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HomeMy WebLinkAboutCliffside Errata 5-5-20161P synTerra CORRECTIVE ACTION PLAN UPDATE REVISED: APRIL 23, 2020 Site Name and Location: Cliffside Steam Station 573 Duke Power Road Mooresboro, NC 28114-7754 Groundwater Incident No.: Not Assigned NPDES Permit No.: NC0005088 NCDEQ CCR Impoundment Ranking: Active Ash Basin Low -Risk Former Units 1-4 Ash Basin Low -Risk Unit 5 Inactive Ash Basin Low -Risk Date of Report: December 31, 2019 Permittee and Current Duke Energy Carolinas, LLC Property Owner: 526 South Church Street Charlotte, NC 28202-1803 (855) 355-7042 Consultant Information: SynTerra Corporation 148 River Street, Suite 220 Greenville, SC 29601-2567 (864) 421-9999 Latitude and Longitude of Facility: N 35.209267/W-81.761258 FIGURES A (SOUTH) - AN (NORTH) ACTIVE ASH BASIN —I ILn In POSSIBLE RADIAL GROUNDWATER FLOW N N IN THIS AREA n rn c CCR oaD � 800 3 m m N a s rn rn B6 � Q m 800 2 s Li LO a 3 U a �� � m mmmm m mm m L) mm A6N mm aaaaaa aaa so 22 �a� a a WATER IN BASIN AB 04UA15 ASH SAPROLITE TDS 84 ------------ - __ ----------------------- -- B zB13 -_- —TER BASIN -------------------------------------- - _ __s__ ��--------------------- Aaass -------------- ----------------------------------- - --- ---------- --- ----- --- ----------------------------------- 750 nNrvu-os=____�__�__�____— = e B3ao _=-=�===�================ _�_-== soa 12s _=_-_=_== - Across B 2ts 750 GWA-25S B <50 ___ - - _ __ _= Li ID3 _ __ ___ _-TDS __ __ ____ _____ 8 5910 _ __ __ _ _ ______ __ _ __ __ _ _ _ ___________ __ e <so D L1 ______ m -ASH PORE WATER -=====_== ---- _ _ LI lob =___-_ __-_ __-_ __ — \ , B so s04 SAPROLITE - _____- _= TDS 377 ________ = A&��ss ___ _= SAPROLITE 504 739 ______ ____ ____ _____ / _ 504 60 <1 - _ _ _ -- -- -- -- Li 25 _ _ ______________ __ __ __ _____ __ _ B 606 r _________________ TDS 189 \— / __ Li 14.5 TDS 415 \ so4 1 ros 3a = =�=== _====� ' soa a TDS 3$ TRANSITIONZ ___ ___ __ ___ ___ ___ ____ _____ _____ rylyy-70D - ♦ - \ / /� \ \ B A&O8D pool- � _ 504 1 — B A&09Dn ,` N N N N 700 \ K I / \ \ / I / \ = TDS 77 I / \ Li 3.4 TR ZONE /I so4 16 7 i \~�q� FILL Q Q Q Q 700 AB045L `/ •/�/\II ros 4s / /1�-T w / ��1�1'/♦/ i /� C9C9C9t�9 ,;—ALLUVIUM / e Lwb _ / � .v / 1 34 Ae-oeeR /—� — / `—_ //♦ 56.5 ac50 /. / \I — \/ _\'♦. //\� \ \,\. / \I r,--♦/\ —�\�/ — /� —1'/ BROAD RIVER <50 31 00 65T 00 172 0 650 \'/ — \ 1'/ — \ —\ ? soa 5 \ —\'/ \ —\'/ A8-o4s — \ —\�/ — / 1 \ ` ram/ \/\ /1 / I/\ �/ �/ / \//\ / I/\ GWA-zu 650 — / ` �� / \ / �' \ _ / \ \ ♦ / so4 1s ♦ — / \'/.—_ / / — \ i I \ \�>w l / / \� \ / I / \— l / I / \— / / / \� \ zs13 / / i \ / I ♦ — \ / \— 1'/.-- \ � /— \ � / —�\ B \ , i \ I _ \ , i \ , i \ I \ , I \ ros uF \ / / l \ / I \ l / / I ♦ / I ` / — — 8 1s6 14`/—/\I \/I 1\/ /\I ♦/\/\I 127 ♦/\/ I/1 /\I ♦/`/\��; I♦/\/—\,♦/—_/ /�_IY \ 1 Li L9\/1 _ Q - ��/ \ \ / / 1 — 1 ' n AB-04BR I i /_ — \ % i' `♦— \ \ 1 e aoa / a \/� / I / / \ / I � \�� \ / I' / \ / I � \/� \ / Irk// / \ / I � \/� \ - / \/� B \ ♦ y — 1' \ � / — ` ` /\ / \ so4 36 i I / _ / 'ros zaD S� / Z / \ I �� / _ I ♦ / / \ I ` / _ I \ / / \ I ` / _ I \ / / \ I ♦ A&MD / / \ . Li SS I �f�, / I / \\ / I ��1►Y 302 \ I 1 AB-018ROR \ / GWA-naR Z 600 <so \ soa 4 / 1 / / \ / — ` I ` / — \ fd / — \ — \ ' / — \ \ 8 397 / / — 600 Z O BEDROC)i'!.' \ — \ i /\ \ \ \ 1 /♦ / \ — \' /\ \ /\—/ sofa <1 \ \ j TDS 120 \ \ i' 1 / \ ; /; 1 / \ / \f / 1 / /r{ `�'� i`./ I \\ \� /I \� \ 1 / /� Li 6.9 \ \ Li 7.0 / \♦/ I O \_ %./I/`\�i/I \ \�./ �\'i /I ` %./I/\�f',\/I \\ %./I/ ros 3D \ %./I—\\/ ',}�' / /\/I,\ j ♦i—� \/—\ I /♦/—/\I ♦/I soa a La t'� SO4 <1 /♦/ \ ./ — — `K\ ./ — _ I/—f\ ♦/ — — I \ _ \/—\ ♦ / I—\ \,\/ — / I \\/ \/\ /1 \ /1/ \/— I TDS 364 \/_ I Q\/\II/1\\/\Il/1`/Il\I/1♦\/\/1/\/\I/1\/��,/I/1/�\/\I/1`���H/—/\I ♦/—\ I♦/♦�--\—\'/♦—\-1�/♦—_\— \ �`/1 ,./ ros 237 \/1 r 1- I !� I'/.— I Y. /�—�'`.— I /; —I \ /� 1 �\ /1/�\/\/1 /I/\ / / . /. \/I/\\-1.Y \—�.--\— -,/— \ \i♦jj � F�/�\i♦j� � , / \i\j�''� ,I/ \i\jj �'T-• ,I/�\i\"/1 4 /�/_li� I \ ,♦/—lei 1 T� ,♦/_•i. � 1Z��,�/— \ W 550 ♦ /��� \�/ \ \/ �� ♦ / \ —\'/ —\ \ —1/ ♦ /,Y►i�\'/ —\ \/ �� \ / \ —\'/ —\ \ —\/ ♦ / \ —\'/ —\ \/ �� ♦ / \ —\'/ —\ \ — / 1 /\I 4/\/\ /1 /\/\I 1`/ \/\ /1/ \/ I swA-z1sm: /1/ 550 —/ —/ \ \ / / —/ \ \—/ / \ \ / / —/ \ \ - \/I�%�— \ /1/ /— / /— W BEDROCK /I/\i� I/\� \/I/y`\/./ • \-1'/— \-1' \—I'/— \-1' \-1 / B 213 \ I \/— I ./ I ./— I ./ I ./— I ./ I ./— IO \/ I ./— I ./ I ./—\ I♦/./�\/\I/1\//�/ / \ ♦—/ ♦—/ `// — Li 9.8 W / 1 / / 1 / \ / \ / T� \ / \ / 1 / \ / \ / 1 \ / \ / 1 / \ I t \ / I / \ GwA-saBRt I \Lu _ _�_ /♦_ram—\�/♦__�_ /`__\�/\_ \ /;1/.--\ /\/�\� _\/I 8 236 /\ _\/I♦/\�\\, SO4 z /\i- / i — \ /♦ \ \ /♦/ — — \ /♦—_ \ 1 /♦/ —� — \ /♦—_ \ — 1 / /`/\I TDS 268 / 1 \ I_\/i \/I/\/� ` I_\/i \/I/\/� ` I_\/i \/I/\/� ` I_\/i \/I/\/� ` I_\/i \/I/\/� ` I—`/i \/I/ _\�♦/—_/ \ /1/�— Li 43.S / I♦/♦/I♦/\/I♦/\/I♦/♦/I♦/\/—\/I\/`/—\/I\/♦% \/\I/1\//—�—\�/♦—_\ 1/ SO4 21 --\—\�/♦�—;-1�/♦--\—\//♦�—%- 500 /1/ \/\/1 \/\/1/�\/\/1 \/\/1/�\/\/\ \/♦/1/�\/\/1 \/\/1/�\/\/1 TDS ias I \/�� I—\/i \/I/\/i� I \-500 /\—/ \ —_\'/\ � \ \ //♦—/ \ —_\'/\ \ \ 1 //`—/ \ —\'/\ � � —1 //♦—/ \ —\'/\ \ \ 1 //♦—/ \ —_\'/\ � \ 1 //\—/ \ —_\'/\ \ \ \ �/\\/ i, 1\ /�/\I/1\ /\/\I/1 � \/`I/1`/ \/\I/1\ /�/\I/1\/\/\I/1` / \/I/\il\/I/\\� \/I/\il\/I/\\� \/I/\il\/I/\`� \/I/\il\/I/\`� \/I/\il\/I/\`� \/I/\il\/I/ \\,♦/—\—/\ /—/�-1'/—/\ /—/—1'/—/\ /—/�-1'/—/\- `/\/\I/1��\/\I/1`/\/\I/1/�\/\I/1`/\/\I/1��\/\I/1`/�\/\I/1, \ / \ — 1 /♦—_ \ \ `/ - \ — \ /♦—_ \ \ `/ - \ — \ /♦—_ \ - 1 / `/ - \ — \ / /`/ i l i l \ i l /♦/ i l i l \`/ i U 450 ,IF RACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED — \ / / — _ \ / . / — \ / / — — \ / • / _ \ / / I ♦ / —_ \ — \ ' /\—_ \ 1 ' /♦—_ \ — \ ' /� — s04 — 1 ' /\-- \ \ ' /♦ \ — 450 / ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE /\ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANE OF THE CROSS SECTION, AND —\'/ —\ \ \'/\ / \ —\'/ —\ \/ \'/� / \ —\'/ —\ \ — / \/\/ 1`/��\I/�`/�/`I/1\/��\I/�\/ \/\ /1 /��♦I/�`/�/\I/1`/ \\VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO//I/\`/`/I/\/\\/I/\��/`/I/\/\\/I/y`�i\/I_\_/\_\'/—/\-1'/—/\—\'/—/;_\'/—/\-1'/—/\_\'/—/\ /ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH I j \ / \I / 1 ` / \ �I / ♦ / \ I / 1 ` / I / \ /� \ / \ I / 1 �/ I / \ / \�/ I / \\ i / \♦/ I / \ l \�/ / \\ i l \�/ I / \ / \\/ I / \` i / \ / I / \ /♦-ARE CONCEPTUAL ONLY. _ / — / \ /\_ / \ / / 1 / \ /\— / \ / / 1 / — 1 /.77 \ / \ / \ / ♦ / _ \ /I \ \ \ , . / _ \ /I \ \ \ , ♦ / _ ♦ /I \ / 400 400 NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. .. ;' FORMER UNIT ASH BASIN ASH -CLIFFSIDE\ �1 C STOR A STEAM Ilt STATION chi UNITS /Y 3¢ INACTIVE �N ASH BASIN O�F9ROHp CCP LANDFILL a 1- ACTIVE I: H BASIN J NOTE: CROSS SECTION A -A' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION LEGEND GWA 25S WELL IN SHALLOW FLOW LAYER GWA 25D WELL IN DEEP FLOW LAYER GWA 21BR WELL IN BEDROCK FLOW LAYER AB-6S WELL IN ASH PORE WATER — GENERALIZED WATER TABLE GENERALIZED BEDROCK FRACTURE ORIENTATION GENERALIZED GROUNDWATER FLOW DIRECTION ASH L—� ASH PORE WATER ® FILL SAPROLITE ® TRANSITION ZONE BEDROCK ALLUVIUM 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER V ASH PORE WATER ELEVATION LITER (Ng/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) SHALLOW GROUNDWATER ELEVATION - WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. V DEEP GROUNDWATER ELEVATION -NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS BEDROCK GROUNDWATER ELEVATION REPORTING UNITS 700 g/L uNE 250 Soo 15A NCAC 02L STANDARD 700 NE 250 S00 GWA-60RL MEAN BORON (B) CONCENTRATION (ug/L) BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' SO 3 4 57 B Li 236 MEAN LITHIUM Li CONCENTRATION �/ L ( ) (NH ) BACKGROUND THRESHOLD VALUES so 12 15 107 (TRANSITION FLOW ZONE)' soa 43.5 21 MEAN SULFATE (SO4) CONCENTRATION (mg/L) BACKGROUND THRESHOLD VALUES TDS 348 MEAN TOTAL DISSOLVED SOLIDS (TDS) SO 11 17 120 (BEDROCK FLOW ZONE)' CONCENTRATION (mg/L) UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. WELL SCREEN NE - NOT ESTABLISHED COMPLIANCE BOUNDARY �' DUKE 0 100 200 400 FIGURE 6-8a GENERAL CROSS SECTION A -A' ENERGY HORIZONTAL SCALE: 1-400' VERTICAL SCALE: 1"=80' CONSERVATIVE GROUP CAROLINAS SXVERTICAL EXAGGERATION MEAN OF BORON, LITHIUM, SULFATE AND TOTAL DRAWN BY: J. CHASTAIN DATE: 10/22/2019 REVISED BY: D. KREFSKI DATE: 3/2/2020 DISSOLVED SOLIDS (TDS) CHECKED BY: T. GRANT DATE: 3/2/2020 ACTIVE ASH BASIN APPROVED BY: S. SPINNER DATE: 3/2/2020 CORRECTIVE ACTION PLAN UPDATE PROJECT MANAGER: S. SPINNER CLIFFSIDE STEAM STATION synTem www.synterracorp.com MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 A (SOUTH) ACTIVE ASH BASIN LO Ln POSSIBLE RADIAL GROUNDWATER FLOW Nc� IN THIS AREA 0 Ln 800 �� g 7fJ/1NO m Nm G � ASH aaaaaa aaa __z--- __ __ aaa WATER IN BASIN AB-04UA15 ASH __---------------------------- As 923 _____________________ _____ �� _=-==_=-===-== _-�___] AB-0ss �� sr znB - =- - - - �--�-- -- Ae4a9s 750 CO 00 Q650 Q Z 600 O > 550 I.I.I J W - AN (NORTH) � J m � N O �-S IL) iaa� SAPROLITE MW-1Q5 WATER IN BASIN WATER IN BASIN 800 GWA7255 QNNYHl6 ---- --- --- --- -- = As 323 = —_—_ —_— —_— —_— =-- ____ _____= u (total) O.Oo01 =__ _ —_ _ _ _ __ _ ___ = As 19bs = As al 750 AS '(11As <al =___ __ __ __ — _= Sr 2510 =__ (total) aam0 -ASH PORE WATER==_- - _ ___ u (total) QOD19=__—___—_______—__— V a3 ,� � (total) SAPROLITE ___= -- V &9 __ __ = AS 184 -= SAPROLITE_-___-___ 1 \ / _ / `U (total) = -------------------------- - __ ___ ____ -___- -___- -___- -___--________ - _ _ _ __ _ / \ J ___________________________ V <0.3_______________________________________________ Sr 3w A609D __ MW-IOD \ \ / AB-015 U (total) a0001 AS Q2 _ A5 <Ql / / / - / \ \ AS 0.3 :�i m m m V L4 sr az TRANSITION / sr 51 I \ \ \\ /I / sr 32HHH4N N N N \ _ i •/- \\� / I / \ / As al - I / \ I / \/ , u (total) aaool I / \ u!E �- OL- I / u RaraO aaoo3 700 `•�- ` ' \ / a ABML I . / \ / _ - v a3 ZONE / \ / �,( w'(\ / \ \ Q Q Q a \/\>6d�_�/\I/\ \/\ As 169z /1 ' �► \'/.-'�-\ v as 3��� ALLUVIUM AB 06BR/ Sr Iv / / / I \• / / /� Vr Vr Vr V' I/\ / / / /�� I/\ / / / /�/IUtota amw '/-\\♦\'` ♦\-1'/-\\ /�/-\•'`/-_%\I` - BROAD RIVER _ / ; `. /I - \ , •� ` As <a1 _ / \ \` /I - \ \' (v ) as.9 \. /I - \ \ , AB09BR \\/ / / \ I \ \/ / `\.� ri \ ` / _ _\ / _ ./ \ /'. / \I I / \I As a3 I \ ♦ / - \' I rj�/ �_ v ♦ �- / GWA-23500 1 / \ �.�\ / 1 (total) <o.000s 1 / \ / \ / 1 N` AB-M _ / _ /_I sr / \ _ �I. % \ I i ` /\/ \ / \\ ♦ \ Sr zw \ ` 65T 650 1 1, / As 926 / \\ \ '. ♦\u(taral) aaom /1♦�\ ).1, /\ / - \ Sr zm7 \\/ 1 / \`� / / I / v a3 \`/ / / \\/ I / \ // / / /\ / /I \ /� ♦I u(taral aooB6 tool i/ \\`•. s az v az AweEner01 \ `O/\/\I/1��/-/\I \/\i`rl 1/\I \/\/\I (total) 0.00061 \/\/\I /\/~� I\'\/-\�-� / ♦ _\Y/ r 256 \ sr 174 \/1 / \ / 1 / r \ / 1 ( / \ / 1 als / 1 ABOImt \ 1 ,� I _ \ ' \-- \ Q s 1 \ \ �'/ \ / \ / \ / 1 / I / \ / Gal)- \/i AB-07D-.. I / \ / �\ r 1as I / \\ \ - / �y \ - \ \ \ /` / - \ /I � /\ /_-/ \I as AB-o16rt0.2 Sr a \/\ V _ ♦�/ �Y►Y \ I \- / /- _�\ \ Sr 268 / GWA-21BR co. � � \ / 1 / \ I / 1 u(taraD <o.aoos i'1 uRaral) - 1' \ / i�/I/\,!U(taral)< , / \/\I/1i\I�/\I/1M•\►<I./\��/\I/1` \ /\71 `,1�`-/` \AY `!1/; 7 7-`,,�\-1•:Y 14 —550 \ I \ LU \- i BEDROCKS I;\ s�9,/I \•� s� s�\'�'\ w /\-_ _ / / - 1 /.-_ \ _ / ♦ - \ /\-_ u (carol) <o.aooz I / \ / i \ I•j \ \ I_\/i \/I/\/�� I_\/i \/I/\l�� I_\/i \/I/\l�� I_\/i \/I/\l�� I_\/i \/I/\l�� I_\/i \/I/)_\/./--/� ♦�- - _�03 /�_ V o.3 /\�� \ -_\i/ -� � \1'/\�� \ -\%/ -� � `\'/\�� \ -1%/ -� � \\'/`�� \ -\%/ -� � `\'/\�� \ -\ i/ -� � \1'/\�� \ -\%/ -� � -\ i/\ \ \\;�\-� ♦I./\�-/\I/1��\/\I/1`/ \/\ /\ /�/\I/1` /\/\I/1�/ 500 _\/\/\\/\/1/\/\I/1`/\/\I/1/\/\I/1\/\/\I/\♦�\/\I/1`/\/\I/1/�\/\I/1\/�\ /1/ /I/\i/\/I/\`�� /I/\i/\/I As \�- �- \-\/\--; \/\�- utaral - \/\I/1` .FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED / i 1 \ - / ` I _ \ - / ` I _ y _ \ / __/ _ ♦ __' _ / (total) _ _ /ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE / /\I\/l' V \ i l /\/ l \\/ I i 450 /ORIENTATIONS /-�\♦�/-`-�'./-�\ice/I-\_\'�/-�\ice/1-\_\/�/- ACCOUNT FOR APPARENT DIP WITHIN -1'/\ \-�// \ 'VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO \� / I / \ \ /I \\� / I / \ ` /I \\� / I / y \ ' / - \ - \ /\ \ \ \ /\-♦ \ - \' /\ \ \ \ /� / \ - \' /\ \ \ \ /ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH ARE CONCEPTUAL ONLY.-\'./.-\'\i/\--\�\'./.-\-li/�-\�\'./.-�\ vx/-, ♦/-�.I�'\/.-i.l �/-`.lam'\.-:.1..\/-`_lam/\.-:.1-'`♦ NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON LEGEND CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. ARSENIC (AS), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE eR�go GWA 25S WELL IN SHALLOW FLOW LAYER V ASH PORE WATER ELEVATION IN MICROGRAMS PER LITER (pg/L). TOTAL URANIUM (U) CONCENTRATIONS ARE Ri�FR IN PICMICROGRAMS PER MILLILITER (pg/m L). GWA 25D WELL IN DEEP FLOW LAYER * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE WELL IN BEDROCK FLOW LAYER SHALLOW GROUNDWATER ELEVATION MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. \ GWA 21BR - NO DATA AVAILABLE FORMER Q AB 6S WELL IN ASH PORE WATER V DEEP GROUNDWATER ELEVATION ANALYTICAL PARAMETER As Sr U V `UNITS I4 _ ASH BASIN -/ ASH - . REPORTING UNITS pg/L pg/L pg/mL pg/L CLIFFSIDEN 1, STORRAAGE _ GENERALIZED WATER TABLE STEAM \ �` STATION - AcnvE GENERALIZED BEDROCK FRACTURE UNITS 3 / r ASH BASIN ����� ORIENTATION GWA-6IBIa ASH BAISINGENERALIZED OUNDWATER Sr 4 FLOW DIRECTION u(taral) a rou v <a3 ASH ASH PORE WATER FILL 'LANDFILL DFILL - 9aw . - SAPROLITE - - - 1 ® TRANSITION ZONE '-- NOTE: i BEDROCK -," CROSS SECTION A -A' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE ALLUVIUM - PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION BEDROCK GROUNDWATER ELEVATION MEAN ARSENIC (AS) CONCENTRATION (ug/L) MEAN STRONTIUM (Sr) CONCENTRATION (ug/L) MEAN TOTAL URANIUM (U) CONCENTRATION (ug/mL) MEAN VANADIUM (V) CONCENTRATION (ug/L) WELL SCREEN COMPLIANCE BOUNDARY 'DUKE ENERGY CAROLINAS ,4WA synTena 15A NCAC 02L STANDARD 10 NE NE 3* (SHALLOW FLOW ZONE)l 0.2 34 0.0005 1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 0.0005 11 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 1 93 0.0005 1 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019, 0 100 200 400 HORIZONTAL SCALE: V = 400' VERTICAL SCALE: 1" = 80' 5X VERTICAL EXAGGERATION DRAWN BY: J. CHASTAIN DATE: 10/22/20 REVISED BY: D. KREFSKI DATE: 3/2/2020 CHECKED BY: T. GRANT DATE: 3/2/2020 APPROVED BY: S. SPINNER DATE: 3/2/2020 PROJECT MANAGER: S. SPINNER www.synterracorp.com FIGURE 6-8b I GENERAL CROSS SECTION A -A' NON -CONSERVATIVE GROUP MEAN OF ARSENIC, STRONTIUM, TOTAL URANIUM AND VANADIUM ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 A - A' (SOUTH) (NORTH) ACTIVE ASH BASIN - Lo U, POSSIBLE RADIAL GROUNDWATER FLOW M fV IN THIS AREA In m a _j 800 3 a cw _j -1� mmmmmm mm aaaaaa aaa �aa� WATER IN BASIN AB MATS ASH SAPROLITE -------- -- _ _ --- __________S____C. <al — _ _________ ____ERINBASIN 41k WATER IN B IN-----T------ 00 00 1 Q 650 'a Z 600 O Q W 550 J Lu 400— Fe 144 ----------- _- Mn ________________________ _______=J J ___ _ _ _ _____ Fe 1I? _'_-�— 1 / \/i / Mn 165 SAPROLITE PORE WATER -------- ASH _----------------- / \ _ —___-_ _= TI <0.1_______________________ __ ________ � 5 ---- — SAPROLITE Mn 43 _____ __-- __-- __-- __- Mn 197 \ / — \ CCR-M I GWA-255 __ _-- -- -- -- -- —____ AB-O6D .►_ TI 0.3 _ Co 12020TRZONE/ Mn 92 / 1�-06a6 ALLUVIUM / �7 w \ /\-/ \ _ \ / - \ \ / \ / Rs� \ I \ / Fe 1478- _ / _\ / `/ -\ \/ `/ I_\\ \- / / 1 /\r\ /\ Mn MA5 BROAD RIVER Co SLY /\/-\/\/ -\ I rl alI I \/ / I/ \ \ I/\ \ / I/ / ti� /\ \ / '�V 1 \ / \ I / \ ♦ \ / \ / 1 / \ �.\ / Fe aua 1 \ / \ I / 1 \ �� /� / \ ♦ / \ / 1 AB-a9BR \/ / \ \ \ / \ / ���_ \ — \� / — / \ — \ ' / rI as — 657' Co 0.2 -1'/L�\-_\'/-♦\-1'/\-/\-1 ? Mn ®_ /\-\'/:�\-\ / AB -\ . /\ Fe 2035 /\ \�� I_)yi \/I/\�/ I \i \ I \i \/I/\�i Fe <s0 / /\ \ I Mn 91 \ l / i // /♦/� / ♦/ ♦/-\\ -\\ _\I♦/\/-\/���--\I..i-\\/�/-+.\ /-\\/\/-_\ ./-_\/�/♦/TI <0.1 //I/\/���/I_\/i�/I/\1/�\/\I/\ \c�i` I-M \/\/\ \�,I/\�/\/\/1��/-/\I ♦/\��I 1♦/ /\I ♦/\/\I, Mn <5 ♦/\ \I/1 � � ♦/~� I ♦/-\ �/-- /�_\YjFe TI <al / / \/1 /\ I / / 9187 _lFe s16___AB-010 / I / \/ i \� I / \\ \ y \ / — I \ / / y / - / - / - / - _ \ P. \ / ' / 1 \ / \ / \ \AB-018ROR/�J� /\\/\/1 /\\/\/1 /\\/\s.3 \ a uaa7 /\_\�/\ /-\- 1 Co 3.e \ / 1 \ / 1 \ /1 Fe 5s / 1 _ / 1 / - t�1 /♦ / - \' \ _ \ / \ - GWA-21BR /1�♦/\—\//�\\—\/ /\\/\/♦/\\ \/ Mn 180 ti\\\/ \ /\/\/1/ ��\/I/\\i i\/I/\\•\—/\ Mn 1555 / Co Fe 15 a4 BEDROC)i'A�\i/\/I/\\�� TI <al -\% \/-��\%/♦--\ /\/�\/I\/♦/-\ I ♦/_— \ i�/I TI =\.! Fe 3630 `�t'���`/1/; TI 4 10 IBFIL a/�1 \/BEDROCK /I/\\i \/I/\i/\/I/ \\��/I��� \-\'/-/\�\'/ GWA3aBRL-/\-\'/- \-\ Co 0.2Co \ /1//\/\I/1♦/\/\I/1//\/\I/\\/\/\I/1//\/\I/1\/\/\I/1\/\I��'/\/\I/1\/\I/1\/\/\I/1\/\I/1\ Fe 3520 /�\/\/1/ //I �'/I/\\�i Fe sb7s /I \\�i�/I/\\'/ 1/\ /\�- \- \ /� _ \ - \ /`/ / \ l \ _ \ l /\/ / \ l \ _ \ l / / 1 / \ _ \ l / / \ l \ _ \ l / i \ l /\ _ \ \l i l \ / I / \ 1 / \I ♦ / / \I n 576 ♦ / / \I ♦ /_- ♦ /- TI <a1 1 / I/1�/\/\I/1\ /\/\I/1�/\/\I/1♦/\/\I/1�/\/\I/1\/ \/\I/1�/\/\I/1\/\/\I/1�/\/\I/1♦ / \/\I/1�/\/\I/1\/�\/\//1/ //I' \/� /\ / I/ \/� �� /I, \/i ♦ / I \/ �i � /I� \/� /\ / I/ \/_' � \ /I� \ /1,//\I/1\\/\I/1�//\I/\♦\/\I/1,//\I/1\\/\I/1///\I/1\\/\I/1//\I/1♦\/\I/1,//\I/1\\/\/1////I/\\�/\/I/\\�/\�/I/\\�/\\/I / mw-S1RRL \� \�\'/\- �\ \�/\-- ��\'/\- �\ \'/\-- ��\�/\- �\ \'/\--\�i'/♦� /% lil\\/ I \ it/\/ /i lil\\/ I� \ it/\/ /% \/� /\♦/ I/ \ 1//\/\I/\\/\/\I/\,/\/\I/1\ / CO F. ' \FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED - \ /I / \ i - \ /I \ / ♦ / - \ /I / ♦ - \ /I \ / \ / / I / 1 ♦ / \ / /\ - \ \ / /\ - \ \ ' /\ - \ Mn /ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE / ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANE OF THE CROSS SECTION, AND - 1 ' / - \ \ / \ - \ ' / - \ - \ / \ - \ ' / - \ \ \ \ / - \ I / \ / I ♦ / - \ I / \ / / - \ I / ♦ / I \ / \ VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO /ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH �I j i / j \I / \ /_� �I j i / j \I/ 1 /_� �I j i i \; ��` 1 �\ /� / \\�\ \//I / \\ `�\ /�I / \\�\ �, `/i / \\ \ �\\//I / \\�\\\//I / \\ \ �\♦/� / \ /.