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WQ0004936_Complete File - Historical_20200928
�1_cps�"jj React Environmental Services, Inc. P.O. Box 33363 * 6901 Kingsessing Avenue, Philadelphia, PA 19142 (800) 326-2439 / Fax (215) 729-1557 March 18, 2005 State of North Carolina Department of Environment and Natural Resources Division of Water Quality Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Attn: Mr. Ervin Lane [via email: ervin.lane@ncmail.net] RE: Texfi Industries, Inc. New Bern Facility New Bern, Craven County, NC Permit Number: WQ0004936 Mr. Lane: As we discussed, React Environmental Services, Inc. has been contracted by The Recovery Group to provide environmental consulting services for the above -referenced site. The Recovery Group is in receipt of correspondence dated February 17, 2005 from the Division of Water Quality office pertaining to the expired discharge permit related to the groundwater remediation system at the New Bern facility. The Recovery Group is committed to addressing your request for permit renewal or rescissi n, but respectfully requests a 30-day deadline extension to determine the most appropriate course of action. Based on our telephone conversation on March 16, 2005, I trust that your office can accommodate this request. If not, please let me know immediately. If you have any questions or require additional information, please contact me at (215) 729-2777008 or via email at JPlucinski(a,reactenv.com. Thank you very much for your assistance in this matter. Sincerely, React nvironmental Services, Inc. Jason D. Plucinski Project Scientist CC. Mr. Bruce Erickson The Recovery Group 270 Congress Street Boston, Massachusetts 02210 [via facsimile 617-483-9804] k i r. Je . Naples, Jr. President O:Vob Numbers 4501-5000\4876 Recovery Group, ph I, Texft Ind., New Bern, NC\NewBern -Request for permit deadline extension 3-18-05.doc Michael F. Easley, Governor William G. Ross Jr., Secretary North Carolina Department of Environment and Natural Resources Alan W. Klimek, P.E. Director Division of Water Quality February 17, 2005 The Recovery Group Attn: Mr. Bruce Erickson 270 Congress Street Boston, Massachusetts 02210 CERTIFIED MAIL RETURN RECEIPT REQUESTED 7002 2410 0003 0272 8965 Subject: Request for Permit Renewal Groundwater Remediation Permit Texfi Industries Inc. -New Bern Permit Number. WQ0004936 Craven County Dear Mr. Erickson, As of this date, our records indicate that the above referenced permit, which was issued on May 31, 1996 and expired on April 30, 2001, has not been renewed. You also have not responded to the letter mailed to you on December 7, 2004 requesting permit renewal. It is both a condition of your permit and required by 15A NCAC 21-1.0211 to request a renewal of your permit at least 180 calendar days prior to its expiration date. Failure to apply for pemut renewal, and continued operation of your facility without an active permit may result in an enforcement action by the Division, in accordance with North Carolina General Statute 143-215.6A to 143-215.6C. Therefore, it is imperative that you submit a permit renewal application for review as soon as possible. Although the Underground Storage Tank (UST) Section may have informed you that groundwater remediation is temporarily not being directed at your facility due to Session Law 2004-124, you are still required to submit either a permit rescission request or a permit renewal application to the Aquifer Protection Section (APS). To comply with the permit requirements set forth in your permit and 2H .0211, the APS is making the following options available to you: 1. Permit Renewal. When you apply for and receive a renewal, operation of the groundwater remediation system will be permitted to continue. As such, annual fees, all requirements for sampling and annual reports, and any operation and maintenance specified in your previous permit will be required. 2. Pen -nit Renewal with Suspended Actions. Under this option, you must still apply for a permit renewal. However, you may indicate that operation of the remediation system has been suspended, but you desire to maintain the permit should the need arise to restart the system. As such, operation of the remediation system will be prohibited until such time that a permit modification is obtained from the Division allowing operation of the system. Under the "Permit Renewal with Suspended Actions" option, all monitoring and annual reports will be suspended until otherwise notified. Infiltration galleries will be directed to be winterized as a permit condition, as well as temporary abandonment of any monitoring wells in accordance with 15A NCAC 2C .0113(a). Annual fees will still be required, but may be reimbursed under the NC State Trust Fund as a directed cost. This option allows you to keep your system inactive until remediation is once again directed by the UST Section. At that point, you will need to request a modification to your permit to activate your system. Noy` Carolina Awma!!y Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Phone (919) 733-3221 Customer Service Internet: http://h2o.enr.state.nc.us 2728 Capital Boulevard Raleigh, NC 27604 Fax (919) 715-0588 1-877-623-6748 Fax (919)715-6048 An Equal Opportunity/Affirmative Action Employer — 50% Reayded/10% Post Consumer Paper • 3. Permit Rescission. To apply for a rescission, you must request your permit be rescinded in writing. Upon receipt of your request, you will be directed to close your infiltration gallery in accordance with the July 8, 2003 policy "Guidelines for the Closure of Infiltration Galleries and the Abandonment of Injection Wells at Groundwater Remediation Sites." This policy is available at the website located at http://gw.ehnr.state.nc.us/ under the Publications link. Any abandonment of wells, either temporarily or permanent, must be in accordance with 15A NCAC 2C .0113. Reactivation of the subject remediation system will require a new permit should you elect to have your permit rescinded. Failure to respond to this notice within thirty (30) calendar days from the date of this letter shall result in a Notice of Violation and a civil penalty. If you choose to renew your permit, please complete the Groundwater Remediation Permit Application at the website http://gw.elinr.state.nc.us/ under the Publications link and submit to the following address. Written requests to have your permit rescinded may also be submitted to the address listed below: NCDENR-DWQ Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 If you have any questions concerning the renewal/rescission of your permit, please contact Ervin Lane at (919) 715-6168, or email him at ervin.laneAncmail.net. If you have any questions concerning reimbursement of your system, please contact George Matthis with the UST Section at (919) 733-1332. cc: Washington Regional Office — APS APS Central Files UST Section Sincerely, Debra J. Watts, Supervisor Groundwater Protection Unit o f W ATF9 Michael F. Easley, Governor \OCR QG William G. Ross Jr., Secretary 6 North Carolina Department of Environment and Natural Resources 5: - I Alan W. Klimek, P.E. Director Q 'C Division of Water Quality September 29, 2004 DANE VINCENT OWNER/PERMITTEE PO Box 31728 RALEIGH, NC 27622 Subject: Request for Permit Renewal Groundwater Remediation Permit Texfi Industries Inc. -New Bern Permit Number. WQ0004936 Craven County Dear Mr. Vincent, As of this date, our records indicate that the above referenced permit, which was issued on 5/31/1996 and expired on 4/30/2001, has not been renewed. It is both a condition of your permit and required by 15A NCAC 2H .0211 to request a renewal of your permit at least 180 calendar days prior to its expiration date. Failure to apply for permit renewal, and continued operation of your facility without an active permit may result in an enforcement action by the Division, in accordance with North Carolina General Statute 143-215.6A to 143-215.6C. Therefore, it is imperative that you submit a permit renewal application for review as soon as possible. Failure to respond to this notice within sixty (60) calendar days from the date of this letter shall result in a Notice of Violation and a civil penalty. Please submit a completed Groundwater Remediation Permit Application which is available online at http://gw.ehnr.state.nc.us/. The Groundwater Remediation Permit Application is in the process of being revised and the address indicating where to send the completed application is not current. Therefore, please submit the enclosed application to the following address. NCDENR-DWQ Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Please note that if the groundwater remediation system has reduced contaminant levels below the groundwater standards defined in 15 NCAC 2L .0202 and/or is no longer active, the option to request permit rescission is available. Written requests to have your permit rescinded can also be submitted to the address listed above. Thank you in advance for your cooperation and timely response. If you have any questions, please contact Ervin Lane at (919) 715-6168, or email him at ervin.lane@ncmail.net. Sincerely, bra ). W-�Jds Debra J. Watts, Supervisor Groundwater Protection Unit cc: Washington Regional Office — Aquifer Protection Section Nw° Carolina Aquifer Protection Central Files YattlCal; Aquifer Protection Section 1636 Mail Service Center Raleigh, NC 27699-1636 Phone (919) 733-3221 Customer Service Internet: http://h2o.enr.state.nc.us 2728 Capital Boulevard Raleigh, NC 27604 Fax (919) 715-0588 1-877-623-6748 Fax (919) 715-6048 An Equal Opportunity/Affirmative Action Employer - 50% Recycled/10% Post Consumer Paper AQUATERRA Environmental Consultants August 6, 1992 Mr. Dana Bolton Permits and Engineering Unit North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Water Quality Section Post Office Box 27687 Raleigh, North Carolina 27611-7687 Reference: Non -Discharge Permit No. W00004936 Texfi Industries New Bern, North Carolina Aquaterra Job No. 778 Dear Mr. Bolton: ��Wai�R �E��10N Nc, Jack Floyd and I met on August 5, 1992, to discuss the Texfi Industries (Texfi) Non -discharge Permit modification. Two modifications have been proposed for this permit: (1) eliminating the metals treatment system and (2) reducing the number of recovery wells. Metals Treatment System It is my understanding that Mr. Floyd concurs with eliminating the metals treatment system provided the zinc and nickel concentrations in the effluent are monitored on a regular basis. Reducing the Number of Extraction Wells Based on the pumping test data, Mr. Floyd concurs with reducing the number of extraction wells. If a sufficient capture zone is not developed, the number of extraction wells would be increased. Mr. Floyd has expressed concern about whether the infiltration trench is located in the capture zone of the recovery system (i.e., forms a closed -loop system). Based on the water level data collected since 1988, it appears that the infiltration trench is located hydraulically upgradient from the recovery well system, which does create a closed -loop system. To determine whether the infiltration trench is within the recovery well system's zone of influence, we discussed measuring water levels in all on -site monitoring wells monthly to develop a data base of these measurements. I suggest incorporating six monthly water level measurements into the permit modification . As requested by Mr. Floyd, a map illustrating the locations of the recovery wells relative to the infiltration trench is enclosed. A map showing the capture zone will be generated and submitted to DEM once the ground water remediation system OPT operational and the data ids obtained. Corporate O ce har otte Office Greensboro Office P. O. Box 50328 P. O. Box 668107 P. O. Box 16241 Raleigh, NC 27650 Charlotte, NC 28266-8107 Greensboro, NC 27416-0241 (919) 859-9987 (704) 525-8680 (919) 273-5003 FAX (919) 859-9930 FAX (704) 527-2792 FAX (919) 271-8138 Texfi Industries L2777-92 August 6, 1992 Page 2 Desire to Initiate Remediation I want to reemphasize Texfi's desire to resolve this matter. As you are aware, Texfi cannot initiate ground water remediation until approval is granted for the March 3, 1992, permit modification request. The ground water remediation system without the metals treatment system was installed in April in accordance with Non -Discharge Permit No. W00004936; however, no remediation has been permitted to occur during the past 5 months. In addition, failure to initiate the restoration of the impacted ground water may result in contaminant plume migration. Texfi has been very willing to comply with the remediation program your agency has required and cannot understand the lengthy delay in allowing them to fulfill this request. Your help in resolving this issue will be greatly appreciated. If you have any questions, please call us at (919) 859-9987. Sincerely, AQUATERRA, INC. ? #Pohizc Kenneth B. White Project Manager /� 46• i1�ze� Kirk B. Pollard Senior Project Manager cc: John Tate —Southridge Corporation Jack Floyd—DEM, Raleigh Central Office L2777-92/KB W/KBP/pj c AQUATERRA Infiltration Trenc (3' x 400') RW-8 e ❑ RW-11 RW-7A RW-7 >RW-4 A Legend e Shallow Recovery Well Location 0 Deep Recovery Well Location Intermediate Recovery Well Location AQUATERRA , INC. Author DLG Drawing 778-2 Layers 0,1 Date 06-25-92 Title Recovery Well Location Map . d ab Raleigh, Greensboro, Charlotte Job No. Revision Figure Scate Project Texfi Incorporated N O R T H C A R 0 L I N A 778 8-6-92 1 1" = 200' New Bern, North Carolina to •; W a Z a r.• Zis v ► r.a is August 10, 1992 MEMORANDUM TO: Don Safrit -1 m(X is Bob Cheeky FROM: Jack Floyd SUBJECT: modification of Permit No. WQ0004936 Texfi Industries Groundwater Remediation System Craven County WQ0004936/GW92127 Dana Bolden : Review Engineer The Groundwater Section has reviewed the subject modification request to abandon most of the recovery wells and eliminate the use of the metals recovery device. The original permit was issued September 23, 1991 for a 60 GPM groundwater remediation system. Since the initial site assessment the consultant has concluded that the eleven recovery wells are unnecessary. Capture zones for the five remaining recovery wells are adequate for remediation purposes. The metals concentrations were never found in such great quantities as to require removal before reinfiltration. Therefore, the' Groundwater Section recamends that the permit be modified to: 1) Abandon all wells except RW-4a, RW-7a, RW-8, RW-10a, and RW-11, and 2) Eliminate the metals treatment unit. These recommendations are contingent upon inclusion of the following conditions: 1) All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 2) The groundwater recovery, treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Regional Office. 3) The influent and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) mcnths and quarterly thereafter for the parameters specified below: Volatile Organic Compounds - by Method 1 or Method 2 below Method 1: Method 6230D (Capillary - Column), "Standard Methods for the Examination of Water and Wastewater", 17th edition, 1989 Method 2: Method 502.2 "Methods for the Determination Organic Ccmpounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 4) The influent of the system shall be sampled quarterly for the following parameters: Total Nickel Total Zinc 5) The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 27611-7687 within 30 days of sample collection. 6) After data has been collected for one full year, the permittee may request a reduction in the above monitoring requiremdnts. 7) The permittee shall submit a detailed map depicting the capture zone of each recovery well within 1 year of permit issuance and submit it to the Groundwater Section. If there are any questions please let me know. BC/JF:ja/92127. cc: Willie Hardison Central Files Permit Files State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director September 27, 1995 Dane Vincent, Vice President of Finance, Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Subject: Application No. WQ0004936 Additional Information Request Texfi Industries, Inc. New Bern Facility Groundwater Remediation Facility Craven County Dear Mr. Vincent: The Permits and Engineering Unit has completed a preliminary review of the subject application. It has come to our attention that the subject permit is due to expire on August 31, 1996. In accordance with Permit Condition No. VI 10, a renewal request is required 180 days prior to expiration. Therefore, the renewal request would be due to the Division no later than February 28, 1996. If Texfi Industries, Inc. would like, in addition to the amendment request, the Division could also proceed with the renewal of the subject permit. No additional fee would be necessary at this time. Please let me know as soon as possible if you would like the Division to renew this permit at this time. If there is no response by October 26, 1995, the Division will continue with the amendment request by will not renew the permit at this time. If you have any questions on this matter, please call me at (919) 733-5083 ext. 547. Sincerely, Michael D. Allen Environmental Engineer State Engineering Review Group cc: Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Bob Cheek, Groundwater Section, Central Office Aquaterra, Inc. Permit File WQ0004936 P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director December 7, 1995 Dane Vincent, Vice President of Finance & Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Dear Mr. Vincent: .A4 IDEHNR Subject: ca � 3 cs rn r)l � x< OD om .rc Application No. WQ000�636 Additional Information RTque 7 Texfi Industries, Inc. ` 1 New Bern Facility n Groundwater Remediation Facility Craven County The Division of Environmental Management's Permits and Engineering Unit and Groundwater Section have completed a preliminary engineering review of the subject application. The following items must be addressed before we can complete our review: Information requested by the Groundwater Section 1. See attached MEMO from Ken Pohlig. Information requested by the Permits and Engineering_Unit 1. The Division is still waiting fu. a response to our September 27, 1995 letter. Refer to the subject permit application number when providing the requested information. Please submit four (4) copies of all requested information to my attention at the address below. Also, please note that failure to provide this additional information on or before December 7, 1995 will subject your application to being returned as incomplete, in accordance with 15A NCAC 2H .0208. If you have any questions regarding the information requested by the Groundwater Section, please call Ken Pohlig at (919) 715-6161. If your questions concern the information requested by the Permits - and Engineering Unit, please call me at (919) 733-5083 extension 547. Sincerely, �WL Michael D. Allen Environmental Engineer State Engineering Review Group cc: Washington Regional Office, Water Quality Washington Regional Office, Groundwater Ken Pohlig, Central Office, Groundwater Aquaterra, Inc. Permit File WQ0004936 P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION November 29, 1995 u 1 u (1) 7WMIJ► l To: Michael Allen Through: �,(�l Bob Cheek From: Ken Pohlig ®•P' Subject: Texfi Industries Groundwater Remediation Craven County WQ0004936/GW95214 The Groundwater Section has conducted a preliminary review of the subject application, and cannot recommend issuence of the permit admendment without the following information and/or clarification: (1) Cross -sections of the surficial aquifer and Castle Haynes aquifer formations, showing recovery and monitoring well screens, in addition to the static groundwater levels in both aquifers and the contaminant contours in both aquifers. (2) Plan view maps of the contaminant contours in both surficial aquifer and Castle Haynes aquifer. (3) A comparison of chemical analyses from (a) the surficial aquifer influent water, (b) the deeper Castle Haynes aquifer influent water, and (c) the effluent of the treatment system. This chemical analysis comparison should include all organic/inorganic contaminants, in addition to what would be considered a normal water quality suite of constituents (TDS, pH, chloride, manganese, iron, etc.). The purpose of this comparison is to verify that after the surficial waters and Castle Haynes waters have been treated and mixed, the effluent water quality injected back into the Castle Haynes aquifer does not degrade the natural water quality of the Castle Haynes aquifer. This anaysis should consider not only the organic contaminants, but also the natural water quality difference between the two aquifers. For example, if the surfical aquifer is high in iron, but the Castle Haynes aquifer is low in iron, then the injection will degrade the Castle Haynes quality with regards to iron. (3) From the above chemical analysis, if the Castle Haynes aquifer is determined to be degraded sufficiently, then it may be necessary to separate the surficial water treatment system from the Castle Haynes water treatment system. (4) An analysis of the chemical components/products to be expected in the effluent from the addition of acetic/hydroxyacetic acid to the wastestream. If there are any questions please call me at 715-6161. cc: Willie Hardison Permit Files kop/TEXFI-I.DOC State of North Carolina Department of Environment, Health and. Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director September 27, 1995 Dane Vincent, Vice President of Finance, Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Dear Mr. Vincent: Ak4 07A I DEHNF� Subject: Application No. WQ0004936 Additional Information Request Texfi Industries, Inc. New Bern Facility Groundwater Remediation Facility Craven County The Permits and Engineering Unit has completed a preliminary review of the subject application. It has`come to our attention that the subject permit is due to expire on August 31, 1996. In accordance with Permit Condition No. VI 10, a renewal request is required 180 days prior to expiration. Therefore, the renewal request would be due to the Division no later than February 28, 1996. If Texfi Industries, Inc. would like, in addition to the amendment request, the Division could also proceed with the renewal of the subject permit. No additional fee would be necessary at this time. Please let me know as soon as possible if you would like the Division to renew this permit at this time. If there is no response by October 26, 1995, the Division will continue with the amendment request by will not renew the permit at this time. If you have any questions on this matter, please call me at (919) 733-5083 ext. 547. Sincerely, Michael D. Allen Environmental Engineer Srste E^^;^eer;"^ . h.. ,.b w cc: Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Bob Cheek, Groundwater Section, Central Office Aquaterra, Inc. Permit File WQ0004936 P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION October 31, 1995 MEMORANDUM TO: Ken Pohlig,Permits and Compliance Unit THROUGH: Willie Hail'ison, Regional Groundwater Supervisor Washington � Regional Office FROM: Guy PearPe,H ydrogeologist Washington Regional Office SUBJECT: Non -Discharge Permit Amendment Texfi Industries, Inc. - New Bern Facility Groundwater Remediation System - Craven Co. WQ0004936 GW95214 n i The Washington Regional Office has reviewed the subject amendment request. Based on our review, the following comments are submitted for your consideration: 1. Although the applicant indicates in Section IV - DESIGN INFORMATION FOR INJECTION WELLS, that the injection well will discharge into the same aquifer from which the contaminated groundwater was extracted, a review of the design plans indicates that groundwater recovery wells RW-4, RW-7, and RW-10 are screened in the shallow Yorktown formation surficial aquifer system, and that only recovery well RW-11 is screened in the confined/semi- confined Castle Hayne Aquifer. Since the proposed injection well will be screened only in the Castle Hayne Aquifer, it appears that some of the treated shallow groundwater will be discharged into the Castle Hayne Aquifer. Our office is concerned that malfunctions in the treatment system due to equipment failures and/or undiscovered "slugs" of contaminated surficial groundwater that exceed the treatment capacity of the two (2) air strippers could result in further contamination of the Castle Hayne Aquifer. 2. Due to the relatively high iron concentration in the groundwater in this area, which quickly clogs up granulated carbon filtration systems, the existing treatment (air strippers) does not include carbon filtration prior to injection. Carbon Filtration also provides a "safety factor" in that it removes any contaminants that are not removed by the air strippers. While we understand the economic rational for not providing carbon filtration, we are concerned that any contaminants that are not removed by the air strippers (see comment No. 1 above) will be injected into the Castle Hayne Aquifer. Memo to Ken Pohlig Texfi Industries, Inc. October 31, 1995 Page Two 3. The plans indicate that the groundwater recovered from the Castle Hayne Aquifer (recovery well RW-11) AND the groundwater recovered from the shallow groundwater recovery wells (RW-4, RW-7, and RW-10), minus the roughly 2 gpm that will be combined with the groundwater recovered from RW-8 (roughly 10 gpm) and disposed of via the existing infiltration gallery, will be injected into the Castle Hayne Aquifer. Although the applicant states in Section 2.3 of the permit application that "Complete capture was shown to occur at a recovery rate of 30 gpm (see Appendix C), while the recharge rate remained at 50 gpm.", we do not understand how a system that injects more groundwater into the Castle Hayne Aquifer than is recovered from the Castle Hayne Aquifer can function as a "closed loop system". Further clarification is needed in this area. 4. The applicant indicates in Section 3.2 that bacterial and chemical precipitates have hindered the operation of the existing remediation system, and proposes to treat the recovery wells and the injection well with hydroxyacetic acid on a periodic basis. While we do not necessarily object to this proposal, the applicant should provide additional discussion of: a) how the "mixture" recovered from the wells after treatment will be neutralized, and; b) what effects, if any, will the mixture (including minerals dissolved by the acid) have on the treatment system, the injection well, and the Castle Hayne Aquifer. In closing, we are not prepared to recommend approval of the amendment request at this time. Upon receipt of additional information addressing the above concerns, our office will re- evaluate this proposal and inform you of our position by memo. If you have any questions, or wish to discuss this matter further, please contact me at any time. cc: WaRO Files DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION May 10, 1996 [UT035(ili_AN�l�lul TO: Brian Wagner, Permits and Compliance Unit Central Office Groundwater Section THROUGH: Willie Hardison, Regional Groundwater Supervisor Washington Regional Office FROM: Guy Pearce, Hydrogeologist "= Washington Regional Office =c SUBJECT: Non -Discharge Permit Renewal Application for Texfi Industries, Inc. Groundwater Remediation - Craven County WQ0004936 GW96057 .. The Washington Regional Office has reviewed the subject renewal application for the continued operation of a groundwater remediation system. Based on our review, the following comments are submitted for your consideration: 1. The system currently consists of wells (RW-4a, RW-7a, RW-8, RW-10 recovery rate of roughly 60 gpm. wells RW-4a, RW-7a, RW-10 and RW-11 and contaminated groundwater from absorption. The treated groundwater infiltration gallery. five (5) groundwater recovery and RW-11) with a combined Contaminated groundwater from is treated by an air stripper, RW-8 is treated by carbon is disposed of in a 3' by 400' 2. The existing permit only requires quarterly influent/effluent sampling, and does not specify the number of monitoring wells that should be sampled or sampling frequency. Although there are as many as twenty-eight (28) wells (both recovery and monitoring) at the site, several of the wells are not usable because their shallow depth results in the wells being dry for extended periods. In addition, several wells are either located upgradient of the plume, or are in close proximity to other monitoring wells, and are not really needed to monitor system performance. We recommend the new permit require semi-annual sampling of the following wells: MW- 3 (upgradient), MW-4, MW-10a, MW-11, MW-12, MW-13, MW-14, RW-4a, RW-7a, RW-8, RW-10 and RW-11. Analysis should be by EPA Method 6230D or Method 502.2 (as required in the current permit). I have attached a site map showing the locations of all the wells with circles around the wells we suggest be sampled. If you have any questions, or wish to discuss this matter further, please contact me at any time. cc: WaRO Files GROUNDWATER SECTION GW # DI DN OF ENVIRONMENTAL MANAGEMI RECORD OF WASTE DISPOSAL PERMIT APPLICATION REVIEW REVIEW BY DATE M_� . 1121 ( FIELD INVESTIGATION? (Y & FACILITY NAME COUNTY C-MOCV, LOCATION 1 0.5 r,,;le sn. .Jrs�_ __� Qv.,__ NC, �.�.�., S_6 o.A NCS1Z 1309 (� .` AWcU J+�0 TYPE OF DISPOSAL SYSTEM (LAGOON, ETC.) i «, ��,.^� i i�oa&DESIGN CAP. (GPD) DESCRIPTION OF FACILITY y cnQllb� 2W re-coyaw weeks. 1 cluo (r 4Acatir) t nV r.' N k'c WASTE SOURCE: MUN. SLUDGE MUN. W. WATER: PRIMARY SECONDARY TERTIARY IND. SLUDGE -IND. WELL WATER *"- -OTHERS: �' "ram, Grow,4�Lzc&Ar DISTANCE FROM WASTE SOURCE TO NEAREST: STREAM- 1000 FT., WELL7500 FT. FOR WELL: TYPE OF USE none_ kou.)v` , DEPTH none_ knowt-PUMP RATE (EST.) KJA WHAT DESIGN CONDITIONS WILL RED UCE44*RSA1rCHANCE OF GW CONTAMINATION: AAr. EAr• 0JILl e� Csrloo w. WHAT NATURAL SITE CONDITIONS WILL REDUCE/INCREASE CHANCE OF GW CONTAMINATION: NIA - G,r-ouwAL-p- Z _ 1. __ . _ L I A DEPTH TO: BEDROCK > 1000 FT., SEASONAL HIGH W.T. ; FT., ANNUAL W.T. FLUX a-3 f FT. SURFICIAL AQUIFER i BEDROCK/ARTESIAN AQUIFER GEN. LITHOLOGY '11�tt "A 'La - �s'C\n 'T HYD. COND. 1 - 3 FT./DAY MEASURED a DAY MEASURED ESTIMATED ESTIMATED THICKNESS 1 2 5 FT. (*� SQc. A tA NU. OF MONITER WELLS: PROPOSED: UP DOWN ; EXISTING: UP FROM WORKSHEET: SITE NUMERICAL DESCRIPTION= - DOWN _* Q&'Nm '�: T 1 2 3 4 5 6 6A 613 SITE GRADE (HYDROGEOL.) = SITUATION GRADE= PROPOSED SAMPLING SCHEDULE & PARAMETER(S): GW HAVE THERE BEEN ANY EXCEEDANCES OF THE GROUNDWATER STANDARDS? YES NO�o `�ec� HAS ANY ENFORCEMENT ACTION BEEN TAKEN? YES NO DATE OF ACTION: BRIEF SUMMARY OF ENFORCEMENT ACTION TAKEN: N / A REMARKS/ RECOMMENDATIONS (Continue on reverse, if necessary): .. A—c�nn& Q0w,Ty\2n_L GW-48 Revised 04/94 HYD. REGIONAL SUPERVISOR QD i ub to `�. ° /•�� / • // �• 1 J°J 111 d ; • t �� � y o •• z /i ! o •I ° o o� � �e \ _v / fj �. \` by \ i tr '•� � �__- - 2 ° ... t .. . y �I !; 311 N W ashingto j. 51/ 3trbsEs4fon _, • - 1 • 2SITE _,moo -4 cb < v 17 - 2 , • JI \ !/ `/Z5 i I per, �1 7'30" 307 308 2 570 000 FEET ��^`-=_ v 310 5' 1 SCALE 1:24 000 2 0 1 MILE 100 0 1000 2000 3000 4000 5000 6000 7000 FEET NE/4 NEW BERN 15' QUADRANGLE 1 .5 0 1 KILOMETER 35077-81-TF-024 Author Drawing Layers Date Title Site Location Map ERnainmerina. eivaTerraJob NPo.JBRevision Figure 9/14/95 Scale Project Te>d huh atries, Inc. enc.e A CREAT LAKES CHEMICAL CORPORATION COMPANY 4401900 1 As Shown New Baia, North Carolina ' As ff AIF ib MW-1 (�E) � MW-2 Existing Treatment System C Infiltration Gallery 8 M W-5 M W-4a MW-e RW-1 Manufacturing Building MW-9 Qb MW-91 MW-2a® i�mzi3 ® Q� MW-14 n ®RW-11 MW-8 RW-4a MW-11 ®RW-1 ® RW-2 0RW-3 �� MW-10a ® RW-5 ® RW-8 RW-7a RW-7 Legend 0 Shallow Monitoring Well ® Recovery Well © Deep Monitoring Well Bosch Boulevard ® Proposed Injection Well uthor Drawing Layers Dote t e n at n e u r 1 n o, 1 n C.� LSG 44019-2 0,1,2 "2-93N�EOQUaTerra Site Map ob No. Revision igv.re Scale Project Texfi Industries, Inc. A GREAT LAKES CHEMICAL COR30RATION COMPANY 4401900 9-15-95 2 1 ° = 200' New Bern, North Carolina CORPORATE \-� 7Clu7TLrr7 POST OFFICE BOX 37579 HEADQUARTERS: NC • 27627-7579 • (919) 859-9987 • FAX (919) 859-9930 A GREAT LAKES CHEMICAL CORPORATION COMPANY October 24, 1994 Ms. Elizabeth Morey North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Water Quality Section Post Office Box 29535 Raleigh, North Carolina 27626-0535 Reference: Non -discharge Permit Modification Permit No. W00004936 Texfi Industries New Bern, North Carolina Aquaterra Job No. 4101003 Dear Mr. Morey: Aquaterra, Inc. (Aquaterra) is assembling a request to modify Texfi Industries' existing Non -discharge Permit to include an injection well. As part of the permit modification package, Aquaterra is addressing the maintenance aspect of the proposed injection well and the existing recovery wells. We would like to determine the Division of Environmental Management's position on the chemical treatment of wells prior to the submission of the permit modification package. It is our understanding that the use of hydrochloric acid and sodium hypochlorite solutions are allowed. However, the resulting formation of chloroform is an issue of concern. Based on the enclosed references, Aquaterra would like to propose treating the wells with an organic acid (i.e., hydroxyacetic acid (CH2OHCO&I) or acetic acid (CH3CO2H)) to remove the chemical and biological precipitates from the well. The advantages for using an organic acid as compared to a chlorinated solution are toxic compounds are less likely to form, iron and manganese deposits are chelated, and safer to use. ENVIRONMENTAL CONSULTANTS Texfi Industries 410801 October 24, 1994 Page 2 Specifically, the proposed treatment program consists of adding 1 gallon of 70 percent hydroxyacetic acid per 10 to 15 gallons of water standing in the well. The mixture will be agitated in the well with a surge block every 2 hours for 8 hours. The material will be purged from the wells and transferred to the treatment system for neutralization, and the process will be repeated. We look forward to receiving your reply. If you have any questions or need additional information, please contact us at (919) 859-9987. Sincerely, AQUATERRA, INC. k6ol�t4--k 31-2,Vltt Srz- Kenneth B. White, Sr. Project Manager Bryson D. Trexler, Jr., Ph.D., P.G. Senior Hydrogeologist/Program Manager 410801/KBW/pjc cc: Mr. Max Cochran - Texfi Industries Mr. John Tate - Southridge Corp. Mr. Harold Bynum - Smith, Helms, Mullis & Moore Hawley's Condensed Chemical Dictionary TWELFTH EDITION Revised by Richard J. Lewis, Sr. ® VAN NOSTRAND REINHOLD COMPANY New York Copyright © 1993 by Van Nostrand Reinhold Library of Congress Catalog Card Number 92-18951 ISBN 0-442-01131-8 All rights reserved. Certain portions of this work © 1930, 1920, 1919 by The Chemical Catalog Co., Inc., and 1987, 1981, 1977, 1971, 1966, 1956, 1950 by Van Nostrand Reinhold. No part of this work covered by the copyright hereon may be reproduced or used in any form or by any means —graphic, electronic, or mechanical, including pho- tocopying, recording, taping, or informational storage and retrieval systems —without written permission of the publisher. Printed in the United States of America Published by Van Nostrand Reinhold 115 Fifth Avenue New York, NY 10003 Chapman and Hall 2-6 Boundary Row London, SE1 8HN Thomas Nelson Australia 102 Dodds Street South Melbourne 3205 Victoria, Australia Nelson Canada 1120 Birchmount Road Scarborough, Ontario M1K 5G4, Canada 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 Library of Congress Cataloging -in -Publication Data Condensed chemical dictionary. Hawley's condensed chemical dictionary.-12th ed./revised by Richard J. Lewis, Sr. p. cm. ISBN 0-442-01131-8 1. Chemistry —Dictionaries. I. Hawley, Gessner Goodrich, 1905-1983 II. Lewis, Richard J., Sr. III. Title. QD5.C5 1992 540' .3—dc20 92-18951 CIP Is acetate fiber, saponified. Regenerated cellulose fibers obtained by complete saponification of highly oriented cellulose acetate fibers. Avail- able in continuous filament form having a high degree of crystallinity and great strength. Properties: Tensile strength (psi) 136,000- 155,000; elongation 607o; d 1.5-1.6; moisture re- gain 9.6-10.707o; decomposes about 149C. Sim- ilar to cotton in chemical resistance, dyeing, and resistance to insects and mildew. Combustible. Use: Cargo parachutes; typewriter ribbons; belts; webbing; tapes; carpet backing. acetate film. A durable, highly transparent film with non -deforming characteristics, produced from cellulose acetate resin. It is grease-, oil-, dust-, and air -proof and hygienic. Combustible. Available forms: Rolls and cut -to -size sheets. Use: Laminates; support for photographic film; document preservation; pressure -sensitive tape; magnetic sound recording tape; window cartons and envelopes packaging. acetate of lime. Commercial term for calcium ac- etate made from pyroligneous acid and milk of lime. There are brown and gray acetates of lime. See also calcium acetate. acetate process. See cellulose acetate. acetate rayon. The yarn made from refined wood cellulose by the acetate process. See acetate fiber acetate rayon process. In this process cellulose is combined with acetic anhydride to make cellu- lose acetate, which is dissolved in acetone and forced through spinnerette holes into a precipi- tating bath. See acetate fiber. acethydrazidepyridinium chloride. See Girard's reagent. acetic acid. (ethanoic acid; vinegar acid; meth- anecarboxylic acid). CAS: 64-19-7. (CH3COOH). Glacial acetic acid is the pure compound (99.80/o min), as distinguished from the usual water solutions known as acetic acid. 34th highest -volume chemical produced in U.S. (1991). Properties: Clear, colorless liquid; pungent odor. Mp 16.63C; by 118C (765 mmHg), 80C (202 mmHg); d 1.0492 (20/4C); wt/gal (20C) 8.64 lb; viscosity (20C) 1.22 cps; flash p (OC) IIOF (43C); refr index 1.3715 (20C). Miscible with water, alcohol, glycerol, and ether; insoluble in carbon disulfide; autoign temperature 800F (426C). Combustible. Derivation: (a) Liquid- and vapor -phase oxida- tion of petroleum gases (with catalyst); (b) oxi- dation of acetaldehyde; (c) reaction of methanol ACETIN and carbon monoxide (with catalyst; this is the most cost-efficient method and has been in gen- eral use for some years); (d) fermentative oxida- tion of ethanol. Grade: USP (glacial, 99.4 wt %, and dilute, 36- 37 wt 076); CP; technical (80; 99.50/0); commer- cial (6, 28, 30, 36, 56, 60, 70, 80, and 99.501o); NF (diluted; 6.0 g/100 mL). Hazard: Moderate fire risk. Pure acetic acid is moderately toxic by ingestion and inhalation, but dilute material is approved by FDA for food use. Strong irritant to skin and tissue. TLV: 10 ppm in air. Use: Manufacturing of acetic anhydride, cellu- lose acetate, and vinyl acetate monomer; acetic esters; chloroacetic acid; production of plastics, pharmaceuticals, dyes, insecticides, photo- graphic chemicals, etc., food additive (acidul- ant); latex coagulant; oil -well acidizer; textile printing. See also vinegar. acetic acid amine. See acetamide. acetic acid, glacial. See acetic acid. acetic aldehyde. See acetaldehyde. acetic anhydride. (acetyl oxide; acetic oxide). CAS:108-24-7. (CH3CO)2O. Properties: Colorless, mobile, strongly refractive liquid; strong odor; d 1.0830 (20/20C); by 139.9C; fp—73.1C; flash p 121F (49.4C) (CC). Autoign temperature 732F (385C); wt/gal (20C) 9.01 lb. Miscible with alcohol, ether, and acetic acid; soluble in cold water; decomposes in hot water to form acetic acid. Combustible. Derivation: (1) Oxidation of acetaldehyde with air or oxygen with catalyst; (2) by catalyzed ther- mal decomposition of acetic acid to ketone; (3) reaction of ethyl acetate and carbon monoxide; (4) from carbon monoxide and methanol. Grade: C.P., technical (75, 85, 90-950/0). Hazard: Strong irritant and corrosive; may cause burns and eye damage. TLV: Ceiling 5 ppm in air. Moderate fire risk. Use: Cellulose acetate fibers and plastics; vinyl acetate; dehydrating and acetylating agent in production of pharmaceuticals, dyes, perfumes, explosives; etc.; aspirin. Esterifying agent for food starch (50/6 max). acetic ester. See ethyl acetate. acetic ether. See ethyl acetate. acetic oxide. See acetic anhydride. acetin. (monoacetin; glyceryl monoacetate). CAS:102-76-1. C3H5(OH)2O0CCH3. 619 hydroquinone diW-hydroxyethyl) ether. (p-di-[2-hydroxyethoxylbenzene) . C6H,(OC,H2OH)2. Properties: White solid, mp 99C, by 185-200C (0.3 mm Hg), slightly soluble in water and most organic solvents, miscible with water at 80C. Combustible. Use: Preparation of polyester, polyolefins, poly- urethanes, and hard waxy resins, organic syn- thesis. hydroquinone dimethyl ether. (1,4-dimethoxy- benzene; DMB; dimethyl hydroquinone). CAS:654-42-2. C6H4(OCH3)2- Properties: White flakes with sweet clover odor, by 213C, mp 56C, d 1.0293 (65C), viscosity 1.04 cP (65C), dielectric constant 2.8, absorbs UV light in range 2800-3000A, soluble in benzene and alcohol, insoluble in water. Combustible. Use: Weathering agent in paints and plastics, fix- ative in perfumes, dyes, resin intermediate, cos- metics, especially suntan preparations, flavor- ing. hydroquinine mono-n-butyl ether. CH3(CHZ)3OC6H2OH. Properties: White flakes; mp 64-65C; by 115C (1.4 mm Hg); insoluble in water; soluble in ben- zene, acetone, ethyl acetate, and alcohol. Com- bustible. hydroquinone monoethyl ether. (4-ethoxy- phenol). C2HSOC6H4OH. Properties: White solid; mp 63-65C; by 246- 247C; slightly soluble in water; soluble in ben- zene, acetone, ethyl acetate, and alcohol. Com- bustible. Use: See hydroquinone monomethyl ether. hydroquinone monomethyl ether. (4-methoxy- phenol; p-hydroxyanisole). CAS: 150-76-5. CH3OC6H4OH. Properties: White, waxy solid; mp 52.5C; by 243C; d 1.55 (20/20C); slightly soluble in water; readily soluble in benzene, acetone, ethanol, ethyl acetate. Combustible. Use: Manufacture of antioxidants, pharmaceuti- cals, plasticizers, dyestuffs; stabilizer for chlori- nated hydrocarbons and ethyl cellulose, inhibi- tor for acrylic monomers and acrylonitriles, UV inhibitor. hydrosilicofluoric acid. See fluosilicic acid. hydrosolvation. Solvent extraction of coal (con- taining up to 5016 sulfur) under hydrogen pres- sure with the use of a catalyst such as zinc chlo- ride; pressures from 1000-2000 psi are necessary for suitable conversion. This process offers a means of deriving fuel oil and petrochemical feedstocks directly from coal: o-HYDROXYACETOPHEN ONE hydrosulfite. See sodium hydrosulfite. hydrosulfite-formaldehyde. One of several mix- tures of sodium formaldehyde hydrosulfite and sodium formaldehyde bisulfite used as dis- charges and stripping or reducing agents in dye- ing and other textile operations. In some cases the zinc derivatives are used. Derivation is by the action of formaldehyde on aqueous sodium hy- drosulfite or from zinc, formaldehyde, sulfur di- oxide, and sodium hydroxide. Hazard: Toxic by ingestion: hydrothermal energy. See geothermal energy. "Hydrotriticum" [Croda]. (hydrolyzed vegeta- ble proteins). TM for wheat protein. Use: For hair waving systems, shampoos, condi- tioners, and skin -care products. hydrotrope. A chemical that has the property of increasing the aqueous solubility of various slightly soluble organic chemicals. Use: Formulation of liquid detergents. hydroxocobalamin. (USAN) (a[5,6-dimethylben- zimidazolyl] hydroxocobaltam ide). C62H89CoN13O15P. A form of vitamin B12. Use: Medicine: See vitamin B12. hydroxyacetal. See hydroxycitronellal dimethyl acetal: p-hydroxyacetanilide. See p-acetylaminophenol. hydroxyacetic acid. (glycolic acid). Efi-- CH2OHCOOH. Properties: Colorless crystals, deliquescent, mp 78-79C, by decomposes. Soluble in water, alco/ hol, and ether; available commercially as a 7007o solution, light straw-colored liquid, odor like burnt sugar, d 1.27, mp IOC. Combustible. Derivation: From chloroacetic acid by reaction with sodium hydroxide, or by reduction of oxa- lic acid. Occurs naturally in sugar cane syrup. Grade: Technical 7007o solution, pure crystals. Use: Leather dyeing and tanning; textile dyeing; cleaning, polishing, and soldering compounds; cop- per pickling; adhesives; electroplating; breaking of petroleum emulsions; chelating agent for iron; chemical milling; pH control. hydroxyacetone. See hydroxy-2-propanone. o-hydroxyacetophenone. C6H4(OH)COCH3. Properties: Greenish -yellow liquid with minty odor, d 1.1307 (20.8C), by 213C (717 min), refr index 1.5580 (20C), slightly soluble in water. Combustible. - E i- y 'C A& A'-.r AM 0.3 0.6 1.3 2.4 3.9 5.5 9.7 15.2 21.9 29.8 38.9 49.2 60.8 73.6 87.5 119 137 156 176 197 ratio is used for WELL AND PUMP MAINTENANCE AND REHABILITATION 641 Welly (20 percent of the weight of the acid) to create a solution that will treat iron and manganese incrustants. Sulfamic acid reacts chemically with mineral deposits in the same manner as hy- drochloric acid, although at a slower rate. Consequently, longer contact time is usually required to achieve the same results; at least 15 hours is recommended. The effec- tiveness of the treatment is enhanced considerably if the acid is agitated while and immediately after it dissolves. Forceful agitation is also recommended before the acid is pumped to waste. Sulfamic acid should not be confused with sulfuric acid. Sulfuric is a strong liquid acid that has been used successfully on rare occasions in well treatment. Its major limitation in well treatment is that when it combines chemically with calcium scale, it forms calcium sulfate which is nearly insoluble in water. Thus, a sulfuric acid treatment may actually reduce the well's performance. In addition, sulfuric acid, even when inhibited, is extremely aggressive in attacking metallic casing and screens. Hydroxyacetic Acid Hydroxyacetic acid, also known as glycolic acid, is a liquid organic acid available commercially in 70-percent concentrations. Although not as well known or commonly used as either hydrochloric or sulfamic acid, its use has achieved excellent results in well treatment. It is quite safe to use because it is relatively noncorrosive and produces little or no toxic fumes. In addition to its ability to dissolve mineral scale, hydroxyacetic acid offers ad- vantages not available with sulfamic or hydrochloric acid. It is an excellent bactericide and therefore may be effective in treating wells with iron bacteria problems. It kills Table 19.4. Amount of Hydroxyacetic Acid Required per 1 ft (0.3 m) of Screen Length or Open Borehole Diameter of Well Amount of 70% Hydroxyacetic Acid per 1 ft (0.3 m) of Screen or Borehole in mm gal I 1 Vh 38 0.006 - 0.009 0.02 - 0.03 2 51 0.01 - 0.02 0.04 - 0.08 3 76 0.02 - 0.04 0.08 - 0.15 4 102 0.04 - 0.07 0.15 - 0.27 6 152 0.10 - 0.15 0.38 - 0.57 8 203 0.17 - 0.26 0.64 - 0.98 10 254 0.27 - 0.41 1.02 - 1.55 12 305 0.39 - 0.59 1.48 - 2.23 16 406 0.70 - 1.00 2.65 - 3.79 20 508 1.09 - 1.64 4.13 - 6.21 24 610 1.57 - 2.36 5.94 - 8.93 28 711 2.14 -3.21 8.10-12.1 30 762 2.45 - 3.68 9.27 - 13.9 32 813 2.79 - 4.19 10.6 - 15.9 34 864 3.15 - 4.73 11.9 - 17.9 36. 