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HomeMy WebLinkAboutWQ0003396_Monitoring - 07-2020_20200813 (2)SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WO0003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): CREEK (SCMS) Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: ft. Well Diameter: 2 in. pH 00400: 7.1 units Temp. 0001c 25.3 oC DRY at Depth to Water Level 82546: ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 0.072 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: gallons Appearance 'LEAR, SLIGHT YELLOW BROWI here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 330 MPN /100mL Nitrate (NO3) as N 00620 0.1 Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.025 rrv/ (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 'mg� 202L (Specify Compounds and Concentration Units): issolved Solids:Total 70300 92 mg/L Al - Aluminum 01105 niAj UTTpH T��IV Nitrate/Nitrite as N: <0.11 mg/L (Lab) 00403 units Ba - Barium 01007 1�'; f1RHAIIQI�CESSW12- 1 ll: TOC 00680 16 mg/L Ca - Calcium 00916 mg/L Chloride 00940 7.8 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 0.19 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Aqent) Name and Title - Please print or twe GW-59 Rev.8/2013 Siqnature tdf FMfmittee (or Authorized I uate ) 8/5/2020 JUtSMI I r-UMM UN TCLLUVV r1Arr ( UIVLT GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Arauco North America, Inc. Permit Name (if different): Facility Address: 985 Corinth Road Contact Person: Well Location/Site Name Savannah Carroll Arauco North America. Inc. WELL ID NUMBER (from Permit): SMW-3 Well Depth: 23 ft. Depth to Water Level 82546: 16 ft. below measuring point Measuring Point is ft. above land surface County Chatham Telephone#: 919-545-5848 No. of wells to be sampled: 9+1 from Permit Date sample collected: 7/15/2020 Well Diameter: 2 in. Screened Interval: ft. to Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 3.6 gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 PERMIT Number: Expiration Date: 7/31/2025 Non -Discharge W00003396 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: ft. FIELD ANALYSES: pH 00400: 5.6 units Spec. Cond. 00094: Odor 00085: Appearance Temp.0001( 211 °C 0.026 µMhos NO ODOR CLEAR Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 2.7 mg/L Zn -Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.026 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 <50 mg/L Al -Aluminum 01105 mg/L Nitrate/Nitrite as N: 2.7 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 0.39 mg/L Ca - Calcium 00916 mg/L Chloride 00940 6.5 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.045 mg/L Mg - Magnesium 00927 mg/L method# (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% If WELL WAS DRY at time of sampling, check here:❑ SUBMIT FORM ON YELLOW PAPER ONLY • . DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge W00003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-4 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 19 ft. Well Diameter: 2 in. pH 00400: 6.3 units Temp. 0001c 22.1 oC DRY at Depth to Water Level 82546: 7.4 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 1.867 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 6 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 3i6i6 <1.0 /100mL Nitrate (NO3) as N 00620 0.063 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.097 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1400 mg/L Al -Aluminum 01105 mg/L Nitrate/Nitrite as N: 0.063 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 4.9 mg/L Ca - Calcium 00916 mg/L Chloride 00940 590 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.045 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Aqent) Name and Title - Please print or type SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge W00003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-5 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 20 ft. Well Diameter: 2 in. pH 00400: 6.8 units Temp. 000ic 21.1°C DRY at Depth to Water Level 82546: 5.6 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 2.8 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: 6.9 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 160 MPN /100mL Nitrate (NO3) as N 00620 0.11 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1700 mg/L Al -Aluminum 01105 mg/L Nitrate/Nitrite as N: 0.11 mg/L pH (Lab) oo403 units Ba - Barium 01007 ug/L TOC 00680 6.9 mg/L Ca - Calcium 00916 mg/L Chloride 00940 740 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.045 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Agent) Name and Title - Please print or tvpe SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: �116117 DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31 /2025 Facility Name: Arauco North America, Inc. Non -Discharge W00003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-8 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 23 ft. Well Diameter: 2 in. pH 00400: 6.9 units Temp. 000lc 183 °C DRY at Depth to Water Level 82546: 5.5 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 2.09 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: 8.1 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 5.1 /100mL Nitrate (NO3) as N 00620 <0.041 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1200 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: <0.041 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 3.2 mg/L Ca - Calcium 00916 mg/L Chloride 00940 500 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes(l) ❑ No(0) pecific Conductance 00095 ltMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.045 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Aqent) Name and Title - Please print or type SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT 8 NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge W00003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery County Chatham ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-9 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 22 ft. Well Diameter: 2 in. pH 00400: 6.9 units Temp. 000ic ' 189 °C DRY at Depth to Water Level 82546: 4 Screened Interval: ft. to ft. Spec. Cond. 00094: 1.189 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: 8.7 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed. 