WQ0035324_Permit Modification_20170509

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Water Resources
Environmental Quality
May 9, 2017
Justin Ballard
ATC Associates
2725 E Millbrook Road, Suite 121
Raleigh, NC 27604
RE: Modification Request for Groundwater Remediation Permit WQ0035324
Former Pro Cleaners
8377 Creedmoor Road
Raleigh, Wake County, NC
Dear Mr. Ballard:
ROY COOPER
Governor
MICHAEL S. REGAN
Secretary
S. JAY ZIMMERMAN
Director
The Water Quality Regional Operations Section (WQROS) has received your permit
modification request on April 10, 2017. Central and Raleigh Regional Office staff have reviewed
the request for sampling modification and has deemed it reasonable and, therefore, it is approved.
If you have any questions, please contact Shristi Shrestha at 919-807-6406 or
[e-mail].
Sincerely,
For Debra J. Watts, Supervisor
Animal Feeding Operations & Groundwater
Protection Branch
Division of Water Resources
cc: Raleigh Regional Office, WQROS
Permit File WQ0035324
--1 "Nothing Compares `--1
State of North Carolina I Environmental Quality I Division of Water Resources
Water Quality Regional Operations Section
1636 Mail Service Center I Raleigh, North Carolina 27699-1636
919-707-9129

Shrestha, Shristi R
From: Robertson, Laura R.
Sent: Wednesday, April 26, 2017 4:08 PM
To: Shrestha, Shristi R
Cc: Bolich, Rick; Rogers, Michael
Subject: RE: Permit questions (W10500937 & WQ0035324)
Hi Shristi and Mike,
Per the application for permit W10500937, the total coliform was still present in the effluent only (not in the influent),
and there was no fecal coliform detected in either sample on either sampling occasion. If you recommend continued
sampling, the homeowner should be responsible for the recommended sampling. Mr. Read has had the well casing
repaired and the well has been chlorinated, so hopefully one more sampling event will show coliform below
detection. If he needs a list of state -certified labs, we keep a list on hand for our NPDES permits.
For the permit mod request for Former Pro -Cleaners DSCA site WQ0035324, I think their suggested monitoring
modifications are adequate.
Thanks,
Laura
Laura R. Robertson, LG
Hydrogeologist
Water Quality Regional Operations Section
Division of Water Resources
Department of Environmental Quality
919 791 4247 office
919 788 7159 fax
laura.robertson(aD-ncdenr.gov
3800 Barrett Drive, Raleigh, NC 27609
1628 Mail Service Center, Raleigh, NC 27699-1628
K.- C'.
"`-^Nothing Compares
Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be
disclosed to third parties.
From: Shrestha, Shristi R
Sent: Wednesday, April 26, 2017 2:18 PM
To: Robertson, Laura R. <[e-mail]>
Cc: Bolich, Rick <[e-mail]>; Rogers, Michael <[e-mail]>
Subject: Permit questions (W10500937 & WQ0035324)
Laura ,
I am following up about Mike voicemail that he left for you about Geothermal permit W10500937. Since the fecal
conc. is above 2L limit we want another round of sampling. Does RRO want to do this sampling ? We wanted to

Also, I had received a permit modification application for permit WQ0035324 (which I forwarded to you on April 19th )
for reducing the monitoring well frequency. Mike and I are ok with this and we were waiting for RRO's input before
sending out the letter.
Thanks,
Shristi
Shristi R. Shrestha
Hydrogeologist
Water Quality Regional Operations Section
Animal Feeding Operations & Groundwater Protection Branch
North Carolina Department of Environmental Quality
919 807-6406 office
shristi.shrestha(aD-ncdenr.gov
512N. Salisbury Street
1636 Mail Service Center
Raleigh, NC 27699 1636
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.

Shrestha, Shristi R
From:
Shrestha, Shristi R
Sent:
Wednesday, April 19, 2017 2:22 PM
To:
Robertson, Laura R.; Bolich, Rick
Cc:
Rogers, Michael
Subject:
FW: WQ0035324 DSCA Site #92-0001
Attachments:
DC920001_20170406_PermitMod ifcationRequest. pdf
Good afternoon ,
We have received a permit modification request (attached) for Formers Pro Cleaners with permit number
WQ0035324. They have asked for a reduction in sampling frequency of the some of the monitoring wells and water
supply wells. Mike and I agree with the reduction in sampling frequency. Please let us know about your opinion and
we will respond to them.
Thank you,
Shristi
Shristi R. Shrestha
Hydrogeologist
Water Quality Regional Operations Section
Animal Feeding Operations & Groundwater Protection Branch
North Carolina Department of Environmental Quality
919 807-6406 office
[e-mail]
512N. Salisbury Street
1636 Mail Service Center
Raleigh, NC 27699 1636
Email correspondence to and from this address is subject to the
North Carolina Public Records Law and may be disclosed to third parties.
-----Original Message -----
From: Rogers, Michael
Sent: Wednesday, April 19, 2017 10:52 AM
To: Shrestha, Shristi R <[e-mail]>
Subject: FW: WQ0035324 DSCA Site #92-0001
Fyi
-----Original Message -----
From: Justin Ballard [mailto:[e-mail]]
Sent: Monday, April 17, 2017 9:06 AM
To: Rogers, Michael <[e-mail]>
Subject: FW: WQ0035324 DSCA Site #92-0001

Hi Michael,
I just wanted to follow up on the attached and email below to make sure received the hard copy in the mail. As
always, if you have any questions, please let me know. Thanks.
Justin Ballard PG I PROJECT MANAGER I ATC Group Services LLC
-----Original Message -----
From: Justin Ballard
Sent: Thursday, April 06, 2017 3:15 PM
To: 'Rogers, Michael' <[e-mail]>
Subject: RE: WQ0035324 DSCA Site #92-0001
Mr. Rogers,
Per our discussion in December 2016, attached is our request to modify the sampling requirements for the above
referenced permit. A hard copy is going out in today's mail but I wanted you to have a digital copy in case there was a
delay in mail. Please let me know if you have any questions. Note that our next scheduled sampling event is
scheduled for this (April) month but if the attached is approved, would ask that a new start date of May 2017 could be
used going forward. Thank you.
Justin Ballard PG I PROJECT MANAGER I ATC Group Services LLC
-----Original Message -----
From: Rogers, Michael [mailto:[e-mail]]
Sent: Thursday, December 15, 2016 2:47 PM
To: Justin Ballard <[e-mail]>
Subject: RE: WQ0035324 DSCA Site #92-0001
Per our discussion, assume the monitoring frequency as stated in the permit, which includes a January sampling date.
-----Original Message -----
From: Justin Ballard [mailto:[e-mail]]
Sent: Wednesday, December 14, 2016 3:44 PM
To: Rogers, Michael <[e-mail]>
Subject: FW: WQ0035324 DSCA Site #92-0001
Michael,
Attached are the two figures we just spoke about. Please let me know if you have any questions. Thanks.
Justin Ballard PG I PROJECT MANAGER I ATC Group Services LLC
-----Original Message -----
From: Justin Ballard
Sent: Wednesday, December 14, 2016 9:55 AM
To: 'Rogers, Michael' <[e-mail]>
Subject: RE: WQ003S324 DSCA Site #92-0001
Mr. Rogers,
Per our phone conversation last week, please see the attached request for postponing the next scheduled

Justin Ballard PG I PROJECT MANAGER I ATC Group Services LLC
-----Original Message -----
From: Rogers, Michael [mailto:[e-mail]]
Sent: Friday, July 22, 2016 4:10 PM
To: Justin Ballard <[e-mail]>; Genna Olson <[e-mail]>
Cc: Bolich, Rick <[e-mail]>
Subject: RE: WQ0035324 DSCA Site #92-0001
Please discard the previous attachment. Debra forgot to sign the permit.
-----Original Message -----
From: Rogers, Michael
Sent: Friday, July 22, 2016 3:25 PM
To: 'Justin Ballard' <[e-mail]>; Genna Olson ([e-mail])
<genna.olson @cardno.com>
Cc: Bolich, Rick <[e-mail]>
Subject: FW: WQ0035324 DSCA Site #92-0001
Please find attached the renewal permit for the above project.
Regards
-----Original Message -----
From: Michael Rogers [mailto:[e-mail]]
Sent: Friday, July 22, 2016 2:39 PM
To: Rogers, Michael <[e-mail]>
Subject:
This E-mail was sent from "RNPAC7DD0" (Aficio 2075).
Scan Date: 07.22.2016 14:39:20 (-0400)
Queries to: [e-mail]

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NA C
ENVIRONMENTAL • GEOTECHNICAI
BUILDING SCIENCES • MATERIALS TESTING
April 6, 2017
Mr. Michael Rogers
NCDEQ Division of Water Resources
Underground Injection Control Program
1636 Mail Service Center
Raleigh, North Carolina 27699-1636
2725 East Millbrook Road
Suite 121
Raleigh, NC 27604
Tel: [phone]
Fax: [phone]
www.ateassociates.com
N.C. Engineering License No. C-1598
;�ECENEDIP,CDE irWR
APR 0 2017
Water Quality RegionV
RE: Modification Request for Groundwater Remediation Permit WQ0035324
Former Pro Cleaners
8377 Creedmoor Road
Raleigh, Wake County, North Carolina
ATC Project No. DC9201SL34
DSCA Site No. DC920001
Dear Mr. Rogers:
ATC Associates of North Carolina, P.C. (ATC), under contract to the North Carolina Department of
Environmental Quality's (NCDEQ's) Drycleaning Solvent Cleanup Act (DSCA) Program, is submitting
this request to the Underground Injection Control Program for modifications to the monitoring requirements
referenced in Section IV of non -discharge Groundwater Remediation Permit WQ0035324. The permit was
approved on April 16, 2012, renewed on July 22, 2016, and covered installation of an In Situ Delivery
(ISDTM) system and injection of CarBstrateTM for remediation of chlorinated solvent compounds. Section
1.0 of this submittal includes project background information and ISDTM system specifications. Section
2.0 details historical data collected at the site and trends related to groundwater remediation efforts. Section
3.0 provides the requested sampling modifications.
1.0 Background Information and ISDTM System Specifications
The source property is located southwest of the intersection of Creedmoor Road and Strickland Road in
Raleigh, North Carolina. The property currently contains Towne North Shopping Center, which is a multi -
tenant shopping center. Pro Cleaners operated an active drycleaning operation in the tenant space at 8377
Creedmoor Road using tetrachloroethylene (PCE) from an unconfirmed date through 1998. Pro Cleaners
currently operates in a different tenant space in the Towne North Shopping Center; however, the current
location is a drop-off/pick-up drycleaning facility and no drycleaning operations have been performed in
the new space. The former Pro Cleaners space at 8377 Creedmoor Road is currently occupied by Lux Salon
(a hair salon). A release of drycleaning solvents was first identified at the site during a Phase II
Environmental Site Assessment (ESA) in 1995. Subsequent assessment activities indicated a plume of
groundwater impacted by PCE and PCE breakdown products extending downgradient to the north towards
a residential neighborhood across Strickland Road.
Historical remedial activities performed at the site included operation of an air sparge (AS)/soil vapor
extraction (SVE) system from 1996 through 2001, excavation of impacted soil in 2007, pilot -scale injection
of Anaerobic Biochem Plus Zero Valent IronTM (ABC+TM) in 2009, and beginning in 2013, groundwater
remediation commenced through injection of CarBstrateTM via an ISDTM system. The system consists of
seven injection wells (IW-IA, IW-2, IW-3, IW-4, IW-5A, IW-6, and IW-7A) and three extraction wells
(EW-8, EW-9A, and EW-10). Following extraction, the groundwater is pumped through two granular
activated carbon (GAC) AF-500 filters, into a holding tank, then into the ISDTM system where the