914 3.53 - 5.30 13.4 - 20.1 642 GROUNDWATER AND WELLS the bacteria and simultaneously dissolves the bacterial iron deposits as well as other mineral scale. In addition to its bactericidal properties, hydroxyacetic acid is a chelating or se- questering agent. This means that it has the ability to "surround" metal ions (such as iron, calcium, and magnesium) in solution and keep them from combining chem- ically with other ions. This insures that all the scale dissolved by the acid remains in solution during the entire treatment period. Hydroxyacetic acid is placed in the well in the same manner as hydrochloric acid. About 1 gal (3.8 t) of 70-percent hydroxyacetic should be used for every 10 to 15 gal (38 to 56.7 t) of water standing in the well screen. Table 19.4 shows the proper amount of hydroxyacetic acid to use in treating wells of various diameters. Hydroxyacetic acid is weaker than both hydrochloric and sulfamic acid, and longer contact time is required to achieve the same amount of scale removal. The rate at which an acid removes scale is related to the acid's pH (acid strength). Figure 19.3 shows how pH varies with concentration for the acids described above. Note that hydrochloric acid has the lowest pH and thus will work the fastest, whereas hydrox- yacetic has the highest pH and will work more slowly than the other acids. General Procedure for Acid Treatment Great care should be taken in placing liquid acid into a well. Only experienced personnel with specialized equipment should attempt to use it in rehabilitating a well. ■■■■■■■■■■■■ mom N■■MEMO■ ■\\■ .. .. ■■■ ONE MEMO mom ■■■■■■■M■■■■ ■E■■■■■■■■■■ ■■■■■■■■■■■■ . MEMO■■■■■■■■ Figure 19.3. Equal concentrations of different acids form solutions with different pH values; pH of an acid -water solution varies with concentration. When using any liquid acid, personnel should wear protective rubber clothing and goggles. A breathing respirator should also be used by all personnel han- dling the acid and by other persons near the well. All mixing tanks, chemical pumps, and piping (tremie pipes) should be constructed of plastic or black iron to minimize reaction to the acid. A large quantity of water, or a water tank with a mixture of sodium bicarbonate, should be available in the event that an accident oc- curs. Proper ventilation must be main- tained because the fumes released from the well during treatment are lethal. Liquid acid should be introduced into the well through a small -diameter pipe. If the screen is more than 5 ft (1.5 m) long, enough acid should be added to fill the lower 5 ft of screen. Then the pipe should be raised and the next 5 ft of screen filled with acid, continuing in this way until the entire screen is full. Pelletized forms of sulfamic acid dropped into the casing will accumulate in the screen where the pellets dissolve. When the granular forms are WELL AND PUMP MAINTENANCE AND REHABILITATION 643 poured into the casing, they go into solution throughout the entire column of water in the well. After the acid is placed in the well (or the pellets dissolve), a volume of water equal to that standing in the well screen is poured into the well to force the acid solution through the screen -slot openings into the formation. Some form of mechanical agi- tation, such as surging, should be employed while the acid is in the well to help break up the incrustation and improve the overall efficiency of the process. This step is particularly important because it exposes the incrustant to the acid, thereby assuring maximum removal. The use of surge blocks or jetting tools are effective methods of agitating the well. The agitation time will depend on the amount of incrustant in the well. If a surge block is used, the surging effect drives the acid into the formation and brings loosened material into the screen. In the jetting operation, the acid is first poured into the well. The screen or the face of the well bore can then be jetted with clean water from the surface or acidized water from the well (Figure 19.4). A pump pressure of 100 to 250 psi (690 to 1,720 kPa) is sufficient for this type of operation. Circulation of the acid solution may be corrosive to the jetting pump and other equipment, but the wide use of plastic impellers has eliminated most of this type of corrosion damage. If the job requires recirculating the jetting acid at the surface, it is best to call on a ' well servicing company that has special- ized equipment for this work. Great care should always be exercised whenever acid is being pumped in any well rehabilita- tion operation. An extended zone of the formation around the well screen may be wholly or partially clogged. Thus, it must never be assumed that the chemical solution moves uniformly outward into the voids of the water -bearing materials in all di- rections throughout the full thickness of the formation. The chemical solutions will now most readily into those areas where the formation or screen is the most open, that is, where resistance to flow is the least. Therefore, it may be extremely difficult and even impossible to diffuse the chemical solution to all points where it can dissolve or otherwise remove the unwanted deposits. The use of chelating agents is recom- mended if iron and manganese incrus- tants are present and the pH of the treat- ment solution is approximately 3 or less. Figure 19.4. To avoid the dangerous practice of pumping acid at the surface, jetting can be accom- plished by setting a pump in the well and using the acidified water in the borehole. 644 GROUNDWATER AND WELLS At this pH, these cations form insoluble precipitates that settle out and reduce the effectiveness of the acid treatment. Citric, phosphoric, and tartaric acids are three common chelating agents. Four pounds (1.8 kg) of chelating agent are usually added to each gal (3.8 t) of 31-percent (20 degrees Baum6) hydrochloric acid and 1 lb (0.5 kg) of chelating agent to 15 lbs (6.8 kg) of sulfamic (granular) acid. After mechanical agitation, the solution is left in the well to react with the incrusting materials until the pH is between 6.5 and 7, then agitated again and pumped to waste. The time for the reaction to be completed will vary from a few hours to more than 15 hours, depending on the type of acid used and the amount of incrustants. To minimize disposal problems, the water in the well should be neutralized if necessary before it is removed from the well. In many communities, the water well contractor may be required to haul away the spent acid and dispose of it according to local regulatory agencies. If not, the spent acid should be run onto a sandy section of ground as far away as practicable from the well head. Some contractors neutralize acid waste- water by running it through a limestone -filled container. Many water well contractors will redevelop the well after it has been acid treated. Solid particles of incrustant can be removed along with any fine sediments that may have entered the zone immediately around the screen after the well was placed in service. In many instances, effective redevelopment of an older, acid -treated well will result in a specific capacity that equals or even exceeds the original specific capacity. The various development procedures are discussed in Chapter 15. Mechanical Methods to Remove Incrustants Although removal of most incrustants by acid treatment is extremely effective, several mechanical methods are useful either in preparing for acid treatment or as a primary method of removing incrustants. Wire brushing or other means of mechanical scraping can remove incrustants that have been deposited on the inside of the well screen. The loosened material is then removed from the well by bailing, air-lift pump- ing, or other means. Removal of these incrustants minimizes the quantity of acid that must be used in any subsequent acid treatment, enhances the effectiveness of this treatment, and reduces the time required for the acidizing process. Controlled blasting techniques are often useful for temporarily improving well yield by fracturing the incrusting matrix so that water can reach the screen. Incrusting materials are sometimes deposited on formation materials several inches or more away from the screen. The incrustant may become so massive that all voids in the formation become filled and little water can reach the screen. Blasting procedures create cracks in the incrustant, allowing water to enter the well. Some fragments of the incrustant will break away and can be pumped from the well. Unfortunately, the opened cracks eventually will also become incrusted and additional blasting or acid- izing treatments will be needed to maintain yield. This technique, when combined with acidizing, is particularly effective. Special service companies have formed to provide this type of blasting service. Incrustation of Rock Wells Although this discussion has referred only to screened wells in unconsolidated formations, wells in consolidated rock also suffer from incrustation of the borehole wall or the cracks and fissures leading to the borehole. Many rock wells require water well technology Field Principles of Exploration Drilling and Development of Ground Water and Other Selected Minerals Michael D. Campbell Jay H. Lehr McGRAW-HILL BOOK COMPANY New York St. Louis San Francisco Dusseldorf London Kuala JPoanamaesbu Rio de Janeiro Lumpur Singapore Montreal Sydney NeToronto I 368 Well Efficiency and Maintenance ' Like hydrochloric a (1) Dissolves and disintegrates residual mud cake. particles to form hydr (2) Dissolves insoluble clay or cement particles which may have _ ment, these clay partic- filtered into the formation rock. 7 (3) Dissolves silicate particles in the matrix which may have been ; ; Because of the di: swollen by contact with mud or cement filtrates. T.: hydrochloric acid and In addition to restoring damaged permeability, "mud acid" has n ditions, IIa17iS307 utllr2E by blending th often been used to improve the permeability of sandstone five to ten solubility in dation blended and excellent formations. Man rocks showing only percent Y g Y P Y� ;�t°c� - as a first-stagE hydrochloric acid reveal from 15 to 50 percent solubility in mud acid pumped because the hydrofluoric -acid component attacks and dissolves the ventional hydrochloric silicate -cementing materials in the sandstone. Special handling is S i'' ��,.: performed remarkabl} is that the lead required for mud acid application. theory ed, thus lessening the Acetic acid has been widely used as an aid in overcoming many of ,: standing of this retarc the problems encountered in well completion, stimulation, and one of the primary f reconditioning. Even though this acid has been used in the past for '' rz in a lime stone form g - well stimulation, factors such as economics, handling, and the lack of z.: _ data have limited the use over the past few years. 2Z1, A three to five per technical Acetic acid does not present many of the operational difficulties "kill' fluid for petrol often associated with other acids. 285 The corrosive action of _ {' its acidic characterist are exposed to fresh acetic -acid mixtures can be greatly minimized even at temperatures --= j in excess of 2400 F. Contact time of acid and pipe can now be ex- -_= will absorb water ar blocking the formati( tended for days with proper inhibition. The mixtures currently being An aceti used in the oil industry have not caused electrolytic corrosion, - condition. than othF 1 hydrogen embrittlement, or stress cracking of metals. Unlike hydro- - efficiently j chloric acid, acetic acid can be effectively inhibited for most types of does not damage mei 1 steel. Inhibited acetic a i ' The type of corrosion caused by acetic acid differs from that - remover in pum'. caused by hydrochloric acid, the latter tends to "pit corrode" heat -treated pump 1 the dissolvi tubular goods with extended exposure. This action accelerates with percent inhibited acetic acid increasing temperatures. By comparison, acetic acid at equivalent test conditions of time, temperature, and pressure will produce only a pumps. minor removal of steel from pipe. Furthermore, when the acid was Acetic acid can allowed to spend completely, serious damage did not occur to emulsified acid, t1hu laboratory and field test samples, and pronounced pit -type corrosion porary bridging ag did riot form. A special inhibitor is always added to the acid to stronger hydrochlo permit storage within the casing or tubing for many hours so that formation. i full-strength acid will be present when needed. Acetic acid inherently reacts more slowly than hydrochloric acid. When acting on carbonates, acetic -acid -reaction rates are influenced Pressure Acidizing greatly by pressure. While temperature does exert an influence on Koenig summar i( rate of reaction, the rate is not accelerated as much as with hydro- techniques which a chloric acid. Well Efficiency and Maintenance 369 cake. Like hydrochloric acid, acetic acid will chemically react on clay articles to form hydrogen -activated clay.With an acidic environ- ment, these clay particles will remain in the least -swollen condition. which may have been Because of the distinct difference of reaction rates between t filtrates. hydrochloric acid and acetic acid on limestone under identical con- ility, "mud acid" has ditions, Harris30. utilized this difference to obtain a significant retar- ability of sandstone i dation by blending the acids. In field applications, the acids were !n percent solubility in blended and excellent results were obtained. The acetic acid was solubility in mud acid :'? pumped as a first -stage treatment immediately followed by the con- acks and dissolves the ventional hydrochloric -acid treatment, a procedure which has been e. Special handling is _ performed remarkably well in many instances. In this method, the theory is that the leading edge of the acid will be considerably retard - in overcoming many of - ed, thus lessening the possibility of pumping spent acid. An under- tion, stimulation, and :Y standing of this retardation is considered by the oil industry to be en used in the past for one of the primary factors governing the success or failure in acid- 3 idling, and the lack of _" izing a limestone formation?" st few years. A three to five percent solution of acetic acid has been used as a operational difficulties_ "kill" fluid for petroleum workover operations. This fluid because of e corrosive action of its acidic characteristics is highly suitable. If fine-grained sediments d even at temperatures are exposed to fresh water, or infrequently to brines, clay particles id pipe can now be ex- = will absorb water and swell several times their original size, thus zixtures currently being � blocking the formation permeability. Acids can limit this undesirable electrolytic corrosion, _ = condition. An acetic -acid solution will limit clay -swelling more f metals. Unlike hydro- T- efficiently than other types of fluids. Properly inhibited acetic acid ibited for most types of _ _. does not damage metals during this type of acidizing. Inhibited acetic acid has been used frequently as a carbonate -scale acid differs from that remover in pumping wells containing chromium -plated and ends to "pit corrode" heat -treated pump parts. Even though this acid has only about 60 action accelerates with percent the dissolving ability on carbonates as hydrochloric acid, ,ic acid at equivalent test inhibited acetic acid has performed effectively without harm to the ire will produce only a pumps. ,lore, when the acid was _ to Acetic acid can be made into a high -viscosity, gelled and/or nage did not occur emulsified acid, thus becoming a suitable carrier for producing tem- unced pit -type corrosion to the acid to porary bridging agents during the treatment of a well, where a ,vs added hours so that _ stronger hydrochloric acid may have a harmful effect on the for many formation. d. than hydrochloric acid..:' Lion rates are influenced ; a Pressure Acidizing �s exert an influence on as much as with hydro - ' s{ Koenig summarizes the effectiveness of the pressure -acidizing g techniques which are in common use in the petroleum industry.36' MANUAL OF WATER WELL MAINTENANCE AND REHABILITATION TECHNOLOGY by Tyler E. Gass Truman W. Bennett James Miller Robin Miller The National Water Well Association Grant No. R805211-02-1 Project Officer Jack W. Keeley Robert S. Kerr Environmental Research Laboratory National Environmental Research Center U.S. Environmental Protection Agency Ada. Oklahoma ms and Frequency annua daily ti E ':daily. -cumulate, well problems .ations will facilitate the ES maintenance is deemed ;truction and operational eve the production pump. nts are not severe, the auction pump and install -n the well can be treated :hat can be introduced e: Because chemicals and ular pump should always well is then surged by rip. After an appropriate e and returned to service. �ry limited in its effective- i more severe cases. ,ell should be sounded or with aweighted steel line ,th should be compared to l logs, for evidence of hole i in the well. If geophysical logs (gamma, resistivity, spontaneous potential, or others) from the time of construction are not available, they can be obtained from information collected at this time. Utilizing logging techniques, casing and grouting problems, screen location, permeable zones, and other pertinent information necessary for the proper application of maintenance, procedures can be identified. A closed-circuit television or photographic survey of the well after the pump is removed is often the most reliable means of obtaining specific information concerning the condition of the well. Both of these techniques have been successfully used in evaluating well condition8, and both produce clear pictures that identify specific problems. Television and photographic surveys can pinpoint the exact location of casing problems, screen blockage or failure, and the location and nature of production zones in rock wells. When screens or zones are heavily incrusted, the television camera can help obtain a sample of the incrusting materials while performing the inspection. A sample can be taken by lowering a small bucket -shaped container ahead of the camera to scrape off a portion of the material in question. These samples can then be analyzed, and the results can be used to select the appropriate chemical treatment. CHEMICAL TREATMENT The purposes of chemical treatment are diverse, but the objectives are usually to dissolve incrusting inorganic deposits from screens, pore spaces of the aquifer adjacent to the screens, and other areas that affect well performance. Most frequently these deposits are calcium, magnesium, or iron carbonates, oxides, hydroxides and occasionally sulfates. Certain chemicals act as biocides, killing bacteria present in the well and aquifer and dissolving their gelatinous remains in order to release and remove inorganic materials. Still other chemicals disperse fine materials, such as clay and silt, maintaining them in suspension until they can be removed from the well. Three classes of chemicals are commonly used in well mainten- ance procedures: acids, biocides and phosphates. Table 3.1.3 sum- marizes some of the more commonly used chemicals, along with their significance and utility. CHELATION, WETTING AGENTS AND INHIBITORS An important attribute of some chemicals —including hydroxyacetic acid, citric acid, mixtures of these and similar chemicals —is theirability to form soluble complexes with iron. This prevents iron from redepositing during the latter stages of chemical treatment. This process is 116 ' r Table 3.1.2 # Chemicals Used for Well Maintenance f r Chemical Name • Formula Application , .';, " Concentration `' y 'Acids and Hydrochloric Acid ` , HCl Carbonate scale oxides; 15%; 2-3 times zone - hBiocides.', : hydroxides - volume Sulfamic Acid NH2SO3H Carbonate scale, oxides; .15%: 2-3 times zone . w hydroxides Volume' Hydroxyacetic Acid C2H403 Biocide, chelating agent, #' weak scale removal agent Chlorine CL2 Biocide, sterilization, • 50-500 ppm very weak acid :,Inhibitors Diethylthiourea (C2H5)NCSN Metalprotection 0.2% Dow A 73 Metal. protection` 0.01% it }5 ,��,:JHydrated Ferric}Sulfate Fe2(SO.�)3• For stainless steel 1% ,.4 2-3H2O Alder 97,With sulfamic acid 2% Pol d.I1OA' Ym Metal protection' r� .375% Chelating s <CitricElcid + , CFlO Keeps metal tons In Agents r z I solution, ". 1 Y Phosphate Acid 4 H3I'O4 Keeps metal ions in ys:� a i ; r :Rochee11E Salt SOluttOn mNaOetal ions in E ,t (CHOH)2 Solution Y COOK � �:Y .. ,... ..... ,,. -a.. .... ...r,,.,,.: _ - .i.. .. -i. M«.i-.:i ta- : is-. ,..e_...I t,,.,.., ,....•..,�f...,...,.,su.... ai...--BrsK! Y..t."..u�+x ..v::i 4E:K �.1ti:.�� Y��a Hydroxyacetic Acid C2H rO3 Keeps metal ions in . solution k .. �4, �tn Wetting Plutonic F-68 Renders a surface nonre- Agents pellenl to a wetting liquid <".. Plutonic 1,62 ,' Renders a surface nonre { 1 pellent to a wetting liquid a Surfactants Dow F-33 Lowers surface tension of rl ?`' water thereby increasing ,+ w its cleaning power. �;'c •' Sn�ii, �m Tririnl+mhn�nh;�f,, Im ri> - 1 , c O O O C V) 5 . C L a : cc 3 �f3 ca,Q a. - ` v tc co o-M a c ct FO . ,fU s, tf— wa+ 118 termed chelation. Iron is commonly present in ground water in the soluble ferrous (Fe+z) state. Foranyofseveral reasons, iron maybe present not only in solution, but in a colloid form, precipitated in the ferric (Fe+3) state (insoluble) or hydrolized as insoluble hydrated ferric oxide. Thus the chelation process is indispensible to the removal of iron from any well troubled by iron -related deposits. Wettingagents act to reduce the natural surface tension ofwater. This surface tension is the result of the weak forces that attract molecules of water to each other. By adding a wetting agent, these weak molecular bonds are broken. By doing this, it is possible to increase the penetration ofchernicals into theaquifer, improving the impact of the chemical treatment. Corrosion inhibitors are employed with many strong acids in order to optimize their cleaning capability. The acids dissolve scales that plug screens and pore spaces. The inhibitors are specifically designed to "inhibit" the activity of the chemical being applied with regard to certain materials and to selectively permit the maximum dissolution of other materials. SURFACTANTS/POLYPHOSPHATETRF.ATMENT Somechemicals, rather than dissolving, precipitating or chelating have the capacity to attach themselves to the small particles of clay, colloids, and even some ionic metals such as iron. This causes all of the resulting complex particles to have the same ionic electrical charge. Similar electrical charges repel each other, therefore, there is a strong impetus for large particles to break up into small ones, with the dispersed smaller particles being easy to pump from the well. Chemicals which cause these similarly charged surface particles are called "surface- active agents" or "surfactants." Theyare also commonly referred to as dispersants or sequestering agents. A well known surfactant, used in laundry detergents, is alkyl benzene sulfonate (ABS). Even in small quantities, it can create significant foaming and frothing of water. The most widely used surfactants are the glassy sodium phos- phates (polyphosphates) that are effective in the dispersion of clays, silts, iron and manganese oxides and hydroxides, and most other fine-grained particulate material than may occur in a well. These phosphates are usually applied in concentrations of approximately three percent (25 pounds in 100 gallons of water), in combination with at least 50 ppm of chlorine (about one-half gallon three percent household bleach, or Clorox, in 100 gallons of water), and agitated 119 vigorously. Since the phosphate's contact time is not a signif'. contact be made. Hence a reach out as far as possit repetitions, injecting, surgii a two- to four-hour cycle w treatment with extended dt with a jetting tool, surge bloc than simply back flushing a best results the pump mus It is essential that & phosphates are utilized. Ma phosphate in their life proce be alimiting factor in theirp without a controlling bioc munity may grow explosive: screens etc. in the process. Phosphates should also of shales, silts or clays whici zones may be disintegra resulting in enlargement of communication, or contan separated and create a "clo only by prolonged develops Phosphate solutions arc well, and preferably intro( usually in a glassy -platelet suspension in a wire bask swirling water. New materi; the phosphate is dumped c large, slick lump which car extended period of time. Polyphosphates are eas They are nonfoaming, anc fine-grained materials, can METHODS OF CHEMICY acids. biocides, chlorine should be injected by mear. the zone of the well to be tr well quickly attains the de isolation of the treatmen illustrates a very econon Well disinfection is a problem for almost every water well con- tractor. Many drillers do not fully understand the way disinfectants work, how chlorine demand varies throughout the well and the difficulties in achieving proper disinfectant distribution. It is also rare that drillers understand exactly how the time that elapses 9tween disinfection and well ..:sting effects the test results. Some form of chlorine is the substance most often used in disinfection, so it is important that drillers understand how it reacts in water. Reaction with reducing ions such as ferrous, manganous, nitrite, sulfide and sulfite form the initial demand (See figure 1). The chlorine reduced to chlorides in these reactions has no disinfec- tion ability. Additional chlorine will then react with ammonia and certain organic compounds to form chloro-organic compounds and chloramines. Combined residuals reach a peak (point C), then decline as more chlorine is added —offering a limited disin- fection ability. The point at wich combined chlorine residuals reach a minimum and a free chlorine residual begins to appear, is known as the break- aint. Up to this point chlorine smand (dosage minus residual) varies with dosage. Beyond the breakpoint the free chlorine Well disinfection How fast'? How sire? residual increases directly with dosage as free chlorine is a rapid disinfectant. Much of the available chlorine lost to long term chlorine demand is used to oxidize organic matter. The hydrochloric acid rapidly reacts with adjacent organic or mineral matter and normally increases the possibility of further chemical reaction. The major chlorine demand of concern in well disinfection is not in the water, but on the surfaces of the well. Nuisance organisms (organisms able to reproduce in the environment of the well) often produce large quantities of organic matter. The result is a high chlorine demand and sufficient organic energy for the J Q _o U1 W Ix W z O J S U 1 1 1 1 1 1 1 1 FORMATION OF CHLORO-ORG COMPOUNDS AND CHLORAM �OFCHLORINE BY REDUCING 0.1 COMPOUNDS possible propagation of coliform if the water temperature is above 13° C. In addition, the submersible pump motor may be several degrees warmer than the well water and can create a microenvironment where coliform can reproduce in wells with water cooler than 13° C. Grass and weed stems on the riser pipe and electrical wires above the water level may also provide -a habitat for nuisance organisms. Many nuisance organisms are filamentous or slime formers and produce particles that settle to the bottom of the well, along with soil particles. Until further evidence is available, it is wise to assume that 20% of the chlorine demand exists at the bottom of � I I FORMATIONOF FREE CHLCRI14E AND PRESENCE OF CHLORO-ORGANIC. COMPOUNOS NOT DESTROYED DESTRUCTION OF CHLORAMINES AND CHLORrO--OR—GANIICCCCOMP. ANIC. oo� INESi C r I r r iB Comb nqd Rss,d= 1 OL I I r r r I' I I r I r 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 CHLORINE ADDED Figure 1. A chlorine demand curve for a water sample showing the initial demand, combined chlorine compound increase, peak and decline to the breakpoint where a free chlorine residual is first detected. 56 Water Well Journal, November, 1979 the well. In wells that have been inadequately disinfected several times, over 90% of the demand may be at the bottom due to settled slimes loosened in previ- ous disinfection attempts. Two chlorine products are commonly used in well disinfec- tion, 5.250io sodium hypochlorite (laundry bleach containing 50,000 ppm available chlorine) and 65 or 70% calcium hypochlorite avail- 2.b!e as a dry granular powder or tablets containing 650 to 700,000 ppm available chlorine. Disinfectants are pesticides regulated by the Environmental Protection Agency in accordance with the "Federal Insecticide, Fungicide and Rodenticide Act" (FIFRA). Every pesticide container must bear a Registration and Establishment Number and be labeled in accordance with FIFRA Regulations. Products such as the hypochlorites have many uses and may have supplemental use instructions distributed in bulle- tins. The user should have the appropriate instructions present to be sure of compliance. Laundry bleach poured into a well will stratify in the upper well water. Granular calcium hypo - chlorite settles too slowly and dissolves too fast to achieve uniform distribution. Calcium hypochlorite tablets have the opposite problem, initially settling at about 1.33 fps and dissolving at about 3% per minute. Recently the U.S. Department of Agriculture provided informa- tion on settling and dissolving rates. They indicated that about 50% of the granular calcium hypochlorite dissolves in the well's upper eight feet. Other studies indicated that residuals would be lower at lower depths for tablets. After the initial rapid weight loss, the rate of weight loss was fairly constant- 1% per minute per square . cm/gm. - The series of studies also proved that a properly selected variety of particle sizes is required to give uniform dosage through- out a well bore. For 150 feet of water with about 20% of particles reaching bottom undissolved, the following size distribution gives fairly uniform results. Field use of the prefractured tablets is extremely fast and easy. The only other process that can produce a uniform dosage throughout the well is the installation of a tube to the bottom of the well through which the chlorine solution is dis- charged. The tube is gradually withdrawn as the chlorine solution is added, exposing all parts of the well. Use of prefrac- tured tablets saves over two hours per well. There is one serious problem: Calcium hypochlorite manufac- turers do not recommend fracturing tablets under field con- ditions since there is a danger of severe chemical burns, fire or explosion if adequate safety precautions are not taken. (See Box) The use of this technique by drillers will depend upon commercial firms making frac- STATIC WATER LEVEL PUMPING WATER LEVEL UPPER DEAD BORE VOLUME PUMP INTAKE ACTIVE PUMPING BORE VOLUME PRODUCTION ZONE LO`:/ER DEAD BORE VOLUME Figure 2. Terminology applied to the well bore water volume in well disinfection. Water Well Journal, November, 1979 57 �F . CTURED TIABLET LARGER SCREEN PARTICLES AND PASSED RETAINED UPI SILL IAUIL itu GR PAii 2mm dmm 8mm TAB Figure 3. Settling velocities of tablets, tablet particles and granular calcium hypochlorite. tured tablets available. A removable stick -on label which could be dated and attached to the well casing would be desirable. Chlorine residuals in well bores should be checked occa- sionally, with one of the many available sampling devices. You can easily fabricate your own fit- ting 'ia or 1" pipe length 200-300 cc in volume with a check valve at the bottom and reducing ccup!ing at the top. The lower portion of the check valve is cut off to minimize dead water volume below it. An air line is attached to the reducing coupling. The cylinder and air line are pressurized to hold the check valve closed until the desired depth is reached. As the pressure reduces, the cylinder fills with water and can be withdrawn. (A safety line may be attached to the cylinder.) If the cylinder is lowered to the bottom of the well, bottom sediments may be ''obtained in addition to a water sample that may be checked for chlorine residual. Unfortunately, little data has previously been published on vtell disinfection. However, when the most frequently heard complaint is "I can't clear it up, it's in the formation," current recommenda- tions for displacement disinfection should be reconsidered: A common recommendation is to back flush the bore with two bore volumes of water containing 50 ppm of available chlorine. Water in the bore is forced back into the formation and is then followed by the chlorine solution. If the chlorine demand is high, slime sludge and chloro-organic com- pounds may also enter the production zone. Depending on the location and nature of the production zone, much of the bore may not receive any chlorine solution. A good rule to follow is not to force water from the bore into the formation until the bore is fairly clean and the displaced water contains a desirable free chlorine residual. This can only be done after the installation of a pump. My recommendations are as follows: place a strong chlorine solution in the well before installing the pump, then the pump, pipe and wiring will pass through this chlorine solution on entering the well water. Immediately after the pump is installed, the well should be pumped to waste over the upper casing terminal —not into the dis- tribution system. After the pumped water clears, it may be returned to the bore and a chlorine compound added either to the return stream or directly to the bore. The returned water establishes a recirculating bore volume from the water level to the intake up the riser, to the ar casing terminal to be ..-rned to the bore, or run to waste. When recirculating 100% of the pumped water, it is possible to calculate the chlorine demand. For accuracy it is necessary to know the recirculat- ing bore volume and pumping rate. A high chlorine residual test kit is essential. Most are based on the lodometric Method in Standard Methods, modified for easy field use. Problem wells can have very high chlorine demands. When 500 ppm goes in and 50 ppm comes back after one recirculation cycle, you may wish to increase the dosage by 200 ppm. When this happens the pumped water normally becomes turbid with released bacterial slimes. The turbid water should be pumped to waste rather than returned to the well. After it begins to clear, return 30 to 50% of the water to the bore. Otherwise, clear water may be obtained quickly from the production zone but as soon as circulation is restarted, turbid water will be pumped from the upper dead bore volume. When the pump intake is located above the production zone, chlorine can be introduced into the active pumping bore volume and lower dead bore volume in this manner: stop pumping and add batches of fractured tablet calcium hypo - chlorite and give it time to settle before restarting the pump. Circulation is not established in the lower dead bore volume and the chlorine is rapidly removed from the active pumping bore volume. In some areas of the country, centering guides are used in most wells. These have horizontal surfaces that will retain slimes and tablet particles and greatly reduce the chlorine that reaches the lower dead bore volume. In areas where nuisance organisms are common or in wells where a very low Standard Plate Count is desired, a means of establishing circulation from the bottom of the well to the 58 Water Well Journal. November, 1979 pump intake should be provided. This can be '/ or 3/4" pipe, with a hose fitting a few inches below the upper casing terminal. The lower two inches should be perforated to discharge water in several directions and permit free discharge of water without pipe vibration. Calculation of chlorine demand is simplified if 100%-of the pumped water is recirculated. This also reduces chlorine requirements as none is pumped to waste except when it is desired to waste turbid water. If not all water is recirculated it is neces- sary to know the ratio of recirculated water to pumped water to calculate chlorine demand. Without recirculation it is impossible to be sure that the chlorine demand of the lower dead bore volume has been satisfied. It also is impossible to remove the residual of bacterial slimes that have been killed and loosened by the chlorine. The importance of under- standing good well disinfection processes is illustrated by one t" conscientious well driller from whom we learned of this need. His standard procedure was to pour two gallons of laundry bleach into the well. If the health - department found the well contaminated he would return, pour five gallons of bleach into the well and pump the well to establish circulation. If the well is still contaminated, he would use 10 and then 20 gallons of bleach. Because of the time lag between disinfection attempts, health department sampling, return of bacterial results and notification and redisinfection, considerable regrowth of nuisance organisms .occurred in the recirculating bore volume between the pump intake and the static water level in the well. Without a tube to establish recirculation, no amount of bleach could disinfect the lower dead bore volume. The exact role that decomposing organic matter .__ in the lower dead bore volume plays in supplying nutrients for Calcium hypochlorite precautionary statements' Hazards to humans and domestic animals. D� r keep out of reach of children. Danger: Corrosive, causes eye damage. May be fatal if swallowed. Don not get in eyes, on skin, or on clothing. Irritating to nose and throat. Avoid breathing dust. May cause burns to broken skin. Wear goggles or face shield and protective clothing when handling. Wash hands after handling. Practical treatment (First Aid): If swallowed feed gruel, cooked cereal, or bread soaked in milk, followed by olive oil or cooking oil. In case of personal contact, remove excess material and flush skin or eyes with cold water for at least 15 minutes. For eyes get medical attention as soon as possible. Remove and wash contaminated clothing before reuse. Chemical hazards: Strong oxidizing agent. Do not use moist or damp utensils. Contamination with moisture, dirt, organic matter, or other chemicals, or any other foreign matter may start a chemical reaction with generation of heat, liberation of hazardous gases and possible generation of fire. Environmental hazards: This pesticide is toxic to fish. Keep out of lakes, streams, ponds, or public waters. Permits may be required for discharges containing this pesticide into public waters. For guidance contact the regional office of the Environmental Protection Agency. Storage and disposal: Keep product dry in tightly closed container when not in use. Store in a cool, dry, well ventilated area away from heat or open flame. In case of decomposition isolate container in open area if possible and flood with large amount of water. Do not reuse empty container. Rinse empty container thoroughly with water to dissolve all material before discarding. Place in trash collection or dispose in approved landfill area or bury in a safe place. Directions for use It is a violation of Federal Law to use this product in a manner inconsistent with its labeling. ' U.S. Environmental Protection Agency Pesticide Registration Division regrowth of nuisance organisms is not known. Regrowth in one well was surprisingly rapid in about two weeks, regrowth above the pump intake created a chlorine demand over 1000 ppm. To achieve satisfactory disin- fection, the entire well must be treated. The highest chlorine demand should be expected at the bottom of the well where dirt and' organic debris settle. Most wells can be quickly and surely disinfected by use of proper techniques. Wells designed or constructed with dead water pockets behind the casing may be impossible to disinfect without either eliminating the dead water pockets or making it possible to establish circulation. In new wells, fractured tablets can quickly distribute chlorine in the bore water. In wells that have nuisance organism problems much guess work can be eliminated by establishing circulation, measur- ing chlorine residuals and adding chlorine as needed to satisfy demand. Written by Elmer E. Jones Jr., Research Agricultural Engineer for Rural Sanitation, United States Department of Agriculture, Beltsville, MD. Water Well Journal, November, 1979 59 FROM .FISFER SCIENTIFI TO :9P19198699930 I Fisher Scientific Company r.o. 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"rkG B':PiON: tsph!ze mrst Near splist-prns Sr a.s:'.:Siat2Tst saieti ',Cj?+35 ail z IaCeshietd tO rT-VeLt ClEt"Ect Yitl tt15 sahs'._L`re. Wash 6d2rs 'tna 15 E;! pG55it•Liity tlat iz eE='lL_'c24 5Y'25 .`-.Lei:* st_L may b SIp4rEd - th 5Gt`SYsr!e, ,h2 8Ilpi3y?r :tCtilai gCisLL2 8; ?v-v Mr35t' 4.51L:d:.^. ant ciiz*l- drerch sieve: 1ii.tt:A tte 14 2diat2 var-t i_w2a icr zmerTEncf ikse. �:DJd4 k�?-S s DA- .'7.+'f- 1CM11410 ICE §�ol_n� 2� w I:bG I2aNATU D !pG£ a s 2£2 El m :2. 3 :« 2i:i I- §q: ) �;\`lfgR.2.z').m\/_ 11 /m _ K_�w' t ��w _- - . | Cu l22G 0.63 % 32z 2 2g'?l ;222 \22 @E 2 2! g UtE HLILE T BOA- G2wIaT 2S e of e!£ THE T",-, l22 SQFR;22aQ:6g &2. i| } IL, iL FROM :FISHER SCIENTIF', TO :13PIS198599930 1994,10-29 08:47RM #124 P.01/03 •���� �t� r ��� ��� ! !tat• Fisher Scientific Company r.O.1Tox 4829 2775 Pacific Drive Norcross, GA. 30091 Telephone; . (800) 766-70W Fax: (M) 926-1166 Please deliver the following page(s) to. - Name., (4 From: Location; Dale: Atlanta 1996 QQ-Q 1k 10 Fax No. Callum 1'a. 2CRNo. of Pages (Including Cvr): Message: tj Ck) �, FROM *-FISTER SCIENTIFI TO :9P19198999930 994,10-26 08:48rtl #124 P.02/03 MATERIAL SAFETY DATA SHEET EASTMAN KOUAK COMPANY 343 State street Rochoctor, Neu York 14650 For Errorgency Haralth, Safety, and Fnvirimmental Iaforratioo, call 716-722-5151 For all other phrpeses, call 500-225-5352, in Neu York State call 716-459-4014 Date of Revisions 03/22/90 Kodak Accessiaa Nuavrr 54348V MECTION prxrraIr�R�4RAS�FRIXfRRf;txSG:R«SC�C__________________97______x=�ox�_so__n�m:_-_c SE, IDENTIFICA710H Prodact Naaet (,+-,)-1,7,7-Trinethyl-bityclo(2r2,1.)heptane-2,3-di4lta Sytaonym(s)l OLw2,3-Boraanediohe Formulae CIO H14 02 - CAT No(a)t 120 9329; 833 3981 Chem, No(s)i 50941 i(IM s IatrirwaI Hazard Ratiap C9495; R; 1 8: 1 Fi 1 Cr 0 s_s_=s__o:s_ns:asxatnasx7eraa7eaCansser,CsnRRse�saasexase_CxagCewexax=xeSsre«W�,;rS's SECTION II. PRODUCT AND COKPONENT HAZARD DATA ACGIH COMP014I;NT(S)o Percent TLV(R) CAS Reg, No, DL-2,3-Bornanedione ca. 100 10373-78-1 xrz ouacs:ass:maC;cMzorAcMUKZasEra:rxEms gMPTK=zA=Tmr=tccC9= Sl(;Y1UN III, PHYSICAL DATA » Apppearance: Solid Meoltin points Not Available vapor ressure� Negligible Evaporatioi Rrta (tI-butyl Itatate M l); Ne;ligibly Volatile fraction by Weiahti Negliggible - Specific Gravity (Water a 1)1 Not Rveilably -_ Solubility in dater (by Uei9ht): Nat Available_ ._-�-__5a:�':aT.i'aRaaiaaMa ao aaaataaar■leC4aSRRC�C��«�_w__w_-_-...�.-.�.-.: �`.�..-.:}: �it3�� rD SECTION Iv. FIRE AND tXPLOSION HAZARD DATA - Flail, Poietj Not Applicable - Extinsuishing Medial Water ;pray! Dry chemical; Carbon dioxide+ Special Fire Fi htin Procedures; Non@ Unusual Firy aid Exp osion Haxardsr This vaterial, like twst organic materials in powder form, is capable of creating a dust explosioe. MnwaEEErutEMEMssx,eq:rcaGs_7 e_:;s«ss�t�s=�scs«�s�s��rnszscruiauanaaerRISE maxwMaaen=Neu SECI'IL}b! U� REACTIVITY DATA Stabilltyc 5teble ITMcompatibilityl Strong oxidizers Hazardous Docappigitioa Proddcts: CombuStioa will produrp carbon t✓ dioxide and pro6ably carbon monoxide, - Hazardous Polymerizationi Uill not occur. FlMxZa: EiISEr RESCrC C.ESCS��'-^^_!`��"�«!'�_•-Fl,: xt=*ataa**&* MEND a a M Mown a Ron Rana MIS Nona"n R-0046,750A 86-8122 Ci FROM :FISHER SCIENTIF TO :9P19198699930 1994,10-26 OB:48RM #124 P.03/03 a NrpaCaprr Ylamrstivar•bamrc2b krrobvrrarbrrCprpapiFmraipiRUaiIIPsiiOaiiiP AFiifR�'s aPp SECTION VI, IUXICITY AND WALTH WARR DATA A. EXPDSURE LIMITS., Not established. H. UNGURE CHUM Inhalationi Low hazard for usual industrial handliay. Skims Lew hazard for ksoal industrial handling. Eyei No specific hazard keown, Contact ssy cause transient irritation, Ingeutiaxt Expacted to be a law ingestion hazard. C. FIRST AIDS Inhalatiani If symptomatic, remove to fresh air. Get medical attention if sym tort persist, Skih: ash after path toxtoct. Get medical attention if symptoms accnr, Eye: Any material that contacts the eye should be washed out imwadiately with water, Get FoedicaI attention if symptoms occur, IngestioA, Drink 1-•2 glasses of rater, Seek medical attention, tU�;;;== =9::=t t ZkttY Xw2M--ZG7tzzw__=zuzzz___s_cmro=racrresrrcresrs=ra_:a=a SECTION Wt . VENTILATIDN AND PERSONAL PROTECT10H A. VLNTILAT•ION AND RESPIRATORY PROTECTIONi Goad ventilationA should be sufficient. SuPplelaentary mil latSoh Or respiratory proteetisA ioay be needed in special circumstances, i TypicullY ten roam volumes per hair is considered good general venti•lation� ventilation rates should be viatchad to conditions of uuc, ID R. SKIN AND EYE PROTECTION; Safety glasses recommended in industrial operations involving chemicals. It pprolonged or repeated skin contact is xecessary, gloves or other praioction mny bo required, WEi ktrasaai6orckas.kkiEsf bLk FFar04 MCC! xr':+e==V;r----.".