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 <0.041 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 3i504 /100mL Phosphorus: Total as P 00665 0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 650 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: <0.041 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 5.6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 200 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 0i042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 <0.045 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WQ0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery County Chatham ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-18R Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 21 ft. Well Diameter: 2 in. pH 00400: 5.2 units Temp. 0001c 23.4 °C DRY at Depth to Water Level 82546: 8.4 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 0.0152 µMhos time of Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 000m: NO ODOR sampling, check Volume of water pumped/bailed before sampling: 6 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 <1.0 /100mL Nitrate (NO3) as N 00620 0.27 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 80 mg/L Al -Aluminum 01105 mg/L Nitrate/Nitrite as N: 0.27 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 2 mg/L Ca - Calcium 00916 mg/L Chloride 00940 11 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.045 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge WO0003396 UIC NPDES Other Permit Name (if different): Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-19 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 17 ft. Well Diameter: 2 in. pH 00400: 6.4 units Temp. 000lc 20.7°C DRY at Depth to Water Level 82546: 7 Screened Interval: ft. to ft. Spec. Cond. 00094: 1.11 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: 1.5 gallons Appearance LIGHT YELLOW BROWN here:[] Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO Dry LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 31 /100mL Nitrate (NO3) as N 00620 0.062 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 940 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: 0.062 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 9.6 mg/L Ca - Calcium 00916 mg/L Chloride 00940 360 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.084 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES GROUNDWATER QUALITY MONITORING: DIVISION OF WATER RESOURCES -INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 7/31/2025 Facility Name: Arauco North America, Inc. Non -Discharge W00003396 UIC Permit Name (if different): NPDES Other Facility Address: 985 Corinth Road TYPE OF PERMITTED OPERATION BEING MONITORED County Chatham ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: Contact Person: Savannah Carroll Telephone#: 919-545-5848 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): SMW-20 Date sample collected: 7/15/2020 FIELD ANALYSES: WAS Well Depth: 40 ft. Well Diameter: 2 in. pH 00400: 7 units Temp. 000lc 18.6 °C DRY at Depth to Water Level 82546: 5.2 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 0.356 µMhos time of sampling, Measuring Point is ft. above land surface Relative M.P. Elevation: ft. Odor 00085: NO ODOR check Volume of water pumped/bailed before sampling: 18 gallons Appearance CLEAR here:❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 1 /100mL Nitrate (NO3) as N 00620 <0.041 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.087 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 300 mg/L Al - Aluminum o1105 mg/L Nitrate/Nitrite as N: <0.041 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 6.4 mg/L Ca - Calcium 00916 mg/L Chloride 00940 88 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 EtMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 0.088 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FUKM ON YLLLUW F'AVLK UNLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Facility Name: Permit Name (if different): Facility Address: Please Print Clearly or Type Arauco North America, Inc. 985 Corinth Road County Chatham act Person: Savannah Carroll Telephone#: 919-545-5848 Location/Site Name Arauco North America, Inc. No. of wells to be sampled: 9+1 WELL ID NUMBER (from Permit): SMW-21 Well Depth: 16 ft. Depth to Water Level 82546: 8 Measuring Point is ft. above land surface Volume of water pumped/bailed before sampling: 3.3 SamDles for metals were collected unfiltered: ❑ YES Date sample collected: Well Diameter Screened Interval Relative M.P. Elevation gallons DEPARTMENT OF ENVIRONMENT & NATURAL RESOURCES DIVISION OF WATER RESOURCES - INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807-6306 PERMIT Number: Expiration Date: 7/31/2025 Non -Discharge WQ0003396 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: 7/15/2020 2 in. ft. to ft. ft. ❑ NO and field acidified: ❑ YES ❑ NO FIELD ANALYSES: pH 00400: 6.3 units Spec. Cond. 00094: Odor 00085: Temp.000u 19.6 2.2 µMhos NO ODOR oC Appearance CLEAR, SLIGHT TURBIDITY Date sample analyzed: 7/16/20, 7/22/20, 7/23/20, 7/27/20 Laboratory Name: ENCO Certification No. NC591 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 0.017 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 8.6 /100mL Nitrate (NO3) as N 00620 0.052 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.025 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 1100 mg/L Al - Aluminum 01105 mg/L Nitrate/Nitrite as N: <0.052 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 6.5 mg/L Ca - Calcium 00916 mg/L Chloride 00940 520 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 0.05 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VUL; Kemoval is Jeff McMillian - Moncure Plant Manager Permittee (or Authorized Agent) Name and Title - Please print or tvpe GW-59 Rev.8/2013 (or Authorized Aqent) (Date) If WELL DRY at time of sampling, check here: ❑ Dry 8/5/2020 GW-59a ATTACHMENT HISTORICAL EXCEEDANCE RESULTS - PREVIOUS 2 YEARS Chlorides (mg/L) Well Limit 3/6/2018 7/13/2018 11/20/2018 3/21/2019 7/12/2019 11/6/2019 3/19/2020 7/15/2020 SMW-4 580 580 620 670 620 650 580 590 SMW-5 770 780 750 770 760 730 730 740 SMW-8 250 620 620 110 550 510 530 480 500 SMW-19 NT NT 42 260 NE NE NE 360 SMW-21 64 110 83 240 160 54 440 520 TDS (mg/L) Well Limit 3/6/2018 7/13/2018 11/20/2018 3/21/2019 7/12/2019 11/6/2019 3/19/2020 7/15/2020 SMW-4 1200 1300 1200 1300 1300 1400 1200 1400 