Modification Request for Groundwater Remediation Permit WQ0035324 April 6, 2017
Former Pro -Cleaners, DSCA Site #DC920001 Page 2
groundwater is amended with CarBstrateTM on a weekly basis before re -injection into the subsurface.
CarBstrateTM is a nutrient -amended carbohydrate substrate that has a high solubility and low -retardation
factor. It is a non -toxic, food -grade product that includes the macro -nutrients necessary for effective
microbial growth of nitrogen and phosphorous, as well as a specific suite of trace metals that have been
shown to be critical for active anaerobic microbial activity. The ISDTM system contains an injection pump,
booster pump, solution tank, mixer, metering pump, air -actuated ball valves, flow meters, compressor,
pressure gauges, and a touch screen programmable logic computer (PLC) component that provides a high
degree of flexibility in system operation.
ATC performs operation and maintenance (O&M) at the site on an approximate weekly basis. O&M
activities include recording flow measurements, amending the extracted groundwater with CarBstrateTM,
and monitoring injection pressures and pH of the extracted groundwater. In addition, ATC collects
quarterly groundwater samples from locations prior to the working GAC vessel, in-between the working
and polishing GAC vessels, and following the polishing GAC vessel to ensure proper treatment of the
extracted groundwater. Based on the GAC monitoring, replacement of the carbon has been needed only
twice with the most recent change out even occurring in February 2017.
2.0 Groundwater Data Evaluation
Since groundwater remediation efforts began in 2009, sampling has been conducted at the site on a
minimum semi-annual basis with quarterly sampling commencing in 2012 with the operation of the ISDTM
system. PCE concentrations have reduced substantially since startup of the ISDTM system. Specifically,
these reductions can be seen in monitoring wells MW-813, MW-225, MW-22D, and MW-23 and extraction
wells EW-8 and EW-9/9A. Volatile organic compound (VOC) groundwater analytical data are included in
Table 1. A groundwater gradient map and PCE isoconcentration contour map for the January 2017
sampling event is included as Figures 1 and 2, respectively.
The remaining groundwater impacts are primarily centered around the downgradient property boundary.
ATC used the GSI Mann -Kendall Tookit (Mann Kendall) to evaluate plume stability trends. A review of
groundwater analytical data since projects startup indicates increasing trends in some monitoring wells
(EW-8, MW-IOB, MW-11A, and MW-5). However, if shorter time periods are used for each well, wells
MW-IOB, MW-11A, and EW-8 report stable or decreasing trends. This trend reversal is logical, since
increasing downgradient plume migration would be expected near the start of the project, followed by a
reducing contaminant trend after remediation is initiated. The Mann -Kendall graphs for wells MW-IOB,
MW-I IA, and EW-8 are included in Appendix A.
Samples have also been collected from the downgradient water supply wells on a quarterly and semiannual
basis. Low level VOC concentrations have been observed in the water supply well network dating back to
initial sampling efforts in the 1990s. Note that water supply wells with VOC concentrations exceeding
Title 15A NCAC 2L .0202 Groundwater Standards (21, Standards) were properly abandoned. A review of
the data for the remaining water supply wells indicates that while VOCs are present at concentrations below
2L Standards, these concentrations appear stable and within historical ranges. VOC groundwater analytical
data for these water supply wells are included in Table 2. A water supply well results map for the January
2017 sampling event is included as Figure 3.
In addition to the VOC data discussed above, natural attenuation parameters were also collected for select
monitoring and water supply wells. The results of this data collection show changes in aquifer conditions
in the injection area that are reflective of enhanced reductive dechlorination, including increases or presence
of iron, total organic carbon, manganese, and methane and decreases in oxidation reduction potential
(ORP), dissolved oxygen, nitrate, and sulfate. However, these changes in aquifer conditions are generally
limited to the injection area and no substantial changes in natural attenuation parameters have been
measured in the perimeter monitoring wells or downgradient water supply wells. Natural attenuation data
are included in Table 3.

Modification Request for Groundwater Remediation Permit WQ0035324 April 6, 2017
Former Pro -Cleaners, DSCA Site #DC920001 Page 3
3.0 Permit Modifications Request
The current monitoring program costs in excess of $75,000 per year. This monitoring has been underway
for over four years and substantial data has been collected to evaluate the aquifer effects associated with
the ISDTM system operation. The monitoring shows that the ISDTM system operation has had a beneficial
effect on the aquifer quality in that contaminant trends are stable or decreasing, and there are no unwanted
secondary impacts associated with the CarbstrateTM injection. As such, ATC believes that sufficient
monitoring can still be achieved through the reduction of sampling analysis and frequency for select
monitoring wells. Currently, the following sampling is required:
Collect groundwater samples from nine monitoring wells (MW-5, MW-IOA, MW-IOB, MW-I IA,
MW-1113, MW-12, MW-16, MW-24S, and MW-2413, two extraction wells (EW-8 [former
injection well IW-8] and EW-9A [former injection well IW-9]) for analysis of volatile organic
compounds (VOCs) by EPA 8260, nitrate (nitrogen), nitrite (nitrogen), sulfate, sulfide, methane,
ethane, total ammonia nitrogen, and total organic carbon on a quarterly basis; and
Collect groundwater samples from water supply wells 8404 and 8405 Azalea Place and 8401, 8404,
8405, 8408, and 8409 Camellia Drive on a quarterly basis and water supply wells 8408 and 8409
Azalea Place and 8412 and 8413 Camellia Drive on a semi-annual basis.
ATC is requesting the following sampling modifications:
• Collect groundwater samples from five monitoring wells (MW-8B, MW-10A, MW-lOB,
MW-I IA, and MW-I IB) on a semi-annual basis and five monitoring wells (MW-5, MW-12,
MW-16, MW-24S, and MW-24D) on an annual basis for analysis of VOCs by EPA 8260, nitrate
(nitrogen), nitrite (nitrogen), sulfate, sulfide, methane, ethane, total ammonia nitrogen, and
total organic carbon; and
• Collect groundwater samples from water supply wells 8404 and 8405 Azalea Place and 8401, 8404,
8405, 8408, and 8409 Camellia Drive on a semi-annual basis and water supply wells 8408 and 8409
Azalea Place and 8412 and 8413 Camellia Drive on an annual basis.
Note that ATC's request includes the sampling of monitoring well MW-8B, which is not currently part of
the permit requirements but will be sampled on a semi-annual basis to provide continued monitoring for
the groundwater extraction area. Further, quarterly monitoring of extraction wells EW-8 and EW-9A will
continue under the current permit requirements via sampling of the ISDTM system's GAC influent
groundwater stream.
If you have questions or require additional information, please do not hesitate to contact us at (919) 871-
0999.
Sincerely,
ATC Associates of North Carolina, P.C.
Justin C. Ballard, P.G.
Project Manager
NC Professional Geologist #2257
Genoa K. Olson, P.G.
Program Manager
NC Professional Geologist # 1660

Modification Request for Groundwater Remediation Permit WQ0035324
Former Pro -Cleaners, DSCA Site #DC920001
3.0 Permit Modifications Request
April 6, 2017
) Paee 3
The ent monitoring program costs in excess of $75,000 per year. This monitoring been underway
for o four years and substantial data has been collected to evaluate the aquifer a cts associated with
the ISD system operation. The monitoring shows that the ISDTM system operat' has had a beneficial
effect on th quifer quality in that contaminant trends are stable or decreasing, d there are no unwanted
secondary im cts associated with the CarbstrateTM injection. As such, C believes that sufficient
monitoring can 11 be achieved through the reduction of sampling anal is and frequency for select
monitoring wells. ntly, the following sampling is required:
Collect ground ter samples from nine monitoring wells ( -5, MW-10A, MW-IOB, MW-I IA,
MW-11BZ11WIPW
-1 MW-16, MW-24S, and MA extraction o extraction wells (EW-8 [former
injection -8 d EW-9A [former injection we IW-9]) for analysis of volatile organic
compounds (VOCs) b PA 8260, nitrate (nitrogen), ttrite (nitrogen), sulfate, sulfide, methane,
ethane, total ammonia ni gen, and total organic c on on a quarterly basis; and
Collect groundwater sample from water supply w s 8404 and 8405 Azalea Place and 8401, 8404,
8405, 8408, and 8409 Camel Drive on a q rly basis and water supply wells 8408 and 8409
Azalea Place and 8412 and 841 Camellia ' e on a semi-annual basis.
ATC is requesting the following sampling
Collect groundwater saVsua,te,
a\n,ng wells (MW-8B, MW-10A, MW-IOB,
MW-1�A, and N�W-li' and five monitoring wells (MW!S, MW�12,
MW- It, MW-24S, andon an sis for analysis of VOCs by EPA 8260, nitrate
(nitrogen), nitrite (nitrote, sulhane, ethane, total ammonia nitrogen, and
total organic carbon; J.
Collect groundwater sawater supply we 8404 and 8405 Azalea Place and 8401, 8404,
84d'5, 8468, and 84a9 Cive on a semi-annua basis and water supply wells 84`08 and8409
Azalea Place and 8411amellia Drive on an ual basis.
Note that ATC's request incl des the sampling of monitoring well IS -8B, which is not currently part of
the permit requirements b will be sampled on a semi-annual basis provide continued monitoring for
the groundwater extracti9A area. Further, quarterly monitoring of extra ion wells EW-8 and EW-9A will
continue unde/ions
ent permit requirements via sampling of the SDTM system's GAC influent
groundwater st
If you have qurequire additional information, please do not hesitate to ontact us at (919) 871-
0999.
Sincerely,
ATC Ass ciates of North Carolina, P.C.
stin C. Ballard, P.G.
Project Manager
NC Professional Geologist #2257
l
Genna K. Olson, P.G.
Program Manager
NC Professional Geologist #1660

