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WI0400552_Application_20200901
AECOM 919.461.1100 tel 1600 Perimeter Park Drive, Suite 400 919.461.1415 fax Morrisville, NC 27560 July 7, 2020 Mr. Michael Rogers North Carolina Department of Environmental Quality Division of Water Resources, Groundwater Protection Section Underground Injection Control Program 1636 Mail Service Center Raleigh, North Carolina 27699-1636 Subject: Application for Permit to Construct and/or Use a Well(s) for Injection Former Rental Towel Uniform/National Services Industries, Inc. Site (Cintas Corporation) 610 Woody Drive, Graham, Alamance County, North Carolina #NONCD0001655 Dear Mr. Rogers, AECOM Technical Services of North Carolina, Inc. (AECOM), on behalf of Cintas Corporation, is submitting the attached Application for Permit to Construct and/or Use a Well(s) for proposed injection activities at the former Rental Towel Uniform/National Services Industries, Inc. facility located in Graham, North Carolina (NCDEQ Site ID # NONCD0001655). Please contact Matthew Allen at (919) 500-9716 if you have any questions. Yours sincerely, Matthew Allen Project Manager Attachments: Application for Permit to Construct and/or Use a Well(s) for Injection North Carolina Department of Environmental Quality – Division of Water Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Groundwater Remediation (15A NCAC 02C .0225) Do not use this form for UIC wells Permitted by Rule (ref. 15A NCAC 02C .0217) Groundwater Remediation Application Rev. 2-17-2020 Page 1 of 9 Permit Number (to be completed by DWR for new projects): WI I. APPLICATION INFORMATION 1. Project is: [X] New [ ] Modification [ ] Renewal without modification [ ] Renewal with modification 2. If this application is being submitted for Renewal and/or Modification to an existing permit, provide: Existing permit number WI Issued Date: & Expiration Date: For all Renewals, attach an updated site map and status report including monitoring results of all injection activities to date. For Renewal without modification only, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner’s signature to indicate consent (if the applicant is not the owner). II. WELL OWNER(S)/PERMIT APPLICANT (generally the responsible party) 1. Name(s): Cintas Corporation 2. Signing Official’s Name*: Stephen Koehler Title: Chemical/Environmental Engineer * Signing Official must be in accordance with instructions in Part XII. 3. Mailing address of Permittee/Applicant: 27 Whitney Drive City: Milford State: OH Zip: 45150 4. Telephone number: 513-956-4906 Email: KoehlerS@cintas.com 5. Status (choose one): Individual X Business/Org. Federal State County Municipality III. PROPERTY OWNER(S) (if different than well owners) 1. Name(s): 2. Mailing address: City: State: Zip: 3. Telephone number: Email: IV. PROJECT CONTACT – (generally the environmental/engineering consultant). 1. Name: Matt Allen, PG Title: Project Manager 2. Company: AECOM Technical Services of North Carolina 3. Address: 1600 Perimeter Park Drive, Suite 400 4. City: Morrisville State: NC Zip: 27560 5. Telephone number: 919-500-9716 Email: matthew.allen@aecom.com Groundwater Remediation Application Rev. 2-17-2020 Page 2 of 9 V. FACILITY INFORMATION 1. Facility name: Former RTUS/NSI Site Phone No. (if available): N/A 2. Physical address: 610 Woody Drive City: Graham County: Alamance Zip: 27253 3. Geographic Coordinates: Latitude: 36 o.058711 Longitude: -79.383682 Reference Datum: NAD 83 Accuracy: +/- 1 cm Method of Collection (i.e., Google Earth, GPS, etc.): Google Earth 4. Brief description of business: Industrial uniform cleaning and laundry facility VI. INCIDENT DESCRIPTION 1. Source and date of contamination: The former Rental Towel Uniform Services (RTUS)/National Services, Inc. (NSI) has reportedly housed commercial laundering facilities since 1972. The facility was initially owned and operated by RTUS. The Site was purchased by NSI in 1991. In 1997, G&K Services, Inc. (G&K) purchased the property from NSI. Englewood Holdings Corporation is the successor to NSI. Cintas Corporation (Cintas) completed an acquisition of G&K in spring of 2017. Chlorinated solvents, primarily tetrachloroethene (PCE), were used in dry-cleaning activities on site from approximately 1972 to 1981. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbici des, etc): Chlorinated Volatile Organic Compounds – specifically tetrachloroethene and daughter products 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? [ ] Yes If yes, list maximum measured separate phase thickness: feet [X] No If no, list maximum concentration of total VOCs observed at site: 147,297 (MW-53) ppb 4. Agency managing the contamination incident: [ ] UST Section [ ] Superfund Section (including REC Program and DSCA sites) [ ] DWR Aquifer Protection Section [ ] Solid Waste Section [ ] Hazardous Waste Section [X] Other: IHSB DWM 5. Incident manager’s name: Keith Snavely Phone No.: 919-707-8355 6. Incident number or other incident mgmt. agency tracking number: NONCD0001655 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Previous or other UIC permits issued by DWR (e.g., NOIs) WI0400485 2. Other Non-Discharge or NPDES permit issued by DWR: 3. County or DEH subsurface wastewater disposal permits: 4. Hazardous waste management or other environmental permits required by state or federal law: Groundwater Remediation Application Rev. 2-17-2020 Page 3 of 9 VIII. INJECTION SUMMARY 1. List all proposed injectants/additives. NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/ground-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info if you wish to get approval for a different additive. However, please note it may take 3 months or longer. If no injectants are to be used use N/A. Onsite Eastern Barrier (8 permanent wells) Injectant: EDS-ER® Total Amt. to be injected (lbs)/event Approx. 16,800 Injectant: Sodium Bicarbonate Total Amt. to be injected (lbs)/event Approx. 15,200 Injectant: Nutrimens® Total Amt. to be injected (gal)/event Approx. 40 Injectant: KB-1® Total Amt. to be injected (liter)/event Approx. 24 Total Amt. to be injected (gal/event): 22,000 No. of separate injection events: 2 Total Amt. to be injected (gal): 22,000 Onsite Southwestern Barrier (10 permanent wells) Injectant: EDS-ER® Total Amt. to be injected (lbs)/event Approx. 21,000 Injectant: Sodium Bicarbonate Total Amt. to be injected (lbs)/event Approx. 19,000 Injectant: Nutrimens® Total Amt. to be injected (gal)/event Approx. 50 Injectant: KB-1® Total Amt. to be injected (liter)/event Approx. 30 Total Amt. to be injected (gal/event): 27,500 No. of separate injection events: 2 Total Amt. to be injected (gal): 27,500 Offsite Barrier (6 permanent wells) Injectant: EDS-ER® Total Amt. to be injected (lbs)/event Approx. 12,600 Injectant: Sodium Bicarbonate Total Amt. to be injected (lbs)/event Approx. 11,400 Injectant: Nutrimens® Total Amt. to be injected (gal)/event Approx. 30 Injectant: KB-1® Total Amt. to be injected (liter)/event Approx. 18 Total Amt. to be injected (gal/event): 16,500 No. of separate injection events: 2 Total Amt. to be injected (gal): 16,500 Source of Water (if applicable): Off-site source 2. Estimated Injection rate per well: 4 GPM 3. Estimated Injection pressure: <50 pounds/square inch (PSI) 4. Temperature at point of injection: ambient air oF 5. Injection will be via: Existing well(s)- Total No.: 0 ; Well Type (DPT, Permanent, etc.): Proposed well(s)- Total No.: 24 ; Well Type (DPT, Permanent, etc.): Permanent 6. NC Certified Well Drilling Contractor’s Name (if known): TBD NC Well Contractor Certification No.: Groundwater Remediation Application Rev. 2-17-2020 Page 4 of 9 7. Date to be constructed if proposed: 2020 (attach well construction records [GW-1s] for existing injection wells) 8. Screened interval/Injection interval of injection wells: Depth from 10 to 40 feet below land surface (BLS)(if multiple intervals, indicate shallowest to deepest depth) 9. Well casing (leave blank if Geoprobes®): Type (PVC, stainless steel, other): PVC Casing depth: 0 to 30 ft. BLS Type (PVC, stainless steel, other): PVC Casing depth: 0 to 35 ft. BLS Type (PVC, stainless steel, other): PVC Casing depth: 0 to 40 ft. BLS 10. Grout (leave blank if Geoprobes): Type (cement, bentonite, other): cement and bentonite Grout depth: 0 to 8 ft. BLS Type (cement, bentonite, other): cement and bentonite Grout depth: 0 to 13 ft. BLS Type (cement, bentonite, other): cement and bentonite Grout depth: 0 to 18 ft. BLS IX. ATTACHMENTS – provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE – Per 15A NCAC 02C .0225(f)(3), specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. 2. HYDROGEOLOGIC EVALUATION – Per 15A NCAC 02C .0225(f)(4), provide a hydrogeologic evaluation of the injection zone that includes all of the following: (A) Regional and local geology and hydrology; (B) Changes in lithology underlying the facility; (C) Depth to bedrock; (D) Depth to the mean seasonal high water table; (E) Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site-specific material, including a description of the test(s) used to determine these parameters; (F) Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; (G) Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells; and (H) For systems re-injecting treated on-site contaminated groundwater only- evaluation of infiltration galleries or injection wells. Groundwater Remediation Application Rev. 2-17-2020 Page 5 of 9 3. INJECTANT INFORMATION – Per 15A NCAC 02C .0225(f)(6), provide information on each injectant as indicated below: (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant’s potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. 4. INJECTION PROCEDURE – Per 15A NCAC 02C .0225(f)(7), submit a table with a detailed description of the proposed injection procedure that includes the following: (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. 5. FRACTURING PLAN (if applicable) – Per 15A NCAC 02C .0225(f)(9), submit a detailed description of the fracturing plan that includes the following: (A) Material Safety Data Sheets of fracturing media including information on any proppants used; (B) a map of fracturing well locations relative to the known extent of groundwater contaminatio n plus all buildings, wells, septic systems, underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes, joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS – Per 15A NCAC 02C .0225(f)(10), submit the following information in tabular or schematic form as appropriate for each item: (A) number and depth of injection wells; (B) number and depth of borings if using multi-level or “nested” well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary “direct push” points; and (H) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN – Per 15A NCAC 02C .0225(f)(11), submit a monitoring plan that includes the following: (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; (B) other parameters that may serve to indicate the progress of the intended reactions; (C) a list of existing and proposed monitoring wells to be used; and Groundwater Remediation Application Rev. 2-17-2020 Page 6 of 9 (D) a sampling schedule to monitor the proposed injection. Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule, pace of the anticipated reactions, and rate of transport of the injectants and contaminants. 8. WELL DATA TABULATION – Per 15A NCAC 02C .0225(f)(12), provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. 9. MAPS AND CROSS-SECTIONS – Per 15A NCAC 02C .0225(f)(13), provide scaled, site-specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5’ topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; (D) potentiometric surface map(s) that show the direction of groundwater movement, existing and proposed wells; (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells; and (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. X. UIC SYSTEMS RE-INJECTING TREATED ON-SITE CONTAMINATED GROUNDWATER ONLY 1. FEES – Per 15A NCAC 02C .0225(m), submit/attach fees for new permits or modifications (refer to fee schedule at https://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/non-discharge-groundwater-remediation 2. SOILS EVALUATION - Per 15A NCAC 02C .0225(f)(2), for systems with proposed discharge within seven feet of land surface and above the seasonal high water table, a soil evaluation of the disposal site shall be provided to the Division by the applicant. If required by G.S. 89F, a soil scientist shall submit this evaluation. This evaluation shall be presented in a report that includes the following information: (A) Field description of soil profile. Based on examinations of excavation pits or auger borings, the following parameters shall be described by individual horizons to a depth of seven feet below land surface or to bedrock: thickness of the horizon; texture; color and other diagnostic features; structure; internal drainage; depth, thickness, and type of restrictive horizons; pH; cation exchange capacity; and presence or absence of evidence of any seasonal high water table. Applicants shall dig pits when necessary for evaluation of the soils at the site. (B) Recommendations concerning annual and instantaneous loading rates of liquids, solids, other wastewater constituents and amendments. Annual hydraulic loading rates shall be based on in-situ measurement of saturated hydraulic conductivity in the most restrictive horizon. 