACRES PERMITTED: 22.70 Page Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 10/8/14 325.00 (CY) 14.317 14.94 1.802 STFCC DRY 0-<1/2" SUR 0.5 0.30 50,500. p 7,760.00 p 2.00 p 16704 WHEAT Oct-14 1 325.00 (CY) 14.317 10/8/14 50.00 (CY) 2.203 16.43 0.305 STTCC DRY 0-<1/2" SUR 0.5 0.30 39,700. p 4,020.00 p 21.90 p 12736 I WHEAT 10/9/14 250.00 (CY) 11.013 16.43 1.524 STTCC DRY 0-<1/2" SUR 0.5 0.30 39,700. p 4,020.00 p 21.90 p 12736 WHEAT Oct-14 300.00 (CY) 13.216 r oral l.uD10 r U5/1 W: L7.D3 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual Ibs/acre 0.025 0.069 0.521 2.990 0.573 0.003 0.109 0.251 0.036 5.180 181.26 107 Cumulative lbs/acre 0.025 0.069 0.521 2.990 0.573 0.003 0.109 0.251 0.036 5.180 r" s., " 7- `° 120 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop t ,. ) d$ FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 .;$ 1339.0 267.9 15.0 375.0 89.0 2500.0 t .: STFCC = STATESVILLE, NC FOURTH CREEK CAKE STTCC = STATESVILLE, NC THIRD CREEK CAKE X (SIGNATURE OF D APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = pp- or mg/kg ** Volatilization Rate: Surface 0.5, hijection/Incorporation 1.0 Application Method: SUR - Surface, INJ -Injection, SURIN- Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: DENNIS PHILLIPS SITE #: NC IR 00020 FIELD# : IR 00020 0004 A RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 142.19 OPERATOR: DENNIS PHILLIPS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 44.20 ACRES PERMITTED: 44.20 Page : 1 Lime Appfied •*• Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 1/27/14 224.00 (CY) 5.068 14.19 0.606 STTCC DRY 0-<1/2" SUR 0.5 0.30 49,300. p 4,580.00 p 14.80 p 15721 FESCUE 1/28/14 416.00 (CY) 9.412 14.19 1.125 STTCC DRY 0-<1/2" SUR 0.5 0.30 49,300. p 4,580.00 p 14.80 p 15721 FESCUE Jan-14 640.00 (CY) 14.480 2/27/14 416.00 (CY) 9.4121 14.19 1.125 STTCC MOIST 0-<1/2" SUR 0.5 0.30 49,300. p 4,580:00 p 14.80 p 15721 FESCUE Feb-14 416.00 (CY) 9.412 3/1/14 128.00 (CY) 2.8961 14.83 0.362 STFCC MOIST 0-<1/2" SUR 0.5 0.30 54,600. p 9,510.00 p 12.10 p 18214 FESCUE Mar-14 128.00 (CY) 2.896 Total Cubic Yds/Ac: 26.79 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: 103 Annual lbs/acre 0.032 0.072 0.537 2.765 0.591 0.003 .0.141 0.339 0.032 6.738 128:88 Cumulative lbs/acre 0.131 0.197 1.649 10.616 1.704 0.039 0.393 1.070 0.109 21.923 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop - 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 STTCC = STATESVILLE, NC THIRD CREEK CAKE STFCC = STATESVILLE, NC FOURTH CREEK CAKE X D 13 ►S (SIGNATURE fenalty ND AP R) DATE "I certify, undeof law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: DENNIS PHILLIPS SITE #: NC IR 00020 FIELD# : IR 00020 0007 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: HELENA PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 35.28 OPERATOR: DENNIS PHILLIPS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 13.90 ACRES PERMITTED: 13.90 Page Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) "�o Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 2/28/14 160.00 (CY) 14.83 1.438 STFCC MOIST 0-<1/2" SUR 0.5 0.30 54,600.p 9,510.00 p 12.10 p 18294 FESCUE Feb-14 160.00 (CY) 2/27/14 128.00 (CY) ]9.2091 14.19 1.101 STTCC MOIST 0 <1/2" SUR 0.5 0.30 49,300. p 4,580.00 p 14.80 p 15721 FESCUEFeb-14 1 128.00 (CY) I UU11 I.UUIU IUWI-W. GU./L As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.025 0.041 0.332 2.011 0.321 0.005 0.091 0.219 0.025 4.438 116.67 87 Cumulative lbs/acre 0.113 0.124 1.143 8.154 1.012 0.044 0.299 0.759 0.125 15.288 a., Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 188 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 ( La 1339.0 267.9 15.0 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE STTCC = STATESVILLE, NC THIRD CREEK CAKE X D2- 13 r (SIGNATURE LAND PLIER) DATE "I certify, and penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, . Injection/Incorporation 1.0 k Application Method: SUR - Surface, INJ -Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: DENNIS PHILLIPS SITE #: NC IR 00020 FIELD# : IR 00020 0008 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: APPLING PERMIT #: WQ0016247 ANNUAL DRY TONS APPLIED: 27.98 OPERATOR: DENNIS PHILLIPS CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 11.20 ACRES PERMITTED: 11.20 Page : 1 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 2/28/14 224.00 (CY) 20.000 14.83 2.498 STFCC MOIST 0-<1/2" SUR 0.5 0.30 54,600. p 9,510.00 p 12.10 p 18294 FESCUE Feb-14 224.00 (CY) 20.000 1 1 1 VLaL VUUIU IUW/ V. LU.UU As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 91 0.025 0.025 0.240 1.819 0.180 0.006 0.070 0.170 0.025 3.542 128.90 Cumulative lbs/acre 0.113 0.161 1353 9.838 1.333 0.042 0331 0.871 0.159 17.787 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop ::: 4 r 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 ° e: a •,";- i 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE x (SIGNATURE 0 AND PLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN- Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: STATESVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: DENNIS PHILLIPS PERMIT #: WQ0016247 ANNUAL DRY TONS APPLIED: 43.79 SITE #: NC IR 00020 FIELD# : IR 00020 0009 OPERATOR: DENNIS PHILLIPS CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 12.20 ACRES PERMITTED: 12.20 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) 0 Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 2/28/14 320.00 (CY) 26.230 14.83 3.276 STFCC MOIST 0-<1/2" SUR 0.5 0.30 54,600. p 9,510.00 p 12.10 p F794 FESCUE Feb-14 320.00 (CY) 26.230 3/l/14 32.00 (CY) 2.623 14.19 0.313 STTCC MOIST 0-<1/2" SUR 0.5 0.30 49,300. p 4,580.00 p 14.80 p 15721 FESCUE Mar-14 32.00 (CY) 2.623 i VLaI �UUu 1 UWn . La.BJ As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 130 0.036 0.040 0.370 2.660 0.298 0.009 0.106 0.257 0.036 5.329 181.15 Cumulative Ibs/acre 0.121 0.194 1.613 10.909 1.635 0.046 0.390 0.999 0.164 20.661 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 `�iar:., �., �.5 "*:"'',i ,.r9":.' M*1 a,. ,,*j ,v v ,. ax .,.'+.' .da.,.." p 5i., ,k. FD Cumulative Pollutant LoadingRate Limit lbs/acre ( ) 36.6 34.8 � � 1339.0 267.9 15.0 375.0 89.0 2500.0 � .� STFCC = STATESVILLE, NC FOURTH CREEK CAKE STTCC = STATESVILLE, NC THIRD CREEK CAKE X (SIGNATURE O AND LIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ 7 Injection, SURIN- Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: LORANE PAGE SITE #: NC IR 00023 FIELD# : IR 00023 0001 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 66.37 OPERATOR: EDDIE PORTER CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 17.20 ACRES PERMITTED: 17.20 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 3/1/14 256.00 (CY) 14.884 14.83 1.859 STFCC MOIST 0-<1/2" SUR 0.5 0.30 54,600. p 9,510.00 p 12.10 p 18294 FESCUE Mar-14 256.00 (CY) 14.884 3/1/14 128.00 (CY) 7.442 14.19 0.889 STTCC MOIST 0-<1/2" SUR 0.5 0.30 49,300. p 4,580.00 p 14.80 p 15721 FESCUE Mar-14 128.00 (CY) 7.442 6/23/14 160.00 (CY) 9.3021 14.17 1.110 STFCC DRY 0-<1/2" SUR 0.5 0.30 59,600.p 15,100.00 p 2.00 p 20102 FESCUE Jun-14 160.00 (CY) 9.302 iota[ uuotc ras/Ac: 31.63 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.039 0.051 0.459 2.816 0.381 0.007 0.120 0.326 0.039 6.138 181.99 142 Cumulative lbs/acre 0.144 0.240 1 2.079 1 14.219 2.374 0.053 0.507 1 1.180 0.158 25.500 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE STTCC = STATESVILLE, NC THIRD CREEK CAKE �, x �L 13 l f (SIGNATURE OF L APP R) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 k Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: STATESVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: LORANE PAGE PERMIT #: WQ0016247 ANNUAL DRY TONS APPLIED: 103.63 SITE #: NC IR 00023 FIELD# : IR 00023 0002 OPERATOR: EDDIE PORTER CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 32.40 ACRES PERMITTED: 32.40 Page Lime Applied *** Date Lbs/Ac DATE or allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) oho Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (ppm) Crop MONTH Total Per Acre Solids 6/17/14 448.00 (CY) 13.827 15.38 1.791 STTCC DRY 0- 1/2" SUR 0.5 0.30 53,400. p 5,330.00 p 7.15 p 17093 FESCUE 6/18/14 352.00 (CY) 10.864 15.38 1.407 STTCC DRY 0- 1/2" SUR 0.5 0.30 53,400. p 5,330.00 p 7.15 p 17093 FESCUE Jun-14 1 800.00 (Cl) 24.691 As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annuallbs/acre 109 0.019 0.070 0.544 2.360 0.525 0.003 0.102 0.345 0.032 7.868 115.78 Cumulative lbs/acre 0.130 0.295 2.373 14.420 2.811 0.046 0.540 1.298 0.156 29.304 T Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop t y m 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 >' 1339.0 267.9 15.0 ; 375.0 89.0 2500.0 „ ;.; ,, STTCC = STATESVILLE, NC THIRD CREEK CAKE X d2 r 3 i (SIGNATURE /enalty ND PLIER) DATE "I certify, unde of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg * * Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: LORANE PAGE SITE #: NC IR 00023 FIELD# : IR 00023 0003 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 42.01 OPERATOR: EDDIE PORTER CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 23.00 ACRES PERMITTED: 23.00 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) "�u Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 6/23/14 160.00 (CY) 6.957 14.17 0.830 STFCC DRY 0-<1/2" SUR 0.5 0.30 59,600.p 15,100.00 p 2.00 p 20902 FESCUE 6/24/14 192.00 (CY) 8.348 14.17 0.996 STFCC DRY 0-<1/2" SUR 0.5 0.30 59,600.p 15,100.00 p 2.00 p 20902 FESCUE Jun-14 1 352.00 (CY) 15.305 1otaiuuoic ras/tic: 15.3U As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 0.018 0.018 0.205 1.125 0.117 0.002 0.044 0.168 0.018 2.572 85.11 76 Cumulative lbs/acre 0.066 0.063 0.844 5.759 0.485 0.032 0.205 0.528 0.087 10.893 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE X r 4IQ— r (SIGNAT L APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 K Application Method: SUR - Surface, INJ Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 ANNUAL LAND APPLICATION FIELD SUMMARY FORM FACILITY NAME: STATESVILLE, NC PREDOMINANT SOIL SERIES: CECIL OWNER: LORANE PAGE PERMIT #: W00016247 ANNUAL DRY TONS APPLIED: 34.37 SITE #: NC IR 00023 FIELD# : IR 00023 0004 OPERATOR: EDDIE PORTER CATION EXCHANGE CAPACITY (NON-503): RESIDUAL SOURCE(S):* See list at bottom of report ACRES UTILIZED: 13.70 ACRES PERMITTED: 13.70 Page Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) Tons Cond. Precip. cation tili- ali- Ammonia Nitrate Nitrate DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Acre Solids 6/20/14 288.00 (CY) 21.022 14.17 2.509 STFCC DRY 0- 1/2" SUR 0.5 0.30 59,600.p 15,100.00 p 2.00 p 20902 FESCUE Jun-14. 288.00 (CY) 21.022 1 1 1 1 ULUI %-UU11i 1 Ubft k,. L1.VL As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual lbs/acre 105 0.025 0.025 0.281 1.545 0.161 0.003 0.060 0.231 0.025 3.532 116.91 Cumulative lbs/acre 0.093 1 0.109 1 1.183 1 8.295 1 0.889 0.037 0.314 1 0.775 0.125 16.670 ' ° Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 V, FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE X 2, ,s (SIGNATU F L ' APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mgAg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 FACILITY NAME: STATESVILLE, NC OWNER: LORANE PAGE SITE #: NC IR 00023 FIELD# : IR 00023 0005 RESIDUAL SOURCE(S):* See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CECIL PERMIT #: WQ0016247 ANNUAL DRY TONS APPLIED: 47.13 OPERATOR: EDDIE PORTER CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 16.10 ACRES PERMITTED: 16.10 Page Lime Applied *** Date LUs Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) oho Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop MONTH Total Per Are Solids 6/19/14 256.00 (CY)R7.9501 14.17 1.898 STFCC DRY 0-<1/2" SUR 0.5 0.30 59,600.p 15,100.00 p 2.00 p F77 FESCUE Jun-14 256.00 (CY) 6/19/14 128.00 (CY)15.38 1.030 STTCC DRY 0-<1/2" SUR 0.5 0.30 53,400.p 5330.00 p 7.15 p 17093 FESCUE Jun-14 128.00 (CY) 1 V LM I UUII 1 ul/t . LJ.aJ As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN TOTALS: Annual Ibs/acre 115 0.025 0.042 0.388 1.929 0.290 0.003 0.079 0.286 0.029 5.205 125.71 Cumulativelbs/acre 0.108 0.154 1.583 10.020 1.419 0.046 0.392 0.960 0.130 20.403{" Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop k 216 FD Cumulative Pollutant Loading Rate Limit (Ibs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 STFCC = STATESVILLE, NC FOURTH CREEK CAKE STTCC = STATESVILLE, NC THIRD CREEK CAKE X oz i 3 1 l (SIGNATURE LAND PLII DATE "I certify, under penal of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR= Not Reported or Not Required %= percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 " Application Method: SUR - Surface, INJ -Injection, SURIN -Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2015 Summit Environmental Technologies, Inc. i 3310 Win St. F,�1PIR4iJIA1 N'I'riL 5E1iJ6LbGES IFd Cuyahoga Falls, Ohio 44223 dirPgr rer�f'ti4#�*pF TEL: (330) 253-8211 FAX. (330) 253-4489 Website: htto://www.settek.com January 21, 2014 Edward Stephens Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Statesville Dear Edward Stephens: Order No.: 14010514 Summit Environmental Technologies, Inc. received 2 sample(s) on 1/10/2014 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Dr. Mo Osman Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 A2LA 0724.01, Alabama 41600, Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0105, Delaware, Florida NELAC E87688, Georgia E87688 and 943, Idaho 01100923, Illinois 200061 and Reg.5, Indiana C-OH-13, Kansas E-10347, Kentucky (underground Storage Tank) 3, Kentucky 90146, Louisiana 04061 and LA12004, Maine 2012015, Maryland 339, Massachusetts M-OPH923, Minnesota 409711, Montana CERT0099, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, Ohio 4170, Ohio VAP CL0052, Oklahoma 9940, Oregon OH200001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Tennessee TN04018, Texas T104704466-11-5, Region 8 8TMS- L, USDA/APHIS P330-11-00244, Utah OH009232011-1, Vermont VT-87688, Virginia 00440 and 1581, Washington C891, West Virginia 248 and 9957C and E87688, Wisconsin 399013010 Page 1 of 8 Environmental Technologies, Inc. Workorder -ITSunnnit 3310 Win St. Sample Summary ENVIRGt TA T£CHAd-9 OCilZ,;IPNC, Cuyahoga Falls, Ohio44223 tiraFwtrexi'CgRi'4t�3ald TEL: (330) 253-8211 FAX. • (330) 253-4489 WO#: 14010514 Website: htto://wivw.settek.com 21-Jan-14 CLIENT: Synagro Project: Statesville Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 14010514-001 Statesville 3rd CK 1/9/2014 9:15:00 AM 1/10/2014 9:52:00 AM Sludge 14010514-002 Statesville 4th CK 1/9/2014 9:20:00 AM 1/10/2014 9:52:00 AM Sludge Page 2 of 8 Q Summit Environmental Technologies, Inc. WO#: 14010514 3310 Win St. It c ,VI OiNPe1E)aT1�L1Wei Cuyahoga Falls, Ohio 44223 Date Reported: 1/21/2014 J 1l'irericf hati'araorFc�s TEL: (330) 253-8211 FAX. (330) 253-4489 Company: Synagro Website: htip:/hvxnv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Statesville TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 VVK Statesville 3rd CK 001 1/9/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 VVK TCLP Mercury Analysis (1311/7470) Client ID# - Lab ID# Collected Analyte Rep Lmt Result Units - Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 1/15/2014 ALJ SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 gamma-BHC 0.0020 ND mg/L Sludge EPA 8081 B 1 0.40 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Statesville 3rd CK 001 1/9/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 1/15/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 1/15/2014 MES Statesville 3rd CK 001 1/9/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 1/15/2014 MES Page 3 of 8 Summit Environmental Technologies, Inc. - g 3310 Win St. WO#: 14010514 �. Cuyahoga Falls, Ohio 44223 Date Reported. 1/21/2014 -_ i teal t(,. 1'P; t,ara cai TEL: (330) 253-8211 FAX. (330) 253-4489 Company: Synagro Website: htto://wwiv.settek.com Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Statesville SVOC 8270 TCLP BNA List Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge. EPA 8270 C 1 0.13 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Cresols, Total 5.0 ND mg/L Sludge. EPA 8270 C 1 200 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 1/15/2014 AKE butadiene Statesville 3rd CK 001 1/9/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 100 1/15/2014 AKE Statesville 3rd CK 001 1/9/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 1/15/2014 AKE SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 3rd CK 001 1/9/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 1/15/2014 AMZ Statesville 3rd CK 001 1/9/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 1/15/2014 AMZ TCLP Metals Analysis (6010) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 TCLP Arsenic(As) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Barium(Ba) 5.0 ND mg/L Sludge EPA 6010 C 1 100 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Cadmium(Cd) 0.10 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Chromium(Cr) 0.20 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Lead(Pb) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Selenium(Se) 0.50 ND mg/L Sludge EPA 6010 C 1 1.0 1/15/2014 WK Statesville 4th CK 002 1/9/2014 TCLP Silver(Ag) 0.50 ND mg/L Sludge EPA 6010 C 1 5.0 1/15/2014 WK TCLP Mercury Analysis (1311/7470) Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 TCLP Mercury 0.0020 ND mg/L Sludge EPA 7470 A 1 0.20 1/15/2014 ALJ Page 4 of 8 Summit Environmental Technologies, Inc. ' 3310 Win St. ia31�IR4IPe9EN`it�LrEOPE�']K3t01�S�3P�G. Cuyahoga Falls, Ohio44223 4r (irl3+tree# t .lactxaYeet x TEL: (330) 253-8211 FAX.