Modification Request for Groundwater Remediation Permit WQ0035324
Former Pro -Cleaners, DSCA Site #DC920001
Permit Modifications Request
April 6, ?017
ee 3
The urrent monitoring program costs in excess of $75,000 per year. This monitoring has b n underway
for o four years and substantial data has been collected to evaluate the aquifer effects sociated with
the ISD system operation. The monitoring shows that the ISDTM system operation h ad a beneficial
effect on t aquifer quality in that contaminant trends are stable or decreasing, and the are no unwanted
secondary i acts associated with the CarbstrateT"' injection. As such, ATC bel' ves that sufficient
monitoring c still be achieved through the reduction of sampling analysis anfrequency for select
monitoring wells. Currently, the following sampling is required:
• Collect grounlkyater samples from nine monitoring wells (MW-5, MW- OA, MW-lOB, MW-11A,
MW-IIB, M 2, MW-16, MW-24S, and MW-24D, two extra ion wells (EW-8 [former
injection well IW- and EW-9A [former injection well I/qe
analysis of volatile organic
compounds (VOCs)\*trogen,
60, nitrate (nitrogen), nitrit), sulfate, sulfide, methane,
ethane, total ammonand total organic carbon ony basis; and
• Collect groundwaterm water supply wells 8404 zalea Place and 8401, 8404,
8405, 8408, and 84Drive on a quarterly basisupply wells 8408 and 8409
Azalea Place and 84Camellia Drive on a semi -is.
ATC is requesting the following sampling
• Collect groundwater samples from fiv monitori wells (MW-8B, MW-10A, MW-lOB, MW-
I IA, and MW-I IB) on a semi-annu ba 's and ive monitoring wells (MW-5, MW-12, MW-16,
MW-24S, and MW-24D) on an annual basi analysis of VOCs by EPA 8260, nitrate (nitrogen),
nitrite ' ugen),_& , sulfid/amnellia
hane, total ammonia nitrogen, and total organic
carbo !�rly basis; d
• Collect groun w es froly we 8404 and 8405 Azalea Place and 8401, 8404,
8405, 8408, and 8409 Camellia Di-annu basis and water supply wells 8408 and 8409
Azalea Place and 8412 and 8413ive on an ual basis.
Note that ATC's reques/will
sampling of monitoring well W-8B, which is not currently part of
the permit requirementsampled on asemi-annual basis t rovide c e7mring
for
the groundwater extractiher, quarterly monitoring of extrac ' n w is EW-8 9A w 11
continue under the currequirements via sampling of the TM system uent
groundwater stream.
If you have que ons or require additional information, please do not hesitate to co tact us at (919) 871-
0999.
ATC ssociates of North Carolina, P.C.
.
Justin C. Ballard, P.G.
Project Manager
NC Professional Geologist #2257
l
Genna K. Olson, P.G.
Program Manager
NC Professional Geologist #1660

Modification Request for Groundwater Remediation Permit WQ0035324 April 6, 2017
Former Pro -Cleaners, DSCA Site #DC920001 Page 4
Attachments:
1. Figure 1 — Groundwater Gradient Map (January 2017)
2. Figure 2 — PCE Isoconcentration Contour Map (January 2017)
3. Figure 3 — Water Supply Well Results Map (January 2017)
4. Table 1 — Analytical Data for Groundwater
5. Table 2 — Analytical Data for Natural Attenuation Parameters
6. Table 3 — Analytical Data for Water Supply Wells
7. Appendix A — GSI Mann -Kendall Toolkit for Constituent Trend Analysis Graphs

FIGURES

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NOTES:
1. FEATURES SHOWN ARE NOT AN AUTHORITATIVE
F
TITLE FIGURE 1
LOCATION. NOR ARE THEY PRESENTED TO A STATED
GROUNDWATER GRADIENT MAP
IV2.
ACCURACY.
1/2-25D017. ELEVATIONS MEASURED ON
FORMER PRO CLEANERS, 8377 CREEDMOOR ROAD
AWA
1 'INJECTION WELLS (IW), DEEP MONITORING WELLS
TOWN E NORTH SHOPPING CENTERA
wr ITC
(MW-11A AND MW-8A) AND INTERMEDIATE MONITORING
WELL MW-10A, AND SHALLOW MONITORING WELLS
NORTH CAROLINA
ATC Associates of North Carolina, P.C.
MW-17, MW-21 AND MW-22S WERE NOT USED TO
RALEIGH,
Raleigh, North Carolina,27604 [phone]
CONSTRUCT CONTOURS.
COORDINATE SYSTEM:
;;AD FILE
DCSA ID
PREP. BY
REV. BY
SCALE
DATE
PROJECT NO.
NAD 1983 NORHT CAROLINA STATE PLANE FIPS 3200, US
SEE LOWER LEFT
DC920001
AK
JB
AS SH OWN
2/17
DC9201 SL35
SURVEY FEET

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NOTES: TITLE FIGURE 2
1. FEATURES SHOWN ARE NOT AN AUTHORITATIVE PCE ISOCONCENTRATION CONTOUR MAP
LOCATIONS, NOR ARE THEY PRESENTED TO A STATED
ACCURACY
2. GROUNDWATER SAMPLES COLLECTED ,I24_,12G/20,7. FORMER PRO CLEANERS, 8377 CREEDMOOR ROAD
3. J VALUES INDICATED ESTIMATED CONCENTRATIONS
BETWEEN METHOD DETECTION LIMIT AND PRACTICAL TO WN E NORTH SHOPPING
QUANTITATIVE LIMITS.
RALEIGH, NORTH CAROLINA
AffAkT
F C
COORDINATE SYSTEM: (:AD FILE DCSA ID PREP. BY REV. BY
NAD 1983 NORHT CAROLINA STATE PLANE FIPS 3200, US SEE LOWER LEFT DC920001 AK AM
SURVEY FEET
ATC Associates of North Carolina, P.C.
Raleigh, North Carolina, 27604 [phone]
SCALE DATE PROJECT NO.
AS SHOWN 2/17 _ DC9201SL35

H:\1017\0THER OFFICES\NORTH CAROUNA\NCDEO-DWM-DSCA PROGR4M\92-0001 PRO CLEANERS, RALEIGH SL 35\DC9201SL35-WSW-DA7A.DWG, IIA
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NOTES: TITLE FIGURE 3
1. DATA SHOWN IN mg/L.IF
2. J INDICATES ESTIMATED CONCENTRATION BETWEEN WATER SUPPLY WELL RESULTS MAP
METHOD DETECTION LIMIT AND PRACTICAL
QUANTITATION LIMIT. FORMER PRO CLEANERS, 8377 CREEDMOOR ROAD Awl
3. (") WATER SUPPLY WELL IS KNOWN TO EXIST AT 8409
AZALEA PLACE BUT EXACT LOCATION UNABLE TO BE TO WN E NORTH SHOPPING CENTER
DETERMINED DURING OCTOBER 2011 RECEPTOR ATC Associates of North RALEIGH, NORTH CAROLINA Raleigh, North
SURVEY. (919)871_0999
,AD FILE DCSA ID PREP. BY REV. BY SCALE DATE PROJECT N0.
SEE LOWER LEFT IDC920001
AK AM I AS SHOWN 1 2/17 DC9201SL35

TABLES

Table 1
Monitoring Requirements
Groundwater Remediation Permit W00035324
Former Pro Cleaners
DSCA Site DC920001
8377 Creedmoor Road, Raleigh, North Carolina
H&H Job No. DSO-130
Quarterly for the following analyses:
Semiannually for the following analyses:
Annually for the following analyses:
-extraction wells will be sampled from the
-monitoring wells and water supply wells will
-monitoring wells will be sampled for VOCs
ISDTM system's GAC influent groundwater
be sampled for VOCs by EPA Method 8260
by EPA Method 8260, nitrate, nitrite, sulfate,
stream for VOCs by EPA Method 8260
-field analysis will be performed on
sulfide, methane, ethane, ethene, ammonia
-field analysis will be performed on extraction
monitoring well and water supply well
nitrogen, and total organic carbon
well samples for oxidation-reduction potential,
samples for oxidation-reduction potential, pH,
-water supply wells will be sampled for VOCs
pH, dissolved oxygen, conductivity, and
dissolved oxygen, conductivity, and turbidity
by EPA Method 8260
turbidity
-field analysis will be performed on
monitoring well and water supply well
samples for oxidation-reduction potential, pH,
dissolved oxygen, conductivity, and turbidity
-extraction wells EW-8 and EW-9A
-monitoring wells MW-IOA, MW-IOB, MW-
-monitoring wells MW-5, MW-IOA, MW-
I IA, and MW-I I and water supply wells at
IOB, MW-11A, MW-I 1B, MW-12, MW-16,
8404 and 8405 Azalea Place and 8401, 8404,
MW-24S, and MW-24D and water supply
8405, 8408, and 8409 Camellia Drive
wells at 8404, 8405, 8408, and 8409 Azalea
Place and 8401, 8404, 8405, 8408, 8409,
8412, and 8413 Camellia Drive
9:wA ,a P,OwWV)Scn-osao IMPmc�w�%Addmwlta R� tan-+aocex000l_solW22 ssmpIWVI Table t (Page 1 of 1)
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Table I::�nal3tical 13a[a for Grounde:�tcr 1
DSCA ID No.: D('920001
E
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bv%
NA
NA
NA
NA
NA
0.089
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Nis-MNB
m
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ND
ND
m
O.W22
ND
ND
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ND
ND
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m
m
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NA
NA
112o/9g
ND
ND
ND
NO
ND
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ND
ND
ND
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m
m
m
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m
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NA
NA
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m
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m
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NA
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ND
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-
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NA
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NA
NA
NA
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m.005
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NA
NA
NA
m.01
NA
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m.025
0.0131
0.025
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NA
NA
m.025
NA
NA
NA
NA
m.025
m.025
m.025
NA
NA
NA
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NA
1L 13
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m.0o5
m.0o5
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NA
NA
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NA
NA
NA
NA
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NA
NA
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NA
3 13
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Table 3: Analytical Data for Natural Attenuation Parameters
i
a
E
o
0
t
Units
my
m^
m
m�
m
m
mV
m
m
s/cm'
std unit
° c
m
m /L
m
3/112005
7.7
0.68
<1.0
NA
<0.026
ND
73
15
IO
4.0
5.89
19.9
NA
<0.026
<0.026
11/1l/20ON
3.7
NA
NA
NA
NA
NA
204.8
NA
NA
27
4.71
14.88
2.5
NA
NA
2/42009
0.65
NA
NA
NA
NA
NA
202.3
NA
NA
NA
4.62
16.47
1.03
NA
NA
422009
3.23
NA
NA
NA
NA
NA
226.7
NA
NA
NA
3.99
17.81
0.67J
NA
NA
7/142009
5.01
NA
NA
NA
NA
NA
100.3
NA
NA
NA
4.92
21.28
2.17
NA
NA
IO/72009
0.85
NA
NA
NA
NA
NA
67.9
NA
NA
26
4.14
21.38
1.25
NA
NA
2/4/2010
4.28
NA
NA
NA
NA
NA
209.4
NA
NA
NA
4.43
12.01
0.688J
NA
NA
4/212010
2.87
NA
NA
NA
NA
NA
214.6
NA
NA
NA
4.52
16.33
0.598J
NA
NA
7/142010
2.33
NA
NA
NA
NA
NA
67.2
NA
NA
27
4.71
23.21
1.37
NA
NA
1020/2010
2.27
NA
NA
NA
NA
NA
101.3
NA
NA
NA
4.81
17.85
NA
NA
NA
7272011
4.3
NA
NA
NA
NA
NA
97.9
NA
NA
89
4.62
28.35
NA
NA
NA
II22011
5.02
NA
NA
NA
NA
NA
216.3
NA
NA
34
4.83
18.59
NA
NA
NA
1252012
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/202012
NA
0.145
0.686
NA
<0.11
ND
NA
NA
NA
NA
NA
NA
0.817J
<0.23
<0.31
12/32012
NA
0.037
<5.0
NA
<0.00003
ND
NA
NA
NA
NA
NA
NA
22
<0.00023
<0400031
MW-1013
2272013
NA
0.203
0.425
NA
<0.11
NA
NA
NA
NA
NA
NA
NA
3.63
<0.23
<0.31
5/312013
4.47
NA
NA
NA
NA
NA
116.7
NA
NA
28
4.39
20.61
1.99
NA
NA
9/122013
5
0.035J
0.373
NA
0.00018
NA
134.8
NA
NA
62
4.22
27.69
2.57
<0.00023
<0.00031
12/132013
NA
0.135J
0.817
NA
0.00011
NA
NA
NA
NA
NA
NA
NA
1.11
<0.00023
<0.00031
3/272014
NA
0.19
<2.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
0.69
<0.0028
<0.0038
6/192014
NA
0.11
<2.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
033J
<0.0028
<0.0038
9252014
7.73
<0.050
1.73
NA
<0.0026
ND
121.1
NA
NA
51
5.49
19.59
0.33J
<0.0028
<0.0038
12/182014
NA
0.075
Q.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
0.3IJ
<0.0028
<0.0038
3202015
6.64
0.047J
<2.0
NA
0.0062
NA
57.8
NA
NA
43
5.05
15.65
.0028
<0.0038
6/182015
NA
<0.050
<2.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
.0028
<0.0038
9/162015
3.23
<0.050
<2.0
NA
56
ND
284.5
NA
NA
44
5.00
29.27
.0028
<0.0038
12/I52015
NA
0.1
0.87J
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
.0028
<0.0038
3/162016
NA
0.0191
<2.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
.0028
J04314J<0.0028
<0.0038
6/302016
2.22
0.0211
<2.0
NA
<0.0026
ND
171.9
NA
NA
35
5.3
21.20
.0028
0. 2269282016
7.76
0.13
<2.0
NA
<0.0026
ND
153.5
NA
NA
63
6.05
20.60
.0028
<0.00381252017
3.74
0.0331
<2.0
NA
<0.0026
1
243.5
NA
NA
28
5.16
19.46
.0028
<0.0038
Page 4 of 34