3. ENGINEERING PLANNING DOCUMENTS – Per 15A NCAC 02C .0225(f)(8), the following documents shall be provided to the Division by the applicant (Note: if required by G.S. 89C, a professional engineer shall prepare these documents): (A) engineering plans for the entire system, including treatment, storage, application, and disposal facilities and equipment, except those previously permitted unless they are directly tied into the new units or are critical to the understanding of the complete process; (B) specifications describing materials to be used, methods of construction, and means for ensuring quality and integrity of the entire groundwater remediation system; (C) plans that include construction details of recovery, injection, and monitoring wells and infiltration galleries; Groundwater Remediation Application Rev. 2-17-2020 Page 7 of 9 (D) operating plans that include: (i) the operating schedule including any periodic shut-down times; (ii) required maintenance activities for all structural and mechanical elements; (iii) a list of all consumable and waste materials with their intended source and disposal locations; (iv) restrictions on access to the site and equipment; (v) provisions to ensure the quality of the treated effluent and hydraulic control of the system at all times when any portion of the system ceases to function, such as standby power capability, complete system-off status, or duplicity of system components; and (E) Completed, signed, and sealed Professional Engineer’s Certification for new permit applications (form attached). Groundwater Remediation Application Rev. 2-17-2020 Page 8 of 9 XII. CERTIFICATION (to be signed as required below or by that person’s authorized agent*) NCAC 15A 02C .0211(e) requires that all permit applications shall be signed as follows: 1. for a corporation: by a responsible corporate officer 2. for a partnership or sole proprietorship: by a general partner or the proprietor, respectively 3. for a municipality or a state, federal, or other public agency: by either a principal executive officer or ranking publicly elected official 4. for all others: by the well owner. *If an authorized agent is signing on behalf of the applicant, then supply a letter signed by the applicant that names and authorizes their agent. “I hereby certify under penalty of law that I have personally examined and am familiar with the information submitted in this document and all attachments therein, and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate, and complete. I am aware that there are penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well(s) and all related appurtenances in accordance with the approved specifications and conditions of the Permit.” Typed or Printed Name and Title: Signature: Date: XIII. CONSENT OF PROPERTY OWNER (if the property is not owned by the permit applicant) “Owner” means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. “As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200).” Typed or Printed Name and Title: Signature: Date: Submit TWO hard copies of the completed application package with an electronic version in CD or USB Flash Drive to: DIVISION OF WATER RESOURCES – UIC PROGRAM 1636 MAIL SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1636 TELEPHONE NUMBER: (919) 707-9000 Stephen Koehler, Chemical/Environmental Engineer 7/7/2020 Stephen Koehler, Chemical/Environmental Engineer 7/7/2020 Groundwater Remediation Application Rev. 2-17-2020 Page 9 of 9 Professional Engineer's Certification (for new permit application for UIC systems re-injecting treated on-site contaminated groundwater only): Permit No.: WI_____________ Typed or Printed Name of Professional Engineer: __________________________________________________________ License Number: ____________ Name of Engineering Firm (if applicable): ________________________________________ _____________________ Mailing Address: _____________________________________________________________________________________ City: ___________________________________ State: _____________ Zip: __________________ Office Number: (_______) ______________________ Mobile Number: (_______)_______________ Email Address: _______________________ I, _________________________________________ , attest that this application for has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Seal, Signature, and Date: Cintas Corporation Milford, OH Application for Underground Injection Control Permit – Attachments Former Rental Towel Uniform/National Services Industries, Inc. Site 610 Woody Drive, Graham, Alamance County, North Carolina IHSB#NONCD0001655 60625953 June 2020 Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM i Quality information Prepared by Prepared by Reviewed by Elizabeth Maurer, PG Staff Geologist Matt Allen, PG Project Manager Matt Zenker, PE Senior Engineer Prepared for: Cintas Corporation Milford, Ohio Prepared by: AECOM 1600 Perimeter Park, Suite 400 Morrisville, North Carolina 27560 USA aecom.com Copyright © 2019 by AECOM All rights reserved. No part of this copyrighted work may be reproduced, distributed, or transmitted in any form or by any means without the prior written permission of AECOM. Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM ii Table of Contents 1. Injection Zone .............................................................................................................................................. 5 2. Hydrogeologic Evaluation ............................................................................................................................. 5 2.1 Regional Geology and Hydrogeology ................................................................................................. 5 2.2 Site Geology ..................................................................................................................................... 5 2.3 Site Hydrogeology ............................................................................................................................. 6 2.3.1 Aquifer Parameters ........................................................................................................................... 6 3. Injectant Information ..................................................................................................................................... 6 3.1 Onsite Downgradient Injection Barriers .............................................................................................. 6 3.2 Offsite Downgradient Injection Barrier ................................................................................................ 7 3.3 Bioaugmentation ............................................................................................................................... 8 4. Injection Procedure ...................................................................................................................................... 8 5. Well Construction Details.............................................................................................................................. 8 6. Monitoring Plan ............................................................................................................................................ 8 7. Well Data Tabulation .................................................................................................................................... 9 8. Maps and Cross Sections ............................................................................................................................. 9 9. References .................................................................................................................................................. 9 Appendices Appendix A Proposed Well Construction Diagrams Appendix B Material Safety Data Sheets Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM iii Tables Table 1. Proposed Injection Intervals Table 2. Groundwater Elevation Data Table 3. Summary of Proposed Injection Quantities Table 4. Proposed Full Scale Enhanced Reductive Dechlorination Implementation Schedule Table 5. Existing Well Construction Details Figures Figure 1. Site Location Map Figure 2. Site Plan with Proposed Injection Well Locations Figure 3. PCE Results Map – Shallow Wells (February 2020) Figure 4. TCE Results Map – Shallow Wells (February 2020) Figure 5. Cross Section Location Map A-A’ Figure 6. Cross Section A-A’ Figure 7. Cross Section B-B’ Figure 8. Groundwater Potentiometric Map: Shallow Wells (February 2020) Figure 9. Groundwater Potentiometric Map: Deep Wells (February 2020) Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM iv Acronyms bgs below ground surface DHC Dehalococcoides ethenogenes bacteria EDS-ER® Electron Donor Solution-Extended Release® ERD enhanced reductive dechlorination ft/day foot per day K hydraulic conductivity IBC intermediate bulk container NSI National Services Industries, Inc. PCE tetrachloroethene PVC polyvinyl chloride PWR partially weathered rock ROI radius of influence RTUS Rental Towel Uniform Services Site Former Rental Towel Uniform/National Services Industries, Inc. facility located at 610 Woody Drive, Graham, Alamance County, North Carolina SVE soil vapor extraction TCE trichloroethene µg/L micrograms per liter Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM 5 1. Injection Zone The Former Rental Towel Uniform Services (RTUS)/National Services Industries, Inc. (NSI) facility (the Site) is located at 610 Woody Drive, Graham, Alamance County, North Carolina (Figure 1). The proposed enhanced reductive dechlorination (ERD) injection will be completed in accordance with Title 15A North Carolina Administrative Code 02C .0225. The proposed injection locations are shown in Figure 2. Injections will be completed at three downgradient barriers, including two onsite barriers and one off-site barrier each completed in saprolite/partially weathered rock (PWR). Injections will occur in the barriers via permanent wells. The onsite eastern barrier will include two 150-foot rows of permanent injection wells, the onsite southwestern barrier will include two 200-foot rows of permanent injection wells, and the offsite barrier will include two 100-foot rows of permanent injection wells. Injections into the permanent wells will target a 20-foot interval in the shallow aquifer at a general depth of 20-40 feet below ground surface (bgs). Figures 3 and 4 show the proposed injection locations with February 2020 tetrachloroethene (PCE) and trichloroethene (TCE) data for shallow wells, respectively. A cross section location map is provided in Figure 5. Figure 6 presents a hydrogeologic cross-section that illustrates the interpreted water table equipotential lines and PCE isoconcentrations at the Site with proposed eastern barrier injection locations. Table 1 summarizes proposed injection intervals and well construction details, and Appendix A includes well construction diagrams for the proposed permanent injection and monitoring wells. 2. Hydrogeologic Evaluation 2.1 Regional Geology and Hydrogeology The Site is located in the Piedmont physiographic province. Both the regional and local landscape of the area is characterized by broad, gently rolling uplands and moderate to steep slopes common to the Piedmont. Geologically, the Site is located in the Carolina terrane of North Carolina (Brown, 1985). Bedrock in the area is described as foliated to massive metamorphosed gabbro and diorite, and mafic metavolcanics (NCGS, 1985). Bedrock is typically highly deformed with multiple fracture and foliation planes, and granitic intrusions are common. Rocks of these compositions weather to form several distinct lithologic zones. Overlying the competent bedrock are unconsolidated, granular and porous materials (regolith) that may consist of alluvial deposits, soils and residual material formed from in situ physical and chemical weathering of the parent bedrock. The portion of the regolith that is derived from weathered rock, commonly referred to as saprolite, retains much of the relic fabric, texture, and structures o f the parent rock (Heath, 1980). Saprolite represents the most extreme weathered condition of the parent bedrock from which it is derived. A transitional zone of PWR is typically found between the saprolite zone and the lower competent bedrock. PWR is typically friable bedrock that retains the parent rock structure, but it has undergone less weathering than saprolite. The transitional zone PWR is often highly fractured and permeable and contains fragments of unweathered rock. Distinct zones of PWR are more frequent over metamorphosed bedrock than in massive homogenous igneous rocks. Bedrock in this region typically has decreasing fracture density with depth (Heath, 1989). Groundwater aquifer systems in this part of the Piedmont region correspond with either unconsolidated porous media or fractured, crystalline bedrock. The porous saprolite media typically represents the unconfined or “water table” hydrostratigraphic unit of the regional aquifer. Saprolite and PWR act as a storage reservoir for groundwater that feeds the underlying fractured bedrock hydrostratigraphic unit. PWR and bedrock units can exhibit unconfined, semi-confined, or even confined hydraulic behavior. Hydraulic conductivity is typically higher in PWR relative to the overlying saprolite and the bedrock below. Most water supply wells in this region tap the fractured bedrock unit. 2.2 Site Geology Surface soils in some areas of the Site consist of a 1- to 5-feet thick layer of reddish-brown-tan clay to clayey sand overburden. The overburden is underlain by a 20- to 30-feet thick saprolite layer that consists predominantly of silty- sand but varies from silty clay to coarse-grained sand in certain areas of the Site. The saprolite layer is interbedded with and underlain by a PWR layer. The PWR layer has an average thickness of 5- to 10-feet and is underlain by fractured metamorphosed bedrock. PWR and bedrock are locally interlayered. Bedrock onsite is described as black Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM 6 and white meta-volcanic rock. The bedrock surface mimics land surface topography and dips to the east and southeast. Depth to bedrock ranges from 21 to 42 feet bgs onsite and decreases to approximately 10 feet bgs east of Town Branch Creek. A cross section location map and cross sections with subsurface lithology are provided in Figures 5 through 7. 2.3 Site Hydrogeology In February 2020, onsite groundwater (within the Cintas property boundary) was encountered at depths ranging from 5.75 to 18.60 feet bgs. Offsite, depth to groundwater ranges from 3.77 to 23.60 feet bgs. Depth to water measurements and groundwater elevations are summarized in Table 2. Potentiometric values and equipotential contours for groundwater in the shallow and deep hydrogeologic units are presented in Figures 8 and 9, respectively. Figure 6 presents a hydrogeologic cross-sections that illustrates the interpreted water table for the eastern portion of the Site. Potentiometric data indicate that the Site is located on a groundwater divide with groundwater in the shallow hydrostratigraphic unit flowing to the south, southeast, and east. Similar to the shallow groundwater flow, groundwater in the bedrock aquifer is flowing to the south, southeast, and east. Groundwater flow patterns indicate that groundwater in both hydrostratigraphic units flows towards the nearest surface water body. The site is situated between Town Branch Creek, a tributary of the Haw River, to the east and Country Home Branch Creek, a tributary of Town Branch Creek, to the west. Additionally, a southeast-northwest oriented unnamed tributary of Town Branch Creek exists to the southeast of the Site. 2.3.1 Aquifer Parameters Pneumatic slug tests were performed on two deep source area monitoring wells and traditional physical slug tests were performed on two shallow source area monitoring wells. Details of aquifer test methods and results are presented in the Source Area Investigation Report (Geosyntec, 2016). The hydraulic conductivity (K) for the water bearing zone (15- 35 feet) is variable, with estimates ranging from 0.02 to 0.15 foot per day (ft/day). Based on plume length, K values are likely closer to 0.15 ft/d. These ranges are typical for silt. 3. Injectant Information An ERD pilot test was performed at the Site in 2018 using a dilute Electron Donor Solution-Extended Release® (EDS-ER®)/sodium bicarbonate/Nutrimens® solution. These materials were used with success during the pilot test and no problems were identified following injection. Each proposed injectant is included on the NCDEQ list of approved injectants (NCDEQ, 2017). The same materials will be used during the proposed full-scale barrier injections. 