����.". SECTION WIT. SPECIAL MRAU AND HANDLING PRECAUTIONS Keep from contact with oxidizing materials, FeC,.eerr=VV==Mr=.=Z%C===SL.:CwGSCCS. SECTION IX. SPILL., LEAK, AND DISPOSAL PROCEDURES SWOOP VP material tAd package for safe feed to an incinerator. Dispose by incineratiaa or contract With licensed chemical Waste disposal agency. Discharge, treatment, or disposal may be subject to tederel, state or local laws, rseac1%dtIAaaG�sCC=VCr- CCU CCact=xte_ ___ ___ae_c_s=7aL'rRCLVXtit L+It1lAIrUkk0aKMNoaam the information contained herein is furniG404 Without Warranty of any kxpd. Users should consider these data only as a supplement to other information 9at4vred by them and must make indHpendeat determinatiois of the suitability and completeness of iafarnation from all €okrces to assure proper use aril ( disposal of there materials tied the safety and health of employees and customers. `v'aza4RFF.:at7- ;zkeF: •-: '.===== :7.Ze=Z=========:'==--====xSerYh to tt* iltzkbb a bblin ubbb an R togas R-0046.750A 86-8122 0543694-A r"� Engineering and Construction Information for the Non -Discharge Permit Modification Permit No. WQ0004936 Ted Industries New Bern, North Carolina September 15,1995 Prepared for Ted Industries New Bern, North Carolina Prepared by Aquaterra Engineering, Inc. Raleigh, North Carolina ��,,.o��t�, CARUJ . •••.. • .• �,.•,FESS�pN •a SEAL 184 '.`'y /'(•� . I NIL '•.,Ty 1. )ES �7ClUaTLrr7 e n ra i n e e r 1 In ra A GREAT LAKES CHEMICAL CORPORATION COMPANY September 15, 1995 ENGINEERING: POST OFFICE Box 37579 - RALEIGH, NC - 27627-7579 - (919) 859-0608 - FAX (919) 859-6008 Ms. Caroline McCaskill North Carolina Division of Environmental Management Water Quality Section Permits and Engineering Unit Post Office Box 29535 512 North Salisbury Street Raleigh, North Carolina 27626-0535 Reference: Non -Discharge Permit Modification Texfi Industries, Inc. New Bern, North Carolina Aquaterra Engineering Job No. 4401900 Dear Ms. McCaskill: Aquaterra Engineering, Inc. has completed the enclosed non -discharge permit modification on behalf of Texfi Industries, Inc. The permit is accompanied by the reports titled Hydrogeologic Information for the Non -Discharge Permit Modification and Engineering and Construction Information for the Non -Discharge Permit Modification. If you have any questions or require additional information, please do not hesitate to contact me at (919) 859-0608. Sincerely, AQUATERRA ENGINEERING, INC. Pa ick J. Barbeau Staff Engineer Senior Peer Review By Kenneth L. Jesneck, P.E. Senior Engineer/Project Manager 540150/PJB/KL J/dhf cc: Mr. Dale Vincent—Texfi Industries, New Bern, NC Mr. John Tate —Southridge Corporation, Greensboro, NC Mr. Harold Bynum —Smith, Helms, Mullis & Moore, Greensboro, NC CORPORATE HEADQUARTERS: 4901 WATERS EDGE DRIVE, RALEIGH, NC 27606 - (919) 859-9987 - FAX (919) 859-9930 Contents 1 Introduction 1 1.1 Background 1 1.2 Request for Non -Discharge Permit Modification 1 1.3 Existing Recovery, Treatment, and Disposal System 2 1.4 Drinking Water Survey 3 2 Injection Well Design 3 2.1 Injection Well Construction 3 2.2 Operating Parameters 3 2.2 Capture Zone Modeling 4 2.3 Conclusions and Recommendations Based on Modeling Results 4 2.4 Assumptions and Limitations of RESSQC Module 4 2.5 Surface Area Requirements for the Injection Well Screen 5 2.6 Estimated Injection Well Pressure 5 2.7 Mechanical Integrity 5 3 Monitoring and Maintenance 6 3.1 Monitoring Schedule 6 3.2 Maintenance 6 4 References 7 id Non -Discharge Permit Modification Permit No. WQ0004936 Ted Industries New Bern, North Carolina September 15,1995 1 Introduction 1.1 Background Teti Industries (Texi'i) previously owned and operated a fiber manufacturing facility (see Figure 1) located on the northwest side of Stanley Boulevard in New Bern, North Carolina (site). Amital Spinning Corporation (Amital) began operating the facility in August 1986 (see property boundaries delineated in Figure 4). Prior to initiating operations at the facility, Amital contracted Law Engineering to conduct an environmental audit of the site. A preliminary ground water assessment determined that the ground water had been impacted by chlorinated compounds. Chas T. Main (C. T. Main) was subsequently contracted by Teti to address the impacted ground water. C. T. Main conducted a three phase assessment, designed a pump and treat ground water remediation system, obtained the initial non -discharge permit (Permit No. W00004936, issued September 23, 1991), and installed ten recovery wells. Four Seasons Environmental, Inc. (Four Seasons Environmental) was contracted to complete the remaining portion of the ground water remediation system. Only two of the ten recovery wells (RW-8 and RW-11) installed by C. T. Main produced sufficient volumes of ground water to allow effective plume control. Four Seasons Environmental contracted Aquaterra Inc. (Aquaterra) to evaluate and redesign the system of recovery wells. Modifications to Non -Discharge Permit No. WQ0004936 were approved by the Department of Environment, Health, and Natural Resources, Department of Environmental Management (DEM) on August 20, 1992, at which time the remediation system became operational. 1.2 Request for Non -Discharge Permit Modification The current ground water remediation system is designed to operate at a flow rate of 60 gallons per minute (gpm). However, the ground water disposal system, which consist of an infiltration gallery, is only capable of handling a discharge rate of 12 gpm. The low infiltration rate in the infiltration gallery is due to the low permeability of the Post -Miocene sediments that define the soil profile below the gallery. The most feasible method of increasing the capacity of the ground water disposal system is to supplement the existing infiltration gallery with an injection well. This injection well will transfer the treated ground water through the less permeable Post -Miocene sediments and the Yorktown Formation to the Castle Hayne Formation, which has a higher permeability. Hydrogeological data for the site has been enclosed in the Aquaterra, Inc., report entitled Hydrologic Information for the Non -discharge Permit Modification (Hydrologic Report). Page 1 of 7 Texfi, [on -Discharge Permit 540150 September 15, 1995 1.3 Existing Recovery, Treatment, and Disposal System Texfi currently operates a ground water remediation program at the site that began operation August 20, 1992. The ground water restoration program has been in operation for approximately 3 years in accordance with Non -Discharge Permit No. W00004936, which is included in Appendix E of this report. The purpose of the remediation system is to recover and remove chlorinated compounds from the ground water and discharge the treated effluent to the subsurface. The existing ground water recovery system consist of the following extraction wells: Shallow recovery wells RW-4, RW-7, RW-8, and RW-10 Deep recovery well RW-11 There are two waste streams that make up the ground water treatment system (see Figure 3): The primary waste stream consist of the following: • Influent recovered from extraction wells RW-4, RW-7, RW-10, and RW-11. • A holding tank that acts as a combination flow regulator and settling tank for bacterial and chemical precipitates. • Air stripper column No. 1 • Air stripper column No. 2 • Compilation of bag filters, pumps, valves, and sampling ports as shown in Figure 3. The secondary waste stream consist of the following: • Influent recovered from extraction well RW-8. • Carbon Absorption Unit 1 • Carbon Absorption Unit 2 • Compilation of valves and sampling ports as shown in Figure 3. A total of 12 gpm is currently being gravity discharged from the treatment system to a 400 foot long by 3 foot wide by 8 foot deep infiltration gallery (see Figure 4). 1.4 Concentration of Contaminants in the Castle Hayne Formation The August 1986 environmental audit of the site, conducted by Law Engineering, determined that ground water had been impacted by chlorinated compounds including 1,1,1-trichlorethane and 1,1-dichloroethane. Page 2 of 7 Teafi [on -Discharge Permit 540150 September 15, 1995 The July 20, 1995, analysis (SW-846 Method 8240) of the three deep wells (RW-11, MW-13, MW-14) represents contaminant concentrations in the primary waste stream prior to remedial treatment (see Appendix A). The analysis detected chloroethane and 1,1-dichloroethane in RW-11 and MW-13, with the highest concentrations measured in MW-13 at 4.7 parts per billion (ppb) and 12 ppb, respectively (see Figure 5 for deep well VOC plume delineation). Concentrations of treated contaminants in the primary waste stream effluent, that would be discharged to the injection well, have been below detection limits (BDL) since August 27, 1992, as shown in Table 1. 1.4 Drinking Water Survey Aquaterra personnel conducted a door to door drinking water survey of the residents within a quarter mile of the site property boundaries. Of the residents that could be contacted, all verified mandatory use of the public water system. Aquaterra personnel followed this information up by contacting Erik Frank of the New Bern Water Department, Engineering Division. Mr. Frank confirmed that the Washington Forks area, including Craven Community College and area residents were on the city water system. 2 Injection Well Design 2.1 Injection Well Construction The injection well will be constructed with a 6 inch inside diameter, to a depth of approximately 90 feet. The expected injection rate is 50 wpm .(72,000 gallons per day) at an injection pressure of 32.5 pounds per square inch (psi). The well will be constructed with a galvanized steel casing from ground surface to a depth of approximately 40 feet and will be screened for the remaining 50 feet. The well will be grouted from ground surface to a depth of approximately 40 feet. The screen will be constructed of stainless steel, with an inside diameter of 6 inches and have 0.03 inch slots or an open inlet area of approximately 62 square inches per foot of screen. An electric conductivity probe will be located in the injection well, at approximately 10 feet below ground surface. This probe will be wired in such a manner as to shut down the entire treatment system if excessive mounding is detected due to recharge. 2.2 Operating Parameters The proposed injection well is designed to operate at a flow rate approximately equal to the rate at which ground water is being pumped from the Castle Hayne Formation. The deep extraction well (RW-A) located in the Castle Hayne Formation will be pumped at approximately 50 gpm and the injection well will discharge ground water to the subsurface at apFRr- rately 48 to 50 gpm. The 10 gpm recovered from the Yorktown Formation ) will be discharged into the infiltration gallery, leaving a buffer capacity of 2 gpm. Page 3 of 7 Texfi don -Discharge Permit 540150 September 15, 1995 2.2 Capture Zone Modeling To determine if a closed loop system exists between the injection well and the deep extraction well (RW-11), ground water flow lines were mathematically modeled using the software modeling program RESSQC Module of the Wellhead Protection Area (WHPA). This program estimated the effective capture zone associated with the simultaneous pumping and injection of ground water into the Castle Hayne Formation using aquifer parameters obtained from on -site testing as input data see Appendix C). The recovery well was located 212 feet immediately downgradient of the injection well and full capture of the recharged ground water was demonstrated. Site specific input parameters for the RESSQC model were obtained from the hydrogeological data included in the Hydrologic Report. These parameters included a transmissivity of 10,792 square feet per day, an aquifer thickness of 50 feet, and a hydraulic '6 gradient of 0.016 ft/ft. The results of the modeling program indicate that the capture zone associated with the operation of RW-11 will be sufficient to recover the ground water discharged from the injection well provided: The injection well is positioned directly upgradient from the pumping well at a distance no greater than 200 feet. The rate of injection is approximately equal to the rate of recovery 2.3 Conclusions and Recommendations Based on Modeling Results Analysis of the modeling results generated from the RESSQC, WHPA program suggest that a conservative spacing between the injection well and the recovery well would be approximately 100 to 150 feet. The injection well will be located immediately upgradient of the recovery well as shown in Figure 2, for complete capture of the discharged ground water to occur. The estimated pumping rate of 50 gallons per minute (gpm) from RW-11 was used as a single variable in the RESSQC module to determine the sensitivity between the rate of recovery and closed loop capacity of the system. Complete capture was shown to occur at a recovery rate of 30 gpm (see Appendix C), while the recharge rate remained at 50 gpm. This data shows that small variations between the pumping rate and injection rate will not significantly effect the capture zone. However, the system has been designed such that the rate of injection and the rate of recovery are both approximately 50 gpm. 2.4 Assumptions and Limitations of RESSQC Module The RESSQC module included in the WHPA program can be used to delineate time related capture zones for a system of one or more pumping/injection wells that fully penetrate a isotropic, homogeneous aquifer. Ground water flow must be two dimensional in the x-y plane, and therefore the aquifer may be confined or unconfined if the drawdown-to-initial saturated thickness ratio is small. Steady ground water flow is assumed. Page 4 of 7 Texfi ion -Discharge Permit 540150 September 15, 1995 2.5 Surface Area Requirements for the Injection Well Screen The maximum recommended entrance velocity for an injection well is 0.05 feet per sec (ft/s) according to Driscoll, 1986. The screened surface area required for safe discharge of ground water into the surrounding aquifer was evaluated using the following conditions: Maximum flow rate of 50 gpm 6 inch inside diameter screen 50 foot length of screen with an intake area of approximately 62 inches of open inlet area per foot of the screen (0.03 inch slots). Based on the maximum flow rate and the recommended entrance velocity, the minimum open surface area of the proposed injection well is approximately 2.2 square feet (see Appendix D). The actual open area available for discharge of ground water to the surrounding aquifer was calculated using a 50 foot screened zone, with an intake area of 62 inches of open area per foot of screen (0.03 inch slots). The resulting available discharge surface area is 21.6 square feet. Since the anticipated available open area in the injection well is greater than the minimum required by a factor of 10, the proposed injection well should adequately handle the estimated entrance velocity. 2.6 Estimated Injection Well Pressure The pressure used to inject the effluent into the Castle Hayne formation must overcome the existing hydrostatic forces present below the ground surface. This hydrostatic force can be determined by multiplying the estimated water column that would exist between the bottom of the proposed injection well and the mean high seasonal water table (approximately 60 feet) times the unit weight of water (0.0361 pounds per cubic inch). The resulting hydrostatic force that must be overcome by the injection pressure is 26 pounds per square inch (psi). As a conservative measure the injection pressure has been increased by 25 percent to 32.5 psi or 4,680 pounds per square foot (see Appendix D for calculations). 2.7 Mechanical integrity The consolidation pressure of the Castle Hayne aquifer was calculated to determine if the proposed injection well would present a fracture risk to the aquifer (see Appendix D). The consolidation pressure was calculated using the summation of the individual stratum unit weights multiplied by the corresponding stratum thicknesses. The total consolidation pressure for the Castle Hayne aquifer, to a depth of 90 feet, is 16,328 pounds per square foot (psf). The injection pressure required to overcome the hydrostatic forces of the ground water is 4,680 psf (see Section 2.6). Since the consolidation pressure is greater than the injection pressure by a factor of approximately 3.5, the risk of fracture to the Castle Hayne aquifer is minimal. Page 5 of 7 Texfi [on -Discharge Permit 540150 September 15, 1995 Mounding of ground water in the injection well due to recharge is not expected to be a problem. Pumping test of the deep wells (RW-11, MW-13, MW-14) in the Castle Hayne formation indicated draw down of less than 1.2 feet in the wells, at a pumping rate of 51 gpm (see Hydrologic Report). As a safety precaution, an electric conductivity probe will be located in the injection well, at approximately 10 feet below ground surface. This probe will be wired in such a manner as to shut down the entire treatment system if excessive mounding is detected due to recharge. 3 Monitoring and Maintenance 3.1 Monitoring Schedule The existing monitoring wells will be adequate to assess the impact of the discharge on the quality of the underlying ground waters. The monitoring wells surrounding the injection well will be monitored for water level fluctuations on a monthly basis for the first three months immediately following the activation of the injection well, and then a semiannual basis. The injection well will be monitored for flow rate and mounding on a weekly basis for the first month of operation, monthly for the following 5 months, and then on a semiannual basis. The quarterly sampling schedule currently in effect at the site will be sufficient to monitor any impact the injection well may have on plume delineation. However, an additional sampling port will be added (see Figure 3) on the effluent line designated for injection well discharge so that the treated effluent can be monitored prior to discharge to the injection well. 3.2 Maintenance Bacterial and chemical precipitates have significantly hindered the operation of the remediation system at the site. A holding tank, currently in place on the system, receives influent from the recovery wells and acts as a combination flow regulator and settling tank. However, this has not proven to be an effective deterrent to deposit buildup within the treatment system and precipitate removal is frequently required. In addition, reduced recovery rates have been noticed from the pumping wells due to screen clogging. Therefore the following maintenance program has been proposed. The maintenance program for the injection well and existing extraction wells will consist of periodic treatments with a diluted organic acid wash (hydroxyacetic or acetic acid). Documentation of this proposed maintenance program has been included in Appendix B. The use of hydrochloric acid and sodium hypochlorite solutions to remove bacterial and chemical precipitates has been reviewed, but the possibility of chloroform generation during maintenance activities makes this an objectionable alternative. Page 6 of 7 Texf don -Discharge Permit 540150 September 15, 1995 The suggested maintenance program consist of the addition of 1 gallon of 70 percent acid per 10 to 15 gallons of standing well water. The mixture would be agitated with a surge block every 2 hours for a total of 8 hours. The mixture would then be purged from the well and transferred to the treatment system for neutralization. The frequency of treatments would be based on observed recovery well draw down rates and injection well mound measurements. 4 References Das, B.M., 1990, Principles of Geotechnical Engineering, Second Edition: PWS KENT, Boston, Massachusetts, pp 43, pp 110 - 112. Page 7 of 7 m4g a3 � A 43, i ub to\ V sa •ass // • e / I �. - /i r /r washing 1 d orks ' QUAR SITE 15 a 1 13 17 f I 7'30" 307 a�g 25 FEET " vF Coca 2� M ,10 5' 1 SCALE 1:24 000 2 0 1 MILE i�gr y�r �c.�+1KIUV, N.C. 100 0 1000 2" 3000 4000 5000 6000 7000 FE£T NE/4 NEW BERN 15. OUADRANOLE 1 .5 0 1 KILOMETER 35077-81-TF-024 uthor Drawing Layers Date Title Site Location Map PJB 7C.1UaTerr7Job No V o9/14/95 . Revision Figure Scale Project Teas$ Industries, Irre. a n o i n a e r i n a. one . ass,. 1 Shown New Berrl, North Carolina A GREAT LAKES CHEMICAL CORPORATION COMPANY 4401900 'e MW-1 MW-2 Existing Treatment System .K MW-4 M W-3 0 RW-8 Infiltration / Gallery MW-9*05 MW-2aq,,� ® Q MW-14 MW-13A ® RW-11 MW-12 0 Bosch Boulevard MW-11 0RW-1 O RW-2 QRW-3 �RW-4 MW-10 M W-10a RW-5 .c_i RW-6 RW-7a4b 46 RW-7 Legend ,j,, Shallow Monitoring Well Recovery Well S] Deep Monitoring Well ® Proposed Injection Well _ iqet u� T e r r a ■ncin••rina, inc.� A GREAT LAKES CHEMICAL CORPORATION COMPANY Author LSG L)rawLng 44019-2 LayerS 0,1,2 I.)ate 6-02-93 Jau.e Site Map Job No. 4401900 Revision 9-15-95 Figure 2 Scale 1" = 200' Project TexfiIndustries,Inc. New Bern, North Carolina / Bd1Ang Trodmant 8ystwn i R , lq��EESStO�; i S€AL 18498 Y U� ,f Xz� Rs"nm Mto A=m and Id.nt/Jicatton on Aynrent Dated 9/25/VO P►ovided try 9m4O4 /lelmz m.MUUJS t AkoM LLA Inlira6m Y Lap,nd - — - - T.0 Property Una ------ L-ead by M+td from T.9 to Injection Point — 50 Pant Propwy Lin. B ft, ,?, MW-1 MW-2 Existing Treatment System ,,, MW-4 >- MW-3 0 RW-8 Infiltration / Gallery --� MW-990 MW-2a _. 0 MW-14 0 / _(BDL) El MW-13A ® RW-11 (16.7) (12.5) BDL— MW-12 Author Nift IqQUMTerriq JobNo.G nQ1n!!flnc. 1nC.� A GREAT LAKES CHEMICAL CORPORATION COMPANY 4401900 MW-11 0RW-1 O RW-2 0RW-3 )RW-4 MW-10 MW-10a RW-5 ® RW-6 RW-7a0, RW-7 Legend 0 Shallow Monitoring Well ® Recovery Well 0 Deep Monitoring Well (12.5) Total VOCs Bosch Boulevard ��- VOC Contour Line (Dashed Where Inferred) )raving Layers Date Title Deep Well Total VOC Map 44019-2 0,1,10 6-02-93 Zevision Figure Scale Project Texfi Industries, Inc. 9-15-95 5 V = 200' New Bern, North Carolina Table 1 Primary Waste Stream Analytical Results Dates Sampled 8/27/92 11/17/92 12/29/92 3/2/93 Compounds influent effluent influent effluent influent I effluent influent effluent 1,1 - Dichloroethane 1,000 BDL BDL BDL 590 BDL 410 BDL Acetone BDL BDL BDL BDL BDL BDL BDL BDL 2 - Butanone BDL BDL BDL BDL BDL BDL BDL BDL Chloroethane BDL I BDL BDL BDL I BDL BDL BDL BDL BDL - Below Quantitative Limits Dates Sampled 6/2/93 3/25/94 6/15/94 1/12/95 Compounds influent effluent influent effluent influent effluent influent effluent 1,1-Dichloroethane 1,000 BDL 820 BDL 440 BDL 2,100 BDL Acetone BDL BDL BDL BDL BDL BDL BDL BDL 2 - Butanone I BDL BDL BDL BDL BDL BDL BDL BDL Chloroethane I BDL I BDL BDL BDL I BDL I BDL BDL BDL BDL - Below Quantitative Limits Page 1 Post Office Box 5 Research Trianc rk, NC 27709 Phone 919.677.0090 Fax 919.677.0427 IEA An Aquarion Company June 30, 1995 Kent White Aquaterra, Inc. 4901 Water's Edge Drive Raleigh, NC 27606 IEA Project No.: IEA Reference No.: Client Project I.D.: Dear Mr. White, 196658/9506442 W9506381 4101003 Transmitted herewith are the results of analyses on four samples submitted to our laboratory. The sample(s) were received intact. Analyses were performed according to approved methodologies and meet the requirements of the IEA Quality Assurance Program except where noted. Please see the enclosed reports for your results and a copy of the Chain of Custody documentation. Thank you for selecting IEA for your sample analysis. Please do not hesitate to call your project manager representative at 1-919-677-0090 or 1-800-444-9919 should you have any questions regarding this report. We look forward to serving you in the future. Very truly yours, IEA, Inc. /C-- William R. Drago Laboratory Director Monroe, Sunrise, Schaumburg, N. Billerica, Whippany, Connecticut Florida Illinois Massachusetts New Jersey 203.261 4458 305-846-1730 708-705.0740 508-667.1400 201-428-8181 :n recycled pacer M mffl 1EA An Aquarion Company IEA-NORTH CAROLINA CERTIFICATIONS Alabama DW 40210 California DW, WW, HW 1-1035,1768 Radiolog. 1-1018 (Rad) Connecticut DW, WW PH-0135 Florida DW 87350 WW E87439 (CompQAP) QAP#930007G Georgia DW None Kansas DW, HW, WW E-158 (DW, WW) E-1189 (HW) Kentucky DW 90049 Massachusetts DW, WW M-NC039 New Jersey DW, WW 67719 Radiolog. 67681 New York Radiolog. 11422 North Carolina DW DW 37720 WW WW 84 Radiolog. Rad 37720 South Carolina DW 99021 WW HW Tennessee DW 02914 UST App List Utah Radiolog. E-206 RCRA E-226 Virginia DW 00179 West Virginia DW 9908C Wisconsin WW 998051010 DW=Drinking Water WW=Wastewater HW=Hazardous Waste Radiolog.=Radiological R- 01O j Industrial & Environmental Analysts, Inc. (IEA) PURGEABLE HALOCARBONS EPA 601 COMPOUND LIST IEA Project Number: 196-658 Date Received: 06/21/95 IEA Sample Number: 9506442-01 Date Sampled: 06/20/95 Client Name: Aquaterra Inc. Date Analyzed: 06/27/95 Client Project ID: 4101003 Analysis By: Collins Sample Identification: RW-11 Dilution Factor: 1.0 Matrix: Water Quantitation Results Limit Concentration Number Compound (ug/L) (ug/L) 1 Chloromethane 1.0 BQL 2 Bromomethane 1.0 BQL 3 Vinyl Chloride 1.0 BQL 4 Dichlorodifluoromethane 1.0 BQL 5 Chloroethane 1.0 2.5 6 Methylene chloride 1.0 BQL 7 Trichlorofluoromethane 1.0 BQL 8 1,1-Dichloroethene 1.0 BQL 9 1,1-Dichloroethane 1.0 10 10 trans-1,2-Dichloroethene 1.0 BQL 11 Chloroform 1.0 BQL 12 1,2-Dichloroethane 1.0 BQL 13 1,1,1-Trichloroethane 1.0 BQL 14 Carbon tetrachloride 1.0 BQL 15 Bromodichloromethane 1.0 BQL 16 1,2-Dichloropropane 1.0 BQL 17 cis-1,3-Dichloropropene 1.0 BQL 18 Trichloroethene 1.0 BQL 19 trans-1,3-Dichloropropene 1.0 BQL 20 1,1,2-Trichloroethane 1.0 BQL 21 Dibromochloromethane 1.0 BQL 22 2-Chloroethylvinyl ether 1.0 BQL 23 Bromoform 1.0 BQL 24 Tetrachloroethene 1.0 BQL 25 1,1,2,2-Tetrachloroethane 1.0 BQL 26 Chlorobenzene 1.0 BQL 27 1,3-Dichlorobenzene 1.0 BQL 28 1,2-Dichlorobenzene 1.0 BQL 29 1,4-Dichlorobenzene 1.0 BQL Comments: Qualitative identifications performed using second GC column confirmation. Sample specific quantitation limits may be calculated by multiplying the quantitation limit by the dilution factor. BQL = Below Quantitation Limit FORM 601 REV. 020494 Industrial & Environmental Analysts, Inc. (IEA) PURGEABLE HALOCARBONS EPA 601 COMPOUND LIST IEA Project Number: 196-658 Date Received: 06/21/95 IEA Sample Number: 9506442-02 Date Sampled: 06/20/95 Client Name: Aquaterra Inc. Date Analyzed: 06/27/95 Client Project ID: 4101003 Analysis By: Collins Sample Identification: MW-13 Dilution Factor: 1.0 Matrix: Water Quantitation Results Limit Concentration Number Compound (ug/L) (ug/L) 1 Chloromethane 1.0 BQL 2 Bromomethane 1.0 BQL 3 Vinyl Chloride 1.0 BQL 4 Dichlorodifluoromethane 1.0 BQL 5 Chloroethane 1.0 4.7 6 Methylene chloride 1.0 BQL 7 Trichlorofluoromethane 1.0 BQL 8 1,1-Dichloroethene 1.0 BQL 9 1,1-Dichloroethane 1.0 12 10 trans-1,2-Dichloroethene 1.0 BQL 11 Chloroform 1.0 BQL 12 1,2-Dichloroethane 1.0 BQL 13 1,1,1-Trichloroethane 1.0 BQL 14 Carbon tetrachloride 1.0 BQL 15 Bromodichloromethane 1.0 BQL 16 1,2-Dichloropropane 1.0 BQL 17 cis-1,3-Dichloropropene 1.0 BQL 18 Trichloroethene 1.0 BQL 19 trans-1,3-Dichloropropene 1.0 BQL 20 1,1,2-Trichloroethane 1.0 BQL 21 Dibromochloromethane 1.0 BQL 22 2-Chloroethylvinyl ether 1.0 BQL 23 Bromoform 1.0 BQL 24 Tetrachloroethene 1.0 BQL 25 1,1,2,2-Tetrachloroethane 1.0 BQL 26 Chlorobenzene 1.0 BQL 27 1,3-Dichlorobenzene 1.0 BQL 28 1,2-Dichlorobenzene 1.0 BQL 29 1,4-Dichlorobenzene 1.0 BQL Comments: Qualitative identifications performed Sample specific quantitation limits ma the quantitation limit by the dilution BQL = Below Quantitation Limit FORM 601 REV. 020494 using second GC column confirmation. y be calculated by multiplying factor. Industrial & Environmental Analysts, Inc. (IEA) PURGEABLE HALOCARBONS EPA 601 COMPOUND LIST IEA Project Number: 196-658 Date Received: 06/21/95 IEA Sample Number: 9506442-03 Date Sampled: 06/20/95 Client Name: Aquaterra Inc. Date Analyzed: 06/27/95 Client Project ID: 4101003 A Analysis By: Collins Sample Identification: RW- ,4 (V) W 144 Dilution Factor: 1.0 Matrix: Water Quantitation Results Limit Concentration Number Compound (ug/L) (ug/L) 1 Chloromethane 1.0 BQL 2 Bromomethane 1.0 BQL 3 Vinyl Chloride 1.0 BQL 4 Dichlorodifluoromethane 1.0 BQL 5 Chloroethane 1.0 BQL 6 Methylene chloride 1.0 BQL 7 Trichlorofluoromethane 1.0 BQL 8 1,1-Dichloroethene 1.0 BQL 9 1,1-Dichloroethane 1.0 BQL 10 trans-1,2-Dichloroethene 1.0 BQL 11 Chloroform 1.0 BQL 12 1,2-Dichloroethane 1.0 BQL 13 1,1,1-Trichloroethane 1.0 BQL 14 Carbon tetrachloride 1.0 BQL 15 Bromodichloromethane 1.0 BQL 16 1,2-Dichloropropane 1.0 BQL 17 cis-1,3-Dichloropropene 1.0 BQL 18 Trichloroethene 1.0 BQL 19 trans-1,3-Dichloropropene 1.0 BQL 20 1,1,2-Trichloroethane 1.0 BQL 21 Dibromochloromethane 1.0 BQL 22 2-Chloroethylvinyl ether 1.0 BQL 23 Bromoform 1.0 BQL 24 Tetrachloroethene 1.0 BQL 25 1,1,2,2-Tetrachloroethane 1.0 BQL 26 Chlorobenzene 1.0 BQL 27 1,3-Dichlorobenzene 1.0 BQL 28 1,2-Dichlorobenzene 1.0 BQL 29 1,4-Dichlorobenzene 1.0 BQL Comments: Qualitative identifications performed Sample specific quantitation limits ma the quantitation limit by the dilution BQL = Below Quantitation Limit FORM 601 REV. 020494 using second GC column confirmation. y be calculated by multiplying factor. Industrial & Environmental Analysts, Inc. (IEA) PURGEABLE HALOCARBONS EPA 601 COMPOUND LIST IEA Project Number: 196-658 Date Received: 06/21/95 IEA Sample Number: 9506442-04 Date Sampled: 06/20/95 Client Name: Aquaterra Inc. Date Analyzed: 06/27/95 Client Project ID: 4101003 Analysis By: Collins Sample Identification: PW-1 Dilution Factor: 1.0 Matrix: Water Quantitation Results Limit Concentration Number Compound (ug/L) (ug/L) 1 Chloromethane 1.0 BQL 2 Bromomethane 1.0 BQL 3 Vinyl Chloride 1.0 BQL 4 Dichlorodifluoromethane 1.0 BQL 5 Chloroethane 1.0 1.9 6 Methylene chloride 1.0 BQL 7 Trichlorofluoromethane 1.0 BQL 8 1,1-Dichloroethene 1.0 BQL 9 1,1-Dichloroethane 1.0 11 10 trans-1,2-Dichloroethene 1.0 BQL 11 Chloroform 1.0 BQL 12 1,2-Dichloroethane 1.0 BQL 13 1,1,1-Trichloroethane 1.0 BQL 14 Carbon tetrachloride 1.0 BQL 15 Bromodichloromethane 1.0 BQL 16 1,2-Dichloropropane 1.0 BQL 17 cis-1,3-Dichloropropene 1.0 BQL 18 Trichloroethene 1.0 BQL 19 trans-1,3-Dichloropropene 1.0 BQL 20 1,1,2-Trichloroethane 1.0 BQL 21 Dibromochloromethane 1.0 BQL 22 2-Chloroethylvinyl ether 1.0 BQL 23 Bromoform 1.0 BQL 24 Tetrachloroethene 1.0 BQL 25 1,1,2,2-Tetrachloroethane 1.0 BQL 26 Chlorobenzene 1.0 BQL 27 1,3-Dichlorobenzene 1.0 BQL 28 1,2-Dichlorobenzene 1.0 BQL 29 1,4-Dichlorobenzene 1.0 BQL Comments: Qualitative identifications performed using second GC column confirmation. Sample specific quantitation limits may be calculated by multiplying the quantitation limit by the dilution factor. BQL = Below Quantitation Limit FORM 601 REV. 020494 Industrial & Environmental Analysts, Inc. (IEA) PURGEABLE HALOCARBONS EPA 601 COMPOUND LIST IEA Project Number: 196-658 Date Received: IEA Sample Number: 9506442 Date Sampled: Client Name: Aquaterra Inc. Date Analyzed: Client Project ID: 4101003 Analysis By: Sample Identification: QC Blank(VO5BK45W) Dilution Factor: Matrix: Water Number Compound Quantitation Limit (ug/L) N/A N/A 06/26/95 Eischen 1.0 Results Concentration (ug/L) 1 Chloromethane 1.0 BQL 2 Bromomethane 1.0 BQL 3 Vinyl Chloride 1.0 BQL 4 Dichlorodifluoromethane 1.0 BQL 5 Chloroethane 1.0 BQL 6 Methylene chloride 1.0 BQL 7 Trichloroflucromethane 1.0 BQL 8 1,1-Dichloroethene 1.0 BQL 9 1,1-Dichloroethane 1.0 BQL 10 trans-1,2-Dichloroethene 1.0 BQL 11 Chloroform 1.0 BQL 12 1,2-Dichloroethane 1.0 BQL 13 1,1,1-Trichloroethane 1.0 BQL 14 Carbon tetrachloride 1.0 BQL 15 Bromodichloromethane 1.0 BQL 16 1,2-Dichloropropane 1.0 BQL 17 cis-1,3-Dichloropropene 1.0 BQL 18 Trichloroethene 1.0 BQL 19 trans-1,3-Dichloropropene 1.0 BQL 20 1,1,2-Trichloroethane 1.0 BQL 21 Dibromochloromethane 1.0 BQL 22 2-Chloroethylvinyl ether 1.0 BQL 23 Bromoform 1.0 BQL 24 Tetrachlorcethene 1.0 BQL 25 1,1,2,2-Tetrachloroethane 1.0 BQL 26 Chlorobenzene 1.0 BQL 27 1,3-Dichlorobenzene 1.0 BQL 28 1,2-Dichlorobenzene 1.0 BQL 29 1,4-Dichlorobenzene 1.0 BQL Comments: Qualitative identifications performed using second GC column confirmation. Sample specific quantitation limits may be calculated by multiplying the quantitation limit by the dilution factor. BQL = Below Quantitation Limit N/A = Not Applicable Corresponding Samples: 9506442-01 through 04 FORM 601 REV. 020494 Industrial & Environmental Analysts, Inc. (IEA) EPA METHOD 601 WATER VOLATILE MATRIX SPIKE/MATRIX SPIKE DUPLICATE RECOVERY IEA Project No.: 196-658 IEA Reference No: 9506467-11 SPIKE SAMPLE MS MS QC ADDED CONCENTRATION CONCENTRATION % LIMITS COMPOUND (ug/L) (ug/L) (ug/L) REC # REC 1,1-Dichloroethene 20 BQL 17 85 28-167 Trichloroethene 20 BQL 13 65 35-146 Chlorobenzene 20 BQL 16 80 48-150 SPIKE MSD MSD ADDED CONCENTRATION % % QC LIMITS (ug/L) (ug/L) REC # RPD # RPD REC 1,1-Dichloroethene 20 18 90 6 15 28-167 Trichloroethene 20 14 70 7 15 35-146 Chlorobenzene 20 16 80 0 15 48-150 Comments: Corresponding Samples: 9506442-01 through 04 FORM 601W-MS.WK1 REV 030994 Industrial & Environmental Analysts, Inc. (IEA) WATER VOLATILE SURROGATE RECOVERY EPA Method 601 IEA Project No.: 196-658 Sample ID SURR 1 % Recovery VO5BK45W 116 9506467-11MS 78 9506467-11MSD 85 9506442-01 140 9506442-02 120 9506442-03 106 9506442-04 128 QC Limits S1 = 1,4-Dichlorobutane (60-140) tllh \-�acivaTerra A GREAT LAKES CHEMICAL CORPORATION COMPANY PROJECT NAME: _4--' a REPORT TO: ADDRESS: AFFILIATION/ OCATION: 0 1? lA-) 1� p ( I, - JOB NUMBER: PHONE: H\010D3 SAMPLED BY (PRINT): NUMBER OF C' j\ CHAIN -OF -CUSTODY RECORD ANALYTICAL REQUEST NO. 2103 TURNAROUND: UAOIRMAL n 5-DAY [] OTHER (SPECIFY): REQUESTED DUE DATE: P.O. # / BILLING REFERENCE: ra r ANALYSES REQUEST 7 / 7-7-7-7-1-1- SAMPIER'S ATURE: 0 > C4 0 0 z Y I N 33 2 q vi ADDITIONAL COMMENTS: RELINQUISHED BY AFFILIATION ACCEPTED BY z, 1491ITr 1!•RrW +Tnl'Y PfPr)PT (-OPY PINK IAPnRATr)RY CnPY CANARY SAMPIFR'S COPY REMARKS Hawley's Condensed Chemical Dictionary TWELFTHEDITION Revised by Richard J. Lewis, Sr. ® VAN NOSTRAND REINHOLD COMPANY New York )perry is char - as algin, vege- , a: of com- oll: n. ter, incapable rt, ' charac- rr y resins, rs ! carbon in( p-dihy- C _ 4(OH)2- in water, alco- C• hp 285C; pe ure 960F o quinone by educed to hy- halation, irri- pt or film); liz in paints Is; _.ioxidant lymerization; p _ _nzyloxy- 1 -16-2. (min); purity ;ohd-ie in ace- e. ombusti- tics, and phar- (1, libutoxy- o appreciable nn Lg), 158C ter: aluble in anu alcohol. 1-d hoxyben- with anise -like feit r boiling .ny tdrolysis. ate-, .;oluble in and alcohol. 619 hydroquinone dio-hydroxyethyl) ether. (p-di-[2-hydroxyethoxy]benzene). C6H,(OC2H2OH)2. Properties: White solid, mp 99C, by 185-200C (0.3 min Hg), slightly soluble in water and most organic solvents, miscible with water at 80C. Combustible. Use: Preparation of polyester, polyolefins, poly- urethanes, and hard waxy resins, organic syn- thesis. hydroquinone dimethyl ether. (1,4-dimethoxy- benzene; DMB; dimethyl hydroquinone). CAS:654-42-2. C6H4(OCH3)2• Properties: White flakes with sweet clover odor, by 213C, mp 56C, d 1.0293 (65C), viscosity 1.04 cP (65C), dielectric constant 2.8, absorbs UV light in range 2800-3000A, soluble in benzene and alcohol, insoluble in water. Combustible. Use: Weathering agent in paints and plastics, fix- ative in perfumes, dyes, resin intermediate, cos- metics, especially suntan preparations, flavor- ing. hydroquinine mono-n-butyl ether. CH3(CH2)3OC6H2OH. Properties: White flakes; mp 64-65C; by 115C (1.4 min Hg); insoluble in water; soluble in ben- zene, acetone, ethyl acetate, and alcohol. Com- bustible. hydroquinone monoethyl ether. (4-ethoxy- phenol). C2H5OC6H40H. Properties: White solid; mp 63-65C; by 246- 247C; slightly soluble in water; soluble in ben- zene, acetone, ethyl acetate, and alcohol. Com- bustible. Use: See hydroquinone monomethyl ether. hydroquinone monomethyl ether. (4-methoxy- phenol; p-hydroxyanisole). CAS: 150-76-5. CH3OC6H2OH. Properties: White, waxy solid; mp 52.5C; by 243C; d 1.55 (20/20C); slightly soluble in water; readily soluble in benzene, acetone, ethanol, i ethyl acetate. Combustible. Use: Manufacture of antioxidants, pharmaceuti- cals, plasticizers, dyestuffs; stabilizer for chlori- nated hydrocarbons and ethyl cellulose, inhibi- tor for acrylic monomers and acrylonitriles, UV inhibitor: hydrosilicofluoric acid. See fluosilicic acid. hydrosolvation. Solvent extraction of coal (con- taining up to 5% sulfur) under hydrogen pres- sure with the use of a catalyst such as zinc chlo- ride; pressures from 1000-2000 psi are necessary for suitable conversion. This process offers a means of deriving fuel oil and petrochemical feedstocks directly from coal: o-HYDROXYACETOPHENONE hydrosulfite. See sodium hydrosulfite. hydrosulfite-formaldehyde. One of several mix- tures of sodium formaldehyde hydrosulfite and sodium formaldehyde bisulfite used as dis- charges and stripping or reducing agents in dye- ing and other textile operations. In some cases the zinc derivatives are used. Derivation is by the action of formaldehyde on aqueous sodium hy- drosulfite or from zinc, formaldehyde, sulfur di- oxide, and sodium hydroxide. Hazard: Toxic by ingestion: hydrothermal energy. See geothermal energy. "Hydrotriticum" [Croda]. (hydrolyzed vegeta- ble proteins). TM for wheat protein. Use: For hair waving systems, shampoos, condi- tioners, and skin -care products. hydrotrope. A chemical that has the property of increasing the aqueous solubility of various slightly soluble organic chemicals. Use: Formulation of liquid detergents. hydroxocobalamin. (USAN) (a[5,6-dimethylben- zimidazolyl] hydroxocobaltamide). C62HayCoN13015P. A form of vitamin B12. Use: Medicine. See vitamin B12- hydroxyacetal. See hydroxycitronellal dimethyl acetal: p-hydroxyacetanilide. See p-acetylaminophenol. hydroxyacetic acid: (glycolic acid). CH20HCOOH:- Properties: Colorless crystals, deliquescent, mp 78-79C, by decomposes. Soluble in water, alco- hol, and ether; available commercially as a 7007o solution, light straw-colored liquid, odor like burnt sugar, d 1.27, mp IOC. Combustible. Derivation: From chloroacetic acid by reaction with sodium hydroxide, or by reduction of oxa- lic acid. Occurs naturally in sugar cane syrup. Grade: Technical 7007o solution, pure crystals. Use: Leather dyeing and tanning; textile dyeing; cleaning, polishing, and soldering compounds; cop- per pickling; adhesives; electroplating; breaking of petroleum emulsions; chelating agent for iron; chemical milling; pH control. hydroxyacetone. See hydroxy-2-propanone. o-hydroxyacetophenone. C6H4(OH)COCH3. Properties: Greenish -yellow liquid with minty odor, d 1.1307 (20.8C), by 213C (717 min), refr index 1.5580 (20C), slightly soluble in water. Combustible. Non -Discharge Permit No. WQ0004936 Texfi Industries New Bern, North Carolina March 10,1992 Prepared For North Carolina Department of Environment, Health and Natural Resources Raleigh, North Carolina Prepared By Aquaterra, Inc. Raleigh, North Carolina Ua Luc 25 ,992 CENTRAL FILES AQUATERRA `_ d7W ,I AQ LLATERPA Environmental Consultants March 10, 1992 Mr. Donald L. Safrit, P.E. North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Post Office Box 27687 Raleigh, North Carolina 27611-7687 Re ference: Non -Discharge Permit No. W00004936 Texfi Industries New Bern, North Carolina Facility Aquaterra Job No. 778 Dear Mr. Safrit: Aquaterra, Inc. (Aquaterra) has been asked by Texfi Industries and their remediation contractor to assess the ground water conditions at the referenced site. During this assessment activity, two major characteristics used in developing the original ground water remediation plan and subsequent Non -Discharge permit application have changed. Because of these site characteristic changes, Aquaterra on behalf of Texfi Industries is requesting two permit modifications to the existing permit. Modification No.1 The original remediation plan and permit included ground water removal from 00) one gallon per minute (gpm) shallow recovery wells and (one) 50 gpm intermediate recovery well. Because of a significant drop in ground water table depth, all but four of the shallow wells will need to be abandoned. Three of the remaining shallow wells will require redrilling before they are usable. This redrilling is necessary to provide a sufficient depth of ground water in these wells for four -inch diameter submersible ., W-4a, RW-7a, and RW-10a. These three wells will pumps. These three wells are R be combined with the original 50 gpm recovery well, RW-11, to capture the existing ground water contaminant plume. The fourth shallow well, RW-8, will be used to recover ground water impacted by the past release of Dowtherm heat transfer fluid. The extracted ground water from this well will be treated by activated carbon adsorption. Two 170-pound carbon canisters connected in series will be used to treat the round water from ,this W ddl� lusively. g .. -? The carbon is required to adsorb the Dowtherm constituents, 5 1992 Greensboro OfFic Corporate Office Charlotte Office P. O. Box 1624 P. O. Box 50328 P. O. Box 668107 tcnsboro, NC 2741 ftalcigh, NC 27650 Charlotte, NC 28266.8107 t+` `\1 (: 1ro NC 5003 (919) 859-9987 (704) 525-8680 rVA FAX () 2 -5003 FAX (919) 859-9930 FAX (704) 527-2792 Texfi Permit Modification L2471-92 March 10, 1992 Page 2 las hodification No. 2 The second modification involves the deletion of the proposed metal treatment/removal system from the permit. Aquaterra has reviewed the data collected by C.T. Main and concluded that only one round of samples collected and analyzed were used to determine the need for the metal treatment system. Of these samples, only three wells, MW-3, MW-4a, and MW-8, had nickel readings above the state's GA standards for nickel (0.15 parts per million). Only one well, MW-8, was equal to the same GA standards for zinc (5.0 parts per million). Aquaterra recently completed a pumping test of the new extraction wells, RW-4a, RW-7a, and RW-10a. During the pumping test, both discrete and composite samples were collected to determine the levels of nickel and zinc in the extracted ground water. The samples were analyzed by EPA Method 200.7 (see Table 1). Based on the results of this sampling and the low levels of zinc and nickel present in the earlier C. T. Main work, Aquaterra is requesting the deletion, at least temporarily, of the metal treatment/removal system. To monitor the effluent metal levels, Aquaterra is recommending changing Permit Condition IV.3. to monthly effluent water sampling for metals for the first 12 months of remediation system operation. If the sample results do not indicate an increase the levels of nickel and zinc, the sampling would change to quarterly for one year, and then eventually to semiannual sampling. If the sampling indicates an increase in the metal levels above the GA standards, Texfi would stop remediation until the high metal levels could be treated by adding the capability to the overall remediation system. To make review of these requests as simple as possible, Aquaterra is including the original permit and a completed DEM form LLPG 4/91 as attachments. If you have any questions on the above modification requests, please do not hesitate to contact us at (919) 859-9987. Sincerely, AQUATERRA, INC. ���.o��N.CP�R Bruce D. Reill .E. 15532 Senior Project Manager :,6'�G :•Fly! �iL 4°�;; "� BDR/pjc cc: Mr. Michael Miller - Texfi Industries Mr. Harold Bynum - Smith, Helms, Mulliss & Moore AUG 25 1992 CENTRAL FILES AQUATERRA F X= = Table 1. Ground Water Analytical Results. Well No. Nickel Zinc .RW-4a <0.03 <0.02 <0.02 RW-7a <0.03 <0.03 0.06 RW-10 Composite <0.03 0.04 WQsi 0.15 5.0 1 Water Quality Standard (MA: 02L .0202(g)) Analytical Laboratory: Industrial & Environmental Analysts, Inc. Cary, North Carolina Aquaterra Job No. 778 L2471-92 7 f" L E L r L I F r L I I r State of North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Non -Discharge Permit Application (THIS FORM MAYBE PHOTOCOPIED FOR USE AS AN ORIGINAL) SEPTIC TANK / LOW PRESSURE PIPE / GRAVITY SUBSURFACE DISPOSAL SYSTEMS [FOR MECHANICAL TREATMENT SYSTEMS WITH SUBSURFACE DISPOSAL USE FORM MTDSI (THE DIVISION OF ENVIRONMENTAL MANAGEMENT HAS JURISDICTION IF THE SYSTEM TREATS INDUSTRIAL WASTEWATER OR IF THE SYSTEM IS OWNED BY A SANITARY DISTRICT, A METROPOLITAN SEWAGE DISTRICT, A WATER & SEWER AUTHORITY, A COUNTY, A MUNICIPALITY, OR A PUBLIC UTILITY. THE DIVISION OF ENVIRONMENTAL HEALTH HAS JURISDICTION FOR OTHER DOMESTIC SUBSURFACE SYSTEMS) I. GENERAL INFORMATION: _ 1. Applicant (corporation, individual, or other): Texfi Industries, Inc. 2. Print Owners or Signing Official's Name and Title (the person who is legally responsible for the facility and its compliance): Michael Miller, Executive Vice President 3. Mailing Address: 5400 Glenwood, Suite 318 City: Raleigh State: NC Zip: 27612 Telephone No.: 9( 19 ) 783-4736 4. Project Name (subdivision, facility, or establishment name - should be consistent with project name on plans/specs., letters of flow acceptance, Operational Agreements, etc.): Texfi Industries, New Bern Facility "'6 5. Application Date: 3/6/92 6. Fee Submitt `cam 7. County where project is located: Craven E5 8. Address of treatment and subsurface facility: Highway 55, New Bern, 4t 9. Latitude: 350 08' 23" ; Longitude: 770 6' 36" of subsurface fields FORM: LPPG 4/91 Page 1 of 10 II. PERMIT INFORM ON: LOW PRESSURE/GRAVITY PAGE 2 (4/91)-� 1. Permit No. (will be completed by DEM): 2. Specify whether project is: new; renewal*; X modification. *If renewal, complete only sections I, II, III and applicant signature (on pg.9). Submit only pgs. 1, 2, 9 (original and 3 copies of each). Engineer signature not required for renewal. 