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Table 3: Analytical Data for Natural Attenuation Parameters
QI ;
t
__
c
a
c
o
O
F
$
$
Units
mR/L
mg/L
m /L
m�
m
m°/L
mV
m /L
m
s/cm'
std unit
° C
m /L
m /L
MWL
3/10/2005
8.0
0.44
<1.0
NA
<0.026
ND
295
15
15
2.0
5.35
17.9
NA
<0.026
<0.026
7/142010
7.0
NA
NA
NA
NA
NA
156.2
NA
NA
19
4.66
22.56
NA
NA
NA
3/20/2015
NA
NA
NA
NA
0.0047
NA
NA
NA
NA
NA
NA
NA
NA
<0.0028
<0.0038
6/17/2015
7.78
0.32
4.1
NA
0.014
ND
227.8
NA
NA
25
4.01 1
23.67
0.37J
10,0028
<0,0038
9/16/2015
7.76
0.63
1.6J
NA
65
ND
169.3
NA
NA
31
5A6
1 22.57
040
<0.0028
<0.0038
MW 12
12/17/2015
NA
0.74
<2.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
1.6
<0.0028
<0.0038
3/17/2016
NA
0.66
<2.0
NA
<0.0026IND
NA
NA
NA
NA
NA
NA
2.45
<0.0028
<0.0038
6/302016
2.65
0.68
<2.0
NA
0.00191189.6
NA
NA
55
5.16
24
1.69
<040029
<0.0038
9/282016
8.10
0.63
<2.0
NA
0.05168.8
NA
NA
37
6.17
22.54
2.8
<0.0028
<0.0038
1/252017
5.42
0.52
<2.0
NA
430250.3
NA
NA
17
5.41
IT56
0.43 J
<0.0028
<0.0038
3/9/2005
18.06
0.89
<1.0
NA
<0.026
242
5.0
10
28
4.93
16.78
NA
<0.026
<0.026
MW-13
7/142009
4.58
NA
NA
NA
NA
142
NA
NA
NA
3.99
2668
NA
NA
NA
7/142010
6A
NA
NA
NA
NA
118.4
NA
NA
26
1 4.24
24.94
NA
NA
NA
3/112005
7.8
0.62
NT
NA
<0.026
ND
354
15
25
3.0
5.1
16
NA
<0.026
<0.026
11/122008
6.72
NA
NA
NA
NA
NA
77.1
NA
NA
36
4.37
15.13
0.57J
NA
NA
2/4/2009
1.17
NA
NA
NA
NA
NA
208.8
NA
NA
NA
4.08
13.07
0.5111
NA
NA
422009
6.04
NA
NA
NA
NA
NA
115.1
NA
NA
47
3.84
17.38
0.432J
NA
NA
7/152009
2.79
NA
NA
NA
NA
NA
195
NA
NA
55
4.27
23.4
146
NA
NA
10/62009
5.61
NA
NA
NA
NA
NA
100.3
NA
NA
32
4.22
18.64
7.01
NA
NA
2/3/2010
7.14
NA
NA
NA
NA
NA
86.2
NA
NA
NA
3.88
15.63
0.6071
NA
NA
4/212010
6.24
NA
NA
NA
NA
NA
202.6
NA
NA
NA
4.1
17.74
0.748J
NA
NA
7/132010
6.6
NA
NA
NA
NA
NA
210.3
NA
NA
NA
4.27
21.76
0.65J
NA
NA
1020/2010
6.69
NA
NA
NA
NA
NA
217.2
NA
NA
NA
4.27
17.73
NA
NA
NA
4262011
NA-
NA
NA
NA
NA
NA
166.3
NA
NA
NA
4.54
20.06
NA
NA
NA
1262012
1.35
0.297
0.344
NA
NA
ND
211.4
NA
NA
-64
4.31
18.29
0.221J
NA
NA
7/182012
5.36
0.329
0.822
NA
<0.11
ND
55.1
NA
NA
33
5.35
24.62
0.258J
<0.23
<0.31
11292012
7.91
0.491
<5.0
NA
<0400011
ND
270
NA
NA
53
4.77
16.84
0.62J
<0.00023
<0000031
2272013
5.54
0.856
0.200
NA
<0.11
ND
107.7
NA
NA
32
4.38
17.85
0.3371
<0.23
<0.31
MW 16
5/302013
5.83
0.429
0.631
NA
NA
ND
92.1
NA
NA
40
4.37
24.35
0.45J
NA
NA
9/102013
7.01
0.76
0.32
NA
<0.00011
0.45
159.6
NA
NA
42
4.38
19.91
0.4361
<0.00023
<0.00031
12/112013
7.01
0.344J
0.284
NA
<0.00011
ND
259.4
NA
NA
25
4.59
13.44
1.05
<0.00023
<0.00031
3/262014
7.78
0.89
<2.0
NA
<0.0026
ND
151.5
NA
NA
48
5.09
13.59
0.32J
<0.0028
<0.0038
6/182014
5.31
0.88
<2.0
NA
<0.0026
ND
315
NA
NA
49
3.31*
29.18
0.25J
<0.0028
<0.0038
9/252014
7.56
0.86
4.5
NA
0.006
ND
149
NA
NA
38
4.54
18.27
0.36J
<0.0028
<0.0038
12/18/2014
6.14
0.78
<2.0
NA
0.013
ND
176A
NA
NA
32
6.04
15.16
2.1
<0.0028
<0.0038
3/192015
10.25
0.81
<2.0
NA
0.0024J
NA
192.3
NA
NA
43
4.23
15.88
0.56
<040028
<0.0038
6/182015
7.15
0.82
<2.0
NA
<0.0026
2
251.2
NA
NA
37
3.68
21.03
<0.50
<0.0028
<0.0038
9/152015
6.20
0.73
<2.0
NA
160000
ND
232.1
NA
NA
44
4.58
18.79
0.73
<0.0028
<0.0038
12/152015
6.20
0.76
3.2
NA
<0.0026
ND
150.9
NA
NA
40
4.77
18.61
<0.50
<0.0028
<0.0038
3/172016
10.51
0.79
<2.0
NA
<040026
ND
161.2
NA
NA
33
4.80
18.50
0.64
<0.0028
<0.0038
6/282016
4.80
0.84
1.5J
NA
0.0043
ND
331
NA
NA
40
4.01
20.30
0.423J
<0.0028
<0.0038
9/292016
9.78
0.80
<2.0
NA
<0.0026
ND
320.9
NA
NA
44
4.42
19.80
0.54
<0.0028
<0.0038
1/242017
6.95
14.00
<2.0
NA
<0.0026
ND
303.3
NA
NA
35
4.55
17.50
<0.50
<0.0028
<0.0038
MW-16-A
2/62006
8.53
NA
NA
NA
<0.0002
NA
NA
NA
NA
NA
NA
NA
NA
<0.0002
<0.0003
MW-16 •B
2/6/2006
8.79
NA
NA
NA
<0.0002
NA
NA
NA
NA
NA
NA
I NA
NA
<0.0002
<0.001G
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a
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Table 3: Analytical Data for Natural Attenuation Parameters
_
_
z
__
O
o
a
v
o
$
Units
mN
m
m
m°
m°/L
m
mV
mWL
m
s/Cfi1'
std unit
° C
m
m
11/12/2008
3.86
NA
NA
NA
NA
NA
168.1
NA
NA
177
6.15
18.22
5.4
NA
12/2/2008
4.09
NA
NA
NA
NA
NA
74.7
NA
NA
88
6.12
19.13
NA
NA
2/5/2009
0.47
NA
NA
NA
NA
NA
130A
NA
NA
NA
5.18
15.67
0.707J
RNAL
NA
4/2/2009
1.98
NA
NA
NA
NA
NA
54.3
NA
NA
NA
4.9
19.28
0.44J
NA
7/152009
1.4
NA
NA
NA
NA
NA
-11.2
NA
NA
NA
4.63
25.62
0.3051
NA
9/162009
1.96
NA
NA
NA
NA
NA
216.9
NA
NA
72
4.84
22.75
0.6221
NA
10/62009
2.56
NA
NA
NA
NA
NA
92.6
NA
NA
57
4.93
21.47
0.455J
NA
NA
2/32010
3.51
NA
NA
NA
NA
NA
14.7
NA
NA
NA
4.59
32.00
0.533J
NA
NA
4/202010
3.67
NA
NA
NA
NA
NA
32.1
NA
NA
NA
4.37
22.64
0.327J
NA
NA
7/132010
3.7
NA
NA
NA
NA
NA
221.8
NA
NA
57
4.61
24.56
1.78
NA
NA
10202010
1.72
NA
NA
NA
NA
NA
1/76
NA
NA
211
5.14
19.84
NA
NA
NA
4252011
NA-
NA
NA
NA
NA
NA
-a,'
NA
NA
175
5.54
24.72
NA
NA
NA
1l/12011
1.55
NA
NA
NA
NA
NA
772.2
NA
NA
175
NA
19.69
NA
NA
NA
91AA'-'
7/I82012
2.23
1.48
1.05
NA
0.4
ND
0
NA
NA
76
5.0
28.95
0.3581
<0.23
N.31
1128n012
1.33
0.049
<5.0
NA
0.155
6.0
-16.5
NA
NA
266
5.53
18.61
8.2
<0.00023
<0400031
-228/2013
0.37
0.012
0.74
NA
0.138
I.5
-127.5
NA
NA
146
5.75
IZ57
1.62
<0.00023
<0.00031
5/302013
0.33
0.057
2.55
NA
NA
ND
11.7
NA
NA
105
5.65
21.95
1.07
NA
NA
9/112013
1.68
0.102
3.02
NA
0.013
>1.2
97.1
NA
NA
85
1 4.77
21.47
0.796J
<0.00023
<0.00031
12/122013
0.59
0.028J
1.01
NA
2.9JNA-208.1
NA
NA
525
5.85
16.09
110
<O.00023
<0.00031
3252014
0.72
<0.010
<2.0
NA
6.7
NA
NA
508
6.6
13.67
30
<O.Ol4
<0.019
6/182014
0.29
<0.050
<20
NA
151
NA
NA
581
6.47•
26.50
47
<0.0028
<0.0038
9242014
0.49
<0.050
2.2
NA
22.1
NA
NA
521
6.93
17.52
39
<0.0028
<0.0038
12/182014
0.92
<0.050
<2.0
NA
24
.9
NA
NAE717
8
7.4
16.64
13
<0.0028
<0.0038
3/192015
0.39
0.05
<4.0
NA
43
.1
NA
NA9
7.33
17.1
33
<0.0028
<0.0038
6/162015
0.25
<0.050
<2.0
NA
27.2
NA
NA6
7
23.39
14
<0.0028
<0.0038
9/1520I5
0.56
<0.050
Q.0
NA
1600001
NA
NA
6.60
23.67
3.3
<0.0028
<0.0038
Page 9 of 34