3.1 Onsite Downgradient Injection Barriers ERD injections will be administered in two onsite downgradient areas of the plume. A dilute (EDS-ER®/sodium bicarbonate/Nutrimens® solution will be injected along the eastern and southwestern property lines, near EW-6 and MW-11, respectively. To administer injections in the eastern barrier, eight permanent wells spaced approximately 50 feet apart would be installed along two 150-foot rows, coincident with the 700 micrograms per liter (µg/L) (1,000 times the PCE remedial goal [0.7 µg/L]) PCE groundwater contour. To administer injections in the southwestern barrier, ten permanent wells spaced approximately 50 feet apart would be installed along two 200-foot rows, coincident with the 700 µg/L PCE groundwater contour. Injections in the onsite barriers would target a 20-foot interval from approximately 10 to 30 feet bgs in the eastern barrier and 15 to 35 feet bgs in the southwestern barrier. Injection wells will be installed on top of bedrock and screened in saprolite/PWR. The proposed onsite injection barrier locations are shown in Figure 2, and proposed injection intervals are summarized in Table 1. It is proposed that 22,000 gallons of a dilute EDS-ER®/sodium bicarbonate/Nutrimens® solution be injected into the eastern barrier and 27,500 gallons of a dilute EDS-ER®/sodium bicarbonate/Nutrimens® solution be injected into the southwestern barrier. The total injection volume assumes a radius of influence (ROI) of 15 feet and a pore volume replacement of 24 percent of the effective pore volume. The ROI is assumed based on the pilot study injection performed at the site, during which changes in field parameters were observed in a monitoring well 10 feet Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM 7 downgradient of the injection well and similar, but less significant, changes were observed in a monitoring well 20 feet downgradient. Approximately 16,800 pounds of EDS-ER®, 15,200 pounds of sodium bicarbonate, and 40 gallons of Nutrimens® will be injected into the onsite eastern barrier. Approximately 21,000 pounds of EDS-ER®, 19,000 pounds of sodium bicarbonate, and 50 gallons of Nutrimens® will be injected into the onsite southwestern barrier. Injection make-up water will be derived from an offsite fire hydrant owned by the City of Graham. EDS-ER® will be injected to stimulate the formation of anaerobic conditions and provide an electron donor for dehalorespiring bacteria. Sodium bicarbonate will be added as a neutralizing agent to limit decreases in the groundwater pH during biodegradation of the carbon substrate and Nutrimens®, a reduced carbon fermentation product, contains required cofactors utilized by dehalorespiring bacteria. The injection amendments will be mixed above-ground in a batch process prior to subsurface delivery. Injection make-up water will be delivered to the Site in a clean 4,000 gallon capacity tanker truck. Intermediate bulk container (IBC) totes (300-gallon) will be connected to the tanker truck and the EDS-ER® and sodium bicarbonate will be mixed in the IBC totes with water from the truck. Small batches will be mixed in the IBC tote and transferred to the tanker truck. Once the EDS-ER® and sodium bicarbonate has been transferred to the tanker truck, the solution will be recirculated within the tanker truck during the injection to keep the solution mixed. Once mixed, the solution will be injected into the proposed permanent injection wells using a pneumatic double diaphragm pump. Proposed injection quantities are summarized in Table 3. Materials safety data sheets for the injection amendments are included as Appendix B. 3.2 Offsite Downgradient Injection Barrier ERD injections will be administered in one offsite downgradient area of the plume. A dilute EDS-ER®/sodium bicarbonate/Nutrimens® solution will be injected to the east of the Site, near MW-32. To administer injections in the offsite barrier, six permanent wells spaced approximately 50 feet apart would be installed along two 100-foot rows, coincident with the 700 µg/L PCE groundwater contour. Injections in the offsite barrier would target a 20-foot interval from approximately 20 to 40 feet bgs. Injection wells will be installed on top of bedrock and screened in saprolite/PWR. The proposed offsite injection barrier location is shown in Figure 2, and proposed injection intervals are summarized in Table 1. It is proposed that 16,500 gallons of a dilute EDS-ER®/sodium bicarbonate/Nutrimens® solution be injected into the offsite barrier. The total injection volume assumes an ROI of 15 feet and a pore volume replacement of 24 percent of the effective pore volume. The ROI is assumed based on the pilot study injection performed at the site, during which changes in field parameters were observed in a monitoring well 10 feet downgradient of the injection well and similar, but less significant, changes were observed in a monitoring well 20 feet downgradient. Approximately 12,600 pounds of EDS-ER®, 11,400 pounds of sodium bicarbonate, and 30 gallons of Nutrimens® will be injected. Injection make-up water will be derived from an offsite fire hydrant owned by the City of Graham. EDS-ER® will be injected to stimulate the formation of anaerobic conditions and provide an electron donor for dehalorespiring bacteria. Sodium bicarbonate will be added as a neutralizing agent to limit decreases in the groundwater pH during biodegradation of the carbon substrate and Nutrimens®, a reduced carbon fermentation product, contains required cofactors utilized by dehalorespiring bacteria. The injection amendments will be mixed above-ground in a batch process prior to subsurface delivery. Injection make-up water was delivered to the Site in a clean 4,000 gallon capacity tanker truck. IBC totes (300-gallon) will be connected to the tanker truck and the EDS-ER® and sodium bicarbonate will be mixed in the IBC totes with water from the truck. Small batches will be mixed in the IBC tote and transferred to the tanker truck. Once the EDS-ER® and sodium bicarbonate has been transferred to the tanker truck, the solution will be recirculated within the tanker truck during the injection to keep the solution mixed. Once mixed, the solution will be injected into the proposed permanent injection wells using a pneumatic double diaphragm pump. Proposed injection quantities are summarized in Table 3. Materials safety data sheets for the injection amendments are included as Appendix B. Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM 8 3.3 Bioaugmentation Bioaugmentation will be completed using the KB-1® bioaugmentation culture in each of the permanent injection wells. The culture will contain an enriched dechlorinating culture, including Dehalococcoides ethenogenes bacteria (DHC), capable of complete dechlorination of PCE and its daughter products. Groundwater data collected prior to the pilot injection at the Site indicates that native dechlorinating cultures, especially DHC, were limited in some aquifer zones. Therefore, bioaugmentation will be used to enhance the natural population of dechlorinating microbes in the ERD treatment areas. Bioaugmentation injections will be performed at each of the proposed permanent barrier injection wells. Following the ERD injection, and when optimal anaerobic conditions develop for bioaugmentation in the injection areas, each location will receive 3 liters of bioaugmentation culture KB-1®. Prior to injecting the culture, 2 pounds of KB-1® primer will be injected at each well to further develop anaerobic conditions within the water and limit inactivation of the KB-1® culture, which is highly sensitive to aerobic conditions. The bioaugmentation solution will be injected using a double diaphragm pump. 4. Injection Procedure The proposed permanent injection wells (described in Section 5) will be used to facilitate the proposed injections. The proposed injection activities are estimated to take up to 40 days to complete, following well installation and development. Injection rates are expected to range from approximately 1 to 5 gallons per minute via permanent well and double diaphragm pump. Injection pressures are expected to be less than 50 pounds per square inch (psi) at injection wells. However, the injection rate, amount and pressure will vary depending on field conditions. 5. Well Construction Details The full-scale ERD field activities will include injection via permanent wells at two onsite barriers immediately downgradient of the source area, and injection via permanent wells at one off-site barrier approximately 900 feet downgradient of the source area. Proposed injection wells are shown on Figure 2, and proposed injection intervals are summarized in Table 1. Eight proposed permanent injection wells (IW-1 through IW-8) and ten proposed permanent injection wells (IW-9 through IW-18) will be installed to complete the onsite barriers to the east and southwest, respectively. Six proposed permanent injection wells (IW-19 through IW-24) will be installed to complete the off-site barrier to the east. Eighteen wells will be installed using a combination of hollow stem auger (HSA) and air rotary techniques, and six wells will be installed using Rotosonic drilling techniques. Wells will be spaced approximately 50 feet apart and constructed of schedule 40 polyvinyl chloride (PVC) with 20-foot 0.010-inch screen. Injection wells will be installed on top of bedrock, and screened in saprolite/PWR. Proposed well construction diagrams are presented in Appendix A. To evaluate downgradient injection performance, two shallow performance monitoring wells (PMW-4 and PMW-5) will be installed at similar depths and screened intervals as the injection points/wells. The performance monitoring wells will be installed using a combination of HSA and air rotary techniques. Performance monitoring wells will be completed as 2-inch PVC with 10 feet of 0.010-inch well screen. Proposed well construction diagrams are provided in Appendix A. Prior to performing any invasive work, utilities will be marked by a private utility locator and surrounding public utilities will be marked by a public utility locating service via 811 ticket. Additionally, each location will be pre-cleared using a stainless-steel hand auger to a depth of at least 5 feet bgs. AECOM will complete and submit the necessary documents to obtain access to install off-site injection and monitoring wells. Solid and liquid investigative derived waste will be placed in drums, sampled, and properly manifested and transported off-site for disposal. 6. Monitoring Plan Prior to injection, new injection wells, and existing and new monitoring wells will be purged and sampled to establish baseline conditions. The sampling parameters to be analyzed during the baseline sampling event and post-injection Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM 9 sampling will follow the tentative schedule/parameter list presented in Table 4. Proposed injection well construction details are summarized in Table 1 and existing well construction details are summarized in Table 5. Sampling frequency and parameters may be modified during the injection performance monitoring, based on interpretation of the results. 7. Well Data Tabulation See Table 5 for existing well construction details and Table 1 for proposed injection wells and DPT locations details. 8. Maps and Cross Sections See Figures 1-9. 9. References Brown, P.M., 1985. Geologic Map of North Carolina. Prepared by NC Department of Natural Resources and Community Development, Division of Land Resources. Geosyntec, 2016b. Source Area Investigation Report: Former RTUS/NSI Site. Geosyntec Consultants of NC, June 2016. Heath, 1980. Basic Elements of Groundwater Hydrology with Reference Conditions in North Carolina. Ralph C. Heath, 1980. Heath, Ralph C., 1989. The Piedmont Ground-Water System. Presented in Ground Water in the Piedmont: Proceedings of a Conference on Ground Water in the Piedmont of the Eastern United States. October 16- 18, 1989. Published by Clemson University, Clemson, South Carolina. NCDEQ, 2017. Additives and Tracers Approved by NC DHHA to Inject into Groundwater. May 2017. Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM Tables Table 1 Proposed Injection and Monitoring Well Construction Details Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well ID Well Status Install Date Well Type Well Construction Well Install Method Well Diameter (inches) Total Well Depth (ft bgs) IW-1 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-2 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-3 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-4 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-5 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-6 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-7 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-8 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-9 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-10 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-11 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-12 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-13 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-14 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-15 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-16 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-17 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-18 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-19 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-20 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-21 Proposed NE Injection - Permanent PVC Rotosonic 2 20 -40 40 IW-22 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-23 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 IW-24 Proposed NE Injection - Permanent PVC HSA/AR 2 20 -40 40 PMW-5 Proposed NE Monitoring - Permanent PVC HSA/AR 2 20 -40 40 PMW-6 Proposed NE Monitoring - Permanent PVC HSA/AR 2 20 -40 40 Notes ARH - Air Rotary/Air Hammer DPT - Direct Push Technology ft bgs - feet below ground surface ft bgs - feet below ground surface ft msl - feet mean sea level HSA - Hollow Stem Auger IP - Injection Point IW - Injection Well MR - Mud Rotary NA - Not Applicable NE - Not Established NS - Not Surveyed PVC - Polyvinyl Chloride SS - Stainless Steel Total well depths for proposed wells are estimated and subject to change during installation. Screened Interval (ft bgs) AECOM Page 1 of 1 Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) August 2013 7.87 - July 2017 11.1 - April 2018 Destroyed August 2013 16.95 - July 2017 19.6 - April 2018 18.56 - October 2018 18.44 - April 2019 14.31 - February 2020 17.12 - August 2013 15.35 570.29 July 2017 18.2 567.44 April 2018 Destroyed August 2013 14.78 570.63 July 2017 17.6 567.81 April 2018 16.96 568.45 October 2018 16.46 568.95 April 2019 12.50 572.91 February 2020 15.52 569.89 MW-172 585.36 NM November 2014 24.97 560.39 November 2014 26.10 558.47 April 2018 25.23 559.34 October 2018 24.52 560.05 April 2019 21.10 563.47 February 2020 23.60 560.97 August 2013 10.08 569.93 July 2017 13.1 566.91 April 2018 11.66 568.35 October 2018 11.76 568.25 April 2019 8.00 572.01 February 2020 10.32 569.69 August 2013 15.6 555.91 April 2019 Dry -- February 2020 Dry -- MW-22 583.71 32.73 July 2017 25.38 558.33 November 2014 15.70 566.50 July 2017 15 567.20 April 2018 14.55 567.65 October 2018 14.05 568.15 April 2019 10.00 572.20 February 2020 13.60 568.60 November 2014 24.37 559.23 July 2017 23.6 560.00 April 2018 23.35 560.25 October 2018 22.80 560.80 April 2019 19.26 564.34 February 2020 22.75 560.85 MW-3 NA 24.15 MW-8 NA 32.23 MW-18 584.57 33.21 MW-20 580.01 57.61 MW-10 585.64 34.68 MW-11 585.41 46.32 MW-24 583.60 37.38 MW-213 571.51 NM MW-23 582.20 29.70 Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) August 2013 19.31 572.91 November 2014 22.77 569.45 July 2017 21.85 570.37 April 2018 21.03 571.19 October 2018 19.50 572.72 April 2019 17.25 574.97 February 2020 18.60 573.62 August 2013 17.86 574.17 November 2014 21.91 570.12 July 2017 21 571.03 April 2018 20.31 571.72 October 2018 20.45 571.58 April 2019 15.80 576.23 February 2020 18.20 573.83 August 2013 12.99 555.63 July 2017 15.3 553.32 April 2018 14.71 553.91 October 2018 15.08 553.54 April 2019 10.90 557.72 February 2020 14.10 554.52 August 2013 14.06 565.16 November 2014 18.21 561.01 July 2017 16.4 562.82 April 2018 15.99 563.23 October 2018 14.60 564.62 April 2019 11.10 568.12 February 2020 12.80 566.42 August 2013 16.99 573.12 November 2014 20.96 569.15 July 2017 20 570.11 April 2018 19.37 570.74 October 2018 18.87 571.24 April 2019 14.68 575.43 February 2020 17.50 572.61 November 2014 19.72 530.70 July 2017 16.6 533.82 April 2018 15.69 534.73 October 2018 16.14 534.28 April 2019 11.85 538.57 February 2020 14.40 536.02 April 2018 13.04 569.28 October 2018 12.55 569.77 April 2019 NG -- February 2020 NG -- MW-25 592.22 37.60 MW-28 579.22 33.30 MW-30 590.11 43.94 MW-26 592.03 43.00 MW-27 568.62 34.55 MW-32 550.42 41.42 MW-34 582.32 38.46 Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) November 2014 7.31 575.66 July 2017 7.65 575.32 April 2018 4.72 578.25 October 2018 6.07 576.90 April 2019 4.95 578.02 February 2020 3.77 579.20 July 2017 11.8 568.99 April 2018 8.82 571.97 October 2018 8.45 572.34 April 2019 6.00 574.79 February 2020 7.09 573.70 August 2013 10.65 572.15 November 2014 14.04 568.76 July 2017 12.65 570.15 April 2018 11.61 571.19 October 2018 11.25 571.55 April 2019 8.85 573.95 February 2020 10.06 572.74 November 2014 25.45 543.95 July 2017 24.5 544.90 April 2018 23.05 546.35 October 2018 22.85 546.55 April 2019 14.80 554.60 February 2020 19.40 550.00 November 2014 27.10 542.42 July 2017 23.31 546.21 April 2018 23.88 545.64 October 2018 23.11 546.41 April 2019 15.30 554.22 February 2020 19.00 550.52 November 2014 7.69 508.90 July 2017 7.52 509.07 April 2018 6.97 509.62 October 2018 7.25 509.34 April 2019 7.10 509.49 February 2020 7.00 509.59 November 2014 7.60 508.80 July 2017 7.6 508.80 April 2018 6.56 509.84 October 2018 7.25 509.15 April 2019 6.82 509.58 February 2020 6.60 509.80 MW-354 582.97 31.20 MW-36 580.79 32.56 MW-39 569.52 41.40 MW-40 516.59 14.79 MW-37 582.80 43.90 MW-38 569.40 26.71 MW-41 516.40 29.19 Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) November 2014 24.03 545.42 July 2017 22 547.45 April 2018 22.69 546.76 October 2018 23.93 545.52 April 2019 25.80 543.65 February 2020 Dry -- November 2014 14.32 567.02 July 2017 14.02 567.32 April 2018 12.6 568.74 October 2018 13.33 568.01 April 2019 11.70 569.64 February 2020 11.81 569.53 November 2014 24.13 546.51 July 2017 23.2 547.44 April 2018 22.21 548.43 October 2018 19.64 551.00 April 2019 12.90 557.74 February 2020 18.10 552.54 November 2014 23.93 546.32 July 2017 22.95 547.30 April 2018 22.15 548.10 October 2018 19.45 550.80 April 2019 12.65 557.60 February 2020 19.50 550.75 November 2014 10.13 504.27 July 2017 10 504.40 April 2018 9.61 504.79 October 2018 9.54 504.86 April 2019 9.45 504.95 February 2020 9.35 505.05 November 2014 18.53 560.78 July 2017 17.4 561.91 April 2018 15.03 564.28 October 2018 15.58 563.73 April 2019 12.20 567.11 February 2020 13.85 565.46 July 2017 18.2 553.31 April 2018 18.81 552.70 October 2018 17.88 553.63 April 2019 15.38 556.13 February 2020 16.75 554.76 July 2017 18.95 552.56 October 2018 18.62 552.89 April 2019 15.77 555.74 February 2020 16.90 554.61 MW-45 581.34 29.27 MW-46 570.64 35.35 MW-43 569.45 27.72 MW-50 579.31 58.12 MW-51 571.51 32.55 MW-47 570.25 50.97 MW-49 514.40 26.22 MW-52 571.51 31.40 Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) July 2017 20.17 551.34 April 2018 18.82 552.69 October 2018 17.92 553.59 April 2019 16.02 555.49 February 2020 18.00 553.51 July 2017 19.21 552.30 October 2018 17.85 553.66 April 2019 15.98 555.53 February 2020 17.40 554.11 October 2018 8.77 -- April 2019 4.90 -- February 2020 5.75 -- MW-56 NS 40.49 September 2018 17.77 -- MW-57 NS 39.23 September 2018 17.64 -- NS September 2018 19.22 -- April 2019 14.90 -- NS February 2020 16.50 -- MW-59 NS 37.79 September 2018 19.52 -- NS September 2018 19.00 -- April 2019 15.40 -- NS February 2020 16.70 -- NS September 2018 17.34 -- April 2019 14.95 -- NS February 2020 16.35 -- MW-62 NS 40.00 June 2019 7.80 -- July 2017 20 568.62 April 2018 19.26 569.36 October 2018 18.56 570.06 July 2017 18.3 567.82 April 2018 17.64 568.48 October 2018 17.12 569.00 July 2017 19.95 563.27 April 2018 18.7 564.52 October 2018 18.55 564.67 July 2017 15.8 561.69 April 2018 14.42 563.07 October 2018 17.70 559.79 April 2019 12.77 564.72 February 2020 14.35 563.14 MW-54 571.51 23.40 MW-55 NS 26.54 MW-53 571.51 21.90 EW-2 588.62 44.60 EW-3 586.12 31.30 MW-58 32.14 MW-60 39.72 MW-61 41.60 EW-4 583.22 45.35 EW-6 577.49 NM Table 2 Groundwater Elevation Data Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Top of Casing Elevation (ft NAVD88) Depth to Bottom 1 (ft msl)Date Gauged Depth to Water (ft btoc) Groundwater Elevation (ft msl) July 2017 9.5 568.53 April 2018 8.2 569.83 October 2018 8.00 570.03 July 2017 14.7 558.80 April 2018 12.02 561.48 October 2018 13.30 560.20 Notes: 1 - Depth to bottom of well measured in July 2017 2 - Well not gauged in July 2017 due to lack of access 3 - Well not gauged in July 2017 due to obstruction in well 4 - Anomalous groundwater elevation; TOC elevation needs to be surveyed ft btoc - feet below top of casing ft - feet msl - feet relative to mean sea level N/A - Data not available NAVD88 - North American Vertical datum of 1988 NM - Not Measured NS - Not Surveyed Top of casing elevations taken from Geosyntec "Interim Remedial Assessment Report"; January 2015; pg. 40 EW-8 578.03 NM EW-9 573.50 NM Table 3 Summary of Proposed Injection Quantities Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Area EDS-ER® (LB) Sodium Bicarbonate (LB) Nutrimens® (GAL) Total Injection Volume (GAL) Number Injection Points/Wells Injection Volume per Well (GAL) Downgradient Onsite Eastern Barrier Injection Wells 16,800 15,200 40 22,000 8 2,750 gal per well Downgradient Onsite Southwestern Barrier Injection Wells 21,000 19,000 50 27,500 10 2,750 gal per well Downgradient Offsite Barrier Injection Wells 12,600 11,400 30 16,500 6 2,750 gal per well Notes: EDS-ER® - Electron Donor Solution-Extended Release® GAL - Gallons LB - Pounds AECOM Table 4 Enhanced Reductive Dechlorination Implementation Schedule Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Field TOC VOC DP Microbial Field TOC VOC DP Microbial Field TOC VOC DP Microbial Field TOC VOC DP Microbial Field TOC VOC DP Microbial MW-8 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-18 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-23 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-24 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-28 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-32 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 MW-35 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 PMW-1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 PMW-3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 PMW-4 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 PMW-5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 IW-1 1 1 IW-2 1 1 1 1 1 1 1 1 1 1 1 1 1 IW-3 1 1 IW-4 1 1 IW-5 1 1 IW-6 1 1 1 1 1 1 1 1 1 1 1 1 IW-7 1 1 IW-8 1 1 IW-9 1 1 IW-10 1 1 IW-11 1 1 1 1 1 1 1 1 1 1 1 1 1 IW-12 1 1 IW-13 1 1 IW-14 1 1 1 1 1 1 1 1 1 1 1 1 IW-15 1 1 IW-16 1 1 IW-17 1 1 IW-18 1 1 1 1 1 1 1 1 1 1 1 1 IW-19 1 1 IW-20 1 1 1 1 1 1 1 1 1 1 1 1 1 IW-21 1 1 IW-22 1 1 IW-23 1 1 1 1 1 1 1 1 1 1 1 1 1 IW-24 1 1 Notes Field - Field Parameters - DTW, DO, pH, ORP, temperature, conductivity TOC - Total Organic Carbon (EPA 415.1) VOC - Volatile Organic Compounds (EPA 8260B) DP - Degradation Products: carbon dioxide (MOD EPA 3810), ethene (MOD EPA 3810), ethane (MOD EPA 3810), methane (MOD EPA 3810) Microbial - Dehalococcoides sp. And Dehalobacter sp. and Census DNA bvcA Reductase, tceA Reductase, Vinyl Chloride Reductase PMW- Performance Monitoring Well IW- Injection Well DTW - depth to water DO - dissolved oxygen ORP - Oxidation Reduction Potential EPA - Environmental Protection Agency bgs - below ground surface The proposed monitoring schedule is subject to change. Additions and/or deletions to the proposed monitoring plan are expected. Proposed Monitoring Wells Proposed Injection Wells (Eastern Property Boundary) Proposed Injection Wells (Southern Property Boundary) Proposed Injection Wells (Off-Site Alignment) Existing Monitoring Wells Monitoring Program Baseline Month 3 Month 6 Month 9 Month 12 AECOM Table 5 Monitoring Well Construction Details Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Date Installed Well status Well Diameter Top of Casing MP Elevation (ft msl) Screened Interval (ft bgs) Total Well Depth (ft btoc) Total Well Depth (ft msl) Aquifer Unit Monitored (see code) Depth to Top of Bedrock (ft) Top of Bedrock Elevation (ft msl) EW-6 4/29/1993 Existing 6" diameter 577.49 11 - 31 31.0 546.49 Saprolite/PWR/Bedrock 30.00 547.49 EW-8 11/21/1994 Existing 12" diameter 578.03 11 - 41 45.0 533.03 Saprolite/PWR/Bedrock 36.00 542.03 EW-9 11/22/1994 Existing 12" diameter 573.65 19 - 49 52.0 521.65 Saprolite/PWR/Bedrock 30.00 543.65 MW-8 10/17/1989 Existing 2" diameter NA 15 - 35 35.0 NA PWR 30.00 NA MW-11 2/20/1990 Existing 2" diameter 585.41 8.5 - 43.5 43.5 541.91 Saprolite/PWR 41.50 543.91 MW-15/EW-3 3/28/1990 Existing 4" diameter 586.12 8.3 - 33.3 33.3 552.82 Saprolite/PWR 32.00 554.12 MW-18 6/21/1990 Existing 2" diameter 584.57 7 - 32 32.0 552.57 Saprolite/PWR/Bedrock 27.00 557.57 MW-20 6/13/1991 Existing 2" diameter 580.01 49 - 54 55.0 525.01 Bedrock 23.00 557.01 MW-21 3/15/1991 Existing 2" diameter 571.51 11.5 - 31.5 31.5 540.01 Saprolite --NA MW-22 10/22/1992 Existing 2" diameter 583.71 20 - 35 35.0 548.71 Saprolite/PWR 35.00 548.71 MW-23 10/22/1992 Existing 2" diameter 582.20 15 - 30 30.0 552.20 Saprolite/PWR 30.50 551.70 MW-24 10/22/1992 Existing 2" diameter 583.60 17 - 37 37.0 546.60 Saprolite/PWR/Bedrock 28.00 555.60 MW-25 10/23/1992 Existing 2" diameter 592.22 15 - 35 35.0 557.22 Saprolite/PWR 35.00 557.22 MW-26 10/23/1992 Existing 2" diameter 592.03 15 - 40 40.0 552.03 Saprolite/PWR 40.00 552.03 MW-27 10/23/1992 Existing 2" diameter 568.62 15 - 30 30.0 538.62 Saprolite/PWR 30.00 538.62 MW-28 10/23/1992 Existing 2" diameter 579.22 15 - 30 30.0 549.22 Saprolite/PWR 30.00 549.22 MW-29/EW-4 10/23/1992 Existing 6" diameter 583.22 15 - 40 40.0 543.22 Saprolite/PWR/Bedrock 35.00 548.22 MW-30 10/26/1992 Existing 2" diameter 590.11 20 - 40 41.0 549.11 PWR/Bedrock 34.00 556.11 MW-31/EW-2 10/26/1992 Existing 6" diameter 588.62 15 - 42 42.0 546.62 Sand/PWR 34.00 554.62 MW-32 10/21/1992 Existing 2" diameter 550.42 12 - 42 42.0 508.42 Sand/Bedrock 42.00 508.42 MW-34 10/21/1992 Existing 2" diameter 582.32 18 - 38 38.0 544.32 Sand/PWR 38.00 544.32 MW-35 10/27/1992 Existing 2" diameter 582.971 5 - 30 30.0 552.97 Sand/Bedrock 19.00 563.97 MW-36 10/27/1992 Existing 2" diameter 580.79 10 - 30 31.0 549.79 Sand/Bedrock 28.00 552.79 MW-37 10/21/1992 Existing 2" diameter 582.80 27 - 42 42.0 540.80 PWR/Bedrock 28.00 554.80 MW-38 11/24/2014 Existing 2" diameter 569.40 15 - 25 26.7 542.70 PWR 26.00 543.40 MW-39 11/24/2014 Existing 2" diameter 569.52 30 - 40 41.3 528.22 Bedrock 26.00 543.52 MW-40 9/30/2014 Existing 2" diameter 516.59 5 - 15 15.0 501.59 Saprolite/PWR 15.50 501.09 MW-41 9/30/2014 Existing 2" diameter 516.40 20 - 30 30.0 486.40 Bedrock 15.00 501.40 MW-43 10/6/2014 Existing 2" diameter 569.45 15 - 25 25.0 544.45 Bedrock 10.00 559.45 MW-45 10/2/2014 Existing 2" diameter 581.34 20 - 30 30.0 551.34 Bedrock 15.00 566.34 WELL CONSTRUCTION DETAILS AQUIFER DATA AECOM Page 1 of 2 Table 5 Monitoring Well Construction Details Cintas - Former Rental Towel Uniform/National Services Industries, Inc. Site Graham, North Carolina Well Number Date Installed Well status Well Diameter Top of Casing MP Elevation (ft msl) Screened Interval (ft bgs) Total Well Depth (ft btoc) Total Well Depth (ft msl) Aquifer Unit Monitored (see code) Depth to Top of Bedrock (ft) Top of Bedrock Elevation (ft msl) WELL CONSTRUCTION DETAILS AQUIFER DATA MW-46 10/1/2014 Existing 2" diameter 570.64 25- 35 35.0 535.64 Saprolite/PWR 32.50 538.14 MW-47 10/1/2014 Existing 2" diameter 570.25 40 - 50 50.0 520.25 Bedrock 35.00 535.25 MW-49 10/2/2014 Existing 2" diameter 514.40 15 - 25 25.0 489.40 Bedrock 10.00 504.40 MW-50 9/29/2014 Existing 2" diameter 579.31 45 - 55 55.0 524.31 Bedrock 33.00 546.31 MW-51 2/14/2015 Existing 2" diameter 571.51 27 - 32 32.0 539.51 PWR 32.00 539.51 MW-52 2/15/2015 Existing 2" diameter 571.51 27 - 32 32.0 539.51 PWR 32.00 539.51 MW-53 2/14/2015 Existing 2" diameter 571.51 17 - 22 32.0 539.51 PWR --NA MW-54 2/15/2015 Existing 2" diameter 571.51 18 - 24 23.0 548.51 PWR --NA MW-55 6/6/2018 Existing 2" diameter NS 16.5 - 26.5 26.5 NS Saprolite 26.50 NS MW-56 9/11/2018 Existing 