3. If this application is being submitted as a result of a renewal or modification to an - s existing permit, list the existing permit number WQ0004936 and issue date 9/23/91 4. Specify whether the applicant is public or X private. "- 5. Specify whether applicant is: sanitary district; metropolitan sewage district; water & sewer authority; county; municipality; public utility; X other (explain) Industry III. INFORMATION ON WASTEWATER: 1. Nature of Wastewater. % Domestic; % Commercial; % Industrial; 100 %Other waste (specify). Ground Water 2. Please provide a one or two word description specifying the origin of the wastewater, such as school, subdivision, hospital, commercial, industrial, apartments, etc.: Ground Water Remediation 3. If wastewater is not domestic in nature, what level of pretreatment has been provided to ensure protection of the receiving treatment system: Complete for known -_ contaminants 4. Volume of wastewater generated by this project: 129,600 gallons per day 5. Explanation of how wastewater volume was determined: Yield test on recovery wells 6. Brief project description: Ground water extraction plus treatment by =` either carbon adsorption or air stripping for organic removal =_ There may be questions on this application that are not applicable to the subject project, such as questions aimed at low pressure systems vs. gravity systems. In those instances state not applicable or N/A; however, be certain that all pertinent questions have been answered or the application package will be returned as incomplete. IV. DESIGN INFORMATION: 1. Specify the type of system that is being installed: low pressure; - r_ X gravity; other 2 of 10 1 rY • 1 PRESSURE/GRAVITY E 3 (4/91) 2. Provide a brief listing of the components of this treatment and disposal system (if not cation. covered by specific questions below), including dimensions, capacities, loading rates, na re ig �er and detention times of tanks, pumping facilities (duplex pumps), high water alarms, filters (specify type), ponds, lagoons, disinfection facilities, subsurface fields, etc.: • 60 GPM air stripping unit, all wells; 2 170 pound carbon canisters, i an 3,_L well RW-8; and infiltration trench (400' x 3') district; 3. Specify the loading rate recommendation, as determined by the soils scientist, for e ity; — — subsurface disposal field: GPD per square foot . 4. Specify the loading rate recommendation, as determined by the soils scientist, for the =ate (100% replacement) subsurface disposal field: N/A GPD per square fL 5. Specify design loading rate that will occur in disposal field: 24 GPD / fL2 (In coastal areas the maximum is 1.5 GPD / square foot for gravity systems and 1.0 ste ater, GPD per square foot for low pressure systems). — — 6. Specify the number of subsurface fields: 1 ; The dimensions of the fields: 400' long x 3' wide x t 8' deep provided Supply line dia.: Manifold dia.: ; Distribution lateral PP Y n — Via.; 4" ; Hole dia.: z" ; Number of laterals: 1 ;Lateral length ,-is per day (typically 70 ft. max. for UP & 100 ft. max. for gravity): 400' ; Trench — Gravity . width: 3' ; Trench depth: 8 ' ; Minimum pressure head: , _— Maximum pressure head: Gravity ; Minimum vertical separation between trench bottoms and mean seasonal high water table: 2 ' ; Distance on centers (for LPP not less than 5 ft.): N/A ; Maximum slope of trenches (should be less than 0.2% for va' gravity systems): 0.1% ; Details must be provided in plans/specs which demonstrate that the ends of lines are plugged, that turn -ups are provided le •o the for UP, and that measures will be taken (grade boards, etc.) to ensure s, ravtty pertain that laterals are properly installed. ie ,knge will 7. The following criteria should be used for the siring of residential se,}$_:.g: a. three bedrooms or less, use minimum 900 gallons; �W r �°► b. four bedrooms, use minimum 1000 gallons; c. five bedrooms , use minimum 1250 gallons. ,`a�.�� 8. For businesses with a design flow less than 600 GPD, the minimum tan_CrKl pacity shall — be twice the flow. 3of10 PAGE 4 (4/91) 9. The following criteria should be used for the sizing of sepuc tanks for residences with more than five bedrooms, multiple family residences, tanks serving two or more residences*, or establishments with a flow between 600 GPD and 1500 GPD: Septic Tank Volume = (1.17) (daily sewage flow) + 500 gallons *Minimum septic tank capacity shall be 1500 gallons 10. For design flows between 1500 GPD and 4500 GPD, the following criteria shall be used: Septic Tank Volume = (0.75) (daily sewage flow) + 1125 gallons - 11. For design flows which exceed 4500 GPD, use a septic tank capacity equal to the flow. 12. Specify the septic gallons c tank 13. Specify the pump tank volume: gallons , 14. Specify the number of pumps and their capacity: pumps at GPM 15. Specify the high water alarms: audible & visual; auto dialer 1 16. Name of closest downstlope surface waters: 17. Classification of closest downslope surface waters: (as established by the Environmental Management Commission and specified on page 7 of this -J application). 18. If a power failure at the facility could impact waters classified as WS, SA, B, or =� SB, describe which of the measures are being implemented to prevent such impact, as required in 15 NCAC 2H .0200: 19. The different disposal fields, laterals, or groups of laterals in a subsurface system are typically designed to be dosed at different rates or volumes from one another. Explain the method that will be used to ensure that the proper dosing rates and volumes occur: _ 20. The project must conform to the following buffers: a) 100 feet between the disposal area and any public or private water supply - including wells; - b) 50 feet between disposal area and waters classified as WS-I, WS-II, WS-III or B; and 100 feet between the disposal area and the normal high water level of waters classified as SA or SB; c) 50 feet between any the disposal area and any stream, lake, river, or natural drainage way; d) 50 feet between the treatment/disposal systems and property lines; 4 of 10 V PRESSURE/GRAVITY .iE 5 (4/91) :es with wmti' e) 10 feet between the disposal area and any surface water interceptor drains )r ore or diversions (upslope); fl 25 feet between the disposal area and any surface water interceptor drains r or diversions (downslope) and any groundwater drainage systems; shall be r : g) 20 feet between disposal area and any other subsurface disposal area e flow. t ` except the repair area. 21. If any of the applicable buffers are are not being met, please explain how the proposed buffers will provide equal or better protection of the Waters of the State with no _ M increased potential for nuisance conditions: dialer ashed ': APPLICATION PACKAGE WILL NOT BE THIS 0 GE O ACCEPTED BY THE DIVISION OF ENVIRONMENTAL MANAGEMENT UNLESS ALL OF r `this THE APPLICABLE ITEMS ARE INCLUDED WITH THE SUBMITTAL A: B, or Required Irerz nI :t, as }'' a.. One original and three copies of the completed and appropriately executed application form. '{ b. 'lire appropriate permit processing fee, in accordance with 15A NCAC 2H .0205(c)(5). c. Five sets of detailed plans and specifications signed and sealed by a North Carolina Professional Engineer. The plans must include a general location map, a topographic map, Isl z are, a site map which indicates where borings or hand auger samples were taken, a map L,plain showing the treatment/disposal facilities, buffers, structures, and property lines; along with all wells, surface waters (100-year flood elevation), and surface drainage features within ie: ccur. "f 500 feet of the treatment/disposal facilities. Each sheet of the plans and the first page of the specifications must be signed and sealed. d. Five copies of an Operational Agreement (original and 4 copies) must be submitted if the wastewater treatment and disposal facilities will be serving single family residences, condominiums, mobile homes, or town houses and if the subject facilities will be owned by the individual residents, a homeowners association, or a developer. e. Five copies of all reports, evaluations, agreements, supporting calculations, etc., must be er supply submitted as a part of the supporting documents which are signed and sealed by the Non), Carolina Professional Engineer. Although certain portions of this required submittal-r6V be developed by other professionals, inclusion of these materials under the signaiuie'-a 47 S-I11 seal of a North Carolina Professional Engineer signifies that he has revi u $ [ its Tnatena�` and has judged it to be consistent with his proposed design. ig water �;•k 6 %5 \ f. Five copies of the existing permit if a renewal or modification.`" p� \\�. Ci i ;r, or g. A soils scientist report which includes texture, color, and structure of soils d--QQ� a depth of seven feet, depth, thickness and type of any restrictive horizons,0 raulic conductivity in the most restrictive horizon, cation exchange capacity (CEC), depth of seasonal high water table, soil pH, soils map (if available), and recommended loading rates. This report must be signed by the soils scientist. 5 of 10 LOW pRESSORE/GPAVITY Pf 6 (4/91) h. For systems treating industrial waste or any system with a design flow greater than - 25,000 GPD a hydrogeologic and soils description of the subsurface to a depth of twenty feet or bedrock, whichever is less. The number of borings shall be sufficient to determine significant changes in lithology, the vertical permeability of the unsaturated zone and the hydraulic conductivity of the saturated zone, depth to the mean seasonal high water table, and a determination of transmissivity and specific yield of the unconfined aquifer. i. Proposal for groundwater monitoring. j. Information on the location, construction details, and primary usage of all wells within 500 feet of the treatment/disposal facilities. I k. For industrial waste a complete chemical analysis of the typical wastewater to include, but not be limited to Total Organic Carbon, BOD, COD, Chlorides, Phosphorus, Ammonia, Nitrates, Phenol, Total Trihalomethanes, Toxicity Test Parameters, Total Halogenated Compounds, Total Coliforms and Total Dissolved Solids. ' po , I 6 of 10 he nin 1-Ow rRESSURE/GRAVITY PAGE 7 (4/91) TO: REGIONAL WATER QUALITY SUPERVISOR Please provide me with the classification of the surface waters identified in number 5 below and on the attached trap segment: Name of surface waters: Classification (as established by the Environmental Management Commission): proposed Classification, if applicable: Signature of regional office personnel INSTRUCTIONS TO ENGINEER Date: In order to determine whether provisions for dual or standby power may be required for the subject facility, the classification of the closest downslope surface waters (the surface waters that any overflow from the facility would flow toward) must be determined. You are required to submit this form, with items 1 through 10 completed, to the appropriate Division of Environmental Management Regional Water Quality Supervisor (see attached listing). At a minimum, you must include an 8.5" by 11" copy of the portion of a 7.5 minute USGS Topographic Map which shows the subject surface waters. You must identify the location of the facility and the closest downslope surface waters (waters for which you are requesting the classification) on the submitted map copy. The application may not be submitted until this form is completed and included with the submittal. 1. Applicant (corporation, individual, or other): 2. Name and Complete Address of Engineering Firm: City: Telephone No. 3. Project Name: 4. Facility design flow: State: 5. Name of closest downslope surface waters: 6. County(s) where project and surface waters are located: _ 7. Map name and date: 8. North Carolina Professional Engineer's Registration No. Zip: GPD 9. Print Name of Engineer 10. Seal and Signature (specify date): 7of10 DIVISION OF ENVIRONMENTAL MANAGEMENT REGIONAL OFFICES (4/91) Asheville Regional WQ Super. Washington Regional WQ Super. Raleigh Regional WQ Super 59 Woodfin Place P O Box 1507 3800 Barreu Dr., Suite 101 Asheville, NC 28802 Washington, NC 27889 Raleigh, NC 27609 704/251-6208 919/946-6481 919/733-2314 - Avery Macon Beaufort Jones Chatham Nash Buncombe Madison Bertie Lenoir Durham Northampton Burke McDowell Camden Martin Edgecombe Orange Caldwell Mitchell Chowan Pamlico Franklin Person Cherokee Polk Craven Pasquotank Granville Vance Clay Rutherford Cun ituck Perquimans Halifax Wake Graham Swain Dare Pitt Johnston Warren Haywood Transylvania Gates Tyrell Lee Wilson Henderson Yancy Greene Washington Jackson Hertford Wayne Hyde Fayetteville Regional WQ Super. Mooresville Regional WQ Super. Wilmington Region. WQ Super Wachovia Building, Suite 714 919 North Main Street 127 Cardinal Drive Extension Fayetteville, NC 28301 Mooresville, NC.28115 Wilmington, NC 28405-3845 919/486-1541 704/663-1699 919595-3900 Anson Moore Alexander Mecklenburg Brunswick New Hanover Bladen Robeson Cabarrus Rowan Carteret Onslow Cumberland Richmond Catawba Stanly Columbus Pender Hamea Sampson Gaston Union Duplin Hoke Scotland Iredell Cleveland Montgomery Lincoln Winston-Salem Regional WQ Super. 8025 North Point Boulevard, Suite 100 Winston-Salem, NC 27106 919/761-2351 Alamance Rockingham Alleghany Randolph Ashe Stokes Caswell Surry Davidson Watauga Davie Wilkes Forsyth Yadkin Guilford 8of10 LOW PRESSURE/GRAVITY P 9 (4/91) (4/91) Name and Complete Adaress of Engineering Firm: C. T. Main t original) Aquaterra (revisions); 901 Jones Franklin Road City: Raleigh State: NC Zip: 27606 y4— Super Telephone No. (919) 859-9987 Sc 101 )9 Professional Engineer's Certification: attest that this application for tic r..•_ 'a ntxon has been reviewed by me and is accurate ge and complete to the besf of my knowledge. I further attest that to the best of my knowledge the �n proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and'have judged it to be consistent with the proposed design. North Carolina Professional Engineers Registration No. /5, Y3z Print Name of Engineer /L-?!1r" AH CARO/�'� Seal and Signature (specify date): �.�`���..••''SSI•'' ���'��� s -I. wQ sui 4Qf+. bLsion SE . .. 3845 `n • • • .a ,o an .r Applicant's Certification: I, Dane Vincent , attest that this application for Inf iltration Trench at the New Bern Facility has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that if all required parts of this application are not completed and that if all required supporting information and attachments are not included, this application package will be returned as incomplete. Signature _ Date 3 9 9� THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING i INFORMATIONAND MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DIVISION OF ENVIRONMENTAL MANAG WATER QUALITY SECTION PERMITS AND ENGINEERING UNIT POST OFFICE BOX 295351 5 512 NORTH SALISBURY STREET RALEIGH, NORTH CAROLINA 27626-0535 C TELEPHONE NUMBER: 919/733-5083 9 of 10 NORTH CAROLINA ENV1___NMENTAL MANAGEMENT CO [ISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH INFILTRATION GALLERY PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Texfi Industries Craven County FOR THE Pycon�and struc peration of a groundwater remediation facility consisting ofl recovery wclls,ecovery well, , ual carbon adsorption units 60GPM air stripping unit with flow equalization ` -'ti'� rr�atmr�nt ofyrninri. ror �f, �,;, It a 3 foot by 400 foot upgradient infiltration gallery with groundwater mounding monitoring equipment, and, if needed, an additional 3 foot by 400 foot infiltration gallery to serve Tcxfi Industries New Bern facility with no discharge to the surface waters, pursuant to the application received April 11, 1991 and in conformity with the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the following specified conditions and limitations: I. PERFORMANCE STANDA-RDS I. Upon completion of construction and prior to operation of this permitted facility, a certification must be received from a professional engineer certifying that the permitted facility has been installed in accordance with this permit and the approved plans and specifications. Mail the Certification to the Permits and Engineering Unit, P.O. Box 29535, Raleigh, NC 27626-0535. 2. The Washington Regional Office, phone no. (919) 946-6481 shall be notified at least forty-eight (48) hours in advance of operation of the installed facilities so that an in -place inspection can be made. Such notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. 3. This permit shall become voidable if the soils fail to adequately absorb the wastes and may be rescinded unless the facilities are installed, maintained, and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 4 �nAe event that the facilities fail to perform satisfactorily, including the creation of nuisance conditions, the Permittee shall take imineri; *e corrective action, including those as r be required by this Division, such , e constriction of additional or replacen treatment or disposal facilities. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 6. Any sludge generated from these treatment facilities must be disposed of in accordance with General Statute 143-215.1 and in a manner approved by the North Carolina Division of Environmental Management. 7. Diversion or bypassing of the untreated groundwater from the treatment facilities is prohibited. II. OPERATION AND MAINTENAN E REOIIIREMI+NTS I. The facilities shall be properly maintained and operated at all times. 2. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge of the wastewater treatment facilities. The operator must hold a certificate of the type and grade at least equivalent to the classification assigned to the wastewater treatment facilities by the Certification Commission. Once the facility is classified, the Permittee must submit a letter to the Certification Commission which designates the operator in responsible charge within thirty days after the wastewater treatment facilities are 50% complete. 3. The facilities shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastewater resulting from the operation of this facility. III• MONITORING ANt) REPORTING REOtIIRCMENTS Any monitoring deemed necessary by the Division of Environmental Management to insure surface and ground water protection will be established and an acceptable sampling reporting schedule shall be followed. 2. Noncompliance Notification: The Permittee shall report by telephone to the Washington Regional Office, telephone no. (919) 946-6481, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the wastewater treatment facility which results in the treatment of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a basin or tank; the known passage of a slug of hazardous substance through the facility; or any other unusual circumstances. b. Any process unit failure, due to known or unknown reasons, that render the facility incapable of adequate wastewater treatment such as mechanical or electrical failures of pumps, aerators, compressors, etc. 2 t y resulting in a by-pass directly to receiving waters without treatment of all or any portion of &- :-fluent to such station or facility. d. Any time that self -monitoring information indicates that the facility is not in compliance with its permit limitations. Persons reporting such occurrences by telephone shall also file a written report in letter form within 15 days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. IV. GROUNDWATER REQUIREMENTS 1. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. 2. All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 3. The influent and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) months and quarterly thereafter for the parameters specified below: Total Nickel Total Zinc Volatile Organic Compoundsby Method I or Method 2 below Method 1: Method 6230D ( Capillary - Column), "Standard Methods for the Examination of Witter and Wastewater", 17th edition, 1989 Method 2: Method 502.2 " Methods for the Determination of Organic Compounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 27611-7687 within 30 days of sample collection. 4. Two (2) weeks prior to system start-up, the Permittee shall notify the Division of Environmental Management's Washington Regional Office that operation is about to commence. 5. The groundwater recovery treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office. V. INSPECTIONS 1. Adequate inspection, maintenance and cleaning shall be provided by tiete'utee to insure proper operation of the subject facilities. V 51� v� A 0`0-ts 3 r4lok the rermmee ar nis ucsigncc Nnau lnsPCCt uie grounawater recovery anti treatment facilities to prevent malfunctions and deterioration, operator errors and discharges which may ;e or lead to the release of wastes t : environment, a threat to human heals - a nuisance. The Permittee shall kee inspection log or summary including at least the date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Permittee for a period of three years from the date of the inspection and shall be made available upon request to the Division of Environmental Management or other permitting authority. 3. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site and facility at any reasonable time for the purpose of determining compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. VI. GENERAL CONDITIONS 1. This permit shall become voidable unless the facilities are constructed in accordance with the conditions of this permit, the approved plans, specifications and other supporting data. 2. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 3. This permit is not transferable. In the event there is a desire for the facilities to change ownership, or there is a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 4. The Permittee shall obtain a well construction permit from the Washington Regional Office prior to construction of the recovery wells. 5. Prior to a transfer of this land to a new owner, a notice shall be given to the new owner that gives full details of the materials applied or incorporated at this site. 6. A set of approved plans and specifications for the subject project must be retained by the Permittee for the life of this project. 7. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6. 8. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205 (c)(4). 9. The issuance of this permit does not preclude tha Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. Ell 1U j= rcll111llCiG, al ,CidZ)L J1A k_UUMjjJ P11V1 lV Lit l. , tti regbest its extension. Upon receipt of the request the Commission will review the adequacy i e facilities described therein, and if anted, will extend the permit for such p i of time and under such condition 3 limitations as it may deem N appropriate. F. permit issued this the 23rd day of September, 1991 NO CAROLINA E VIR G orge T. Everett, u ctor Division of Envr nmental M, By Authority of e Environm Permit Number WQ0004936 'AL MANAGEMENT COMMISSION nent Management Commission 5 Name of P : eyp; To a, .,-S �n c. -�' r,�- 4r%'o.� Owner or Gviitact Person: ,l19e-, 1;c�rr'//y%//10 -610e` 14-11e ITEM (1) (2) (3) Mailing Address: S-y00 County: C{a,.-e✓t Telephone: -793 y036' NPDES Permit No. NC00 Nondisc. Per. No. 1,✓Q IssueDate: ��3��9� Expiration Date: 7 31 94 Existing FacilitNew Facility Rated By:_ oi Prl Date: Reviewed (Train. & Cert.) Reg. Office Reviewed (Train. & Cert.) ORC Plant Class: (circle one) Central Office Grade POINTS Industrial Pretreatment Units and/or Industrial Pretreatment Program (see definition No. 33) 4 Q SI ,N FLOW OF PLANT IN GPD (not applicable to non -contaminated cooling waters, sludge handling facilities for water purification plants, totally closed cycle systems (def. No. 11). and facilities consisting only of Item (4) (d) or Items (4) (d) and (11) (d)) 0 - 20.000.......................... 1 20,001 - 50,000.......................... 2 50,001 — 100,000.......................... Q 100.001 - 250,000.......................... 4 250,001 — 500,000.......................... 5 500,001—1,000,000.......................... 8 1,000,001 -- 2,000,000 ......................... 10 2,000,001 (and up) - rate 1 point additional for each 200,000 gpd capacity up to a maximum of 30 Design Flow (gpd) F,� KOD rCP PRELIMINARY UNITS (see definition no. 32) (a) Bar Screens ................................ 1 or (b) Mechanical Screens, Static Screens or Comminuting Devices ........... ............. (c) Grit Removal ............................... or (d) Mechanical or Aerated Grit Removal ........... (e) Flow Measuring Device ....................... or (t) Instrumented Flow Measurement .............. (g) Preaeration ................................ (h) Influent Row -Equalization ................... 0i Grease or Oil Separators - Gravity .......... Mechanical .......... Dissolved Air Flotation. (7i Prechlorination .............................. (4) PRIMARY TREATMENT UNITS (a) Septic Tank (see definition no. 43) .............. (b) Imhoff Tank .................................. (c) Primary Clarifiers ............................ (d) Settling Ponds or Settling Tanks for Inorganic Non -toxic Materials (sludge handling ,facilities for water purification plants, sand, gravel, stone, and other mining operations except recreational activities such as gem or gold mining) ...................................... III IV Total Points �7- Y (5) SECONDARY TREATMENT UNITS (a) Carbonaceous Stage (i)Aeration - High Purity Oxygen System ..... Diffused Air System ........... Mechanical Air System (fixed, floating or rotor) .............. Separate Sludge Reaeration ..... (ii) Trickling Filter High Rate ................... Standard Rate ............... Packed Tower ............... (iii) Biological Aerated Filter or Aerated Biological Filter ...................... (iv) Aerated Lagoons ..................... . (v) Rotating Biological Contactors .......... (vi) Sand Filters - intermittent biological .... . recirculating biological .... . (vu) Stabilization Lagoons . ............... . (viii)Clarifier .............................. (ix) Single stage system for combined carbonaceous removal of BOD and nitrogenous removal by nitrification 2 (see def. No. 12) (Points for this item 1 have to be in addition to items (5) (a) n through (5) (a) (vir7 ................. 2 (x) Nutrient additions to enhance SOD 1 femoval............................... (xi) Biological Culture ('Super Bugs') addition r:�a♦ to enhance organic compound removal .... . �ryP 2 r' s' f>lkogenous Stage r ; vr,�, �'y 4 *on - High Purity Oxygen System ..... Diffused Air System ........... 2 �.:R�� Mechanical Air System (fixed, 3 4�`u� n0 vs floating, or rotor) ...... ...... 8 l%� 2 Separate Sludge Reaeration ..... 5 (ii) Trickling Filter - Ct�r�r��L FILES Standard Ratete ............ 2 Packed Tower............ 5 (iii) Biological Aerated Filter or Aerated 5 Biological Filter ......................... (iv) Rotating Biological Contactors ............ (v) Sand Filter - intermittent biological ....... . recirculating biological ....... . (vi) Clarifier ................................ ( TERnARY OR ADVANCED TREATMENT UN �$) Activated Carbons Beds - wrlhout carbon regeneration .................. with carbon regeneration .......... . ........ (b) powdered or Granular Activated Carbon Feed : 5 without carbon regeneration ......... 1 5 with carbon regeneration ..................... (c) Air Stripping .................... 1 0 (d) Denibification Process (separate process) Electrodialysis . ... 5 (0 Foam Separation ............................. .................. 5 5 (g) Ion Exchange................................ (h) Land Application of Treated Effluent (see definition no. 22b) (not applicable for sand, gravel, stone and other similar mining operations) (i) on agricptlturally managed sites (See del. 10 No.4)................................. (ii) by high rate infiltration on non -agriculturally managed sites (includes rotary distributors and similar fixed nozzle systems) ........... rii) by subsurface disposal (includes low pressure pipe systems and gravity systems except at plants consisting of septic tank and nitrifica- tion lines only) ....................... 5 (7 Microscreens ........................ (j) Phosphorus Remo+al by Biological Processes 20 (See diet. No. 26) 2 (k) Polishing Ponds - without aeration . . with aeration .......... 5 cascade .... 0 (I) Post Aeration diffused or mechanical ... 5 (m) Reverse Osmosis ...................5 .......... 2 (n) Sand or Mixed -Media Fitters - low rate . 5 gh (o) Treatment processes for removal of metal or 15 cyanide............................... (p) Treatment processes for removal of toxic materials other than metal or cyanide ......... 15 (10) CHEMICAL ADD SYSTEM (S) (See definition No. 9) (not applic o chemical additions rated as item (3) 0. (5) l 1. (6) (a). (6) (b), (7) (b). (7) (e), (9) (a) (9) (b), or (9) (c) 5 points each: List: 5 5 SLUDGE TREATMENT (a) Sludge Digestion Tank - Heated ....:.....: • .. 10 Aerobic ... 53 Unheated ............. 5 (b) Sludge Stabilization (che Gnvii r thermal).. • .. • . • . 2 (c) Sludge Drying Beds - Y • • • • Vacuum Assisted ....... 5 5 (d) Sludge Elulriation ....................... 5 (e) Sludge Conditioner (chemical or thermal) . • ..... 5 (1) Sludge Thickener (gravity) ............... (g) Dissolved Air Flotation Unit (not applicable to a unit rates as (3) n 8 ......... 2 (h) Sludge Gas Utilization (including gas storage) .... 5 Non -aerated . (i) Sludge Holding Tank - Aerated .....• • ....... • • 2 • (i) not including activated 10 Sludge Incinerator - carbon regeneration) (k) Vacuum Filter, Centrifuge or Filter Press or other 10 similar dewatering devices ......... . (8) SLUDGE DISPOSAL (including incinerated ash) . 2 (a)Lagoons .................... (b) Land Application (surface and subsurface) (see definition 22a) permit 1 0 -where the facility holds the land app. p -by contracting to a land application operator who holds the land application permit ................ 2 -land application of sludge by a contractor who does not hold the permit for the wastewater treatment 1 0 facility where the sludge -is generated ......... 5 (c) Landfilled (burial])......................... .. (9) DISINFECTION _ 5 (a) Chlorination ................... 5 (b) Dechlorinat"wn ...................... 5 (c) Ozone .............................. 5 (d) Radiation .......................... (11) MISCELLANEOUS UNITS (a) Holding Ponds, Holding Tanks or Settling Ponds for Organic or Toxic Materials including wastes from mining operations containing nitrogen and/or phosphorous compounds in amounts significantly 4 greater than is common for domestic wastewater .......... (b) Effluent Flow Equalization (not applicable to storage inherent in land application systems). 2 (c) basins which are Stage Discharge (not applicable to storage basins 5 inherent in land application systems..._ .. ............... _.............. _ - (d) (e) Pumps._-_-._._-- Stand -By Power Supply------—-.3 3 (f) Thermal Pollution ConL•ol Device.-.---•------•••--•--•-•-• TOTAL POINTS a y CLASSIFICATION Class I_ 5 - 25 Points 26- 50 Points Crass II. 51- 65 Points Class Class IV._ _ 66 Up Points Facilities having a rating of one through four points, inclusive, do not require a certified operator. Classification of all other facilities requires a comparable grade operator in responsible charge. Facilities having an activated sludge process will be assigned a minimum classification of Class It. Facilities having treatment processes for the removal of metal or cyanide will be assigned a minimum classification of Class it. Facilities having treatment processes for the biological removal of phosphorus will be assigned a minimum classification of Class III. In -plant processes and related control equipment which are an integral part of industrial production shall not be considered waste treatment. Likewise, discharges of wastewater from residences having a design flow of 1,0oo gpd or less, shall not be subject to rating. AAQQITIONAI COMMENTS: v I992 C�Mr�L F;LES Infiltration Tre (3' x 400, RW-8 0 0 cam- Building - G F, -V AQUA TERRA J?W-7A Raleigh, Greensboro, 9 N INC. Author RW-7 0 R 7' 11 Charlott,, C A R DL4G Laye., Da te 0 L Q1 Job No Revision. 778 Revision.ure 06-25-92 Shallow Recovery Well Location Deep Recovery Well Location Irate r'nediate Recovery , ffell Location Recovery Well Location Map New Berzi,Incorporated North Carolina SLATE State of North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Non -Discharge Permit Application (THIS FORM MAY BE PHOTOCOPIED FOR USE AS AN ORIGINAL.) GROUNDWATER REMEDIATION SYSTEMS This permit application form is for systems which use either infilsation galleries or injection wells to discharge treated groundwater into the subsurface. Each section of this application must be completed unless otherwise noted. Contact the Groundwater Section at 919/733-3221 to obtain Groundwater Remediation System Permit Application Guidelines. I. GENERAL INFORMATION: 1. Applicant (corporation, individual, or other): Texfi Industries, Inc. 2. Print Owners or Signing Official's Name & Title (person legally responsible for the treatment 8- disposal system &its compliance): Dane Vincent, Vice President of Finance & Treasurer 5400 Glenwood Ave., Suite 215 3. Mailing Address: - City: Raleigh North Carolina Zip: 27612 State: 919 783-4736 Telephone No.: ( ) 4. Remediation Site Owner: Federal; State; X Private; Public; Native American Lands; Other (specify) 5. List the principal products or services provided by facility: Ground water remediation facility 6. Project Name (facility or establishment name, should be consistent on all documents included in this application package): Texfi Industries, New Bern Facility 7. Groundwater Incident Number (if known): 8. Location of Remediation Activities (Street Address): Highway 55_ New Bern Craven North Carolina x City: - County: - State: 9-15-95 400.00 Application Date: 10. Fee Submitted: $ 11. Contact person who can answer questions about application: Ken Jesneck, P. E. 919 859-0608 Name: FORM: GWRS 12/92 Telephone number: ( ) Page 1 of 10 II. PERMIT INFORMATION: 1. Permit Number (will be completed by DEM): 2. Specify whether project is: _ new; _ renewal*; X modification; —name change*; *If renewal or name change without other modifications, complete only sections I, II, and applicant signature (on pg. 9). Submit only pp. 1, 2, and 9 (original and three copies of each). Engineer's signature not required for renewal or name changes without other modifications. 3. If this application is being submitted as a result of a renewal or modification to an existing permit, list the existing permit number WQ0004936 and issue date 8/20/92 III. INFORMATION ON CONTAMINATED GROUNDWATER: Provide a brief description of the events or cause of the groundwater contamination: Texfi Industries owned and operated a fiber manufacturing facility located in NPw Bern, NC, prior to August 1986. An environmental audit of the facility determined that the ground water had been impacted from facility operations. 2. List contaminants detected: Chlorinated compounds including 1, 1, 1=trichloroethane and 1,1-dichloroethane. 3. Volume of groundwater to be remediated per day: 86,400 gallons (per day) 4. Explanation of how volume was determined: The volume was determined through a pumping test and from recorded ground water recovery rates from wells currently in operation. IV. GENERAL DESIGN INFORMATION: Specify the type of system that is being installed: infiltration gallery; X injection well; other (specify 2. Provide a brief description of all components of the treatment and disposal system (i.e., treatment units, pumps, tanks, chemical feed system, injection and/or recovery wells, etc.): The ground water recovery system consist of 5 active and 7 inactive wells. A storage tank feeds a dual pass air stripper with a 60 gpm capacity. The treated effluent is currently discharged to an existing infiltration gallery. In addition, a separate recovery system pumps ground water from RW-8 to dual carbon absorption units and discharges the treated effluent to the infiltration gallery. 3. 15A NCAC 2C .0213 (Well Construction Standards, Applicable to Injection Wells) requires that contaminant levels in the fluid injected into any well be monitored; therefore, a sampling port must be provided on the effluent lines (treated water prior to being injected into the wells or infiltration gallery). The permit will specify the requirements for monitoring this effluent. Identify the location in the plans/specifications where the sampling port design is detailed: A sampling port will be located immediately after the dual air Gtr;nnpr unit. (See Figure 3) FORM: GWRS 12/92 Pace 2 of 10 . V . DESIGN INFORMATION FOR INFILTRATION GALLERIES: 1. Specify the dimensions of each infiluation gallery: (a) L= ft. W= D= ft. (b) Lr- ft W= ft. D= (c) L= ft. W= ft. D= ft. 2. The static water level at the gallery location is feet. The veitical separation between the gallery trench bottom and the mean seasonal high water table is feet. 3. A soil scientist must provide an evaluation of the soils where the infiltration gallery will be located and must specify an acceptable loading rate (amount of water gallery can accept). This evaluation should determine whether the loading rate shall be based upon only the surface area of the infiltration gallery or whether it is appropriate to include some of the side wall depth. a. What is the area used to determine the loading rate? square ft. b. Does the area specified above include only the surface area or has some of the side wall depth been used? surface area only; or surface area plus side wall depth. c. If side wall depth has been used, specify how much depth or height above the infiltration gallery bottom has been used. inches. d. The recommended loading rate is GPD per square foot. 4. Briefly describe any mounding of groundwater, above the static groundwater levels, that rnav result from infiltration (please attach calculations and/or diagral-ns): N. DESIGN INFORMATION FOR INJECTION WELLS: 1. Identify the principal aquifer to which the injection wells will be discharging: Castle Hayne Formation 2. Is the aquifer identified in VI.1 above the same aquifer from which the contaminated groundwater was extracted? X yes _ no If no, describe how the aquifers are hydraulically related: 3. Briefly describe any mounding of groundwater, above the static groundwater levels, that may result from the injection (please attach calculations and/or diagrams): Pumping test of the Castle Hayne formation indicate draw down of less than 1.2 feet in the wells, at a pumping rate of 51 gpm, Merefore, moun dtng of the ground water is not expected to exceed S' feet (see Section 2.7). FORM: GWRS 12/92 Page 3 of 10 4. Characteristics of injection well(s) [attach additional sheets if necessary]: Injection Well Well A I WellB ( Well C Characteristics Depth (ft-) 90' 90' I Diameter (inches) 6.0 - 6.0 I Injection rate (GPM) 50 gpm_ I 50 gpm Injection volume (GPD) 72,000 72,000 Injection pressure (PSI) I 32.5 psi 32.5 psi Injection temp. () C) 21.1 I 21.1 I CasinE material I Gal. steel I Gal. steel I Depth of casing (ft.) 40' I 40' Casino diameter (in) 16 1/4" ID I 6. 25" ID I Casing schedule number Sch 40 I Sch. 40 Cement arout from Surf ft. from Surf fr from ft. (primary or inner casing) to 40 ft. to40 ft. to ft. Cement gout (outer from NA ft. from NA ft. from ft. casing. if applicable) to NA ft. to NA ft. to ft. Screened or uncased from 40 ft. from 40 ft. from ft. interval (if applicable) to 90 ft. to 90 ft.. to ft. Type of screen Stainless Steel Stainless Steel manufactured or hand with 0.03 inch slots with 0.03 inch slo s slotted (if applicable) Screens inner diameter (inches -if applicable) 6 inches 6 inches Gravel pack from NA ft. from NA ft. from ft. (if ap licable) to NA ft to NA ft. to ft. Well contractor To Be Determined I To BE Determined Contractor registra. no. VII. ADDITIONAL INFORMATION: FORM: G`VRS 12/92 Paae 4 of 10 1. Substances may I ded to enhance in situ treatment. C those substances that can be demonstrated to have advantages that outweigh disadvantages will be considered. Will anv substances be added to the effluent to enhance in situ treatment? X yes; _ no If yes, provide a detailed description of these substances, including amounts to be added. Attach studies which describe the instances in which these substances have been used: A maintenance program is proposed for both the injection wells and the existing extraction wells that consist of periodic treatments with an organic acid (hydroxy acetic acid or acetic acid) for the removal of bacterial and chemical deposits._. 2. Classification of the closest downslope surface waters: SC Sw1lsW (as established by the Environmental Management Commission and specified on page 7 of this application). 3. In accordance with 15A NCAC 2H .0219 0) (3), describe which measure is being utilized to prevent overflows into downslope surface waters or adjacent aquifers in the event of a power failure or equipment malfunction. An electric conductivity probe in the injection well will shut down system operations if a rise in recharge mound -is detected. Electric conductivity strips are currently present at the base of the settling tanks/stripper units -to -shut system down in the event of overflow. A. The applicable buffers must be met in accordance with 15A NCAC 2H .0200 and 15A NCAC 2H .0400. Some of those buffers are described below: a. 100 feet between injection wells or infiltration galleries and any private or public water supply source; b. 50 feet between injection wells and waters classified as WS, B, or other streams, canals, marshes, lakes, impoundments, or coastal waters; c. 100 feet between infiltration galleries and waters classified as WS, B, or other sreams, canals, marshes, lakes, impoundments, or other coastal waters; d. 100 feet between injection wells or infiltration galleries and the mean high water of waters classified as SA or SB; e. 100 feet from injection well and infiltration gallery treatment and disposal systems and the normal high water of Class I and Class II impounded reservoirs which are used as a source of drinking water, f. 50 feet from injection well and infiltration gallery treatment and disposal systems and propery lines-, If any of the applicable buffers cannot be met, please explain how the proposed buffer s will provide equal or berer protection of the surface or groundwaters with no increased potential for nuisance conditions: THIS APPLICATION PACKAGE WILL NOT BE ACCEPTED BY THE DI`'ISION OF ENVIRONMENTAL MANAGEMENT UNLESS ALL OF THE APPLICABLE ITEMS ARE INCLUDED MVITH THE SUBMITTAL Required lterns a. One original and three copies of the completed and appropriately executed application form. The appropriate permit processing fee (see page 10), in accordance with 15A NCAC 2H .0205(c)(5). C. Submit four copies of the Corrective Action Plan if it contains any of the requested pertinent information. d. Four copies of the existing permit if a renewal or modification. e. Four sets of detailed plans and specifications signed and sealed by a North Carolina Professional Engineer. The plans must include a general location map; a topographic map which extends one mile beyond property boundaries and FORM: GWRS 12/92 Page 5 of 10 depicts the facility and each of stake and discharge structures (with the quac _ e name); a scaled site -specific map which indicates where borings or hand auger samples were taken; and a map showing the groundwater treatment/disposal facilities, buffers, structures and property lines. A map must also identify any hazardous waste treatment, storage, and disposal facilities; each well where fluids from the facility are injected underground; and those wells, springs and other surface water bodies and drinking water wells listed in public records or otherwise known to the applicant within a quarter mile of the facility property boundary. Each sheet of the plans, including any plan pages that are incorporated into a bound document, and the first page of the specifications, must be signed and sealed by an NC P. E. Four copies of a tabulation of data on all wells which are within the area of review and which penetrate the proposed injection zone. Such data shall include an identification number (same number referenced on map required in "e" above) for each well, a description of each well type, date installed, depth of well, and record of completion or abandonment (if available). A soil scientist report which includes texture, color, and structure of the soils down to a depth of seven feet; depth, thickness and type of any restrictive horizons, hydraulic conductivity in the most restrictive horizon, cation exchange capacity, depth of the mean seasonal high water table, soil pH, soil maps (if available, even if unpublished), and recommended loading rates (when using an infiltration gallery). This report must be signed by the soil scientist. A hydrogeologic description, soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The number of borings shall be sufficient to determine significant changes in lithology, the vertical permeability of the unsaturated zone, the hydraulic conductivity of the saturated zone, the depth to the mean seasonal high water table, and a determination of transmissivity and specific yield of the unconfined aquifer (show calculations used for transmissivity and specific yield). Report should also indicate whether the aquifer is attributable to fracture porosity storage or stradgraphically controlled (bedding planes). Include a generalized map and cross section illustrating the regional geologic setting. Describe the proposed injection procedure and describe expected changes in pressure and direction of movement of injected fluid (provide data from fracture studies where applicable). Applicant must demonstrate complete hydraulic control over contaminant plume and injectate. Proposal for groundwater monitoring (e.g., schedule, analytical methods, etc.). Describe the method for determining mechanical integrity of injection well over a five year period. A complete analysis of the contaminated groundwater to include, but not limited to BTEX. volatile and sernivolatile compounds, pH, nitrates, and phosphates or additional information the Director deems necessary to evaluate the proposed treatment and disposal system. M. Describe contaminant concentrations in the effluent given the proposed treatment. Include expected treatment efficiency. Provide calculations or documentation to show how proposed degree of treatment was derived. n. Diagram of the contaminant plume both horizontally and vertically, including vadose zone contamination (isoconcentration maps and plume cross sections). Include direction of groundwater flow for both surface aquifer and deep aquifers. o. Four copies of all reports, evaluations, agreements, supporting calculations, etc., must be submitted as a part of the supporting documents which are signed and sealed by the North Carolina Professional Engineer. Although certain portions of this required submittal must be developed by other professionals, inclusion of these materials under the signature and seal of a North Carolina Professional Engineer signifies that he or she has reviewed this material and has judged it to be consistent with his or her proposed design. p. An executed page 7, which has been completed by the appropriate Regional Water Quality personnel, and reincorporated into the application form prior to submittal of the application package. INSTRUCTIONS TO NC PROFESSIONAL ENGINEER: FORM: G`VRS 12/92 Page 6 of 10 The classification of the c st downslope surface waters (the surf,, vaters that any overflow from the groundwater remediation facility would flow towards) must be determined by the appropriate DEM regional office. Therefore, you are required, prior to submittal of the application package, to submit this form, with items 1 through 8 completed, to the appropriate Division of Environmental Management Regional Water Quality Supervisor (see page 10). At a minimum, you must include an 8.5" by 11" copy of the portion of a 7.5 minute USGS Topographic Map which shows the subject surface waters. You must identify the location of the groundwater remediation facility and the closest downslope surface waters on the submitted map copy. Once the regional office has completed the classification, reincorporate this completed page and the topographic map into the complete application form and submit the application package. 