- (330) 253-4489 4 Website: htto://www.settekcom WO#: 14010514 Date Reported: 1/21/2014 Company: Synagro Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Statesville SVOC SW-846: 8081-TCLP Pesticides Client ID# Lab ID# Collected Analyte Rep Lint Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 Chlordane, total 0.010 ND mg/L Sludge EPA 8081 B 1 0.030 1/15/2014 JBN Statesville 4th CK 002 1/9/2014 Toxaphene 0.10 ND mg/L Sludge EPA 8081 B 1 0.50 1/15/2014 JBN Statesville 4th CK 002 1/9/2014 Endrin 0.0020 ND mg/L Sludge EPA 8081 B 1 0.020 1/15/2014 JBN Statesville 4th CK 002 1/9/2014 gamma-BHC 0.0020 ND mg/L Sludge .EPA 8081 B 1 0.40 1/15/2014 JBN Statesville 4th- CK 002 1/9/2014 Heptachlor 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Statesville 4th CK 002 1/9/2014 Heptachlor epoxide 0.0020 ND mg/L Sludge EPA 8081 B 1 0.0080 1/15/2014 JBN Statesville 4th CK 002 1/9/2014 Methoxychlor 0.0020 ND mg/L Sludge EPA 8081 B 1 10 1/15/2014 JBN VOC by GC/MS (8260)-TCLP Client ID# Lab ID# Collected Analyte Rep Lint Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 1,1-Dichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES ctatesville 4th CK 002 1/9/2014 1,2-Dichloroethane 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES tatesville 4th CK 002 1/9/2014 Benzene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES ctatesville 4th CK 002 1/9/2014 Carbon tetrachloride 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 4th CK 002 1/9/2014 Chlorobenzene 0.10 ND mg/L Sludge EPA 8260 B 1 100 1/15/2014 MES Statesville 4th CK 002 1/9/2014 Chloroform 0.10 ND mg/L Sludge EPA 8260 B 1 6.0 1/15/2014 MES Statesville 4th CK 002 1/9/2014 Tetrachloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.70 1/15/2014 MES Statesville 4th CK 002 1/9/2014 Trichloroethene 0.10 ND mg/L Sludge EPA 8260 B 1 0.50 1/15/2014 MES Statesville 4th CK 002 1/9/2014 Vinyl chloride 0.20 ND mg/L Sludge EPA 8260 B 1 0.20 1/15/2014 MES Statesville 4th CK 002 1/9/2014 MEK 2.0 ND mg/L Sludge EPA 8260 B 1 200 1/15/2014 MES SVOC 8270 TCLP BNA List Client ID#, Lab ID# Collected Analyte Rep Lint Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 1,4-Dichlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 7.5 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 2,4,5-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 400 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 2,4,6-Trichlorophenol 0.25 ND mg/L Sludge EPA 8270 C 1 2.0 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 2,4-Dinitrotoluene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Cresols, Total 5.0 ND mg/L Sludge EPA 8270 C 1 200 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Hexachloro-1,3- 0.10 ND mg/L Sludge EPA 8270 C 1 0.50 1/15/2014 AKE butadiene Statesville 4th CK 002 1/9/2014 Hexachlorobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 0.13 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Hexachloroethane 0.10 ND mg/L Sludge EPA 8270 C 1 3.0 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Nitrobenzene 0.10 ND mg/L Sludge EPA 8270 C 1 2.0 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Pentachlorophenol 0.25 ND mg/L Sludge EPA 8270 C.. 1 100 1/15/2014 AKE Statesville 4th CK 002 1/9/2014 Pyridine 0.25 ND mg/L Sludge EPA 8270 C 1 5.0 1/15/2014 AKE Page 5 of 8 Summit Environmental Technologies, Inc. I ffl� i 3310 Win St. rriv RdtdPe1ENfdtL 9-£ t+dc 14098s, Ipt8 Cuyahoga Falls, Ohio 44223 Arg-aTEL: (330) 253-8211 FAX.- (330) 253-4489 Website: htto://Wivw.settek.coin WO#: 14010514 Date Reported: 1/21/2014 Company: Synagro Address: 284 Boger Rd. Mocksville NC 27028 Received: 1/10/2014 Project#: Statesville SVOC SW-846: 8321 Herbicides-TCLP Client ID# Lab ID# Collected Analyte Rep Lmt Result Units Matrix Method DF RegLvl Run Analyst Statesville 4th CK 002 1/9/2014 2,4-D 5.0 ND mg/L Sludge EPA 8321 A 1 10 1/15/2014 AMZ Statesville 4th CK 002 1/9/2014 2,4,5-TP 0.50 ND mg/L Sludge EPA 8321 A 1 1.0 1/15/2014 AMZ Page 6 of 8 Summit Environmental Technologies, Inc. ' �. - WO#: 14010514 l �� tom" Avg 3310 Win St. � - �i•StrlRgtJF.IEi+J'PhL•;fieCt4Cdt�G,ik�JJ:��Jtt€; Cuyahoga Falls, Ohio 44223 Date Reported: 1/21/2014 _naPyYclL.aliar�lvTe TEL: (330) 253-8211 FAX.- (330) 253-4489 Company: Synagro Wehsite: http:/hvww.settek.com Address: 284 Boger Rd. Mocksville.NC 27028 Received: 1/10/2014 Project#: Statesville Client ID# Lab ID# Collected Analyte Result" Units Matrix Method DF RL Run Analyst Statesville 3rd CK 001 1/9/2014 Flashpoint (140T) >140 T Sludge EPA 1010 1 1/13/2014 TAH Statesville 3rd CK 001 1/9/2014 Cyanide, Reactive ND ppm Sludge EPA 9014 1 0.50 1/13/2014 TIR Statesville 3rd CK 001 1/9/2014 pH 6.0 s.u. Sludge EPA 9045 D 1 1/13/2014 AYS Statesville 3rd CK 001 1/9/2014 Sulfide, Reactive ND ppm Sludge EPA 9034 1 25 1/13/2014 TIR Client ID# Lab ID# Collected Analyte Result Units Matrix Method DF RL Run Analyst Statesville 4th CK 002 1/9/2014 Flashpoint (140T) >140 T Sludge EPA 1010 1 1/13/2014 TAH Statesville 4th CK 002 1/9/2014 Cyanide, Reactive ND ppm Sludge EPA 9014 1 0.50 1/13/2014 TIR tatesville 4th CK 002 1/9/2014 pH 5.9 s.u. Sludge EPA 9045 D 1 1/13/2014 AYS Statesville 4th CK 002 1/9/2014 Sulfide, Reactive ND ppm Sludge EPA 9034 1 25 1/13/2014 TIR Page 7 of 8 Summit Environmental Technologies, Inc. Analysis Request/Chain of Custody 3310 Win Street For Summit Emironmentai Technologies. Inc. use only Cuyahoga Falls, Ohio 44223 Tel: 330,253.8211 Fax: 330.253.4489 c�of 1 Sl T No. -_ --- _- ,,._--- ,n,...-- Dr;A1t I Project Name Analytical Parameters and Method', sA.lv- slN 1-7dzl lien[ Pltone No. 3 3� _ 5 7 1 y 08 Client Fax No. } Pl��Sc El client Email M'iet� !��i� Frnai Resut��✓ Ca�ntact Pc •sane, C �� , l�c.,.� ampled by f Zprle � Identirestion CD 00 O W 41V�VPl__ t . ddre :s C p 11 e —/ // a 4 0 samples ✓ El 2 Date Time I -;i E Collected Collected v j a and Yellow pages sfioutd sucpmp'w,ample, to dw laboratory, Pkau fh+a... ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Statesville WWTP Name: Fourth Creek WWTP WQ Permit Number: WQ 00016247 NPDES Number: NCO031836 Monitoring Period: From Jan 1, 2014 To Dec 31, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/1) (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density XX Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion If onnlicahle to alternative nerformed (Class A or Class R) comnlete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 6 1h MPN Coliform power per gram 96 6363 70,485 MPN/g 0 quarterly grab SM92210E of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Mt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) XX Option/Mt. 5 Option/Alt_ 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction XX reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." —Andd SrAh, Residuals SuDerintendent PrWrerme title type or print) Land Applier Name and Title (if applicable) (type or print) Signatur t f Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results Synagro 284 Boger Rd. Mocksville NC 27028 Entered 1/14/2014 Reported: 1/22/2014 For: 4th Creek -Statesville Date Sample ID Parameter Cust ID Result Units Method Analyzed Analyst 140114-14.1 % Solids 1 30.1 % SM2640B-1997 1/16/14 CL t40114-14.1 Fecal Coliform MTF 1 9302 MPN/g SM92210E-2006 1/16/14 CL 140114-14.1 Geometric Mean 1 6363 MPN/g dry wt. basis 1/17/14 CL 140114-14.2 % Solids 2 21.9 % SM2540B-1997 1/15/14 CL 140114-14.2 Fecal Coliform MTF 2 22,831 MPNIg SM9221 CE-2006 1/15/14 CL 140114-14.3 % Solids 3 25.7 % SM2640B-1997 1/15/14 CL 140114-14.3 Fecal Coliform MTF 3 1167 MPN/g SM92210E-2006 1116/14 CL 140114-14.4 % Solids 4 32.6 % SM2540B-1997 1116/14 CL 140114-14.4 Fecal Coliform MTF 4 27,607 MPN/g SM92210E-2006 1115/14 CL 140114-14.6 % Solids 5 41.5 % SM2640B-1997 1115114 CL 140114-14.5 Fecal Coliform MTF 5 96 MPN/g SM92210E-2006 1/15/14 CL 140114-14.6 % Solids 6 22.7 % SM254OB-1997 1116/14 CL 140114-14.6 Fecal Coliform MTF 6 70,485 MPN/g SM92210E 2006 1115/14 CL 140114-14.7 % Solids 7 32.9 % SM2540B-1997 1/15/14 CL 140114-14.7 Fecal Coliform MTF 7 9119 MPN/g SM92210E 2006 1116/14 CL P.O. Box 228 • Statesvllle,'North Carolina 28687.704/812/4697 Synagro 284 Boger Rd. Mocksville NC 27028 Entered 1/14/2014 Reported: 112212014 For: Date Sample ID Parameter - Cust ID Result Units Method Analyzed Analyst Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA NCO0909 P.O. Box 228 • StatesvMe, North Carolina 28687.704/872/4697 Client: ;- - V A STATESVILLE ANALYTICAL 122 Court Street • P.O. Boa 228 Address: Statesville,NC 28687 (704) 872-4697 ChahiOf Contact Person: t^; '--i,, ov-�'l.�S Jam` Phone#3�Q ,` O,�,J7 FAX#� - _ r am PO # '7, ,� Requisitioned by: r'$ ' r �` ' , 4 (Time Date) ; ` l,: i : rn'! r v,. (' ( ai r( '! b¢ 4.