Table 3: Analytical Data for Natural Attenuation Parameters
Rooms
EE
l
o
�
e
$
a
Units
mwL
mWL
mWL
mOL
mwL
m V
m
m
s/cmz
std unit
- C
m9JL
m /L
m
2/82012
7.84
0.173
22.2
NA
0.00026
ND
93.2
NA
NA
126
6.11
14.76
5.07
<0.00023
<0.00031
11/30/2012
7.77
0.479
<5
NA
<0.00011
ND
178.8
NA
NA
69
5.59
18.59
1.14
<0.00023
<0.00031
2/252013
6.49
133
0.2081
NA
<O.II
ND
96.1
NA
NA
27
5.37
13.72
1.19
<0.23
<0.31
5/292013
6.76
0.487 1
0.491
NA
NA
ND
88.8
NA
NA
25
4.98
21.67
0.3931
NA
NA
9/102011
7.25
0.602
0.367
NA
<0.00011
ND
183.9
NA
NA
24
4.36
21.91
0.771J
<0,00023
<0.00031
12/102013
6.53
0.351J
1.02
NA
0.00012
ND
265.5
NA
NA
21
5.62
12.52
1.74
<0400023
<0.00031
3242014
6.93
0.60
Q.0
NA
<0.0026
ND
107.2
NA
NA
38
5.43
15.34
0.441
<0.0028
<0.0038
6/162014
6.17
0.47
2.5
NA
<0.0026
ND
162.4
NA
NA
32
4.98-
32.85
<0.50
<0.0028
<0.0038
9232014
7.17
0.58
<2.0
NA
<0.0026
ND
1217
NA
NA
20
4.82
1931
<0.50
<0.0028
<0.0038
MW-24S
12/172014
6.74
0.66
<2.0
NA
0.0059
ND
183.1
NA
NA
19
7.17
16.52
0.61
<0.0028
<0.0038
3/172015
10.61
0.53
Q.0
NA
<0.0026
NA
101.9
NA
NA
25
3.89
26.61
<0.50
<0.0028
<0.0038
6/152015
5.66
0.56
Q.0
NA
<0.0026
ND
196.9
NA
NA
30
5.09
28.89
<0.50
<0.0028
<0.0038
9/152015
6.87
0.61
Q.0
NA
0,0055
0.2
169.1
NA
NA
25
5.23
25.2
0.45J
<0.0028
<0.0038
12/142015
8.25
0.51
0.67J
NA
<0.0026
ND
151.0
NA
NA
17
5.53
19.83
<0.50
<0.0028
<0.0038
3/152016
8.34
0.78
Q.0
NA
<0.0026
ND
293.2
NA
NA
20
1 4.66
19.97
0.36J
<0.0028
<0.0038
6272016
5.59
0.57
Q.0
NA
<0.0026
ND
254.2
NA
NA
28
4.51
28.4
0.25J
<0.0028
<0.0038
9262016
6.57
0.75
<2.0
NA
<0.0026
ND
203.0
NA
NA
26
4A2
20.71
<0.50
NA
NA
1232017
6.32
0.63
Q.0
NA
<0.0026
ND
303.8
NA
NA
26
4.99
17.8
<0.50
<0.0028
<0.0038
2182012
9.89
<0.01
27.8
NA
<0.00011
ND
105
NA
NA
115
5.79
16.71
4.54
<0.00023
<0.00031
11/302012
7.48
0.054
<5
NA
<0.00011
ND
132.9
NA
NA
103
5.9
17.70
1.44
<0.00023
<0.00031
2272013
6.25
0.049J
0.321
NA
<0.11
ND
95.4
NA
NA
45
6.04
16.37
0.863J
<0.23
<0.31
5292013
6.1
0.015
0.417
NA
NA
ND
72.6
NA
NA
4]
5.76
22.00
1 0.6071
NA
NA
9/102013
7.19
0.0281
0.334
NA
<0.00011
ND
185.3
NA
NA
37
5.09
20.05
0.313J
<0.00023
<0.00031
12/10/2013
6.29
<0.5
0.33
NA
<0.00011
ND
263.4
NA
NA
31
6.11
15.97
0.288J
<0.00023
<0.00031
3252014
7.5
0.010
Q.0
NA
<0.0026
0.2
153.1
NA
NA
48
5.97
11.68
0.66
<0.0028
<0.0038
6/192014
6.89
<0.050
Q.0
NA
<0.0026
ND
2023
NA
NA
33
4.38-
23.31
1.1
<0.0028
<0.0038
9232014
7.66
<0.050
3.5
NA
<0.0026
0.25
113.7
NA
NA
30
5.27
19.55
<0.50
<0.0028
<0.0038
MW- 41)
12/172014
7.27
0.087
<]ODL-02
NA
<0.0026
ND
190.E
NA
NA
26
7.54
16.53
0.411
<0.0028
<0.0038
3/182015
12.35
<0.050
3.7
NA
<0.0026
NA
61.7
NA
NA
34
5.21
14.96
<0.50
<0.0028
<0.0038
6/152015
6.26
<0.050
<2.0
NA
<0.0026
ND
209.8
NA
NA
36
5.26
24.120
8.2
<0.0028
<0.0038
9/152015
7.04
<0.050
<2.0
NA
<0.0026
0.8
184.00
NA
NA
38
5.48
20.870
0.30J
<0,0028
<0.0038
12/16/2015
7.25
0.14
<2.0
NA
<0.0026
ND
115.7
NA
NA
35
5.98
19.020
0.28J
<0.0028
<0.0038
3/152016
7.45
<0.050
<4.0
NA
<0.0026
ND
313.2
NA
NA
33
3.99
19.54
0.33J
<0.0028
<0.0038
6/302016
5.41
0.0111
<2.0
NA
<0.0026
>1.2
131.6
NA
NA
35
5.78
22.60
0.6861
<0.0028
<0.0038
9262016
7.66
0.013 J
<2.0
NA
<0.0026
0.4
184.3
NA
NA
32
4.95
19.77
<0.50
NA
NA
1232017
1 4.9
0.017 J
Q.0
NA
<0.0026
ND
324.2
NA
NA
33
5.66
17.90
<0.50
<0.0028
<0.0038
Page 10 of 34

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Table 3: Analytical Data for Natural Attenuation Parameters
DSCA ID No.: DC92U0'
a
-a
E
O
L1
m
O
E
0
py
c
L
pp
pp
0
Units
my
m /L
mg
mviL
m
m�
mV
m
m
s/cm'
std unit
- c
m
m
m
9/152009
4.33
NA
NA
NA
NA
NA
27.3
NA
NA
NA
4.61
20.88
NA
NA
NA
1272012
1.19
NA
0.466
NA
NA
ND
238
NA
NA
26
4.24
18.6
0.3111
NA
NA
7/192012
6.62
0.983
3.16
NA
<0.11
ND
47.6
NA
NA
36
4.61
29.16
0.535J
<0.23
<0.31
11/302012
8.14
0.679
<5.0
NA
0.00014
1.2
258.8
NA
NA
60
4.86
17.79
1.47
<0.00023
<0.00031
-2282013
7.4
0.866
0.311
NA
<0.00011
ND
125.5
NA
NA
26
4.86
17.04
<1
<0.00023
<0.00031
5/302013
7.02
0.872
0.382
NA
NA
ND
104.2
NA
NA
25
4.29
21.49
0.24J
NA
NA
9/112013
6
0.804
0.503
NA
0.0071
0.25
93.4
NA
NA
31
5.01
35.57
1.01
<0.00023
<0.00031
-1 \\-x
12/11201,
NA
0.481J
0.42
NA
0.00014
NA
NA
NA
NA
NA
NA
NA
0.24J
<0.00023
<0.00031
0327/2014
NA
0.57
<2.0ONA
<0.0026
NA
NA
NA
NA
NA
NA
NA
<0.50
<0.0028
<0.0038
6202014
NA
0.43
<.0<0.0026
NA
NA
NA
NA
NA
NA
NA
<0.50
<0.0028
<0.0038
9252014
7.98
0.46
<.0<0.0026
NA
156.4
NA
NA
21
4.79
21.74
<0.50
<0.0028
<0.0038
12/182014
6.65
0.76
<2.00.0081
NA
193.6
NA
NA
20
6.08
15.13
0.471
<0.0028
<0.0038
3202015
11.51
0.35
<2.0
0.28
NA
180.4
NA
NA
24
5.02
15.53
1
<0.0028
<0.0038
12/162015
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
NS
1262017
4.57
0.58
<0
0.019
0.5
261.3
NA
NA
22
5.04
16.68
<0.50
<0.0028
<0.0038
9/152009
5.66
NA
NA
NA
NA
NA
76.6
NA
NA
NA
4.98
20.68
0.412J
NA
NA
1272012
1.22
NA
0.973
NA
NA
ND
206.1
NA
NA
27
4.94
18.53
0.251J
NA
NA
7/192012
6.67
0.576
0.993
NA
0.17
ND
60.3
NA
NA
27
5.21
25.8
0.3381
<0.23
<0.31
12/32012
6.91
0.535
<5.0
NA
0.00018
NA
168.2
NA
NA
56
4.9
20.2
<5.0
<0.00023
<0.00031
-2/282013
7.35
0.574
0.802
NA
0.00019
ND
125.3
NA
NA
21
5.34
16.7
0.1531
<0.00023
<0.00031
5/302013
7.02
0.474
1.06
NA
NA
ND
98.2
NA
NA
22
4.8
23.04
0.351J
NA
NA
9/112013
13
0.134
1.32
NA
0.00049
0.1
120.4
NA
NA
41
5.09
37.15
4.95
<0.00023
<0.00031
•••EW-9
0327/14
NA
0.17
<.0
NA
<0.0026
NA
NA
NA
NA
NA
NA
NA
<0.50
<0.0028
<0.0038
9252014
1.53
<0.050
<.0
NA
<0.0026
NA
115.1
NA
NA
65
5.61
21.81
0.53
<0.0028
<0.0038
12/182014
2.02
<0.050
<.0
NA
1.2
NA
152.8
NA
NA
55
6.66
15.64
0.44J
<0.0028
<0.0038
6/172015
0.34
<0.050
<.0
NA
4.8
2
50.1
NA
NA
91
5.92
30.69
7.3
<0.0028
<0.0038
9/152015
NA
<0.050
<2.0
NA
5.8
1.2
NA
NA
NA
NA
NA
NA
0.40J
<0.0028
<0.0038
12/172015
NA
<0.050
<2.0
NA
4.1
NA
NA
NA
NA
NA
NA
NA
1.8
<0.0028
<0.0038
3/172016
2.51
<0.050
<.0
NA
6.7
>1.2
-12.2
NA
NA
88
5.98
23.56
1.54
<0.0028
70.0038
2.07
0.32
<2.0
NA
0.42
1.6
215.1
NA
NA
51
5.19
24.80
0.37J
<0.0028
<0.0038
EW-9A
6.29
0.28
<2.0
NA
2.3
ND
138.3
NA
NA
49
<0.50
<0.0028
<0.0038
t6/29/2016
2.53
0.35
1.4 J
NA
3.6
ND
219.1
NA
NA
42
5.38
17.91
<0.50
<0.0028
<0.0038
4.23
NA
NA
NA
NA
NA
114.4
NA
NA
NA
5.07
21.34
0.242J
NA
NA
•••EW-10
6.69
NA
NA
NA
NA
NA
116.1
NA
NA
0.039
5.64
2L72
NA
NA
NA
Page 13 of 34