1. 2. 3. 4. Applicant (corporation, individual, or other): Name R complete address of engineering firm: City: Raleigh State: NC Telephone number: (919) 859-0608 Texfi Industries, Inc. Aquaterra Engineering, P.O. Box 37579 Zip: 27627-7576 Project name: Texfi Incorporated, New Bern, North Carolina Facility design flow: 86,400 gpd 5. Name of closest downslope surface waters: Neuse River 6. Counry(s) where project and surface waters are located: 7. Map name and date: Craven County Askin, NC - 1978, Photorevised 1983 GPD 8. NC Professioaal Engineer Seal and Signature [must be legible] (specify date): ��ys�Nrrrhr�� : Hkk ARa�''••�e aFES..tp�; . 2 SE AL RECEIVED • 18498 WASHINGTON OFFICE N��•' JUN 1 2 19�15 4, �'•�FTH L. 1�:-- ,.• ''•r,rrr„„N• 0.EM. TO: REGIONAL WATER QUALITY SUPERVISOR Please provide me with the classification of the surface eaters identified in number 5 above and on the attached map segment: Name of surface waters: AJ Eyi c e , I 0 E R- Classification (as established by the Environmental Management Commission): SC Proposed classification, if applicable: nl Signature of regional office personnel: Date: S Name and Complete Address of Engineering Firm: FORM: GWRS 12/92 Page 7 of 10 City: State: Zip: Telephone No.: PRO,F/ESSIONAL ENGINEER'S CERTIFICATION: N A- L - J �s �1talL , attest that this application for T�J F \ ( � usT2 • c has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. NC Professional Engineer's Seal and Signature [must be legible] (specify date) .•��Zt't CARp���•,, ram SE AL 194 • •• go F••....• T5���.• '•�. H 15 APPLICANT'S CERTIFICATION: _ I, -Da ae 4- e i7( , attest that this application for 7ex-Ic. has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that if all required pans of this application are not completed and that if all required supporting information and attachments are not included, this ill pplication package wbe returned as incomplete. Signature: Date: THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORAIATION AND MATERIALS, SHOULD. BE SENT TO THE FOLLOWING ADDRESS: North Carolina Division of Environmental Management Water Quality Section Permits and Engineering Unit P.O. Box 29535 512 North Salisbury Street Raleigh, North Carolina 27626-0535 Telephone Number: 919/733-5083 PERMIT APPLICATION PROCESSING FEES FORA: GWRS 12/92 Page 8 of 10 ra, ::C•ORY PEI T APPLICATION PROCESSIN' -EES �,-EW APPLTC4TIO?�S/ �-Y � �lODIFiC4Ti0Sl �i-r�;��i i tiiODIFICATIONS LAB RFivE�'AI,S > 1,000,000 GPD Industrial Se3y.aEe/Cooling Water 10,001-1,000,000 GPD Industrial Se•x,aEe/Cooling Water 1,001-10,000 GPD Industrial se,;,=Ee/Coo1Ln-z Water < or = 1,000 GPD and Single fa--r_ly dwe—Hr.E S400 5300 $400 5300 $400 5250 S1100 5250 S400 5200 S400 5200 S2�0 S120 Modifications that involve only name changes are S50. FORM: GWRS 12192 Page 9 of 10 North Carolina - Department of Envirol,lrlerit, Health, & Natural Resources Division of Environtrlental Management Groundwater Section 512 N. Salisbury Street Raleiclh, NC 27626-0535 Winston-Salem Regional 011ico 13025 North Point Blvd. Winston -Salons, NC 271OG (919)896-7007 Asheville Regional 011ice 59 Woodf in Place Asheville, NC 28801 (704)251-6208 Mooresville Regional 011ico 919 N. Main St. Mooresville, NC 28115 (704)G63-1699 GvCff, P,Z �__: i niron I nrntinn Fayetteville Regional 011ice Wacliovia Bldg. Suite 714 Fayetteville, NC 213301 (919)486-1541 11weigh Regional 011ice moo Barrell Dr. Raleigh, NC 27609 (919)571-f1700 Washington Regional 011ice 1424 Carolina Ave. Washington, NC 27889 (919)946-6481 Wilmington Regional 011ice 127 Cardinal Ur. Extension Wilmington, NC 28405-3845 (919)395-3900 2/92 MC1uM T P. r r a POST OFFICE Box 37579 • RALEIGH. NC 27627-7579 - (919) 859-0608- FAX (919) 859-9930 A GREAT LAKES CHEMICAL CORPORATION COMPANY February 29, 1996 Mr. Michael Allen North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Post Office Box 29535 Raleigh, North Carolina 27626-0535 Reference: Nondischarge Permit Renewal Application Texfi. Industries, Inc. New Bern, North Carolina Aquaterra Engineering Job 5402600 Dear Mr. Allen: Aquaterra Engineering, Inc., has prepared the renewal application for the Non -Discharge Permit #WQ0004936 for the ground water remediation system at the Texfi Industries, Inc. (Texfi), site located in New Bern, North Carolina. As we discussed, Aquaterra Engineering requests that the permit application fee submitted with the injection well permit application be applied to the renewal fee. The status of the injection well permit application will be resolved within the next week. The ground water remediation system has not been modified; therefore, the original and three copies of only Sections I, II, and the signature page are being forwarded. If you need additional assistance, please feel free to contact me at (919) 859-0608. Sincerely, Kenneth L. Jesneck, P.E. r Sr. Engineer/Project Manager 610167/KJ/pac cc: Mr. Dane L. Vincent - Texfi Industries, Raleigh, North Carolina Mr. John Tate - Southridge Corporation, Greensboro, North Carolina Mr. Harold N. Bynum - Smith, Helms, Mulliss & Moore, L.L.P., Greensboro, North Carolina CORPORATE HEADQUARTERS: 4901 WATERS EDGE DRIVE, RALEIGH, NC 27606 - (919) 859-9987 - FAX (919) 859-9930 � r ST'vt �.. `C State of North Carolina AMLAN Department of Environment, Health, and Natural Resources F� Division of Environmental Management 2� Non -Discharge Permit Application (THIS FORM MAY BE PHOTOCOPIED FOR USE AS AN ORIGINAL) ;lop GROUNDWATER GROUNDWATER REMEDIATION SYSTEMS This permit application form is for systems which use either infiltration galleries or injection wells to discharge treated groundwater into the subsurface. Each section of this application must be completed unless otherwise noted. Contact the Groundwater Section at 919/733-3221 to obtain Groundwater Remediation System Permit Application Guidelines. I. GENERAL LNFORMATIONt 1. Applicant (corporation, individual, or other): Texfi Industries, Inc. 2. Print Owners or Signing Official's Name & Title (person legally responsible for the treatment & disposal system &, its compliance): Dane L . Vincent , VP - Finance 1 3. Mailing Address: 5400 Glenwood Avenue, Suite 318 City: Raleigh State: NC Zip: 27612 Telephone No.: ( 919 ) 7 8 3- 4 7 3 6 4. Remediation Site Owner: Federal; State; X Private; Public; Native American Lands; Other (specify) 5. List the principal products or services provided by facility: Site is not operated by Texfi Industries 6. Project Name (facility or establishment name, should be consistent on all documents included in this application package): Texfi Industries, New Bern Facility 7. Groundwater Incident Number (if known): 3 3 S .a 8_ Location of Remediation Activities (Street Address): City: New Bern County: Craven State: NC 9. Application Date: 2 - 2 8 - 9 6 10. Fee Submitted: $ 11. Contact person who can answer questions about application: Name: Kenneth L. Jesneck Telephone number:( 919 ) 859-0608 FOR',%'I: GNVRS 12/92 Page 1 of 10 jj. PERMIT INFORMATIO 1. Permit Number (will be completed by DEW 2. Specify whether project is: _. new; X renewal*; _ modification; name change*; *If renewal or name change without other modifications, complete land three copies of applicant signature (on pg. 9). Submit only pgs. 11 2, and 9 (original ired for renewal or name changes without other each). Engineer's signature not requ modifications. 3. mitted as a result of a renewal or modification to an existing If this application is being sub _ permit, list the existing permit number Wg00049 3 6 and issue date/ � 2I91—• III, INFORMATION ON CONTAMINATED GROUNDWATER: 1. Provide a brief description of the events or cause of the groundwater contamination: 2. List contaminants detected: 3. Volume of groundwater to be remediated per day: gallons (per day) t 4. Explanation of how volume was determined: IV. GENERAL DESIGN, INFORMATION: 1. Specify the type of system that is being installed: infiltration gallery; injection well; other (specify) 2. Provide a brief description of all componentsd system, injection and/orhe treatment recoverydisposal wells, etc.):i.e., treatment units, pumps, tanks, chemical 3. 15A NCAC 2C .0213 (Well Construction Standards, Applicable to Injection Wells) requires that contaminant levels in the fluid injected meat any prior�otbeins i jected into tsampling e P ells port must be provided on the effluent linesthis or infiltration gallery). The permit Fill specify the requirements monito rt designnts detaileduent. Identify the location to the plans/specifications where the sampling p P FORM: GWRS 12/92 age 2 of 10 V . DESIGN INFORMATION FOR INFILTRATION GALLERIES: 1. Specify the dimensions of each infiltration gallery: (a) L= ft. W= D= ft. (b) L= ft. W= ft. D= (c) L= ft. W= ft. D= ft. 2. The static water level at the gallery location is feet. The vertical separation between the gallery trench bottom and the mean seasonal high water table is feet. 3. A soil scientist must provide an evaluation of the soils where the infiltration gallery will be located and must specify an acceptable loading rate (amount of water gallery can accept). This evaluation should determine whether the loading rate shall be based upon only the surface area of the infiltration gallery or wh ether it is appropriate to include some of the side wall depth. a. What is the area used to determine the loading rate? square ft. b. Does the area specified above include only the surface area or has some of the side wall depth been used? surface area only; or surface area plus side wall depth. c. If side wall depth has been used., s-cify he�a, much depth or height above the infiltration gallery bottom has been used. inches. d. The recommended loading rate is GPD per square foot. 4. Briefly describe any mounding of ground,;,-ater, above the static groundwater levels, that may result from infiltration (please attach calculations and/or diagrams): VI. DESIGN INFORMATION FOR INJECTION WELLS: 1. Identify the principal aquifer to which the injection wells will be discharging: 2. is the aquifer identified in V1.1 above the same aquifer from which the contamirateu groundwater was extracted? _ yes _ no If no, describe how the aquifers are hydraulically related: 3. Briefly describe any mounding of groundwater, above the static groundwater levels, that may result from the injection (please attach calculations and/or diagrams): FORM: G«'RS 12/92 Pace 3 of 10 4. Characteristics of injection well(s) [attach additional sheets if necessary]: Injection Well Characteristics Well A Well B Well C Depth (ft.) Diameter (inches) Injection rate (GPM) Injection volume (GPD) Injection pressure (PSl) Injection temp. (° C) Casing material Depth of casing (ft.) Casing diameter (in) Casino schedule number Cement grout (primary or inner casing) from to ft. ft. from to ft. ft. from to ft. ft. Cement grout (outer casing, if applicable) from to ft. ft. from to ft. ft. from to ft. ft. Screened or uncased interval (if applicable.) from to ft. ft. from to ft. ft.. from to ft. ft' Type of screen manufactured or hand slotted (if applicable) Screens inner diameter (inches -if applicable) Gravel pack (if applicable) from to _ft. ft. from to ft. ft. from to ft. ft. Well contractor Contractor registra. no. VII. ADDITIONAL INFORMATION: FORM: GWRS 12/92 Page 4 of 10 1. Substances may be ad to enhance in situ treatment. Only e substances that can be demonstrated to have advantages that outweigh disadvantages be considered. Will any substances be added to the effluent to enhance in situ treatment? _ yes; W no If yes, provide a detailed description of these substances, including amounts to be added. Attach studies which describe the instances in which these substances have been used: 2. Classification of the closest downslope surface waters: (as established by the Environmental Management Commission and specified on page 7 of this application). 3. In accordance with 15A NCAC 2H .0219 0) (3), describe which measure is being utilized to prevent overflows into downslope surface waters or adjacent aquifers in the event of a power failure or equipment malfunction. 4. The applicable buffers must be met in accordance with 15A NCAC 2H .0200 and 15A NCAC 2H .0400. Some of those buffers are described below: a. lOG fees between u,jecricn wells or infiltration galleries and any private or public water supply source; b. 50 feet between injection wells and waters classified as WS, B, or other streams, canals, marshes, lakes, impoundments, or coastal waters; c. 100 feet between infiltration galleries and waters classified as WS, B, or other streams, canals, marshes, lakes, impoundments, or other coastal waters; d. 100 feet between injection wells or infiltration galleries and the mean high water of waters classified as SA or SB; e. 100 feet from injection well and infiltration gallery treatment and disposal systems and the normal high water of Class I and Class II impounded reservoirs which are used as a source of drinking water, f. 50 feet from injection well and infiltration gallery treatment and disposal systems and property lines; If any of the applicable buffers cannot be met, please explain how the proposed buffers will provide equal or better protection of the surface or groundwaters with no increased potential for nuisance conditions: THIS APPLICATION PACKAGE WILL NOT BE ACCEPTED BY THE DIVISION OF ENVIR01'MENTAL MANAGEMENT UNLESS LESTSUBMITTAL SALLOHEAPPLICABLE ITEMS ARE INCLUDED ITH Required Items a. One original and three copies of the completed and appropriately executed application form. b. The appropriate permit processing fee (see page 10), in accordance with 15A NCAC 2H .0205(c)(5). C. Submit four copies of the Corrective Action Plan if it contains any of the requested pertinent information. d_ Four copies of the existing permit if a renewal or modification. e. Four sets of detailed plans and specifications signed and sealed by a North Carolina Professional Engineer. The plans must include a general location map; a topographic map which extends one mile beyond property boundaries and FORM: GWRS 12/92 Page 5 of 10 depicts the facility and each of its intake and discharge structures (with the quadrangle name); a scaled site -specific map which indicates where borings or hand auger samples were taken; and a map showing the groundwater treatment/disposal facilities, buffers, structures and property lines. A map must also identify any hazardous waste treatment, storage, and disposal facilities; each well where fluids from the facility are injected underground; and those wells, springs and other surface water bodies and drinking water wells listed in public records or otherwise known to the applicant within a quarter mile of the facility property boundary. Each sheet of the plans, including any plan pages that are incorporated into a bound document, and the first page of the specifications, must be signed and sealed by an NC P. E. Four copies of a tabulation of data on all wells which are within the area of review and which penetrate the proposed injection zone. Such data shar—I include an identification number (same number referenced on map required in "e" above) for each well, a description of each well type, date installed, depth of well, and record of completion or abandonment (if available). A soil scientist report which includes texture, color, and structure of the soils down to a depth of seven feet; depth, thickness and type of any res7 ictive horizons, hydraulic conductivity in the most restrictive horizon, cation exchange capacity, depth of the mean seasonal high water table, soil pH, soil maps (if available, even if unpublished), and recommended loading rates (when using an infiltration gallery). This report must be signed by the soil scientist. h. A hydrogeologic description. soils description, and cross section of the subsurface to a depth that includes the known or projected depth of contamination. The number of borings shall be sufficient to determine significant changes in 41- ology, the vertical permeability of the unsaturated zone, the hydraulic conductivity of the saturated zone, the depth to the mean seasonal high wa:--r table, and a determination of transmissivity and specific yield of the unconfined aquifer (show calculations used for transmissivity and specific yield). Report should also indicate whether the aquifer is attributable to fracture porosi:v storage or stratigraphically controlled (bedding planes). Include a generalized map and cross section illustrating the regional geologic setting. i. Describe the proposed injection procedure and describe expected changes in pressure and direction of movement of injected fluid (provide data fiom fracture studies where applicable). Applicant must demonstrate complete hydraulic control over contaminant plu.-ne and injectate. j. Proposal for groundwater mcnitoring (e.g., schedule, analytical methods, etc.). k. Describe the method for dete.. pining mechanical integrity of injection well over a five year period. 1. A complete analysis of the contaminated groundwater to include, but not limited to BTEX, volatile and semivolatile compounds, pH, nitrates, a::d phosphates or additional information the Director deems necessary to evaluate the proposed treatment and dispc&al system. M. Describe contaminant concentrations in the effluent given the proposed treatment. Include expected treatment efficiency. Provide calculations or documentation to show how proposed degree of treatment was derived. n. Diagram of the contamina_nt lump both horizontally and vertically, including vadose zone contamination (isoconcentration maps and plume cross sections). Include direction of groundwater flow for both surface aquifer and de"p aquifers. Four copies of all reports, evaluations, agreements, supporting calculations, etc., must be submitted as a part of the supporting documents which are signed and sealed by the North Carolina Professional Engineer. Although certain portions of this required submittal must be developed by other professionals, inclusion of these materials under the signature and sea] of a North Carolina Professional Engineer signifies that he or she has reviewed this material and has judged it to be consistent with his or her proposed design. p. An executed page 7, which has been completed by the appropriate Regional Water Quality personnel, and reincorporated into the application form prior to submittal of the application package. INSTRUCTIONS TO NC PROFESSIONAL ENGLNEER: FORM: GWRS 12/92 Page 6 of 10 ' The classification of the close >wnslope surface waters (the surface :rs that any overflow from the groundwater remediation iacility would flow towards) must be ( mined by the appropriate DEM regional office. Therefore, you are required, prior to submittal of the application package, to submit this form, with items 1 through 8 completed, to the appropriate Division of Environmental Man=_dement Regional Water Quality Supervisor (see page 10). At a minimum, you must include an 8.5" by 11" copy of the portion of a 7.5 minute USGS Topographic Map which shows the subject suface waters. You must identify the location of the groundwater remediation facility and the clos-st downslope surface waters on the submitted map copy. Once the regional office has completed the classification, reincorporate this completed page and the topographic map into the complete application form and submit the application package. 1. Applicant (corporation, individual, or other): 2. Name & comp:=te address of engineering firm: City: State: Zip: Telephone nur_ber: 3. Project name: 4. Facility design low: 5. Name of close:: downslope surface waters: 6. County(s) whe--- project and surface waters are located: 7. Map name anc date: 8. NC Professio al Engineer Seal and Signature [must be legible] (specify date): TO: REGION -AL '%�'ATFR QUALITY SUPERVISOR GPD Please provide me with the classification of the surface waters identified in number 5 above and on the attached map sc_ment: Name of surface waters: Classification fas established by the Environmental Management Commission): Proposed clan=fication, if applicable:. Signature of r:gional office personnel: Name and Complete Aelfress of Engineering Firm: FORNM: GWRS 12 92 Page 7 of 10 Date: Tin - City: Telephone No.: State: PROFESSIONAL ENGINEER'S CERTIFICATION: , attest that this application for I, has been reviewed by me and is accurate and complete to the osed best of m knowledge. I further attest that to the best otfhou h ceknowledge rtain pore° nr°P ab pa age esign has been Y prepared in accordance with the applicable ionals, i n l g ma have been developed by other professionals, inclusion of to be consistent with the proposed design. and Y signifies that I have reviewed this material and have judged it NC Professional Engineer's Seal and Signature [must be legible] (specify date) APPLICANT'S CERTIFICATION: Groundwater Remediation 1, Dane L . Vincent , attest that this application for System Permit Renewal d complete to has been reviewed by me and is accurate an that if all quireunderstand d supporting informatiionaanc all required parts of this application are not completed and attachments are not included, this application package will be returned as incomplete. Signature: ' �, Date: THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDRESS: North Carolina Division of Environmental Management Water Quality Section Permits and Engineering Unit P.O. Box 29535 512 North Salisbury Street Raleigh, North Carolina 27626-0535 Telephone Number: 919/733-5083 PERMIT APPLICATION PROCESSING FEES Page 8 of 10 FORA: GNN'RS 12/92 ' CATEGORY PERMIT APPLICATION PROCESSING FEES > 1,000,000 GPD Industrial Sewage/Cooling Water 10,001-1,000,000 GPD Industrial Sewage/Cooling Water 1,001-10,000 GPD Industrial Sewage/Cooling Water < or = 1,000 GPD and Single family dwelling PPLT [01MOU11ML1 1: .T! $240 Modifications that involve only name changes are $50. Is FOR]N1: GNN'RS 12/92 Page 9 of 10 $300 $300 $250 $250 $200 $200 $120 Asheville Regional Office 59 Woodlin Place Asheville, NC 28801 (704)251-6208 North Carolina - Department of Environment, Health, & Natural Resources Division of Environmental Management Groundwater Section 512 N. Salisbury Street Raleigh, NC 27626-0535 Winston-Salem Regional Office Raleigh Regional Office Washington Regional Office 8025 North Point Blvd. 3800 Barrett Dr. 1424 Carolina Ave. Winston-Salem, NC 27106 Raleigh, NC 27609 Washington, NC 27889 (919)896-7007 (919)571.4700 (919)946-6481 0 A.1.• s..ry yw,•. Iwa.,W,«n c.....n U«N � Wruy Wikw Y..ke, F..yn Cu1h.d 6 Fir `\\ Arwy • Y.nc• C.k" N««rW 0... 1 W.A.. I `lyw War, VI• a.k. k.a.� o.via.nn P.n U•ril..l Bun•omA. WQ—, C.r..b. ,) )ti y ' H.yr. w Ilr«.n Julvr�u� G••,,• fi�tw.lcrd C.1.r,w Ilrn•n �f+, W.yn• lw.i Cr.)wn J.ri.m G`•v" swly µ°°'• G.r.n PrnAao Pk CI•vLnd ♦` y{ Cho ok" Clay Uim M.an IlJn�ad IbA• S—P.- � �1 Mooresville Regional Office 919 N. Main St. Mooresville, NC 28115 (704)663-1699 n :--.I r)lfirrn I nCallon Fayetteville Regional Office Wachovia Bldg. Suite 714 Fayetteville, NC 26301 (9 t 9)486-1541 Pr,d« If11 N.w I I.rovr Wilmington Regional Office 127 Cardinal Dr. Extension Wilrninglon, NC 28405-38,15 (919)395-3900 2/92 • uenotes nCylvll", ---- LAW X I N I C HAS. T. MAI ICI, A Imo? C. 1893 4701 HEDGEMORE DRIVE, CHARLOTTE, NORTH CAROUNA 28209 • TEL. 704-529-MAIN (6246) • FAX: 704-529-0374 April 8, 1991 3136-013-2000 Mr. Randy Jones State Engineering Review Group North Carolina Division of Environment, Health, and Natural Resources P.O. Box 27687 512 North Salisbury Street Raleigh, North Carolina 27611 �� c c��;-rE`IP1G SUBJECT: Application (Revision 2) for North Carolina Non_Discharge Permit for Texfi Industries Facility in New Bern, North Carc:i ina Dear Mr. Jones: In accordance with North Carolina's requirements for a non - discharge permit as cited in Subchapter 2H, Section 205, Chas. T. Main, Inc. (MAIN) is submitting the enclosed application and support documentation on behalf of Texfi Industries. As per our meeting to review the application on Friday, March 15, the following deficiencies in the permit application were noted: P&ID Drawings must be signed and sealed. • Specifications must include engineered drawings for the physical/chemical treatment equipment and for the air stripper. These deficiencies have now been addressed in this resubmittal of the non -discharge permit application. In addition, the requested additional information concerning the hydrogeology of the site is being provided. Included is the excerpted "Hydrogeology" section from the "Preliminary Groundwater Assessment" report issued March 17, 1987. A copy of the Remedial Action Plan (RAP) that has been submitted and approved by the state has also been included to provide additional background concerning this site. BOSTON, MASSACHUSETTS • CHARLOTTE, NORTH CAROLINA • PASADENA, CALIFORNIA Er, April 8, 1991 Page 2 I will be contacting you soon to inquire if there are any further questions. Thank you for your prompt attention to this application. Very truly yours, �V`. _z ' l APR 1 i 1991 PERMITS & ENGI vEER1NG Richard D. Griffiths Project Manager enc: Non -Discharge Permit Application Hydrogeology Section, Preliminary Groundwater Assessment Remedial Action Plan North Carolina Department of ironment, Health, and Natural Resourc DEM USE ONLY Environmental Management Commission Permit Number: NON -DISCHARGE PERMIT APPLICATION* Min accordance with NC General Statutes Chapter 143, Article 21 County: _ Craven Count Applicant (name of board, individual, or others): Application Date: Mi Project (name of city, village, town, sanitary district, establishment): Texfi Industries Groundwater Remediation Facility FOR: Brief Project Description: Q Non -Discharge Treatment/Disposal Facilities Semi —closed loop recycle system for ❑ Pretreatment Facilities the recharge of the shallow aquifer ❑ Sewer Collection System (private) ❑ Extension of Sewer Systems (public) with treated groundwater from the ❑ Sludge Disposal groundwater treatment facility ❑ Spray Irrigation NATURE OF WASTEWATER: ❑ Domestic Sewage ❑ Sludge/Industrial Waste Estimated Completion Date: March 1990 ® Other Waste Treated Groundwater From (sewers, pretreatment plant): Serving (city, institution, industry): Groundwater Treatment Facilit t i Texfi Industries Facility Into (name of treatment plant): Average Daily Gallons Sewage or Waste Flow: N/A 86,400 gpd At (location of plant): (NPDES No.) -New Bern North Carolina NC00 7F1,1;4 Name and Complete Address of Engineering Firm: Chas . T . Main , Inc . Zip Code: 28209 4701 Hedgemore Drive Telephone No. 704-529-6246 Charlotte NC Applicant assures that proposed works will be constructed, supervised, operated and maintained in accordance with approved plans and specifications or approved changes thereto. Mailing Print Name • �l ddress:/©/t!�wOOG� �✓ C S�/ ���� Title: j ✓Gy' �"%L �io�l�- / `,,o e, (7. /i zipCode• / �' Signature../�/ � �P� i'i "L F���,� Telephone No. INSTRUCTIONS: 1.Fill-in All Spaces. If not applicable, enter N/A. 11 2.Secure appropriate signature (mayor/city manager for municipality, chairman for sanitary district board, owner/proper official of corporation, or legally constituted board or commission in charge of proposed works). A letter of authorization is required from proper official if design engineer or other agent signs application. 3. Submit to Division of Environmental Management, Permits and Engineering Unit, P.O. Box 27687, Raleigh, NC 27611 the original and ALL carbon copies of the application, 3 sets of finalized plans, specifications and other supporting data as required by Com- mission Rules, and permit fee. Plans and specifications must be signed and sealed by a registered North Carolina engineer. FOR ASSISTANCE, CALL THE STATE CENTRAL OFFICE (919) 733-5083, PERMITS & ENGINEERING UNIT, OR: Asheville (704) 251-6208 Fayetteville (919) 486-1541 Mooresville (704) 663-1699 Winston-Salem (919) 761-2351 59 Woodfin Place Suite 714 Wachovia Bldg. 91.9 North Main Street 8025 North Point Boulevard Asheville, NC 28801 Fayetteville, NC 28301 Mooresville, NC 28115 Suite 100 Raleigh (919) 733-2314 Washington (919) 946-6481 Wilmington (919) 256-4161 Winston-Salem, NC 27106 3800 Barrrett Drive 1424 Carolina Avenue 7225 Wrightsville Avenue P.O. Box 27687 P.O. Box 1507 Wilmington, NC 28403 Raleigh, NC 27611 Washington, NC 27889 r 3. HYDROGEOLOGY A. Site Geology B CEIVFD APR 11 1991 QERMiTS & ENGINEFF!NC, Existing geologic cross -sections (drawing R2) ha41e been modified to reflect hydrogeologic information obtained during Phase II. Section C (drawing R3) was generated from existing well 8 boring log data and new information obtained from wells 10 and 10A. Boring logs for new wells are located in Appendix C. The coquina - limestone contact below well 9 has been shown lower indicating the actual contact position. The apparent undulating nature of the contact is attributed to a post - Eocene erosional event where channel scouring was probably the dominant erosional process. In the upper unconsolidated post -Miocene sediments, contacts between sand and clay beds are somewhat variable across the site. This variability is characteristic of a subaerial channel dominated depositional environment where meandering channels (sands) and inter -channel basins (clays) migrate laterally with time. The contact between these unconsolidated sediments and the underlying semi - consolidated sediment of the Yorktown Fm. (coquina bed) varies about one foot in depth between the deep wells. Site Groundwater Hydrology Water level positions for both the upper and lower (Castle Hayne) aquifers are shown on the potentiometric map (drawing Rl) and on the accompanying cross -sections (drawings R2. R3). The water table is super -positioned or the cIa;: confining beds suggesting that the lower relative hydraulic conductivity of the clay beds influence the water table 3136-8-1000 6 TEX001WP position. In the Castle Hayne aquifer the piezometric (pressure) surface is situated between elevation 10 and 11 feet above mean sea level, from about one to seven feet below the water table surface. The difference in water levels is attributed to the semi -confined nature and the high relative hydraulic conductivity of the lower aquifer. In hydrogeologic settings such as this w h e r e 1 i th o 1 o g y changes abruptly between a low hydraulic conductivity unit and a high conductivity unit, head differences between the units cause a movement of water from the low hydraulic conductivity unit to the high. This differential pressure between the two aquifers is a direct function of contrasting hydraulic conductivity between the aquifers and indicates rapid transport of water within the lower aquifer relative to the unconsolidated sediments above. Groundwater flow directions in each aquifer may be inferred from drawing R1. The water table aquifer flows generally from west to east along flow lines which are perpendicular to the equipotential lines shown. A groundwater mound is apparently situated in the vicinity of well 3A creating a groundwater divide in the northwest corner of the site. A representative hydraulic gradient for the water table aquifer is 0.013 ft/ft. Based on the groundwater measurements taken on 10 July 87, groundwater flow in the lower aquifer is in the southern direction under the influence of a 0.0014 ft/ft hydraulic gradient. Flow in this direction was unexpected taking into account the nearby Neuse River and the large sink created by the Martin -Marietta quarry dewatering operation. However, since the lower pressure surface is defined by three points, one of which is located in an area where the confining unit does not exist, it seems likely that the lack of a confining unit at well 10 would allow a more rapid recharge of water 3136-8-1000 7 TEX001WP an into the lower aquifer thus biasing the lower aquifer pressure surface in the southern direction. It is estimated that increased elevation control on the lower pressure surface will support a southeasterly flow direction on a regional scale. Groundwater flow velocities in both aquifers may be estimated from hydraulic conductivity data presented in the Phase I report and from recently obtained hydraulic gradient data presented above. Because of the interlayered nature of the post-miocene sediments, groundwater in the upper aquifer moves at two different velocities. Using the relationship V = KHi where V = velocity, KH = horizontal hydraulic conductivity, and i = horizontal hydraulic gradient, it is estimated that groundwater transmitted by upper aquifer clays moves at a velocity of 0.0012 ft/d and through the sands at 0.11 ft/d. Best available formation indicates that groundwater flow velocity in the "Castle Hayne" aquifer is approximately 0.14 ft/d. Due to the nature of the double aquifer system, vertical hydraulic gradients are considerably higher than horizontal. However, this does not necessarily imply that vertical flow velocities are proportionally as high. The relationship is possible given the fact horizontal hydraulic conductivities may be considerably higher than vertical hydraulic conductivities in sedimentary environments. Clay particles, which are platy in structure, are deposited in such a manner that the plates align horizontally with one another thus allowing groundwater to move with relative ease in the horizontal direction compared to the vertical direction. Since the clays control the flux of water in the vertical direction, it is not likely that the vertical flow velocity would be equal to the horizontal velocity under conditions of equal horizontal and vertical hydraulic gradient (KH = 3136-8-1000 8 TEX001WP KV). In the absence of vertical hydraulic conductivity data and given the fact that the average vertical hydraulic gradient is 15 times the horizontal, it is likely that the vertical flow velocity through the clay is somewhat higher than the horizontal velocity in the clay. 3136-8-1000 9 TEX001WP y, WELL ~ 7 ' CL CLAY WITH:' ATERBEDDED POST- MIOCENE FINE SAND SEDIMENTS SAND - rk ,SEMI ;� CONS IndYORKTOWN FM At =LL 8 —Z— WATER TABLE( 2.17.87) WELL SCREEN INTERVAL b {' f ER TEXFI PLANT." - " BERN , N.C. 'IlePRELIMINARY GROUNDWATER .:' ASSESSMENT y�� 0. FIGURE 3 S 13 f :``8 - I000 Non -Discharge Permit No. WQ0004936 Ted Industries New Bern, North Carolina March 10,1992 Prepared For North Carolina Department of Environment, Health and Natural Resources Raleigh, North Carolina Prepared By Aquaterra, Inc. Raleigh, North Carolina �.! ! r'r.3 ri�5 Vi CA I rn C3 AQllATEPRA } A LIATERPA Environmental Consultants March 10, 1992 Mr. Donald L. Safrit, P.E. North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Post Office Box 27687 Raleigh, North Carolina 27611-7687 Reference: Non -Discharge Permit No. W00004936 Texfi Industries New Bern, North Carolina Facility Aquaterra Job No. 778 Dear Mr. Safrit: Aquaterra, Inc. (Aquaterra) has been asked by Texfi Industries and their remediation contractor to assess the ground water conditions at the referenced site. During this assessment activity, two major characteristics used in developing the original ground water remediation plan and subsequent Non -Discharge permit application have changed. Because of these site characteristic changes, Aquaterra on behalf of Texfi Industries is requesting two permit modifications to the existing permit. Modification No. 1 The original remediation plan and permit included ground water removal from (10) one gallon per minute (gpm) shallow recovery wells and (one) 50 gpm intermediate recovery well. Because of a significant drop in ground water table depth, all but four of the shallow wells will need to be abandoned. Three of the remaining shallow wells will require redrilling before they are usable. This redrilling is necessary to provide a sufficient depth of ground water in these wells for four -inch diameter submersible pumps. These three wells are RW-4a, RW-7a, and RW-10a. These three wells will be combined with the original 50 gpm recovery well, RW-11, to capture the existing ground water contaminant plume. The fourth shallow well, RW-8, will be used to recover ground water impacted by the past release of Dowtherm heat transfer fluid. The extracted ground water from this well will be treated by activated carbon adsorption. Two 170-pound carbon canisters connected in series will be used to treat the ground water from this well exclusively. The carbon is required to adsorb the Dowtherm constituents. Corporate Office Charlotte Office Greensboro Office P. O. Box 50328 P. O. Box 668107 P. O. Box 16241 Raleigh, NC 27650 Charlotte, NC 28266-8107 Greensboro, NC 27416-0241 (919) 859-9987 (704) 525-8680 (919) 273-5003 FAX (919) 859-9930 FAX (704) 527-2792 FAX (919) 271-8138 ___i Permit Modification L2471-92 March 10, 1992 Page 2 Modification No. 2 The second modification involves the deletion of the proposed metal treatment/removal system from the permit. Aquaterra has reviewed the data collected by C.T. Main and concluded that only one round of samples collected and analyzed were used to determine the need for the metal treatment system. Of these samples, only three wells, MW-3, MW-4a, and MW-8, had nickel readings above the state's GA standards for nickel (0.15 parts per million). Only one well, MW-8, was equal to the same GA standards for zinc (5.0 parts per million). Aquaterra recently completed a pumping test of the new extraction wells, RW-4a, RW-7a, and RW-10a. During the pumping test, both discrete and composite samples were collected to determine the levels of nickel and zinc in the extracted ground water. The samples were analyzed by EPA Method 200.7 (see Table 1). Based on the results of this sampling and the low levels of zinc and nickel present in the earlier C. T. Main work, Aquaterra is requesting the deletion, at least temporarily, of the metal treatment/removal system. To monitor the effluent metal levels, Aquaterra is recommending changing Permit Condition IV.3. to monthly effluent water sampling for metals for the first 12 months of remediation system operation. If the sample results do not indicate an increase the levels of nickel and zinc, the sampling would change to quarterly for one year, and then eventually to semiannual sampling. If the sampling indicates an increase in the metal levels above the GA standards, Texfi would stop remediation until the high metal levels could be treated by adding the capability to the overall remediation system. To make review of these requests as simple as possible, Aquaterra is including the original permit and a completed DEM form LLPG 4/91 as attachments. If you have any questions on the above modification requests, please do not hesitate to contact us at (919) 859-9987. Sincerely, AQUATERRA, INC. Bruce D. Reilly, P. . Senior Project Manager BDR/pjc CARnC��'s% SSIp •. q /fe 15532 00 cc: Mr. Michael Miller - Texfi Industries Mr. Harold Bynum - Smith, Helms, Mulliss & Moore AQllAMRRA Table 1. Ground Water Analytical Results. Well No. Nickel Zinc RW-4a <0.03 <0.02 RW-7a <0.03 <0.02 RW-10 <0.03 0.06 Composite <0.03 0.04 WQS1 0.15 5.0 1 Water Quality Standard (T15A: 02L .0202(g)) Analytical Laboratory: Industrial & Environmental Analysts, Inc. Cary, North Carolina Aquaterra Job No. 778 L2471-92 State of North Carolina Department of Environment, Health, and Natural Resources Division of Environmental Management Non -Discharge Permit Application (THIS FORM MAY BE PHOTOCOPIED FOR USE AS AN ORIGINAL) SEPTIC TANK / LOW PRESSURE PIPE / GRAVITY SUBSURFACE DISPOSAL SYSTEMS [FOR MECHANICAL TREATMENT SYSTEMS WITH SUBSURFACE DISPOSAL USE FORM MTDS1 (THEDIVISION OF ENVIRONMENTAL MANAGEMENT HAS JURISDICTION IF THE SYSTEM TREATS INDUSTRIAL WASTEWATER OR IF THE SYSTEM IS OWNED BY A SANITARY DISTRICT, A METROPOLITAN SEWAGE DISTRICT, A WATER & SEWER AUTHORITY, A COUNTY, A MUNICIPALITY, OR A PUBLIC UTILITY. THE DIVISION OF ENVIRONMENTAL HEALTH HAS JURISDICTION FOR OTHER DOMESTIC SUBSURFACE SYSTEMS) I. GENERAL INFORMATION: 1. Applicant (corporation, individual, or other): Texfi Industries, Inc. 2. Print Owners or Signing Official's Name and Title (the person who is legally responsible for the facility and its compliance): Michael Miller, Executive Vice President 3. Mailing Address: 5400 Glenwood, Suite 318 City: Raleigh State: NC Zip: 27612 Telephone No.: 9( 19 ) 783-4736 4. Project Name (subdivision, facility, or establishment name - should be consistent with project name on plans/specs., letters of flow acceptance, Operational Agreements, etc.): Texfi Industries, New Bern Facility 5. Application Date: 3/6/92 7. County where project is located: Craven 6. Fee Submitted: $ 8. Address of treatment and subsurface facility: Highway 55, New Bern, NC 9. Latitude: 350 08' 23" ; Longitude: 770 6' 36" of subsurface fields FORM: LPPG 4/91 Page 1 of 10 LOW PRESSURE/GRAVITY PA ? (4/91) II. PERMIT INFORMA .tON: 1. Permit No. (will be completed by DEM): 2. Specify whether project is: new; renewal*; X modification. *If renewal, complete only sections I, II, III and applicant signature (on pg.9). Submit only pgs. 1, 2, 9 (original and 3 copies of each). Engineer signature not required for renewal. 3. If this application is being submitted as a result of a renewal or modification to an existing permit, list the existing permit number W00004936 and issue date 9/23/91 4. Specify whether the applicant is public or X private. 5. Specify whether applicant is: sanitary district; metropolitan sewage district; water & sewer authority; county; municipality; public utility; X other (explain) Industry III. INFORMATION ON WASTEWATER: 1 Nature of Wastewater: % Domestic; % Cornmercial; % Industrial; 100 % Other waste (specify): Ground Water 2. Please provide a one or two word description specifying the origin of the wastewater, such as school, subdivision, hospital, commercial, industrial, apartments, etc.: Ground Water Remediation 3. If wastewater is not domestic in nature, what level of pretreatment has been provided to ensure protection of the receiving treatment system: Complete for known contaminants 4. Volume of wastewater generated by this project: 129,600 gallons per day 5. Explanation of how wastewater volume was determined: Yield test on recovery wells 6. Brief project description: Ground water extraction plus treatment by either carbon adsorption or air stripping for organic removal There may be questions on this application that are not applicable to the subject project, such as questions aimed at low pressure systems vs. gravity systems. In those instances state not applicable or N/A; however, be certain that all pertinent questions have been answered or the application package will be returned as incomplete. IV. DESIGN INFORMATION: 1. Specify the type of system that is being installed: low pressure; X gravity; other 2 of 10 V P RES S URE/G RA V ITY ; E 3 (4/91) 2. Provide a brief listing of the components of this treatment and disposal system (if not covered by specific questions below), including dimensions, capacities, loading rates, and detention times of tanks, pumping facilities (duplex pumps), high water alarms, filters (specify type), ponds, lagoons, disinfection facilities, subsurface fields, etc.: 60 GPM air stripping unit, all wells; 2 170 pound carbon canisters, well RW-8; and infiltration trench (400' x 3') 3. Specify the loading rate recommendation, as determined by the soils scientist, for the subsurface disposal field: GPD per square foot 4. Specify the loading rate recommendation, as determined by the soils scientist, for the repair area (100% replacement) subsurface disposal field: N/A GPD per square fL 5. Specify design loading rate that will occur in disposal field: 24 GPD / fL2 (In coastal areas the maximum is 1.5 GPD / square foot for gravity systems and 1.0 GPD per square foot for low pressure systems). 6. Specify the number of subsurface fields: 1 The dimensions of the fields: 400' long x 3' wide x ± 8' deep ; Supply line dia.: ; Manifold dia.: ; Distribution lateral dia.: 4" ; Hole dia.: 2" ; Number of laterals: 1 ; Lateral length (typically 70 ft. max. for LPP & 100 ft. max. for gravity): 400' ; Trench width: 31 ; Trench depth: 8 ' ; Minimum pressure head: Gravity . Maximum pressure head: Gravity ; Minimum vertical separation between trench bottoms and mean seasonal high water table: 2' ; Distance on centers (for LPP not less than 5 ft.): N/A ; Maximum slope of trenches (should be less than 0.2% for gravity systems): 0•1% ; Details must be provided in plans/specs which demonstrate that the ends of lines are plugged, that turn -ups are provided for LPP, and that measures will be taken (grade boards, etc.) to ensure that laterals are properly installed. 