SMW-5 1700 1600 1700 1700 1700 1500 1700 1700 SMW-8 500 1400 1200 290 1200 1200 1400 1100 1200 SMW-9 640 620 350 660 630 620 680 650 SMW-19 NT NT 5400 1000 1600 NT 4200 940 SMW-21 240 260 1100 520 400 160 920 1100 pH Well Limit 3/6/2018 7/13/2018 11/20/2018 3/21/2019 7/12/2019 11/6/2019 3/19/2020 7/15/2020 SMW-3 5.4 5.3 5.4 5.8 4.8 4.8 5.2 5.58 SMW-4 6.7 6.5 6.6 6.8 6.4 NE NE 6.31 SMW-18R 5.4 5.3 5.3 5.4 5.2 5.5 5.1 5.2 SMW-19 6.5 - 8.5 NT NT 6.9 7.3 6.4 NT 5.5 6.43 SMW-20 7.4 7.7 6.8 7.5 7.0 7.7 6.5 NE SMW-21 1 7.2 1 7.1 6.4 6.4 6.9 6.8 6.4 NE *NT - not enough water fo 4 ENCO Laboratories Accurate. Timely, Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Wednesday, July 29, 2020 Arauco North America, Inc. (UN039) Attn: Savannah Carroll 985 Corinth Road Moncure, NC 27559 RE: Laboratory Results for Project Number: GW/SW Monitoring, Project Name/Desc: GW/SW Monitoring -TriAnnual(Mar,luly) ENCO Workorder(s): CD11305 Dear Savannah Carroll, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Thursday, July 16, 2020. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, Amanda L. Gaines Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 Of 2 E�Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SMW-3 Lab ID: CD11305-01 Sampled: 07/16/20 11:06 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 19:01 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:08 EPA 353.2 NO PREP 07/18/20 11:06 07/16/20 15:39 07/16/20 16:42 EPA 353.2 [CALC] 07/18/20 11:06 07/22/20 16:09 07/23/20 11:05 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:05 EPA 365.4 Same 08/13/20 07/24/20 11:20 07/29/20 14:18 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:13 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-4 Lab ID: CD11305-02 Sampled: 07/16/20 10:46 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 18:41 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:10 EPA 353.2 NO PREP 07/18/20 10:46 07/16/20 15:39 07/16/20 16:43 EPA 353.2 [CALC] 07/18/20 10:46 07/22/20 16:09 07/23/20 11:07 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:07 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:05 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:13 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-5 Lab ID: CD11305-03 Sampled: 07/16/20 10:15 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 18:10 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:12 EPA 353.2 NO PREP 07/18/20 10:15 07/16/20 15:39 07/16/20 16:44 EPA 353.2 [CALC] 07/18/20 10:15 07/22/20 16:09 07/23/20 11:08 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:08 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:07 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:15 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-8 Lab ID: CD11305-04 Sampled: 07/16/20 10:27 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 18:22 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:14 EPA 353.2 NO PREP 07/18/20 10:27 07/16/20 15:39 07/16/20 16:45 EPA 353.2 [CALC] 07/18/20 10:27 07/22/20 16:09 07/23/20 11:10 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:10 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 14:48 SM 254OC-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:16 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 Of 2� (FJ�Go www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SMW-9 Lab ID: CD11305-05 Sampled: 07/16/20 10:37 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analvsis Date/Time(s) Colilert 18 NO PREP 07/16/20 18:32 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:15 EPA 353.2 NO PREP 07/18/20 10:37 07/16/20 15:39 07/16/20 16:46 EPA 353.2 [CALC] 07/18/20 10:37 07/22/20 16:09 07/23/20 11:12 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:12 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 14:49 SM 254OC-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:17 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-18R Lab ID: CD11305-06 Sampled: 07/16/20 08:55 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(sl Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 16:50 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/22/20 08:27 07/22/20 10:17 EPA 353.2 NO PREP 07/18/20 08:55 07/16/20 15:39 07/16/20 16:47 EPA 353.2 [CALC] 07/18/20 08:55 07/22/20 16:09 07/23/20 11:14 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:14 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 14:51 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:17 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-19 Lab ID: CD11305-07 Sampled: 07/16/20 09:25 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 17:20 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/21/20 14:11 07/21/20 17:03 EPA 353.2 NO PREP 07/18/20 09:25 07/16/20 15:39 07/16/20 16:48 EPA 353.2 [CALC] 07/18/20 09:25 07/22/20 16:09 07/23/20 11:16 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:16 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:08 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SMW-19 Lab ID: CD11305-07RE1 Sampled: 07/16/20 09:25 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(sl Analysis Date/Time(s) SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 13:37 Client ID: SMW-20 Lab ID: CD11305-08 Sampled: 07/16/20 09:40 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 17:35 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/21/20 14:11 07/21/20 17:05 EPA 353.2 NO PREP 07/18/20 09:40 07/16/20 15:39 07/16/20 16:50 EPA 353.2 [CALC] 07/18/20 09:40 07/22/20 16:09 07/23/20 11:17 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:17 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:12 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:19 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of Z 1 E �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: SMW-21 Lab ID: CD11305-09 Sampled: 07/16/20 09:45 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(sl Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 17:40 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/21/20 14:11 07/21/20 17:06 EPA 353.2 NO PREP 07/18/20 09:45 07/16/20 15:39 07/16/20 16:51 EPA 353.2 [CALC] 07/18/20 09:45 07/22/20 16:09 07/23/20 11:18 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:18 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:13 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:19 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 