n
�
Sample ID
>
w
o
m_
Date
b
0
0 0
0 0
0 0
0 0
10 0
0 0
0 0
0 0
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0 0
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o q'
ampiing (mm/dd/w)
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b
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z
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z 3
Vat.
a
a
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°hate
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n
z
z z
z z
z z
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z Y
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Y Y
Y 3Major
Cations
I
a
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z
z Y
z z
z z
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z z
z z
z z
z z
z Y
z z
z z
z Y
z z
Y Y
Y Y
X Y
z
ethane
a
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>>>>>>>>
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a>>>>>>>>>>>>>>
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°r°
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Z>>>>>>>>>>>>>>>>3
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to D\
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otal organic carbon
a
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then.
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a
a a
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Table 3: Analytical Data for Natural Attenuation Parameters 1
9
O
g u
c
o
C
s
oo
C
Units
my
mr/L
m
m�
m�
ANA
mV
m /L
m
s/cmZ
std unit
° C
m
m /L
m
12/320/2
4.05
NA
NA
NA
NA
194.4
NA
NA
138
6.21
18.11
NA
NA
NA
2/252013
2.25
NA
NA
NA
NA
152.8
NA
NA
135
6.22
13.02
NA
NA
NA
5/312013
5.34
NA
NA
NA
NA
78
NA
NA
167
6.39
25.99
NA
NA
NA
9/132013
4.96
NA
NA
NA
NA
NA
213.2
NA
NA
188
6.47
21.49
NA
NA
NA
12/112013
3.2
NA
NA
NA
NA
NA
187
NA
NA
147.9
6.2
13.2
NA
NA
NA
3/272014
3.23
NA
NA
NA
NA
NA
165.5
NA
NA
I15
6.13
12.97
NA
NA
NA
6202014
4.16
NA
NA
NA
NA
NA
138.6
NA
NA
142
5.6-
21.44
NA
NA
NA
9/222014
3.8
NA
NA
NA
NA
NA
119.9
NA
NA
118
5.99
19.43
NA
NA
NA
8405 Camellia
12/192014
2.87
NA
NA
NA
NA
NA
180
NA
NA
95
7.15
13.9
NA
NA
NA
3/162015
4.64
NA
NA
NA
NA
NA
113.1
NA
NA
132
6.13
15.36
NA
NA
NA
6/152015
2.51
NA
NA
NA
NA
NA
131.6
NA
NA
146
6.21
20.43
NA
NA
NA
9/142015
2.51
NA
NA
NA
NA
NA
95.1
NA
NA
130
6.35
20.34
NA
NA
NA
12/14/2015
3.19
NA
NA
NA
NA
NA
129.8
NA
NA
99
6.04
1 16.99
NA
NA
NA
3/142016
2.84
NA
NA
NA
NA
NA
211.9
NA
NA
126
5.51
18.21
NA
NA
NA
6272016
1
NA
NA
NA
NA
NA
103.6
NA
NA
140
6.44
22
NA
NA
NA
9/272016
3.56
NA
NA
NA
NA
NA
141.0
NA
NA
114
6.15
18.55
NA
NA
NA
1262017
5.68
NA
NA
NA
NA
NA
258.5
NA
NA
123
6.19
15.04
NA
NA
NA
12/32012
4.87
NA
NA
NA
NA
NA
203.5
NA
NA
80
5.89
17.15
NA
NA
NA
2/252013
5.18
NA
NA
NA
NA
NA
158.8
NA
NA
78
5.99
11.12
NA
NA
NA
5/312013
6.8
NA
NA
NA
NA
NA
86.9
NA
NA
80
6.21
21.21
NA
NA
NA
9/132013
5.04
NA
NA
NA
NA
NA
203.2
NA
NA
78
6.21
23.82
NA
NA
NA
12/11/2013
5.34
NA
NA
NA
NA
NA
192
NA
NA
77.1
5.81
12.7
NA
NA
NA
3/27/2014
5.82
NA
NA
NA
NA
NA
141.2
NA
NA
72
5.9
149
NA
NA
NA
6/20/2014
6.81
NA
NA
NA
NA
NA
129.4
NA
NA
65
5.43•
23.19
NA
NA
NA
9222014
7.06
NA
NA
NA
NA
NA
152.1
NA
NA
60
5.31
18.1
NA
NA
NA
8408 Camellia
12/192014
5.95
NA
NA
NA
NA
NA
184
NA
NA
55
7.31
11.03
NA
NA
NA
3/162015
10.73
NA
NA
NA
NA
NA
164.3
NA
NA
77
5.62
15.02
NA
NA
NA
6/152015
4.04
NA
NA
NA
NA
NA
86.1
NA
NA
259
7.05
22.96
NA
NA
NA
9/142015
4.78
NA
NA
NA
NA
NA
168.9
NA
NA
200
7.07
19.81
NA
NA
NA
12/142015
6.87
NA
NA
NA
NA
NA
75.3
NA
NA
248
7.34
17.36
NA
NA
NA
3/142016
4.61
NA
NA
NA
NA
NA
171.1
NA
NA
180
6.14
18.55
NA
NA
NA
6272016
4.12
NA
NA
NA
NA
NA
87.2
NA
NA
239
7.02
21.7
NA
NA
NA
9272016
4.93
NA
NA
NA
NA
NA
124.6
NA
NA
154
6.40
18.28
NA
NA
NA
1262017
6.61
NA
NA
NA
NA
NA
267.4
NA
NA
204
6.58
15.8
NA
NA
NA
Page 15 of 34