7. The following criteria should be used for the sizing of residential septic tanks: a. three bedrooms or less, use minimum 900 gallons; b. four bedrooms, use minimum 1000 gallons; c. five bedrooms, use minimum 1250 gallons. 8. For businesses with a design flow less than 600 GPD, the minimum tank capacity shall be twice the flow. 3 of 10 LOW PRESSURE/GRAVITY AGE 4 (4/91) 9. The following criteria should be used for the sizing of septic tanks for residences with more than five bedrooms, multiple family residences, tanks serving two or more residences*, or establishments with a flow between 600 GPD and 1500 GPD: Septic Tank Volume = (1.17) (daily sewage flow) + 500 gallons *Minimum septic tank capacity shall be 1500 gallons 10. For design flows between 1500 GPD and 4500 GPD, the following criteria shall be used: Septic Tank Volume = (0.75) (daily sewage flow) + 1125 gallons 11. For design flows which exceed 4500 GPD, use a septic tank capacity equal to the flow. 12. Specify the septic tank volume: gallons 13. Specify the pump tank volume: gallons 14. Specify the number of pumps and their capacity: pumps at GPM 15. Specify the high water alarms: audible & visual; auto dialer 16. Name of closest downstlope surface waters: 17. Classification of closest downslope surface waters: (as established by the Environmental Management Commission and specified on page 7 of this application). 18. If a power failure at the facility could impact waters classified as WS, SA, B, or SB, describe which of the measures are being implemented to prevent such impact, as required in 15 NCAC 2H .0200: 19. The different disposal fields, laterals, or groups of laterals in a subsurface system are typically designed to be dosed at different rates or volumes from one another. Explain the method that will be used to ensure that the proper dosing rates and volumes occur: 20. The project must conform to the following buffers: a) 100 feet between the disposal area and any public or private water supply including wells; b) 50 feet between disposal area and waters classified as WS-I, WS-II, WS-III or B; and 100 feet between the disposal area and the normal high water level of waters classified as SA or SB; c) 50 feet between any the disposal area and any stream, lake, river, or natural drainage way; d) 50 feet between the treatment/disposal systems and property lines; 4 of 10 W PRESSURE/GRAVITY jE 5 (4/91) e) 10 feet between the disposal area and any surface water interceptor drains or diversions (upslope); f) 25 feet between the disposal area and any surface water interceptor drains or diversions (downslope) and any groundwater drainage systems; g) 20 feet between disposal area and any other subsurface disposal area except the repair area. 21. If any of the applicable buffers are are not being met, please explain how the proposed buffers will provide equal or better protection of the Waters of the State with no increased potential for nuisance conditions: THIS APPLICATION PACKAGE WILL NOT BE ACCEPTED BY THE DIVISION OF ENVIRONMENTAL MANAGEMENT UNLESS ALL OF THE APPLICABLE ITEMS ARE INCLUDED WITH THE SUBMITTAL Required Items a. One original and three copies of the completed and appropriately executed application form. b. The appropriate permit processing fee, in accordance with 15A NCAC 2H .0205(c)(5). c. Five sets of detailed plans and specifications signed and sealed by a North Carolina Professional Engineer. The plans must include a general location map, a topographic map, a site map which indicates where borings or hand auger samples were taken, a map showing the treatment/disposal facilities, buffers, structures, and property lines; along with all wells, surface waters (100-year flood elevation), and surface drainage features within 500 feet of the treatment/disposal facilities. Each sheet of the plans and the first page of the specifications must be signed and sealed. d. Five copies of an Operational Agreement (original and 4 copies) must be submitted if the wastewater treatment and disposal facilities will be serving single family residences, condominiums, mobile homes, or town houses and if the subject facilities will be owned by the individual residents, a homeowners association, or a developer. e. Five copies of all reports, evaluations, agreements, supporting calculations, etc., must be submitted as a part of the supporting documents which are signed and sealed by the North Carolina Professional Engineer. Although certain portions of this required submittal must be developed by other professionals, inclusion of these materials under the signature and seal of a North Carolina Professional Engineer signifies that he has reviewed this material and has judged it to be consistent with his proposed design. f. Five copies of the existing permit if a renewal or modification. g. A soils scientist report which includes texture, color, and structure of soils down to a depth of seven feet, depth, thickness and type of any restrictive horizons, hydraulic conductivity in the most restrictive horizon, cation exchange capacity (CEC), depth of seasonal high water table, soil pH, soils map (if available), and recommended loading rates. This report must be signed by the soils scientist. 5 of 10 L( 'RESSURE/GRAVITY- PAGE 6 (4/91) h . For systems treating industrial waste or any system with a design flow greater than 25,000 GPD a hydrogeologic and soils description of the subsurface to a depth of twenty feet or bedrock, whichever is less. The number of borings shall be sufficient to determine significant changes in lithology, the vertical permeability of the unsaturated zone and the hydraulic conductivity of the saturated zone, depth to the mean seasonal high water table, and a determination of transmissivity and specific yield of the unconfined aquifer. i. Proposal for groundwater monitoring. j. Information on the location, construction details, and primary usage of all wells within 500 feet of the treatment/disposal facilities. k. For industrial waste a complete chemical analysis of the typical wastewater to include, but not be limited to Total Organic Carbon, BOD, COD, Chlorides, Phosphorus, Ammonia, Nitrates, Phenol, Total Trihalomethanes, Toxicity Test Parameters, Total Halogenated Compounds, Total Coliforms, and Total Dissolved Solids. 6 of 10 LO'— , RESSURE/GRAVITY PAGE 7 (4/91) TO: REGIONAL WATER QUALITY SUPERVISOR Please provide me with the classification of the surface waters identified in number 5 below and on the attached map segment: Name of surface waters: Classification (as established by the Environmental Management Commission): Proposed Classification, if applicable: Signature of regional office personnel: INSTRUCTIONS TO ENGINEER Date: In order to determine whether provisions for dual or standby power may be required for the subject facility, the classification of the closest downslope surface waters (the surface waters that any overflow from the facility would flow toward) must be determined. You are required to submit this form, with items 1 through 10 completed, to the appropriate Division of Environmental Management Regional Water Quality Supervisor (see attached listing). At a minimum, you must include an 8.5" by 11" copy of the portion of a 7.5 minute USGS Topographic Map which shows the subject surface waters. You must identify the location of the facility and the closest downslope surface waters (waters for which you are requesting the classification) on the submitted map copy. The application may not be submitted until this form is completed and included with the submittal. Applicant (corporation, individual, or other): 2. Name and Complete Address of Engineering Firm: City: Telephone No. 3. Project Name: 4. Facility design flow: State: Zip: 5. Name of closest downslope surface waters: 6. County(s) where project and surface waters are located: 7. Map name and date: 8. North Carolina Professional Engineer's Registration No. 9. Print Name of Engineer 10. Seal and Signature (specify date): GPD 7 of 10 DIVISION OF ENVIRONMENTAL MANAGEMENT REGIONAL OFFICES (4/91 Asheville Regional WQ Super. Washington Regional WQ Super. Raleigh Regional WQ Super. 59 Woodfin Place P O Box 1507 3800 Barrett Dr., Suite 101 Asheville, NC 28802 Washington, NC 27889 Raleigh, NC 27609 704/251-6208 9191'946-6481 919/733-2314 Avery Buncombe Burke Caldwell Cherokee Clay Graham Haywood Henderson Jackson Macon Madison McDowell Mitchell Polk Rutherford Swain Transylvania Yancy Fayetteville Regional WQ Super. Wachovia Building, Suite 714 Fayetteville, NC 28301 919/486-1541 Beaufort Bertie Camden Chowan Craven Currituck Dare Gates Greene Hertford Hyde Jones Lenoir Martin Pamlico Pasquotank Perquimans Pitt Tyrell Washington Wayne Mooresville Regional WQ Super. 919 North Main Street Mooresville, NC.28115 704/663-1699 Anson Moore Alexander Mecklenburg Bladen Robeson Cabamrs Rowan Cumberland Richmond Catawba Stanly Harnett Sampson Gaston Union Hoke Scotland Iredell Cleveland Montgomery Lincoln Winston-Salem Regional WQ Super. 8025 North Point Boulevard, Suite 100 Winston-Salem, NC 27106 919/761-2351 Alamance Rockingham Alleghany Randolph Ashe Stokes Caswell Surry Davidson Watauga Davie Wilkes Forsyth Yadkin Guilford 8 of 10 Chatham Nash Durham Northampton Edgecombe Orange Franklin Person Granville Vance Halifax Wake Johnston Warren Lee Wilson Wilmington Region. WQ Super. 127 Cardinal Drive Extension Wilmington, NC 28405-3845 919/395-3900 Brunswick New Hanover Carteret Onslow Columbus Pender Duplin LOW PRESSURE/GRAVITY Po (4/91) Name and Complete Address of Engineering Firm: C. T . Main (original) Aquaterra (revisions); 901 Jones Franklin Road City: Raleigh State: NC Telephone No. (919) 859-9987 Zip: 27606 Professional Engineer's Certification: _ I, Z) , attest that this application for 7,4z- has been reviewed by me and is accurate and complete to the besf of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Registration No. ff3 Print Name of Engineer 1:��Ce Seal and Signature (specify date): ;OES1�` s� SCAB JJJL s O0`..Q,.aa�e Applicant's Certification: �141111 111%; I, Dane Vincent , attest that this application for Infiltration Trench at the New Bern Facility has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that if all required parts of this application are not completed and that if all required supporting information and attachments are not included, this application package will be returned as incomplete. /' Signature Date `� THECOMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DIVISION OF ENVIRONMENTAL MANAGEMENT WATER QUALITY SECTION PERMITS AND ENGINEERING UNIT POST OFFICE BOX 29535 512 NORTH SALISBURY STREET RALEIGH, NORTH CAROLINA 27626-0535 TELEPHONE NUMBER: 919/733-5083 9 of 10 LOW PRESSURE/GRAVITY Pag (4/91) PERMIT APPLICATION PROCESSING FEES (effective October 1, 1990) CATEGORY NEW APPLICATIONS/ RENEWALS WITHOUT MODIFICATIONS MODIFICATIONS > 1,000,000 GPD Industrial $400 $300 Domestic/Cooling Water $400 $300 10,001 - 1,000,000 GPD Industrial $400 $250 Domestic/Cooling Water $400 $250 1,001 - 10,000 GPD Industrial $400 $200 Domestic/Cooling Water $400 $200 < or = 1,000 GPp and Single Family Dwelling $240 $120 Sludge < or = 300 Acres $400 $250 Sludge > 300 Acres $400 $250 Sewer Extensions (nondelegated) $400 0 Sewer Extensions (delegated) $200 0 Closed -Loop Recycle or Evaporative $400 $200 NOTE: The Fees for Soil Remediation Projects are the same as for Sludges. Under the Sewer Extension Fee, "delegated to municipalities" applies only to those governmental jurisdictions that have specific delegation review authority, as granted by the Division of Environmental Management. 10 of 10 State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management 512 North -Salisbury Street • Raleigh, North Carolina 27626-0535 James G. Martin, Governor George T. Everett, Ph.D. William W. Cobey, Jr., Secretary Director September 23, 1991 Mr. Michael A. Miller, Executive Vice President Texfi Industries 5400 Glenwood Avenue, Suite 318 Raleigh, North Carolina 27612 Subject: Permit No. WQ0004936 Texfi Industries New Bern Facility Groundwater Remediation Facility Dear Mr. Miller: Craven County In accordance with your application received April 11, 1991, we are forwarding herewith Permit No. WQ0004936, dated September 23, 1991, to Texfi Industries for the construction and operation of a groundwater remediation facility. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the conditions and limitations as specified therein. Please pay particular attention to the monitoring requirements in this permit. Failure to establish in adequate system for collecting and maintaining the required operational information will result in future compliance problems. If any parts, requirements, or limitations contained in this permit are unacceptable to you, you have the right to request an adjudicatory hearing ttpotr written request within 30 days following receipt of this permit. This request must be in the fotlll of :t written petition, conforming to Chapter 150B of North Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Box 11666, Raleigh, NC 27604. Unless such demands are made this permit shall be final and binding. One set of approved plans and specifications is being forwarded to you. If you need additional information concerning this matter, please contact Mr. MArk Hawes at 919/ 733-5083. ce cc: Craven County Health Department Georg Washington Regional Office Groundwater Section Chas. T. Main, Incorporated Facilities Assessment Unit Pollution Prevention Pays P.O. Box 29535, Raleigh, North Carolina 27626-0535 Teleplumc 919-733-7015 An Equal Opportunity Affirmative Action Employer NORTH CAROLINA ENVIRONMENTAL MANAGEMENT CO IISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH INFILTRATION GALLERY PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Texfi Industries Craven County FOR THE construction and operation of a groundwater remediation facility consisting of ten 1 GPM recovery wells, a 50 GPM recovery well, a metal removal system with caustic soda, polymer, and sulfuric acid feed equipment for the treatment of groundwater streams from wells RW-3 and RW-4, dual carbon adsorption units for the treatment of groundwater streams from wells RW-8 and RW-9, a 60 GPM air stripping unit with flow equalization for the treatment of groundwater streams from all recovery wells, a 3 foot by 400 foot upgradient infiltration gallery with groundwater mounding monitoring equipment, and, if needed, an additional 3 foot by 400 foot infiltration gallery to serve Texfi Industries New Bern facility with no discharge to the surface waters, pursuant to the application received April 11, 1991 and in conformity witli the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the following specified conditions and limitations: I. PERFORMANCE STANDARDS l . Upon completion of construction and prior to operation of this permitted facility, a certification must be received from a professional engineer certifying that the permitted facility has been installed in accordance with this permit and the approved plans and specifications. Mail the Certification to the Permits and Engineering Unit, P.O. Box 29535, Raleigh, NC 27626-0535. 2. The Washington Regional Office, phone no. (919) 946-6481 shall be notified at least forty-eight (48) hours in advance of operation of the installed facilities so that an in -place inspection can be made. Sucli notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. 3. This permit shall become voidable if the soils fail to adequately absorb the wastes and may be rescinded unless the facilities are installed, maintained, and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 4. In the evert that the facilities fail to perform satisfy 'ly, including the creation of nuisance ci Lions, the Permittee shall take immedi :orrective action, including those as may ue required by this Division, such as use construction of additional or replacement treatment or disposal facilities. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 6. Any sludge generated from these treatment facilities must be disposed of in accordance with General Statute 143-215.1 and in a manner approved by the North Carolina Division of Environmental Management. 7. Diversion or bypassing of the untreated groundwater from the treatment facilities is prohibited. II. OPERATION AND MAINTENANCE REQUIREMENTS 1. The facilities shall be properly maintained and operated at all times 2. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge of the wastewater treatment facilities. The operator mast hold a certificate of the type and grade at least equivalent to the classification assigned to the wastewater treatment facilities by the Certification Commission. Once the facility is classified, the Permittee must submit a letter to the Certification Commission which designates the operator in responsible charge within thirty days after the wastewater treatment facilities are 50% complete. 3. The facilities shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastewater resulting from the operation of this facility. III. MONITORING AND REPORTING REQUIREMENTS I. Any monitoring deemed necessary by the Division of Environmental Management to insure surface and ground water protection will be established and an acceptable sampling reporting schedule shall be followed. 2. Noncompliance Notification: The Permittee shall report by telephone to the Washington Regional Office, telephone no. (919) 946-6481, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the wastewater treatment facility which results in the treatment of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a basin or tank; the known passage of a slug of hazardous substance through the facility; or any other unusual circumstances. b. Any process unit failure, due to known or unknown reasons, that render the facility incapable of adequate wastewater treatment such as mechanical or electrical failures of pumps, aerators, compressors, etc. 2 C. Any failure of a pumping station, sewer line, or treatment facility resulting in a by directly to receiving waters withou ztment of all or any portion of th- ...--uent to such station or facility. d. Any time that self -monitoring information indicates that the facility is not in compliance with its permit limitations. Persons reporting such occurrences by telephone shall also file a written report in letter form within 15 days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. IV. GROUNDWATER REQUIREMENTS Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. 2. All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 3. The influent and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) months and quarterly thereafter for the parameters specified below: Total Nickel Total Zinc Volatile Organic Compounds - by Method 1 or Method 2 below Method 1: Method 6230D ( Capillary - Column), "Standard Methods for the Examination of Water and Wastewater", 17th edition, 1989 Method 2: Method 502.2 " Methods for the Determination of Organic Compounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 2761 1-7687 within 30 days of sample collection. 4. Two (2) weeks prior to system start -tip, the Permittee shall notify the Division of Environmental Management's Washington Regional Office that operation is about to commence. 5. The groundwater recovery treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office. V . INSPECTIONS Adequate inspection, maintenance and cleaning shall be provided by the Perrmittee to insure proper operation of the subject facilities. 3 2. The Permittee or his designee shall inspect the groundwater recovery and treatment facilities to rent malfunctions and deterioration, rator errors and discharges which may ..use or lead to the release of wastes IV Me environment, a threat to human health, or a nuisance. The Permittee shall keep an inspection log or summary including at least the date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Permittee for a period of three years from the date of the inspection and shall be made available upon request to the Division of Environmental Management or other permitting authority. 3. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site and facility at any reasonable time for the purpose of determining compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. VI. GENERAL CONDITIONS 1. This permit shall become voidable unless the facilities are constructed in accordance with the conditions of this permit, the approved plans, specifications and other supporting data. 2. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 3. This permit is not transferable. In the event there is a desire for the facilities to change ownership, or there is a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 4. The Permittee shall obtain a well construction permit from the Washington Regional Office prior to construction of the recovery wells. 5. Prior to a transfer of this land to a new owner, a notice shall be given to the new owner that gives full details of the materials applied or incorporated at this site. 6. A set of approved plans and specifications for the subject project must be retained by the Permittee for the life of this project. 7. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6. 8. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205 (c)(4). 9. The issuance of this permit does not preclude the Permittee fi•om complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. al 10. The Permittee, at least six (6) months prior to the expiration of this permit, shall request its a ision. Upon receipt of the request, t 'ommission will review the adequacy o: facilities described therein, and if w,....,nted, will extend the permit for such period of time and under such conditions and limitations as it may deem appropriate. Permit issued this the 23rd day of September, 1991 NORTH CAROLINA ENVIR G orge T. Everett, u- ctor Division of Envi nmental M, kt�* By Authority of Permit Number WQ0004936 AL MANAGEMENT COMMISSION nent Management Commission 5 Permit No. WQ00049" -September 23, 1991 Engineer's Certification 1, , as a duly registered Professional Engineer in the State of North Carolina, having been authorized to observe (periodically, weekly, full time) the construction of the project, Project Name Location for the Permittee hereby state that, to the best of my abilities, due care and diligence was used in the observation of the construction such that the construction was observed to be built within substantial compliance and intent of the approved plans and specifications. Signature Date Registration N 9 31 3!9 51000C FEET 3989 07'30" 77.07 Mapped, edited, and published by the Geological Survey Control by USGS, NOS/NOAA, and North Carolina Geodetic Survey • Topography by photogrammetric methods from aerial photographs taken 1974. Field checked 1975. Map edited 1978 Selected hydrographic data compiled from NOS 11552 (1975) This information is not intended for navigational purposes Projection and 10,000-foot grid ticks: North Carolina coordinate system (Lambert conformal conic) 1000-meter Universal Transverse Mercator grid, zone 18 1927 North American datum . Fine red dashed lines indicate selected fence and field lines where generally visible on aerial photographs. This information is unchecked — 310 5' HAVELOCK 20 /d! ♦. 1 MNJ 1000 GN 61h 116 MILS 1.11, 21 MILS uT•y GRltr AHu 1978 MAGNETIC NORTH DECLINATION AT CENTER OF SHEET A FC• - RATING __ lLE FOR CLASSIFICATION OF �CILITIES Name of Plant: /2xE Owner or Contact Person: 44r. /A'CA-e Mailing Address: --------------------�----- County: Telephone: 7 z,-,13 -1t7Y NPDES Permit No. NC00 Nondisc. Per. No. c--a6t'2n y4 36 IssueDate: -7ro - / Expiration Date: V7/�� Existing Facility New Facility Rated By: A& I(leo Date: Reviewed (Train. & Cert.) Reg. Office_ Reviewed (Train. & Cert.) Central Office ORC EM Grade POINTS ITEM t �) Industrial Pretreatment Units and/or Industrial Pretreatment Program (see -definition No. 33) DESIGN FLOW OF PLANT IN GPD (not applicable to non -contaminated cooling waters, sludge handling facilities for water purification plants, totally closed cycle systems (def. No. 11). and facilities consisting only of Item (4) (d) or Items (4) (d) and (11) (d)) 0 20,000.......................... 20.001 50.000.......................... 50.001 100.000.......................... 100.001 -- 250.000.......................... 250,001 -- 500,000.......................... 500.001--1,000,000.......................... 1,000,001 -- 2,000,000 .... . ................... 2,000.001 (and up) - rate I point additional for each 200.000 gpd capacity up to a maximum of 30 Design Flow (gpd) 3) PRELIMINARY UNITS (see definition no. 32) (a) Bar Screens ....... . ........................ or (b) Mechanical Screens, Slavic Screens or Comminuting Devices ........... ............. (c) Grit Removal ...... . ........................ or 1 2 4 5 8 10 (d) Mechanical or Aerated Grit Removal . , .... , . _ .. 2 (e) Flow Measuring Device ....................... 1 or (1) Instrumented Flow Measurement .............. (g)Preaeralion................................ 2 (h) Influent Flow Equalization ................... (i) Grease or Oil Separators - Gravity .......... 2 Mechanical .......... 3 (j) PreChlorinalion Dissolved Air Flotation. 8 . 5.......................... (4) PRIMARY TREATMENT UNITS POI "'I (a) Septic Tank (see definition no. 43) .............. (b) Imhoff Tank ................................. . (c) Primary Clarifiers ............................ (d) Settling Ponds or Settling Tanks for Inorganic Non -toxic Materials (sludge handling facilities for water purification plants, sand, gravel, stone, and other mining operations except recreational activities such as gem or gold mining) ...................................... (5) SECONDARY TREATMENT UNITS (a) Carbonaceous Stage (i)Aeralion - High Purity Oxygen System . �.. , 2 Diffused Air System ........... 1 Mechanical Air System (fixed, floating or rotor) .............. Separate Sludge Reaeration ..... (i i) Trickling Filler High Rate ................... Standard Rate ............... Packed Tower ............... (iii) Biological Aerated Filter or Aerated Biological Filter ...................... 1 (iv) Aerated Lagoons ..................... . 1 (v) Rotating Biological Conlactors ...... . . (vi) Sand Fillers - intermittent biological . . . . . recirculating biological . . . . . (vii) Stabilization Lagoons ................... (viii)Clarilier ......... .. C . .................. (ix) Single stage system for combined carbonaceous removal of BOO and nitrogenous removal by nitrification (see def. No. 12) (Points for this item have to be in addition to items (5) (a) (i) through (5) (a) (viii) ................. (x) Nutrient additions to enhance BOO removal ............................... (xi) Biological Culture ('Super Bugs-) addition to enhance organic compound removal .... . Nitrogenous Stage (i) Aerztion - High Purity Oxygen System . . . . . 20 (i) Sludge Holding Tank - Aerated ................ 5 Diffused Air System .. - . . • .. 10 Non -aerated ............. Mechanical Air System d, (j) Sludge Incin r - (not including activated floating, or rotor) ...... ...... 8 carbon regeneration) ..... 10 Separate Sludge Reaeralion ..... 3 (k) Vacuum Filter, Centrifuge or Filler Press or other ii) Trickling Filter - similar dewalering devices ...... . .......... ... 10 High Rate .............. 7 Standard Rate ............ 5 (8) SLUDGE DISPOSAL (including incinerated ash) Packed Tower............ 5 (a)Lagoons........................................ 2 i i i) Biological Aerated Filter or Aerated (b) Land Application (surface and subsurface) Biological Filter ................. • . • • • . 10 (see definition 22a) tiv) Rotating Biological Contactors ............ 10 -where the facility holds the land app. permit 1 0 (v) Sand Filter- -by contracting to a land application operator who intermittent biological ........ 2 holds the land application permit ................ 2 recirculating biological ........ 3 -land application of sludge by a contractor who does (vi) Clarifier ................................ 5 not hold the permit for the wastewater treatment facility where the sludge is generated .......... 1 0 4RY OR ADVANCED TREATMENT UNIT (c) Landflled (burial) ............................. 5 clivated Carbons Beds - (9) DISINFECTION without carbon regeneration .................. © (a) Chlorination .............................. 5 with carbon regeneration .................... 15 (b) Dechlorination ........................ 5 owdered or Granular -Activated Carbon Feed - (c) Ozone .............................. 5 without carbon regeneration ................. 5 (d) Radiation .......................... 5 with carbon regeneration ................... 15 (10) CHEMICAL ADDITION SYSTEM (S) (See definition No. 9) Air Stripping < (not applicable to chemical additions rated as item Oenitrification Process (separate process) .... . 10 (3) 0). (5) (a) (x7, (6) (a), (6) (b), (7) (b), (7) (e), Electrodialysis ........................... • .. 5 (9) (a)• (9) (b), or (9) (c) 5 points each: List: Foam Separation ............................. 5 (.arcs f,'c Sscb . . . . . {c Ion Exchange ................................. 5 �o lY .t ar . . . . . y Land Application of Treated Effluent (( 5 (see definition no. 22b) (not applicable for . . . . . 5 sand, gravel, stone and other similar mining (11) MISCELLANEOUS UNITS operations) (a) Holding Ponds, Hong Tanks or Settling Ponds ,,(i) on agriculturally managed sites (See def. for Organic or Toxic Materials including wastes No. 4)................................... 10 from mining operations containing nitrogen and/or (ii) by high rate infiltration on non -agriculturally phosphorous compounds in amounts significantly managed sites (includes rotary distributors greater than is common for domestic wastewater .......... 4 and similar fixed nozzle systems) ........... O4 (b) Effluent Flow Equalization (not applicable to storage (iii) by subsurface disposal (includes low pressure basins which are inherent in land application systems). 2 pipe systems and gravity systems except at (c) Stage Discharge (not applicable to storage basins plants consisting of septic tank and nitrifica- inherent in land application systems ....................................... 5 lionlines only) ............................. 4 (d) Pumps ... __--__._... ............................................................................. ® Microscreens.................................. 5 (e) Stand -By Power Supply.................................................................. 3 Phosphorus Removal by Biological Processes (1) Thermal Pollution Control Device ............................................. 3 (See def. No. 26) ............................. 20 Polishing Ponds - without aeration ....... 2 with aeration .......... 5 Post Aeration - cascade .............. 0 diffused or mechanical ... 5 TOTAL POINTS S� Reverse Osmosis ............................... 5 Sand or Mixed -Media Filters - low rate ........... 2 high rate .......... 5 CLASSIFICATION Treatment processes for removal of metal or cyanide .................................... 1 S Class I............----.......---................................. 5 - 25 Points Treatment processes for removal of toxic Class II ................ ....................................... 26- 50 Points materials other than metal or cyanide ......... 15 Class III ....................................................... 51- 65 Points Class IV ............. _........................................ 66- Up Points AGE TREATMENT Facilities having a rating of one through four points, inclusive, Sludge Digestion Tank -Healed ............... 10 do not require a certified operator. Classification of all other Aerobic ............... 5 facilities requires a comparable grade operator in responsible Unheated ...... ....... 3 charge. Sludge Stabilization (chemical or thermal) .... . . . 5 Sludge Drying Beds - Gravity ................. 2 Facilities having an activated sludge process will be assigned Vacuum Assisted ....... 5 a minimum classification of Class II. Mudge Eluldalion ............................. 5 Sludge Conditioner (chemical or thermal) ...... . . 5 Facilities having treatment processes for the removal of metal ;fudge Thickener (gravity) ..... ............. _ . _ , 5 or cyanide will be assigned a minimum classification of Class if. )issolved Air Flotation Unit (not applicable to a unit rates as (3) (i) ... .... . . 8 Facilities having treatment processes for the biological removal Sludge Gas Utilization (including gas storage) . . . . 2 of phosphorus will be assigned a minimum classification of Class - III N IT 10 H5 Calben B.d,. A phrskaVc A•mk11 m•111od le, red-;.9 ,.olvbl• organs m.s,i 11 Irom w .-slur .Irwin,: In. colr,.tet.,rp. bed. , .used wi. have , It— n.,• ...y:rq I.o I-o to •:qru ga..nl p., nl.nvl. per 1q.. 1. Lot ,..d mar W .;,h., ..pno- of d•wnrto- <„bon Leda. Carbon mar na, b. 1.9--1 t•d an ON. w •rtt., V•alm.N Pl.nl ';. . (7 stud l,9oen1. A batin in which at, ,l,Cd, ,.• lauted r .v,P.n,ion ,.d by wl <h biorogk,l e . orgy k-1t.I., ,• r. J..ced .Iw o.7n a•lil.Tll,y I<c....... e utnal., or ,rq• en a rb-� I2)A•., keen, A pe<•ti of bl irtgirtq above nl.mat• (enlace b.t-.en a., or nigh Pv:Ir olyq•n in a Cq and by sp,sying. IC;Izt; n dilfut;on: I, .cvnwa.y minap•d a . Any sit• on -hkh a <,ep I, p,odu<od, m.naq•d. no ha•veilod (C,op w • 9.a I. pra Y .,. eIc): ' IS Suipp;,n,A plo<•tI by which N. . Ion Is f" sl c n<.11.d to diltolvad ammoma (pH a all nm.nt) with Ih- ammonia Then r.w... 4 Io the -,ph- by phy,kal m.sr - r auolner sinJ7u ()weer•, w7Jcn I-- P19- p,educl, loch is bonl•n.. loiu.n•, aril arten., (6" --bon Req-Cation. The r•q.naralion of Ithaun.0 cubon by VI. via of I Ivtmc• to pov(de •1 t.ly high -Wien volasi;le anal ol;d:,. Ih. absorbed nlpur;L•, (7 ben,Nevl 51.q.. A sup. of xaa..-au vu VneN d.I:gn.d 1. .ch;.,.-u<o,dary- .lflvom fir , (. )CenY:I,.g •, A t .lI ;C2I devka n which C-il,gal lo,ce Is used to s•paral• ,W:d, Irom 1;,q,;d. „dew w repast. kAd- of dlwr.N cf mw;.: (9 - 1.I;c.1 Add;l;on Syal.mt - Tit. addden of chemical Is) a xaawwawr .1 an .pplkudn Pa^, to, p, tee e/ Lhptov n sofas an-1. PH adjustm.nL ark-"r eenLol, •la.: the capabl4.7, Io .. men, I ;sn 4a*,•N ch.ni.caft and flf• m appricafen po'ru, to a h'.v. a .p.c;4c 61,44 Will be co .red one sr-: the capa"ty N add ch•ni•c,l 11) to dual wJta a ll be riled a on+ system: Iap.b]:I), I. add a ch•m;cal aI diflre ap;X..6- peal. 1« dAl•I•M p-p.,.. -W r.,,At 1n the . ycs•ma ti-•;np law .. ..past. ay.I.m. (1 m:e al Shag. C-disio-Je-g, Th. addtia- W tI one .:cal e.npovnd such is ". f•rrk cht-;d., « t m•r b xS t slag• ao coalesce Lho mass prior to ;u application to . dowu,4,n device: (I +•o Crcl• ST.wrts- Us• of hoidup P.M. « he16'q tank. lu c.N.nmeN el-aal•wal.r ten „t Laerq.,.;c, non -brie materials from land, pls.e4 uvthad steno w oN•r s;ml.r op.slion., 4.m which ch,ts is sto ,Sschaig• w the swlac• water-; +uch sysl•nu shaft curry a maaimvrn of t..o po:n„ 1•9udl•s, of p.r,tp;rag l.cY.;.s w any that appxl.nl,.ca s• (1 wrabLn 4 Re,:aoval et Carbonaceous 800 Ind 1,4voga 1 R_11 by K.v;Crcat:on - A .;rql• stag• IT n-d..lgn.d' to acl:•r. 'advanced' p.,-;. •fdleN "i; en BOO aM ammeria nuuoge. with;n N .w Uological nastier (I3I0s-ch1win.lion. The patl;al w corraplel• ledvl;;m a: st;duil cN«no in a r-quid by any chem:c.l of Physkil ()natal: I1 - �rJu;f;cat:on Process• Th• c-.,,;on of niYal.-n:voq •n to rluoq•n gas• (1 .cuodittly.u. Prweas lot umo.:ng "led all. U.- -we dveugh the us. of ;on -sus Uire change m nbr.n..: (1 ,. 1•1 Prest. A process top ... led mKhir ,fly for paltiafty d-wfir+9 sk>d9.: (17)Foam Sip ul tort The pf.nn.d Irollwq el wl u.ru•r w - Ia aw, •,tenth as a na•an. of ,mov;ng elc.sliv• ..tat. 48 of d.1•19en1 mal•,:al. Vvough the Llu.dv1s1- W .:r in hie 1— of fn• b. -I.. called I 1' 11 w R•mov.L The process of 1.mo.v1g 9111 end auger h a y r"lal maul, vom-as,e-. w,• (i han Tani A deep by c sorry w2ll•x2ler tank cons;atirq of an upper aedwt•Nal:on charrtbo, and s rower sludge dgestion ctlambar, (20)In.uvm.nt•d Fla. 1A.astair-L A device which ;meat., ardlor records it. of For E.charaq., A chem:c al F-Cc.ss La which ;ens Lom Na ddt•r.N rowcut., I,. ..ch.nq.d: (2 rtd IPPfcaio,: (a) S"9e O;spesaL A [',I[ Iltaeq, dispelal m.Nod by which -ludo. m.y be tp J IQ land .;dter by spr.y;eV on Ilse svdico or by tvbtwlac• nj•cbo„ (1,., cNtei pww): (not IF ibl• W Iyp.I .1 sludge d-lib.d n (11) of Nis Rul•): (b)Ti.ai•d Elnv.nl Th. p,-.ss of ,preying uawd wa.t•-atel onus a land area el allyl rrt.Vtods of aPprc.6- of wa H. water onto a Ord >rs at I moan. of 6n.I dilpoul ardor b.: Vrtenr (2 Krosu.- A low speed, continuously bac),---shed, rctitNg drum r.11.1 opotal;ng vnd•f 9, conrftionr a, . poishinq m.thod r•movng ,v,p.,Z.d solids Iron, .0u.n1: 12 tf;iksl;en Process. Th. bloeh. meal a --Lon of v Lda•d nivog.n (. i, end oll, n;c n.-,,n) to o;l:t.d ry. uoqn (21)H;v oq •noes St19-. A ..paral. stag- of waI•wal.r Vau,t•N da;gn•d t« the sp•c:lk pwpo,• of cen..rtirtg ammo,Ii. 1auogsn to rt;Ulle rJvogon: (2 o s Phll- Re novel Biotog;cal TM r.m tl ai phosphorus Lom wa swwtl.( by in-itlanmk p. I d•.;gn•d 1e . Wince k.sury uptak. of phot,,h_ by tM. rt croo,gl J1ms; 12. iahirq Peed, A hoidulq pond lobwnq -•<ondary, u.stmeN v.:lh .v(Lei•N d.I.-;.n to aa.- I« I the ,est4r g el F -ly s p.M.d solids: I f2<)Po11 A....;a, k... lion lobo w'i^9 conv•nt:onli +.ccrGary 1r..un.N units to L-ise •If)v..1 0.0, or -ny other pvrpoa.: (2' 91 A•,.0 (Cased.) A po6ahi,19 me Nod by which dcsohod o179•n it added w the elduonl by n.chanlcaL 91-tiy means at hose;,() down a i.r;., of awpt w w• <: The Gow oc<w,;'n ,clo,s Ih. rp, er w•ut mw.. n . sLtr th;n lay., .rd the. of-1-d- el vt• -lad- I.gwes ne oP•s adjva,nt•m- viva, ]tre po;nls are ...;"so •run u,_qh th;, i, in •aa•nY0 iI.p to m•.,ng it. "Is of V1. d;tcha,g• p• n;r 01 wd.r.d of Gr.mAar Act;vawd Cuban F..d. A b:opAysic.l cubon poces, That VYLI., b;o1o9'K,l .c 1 and organk .b.olption by u[inq po-e... d or Csnd.r auFvlt•d carbon• Vmg:n andta, •� �sl•d alball it wed convon•d nw the cyste () Imo••, •r. Lon- A 'Irkcensu-cl to polio• a•e ;� pier Io plm.,y va Yn•nr 1]2)pr•Cm;nlly UrJn. Unil operations in the 1r 11 .nt F, o<. ss, .ucA as scl,"'mg aril <omn4nv4; n Nu «.Ptn N. ]qua lot svb,.Ru.m major c'P : iian,: . (] Iv, vi.i Pr. u.iv.. nt: (a)Pr•-uulm.nt Vn:l, InauuA.l. TM cohditio,Jng al a wise al ;u -e b.lot. Oit<h i,q., to I._. w to n•vtr all:. .ubllan:.t Injv,", to •went and 1,•.,m.nt p 1•, er to -11-11 1 Pan: -I I-dvct:on n bad on l L., VSI•n, p,-.,c whkh it to p-.I.d by the I q o..rninq boar a, s\. -,.I•-air u•asm•nl phnl L.Lq I-d: (b)Pn- .tm.nt Props , indu, ;.1 run W , Sul. of EPA I.quw•d pegs- to ,.c.-. an N• n alnq sneer I7r miry Cltsw;tr,. Th' Cent I-Cnq snA, mrovgn which -a newslu I, p.,1.d in I. atmenl o I., In. purpose el ,•moving a. hi•Id. end sv-p•ne.d sold- end BOO -KKh it 11.«ilt.d w:Ih the (l:• -mp,_ Atr Wlvtnl, •,flue nl, and n-plum pu.-;,,: O61R adnlion. O:-;N. u;on Irdeo, +t•,i1;taGon Flats, udClnq d•vke, •m:Itinq 4w,.;ol•t o. .mm. ray,: 9 pl •us. O,m 14 A u•.Im.nl pace,, in I hilly tonllminll.d Cqu:d` t• F. I.d rv� I I membrane hm:nWei r9 ll, pun. I:qu;d I- Lom .usp•nd.d ..W,: . (St I..:nq p;ologw sl Conscw.,. A G.•d bieloCLal growvl ()noel- in -hkh -1s1. x1lar Ito.•, uYough lank, n whKh I l•ri•1 .1 Pall,uy Ivb, , T.d <L I., .w1aU, ue Iaubd: ()?)Sand F7,•r1:(I)Inlu rt1i 11. nt B;olagKal. Fdln,:en of .Invent I000-ino .PI:c land- Uqe .er oN.' I.ol,rr. nl protect .n which Ivnh•r "n b:ed.compe.:,;on it .,p,cl.d 1. p,eouc. d.,.d .w 1.: Ilydr,v,:<, Ladino , . t Ih•-• 1:1,... are <o mp,.,•d h qPW,, and h.., , r. ,,A,:r.q to- 9p, (1.1, than .n.): q b:oloo;:-I N. I'm' , rP• 01 sand 0- 1t e.caed n (a) -;,n use ,.O cups bi4y b ,.cycle •10 Y•nl back N.o VgA N• ,and (c0)S.nd of a-:.•0.41•dii Fill., 1, A Pc6lltitq pros... by -hach •,,Wine 6.-;,I a.. IcN. d the 9h a ,wens .dVc4on eI lulp-nd.d .Los :(')I'- 11, •- hrds A;l I-lo-d-d IJIN F ., -iload: r gnr;y, nq rrt . rn. on. 1. 1-- OP-1s. a nq.:(b)h:gh I.I, . pr.,l hyd„trC1..r lold.d w.., -:u, bad: 9 In. t In• lieu 1;ytl 1 r9-: A, any vas_ In• lo,d...p 1, 1. -Jf ..<..d IN.. gpm„1' (<ijS.c ondiry C11r:l:.r,. A lank >rbw u1• b;oto9;<ll ,it of a W PIaN end which hat Ih. pv.Po el .• .inq ,kudq• „evil led w+N th. bio4"1 ,1 (12)S•PI111. Sla io, qa ,.I Len A Fan of N• ten> .« t0ba:111:on Fawn.•. the It". wd Ikdg. ' I..I rI nIl• •.d le k and a•r.l•4 tole.• .•I_,;<qit11. N. b.,-et: t Ti A •iny:..,,ery -on:.q sank I, -Ncn a.,,I.d 11vdq. II n tens l...:,n .h• Ito-inq II vQi, he lank' ,K.. nee b• apprk ,l.1• for ,.plk land tylr•... •.. i.sg .ingl. family n ,:d.nc.r A,.Ltq ap,Cr of loci glean, or 1• which d; hs,ga le 1 ml+ ation G•td (t <)51vdq. Ory•tl:on< It-- peel. by -Nkh a.p an:< or vo1.0- m>sle, and 1h.dg. it gIl:L•d. lyv.l:oo mrn f"l-d w mere convoll•d :nee ft>bl• on,,mat ter tter IhloVgh In• >cti.i.r of Lh:ng erg anism 1, which irtclld a seal I.c:<:rtq link.: (45)Sldq. Ory;nq O.ds. Mara ca.apruirq natw.i « artiCrclll ear•.. of ()«ova mal•r:.la YPon wltkh dq•ued .•-Iq• sludge is e,;•d by c,aaa0• and •vapor Lon: 146)Slu491 Ek,u;ation. A Frocen W sh.dq• conditiorrnq in which c•11141 c-6-nis - removed by .vc<... ;v• wa hL-.gs -.,% Lash w, N plaN •Iay.nl: (42)S"q. Gas Utilizvi .. Th. prase., of vsi g .ewe9. 9t. I« the PwPole o( n. i. q bushings_ d.:+wq •np:n•s, .Ic.: (et)Sl,dg• Hold Lap lank (A.rawd :veil Hona •Iawd). A 11,Ik NXI.d lee .man -a,wwat.r Ye atmenl planet not <eNaLvrlo . .:wr In inch .ludo. may I- k.pt L.:h, and Ivf+.,n> "),,Iral.r, p„u, I. . Cryirq -01" (i.•. Ii,C,I dlr;nq NC,): This rn.), a don. by addn9 a -mac amo.,N of .r simply to keep the .ladg• L..h, bv: no( noc-ItRy an a-," Nat xwo,Ad be I.q,,iI,d Io -01; • llabi:calan of «9-n- nicer- A nona.rl+d tank •.atdd s;np b. used w if. -I sludge prior b d•-.1•rvq and ".w ai,nOr be V-.d w deems Ih,69. p"•u w dexal.li,sp aril w M rof 111— long p.,iod. (s.v•at day, of d•t.-;-) wit,eln leswirrtq oil« prob:em,: 091Sludge Inc'vIe<a b,[, A 1-1. Celi9n•d to buen alvdg. a 4 b 1•more ae rt»iss 1. and comlavalrLl• m.l.r:+ls Ind 1.d-. the ,Wq. w a swil. ..h• (SO1Shd9• Slab7kal:on (Cn--k-I - Th•Imal)- A Prowl. a make trailed skdg. I.,. odorous and puv-scn24-, and to led-- the p-Ne9.nk w9arti4m Co IiinL Tn;, mty be done by pH adj',vn.N chlo,in. dOfnq, w by h.tl v.mv < (51)Skadq. Tn:<t chore A "a W a•_rne"Is-6 t lank n which the sludge It p.lm:tl.d to s..u. Ind thick•. "sn"), .9il.6on and Vr ir-. (52)Sfabsaion Lagoa.- A ttp• of --;oil;- lagoon ),I -Kith b;obg:c al osidat;en •7 �erp snit mluu ,t effected bT rue„a{ Vanlwr W o Tq.. w hie _wr Lom a;r (roe . poll K:rq pw>d): (SJ)Slud•Br Paver S.a99.11. 0..e. er pori.bl. et..wk.l q.n,s Gq •gvipm.rt� (5c) Suds Suuns. A stationar y tc,... dst;gswd 1. 1.-. e.tdlvd s Lx;nusg sb;od.gradabt• pall; Aal- (heatable soWt, suspended Sards and BOO c,tlocion) Gam murticipal and w+dv. Yi,l xllwxiwf v.Ilm•nl tys:•ma; (SSJT eriury Tr. atmenl A stag. of Vials-rA IoLowLtq s.c.Maq wta:ch is pr;marify Iw the Pulp.- el e19wN P-6lh:rp: A sc;nq I19oon as sand w coal ltt.r 65'N be •mplor.d (w Nit pwpoie. (SC)Th. r j P.thri; n Camel O..ic., A devk. p_;&n9 I« V. vans(., of heal I,_ a Avid yt_:'g in Met to Ine,ra•r livid ,xn.;d• the tubes, w vk. vena: «, other means of requ/.tinq Gg11id wrrlp.ratw.I: (S7)Th•,-al Sladg• Ce,td'it; n , A tcrCiwlirq PICK.- by -tilh heat 1. added Iw a provacsd P.Iiod of hut. w Lr.prov• she d•-1l. rabi:ly of .k.dg. by W. aiah,. uirq .1Id hydr.v4a6p of th. sm.d•t and e highly hrdr.,.d .IvU• ptn;c%,; (511)Tcak klawr;at., That. -I., « ce.tblAl Y.nt of -a.w. 6..IdL g a;a..>.e-caysLt� ag ens -hkh Ill*( 4-huge and upon e,poswe, ;ngaboel inhalation w a.s;mlation into a T o,g artism s;N., dir.cly Lom the •cvironm<N at 41d..cttr by )ngasfion Lhi"h loud cMIni. w;A cause death, d;sals, b.h.r;or.l abeb,m.lri.., e.ne.(, 9.utk snulae;ons, physiotoglcai ma Wnetwrtt (".neh>d.,g matfunel:ons in r.poducti-) w phy.kil dalornllions, in such wg"i-s w New of1spl;ng: Task mat. rills inchad., by way iltvsv slush and not Gm:talw>n• lead, admiv.-, chromium m.rcury, v nidwm, ar,.,k. ine, «flee-rJlro-c:Josb.N ens (OHCB PoirehI.A11-1•6 b;ph.nyli (PCBs) .sad dchtolodiph. nyl uiW«w Nan• (00T): and ant oher nu•fiils that nave w mar hu.ah.r be d.a• ;_d to have leek prop.ni.s: (S9)T,kk4nq WLI. A b;o!oycal v.I'I-I unit conlstinq of male vial .wh as broken atone , Io<i "" whch wuwwal•r ;s sr1V;but.d: A high W. Vkkr" Wt.r it m. which it op.rat.�-a1•b•-...en 10 snd 30 mqd P•r a<r I. A bw IaI. ,kVW IJW( it on• which 11 d.,;gn.d to opus]• at on• •I< lour mqd per au.: (60)Tr:ckLnq F+Lr (Pa<kec io-•r), A plug Ilex type of op•,t Lan in which wasl•xaler Ito-s down th,-gh Ivcc..IN. lay•. .1 moil;, ar lltlal• mawrilh 019ink mal-dll is r. moved Conti-%y by acl;v. GWog411 raid 01n each .Xc.Ii:ve 11yef. Thu method may produce-acoM,iy- c,,aLlr •I/l..N, - mty W Id.pud to prod,,. I riuir,,.d elAw N; (61)Vtcw.n FRI—. C•Nulvyt , or FL„ Preuu. Oac.a wKch .r. d.,,.".d to remove ac•u .1I.1 vom aitA., dq•,t•d u uMdq.tt.0 s,dg. prior I. d;.poal at IvIN.r V-1n L xx r Sy�t � �5 #* W Si>� Ater ode .................. ......... ......... :> 41.Miningandmaterialprocessing 42. Mine dewatering Pit, Pond, Lagoon O1. Domestic- Municipal WWTP 43. Sand dredging 02. Domestic- Industrial/comercial 44. Gem mining 11. Wastewater: storage/treatment (ril, lgw) 03. Domestic- Schools 45. Swimming pool backwash 12. Sludge: storage (nl, lgs) 04. Domestic- Single Family 46. Peat mining 13. Soils: petroleum contaminated storage- 05. Domestic- Subdivisions 47. Battery manufacturing treatment (-, lgc) 06. Domestic Condominiums 48. Hydroelectric turbines Spray Systems 07. Domestic- Apartments 49. Paint and ink formulation 08. Domestic- Mobile Home Parks 50. Printing and publishing 21. Wastewater: beds (sbd, spb) 09. Domestic- Hospitals 51. Photographic equipment, supplies and 22. Wastewater. field irrigation (ns, spi) 10. Domestic- Restaurants film processing 23. Wastewater: rotary distributor (rd, spr) 11. Domestic -Institutions (college, 52. Soap and detergent manufacturing orphanage, boarding schools, nursing 53. Dairy product processing homes, etc.) Infiltration Systems 12. Domestic- Child Care Facilities 54. Cement manufacture 31. Ponds, including stormwater (ip, inp) 13. Domestic- Hotels, motels, inns, guest houses, campgrounds, rest areas, etc. 55. Textiles 56. Metal plating 32. Trenches: petroleum contaminated wastewater or groundwater (-, int) 14. Non -contact cooling water and condensate 57. Metal finishing 58. Metal forming Land Application 15. Contact cooling water 59. Electrical and electronic components p 16. Boiler blowdown 60. Railway yards 41. Sludge: municipal, industrial (na, asl) 17. Cooling tower blowdown 61. Car wash 42. Sludge m beds (sb, slb g drying ) 18. Pulp and paper 62. Porcelain enameling 43. Petro -contaminated soils 19. Wood products 63. Rubber processing 44. Other 20. Wood treatment 64. Glass manufacturing 21. Water plants (surface water) 65. Leather tanning and processing Subsurface Disposal 22. Water plants and water conditioning (groundwater) 66. Aquifer restoration 51. Septic tank/distribution lines (st, st) 23. Meat processing and rendering 67. Non-ferrous metals manufacturing 52. Sand filter Of, sf). 