�—, fyy I Custody Record Customer Lab-1D # Time Sampled Sample 1D# _ (Grab Only) Date Sampled a (Grab Only) a Matrix sludao /w ywy Parameters requested for analysis 17 i 3 I T � I y _ t 1 ( i Relinquished by: ;,' ,f �f ', �� � ,� Time I mo/1? �'5 am Date �P ,:� �/ Sampled by: Received b ` �V' Y= �%� �1v- Time .yarn Date Transported by: ,�.. Relinquished by: Time am, pm Date 7/- Holding times met: 1/ Received by: Time am, pm Date Compliance work: Composite Sampling #1: Time begin am, pm Date �_/ Non-compliance work: Time end am, pm Date �/ Lab Comments: Composite Sampling #2: Time begin am, pm' Date Time end am, pm Date ___/� Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Fourth Creek WW Biosolids Permit Number: Date: 1 /6/2014 Digester Temperature: 13.8 Sampling Date/Time: 1/6/14 9:24AM Sampled By: LC Analysis Date/Time: 1/6/14 9:31 AM Analyzed By: BJ Sample Volume: 300 Total Solids: 1.3 Beginning Temperature: 13.8 End Temperature: 14.2 Dissolved Oxygen Level 5.59 5.57 55 8 5.61 5.63 5.68 5.65 5.59 55 85.55 5. Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: milliliters % Dry Solids degrees Celsius dearees Celsius 0.0 5.6 0.4 0.24 mg Oxygen/hr 0.06 mg Oxygen/g/hr 14 degrees Celsius 1.500730352 Temperature Corrected Specific Oxygen Uptake Rate:] 0.09 rW`{mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time Dissolved Oxygen Level (minutes) (m /1) 0 7.63 1 7.6 2 7.63 3 7.67 4 7.64 5 7.63 6 7.58 7 7.54 8 7.51 9 7.48 10 7.51 11 7.49 12 7.48 13 7.46 14 7.44 15 7.43 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Fourth Creek WWTP 1 /7/2014 12.9 1/7/14 2:30 PM LC 1/7/14 2:38 PM 300 1.34 13.4 13.6 0.0 7.7 0.9 milliliters % Dry Solids degrees Celsius degrees Celsius 0.94 mg Oxygen/hr 0.23 mg Oxygen/g/hr 14 degrees Celsius 1.500730352 ........... Temperature Corrected Specific Oxygen Uptake Rate: 0.35 `jmg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Dissolved Oxygen Level (mg/1) 8.4 8.43 8.39 8.36 8.34 8.29 8.26 8.25 8.23 8.18 8.15 8.09 8.04 7.99 7.92 7.88 11.5 1/8/14 1:00 PM LC 1 /8/14 1:12 PM BJ milliliters % Dry Solids degrees Celsius degrees Celsius Slope: 0.0 Intercept: 8.5 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 2.15 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 0.48 mg Oxygen/g/hr Average Temperature: 12 degrees Celsius Temperature Correction Factor: 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate:„ 0.82 lmg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level (mg/1) 8.45 8.4 8.39 9.34 8.32 8.26 8.2 8.23 8.21 8.2 8.17 8.14 8.13 8.1 8.07 8.05 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Fourth Creek WWTP11 1 /9/2014 10.2 1/9/14 1:14 PM 1/9/14 1:25 PM BJ 300 1.3 10.7 milliliters % Dry Solids degrees Celsius degrees Celsius 2.30 mg Oxygen/hr 0.59 mg Oxygen/g/hr 12 degrees Celsius 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate:`, 1.01 Img Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time Dissolved Oxygen Level (minutes) (mg/1) 0 6.98 1 6.94 2 6.93 3 6.93 4 6.92 5 6.91 6 6.95 7 6.9 8 6.83 9 6.82 10 6.8 11 6.77 12 6.76 13 6.75 14 6.74 15 6.71 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Fourth Creek WWTP11 11.9 1/10/14 12:54 PM RG 1/10/14 1:06 PM BJ 1.4 12.2 0.0 7.0 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius 1.08 mg Oxygen/hr 0.26 mg Oxygen/g/hr 13 degrees Celsius 1.605781476 Temperature Corrected Specific Oxygen Uptake Rate: i 0.41 1mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time. Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Fourth Creek WWT 1 /13/2014 15.1 1/13/14 123PM RG 1/13/14 128PM SS 300 1.6 15.4 16.1 Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Dissolved Oxygen Level (m /1) 6.31 6.07 5.88 5.72 5.56 5.45 5.4 5.38 5.3 5.25 5.22 5.17 5.15 5.12 5.1 5.07 milliliters % Dry Solids degrees Celsius deqrees Celsius Slope: 0.1 Intercept: 6.0 Correlation Coefficient: 0.9 Oxygen Uptake Rate: 4.33 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 0.90 mg Oxygen/g/hr Average Temperature: 16 degrees Celsius Temperature Correction Factor: 1.31079601 Temperature Corrected Specific Oxygen Uptake Rate:] 1.18 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time Dissolved Oxygen Level (minutes) (m /1) 0 6.45 1 6.31 2 6.3 3 6.21 4 6.21 5 6.12 6 6.05 7 6.12 8 6.11 9 6.12 10 6.13 11 6.13 12 6.16 13 6.18 14 6.14 15 6.15 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Fourth Creek WWTP11 1/14/2014 15.3 1/14/14 12:51 PM RG 1/14/14 1:02 PM BJ 300 1.5 15.8 16.9 0.0 6.3 0.6 milliliters % Dry Solids degrees Celsius degrees Celsius 0.78 mg Oxygen/hr 0.17 mg Oxygen/g/hr 16 degrees Celsius 1.31079601 Temperature Corrected Specific Oxygen Uptake Rate T, 0.23 Jmg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Statesville WQ Permit Number: WQ 00016247 WWTP Name: Third Creek WWTP NPDES Number: NCO020591 Monitoring Period: From Jan 1, 2014 To Mar 31, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density XX Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion it UPP11CUDIC to auernauve periormeu t- ass A or %.lass li com fete the ionowing monitoring aata: Parameter Allowable Level in'Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dances Analysis Fecal 2x10 to the 6` MPN Coliform power per gram 30,488 59,351 100,000 MPN/g 0 quarterly grab SM92210E of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt. 3 Option/Alt.4 (V S reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) XX Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction XX reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification inclding fine and imprisonment." AnOy Smith, Residuals Su erintendent Vare��= amprint) Land Applier Name and Title (if applicable) (type or print) -IDS Signatur of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Date Analytical Results Synagro 284 Boger Rd. Mocksville Entered 1/14/2014 Reported: 1/22/2014 For: 3rd Creek -Statesville NC 27028 Sample ID Parameter ' Cust ID Result Units Method Date Analyzed Analyst 140114-13.1 % Solids 1 15.4 % SM2540B-1997 1/15/14 CL %140114-13.1 Fecal Coliform MTF 1 32,468 MPNIg SM92210E 2006 1/16/14 CL 140114-13.1 Geometric Mean 1 59,351 MPN/g dry wt. basis 1/17/14 CL 140114-13.2 % Solids 2 15.7 % SM2540B-1997 1116/14 CL 140114-13.2 Fecal Coliform MTF 2 57,325 MPN/g SM92210E 2006 1115/14 CL 140114-13.3 % Solids 3 16.0 % SM254OB-1997 1115114 CL 140114-13.3 Fecal Coliform MTF 3 100,000 MPN/g SM92210E-2006 1116114 CL 140114-13.4 % Solids 4 21.0 % SM2540B-1997 1/15114 CL 140114-13.4 Fecal Coliform MTF 4 76,190 MPNIg SM92210E-2006 1/15/14 CL 140114-13.5 % Solids 5 16.4 % SM2540B-1997 1/15/14 CL 140114-13.5 Fecal Coliform MTF 5 30,488 MPN/g SM92210E-2006 1115114 CL 140114-13.6 % Solids 6 15.0 % SM2540B-1997 1115114 CL 140114-13.6 Fecal Coliform MTF 6 60,000 MPN/g SM92210E-2006 1/15/14 CL 140114-13.7 % Solids 7 16.0 % SM2640B-1997 1/15/14 CL 140114-13.7 Fecal Coliform MTF 7 100,000 MPN/g SM92210E-2006 1115/14 CL i P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697 Synagro 284 Boger Rd_ "/locksville Entered 1/14/2014 Reported: 1/22/2014 For: NC 27028 Date - Sample 1D Parameter Cust ID Result Units Method Analyzed Analyst Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, ,EPA NCO0909 P.O. Box 228 9 Statesville, North Carolina 28687 • 704/872/4697 STATESVILLE ANALYTICAL 122CourtStrect - P.O.Box 228 Address: L Statesville.NC 28687 (704) 972-4697 W� n, C r\S Contact Person: Phone #:K.,2/ FAXII Cl —glin Chain of PO #jz)•Requisitioned by: crime 1 4 Date) Custody Record - Customer Time Sampled Sample lD# Lab-10 # (Grab Only) Date Sampled (Grab Only) X sludge 1,,VV WW Parameters requested for analysis --,--,j ZI f CCk f3lo i�Yvl^ LIP /v v Relinquished by: M16 L-41 Tim& �pr®rDate LiE, JI'l ampled by: I S Received by: Time Date Z Yam",m Da /7 1 Transported by: Relinquished by: Time am, pm Date Holding times met: Received by: Time am, pm Date Compliance work: Composite Sampling #1: Time begin— am, pm Date Non-compliance work: Time end am, pm Date Lab Comments: Composite Sampling #2: Time begin— am, pm- Date Time end am, pm Date Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Third Creek WV\ W00016247 1 /2/2014 12.7 1/2/14 8:43 SA 1/2/14 8:51 SA 300 1.9 12.3 12.8 Time Dissolved Oxygen Level (minutes) (m /1) 0 8.23 1 8.17 2 8.15 3 8.11 4 8.08 5 8.02 6 8 7 7.98 8 7.91 9 7.85 10 7.81 11 7.76 12 7.76 13 7.75 14 7.73 15 7.69 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: milliliters % Dry Solids degrees Celsius degrees Celsius 0.0 8.2 1.0 2.22 mg Oxygen/hr 0.39 mg Oxygen/g/hr 13 degrees Celsius 1.605781476 Temperature Corrected Specific Oxygen Uptake Rate:,] 0.63 1mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Dissolved Oxygen Level (mg/1) 9.53 9.48 9.4 9.34 9.28 9.23 9.15 9.11 9.04 8.97 8.9 8.85 8.79 8.74 8.68 8.65 Slope: Intercept: Correlation Coefficient: Third Creek WWTP WQ0016247 1 /3/2014 10.8 1/3/14 13:23 SA 1/3/14 13:32 SA 1.9 11.9 0.1 9.5 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius Oxygen Uptake Rate: 3.62 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 0.64 mg Oxygen/g/hr Average Temperature: 12 degrees Celsius Temperature Correction Factor: 