2" diameter NS 30 - 40 40.0 NS Saprolite --NS MW-57 9/17/2018 Existing 2" diameter NS 30 - 40 40.0 NS PWR 40.00 NS MW-58 9/18/2018 Existing 2" diameter NS 23 - 33 33.0 NS PWR/Bedrock 27.00 NS MW-59 9/19/2018 Existing 2" diameter NS 27 - 37 37.0 NS PWR/Bedrock 30.00 NS MW-60 9/20/2018 Existing 2" diameter NS 30 - 40 40.0 NS PWR/Bedrock 39.00 NS MW-61 9/11/2018 Existing 2" diameter NS 30 - 40 40.0 NS Saprolite --NS MW-62 5/30/2019 Existing 2" diameter NS 30 - 40 40.0 NS Bedrock 7.00 NS PMW-1 6/7/2018 Existing 2" diameter NS 11 - 31 31.0 NS Saprolite/PWR/Bedrock 30.00 NS PMW-2 6/7/2018 Existing 2" diameter NS 11 - 31 31.0 NS Saprolite/PWR/Bedrock 30.00 NS PMW-3 6/7/2018 Existing 2" diameter NS 11 - 31 31.0 NS Saprolite/PWR/Bedrock 30.00 NS Notes: 1Top of casing elevation is anomalous bgs - below ground surface btoc - below top of casing ft - feet msl - relative to mean sea level NA - No data available PWR - Partially Weathered Rock NS - Not Surveyed AECOM Page 2 of 2 Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM Figures Site Location Copyright:© 2013 National Geographic Society, i-cubed Map Location November 2017 60547865 Site Location MapCintas: Former Rental Towel Uniform/Natio nal Se rvices Ind ustries, Inc. Site610 Woody DriveGraham, North Carolina Figure 1 AECOM1600 Perimeter Park Drive, Suite 400Morrisville, NC 27560tel: 919-461-1100fax: 919-461-1235web: www.AECOM.com 0 2,000 4,000Feet ¦NC VA SCGA KY TN WV AL MDIN EW-1EW-2EW-8MW-13MW-2MW-20MW-21MW-25MW-26MW-27MW-3MW-30MW-36MW-12MW-43MW-45MW-49MW-5MW-50MW-51MW-52MW-53MW-54MW-6MW-7MW-8TOWN BRANCHCREEKU N AM E D T R I B U T A R Y KAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.CINTAS FACILITY(FORMER G&K)MW-10MW-55MW-59MW-58MW-57MW-56MW-61MW-60EW-5MW-9PMW-1PMW-3PMW-2MW-19MW-33MW-41MW-62MW-28PMW-4MW-35MW-32EW-7EW-9EW-6MW-1MW-34MW-37MW-23PMW-5MW-24MW-18MW-22MW-17MW-16MW-14EW-4MW-11EW-3MW-39MW-38MW-47MW-46MW-40FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 606259531" = 250'250250SCALE IN FEET0LEGENDANSI B 11" x 17"Last saved by: MAURERE(2020-06-25) Last Plotted: 2020-09-01 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\ERD_DWG\FIGURE 2_SITE MAP_NOAERIAL.DWG SITE MAP Figure: 2Date: 2019-08-13 CC NO MA SHALLOW MONITORING WELLREMEDIATION SYSTEM EXTRACTION WELLDEEP MONITORING WELLDESTROYED/ABANDONED WELLSITE BOUNDARYNOTE: MONITORING WELLS MW-55 THROUGH MW-62 HAVE NOTBEEN SURVEYED, LOCATIONS ARE APPROXIMATE.PERFORMANCE MONITORING WELLPROPOSED PERFORMANCE MONITORING WELLPROPOSED PERMANENT INJECTION WELLEXTENT OF INJECTION ZONE U N AM E D T R I B U T A R YMW-27EW-6TOWN BRANCHCREEKKAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.MW-18EW-8EW-9MW-40MW-38MW-46EW-4(103)(<1.00)(NS)(1,000)(2,260)(278)(163 J)(3.35 J)(2,370)(167 J)(18,600)(88,300 J)(NS)(<1.00)(2,410)(105 J)(2,510)(5,510)(40.8)(44.4)(28,200)(NS)(46,100 J)(NS)(NS)(NS)(NS)(29,200 J)(8.43)(NS)(2,370)(NS)(NS)(81.5)(8,190)MW-25MW-28MW-32MW-35MW-36MW-22MW-23MW-24MW-8MW-34MW-55MW-58MW-57MW-56EW-2MW-21MW-26MW-51MW-52MW-53MW-11MW-30MW-54MW-60MW-59(NS)EW-370000 µg/L700 µg/L70 µg/LMW-617000 µg/L7.0 µg/L0.7 µg/L FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 605692471" = 250'250250SCALE IN FEET0ANSI B 11" x 17"Last saved by: MAURERE(2020-04-30) Last Plotted: 2020-06-18 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\DWG\FIGURE 5_PCE RESULTS MAP-SHALLOW.DWG PCE RESULTS MAP SHALLOW WELLS (FEBRUARY 2020) Figure: 3Date: 2020-04-28 CC NO MA NOTES:1. 15A NCAC 2L STANDARD FOR TETRACHLOROETHYLENE (PCE) 0.70 µg/L.2. MONITORING WELLS MW-55 THROUGH MW-61 HAVE NOT BEEN SURVEYED, LOCATIONS ARE APPROXIMATE.PCE ISOCONCENTRATION CONTOUR (µg/L)(DASHED WHERE INFERED)(3,120)PCE CONCENTRATIONS IN µg/L.TETRACHLOROETHENEPCEMICROGRAMS PER LITERµg/LNOT SAMPLEDNS7.0 µg/LLEGENDSITE BOUNDARYSHALLOW MONITORING WELLFORMER REMEDIATION SYSTEMEXTRACTION WELL U N AM E D T R I B U T A R Y TOWN BRANCHCREEKKAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.EW-6MW-18MW-21MW-25MW-26MW-28MW-32MW-35MW-36MW-40MW-51MW-52MW-53MW-54MW-22MW-38MW-46MW-11MW-23MW-24MW-30MW-8MW-34MW-55MW-59MW-58MW-57MW-56MW-61MW-60300 µg/L1000 µg/LMW-27EW-8EW-9EW-2EW-3EW-4(6.16)(<1.00)(NS)(23.8)(58)(10.2)(<1.00)(<1.00)(50.2)(29.4)(<5,000)(586 J)(1,190 J)(NS)(<1.00)(7.32)(5.24)(92.2)(291)(3.2)(26.3)(850 J)(157)(NS)(NS)(NS)(NS)(NS)(NS)(<1.00)(24 J)(NS)(NS)(2,900)(2.79)(NS)3 µg/L 30 µg/L FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 606259531" = 250'250250SCALE IN FEET0ANSI B 11" x 17"Last saved by: MAURERE(2020-04-30) Last Plotted: 2020-06-18 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\DWG\FIGURE 7_TCE RESULTS MAP-SHALLOW.DWG TCE RESULTS MAP SHALLOW WELLS (FEBRUARY 2020) Figure: 4Date: 2020-04-28 CC NO MA NOTES:1. 15A NCAC 2L STANDARD FOR TRICHLOROETHENE (TCE) 3 µg/L.2. MONITORING WELLS MW-55 THROUGH MW-61 HAVE NOT BEEN SURVEYED, LOCATIONS ARE APPROXIMATE.TCE ISOCONCENTRATION CONTOUR (µg/L)(DASHED WHERE INFERED)(1,020)TCE CONCENTRATIONS IN µg/L.TRICHLOROETHENETCEMICROGRAMS PER LITERµg/LNOT SAMPLEDNS3.0 µg/LLEGENDSITE BOUNDARYSHALLOW MONITORING WELLFORMER REMEDIATION SYSTEMEXTRACTION WELL EW-1EW-2EW-8MW-13MW-2MW-20MW-21MW-25MW-26MW-27MW-3MW-30MW-36MW-12MW-43MW-45MW-49MW-5MW-50MW-51MW-52MW-53MW-54MW-6MW-7MW-8TOWN BRANCHCREEKU N AM E D T R I B U T A R Y KAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.CINTAS FACILITY(FORMER G&K)MW-10MW-55MW-59MW-58MW-57MW-56MW-61MW-60EW-5MW-9PMW-1PMW-3PMW-2MW-19MW-33MW-41MW-62MW-28PMW-4MW-35MW-32EW-7EW-9EW-6MW-1MW-34MW-37MW-23PMW-5MW-24MW-18MW-22MW-17MW-16MW-14EW-4MW-11EW-3MW-39MW-38MW-47MW-46AA'MW-40FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 606259531" = 250'250250SCALE IN FEET0LEGENDANSI B 11" x 17"Last saved by: MAURERE(2020-06-18) Last Plotted: 2020-06-18 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\ERD_DWG\FIGURE 5_CROSSSECTIONLOCATIONMAP.DWG CROSS SECTION LOCATION MAP A-A’ Figure: 5Date: 2019-08-13 CC NO MA SHALLOW MONITORING WELLREMEDIATION SYSTEM EXTRACTION WELLDEEP MONITORING WELLDESTROYED/ABANDONED WELLSITE BOUNDARYNOTE: MONITORING WELLS MW-55 THROUGH MW-62 HAVE NOTBEEN SURVEYED, LOCATIONS ARE APPROXIMATE.PERFORMANCE MONITORING WELLPROPOSED PERFORMANCE MONITORING WELLPROPOSED PERMANENT INJECTION WELL (HSA/AIR)PROPOSED PERMANENT INJECTION WELL (SONIC)AA'LINE OF TRANSECTBB' 590Elevation ( ft. msl )540550520530510500480490Elevation ( ft. msl )590580570540500480MW-40/MW-41 A'( East )A( West )MW-35 Former RTUS/NSI Faculity BuildingMW-32 MW-62 MW-53MW-26MW-60MW-37 MW-28/MW-50573.83536.02572.74566.42UnnamedTributary509.59922.80Town BranchCreek570550Proposed OnsiteEastern BarrierInjection Area560490580560510Proposed Off-siteEastern BarrierInjection Area530520700702,510<1.088,300 J70,0001,5507,0006,170 J40.849.3 J7NS5,51044.4 J8,190FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 60625953 ANSI B 11" x 17"Last saved by: MAURERE(2020-06-26) Last Plotted: 2020-06-26 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\ERD_DWG\FIGURE 6_CROSS SECTION A-A'.DWG CROSS SECTION (A-A') Figure: 6Date: 2020-06-18 CC NO MA VERTICAL EXAGGERATION : 5xSandy Silt to Clayey Silt SaproliteCompetent Bedrock ( Biotite Gneiss and Schist )Lithology LegendLegendLithologic Contact Line( Dashed Where Inferred )( ft. msl )Groundwater Potentiometric ElevationMonitoring WellScreened IntervalPartially Weathered Rock ( PWR )Feet mean sea levelft. mslMicrograms per Literug/L( Dashed Where Inferred )Groundwater Equipotential Surface951.35GroundwaterPCE Concentration ( ug/L ) in395PCE Isoconcentration ( ug/L )( Dashed Where Inferred )10Perchloroethene ( Tetrachloroethene )PCEAbbreviationsNotes1. All monitoring wells, except MW-62, gauged and sampled in February 2020.2. MW-62 location has not been surveyed. Location is approximate.Silty SandSilty Clay 7 TOWN BRANCHCREEKU N AM E D T R I B U T A R Y KAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.CINTAS FACILITY(FORMER G&K)570565560555550545540535530525520515510510515520525530535540545550555560565570MW-34MW-55MW-58MW-57MW-56MW-61MW-60MW-59********EW-6EW-8EW-9EW-2EW-3EW-4MW-18MW-21MW-25MW-26MW-27MW-28MW-32MW-35MW-36MW-40MW-51MW-52MW-53MW-54573.70DRY573.83573.62554.52566.42536.02509.59MW-22MW-38MW-46550.00552.54NGMW-11MW-23MW-24MW-30MW-8560.85568.60569.89572.61******NGNGNG563.14NGNG560.97FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 606259531" = 250'250250SCALE IN FEET0LEGENDSITE BOUNDARYANSI B 11" x 17"Last saved by: MAURERE(2020-04-30) Last Plotted: 2020-06-18 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\DWG\FIGURE 3_GW POTENTIOMETRIC MAP-SHALLOW.DWG GROUNDWATER POTENTIOMETRIC MAP SHALLOW WELLS (FEBRUARY 2020) Date: 2020-04-28 Figure: 8 CC NO MA GROUNDWATER ELEVATION (ft AMSL)DIRECTION OF GROUNDWATER FLOWSHALLOW MONITORING WELLFORMER REMEDIATION SYSTEMEXTRACTION WELLNOTES:1. WELL NOT USED IN GROUNDWATER ELEVATION INTERPRETATION.2. MONITORING WELLS MW-55 THROUGH MW-61 HAVE NOT BEEN SURVEYED, LOCATIONS ARE APPROXIMATE.GROUNDWATER ELEVATION CONTOUR (ft AMSL)(DASHED WHERE INFERED)571.58570*NOT GAUGEDNG U N AM E D T R I B U T A R Y TOWN BRANCHCREEKKAUMANPACKAGING INC.PEAK OFGRAHAM LLCUSA DUTCH INC.CINTAS FACILITY(FORMER G&K)570565560555550545540535530525520515510510515520525530535540545550570565560555550.52550.75569.69NG572.74565.46569.53509.80505.05MW-37MW-45MW-50MW-20MW-43MW-62*MW-41MW-47MW-39MW-49FORMER RENTAL TOWEL UNIFORM/ NATIONAL SERIVICES INDUSTRIES, INC. SITE GRAHAM, NORTH CAROLINA Project No.: 606259531" = 250'250250SCALE IN FEET0LEGENDSITE BOUNDARYANSI B 11" x 17"Last saved by: MAURERE(2020-04-30) Last Plotted: 2020-06-18 Project Management Initials:Designer:Checked:Approved:Filename: C:\USERS\MAURERE\DESKTOP\GRAHAM\DWG\FIGURE 4_GW POTENTIOMETRIC MAP-DEEP.DWG GROUNDWATER POTENTIOMETRIC MAP DEEP WELLS (FEBRUARY 2020) Date: 2020-04-28 Figure: 9 CC NO MA GROUNDWATER ELEVATION (ft AMSL)DIRECTION OF GROUNDWATER FLOWDEEP MONITORING WELLGROUNDWATER ELEVATION CONTOUR (ft AMSL)(DASHED WHERE INFERED)504.95570NOTES:1. * WELL NOT IN USE IN GROUNDWATER ELEVATION INTERPRETATION.2. MONITORING WELL MW-62 HAS NOT BEEN SURVEYED, LOCATION ISAPPROXIMATE. Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM Appendix A Proposed Well Construction Diagrams Client: Project Number: Site Location:Date Installed: Well Location: Coords:Inspector: Method: Contractor: PROPOSED INJECTION WELL CONSTRUCTION DETAIL Depth from G.S. (feet)Elevation(feet) Datum __________ Measuring Point Top of Riser Pipe for Surveying & Water Levels Ground Surface (GS) Top of Cement Cement, Bentonite or Bentonite Slurry Grout Riser Pipe: Length Inside Diameter (ID) 95 % Cement Type of Material 5 % Bentonite Bottom of Steel Guard Pipe 0 % Native Materials Top of Bentonite Bentonite Seal Thickness Top of Sand Top of Screen Stabilized Water Level Screen: Length Inside Diameter (ID) Slot Size Type of Material Type/Size of Sand Sand Pack Thickness Bottom of Screen Bottom of Tail Pipe: Stainless Steel Threaded Plug Bottom of Borehole Borehole Diameter:12-in Approved: Describe Measuring Point: Signature Date 0.0 Cintas Coorporation WELL ID:IW-1 through IW-860625953 Graham, North Carolina Proposed Proposed Proposed Roto-Sonic or Hollow Stem Auger/Air Rotary TBD 0.0 0.75 ft 10 ft 2-in PVC NA 5 ft 3 ft 8 ft 10 ft Unknown Land Surface 20 ft 2-in 0.01 in PVC #2 22 ft 30 ft 30 ft 30 ft Client: Project Number: Site Location:Date Installed: Well Location: Coords:Inspector: Method: Contractor: PROPOSED INJECTION WELL CONSTRUCTION DETAIL Depth from G.S. (feet)Elevation(feet) Datum __________ Measuring Point Top of Riser Pipe for Surveying & Water Levels Ground Surface (GS) Top of Cement Cement, Bentonite or Bentonite Slurry Grout Riser Pipe: Length Inside Diameter (ID) 95 % Cement Type of Material 5 % Bentonite Bottom of Steel Guard Pipe 0 % Native Materials Top of Bentonite Bentonite Seal Thickness Top of Sand Top of Screen Stabilized Water Level Screen: Length Inside Diameter (ID) Slot Size Type of Material Type/Size of Sand Sand Pack Thickness Bottom of Screen Bottom of Tail Pipe: Stainless Steel Threaded Plug Bottom of Borehole Borehole Diameter:12-in Approved: Describe Measuring Point: Signature Date 0.0 Cintas Coorporation WELL ID:IW-9 through IW-1860625953 Graham, North Carolina Proposed Proposed Proposed Roto-Sonic or Hollow Stem Auger/Air Rotary TBD 0.0 0.75 ft 15 ft 2-in PVC NA 10 ft 3 ft 13 ft 15 ft Unknown Land Surface 20 ft 2-in 0.01 in PVC #2 22 ft 35 ft 35 ft 35 ft Client: Project Number: Site Location:Date Installed: Well Location: Coords:Inspector: Method: Contractor: PROPOSED INJECTION WELL CONSTRUCTION DETAIL Depth from G.S. (feet)Elevation(feet) Datum __________ Measuring Point Top of Riser Pipe for Surveying & Water Levels Ground Surface (GS) Top of Cement Cement, Bentonite or Bentonite Slurry Grout Riser Pipe: Length Inside Diameter (ID) 95 % Cement Type of Material 5 % Bentonite Bottom of Steel Guard Pipe 0 % Native Materials Top of Bentonite Bentonite Seal Thickness Top of Sand Top of Screen Stabilized Water Level Screen: Length Inside Diameter (ID) Slot Size Type of Material Type/Size of Sand Sand Pack Thickness Bottom of Screen Bottom of Tail Pipe: Stainless Steel Threaded Plug Bottom of Borehole Borehole Diameter:12-in Approved: Describe Measuring Point: Signature Date 40 ft 40 ft 40 ft Land Surface 20 ft 2-in 0.01 in PVC #2 22 ft 0.0 0.75 ft 20 ft 2-in PVC NA 15 ft 3 ft 18 ft 20 ft Unknown 0.0 Cintas Coorporation WELL ID:IW-19 through IW-2460625953 Graham, North Carolina Proposed Proposed Proposed Roto-Sonic or Hollow Stem Auger/Air Rotary TBD Client: Project Number: Site Location:Date Installed: Well Location: Coords:Inspector: Method: Contractor: PROPOSED MONITORING WELL CONSTRUCTION DETAIL Depth from G.S. (feet)Elevation(feet) Datum __________ Measuring Point Top of Riser Pipe for Surveying & Water Levels Ground Surface (GS) Top of Cement Cement, Bentonite or Bentonite Slurry Grout Riser Pipe: Length Inside Diameter (ID) 95 % Cement Type of Material 5 % Bentonite Bottom of Steel Guard Pipe 0 % Native Materials Top of Bentonite Bentonite Seal Thickness Top of Sand Top of Screen Stabilized Water Level Screen: Length Inside Diameter (ID) Slot Size Type of Material Type/Size of Sand Sand Pack Thickness Bottom of Screen Bottom of Tail Pipe: Stainless Steel Threaded Plug Bottom of Borehole Borehole Diameter:12-in Approved: Describe Measuring Point: Signature Date 40 ft 40 ft 40 ft Land Surface 10 ft 2-in 0.01 in PVC #2 12 ft 0.0 0.75 ft 30 ft 2-in PVC NA 25 ft 3 ft 28 ft 30 ft Unknown 0.0 Cintas Coorporation WELL ID:PMW-5 AND PMW-660625953 Graham, North Carolina Proposed Proposed Proposed Roto-Sonic or Hollow Stem Auger/Air Rotary TBD Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM Appendix B Material Safety Data Sheets Material Safety Data Sheet Material Safety Data Sheet Date: May 11, 2011 Page 1 Rev. Date: January 24, 2013 Electron Donor Solution Section 1: Chemical Product and Company