-ARE CONCEPTUAL ONLY. - /. - - \ /.-_ \ _ /- - - 1 /.-_ \ _ /. - / ♦ / - - , . I ♦ /- _ - , . I _ \ / - _ - , . I _ \ / - Ri�FR R UNITS I-4 `___ -,. AS f ASH 1 'CLIFFSIDA 1_STOR A STEAM � _ ` 1 STATION UNIT INACTIVE ASH BASIN \` 1 CCP LANDFILL NOTE: CROSS SECTION A -A' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION LEGEND GWA 25S WELL IN SHALLOW FLOW LAYER GWA 25D WELL IN DEEP FLOW LAYER GWA 21BR WELL IN BEDROCK FLOW LAYER AB 6S WELL IN ASH PORE WATER • — GENERALIZED WATER TABLE �...� GENERALIZED BEDROCK FRACTURE ORIENTATION GENERALIZED GROUNDWATER FLOW DIRECTION 0 ASH ASH PORE WATER ® FILL SAPROLITE ® TRANSITION ZONE BEDROCK ALLUVIUM V ASH PORE WATER ELEVATION V SHALLOW GROUNDWATER ELEVATION V DEEP GROUNDWATER ELEVATION V BEDROCK GROUNDWATER ELEVATION GWAHiaBRL Co al MEAN COBALT (Co) CONCENTRATION (ug/L) Fe s67s MEAN IRON (Fe) CONCENTRATION (Ng/L) Mn s76 MEAN MANGANESE (Mn) CONCENTRATION (ug/L) TI <al MEAN THALLIUM (TI) CONCENTRATION (ug/L) WELL SCREEN r COMPLIANCE BOUNDARY (' DUKE ENERGY CAROLINAS synTena NOTES: 800 750 700 00 co 1 650 0 'a 600 Z O Q 550 W J Lu 500 450 400 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. COBALT (Co), IRON (Fe), MANGANESE (Mn), AND THALLIUM (11) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (Ng/L) * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Co Fe Mn T1 REPORTING UNITS Pg/L Pg/L Pg/L Ng/L ,SA NCAC 02L STANDARD 1* 300 50 0.2* BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE), 21 1700 969 0.2 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE), s 1840 260 0.2 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE), 2 7680 113 0.2 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2010 AS SUBMITTED IN JUNE 2019. 0 100 200 400 HORIZONTAL SCALE: 1" = 400' VERTICAL SCALE: 1" = 80' 5X VERTICAL EXAGGERATION DRAWN BY: J. CHASTAIN DATE: 10/22/201 REVISED BY: D. KREFSKI DATE: 2/28/2020 CHECKED BY: T. GRANT DATE: 2/28/2020 APPROVED BY: S. SPINNER DATE: 2/28/2020 PROJECT MANAGER: S. SPINNER www.synterracorp.com FIGURE 6-8c GENERAL CROSS SECTION A -A' VARIABLE GROUP MEAN OF COBALT, IRON, MANGANESE, AND THALLIUM ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 ApHiEFR .,— , ..+-•�*"",� ` FORME - ` UNITS 1-4 \ _ ASH BASIN CLIFFSIDE\ Y ' SI OR\GE STEAM �u ARI A ` STATION ' INACTIVE `. /Ir U 1 !� xx ASH BASIN -- O CCP LANDFILL NOTE: CROSS SECTION J-Y IS LINEAR IN NATURE AND ALL _ - - LOCATIONS NOT ALONG THE CROSS SECTION ARE -- PROJECTED ONTO THE CROSS SECTION. J -_ (SOUTH) r 800 - 7 V 750 Do a z Z 700 O w J LU ASH STORAGE AREA ■■MENEM ■■■■M., CLMW-■■ I.. 00.Sr �� fin►. n■■. f ,.0005'�!�■ II p ��■■illii �■■Ilni�i■■ ■ I;; 1 �� • • - iiji 7�I ' � II II'ij ! o / \ / AS-M SAPROUTE As 1 3.9 J' (NORTH) h As0.5 ,. - .-V--• - < 0.3 BROAD RIVER 0.3 0.5650- AS-R7D U (total) / sr 259 - / BEDROCKS — \ V <0.3 / R ZOION :A� As 0.6 W0.0005 AS-MRB / \ / As 1 1.6Sr 78 \ / CROSS SECTION DOES NOT INCLUDE A BEDROCK (total) 0.0040 600 EVALUAl1ON BORING WHERE OPTICAL TELEVIEWER DATA / 1 v �� 0.8 \ u (total) 0.0016 CAN BE USED TO DETERMINE GENERALIZED FRACTURE BEDROCK/ ORIENTATION. LEGEND GWA 25S WELL IN SHALLOW LAYER GWA-25D WELL IN DEEP LAYER GWA 21BR WELL IN BEDROCK LAYER AB 6S WELL IN ASH PORE WATER GENERALIZED WATER TABLE -� GENERALIZED GROUNDWATER FLOW DIRECTION ASH ASH PORE WATER ® FILL SAPROLITE ® TRANSITION ZONE BEDROCK ALLUVIUM V ASH PORE WATER ELEVATION V SHALLOW GROUNDWATER ELEVATION V DEEP GROUNDWATER ELEVATION BEDROCK GROUNDWATER ELEVATION As �NOS MEAN ARSENIC As CONCENTRATION L ( ) (ug/ ) sr MEAN STRONTIUM (Sr) CONCENTRATION (Ng/L) U (tota MEAN TOTAL URANIUM (U) CONCENTRATION (ug/mL) v MEAN VANADIUM (V) CONCENTRATION (Ng/L) WELL SCREEN COMPLIANCE BOUNDARY 800 750 OP 0 a z 700 Z O w J W 650 600 NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. ARSENIC (As), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L). TOTAL URANIUM (U) CONCENTRATIONS ARE IN MICROGRAMS PER MILLILITER (pg/mL). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER As Sr U V REPORTING UNITS pg/L pg/L pg/mL pg/L 15A NCAC 02L STANDARD 10 NE NE 3* BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)1 0.2 34 0,0005 1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 0.0005 11 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 1 93 0.0005 1 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. CROSS SECTION LOCATION Rev. 1 23 April 2020 eRpAOHi FR .,— £ \ \ FORME .n .i•�*"`.��► _ = ` UNITS 1-4 I ` •� ASH BASIN CSTEAM B\\ �u '"SIOR ARIA E, STATION ACTIVE Qom. UNIT ` �� ASH BASININACTJ r� ASH BAISIN ' -; "i CCP 41 LANDFILL OCRgW _ R04 NOTE: CROSS SECTION J-J' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. J- (SOUTH) 800 750 0 Q z z 700 O H Q w J W 650 600 n ASH STORAGE AREA LEGEND GWA 25S WELL IN SHALLOW LAYER V ASH PORE WATER ELEVATION GWA-25D WELL IN DEEP LAYER GWA 21BR WELL IN BEDROCK LAYER _y SHALLOW GROUNDWATER ELEVATION AB 6S WELL IN ASH PORE WATER DEEP GROUNDWATER ELEVATION GENERALIZED WATER TABLE BEDROCK GROUNDWATER ELEVATION GENERALIZED GROUNDWATER -ot. FLOW DIRECTION MEAN COBALT (Co) CONCENTRATION (pg/L) MEAN IRON (Fe) CONCENTRATION (pg/L) © ASH Fe MTI� MEAN MANGANESE (Mn) CONCENTRATION (pg/L) ASH PORE WATER MEAN THALLIUM (TI) CONCENTRATION (pg/L) ® FILL WELL SCREEN SAPROLITE ® TRANSITION ZONE COMPLIANCE BOUNDARY ca: BEDROCK r 0 ALLUVIUM I J' (NORTH) 800 750 700 650 600 G 0 Q z z O H Q w J W NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. COBALT (Co), IRON (Fe), MANGANESE (Mn), AND THALLIUM (TI) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L) * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Co Fe Mn TI REPORTING UNITS pg/L pg/L pg/L pg/L 15A NCAC 02L STANDARD 1* 300 50 0.2* BACKGROUND THRESHOLD VALUES 21 1700 969 0.2 (SHALLOW FLOW ZONE)1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' S 1840 260 0.2 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONEV 2 7680 113 0.2 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. CROSS SECTION LOCATION Rev. 1 23 April 2020 800 750 650 600 500 450 400 K = (WEST) GWaM J B <w II p m Li 19 TDa 2a] GWA-585 N N M Q 50 GWA_SJgy \ Li 2.2 In m Q Q a i —__ —__ m m m m M---------- ----------------- W y------------ ---------------- ros N C7 n n n ao 0 o t9 0 u _ MM M M M N a p_----------------------------------------. ACTIVE ASH BASIN Q GROUNDWATER FLOW IS PERPENDICULAR CROSS SECTION IN THIS AREA m — y N 1--c �ic 000 mm00 mQ Q¢ Q 7 Ipbp FILL ---------------------- I__________ ________ __. Q-- -- -----_-_-='ASH ---_ = ASH --- — _ _____-------- __ FILL -. __ __--- _-- ------------- _______________ --==-vv--_ ____ ___ A8-035 _ _ _-________________________________________ _______________ B z9Ja - - ___---_---_---====-ASH PORE WATER-====__--_ AB-085 _-_-_-_-_- _ __ ___ _ _ _ _ _ _ _ _ _ _ _ __________ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ________ -------------- --- B a36o ----- - -_ _ _ _ _ _ _ _ - - ---------- - 2913 A"-0 - Li 141 _ so4 126 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ GWA-29D 119 --- - TDs 470----------------------- B <50 ----------- ASH PORE WATER ----- -- --- - ---- KI (EAST) ----------------- - ASH- PORE WATER -------- - ros 16os -_- - - - - - - - - - - - - - - - - - - - _= -- ------------ -__ --- P RE WA ER ros 3n B 311 _ TRANSITION• / --- - ---- -- sucK U'--------------------------- - - -_--- a sas - ae-oauLss -----------------------_-_--- CREEK __________________ ZONE ___-- i GWA-ZOS SO4 31.1 / 1 / \ / --- __-- -� - B 283 ___________ A&a35L TDS 172 Li 145 _____________/ / SAPROLITE soa 1.a -- B <50 So4 92.4 A8-09D<60 TDS J6.8 -------- _ __-_ _ _ / \ GWA-240R Li 62 NA TDS 349 TDS 124 AB-0BI SAPROLITE 504 6s.7 Li 1.9 _--- \ B <so / \/ / Li L8 � 97 Toy 191 Soo _ / \ \ \ TRANSITION ZONE a TRANSITION BBa —ZONE /] u 1a.a / \ /I \ I \l / //\ /�♦ \ \ /\ ` .I /// \ \/ I — Al 49.] If a9 - — M9 GWA-58BRU � / / _ ]06 StX 44.q Li 5.0 / ♦ 60-.0 / I \ /I I / /\I ♦I Li ABa4M 916 GWA-20BR i580 / % \ I GWM43D� \ / \ "'IF- 1 504 ♦♦\ ABO336 / \ ♦ 1 / 13 82.4 TBEDROCK BEDROCK , \ / \ / / aToDBa e2a539 -/ I \♦♦ \ \ /� �y \ / 8.-0 / _ /\I / \\/ / I—/ �\ \ /\ / / \ \\ / I —, •\,t \ / / \ �1 / / I—/ \ \ /\ / AB-01 .y \ BEDROCK\ B 380 B 47G I— GWA-H / GWA-MM u - u 1.a I I �\ / i 1 \ / ♦ I 1 \ % — I \ / I \ / — I \ / ��'• I I . \ / — I \ / Y / �� B 160 GWA- 57RR 1 _ /♦ I \ / \ B 231 \ / B 366 ��� soa SO4 53.3 \ �•\ / 1 I \ / \ / I \ I \ \ I / 1 \ 1 \ ,FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED Li 111 % /- Li 11.0 ros ros z9z h I/ t / I / / ♦ / / �/ / / / \ / / ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE 5O9 79 ♦♦ { soa lza \ — � / I / 1 \ / „ \ I / ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANE OF THE CROSS SECTION, AND 28z / 1 - Tos M4 I*� TDs 3az �l / / II / \ / / I /I� / / \ 1/ I / / / B eaa6 / / \ / I / \ I/ / / / I / / ,/ I / \ / / \ VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR T00 NUMEROUS TO _ / II \ it /\ `_ i I •\ /i\ / — l / // ♦ \ - \ / — - \ \ \ r _ \ ♦ \ \ \ \ / I _ \ \ 'ILLUSTRATE ATTHIS SCALE. IN ADDITION, THE DEPTHSAND LENGTHS OF FRACTURES VERSUS DEPTH / \ X - I \ I \ / I I \ / - I soa / \ I \ / I \ I \ / I ARE CONCEPTUAL ONLY. /� /� T05 \ LEGEND 'M \ / \ / — \ / ♦� \ / \ I �� GWA66BRL / WELL IN SHALLOW LAYER © ASH ♦ , I �j I , /'1' / \ B 403 \I GWA 58S ASH PORE WATER ELEVATION F_ 800 750 700 Z 650 600 Q LL J W TM Z \ /I j / GWA 58D WELL IN BEDROCK LAYER SHALLOW GROUNDWATER ELEVATION WELL IN DEEP LAYER ASH PORE WATER NOTES: / \ / \ FILL 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON 4 I / \ / / \ __.� / 1\ / _ _ _ \ GWA-58BR ® CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 WELL IN ASH PORE WATER TO JUNE 2019. 0 SAPROLITE DEEP GROUNDWATER ELEVATION GENERALIZED WATER TABLE ® TRANSITION ZONE BEDROCK GROUNDWATER ELEVATION L2. ITER BORON ALB) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER �, l \ �` i I i� 3. SULFATE(SO4)AND TOTAL DISSOLVED SOLIDS TIES CONCENTRATIONS ♦,\, \ /\ \ / I \ \ ORIENTATION BEDROCK FRACTURE -I_ BEDROCK AB-04BR MEAN BORON (B) CONCENTRATION (ug/L) ARE IN MILLIGRAMS PER LITER (mg/L) (TIES) GENERALIZED GROUNDWATER B 550 MEAN LITHIUM (Li) CONCENTRATION (pg/L) FLOW DIRECTION so4 3.6 MEAN SULFATE (SO4) CONCENTRATION (mg/L) WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE \ / \ MOST RECENT VALID SAMPLE DATA UP TO DUNE 2019 WAS USED. T05 u° MEAN TOTAL DISSOLVED SOLIDS (TDS) / 1-_BRogo CONCENTRATION (mg/L) No DATA AVAILABLE / I \ 7 \ / _ \ / \ / — RR. ANALYTICAL PARAMETER B Li SO4 TDS - I \ / I / I \ _ ^ WELL SCREEN REPORTING UNITS pg/L pg/L mg/L mg/L \ / / \ / \ \ / /\ �i♦\ / — \ _ \ ���/ — / \ % \ L 15A NCAC 02L STANDARD 700 NE 250 500 \ / \ \ \ -♦♦` \ / / i / \ \ \ /-- FORMER COMPLIANCE BOUNDARY BACKGROUND THRESHOLD VALUES 50 3 4 57 71 UNITS 1-4 (SHALLOW FLOW ZONE) ASH BASIN ^ BACKGROUND THRESHOLD VALUES NA NOT AVAILABLE OR NOT MEASURED 50 12 15 107 N / — / I \ / — ` ASH (TRANSITION FLOW ZONE) _ \ \ / _ \ / / \ I \ / / 1 CLIFFSIDE r. STORAGE STEAM n ' AREA BACKGROUND THRESHOLD VALUES STATION �o�l.- ;' . , ACTIVE ---�- BREAKLINE (BEDROCK FLOW ZONQ) 50 11 17 120 UNIT r ASH BAST" 1 _ � -UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING ASH IN / �`O - DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY _ \ \ / \ / \ / — - \ 2010 TO DECEMBER 2018 AS SUBMITTED IN TUNE 2019. I \ \ / i •`,� /`�\ \ / / �Gk A ` \�. \ .' NE - NOT ESTABLISHED 350 CCP Mc O BO 120 240 FIGURE 6-10a LANDFILL CRgw DUKE \— \ \\— / \ ROgo` �' HORIZONTAL SCALE:1°=240 GENERAL CROSS SECTION K- \ ENERGY VERTICAL SCALE:I"=48' CONSERVATIVE GROUP 5X VERTICAL EXAGGERATION _ CAROLINAS DRAWN BY:J.CHASTAIN DATE:10/22/2019 MEAN OF BORON, LITHIUM, SULFATE A \ GWA-08RL / \ I \ / \ SECTION K-WIS LINEAR IN NATURE AND ALL REVISED BY: D.KREFSKI DATE:3/2/2020 DISSOLVED SOLIDS (TDS) 300 / I \ - LOCATIONS NOT ALONG THE CROSS SECTION ARE * CHECKED BY: T. GRANT DATE: 3/2/2020 ACTIVE ASH BASIN / \ I / 1 \ I \_ PROJECTED ONTO THE CROSS SECTION. APPROVED BY: S. SPINNER DATE: 3/2/2020 CORRECTIVE ACTION PLAN UPD _ _ \ / _ PROJECT MANAGER: S. SPINNER T� CROSS SECTION LOCATION �mTPra CLIFFSIDE STEAM STATION Rev. 1 23 April 2020 K - - KI (WEST) ACTIVE ASH BASIN _i (EAST) Q GROUNDWATER FLOW IS PERPENDICULAR T p CROSS SECTION IN THIS AREA p W GWA-57s 8OO Ao m m 0] m 0] m Q p m aQQQQ �+C7C7 Sr 132 �. ________- _ _________ FILL 1fi N GWA _ U (total) 0.00035 ___ QQ v 0 AS 0.13_-_-_-_-_----------- ------------------- p (/� m y J Sr 175 m FILL mm�m__ -_____:- _ _ ________ Gwa757Blu u(rota0 <o.000s N a a Q U' --- - _ _---==ASH_====_____- m m A AS 1.3 V 0.30--------------------- - - - - -------------------- ----- __ _________ ___ ________________________FILL-: ___ _____________Ix __________ Q Q Q Q a a s _____________ _________________________ Sr 293 "_____________ ____- __ ___________________________ �� U(tc A8-WIlA15 U (total) 000e35________________________________ -_ -- - --------------_____________- _ AS 92.3--_------------- --_- V o ------------------------ _ -- --� --_--- - --------------------------------__=====-=====---- um - SAPROLITE V o.91 r r r oo0oao p o r t9 = _�_=-_�-ASH_=-�=__ �_ =---- _ -__--_---_-_-�__-�__-�__-�__-�__-�__-�__-�__-�__-�___-_�_- - __ NNY�7�NN oNQ __________________�.r_ ______-----___________ _ _ _ __________________ N -__-__-'_-_____ _--_-___-______- s 37z _ ___---___-�_=-�==ASH PORE WATERv9 GWA-24D 750N C m y O QQ a aQ Q r Q3 ___-_---____-------------------- - S 3Go7 -- =-----=-=----=-=-=-_-�__-�_=-=-=-==-=--- 92.6 -------=-==-=-==-=-==-=-==-=-==-== A5 <G.1 -- A&085 �• - _ _ mod`"_______________________ ____ M M M M M �� w a�0 FILL #=-- _---_- __ As Gs.i--____ugarap o.00n - __ Aa-o3rAass--____--___--___ --- ----_- Sr_--__---- ------------------_-__= sr z3.G jM jM jM j� C7 C7 �U'______________________________ _ v s.1 = - ___-- As zsz---___-_ _ -- -- ugara0 000G6 -=-===-=== ASH PORE WATER __2�n5 -------_-_------ �' _ _ _ _ - ASH PORE WATER -- - - - - u (vta0 asZ ss ,I�a3u _ _ - u (taraD oaoa3 ,�e.amass v < 3 i _ U' C9 0 C7 U' ARass------------------------- - As 851 v 109 aR-aril _ As 184 __ TRANSITION• / SUCK (� ns _ _ 00 CREEK o.7a _-_-_-_-__ sw As lfi9z - __ __-_\ ZONE 00GW----- -335 AsGWA-TG0SAPROLITE U(tvota_1) \ / \ GWA- 0 -lie AS 2a61 R0.1 > 29.2Q I 1 Z s 14z v 0s SAPROLITE u Rarap 0.0a0m \ as-ael �, Z 700 v \ TRANSITION ZONE As 3.1 AS 31 I \ ns aaa _ \ ♦� ? \\ / j / , 1 / \ i j _ u (rotap olooaa u (tota0 Sr 131 --�- \ TRANSITION \ a - NA / D (total) / \ % \ - \ \ � � / <as w�°eaRosz � � z.a 1 ; / \ � ZONE � / v <as i / \ / - � � / � ♦ \ / \ � - LU �GwAaw a AswA a3s ♦ \ / I I \ v _ \ / I / s vz \ / I / \ I \ / / \ / / \ / /`.• \ I - \ / / \ / I \ / / \ ♦T - \ / / \• �♦ I / \ ` / \ J 0.0006 - \ / A..A / �- e / \ / / �- _ \ / \ ♦/ / • \ / \ �/ W Sr 169 sr lei ewa-a3o • ,� _ \ I♦\ j - I u (total) oaoss \ \ - As _ - \ \ - I \ / - \ '( I I♦ \ / - \ \ • I j \ V <0.3 GWA-208R , \ \ / u RaraO - u(tota0 - 0.3a GWA-zao As o.fi7 / II / \ I ♦ / / \ / / I\ I / '-� - / \ i• / \ / \ / 1 •d / \ / \ ♦/ 1 / \! / •\ / \ / •1 V 0.4 v I s 1 \ / 1 \ / 1 \_ \ \ • / \ \ ti As <0.1 1 \_ \ \ / 1 \• 1fis / / ns 0.z3 sr sza I / / ♦I aB-GSBR - • I / u (mta0 - / I / _ / - / , _ \ / total) - sr sag - u (totap omoz \ - 1 /♦ ns o.a2 / I \ - \ j / - \ \ - �- \ I/ - \ 1 ,/ \ Jos\BEDROCK o.m / u [totap <0.000s v <0s k BEDROCK _ ♦ \ sr 1Ga \ / _ \ • _ \ / \ / (totap <0.ao0s \ \ / 650 \ / \ \ v 0s ♦ \ u (mtap a.00la �t \ - ` v <os - / /� \ • BEDROCK\ - - / \ I \ • - / \ I - \ 6WA-57SR \. AS <0.1 \ , . I / .- 1 \ , ♦ I • \ y I \ , I \ / I . , �._. I \ / \ 1 . , y • I GWA-33R u(totap - /� I • ♦/ \ / \, / y /• \ / 1 /♦\ \ / \ / , \ / \ FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED I: 0.1 \ / Sr 241 ,.�- \ .� / 1 , \ \ I` / 1 \ • / \ \ . / 1 \ 1 / \ � 2na 1 / , sr 199 _ _ \ u (tara0 o.aooa - / - \ / \ V �0•� A, ,/ ♦♦. 1 / / \ - / \ J� / _ / ` / / _ I / / / / / ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE ♦ (totap 00009 V - \ }1 ♦ \ \ \ / - \ \ ,� \ I - \ \ / ORIENTATIONS ACCOUNT FORAPPARENT DIPWITHINTHE PLANE OF THE CROSS SECTION, AND u(totao `�� V { / / / ♦ / •/ / / aRmRR / / / / • / ♦/ / / / \VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FART00 NUMEROUS TO / / / _ / \ ♦% - / • ♦ _ / / - / sr \ / \ / - / • /♦ \ / - / ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH ARE CONCEPTUAL ONLY. 600 LEGEND / \ \/ I / \ / % - \ \ / \ \ / -• \ GWA 58S WELL IN SHALLOW LAYER - - - - ASH ASH PORE WATER ELEVATION /��I`� / / ♦ \ Sr 39s \ _ / GWA 58D WELL IN DEEP LAYER ASH PORE WATER 500 \ / /� / \� \ / /1 - / /; - - ,•\ u (total) o.oao1 \ 1 / GWA 586R WELL IN BEDROCK LAYER SHALLOW GROUNDWATER ELEVATION 800 750 700 Z 650 600 1 / / \ •- \ / \ / / \• / I �/ \ / V 0.3 / \ / / 0 ® FILL NOTES: I / \ / / / �\ / \ / \ / _ \ AB_8 WELL IN ASH PORE WATER 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON / - / I• \ / - © SAPROLITE DEEP GROUNDWATER ELEVATION \ \ / \ _ \ I / \ / \ / 1 \ / \ I � 1 \ / \ / . CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM ]AN UARV 2018 / \ I �.