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate: I 1.09 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Third Creek WWTP milliliters % Dry Solids degrees Celsius degrees Celsius WO0016247 1 /6/2014 11.3 1/6/14 10:19 SA 1/6/14 10:24 SA 300 1.8 11.4 11.8 Time Dissolved Oxygen Level (minutes) (m /1) 0 9.6 1 9.53 2 9.48 3 9.42 4 9.39 5 9.34 6 9.28 7 9.26 8 9.24 9 9.18 10 9.14 11 9.07 12 9.01 13 8.96 14 8.92 15 8.87 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.0 9.6 1.0 2.81 mg Oxygen/hr 0.52 mg Oxygen/g/hr 12 degrees Celsius 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate: 0.891mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids; Beginning Temperature End Temperature Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Dissolved Oxygen Level (mg/1) 7.51 7.49 7.45 7.42 7.38 7.34 7.32 7.24 7.17 7.14 7.08 7.03 6.97 6.92 6.86 6.81 Third Creek WWTP WQ0016247 1 /14/2014 12.8 1/14/14 12:27 SA 1/14/14 12:32 SA 300 1.7 12.6 13.2 milliliters % Dry Solids degrees Celsius degrees Celsius Slope: 0.0 Intercept: 7.6 Correlation Coefficient: 1.0 Oxygen Uptake Rate: 2.91 mg Oxygen/hr Ambient Specific Oxygen Uptake Rate: 0.57 mg Oxygen/g/hr Average Temperature: 13 degrees Celsius Temperature Correction Factor: 1.605781476 Temperature Corrected Specific Oxygen Uptake Rate: 0.91 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time Dissolved Oxygen Level (minutes) (mg/1) 0 7.08 1 7.03 2 7.02 3 6.97 4 6.94 5 6.88 6 6.8 7 6.76 8 6.71 9 6.68 10 6.63 11 6.58 12 6.55 13 6.53 14 6.5 15 6.48 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP W00016247 1/15/2014 11.4 1/15/14 10:32 SA 1/15/14 10:38 SA 300 1.7 11.7 12.3 0.0 7.1 1.0 milliliters % Dry Solids 9egrees Celsius Degrees Celsius 2.58 mg Oxygen/hr 0.51 mg Oxygen/g/hr 12 degrees Celsius 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate:; 0.87 lmg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids: Beginning Temperature End Temperature Time Dissolved Oxygen Level (minutes) (mg/1) 0 7.52 1 7.47 2 7.43 3 7.36 4 7.32 5 7.25 6 7.21 7 7.14 8 7.12 9 7.08 10 7.06 11 7.02 12 6.97 13 6.93 14 6.86 15 6.82 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0016247 1/16/2014 11.5 1/16/14 10:08 SA 1/16/14 10:14 SA 300 1.7 11.7 12.4 0.0 7.5 1.0 milliliters % Dry Solids Degrees Celsius Degrees Celsius 2.73 mg Oxygen/hr 0.53 mg Oxygen/g/hr 12 degrees Celsius 1.71818618 Temperature Corrected Specific Oxygen Uptake Rate:1, 0.92 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Time Dissolved Oxygen Level (minutes) (mg/l) 0 7.17 1 7.13 2 7.06 3 7.03 4 6.99 5 6.94 6 6.88 7 6.84 8 6.81 9 6.79 10 6.74 11 6.7 12 6.67 13 6.61 14 6.58 15 6.56 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0016247 1/17/2014 11.5 1/17/14 12:26 SA 1/17/14 12:31 SA 300 1.8 13 13.9 0.0 7.2 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius 2.45 mg Oxygen/hr 0.45 mg Oxygen/g/hr 13 degrees Celsius 1.605781476 Temperature Corrected Specific Oxygen Uptake Rate: j 0.73 1mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Statesville WQ Permit Number: WQ 00016247 WWTP Name: Third Creek WWTP NPDES Number: NCO020591 Monitoring Period: From Apr 1, 2014 To Jun 30, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density XX Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion lr appucaDie To alternative periormea q- ass A or (.;lass is complete Lne ionowing monlrorm tiara: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10to the 6h MPN Coliform power per gram 3106 16,593 53,892 MPN/g 0 quarterly grab SM92210E of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt.2 Option/Alt.3 Option/Alt.4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) XX Option/Alt. 5 Option/Alt. 6 Option/Mt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction XX reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Andy SAnith,Residuals Su erintendent P ar Nam nd T e"(ty e_ or print) l Land Applier Name and Title (if applicable) (type or print) Signature of Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results Synagro 284 Boger Rd. Mocksville NC 27028 Entered 5/1/2014 Reported: 5/5/2014 For: 3rd Creek City of Statesville Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 140501-7.1 % Solids 1 15.5 % SM2540B-1997 5/1/14 CL j501-7.1 Fecal Coliform MTF 1 19,355 MPN/g. SM92210E-2006 5/1/14 CL -+J501-7.1 Geometric Mean 1 16,593 MPN/g dry wt. basis 5/5/14 CL 140501-7.2 % Solids 2 14.7 % SM254OB-1997 5/1114 CL 140501-7.2 Fecal Coliform MTF 2 34,014 MPN/g SM92210E-2006 5/1/14 CL 140501-7.3 % Solids 3 16.7 % SM2540B-1997 5/1/14 CL 140501-7.3 Fecal Coliform MTF 3 53,892 MPN/g SM92210E-2006 5/1/14 CL 140501-7.4 % Solids 4 14.3 % SM2540B-1997 5/1/14 CL 140501-7.4 Fecal Coliform MTF 4 16,783 MPN/g SM92210E-2006 5/1/14 CL 140501-7.5 % Solids 5 16.1 % SM2540B-1997 5/1114 CL 140501-7.5 Fecal Coliform MTF 5 3106 MPN/g SM92210E-2006 5/1/14 CL 140501-7.6 % Solids 6 17.8 % SM2540B-1997 5/1/14 CL 140501-7.6 Fecal Coliform MTF 6 9551 MPN/g SM92210E-2006 5/1/14 CL 140501-7.7 % Solids 7 15.3 % SM2540B-1997 5/1/14 CL 140501-7.7 Fecal Coliform IVITF 7 19,608 MPN/g SM92210E-2006 5/1/14 CL P.O. Box 228 • Statesville, North Carolina 28687. 704/872/4697 Synagro 284 Boger Rd. Mocksville NC 27028 ered 5/1/2014 Reported: 5/5/2014 For: Date Sample ID Parameter Cust ID Result Un is Method Analyzed Analyst Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, PDA NCO0909 P.O. Box 228 o Statesville, North Carolina 28687 o 704/872/4697 Client: I < '7" Address: I Soqer STATESVI. ,mNALYTWAL 122 Court Street - P.O.Box 228 10, (Roa M(n<SV%\ke_ s�}"'0'22 4 Statesville, NC 29687 (704) 872-4697 Contact Person:,— Phone 4 FAX# M-10 � Chain of PO# �O Requisitioned by: A 'Wil (Timg304;j Date) Custody Record 5M, 4". - , 5-1-11 Customer Time Sampled Lab -ID # Sample JD# (Grab Only) Date Sampled (Grab Only) CL M Matrix - E Parameters /6 ISludge I W I WW requested for analysis 06 gvvg 6- j_Iq I I tJ 0 5 I:P� /7 Relinquished by: Time (,Qam', pm Date _/2 Sampled by: _& ` '('Ob I'd SaA Received by:1.t'tTime 'Z 5ta`m) pm Date Transported by: Akjk Relinquished by: Time am, pm Date Holding times met: Received by: Time ")_F'am, pm Date Compliance work: Composite Sampling #1: Time begin— am, pm Date Non-compliance work: Time end am, pm Date Lab Comments: Composite Sampling #2: Time begin— am, pm Date (A, Time end am, pm Date Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Nam( Biosolids Permit Numbe Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By. Sample Volume: Total Solids: Beginning Temperature: End Temperature. Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 4 300 milliliters 1.8 % Dry Solids 12.4 degrees Celsius 13.3 degrees Celsius 0.1 9.8 1.0 3.12 mg Oxygen/hr 0.58 mg Oxygen/g/hr 13 degrees Celsius 1.605781476 Temperature Corrected Specific Oxygen Uptake Rate: 0.93 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Nam( Biosolids Permit Numbe Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: WQ0016 247 04/02/14 13.6 /18:26 A 8:35 0.1 9.5 1.0 milliliters % Dry Solids degrees Celsius deqrees Celsius 3.21 mg Oxygen/hr 0.59 mg Oxygen/g/hr 14 degrees Celsius 1.500730352 Temperature Corrected Specific Oxygen Uptake Rate:1 0.89 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 9.21 9.15 9.07 901 8.95 8.9 8.83 8.77 8.71 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP F. W00016247 04/03/14 4.5 5.4 0.1 9.6 1.0 Aliliters o Dry Solids egrees Celsius egrees Celsius 3.49 mg Oxygen/hr 0.61 mg Oxygen/g/hr 15 degrees Celsius 1.402551731 Temperature Corrected Specific Oxygen Uptake Rate:1 0.86 =mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature. - Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level 8.83 8.81 8.77 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0017247 04/04/14 16.2 4/4/14 9:19 illiliters Dry Solids )grees Celsius wees Celsius 0.1 8.9 1.0 3.38 mg Oxygen/hr 0.63 mg Oxygen/g/hr 16 degrees Celsius 1.31079601 Temperature Corrected Specific Oxygen Uptake Rate:1 0.82 =mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Third Creek WWTP milliliters % Dry Solids degrees Celsius degrees Celsius WO0017247 04/07/14 16.6 4/7/14 12:29 SA 4/7/14 0:36 SA 300 1.8 16.6 17.4 Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.0 8.2 1.0 1.94 mg Oxygen/hr 0.36 mg Oxygen/g/hr 17 degrees Celsius 1.225043 Temperature Corrected Specific Oxygen Uptake Rate:1 0.44 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 14 13:49 milliliters % Dry Solids degrees Celsius degrees Celsius SA 14 13:56 SA 300 1.9 16.3 16.8 0.0 8.7 1.0 2.98 mg Oxygen/hr 0.52 mg Oxygen/g/hr 17 degrees Celsius 1.225043 Temperature Corrected Specific Oxygen Uptake Rate:1 0.64 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 1.8 0.0 9.9 1.0 Ililiters Dry Solids grees Celsius grees Celsius 2.74 mg Oxygen/hr 0.51 mg Oxygen/g/hr 15 degrees Celsius 1.402551731 Temperature Corrected Specific Oxygen Uptake Rate:1 