Identification Product Name: Electron Donor Solution Extended Release Catalog Codes: EDS-ER CAS#: 8001-22-7 TSCA: TSCA 8(b) inventory: Soybean oil HMIS Code: H F R P: 10 0 A Trade Name and Synonyms: EDS-ER Chemical Family: Glyceride Oils Contact Information: Tersus Environmental, LLC 109 E. 17th Street, Suite #3880 Cheyenne, WY 82001 Ph: 307.638.2822 • info@tersusenv.com www.tersusenv.com For emergency assistance, call: 919.638.7892 Section 2: Composition and Information on Ingredients COMPONANT CAS # OSHA TWA OSHA STEL ACGIH TWA ACGIH STEL Soybean Oil 8001-22-7 --- 10 mg/m3 --- --- Vegetable Oil Derived Fatty Acid Esters Confidential --- --- --- --- HAZARDOUS INGREDIENTS: NONE AS DEFINED UNDER THE U.S. OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) OR THE CANADIAN HAZARDOUS PRODUCTS. ACT S.C. 1987, C.30 (PART 1). THE PRECISE COMPOSITION OF THIS PRODUCT IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE WILL BE PROVIDED TO A PHYSICIAN IN THE EVENT OF A MEDICAL EMERGENCY. SARA HAZARD: NONE NOTED (SECTION 311/312) TITLE III SECTION 313 - NOT LISTED All components of this product are listed on the TSCA registry. Section 3: Physical/Chemical Characteristics BOILING RANGE: Not applicable VAPOR DENSITY: Exceeds 1.0 SPECIFIC GRAVITY (H20=1.0): 0.92 - 0.925 VAPOR PRESSURE: Not applicable PERCENT VOLATILE BY VOLUME: 0% SOLUBILITY IN WATER: Miscible EVAPORATION RATE: Not applicable APPEARANCE AND ODOR: A pale yellow, oily liquid - only a faint odor. WEIGHT PER GALLON: 7.7 lbs. at 60F. Material Safety Data Sheet Material Safety Data Sheet Date: May 11, 2011 Page 2 Rev. Date: January 24, 2013 Section 4: Fire and Explosion Data FLAMMABILITY CLASSIFICATION: Combustible Liquid - Class IIIB. FLASHPOINT: Greater than 550 F (288 C). METHOD USED: Tag Closed Cup. EXTINGUISHING MEDIA: CO2, dry chemical, foam, sand. SPECIAL FIREFIGHTING PROCEDURES: Avoid use of water as it may spread fire by dispersing oil. Use water to keep fire-exposed containers cool. Water spray may be used to flush spills away from fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: Rags soaked with any oil or solvent can present a fire hazard and should always be stored in UL Listed or Factory Mutual approved, covered containers. Improperly stored rags can create conditions that lead to oxidation. Oxidation, under certain conditions can lead to spontaneous combustion. Section 5: Reactivity Data STABILITY: Generally stable. Spontaneous combustion can occur. See Unusual Fire and Explosion Procedures, Section IV. CONDITIONS TO AVOID: High surface area exposure to oxygen can result in polymerization and release of heat. INCOMPATABILITY (MATERIALS TO AVOID): Avoid contact with strong oxidizing agents. HAZARDOUS DECOMPOSITIONS OR BY-PRODUCTS: Decomposition may produce carbon dioxide and carbon monoxide. HAZARDOUS POLYMERIZATION: Will not occur. Section 6: Health Hazard Data THRESHHOLD LIMIT VALUE: As a liquid - none. As oil mist - 10 mg/m3 total particulate. INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Excessive inhalation of oil mist may affect the respiratory system. Oil mist is classified as a nuisance particulate by ACGIH. SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: Not classified as a primary skin irritant or corrosive material. Sensitive individuals may experience dermatitis after long exposure of oil on skin. HEALTH HAZARDS (ACUTE AND CHRONIC): Acute: none observed by inhalation. Chronic: none reported. EMERGENCY AND FIRST AID PROCEDURES FOR: SKIN CONTACT: May be removed from skin by washing with soap and warm water. EYE CONTACT: Immediately flush eyes with plenty of cool water for at least 15 minutes. Do NOT let victim rub eyes. INHALATION: Immediately remove exposed individual to fresh air source. If victim has stopped breathing give artificial respiration, get medical attention immediately. Material Safety Data Sheet Material Safety Data Sheet Date: May 11, 2011 Page 3 Rev. Date: January 24, 2013 Section 7: Precautions for Safe Handling and Use ENVIRONMENTAL PRECAUTIONS: Where large spills are possible, a comprehensive spill response plan should be developed and implemented. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Wear appropriate respiratory protection and protective clothing as described in section VIII. Depending on quantity of spill: (a) Small spill - add solid adsorbent, shovel into disposable container and wash the area. Clean area with detergent. (b) Large spill - Squeegee or pump into holding container. Clean area with detergent. In the event of an uncontrolled release of this material, the user should determine if this release is reportable under applicable laws and regulations. WASTE DISPOSAL METHOD: All recovered material should be packaged, labeled, transported, and disposed or reclaimed in accordance with local, state, and federal regulations and good engineering practices. Section 8: Control Measures RESPIRATORY PROTECTION: Not normally needed. A qualified health specialist should evaluate whether there is a need for respiratory protection under specific conditions. VENTILATION: Handle in the presence of adequate ventilation. Intermittent clean air exchanges recommended, but not required. PROTECTIVE GLOVES: Not normally needed. However, protective clothing is always recommended when handling chemicals. EYE PROTECTION: Eye protection is always recommended when handling chemicals. Wear safety glasses meeting the specifications established in ANSI Standard Z87.1. Section 9: Special Precautions PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Store away from flame, fire, and excessive heat. Section 10: Disposal Considerations General Information: Do not discharge into drains, watercourses or onto the ground. Discharge, treatment, or disposal may be subject to national, state, or local laws. Empty containers may contain product residues. Disposal Methods: No specific disposal method required. Container: Since emptied containers retain product residue, follow label warnings even after container is emptied. Material Safety Data Sheet Material Safety Data Sheet Date: May 11, 2011 Page 4 Rev. Date: January 24, 2013 Section 11: Transportation Information DOT Not regulated. TDG Not regulated. IATA Not regulated. IMDG Not regulated. Section 12: Other Information Hazard Ratings Health Hazard Fire Hazard Instability Special Hazard NFPA 1 1 0 NONE Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe NFPA Label colored diamond code: Blue - Health; Red - Flammability; Yellow - Instability; White - Special Hazards Health Hazard Flammability Physical Hazard Personal Protection HMIS 1 1 0 -- Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe HMIS Label colored bar code: Blue - Health; Red - Flammability; Orange - Physical Hazards; White - Special Section 13: Disclaimer and/or Comments We suggest that containers be either professionally reconditioned for re-use by certified firms or properly disposed of by certified firms to help reduce the possibility of an accident. Disposal of containers should be in accordance with applicable federal, state and local laws and regulations. "Empty" drums should not be given to individuals. The conditions of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Tersus Environmental be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Tersus Environmental has been advised of the possibility of such damages. MATERI AL SAFETY DATA SHEET SODIUM BICARBONATE PAGE 01 OF 04 1. IDENT IFICAT ION OF T HE SUBST ANCE AND COMPANY Product : SODIUM BICARBONATE Chemical Name : Sodium Bicarbonate. Alternative Name : Bicarbonate of Soda. Baking Soda, Soda Bicarb Sodium Hydrogen Carbonate. Chemical Formula : NaHCO3 Manufacturing Sites : Gujarat, Saurashtra Company Address : GHCL Limited, Sutrapada, Dist. Gir Somnath Gujarat. Telephone Number : 02876 - 263401, 263402, 263403 Fax No. : 02876 - 263480, 263483 2. COMPOSIT ION / INFORMAT ION ON INGREDIENT S - Sodium Bicarbonate CAS Number : 144 - 55 - 8 EC Number : 205 - 633 8 3. HAZ ARDS IDENT IFICAT ION - A substance of low toxicity widel y used in food and medicine. - Treat as low toxicity dust - No significant health or environmental hazards associated with the material 4. FIRST AID MEASURES Inhalation - Remove to fresh air Skin Contact - W ash skin with plenty of water - If irritation occurs and persists seek medical advice Eye Contact - Irrigate eye thoroughly with eye wash solution or clean water for at least 10 minutes. - Eyelids should be held away from the eyeball to ensure through rinsing. - Obtain medical attention if necessar y. Ingestion - DO NOT induce vomiting - W ash out mouth with water and give plenty of water to drink (at least 300 ml. - Obtain medical attention if necessar y. MATERI AL SAFETY DATA SHEET SODIUM BICARBONATE PAGE 02 OF 04 5. FIRE-FIGHT ING MEASURES Flash Point - Non-combustible Extinguishing Media - All extinguishing products are allowed Special Hazards - Non-combustible Hazardous Decompositio n Products (under fire conditions) - Not applicable 6. ACCIDENT AL RELEASE MEASURES Environmental Precautions - Prevent discharges into the environment (rivers, water courses, sewers etc.) Methods for clean up - Clear up spillages by suitable means, avoiding dust formation - Collect as much as possible in a suitable clean container, preferably for re-use, otherwise for disposal. - W ash the spillage area with large quantities of water. 7. HANDLING AND ST ORAGE Handling - Atmospheric levels should be controlled in compliance with the occupational exposure limit. - Skin protection should be worn for regular and continuous use. Storag e - Store in a cool dry place (in humid conditions the product will absorb moisture from the atmosphere and this will eventually cause caking and loss of free flowing properties). - Do not store adjacent to acids. Fire and Explosion Prevention - Non-combustible 8. EXPOSURE CONT ROLS / PERSONAL PROT ECT ION Engineering Controls - Provide adequate ventilation - In the case of insufficient ventilation, wear suitable respiratory equipment Occupational Exposure Standards - Not listed by H&SE - Nuisance Dust Recommended Limits: OES 10mg/m3 (total dust) (8hr TW A) 5mg/m3 (respirable dust) 8hr TW A). Respiratory Protection - In the case of high dust levels wear suitable respiratory protective equipment, i.e. Dust masks or respirator. Hand Protection - W ear suitable chemical resistant protective gloves for frequent or prolonged operations. Eye Protection - Suitable eye / tace protection. Skin and Body Protection - Protective clothing is required, overalls as a minimum. MATERI AL SAFETY DATA SHEET SODIUM BICARBONATE PAGE 03 OF 04 9. PHYSICAL AND CHEMICAL PROPERT IES Appearance Cr ystalline Powder Oxidizing Properties None known Color W hite Vapor Pressure Not applicable Odors Odorless Specific Gravity 2.22 Melting Point Decomposes Bulk Density 980 kg/m3 Flash Point Not applicable Solubility in water 9.5%w/w @250C Flammability Not applicable Solubility in other solvents Not applicable Auto Ignition T emp. Not applicable pH value 8.3 (1%w/w solution) Explosive properties None known Partition Coefficient Not applicable (n-octanol/water) Explosion Limits Not applicable Relative vapor density (air-1) Not applicable 10. ST ABILIT Y AND REACT IVIT Y Stability - Stable under recommended storage and handling conditions (see Section 7). Conditions to avoid - Contact with acids unless under controlled conditions - Heating the product above 60 deg cel. - Humidity and moisture can cause caking of product. Materials to avoid - Acids Hazarous decomposition proctus - Not applicable 11. T OXICOLOGICAL INFORMAT ION Acute T oxicity - Oral LD 50, rat : 4220 mg/kg. - Inhalation : Dust may cause discomfort Eye Irritation - Dust may cause discomfort Skin Irritation - No known effect Long T erm Exposure - No known effect 12. ECOLOGICAL INFORMAT ION Acute Ecotoxicity - Fish, Lepomis macrochirus : 96hr-LC50 : 8600mg/l - Daphnia sp. : 48hr-LC50 : 2350mg/l Bio - degradability - Aerobic / Anaerobic degradation : Not applicable (inorganic compound) MATERI AL SAFETY DATA SHEET SODIUM BICARBONATE PAGE 04 OF 04 13. DISPOSAL CONSIDERAT IONS Product - Must be disposed in accordance with local, state or national regulations - Do not dispose of directly with acids - Dissolve in water and neutralize with an acid Packaging - Must be disposed in accordance with local, state or natural regulations - Contact the manufacturer about recycling. 14. T RANSPORT INFORMAT ION - Not classified as hazardous for transport. * Land T ransport ADS Class Not restricted ADR item number Not relevant RID Class Not restricted RID item number Not relevant T REM - Card Not relevant UN Number None Hazard Identification number None Substance Identification None Proper shipping name None number * Sea T ransport IMO / IMGD Not regulated Class Not relevant Packing group None UN Number None EMS Not relevant MFAG Not relevant Marine Pollutant No Proper shipping name Not relevant * Air T ransport ICAO/IAT A-DGR Class Not regulated UN number None Proper shipping name None Packing number None 15. Regulato ry Informatio n - Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulations Major Accident Hazard 96/82/EC Legislation Directive 96/82/EC does not apply National Legislation Storage Class 10-13 16. Other Information Provide adequate information, instruction and training for operators 1/4 KB-1® Material Safety Data Sheet Section 1: Material Identification Trade Name: KB-1® Chemical Family: bacterial mixture Chemical name: No IUC name for mixture is known to exist Manufacturer/Supplier: SiREM 130 Research Lane, Suite 2, Guelph, Ontario, Canada N1G 5G3 For Information call: 519-822-2265 / 1-866-251-1747 x236 Emergency Number: 519-822-2265 Description: Microbial inoculum (non-pathogenic, non-hazardous) Trade Name: KB-1® Product Use: Bioremediation of contaminated groundwater. Date Prepared: 2 February 2005 Section 2: Composition, Information on Ingredients KB-1® is a microbial culture grown in an aqueous dilute mineral salt solution media containing no hazardous ingredients. The microbial composition of KB-1® (as determined by phylogenetic analysis) is listed in Table 1. Identification of organisms was obtained by matching 16S rRNA gene sequence of organisms in KB-1® to other known organisms. The characteristics of related organisms can be used to identify potential or likely characteristics of organisms in KB-1®. Table 1. Genus’ Identified in KB-1® Microbial Inoculum Genus Dehalococcoides sp. Geobacter sp. Methanomethlovorans sp. Section 3: Hazards Identification: A review of the available data does not indicate any known health effects related to normal use of this product. Section 4: First Aid Measures: Avoid direct contact with skin and eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. Eye Contact: Flush eyes with water for at least 15 minutes, occasionally lift upper and lower eyelids, if undue irritation or redness occurs seek medical attention. Skin Contact: Remove contaminated clothing and wash skin thoroughly with water and antibacterial soap. Seek medical attention if irritation develops or open wounds are present. 