� \ / \ \_ / •� \_ GENERALIZED WATER TABLE ® TRANSITION ZONE TO JUNE 2019, \ ♦ / 1./ 1 \♦ / �'� \ \ / \ \ BEDROCK GROUNDWATER ELEVATION 2. ARSENIC (As), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE ♦/ - - \ / �♦ \ / ` _ 1 IN MICROGRAMS PER LITER (pg/L). TOTAL URANIUM (U) CONCENTRATIONS ARE / \ - / _ GENERALIZED BEDROCK FRACTURE -1- „I; BEDROCK IN MICROGRAMS PER MILLILITER (Ng/m L). �♦ \ \ /�� / ♦y / \ / I /`� / / / \ / ORIENTATION GENERALIZED GROUNDWATER As B-046R 0.1 MEAN ARSENIC (As) CONCENTRATION (pg/L) ' WELLS WITH DATAS ETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE 450 \ / \ / - _ \ / I \ / - ' I \ / �� MEAN STRONTIUM (Sr) CONCENTRATION (pg/L) MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. \ / \ / 1 / \ / FLOW DIRECTION Sr 105 - NO DATA AVAILABLE \/ \ / I / \7, 350 300 I CROSS SECTION LOCATION u (total) <o.000s MEAN TOTAL URANIUM (U) CONCENTRATION (pg/mL) V <0.3 MEAN VANADIUM (V) CONCENTRATION (pg/L) WELL SCREEN COMPLIANCE BOUNDARY BREAKLINE NOT AVAILABLE OR NOT MEASURED 4' DUKE ENERGY CAROLINAS 111611111, synTero 0 60 120 240 HORIZONTAL SCALE: 1" = 240' VERTICAL SCALE: 1" = 48' 5X VERTICAL EXAGGERATION DRAWN BY: J. CHASTAIN DATE: 10/22/2011 REVISED BY: D. KREFSKI DATE: 3/24/2020 CHECKED BY: T. HARTMAN DATE: 3/31/2020 APPROVED BY: T. GRANT DATE: 3/32/2020 PROJECT MANAGER: S. SPINNER www.synterracorp.com ANALYTICAL PARAMETER AS Sr U V REPORTING UNITS pg/L pg/L Ng/mL pg/L 1SA NCAC 02L STANDARD 10 NE NE 3- BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)1 0.2 34 0.000S 1 BACKGROUND THRESHOLD VALUES (TRANSITION ROW ZONE)1 2 69 0.000S 11 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)t 1 93 0.000S 1 ^ - FEDERAL MAXIMUM CONTAMINANT LEVEL. "- IMAC OF THE SSA NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013, 1-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. FIGURE 6-10b GENERAL CROSS SECTION K-K' NON -CONSERVATIVE GROUP MEAN OF ARSENIC, STRONTIUM, TOTAL URANIUM AND VANADIUM ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA O F- LU J W Rev. 1 23 April 2020 K— sm—sm KI (WEST) ACTIVE ASH BASIN _i (EAST) Q GROUNDWATER FLOW IS PERPENDICULAR TO CROSS SECTION IN THIS AREA N 800 Ca 14.5 O m Fe 246 O: tD ___ FILL N N (7 GY Mn >ess �AB�la.v J N N N Q CF. O oQ OQ 00 ____ ___ ___ _ _ ____________ Fe L56 m m m m HILL m m�m _____________ _______. _ _ _ ________ Mn Mal Mn 1am N -=__=_____==ASH==_ ASH=====_ rl ________________________________________________a36 :� ______ - _____________FILL-: _- __________________ __________________________co ____. __ ___________________________ AB-045 ���GWA-____ _ ____________________ AB-0MIALS�v___0 9 _________=___ _____-�____- ____-____________________ AB-D3s ___________________________ -_- m o.11 _ _co <oa---------------=SAPROLITEFe nmm 00O QO=V 5� --_ASH_—_-- _—�----------------------------- 1.0 _ _________________________________________ Fe <50 - - Fe <50 Mn Pe Mn <s Q a a a Q Q N Q�__-�__-�_ �y ___-__-- --_ --_ ---_-_ - - - -- -----------==-=-ASH PORE WATER =__- rl <0.1 --_- - n <0.1-___-___-___-___-___-_- TI 750 w c m In o Q _____ -- -------------------- Aeass M" 1165 = -_--_ _------=--------------�___---- --- _ --__ __ __=-==-=-==-=-==-�__-�__ -------- co _2=______________________------------------------- --- --- --- --- FILL - ---- - --- --- --- --- - M M M Y C7 C7� Oyi �(9=-------------------------- - uo --- TI o.6a -_ - ---- aAnoa---____-_ _ -- ----- ---- -- - -__ -_-- ASH PORE WATER Q Q Q Q Q Q U' - --- -- --- -- --- -------------- ASH ---M n -- - - � - - - - - - - --- - - - - - - - - - 3 =-_-_- PORE =-_- -- rl oss _ ___ <s - ABonAss_________________ \TRANSITION Z-_ _ _ _ _ _ Fe 97.1-_-_-_- - C'u 5.4 _-_-_- -_- - \ GWA-246 SUCK AB-025 __ ___ ___________ ____ _ a179 - _ TI <a.l Mn 9.1 Fe 41a8-___________ co 0 CREEK ______________________ _ _ rl _ \ ZONE F. 00 GWA-21K ca 39.2___________________ _ M" <a1 <o.l T� p�7-----__-__-_-__-_-/ / / 1 / \ \ /`/ / Mn s i Gwa- ---- - -- - Co 13.3 Fe sloz =- _ _- TI SAPROLITE _--_-_-_-_-- _-_ -_ \ — 1 -- Mn 1]59s -- C.X�6 \ TI > 146 Fe 966 a Fe �� NA Mn W13 TI osa AB I SAPROLITE _ __ Z 700 Mn 546 <0.1 CO 11.8 GWA-5M / — - _ _ _ _ \ \ / \ / — -I \♦� : / TI <al \ \ TRANSITION ZONE Fe zazso 42 + \ \ / \ / ��♦ \ \ \ ` i AB-DZD n o.osz Fe ao.o �qj/ 1 \ / \ / \ / co jIn - \ I �♦ \ Co 11.7 NA, 1 / \ Fe ma6 / / �1 UJ Fe \ • I Fe 31aa / TI \ / I / \ / / \ \ / I / \ I \ / / \ / �► / \ / /`.• \ I \ / / \ / I \ / / \ of \ / / \• /� I / \ / \ J Mn 89 // m.- ,,.625 Mn ]2a / / _ / \ Fe 13S! / — ABQSBIIUA / ♦♦- e / \ / — / �- \ / \ I/ — /• , — \ / \ 1/ / — /� / _All w TI of M� <50 \ / \ ca 100 /�1 ! / \I ♦�\ /i\ / \I / a.1 /I\I \ / \I \ /1 /•�I \I ♦ \ / — ! \ /i / \I I GWA-65 I / TI <al / \ Fe 1664 I / \ 1 / / • I / 1 \ / \ \ / AB-04BR 1 / \ \ / 1 / \ \ / i / 1 / \• \ / ; 1 - L3 / — — 0.1 F. V4, y 1 / Mn WIS / I / — • I' — / Mn — \BEDROCK / \ \ 1 \ _ rl a.71. �t BEDROCK ♦ \ _ • \ • _ \ / 1sa7 \ \ / _ \ \ Mn 13 ..� . � AB-0BB0. 1 r / ♦ P. \ / \155 \ / \ I / TI <al / ��_ / I _- - •/� I / . / I \ / I / \ / 1.3 / \•�/ I / \ /• \I I �•� / \ / • \ I / \ i� / GwA-zaeR — ♦ \ / — \ 1 — / Fe zags \ / I / BEDROCK\ •/ \ / — TI o.l — ♦ / y / — \ / — I~� / \ / ♦ Gwa.SZBR ♦ Fe a.25 / \ i \ / — \ \ \ / — _ \• I \ \ / — \ / ♦� \ I \ \ / GWA-33m as / \ - Fe a625 \ / — /f I \ / ♦ I Mn SA 1 1 \ / ♦ I I \ f' — I \ / I \ / — I \ / ♦y I ■ . \ / — I \ / y / 't♦. I . , <al n aas gyp.' AB-02BR0 / 1 / \ \ /♦♦r\ / \ \ \, �/ \ TI <o. I\ / / 1 \ \ / 1 \ \ /��\ / \ \ / \ / lI \ \ / \ FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED Fe 13os ♦ 7 M" e5s — Co 12352 \ --I• \ �� / It \ / 1 / — ♦\ / / \ — \ / / \T1 ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE Mn, ♦ TI <al i AB-a36RA / \ \ • / ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANE OF THE CROSS SECTION, AND ♦ \ *,f GWA-586R Mn 218e / / •/ / / / / / rl <al \ I cn o.31 \ / / \ / • I /� \ / / \ • I / / \ c° - \ I \ `I/ \ / I / I\ / / y I \ / / \ VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUSTO Fe ls3sa \ / / \ \ / \ r — \ / j / \ / Fe ILLUSTRATE AT THIS SCALE. IN ADDITION,THE DEPTHSAND LENGTHSOF FRACTURESVERSUS DEPTH Mn lo3a \ / \ I \ / — I \ / / \ I • \ / \ / \ I Mn ARE CONCEPTUAL ONLY. TI 01 Soo A_ LEGEND / WELL IN SHALLOW LAYER ASH ASH PORE WATER ELEVATION "♦ \ /\ \ / I / \ \ \ �\ — � \ I \ / \ ./i \ \ B:1s I /\ �/ GWA-58S 0 — �♦�I:♦ WELL IN DEEP LAYER ASH PORE WATER 500 \ / 1 / \ • / \ — / \— — •\ Mn z63 \ —I \ SHALLOW GROUNDWATER ELEVATION 450 400 350 300 800 00 0 Q Z 700 Z O Q W J Lu 650 600 �— \ i \ / / / / Al / I I/ \ TI D.1 ' / / / / GWA 586R WELL IN BEDROCK LAYER ® FILL 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON 1 r / / / l \...r / I\ / — l — \ \ WELL IN ASH PORE WATER CENTRALTENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 'C \ I — \ — \ / /'— / \ I� \ / — \ I \ / \ / — / AB 8 SAPROLITE DEEP GROUNDWATER ELEVATION TO JUNE 2019. \ / \; / 1 % \ / % I \ \ \; / •� \ \ / A ��� 1 / \ \ / — V GENERALIZED WATER TABLE ® TRANSITION ZONE 2 COBALT CONCENTRATIONS ARIRONE IN MICROGRAMS MANGANESE (Mn),PEANDTHALLIUM(u LL UM (TI) BEDROCK GROUNDWATER ELEVATION GENERALIZED BEDROCK FRACTURE % • ,; ; BEDROCK ,� \ \ ♦� l► / \ / I �♦♦ / / / \ / ORIENTATION WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE GENERALIZED GROUNDWATER �AB-04BX01 MEAN COBALT (Co) CONCENTRATION (ug/L) MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. / \ / FLOW DIRECTION MEAN IRON (Fe) CONCENTRATION (ug/L) Fe 18a7 NO DATA AVAILABLE MEAN MANGANESE M CONCENTRATION L 1,7 q \ / / I \ / \ / \I\\ // I♦��� / \ \ ♦\/�I \ _ _ [n Fe MnTI CROSS SECTION LOCATION NA] 4' DUKE ENERGY CAROLINAS 111611111, synTero ( H) W ) ANALYTICAL PARAMETER Co Fe Mn TI MEAN THALLIUM (TI) CONCENTRATION (pg/L) REPORTING UNITS Ng/L Ng/L u9/L Ng/L 15A NCAC 02L STANDARD 1* 300 50 0.2* WELL SCREEN BACKGROUND THRESHOLD VALUES 21 1700 969 (SHALLOW FLOW ZONE)1 0.2 COMPLIANCE BOUNDARY BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' S 1840 260 0.2 BREAKLINE BACKGROUND THRESHOLD VALUES 2 7680 113 0.2 (BEDROCK FLOW ZONE)' NOT AVAILABLE FOR WELL * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. 0 60 120 240 HORIZONTAL SCALE: 1" = 240' VERTICAL SCALE: 1" = 48' 5X VERTICAL EXAGGERATION DRAWN BY: J. CHASTAIN DATE: 10/22/20 REVISED BY: D. KREFSKI DATE: 3/2/2020 CHECKED BY: T. GRANT DATE: 3/2/2020 APPROVED BY: S. SPINNER DATE: 3/2/2020 PROJECT MANAGER: S. SPINNER www.synterracorp.com FIGURE 6-10c GENERAL CROSS SECTION K-K' VARIABLE GROUP MEAN OF COBALT, IRON, MANGANESE AND THALLIUM ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 850 N - N-.0111111 mo N N ACTIVE ASH BASIN as m N � N N N � L) POSSIBLE RADIAL GROUNDWATER FLOW 800 IN THIS AREA SAP OLITE co � N N w IM m m SAPROLITE ASH a iA. Q GwA-z2s / \ / / TRANSITION ZONE -----___-__---_- ____ _----------------- __-_-_-_-_-_-_--- -_ __________-_ ' ' uR�t�l) 0.1 \ 10 LLJJ AGWA 27DA lam- --�-�- ACca-isoo.l - - - - - - - - - - - - --A8-065 = - — - - - - - - - - - -___ _-_-_-_-_-_-_-_-_- v os Sr 107 / \ Sr 10 __ _ As 323_____________________________________ ! Q750U U([arap <0.0005 / / 1 / \ \ / \Oct (total) - \— Sr 2511---------------------_________ - Sr 35aU \ / > U / \ / \ v <0.3 \ \ (tarap o.0010 ------------------- ------ u(tota0 o.ue7 -_--- As <0.1 / V < a.3 v . —9- _ ASH PORE 1.6 _ — _ - - - —_ _- _- _ - -_- _ _ ___-_-_---_-_-- u (e tap za WATER / � / / \ Z --------------- --_-_ _ /TRANSITION / \ / \ u(a<zs ZONE 1 \\ / V ) o.3 Rrf > — \ / / — \ \ / \ — — \ / — w / I / // \ / ► / \// / \ / I / \// \ S 3'8 J / — / GWA-278R / \ / — / _ / as o / \ I \ / — / / u (total) W 700 \ / — \ \ As 0.3 \ I \ / — \ \ / \ / — \ I u (total) <o.000s \ / I \ / \ — \ I \ / \ / — \ i �� Sr 206 / \ / \ V <0.3 1 / U (totap 0.0019 v <0.3 BEDROCK' TSr23 zYll /\ \ / ISr 101//\ u (tarap <o.000s \ 650 /\BEDROCK \ �'3\— / BEDROCK NOTES: CROSS SECTION DOES NOT INCLUDE A BEDROCK , I / \ / / \ / I / / \ / I / \ / / \ / I / \ \ / \ / I / \ / / ' 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 CAN BE USED TO DETERMINE GENERALIZED FRACTURE \ \ / — \ \ \ / — \ \ TO JUNE 2019. ORIENTATION. \ \ I \ / \ 2. ARSENIC (As), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE 6OO IN MICROGRAMS PER LITER (pg/L). TOTAL URANIUM (U) CONCENTRATIONS ARE IN MICROGRAMS PER MILLILITER (pg/mL). I _ - LEGEND * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE . MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. � slo - NO DATA AVAILABLE ; gDRirFR ,. GWA-25S WELL IN SHALLOW LAYER � ASH PORE WATER ELEVATION GWA 25D WELL IN DEEP LAYER ANALYTICAL PARAMETER As Sr U V GWA 21BR WELL IN BEDROCK LAYER V SHALLOW GROUNDWATER ELEVATION REPORTING UNITS p9/L P9/L P9/mL p9/L 15A NCAC 02L STANDARD 10 NE NE 3* UNITS is .► 1 AB 6S WELL IN ASH PORE WATER DEEP GROUNDWATER ELEVATION BACKGROUND THRESHOLD VALUES 0.2 34 0.0005 1 ASH BASIN 1 / � ASH I . (SHALLOW FLOW ZONE)1 CUFFSIDE r STORAGE, GENERALIZED WATER TABLE BACKGROUND THRESHOLD VALUES / STEAM �.cRL�r' ( BEDROCK GROUNDWATER ELEVATION \ STATION (TRANSITION FLOW ZONE)' 2 69 0.0005 11 uwr5 1 �r I �� GENERALIZED GROUNDWATER BACKGROUND THRESHOLD VALUES INACTIVE r FLOW DIRECTION MEAN ARSENIC (As) CONCENTRATION (pg/L) (BEDROCK FLOW ZONE)' 1 93 0.0005 1 is ASH BASIN 1 ACTIVE - 1 AB-w N ASH BASIN _ _ _ _ AS o MEAN STRONTIUM (Sr) CONCENTRATION (pg/L) Nr © ASH s. �' MEAN TOTAL URANIUM (U) CONCENTRATION (pg/m L) IMAC OFTHE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. u (totap <o.000s ASH PORE WATER v <o.a MEAN VANADIUM (V) CONCENTRATION (pg/L) 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY FILL 2010TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. WELL SCREEN SAPROLITE ". M _ DUKE 0 so 100 200 FIGURE 6-1' CCp °CRyw - ��� ® TRANSITION ZONE 40) GENERAL CROSS SE LANDFILL RO:n a, CQMPLIANCE BOUNDARY HORIZONTAL SCALE: 1"=200'BEDROCK ENERGY VERTICAL ERTI ACAL SCALE: 1"=40' NON-CONSERVATI% - � P � syir _i NOTE: CAROLINAS MEAN OF ARSENIC, STRONTII /" DRAWN BY: J. CHASTAIN DATE: 10/22/2019 CROSS SECTION NW IS LINEAR IN NATURE AND ALL ALLUVIUM REVISED BY: D. KREFSKI DATE: 3/2/2020 AND VANADI LOCATIONS NOT ALONG THE CROSS SECTION ARE ACTIVE ASH B PROJECTED ONTO THE CROSS SECTION. �� CHECKED BY: T. GRANT rc DATE: 3/2/2020 ^ ^ .. ^ ACTIVE - ASH , . e 000 _ov c coinn -- 850 800 750 700 650 600 CROSS SECTION LOCATION Rev. 1 23 April 2020 850 N — N850 mo N N ACTIVE ASH BASIN as m y Na N N N POSSIBLE RADIAL GROUNDWATER FLOW 800 IN THIS AREA 800 SAP OLITE Lo m m m m m SAPROLITE a a a ASH a GWA-27DA / TRANSITION ZA----- ---------------- _________ _ _ _ _ _ _ _ _ _ _ _ __ _ __ ________ _ _ _ _ _ _ _ _ GWA-245LLJ Fe 97 - _ _ _ _ _ _ _ _ _ Co 0.1 ____-Z4DCo 0 0.2 00 3.6 co (Y Mn 1296 \I \ \\ _____________ _ __ - Mn 21_ _ _ _ _ _ _ _ _ _ Fe 1 3 \ Fe < 50 750 00 0 75U U A=-O2_/ Mn_________________________---<0.1 __ _________ _ Mn 52 Mn 5 0 iU \\ — / / _ -- ---- - -----------AWATERE_--- n <o.i i ------------ TRANSITION __O ZONE1 \ O 24R 1/ 0.1 — \ \ \ / / \ — \ \ \ AB-OSBRu \ \ / / Fe 54 / / \ — ; J / --2 I \ / / \ / I \ / / \ / / / \ / I \ / C. Fe 3.5 / / \ / Tn <0.1 / J Co 0.6 \ \ - \ LU 700 / \ / \ / C. / \ / \ / — — \ / Fe <50 \ / \ / — \ / \ / \ / Mn 171 — \ / \ / \ / \ 700 LLI Mn 1 \ I / 1 \ I I / 1 \ I / 1 \ TI 0.1 / BEDROCK'/ Fe 49 _ Mn 109 TI\ <0.1 650 — — \ /\— \ — \ / /\BEDROCK_ 650 BEDROCK CROSS SECTION DOES NOT INCLUDE A BEDROCK NOTES: EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA I / \ / \ / I \ / \ / I / \ / \ / I / \ / \ I / \ / \ / I / \ / 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CAN BE USED TO DETERMINE GENERALIZED FRACTURE \ \ / \ / — — \ / \ / \ \ / \ / — — \ / \ / \ \ / \ / — — \ /CENTRALTENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 ORIENTATION. \ / — I \ / \ / — I \ / \ / — I \ / TO JUNE 2019. 600— 2. COBALT (Co), IRON (Fe), MANGANESE (Mn), AND THALLIUM (TI) CONCENTRATIONS ARF IN MICROGRAMS PER ITTFR (unh) SPO'D R -- fq FORMER UNITS 1-4 .►.� - ASH BASIN 1 f " ASH CLIFFSIDE Y STORAGE STEAM 'REH STATION v >� UNIT csi is INACTIVE ACTIVE ASH BASIN c�N \ N ASH BASIN N. Fp .00, LANDFILL NOTE: CROSSSECTION NW IS LINEAR IN NATUREANDALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. LEGEND GWA 25S WELL IN SHALLOW LAYER GWA 25D WELL IN DEEP LAYER GWA 21BR WELL IN BEDROCK LAYER AB 6S WELL IN ASH PORE WATER V —GENERALIZED WATER TABLE _� GENERALIZED GROUNDWATER FLOW DIRECTION 0 ASH ASH PORE WATER 0 FILL SAPROLITE TRANSITION ZONE BEDROCK ALLUVIUM V V V V ASH PORE WATER ELEVATION SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION BEDROCK GROUNDWATER ELEVATION -assR MEAN COBALT (Co) CONCENTRATION (ug/L) <' MEAN IRON (Fe) CONCENTRATION (Ng/L) MEAN MANGANEEa. MEAN THALLIUM STI)(CONCENTRATIONT(Og/L)g/L) WELL SCREEN COMPLIANCE BOUNDARY F * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Co Fe Mn TI REPORTING UNITS ug/L P9/L u9/L u9/L 15A NCAC 02L STANDARD 1* 300 50 0.2* BACKGROUND THRESHOLD VALUES 21 1700 969 (SHALLOW FLOW ZONE)1 0.2 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 5 1840 260 0.2 BACKGROUND THRESHOLD VALUES 2 7680 113 (BEDROCK FLOW ZONE)' 0.2 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. CROSS SECTION LOCATION Rev. 1 23 April 2020 �1 � O 1 1 f ' ■ j 1 ❑ 1 • 1 • �� ' ENERGY (IN FEET) . �• �, • DRAWN BY: C. DAVIS DATE: 06/13/2019 ' �� / - ■ • ♦ �♦ REVISED BY: C. DAVIS DATE: 02/24/2020 CHECKED T. GRANT DATE: 02/24/2020 / B APPROVED BY: T. GRANT DATE: 02/24/2020 - - (�/�'� PROJECT MANAGER: S. SPINNER "i' ' e www.synterracorp.com LEGEND NOTES: FIGURE 6-27a ISOCONCENTRATION MAP TOTAL URANIUM IN SHALLOW FLOW ZONE ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 UNIT 6 i Ir_ f♦ \ f♦ f♦ f ♦ f A m NX 1 .0 I 1 i (> DUKE ENERGY CAROL WAS N FEET) _ - ♦' II ♦♦ �� DRAWN BY: C. DAVIS REVISED BY: C. DAVIS CHECKED BY: T. GRANT APPROVED BY: T. GRANT DATE: DATE: DATE: 06/13/2019 02/24/2020 02/24/2020 A / svnTeiid PROJECT MANAGER: S. SPINNER ... ,.....DATE^02/24/2020 LEGEND O�. NOTES: FIGURE 6-27b ISOCONCENTRATION MAP TOTAL URANIUM IN BEDROCK FLOW ZONE ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION MOORESBORO, NORTH CAROLINA Rev. 1 23 April 2020 750 _ G--No (NORTHWEST) GROUNDWATERCROSS SECTION FLOW IS PERPENDICULAR TO FORMER UNITS 1-4 ASH BASIN FORMER ASH BASIN i 700 co co Z 0 650 W J W 600 550 � y FORMER /.+F U;'ITS 14 4V ASH '4SIN, ASH CLIFFSIDE` STORAGEA' STEAM -,�} AREA STATION r, UNIT 5 r3a \•; INACTIVE J�N s• E$ ASH BASIN '_� \ �J ACTIVE ASH BA,] LANDFILL qH'R q0 s ALLUVIUM soa zss SAPROLITE IB-021 B TDS 12s / Li 99.0 - SO4 62 TRANSITION ros afi6 — \ — ZONE Is \ B 6p 504 436 I ros Sso 1 \ \ o ED 6ROCK/ \ / TD CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 10S WELL IN SHALLOW FLOW LAYER GWA 10D WELL IN DEEP FLOW LAYER ABANDONED WELL/ IB 1D GEOTECHNICAL BORING GENERALIZED WATER TABLE GENERALIZED GROUNDWATER '..1 FLOW DIRECTION 0 ASH did ASH PORE WATER ® FILL O SAPROLITE ® TRANSITION ZONE 0 BEDROCK `1 NOTE: CROSS SECTION G-G' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE .± PROJECTED ONTO THE CROSS SECTION. ALLUVIUM 111111- G' (SOUTHEAST) I I m i/i I N N I � � I I I I I I I i SAPROLITE soa 9 � /F TDS 1 101 \ le -mu TRANSITION SAPROLITE Lid soa 33-7 / ZONE _/ \ TDS 3 I-OQ R \ / 7.0 LI0439.9 TDS TDS198 EDROCK\ SHALLOW GROUNDWATER ELEVATION V DEEP GROUNDWATER ELEVATION MEAN BORON (B) CONCENTRATION (ug/L) a MEAN LITHIUM (Li) CONCENTRATION (ug/L) 6� MEAN SULFATE (SO4) CONCENTRATION (mel-) MEAN TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATION (mg/L) WELL SCREEN r COMPLIANCE BOUNDARY 1 750 700 OD 00 Z 650 Z O W J W 600 NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER 550 LrrER (ug/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS REPORTING UNITS Ng/L Ng/L mg/L mg/L I 15A NCAC 02L STANDARD 700 NE 250 500 BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 50 3 4 57 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 50 12 15 107 BACKGROUND THRESHOLD VALUES 50 11 17 120 (BEDROCK FLOW ZONE)' 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED CROSS SECTION LOCATION Rev. 1 23 April 2020 750 G--No _ (NORTHWEST) GROUNDWATERCROSS SECTION FLOW IS PERPENDICULAR TO FORMER UNITS 1-4 ASH BASIN FORMER ASH BASIN it /� mm _ NNNN 700 OD co Q Z GWA-WS As 0.6 6r Z 650 W J W 600 550 P' G a � gROAO RI FFF r a � A �-- �"".,.� ASH 4SIN', �.• ASH CLIFFSIDE\ _ �: r" STORAGEA' STEAM -,, AREAUNIT 5' �. STATION r3a \•; INACTIVE ASH BASIN '_� \ �J ACTIVE ASH BASIN LANDFILL AwR qp s ALLUVIUM V a.4 SAPROLITE a ozl AS 0.54 / sr 270 V LO TRANSITION \ — ZONE \ 6EDRbCK \ / _ CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 10S WELL IN SHALLOW FLOW LAYER GWA 10D WELL IN DEEP FLOW LAYER ABANDONED WELL/ IB 1D GEOTECHNICAL BORING 1 . GENERALIZED WATER TABLE GENERALIZED GROUNDWATER 1 FLOW DIRECTION 0 ASH O ASH PORE WATER ® FILL O SAPROLITE ® TRANSITION ZONE 0 BEDROCK 1 NOTE: CROSS SECTION G-G' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE .± PROJECTED ONTO THE CROSS SECTION. G' (SOUTHEAST) it N N ii C7 t9 GWA-125 SAPROLITE --- 1 1 1 Sr 49 xL�3 . - As IB o.sa \ TRANSITION \ ZONE / \ SAPROLITE Sr V 3 — IEWMIRR 13 / \ Sr 130 _ — \ gEDROCK\ O ALLUVIUM SHALLOW GROUNDWATER ELEVATION V DEEP GROUNDWATER ELEVATION MEAN ARSENIC (As) CONCENTRATION (ug/L) W�30,03 MEAN STRONTIUM (Sr) CONCENTRATION (ug/L) V MEAN VANADIUM (V) CONCENTRATION (ug/L) WELL SCREEN COMPLIANCE BOUNDARY r 750 700 650 600 NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 550 2. ARSENIC (As), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (u9/L). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER As Sr V REPORTING UNITS ug/L u9/L u9/L 15A NCAC 02L STANDARD 10 NE 3* BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 0.2 34 1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 11 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 1 93 1 - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. CROSS SECTION LOCATION Rev. 1 23 April 2020 750 G (NORTHWEST) GROUNDWATER FLOW IS PERPENDICULAR TO CROSS SECTION FORMER UNITS 1-4 ASH BASIN I FORMER ASH BASIN I � IIIr NNNN L 700 / T--T-J CD 00 a Z Z 650 O W J W GW/4ll15 GWA-10D I le-o 600 / — C. \ Fe Mn 1 / \ Ra 550 i OR% R�VEA \ FORMER C. - -. G'ITS 1-4 - ASH BASIN , ASH CLIFFSIDE Y STORAGE STEAM ¢ AREA STATION- >� UNIT5 cr, zQ INACTIVE ACTIVE ASH BASIN �cv ASH BASIN 0 /CCP LANDFILL ID q ft /. 00- G' (SOUTHEAST) I I Q Q I I I I I i 7 SAPROLITE Mn 43 Ra \ , IB-OSD TRANSITION \ / ALLUVIUM Fe zw _ CO 0.20 ZONE Mn szo SAPROLITE Fe ze°o Mn 160 Ra Ra SAPROLITE A TRANSITION ZONE Imiiiiiii EDROCK\ \ co -as , \ -L 1Mn 9 0 6EDROCK \ / I Ra / CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 10S WELL IN SHALLOW FLOW LAYER GWA 10D WELL IN DEEP FLOW LAYER ABANDONED WELL/ IB 1D GEOTECHNICAL BORING GENERALIZED WATER TABLE -� GENERALIZED GROUNDWATER FLOW DIRECTION 0 ASH ASH PORE WATER ® FILL �- SAPROLITE ® TRANSITION ZONE BEDROCK NOTE: •�_,�' CROSS SECTION G-G' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION O ALLUVIUM SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION a MEAN COBALT (Co) CONCENTRATION (pg/L) MEAN IRON (Fe) CONCENTRATION (Ng/L) MEAN MANGANESE (Mn) CONCENTRATION (pg/L) MEAN TOTAL RADIUM (Ra) CONCENTRATION (pCVL) WELL SCREEN COMPLIANCE BOUNDARY 750 700 600 NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. COBALT (Co), IRON (Fe), AND MANGANESE (Mn) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L). TOTAL RADIUM (Ra) CONCENTRATIONS ARE 550 IN PICOCURIES PER LITER (PCVL). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Co Fe Mn Ra REPORTING UNITS pg/L pg/L pg/L PCVL 15A NCAC 02LSTANDARD 1* 300 50 NE BACKGROUND THRESHOLD VALUES 21 1700 969 2 (SHALLOW FLOW ZONE)1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 5 1840 260 2 BACKGROUND THRESHOLD VALUES I (BEDROCK FLOW ZON' 2 7680 113 3 E) * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. Rev. 1 23 April 2020 800 -�:] H --a*- (SOUTHWEST) H' (NORTHEAST) FORMER UNITS 1-4 750 ASH BASIN aav 333 SAPROLITE (� C7 C7 J FORMER ASH BASIN N N N N 700 GWl414S B 63 -- --- Li 11 504 SS 1 TDS 217 SAPROLITE FILL tGW-n1 OAD RIVER > TRANSITION ZONE -657' 101 ♦ �j ? 650 \ / 5Li 03 / / \ B I&02A 49D SAPROLITE Z / \ TDS 413 \ / Li - 0_ \ / _ \ I 504 83 IB-02111BW B 99.0 Li 150♦� ` / / \ . / J \ / / \ \ \�` \ - / \ ♦♦ \ / / \ SL04 52 / TS04 103 DS 319 \ l / /\ ♦ I I!• 1+•� j,� \ � 1 • W \ / / �EDR6CK I / \ / \ / I / \ � / \ / I TDS 466 600 GWA-148R \ / / I /'1���BB 62BLi 173 SO4 54 TDS ]84. \ / I \I / ♦ I \ ROCK �► \ 1 / I \ / /Ivy\ 1 \/\ /1�,/�\/\♦♦♦/1 \/�c Z!�..��/\ \ - \ / / \ - \ 1 / / \ '�� \ \ / / \♦♦♦ - \ 1 / / \ \ 1 / / \ - BEDROCK 550 FRACTURES CONCEPTUALLY DEPICTED ONTHIS CROSS SECTION REPRESENT GENERALIZED ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE _ \ / / \ - \ 1 / / GWA-11BIE ORIE NTATIONS ACCOUNT FOR APPARENT DIP WITHI N THE PLANE OF TH E CROSS SECTION, AND / / / \ B <50 VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO \ I \ / Li - 500 ILLUSTRATE ATTHIS SCALE. IN ADDITION,THE DEPTHSAND LENGTHS OF FRACTURES VERSUS DEPTH \ / \ / - - \ SO4 ARE CONCEPTUAL ONLY. LEGEND GWA-14S WELL IN SHALLOW LAYER ® TRANSITION ZONE WELL SCREEN GWA-14D WELL IN DEEP LAYER r-� BEDROCK 0 FGWA-14BRI WELL IN BEDROCK LAYER ® FILL - - - COMPLIANCE BOUNDARY ABANDONED WELL/ IB 2AL SHALLOW GROUNDWATER ELEVATION a MEAN BORON B CONCENTRATION L GEOTECHNICAL BORING ( ) (p�✓ . MEAN LITHIUM (Li) CONCENTRATION (pg/L) DUKE GENERALIZED WATER TABLE V DEEP GROUNDWATER ELEVATION MEAN SULFATE (SO4) CONCENTRATION (mg/L) ENEF GENERALIZED BEDROCK FRACTURE MEAN TOTAL DISSOLVED SOLIDS (TDS) CAROLI ORIENTATION V BEDROCK GROUNDWATER ELEVATION CONCENTRATION (mg/L) -, GENERALIZED GROUNDWATER FLOW DIRECTION 800 750 700 600 CROSS SECTION LOCATION NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS REPORTING UNITS pg/L pg/L mg/L mg/L 15A NCAC 02L STANDARD 700 NE 250 500 BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 50 3 4 57 550 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 50 12 15 107 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 50 11 17 120 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED 500 SAPROLITE Rev. 1 23 April 2020 800 -�:] H --a*- (SOUTHWEST) 750 \ U) vaa r r r SAPROLITE 0 0 700 600 550 500 H' (NORTHEAST) FORMER UNITS 1-4 ASH BASIN IFORMER ASH BASIN swA-laz �� • ��_ 3333 95 v 11 1 SAPROLITE FILL _ GWA-14D � BROAD RIVER AS 0.1>TRANSITION ZONE -65T • �(� Sr 22s — — �� V GS IB-wAL SAPROLITE y AS 0.42 GWA-11BRG AS 12� AS 0.3 Sr 5- Sr 2R5 V LZ\ IB-MI V 06 / AS 0.54 \ / / b9DR6CK I / \ / \ / I / \ 7 / \ / I V \ 0 IB-0RU ASWA-llBi 3 0.5 GWA-146R AS L3Vr Sr in\ \ / BEDROCK \ .� II — \ \ / / \ — \ 1 / / '�♦ \ \ / / \♦♦♦ — \ 1 / / \ \ \ / / \ — IS /I \ /I \ /I \ FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE ORE NTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANE OF THE CROSS SECTION, AND VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH ARE CONCEPTUAL ONLY. \ ` / L ` \ / \ I \ V LEGEND GWA-14S WELL IN SHALLOW LAYER ® TRANSITION ZONE 0 WELL SCREEN GWA-14D WELL IN DEEP LAYER BEDROCK FGWA-14BRI WELL IN BEDROCK LAYER ® FILL — — — COMPLIANCE BOUNDARY ABANDONED WELL/ IB 2AL GEOTECHNICAL BORING SHALLOW GROUNDWATER ELEVATION MEAN ARSENIC (As) CONCENTRATION (pg/L) ° .wA GENERALIZED WATER TABLE MEAN STRONTIUM (Sr) CONCENTRATION (ug/L) — — V DEEP GROUNDWATER ELEVATION MEAN VANADIUM (V) CONCENTRATION (pg/L) GENERALIZED BEDROCK FRACTURE ORIENTATION V BEDROCK GROUNDWATER ELEVATION GENERALIZED GROUNDWATER FLOW DIRECTION SAPROLITE 800 750 700 600 550 500 ♦_ FORMER \ AS14 HTASNASH / 1 CLIFFSIDE\ r �STORAGES Ik STEAM AREA _. STATION ' c� ACT ASH BIVASIE UN INAITIS r NI ASH BASNI 1 � � -. LANDFILL MCCRAI,I,R �`I�' NOTE: ... CROSS SECTION H-H' IS LINEAR IN NATUREANDALL _ LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION NOTES: CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. ARSENIC (As), STRONTIUM (Sr), AND VANADIUM (V) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER As Sr V REPORTING UNITS pg/L fag/L fag/L 15A NCAC 02L STANDARD 10 NE 3* BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 0.2 34 1 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 11 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 1 93 1 * - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. Rev. 1 23 April 2020 -800 (SOUTHWEST) (NORTHEAST) FDRM`�.• ` UNITS 14 ASH BASIN STEAM 'u •AREA \` M \ ASH CLIFFSIDE � �SiORAGE STATION 'c� ACTIVE a� UNITS r SASH BASINIV NAC=.y ASH BIAS N FORMER UNITS 1-4 \ r 750 ASH BASIN 750 JIT�V CCP a oil LANDFILL SAPROLITE (� o C� J � FORMER ASH BASIN NOTE: 7UU \ \ _ — 700 CROSS SECTION H-H' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. / GWA-1as a a a CROSS SECTION LOCATION CO _—�--- _ as 0 Fe 392 00 / / \ Mn 19 1 00 Ra - SAPROLITE FILL _ _ / / ,+� ,� J / GWA-14D BROAD RIVER ; TRANSITION ZONE � -657' z - r '�•,� Fe 79 IR-02AL SAPROLITE \► 650 ? NOTES: z 650 _ \ M^ Z \ / \ / Ra / \/ Fe 250 Z O \ /♦ / \ Mn szo - swAveRu coW�b / 111 \ / \ / 2 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON H —►�'� \ / �• \ \ � \ / — Ra co a7 Fe eu 1 / � _ / / � CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 Q / I r •` I \ / Fe 421 Mn 1970 \ \ / \ ff• 1 / \ \ / 1 \ \ Co IB-OQI ISB Mn 740 \ ; \ 0.456 — j •� l \ • l TO JUNE 2019. — / 947 J \ / /\ / — \�� <-- ♦ — \ / / \ Fe 200 \ • %' \ J 2. COBALT (Co), IRON (Fe),AND MANGANESE (Mn) CONCENTRATIONS ARE IN W I�DR(CK / \ / / ,�� / \ / I Ra lsoo / / \ / — \ / \ �:�•� \ I Lu MICROGRAMS PER LITER (pg/L). TOTAL RADIUM (Ra) CONCENTRATIONS ARE \ \ / \ / — / /\ \ �, , \ / — \ / \ / \ I / 1•�� \ ���\ / IN PICOCURIES PER LITER (pCi/L) IB-02BRu I \ co aB — \ / WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, 600< \ /-_ / 4� '< \ /" was \ / \ /-1 Fe 4e — \ 600 THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. T GWA-14BR / \ 7 / Fe 190 co o.z 1 / \ / \ / �� \ Mn 99.0 / \ / Ra 1•ss \ / / ��/ \ - NO DATA AVAILABLE Mn 527 — — Ra BEDROCK \ / Ii / — ,� \ / / \ .l / — ANALYTICAL PARAMETER Co Fe Mn Ra /lug\� /1 �\ \ /1�,/�\/\�.�/1 /BEDROCK REPORTING UNITS pg/L pg/L pg/L pCi/L 15A NCAC 02L STANDARD 1* 300 50 NE Ilk% \ / \ / — _ \ \ BACKGROUND THRESHOLD VALUES „� / \ / \t•/ 1 \ � \ / \ I / 1 \ � \ / \ I / 1 \ \ \ / \ I / 1 / (SHALLOW FLOW ZONE)1 21 1700 969 2 550 / 1� / / / / _ _ _ - _ 550 BACKGROUND THRESHOLD VALUES ,� \ / / / �� \ / / / / / \ •••/ \ / / / \ / (TRANSITION FLOW ZONE)1 5 1840 260 2 BACKGROUDTHRESHOLD FLOW ZONES (BEDROCK 1 2 7680 113 3 IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED — \ /<— / — \ / /\-- \ /<— / — \ /\ DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE GW-TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHI N THE PLANE OF THE CROSS SECTION, AND / / \ / I / \/ / CoVERTICAL EXAGGERAl- 500 ILLUSTRATE ATTH SASCALE. N ADD IONNT EHE ACTUALBER DEPTHS AND LENGTHS OF FRACTURES OF FRACTURES IS FAR TOONUMEROUS VER VERSUS DEPTH — \ / — \ / I Mn / I \ / \ / I \ 5OO ARE CONCEPTUAL ONLY. _ / \ I / \ / \ Ra - LEGEND GWA-14S WELL IN SHALLOW LAYER GWA-14D WELL IN DEEP LAYER FGWA-14BRI WELL IN BEDROCK LAYER IB 2AL ABANDONED WELL/ GEOTECHNICAL BORING V — GENERALIZED WATER TABLE ® TRANSITION ZONE r— J BEDROCK ® FILL — — SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION GENERALIZED BEDROCK FRACTURE ORIENTATION V BEDROCK GROUNDWATER ELEVATION _� GENERALIZED GROUNDWATER FLOW DIRECTION SAPROLITE WELL SCREEN COMPLIANCE BOUNDARY m MEAN COBALT (Co) CONCENTRATION (pg/L) M 3 3 MEAN IRON (Fe) CONCENTRATION (pg/L) " MEAN MANGANESE (Mn) CONCENTRATION (pg/L) MEAN TOTAL RADIUM (Ra) CONCENTRATION (pCi/L) Rev. 1 23 April 2020 D- 850 (WEST) 800 m Q 00 750 Q Z z O Q W w 700 650 600 SAPROLITE TRANSITION ZONE UNIT 5 INACTIVE ASH BASIN GROUNDWATER FLOW IS PERPENDICULAR TO CROSS SECTION IN THIS AREA In D' (EAST) F- 850 B �so ASH / soa SAPROLITE _ -------------------------------------------------------- -- - ------------------------------------------------------- \_-_-__-_-__-_-__-_-__-_-__-_-==--ASH=-==-_-__-_-__-_-__-_-__-_-__- usoss ----------------------------------------------- B 1 158 ❑ y I iASH PORE WATER B zci ------------------------------------------------ soa 1c7 ---------- -_----------------------------------------_- \ U 54.9 _ _ _ _--------------�—.- - ------------ TDS 301 ______________________________________ _____________________________________ TDS 429 TRANSITION ----------------------------------- ---- 2 'L TDS az9: ZONE usBeD V B IG2 —------------------ \ LI 214 SAPROLITE ewA-ou BEDROCK / — / \ _ \ rDs 33a / — / \ _ \ i / — / \ _ \ / — =-===ASH PORE WATER -_- r� 3� / B 159 5.8 MW�aS SOa 194 B <50 TRANSITION / TDS 343 Li as MW-408RU ZONE T I \ — \ D4 113 B 150 BEDROCK / — I \ / / \ I \ / — / \ I B 165 / os za7 Li z4 / 1 BEDROCK / 1 / � soa 9B soa / / rDs z9s TDB 433— /I CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 25S WELL IN SHALLOW LAYER eRo q�Ri�ER GWA-25D WELL IN DEEP LAYER ,�� IFE GWA-21BR WELL IN BEDROCK LAYER u WELL IN ASH PORE WATER ,. -'FORMER- Q UNITS 1-4 1 ABANDONED WELL/ AB 4APW ASH BASIN GEOTECHNICAL BORING CSTEnME ASH I STORAGE STATION v - '. GENERALIZED WATER TABLE GENERALIZED GROUNDWATER Y J Q alr5 - INACTIVE FLOW DIRECTION < ASH BASIN coN ACTIVE ASH BASIN ASH ASH PORE WATER OG� FA O�FA ;r ® FILL Aogo SAPROLITE ® TRANSITION ZONE LANDFILL o ,-,;I' BEDROCK NOTE: CROSS SECTION D-V IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. V V V ASH PORE WATER ELEVATION SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION BEDROCK GROUNDWATER ELEVATION MEAN BORON (B) CONCENTRATION (ug/L) a MEAN LITHIUM (Li) CONCENTRATION (ug/L) s« MEAN SULFATE (SO4) CONCENTRATION (mg/L) MEAN TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATION (mg/L) NA NOT AVAILABLE OR NOT MEASURED WELL SCREEN r COMPLIANCE BOUNDARY NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (Ng/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) - WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. -NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS REPORTING UNITS Hg/L Ng/L mg/L mg/L 1SA NCAC 02L STANDARD 700 NE 2S0 Soo BACKGROUND THRESHOLD VALUES so (SHALLOW FLOW ZONE)' 3 4 S7 BACKGROUND THRESHOLD VALUES 50 (TRANSITION FLOW ZONE)' 12 is 107 BACKGROUND THRESHOLD VALUES 50 (BEDROCK FLOW ZONE)' 11 17 120 '-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED 800 750 a? ❑ Q Z z O Q W 700 w 650 600 CROSS SECTION LOCATION Rev. 1 23 April 2020 850 800 c? 750 Q Z Z O Q W W 700 650 600 - D = UNIT 5 INACTIVE ASH BASIN D' (WEST) I I (EAST) GROUNDWATER FLOW IS PERPENDICULAR TO CROSS SECTION IN THIS AREA N m LA rA Lei a 3 SAPROLITE FILL _ _ FILL > -_ TRANSITION 1 1 \ -_ — ��n�io Y_ __ --- =_:ASH= -------------------------------------------------------------_ sr 4s \ \ / SAPROLITE--==---==---==---==---==---==---= ASH -_-==---==---==---==---==---== �_ --------------------------- ----------------------- }. -- ------------------------------------------------ ----- \ US-029•SLR---------------------------------------------- N Ib /ASH PORE WATER - o- os----------------------------------------------------- s a�a a a TZONERANSITION---------- \ U. - �:7 rL rL / — \ \ \-------------------------------- y _ ------------------------------ I \- --------- ASH PORE WATER SAPROLITE GwAos BEDROCK o- os _---__-_-__-__--__-- ------- _ s. s3� nnv.am 1.2 TRANSITION \ / I sr sse _ 'ZONE \ / _ IAW-a RIJ BEDROCK/ \ \ / I \ \ / I 449 \ / \ �0.5\ / BEDROCKI Srmi CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 25S WELL IN SHALLOW LAYER >) e ROgpRi�ER. GWA-25D WELL IN DEEP LAYER GWA-21BR WELL IN BEDROCK LAYER _ u 1 WAS AB 6S WELL IN ASH PORE WATER FORMER - Q -- UNITS 1-4 ,.. ABANDONED WELL/ AB 4APW GEOTECHNICAL BORING ASH BASIN ASH I CSTESME STORAGE V STATION I GENERALIZED WATER TABLE GENERALIZED GROUNDWATER > Q AIT5 —► FLOW DIRECTION -� < INACTIVE - - c�N. ASH BASIN ACTIVE ASH BASIN _ ASH ASH PORE WATER SLR . F 'OO �Fq gpgo FILL SAPROLITE MCCR ® TRANSITION ZONE CCP LANDFILL,.'FewRp ;-• r -� "D .6-- %Tcv:'' BEDROCK NOTE: _ CROSS SECTION D-D' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. V ASH PORE WATER ELEVATION SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION V BEDROCK GROUNDWATER ELEVATION MEAN CHROMIUM (Cr) CONCENTRATION (Ng/L) MEAN STRONTIUM (Sr) CONCENTRATION (ug/L) NA NOT AVAILABLE OR NOT MEASURED WELL SCREEN COMPLIANCE BOUNDARY NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. CHROMIUM (Cr) AND STRONTIUM (Sr) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (ug/L). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Cr Sr REPORTING UNITS ug/L Ng/L 15A NCAC 02L STANDARD 10 NE BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 26 34 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 BACKGROUND THRESHOLD VALUES 3 93 (BEDROCK FLOW ZONE)' 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. 850 800 650 600 CROSS SECTION LOCATION Rev. 1 23 April 2020 UNIT 5 INACTIVE ASH BASIN 850 (WEST) (EAST) 850 I I GROUNDWATER FLOW IS PERPENDICULAR TO CROSS SECTION IN THIS AREA m Q J J J �� rn ci m m � N N N N 800 m Ln Lf) lug Ln Ln 800 Q SAPROLITE - _ = FILL 750 ❑ Q Z Z O Q W W 700 650 600 _TRANSITION ZONE ----r-_ cr(w) o.a67 co_.ASH=-- - ----------- - ----------------------------------------------------------- Fe 79s Mn 69 \ \ / \ \ -- - __ -- �-------- _--- -- SAPROLITE -_______________________________ ___ _________________________ ASH =_=_=__-_�____-_�____-_�____-_�____-_�____ Crc(a ) <o� / \ / --__ u -----�---�---�---�---�==-== ---------- Mn 5960 / ASH PORE WATER �- ___ ___ _________-____-____-_-__-____-____-_ Ra Q Q Fe 62a6o _ _ TRANSITION / :7 C� ZONE==__-==__-==___-cr(v1) 0.029 ------------------------------ V----- �---------------------------- SAPROLITE I / \ / Fe 14182 -_-___=ASH PORE WATER =_-_-__ \BEDROCK / — \ _ \ i / Ra Ls 1 i / _ \ _ ` / — / \--___---_____-_--__--__ Mn 144z / usozeR / \\/ ( \ / / \/ / \ / / \\/ \ / / / / ------------ -__ -__ _-_ �/ RaTRANSITION \\/ Cr(VI) <0.025 25.1 \ \ \ ------ / \ ZONE Fe 6266 — _ / \ GWA-09D s93o/\I/1\\/\I/1\\/\B��CK\I/1\I/ `col)<930 Mn 432 CROSS SECTION DOES NOT INCLUDE A BEDROCK EVALUATION BORING WHERE OPTICAL TELEVIEWER DATA CAN BE USED TO DETERMINE GENERALIZED FRACTURE ORIENTATION. LEGEND GWA 25S WELL IN SHALLOW LAYER eR OgoRReR GWA-25D WELL IN DEEP LAYER GWA-21BR WELL IN BEDROCK LAYER WELL IN ASH PORE WATER FORMER - :- UNITS 1-4 ABANDONED WELL/ AB 4APW . ASH BASIN „y s GEOTECHNICAL BORING STORAGE CSTEnME STATION v GENERALIZED WATER TABLE GENERALIZED GROUNDWATER >L INACTIVE_ — FLOW DIRECTION 'a ASH BASIN ACTIVE �N ASH BASIN =N ASH ASH PORE WATER o L� FOo�F A r ROgo ® FILL SAPROLITE MQQRwRogo ® TRANSITION ZONE LANDFILL ..• r r� BEDROCK " - P-- NOTE: _ CROSS SECTION D-Dr IS LINEAR IN NATURE AND ALL " --:--'-" LOCATIONS NOTALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION V ASH PORE WATER ELEVATION V SHALLOW GROUNDWATER ELEVATION V DEEP GROUNDWATER ELEVATION BEDROCK GROUNDWATER ELEVATION MEAN CHROMIUM (Cr VI) CONCENTRATION (pg/L) cr(VI) aoss MEAN COBALT (Co) CONCENTRATION (pg/L) m 7S1 MEAN IRON (Fe) CONCENTRATION (pg/L) M S9�10 MEAN MANGANESE (Mn) CONCENTRATION (pg/L) TOTAL RADIUM (Ra) CONCENTRATION (pCii/L) FNAI NOT AVAILABLE OR NOT MEASURED WELL SCREEN COMPLIANCE BOUNDARY NOTES: Co 59.4 Co T Fe 18260 Fe a6 356 Mn 2014 Mn 28 MW-40BRU Ra 15 \ Ra C.r(vl) 0.082 Co -al \ / BEDROCK / / Fe 159 / _ \ Mn 196 Ra 4.6 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. HEXAVALENT CHROMIUM (Cr (VI)), COBALT (Co), IRON (Fe), AND MANGANESE (Mn) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L). TOTAL RADIUM (Ra) CONCENTRATIONS ARE IN PICOCURIES PER LITER (pCi/L) * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Cr (VI) Co Fe Mn Ra REPORTING UNITS Ug/L pg/L Ug/L pg/L pCi/L 15A NCAC 02L STANDARD NE 1* 300 50 NE BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 4 21 1700 969 2 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 0.6 5 1840 260 2 BACKGROUND THRESHOLD VALUES (BEDROCK FLOW ZONE)' 0.7 2 7660 113 3 * - IMAC OFTHE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED 750 0? Q Z Z O Q W 700 W 650 600 Rev. 1 23 April 2020 E _ (SOUTHWEST) m G J 800 I _ » 750 W Co ° Q Z Z 700 0 H w w 650 600 550 500 350 300 U"Is UNIT 5 INACTIVE ASH BASIN ------------- TDS 217 _ _ _ _ _ _ ___ ------------------------ - ASH PORE WATER-_------_--- J -- - ----- ASH -��---------- -- US-01D - U"2S-SLB -_ - B <50 8 267 ------------------------ Li_ _ m 2a7 \ Li 54.9FILL 19 SO4 3 SO4 145 --- .42W \ r\\/ i \ TRANSITION ONE IN / \ / — B 125 Li lfi7 \ = US-GZBR SO4 / Li lm / SAPROLITE — \ B US-0ns135 — I Li 12 \ / — I \ / I \ / — / \ I \ SO4 22 TD5 n BEDROCK / — / \ — 1 / — / \ _.�� — \ _ Bus mD \T/ lI,\/ / / \ �... . / \/ \ l \ Li 9.6 / / ♦\ I�\ / \ /\ / \ I�\ / \ /�(/ \ / \ s04 G5 \ — %� / �•.� — \ \ / \ / — _ IN / \ / — \ / \ �j — _ \ / \ / TDS / \/\I/1��•�/\I/1\\•�•\I/1\\/\I%1\ / uso/4BRAI ks IN IN log IN IN IN AV IN IN IN IN ` 1 / / \ �• ''� \ 1 / , I, / \ 1 / BEDROCK 1•�•• 1 / / \ / \ 1 / / IN IN IN IN IN T T7\ Rm-- E' (NORTHEAST) 800 750 co Go 00 f/i m m m M M Q IVNNN Q' Q' Z �� 700 3333 Z 0 \GWA-02S j i B 129 BROAD w Li 0.5 ------e 35s-- \ RIVER w SO4 65 IDS 191 \\\ -666, / Li 504 ca5 41 ---i---- GWA-02BRU / \ TDS 131 B 127 \ / Li la7 I \ TRANSITION SO4 G9 / 1►♦ ; ZONE TDS 269 GWh35D — 1 / 02B ♦ / 8 12S / I♦x♦ \l / B a / x 1a5 / IN Li 5.4 _ ' / SO4 63. \ 1 \ 48 ♦\ / \ TDS IN IN / — F ININ ♦1 / — \ / I / \\ — 11 %\ / I / \ " / \\/ I / \ / / — IN \ — \ / \ / — IN _ IN / \ / — \ / IN / — — IN / \ / — _ IN / \ / — — IN / IN / — _ \ / \ / — _ IN / \ / — \ / \ / \ — _ IN IN \ / N, / I — — \ / \ / — \ \ / N, / — — IN / \ / \I /1 \ GWA-68BRL B Li 9.0 / — — NN / \ / — \ IN 95 / /\ / \ FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED / \ / ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE I / \ / / \ / IN / \ / TS04 DS I / / — 302 \ / I / \ / / / IN / \ / ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANEOFTHE CROSS SECTION, AND I VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO — — \ / / \I \ / \ / \ / — I \ — — \ / / \I \ / \ / N, — — ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHSAND LENGTHS OF FRACTURES VERSUS DEPTH ARECONCEPTUALONLY. 650 600 550 FORMER �...}:. UNITS 14 ASH BASIN ' 14ASH CLIFFSIDE\ Y STORAGE STEAM ' AREA STATION ' c� ACTIVE NIT 5 or ASH BASIN INACTIVE .ASH BASIN' l`9 LANDFILL MCCRA�'R \`/, NOTE: CROSS SECTION E-E' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. CROSS SECTION LOCATION LEGEND U5 4S WELL IN SHALLOW FLOW LAYER ASH PORE WATER ELEVATION U5 4D WELL IN DEEP FLOW LAYER SHALLOW GROUNDWATER ELEVATION U5-4BR WELL IN BEDROCK FLOW LAYER U5 2S SLA WELL IN ASH PORE WATER DEEP GROUNDWATER ELEVATION GENERALIZED WATER TABLE BEDROCK GROUNDWATER ELEVATION GENERALIZED BEDROCK FRACTURE ORIENTATION MEAN BORON (B) CONCENTRATION (ug/L) GENERALIZED GROUNDWATER R MEAN LITHIUM (Li) CONCENTRATION (ug/L) —� FLOW DIRECTION T� MEAN SULFATE (SO4) CONCENTRATION (mg/L) MEAN TOTAL DISSOLVED SOLIDS (TDS) 0 ASH CONCENTRATION (mg/L) ASH PORE WATER ® FILL WELL SCREEN SAPROLITE ® TRANSITION ZONE — — — COMPLIANCE BOUNDARY BEDROCK �� BREAKLINE NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO TUNE 2019. 500 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (Hg/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO TUNE 2019 WAS USED. -NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS REPORTING UNITS Ng/L Ng/L mg/L mg/L 350 1SA NCAC 02L STANDARD 700 NE 2S0 S00 BACKGROUND THRESHOLD VALUES 50 3 4 57 (SHALLOW FLOW ZONE)' BACKGROUND THRESHOLD VALUES 50 12 15 107 (TRANSITION FLOW ZONE)' BACKGROUND THRESHOLD VALUES 50 11 17 120 (BEDROCK FLOW ZONE)' �-UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN TUNE 2019. NE - NOT ESTABLISHED 300 Rev. 1 23 April 2020 (SOUT WEST) (NORTHEAST) * eRpgR _. pp UNIT 5 INACTIVE ASH BASIN A FORMERUNITS 14 \> ASH BASINHOO > N SOO 1 4CLIFFSIDE\ STORAGE STEAM � ' AREA STATION ' ACTIVE � I � � NIT 5 � r ASH BASIN - m 0 INACTIVE I ram" J U"Is a 0.7 750 ASH _ _ _ _ - _ _ _ 750 ap�q 00 usmn - -_ R - ASH PORE WATER = _ = li pqp 6 <0.5 - _ may`- _ _ _ _ ` _ ---_ _ FILL1 LAN FlLL MCCRgw \`/% W \ /� / 1 / saa-s0.6 �' _ - _ Q 00 F^ W > \ 1 .yam/ \ / as TRANSITION Q > Z a /\ / I/\ usmn I/ \ ZONE N N N N M M Z NOTE: / \ / — \ Q Q CROSS SECTION E-F IS LINEAR IN NATURE AND ALL Z 700 / — ` I \ / ; \ _ Q Q Q Q ?� 700 Z LOCATIONS NOT ALONG THE CROSS SECTION ARE \ / 1 / �� / j / 1 / —1 / SAPROLITE 0 0 0 O PROJECTED ONTO THE CROSS SECTION. 3.8 W —ol W CROSS SECTION LOCATION se'/ — \ / \ / 11 ------ ------ BROAD �.� RIVER LU LEGEND 1 — 1 ' /♦ — BEDROCK / — / \ — 1 ' / — ' \ T� �,/ 1 / \ — 1 ' / a, °�01OL7 \r z� QcwA.as s `.� -sss — U5-4S WELL IN SHALLOW FLOW LAYER ASH PORE WATER ELEVATION ♦ ` / \ coo 650 WELL IN DEEP FLOW LAYER 'j�BSO wox WELL IN BEDROCK FLOW LAYER SHALLOW GROUNDWATER ELEVATION TRANSITION C•� / \ / 1 \ �.\ / 1 \ / \ / 1 1 \ / \ 1 ZONE WELL IN ASH PORE WATER . / / , / , _ i — ��/ Gw� U5 2S SLA DEEP GROUNDWATER ELEVATION ;Anj GENERALIZED WATER TABLEBEDROCK GROUNDWATER ELEVATION `sGENERALIZED BEDROCK FRACTURE \ ✓ 1 / \ / \ / 1 \ / 1 / \ / \ / 1 \ / 1 \ / \ 1 \ X�1 / ��\ / \ /IA ORIENTATION MEAN CHROMIUM (Cr) CONCENTRATION (ug/L) 600 _ 1 / \ — 1 ' / — ' 1 / \ — \ ' / — ' �� / �1 — \ ' / ' 1 ' / �� \ — 1 ' / ' — 600 —� GENERALIZED GROUNDWATER 117 MEAN STRONTIUM (Sr) CONCENTRATION (ug/L) FLOW DIRECTION ASH WELL SCREEN ASH PORE WATER BEDROCK I / / \ l / / / ® FILL COMPLIANCE BOUNDARY _ SAPROLITE 550 \\ / \I / 1 \ �\ / \I / 1 \ \ / \I / 1 \ �\ / \I / 1 \ �\ / \I / 1 \ �\ / \I 1 \ i / \I / 1 \ %�►\ \,, 550 BREAKLINE TRANSITION ZONE As �•.,-��/ \ / _♦ \ — / \ / �, \ �� — / \ �f. — / \ / \ — / _ i- . BEDROCK NOTES: / — �► V •/ — I �k , — I \ / — I \ `� i• \ 6wA-67BI1 \ ♦ I \ l� — �, va �1 / •� \ / i �/ 1 ,/ �,\ / <� /,�� / A\ 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATAS ET USING DATA RANGING FROM JANUARY 2018 TO 500 500 DUNE 2. CHROMIUM (Cr) AND STRONTIUM (Sr) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (u9/L). * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. NO DATA AVAI LAB LE ANALYTICAL PARAMETER Cr Sr REPORTING UNITS \\ \ / \\/ /I —/ \_/\ / \ \/ ► / \ \ / \\/ /I —/ \—/\ / \ \/ I / \ / \ /I —/ \_/\ / \ \/ I / \ \ / \\/ /I—/ \_/\ / ug/L u 350 15A NCAC 02L STANDARD 10 NE350 BACKGROUND THRESHOLD VALUES 3a (S HALLOW FLOW ZONE)' 26 34 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED \ / I / \ / / I \ / / \ / I / \ / / I \ / / \ / I / \ / / ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE / \ / — \ \ / \ / \ / — — \ \ / \ / \ / — _ \ BACKGROUND THRESHOLD VALUES 3 93 VRIENTATIONS ACCOUNT FOR ERTIAPPARENT O CROSS SECTION, AND CAL EXAGGERATION. THE ACTUALNUMBERO FRACT FRACTURES ISFARTOO NUMEROUSTO\ I / 1 \ ' \ I / 1 \ \ ' \ I / 1 \ \ ' (BEDROCK FLOW ZONE)' ILLUSTRATE ATTHIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH / — ' \ 1. / �. — 1 ' / — ' \ 1 ' / / — 1 ' / — ' \ / 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA 300 ,ARE CID NCEPTUALONLY. — \ / — `\ ' — / \ , — ' — / \ / — / 300 FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. Rev. 1 23 April 2020 E- (SOUTHWEST) m J 800 7 7 If2 LLY N 750 0 Q Z Z 700 0 H W W 650 600 550 500 350 300 US-0Is UNIT 5 INACTIVE ASH BASIN as ......zs \ — Co 119 TRANSITION - Fe 6785o Mn 643 ZONE I / Ra 0.145 / GWA-02BR US-02D \ Cr(VI) <0.025 vI) 0.034 1 / co o.l / SAPROLITE Co 3.1 / �•••/ / Fe 36740 Mn 125 / / us-m Mn 872 I / Ra 17 ��� _ \/ / \ Cr (VI) 2.640 Ra LS / \— _ I� / \ / \ / Co 15 Fe 353 Mn 23 \ / — BEDROCK / — / \ — \ / — / -•T•L f — / Ra US-04D Cr(VI) 0.105 Co (13 Fe ac \ ��, / I�••`•O / \ \ / \ / — _ \ / \ / \ \ \ / \� �/ \\ \/ /C /\ \\// 1 I / �•\ '�/� /\ /I \// 1 \/i \/•�/•�\ �I \//•1 I•\•\ // /\ /I \%/ 1 \/ /\ /1 Mn 29usoR CrIVI) 0.580m M/ I ks AV ` \ / / \ �• ''� \ \ � / � , I, / \ \ / / \ / � � r BEDROCK 1•�•• \ / / \ / \ \ / / Fe 1al 825 Mn 197 \ Ra 3.7 E' (NORTHEAST) MM Im N � � __L___-- BROAD GWA-355 q4A, ---- cr(vp <onzs \\ RIVER 666' Co F. ]60A0\ RaTRANSITION ZONE / — C icr(vl) <o.oa X <(IS 2S1 as7s Fe 6266 Mn 5910 \ / \ I / n 119 jr -0BBRL o.06o 01 VFe 1 FRACTURES CONCEPTUALLY DEPICTED ON THIS CROSS SECTION REPRESENT GENERALIZED ORIENTATIONS OF FRACTURES OBSERVED BASED ON TELEVIEWER LOGGING. THE DEPICTED FRACTURE ORIENTATIONS ACCOUNT FOR APPARENT DIP WITHIN THE PLANEOFTHE CROSS SECTION, AND VERTICAL EXAGGERATION. THE ACTUAL NUMBER OF FRACTURES IS FAR TOO NUMEROUS TO ILLUSTRATE AT THIS SCALE. IN ADDITION, THE DEPTHS AND LENGTHS OF FRACTURES VERSUS DEPTH ARE CONCEPTUAL ONLY. 800 750 R 0 Q Z 700 Z O LU W LEGEND CROSS SECTION LOCATION U5 4S WELL IN SHALLOW FLOW LAYER ASH PORE WATER ELEVATION 650 U5 4D WELL IN DEEP FLOW LAYER U5-4BR WELL IN BEDROCK FLOW LAYER SHALLOW GROUNDWATER ELEVATION U5 2S SLA WELL IN ASH PORE WATER DEEP GROUNDWATER ELEVATION V — GENERALIZED WATER TABLE BEDROCK GROUNDWATER ELEVATION GENERALIZED BEDROCK FRACTURE ORIENTATION MEAN CHROMIUM (Cr VI) CONCENTRATION (pg/L) 600 GENERALIZED GROUNDWATER o-m MEAN COBALT (Co) CONCENTRATION (pg/L) mmoo, FLOW DIRECTION Mn MEAN IRON (Fe) CONCENTRATION (pg/L) MEAN MANGANESE (Mn) CONCENTRATION (pg/L) © ASH MEAN RADIUM (TOTAL)(Ra) CONCENTRATION ASH PORE WATER (pCi/L) ® FILL WELL SCREEN SAPROLITE 550 ® TRANSITION ZONE — — — COMPLIANCE BOUNDARY BEDROCK BREAKLINE NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 500 2. HEXAVALENT CHROMIUM (Cr (VI)), COBALT (Co), IRON (Fe), AND MANGANESE (Mn) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (pg/L). TOTAL RADIUM (Ra) CONCENTRATIONS ARE IN PICOCURIES PER =R (pCi/L) 3. WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER Cr (VI) Co Fe Mn Ra REPORTING UNITS pg/L pg/L Pg/L pg/L POP SSA NCAC 02L STANDARD NE 1' 300 5o NE BACKGROUND THRESHOLD VALUES 350 (SHALLOW FLOW ZONE)' 4 21 1700 969 2 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 0.6 5 1840 260 2 BACKGROUND THRESHOLD VALUES 0.7 2 7680 113 3 300 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED Rev. 1 23 April 2020 L- (SOUTH) UNIT 5 INACTIVE ASH BASIN 800 mNI^� J > > > FILL to j us z 700 0 a > -J J W -- - - - - - - - - - - - - - - - - - - - - - - - - - - - FILL- - - - - - - - - - - - - - - - - - --_-_-_-_-_-_-_-_-_ ----------------- ---------------ASH -------- us- 0B5 ------ — — — — — — — — — — — — — — — — — — — — — i c0.s — — — — — =— — — — — — — — — —R- )4 27—_—_—_—_—_—__—_ S 211 — _ SAPROLITE _— �� ---_____________- -------------- - - - ASH PORE WATER - TRANSITION _ _ _ _ _ usanL B 180 u FILL \ US-07D B 1 331 - SAPROLITE \ s04 2 \ / \ / — / \ / — / \ / — 141 \ / — — \ / \ / SLi 04�28.7 / BWA� 400 229 \TDS \ I / 1 \ 504 184 TDS 362 SITION ZONEbw p�- 4.5 // \ so4 GWA-37s US-OSBR I TDS 452 I \ / — B 80 \ / / 1 U 447 \ / / 1 / \ \ / U 0.6 B - / BEDROCK - / / - / / - / / - _ / _ _ 1 / SO4 5 / \ \ / \ \ / TDS 182 TDS / BEDROCK 11.6 SO4 Luc a a: � BROAO R/V! FO ^:./�_'��r�� UNITS 1-4 ASH BASIN ,a.t "CLIFFSIDE \ \ �� A. -r STOF STEAM STATION U UNIT P=Q ` INACTIVE ASH BASIN ", < r, loo, a ASH MccRgk'ROgO -, LAND ILL �, - NOTE: "- CROSS SECTION L-L' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. LEGEND GWA 37S WELL IN SHALLOW LAYER GWA 37D WELL IN DEEP LAYER U5 5BR WELL IN BEDROCK LAYER ABANDONED WELL/ U5 7SL GEOTECHNICAL BORING V - GENERALIZED WATER TABLE -o. GENERALIZED GROUNDWATER FLOW DIRECTION 0 ASH ASH PORE WATER FILL �J SAPROLITE ® TRANSITION ZONE BEDROCK ALLUVIUM V ASH PORE WATER ELEVATION V SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION V BEDROCK GROUNDWATER ELEVATION a MEAN BORON (B) CONCENTRATION (ug/L) MEAN LITHIUM (Li) CONCENTRATION (pg/L) MEAN SULFATE (SO4) CONCENTRATION (mg/L) MEAN TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATION (mg/L) WELL SCREEN COMPLIANCE BOUNDARY - L' (NORTH) NOTES: 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. BORON (B) AND LITHIUM (Li) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (Ng/L) 3. SULFATE (SO4) AND TOTAL DISSOLVED SOLIDS (TDS) CONCENTRATIONS ARE IN MILLIGRAMS PER LITER (mg/L) - WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. - NO DATA AVAILABLE ANALYTICAL PARAMETER B Li SO4 TDS REPORTING UNITS Pg/L Pg/L mg/L mg/L 15A NCAC 021 STANDARD 700 NE 250 500 BACKGROUND THRESHOLD VALUES (SHALLOW ROW ZONE)' 50 3 4 57 BACKGROUND THRESHOLD VALUES 50 12 15 107 (TRANSITION ROW ZONE)' BACKGROUND THRESHOLD VALUES 50 11 17 120 (BEDROCK FLOW ZONE)' ' - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. NE - NOT ESTABLISHED w o� m z O > W J W CROSS SECTION LOCATION Rev. 1 23 April 2020 L- (SOUTH) UNIT 5 INACTIVE ASH BASIN 800 > > > FILL to j L6 T R. z 700 O a W J w FILL ■■■■■■■■■■■■■■v--___--------------------------- G3Y=QSw-� i ASH- '■• SAPROLITE ASH • ' TRANSITION — — — — hi��l o® lip SAPROLITE \ SriawAo3oo Sr 233 o- IVus oo \ TRANSITION us aaen BEDROCK a 33 — / / — / \ \ \ — / \ / / — / \ \ \ — / \ / — / \ \ \ — / / — / BEDROCK / Sr ssl NOTES: - F .. FORMER UNITS 1-4 ASH BASIN s� ASH / Cl FFSIDE - r STORAG 1A' STEAMUNIT 5 sTAnoN � '� P=Q ` INACTIVE f -- - k ... ,. ASH BASIN " \ k_ ACTIVE 'c�a i 1 `� :_ tk►� � ` = ASH BASIN o / qo � LAND ILL NOTE: "- CROSS SECTION L-L' IS LINEAR IN NATURE AND ALL LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. LEGEND GWA 37S WELL IN SHALLOW LAYER GWA 37D WELL IN DEEP LAYER U5 5BR WELL IN BEDROCK LAYER ABANDONED WELL/ ISL GEOTECHNICAL BORING V — GENERALIZED WATER TABLE —o, GENERALIZED GROUNDWATER FLOW DIRECTION 0 ASH ASH PORE WATER FILL L—� SAPROLITE ® TRANSITION ZONE BEDROCK ALLUVIUM 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. CHROMIUM (Cr) AND STRONTIUM (Sr) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (u9/L). ASH PORE WATER ELEVATION * WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. SHALLOW GROUNDWATER ELEVATION DEEP GROUNDWATER ELEVATION V BEDROCK GROUNDWATER ELEVATION u�Q58A MEAN CHROMIUM (Cr) CONCENTRATION (ug/L) a 1342 MEAN STRONTIUM (SR) CONCENTRATION (Ng/L) WELL SCREEN COMPLIANCE BOUNDARY - NO DATA AVAILABLE ANALYTICAL PARAMETER Cr Sr REPORTING UNITS P9/L Pg/L 15A NCAC 02L STANDARD 10 NE BACKGROUND THRESHOLD VALUES (SHALLOW FLOW ZONE)' 26 34 BACKGROUND THRESHOLD VALUES (TRANSITION FLOW ZONE)' 2 69 BACKGROUND THRESHOLD VALUES 3 93 (BEDROCK FLOW ZONE)' 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS SUBMITTED IN JUNE 2019. - L' (NORTH) CROSS SECTION LOCATION Rev. 1 23 April 2020 L- (SOUTH) UNIT 5 INACTIVE ASH BASIN 800 > > > FILL to j L6 oz 700 a W J W �■■■�■■■■■■■■■v---------------- - ■■■■■■ J■■■■■�� av--- -- �����' '® '� SAPROLITE ASH PORE WATER ' QO ZONE AD mmmm FILL Cr(VI) 0.035 Fe 150 �- \ _ Ra — cr(wl is GWA-a3D SAPROLITE Mn 8 \ / \ / \ \ _ \ / \ / \ \ _ \ Co SA \ / — — \ / \ Co 19.2 / - I / I \ / Mn Fe 4410- \ / \ / \ I 1 MO llF. \ I r(VEe 174 ` Ra _ I \ I) \ Mn 1464 Fe 5-4 \ / / R. 1.6—ZONeslTloN Ra <0.599 — GWA-375 Cr(VIrr080.690 \_ / / I 1 / \ \ \ I 1 \ \ \ / I 1 / \ \ \ I \ \ / I 1 / \ \ \ I 1 \ / I / 1 59 CrCo <9 .7 _ / BEDROCK — _ / _ / — _ / _ / — — Fe 15860 Fe 4� \ / \ / \ _\ / \ \ / \ / \ \ / \ \ \ / \ / \ _\ / \ \ / \ Ra 31_\ / BEDROCK \ \ / \ / \ _ \ / 7866 Mn <5\mil\ \/ i Ra \ I \ \ I \ \ I \ \ I \ \ I a6 85 48 Ra NOTES: - L' (NORTH) 1. CONCENTRATIONS SHOWN ARE STATISTICAL MEAN CALCUALTED BASED ON CENTRAL TENDENCY OF DATASET USING DATA RANGING FROM JANUARY 2018 TO JUNE 2019. 