Client ID: SCMS Lab ID: CD11305-10 Sampled: 07/16/20 10:00 Received: 07/16/20 11:45 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) Colilert 18 NO PREP 07/16/20 17:55 07/17/20 12:04 07/16/20 14:00 07/17/20 10:06 EPA 350.1 NO PREP 08/13/20 07/21/20 14:11 07/21/20 17:08 EPA 353.2 NO PREP 07/18/20 10:00 07/16/20 15:39 07/16/20 16:52 EPA 353.2 [CALC] 07/18/20 10:00 07/22/20 16:09 07/23/20 11:21 EPA 353.2 NO PREP 08/13/20 07/22/20 16:09 07/23/20 11:21 EPA 365.4 Same 08/13/20 07/22/20 13:15 07/24/20 15:14 SM 2540C-2011 NO PREP 07/23/20 07/21/20 15:37 07/21/20 15:37 SM 4500CIE-2011 NO PREP 08/13/20 07/27/20 10:40 07/27/20 12:20 SM 531OB-2011 Same 08/13/20 07/22/20 18:00 07/23/20 03:47 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 Of Z ENCO www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SMW-3 Lab ID: CD11305-01 Analvte Results %s MQL POL units Method IN Chloride 6.5 1.9 5.0 mg/L SM 4500CI E-2011 Nitrate as N 2.7 D 0.082 0.20 mg/L EPA 353.2 Nitrate/Nitrite as N 2.7 D 0.082 0.20 mg/L EPA 353.2 Phosphorus 0.026 3 0.025 0.10 mg/L EPA 365.4 Total Organic Carbon 0.39 3 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-4 Lab ID: CD11305-02 Analvte Results Flag MDL POL Units Method Notes Chloride 590 D 9.5 25 mg/L SM 4500CI E-2011 Nitrate as N 0.063 3 0.041 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.063 3 0.041 0.10 mg/L EPA 353.2 Phosphorus 0.097 3 0.025 0.10 mg/L EPA 365.4 Total Dissolved Solids 1400 50 50 mg/L SM 254OC-2011 Total Organic Carbon 4.9 0.34 1.0 mg/L SM 5310E-2011 Client ID: SMW-5 Lab ID: CD11305-03 Analvte Results Flag MQL M Units Method Notes Chloride 740 D 19 50 mg/L SM 4500CI E-2011 Coliform, Fecal 160 1.0 1.0 MPN/100 mL Colilert 18 Nitrate as N 0.11 0.041 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.11 0.041 0.10 mg/L EPA 353.2 Total Dissolved Solids 1700 100 100 mg/L SM 2540C-2011 Total Organic Carbon 6.9 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-8 Lab ID: CD11305-04 Analyte Results Flag MDL POL Units Method Notes Chloride 500 D 19 50 mg/L SM 4500CI E-2011 Coliform, Fecal 5.1 1.0 1.0 MPN/100 mL Colilert 18 Total Dissolved Solids 1200 50 50 mg/L SM 2540C-2011 Total Organic Carbon 3.2 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-9 Lab ID: CD11305-05 Analvte Results Flag MQL R" Units Method Notes Chloride 200 D 9.5 25 mg/L SM 4500CI E-2011 Total Dissolved Solids 650 50 50 mg/L SM 254OC-2011 Total Organic Carbon 5.6 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-18R Lab ID: CD11305-06 Anal vte Results Flag MQL P" Units Method Note Chloride 11 1.9 5.0 mg/L SM 4500CI E-2011 Nitrate as N 0.27 0.041 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.27 0.041 0.10 mg/L EPA 353.2 Total Dissolved Solids 80 50 50 mg/L SM 254OC-2011 Total Organic Carbon 2.0 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-19 Lab ID: CD11305-07 Analyte Results Flag MDL POL units Method Notes Ammonia as N 0.084 3 0.045 0.10 mg/L EPA 350.1 Nitrate as N 0.062 1 0.041 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.062 3 0.041 0.10 mg/L EPA 353.2 Total Dissolved Solids 940 50 50 mg/L SM 2540C-2011 Total Organic Carbon 9.6 0.34 1.0 mg/L SM 531OB-2011 Client ID: SMW-19 Lab ID: CD31305-07RE3 Analyt Results Flag MDL POL Units Method Notes Chloride 360 D 9.5 25 mg/L SM 4500CI E-2011 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 5 Of 2 (��Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: SMW-20 Lab ID: CD11305-08 Analvte Results fin Hu r" Units Method lyote� Ammonia as N 0.088 ] 0.045 0.10 mg/L EPA 350.1 Chloride 88 1.9 5.0 mg/L SM 4500CI E-2011 Coliform, Fecal 1.0 1.0 1.0 MPN/100 mL Colilert 18 Phosphorus 0.087 ] 0.025 0.10 mg/L EPA 365.4 Total Dissolved Solids 300 50 50 mg/L SM 2540C-2011 Total Organic Carbon 6.4 0.34 1.0 mg/L SM 5310E-2011 Client ID: SMW-21 Lab ID: CD11305-09 Anal vte Results Flag MDL P L Units Method Notes Ammonia as N 0.050 ] 0.045 0.10 mg/L EPA 350.1 Chloride 520 D 9.5 25 mg/L SM 4500CI E-2011 Coliform, Fecal 8.6 1.0 1.0 MPN/100 mL Colilert 18 Nitrate as N 0.052 1 0.041 0.10 mg/L EPA 353.2 Nitrate/Nitrite as N 0.052 J 0.041 0.10 mg/L EPA 353.2 Total Dissolved Solids 1100 50 50 mg/L SM 2540C-2011 Total Organic Carbon 6.5 0.34 1.0 mg/L SM 531OB-2011 Client ID: SC MS Lab ID: CD11305-10 Anal a Results Flag MDL POL Units Method Notes Ammonia as N 0.19 0.045 0.10 mg/L EPA 350.1 Chloride 7.8 1.9 5.0 mg/L SM 4500CI E-2011 Coliform, Fecal 330 1.0 1.0 MPN/100 mL Colilert 18 Nitrate as N Nitrate/Nitrite as N Total Dissolved Solids Total Organic Carbon 0.11 0.041 0.10 mg/L EPA 353.2 0.11 0.041 0.10 mg/L EPA 353.2 92 50 50 mg/L SM 254OC-2011 16 0.34 1.0 mg/L SM 531OB-2011 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 of 212 ce-INco www.encolabs.com ANALYTICAL RESULTS Description: SMW-3 Lab Sample ID:CD11305-01 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 11:06 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By:John Sherrill lClassical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL Q Batch Method Analyzed By Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:08 JAH Chloride [36887-00-6]^ 6.5 mg/L 1 1.9 5.0 OG27020 SM 4500CI E-2011 07/27/20 12:13 JAH Nitrate as N [14797-55-8] 2.7 D mg/L 2 0.082 0.20 [CALC] EPA 353.2 07/23/20 11:05 JAH Nitrate/Nitrite as N^ 2.7 D mg/L 2 0.082 0.20 OG22043 EPA 353.2 07/23/20 11:05 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:42 JAH Phosphorus [7723-14-0]^ 0.026 1 mg/L 1 0.025 0.10 OG24010 EPA 365.4 07/29/20 14:18 JAH Total Dissolved Solids^ < 50 mg/L 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag y ni tj DF pQ Batch Method Analyzed ¢y Notes Coliform, Fecal^ < 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PPOL Batch Method Analyzed By Notes Total Organic Carbon^ 0.39 J mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA Description: SMW-4 Lab Sample ID:CD11305-02 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 10:46 Work Order: CD11305 Project: GW/SW Mon itoring-TriAnnual(Mar,July) Sampled By:John Sherrill lClassical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL Q Batch Method Analyzed Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:10 JAH Chloride [16887-00-6]^ 590 D mg/L 5 9.5 25 OG27020 SM 4500CIE-2011 07/27/20 12:13 JAH Nitrate as N [14797-55-8] 0.063 J mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:07 JAH Nitrate/Nitrite as N^ 0.063 J mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:07 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:43 JAH Phosphorus [7723-14-0]^ 0.097 J mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:05 JAH Total Dissolved Solids^ 1400 mg/L 1 50 50 OG21010 SM 254OC-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF P(L Batch Method Analyzed By Notes Coliform, Fecal^ < 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PPOL Batch Method Analyzed My Notes Total Organic Carbon^ 4.9 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page % Of 21 CESlVCO www.encolabs.com ANALYTICAL RESULTS Description: SMW-5 Lab Sample ID: CD11305-03 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 10:15 Work Order: CD11305 Project: GW/SW Monitoring -TriAnnual(Mar,Iuly) Sampled By: John Sherrill I Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units PE MU M Batch Method Analyzed @y Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:12 JAH Chloride [16887-00-6]^ 740 D mg/L 10 19 50 OG27020 SM 4500CIE-2011 07/27/20 12:15 JAH Nitrate as N (14797-55-81 0.11 mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:08 JAH Nitrate/Nitrite as N^ 0.11 mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:08 JAH Nitrite as N [14797-65-O]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:44 JAH Phosphorus[7723-14-0]^ < 0.025 mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:07 JAH Total Dissolved Solids^ 1700 mg/L 2 100 100 OG21010 SM 254OC-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Racultc Flaa Units gF POL Batch Method Analyzed jay Notes Coliform, Fecal^ 160 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyfe [NC 424] Analyte rCAS Numberl Results Flao UnJU DF MDL Q Batch Method Analyzed Ay Notes Total Organic Carbon^ 6.9 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA Description: SMW-8 Lab Sample ID:CD11305-04 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 10:27 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By:John Sherrill (Classical Chemistry Parameters ^ - ENCO Cary certifed analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL IQ Batch Method Analyzed By Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:14 JAH Chloride [16887-00-6]^ Soo D mg/L 10 19 50 OG27020 SM 4500CIE-2011 07/27/20 12:16 JAH Nitrate as N [14797-55-8] < 0.041 mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:10 JAH Nitrate/Nitrite as N^ < 0.041 mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:10 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:45 JAH Phosphorus[7723-14-0]^ < 0.025 mg/L 1 0.025 0.10 OG22004 EPA 365.4 07/24/20 14:48 JAH Total Dissolved Solids^ 1200 mg/L 1 50 50 OG21010 SM 254OC-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analoe [NC 591] Analyte rCAS Numberl Results Flaa Units DF IQ Batch Method Analyzed By Notes Coliform, Fecal^ 5.1 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte rCAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 3.2 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 21 E �Eo www.encolabs.com ANALYTICAL RESULTS Description: SMW-9 Lab Sample ID: CD11305-05 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 10:37 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By:John Sherrill Chemistry Parameters ^ - ENCO Cary certified analyze [NC 5911 Analyte rCAS Numberl Resulrc Flo Units DF MDL pQL Batch Method Analyzed Ay Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:15 JAH Chloride [16887-00-6]^ 200 D mg/L 5 9.5 25 OG27020 SM 4500CIE-2011 07/27/20 12:17 JAH Nitrate as N [14797-55-8] < 0.041 mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:12 JAH Nitrate/Nitrite as N^ < 0.041 mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:12 JAH Nitrite as N [14797-65-O]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:46 JAH Phosphorus[7723-14-O]^ < 0.025 mg/L 1 0.025 0.10 OG22004 EPA 365.4 07/24/20 14:49 JAH Total Dissolved Solids^ 650 mg/L 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Resulrc Flag Units )7F IQ Batch Method Analyzed Am Notes Coliform, Fecal^ < 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424) Analyte rCAS Numberl Results Flag Units DF MDL Q Batch Method Analyzed By Notes Total Organic Carbon^ 5.6 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA Description: SMW-18R Lab Sample ID:CD11305-06 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 08:55 Work Order: CD11305 Project: GW/SW Monitoring -TriAnnual(Mar,July) Sampled By:John Sherrill Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed It Notes Ammonia as N [7664-41-7]^ < 0.045 mg/L 1 0.045 0.10 OG22006 EPA 350.1 07/22/20 10:17 JAH Chloride [16887-00-6]^ 11 mg/L 1 1.9 5.0 OG27020 SM 4500CIE-2011 07/27/20 12:17 JAH Nitrate as N [14797-55-8] 0.27 mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:14 JAH Nitrate/Nitrite as N^ 0.27 mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:14 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:47 JAH Phosphorus[7723-14-0]^ < 0.025 mg/L 1 0.025 0.10 OG22004 EPA 365.4 07/24/20 14:51 JAH Total Dissolved Solids^ 80 mg/L 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units OF lQ Batch Method Analyzed Notes Coliform, Fecal^ < 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL lQ Batch Method Analyzed By Notes Total Organic Carbon^ 2.0 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of Z (E�Eo www.encolabs.com ANALYTICAL RESULTS Description: SMW-19 Lab Sample ID:CD11305-07 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 09:25 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By:John Sherrill I Chemistry Parameters ^ - ENCO Cary certified analyze [NC 591] Analyte rCAS Numberl Results Flag Units 2E HU POL Batch Method Analyzed By Notes Ammonia as N [7664-41-7]^ 0.084 J mg/L 1 0.045 0.10 OG21031 EPA 350.1 07/21/20 17:03 JAH Chloride [16887-00-6]^ 360 D mg/L 5 9.5 25 OG27020 SM 4500CI E-2011 07/27/20 13:37 JAH Nitrate as N [14797-55-8] 0.062 J mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:16 JAH Nitrate/Nitrite as N^ 0.062 J mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:16 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:48 JAH Phosphorus[7723-14-O]^ < 0.025 mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:08 JAH Total Dissolved Solids^ 940 mg/L 1 50 50 OG21010 SM 254OC-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units pE EQL Batch Method Analyzed @y Notes Coliform, Fecal^ < 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Numberl Re ul Flag Units DF MDL 1Q Batch Method Analyzed By Notes Total Organic Carbon^ 9.6 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA Description: SMW-20 Lab Sample ID: CD11305-08 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 09:40 Work Order: CD11305 Project: GW/SW Monitoring -TriAnnual(Mar,July) Sampled By: John Sherrill lCaassical Chemistry Parameters ^ - ENCO Cary certified analW [NC 591] Analyte rCAS Numberl Resul Flag Units DF MDL POL Batch Method Anallged By Notes Ammonia as N [7664-41-7]^ 0.088 J mg/L 1 0.045 0.10 OG21031 EPA 350.1 07/21/20 17:05 JAH Chloride [16887-00-6]^ 88 mg/L 1 1.9 5.0 OG27020 SM 4500CIE-2011 07/27/20 12:19 JAH Nitrate as N [14797-55-8] < 0.041 mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:17 JAH Nitrate/Nitrite as N^ < 0.041 mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:17 JAH Nitrite as N [14797-65-0]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:50 JAH Phosphorus [7723-14-0]^ 0.087 J mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:12 JAH Total Dissolved Solids^ 300 mg/L 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary cerh'fied analyte [NC 591] Analyte fCAS Numberl Results Flag Units DF POL Batch Method Analyzed By Notes Coliform, Fecal^ 1.0 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte [CAS Numberl Results Flag Units DF MDL POL Batch Method Analyzed By Notes Total Organic Carbon^ 6.4 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 of 21 CeNCO www.encolabs.com ANALYTICAL RESULTS Description: SMW-21 Lab Sample ID: CD11305-09 Received: 07/16/20 11:45 Matrix: Ground Water Sampled: 07/16/20 09:45 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By -John Sherrill Chemistry Parameters ^ - ENCO Cary certified analyte [NC 5911 Analvte rCAS Numberl Results Flao Units Pf MDL POLL Batch Method wed Ry Notes Ammonia as N [7664-41-7]^ 0.050 J mg/L 1 0.045 0.10 OG21031 EPA 350.1 07/21/20 17:06 JAH Chloride [16887-00-6]^ 520 D mg/L 5 9.5 25 OG27020 SM 4500CIE-2011 07/27/20 12:19 JAH Nitrate as N [14797-55-8] 0.052 J mg/L 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:18 JAH Nitrate/Nitrite as N^ 0.052 J mg/L 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:18 JAH Nitrite as N [14797-65-O]^ < 0.017 mg/L 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:51 JAH Phosphorus[7723-14-0]^ < 0.025 mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:13 JAH Total Dissolved Solids^ 1100 ri 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flaa Units QE pQ Batch Method Analyzed By Notes Coliform, Fecal^ 8.6 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certfied analyte [NC 424] Analvte rCAS Numberl Results Flaa Units DF MDL Q Batch Method Analyzed Ay Notes Total Organic Carbon^ 6.5 mg/L 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA Description: SCMS Lab Sample ID.-CD11305-10 Received: 07/16/20 11:45 Matrix: Surface Water Sampled: 07/16/20 10:00 Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar,July) Sampled By:John Sherrill (Classical Chemistry Parameters ' ^ - ENCO Cary certified analyze [NC 591] Analvte rCAS Numberl Results Flag ni DF MDL Q Batch Method Analyzed ft Notes Ammonia as N [7664-41-7]^ 0.19 ni 1 0.045 0.10 OG21031 EPA 350.1 07/21/20 17:08 JAH Chloride [16887-00-6]^ 7.8 mg/L 1 1.9 5.0 OG27020 SM 4500CIE-2011 07/27/20 12:20 JAH Nitrate as N [14797-55-8] 0.11 ni 1 0.041 0.10 [CALC] EPA 353.2 07/23/20 11:21 JAH Nitrate/Nitrite as N^ 0.11 ri 1 0.041 0.10 OG22043 EPA 353.2 07/23/20 11:21 JAH Nitrite as N [14797-65-O]^ < 0.017 ri 1 0.017 0.10 OG16050 EPA 353.2 07/16/20 16:52 JAH Phosphorus[7723-14-O]^ < 0.025 mg/L 1 0.025 0.10 OG22013 EPA 365.4 07/24/20 15:14 JAH Total Dissolved Solids^ 92 mg/L 1 50 50 OG21010 SM 2540C-2011 07/21/20 15:37 DMJ Microbiological Parameters ^ - ENCO Cary cerb'fied analyte [NC 591] Analvte [CAS Numberl Results Flaa Units DF 1Q Batch Method Analyzed By Notes Coliform, Fecal^ 330 MPN/100 1 1.0 OG16039 Colilert 18 07/17/20 10:06 ZGW mL Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analvte rCAS Numberl Results Flaa Units DF MDL POL Batch Method Analyzed Notes Total Organic Carbon^ 16 ri 1 0.34 1.0 OG22028 SM 531OB-2011 07/23/20 03:47 RSA FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 of 2 �co www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch OG15050 - NO PREP Blank (OG16050-BLK1) Prepared: 07/16/2020 15:39 Analyzed: 07/16/2020 16:33 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.017 U 0.10 mg/L LCS (OG16050-BSI) Prepared: 07/16/2020 15:39 Analyzed: 07/16/2020 17:01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 99 90-110 Matrix Spike (OG36050-MS3) Prepared: 07/16/2020 15:39 Analyzed: 07/16/2020 16:35 Source: CD10203-01 Spike Source %REC RPD Anal ty a R� Flag POL ILnits Level Result %REC Limi RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 0.017 U 99 90-110 Matrix Spike (OG36050-MS2) Prepared: 07/16/2020 15:39 Analyzed: 07/16/2020 16:40 Source: CD10219-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 0.034 96 90-110 Matrix Spike Dup (OG36050-MSD3) Prepared: 07/16/2020 15:39 Analyzed: 07/16/2020 16:36 Source: CD10203-01 Spike Source %REC RPD Analyte Result Flag PQL Units Level Result %REC Limi RPD Limit Notes Nitrite as N 0.99 0.10 mg/L 1.00 0.017 U 99 90-110 0.02 10 Batch OG21010 - NO PREP Blank (OG23010-BLKI) Prepared & Analyzed: 07/21/2020 15:37 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limi RPD Limit Notes Total Dissolved Solids 50 U 50 mg/L LCS (OG23030-BS3) Prepared & Analyzed: 07/21/2020 15:37 Spike Source %REC RPD Analyte Result Flag POL Units Level Resul %REC Limits RPD Limit Notes Total Dissolved Solids 970 50 mg/L 1000 97 80-120 Duplicate (OG21010-DUPl) Prepared & Analyzed: 07/21/2020 15:37 Source: CDO9848-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 2300 100 mg/L 2400 3 20 Duplicate (OG21010-DUP2) Prepared & Analyzed: 07/21/2020 15:37 Source: CD10172-14 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 680 50 mg/L 670 2 20 Batch OG21031 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 12 Of21 ENCO www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch OG21031 - NO PREP - Continued Blank (OG21031-BLKI) Prepared: 07/21/2020 14:11 Analyzed: 07/21/2020 16:21 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L LCS (OG21031-BS3) Prepared: 07/21/2020 14:11 