0.71 =mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Statesville WQ Permit Number: WQ 00016247 WWTP Name: Third Creek WWTP NPDES Number: NCO020591 Monitoring Period: From Jul 1, 2014 To Sep 30, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density XX Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion 11 aPPIlCaDle to auernative periormea %-ass A or %;lass 1i com fete the ionowing monitorin data: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2xl0 to the 6` MPN Coliform power per gram 369 52,945 305,343 MPN/g 0 quarterly grab SM92210E of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) XX Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction XX reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Anhy With, Residuals S erintendent Pr are e itle (ty or print) Land Applier Name and Title (if applicable) (type or print) Signatur t f Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Date ! Synag ro 284 Boger Rd. Mocksville NC 27028 Entered 7/2812014 Reported: 7/30/2014 For: 3rd Creek Sample ID Parameter Cust ID Result Units Method Date Analyzed Analyst 140728-6.1 % Solids 1 61.7 % SM2540B-1997 7/28/14 CL len728-6.1 Fecal Coliform MTF 1 35,656 MPN/g SM92210E-2006 7/28/14 CL ,r28-6.1 Geometric Mean 1 52,945 MPN/g dry wt. basis 7/30/14 CL 140728-6.2 % Solids 2 61.3 % SM2540B-1997 7/28/14 CL 140728-6.2 Fecal Coliform MTF 2 261,011 MPN/g SM92210E-2006 7/28/14 CL 140728-6.3 % Solids 3 32.7 % SM2540B-1997 7/28/14 CL 140728-6.3 Fecal Coliform MTF 3 91,743 MPN/g SM9221CL 2006 7/28/14 CL 140728-6.4 % Solids 4 50.7 % SM2540B-1997 7/28/14 CL 140728-6.4 Fecal Coliform MTF 4 47,337 MPN/g SM92210E-2006 7/28/14 CL 140728-6.5 % Solids 5 54.2 % SM2540B-1997 7/28/14 CL 140728-6.5 Fecal Coliform MTF 5 369 MPN/g SM92210E-2006 7/28/14 CL 140728-6.6 % Solids 6 62.5 % SM2540B-1997 7/28/14 CL 140728-6.6 Fecal Coliform MTF 6 256,000 MPN/g SM92210E-2006 7/28/14 CL 140728-6.7 % Solids 7 52.4 % SM2540B-1997 7/28/14 CL 140728-6.7 Fecal Coliform MTF 7 305,343 MPN/g SM92210E-2006 7/28/14 CL P.O. Box 228 o Statesville, North Carolina 28687 © 704/872/4697 Synagro 284 Boger Rd. Mocksville NC 27028 '��red 7/28/2014 ...,forted: 7/30/2014 For: Date Sample ID Parameter Cust ID Result Units Method Analyzed Analyst Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA NCO0909 P.O. Box 228 o Statesville, North Carolina 28687 0 704/872/4697 Client: <.ry --- , ` • C', ( STATESVIL,LE ANALYTICAL � 122 Court Street a P.O. Box 228 j \ Address: �"+�1`i j� A v4 S Statesville, NC 28687 (704) 872-4697 Contact Person: -I Phone # 7 _ ( FAX#„ Chain of Custody RecordCustomer PO #0 ,ii2! Requisitioned by: k, (Time,, Date) Sample ID# Lab -ID # Time Sampled Only) Date Sampled (Grab Only) E 8 Matrix Parameters requested for analysis Sludge w ww }(Grab G- / T i 1 C Lo - t �( l4i . - OvC J t t 4 ( j tt !i r r Relinquished by: -i��.__ / t/� Time am, pm Date f //l1 Sampled by{ Aohm j'i 1 Received by: / Time f G . Oam,� pm)Date I /z // Ll Transported by: Relinquished by: Time am, pm Date /_/ Holding times met: Received by: Time am, pm Date _/ / Compliance work: Composite Sampling #1: Time begin am, pm Date /_/ Non-compliance work: Time end am, pm Date _/ / Lab Comments: Composite Sampling #2: Time begin am, pm Date Time end am, pm Date _/_/ Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level L;1 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate. - Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0016247 07/08/14 Aliliters 16 Dry Solids egrees Celsius egrees Celsius 0.0 3.4 1.0 2.37 mg Oxygen/hr 0.42 mg Oxygen/g/hr 23 degrees Celsius 0.863837599 Temperature Corrected Specific Oxygen Uptake Rate:1 0.36 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP F. W00016247 07/09/14 300 milliliters 1.7 % Dry Solids 21 degrees Celsius 10.6 degrees Celsius 0.0 3.6 1.0 2.35 mg Oxygen/hr 0.46 mg Oxygen/g/hr 21 degrees Celsius 0.952380952 Temperature Corrected Specific Oxygen Uptake Rate: 0.44 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 1 7/10/14 8:43 1 300 milliliters 1.7 % Dry Solids 21.4 degrees Celsius 21.1 degrees Celsius 0.0 4.6 1.0 2.84 mg Oxygen/hr 0.56 mg Oxygen/g/hr 21 degrees Celsius 0.952380952 Temperature Corrected Specific Oxygen Uptake Rate:1 0.53 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Specific Oxygen Uptake Rate SOUR Facility Name:1 Third Creek WV Biosolids Permit Number-.1 WO0016247 Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Ternperature-1 End Temperature: 07/11 /14 21.7 7/11/14 8:25 SA 7/11/14 8.30 SA 300 1.7 20.5 20.3 Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Dissolved Oxygen Level m 74 .7 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: milliliters % Dry Solids degrees Celsius degrees Celsius 0.0 6.8 1.0 2.69 mg Oxygen/hr 0.53 mg Oxygen/g/hr 20 degrees Celsius 1 Temperature Corrected Specific Oxygen Uptake Rate: 0.53 =mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope.- Intercept - Correlation Coefficient: Oxygen Uptake Rate. - Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WO0016247 07/14/14 22.5 7/14/14 9:56 SA 7/14/14 10:04 SA 300 1.7 21.6 21.1 0.1 8.0 0.6 milliliters % Dry Solids degrees Celsius degrees Celsius 8.37 mg Oxygen/hr 1.64 mg Oxygen/g/hr 21 degrees Celsius 0.952380952 Temperature Corrected Specific Oxygen Uptake Rate-.1 1.56 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name Biosolids Permit Number Date Digester Temperature Sampling Date/Time Sampled By Analysis Date/Time Analyzed By Sample Volume Total Solids: Beginning Temperature End Temperature Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0016247 07/15/14 21.7 7/15/14 10:17 SA 7/15/14 10:23 SA 300 1.7 20.9 20.4 0.1 7.2 1.0 milliliters % Dry Solids degrees Celsius degrees Celsius 3.00 mg Oxygen/hr 0.59 mg Oxygen/g/hr 21 degrees Celsius 0.952380952 Temperature Corrected Specific Oxygen Uptake Rate: 0.56 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level m Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: ree 1.7 28 19.8 milliliters % Dry Solids degrees Celsius degrees Celsius 0.0 6.5 1.0 2.20 mg Oxygen/hr 0.43 mg Oxygen/g/hr 20 degrees Celsius 1 Temperature Corrected Specific Oxygen Uptake Rate: 0.43 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Statesville WQ Permit Number: WQ 00016247 WWTP Name: Third Creek WWTP NPDES Number: NCO020591 Monitoring Period: From Oct 1, 2014 To Dec 31, 2014 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: ' Alt. (1) Fecal Density XX Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion II appimaDie ro arrernarlve periormea L. ass A or l,lass is com Jere me ionowing monitorin oaia: Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units dences Analysis Fecal 2x10 to the 6` MPN MPN/g Coliform power per gram of total solids CFU 1260 4230 8780 CFU/g 0 quarterly grab 9222D-MF 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: 0 tion/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) XX Option/Alt.5 ® Option/Alt.6 Option/Alt.7 Option/Alt.8 (14-Day Aerobic) (Alk Stabilization) (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction XX reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." And S ' h Residuals Su erintendent Pr arer ame�5Mr print) Land Applier Name and Title (if applicable) (type or print) Signature f Preparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Cameron Testing Services, Inc. Laboratory Report NC DENR#654 NC PHHS #37799 US EPA #NC01918 Synagro S Proj. 150132 +c ' Statesville' Yes Sample Information t W E. Thompson 'bate x1 01/29/15 R$ C. Cameron 01/29/15 Analyses -and Results 150132 01 a ;fudge Gr Fec. Coliform-S <8780 CFUrg 8780 01/30/15 SB 9222D - MF b <1260 CFwg 1260 C <1290 CFU+g 1290 d <7750 CFU/g 7750 e <7700 CFU,g 7700 f <7150 CFulg 7150 9 <3970 CFulg 3970 Geomean <4230 150132 01 a Sludge Gr TS (%) 11.2 % 0.01 01/30/15 SB 2540 G JS b 78.6 % 0.01 C 77.0 % 0.01 d 12.2 % 0.01 e e 12.6 % 0.01 f 13.0 % 0.01 9 21.4 % 0.01 Data Review 0 2- bechnician Date S Report Review nbi,,04Lab Dat4 3 219 S. Stcele Str. 919-208-4240 Sanford NC 27330 chris' cainerontesting.com •219, S; 8teele5tr.., Cameron T.6'sting Siervices�,'Inc,. Chaim of Custody ��anford; NC 21330 Phone: i)l 9=208-4240 NGVVWIGW Cot !` #654'NC.PHf8�W "Cert #�gj US SPA NCOI'9"1 8 Paga of :sYpooro, ,f �-pa 4d, s ,on Y, 6mp 'TO on ac :Proj �'Ad dij re, . .... ss. 284: 806er Rd,. _Taxf NC 27028' c L VI R yi� Rai ,� (YIN); Name;' 1�4 ;SiglM L Signature: N Lir of- '0 > sample I'D E a: -.!E Requ6sted Analysis jw­.. C) FZ E 0" 0 rn 3" L/ Sludge' FecalMSolids R6!lh'qui6h_e'& :J Received:: DatalTitne" 4-JO Rusfi.vvbrkvill require, prior -app , roval, Addifional charbes VAII apply Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level m 7.45 7.4 37 87.33 Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: iliters Dry Solids rees Celsius rees Celsius 0.0 7.9 1.0 2.52 mg Oxygen/hr 0.47 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate:1 0.50 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By. - Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate. - Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: Third Creek WWTP WQ0016247 9 Ililiters Dry Solids grees Celsius grees Celsius 0.1 7.2 1.0 3.00 mg Oxygen/hr 0.56 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate: 0.59 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name. Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Third Creek WWTP milliliters % Dry Solids degrees Celsius degrees Celsius WO0016247 09/04/14 21 9/4/14 8:26 SA 9/4/14 8:35 SA 300 1.9 21 20.7 Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: 0.1 5.4 1.0 3.48 mg Oxygen/hr 0.61 mg Oxygen/g/hr 21 degrees Celsius 0.952380952 Temperature Corrected Specific Oxygen Uptake Rate'.1 0.58 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Third Creek WV1 WO0016247 09/05/14 20.2 9/5/14 9:19 SA 9/5/14 9:26 SA 300 1.9 19.6 19.1 Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: milliliters % Dry Solids degrees Celsius degrees Celsius 0.1 8.0 1.0 5.17 mg Oxygen/hr 0.91 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate:1 0.97 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level m Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate. - Average Temperature: Temperature Correction Factor: 09/09/14 19.7 9/9/14 8:26 SA 9/9/14 8:32 SA 300 1.9 milliliters % Dry Solids Degrees Celsius Degrees Celsius 0.0 7.8 1.0 1.66 mg Oxygen/hr 0.29 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate: 0.31 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number. - Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: WQ0016247 09/10/14 19 9/10/14 9:24 SA 9/10/14 9:29 SA 300 0.0 8.1 0.9 milliliters % Dry Solids degrees Celsius degrees Celsius 1.97 mg Oxygen/hr 0.35 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate: 0.37 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Time (minutes) 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 Specific Oxygen Uptake Rate SOUR Facility Name: Biosolids Permit Number: Date: Digester Temperature: Sampling Date/Time: Sampled By: Analysis Date/Time: Analyzed By: Sample Volume: Total Solids: Beginning Temperature: End Temperature: Dissolved Oxygen Level Slope: Intercept: Correlation Coefficient: Oxygen Uptake Rate: Ambient Specific Oxygen Uptake Rate: Average Temperature: Temperature Correction Factor: iliters Dry Solids rees Celsius rees Celsius 0.0 7.9 1.0 1.44 mg Oxygen/hr 0.25 mg Oxygen/g/hr 19 degrees Celsius 1.07 Temperature Corrected Specific Oxygen Uptake Rate: 0.27 mg Oxygen/g/hr Instructions: Enter Data in the Blue Boxes. The Calculation and the Spreadsheet execute automatically. Agricultural Lime Application Log 2014 Project: City of Statesville Field Soil Lime Requirement �T/acffrom Tons/Acre Date Applied (state -county -site -field) pH soil analysis Applied (invoice date) AL-14-1A 6.0 N/A N/A N/A AL-14-1 B 5.6 0.8 IR-204A 7.1 N/A N/A NIA IR-20-07 6.7 N/A N/A N/A IR-20-08 6.2 N/A N/A N/A IR-20-09 7.1 N/A N/A N/A IR-23-01 6.2 N/A N/A N/A IR-23-02 6.3 N/A N/A N/A IR-2 3-03 6.2 N/A N/A N/A IR-23-04 6.7 N/A N/A N/A IR-23-05 6.1 N/A N/A N/A * = Lime to be applied when weather and/or crop removal allows Page 1 of 1 Report Number: 15-013-0601 I� Account Number:46493 www.aleastern:com Send To: SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE NC 27028 Date Received: r 01/13/2015 Date Of Analysis: 01/14/2015 _A&L Eastem_L_abora_ tories 7621, Whitepine Road Richmond, Virginia 23237 (e04) 743-9401 Fax (804) 271- "S Grower: T PAYNE STATESVILLE ANNUAL SOIL ANALYSIS REPORT Date Of Report: 01/14/2015 Submitted By: ERIC THOMPSON Farm ID: AL 14 Analytical Method(s): Mehlich 3 Organic Matter Phosphorus Potassium Magriesium Calcium . Sodium _ . pH Acidity C.E.0 i le ID Lab' .% Rate _ ENR Mehlich 3 Reserve 'K 'Mg - ., -Ca Na Soil Buffer H Field Nu tuber Ibs/A ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index' =megl1006: meq/100g` 1A 237 VH 147 H 182 H 1211 M 13 VL 05098 5.9 H 150 6.0 6.78 1.5 9.5 NC=197 NC=75 Percent Base Saturation Nitrate.- - Sulfur. _ Zinc, _' Manganese Iron . Copper Boron, � - Soluble Salts: Chloride °"i4luiminum Sample ID Field ID, - ' M9 Ca Na H - - ` N NO3. -K S Zn Mn r - Fe Cu B _ 'SS CI"'Al 'ppm - - % % % % ppm Rate ppm Rate ppm ,Rate ppm Rate, ppm'` Rate ppm Rate ppm Rate ' ms/cm Rate Rate ppm . 1A 19 M 24.3 VH 26 H 188 VH 7.7 VH 0.6 M 0.12 VL 4.0 16.0 63.7 0.6 15.3 NC = 40 NC = 607.5 NC = 163 NC = 385.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. by; ppp/ic me G� H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. Pauric McGroary NCDA&CS"_^y.&nomic Division Phone: (919) 733-2655 Report No. FY'.— affil4603 Website: wWw.ii. oyl.gov/agronomi/ tictien Client: Tim.L. Payne Advisor: Synagro Central °�� •, Predictive c/o Superior Jersey Farm Attn:Eric Thompson t 5 a' 1265 Payne Dairy Rd. 284 Boger Rd sx` Soil Report Mehlich-3 Extraction Taylorsville, NC 28681 Mocksville, NC 27028 , t WSO Sampled County: Alexander Sampled: 10/01/2014 Received: 11/07/2014 completed: 11/26/2014 Farm: AZ-14 Links to Helpful Information Sample ID: 1 B Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Small Grain (SG) 0.8 80-100 0 0 0 0 0 0 0 0 Note: 3 2-Soybean 0.0 0 0 0 0 0 0 0 0 0 Note: 3 Test Results [units - WN in g/crn3; CEC and Na in meq/100 cd; NO3-N in mg/dd]: Soil Class: Mineral -HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 1.07 9.7 81 1.9 5.6 186 88 61 16 45 210 136 136 473 473 230 0.1 1 .,North Carolina. aot�araT�uaa r•wEd.�anristrssr���o, I 9 Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. Steve Troxler, Commissioner of Agriculture NCDA&CSa':��::Anomic Division Phone: '(919) 733-2655 Website: www.iot�_,_(g.gov/agronomi/ Report No. FY'a' _t014603 'Tim L. Payne Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at Ca% % CEC occupied by calcium one time, even if the report recommends more. You can apply the rest in similar increments every six months until the CEC cation exchange capacity full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-I and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn=A11 Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn-n- I manganese index mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot pH current soil pH find the exact fertilizer grade recommended on the report, visit www.ncapr.aov/acgronomi/obpart4.htm#fs to find P-1 phosphorus index information that may help you choose a comparable alternate. For more information, readA Homeowner's Guide to Fertilizer. P206 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not Zn-I zinc index routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit wwwncagrpoy/apronomi/uyrst.htm for more information. NCDA&CS _ _.-"comic Division Phone: (919) 733-2655 Website: www.r-.-,-_,'govlagronomi/ Report No. FY1:, _ � )32424 u4ti, uruur:. Client: Dennis Phillips Advisor: Synagro Central 201 Bar ryOak Rd Statesville, NC 28625 Attn:Eric Thompson 284 Boger Rd aA. ' �_ Soil Report Mehlich-3 Extraction � Mocksville, NC 27028 CrR- B:Vi Sampled County: Iredell lil5tti Sampled: Received: 04/07/2014 completed: 04/16/2014 Farm: IR-20 Links to Helpful Information Sample ID: 4A Recommendations: Lime Nutrients (Ib/acre ) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, 1 0.0 120-200 0 60 0 0 pH$ 0 0 0 Note: 12 Note: 2 - Fescue/OGrass/Tim, 0.0 120-200 0 60 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - WN in g/crn3; CEC and Na 'in meq/100 cd; NO3-N in mg/dd]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 0.96 16.3 98 0.3 7.1 206 39 80 17 43 127 76 76 486 486 346 0.1 1 Sample ID: 4B Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, 1 0.0 120-200 0 50 0 0 pH$ 0 0 0 Note: 12 Note: 2 -Fescue/OGrass/Tim, 0.0 120-200 0 50 0 ' 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - WN in g/crr?; CEC and Na in meq/100 cd; NO3-N in mg/dd]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.13 0.94 31.4 100 0.1 7.4 192 42 83 16 80 154 88 88 449 449 272 0.2 1 Sample ID: 7 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - WN in g/crrt3; CEC and Na in meq/100 crrr3; NO3-N in mg/drrr3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 '0.98 15.9 95 0.8 ' 6.7 484 197 75 14 61 586 358 358 759 759 423 0.1 1 North Carolina •TobaccoTais: PuadComa s;ioll Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS'. �:�',nomic Division Phone: (919) 733-2655 Website: °www. t;4e.gov/agronomi/ Report No. FY' 4-�L032424 Dennis Phillips Page 2 of 3 Sample ID: 8 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N 'P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 0 0 0 0 Note:12 Test Results [units - WN in 9/crap; CEC and Na in meq/100 cd; NO3-N in mg/dd]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 0.90 16.6 92 1.3 6.2 314 168 70 17 64 365 234 234 785 785 469 0.1 1 NCDA&CS',�,-y.'nomic Division Phone: (919) 733-2655 Website: www.i �L�.gov/agronomi/ Report No. FY'.i'_-_ 6032424 Dennis Phillips Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at one time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients• In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncagr.gov/agronomi/pubs.htm. Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find the exact fertilizer grade recommended on the report, visit wwwncaarpov/aaronomi/obpart4.htm#fs to find information that may help you choose a comparable alternate. For more information, readA Homeowners Guide to Fer Test Results The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-1, Zn-AI, Cu-1, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncaaroov/agronomiluyrst.htm for more information. Report Abbreviations Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K-1 potassium index K20 potash Mg% % CEC occupied by magnesium MIN_ mineral soil class Mn manganese Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-1 manganese index M-O mineral -organic soil class N nitrogen Na sodium NO3-N nitrate nitrogen ORG organic soil class pH current soil pH P-1 phosphorus index P206 phosphate S-1 sulfur index SS-1 soluble salt index W/V weight per volume Zn-AI zinc availability index Zn-I zinc index Page 1 of 1 _ Report Number: 15-013-0597 Account Number: 46493 vwuwaleastern;om Send To:. SYNAGRO CENTRAL LLC/STATESVILLE Mary Brewer 284 BOGER RD MOCKSVILLE NC 27028 Date Received: 01/13/2015 Date Of Analysis: 01/14/2015 A&L Eastern Laboratories 7.621 Whitepine.Read Richmond, Virginia 23237 (804),743-9401 Fax (804) 271,6446 Grower: D PHILLIPS STATESVILLE ANNUAL SOIL ANALYSIS REPORT Date Of Report: 01/14/2015 Submitted By: ERIC THOMPSON Farm ID: 1 R-20 Analytical Method(s): Mehlich 3 Organic Matter Phosptiorus Potassium -.Magnesium ,,, Calcium Sodium pH Acidity -C.E.0 Sample ID Field ID - ,Lab Number % Rate ENR M-ehlich 3 Reserve K Mg- ` _ - Ca- Na _Soil - Buffer; H . Ibs/A- ppm Rate ,ppm, Rate ppm Rate• ppm Rate ppm` - _Rate ,'ppm Rate- pH = Index megl100g meq/100g 9 05089 13.0 VH 150 342 VH 207 H 281 M 3256 H 14 VL 71 0.0 19.2 9 NC=285 NC=106 Percent Base Saturation Nitrate_ Sulfur Zinc Manganese Iron, ` - Copper Boron ° Soluble Sa_ I'ts Chloride,: 'Aluminum'. .Sample ID - Field`'ID, K Mg Ca Na H �- NO3N s I S _ Zn Mn Fe Cu B SS' "Cl Al % % % % ppm Rate ppm' Rate ppm Rate, ppm Rate: ppm Rate• ppm Rate "ppm - Rate ms/cm Rate ppm ,.:Rate ,' , ;ppm 9 29 H 22.2 VH 62 VH 196 VH 8.5 VH 1.0 M 0.25 VL 2.8 12.2 84.8 0.3 0.0 9 NC=60 NC=555.0 NC=388 NC=425.0 Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble Analysis prepared by: A&L Eastern Laboratories, Inc. C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. by: rAwia me 60,wr Pauric McGroary NCDAiCe-;�"y.,61,nomic Division Phone: (919) 733-2655 Website: y,?.gov/agronomi/ Report No. - FY,,r,­.;Z032426 Client: Eddie Porter Advisor: Synagro Central -Eric Thompson Gantt Horn Rd. Attm Predictive 351 Gan Statesville, NC 28625 284 Boger Rd Mocksville, NC 27028 Mehlich-3 Extraction Soil Report Sampled County: Iredell Sampled: Received: 04/07/2014 Completed: 04/16/2014 Farm: IR-23 Links to Helpful Information .Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P20r) K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, 1 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 2 - Fescue/OGrass/Tim, 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 Test Results [units - WIV in g/cd; CEC and Na in meq/100 cd; NO3-N in mg/drift. Soil Class: Mineral HM% WIV CEC BS% Ac pH P-1 K-1 Ca% Mg% . S-1 Mn-1 Mn-All Mn-Al2 Zn-I Zn-Al * Cu-I Na ESP SS-1 NO3-N 0.41 0.97 12.3 91 1.2 6.2 287 38 76 13 49 154 107 107 435 435 315 0.1 1 _-North `Carolina : dot+atcm rain .. ullj:cmlwlssloll' Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture Division Phone:.(919) 733-2666 Website:'www Report No. Eddie Porter Page 2 of 2 1 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 lb/1000 sq ft) at Ca% % CEC occupied by calcium one time, even if the report recommends more. You can apply the rest in similar increments every six months until the CEC cation exchange capacity full rate.is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes "for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow -the fertilizer recommendations given. If Mg is needed and no'lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-AI1 Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn-I M-O manganese index mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients• In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot pH current soil pH find the exact fertilizer grade recommended on the report, visit www.ncaar.aov/apronomi/obpart4.htm#fs to find P-1 phosphorus index information that may help you choose a comparable alternate. For more information, readA Homeowner's Guide to Fertilizer P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI Zn-I zinc availability index zinc index remaining 16 [P-1, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.gov/agronomi/uvrst.htm for more information. NCDA&CS'hyri�nomic Division Phone: (919) 733-2665 Website: www.l :;ay�:gov/igronomi/ Report No. FY'�-: �006893 Client: Shane Porter Advisor: Synagro Central Predictive ` i' 351 Gantt Horn Rd. Statesville, NC 28677 Attn:Eric Thompson 284 Boger Rd i • :_ } hJ� Mehlich-3 Extraction a r/ Soil Report Mocksville, NC 27028 Sam pled County: Iredell Sampled: Received: 09/25/2014 Completed: 10/06/2014 Farm: IR-23 Links to Helpful Information Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - WN in g/crrr3; CEC and Na in meq/100 crrr3; NO3-N in mg/dd]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 0.93 20.2 94 1.1 6.3 369 151 78 12 80 315 202 202 629 629 362 0.1 1 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 0 0 0 0 'Note: 12 Test Results [units - WN in g/cd; CEC and Na in meq/100 cd; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI. Cu-1 Na ESP SS. -I NO3-N 0.18 1.05 14.7 94 0.9 6.2 361 110 77 13 79 232 153 153 431 431 237 0.1 1 Sample ID: 4 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O6 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: 2-Fescue/OGrass/Tim, 0.0 120-200 0 0 0 0 pH$ 0 0 0 Note: 12 Note: Test Results [units - WN in g/crrP; CEC and Na in meq/100 cd; NO3-N in mg/dm3]: Soil Class: Mineral ' r- HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-1 Zn-AI Cu-I Na ESP SS-1 NO3-N 0.13 1.04 18.5 97 0.6 6.7 365 124 83 10 68 183 116 116 504 504 320 0.1 1 , North'Carol-Ina: >Pltipecce.3ru�9') unrLCnanm6sslc�a_ Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS '-,--nomic Division Phone: (919) 733-2655 Website: WWW.L-.'--,;'.,.gov/agronomi/ Report No. FY',2_-_ ,006893 Shane Porter Page 2 of 3 Sample ID: 5 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, 1 0.0 120-200 0 30 0 0 0 0 0 0 Note: 12 2-Fescue/OGrass/Tim, 0.0 120-200 0 30 0 0 0 0 0 0 Note: 12 Test Results [units - WN in g/cnn ; CEC and Na in meq/100 cO; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-1 Mn-All Mn-AI2 Zn-1 Zn-AI Cu-1 Na ESP SS-1 NO3-N 0.32 1.02 13.1 90 1.3 6.1 266 58 74 14 60 440 279 279 469 469 266 0.1 1 omic Division Phone: (919) Website: www. Report No. Shane Porter Understanding the Soil Report: explanation of measurements,abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months'before planting. For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at one time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and M/cronutrients• In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit neagr.gov/agronomi/pubs.htm. Recommendations forsmall areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find the exact fertilizer grade recommended on the report, visit www.ncaar.aov/apronomi/obpart4.htm#fs to find information that may help you choose.a comparable alternate. For more information, readA Homeowner's Guide to Fer Test Results Report Abbreviations Ac B BS% Ca% CEC Cu-I ESP HM% K-1 K20 Mg% MIN Mn Mn-All Mn-AI2 Mn-I M-O N Na NO3-N ORG pH P-1 P205 S-1 SS-1 WIV The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI remaining 16 [P-I, K-1, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-Al, Cu-1, S-1, SS -I, Na, ESP, SS -I, NO3-N (not Zn-I routinely available)] indicate levels of plant nutrients or other fertility measurement. Visit www:ncagr.goy/agronomi/uyrst.htm for more information. Page 3 of 3 exchangeable acidity boron % CEC occupied by basic cations % CEC occupied by calcium cation exchange capacity copper index exchangeable sodium percent percent humic matter potassium index potash % CEC occupied by magnesium mineral soil class manganese Mn-availability index for crop 1 Mn-availability index for crop 2 manganese index mineral -organic soil class nitrogen sodium nitrate nitrogen organic soil class current soil pH phosphorus index phosphate sulfur index soluble salt index weight per volume zinc availability index zinc index