2/4 Ingestion: Do not induce vomiting, drink several cups of water, seek medical attention. Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Section 5 - Fire Fighting Measures: Non-flammable Flash Point: not applicable Upper flammable limit: not applicable Lower flammable limit: not applicable Section 6 – Accidental Release Procedures Spilled KB-1® should be soaked up with sorbant and saturated with a 10% bleach solution (prepared by making a one in ten dilution of diluted standard bleach [normally sold at a strength of 5.25% sodium hypochlorite] to disinfect affected surfaces. Sorbant should be double bagged and disposed of as indicated in section 12. After removal of sorbant, area should be washed with 10% bleach solution to disinfect. If liquid from the culture vessel is present on the fittings, non-designated tubing or exterior of the stainless steel pressure vessel liquid should be wiped off and the area washed with 10% bleach solution. Section 7 - Handling and Storage KB-1® is shipped in stainless steel pressure vessels and connected to injection lines and inert gas is used to pressurize the vessel to displace the contents. KB-1® should be handled with care to avoid any spillage. Vessels are shipped with 1 pound per square inch (psi) pressure; valves should not be opened until connections to appropriate lines for subsurface injection are in place. Storage Requirements: Avoid exposing stainless steel pressure vessels to undue temperature extremes (i.e., temperatures less than 0°C or greater than 30°C may result in harm to the microbial cultures and damage to the vessels). All valves should be in the closed position when the vessel is not pressurized or not in use to prevent the escape of gases and to maintain anaerobic conditions in the vessel. Avoid exposure of the culture to air as the presence of oxygen will kill dechlorinating microorganisms. Section 8 - Exposure Controls/Personal Protection Personal protective equipment: Skin: Protective gloves (latex, vinyl or nitrile) should be worn. Eye Protection: Wear appropriate protective eyeglasses or goggles when opening pressure vessels, valves, or when pressurizing vessels to inject contents into the subsurface. Respiratory: No respiratory protection is required. Engineering Controls: Good general room ventilation is expected to be adequate. Section 9: Physical and Chemical Properties: Physical State: liquid Odour: skunky odour Appearance: dark grey, slightly turbid liquid under anaerobic conditions, pink if exposed to air (oxygen). Specific gravity: not determined Vapor pressure: not applicable Vapor density: not applicable Evaporation rate: not determined Boiling point: ~100° C Freezing point/melting point: ~ 0°C 3/4 pH: 6.5-7.5 Solubility: fully soluble in water Section 10 – Stability and Reactivity Data Stable and non-reactive. Maintain under anaerobic conditions to preserve product integrity. Materials to avoid: none known Section 11 - Toxicological Information Potential for Pathogenicity: KB-1® has tested negative (i.e., the organisms are not present) for a variety of pathogenic organisms listed in Table 2. While there is no evidence that virulent pathogenic organisms are present in KB-1®, there is potential that certain organisms in KB-1® may have the potential to act as opportunistic (mild) pathogens, particularly in individuals with open wounds and/or compromised immune systems. For this reason standard hygienic procedures such as hand washing after use should be observed. Table 2, Results of Human Pathogen Screening of KB-1® Dechlorinator Organism Disease(s) Caused Test result Salmonella sp. Typhoid fever, gastroenteritis Not Detected Listeria monocytogenes Listerioses Not Detected Vibrio sp., Cholera, gastroenteritis Not Detected Campylobacter sp., Bacterial diarrhea Not Detected Clostridia sp., Food poisoning, Botulism, tetanus, gas gangrene Not Detected Bacillus anthracis Anthrax Not Detected Pseudomonas aeruginosa Wound infection Not Detected Yersinia sp., Bubonic Plague, intestinal infection Not Detected Yeast and Mold Candidiasis, Yeast infection etc. Not Detected Fecal coliforms Indicator organisms for many human pathogens diarrhea, urinary tract infections Not Detected Enterococci Various opportunistic infections Not Detected Section 12. Disposal Considerations Material must be disinfected or sterilized prior to disposal. Consult local regulations prior to disposal. Section 13 – Transport Information Non-hazardous, non-pathogenic microbial inoculum – Biosafety Risk Group 1. Chemicals, Not Otherwise Indexed (NOI), Non-hazardous Not subject to TDG or DOT guidelines. 4/4 Disclaimer: The information provided on this MSDS sheet is based on current data and represents our opinion based on the current standard of practice as to the proper use and handling of this product under normal, reasonably foreseeable conditions. Last revised: 2 August 2011 1/3 KB-1® Plus Material Safety Data Sheet Section 1: Material Identification Trade Name: KB-1® Plus Chemical Family: bacterial mixture Chemical name: No IUC name for mixture is known to exist Manufacturer/Supplier: SiREM 130 Research Lane, Suite 2, Guelph, Ontario, Canada N1G 5G3 For Information call: 519-822-2265 / 1-866-251-1747 x236 Emergency Number: 519-822-2265 Description: Microbial inoculum (non-pathogenic, non-hazardous) Trade Name: KB-1® Plus Product Use: Bioremediation of contaminated groundwater. Date Prepared: 23 October 2008 Section 2: Composition, Information on Ingredients KB-1® Plus is a microbial culture grown in a dilute aqueous mineral salt solution media containing no hazardous ingredients. The microbial composition of KB-1® Plus is listed in Table 1. Table 1. Major Microbial Groups Identified in KB-1® Plus Microbial Inoculum Dehalococcoides sp. Geobacter sp. Methanomethylovorans sp. Dehalobacter sp. Dehalogenimonas sp. Section 3: Hazards Identification: A review of the available data does not indicate any known health effects related to normal use of this product. Section 4: First Aid Measures: Avoid direct contact with skin and eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. Eye Contact: Flush eyes with water for at least 15 minutes, occasionally lift upper and lower eyelids, if undue irritation or redness occurs seek medical attention. Skin Contact: Remove contaminated clothing and wash skin thoroughly with water and antibacterial soap. Seek medical attention if irritation develops or open wounds are present. 2/3 Ingestion: Do not induce vomiting, drink several cups of water, seek medical attention. Inhalation: Remove to fresh air. If not breathing give artificial respiration. In case of labored breathing give oxygen. Call a physician. Section 5 - Fire Fighting Measures: Non-flammable Flash Point: not applicable Upper flammable limit: not applicable Lower flammable limit: not applicable Section 6 – Accidental Release Procedures Spilled KB-1® Plus should be soaked up with sorbant and saturated with a 10% bleach solution (prepared by making a one in ten dilution of diluted standard bleach [normally sold at a strength of 5.25% sodium hypochlorite] to disinfect affected surfaces. Sorbant should be double bagged and disposed of as indicated in section 12. After removal of sorbant, area should be washed with 10% bleach solution to disinfect. If liquid from the culture vessel is present on the fittings, non-designated tubing or exterior of the stainless steel pressure vessel liquid should be wiped off and the area washed with 10% bleach solution. Section 7 - Handling and Storage KB-1® Plus is shipped in stainless steel pressure vessels in a protective over pack. KB-1® Plus should be handled with care to avoid any spillage. Vessels are shipped with 1 pound per square inch (psi) pressure; valves should not be opened until connections to appropriate lines for subsurface injection are in place. Storage Requirements: Avoid exposing stainless steel pressure vessels to undue temperature extremes (i.e., temperatures less than 0°C or greater than 30°C may result in harm to the microbial cultures and damage to the vessels). All valves should be in the closed position when the vessel is not pressurized or not in use to prevent the escape of gases and to maintain anaerobic conditions in the vessel. Avoid exposure of the culture to air as the presence of oxygen will kill dechlorinating microorganisms. Section 8 - Exposure Controls/Personal Protection Personal protective equipment: Skin: Protective gloves (latex, vinyl or nitrile) should be worn. Eye Protection: Wear appropriate protective eyeglasses or goggles when opening pressure vessels, valves, or when pressurizing vessels to inject contents into the subsurface. Respiratory: No respiratory protection is required. Engineering Controls: Good general room ventilation is expected to be adequate. Section 9: Physical and Chemical Properties: Physical State: liquid Odour: skunky odour Appearance: dark grey, slightly turbid liquid under anaerobic conditions, pink if exposed to air (oxygen). Specific gravity: 1 Vapor pressure: not applicable Vapor density: not applicable Evaporation rate: not determined Boiling point: ~100° C Freezing point/melting point: ~ 0°C 3/3 pH: 6.5-7.5 Solubility: fully soluble in water Section 10 – Stability and Reactivity Data Stable and non-reactive. Maintain under anaerobic conditions to preserve product integrity. Materials to avoid: none known Section 11 - Toxicological Information Potential for Pathogenicity: KB-1® Plus has tested negative (i.e., the organisms are not present) for a variety of pathogenic organisms listed in Table 2. While there is no evidence that virulent pathogenic organisms are present in KB-1® Plus, there is potential that certain organisms in KB-1® Plus may have the potential to act as opportunistic (mild) pathogens, particularly in individuals with open wounds and/or compromised immune systems. For this reason standard hygienic procedures such as hand washing after use should be observed. Table 2, Results of Human Pathogen Screening of KB-1® Plus Organism Disease(s) Caused Test result Salmonella sp. Typhoid fever, gastroenteritis Not Detected Listeria monocytogenes Listerioses Not Detected Vibrio sp., Cholera, gastroenteritis Not Detected Campylobacter sp., Bacterial diarrhea Not Detected Clostridia sp., Food poisoning, Botulism, tetanus, gas gangrene Not Detected Bacillus anthracis Anthrax Not Detected Pseudomonas aeruginosa Wound infection Not Detected Yersinia sp., Bubonic Plague, intestinal infection Not Detected Yeast and Mold Candidiasis, Yeast infection etc. Not Detected Fecal coliforms Indicator organisms for many human pathogens diarrhea, urinary tract infections Not Detected Enterococci Various opportunistic infections Not Detected Section 12. Disposal Considerations Material must be disinfected or sterilized prior to disposal. Consult local regulations prior to disposal. Section 13 – Transport Information Non-hazardous, non-pathogenic microbial inoculum Chemicals, Not Otherwise Indexed (NOI), Non-hazardous Not subject to TDG or DOT guidelines. Disclaimer: The information provided on this MSDS sheet is based on current data and represents our opinion based on the current standard of practice as to the proper use and handling of this product under normal, reasonably foreseeable conditions. Last revised: 12 June 2012 Chemical Components in KB-1® Growth Media KB-1® consists of a microbial culture grown in a mineral salts media containing the ingredients listed in Table 1. Table 1: Chemical Ingredients of KB-1® growth media Chemical Name Formula CAS# Concentration grams/Liter Potassium Phosphate Dibasic KH2PO4 7758-11-4 0.27 Potassium Phosphate Monobasic K2HPO4 7778-77-0 0.34 Ammonium Chloride NH4Cl 12125-02-9 0.535 Calcium Chloride CaCl2 10035-04-8 0.07 Magnesium Sulfate MgSO 4 10034-99-8 0.125 Ferrous Chloride FeCl2 13478 0.02 Sodium bicarbonate NaHCO3 144-55-8 2.0 Ferrous Ammonium Sulfate (NH4)2Fe(SO4)2 7783-85-9 0.4 Sodium sulfide Na2S 1313-84-4 0.12 Resazurin C 12 H 6 NNaO 4 62758-13-8 0.001 Boric Acid H3BO3 10043-35-3 0.0006 Zinc Chloride ZnCl 7646-85-7 0.0002 Sodium Molybdate Na2MoO4 10102-40-6 0.0002 Nickel II Chloride NiCl2 7791-20-0 0.0015 Manganese Chloride MnCl2 13446-34-9 0.002 Copper II Chloride CuCl2 10125-13-0 0.0002 Cobalt Chloride CoCl2 7791-13-1 0.003 Disodium Selenite Na2SeO3 10102-18-8 0.00004 Aluminum Trisulfate Al2(SO4)3 10043-01-3 0.0002 Vitamins Various Various 0.01 maximum Rev. No.: 0 Date: 8 March 2016 Page: 1 of 7 SAFETY DATA SHEET 1. CHEMICAL IDENTIFICATION AND COMPANY INFORMATION Product Name: KB-1® Primer Company Info: SiREM 130 Stone Rd. W., Guelph, Ontario, Canada N1G 3Z2 Phone: 519-822-2265 Toll Free, North America: 1-866-251-1747 Fax: 888-635-3470 www.siremlab.com Emergency Phone Number: 519-515-0840 (for 24/7 assistance, contact poison center hotline in your jurisdiction). Recommended Use: For preparation of anaerobic water for use in groundwater remediation. Restrictions on Use: KB-1® products are intended for laboratory research and field applications for groundwater remediation. Products are not intended to be used as human or animal therapeutics, cosmetics, agricultural or pesticidal products, food additives, or as household chemicals. 2. HAZARDS IDENTIFICATION GHS Classification: H302 – Acute toxicity, Oral (Category 4) H319 – Eye irritant (Category 2) GHS Label elements, including hazard and precautionary statements: Signal Word: WARNING Pictogram: Hazard Statements: H302 – Harmful is swallowed. H315 – Causes skin irritation. H319 – Causes serious eye irritation. H335 – May cause respiratory irritation. H402 – Harmful to aquatic life. Precautionary Statements: P264 – Wash hands thoroughly after handling. P270 – Do not eat, drink or smoke when using this product. P273 – Avoid [unintended or indiscriminate] release to the environment. Rev. No.: 0 Date: 8 March 2016 Page: 2 of 7 P280 – Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. P308 + P313 – If exposed or concerned: Get medical advice/attention. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/attention. P330 – Rinse mouth. P501 – Dispose of contents/container in accordance with local/regional/national regulations. HMIS Rating: Health Flammability Physical Hazard Personal Protection 1 0 0 E* NFPA Rating: Health Flammability Reactivity Special Hazard 1 0 0 N/A * E = Safety Glasses, Gloves, Dust Respirator. 