Analyzed: 07/21/2020 16:23 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 1.0 0.10 mg/L 1.01 102 90-110 Matrix Spike (OG21031-MSI) Prepared: 07/21/2020 14:11 Analyzed: 07/21/2020 16:26 Source: CD10705-01 Spike Source %REC RPD Analvtt Result Flag POL Units Level Result %REC Limi RPD Limit Notes Ammonia as N 0.37 0.10 mg/L 0.393 0.045 U 95 90-110 Matrix Spike (OG21031-MS2) Prepared: 07/21/2020 14:11 Analyzed: 07/21/2020 16:32 Source: CD10709-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.43 0.10 mg/L 0.393 0.091 86 90-110 QM-07 Matrix Spike Dup (OG21031-MSD1) Prepared: 07/21/2020 14:11 Analyzed: 07/21/2020 16:28 Source: CD10705-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.37 0.10 mg/L 0.393 0.045 U 95 90-110 0.08 10 Batch 0622OO4 - Same Blank (OG22004-BLK3) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 14:24 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (OG22004-BSI) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 14:25 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 1.5 0.10 mg/L 1.60 95 80-120 Matrix Spike (OG22004-MS1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 14:28 Source: CD03601-01 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Mmft Notes Phosphorus 7.3 D 0.50 mg/L 0.640 6.5 120 80-120 Matrix Spike Dup (OG22004-MSD1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 14:29 Source: CD03601-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD limit Notes Phosphorus 6.9 D 0.50 mg/L 0.640 6.5 61 80-120 5 25 QM-07 Batch OG22006 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 3 Of Z 1 (��Eo www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 0622006 - NO PREP - Continued Blank (OG22006-BLK3) Prepared: 07/22/2020 08:27 Analyzed: 07/22/2020 09:42 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.045 U 0.10 mg/L LCS (OG22006-BSI) Prepared: 07/22/2020 08:27 Analyzed: 07/22/2020 09:44 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.93 0.10 mg/L 1.01 92 90-110 Matrix Spike (OG22006-MS3) Prepared: 07/22/2020 08:27 Analyzed: 07/22/2020 09:48 Source:CD10203-01 Spike Source %REC RPD Anal Result Flag Q Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.76 0.10 mg/L 0.393 0.43 84 90-110 QM-07 Matrix Spike (OG22006-MS2) Prepared: 07/22/2020 08:27 Analyzed: 07/22/2020 09:53 Source:CD10219-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.33 0.10 mg/L 0.393 0.045 U 84 90-110 QM-07 Matrix Spike Dup (OG22006-MSD3) Prepared: 07/22/2020 08:27 Analyzed: 07/22/2020 09:49 Source:CD10203-01 Spike Source %REC RPD Analvte Result Flag PQL Units Level Result %REC Limits RPD Limit Notes Ammonia as N 0.78 0.10 mg/L 0.393 0.43 89 90-110 2 10 QM-07 Batch 0622013 - Same Blank (OG22013-BLK1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 14:59 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (OG22013-BS1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 15:00 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 1.5 0.10 mg/L 1.60 96 80-120 Matrix Spike (OG22013-MS1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 15:03 Source: CDO9851-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 4.9 D 0.50 mg/L 0.640 4.3 106 80-120 Matrix Spike Dup (OG22013-MSD1) Prepared: 07/22/2020 13:15 Analyzed: 07/24/2020 15:04 Source: CD09851-01 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 5.0 D 0.50 mg/L 0.640 4.3 110 80-120 0.5 25 Batch OG22043 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 Of 21 (��09 www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch OG22043 - NO PREP - Continued Blank (OG22043-BLK3) Prepared: 07/22/2020 16:09 Analyzed: 07/23/2020 10:43 Spike Source %REC RPD Analyte Result Flaq PQL Units Level Result %REC Limits RPD kimft Notes Nitrate/Nitrite as N 0.041 U 0.10 mg/L LCS (OG22043-BS3) Prepared: 07/22/2020 16:09 Analyzed: 07/23/2020 10:45 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD limit Notes Nitrate/Nitrite as N 1.2 0.10 mg/L 1.25 95 90-110 Matrix Spike (OG22043-MS3) Prepared: 07/22/2020 16:09 Analyzed: 07/23/2020 10:49 Source: CD10203-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 70 5.0 mg/L 25.0 48 89 90-110 QM-07 Matrix Spike (OG22043-MS2) Prepared: 07/22/2020 16:09 Analyzed: 07/23/2020 10:54 Source: CD10219-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 90 5.0 mg/L 25.0 69 81 90-110 QM-07 Matrix Spike Dup (OG22043-MSD3) Prepared: 07/22/2020 16:09 Analyzed: 07/23/2020 10:51 Source: CD10203-01 Spike Source %REC RPD Anal vte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 70 5.0 mg/L 25.0 48 87 90-110 0.8 10 QM-07 Batch OG24010 - Same Blank (OG24010-BLKI) Prepared: 07/24/2020 11:20 Analyzed: 07/29/2020 13:29 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.025 U 0.10 mg/L LCS (OG24010-BS1) Prepared: 07/24/2020 11:20 Analyzed: 07/29/2020 13:30 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 1.6 0.10 mg/L 1.60 100 80-120 Matrix Spike (OG24010-MS1) Prepared: 07/24/2020 11:20 Analyzed: 07/29/2020 13:32 Source: CD11777-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.73 0.10 mg/L 0.640 0.057 105 80-120 Matrix Spike Dup (OG24010-MSD1) Prepared: 07/24/2020 11:20 Analyzed: 07/29/2020 13:34 Source: CD11777-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Phosphorus 0.71 0.10 mg/L 0.640 0.057 101 80-120 3 25 Batch OG27020 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 21 Ceco www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch OG27O2O - NO PREP - Continued Blank (OG27020-BLK3) Prepared: 07/27/2020 10:40 Analyzed: 07/27/2020 12:07 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limft Notes Chloride 1.9 u 5.0 mg/L LCS (OG27020-BS3) Prepared: 07/27/2020 10:40 Analyzed: 07/27/2020 12:08 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Chloride 100 5.0 mg/L 100 100 80-120 Duplicate (OG27020-DUPi) Prepared: 07/27/2020 10:40 Analyzed: 07/27/2020 12:11 Source: CD10314-02 Spike Source %REC RPD Analyte Result It F� ROL nits Level Result %REC Limi RPD Limit Notes Chloride 14 5.0 mg/L 14 0.6 10 Matrix Spike (OG27020-MS3) Prepared: 07/27/2020 10:40 Analyzed: 07/27/2020 12:09 Source: CD10314-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Chloride 46 5.0 mg/L 37.5 9.8 96 80-120 Matrix Spike Dup (OG27020-MSD3) Prepared: 07/27/2020 10:40 Analyzed: 07/27/2020 12:10 Source: CD10314-01 Spike Source %REC RPD Analyte Result Flaq POL Units Level Resu t %REC Limits RPD Limit Notes Chloride 46 5.0 mg/L 37.5 9.8 