2. HEXAVALENT CHROMIUM (Cr (VI)), COBALT (Co), IRON (Fe), AND MANGANESE (Nb) CONCENTRATIONS ARE IN MICROGRAMS PER LITER (Pg/L). TOTAL RADIUM (Ra) CONCENTRATIONS ARE IN PICOCURIES PER LITER (pCi/L) 3. WELLS WITH DATASETS CONTAINING FEWER THAN FOUR VALID RESULTS, THE MOST LEGEND ASH PORE WATER ELEVATION RECENT VALID SAMPLE DATA UP TO JUNE 2019 WAS USED. Q , RogoRlVeR - NO DATA AVAILABLE GWA 37S WELL IN SHALLOW LAYER SHALLOW GROUNDWATER ELEVATION ANALYTICAL PARAMETER Cr (VI) Co Fe Mn Ra ry GWA 37D WELL IN DEEP LAYER REPORTING UNITS PNE Pg/L P Nso pCi/L \ DEEP GROUNDWATER ELEVATION isN 00 02LSTANDARD NE 1* 300 SO NE "A FORMER"' ' 514 �+' U5-5BR WELL IN BEDROCK LAYER BACKGROUND THRESHOLD VALUES THRCACESHOLD 4 21 1700 969 2 ' / UNITM ,' ASH BASIN V `. i I '' y�.- ASH - U5-7SL 0 ABANDONED WELL / BEDROCK GROUNDWATER ELEVATION (SHALLOW FLOW ZONE) BACKGROUND THRESHOLD VALUES o.6 5 1840 260 2 (TRANSITION FLOW ZONE) , CLIFFSIDE\ A -- STORA�G GEOTECHNICAL BORING BACKGROUND THRESHOLD VALUES ( STEAM 41 STATION 1., o (. GENERALIZED WATER TABLE CCR-U5-05D MEAN CHROMIUM (Cr VI) CONCENTRATION (ug/L) 0.7 2 7680 113 3 (BEDROCK FLOW ZONE) ' <� UNIT B r cr(vq MEAN COBALT (Co) CONCENTRATION (ug/L) - IMAC OF THE 15A NCAC 02L STANDARD, APPENDIX 1, APRIL 1, 2013. ` INACTIVE �, A H BASIN r ACTIVE ASH BASIN', GENERALIZED GROUNDWATER Fe 54 MEAN IRON (Fe) CONCENTRATION (ug/L) 1 - UPDATED BACKGROUND THRESHOLD VALUES WERE CALCULATED USING DATA FROM BACKGROUND GROUNDWATER SAMPLES COLLECTED FEBRUARY 2010 TO DECEMBER 2018 AS .,. FLOW DIRECTION - - MEAN MANGANESE (Mn) CONCENTRATION (Ng/L) SUBMITTED IN JUNE 2019. oG.� r,% .. , �.� - ASH Ra <0.599 MEAN TOTAL RADIUM (Ra) CONCENTRATION (pCi/L) NE -NOT ESTABLISHED (r �FAo r / ASH PORE WATER f �rl R \ I � ` ® FILL WELL SCREEN ' y OggwRo F SAPROLITE - - - COMPLIANCE BOUNDARY DUKE 0 50 100 200 FIGURE 6-71c GENERAL CROSS SECTION L-L' LANDFILL �, N 4)ENERGY HoarzoNrAL SCALE: I°=zoo' RLL u � qo - ® TRANSITION ZONE VERTICAL SCALE: 1"=40' VARIABLE GROUP BEDROCK CARO 5X VERTICAL EXAGGERATION MEAN OF CHROMIUM (VI), COBALT, IRON, MANGA "- CROSS SECTION L-L' IS LINEAR IN NATUREAND ALL IN DATE: 10/22/2019 DRAWN BY:1.REVISED BY: D. REF. KREFSKI DATE: 3/2/2020 AND TOTAL RADIUM LOCATIONS NOT ALONG THE CROSS SECTION ARE PROJECTED ONTO THE CROSS SECTION. ALLUVIUM L� CHECKED BY: T^GRANT -- DATE: 3/2/2020 UNIT 5INACTIVE ASH BASIN CROSS SECTION LOCATION Rev. 1 23 April 2020 TABLES TABLE 4-3 BACKGROUND VALUES FOR GROUNDWATER CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Constituent Reporting Unit 15A NCAC 02L Standard 2017 Background Threshold Values' g 2019 Updated Background Threshold ValueS2 g Piedmont Background Threshold Values Range Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone Shallow Flow Zone Deep Flow Zone Bedrock Flow Zone pH S.U. 6.5-8.5 4.4-6.1 4.8-6.1 5.4-7.4 4.0-6.0 4.9-7.2 4.5-7.5 3.6-9 Alkalinity mg-CaCO3/L NE 14 20 53 19 54 56 19-379 Aluminum pg/L NE 1 253 290 208 820 483 309 100-1,238 Antimony pg/L 1* 1 1 1 0.5 0.5 1 0.5-2.9 Arsenic ug/L 10 1 1 1 0.2 2 1 0.2-6.35 Barium pg/L 700 73 23 19 94 44 19 10.52 - 840 Beryllium p9/L 4* 0.2 0.2 1 0.2 0.2 0.2 0.0625-1 Bicarbonate mg-CaCO3/L NE 14 18 69 19 58 59 19-388 Boron pg/L 700 50 50 50 50 50 50 50-176.8 Cadmium pg/L 2 1 1 1 0.09 1 1 0.08 - 1 Calcium mg/L NE 3 11 16 4 13 17 4-111 Carbonate mg-CaCO3/L NE 5 5 5 5 5 5 5-10 Chloride mg/L 250 8 5 9 8 8 8 3.34 - 250 Chromium pg/L 10 4 2 4 26 2 3 43,491 Chromium (VI) pg/L 10 0.5 0.2 0.1 4 0.6 0.7 0.03-12 Cobalt pg/L 1* 11 5 1 21 5 2 0.088-88.85 Copper p9/L 1,000 7 10 5 9 8 5 0.5 - 17.15 Fluoride mg/L 2 --- --- --- 0.1 0.1 0.1 Iron p9/L 300 684 515 6,220 1,700 1,840 7,680 56.3 - 37,500 Lead pg/L 15 1 1 1 1 0.3 1 0-2 Lithium ug/L NE --- --- --- 3 12 11 2-95.39 Magnesium mg/L NE 2 2 2 2 2 2 1 -45 Manganese Ng/L 50 169 78 89 969 260 113 2,655,496 Mercury pg/L 1 0.2 0.2 0.2 0.2 0.2 0.2 0.05 - 0.5 Methane Ng/L NE 10 3 10 10 10 10 1-2,505 Molybdenum pg/L NE 1 1 2 0.6 4 2 0.5 - 26.2 Nickel pg/L 100 6 13 5 12 13 7 0.87-48 Nitrate + Nitrite mg-N/L NE 9 3 1 4 3 1 0.02-6.3 Potassium mg/L NE 5 5 5 5 1 6 5 1.609-18.8 Selenium pg/L 20 1 1 1 0.5 1 1 0.5 - 2.4 Sodium mg/L NE 6 4 7 6 9 8 6-19 Strontium pg/L NE 37 56 107 34 69 93 27-2,120 Sulfate mg/L 250 1 10 15 4 15 17 1.2 - 510 Sulfide mg/L NE 0.1 0.1 0.1 0.1 0.1 0.1 0.1-2 TDS mg/L 500 75 71 120 57 107 120 50 - 1,200 Thallium pg/L 0.2* 0.1 0.1 0.2 0.2 0.2 0.2 0.1-0.2 TOC mg/L NE 1 1 1 1 2 1 1- 12.3 Total Radium pCi/L NE 3 2 3 2 2 3 0.494-35 Total Uranium pg/mL NE 0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.0002-0.864 Vanadium pg/L 0.3* 1 1 0.4 1 11 1 0.33 - 25.8 Zinc N /L 1,000 15 15 10 26 14 15 5 - 140 Prepared by: HES Checked by: JHG Notes: 2017 background threshold values (BNs) approved by North Carolina Department of Environmental Quality (NCDEQ) on September 1, 2017. Background threshold values (BNs) have been rounded to similar levels of precision as 15A North Carolina Administrative Code (NCAC) 02L Standard or Interim Maximum Allowable Concentration (IMAC). --- - BTV was not calculated for constituent. * - IMAC of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. ' - BNs were calculated using data from background groundwater samples collected June 2015 to September 2017 - Updated BNs were calculated using data from background groundwater samples collected February 2010 to December 2018 3 - Piedmont background threshold value ranges include the Duke Energy calculated 2017' and 20192 background threshold values from 10 Duke Energy facilities located in the Piedmont physiographic region (Allen Steam Station, Belews Creek Steam Station, Buck Steam Station', Cape Fear Steam Electric Plant', Cliffside Steam Station, Dan River Steam Station', Marshall Steam Station, Mayo Steam Electric Plant, Riverbend Steam Station', and Roxboro Steam Electric Plant). pg/L - micrograms per liter pg/ml- - micrograms per milliliter mg/L - milligrams per liter mg-CaCO3/1- - milligrams calcium carbonate per liter mg-N/L - milligrams nitrogen per liter NE - not established pCi/L - picocuries per liter S.U. - standard units TDS - total dissolved solids TOC - total organic carbon Rev. 1 Page 1 of 1 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 ACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. Irg/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 4 11 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone)Z 4.0 - 6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone)Z 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone)Z 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4- 7.4 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone) Z 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone )2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 1 <50 - 11000 1.1 - 7.3 1 5 - 134 16.6 - 116 1 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID Flow Zone Mean, Geomean, or Median Result3 Background Locations BG-01S Shallow 4.9 < 0.1 < 50 0.230 0.9 1.7 171 1.6 39 21 1 < 0.1 41 0.538 < 0.0005 < 0.3 GWA-24S Shallow 5.1 0.1 < 50 0.134 1.4 5.2 113 2.0 52 10 2 < 0.1 30 < 0.732 - 0.5 GWA-25S Shallow 5.2 < 0.1 < 50 0.094 < 0.5 2.7 88 1.7 26 36 < 1 < 0.1 38 - - < 0.3 BG-01D Deep 5.7 0.1 < 50 0.045 < 0.5 0.6 < 50 1.7 12 30 2 < 0.1 56 0.772 < 0.0005 < 0.3 GWA-24D Deep 5.5 < 0.1 < 50 0.032 < 0.5 0.2 < 50 1.7 5 24 3 < 0.1 45 < 0.443 - < 0.3 BG-01BRA Bedrock 11.5 - < 50 - - - - - - - - - - - - GWA-24BR Bedrock 6.0 < 0.1 < 50 0.038 < 0.5 0.1 1 54 1 2.8 1 < 5 1 29 1 7 1 < 0.1 52 - < 0.3 MW-22BR Bedrock 6.4 0.1 < 50 0.084 < 0.5 1.0 369 2.7 49 43 8 < 0.1 67 - 0.3 MW-22DR Bedrock 5.8 < 0.1 < 50 0.036 < 0.5 1.2 511 2.3 52 24 5 < 0.1 39 < 0.3 MW-24DR Bedrock 7.2 < 0.1 < 50 0.033 0.5 < 0.1 1297 6.9 58 80 11 < 0.1 108 2.134 < 0.0005 < 0.3 Within the Waste Boundary Locations AB-03MA15 Ash Pore Water 9.6 282 1708 < 0.025 0.7 < 0.1 < 50 210 < 5 1358 112 < 0.1 327 < 0.0939 0.0003 109 AB-03S Ash Pore Water 7.4 372 2970 < 0.025 1.0 1.0 4268 119 1185 3007 386 0.7 975 0.564 0.0027 5.1 AB-03SL Ash Pore Water 9.6 851 1138 < 0.025 1.1 0.1 128 198 32 897 66 < 0.1 191 1.207 0.0001 75.8 AB-04LA15 Ash Pore Water 5.6 184 606 0.051 0.6 5.4 4108 14.5 686 354 1 0.3 77 1.420 0.0001 1.4 AB-04S Ash Pore Water 9.4 92.6 2513 < 0.025 < 0.5 0.1 < 50 119 < 5 2207 127 < 0.1 471 0.784 0.0006 41.8 AB-04SL Ash Pore Water 9.0 1 1692 1506 0.051 0.7 0.1 97 1 56.5 9 1640 31 1 < 0.1 172 0.415 0.0056 45.9 AB-04UA15 Ash Pore Water 10.0 92.3 2913 < 0.025 0.8 < 0.1 < 50 141 < 5 2270 126 < 0.1 470 1.190 0.0001 38.9 AB-05S Ash Pore Water 8.0 1782 5242 < 0.025 < 0.5 0.1 1728 92.4 211 3540 88 < 0.1 423 1.146 0.1167 1.6 AB-06S Ash Pore Water 8.6 323 8380 0.058 < 0.5 < 0.1 161 103 46 2510 111 < 0.1 377 0.946 0.0010 8.9 AB-07S Ash Pore Water 9.2 157 1760 0.048 0.7 0.1 < 50 133 11 1430 97 0.1 352 < 0.695 0.0017 52.0 AB-08S Ash Pore Water 7.9 65.1 4360 0.033 < 0.5 0.4 120 151 73 2775 842 1.0 1605 < 0.851 0.0725 52.5 AB-09S Ash Pore Water 8.6 1965 5910 1 0.071 < 0.5 < 0.1 119 106 43 2335 1 139 < 0.1 415 0.329 0.0019 0.7 AB-01S Shallow 5.2 0.3 50 < 0.025 < 0.5 68.6 1478 2.5 6045 32 4 0.5 110 - 0.0001 0.4 AB-02S Shallow 5.5 0.8 330 < 0.025 1.9 39.7 9102 2.8 17598 76 24 0.3 124 - 0.5 AB-03I Shallow 6.6 3.1 50 0.447 1.1 0.2 156 5.8 127 131 3 0.4 70 - - 2.4 AB-08I Shallow 6.4 3.1 809 < 0.025 < 0.5 11.8 24250 1.8 10570 109 24 0.1 201 0.750 0.0004 < 0.3 CLMW-05S Shallow 5.2 0.2 < 50 < 0.025 0.4 56.6 294 1 0.9 4790 25 4 0.4 1 65 - - < 0.3 AB-01D Deep 6.6 0.2 804 1 < 0.025 1.3 1.1 9187 4.5 2317 256 36 < 0.1 302 0.4 AB-02D Deep 6.7 0.1 291 0.027 2.5 2.6 17746 15.3 2524 345 50 < 0.1 259 < 0.3 AB-03BRUA Deep 11.4 - 60 - - - - - - - - - - - - AB-04D Deep 4.6 0.1 < 50 0.095 < 0.5 5.3 55 1.9 180 8 < 1 < 0.1 30 < 0.0005 < 0.3 AB-05BRU Deep 5.4 0.4 < 50 0.031 < 0.5 3.5 104 2.3 171 38 5 1 0.1 43 - 0.3 AB-06D Deep 5.2 0.1 < 50 0.027 < 0.5 0.6 < 50 1 1.6 38 29 < 1 < 0.1 34 < 0.0005 < 0.3 AB-07BRU Deep 7.4 - 94 1 - - - - - - - - - - - - - AB-08BRU Deep 6.6 0.5 438 < 0.025 1.5 1.4 1357 14.4 245 172 9 < 0.1 237 1.164 0.0015 0.4 AB-09D Deep 5.9 0.2 77 0.039 0.6 12.0 580 3.4 254 42 3 0.1 48 0.777 0.0001 0.3 AB-01BROR Bedrock 7.0 0.2 397 0.034 15.1 3.8 1550 6.9 1555 268 1 11 < 0.1 364 - - 0.7 AB-02BRO Bedrock 6.9 0.9 476 < 0.025 2.1 8.7 12352 1.8 2188 517 53 < 0.1 292 0.4 AB-03BR Bedrock 12.4 - 46 - - - - - - AB-03BRA Bedrock 12.5 - 33 1 - - - - - - AB-04BR Bedrock 6.3 < 0.1 < 50 < 0.025 < 0.5 < 0.1 11847 5.8 155 105 4 < 0.1 120 2.037 < 0.0005 < 0.3 AB-05BR Bedrock 5.5 0.1 < 50 0.029 1 0.4 1 1.7 49 1.6 109 1 23 6 < 0.1 47 - - < 0.3 AB-06BR Bedrock 6.3 < 0.1 < 50 0.026 0.5 < 0.1 4214 9.1 69 101 5 < 0.1 89 < 0.0005 < 0.3 AB-07BR Bedrock 7.8 0.4 92 < 0.025 2.5 0.2 1018 10.6 1 168 168 5 < 0.1 163 3.285 0.0003 0.3 Rev. 1 Page 1 of 4 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 ACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. lig/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 4 11 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone)Z 4.0 -6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone)Z 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone)Z 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4 - 7.4 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone) Z 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone )2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 1 <50 - 11000 1.1 - 7.3 1 5 - 134 16.6 - 116 1 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID I Flow Zone Mean, Geomean, or Median Result3 Within the Waste Boundary Locations (Continued) AB-08BR Bedrock 6.4 0.8 336 < 0.025 0.9 1.3 2095 8.0 577 164 13 < 0.1 246 1.101 0.0010 0.2 AB-09BR Bedrock 7.4 0.3 < 50 < 0.025 0.6 0.2 2035 8.3 91 93 15 < 0.1 117 0.661 0.0001 0.3 Between Waste Boundary and Compliance Boundary Upgradient of the Ash Basin GWA-23D Deep 5.2 < 0.1 < 50 0.062 < 0.5 0.8 < 50 1.7 9 16 < 1 < 0.1 61 - - < 0.3 MW-21D Deep 5.1 0.1 < 50 0.077 < 0.5 0.9 178 1.5 12 22 2 < 0.1 33 - - < 0.3 MW-24D Deep 5.2 0.2 < 50 0.059 < 0.5 0.1 < 50 1.6 < 5 26 < 1 < 0.1 41 0.427 < 0.0005 < 0.3 CCR-17BR Bedrock 6.0 < 0.1 < 50 < 0.025 2.0 2.0 143 2.1 47 33 6 < 0.1 68 0.906 < 0.0005 0.3 GWA-48BR Bedrock 6.7 < 0.1 < 50 < 0.025 0.6 < 0.1 2300 6.3 49 66 11 < 0.1 91 - - < 0.3 MW-21BR Bedrock 6.9 0.2 < 50 0.029 < 0.5 < 0.1 < 50 4.0 55 53 8 < 0.1 99 - 0.3 Downgradient of the Ash Basin CCR-06S Shallow 4.3 7.0 1317 - 2.5 97.6 - 9.1 - - 508 0.5 867 3.664 - CCR-07S Shallow 6.6 0.2 2714 0.042 0.6 3.0 70 0.9 5496 2648 495 0.5 1153 0.776 < 0.3 CCR-11S Shallow 7.1 0.1 1207 - < 0.5 0.5 - 0.8 - - 125 < 0.1 476 0.624 - CCR-12S Shallow 5.0 0.4 1144 3.475 4.7 16.5 300 3.7 3512 74 47 0.2 177 2.310 < 0.3 CCR-16S Shallow 4.4 0.9 2580 - 1.1 77.5 - 2.8 - - 76 0.2 174 1.493 - - CLMW-01 Shallow 4.7 0.8 1420 0.203 3.1 2.4 224 1.2 213 1 895 111 0.5 318 1.446 < 0.0005 < 0.3 CLMW-06 Shallow 5.0 < 0.1 < 50 0.123 < 0.5 11.5 144 1.1 165 17 < 1 < 0.1 34 - - < 0.3 GWA-20S Shallow 6.4 0.2 283 0.104 0.6 13.3 968 < 0.5 6013 149 92 < 0.1 349 0.487 < 0.0005 < 0.3 GWA-26S Shallow 4.8 0.1 < 50 0.032 0.6 0.8 243 1.1 22 < 5 < 1 < 0.1 < 25 - - < 0.3 GWA-28S Shallow 4.8 0.2 < 50 0.109 1.1 2.3 244 1.8 35 5 2 0.1 30 0.3 GWA-42S Shallow 5.3 < 0.1 29 0.120 < 0.5 0.7 41 - 14 87 49 < 0.1 81 - < 0.3 GWA-43S Shallow 5.1 0.1 79 0.464 0.9 1 1.3 174 0.9 21 167 44 < 0.1 92 - - < 0.3 GWA-57S Shallow 5.5 0.1 < 50 < 0.025 < 0.5 14.5 246 2.9 1855 132 99 < 0.1 207 0.518 0.0004 0.3 GWA-58S Shallow 5.6 0.1 < 50 1.700 1.4 4.2 40 2.2 1890 175 245 0.1 510 < 1.14 < 0.0005 0.3 GWA-63S Shallow 5.8 < 0.1 < 50 0.290 31.6 2.8 188 2.4 485 13 1 0.1 32 < 0.855 < 0.0005 < 0.3 MW-08S Shallow 7.0 0.3 206 0.025 1.0 3.6 1123 < 0.5 2910 134 57 < 0.1 310 0.976 0.0002 0.4 MW-los Shallow 5.1 0.5 216 0.552 1.0 1.6 334 1 2.1 197 56 60 0.1 189 0.652 - 0.3 MW-11S Shallow 5.3 0.2 766 1.617 6.0 1.2 235 2.1 1754 47 40 < 0.1 230 0.672 < 0.0005 < 0.3 CCR-04D Deep 5.4 0.1 56 - 0.5 0.8 - 1.0 - - 22 0.1 84 0.753 - - CCR-05D Deep 5.2 0.2 55 < 0.5 10.7 1.7 12 0.1 88 0.570 CCR-06D Deep 5.0 1.4 1464 - 2.6 5.9 - 4.0 - - 196 0.4 361 1.077 - CCR-07D Deep 5.6 < 0.1 616 0.139 < 0.5 < 0.1 < 50 1.1 99 155 35 0.3 146 1.247 - < 0.3 CCR-08D Deep 5.2 7.2 1991 0.051 < 0.5 294 < 50 1 4.4 8995 1350 328 1.5 673 1.355 < 0.0005 < 0.3 CCR-09D Deep 4.7 2.1 838 - 0.7 83.0 - 2.1 - - 321 0.1 461 0.716 - - CCR-11D Deep 6.8 1 0.1 1210 - < 0.5 2.1 - < 0.5 - - 94 0.2 379 0.837 - CCR-12D Deep 6.2 0.2 373 0.028 1.2 9.4 13800 6.6 1037 76 25 < 0.1 173 1.540 < 0.3 CCR-13D Deep 5.0 < 0.1 54 0.028 < 0.5 1.5 82 2.0 35 14 3 < 0.1 41 < 0.646 < 0.3 CCR-14D Deep 4.7 0.3 1095 - < 0.5 1.6 - 3.5 - - 65 0.2 259 1.260 - CCR-15D Deep 4.8 < 0.1 117 < 0.025 1.0 3.6 < 50 0.9 102 10 < 1 < 0.1 39 < 0.626 < 0.3 CCR-16D Deep 6.2 0.1 30 - < 0.5 0.2 - 4.4 - - 3 < 0.1 68 0.716 - - GWA-20D Deep 5.7 0.2 921 0.041 < 0.5 100 1664 2.0 6015 549 178 0.7 433 1.551 < 0.0005 < 0.3 GWA-27DA Deep 5.1 0.2 980 0.127 0.7 0.8 97 1.5 1296 107 65 0.2 261 0.510 < 0.0005 < 0.3 GWA-28BRU Deep 6.3 0.3 < 50 0.029 0.5 5.5 7330 9.6 53 50 11 < 0.1 98 - - < 0.3 GWA-43D Deep 6.3 0.1 < 50 0.128 0.7 0.3 < 50 21.5 < 5 165 81 < 0.1 253 1 - 0.7 GWA-51D Deep 5.1 1.2 796 0.526 1.9 71.3 141 3.4 8184 237 229 0.3 486 1 5.815 < 0.0005 1 0.3 Rev. 1 Page 2 of 4 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 ACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. Irg/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 4 11 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone)Z 4.0 - 6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone)Z 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone)Z 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4- 7.4 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone) Z 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone )2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 1 <50 - 11000 1.1 - 7.3 1 5 - 134 16.6 - 116 1 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID I Flow Zone Mean, Geomean, or Median Result3 Downgradient of the Ash Basin (Continued) GWA-57BRU Deep 6.9 1.3 78 < 0.025 < 0.5 3.3 1330 15.1 286 293 167 < 0.1 492 15.405 0.0083 0.9 GWA-58BRU Deep 5.9 0.3 < 50 < 0.025 < 0.5 11.7 3140 5.0 720 274 260 0.1 507 1.769 0.0006 < 0.3 GWA-59D Deep 5.5 0.7 597 0.166 1.2 118 1210 7.4 9850 200 187 0.3 379 1.933 0.0001 0.4 GWA-63BRU Deep 