a
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pd
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a
E
c
�
m
c
m
c
2
H
Units
mWL
m
m /L
m
m
m /L
m
m
m /L
m
m
3/102005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2162006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
7/162009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/112005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/162009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-8A
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4262011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
11/1/2011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/10/2005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
11/122008
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/4/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
42/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/162009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/152009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1072009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/4/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4222010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1021/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4252011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1I22011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/192012
0.0159
0.034
0.0171
<0.01
<0.05
>1.2
ND
ND
ND
ND
NA
121'2012
0.00555
0.00724
0.0251
0.013
<0.05
1.2
ND
ND
ND
ND
NA
%I%N-XB
2/282013
<0.01
<0.01
<0.05
NA
<0.05
ND
ND
ND
ND
ND
NA
5/302013
0.0062
0.00881
0.0121
<0.01
<0.05
ND
ND
ND
ND
ND
NA
9/112013
NA
0.0181
0.0161
0.545
<0.05
ND
ND
1.1
ND
ND
NA
I'I2'2013
0.00703
0.0141
0.013J
<0.05
. <0.05
ND
ND
ND
ND
ND
NA
- 2014
0.012
0.012
<0.30
<0.010
<2.0
1
0.8
ND
ND
ND
NA
6/192014
0.033
0.043
<0.30
NA
<2.0
0.7
0.2
ND
ND
ND
NA
9/252014
0.056
0.09
0.4
0.033
<2.0
NA
NA
0.2
ND
ND
NA
12/16/2014
0.059
0.071
<0.30
0.023
<2.0
0.6
0.2
ND
ND
ND
NA
3/192015
0.071
0.077
<0.30
0.03
<2.0
0.7
0.2
ND
ND
ND
NA
6/172015
0.081
0.09
<0.30
0.034
<2.0
>1.2
>1.2
ND
ND
ND
NA
9/16/2015
0.084
0.086
<0.30
0.019
<2.0
ND
0.15
ND
ND
ND
NA
12/16/2015
0.086
0.086
<0.30
0.031
<2.0
>1.20
0.06
0.6
NA
0.04
2.56
3/17/2016
0.092
0.091
0.271
0.011
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0.7
ND
ND
ND
ND
2.05
6282016
0.11
0.12
<0.30
0.037
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0.7
ND
ND
ND
ND
2.05
9292016
0.11
0.12
<0.30
<0.010
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0.9
0.3
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ND
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1/242017
0.22
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1.1
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1
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Table 3 1 : Analytical Data for Natural Attenuation Parameters User Specified Parameters 1
DSCA ID No.: DC920001
EE
c
m
g
2
rn
Units
mWL
MWL
m
m
-AWL
m
m
mwL
MAIL
m
3/172005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/152009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW 9
7/152010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4252011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
II/12011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/112005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10/72009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/4/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4212010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/132010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
I0202010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4262011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
727/2011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
11/12011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
I252012
NA
NA
0.017J
<0.01
<0.05
NA
NA
NA
NA
NA
NA
7202012
<0.01
0.0123
0.245
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<0.05
ND
ND
0.07
ND
ND
NA
12/32012
<0.002
0.0195
0.016J
<0.01
<0.05
0.8
ND
ND
ND
ND
NA
2272013
0.0436
0.0645
0.014J
0.324
<0.05
0.14
ND
ND
ND
ND
NA
MW IOA
5292013
0.00195J
0.0245
0.0121
<0.01
<0.05
0.2
ND
ND
ND
ND
NA
9/122013
NA
0,0243
0.032J
0.907
<0.05
NA
NA
NA
NA
NA
NA
12/132013
0.0165
0.166
0.0081
<0.05
<0.05
0.14
ND
ND
ND
ND
NA
3262014
0.0031
0.022
<0.30
<0.010
<2.0
0.1
ND
ND
ND
ND
NA
6/17/2014
0.0012
0.02
<0.30
NA
<2.0
0.75
ND
ND
ND
ND
NA
9/252014
0.0018J
1 0,029
<0.30
0.0045J
<2.0
NA
NA
ND
ND
ND
NA
12/162014
.0013J
0.0017
<0.30
0.0040J
<2.0
ND
ND
ND
ND
ND
NA
3/192015
0.0097
0.031
0. 15J
0.0047J
12.0
ND
ND
ND
ND
ND
NA
6/182015
0.0012J
0.017
<0.30
0.0025J
<2.0
ND
ND
ND
ND
ND
NA
9/17/2015
0.0010J
0.013
<0.30
<0,010
<2.0
0.25
ND
ND
ND
2
NA
12/15/2015
0.00091J
0.0054
<0.30
<0.010
<2.0
0.18
0.1
ND
ND
0.04
7.68
3/162016
0.00073J
0.0089
<0.30
<0.010
<2.0
0.95
0.35
ND
ND
ND
8.32
6292016
0.0021
0.011
<0.30
<0.010
<2.0
0.8
0.2
ND
ND
ND
8.32
9282016
0.0023
0.014
0.59
<0.010
<2.0
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0.3
ND
OA
4
12.8
1/252017
0.00082
0.0067
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<0.010
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ND
ND
ND
ND
0.64
ND
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW IOB A
2/6/2006
NA
NA
NA
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NA
NA
NA
NA
NA
NA
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Dt920001
c
_
m
c
g
d
�
s
d
Units
moiL
moJL
m
m
mwL
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m
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3/112005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
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11/112008
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/42009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
42/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10/72009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/420I0
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4212010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1021/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4262011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/272011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
I1/12011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1262012
<0.01
0.138
0.027J
<0.01
<0.05
0.2
ND
ND
ND
ND
NA
7202012
0.00879J
0.0228
0.37
<0.01
<0.05
ND
ND
0.07
ND
ND
NA
MW-IIA
12/32012
0.00217
0.0771
<0.05
<0.01
<0.05
1.2
ND
ND
ND
ND
NA
2272013
<0.01
0.00673J
0.019J
0.491
<0.05
0.08
0.08
ND
ND
ND
NA
5292013
0.000898J
0.0129
0.0191
<0.01
<0.05
ND
ND
ND
ND
ND
NA
9/122013
NA
0.166
0.066
0.698
<0.05
ND
ND
>1.2
ND
ND
NA
12/112013
0.00185J
0.0125
0.015J
<0.05
<0.05
0.08
0.08
ND
ND
ND
NA
3262014
0.0036
0.13
<0.30
<0.010
Q.0
>1.2
ND
ND
ND
ND
NA
6/192014
0.0076
0.1
<0.3
NA
<2.0
>1.2
ND
ND
ND
ND
NA
9232014
0.016
0.094
0.271
0.00691
<2.0
NA
NA
ND
ND
ND
NA
12/162012
0.511
17
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
NA
3/192015
0.009
0.041
0.15J
<0.010
<20
>L2
ND
ND
ND
ND
NA
6/192015
0.056
0.59
<0.30
<0.010
<2.0
11.2
ND
ND
ND
ND
NA
9/17/2015
0.037
0.39
<0.30
0.00241
<2.0
0.9
0.01
0.1
ND
ND
NA
12/152015
0.022
0.15
<0.30
0.0034J
Q.0
>1.20
0.55
ND
ND
0.32
1.92
3/162016
0.0093
0.0097
<0.30
<0.010
Q.0
>1.20
0.55
ND
ND
0.32
1.92
6/29/2016
0.0061
0.022
<0.30
<0.010
<2.0
>1.2
0.3
ND
ND
0.2
2.05
92820I6
0.0083
0.0083
<0.30
0.013
<2.0
>1.2
ND
ND
ND
ND
6.4
I252017
0.003
0.28
<0.30
0.00691
<2.0
>1.2
ND
ND
ND
ND
0.64
3/172005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/162014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/202015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/182015
NA
7.7
<0.30
0.0022J
<2.0
NA
NA
NA
NA
NA
NA
MW 1IB
9/162015
NA
12
<0.30
<0.0I0
Q.0
NA
NA
NA
NA
NA
NA
12/152015
NA
NA
<0.30
0.0034J
Q.0
NA
NA
NA
NA
NA
NA
3/172016
8.7
9.2
<0.30
<0.010
<2.0
NA
NA
NA
NA
NA
NA
6/302016
12
12
<0.30
0.00601
<2.0
NA
NA
NA
NA
NA
NA
9282016
NA
12
<0.30
0.00701
<2.0
>1.2
NA
I
NA
2
6.4
I252017
NA
NA
NA
0.0066 J
NA
NA
NA
NA
NA
I NA
NA

Table 3 1 : Analytical Data for Natural Attenuation Parameters(User Specified Parameters) 1
D p No.: DC920001
�d
-Units
c
e
m
m
m
m
m
m
m
m
m3/102005
NA
NA
NA
NA
NA
NA
NA
NA
*NANA
NA
7/142010
NA
NA
NA
NA
NA
NA
NA
NA
NA
3202015
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/172015
NA
1
<0.30
0.0039J
<2.0
>1.2
ND
ND
ND
ND
NA
9/162015
NA
0.89
0.26J
0.00351
Q.0
1.2
ND
ND
ND
ND
NA
MW 12
12/17/2015
0.43
0.42
<0.30
0.0062J
<2.0
NA
NA
NA
NA
NA
NA
3/17/2016
0.15
0.088
<0.30
<0.010
<2.0
NA
NA
NA
NA
NA
NA
6/302016
0.081
0.14
0.27J
0.00571
<2.0
>1.2
>1.2
ND
ND
ND
ND
9/282016
NA
0.28
<0.30
0.00811
<2.0
>1.2
NA
0.8
NA
ND
12.9
1/252017
0.19
9.5
<0.30
<0.010
<2.0
NA
NA
NA
NA
NA
NA
3/9/2005
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-13
7/14/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/14/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/11/2005
NA
NA
NA
N:\
NA
NA
Jill A
NA
NA
NA
NA
11/12/2008
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/4/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
42/2009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/152009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10/62009
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2/3/2010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4/212010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
7/132010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10202010
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4262011
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1262012
0.0383
0.0574
() 021
200247
<0.05
ND
ND
ND
ND
ND
NA
7/182012
0.0337
0.071
0.029J
<0.01
<0.05
>1.2
ND
ND
ND
ND
NA
11292012
0.0316
0.0352
0.024J
<0.01
<0.05
ND
ND
ND
ND
ND
NA
2/272013
0.0265
0.156
<0.05
0.655
<0.05
0.2
0.05
ND
ND
ND
NA
MW 16
5/302013
0.0374
0.111
0.011
<0.01
<0.05
0.08
ND
ND
ND
ND
NA
9/102013
NA
0.0818
<0.05
1.37
<0.05
ND
ND
045
ND
ND
NA
12/112013
0.0369
0.076
0.0231
<0.05
<0.05
0.2
0.05
ND
ND
ND
NA
3262014
0.035
0.06
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
NA
6/182014
0.042
0.049
<0.30
NA
<2.0
IA
ND
ND
ND
ND
NA
9/25/2014
0.046
0.067
<0.30
<0.010
<2.0
NA
NA
ND
ND
ND
NA
12/182014
0.05
0.066
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
NA
3/192015
0.039
0.05
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
NA
6/182015
0.041
0.3
<0.30
0.0083J
<2.0
>1.2
ND
2
ND
ND
NA
9/152015
0.042
0.048
<0.30
0.00421
Q.0
ND
ND
ND
ND
ND
NA
12/152015
0.039
0.0063
<0.30
0.0070J
<20
>1.20
ND
ND
ND
0.06
1.92
3/172016
0.042
0.077
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
2.56
6/282016
0.041
0.14
<0.30
<0.010
<2.0
>1.2
ND
ND
ND
ND
3
9/292016
0.038
0.048
<0.30
<0.010
<2.0
0.1
0.1
ND
ND
ND
12.8
1242017
0.049
0.17
<0.30
<0.010
<2.0
1.2
ND
ND
ND
ND
0.64
MW-16-A
2/62006
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-16 -B
2/6/2006
NA
NA
NA
NA
NA
NA
NA
NA
NA
I NA
NA

mple
SamID
W
b
Q Y
N
b
13
t3
o
o
T F
a
iS
a
o
0 0
o
o
o
o "'
a
^�
@. ampling Date (mm/ddl),)
�.
d
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
3
8
o
a s
w
m
a^
a
W p
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
Dissolved Manganese
z
z Y
z Y
z z
z z
z z
z z
z z
z z
z z
z z
3
"
W
a a
a a
a a
a a
a a
a a
IZI-IZI-I
a a
a a
a a
a a
a a
as
otalMan anew
g
Y
2
0
9 0
0 0
o w
g o
6- W
w o
z Y
z Y
z z
z z
z z
z z
Y z
z z
z z
Y z
z z
z z
3
0
a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
Ammonia (Nitrogen)
c
0
^e
W
o
o
z oA
90
o
o
g
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
3
Nitrite
m
N
a&
^
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
A
ANNNAA?5.
9zzzzzzzzzzzzzzzzzzzzzzzz3
glade
0
0 0
0 0
0 0
0 0
0
0 o
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
^
v N
z
N a
,v.. `!
ti N
o z
N d
o o—
`,
N
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
z .^.,
a
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
3Total Iron
v
m
^
,y.. `.
,. z^
a
V
o X
N d
o o—
N v
o
N a
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
Y z
a a
z?
a A
Y z
a a
z z
a a
z z
a a
z z
a a
z Y
a a
3 Dissolved Imn
4
A
o—
—-i.i�>NN>^'iraaaaaaaaaaaaairaaaaaaaaaa
^
——
--
o
z Y
z Y
z z
z z
z z
z z
z o
Y z
z Y
Y z
z z
z z
3 oral Ferrous Imn
w
^^
N
N^^
p
a a
o
Y z
a a
z z
a a
z Y
a a
z z
a a
z z
a a
z z
a>
z o
a p
X z
a a
z z
a a
z z
a a
Y z
a a
z z
a a
3 issolved Ferrous Iron
"000
d
o 0
00000
o>>>>>>>>>>>>>>>>>>>>a>>>3
nhophosphate
a
> a
a >
> >
a >
a a
> a
> >
> >
> >
> >
a a
> a
a a
s >
> >
> >
a a
a >
ult to