96 80-120 0.04 25 Microbiological Parameters - Quality Control Batch OG16O39 - NO PREP Blank (OG36039-BLKI) Prepared: 07/16/2020 14:00 Analyzed: 07/17/2020 10:06 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Coliform, Fecal 1.0 U 1.0 MPN/100 mL Duplicate (OG16039-DUPi) Prepared: 07/16/2020 14:00 Analyzed: 07/17/2020 10:06 Source: CD10716-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Res I %REC Limits RPD Limit Notes Coliform, Fecal 1.0 1.0 MPN/100 mL 1.0 U 25 Duplicate (OG16039-DUP2) Prepared: 07/16/2020 14:00 Analyzed: 07/17/2020 10:06 Source: CD11305-07 Spike Source %REC RPD Analyte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Coliform, Fecal 1.0 1.0 MPN/100 mL 1.0 U 25 Classical Chemistry Parameters - Quality Control Batch OG22O18 - NO PREP Blank (OG22028-BLK1) Prepared: 07/22/2020 18:00 Analyzed: 07/23/2020 03:47 Spike Source %REC RPD Analyte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 Of Z 1 FNCO www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Li Batch 0622028 - NO PREP - Continued Blank (OG22028-BLK3) Continued Prepared: 07/22/2020 18:00 Analyzed: 07/23/2020 03:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limi RPD iimft Notes Total Organic Carbon 0.34 U 1.0 mg/L LCS (OG22028-BSl) Prepared: 07/22/2020 18:00 Analyzed: 07/23/2020 03:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Organic Carbon 42 1.0 mg/L 40.0 104 85-115 Matrix Spike (OG22028-MS3) Prepared: 07/22/2020 18:00 Analyzed: 07/23/2020 03:47 Source: CD11305-01 Spike Source %REC RPD Anal vte Result Flaq POL Units Level Result %REC Limits RPD kimft Notes Total Organic Carbon 42 1.0 mg/L 40.0 0.39 104 85-115 Matrix Spike Dup (OG22028-MSD1) Prepared: 07/22/2020 18:00 Analyzed: 07/23/2020 03:47 Source: CD11305-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Resul %REC Limits RPD Lima Notes Total Organic Carbon 42 1.0 mg/L 40.0 0.39 104 85-115 0.3 21 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 7 Of 21 (E�Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 Of Z 1 Organ Central Port Dr. Jack E ville, a Park Court, Suite 111 10 y. C 27511ds Industrial Gt. Orlando. FL 32824 Jadcsonvdle. FL 32216-6069 Cary. NC 27511 (407) 826-5314 Fax (407) 850-6945 j904) 296-3007 Fax (904) 296-6210 t919) 467-3090 Fax (919) 467-3515 Client Name Project Number Requested Analyses Arauco North America Inc. UN039 GW/SW MunitorinQ a Address " Project Name/Desc 0 _ 985 Corinth Road _ ` GW/SW Monitoring-TriAnnual(Mar,Juty) Q City ST2ip PO N / Billing Info 0 Moncure, NC 27559 _ 2020: Pa 4504859_1_66_ —� z ap Tel Fax Reporting Contact �va,yA V\ C1% (919) 545-5848 (919) 642-6622 Y.uwmr-ft� C f-r Sarno? ins) Na.- Atf]6al r Wwi ) I dlmg Contact ell( utlp�lWe Accounts Payable �o sampler( Sr lure Site Location r Time Zone U U H PreservaWn (See Codes) (Combine as necessary Collection Mabix Total N of item N Sample ID (I c d dentilicationl Collection Dale Time C. ornp! Grdu isee Cude31 Conlamers SMW-3 GW 5 _ X x x SMW-4 - - 1� ^ - — GW 5-- Xj_X X_.. X SMW-5 _ % _ ��� GW 5 X I X X X SMW-8 GW 5 X! X X X SMW-9 GW 5 X X X X SMW-18R --GW----5--. _X_.� _X X X SMW-19 2rj GW 5 X X -X-X------ - - - SMW-20 +-�(`� GW 5 X X X X SMW-21 GW 5 X X X X SCMS n SW 5 X! X l X X <-- Total q of Containers Page L of Requested Turnarot N_ Times 0 _ Note Hush requests suole acceptance br Cc 'y;,, � Standard I Expeditea Due -- /- Lab Workorder ,Dl 1305 ISample Comments Sample Ka Prepared By Date. -Lime -- Com rns<' pedal Reposing eyuuelTlents Rehn she 1Vy Dale,Time I �-16-2b ! 14� Received B Date/Tane uish By DazeTme ive Datc:Trme Relinquished By DawTime ; R?6erded By Date;Tme 8 Temps on Receipt l FF ConWbon u Receipt Acceptable Unacceptable Matrix GW Groundwater SO -Sod DW-Drinking Water SE-Sed rient SW -Surface Water WW-Wastewater A�AIr U-Uiher (detail in comments) Preservation: i-Ice N-tlUl N-HNU3 5-1­125U4 NU-NaUH u-timer tosiau in comments? Note: All samples submitted to ENCO Labs are in accordance with the terms and conditions fisted on the reverse of this form, unless prior written agreements exist Sample Preservation Verification ENCO Cary Work Order: CD11305 Project: GW/SW Monitoring-TriAnnual(Mar.July Client: Arauco North America, Inc. (UN039) Project #: GW/SW Monitoring Logged In: 16-Jul-20 11:58 Logged By: John C King Preservation Check Performed By: y)� Date/Time: CD11305-01 Cont Type Pres (pH) Requirement PH Checked / In Control PH Adjusted Date/Time Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y N NA Y/ N/ NA CD11305-02 Cont yP Type Pres (PH) Requirement pH Checked / In Control Date/Time PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y" N / NA Y / N NA CD11305-03 Cont yP Type Pres (pH) Requirement pH Checked / In Control Date/Time PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y / N / NA Y iiVj NA C D 11306-04 Cont T e yP Pres (pH) Requirement pH Checked / In Control Date/Time PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y / N / NA Y / N / NA CD11305-05 Cont T e yP Pres (pH) Requirement pH Checked/ In Cgt►trol DatelTime PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y`/ N / NA Y / NA C D11305-06 Cont T e yP Pres (pH) Requirement PH Checked 1 In Control Date/Time PH Adjusted Adjusted Reagent UsedJCornments A 250mLP+H2SO4 <2 Y. / N / NA I Y / -N,/ NA CD11305-07 Cont yP Type Pres (pH) Requirement pH Checked / In Control DatelTme PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y, / N / NA Y h' N ! NA CD11305-08 Cont yP Type Pres (PH) Requirement pH Checked / In Control Date/Time PH Adjusted Adiusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y i N/ NA Y (• N/ NA CD11305-09 Cont yP Type Pres (PH) Requirement pH Checked / In Control Date/Tme PH Adjusted Adjusted Reagent Used/Comments A 250mLP+H2SO4 <2 Y ',/ N / NA Y / N ; NA C:\ELMNT1Printlwko_PreservationCheck rpt Page 20 of 21 Sample Preservation Verification ENCO Cary Work Order. CD11305 Client: Arauco North America, Inc. (LIN039) Project: GW/SW Monitoring-TriAnnual(Mar,July Project #: GW/SW Monitoring Logged In: 16-Jul-20 11:58 Logged By: John C King Preservation Check Performed By: C } Date/Time: CD11305-10 Cont Type Pres (pH) pH Checked / pH Adjusted Date/Time Reagent Used/Comments Requirement In Control Adjusted A 250mLP+H2SO4 <2 ',Y / N / NA Y / ! NA Rea ent Name ID 1 2 pH Strip IDS Rea ent Name ID 3 4 Reacient Name i L: 5 6 Page 21 of 21 C.\ELMNT\Print\wko_PreservationC heck rpt