6.6 0.4 115 < 0.025 1.6 2.3 643 10.3 390 91 8 < 0.1 153 0.558 0.0002 0.3 MW-08D Deep 6.0 < 0.1 130 0.034 < 0.5 4.8 35460 6.7 5356 106 52 < 0.1 212 4.600 < 0.0005 < 0.3 MW-10D Deep 5.1 < 0.1 153 0.120 0.9 2.0 193 1 2.6 92 51 16 0.1 69 0.858 - 0.3 MW-11DA Deep 6.9 0.5 79 0.048 2.2 51.0 5012 9.4 252 145 38 < 0.1 327 2.833 0.3 CCR-03BR Bedrock 6.1 0.5 12 - 3.7 0.8 - 2.9 - - 7 < 0.1 110 1.124 - - CCR-08BR Bedrock 5.4 0.2 901 < 0.025 1.2 4.7 541 1.4 2265 306 65 0.4 243 1.332 < 0.0005 < 0.3 CCR-12BR Bedrock 6.3 0.3 38 < 0.025 1.7 0.6 1001 6.4 278 115 17 < 0.1 179 0.725 < 0.0005 < 0.3 GWA-20BR Bedrock 8.3 0.7 258 0.027 < 0.5 0.3 8625 27.7 489 524 82 < 0.1 283 3.673 0.0002 < 0.3 GWA-27BR Bedrock 6.5 0.3 258 0.029 1.4 0.1 997 19.0 29 206 5 < 0.1 1 198 1.255 0.0019 < 0.3 GWA-28BR Bedrock 6.6 0.1 < 50 0.031 0.4 0.4 5662 5.3 83 80 7 < 0.1 119 - - < 0.3 GWA-57BR Bedrock 7.2 0.1 231 < 0.025 2.6 0.6 305 3.2 965 199 64 < 0.1 324 5.715 0.0009 0.6 GWA-58BR Bedrock 6.7 < 0.1 366 < 0.025 0.6 0.3 19350 11.0 1034 241 124 < 0.1 342 10.370 0.0004 < 0.3 GWA-59BR Bedrock 5.8 0.2 593 < 0.025 0.7 2.1 4760 15.9 922 304 144 < 0.1 366 3.221 0.0001 < 0.3 GWA-64BRL Bedrock 7.8 0.6 236 < 0.025 < 0.5 0.1 5675 43.5 576 436 21 < 0.1 348 3.220 0.0011 < 0.3 GWA-65BR Bedrock 10.9 - 381 - - - - - - - GWA-65BRL Bedrock 12.8 - 83 - - - - - - - GWA-66BRL Bedrock 7.5 0.1 403 < 0.025 < 0.5 0.2 1480 28.8 299 395 17 < 0.1 292 7.135 0.0001 < 0.3 MW-11BRL Bedrock 10.8 - 38 - - - - - - - - - - - - - MW-11BR0 Bedrock 6.6 < 0.1 108 < 0.025 0.9 0.3 11700 6.5 1497 129 8 < 0.1 279 4.270 - 0.3 Near or Beyond Compliance Boundary Downgradient of the Ash Basin AS-07S Ash Pore Water 7.2 83.7 1447 < 0.025 1.6 3.5 14176 85.9 12196 2828 497 1.3 1078 0.650 0.0051 1.8 AS-08S Ash Pore Water 6.7 58.2 147 0.067 0.7 2.4 4414 6.4 2923 1318 28 0.2 247 - - 0.5 AS-01SB Shallow 4.3 6.1 1596 0.158 1.4 14.5 222 8.3 913 113 273 0.6 537 - 0.0011 < 0.3 AS-02S Shallow 4.5 5.6 1003 0.609 1.6 16.8 < 50 2.4 9650 202 315 0.4 594 0.823 < 0.0005 < 0.3 AS-04S Shallow 5.9 0.3 < 50 0.255 14.8 2.0 336 3.4 107 45 3 0.1 76 - - 0.5 AS-05S Shallow 5.3 0.3 < 50 0.057 1.0 0.2 215 2.9 19 7 1 < 1 < 0.1 28 - < 0.0005 < 0.3 AS-06S Shallow 5.4 < 0.1 < 50 0.150 2.5 0.3 219 1.7 100 12 < 1 < 0.1 33 0.474 - < 0.3 AS-07I Shallow 5.5 3.9 645 0.029 < 0.5 15.5 3913 4.9 6477 177 209 0.7 447 < 1.27 0.0002 < 0.3 CLMW-02 Shallow 4.1 1.1 538 0.105 0.8 18.5 88 5.6 1530 92 226 0.4 451 - - < 0.3 CLMW-03S Shallow 4.2 3.9 911 0.091 0.7 37.1 127 9.3 3425 36 253 0.3 498 < 0.833 < 0.0005 0.4 CLP-01 Shallow 5.2 0.3 1 204 0.110 0.6 2.2 1 326 - 101 36 14 1 0.2 58 - - 0.5 CLP-02 Shallow 5.7 0.1 47 < 0.025 5.9 2.5 368 123 27 18 < 0.1 70 - - 0.3 GWA-21S Shallow 9.4 10.4 158 0.453 1.5 0.6 72 3.0 23 204 96 0.3 259 0.507 0.0006 6.2 GWA-22S Shallow 5.5 0.1 264 0.032 1.3 1.6 468 1.2 43 67 3 < 0.1 103 0.797 < 0.0005 1.1 GWA-33S Shallow 4.9 0.2 < 50 0.030 1.1 14.6 6566 6.2 546 142 97 < 0.1 179 - 0.0000 0.4 GWA-54S Shallow 4.9 < 0.1 75 0.044 1.0 6.9 137 2.8 219 21 < 1 0.2 58 1.219 < 0.0005 < 0.3 MW-23S Shallow 4.9 0.1 < 50 2.360 3.0 1.1 150 2.2 64 120 121 0.1 219 - - < 0.3 AS-01D Deep 5.5 0.1 672 0.444 2.1 0.4 157 2.5 291 186 56 0.3 167 - < 0.0005 0.3 AS-02D Deep 7.3 1.3 343 0.072 1.5 0.5 286 28.5 471 533 217 < 0.1 463 1.367 < 0.0005 0.7 AS-03BRU Deep 5.2 < 0.1 < 50 < 0.025 0.9 0.1 229 1.8 13 19 < 1 < 0.1 36 - - < 0.3 AS-04D Deep 5.4 0.1 < 50 0.333 1.3 0.7 107 6.2 39 29 1 < 0.1 62 0.710 - 0.4 AS-05BRU Deep 5.8 0.2 < 50 0.068 1.8 0.2 271 0.8 12 22 < 1 < 0.1 41 - < 0.0005 0.3 AS-06D Deep 5.6 < 0.1 < 50 1 0.068 1 0.9 1 0.2 126 0.9 11 29 < 1 < 0.1 s0 0.747 < 0.3 Rev. 1 Page 3 of 4 23 April 2020 TABLE 6-5 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 ACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. lrg/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 4 11 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone)Z 4.0 - 6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone)2 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone)Z 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4 - 7.4 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone) Z 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone )2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 <50 - 11000 1.1 - 7.3 5 - 134 16.6 - 116 1 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID I Flow Zone Mean, Geomean, or Median Result3 Downgradient of the Ash Basin (Continued) AS-07D Deep 5.5 0.2 836 0.266 1.5 0.3 122 7.7 1950 259 129 0.1 305 - - < 0.3 AS-08D Deep 6.1 0.5 798 < 0.025 2.0 8.2 4310 3.8 4968 280 185 < 0.1 429 - - < 0.3 AS-09D Deep 5.9 0.4 138 0.107 4.2 30.8 265 1.6 470 34 4 0.1 73 < 0.866 < 0.0002 0.5 CLMW-03D Deep 5.2 0.2 912 0.135 1.1 0.2 283 4.2 43 295 280 < 0.1 529 1.351 < 0.0005 0.3 GWA-21BRU Deep 6.5 < 0.1 156 < 0.025 < 0.5 1.0 516 1.9 168 174 23 0.1 200 1.184 < 0.0005 < 0.3 GWA-22BRU Deep 8.0 0.3 < 50 0.069 0.7 < 0.1 174 1 11.7 11 128 4 < 0.1 146 0.536 - 0.8 GWA-33D Deep 6.1 0.2 < 50 0.044 0.4 0.4 709 24.2 89 169 106 < 0.1 278 - 0.4 GWA-47D Deep 5.3 0.1 333 0.064 0.9 1.1 161 2.8 140 70 < 1 0.1 88 1.063 - 0.6 GWA-54D Deep 7.3 0.5 74 0.047 1.0 0.1 851 4.9 210 230 48 < 0.1 292 0.552 < 0.0005 < 0.3 GWA-62BRU Deep 6.5 0.6 72 0.361 2.1 3.8 959 36.0 573 160 146 < 0.1 353 < 1.4 0.0003 0.7 MW-20D Deep 6.5 0.2 442 < 0.025 1.5 1.1 3723 2.8 282 148 15 < 0.1 189 < 1.53 - 0.4 MW-23D Deep 6.9 0.8 < 50 0.026 0.8 0.7 1028 19.6 632 323 335 < 0.1 649 - - < 0.3 AS-02BR Bedrock 8.0 2.0 418 0.050 1.3 0.1 176 12.4 363 222 97 < 0.1 289 0.0016 < 0.3 AS-05BR Bedrock 6.9 0.7 < 50 0.928 1.8 < 0.1 99 6.1 9 47 7 < 0.1 79 - 0.0001 1.6 AS-06BRA Bedrock 6.6 0.3 < 50 0.044 0.8 0.1 84 2.8 26 60 4 < 0.1 96 0.955 - 0.8 AS-07BRB Bedrock 7.6 1.6 72 0.127 2.4 0.3 148 3.8 24 78 40 < 0.1 166 0.601 0.0040 0.8 AS-07BRL Bedrock 12.0 - < 50 - - - - - - - - - - - - - AS-08BR Bedrock 7.3 0.6 43 0.310 1.7 0.2 63 1.3 44 133 71 < 0.1 268 0.760 0.0044 1.0 AS-09BR Bedrock 8.1 6.5 < 50 0.057 1.8 0.2 202 4.8 40 49 7 < 0.1 124 < 0.464 0.0035 0.7 GWA-21BR Bedrock 7.2 < 0.1 133 < 0.025 < 0.5 0.4 3630 7.0 410 271 < 1 < 0.1 237 6.116 < 0.0005 < 0.3 GWA-21BRL Bedrock 7.2 0.4 213 < 0.025 < 0.5 0.2 3520 9.8 662 267 2 < 0.1 268 3.440 < 0.0002 0.3 GWA-33BR Bedrock 8.2 < 0.1 160 < 0.025 < 0.5 < 0.1 1304 31.1 334 204 79 < 0.1 282 - - < 0.3 GWA-54BRO Bedrock 6.6 0.9 92 0.042 4.1 0.2 965 13.9 54 165 109 < 0.1 310 0.878 0.0021 < 0.3 GWA-62BR Bedrock 9.2 - 307 - - - - - - - - - - - - - MW-02DA Bedrock 6.6 0.8 < 50 0.066 1.4 1.6 1609 21.7 801 140 21 < 0.1 143 - < 0.3 MW-20DR Bedrock 7.1 < 0.1 175 < 0.025 < 0.5 < 0.1 301 8.3 577 344 < 1 < 0.1 283 1.247 < 0.3 MW-23DR Bedrock 7.1 0.3 < 50 < 0.025 < 0.5 < 0.1 992 7.3 53 106 25 < 0.1 152 - < 0.3 MW-25DR Bedrock 6.4 1 0.6 < 50 0.196 0.6 1.0 53 2.1 10 51 2 < 0.1 70 0.3 Notes: ' - Background threshold values were calculated using data from background groundwater samples collected June 2015 to September 2017. z - Background threshold values were calculated using data from background groundwater samples collected March 2011 to December 2018. 3 - Statistical mean, geomean, or median calculated from data ranging from January 2018 to June 2019. Ash pore water results are not compared to groundwater standards or criteria. Mean or geomean results were used based on the central tendency of the data set. For wells with datasets containing fewer than four valid results, the most recent valid sample data was used. Means were calculated for wells with four or more valid sample results. Sample results were excluded from calculations: 1) if turbidity >10 NTU (for COIs other than boron) 2) for unusable data (RO qualified) 3) if a result was non -detect at a reporting limit (RL) greater than the normal laboratory RL Bold text - Constituent concentration exceeds applicable comparison criteria. 0 - bold highlighted concentration indicates value is greater than the 15A NCAC 02L .0202 Standard or the IMAC. (Effective date for 15A NCAC 02L .0202 Standard and IMAC is April 1, 2013) - bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard 0 - highlighted concentration indicates value is either within range of background threshold values for constituents where there is no regulatory standard/background threshold values are greater than regulatory standard, or within range of background threshold value and the regulatory standard * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. < - concentration not detected at or above the adjusted reportinq limit. - - value not available NE - not established mq/L - milligrams per liter pCi/L - picocuries per liter uq/L - micrograms per liter S.U. standard unit Prepared by: TJG Checked by: TAW Rev. 1 23 April 2020 Page 4 of 4 TABLE 6-6 COI MANAGEMENT MATRIX ACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC tlotm: - aefereaa Cn-m - e�meaa:pppara map:m - e�meaa spppara e.clpsioa - pis,-lin renecta-001 usud-1-m-308 CSA Update, — the addld-ofIft- - Background threshold values were calculated using data — background groundwater samples colleced June 2015 to April 2017 - Updated background threshold values are In the thlyd column and were calculated using data from background groundwater samples collected ORober 2010 to December 2018 and sumbmitted to NCDEQ June 2019 - A-. c mean was used for COI with concentration range less than or equal to one order of mag—de. Geometric mean was used for C01 with conce—d- range greater than one oMer of magnitude. ' - The exceedance ratio Is the ratio of the mean constituent concentration divided by the comparative criterion. - Assignment of conservative, non-conservatve, Dr variable behavior Is based on geochemical modeling results. C01 a constituent of interest CSA - Comprehensive SiW Assessment iMAC -interim maximum allowable concentration pyL-mac a e e ker mg/L- ga spe kter - N. Applicable Prepared by: = Checked by: S Rev. 1 23 April 2020 TABLE 6-9 WATER SUPPLY WELL ANALYTICAL RESULTS SUMMARY CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Turbidity Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Impacted by coal ash? Alternative Water Supplied? Water Type Reporting Units S.U. NTUs pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L pg/L mg/L pCi/L pg/mL pg/L 15A NCAC 02L Standard 6.5 - 8.5 NE 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Values (Bedrock Flow Zone)' 5.4-7.4 NE 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Values (Bedrock Flow Zone)z 4.5 - 7.5 NE 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 Cliffside Background Dataset Range (Bedrock Flow Zone)z 4.8-7.6 NE <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 <50 - 11000 1.1 - 7.3 5 - 134 16.6 - 116 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Piedmont Background Value Range (Bedrock Flow Zone) 4.5-9.0 NE 1.0 - 6.0 49.1 - 50 0.03 - 8 2.8 - 11 0.2 - 18 147 - 7680 NE 7 - 1773 93 - 2272 2 - 130 0.1 - 0.2 120 - 675 1.0 - 6.0 0.0005 - 0.006 0.38 - 26 Sample ID Sample Date Analytical Results Cl Well 2 02/04/2015 7.5 <1 2.6 <25 <20 <5 <5 540 NA 7.6 26 13 NA 42 NA NA <5 No Yes -municipal water supply connection Calcium Bicarbonate Cl Well 2 05/27/2015 6.2 1.4 <0.5 <5 <0.6 3.2 <0.5 218 NA 13.1 50.1 9 NA 53 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate Cl Well 3 02/04/2015 6.7 <1 <1 <25 <20 <5 <5 210 NA 11 48 8.5 NA 60 NA NA <5 No Yes -municipal water supply connection Calcium Bicarbonate C10 02/04/2015 8.0 <1 1.6 <25 <20 <5 <5 650 NA 42 39 8.1 NA 54 NA NA <5 No Yes -municipal water supply connection Calcium Bicarbonate C10 05/27/2015 7.0 2.2 1.3 <5 <0.6 2.3 <0.5 <50 NA 49.6 38.2 7.6 NA 79 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C-1001: C2801 Riverfront 05/07/2014 NM NM <2 <50 NA <10 NA 78 NA NA 33 2 NA NA NA NA NA No Yes -municipal water supply connection Calcium Bicarbonate C-1001: C2801 Riverfront 10/18/2016 6.4 2.2 0.44 <25 <0.03 <0.5 0.18 289 NA 47.3 36.3 5.9 NA 62 NA NA <0.3 No Yes -municipal water supply connection ND C-1002: 2901 Fox Place 10/18/2016 6.2 6.4 0.19 <25 <0.03 <0.5 0.46 2970 NA 27.6 30.1 15.3 NA 63 NA NA <0.3 No Yes -municipal water supply connection ND C-1003 10/18/2016 7.6 <1 0.98 <25 <0.03 <0.5 <0.1 <50 NA 8.3 65.1 6.1 NA 108 NA NA <0.3 No Yes -municipal water supply connection Calcium Bicarbonate C-1004: C2800 Riverfront 05/07/2014 NM NM <2 <50 NA <10 NA <50 NA NA 20 NA NA NA NA NA NA No Yes -municipal water supply connection ND C-1004: C2800 Riverfront 10/18/2016 4.9 <1 <0.1 <25 0.63 1.2 <0.1 <50 NA 1.5 20.4 <2 NA 27 NA NA <0.3 No Yes -municipal water supply connection ND C-1005 S1 10/17/2016 6.8 1.1 0.3 <25 <0.03 <0.5 0.15 311 NA 23.5 41.1 2.9 NA 108 NA NA 0.64 No Yes -municipal water supply connection Calcium Bicarbonate C-1005 S2 10/17/2016 6.1 5.2 0.17 <25 0.32 0.79 <0.1 161 NA 5.4 20.5 <2 NA 36 NA NA 1.1 No Yes -municipal water supply connection Calcium Bicarbonate C-1005 S4 10/17/2016 7.0 10.8 0.73 <25 0.17 <0.5 0.41 1670 NA 110 26.4 2.4 NA 43 NA NA 0.32 No Yes -municipal water supply connection ND C-1005 S5 10/18/2016 6.9 4.1 <0.1 82 <0.15 <0.5 0.41 483 NA 56.9 26.4 <2 NA 34 NA NA 0.41 No Yes -municipal water supply connection Calcium Sulfate C-1005 W1 10/17/2016 5.3 <1 <0.1 <25 0.13 <0.5 <0.1 <50 NA 1.5 15.6 2.3 NA 31 NA NA <0.3 No Yes -municipal water supply connection Calcium Bicarbonate C-1005 W2 10/17/2016 6.1 <1 0.56 <25 <0.03 <0.5 0.41 392 NA 59.1 54 5.8 NA 65 NA NA 1.1 No Yes -municipal water supply connection Calcium Bicarbonate C-1005 W3 10/17/2016 7.0 <1 <0.1 <25 <0.03 <0.5 <0.1 754 NA 34.9 54.5 5.9 NA 92 NA NA <0.3 No Yes -municipal water supply connection Calcium Bicarbonate C-1006: 2910 Fox Place 11/03/2016 7.3 <1 0.28 <25 0.026 <0.5 <0.1 81.6 NA 14.3 50.9 10.3 NA 104 NA NA <0.3 No Yes -municipal water supply connection Calcium Bicarbonate C-1007: 433 Dysart Place 11/03/2016 7.4 <1 0.23 <25 <0.12 <0.5 <0.1 455 NA 166 59.3 12.7 NA 98 NA NA <0.3 No Not eligible, outside 1/2 mile radius Calcium Bicarbonate C-1007: 433 Dysart Place 03/31/2017 7.4 1.2 0.25 <25 <0.025 0.88 <0.1 453 NA 173 61.5 12 <0.1 115 NA NA <0.3 No Not eligible, outside 1/2 mile radius Calcium Bicarbonate C-1008 11/03/2016 5.2 <1 <0.1 <25 <0.025 <0.5 0.65 <50 NA 12.3 18.4 <2 NA <25 NA NA <0.3 No Not eligible, outside 1/2 mile radius ND C105 Downriver 04/09/2014 5.4 1 <2 <50 NA <10 NA 320 NA NA NA 6.8 NA 99 NA NA NA No Yes -municipal water supply connection ND C11 05/01/2015 6.6 4.2 <0.5 <5 0.096 <0.5 <0.5 <50 NA 3 39.3 <2 NA <25 NA NA <1 No Yes -municipal water supply connection Calcium Sulfate C15 02/04/2015 8.0 2.3 1 <25 <20 <5 <5 2200 NA 230 140 11 NA 190 NA NA <5 No Yes -municipal water supply connection Calcium Bicarbonate C16 02/04/2015 6.6 4.9 <1 <25 <20 <5 <5 380 NA <5 30 2.6 NA 38 NA NA <5 No Yes -municipal water supply connection ND C17 02/04/2015 7.6 11 <25 3200 NA 630 81 1.2 NA 330 NA <5 No Yes -municipal water supply connection ND C19 02/04/2015 7.7 2.4 <1 <25 <20 <5 <5 240 NA <5 33 2.5 NA 25 NA NA <5 No Yes -municipal water supply connection ND C23 05/27/2015 6.9 1.1 <0.5 <5 0.83 1.5 <0.5 110 NA 3.1 15.7 <2 NA 44 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C24 05/27/2015 6.4 <1 <0.5 <5 <0.6 0.91 1.9 <50 NA 40.3 71.4 2.2 NA 106 NA NA <1 No Yes -municipal water supply connection ND C24 08/18/2015 6.3 1 <0.5 <50 0.44 <5 <0.5 <50 NA NA 60.8 2 NA 101 NA NA <1 No Yes -municipal water supply connection ND C24-1 05/27/2015 6.7 <1 1 <0.5 <5 0.63 0.88 <0.5 <50 1 NA 2.7 58.2 1 2.9 NA 90 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C25 05/27/2015 6.5 3.9 <0.5 <5 <0.6 14.1 <0.5 540 NA 3.6 28 5.6 NA 53 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C25 08/17/2015 6.4 1.2 <0.5 <50 0.11 <0.5 <0.5 <50 NA NA 28.2 4.8 NA 54 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C26 05/27/2015 6.1 <1 <0.5 5.6 <0.6 0.81 <0.5 188 NA 2.7 26 3.5 NA 41 NA NA <1 No Not eligible -outside 1/2 mile radius ND C26 08/17/2015 6.2 1.5 <0.5 <50 0.15 <0.5 <0.5 52.5 NA NA 27.1 3 NA 61 NA NA <1 No Not eligible -outside 1/2 mile radius ND C2968 Riverfront 04/09/2014 NM 5.6 NA <50 NA <10 NA 790 NA 33 NA 2 NA 101 NA NA NA No Yes -municipal water supply connection ND C3 02/04/2015 7.2 <1 <1 <25 <20 <5 <5 360 NA 20 51 4.8 NA 48 NA NA <5 No Yes -municipal water supply connection Calcium Bicarbonate C3 05/27/2015 6.5 <1 <0.5 5 <0.6 0.56 1.2 <50 NA 25.5 44 4.4 NA 36 NA NA <1 No Yes -municipal water supply connection Calcium Bicarbonate C4 Well 2 02/04/2015 7.0 1.2 <10 <25 <20 <50 <50 290 NA <50 <100 2.3 NA <10 NA NA <50 No Not eligible-business/church/school ND C4 Well 3 02/04/2015 7.0 210 27 <5 3200 NA 11 24 NA 160 NA 11 No Not eligible-business/church/school ND C5 05/01/2015 6.6 <1 <0.5 6.2 2.2 2.2 <0.5 <50 NA 1 20.2 2.3 NA 80 NA NA <1 No Yes -municipal water supply connection ND C7 05/01/2015 7.6 <1 1.3 <5 <0.03 <0.5 <0.5 <50 NA 7.9 60.6 6.5 NA 94 NA NA <1 No Yes -municipal water supply connection ND C8 05/01/2015 6.2 <1 <0.5 <5 0.74 0.86 0.72 57.3 NA 11 16 <2 NA 59 NA NA <1 No Yes -municipal water supply connection ND C8 Spring 05/01/2015 5.6 34.8 <0.5 6.5 <0.03 2.2 1.6 <50 NA 16.8 14.9 5.9 NA 45 NA NA 3 No Yes -municipal water supply connection ND C9A 05/01/2015 5.7 <1 <0.5 6.2 0.01 <0.5 <0.5 <50 NA 2.3 14.1 2.6 NA 32 NA NA <1 No Yes -municipal water supply connection IND C9B 05/01/2015 7.1 <1 <0.5 <5 <0.03 <0.5 <0.5 749 NA 32.4 48.9 6.2 NA 97 NA NA <1 No Yes -municipal water supply connection IND repared by: TJG Checked by: SAS NNotg, - Background threshold