3. COMPOSITION/INFORMATION ON INGREDIENTS Amino Acid (proteinogenic): 50-70%, C3H7NO2S Potassium Bicarbonate: 25-50%, KHCO3, CAS No. 298-14-6 Sodium Sulfite: 5-20%, Na2O3S, CAS No. 7757-83-7 4. FIRST AID MEASURES Avoid direct contact with skin and eyes. In any case of any exposure which elicits a response, a physician should be consulted immediately. Route of Entry Symptoms First Aid Procedures Ingestion Irritation of digestive tract. DO NOT INDUCE VOMITING. Rinse mouth. Give plenty of water to drink, do not give active carbon. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin contact Skin irritation – reddening, itching or inflammation. Remove contaminated clothes. Wash skin with plenty of water and soap. Eye contact Eye irritation – redness, tearing, blurred vision. Rinse immediately with plenty of water for 15 – 20 minutes, lifting lower and upper eyelids occasionally (remove contact lenses if easily possible). Seek medical attention if undue irritation or redness occurs. Inhalation of dust Respiratory irritation, coughing. Safely remove victim to fresh air. If not breathing, institute cardiopulmonary resuscitation (CPR). If breathing is difficult, ensure clear airway and give oxygen. Get medical attention. Rev. No.: 0 Date: 8 March 2016 Page: 3 of 7 5. FIRE FIGHTING MEASURES Suitable extinguishing media: Water in copious quantities, carbon dioxide, dry chemical powder, or appropriate foam. Use extinguishing media suitable for surrounding fire. Special protective equipment and precautions for firefighters: In the event of a fire, wear full protective clothing and NIOSH approved self- contained breathing apparatus. Evacuate the area and fight fire from a safe distance. Hazardous combustion products: May emit toxic fumes under fire conditions. Toxic gases produced: Carbon monoxide, carbon dioxide, nitrogen oxides, potassium oxides, sulfur oxides Shock/impact sensitivity: Not shock sensitive. 6. ACCIDENTAL RELEASE MEASURES Ventilation: If released in ventilated fume hood, ensure fume hood is on. If released in general room environment, open windows and provide adequate ventilation. Eye/skin protection: Have eye-washing facilities readily available where eye contact can occur. Wear chemical safety goggles. Use appropriate chemical protective gloves when handling. Showering and changing into street clothes after work is recommended. Protective equipment for airborne dust: A NIOSH/MSHA approved air purifying respirator is recommended where airborne concentrations are expected to exceed exposure limits. Protection provided by purifying respirators is limited. Wear suitable protective clothing and a self-contained breathing apparatus if available. Method of containment and cleanup: Wear suitable protective clothing. Avoid dust formation. Avoid breathing dust. Carefully sweep up and remove. Place material in a dry container and cover. Remove from the area. Flush spill area with water. Do not let products enter drains. 7. HANDLING AND STORAGE Handling and storage precautions: Store in a tightly sealed container in a cool, dry and well- ventilated place. Store away from direct light. Avoid generation of dust. Do not breathe dust. Wash thoroughly after handling. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Incompatibilities: Segregate from strong oxidizing agents, acids, bases. Rev. No.: 0 Date: 8 March 2016 Page: 4 of 7 8. EXPOSURE CONTROLS/PERSONAL PROTECTION OSHA Permissible Exposure Limits (PELs): Not established. Not established. ACHIH Threshold Limit Values (TLVs): Engineering controls: Generally not required under normal conditions of use. If method of use will result in significant dust generation, use in lab hood or under conditions of adequate ventilation. Work practices: Use good hygiene practices, avoid dust generation. Personal protective equipment (PPE): Under normal conditions of use, wear safety glasses and protective gloves. For laboratory use, wear lab coat. For higher risk of eye contact, wear safety goggles or face shield, as appropriate. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White to off-white powder or granules Odor: Odorless Solubility: Soluble in water pH: 6 – 8 Melting range: No data Vapor density: N/A Vapor pressure: N/A Relative density: 2.4 to 2.6 g/cm3, depending on formulation Evaporation rate: N/A Initial Boiling point, boiling range: N/A Flammability: N/A Partition coefficient: N/A Auto-ignition temperature: N/A Decomposition temperature: No data, decomposes by heating Flash point: Flammable limits: N/A N/A 10. STABILITY AND REACTIVITY Reactivity: Stable under normal conditions. Hygroscopic – absorbs moisture from air, affecting product quality. Possible decomposition at high temperatures. Chemical stability: Stable under normal conditions. Possibility of hazardous Stable. Spontaneous hazardous chemical Rev. No.: 0 Date: 8 March 2016 Page: 5 of 7 reactions: reactions/decomposition will not occur. Hygroscopic – absorbs moisture from air, affecting product quality. Reacts with acids, bases, oxidizing agents, chlorine trifluoride, magnesium, metals, carbon, calcium oxide. Conditions to avoid: Incompatibles, may be sensitive to light and moist air. Incompatible materials: Strong oxidizing agents, bases. Hazardous decomposition products: Carbon monoxide, carbon dioxide, nitrogen oxides, sulfur oxides, potassium oxides. Shock sensitivity: Not shock sensitive; will not decompose and form shock sensitive compounds. 11. TOXICOLOGICAL INFORMATION The toxicological properties of this product have not been thoroughly investigated. Amino Acid Potassium Bicarbonate Sodium Sulfite Toxicity: LD50 (Oral-Rat)(mg/kg): 1890 2064 2610-3560 LD50 (IV-Rat)(mg/kg): 1140 No data No data LD50 (Oral-Mouse)(mg/kg): 660 No data No data LC50 (Inhalation-Rat)(mg/m3) No data >4880 >5500 LD50 (Dermal-Rat)(mg/kg) No data No data >2000 Carcinogenicity: NTP: No component of this product is identified as a probable, possible or confirmed human carcinogen. IARC: OSHA Z List: OSHA Reg: Teratogenicity: Not established – the chemical structures of components do not suggest a specific alert for these effects. Mutagenicity: Reproductive: Respiratory or skin sensitization: Not established Specific target organ toxicity: Respiratory, skin, eye irritant, bladder, kidney Effects of overexposure: Irritation, itching, gastrointestinal upset, respiratory discomfort, blurred vision. Medical conditions aggravated by exposure Chronic lung conditions, dry eye Routes of entry: Ingestion, inhalation of dust, skin and eye contact. Rev. No.: 0 Date: 8 March 2016 Page: 6 of 7 12. ECOLOGICAL INFORMATION Ecotoxicity: Components of this product are not considered to exhibit significant ecological risks. Persistence and degradability: Amino acid is not persistent in the environment; will readily degrade in the environment via biodegradation. Sodium sulfite and potassium bicarbonate are inorganic products not subject to biodegradation, but will degrade via other chemical processes and are thus not persistent in the environment. Bioaccumulative potential: Significant accumulation in organisms is not expected. Mobility in soil: Soluble in water, high mobility in soil. 13. DISPOSAL CONSIDERATION Waste Disposal: Dispose in accordance with all applicable federal, state, and local environmental regulations. Container Disposal: Dispose in accordance with all applicable federal, state, and local environmental regulations. 14. TRANSPORT INFORMATION Domestic (D.O.T.): Proper Shipping Name: Hazard Class: UN/NA: Labels: CHEMICALS, N.O.S. (NON-REGULATED) Not applicable Not applicable Not applicable International: IMDG: Proper Shipping Name: Hazard Class: UN/NA: Labels: CHEMICALS, N.O.S. (NON-REGULATED) Not applicable Not applicable Not applicable IATA: Proper Shipping Name: Hazard Class: UN/NA: Labels: CHEMICALS, N.O.S. (NON-REGULATED) Not applicable Not applicable Not applicable 15. REGULATORY INFORMATION TSCA: Yes SARA TITLE III Section 302 (EHS) Ingredients: No Section 313 Ingredients: No Section 304 (EHS/CERCLA) Ingredients: No SARA TITLE III NOTIFICATION INFORMATION Acute Health Hazard: No Rev. No.: 0 Date: 8 March 2016 Page: 7 of 7 Chronic Health Hazard: No Fire Hazard: No Sudden Release of Pressure Hazard: No 16. OTHER INFORMATION SiREM provides the information contained herein for hazard communication and safety planning purposes, based on existing information on each of the product components available in the literature; no independent testing was conducted on the final product. The above information is intended to be used only as a guide to the appropriate precautionary handling of this material by a properly trained person. Material Safety Data Sheet Material Safety Data Sheet May 11, 2011 Page 1 Rev Date: April 14, 2014 Nutrimens® - Liquid Bioremediation Nutrient Section 1: Chemical Product and Company Identification Product Name: Yeast Fermentation Product Catalog Codes: Nutrimens® Liquid CAS#: TSCA: NA HMIS Code: NA Trade Name and Synonyms: Nutrimens® - Liquid Chemical Family: Yeast Fermentation Product Contact Information: Tersus Environmental, LLC 109 E. 17th Street, Suite #3880 Cheyenne, WY 82001 Ph: 307.638.2822 • info@tersusenv.com www.tersusenv.com For emergency assistance, call: 919.638.7892 Section 2: Composition and Information on Ingredients COMPONANT CAS # OSHA TWA OSHA STEL ACGIH TWA ACGIH STEL No known hazardous ingredients present. --- --- --- --- HAZARDOUS INGREDIENTS: NONE AS DEFINED UNDER THE U.S. OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) OR THE CANADIAN HAZARDOUS PRODUCTS. ACT S.C. 1987, C.30 (PART 1). SARA HAZARD: NONE NOTED (SECTION 311/312) TITLE III SECTION 313 - NOT LISTED All components of this product are listed on the TSCA registry. Section 3: Physical/Chemical Characteristics Boiling Point ................................................................212 degrees F Vapor Pressure (mmg Hg)........................................... N/A Vapor Density (AIR = 1) ...............................................N/A Solubility in Water......................................................... dispersible Appearance and Odor...................................................brown viscous liquid, yeast aroma Specific Gravity (H2O = 1) ........................................... .N/A Melting Point..................................................................N/A Evaporation Rate ..........................................................N/A (Butyl Acetate = 1) Section 4: Fire and Explosion Data FLASH POINT (METHOD USED) ....................................... N/A FLAMMABLE LIMITS........................................................... N/A LEL....................................................................................... N/A UEL...................................................................................... N/A EXTINGUISHING MEDIA .................................................... none SPECIAL FIRE FIGHTING PROCEDURES ........................ none Material Safety Data Sheet Material Safety Data Sheet May 11, 2011 Page 2 Rev Date: April 14, 2014 UNUSUAL FIRE FIGHTING HAZARDS .............................. none Section 5: Reactivity Data STABILITY: Generally stable. HAZARDOUS POLYMERIZATION: Will not occur. Section 6: Health Hazard Data Based on specific concentration as sold ROUTE(S) OF ENTRY: Inhalation HEALTH HAZARDS (ACUTE AND CHRONIC)................... Respiring yeast generates carbon dioxide. Over exposure to carbon dioxide gas may cause asphyxiation. CARCINOGENICITY: .......................................................... No NPT...................................................................................... No OSHA REGULATED............................................................ No SIGNS AND SYMPTIONS OF EXPOSURE ........................ Over exposure to carbon dioxide include: stupor, dizziness, unconsciousness, death. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ....................................................... None known for this product. Over exposure to carbon dioxide may aggravate certain medical conditions. EMERGENCY AND FIRST AID PROCEDURES ................ If exposed to carbon dioxide, move to fresh air. Give respiratory support if needed. Seek medical attention. Section 7: Precautions for Safe Handling and Use STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Conventional cleanup WASTE DISPOSAL METHOD: In accordance with Federal, State and Local regulations PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a cool area. OTHER PRECAUTIONS: None Section 8: Control Measures RESPIRATORY PROTECTION (SPECIFY TYPE): Confined spaces that held yeast fermentation product could potentially contain carbon dioxide gas. Use NIOSH/MSHA approved self-contained breathing apparatus or supplied respirator if oxygen content below 19%. Use in accordance with 29 CFR 1901.134 IS RESPIRATORY PROTECTION NECESSARY: UNNECESSARY IF VENTILATION IDENTIFIED BELOW IS USED VENTILATION LOCAL EXHAUST: Use adequate mechanical ventilation. Material Safety Data Sheet Material Safety Data Sheet May 11, 2011 Page 3 Rev Date: April 14, 2014 PROTECTIVE GLOVES: Work Type EYE PROTECTION: Safety glasses a good practice OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None HYGENIC PRACTICES: Good manufacturing practices PROTECTIVE CLOTHING UNNECESSARY IF OTHER CONTROL MEASURES ARE USED Section 9: Disclaimer and/or Comments We suggest that containers be either professionally reconditioned for re-use by certified firms or properly disposed of by certified firms to help reduce the possibility of an accident . Disposal of containers should be in accordance with applicable federal, state and local laws and regulations. "Empty" drums should not be given to individuals. The conditions of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Tersus Environmental be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Tersus Environmental has been advised of the possibility of such damages. * Nutrimens® is a registered trademark Tersus Environmental, LLC. Application for Underground Injection Control Permit – Attachments 60625953 Prepared for: Cintas Corporation, Milford, Ohio AECOM About AECOM AECOM is built to deliver a better world. We design, build, finance and operate infrastructure assets for governments, businesses and organizations. As a fully integrated firm, we connect knowledge and experience across our global network of experts to help clients solve their most complex challenges. From high-performance buildings and infrastructure, to resilient communities and environments, to stable and secure nations, our work is transformative, differentiated and vital. A Fortune 500 firm, AECOM had revenue of approximately $20.2 billion during fiscal year 2018. See how we deliver what others can only imagine at aecom.com and @AECOM. AECOM 1600 Perimeter Park Morrisville, NC 27560 USA T: 919.461.1100 F: 919.461.1415 aecom.com