24. Vegetable and fruit processing 68. Ash pond and coal piles 53. Sand filter/septic tank (-, ss) 25. Seafood or fish processing 69. Metal cleaning (steam electric plants) 54. Low -pressure -piping (np, 1pp) 26. Tobacco processing 70. Low volume wastes (steam electric plants) 60. Landfills (If, lfl) 27. Beverage production 71. Brick manufacturing wastewater pond 70. Sludge, Composting/Storage (m, slc) 28. Agricultural animal waste 72. Landfill leachate 80. Mining Operations (m, min) 29. Fish or seafood farms 73. Stormwater 30. Seafood or fish packing 74. Aquifer depressurization Multiple Disposal Systems 3 1. Organic chemical manufature 75. Phosphate rock -clay pondWW 32. Inorganic chemical manufacture 76. Bakeries and confection production 91. Lagoon -Field Irrigation (11, 22) 33. Drug manufacturing 77. Marine fisheries research station 34. Pesticide and herbicide production 78. Wastewater from industrial and commercial (not otherwise listed) 35. Fertilizer production 79. Laboratory wastewater 36. Plastics and synthetics manufacturing 80. Saltwater corrosion research 37.Oil separator 81. Food preparation (not elsewhere 38.Oil refinery classified) 39.Oil terminal 82. Contaminated soils 40. Laundry waste 83. Industrial/commercial washwater GW-69 10/90 Page 4. GROUNDWATER ACTIO N ON LOG Permit Application Processing DEM Groundwater Section Project name-4. TG XT r /Z�6 tQ�s�r r� 5 n 14_ Project description-45 rn� nrt" tom. a 7 aYr ?. rvt c' c�r 4Yi d �1 A. Application Data - Initial Review/ [ ] Applicant-5 lar,F� LA, T -�o Y7r, e, is r J- n C-' [ ] Contact-6 a v1 G Li • V r v1 e- e h [ ] Address-7 �nL/ U C> (i� e- rt L✓0 0, ✓,/ [) City-8 [ ] State-9 I r L [ J Zip-10 < " e % Z [ ] 1" permit no-31 W Q d 0 cl 3 [ ] Date 1't issued-32 '4 3 - 1 [ ] Phone-11 Jl,?- 713' 1-173C [ ] WQ contact-17 44 (1 ean' [ ] GW contact-18 A24 %Ar_r- a Z 6 '7 [ ] RO contact-20 / Gb in ek [ ] Facility no-21 0- [ ] Permit type-13 (1-nondischarge permit 2-certification to construct ) [ ] Region code-12 _ (01-Ash 03 Mor 04-Win 05-Ral 06-Fay 07-Was 08-Wil ) [ ] Ownership-i5 (1-municipal 2-military 3-unknown 4-private 5-federal 6-county 7-state ) B. Data From Issued Permit 1 [] Facility name-38 7 e x f i I hd, s Ir i e. s- N ew 6�c n FAQ [] Synonym-39 G W �- rX C # 133 � O [ ] P.O. box-40 r [] Street address-41 [ ] City-42 [ ] State-43 N C ._ [ ] zip - Completion codes (IS -issued RN -renewed AM-ammended WD-withdrawn RV -revoked RI -returned incomplete DN--denied AJ-adjudicated ) GW number-2 Permit (WQ) no County of facility-3 Lew, Ren, Amend-19 Tracking Status (,mm / dd / yy ) P& E received-54 Z- Z f- ?e GW received-55 3 - 2_ ► - ? G ROnotified-56 3y Z7- fC RO comments due-57 RO comments rec.-58 Addin request 1-59 Response 1 due-6o 1 st addin received-61 Addin request 2-62 Response 2 due-63 2nd addin received-64 Comments submitted-65 S - Z 1-pL Date GW rec. permit-49 6 • - Date permit issued-47 Date permit expires-48 Lt - 3 O - O k Date quality assur. 7 - i ? 4 6 Quality assured by Cd 6 Date keyed Keyed by Date action completed-5o ` /I/ Completion code-51 A C. Action Comments Re -Marne Comments-37 GO 1 1n e• 3 J S O• S 0.0.wt p l C kyV ; f S-� o Jan .� T k I. Mw. loa -> 15 .&Lf - -414+ ► f rJ-?� -� M w I � ; -T tn/ IF r �pW/-164 IZ W ` I I � M W - a2C) • Date of comments-t21 % ` ( "/ 1 6 G W-69 10/90 Page 1. V?. S GROUNDWATER ACTION LOG Permit Application Processing, Page Complete Separate Page for Each Disposal Site D. Disposal Site Data GW number-2 11GO57 Permit (WQ) no-i poo- ff 3C Disposal Site no-33 County of site-34 �^4,, P-P) Site description-52 �r ant."A wni'�r SiLnnG d'l,�ri'1(7N [ ] Latitude (ddwws)-26 S 65 ) 3 [) Disposal system code-14 3 z [ ] Date wells to be installed 66 I � [ J Longitude (dd..,)-27 1 ? Q 66 Waste stream code-16 _ [ ] Date installation compltd.-67 (] Quad no-28 [ ] Design flow (gpd)-22 to ya [ ] Date discharge began-68 [ J River basin code-29 [ ] Application area (sq jt)-2a / 2 D o (] Date discharge ceased-69 [ ] Num. additional wells rec. [ ] Loading rate (gpd/ji )-23 [ ] Date monitoring ceased-7o [ ] Total num. wells at site-3o Q [ ] Sludge rate (Ib/acre/yr)-25 [ J Date site last inspected-u9 [ ] Monitoring schedule code-53 Z [ ] Effluent monitoring (y/n )-a6 (] Site map (y/n)-ils [ ] Site name (ynonym)-12o _ (0-No monitoring; 31-Jan, Apr, Sep; 32 Feb, Jun, Oct; 33-Mar, Jul, Nov; 34-Apr, Aug, Dec; 35 Feb, Jun, Sep; 36-Mar, Jul, Oct; 37 Apr Aug, Nov; 41-Jan, Apr, Jul, Oct; 42 Feb, May, Aug, Nov; 43-Mar, Jun, Sep, Dec; 61-Jan, Mar, May, Jul, Sep, Nov ) E. Parameters to be Monitored ( enter a 1 ) Aluminum Copper Oil & Grease Ammonia Nitrogen Fecal Coliforms Orthophosphate Arsenic Iron I pH Barium Lead Phenol Benzene Magnesium Phosphorous, Total BOD Manganese Potassium Cadmium MBAS SOa - sulphate Calcium Mercury Sodium Chloride Nickel TKN as N Chromium NO2 - nitrite Total Ammonia COD NO3 - nitrate Total Dissolved Solids Other 1 Other 2 Other 3 F. Groundwater System Data ( use form GW-48A ) Storet code I Storet code 2 Storet code 3 TOC Toluene Total Coliforms TOX VOC Water Level Xylenes Zinc [ ] Predominate soil texture-36 [ J Depth to water table-72 [ ] Point of concem-75 [ ] Regional soil code-35 [ ] Water table gradient-73 [ ] Additional (3) qualifiers -76 [ ] Distance to water supply-71 ma's O O [ ] Permeability-sorption-74 G. Disposal Site Comments Comments•77 Date of comments-122 GROUNDWATER ACTION LOG I GWnumber-2 Permit Application Processing, Page Permit (WQ) no-1 Disposal Site 110-33 Complete Separate Entry for Each Monitoring Well County of site-34 H. Well Construction Data [ ] Well no -too [ ] Well permit no-1o2 [ ] Synonym-ioi [ ] Measuring point to LS-ii2 [ ] Grout interval-ios [ J Date well Constructed-im [ ] Casing diameter-1o6 [ ] Screen interval -log [ ] Depth of well-1o5 [ ] Casing material-io7 [ ] MP elevation-tii [ ] Static waterlevel-iio. [ ] (U)pgrade / (D)owngrade-ii3 Comments-123 Date of comments-io3 [ ] Well no-ioo [ ] Well permit no-im [ ] Synonym -tor [ ] Measuring point to LS-li2 [ ] Grout interval-ios [ ] Date well constructed-ioa [ ] Casing diameter -lob [ ] Screen interval-iog [ ] Depth of Well-1o5 [ ] Casing material-107 [ ] MP elevation -ill [ ] Static water level-11o. [ ] (U)pgrade / (D)owngrade-113 Comments-123 Date of comments-103 (] Well no -too [ ] Well permit no-102 [ ] Synonym-1o1 [ ] Measuring point to LS-112 [ ] Grout interval-1o8 [ ] Date well constructed-im [ ] Casing diameter -rob [ ] Screen interval -log (] Depth of well-105 [ ] Casing material-im [ ] MP elevation -ill [ ] Static water level-11o. [ ] (U)pgrade / (D)owngrade-113 Comments-1?3 Date of comments-103 [ ] Well no -too [ J Well permit no-lo2 [ ] Synonym-loi [ ] Measuring point to LS-i12 [ J Grout interval-ios [ ] Date well constructed-im [ ] Casing diameter-1o6 [ ] Screen interval -log [ j Depth of well-1o5 [ ] Casing material-107 [ ] MP elevation -ill [ ] Static water level-uo. [ ] (U)pgmde / (D)ownprade-u3 Comments-123 Date of co nments-im GW-69 10/90 Page 2. GW-69 10/90 Page 3. State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27611 James G. Martin, Governor A. Preston Howard, Jr., P.E. William W. Cobey, Jr., Secretary Acting Director August 20, 1992 �;� Mr. Michael Miller, Executive Vice President Texfi Industries, Incorporated 5400 Glenwood Avenue, Suite 318 Raleigh, North Carolina 27612 Dear Mr. Miller: Rag R'929D GROUNDWATER SECTION RALEIGH, NC Subject: Permit No. WQ0004936 Texfi Industries, Incorporated New Bern Facility Groundwater Remediation Facility Craven County In accordance with your permit modification application received March 26, 1992, we are forwarding herewith Permit No. WQ0004936, dated August 20, 1992, to Texfi Industries, Incorporated for the construction and operation of the subject groundwater remediation facilities. This permit hereby voids Permit Number WQ0004936 issued September 23, 1991. The modifications approved herein include a reduction in the number of groundwater recovery wells from 10 to 4 and the elimination of the metal removal treatment components from the description of the approved facility. Please be advised, should you desire to construct the metals removal portion of the treatment system, or any other treatment facility modifications, you must request and obtain a modified permit to include the additional components. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the conditions and limitations as specified therein. Please pay particular attention to the monitoring requirements in this permit. Failure to establish an adequate system for collecting and maintaining the required operational information will result in future compliance problems. If any parts, requirements, or limitations contained in this permit are unacceptable to you, you have the right to request an adjudicatory hearing upon written request within 30 days following receipt of this permit. This request must be in the form of a written petition, conforming to Chapter 150B of North Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Box 11666, Raleigh, NC 27604. Unless such demands are made this permit shall be final and binding. Regional Offices Asheville Fayetteville Mooresville Raleigh Washington Wilmington Winston-Salem 704/251-6208 919/486-1541 704/663-1699 919/571-4700 919/946-6481 919/395-3900 919/761-2351 Pollution Prevention Pays P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer Mr. Michael Miller, Executivi :e Presi4c11L Texfi Industries, Incorporated August 20, 1992 Page Two One set of approved plans and specifications was forwarded to you in conjunction with the permit of the same number issued September 23, 1991. If you need additional information concerning this matter, please contact Mr. Dana J. Bolden at 919/ 733-5083. Sincerely, A. Presto4 Howard, Jr., P.E. cc: Craven County Health Department Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Jack Floyd, Groundwater Section Aquaterra Facilities Assessment Unit Training and Certification NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH INFILTRATION GALLERY PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Texfi Industries, Incorporated Craven County FOR THE construction and operation of a groundwater remediation facility consisting of four shallow groundwater recovery wells, one deep groundwater recovery well, dual carbon adsorption units, a 60 GPM air stripping unit with flow equalization, a 3 foot by 400 foot upgradient infiltration gallery with groundwater mounding monitoring equipment, and, if needed, an additional 3 foot by 400 foot infiltration gallery to serve Texfi Industries' New Bern facility with no discharge to the surface waters, pursuant to the permit modification application received March 26, 1992 and in conformity with the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the following specified conditions and limitations: 1. Upon completion of construction and prior to operation of this permitted facility, a certification must be received from a professional engineer certifying that the permitted facility has been installed in accordance with this permit and the approved plans and specifications. Mail the Certification to the Permits and Engineering Unit, P.O. Box 29535, Raleigh, NC 27626-0535. 2. The Washington Regional Office, telephone number (919)946-6481, shall be notified at least forty-eight (48) hours in advance of operation of the installed facilities so that an in - place inspection can be made. Such notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. 3. This permit shall become voidable if the soils fail to adequately absorb the wastes and may be rescinded unless the facilities are installed, maintained, and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 4. In the event that the facilities fail to perform satisfactorily, including the creation of nuisance conditions, the Permittee shall take immediate corrective action, including those as may be required by this Division, such as the construction of additional or replacement treatment or disposal facilities. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 6. Any sludge generated from these treatment facilities must be disposed of in accordance with General Statute 143-215.1 and in a manner approved by the North Carolina Division of Environmental Management. 7. Diversion or bypassing of the untreated groundwater from the treatment facilities is prohibited. I 1' ;: 1► 911 0 E'l IIN 13041919)1 1 83 04,75 1. The facilities shall be properly maintained and operated at all times. 2. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge (ORC) of the wastewater treatment facilities. The operator must hold a certificate of the type and grade at least equivalent to or greater than the classification assigned to the wastewater treatment facilities by the Certification Commission. The Permittee must also employ a certified back-up operator of the appropriate type and grade to comply with the conditions of Title 15A, Chapter 8A, .0202. The ORC of the facility must visit each Class I facility at least weekly and each Class II, III, and IV facility at least daily, excluding weekends and holidays, and must properly manage and document daily operation and maintenance of the facility and must comply with all other conditions of Title 15A, Chapter 8A, .0202. 3. The facilities shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastewater resulting from the operation of this facility. Any monitoring deemed necessary by the Division of Environmental Management to insure surface and ground water protection will be established and an acceptable sampling reporting schedule shall be followed 2. Noncompliance Notification: The Permittee shall report by telephone to the Washington Regional Office, telephone number (919)946-6481, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the wastewater treatment facility which results in the treatment of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a basin or tank; the known passage of a slug of hazardous substance through the facility; or any other unusual circumstances. b. Any process unit failure, due to known or unknown reasons, that render the facility incapable of adequate wastewater treatment such as mechanical or electrical failures of pumps, aerators, compressors, etc. 2 C. Any failure of a pumping station, sewer line, or treatment facility resulting in a by- pass directly to receiving waters without treatment of all or any portion of the influent to such station or facility. d. Any time that self -monitoring information indicates that the facility is not in compliance with its permit limitations. Persons reporting such occurrences by telephone shall also file a written report in letter form within 15 days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. IL900 : 1 1►I 11 1: u l ►II All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 2 The groundwater recovery treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office. 3. The influent to and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) months and quarterly thereafter for the parameters specified below: Volatile Organic Compounds -by Method 1 or Method 2 below Method 1: Method 6230D ( Capillary - Column), "Standard Methods for the Examination of Water and Wastewater", 17th edition, 1989 Method 2: Method 502.2 " Methods for the Determination of Organic Compounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 4. The influent to the treatment system shall be sampled quarterly for the parameters specified below: Total Nickel Total Zinc 5. The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 27611-7687 within 30 days of sample collection. 6. After data has been collected for one full year, the Permittee may request a reduction in the above monitoring requirements by requesting a permit modification. 7. Within one year of permit issuance, the Pemuttee shall submit a detailed map depicting the capture zone of each recovery well to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 27611-7687. 3 1► , 01111JIMI 1. Adequate inspection, maintenance and cleaning shall be provided by the Permittee to insure proper operation of the subject facilities. 2. The Permittee or his designee shall inspect the groundwater recovery and treatment facilities to prevent malfunctions and deterioration, operator errors and discharges which may cause or lead to the release of wastes to the environment, a threat to human health, or a nuisance. The Permittee shall keep an inspection log or summary including at least the date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Pernttee for a period of three years from the date of the inspection and shall be made available upon request to the Division of Environmental Management or other permitting authority. 3. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site and facility at any reasonable time for the purpose of determining compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. UFNEMMUS 1141 Iowa11 I► 1. This permit shall become voidable unless the facilities are constructed in accordance with the conditions of this permit, the approved plans, specifications and other supporting data. 2. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 3. This permit is not transferable. In the event there is a desire for the facilities to change ownership, or there is a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 4. The Permittee shall obtain a well construction permit from the Washington Regional Office prior to construction of the recovery wells. 5. A set of approved plans and specifications for the subject project must be retained by the Permittee for the life of this project. 6. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6A to 143-215.6C. 7. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205 (c)(4). 8. The issuance of this permit does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. 4 9. The Permittee, __ _east six lb) months prior to the expira of this,, .nit, shall request its extension. Upon receipt of the request, the Commission will review the adequacy of the facilities described therein, and if warranted, will extend the permit for such period of time and under such conditions and limitations as it may deem appropriate. Permit issued this the 20th day of August, 1992 NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION A. Preston 4ward, Jr., PEJ Acting Direct Division of Environmental Management By Authority of the Environmental Management Commission Permit No. WQ0004936 E Permit No. WQ0004936 August 20, 1992 Engineer's Certification I, , as a duly registered Professional Engineer in the State of North Carolina, having been authorized to observe (periodically, weekly, full time) the construction of the project, for the Project Name Location Permittee hereby state that, to the best of my abilities, due care and diligence was used in the observation of the construction such that the construction was observed to be built within substantial compliance and intent of the approved plans and specifications. Signature Date 1.1 Registration No. M 1 1 7! 3u I&C 10 00f I FEE' 89 30" 77.0 Bella i each rove Ch ° �I 1r• — i �► -r + —i �.r 33 4:3 Imo .1 �� ) 4I t"fir, _ - ... • _ -•L- � •- _ _ _ , -Y.- . SiliJ.(1 Cove p 4m_—'_ -s- '—` Cs a )•.1-' by �- _ ` 4r " Washingtont Forks - ,_J;Substation ' 1 44 t✓' r a _ / "� QUARRY+. � is ♦ •, + i5•BOO 1220 17 :\ Copp. 1�.. 7'30" .307 3- --- --- ---- -- - - 08 Mapped, edited, and published by the Geological Survey Control by USGS, NOS/NOAA, and North Carolina Geodetic Survey Topography by photogrammetric methods from aerial photographs taken 1974. Field checked 1975. Map edited 1978 Selected hydrographic data compiled from NOS 11552 (1975) 1 This information is not intended for navigational purposes r; Projection and 10,000•foot grid ticks: North Carolina coordinate system (Lambert conformal conic) 1000-meter Universal Transverse Mercator grid, zone 18 1927 North American datum Fine red dashed lines indicate selected fence and field lines where generally visible on aerial photographs. This information is unchecked Ha VELOCh: 20 /A.'. ' 1 MN 1000 GN E 6K• 116 M1LS 1.11. 21 MILS UTn GRID AHU 1978 MAGNETIC NORTH OCCLINATION AT CENTER OF SHEET A F.C' State of North Caroling Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director March 22, 1996 Dane Vincent, Vice President of Finance & Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Dear Mr. Vincent: e� Q ON c�, rn rO Subject: Project Return (WQ0004936P Texfi Industries, Inc. New Bern Facility"r Groundwater Remediation Faa-aity Craven County r This is in reference to your modification request received September 25, 1995 for the existing groundwater remediation facility at the Texfi Industries, Inc.'s New Bern Facility. In a letter dated December 7, 1995, you were asked by Mr. Michael D. Allen of the Division of Environmental Management's Water Quality Section, to provide additional information (copy of letter attached). As of today, this information has not been received, therefore, the Division must return your application and support documents as incomplete in accordance with North Carolina General Statute 143- 215.1. The documents are being forwarded to you under separate cover. Please be advised that construction and/or operation of groundwater remediation facility without a valid permit is a violation of North Carolina General Statute 143-215.1 and may subject Texfi Industries, Inc. to appropriate enforcement actions in accordance with North Carolina General Statute 143-215.6. Civil penalties of up to $10,000 per day per violation may be assessed for failure to secure a permit required by North Carolina General Statute 143-215.1. When you have obtained the requested information which is needed to make your application complete, you may submit a new application package and a new $400.00 permit processing fee. Please be advised, the $400.00 permit processing fee submitted with this modification request will be applied to the permit renewal request received February 29, 1996. The Division will proceed with the permit renewal for the existing Groundwater Remediation Facility. If you have any questions or comments concerning this matter, please contact Mr. Michael D. Allen at (919) 733-5083 extension 547. Sincerely, (,C) ��J 1 A. Presto Howard, r., P.E. cc: Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Bob Cheek, Groundwater Section, Central Office Aquaterra, Inc. P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-5083 FAX 919-733-9919 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director December 7, 1995 Dane Vincent, Vice President of Finance & Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Dear Mr. Vincent: Subject: Application No. WQ0004936 Additional Information Request Texfi Industries, Inc. New Bern Facility Groundwater Remediation Facility, Craven County The Division of Environmental Management's Permits and Engineering Unit and Groundwater Section have completed a preliminary engineering review of the subject application. The following items must be addressed before we can complete our review: Information requested by the Groundwater Section 1. See attached MEMO from Ken Pohlig. Information requested by the Permits and Engineering Unit The-:�ivision is still waiting for a response to our September 27, 1995 letter. Refer to the subject permit application number when providing the requested information. Please submit four (4) copies of all requested information to my attention at the address below. Also, please note that failure to provide this additional information on or before December 7, 1995 will subject your application to being returned as incomplete, in accordance with 15A NCAC 2H .0208. If you have any questions regarding the information requested by the Groundwater Section, please call Ken Pohlig at (919) 715-6161. If your questions concern the information requested by the Permits and Engineering Unit. please call me at (919) 733-5083 extension 547. Sincerely, kchael D. Allen Environmental Engineer State Engineering Review Group cc: Washington Regional Office, Water Quality Washington Regional Office, Groundwater Ken Pohlig. Central Office, Groundwater Aquaterra, Inc. Permit File `N'Q0004936 P.O. Box 29535, Raleigh. North Carolina 27626-0535 Telephone 919-733-7015 FAX 919-733-2496 An Equal Opportunity Affirmative Action Employer 50016 recycled,' 100,o post -consumer paper • DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION November 29, 1995 MEMORANDUM To: Michael Allen Through: Bob Cheek Q C From: Ken Pohlig Subject: Texfi Industries Groundwater Remediation Craven County WQ0004936/GW95214 The Groundwater Section has conducted a preliminary review of the subject application, and cannot recommend issuence of the permit admendment without the following information and/or clarification: (1) Cross -sections of the surficial aquifer and Castle Haynes aquifer formations, showing recovery and monitoring well screens, in addition to the static groundwater levels in both aquifers and the contaminant contours in both aquifers. (2) Plan View maps of the contaminant contours in both surficial aquifer and Castle Haynes aquifer. (3) A comparison of chemical analyses from (a) the surficial aquifer influent water, (b) the deeper Castle Haynes aquifer influent water, and (c) the effluent of the treatment system. This chemical analysis comparison should include all organic/inorganic contaminants, in addition to what would be considered a normal water quality suite of constituents (TDS, pH, chloride, manganese, iron, etc.). The purpose of this comparison is to verify that after the surficial waters and Castle Haynes waters have been treated and mixed, the effluent water quality injected back into the Castle Haynes aquifer does not degrade the natural water quality of the Castle Haynes aquifer. This anaysis should consider not only the organic contaminants, but also the natural water quality difference between the two aquifers. For example, if the surfical aquifer is high in iron, but the Castle Haynes aquifer is low in iron, then the injection will degrade the Castle Haynes quality with regards to iron. • (3) From the above chemical analysis, if the Castle Haynes aquifer is determined to be degraded sufficiently, then it may be necessary to separate the surficial water treatment system from the Castle Haynes water treatment system. (4) An analysis of the chemical components/products to be expected in the effluent from the addition of acetic/hydroxyacetic acid to the wastestream. If there are any questions please call me at 715-6161. cc: Willie Hardison Permit Files kop/TEXFI-I.DOC State of North Carolina 0 Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director September 27, 1995 Dane Vincent, Vice President of Finance, Treasurer Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 215 Raleigh, North Carolina 27612 Dear Mr. Vincent: 4J 9 FA IDEHNR Subject: Application No. WQ0004936 Additional Information Request Texfi Industries, Inc. New Bern Facility Groundwater Remediation Facility Craven County The Permits and Engineering Unit has completed a preliminary review of the subject application. It has`come to our attention that the subject permit is due to expire on August 31, 1996. In accordance with Permit Condition No. VI 10, a renewal request is required 180 days prior to expiration. Therefore, the renewal request would be due to the Division no later than February 28, 1996. If Texfi Industries, Inc. would like, in addition to the amendment request, the Division could also proceed with the renewal of the subject permit. No additional fee would be necessary at this time. Please let me know as soon as possible if you would like the Division to renew this permit at this time. If there is no response by October 26, 1995, the Division will continue with the amendment request by will not renew the permit at this time. If you have any questions on this matter, please call me at (919) 733-5083 ext. 547. Sincerely, Michael D. Allen Environmental Engineer State Engineering Review Group cc: Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Bob Cheek, Groundwater Section, Central Office Aquaterra, Inc. Permit File IAIQ0004936 P.O. cox 29535, Raleigh, North Carolina 27626-0535 Te'ephone 919-733-7015 FAX 919-733-2496 An Equa! Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION November 29, 1995 MEMORANDUM To: Michael Allen Through: Bob Cheek Q' - From: Ken PohligV_" Subject: Texfi Industries Groundwater Remediation Craven County WQ000493 6/GW95214 The Groundwater Section has conducted a preliminary review of the subject application, and cannot recommend issuence of the permit admendment without the following information and/or clarification: (1) Cross -sections of the surficial aquifer and Castle Haynes aquifer formations, showing recovery and monitoring well screens, in addition to the static groundwater levels in both aquifers and the contaminant contours in both aquifers. (2) Plan view maps of the contaminant contours in both surficial aquifer and Castle Haynes aquifer. (3) A comparison of chemical analyses from (a) the surficial aquifer influent water, (b) the deeper Castle Haynes aquifer influent water, and (c) the effluent of the treatment system. This chemical analysis comparison should include all organic/inorganic contaminants, in addition to what would be considered a normal water quality suite of constituents (TDS, pH, chloride, manganese, iron, etc.). The purpose of this comparison is to verify that after the surficial waters and Castle Haynes waters have been treated and mixed, the effluent water quality injected back into the Castle Haynes aquifer does not degrade the natural water quality of the Castle Haynes aquifer. This anaysis should consider not only the organic contaminants, but also the natural water quality difference between the two aquifers. For example, if the surfical aquifer is high in iron, but the Castle Haynes aquifer is low in iron, then the injection will degrade the Castle Haynes quality with regards to iron. (3) From the above chemical analysis, if the Castle Haynes aquifer is determined to be degraded sufficiently, then it may be necessary to separate the surficial water treatment system from the Castle Haynes water treatment system. (4) An analysis of the chemical components/products to be expected in the effluent from the addition of acetic/hydroxyacetic acid to the wastestream. If there are any questions please call me at 715-6161. cc: Willie Hardison Permit Files kop/T'EXFI-I.DOC • State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management James B. Hunt, Jr., Governor Jonathan B. Howes, Secretary A. Preston Howard, Jr., P.E., Director May 31, 1996 Dane L. Vincent, Vice President of Finance Texfi Industries, Inc. 5400 Glenwood Avenue, Suite 318 Raleigh, North Carolina 27612 Dear Mr. Vincent: 'A�j 0 DEHNR Subject: Permit No. WQ0004936 Texfi Industries, Inc. New Bern Facility — Groundwater RemediationFacilities Craven County In accordance with the renewal request received February 29, 1996, we are forwarding herewith Permit No. WQ0004936, dated May 31, 1996, to Texfi Industries, Inc. for the continued operation of the subject groundwater remediation facility. This permit shall be effective from the date of issuance until April 30, 2001, shall void Permit No. WQ0004936 issued August 20, 1992, and shall be subject to the conditions and limitations as specified therein. Please pay particular attention to the monitoring requirements in this permit. Failure to establish an adequate system for collecting and maintaining the required operational information will result in future compliance problems. If any parts, requirements, or limitations contained in this permit are unacceptable, you have the right to request an adjudicatory hearing upon written request within thirty (30) days following receipt of this permit. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Drawer 27447, Raleigh, NC 27611-7447. Unless such demands are made this permit shall be final and binding. If you have any questions concerning the Groundwater Conditions or groundwater monitoring requirements, please contact Mr. Brian Wagner in the Groundwater Section at (919) 715-6163. If you need any additional information concerning this matter, please contact Mr. Michael D. Allen at (919) 733- 5083 extension 547. Sincerely, A. Presto Howard, Jr., P.E. cc: Craven County Health Department Aquaterra, Inc. Washington Regional Office, Water Quality Section Washington Regional Office, Groundwater Section Bob Cheek, Groundwater Section, Central Office Training and Certification Unit (no revised rating) Facilities Assessment Unit P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone (919) 733-5083 FAX (919) 733-0719 An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH GROUNDWATER REMEDIATION PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Texfi Industries, Inc. Craven County FOR THE continued operation of a 86,400 GPD groundwater remediation facility consisting of four (4) shallow groundwater recovery wells, one (1) deep groundwater recovery well, dual carbon adsorption units, a 60 GPM air stripping unit with flow equalization, a 3 foot by 400 foot upgradient infiltration gallery with groundwater mounding monitoring equipment, and, if needed, an additional 3 foot by 400 foot infiltration gallery to serve Texfi Industries, Inc.'s New Bern Facility, with no discharge of wastes to the surface waters, pursuant to the renewal request received February 29, 1996, and in conformity with the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. This permit shall be effective from the date of issuance until April 30, 2001, shall void Permit No. WQ0004936 issued August 20, 1992, and shall be subject to the following specified conditions and limitations: I. PERFORMANCE STANDARDS 1. This permit shall become voidable if the soils fail to adequately assimilate the wastes and may be rescinded unless the facilities are installed, maintained, and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 2. In the event that the facilities fail to perform satisfactorily, including the creation of nuisance conditions, the Permittee shall take immediate corrective action, including those actions that may be required by this Division, such as the construction of additional or replacement treatment or disposal facilities. 3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 4. Any residuals generated from these treatment facilities must be disposed in accordance with General Statute 143-215.1 and in a manner approved by the North Carolina Division of Environmental Management. 2 5. Diversion or bypassing of the untreated groundwater from the treatment facilities is prohibited. II. OPERATION AND MAINTENANCE REQUIREMENTS 1. The facilities shall be properly maintained and operated at all times. 2. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge (ORC) of the wastewater treatment facilities. The operator must hold a certificate of the type and grade at least equivalent to or greater than the classification assigned to the wastewater treatment facilities by the Certification Commission. The Permittee must also employ a certified back-up operator of the appropriate type and grade to comply with the conditions of Title 15A, Chapter 8A, .0202. The ORC of the facility must visit each Class I facility at least weekly and each Class II, III, and IV facility at least daily, excluding weekends and holidays, and must properly manage and document daily operation and maintenance of the facility and must comply with all other conditions of Title 15A, Chapter 8A, .0202. 3. The facilities shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastewater resulting from the operation of this facility. III. MONITORING AND REPORTING REQUIREMENTS Any monitoring deemed necessary by the Division of Environmental Management to insure surface and ground water protection will be established and an acceptable sampling reporting schedule shall be followed. 2. Noncompliance Notification: The Permittee shall report by telephone to the Washington Regional Office, telephone number (910) 946-6481, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the wastewater treatment facility which results in the treatment of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a basin or tank, the known passage of a slug of hazardous substance through the facility, or any other unusual circumstances; b. Any process unit failure, due to known or unknown reasons, that renders the facility incapable of adequate wastewater treatment, such as mechanical or electrical failures of pumps, aerators, compressors, etc.; c. Any failure of a pumping station, sewer line, or treatment facility resulting in a by-pass directly to receiving waters without treatment of all or any portion of the influent to such station or facility; or d . Any time that self -monitoring information indicates that the facility is not in compliance with its permit limitations. Persons reporting such occurrences by telephone shall also file a written report in letter form within five (5) days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. I V . GROUNDWATER REQUIREMENTS The Groundwater Section's computerized compliance monitoring system requires sequential monitoring well names. Therefore, the following monitoring wells shall, in the future, be designated with the following sequential names: Old Name New Name MW-10a MW-15 RW-4a MW-16 RW-7a MW-17 RW-8 MW-18 RW-10 MW-19 RW-11 MW-20 These names shall be used in all future correspondences with the Groundwater Section regarding the subject non -discharge permit. 2. Monitor wells MW-3, MW-4, MW-11, MW-12, MW-13, MW-14, MW-15 (formerly MW-l0a), MW-16 (formally RW-4a), MW-17 (formally RW-7a), MW-18 (formally RW- 8), MW-19 (formally RW-10), and MW-20 (formally RW-11) shall be sampled every January and July for the following parameters: Water Level Volatile Organic Compounds - by Method 6230D below Method 6230D (Capillary - Column), "Standard Methods For The Examination of Water and Wastewater", 17th ed., 1989 The measurement of water levels must be made prior to sampling for the remaining parameters. The depth to water in each well shall be measured from the surveyed point on the top of the casing. The measuring points (top of well casing) of all monitoring wells shall be surveyed to provide the relative elevation of the measuring point for each monitoring well. The results of the sampling and analysis shall be sent to the Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on Form GW-59 [Compliance Monitoring Report Form] every February and August. 3. The influent and effluent from the treatment system shall be sampled every month for the parameter specified below: Volatile Organic Compounds - by Method 6230D below Method 6230D (Capillary - Column), "Standard Methods For The Examination of Water and Wastewater", 17th ed., 1989 The results of the sampling and analysis shall be sent to the Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 within 30 days of sample collection. 4. The influent to the carbon treatment system shall be sampled quarterly for the parameters specified below: Total Nickel Total Zinc 4 • The results of ine sampling and analysis shall be sent to [ne Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 within 30 days of sample collection. 5. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. 6. All components of the groundwater recovery, treatment, and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 7. The groundwater recovery, treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office within 48 hours. 8. The groundwater treatment system shall consistently achieve at least a 95% treatment efficiency (i.e. remove 95% of the influent contaminants) prior to discharge to the injection wells. If the treatment system fails to consistently achieve this standard, additional treatment units or changes in operational methods, may be required. 9. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in 15A NCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary is for the disposal system constructed after December 31, 1983 is established at either (1) 250 feet from the waste disposal area, or (2) 50 feet within the property boundary, whichever is closest to the waste disposal area. An exceedance of Groundwater Quality Standards at or beyond the Compliance Boundary is subject to immediate remediation action in addition to the penalty provisions applicable under General Statute 143-215.6A(a)(1). In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the disposal systems midway between the Compliance Boundary and the perimeter of the waste disposal area. Any exceedance of standards at the Review Boundary shall require remediation action on the part of the permittee. V . INSPECTIONS 1. Adequate inspection, maintenance and cleaning shall be provided by the Permittee to insure proper operation of the subject facilities. 2. The Permittee or his designee shall inspect the groundwater recovery and treatment facilities to prevent malfunctions and deterioration, operator errors and discharges which may cause or lead to the release of wastes to the environment, a threat to human health, or a nuisance. The Permittee shall maintain an inspection log or summary including at least the date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Permittee for a period of three years from the date of the inspection and shall be made available to the Division of Environmental Management or other permitting authority, upon request. 3. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site or facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or leachate. V I . GENERAL CONDITIONS 1. Issuance of this permit does not constitute approval for reimbursement from the Leaking Petroleum Underground Storage Tank Cleanup Funds (15A NCAC 2P). 2. This permit shall become voidable unless the facilities are constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 4. This permit is not transferable. In the event there is a desire for the facilities to change ownership, or there is a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 5. A set of approved plans and specifications for the subject project must be retained by the Permittee for the life of this project. 6. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6(a) to 143-215.6(c). 7. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15A NCAC 2H .0205 (c)(4). 8. The issuance of this permit does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. 9. The Permittee, at least six (6) months prior to the expiration of this permit, shall request its extension. Upon receipt of the request, the Commission will review the adequacy of the facilities described therein, and if warranted, will extend the permit for such period of time and under such conditions and limitations as it may deem appropriate. Permit issued this the thirty -fast day of May, 1996 NORTH CAROLINA ENVIRONMENTAL MANAPEMENT COMMISSION i.l_.. .. _ l A. Preston Howard, Jr., P.EI, Director / I Division of Environmental Management / 1 By Authority of the Environmental Management Commission Permit Number WQ0004936 6 y 4 � ' / � �+ _ �� 4f � ~• 'may►_ / -� .! ► '�' �J • '•',:, •' { i Bella ✓ — " �. + — ah rove Ch s~ JJ r► _ + ♦ o 12 3n3 mil`• � - � , -► _ 4 _ � } — M — N, �• }�Y ''. e - _ O � I, `, _ _,� •ter r� - - •a. .,,/� �� _ S/•c�h�a��d� i ,► 3892 ub to • b N ` �J _ N _ 3891 // // • • • / O SF,o ,I. ., b ee _ f -_w_ b � — bb •� _ W ashingto ` ` `b �. ° - Forks rAl - '•� :3 , Substation \: 27. QUARRY` 510 000 FEET o '/C AND � — — r i\\ \ 6 � �� �� %I •,I0 _� n ♦ l �5 �. i, A \ •` —" CAR A � pi � °z • � 220 17 CORP 1 �♦ I 3889 E ER .D +'• 35e07'30" — 307 308 2570000•FEET NAE CIT-e 2O hf! + 310. 5' 77 e07'30" y�. Mapped, edited, and published by the Geological Survey 1 y.!`� Control by USGS, NOS/NOAA, and North Carolina Geodetic Survey MN 1pp E O,G�\\Topography by photogrammetric methods from aerial photographs GN Ve° taken 1974. Field checked 1975. Map edited 1978 Selected hydrographic data compiled from NOS 11552 (1975) 6'�• 116 MILS iThis information is not intended for navigational purposes 21 MILS Projection and 10,000-foot grid ticks: North Carolina coordinate i system (Lambert conformal conic) 1000-meter Universal Transverse Mercator grid, zone 18 UTM GRIU AifU 1978 MAGNET'C NORTH t 1927 North American datum — J DECUNATION AT CENTER OF SHEET . y{ Fine red dashed lines indicate selected fence and field lines where INU 0 MW-1 (�E) � MW-2 Existing Treatment System ®RW8 Ole/ Xc /Il4wlf 1/v-,ftICIG�D 3 3 ly y '3 r3 _- - 17 Rif / H z z0 Infiltration Gallery N MW 5 MW-11 ®RW-1 ® RW-2 M W-4a MW-8 MW-3a RW-1 MW-8 Manufacturing Building RW-4a RW-4 �MW-1Oa W-9a ® RW-5 MW-9 � MW-2`u(li ow ®Rw-s MW-13 uthor im c i Liaoriar r a LSG W enaonwa�rIno, Inc.