m
Sample ID
re
w
0
m
-O
r
r
O
N
a
o 0
0 0
0 o
�
T
�
"�
i3 "�
^' '��
o
^�
3 Sampling Date (mm/dd/), )
n
7
0 0
0 0
0 0
0 0
0 0
0 0
8
o o "Z
F
v
0
N
N g
�=
N>
N
N a>>>>>>>>>>>>2
issolved Manganese
A
z
m
m
000�00000000o
o
w o
z
z z
z z
z z
z z
z z z
3
J N
W
a
a a
a a
a a
a a
a a a
tom, oral Manganese
�
A
O0.
N
N O
U O
O O
P. C
O
C �,'
a
z z
a a
z z
a a
z z
a a
z Z
a a
z Z
a a
Z
a
Ammonia
C
O
7
7
m
0 0
o$
z
o o
g o
o
o z
z z
z z
z z
z z
z z
2 3
i[rite
7
'3
o s
a_
g
o
o
P a
a a
a a
a a
a a
a a
a
A
A A
A N
N N
N o
0
0 0
0 0
0 0
o N
o
o
a
+1z
z z
a a
Z z
a a
z z
a a
z z23
a a
a
ulfide
r
-zoozNkpz�p1lzzzzzzzzzzzz3
Now
W
aU
NvatiNtiaaaaaaaaaaaa�
°taltron
a
m
- z
N v
z z
o o
z z
a v
z o
o N
z z
v v
o z
N v
o z
N a
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
z 3
a�
iswNedIron
f0
3
A
A
Z Z
v v
Z Z
o v
Z Z
v o
o Z
v v
�- Z
N v
Z o
v
o Z
a a
Z Z
a a
z z
a a
z z
a a
Z Z
a a
z Z
a a
Z 3
a
Total Ferrous Iron
0 0
0 0
0 o
v o
a d
a o
d >
> >
> >
> >
> >
> >
>
issolved Ferrous Iron
z6zzzzzzzzzzzzzzZZZzzzzz�Orthophosphate
v
v
v v
v v
v v
v o
o a
a a
a a
a a
a a
a a
a
>>>>>>>>>>>>
a>>>>>>>>>>>>�
"Ifite

w
Cpmplc ID
ee
W
N�
m
a
c
o c
a s
o
t3
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i3 A
��
3 c
3
g
tz�
•- 3
ampling Date loon; dd/.
u
2.
O
C
C
C
>
w
a =
> >
> >
> >
> >
> >
> Z.
>
issohed Manganese
z
2
>>>>>>>>>>>>>3
otalManganese
a
2
nl
U
A
w
N N
0 0
'�o� o
S
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
z z
a a
z 3
a
mmonia(Nitrogen)
0
m
o
s
I
m
3
'000
0 0
s 0
0
>
,..
o
o
z z
z z
z Y
z z
z z
z z
z 3
Nitrite
wood
—
IIa a
a a
a a
a a
a a
a a
a
R
?
N N
N N
N N
o 0
0=
o
z z
z z
z z
z z
z z
z z
z 3
�.Ifid,
C
oococo
c°Occa,
aaaaaaaaaaaaa�
51
N>
N `%o
`^
o o
=>>>>>>>>>>>>>R
Total
m
o
v, z
N C
z z
0 a
N N
o
iv "'
z o—
G i.
z
N 0
z z
a a
z z
a a
z Y
a a
z Y
a a
z z
a a
z z
a a
z 3
atom.
issoWed Iron
m
�
rt
z
z
-
z—
a z
o
z z
a a
z z
a a
a a
a a
a a
a a
a
Total FerrouIron
y
z
z
z
z N
z U—
z N
N
z-
o U
z
o z
z z
a a
Y Y
a a
z z
a a
IT
z
a
z z
a a
z 3
a
issolved Ferrous Iron
w
G a
a C
0 0
C O
C G
a 0
> >
> >
> >
> >
> >
> >
>
rthophosphate
tl,
z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z z
z 3
ulfite
a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a a
a

e
a
Sample ID
w
C
ti
••
O
N �
ti. .�..
N �
� .�..
N N
U
t3 t3
� �
w t3
t3 F
N �
� .�.
N �
� 13
� �
N
� !3
� �
p
iJ
" O
e3
c
t3
o i3ZJi3
i3 0
No
ampliog Date (mm/dd/y 1
0 0
0 0
0 22
0
o
°
0 0
0 0
8 0
0 0
0p 0
0 0
p 0p
0�
a o
pp o
0 0
0 0
0 0
0 0
0 0
0
9N
0 0
jpN
i—Ned Man w
K:1UC
7
A
-
z
m
O O
P O
O A
O b
O
O O
O
O
N
O
O N
O U
O O
O A
0 0
0 0
—
pip
-1
QN
A U
N
Total Manganese
Y
R
0 0
0 0
0 0
0
O A
S
O
o
0 o
N o
0 0
o S
O O
o
O O
a
a
O
o o
a
�+
a o
O P
a a
w
O
9
a
c`
c
3
monia(Nitrogen)
7
m
....
�-r
b
fa
0
0
o o
pop
Qo po
c
a
h o
C N
A o
O
n S
O O
n
O
a A
O O
O n
N O
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Table 3 1 : Analytical Data for Natural Attenuation Parameters(User Specified Parameters 1
-
b
9
o
o
e
g12
N
2
@
e
O
Units
m
m /L
m /L
m
m /L
m
m
m /L
m /L
mc1,
m /L
12/32012
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2252013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
5/312013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/132013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/112013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
32 //2014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/202014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9222014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
8401 Camellia
12/192014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/16/2015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/152015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/162015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/14/2016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/272016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/292016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1262017
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/32012
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2252013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
5/312013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/132013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/112013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/272014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6202014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9222014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
8404 Camellia
12/192014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/162015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/152015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/142016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/272016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/292016
NA
NA
NA
NA
NA
NA
NA
. NA
NA
NA
NA
1262017
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Page 31 of 34

Table 3 1 : Analytical Data for Natural Attenuation Parameters(User Specified Parameters 1
,,. DC920001
CS
m
c
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2
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a
Units
ma
m
m
mwL
i m /1,
m /L
m ;1,
m /L
mwL
ma
MAIL
12/32012
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2252013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
5/312013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/13/2013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/112013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3272014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6202014
NA
NA
NA
NA
NA
NA
NA
NANNA
NA
NA
9222014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
8405 Camellia
12/192014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/162015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/152015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
\A
3/142016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6272016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9272016
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1262017
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/32012
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
225/2013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
5/312013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/13/2013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/112013
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3272014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6202014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9222014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
8408 Camellia
12/192014
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/162015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/152015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
9/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
12/142015
NA
NA
NA
NA
NA
NA
NA
NA
NA
3/142016
NA
NA
NA
NA
NA
NA
NA
NA
NA
6/272016
NA
NA
NA
NA
NA
NA
NA
aNANA
NA
9/272016
NA
NA
NA
NA
NA
NA
NA
NA
�NA
4
1262017
NA
NA
NA
NA
NA
NA
NA
NA

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APPENDIX A
GSI Mann -Kendall Toolkit for Constituent Trend Analysis Graphs

MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Evaluation Date: 16-Nov-16 Job ID: I DC920001
Facility Name:1 Former Pro Cleaners Constituent: MW-10B
Conducted By:1 ATC Associates of North Carolina, P.C. Concentration Units: m IL
Sampling Point ID
IP E TCr —�'—
/2014
0.19 0.0016
r53/20/2015
8/2014
0.15
0.0013
5/2014
0.17
0.00088
8/2014
0.18
0.0011
0.11
0.00076
6
6/18/2015
0.11
0.0006
7
9/16/2015
0.11
0.00058
8
12/15/2015
0.08
0.00047
9
3/16/2016
0.093
0,00057
10
6/30/2016
0.031
0.0005
11
9/28/2016
0.024
0.0005
12
13
14
15
16
17
18
20 ---
Coefficient of Vaddon:
Mann -Kendall Statistic (S)
Confidence Factor. + f @ , �,,, • , z
Concentration Trend:
1
0.1
E
c
0 0,01
...... .: _ ..... .—
... -_ ...—._—.._ _.... .-- -- — .....-.._.....- ... — ..._. _._—._..... ----
Y
0,001
--
0.0001
11113 03114 06114 09114 12/14 04115 07115 10115 01116 05116 06116 11116
Sampling Date
Notes:
1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for to 40 samples.
2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<O): >95% = Increasing or Decreasing,
>_ 90 % = Probably Increasing or Probably Decreasing. < 90 % and S>O = No Trend, < 90%, SsO, and COV >_ 1 = No Trend, < 90 % and COV < 1 = Stable.
3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER, The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., Mnm .osi-netcom

MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Evaluation Date: 16-Nov-16 Job ID: DC920001
Facility Name:I Former Pro Cleaners Constituent: MW-11A
Conducted By: I ATC Associates of North Carolina, P.C. Concentration Units: m /L
Sampling Point lD:1
PCE
I TCE
Event �.:
WMIA
• •
1 3/16/2016
0.009
0.0005
2
6/29/2016
0.0029
0.0005
3
9/28/2016
0.0051
0.0005
4
1/25/2017
0.0044
0.0005
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20 _._
_._._ _
Coefficient of Variation: - ' 0.00
Mann -Kendall Statistic (S): t
iii
__ _
Confidence Factor:
Concentration Trend: Stable Stable
- PCE
-TCE
0.1
E
c
0 0,01
:a
m
Y
0,001
c
o I
U
0.0001
01/16 03/16 05116 06/16 08116 10/16_1111 _01117017, �
Sampling Date.==
Notes:
1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for to 40 samples.
2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing,
> 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S__<0, and COV z 1 = No Trend; < 90% and COV < 1 = Stable.
3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann -Kendall Toolkit is available 'as is". Considerable care has been exercised in preparing this software product, however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., www.osi-ngL0m

MANN-KENDALL TOOLKIT
for Constituent Trend Analysis
Evaluation Date: 16-Nov-16 Job ID: I DC920001
Facility Name:1 Former Pro Cleaners Constituent: EW-8
Conducted By: I ATC Associates of North Carolina, P.C. Concentration Units: I m /L
Sampling Point IDl PCE I TCE
Sampling Sampling
Event Date EM • •
1 9/11/2013 0.18 0.0025
2
12/112013
0.47
0.0014
3
3272014
0.43
0.0040
4
6202014
0.28
0.0032
5
9252014
0.29
0.0032
6
12/182014
0.26
0.0025
7
3/202015
0.24
0.0021
8
1/262017
0.098
0.0005
9
10
11
12
13
14
15
16
17
18
19
20
CoefficientofVariation: t
Mann -Kendall Statistic IS):
Confidence Factor:
Concentration Trend: Stable I Prob. Decreasingi
J
0.1
- ---
c
O 0.01
L
al 0.001
C_.. _...
U
0.0001 --1'
05113 11113 06114 12114 07115 01116 _( /� 03/17 091117,1,v$
Sampling Date '?
Notes:
1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for to 40 samples.
2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing;
z 90% = Probably Increasing or Probably Decreasing, < 90% and S>0 = No Trend; < 90%, S__<0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable.
3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales,
Ground Water, 41(3):355-367, 2003.
DISCLAIMER: The GSI Mann -Kendall Toolkit is available 'as is'. Considerable care has been exercised in preparing this software product; however, no party, including without
limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, orcompleteness of the information contained herein, and no such
party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in
this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein.
GSI Environmental Inc., ".asi-ag=

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000000-000020-026408
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GENERAL REVENUE FUND
5.6815 14,179 14,179
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TRANSPORTATION/ROADS
1.1000 14,179 14,179
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POLK COUNTY SCHOOL BOARD
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LOCAL CAPITAL IMP
1.5000 14,179 14,179
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CITY OF WINTER HAVEN
5.7900 14,179 14,179
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0.4512 14,179 14,179
$0
s(100
SOUTHWEST FLORIDA WATER MGMT
0.3317 14,179 14,179
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Penalty
a0000 0 0
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20.1514 Total Taxes
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