® A GREAT LAKES CiffUICAI. MRPORATION MUPANY 4401900 RW-7a RW-7 CED Legend N Shallow Monitoring Well ® Recovery well ® Deep Monitoring Well Proposed Injection Well Bosch Boulevard h-awing Layers Date 7711e 44019-2 0,1,2 "2-93 Site Map ,evision Scale oject Texff Industries, Inc. 9-15-05 2 1- - 200' Now Born, North Carolina DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION May 21, 1996 MEMORANDUM To: Carolyn McCaskill Through: Bob Cheek From: Brian Wagner -- Subject: Texfi Industries, Inc. Groundwater Remediation Craven County WQ0004936/GW96057 ( Michael Allen: DEM SERG Review Engineer ) The Groundwater Section has reviewed the subject permit renewal application. The current permit only requires monitoring of the influent and effluent. The permittee has sampled the monitroing wells sporadically in the past. To better evaluate the effectiveness of the nondischarge permit, we recommend that semi-annual sampling be conducted of some of the monitoring wells. We recommend reissuance of the permit with the following conditions: * 1. The Groundwater Section's computerized compliance monitoring system requires sequential monitoring well names. Therefore, the following monitoring well(s) shall, in the future, be designated with the following sequential name(s): Old Name New Name MW-10a MW-15 RW-4a MW-16 RW-7a MW-17 RW-8 MW-18 RW-10 MW-19 RW-11 MW-20 This(ese) name(s) shall be used in all future correspondences with the Groundwater Section regarding this nondischarge permit. Monitor wells MW-3, MW-4, MW-11, MW-12, MW-13, MW-14, MW-15 (formally MW-1Oa), MW-16 (formally RW-4a), MW-17 (formally RW-7a), MW-18 (formally RW-8), MW-19 (formally RW-10), MW-20 (formally RW-11) shall be sampled every January and July for the following parameters: Water Level Volatile Organic Compounds - by the method below Method 6230D (Capillary - Column), "Standard Methods For The Examination of Water and Wastewater", 17th ed., 1989 The measurement of water levels must be made prior to sampling for the remaining parameters. The depth to water in each well shall be measured from the surveyed point on the top of the casing. 4. The measuring points (top of well casing) of all monitoring wells shall be surveyed to provide the relative elevation of the measuring point for each monitoring well. The results of the sampling and analysis shall be sent to the Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on Form GW-59 [Compliance Monitoring Report Form] every February and August. *6. The influent and effluent from the treatment system shall be sampled every month for the parameters specified below: Volatile Organic Compounds - by the method below Method 6230D (Capillary - Column), "Standard Methods For The Examination of Water and Wastewater", 17th ed., 1989 The results of the sampling and analysis shall be sent to the Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 within 30 days of sample collection. *7. The influent to the carbon treatment system shall be sampled quarterly for the parameters specified below: Total Nickel Total Zinc The results of the sampling and analysis shall be sent to the Groundwater Section, Permits and Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 within 30 days of sample collection. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. All components of the groundwater recovery, treatment, and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 10. The groundwater recovery, treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office within 48 hours. * 11. The groundwater treatment system shall consistently achieve at least a 95 % treatment efficiency (i.e. remove 95 % of the influent contaminants) prior to discharge to the infiltration gallery. If the treatment system fails to consistently achieve this standard, additional treatment units or changes in operational methods, may be required. cc: Willie Hardison Permit Files baw/96057.doc 5WAWV= g� Fit= O)a /UaK,e ,,/filew /vSMe _3 _3 /y iy Rwyti / � 17 Via 9 — Existing Treatment System 11 re,-4* 1,,,/"/'"e, S C�a✓bn COVAIi 4-Q04!:b h►y 36- MW-9 OB MW-2 Qb r MW-13 IAl RW-11 Bosch Boulevard uthor Drawing Layers LSG 44019-2 0,1,2 �ICI U a(a rr 06 No. Revision figure anqunwmrinq, Inc.® A GREAT I.AKM CHEMICAL CORPORATION MMPANY 4401900 9-15-95 2 6-02-93 le V = 200' W-1 ® RW-2 CYY'a � MW-8 RW-4 RW-5 MW-10a 1fV=1 ® ® RW-6 RW-7a RW-7 Legend 0 Shallow Monitoring Well ® Recovery Well [] Deep Monitoring Well ® Proposed Injection Well Site Map Texfl Industries, Inc. Now Born, North Carolina DIVISION OF ENVIRONMENTAL MANAGEMENT GROUNDWATER SECTION June 17, 1991 MEMORANDUM TO: Don Safrit THROUGH: Bob Cheek FROM: Jeff Lautier SUBJECT: Texfli Industries Groundwater Remediation New Permit Craven County WQ0004936/GW91137 System -Infiltration Gallery (Willie Hardison: DEM SERG Review Engineer) The Groundwater Section has reviewed the subject permit application for a 60 gpd discharge into an infiltration gallery. The remediation plan calls for eleven recovery wells, ten to withdraw from a shallow Miocene sand formation, and one to withdraw from the Castle Hayne Formation. Computer modeling of the remediation site using the analytical models RESSQ and MWCAP indicates that the recovery well network in combination with the upgradient infiltration gallery should operate as a closed loop system. The Groundwater Section recommends approval of the permit with the following conditions: 1. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. 2. All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 3. The influent and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) months and quarterly_ thereafter for the parameters specified below: The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, P.O. Box 27687 Raleigh, N.C. 27611-7687 within 30 days of sample collection. 4. Two (2) weeks prior to system start-up, the Permittee I i f shall notify the Division of Environmental Management, Regional Office, that operation is about to commence. 5. The groundwater recovery, treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Regional Office. JL:hl/91137 cc: Willie Hardison Central Files Permit Issuance Files L�_ State of North Carolina Department of Environment, Health and Natural Resources Division of Environmental Management 512 North Salisbury Street • Raleigh, North Carolina 27626-0535 James G. Martin, Governor ` George T. Everett, Ph.D. William W. Cobey, Jr., Secretary P,l ?��c-r• Director September 23, 1991 �1�5 Mr. Michael A. Miller, Executive Vice President SEP 2519a Texfi Industries-->----�� 5400 Glenwood Avenue, Suite 318 r �s�,!�.�Tc �"Ef4;U�1 ` d Raleigh, North Carolina 27 c + r g Subject: Permit No. WQ0004936 h,,- Texfi Industries 191Bern Facility SAP � 1991 New Be y Groundwater Remediation Facility GRUUNDWAUR SECTION Craven County Dear Mr. Miller: RALEIGH, NC In accordancd with your application received April 11, 1991, we are forwarding herewith Permit No. WQ0004936, dated September 23, 1991, to Texfi Industries for the construction and operation of a groundwater remediation facility. This permit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the conditions and limitations as specified therein. Please pay particular attention to the monitoring requirements in this permit. Failure to establish an adequate system for collecting and maintaining the required operational information will result in future compliance problems. If any parts, requirements, or limitations contained in this permit are unacceptable to you, you have the right to request an adjudicatory hearing upon written request within 30 days following receipt of this permit. This request must be in the form of a written petition, conforming to Chapter 150B of North Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Box 11666, Raleigh, NC 27604. Unless such dernands are made this permit shall be final and binding. One set of approved plans and specifications is being forwarded to you. If you need additional information concerning this matter, please contact Mr. MArk Hawes at 919/ 733-5083. Z Georl cc: Craven County Health Department Washington Regional Office Groundwater Section Chas. T. Main, Incorporated Facilities Assessment Unit Pollution Prevention Pays P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone 919-733-7015 An Equal Opportunity Affirmative Action Employer NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES RALEIGH INFILTRATION GALLERY PERMIT In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as amended, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Texfi Industries Craven County FOR THE construction and operation of a groundwater remediation facility consisting of ten 1 GPM recovery wells, a 50 GPM recovery well, a metal removal system with caustic soda, polymer, and sulfuric acid feed equipment for the treatment of groundwater streams from wells RW-3 and RW-4, dual carbon adsorption units for the treatment of groundwater streams from wells RW-8 and RW-9, a 60 GPM air stripping unit with flow equalization for the treatment of groundwater streams from all recovery wells, a 3 foot by 400 foot upgradient infiltration gallery with groundwater mounding monitoring equipment, and, if needed, an additional 3 foot by 400 foot infiltration gallery to serve Texfi Industries New Bern facility with no discharge to the surface waters, pursuant to the application received April 11, 1991 and in conformity with the project plan, specifications, and other supporting data subsequently filed and approved by the Department of Environment, Health and Natural Resources and considered a part of this permit. This pen -nit shall be effective from the date of issuance until August 31, 1996, and shall be subject to the following specified conditions and limitations: I. PERFORMANCE STANDARDS 1. Upon completion of construction and prior to operation of this permitted facility, a certification must be received from a professional engineer certifying that the permitted facility has been installed in accordance with this permit and the approved plans and specifications. Mail the Certification to the Permits and Engineering Unit, P.O. Box 29535, Raleigh, NC 27626-0535. 2. The Washington Regional Office, phone no. (919) 946-6481 shall be notified at least forty-eight (48) hours in advance of operation of the installed facilities so that an in -place inspection can be made. Such notification to the regional supervisor shall be made during the normal office hours from 8:00 a.m. until 5:00 p.m. on Monday through Friday, excluding State Holidays. 3. This permit shall become voidable if the soils fail to adequately absorb the wastes and may be rescinded unless the facilities are installed, maintained, and operated in a manner which will protect the assigned water quality standards of the surface waters and ground waters. 4. In the event (he facilities fail to perform satisfactc including the creation of nuisance con ns, the Permittee shall take immediate active action, including those as may be required by this Division, such as the construction of additional or replacement treatment or disposal facilities. 5. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwaters resulting from the operation of this facility. 6. Any sludge generated from these treatment facilities must be disposed of in accordance with General Statute 143-215.1 and in a manner approved by the North Carolina Division of Environmental Management. 7. Diversion or bypassing of the untreated groundwater from the treatment facilities is prohibited. II. OPERATION AND MAINTENANCE REQUIREMENTS 1. The facilities shall be properly maintained and operated at all times. 2. Upon classification of the facility by the Certification Commission, the Permittee shall employ a certified wastewater treatment plant operator to be in responsible charge of the wastewater treatment facilities. The operator must hold a certificate of the type and grade at least equivalent to the classification assigned to the wastewater treatment facilities by the Certification Commission. Once the facility is classified, the Permittee must submit a letter to the Certification Commission which designates the operator in responsible charge within thirty days after the wastewater treatment facilities are 50% complete. 3. The facilities shall be effectively maintained and operated as a non -discharge system to prevent the discharge of any wastewater resulting from the operation of this facility. III. MONITORING AND REPORTING REQUIREMENTS 1. Any monitoring deemed necessary by the Division of Environmental Management to insure surface and ground water protection will be established and an acceptable sampling reporting schedule shall be followed. 2. Noncompliance Notification: The Permittee shall report by telephone to the Washington Regional Office, telephone no. (919) 946-6481, as soon as possible, but in no case more than 24 hours or on the next working day following the occurrence or first knowledge of the occurrence of any of the following: a. Any occurrence at the wastewater treatment facility which results in the treatment of significant amounts of wastes which are abnormal in quantity or characteristic, such as the dumping of the contents of a basin or tank; the known passage of a slug of hazardous substance through the facility; or any other unusual circumstances. b. Any process unit failure, due to known or unknown reasons, that render the facility incapable of adequate wastewater treatment such as mechanical or electrical failures of pumps, aerators, compressors, etc. 2 IV. V. C. Any fa of a pumping station, sewer line, or nent facility resulting in a by-p--- _irectly to receiving waters without ti ent of all or any portion of the influent to such station or facility. d. Any time that self -monitoring information indicates that the facility is not in compliance with its permit limitations. Persons reporting such occurrences by telephone shall also file a written report in letter form within 15 days following first knowledge of the occurrence. This report must outline the actions taken or proposed to be taken to ensure that the problem does not recur. GROUNDWATER REQUIREMENTS 1. Any additional groundwater quality monitoring, as deemed necessary by the Division, shall be provided. 2. All components of the groundwater recovery, treatment and disposal system shall be properly weather -proofed to prevent freezing and failure of the system. 3. The influent and effluent from the treatment system shall be sampled once every two (2) weeks for the first three (3) months and quarterly thereafter for the parameters specified below: Total Nickel Total Zinc Volatile Organic Compounds - by Method 1 or Method 2 below Method 1: Method 6230D ( Capillary - Column), "Standard Methods for the Examination of Water and Wastewater", 17th edition, 1989 Method 2: Method 502.2 " Methods for the Determination of Organic Compounds in Drinking Water", United States Environmental Protection Agency - 600/4-88/039 The results of the sampling and analysis shall be sent to the Groundwater Section in the Washington Regional Office and to the Groundwater Section, Permits Unit, Post Office Box 27687, Raleigh, North Carolina 27611-7687 within 30 days of sample collection. 4. Two (2) weeks prior to system start-up, the Permittee shall notify the Division of Environmental Management's Washington Regional Office that operation is about to commence. 5. The groundwater recovery treatment and disposal system shall be inspected weekly. If it is determined that the system is malfunctioning, all repairs should be made as soon as possible and reported to the Washington Regional Office. INSPECTIONS Adequate inspection, maintenance and cleaning shall be provided by the Permittee to insure proper operation of the subject facilities. 3 2. The Permitte is designee shall inspect the ground recovery and treatment facilities to p nt malfunctions and deterioration, o or errors and discharges which may cause or lead to the release of wastes to the environment, a threat to human health, or a nuisance. The Permittee shall keep an inspection log or summary including at least the date and time of inspection, observations made, and any maintenance, repairs, or corrective actions taken by the Permittee. This log of inspections shall be maintained by the Permittee for a period of three years from the date of the inspection and shall be made available upon request to the Division of Environmental Management or other permitting authority. 3. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the disposal site and facility at any reasonable time for the purpose of determining compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. VI. GENERAL CONDITIONS 1. This permit shall become voidable unless the facilities are constructed in accordance with the conditions of this permit, the approved plans, specifications and other supporting data. 2. This permit is effective only with respect to the nature and volume of wastes described in the application and other supporting data. 3. This permit is not transferable. In the event there is a desire for the facilities to change ownership, or there is a name change of the Permittee, a formal permit request must be submitted to the Division of Environmental Management accompanied by an application fee, documentation from the parties involved, and other supporting materials as may be appropriate. The approval of this request will be considered on its merits and may or may not be approved. 4. The Permittee shall obtain a well construction permit from the Washington Regional Office prior to construction of the recovery wells. 5. Prior to a transfer of this land to a new owner, a notice shall be given to the new owner that gives full details of the materials applied or incorporated at this site. 6. A set of approved plans and specifications for the subject project must be retained by the Permittee for the life of this project. 7. Failure to abide by the conditions and limitations contained in this permit may subject the Permittee to an enforcement action by the Division of Environmental Management in accordance with North Carolina General Statute 143-215.6. 8. The annual administering and compliance fee must be paid by the Permittee within thirty (30) days after being billed by the Division. Failure to pay the fee accordingly may cause the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205 (c)(4). 9. The issuance of this permit does not preclude the Permittee from complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other government agencies (local, state, and federal) which have jurisdiction. 0 10. The Permitti 'least six (6) months prior to the e> ion of this permit, shall request its e: ion. Upon receipt of the request, the emission will review the adequacy of the facilities described therein, and if warranted, will extend the permit for such period of time and under such conditions and limitations as it may deem appropriate. Permit issued this the 23rd day of September, 1991 NO CAROLINA E VIR G orge T. Everett, u ctor Division of Envi nmental M By Authority oft r7iro7 Permit Number WQ0004936 AL MANAGEMENT COMMISSION Management Commission Permit No. WQ0004930 September 23, 1991 0 Engineer's Certification I, , as a duly registered Professional Engineer in the State of North Carolina, having been authorized to observe (periodically, weekly, full time) the construction of the project, Project Name Location for the Permittee hereby state that, to the best of my abilities, due care and diligence was used in the observation of the construction such that the construction was observed to be built within substantial compliance and intent of the approved plans and specifications. Signature Date Registration N A ' p I _/�' �" 1F.- -.yam -1 ��.'- -�' 9- •IY- •• (. ` (/ - : laoi " Bella ' -- r l 5 j ;.1 each rove Ch/m l 1 i \ ±I`• . -+� rc r- s�'"��'-_-� � •� cem, • /2 i• e 3892 'may,; Shad -. - t Cove ub to /i _ ; � •�}� t,ot N x• ryry 4 `j - Washington 7Gl�j t r� m Forks � _ - _ o - Sustati bon lip,� - —' `` • 6 y'� ` �/ `` I' 510000V QUARRY FEET �`j•\•I \ WX / • /• ' •; q^'D ,- ) • - � - � \ `�l t :� gyp• } -61 T 1 �i ii O q 17 - C 07'30" op Do 12 •' it 77°07'30" 301 308 - ♦ BDy 2570000 FEET ✓�<` Mapped, edited, and published by the Geological Survey HAVELOCl: Control by USGS, NOS/NOAA, and North Carolina Geodetic Survey Topography by photogrammetric methods from aerial photographs * 1 MNI taken 1974. Field checked 1975. Map edited 1978 G N loco Selected hydrographic data compiled from NOS 11552 (1975) This information is not intended for navigational purposes 614 Projection and 10,000-foot grid ticks: North Carolina coordinate 116 system (Lambert conformal conic) MILS 1 11 21 MILS ' 1000-meter Universal Transverse Mercator grid, zone 18 1927 North American datum Fine red dashed lines indicate selected fence and field lines where uD Gilt/ CCLINAION AT CT C MENTER ER O C NORTH TON OF SHEET generally visible on aerial photographs. This information is unchecked A FC'- • L:i RATING IOLE FOR CLASSIFICATION OF*CILITIES r Name of Plant: /ex F L.�e�..��,'es — 6'rcrartdr�rr �e.►,Bd;,�i,✓� Owner or Contact Person: Mailing Address: -------- ------------ �& ,_���}�------ County: f-VIg � .1 Telephone: NPDES Permit No. NC00 Nondisc. Per. No. cad yq 3f Issue Date:_ Expiration Date: & Existing Facility New Facility Rated By: oJoFe r► Date: Reviewed (Train. & Cert.) Reg. Office Reviewed (Train. & Cert.) Central Office ORC Grade ITEM POINTS ITEM POINTS (1) Industrial Pretreatment Units and/or (4) PRIMARY TREATMENT UNITS Industrial Pretreatment Program (see`delinition No. 33) (a) Septic Tank (see definition no. 43) 2 (2) D SIGN FLOW OF PLANT IN GPD q (b) (c) Imhoff Tank .......... ........................ Primary Clarifiers 5 (not applicable to non -contaminated cooling waters, sludge handling facilities for (d) ......... Settling Ponds or Settling Tanks for Inorganic 5 water purification plants, totally closed cycle Non -toxic Materials (sludge handling facilities systems (def. No. 11). and facilities for water purification plants, sand, gravel, consisting only of Item (4) (d) or Items (4) (d) stone, and other mining operations except ' and (11) (d)) recreational activities such as gem or gold . • • .. 20,001 -- 50.000 1 mining) (5) SECONDARY TREATMENT UNITS ....................... 50,001 -- 100,000....... ............ • • • • • . 2 � (a) Carbonaceous Stage � 100,001 250.000.......................... 4.:D 4 (i)Aeration - High Purity Oxygen System .... , 20 250.001 -• 500.000 .......................... 5 Diffused Air System ........... 10 500,001--1,000,000.......................... 8 Mechanical Air System (fixed, 1,000,001 -- 2,000,000 ........................ 10 floating or rotor) .............. 8 2,000,001 (and up) - rate 1 point additional for each Separate Sludge Reaeration ..... (i i) Trickling Filter 3 200,000 gpd capacity up to a High Rate ................... 7 maximum of 30 Standard Rale ............... 5 Packed Tower ............... 5 Design Flow g (gpd) ��, L%d d G't� (i i i) Biological Aerated Filler or Aerated � 7 Biological Filler ...................... 10 (iv) Aerated Lagoons ..................... . 10 (v) Rotating Biological Conlaciors .......... 10 (3) PRELIMINARY UNITS (see definition no. 32) (vi) Sand Filters - (a) Bar Screens .......... 1 intermittent biological . . . . . 2 or recirculating biological . . . 3 (b) Mechanical Screens, Slavic Screens or (vii) Stabilization Lagoons ........ 5 Comminuting Devices 2 (viii)Clarifier ................... _ r ) (c) Grit Removal (ix) Single stage system for combined ....... ........... . o r 1 carbonaceous removal of BOD and (d) Mechanical or Aerated Grit Removal ........ 2 nitrogenous removal by nitrification ' (e) Flow Measuring Device .......... (see def. No. 12) (Points for this item . Of 1 have to be in addition to items (5) (a) (1) Instrumented Flow Measurement ....... (i) through (5) (a) (viii) ...... 8 (x) Nutrient additions to enhance BOD removal ............................... 5 (h) Influent Flow Equalization ................... (xi) Biological Culture ("Super Bugs') addition (i) Grease or Oil Separators - Gravityto enhance organic compound removal ..... 5 Mechanical........._ 3 Dissolved Air Flotation- (j) Prechlorinalion 8 .. _ Nitrogenous Stage (i) Aeration - High Purity Oxygen Syslem 20 Diffused Air System ....... 10 Mechanical Air System (fixed, floating, or rotor) ...... ...... 8 Separate Sludge Reaeration ..... 3 (I i) Trickling Filter - HighRate------------- 7 Standard Rate - - - - - - - ..... 5 Packed Tower------------ 5 (i i i) Biological Aerated Filter or Aerated Biological Filler ......................... 10 (iv) Rotating Biological Contactors ............ 10 (v) Sand Filter - intermittent biological .... . . .. 2 recirculating biological ..... .. . 3 (vi) Clarifier ................................ 5 NARY OR ADVANCED TREATMENT UNIT Activated Carbons Beds - Q without carbon regeneration .................. with carbon regeneration .................... 15 Powdered or Granular Activated Carbon Feed - without carbon regeneration .... • .. ' ......... 5 with carbon regeneration .......... ' ........ 15 Air Stripping ............................. g Denitrification Process (separate process) . .. . . 10 Electrodialysis .......................... • ... 5 Foam Separation ion ............................. 5 Ion Exchange ................................. 5 Land Application of Treated Effluent (see definition no. 22b) (not applicable for sand, gravel, stone and other similar mining operations) ,(i) on agriculturally managed sites (See def. No.4)................................... 10 (ii) by high rate infiltration on non -agriculturally managed sites (includes rotary distributors and similar fixed nozzle systems) ........... O (iii) by subsurface disposal (includes low pressure pipe systems and gravity systems except at plants consisting of septic tank and nitrifica- tion lines only) ............................. 4 Microscreens.................................. 5 Phosphorus Removal by Biological Processes (See def. No. 26) ............................. 20 Polishing Ponds - without aeration ....... 2 with aeration .......... 5 Post Aeration - cascade .............. 0 diffused or mechanical . .. 5 Reverse Osmosis ............................... 5 Sand or Mixed -Media Filters - low rate ........... 2 high rate .......... 5 Treatment processes for removal of metal or cyanide .................................... 15 Treatment processes for removal of toxic materials other than metal or cyanide ......... 15 3GETREATMENT Sludge Digestion Tank - Heated ............... 10 Aerobic ............... 5 Unheated ...... ...... 3 Sludge Stabilization (chemical or thermal) . . . . . . . 5 Sludge Drying Beds - Gravity ................. 2 Vacuum Assisted ....... 5 Sludge Elulrialjon ......................... 5 Sludge Conditioner (chemical or thermal) .. . . . . 5 Sludge Thickener (gravity) ...................... 5 Dissolved Air Flotation Unit (not applicable to a unit rates as (3) (1) 8 Sludge Gas Utilization (including gas storage) 2 (i) Sludge Holding Imm Aerated ................ 5 Non -aerated 2 (j) Sludge Incinerator - (not including activated carbon regeneration) . . . . . to (k) Vacuum Filter, Centrifuge or Filler Press or other similar dewalering devices ......... ....... . ... 10 (8) SLUDGE DISPOSAL (including incinerated ash) (a)Lagoons........................................ 2 (b) Land Application (surface and subsurface) (see definition 22a) -where the facility holds the land app. permit . 10 -by contracting to a land application operator who holds the land application permit ................ 2 -land application of sludge by a contractor who does not hold the permit for the wastewater treatment facility where the sludge is generated ......... to (c) Landfilled (burial) ............................. 5 (9) DISINFECTION (a) Chlorination .............................. 5 (b) Dechlorination ........................ 5 (c) Ozone .............................. 5 (d) Radiation .......................... 5 (10) CHEMICAL ADDITION SYSTEM (S) (See definition No. 9) (not applicable to chemical additions rated as item (3) 6). (5) (a) (xi). (6) (a), (6) (b). (7) (b). (7) (e), (9) (a), (9) (b), or (9) (c) 5 points each: List: Po (Im ar . . . . . . ya1PM4•o1 / 5 £gd�rrs5 (11) MISCELLANEOUS UNITS (a) Holding Ponds. Holding Tanks or Settling Ponds for Organic or Toxic Materials including wastes from mining operations containing nitrogen and/or phosphorous compounds in amounts significantly greater than is common for domestic wastewater .......... 4 (b) Effluent Flow Equalization (not applicable to storage basins which are inherent in land application systems). 2 (c) Stage Discharge (not applicable to storage basins inherent in land application systems ....................................... 5 (d) Pumps .................. _................................................................................. (e) Stand -By Power Supply................................................................. 3 (f) Thermal Pollution Control Device ............................................. 3 TOTAL POINTS 57 a CLASSIFICATION ClassI ........................................................... 5 - 25 Points ClassIf ............... _....................................... 26- 50 Points ClassIII ...................................................... 51- 65 Points Class IV ........................................................ 66- Up Points Facilities having a rating of one through four points, inclusive do not require a certified operator. Classification of all other facilities requires a comparable grade operator in responsible charge. Facilities having an activated sludge process will be assigned a minimum classification of Class II. Facilities having treatment processes for the removal of metal of cyanide will be assigned a minimum classification of Class II Facilities having treatment processes for the biological removal of phosphorus will be assigned a minimum classification of Class - Ill, QEFIN ITIONC (I)wc-;• I-d Carbon B.d,. A phys;cakch,mical method for reduci,g a.olvb,. og,,;c aterial from .. waI•n .Iflu.nt: the Ilk— type bed, u-.d " IN, m .thart od w:e hart, how let. varying Iron wo I 1oa"0" g,sons per m.nvl. per sq.,a,• tool ,.w may be „Mr upnow or downlbw c.,bon bed,. Capon m,Y o, may not b. r •q.n.r,,.d on qa. wail, w,•r her N plan, ill.. (2)A.ul.d La9oo A b,.w, n e.hkh -e ,ocdtl ,,. m-:nnm.d A ,v.p.nnon -M by ..b;ch Woeoq:c ,l o vJ,honoro,pan-c miner ,- .. 4.c.d nno✓an anitic i,Iti sce.,•,-..d esnal•, of q9• on Iry ovgh bait; n (7)A•r,I:o A ps roces el br;ngin9 ab..al inl;,nal, conlact b,tw.on a;, or high punry o,ygo In a LQ,,d by tp,aying, lCillion dillvsio : (1)A9,kvhw.ty mamg.d silo. Any ill on v-h.h a crop II Fr duc.d, m.n•g.d, and harve,tod (Crop include, qle teat, grain., voes, etc): (5)Air Stripping. A plocus by which u-. ammonium ion is rrsl convened to dhsolr•d ammonia (pH adjvstm•N) rrih the ammonia then r.I..,.d to the stnolph.l• by physical mean,: or other similar p...... which omen polroleum product, such as banl.n., lolv.n•, and nylon.. (6)Cafbon 11.9en.ration. The regon•ration of uhaysl.d carbon by the use of a lulaau to pord. nu•m.ly high IemP... "Al which volalirl. and oaid-a• Ih. abwrb.d inpurili•r- (7)Catbonac.ous Su9.. A stage of wa.tew:te, ltealm.nl designed to ach;ore -secondary' ellbont I;I,;,,. (e)Cenvil.aq., A muclunical dov;co in winch conuivgil force is us" to sepatale solids Iron) G"id, and/or to s.p... 1. liquids of dllorenl d•n,nur (9)Ch•m;c.l Addition System. - Th. addition of chemical Is) to wz,tewaa.r al an application point for purposes of impro1;ra9 solids t.moral, pH adjustment, atkagi;ly control, etc,: he capability to exPer-rnent with ditf uAl chon,icalc ant dllerien, application po;n,s to ach;or• a sp•c;Gc sotult will be considered one sy. tens: he capab:Yly to add eham;c,l (a) to dual unlit will be rated is ono aYatum capability It, add a chemical at dtl.renc• application points Iw d.B.leN pu,pe,.. will result In Ih• systems being me as separate system. (10)C.ham;cal Shd90 CoAditka ltn9, The addition of 1 ch.r cal compound such as lima, ferric cNoride, o, a potym.( b wet sludge 10 coalesce the mass prior 10 its 3PP6cation to a dowato(vag d.tice- III)Closad Cycle Systems. Use of holding ponds or holdn9 Araks Iw containment of wastewater conla;tinp inor97n;c, noel-to'k "Al"" from sand, 91Ar 4. crushed alon. w ohs( simiaf opera lions Iron which {halo is no discharge to the surface wastes: such systems that carry a matwnum of Iwo points tell of purip;ng licllaies w any oh., appun.nanus• (12)Cortabined R.(.,oral of Citboniceous 600 and Nitro9.novs Re/noral by Niuificition - A single 11a9e 1 y.l.m 'd. a;9n.d' to ach;.r• 'advanced- p.mi1 offlv.ry limits on BOo and ammoriz rvuogen within he sarne bioloikal 191c10l. II])Oe-c.hbr;naiiof>. The pars;.) or complete I.ducl;on o! !.;dual chlorine in a rpv;d by any chornkif ,r physical process: IIc)Os'"ficat:on Proces$- The conrslsion of nivale-n;uogen to riiuoilon ga1- i1S)Elscuod"utysls, Process lot (.moving i"zild salts from water Wough the use of ion -selective tail -exchange m.mbe.res: (66)F2ler Press. A process operated mechsnlcafly for pasGlty d.wahring shadg.: (17)Foam S.Psn Gon, The planned frothing of waslawalt, or wa,lowalet effluent as a moans of lemor;nq rleatt;vii amounts of detergent materials "wSh he Introduction of ar In the form of hoe Ivbbl,s: else cited loam fracdon-tion- (se)Grw Aemoral The p,".ss of lemon -wag fill. and other heavy mineral malur kom waswwaror (19)InatwA Tank. A deep two story wastewator link consisting of an upper sedimamatan chimbot and a lower a". digestion chambeir- ('0)insdum•nt•d Flow M-11wilmenL A d.r;c. which "46 et &M/.r record, late o1 pow; (21)lon Exchange, A ch"e'" p(oc.ss in which ions from Iwo different molecults tit sxchanged: (22)Land aP96ct1iorL (a) Sludge (Nsposal. A final sludge disposal method by which sludge may be applied to land either by .praying on the surface or or .ubsvrlic• ini.ct:on (�s� chit•/ plow): InoI pptic able for Iyp., of sludge dezct;b,d in (11) of this Rvl.): (b)Treated Effluent. The pouts of s plaiting tr..led wt atewater onto a land . a er o,h.r m.thod, of application of west. walon on.o a I,rd area as a means of Goal disposal and/or b,arn.nl: ('l)1A:<ro tires. A low speed_ conlwsuoully back-wa,hod, totaling d,um felt., opora;nq under 9� 4 conditions as a Polishing method revs L,7 lu,p.neild solids from •M_, ('ION;hdkal;on ➢roc•,,. Th. bioch.m;ul co ...;.I of vnaoteidil•d nitrogen (smmonu and orq.n;c nwoq •n) 10 oa;d;l,d nitrogen (usually n:,rat•): VS)N;uo9.novs Slag.. A separate slag• of wa ,_ , u.atm•nl d.,;9ned for the sp•cilk pulp.,. of conr•,Gnq ammonia r-itr09sin Ill rl rJvog.I: (i6)Phosphate Re moral Biologkit. The comer 1 of ptiospho(vl from waslewal.( by an oz;danolic press d.sioned to enhance hazvfY upnke of Phosphoevs by the. microo,9anls ma. (7))PoGslainq Pond, A holding pond lobw;nq a.condary trntm.nl wih tu(fcioN d.oman to allow Ior, 1f.. senGn9 01 lin.ly suspended solid,: f (.6)P oil Aeus;on Mullion following eonvenlional saccrGary boatmen, urila to torn Aso e111ve n, D.O. o! Iw any the, P.,Pos.; (79)P091 Asiratiork (Ciscidt) A polishing mo,hod by which dic,o)v.d olyp •n is added 10 the olfluen, by I norun.ch,nica( Vitrify means of Jf win9 down s.ri., of steps or we;,,:The now occurr'in Ire. all a or w .thin "Yet a s q .even P eke more: to a lately, y M the operation of h• cascade legvir. no op. ra,w a, juslmont; thus, S.ra points a.. ...;gn.d er.n hough this I, an Inendal step 10 mining he "1' of th. d;schalpa permit: (77)Powdored or Get-", Activated Carbon F•.d. A b;oThyl;cil carbon pooest that uti6lu biological .kilt;.( and 0193n:c ibsorP don b r.p•n•,aled Y using po.-Geed on granule aclry a,.d <artwn; vi,pin .nd,ol c ,Ilapn i, le eel Controlled k110 the )I)P,.a.rltion. A link constrvcu.d Ill por;d• ,.ralar. prior to aulmr on (72)P(•timinuy Un;... Unit operations in the b.aun,nt;woc•1s, such ' •+act.•ning and thin ;"Par- h, I"., for .ubs.qu.nl mljor operations: con, nvt. n, p5)Indv,u;sl Pu (.)Pre-treatment Uni, scurc• b•for- chIndv unsl. The conditioning of a watt. at ill it l9,, to .mot. or to .n•u1111 i:, aubslara:•s Inj ax.11 and v.a,msnl p, ac.n•, or ,o elect a psnial r.Ovc don in bad on a u.aun,n, poc•tt wh;ch is ra,•d b , y o.erninp body al H• wale water Ire .,mint Plan) Ginq rated' (b)Pn l,,alm.nl opt Y the am• ogle Indw vial - r EPA r.gvi.•d prograrn s o nc. r, pov-1, on she r .ling ,he •,: ry Clan,n,,. Th. Ian I.nt:nq Unl., I11ou9h which wa$,lord•, I, pis, in a Ire a,m•nl weds lot In. pvrPo t. of r•movaq ae,du Dee s oiid tsine lusp•nd.d le6d, and 800 which i, sllocol.d woh in. : (l_)Pumpt, Aff ill!„ I. aIfl..nl, and in-plsnl (30A.ldisdon, Oi,:nl. e,ion and/orste,ifit al ion ul 62ing d•v;e.s srtdl,inq vlu,vwlel o, me gam D7)Ray.rs, Osmosis A u.sim•nl pieces$ in w.nicA s his" conlam inslid Lqua pus:v, feel though a m. mDn let lorrrdnq nutty pear• liquid be. film Ivsp.M.d solid, (7e)Rola 11V B;olog;c.l Conlicaels. A I:a•d bill t ,;arcd ,+ilk, in wh.:h a a.ie of Par.i,lly a„bm led felt pvl,l tawl,.e e,.'a,• 1o12l,0 wettewa.ol (tows 1 1 leFv,,,I:(171n,.,m;n. n.s Biological- Filv,tion of .hive ill lono..int, .plic I.nkt lao 14•,• Oen., tn,I�.. n, preen .n which Ivnher Diod.<ompwiGon 11.apecl.d lea p,odvc•d.li,.od 'lltr'nI': "T"""c to adin9 ran on Ih.l. hh.,1 , mpu�.d In 9pd„c and have s .•svh;ng Ill,. gprv,f pee- than m.): (b)Rec;,cul.dnq b;ob0;:,1 u,. cI a lyp. of land d•l:nod i w Inc sddod c,Plt"y to '-cycle .Invent back through th. .and I'll, n (s) ish (r0;$,nd or red""'te ........ A p"sh:n9 plo_-,I by which 1—;., s,. ,ehi•red Ih.ovgh a ,Vh e•. rin. co,00; 1 ... p.nd.d ,ohds:(s)tow u„ .. g,a✓n T, hYd„vhc,oY laded Ill.' with loadinq n o 1— 9Pn.,,l „ng.:rblhigh ,- •„ - Prhydra Lc 11, load.d I.e., with loading r al,I In Ih. In. 9�,.f nog._ At any is'.Ih. Iolea.,.q r, 1, wall .,k. eel IN.. gpnv,l • (e I)S.conda,y CI.AGers A lank which fol,ows the b;oloq,cd tine of , r.a _1 plane and which hat Iha pu,pol. of ,• ring .IvEq• .suit led vnlh Ih. bio,ng 1 v.avn.N v (42)S.p,31, Slvdg• R•a,n.:on, A pan of eh• cons < oc• alab9:I,l;.A p--,.clear s -h.— the led -h,dgo it tnn-I.,r.d to a lank end a.,,l.d Wt near ning'it I. Ih. b,-in: (ca)S.phc T„y. A tiny:. -,illy 1.IISnp lank In wNrh ,.nl.d llodp. Is in contact wkh ,he .-a,I...ai•, Ito wing 1lvovpn Ina lank' -hall no, be applicatalo for -.plic tank ,y,e -, ,.,ring angle II ;', n,.d•n<., ha•inp a capacity of 20(n q.lbn, or less which dilcha,go ,o , nih;f al;on h.td' (, c)Sludq• Oiq•u:on. Th. p,-.I, by whkh organic or rdalJ. manor and sludge is gs,ir..d. Igv.l:oil m;n•ralit•d or convened into I,— liable olpank matter through the act;v;ly of lining erg, niams, which Lulvd•s .e,al•d t.c: C:nq tenk,: OS)Sludga Drying Beds. An area canp;sing natural w altil' 1A layers of porwas materiel, upon whirl, digested ..wage .Ivdg. it dn.d by nl;ntgo and er.potation: ((6)Slvdg. Ehrviafion. A process of sludge cond;dordng In whch certain consdw cols .1. (tmo•.d by w 11IL-gl wih fresh waver o, pilot effluent; (e7)SI.if Ga. UliGz,der.. Th. p>e.,, of using sewsg. 91. foe the purpose of healing buildings, d,ivinp ongin.,, etc.: (I$)Shdfi. Holding lank (A ... led ,it Nona era ledJ. A link vl-lia.d to, small wasl•walor Ito ammunt pranll not c ca Wog a ours In 1 1h alvdoe may tau k.pl lush. and lierwrnauN -ithd,:.wn pro, to a d,y'rg mod-od (Le, atv C,a d,y;ng Inc,); 77vs may be don. by add.9 , .mat .movN of air ;n,ply 10 keep she a"- flesh, b,1 not Iw sl,l7y an amount that would be logvired to achieve stab;K`Alan of w9.nic mat.. A noes.,.%.d tank av f4 simply be used to decl a lludg. p;or to dewal •ring and _.sd simply be used to decsw tivdg• p,icr to dowilet;ng and would not allow long po,;ods (sereril days of d.leru;on) wehoul rosWivsq odor p,.b4.,; (49)Slvdge lIcie,eral.rl. A lwnxo dt,gntd to burn zhadg. and la tenor•. at naoiatvr. and eombe,ta-I. mat.6als and seduce the I:udq• to . atenl• ash: (50)Shdq• Subrlation (Chamical . Thsfmal). A P(ocas, to make treated sw9e less odorous and puu.icritA., and to rodvice Ihs Pt"'I'sic o(914sm conl.nl: This may be done by pH adjustment chlorine dosing, or by heat usabrant; (SI)Skedge Thickener. A type of s.eirrientalion lank in which he sludge Is permitted to stilt• and thkk.n 0v 0 a9-il.lan and V_ilj: (52)Stib-:aaiM La9e0A A type el eaid-li— 1a90— In whkh biological olidat;en el w9a ;c mall., is effecisd by natural trantlar of oxygen to he water kom air (not a poll Pord)- (S])Sland-By Power SupP:y- On list Or portable electrical 9eneraGrg •gvipn.tit; - (S/) Static Sultans, A stationlry $clean-deslgMd to semen solids including non-b;odegradabl• particulate (Iloatablo solids. suspended solids and 800 seduction) Item municipal and industrial wlslewl le f ke en a Itz1 t 3 7 3:. mi' (55jitsliary Treatment, A stage of uolimenl Ionowing secondary which is Prima,iy for the putpozc Of •10"Ist Jaoishiin: A secinlq Isgoon or sand of coal finer might be employed for Ins purpose. (56)TMrtsul P,tivlion Con..I D_i, A devk. ptovidup for he transfer of heal item A fluid flowing in tubes to anal Ovid okrs;de hs Iubts, er race versa: or, other means of regvlirraq liquid lemptralwes: (57)Th.rnW Sludge C*f"Onot. A ccreioeting process by which heat is added for a protracted period of erns 10 M,proro the dew,ll,abilAy of skdg. by he s(sk,04;ng and hydA.1izwa9 of the .mad., and more highly hyGaled tivc,• p.esktas: (53)T..k Materials. Th... wall•, or cornban.6ea— o1 wait., including des.....causing ag cots v.hk le alter discharge and upon eaposwe, in9eation, ;rtltala Gon or as"ation ;nle, any or9 anism e;theI dir.cdY kom she •eviroMn.n, of L-0-v acdy by IrgestiOA through lood chxins, win cause doith, diso, behav;wil abnormalities, cancer, 9.n.tk mutations, phys;ologkal mallunctions (•,racl,adrg sllunc lions in ropoduclion) or physical d.lo(niions, in such organism, or the;, o(Isprrg: Toxic materials inched., by wzy Olmvatidn and lea "talion: lead, cadmium. chromium, mercury, ranad;u_. ansric, lieu, orslso-n;lm-dJolebani.ne (ONCE polychlorinated b;phonyls (PCBs) and dcNofodiph•ny1 tr;chlo(wthane (OOT): and any other ma14611s that have or mar houailer be detormh•d to have to,;, prop.rli.,: (59)TskkLnq Will. A Dio)ogical It"-` unit "willi g of material such as brokon $ton• or rock one which wi atswaler is C:sat;Dulad: A high file kickrinq tiller is on. - lo and 30 m which is op.saua-.I'b.^.r•rn 96 per acre. A law rasa 1rcUing litter is one which is designed to opolate at one •Ic tear, mqd per aril; (6o)T,r1Gn9 Fill., (Packed Tow ,). A plug /low IYpe of opsralion in which wastewater Ilo—s down lNou9h wcc.alhie lay.$ of media cr Gltnl• maler;at: Organic material is removed continua::y by active biological filed 9,owlh in each lxcsssira IaY.f. This method may product, -socordary- cat tly .Illvsm, or may ba adapted to poduc. i duifiled effluent; I61)Vacwm Fitau, C"i"S41- of Fdu proses- Devices which it, designed to r.mov •ac.s. water kom .eh.( 6;9.al.d u and;g.,,.d shedg. prior W d;,Poal be fursh., t.atm.nL ■ Complete i 1, 2, and 3. Also complete + item 4 if Restricted Delivery is desired. ■ Print your name and address on the reverse so that we can return the card to you. ■ Attach this card to the back of the mailpiece, or on the front if space permits. Article Addressed to: Bruce Erickson The Recovery Group 270 Congress Street Boston, Massachusetts 02210 B. I Art D. Is delivery address di) if YES, enter delivery ❑ Agent ❑ Addressee C. Date of Delivery from item 1? ❑ Yes !ss below: ❑ No 3. Service Type ❑ Certified Mail ❑ Express Mail ❑ Registered ❑ Return Receipt for Merchandise ❑ Insured Mail ❑ C.O.D. 4. Restricted Delivery? (Extra Fee) ❑ Yes 7002 2410 0003 0272 8965 ! ,_ noe UNITED STATES AL S--'" ;E First '- 3 Mail Post =Fees Paid Cj USF _c Permit No. G-10 • Serig V Please print your name, address, and ZIP+4 in this box •- 1 Zquifer Protection Section itgDivision of Water Quality Attn: Ervin Lane 1636 Mail Service Center Raleigh, NC 27699-1636 �ee?eile?:is31::F:1?eltie?:::ii'z3:°°Eli:?�FiIE�':iEt:==•!=:f Z MW-3 m 4 RW-8 Qb M-4 MW-9 Qb (- 051') — 1.0 MW-2a ® 8 14 — 30 ❑ Mdd-13 RW-11 (- 3.76) Aullt.or JobNoo. A GREAT LAKES CHEMICAL CORPORATION COMPANY 4101003 Mdd-12 Bosch Boulevard Driving La?Jers 41010-2 0,1,13 Revision Figure 8-24-95 5 !hale 6-02-93 Scale T = 200' ORW-3 RW-4 MJV-10 tvM/-10a 0RW-g r RW-7a CD %RW-7 0 tj a G' y' Legend ia Shallow tvbnitcri g Well w y I oPBCOV6ry Well x 0 Deep Ivbnitorlrg Well cD a (- 3.75) Water Level Elevations (I'vW > O ^� Potentlorretrlo Contour 17Q O In Feet (tviSLJ y p r' a� Mle Potontlomotric Surtaoo Map (October 91,1991) F—+ ~o Project Texfl he0rp0rated CD _�'o �—+ � � O O -I'#- IJew Bern, North Carollna v' W �3 Q� MVd-3 o MW-2 0 RW-8 Q5 MW-4 A1L thor LSG Job No A GREAT LAKES CHEMICAL CORPORATION COMPANY 4101003 _ga -9 M\W-2a 8 0 MW 14 MW-13 R24 W-11 -2.73 3, tS 0 -12 e Bosch Boulevard Drawing Lc 41010-2 Revision Fi 8-24-95 6-02-93 le T = 200' ORW-3 �RW-4 MW-10 MvV-10a O RW-5 VW-6 c CxxD �-h RW-7a �ORW 7 O CL in. r= y r3 t Legend phi y i ® Shallow Monitoring Well I Recovery Well ►b� Q Deep Monitoring Well H O (-2.73) Ground Water Elevation Reference to Mean Sea Level > •aq '� � �C Inferred Ground Water Contour Line yc p Title Doop Well Ground Water Flow Map (January 12,1995) CO — (D �0 Project Texfl hcorporated •A ~p N 00 � Ory New Bern, North Carolina B 01 0 MW-1 0 MW-2 Q9 MA 0 MW-3 m Author ���� Job No. SG � c� rr� A GREAT LAKES CHEMICAL CORPORATION COMPANY 4101003 MW-2a 0 '� MW-14 _1MW / ;09 RW-11- 2Bg ) — 1.75 — 2.25 0 MW-12 Bosch Boulevard Drawing Layers 41M2 0,1,14 Revision Figure 8-24-95 6 OO RW--3 FMA ® MW-10 MJV-10a :1W-5 v ®RW-e RW-7a CCD ORW-7 p a. In, C Legend ti 0 Shallow Monitoring Well QQ Recovery Well b x Deep Wnitorirg Well Q a' (- 225) Water Level Elevations (N/RJ O r qq Potentiometric Contour 40 In Feet MU O O a� t602 Title ace Map Poten(AuO 93 st 25trlc , M5) Uq o pni C le Project (D � O -'0 00 0 Texfl Incorporated N 1• = 200' New Bem, North Carolina 10 C 20 XXX�/pti. n 0 (8) fF W-4a 66) (12; ;W-10 -674) I s {ter l''w M AI DRY @ 8.10 DOWRY@152 DRY @ 088 0DDRRY@7ffl @232 Manufacturing Bu Ing 4 10 1R4 34) M ' L41". 332 i (0.191� tv>`N-9 Qt (0.70)� ® DRY @ 0.12 DRY @ 761 MW-2a Q MvV-14 08b2) 0 Mw-13 ® RW kRW 6 (3`2 3a®RW-7 0 (t,0m2v7)12 ��- Bosch Boulevard � Author Drawling Lars Date fir] LSG 41010-2 0,1,12 6-02-93 Job No. Revision Figure Scale A GREAT LAKES CHEMICAL CORPORATION COMPANY 4101003 8-24-95 3 1' = 200 Legend 0 Shallow Monitoring Well Recovery well Deep tvbnitorlrg Well (323) Ground Water Elevation (Reference to Maan Sea Level) Inferred Ground Water Contour Line Shallow Ground Water Flow Map (January 12,1996) t TexfI hcor posted New Bern, North Carolina y cD z� 0 �a ay C � y dQ ) (x Qa P.m" G r+ CD r 40 o w a'� aq aw �, C=) y CD L �0LAWp a