values were calculated using data from background groundwater samples collected June 2015 to September 2017. mg/L - milligrams per liter - Background threshold values were calculated using data from background groundwater samples collected March 2011 to December 2018. pCi/L - picocuries per liter Turbidity of Sample 2 10 NTUs pg/L - micrograms per liter Bold text - Constituent concentration exceeds applicable comparison criteria. S.U. standard unit * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. * - concentration not detected at or above the adjusted reporting limit. NA - not analyzed ND - water type of sample not determined due to charge balance >10 or ­10 NM - not measured NE - not established NTU - Nephelometric Turbidity Unit Rev. 1 23 April 2020 TABLE 6-20 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 FORMER UNITS 1-4 ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 4 it 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone)2 4.0 - 6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone)2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone)2 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 it 2019 Background Dataset Range (Deep Flow Zone)2 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4 - 7.4 1 50 0.1 4 1 6220 NE 1 89 1 107 1 15 1 0.2 120 1 3 1 0.0005 1 0.4 2019 Background Threshold Values (Bedrock Flow Zone)2 4.5 - 7.5 1 50 0.7 3 2 7680 1 it 113 1 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone)2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 <50 - 11000 1.1 - 7.3 5 - 134 1 16.6 - 116 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID Flow Zone Mean, Geomean, or Median Result3 Background Locations GWA-30S Shallow 5.7 0.1 < 50 0.041 1.3 5.0 264 1.1 269 24 < 1 0.2 43 - - < 0.3 MW-30S Shallow 5.3 0.1 < 50 3.12 3.0 0.4 159 1.2 8 10 < 1 < 0.1 33 0.490 < 0.0005 < 0.3 MW-32S Shallow 5.0 0.1 < 50 0.177 0.6 1.1 73 2.5 37 27 < 1 0.1 59 1.107 < 0.0005 < 0.3 MW-30D Deep 8.3 1.6 < 50 0.076 < 0.5 < 0.1 53 11.1 8 61 16 < 0.1 107 1.333 0.0003 10.0 MW-30DA Deep 6.7 0.2 < 50 < 0.025 0.6 0.8 241 10.2 219 65 10 < 0.1 116 0.536 < 0.0005 0.3 MW-32D Deep 5.9 0.1 < 50 0.034 < 0.5 1.8 < 50 2.8 it 40 7 < 0.1 73 0.533 < 0.0005 < 0.3 GWA-30BR Bedrock 6.3 0.2 < 50 < 0.025 0.7 < 0.1 7198 3.6 70 52 14 < 0.1 90 - - 0.2 MW-32BR Bedrock 7.0 0.1 < 50 < 0.025 0.8 < 0.1 5305 6.1 1 33 57 16 < 0.1 103 0.386 < 0.0005 < 0.3 Between Waste Boundary and Compliance Boundary Upgradient of the Ash Basin GWA-14S Shallow 6.0 0.2 63 1.300 2.1 0.4 392 - 19 95 85 0.1 217 - - 1.1 GWA-14D Deep 5.9 0.1 101 0.986 1.3 0.2 79 0.7 6 228 186 < 0.1 413 0.5 GWA-13BR Bedrock 6.5 1 0.2 84 < 0.025 1.0 < 0.1 5674 17.7 249 157 91 < 0.1 321 0.4 GWA-14BR Bedrock 8.5 1.3 < 50 0.162 1.4 0.2 227 17.9 52 123 54 < 0.1 184 - 1.4 Downgradient of the Ash Basin GWA-10S Shallow 5.2 0.6 1 97 1 0.043 1 < 0.5 1 5.9 1 182 1 5.0 1 1038 1 227 1 131 1 0.2 1 259 1 1.347 < 0.3 GWA-12S Shallow 5.6 0.1 1 < 50 1 0.042 1.0 0.2 117 0.6 1 6 1 18 1 13 < 0.1 86 - < 0.3 GWA-10D Deep 5.9 < 0.1 < 50 0.780 1.1 3.1 < 50 6.2 174 139 24 < 0.1 125 < 0.573 0.4 GWA-12BRU Deep 6.0 0.1 1 < 50 < 0.025 < 0.5 2.3 503 2.7 43 49 1 9 < 0.1 101 < 0.3 Near Compliance Boundary Downgradient of the Ash Basin CCR-IB-01S Shallow 5.8 0.2 151 0.028 0.6 2.8 858 < 0.5 1706 395 79 < 0.1 196 < 1.14 < 0.3 CCR-IB-03S Shallow 6.3 109 270 0.027 0.9 16.6 4740 15.7 2068 898 200 0.1 471 < 1.09 - < 0.3 GWA-11S Shallow 5.9 1.2 398 < 0.025 0.6 1.6 621 2.6 1970 554 105 < 0.1 299 0.456 < 0.0005 1.2 IB-06S Shallow 5.5 0.1 590 0.028 1.5 18.3 606 3.3 7333 369 258 0.1 457 1.620 < 0.0005 < 0.3 IB-07S Shallow 5.7 12.6 268 < 0.025 1.4 10.5 1613 10.0 1627 305 109 0.2 307 1.240 < 0.0005 0.5 CCR-IB-01D Deep 5.8 0.2 < 50 0.027 0.7 0.3 3328 3.8 110 60 14 0.1 97 < 0.711 - < 0.3 CCR-IB-03D Deep 9.6 0.8 65 2.543 2.5 < 0.1 < 50 28.1 < 5 229 86 < 0.1 321 - - 1.7 GWA-11BRU Deep 6.5 0.3 350 0.120 0.7 0.7 421 16.2 740 285 103 < 0.1 319 2.947 < 0.0005 0.6 GWA-29D Deep 5.7 < 0.1 < 50 0.167 0.9 0.3 150 1.6 9 35 8 < 0.1 66 1.368 < 0.0005 < 0.3 GWA-32D Deep 6.0 0.1 < 50 0.097 < 0.5 0.1 124 0.6 10 11 2 < 0.1 27 - 0.0002 < 0.3 IB-06D Deep 7.0 0.1 128 < 0.025 1.6 0.1 2090 12.2 289 209 51 < 0.1 253 4.930 0.0001 < 0.3 IB-07D Deep 6.7 0.7 < 50 0.028 2.0 1.3 350 5.7 196 126 30 < 0.1 221 - 0.0002 0.5 CCR-IB-03BR Bedrock 6.6 0.4 < 50 < 0.025 0.7 4.6 25750 21.6 9570 813 1395 < 0.1 2298 37.833 0.0002 0.4 GWA-11BR Bedrock 7.5 1.3 207 < 0.025 < 0.5 0.8 46 7.2 84 299 67 < 0.1 322 1.980 0.0016 0.9 GWA-11BRL Bedrock 8.3 < 50 - - - - - - - - GWA-29BRA Bedrock 7.7 1.8 < 50 0.067 0.7 0.2 153 0.4 29 213 11 < 0.1 146 1.2 Notes: ' - Backqround threshold values were calculated usinq data from backqround qroundwater samples collected June 2015 to September 2017. NE - not established 2 - Backqround threshold values were calculated usinq data from background qroundwater samples collected March 2011 to December 2018. mg/L - milligrams per liter 3 - Statistical mean, qeomean, or median calculated from data ranqinq from January 2018 to June 2019. Ash pore water results are not compared to qroundwater standards or criteria. pCi/L - picocuries per liter Mean or geomean results were used based on the central tendency of the data set. Ng/L - micrograms per liter For wells with datasets containing fewer than four valid results, the most recent valid sample data was used. S.U. standard unit Means were calculated for wells with four or more valid sample results. sample results were excluded from calculations: 1) if turbidity >10 NTU (for COIs other than boron) 2) for unusable data (RO qualified) 3) if a result was non -detect at a reporting limit (RL) greater than the normal laboratory RL Bold text - Constituent concentration exceeds applicable comparison criteria. - bold highlighted concentration indicates value is greater than the 15A NCAC 02L .0202 Standard or the IMAC. (Effective date for 15A NCAC 02L .0202 Standard and IMAC is April 1, 2013) 0 - bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard 0 - highlighted concentration indicates value is either within range of background threshold values for constituents where there is no regulatory standard/background threshold values are greater than regulatory standard, or within range of background threshold value and the regulatory standard * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. < - concentration not detected at or above the adjusted reporting limit. - - value not available Prepared by: TJG Checked by: TAW Rev. 1 23 April 2020 Page 1 of 1 DUKE TABLE 6-21 COX MANAGEMENT MATRIX FORMER UNITS 1-4 ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION ENERGY CAROLINAS, LLC, MOORESBORO, NC `J sip Lines of Evidence (LOE) - 02L Criterion Gnuumou, Clifivid, St- Numbo-f-11. Mean Constituents Regulator, Z... st.tis=ly Station k Fiethroont I CbN`sJ,`lr`,rtMaN-r E—d Above Criterion tim-ndissather Monitoring Wall, With COX Concentration 11-i-al Background V.I.."a once C Deltersal R11.0 Compliance Jones No., Co J Greauser Than Cturrinarati- Criteria (2018 C&A, update) Criterion ma Ratio' FlIv, Zone,) to.rdl Boundary Flos, .... 2� 11111" Constituent Standards and Values - 02L Criterion Rationale for Selection of COX, for Corrective Action Evaluation (for constituents where oregreater then compared- c,itlari. in all flow zones and/or multipleIt"$ of evidence support the, constituent occurrences are no, related to the source are,, no correcti- .,I.. I. warranted) Rationale - 02L Criterion CCJ lit -Is M.1thoo means �ra.tar than d21 standard ... --plance boundary and a,hiblits di—ab's plume (Figure 6-46) tar than .11 standard no., compliance boundary No m::n: ggre No m reater than 02L standard near compliance boundary mom .me nsgm,�rth,n02L�nd,M,h,�.�.rb,��g,,t,rth,nb,,kg��nd��l��i�m�pp,d,,,nindi,,t,rofpotenti,l,,hb,�inin,�ence (Fi or, 647.) No m::n::m �rth,n02L-nd�M,ho�.�,rb,,ng,,t,rth,nb,,kg,,nd�,l�.i�m�pp�d���nindic,torofpotnti�,��hb��inin,�ence Illobabal 6-4 J b"kg,,nd�,1,,i�m�pp�d���nindic,torofpot,nti,l��hb��ininl�ence Nor, b m,�rth,n02LMnd��,ho�.�.rb.�ngm,t,rth,n.0 Ili be 6-47:) Chromium ('ratill) No mean: greater than background valu near compliance boundary No bound: a n o:L -nd:d nc: comp b n m u h:n m n:� No mean ro 0 L-nd rd o ��:nc o nd rY Chursonwon (Holoca-lount) No meanogreadarthan backgboundvalue nearcompliance boundary No means inesterthen trock­nd nine muncomphence boundary �CCR-IB-1D �6D� One mean groate r than background alue near com pliance bound,r-,, Isolated occu-1c, (Figure 6-491) 113 Multiple means greater than background value near comoliance boundary and ,hlbits drscarnable plume (Flour, 6-49b) On, mean greater than background value near compliance boundary, Isolated occurrance (Figure 6-491) Multiple means greater than background value near compliance, boundary and a,hlJ discarnable plume (Figure 6-51,) Multhal, mean, greater than background value near compliance boundary and a,hlJ discarnable plume (Figure 6-51b) On, mean greater than background value near compliance boundary, isolated occurrance (Figure 6-511) One mean greater than 02L near compliance bounds,, Isolated occurre1c, (Figure :tandan! No mean greater than 02L standard near compliance boundary One mean greater th:n - ""dar-cl near- compliance bround,,,, isolated occun,ance (Figure 6-53b) Total libub-a-bilids �mm ��o �oaoo® N mean, greater than 02L standard near coml boundary No means greater than 02L standard near compliance boundary One mean greater than 02L standIr-cl n- compliance boundary, isolated occu-ce (Figure 6-54) illill 111111111111111 1111111111 1111111 Jill 11111 1 'Ili 11111 !J1111 1111 111 11111 Retionnis e - IMAC Criterion ®moo©®®��o �000© No mean, g-torthan background value near compliance boundary No mean, greaterthan background value near compliance boundary 0000® One mean gro,- than b,ckg,u,d �,lu, a,, compliance bmmdar-y, Isolated occuerce (Figure 6-48) ®��®®��o m: tor M C comp��:nc: b N :n :h:n AC n comp c und rY 000©® No means greaterthan 1- near compliance boundary moo ®moo 0000One mean grea- tharmackg,ou'd value near compliance bmmdar-,, Isolated occu-ma, (Figure 6-56,) No eans greater than background value near compliance boundary One mean grc.- than background �aluo a,, _Pliam,ab ... dar-y, Isolated occ-ance (Figure 6-56b) . r Constituent Standards and Values - Background Criterion Lines of Evidence (LOE) - Background Criterion Rationale - Background Criterion CCJ 113 6r, IJ �0000®One r gre n b: kgground a boundd:, n: n:bb�:Pp�um Fi or CCJ GWA--11J IJ :h Z'p :nd J u: bou d::h h�b m rog::� h:n :mp i Its mereater than background value near compliance boundary, Isolated occurrance (Figure 6-50b) Multiple Mean g ckgground v Fi:ur:::'::) comp " b:.rd:N:�d::h'btsd':::�r ur P�i:n �:Pp�um ck d r b d d hb' d :b :F or Multiple mo.r: ­: ro v: com i no , i its i m: 1 �:�h:r tb: �u: n::r M,Itipi,m,,n,g,,trth,nb kg,und�,1,,n,,r,ompli,n,,b,und,�,nd,.hibi�di,m�,bi,pl,m,(Fig,m6-52c) No mean, greater than background ,I,, near compliance boundary GWA-11J IJ -tal than b,,kqd value (Figure 6-55,) . • Non -Conservative No means greator than background value near compliance boundary 1­-1 1,: 111 1hockel 1,: �A� tbaJ C,1 lb-=oom-le'llb -dull- 1.11 .... ..... . . ... .... r-k­rrl -1- 11, 11,1 rIUMn - o-d-1, -,Irl .11-In 0,- -. 1. .1-11 aad,mem a1 NCDEQ bbry 2019 nagre- rr-1-- "I'll-en' sl. All.-rl P. .A Appi-lb sta=- lv Rev. 1 23 April 2020 TABLE 6-31 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 UNIT 5 INACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.1 1 50 0.5 1 4 11 684 NE 169 1 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone )2 4.0 - 6.0 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8 - 6.1 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone )2 4.9 - 7.2 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone )2 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4 - 7.4 1 50 0.1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone )2 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone 4.8 - 7.6 <0.1 - 1.2 <50 - 83 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 <50 - 11000 1.1 - 7.3 5 - 134 16.6 - 116 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID Flow Zone Mean, Geomean, or Median Result3 Background Locations GWA-30S Shallow 5.7 0.1 < 50 0.041 1.3 5.0 264 1.1 269 24 < 1 0.2 43 - - < 0.3 MW-30S Shallow 5.3 0.1 < 50 3.120 3.0 0.4 159 1.2 8 10 < 1 < 0.1 33 0.490 < 0.0005 < 0.3 MW-32S Shallow 5.0 0.1 < 50 0.177 0.6 1.1 73 2.5 37 27 < 1 0.1 59 1.206 < 0.0005 < 0.3 CCPMW-01S Deep 5.3 < 0.1 < 50 0.324 0.8 2.2 53 2.0 42 < 5 < 1 < 0.1 < 25 0.138 < 0.0005 0.3 MW-30D Deep 8.3 1.6 < 50 0.076 < 0.5 < 0.1 53 11.1 8 61 16 < 0.1 107 2.13 0.0003 10.0 MW-30DA Deep 6.7 0.2 < 50 < 0.025 0.6 0.8 241 10.2 219 65 10 < 0.1 116 0.420 < 0.0005 0.3 MW-32D Deep 5.9 0.1 < 50 0.034 < 0.5 1.8 < 50 2.8 11 40 7 < 0.1 73 0.526 < 0.0005 < 0.3 CCPMW-01D Bedrock 5.2 < 0.1 < 50 0.056 < 0.5 0.3 < 50 1.1 8 22 1 < 0.1 40 0.693 < 0.0005 < 0.3 GWA 30BR Bedrock 6.3 0.2 < 50 < 0.025 0.7 < 0.1 7198 3.6 70 52 14 < 0.1 90 0.2 MW-32BR Bedrock 7.0 0.1 < 50 < 0.025 0.8 < 0.1 5305 6.1 33 57 16 < 0.1 103 < 0.249 < 0.0005 < 0.3 Within the Waste Boundary Locations U5-02S-SLB Ash Pore Water 6.6 5175.0 267 < 0.025 0.6 11.9 67850 54.9 643 1865 145 1.3 429 0.145 0.0110 0.6 1-15-01S Shallow 6.2 4.2 < 50 < 0.025 0.7 7.5 54348 < 0.5 4504 138 5 < 0.1 217 - - 0.5 U5-04S Shallow 5.4 0.2 135 2.640 3.8 1.5 353 1.2 23 14 22 < 0.1 77 0.4 1-15-06S Shallow 4.2 0.6 158 < 0.025 21 107 4010 8.8 5480 374 167 0.5 301 1.0 U5-08S Shallow 6.5 12.0 < 50 < 0.025 < 0.5 1.1 6580 < 0.5 2980 150 27 < 0.1 211 < 0.3 U5-01D Deep 6.5 0.5 < 50 0.094 < 0.5 1.0 232 20.7 221 68 3 0.1 129 - - 1.6 U5-02D Deep 6.7 4170 125 0.034 0.6 3.1 36740 16.7 872 1440 86 < 0.1 338 1.5 < 0.0005 < 0.3 U5-04D Deep 7.3 1.4 < 50 0.105 1.7 0.3 456 9.6 28 113 65 < 0.1 183 - - 1.3 U5-05D Deep 6.3 1.4 331 0.035 3.1 19.2 11632 28.7 3222 186 194 < 0.1 422 3.3 0.0019 0.5 U5-06D Deep 5.7 1.0 162 0.029 1.1 28.0 14182 21.4 1442 408 163 0.1 319 - - 1.2 U5-08D Deep 10.1 0.1 < 50 1.068 1.3 0.2 < 50 1.6 8 39 2 < 0.1 72 - 0.7 U5-02BR Bedrock 6.0 164 120 < 0.025 1.2 25.1 6266 1.3 5910 396 22 0.3 195 0.0011 0.4 U5-04BRA Bedrock 10.6 2.0 < 50 0.580 0.5 0.3 113 9 57 18 < 0.1 108 - 1.4 1-15-05BR Bedrock 8.9 11.7 447 0.057 2.0 2.1 59 67.1 31 1342 555 < 0.1 1424 9.6 U5-08BR Bedrock 10.0 3.9 < 50 0.690 1.4 0.0 47 11.3 < 5 33 13 < 0.1 124 2.6 Between Waste Boundary and Compliance Boundary Sidegradient of the Ash Basin CCR-U5-10S Shallow 5.0 < 0.1 4 2.5 1.7 1.2 < 1 < 0.1 52 0.642 - GWA-05S Shallow 5.2 0.4 < 50 1.320 3.2 2.8 122 1.9 410 113 532 0.4 793 0.3 CCR-US-10D Deep 5.5 < 0.1 10 1.3 0.8 0.9 15 0.1 88 0.277 - GWA-05BRU Deep 7.3 0.4 < 50 0.073 0.6 1 < 0.1 172 8.4 195 207 53 < 0.1 433 0.4 Downgradient of the Ash Basin CCR-U5-03S Shallow 5.9 < 0.1 94 0.579 1.5 0.2 102 0.4 290 165 50 < 0.1 169 - 0.3 CCR-1-15-04S Shallow 5.4 1.2 563 1.200 1.9 83.7 683 5.2 1830 550 182 0.5 338 0.366 0.6 CCR-US-06S Shallow 4.0 0.3 139 - < 0.5 33.3 - 8.0 - - 150 0.6 289 1.4 - CCR-U5-08S Shallow 5.6 0.4 17 2.6 25.1 1.0 218 0.2 372 0.459 CCR-US-09S Shallow 5.2 < 0.1 324 - 0.6 5.2 - 1.4 - - 12 0.1 61 0.827 - GWA-02S Shallow 5.5 < 0.1 129 0.202 < 0.5 0.2 203 0.5 206 129 65 0.1 181 0.331 < 0.0005 < 0.3 GWA-04S Shallow 4.3 0.8 159 < 0.025 < 0.5 59.4 18260 5.8 2014 537 194 1.3 343 1.5 < 0.0005 < 0.3 GWA-36S Shallow 5.3 1.2 79 < 0.025 0.5 51.6 1851 7.5 1028 234 109 0.6 206 0.613 < 0.0005 < 0.3 CCR-US-01D Deep 5.9 < 0.1 7 - 0.7 1.4 - 1.1 - - 53 < 0.1 195 1.3 - - CCR-U5-02D Deep 5.3 0.1 80 - 4.3 0.7 - 0.9 - - 43 0.1 116 < 0.28 - CCR-US-03D Deep 5.8 0.1 127 0.153 0.6 2.8 297 0.4 2033 253 72 0.2 212 1.3 0.3 CCR-1-15-04D Deep 5.2 0.6 800 < 0.025 < 0.5 61.3 1605 6.8 3620 555 341 0.9 529 1.6 0.4 CCR-US-06DA Deep 4.6 0.1 173 - < 0.5 107 - 1.0 - - 219 0.2 401 0.521 - CCR-U5-08D Deep 4.6 1.1 189 - 1.8 179 17.8 - - 463 2.4 981 1.7 - - GWA-02BRU Deep 6.2 0.2 127 < 0.025 < 0.5 0.5 431 10.7 115 158 69 < 0.1 269 1.2 0.0005 < 0.3 GWA-03D Deep 5.7 0.2 400 0.362 2.0 3.3 174 4.7 1464 233 184 0.1 362 1.6 < 0.0005 0.6 GWA 04D Deep 5.4 0.4 165 < 0.025 < 0.5 93.9 16200 7.4 4320 449 232 < 0.1 433 4.3 0.0007 < 0.3 GWA-31D Deep 6.7 0.4 46 0.214 0.7 0.3 91 4.4 6 461 381 < 0.1 874 7.5 - 0.4 GWA-36D Deep 5.6 0.4 165 < 0.025 0.5 37.4 1368 5.6 4436 323 308 < 0.1 572 0.707 < 0.0005 0.4 CCR-U5-04BR Bedrock 6.8 0.5 1 414 1 < 0.025 0.9 1 0.1 7120 1 9.0 1 598 281 258 < 0.1 577 2.7 0.0003 0.4 Rev. 1 Page 1 of 2 23 April 2020 TABLE 6-31 MEANS OF GROUNDWATER COIs - JANUARY 2018 TO JUNE 2019 UNIT 5 INACTIVE ASH BASIN CORRECTIVE ACTIVE PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Analytical Parameter pH Arsenic Boron Chromium (VI) Chromium Cobalt Iron Lithium Manganese Strontium Sulfate Thallium Total Dissolved Solids Total Radium Total Uranium Vanadium Reporting Units S.U. Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L mg/L Ng/L mg/L pCi/L Ng/mL Ng/L 15A NCAC 02L Standard 6.5 - 8.5 10 700 10 10 1* 300 NE 50 NE 250 0.2* 500 NE NE 0.3* 2017 Background Threshold Values (Shallow Flow Zone)' 4.4 - 6.11 1 50 0.5 4 1 11 684 NE 169 37 1 0.1 75 3 0.0005 1 2019 Background Threshold Values (Shallow Flow Zone )2 4.0 - 6.01 0.2 50 4 26 21 1700 3 969 34 4 0.2 57 2 0.0005 1 2019 Background Dataset Range (Shallow Flow Zone )2 3.3 - 6.1 <0.1 - 0.73 <50 <0.025 - 4.8 <0.5 - 26.2 0.16 - 22.9 <50 - 5750 <0.5 - 4.6 6.7 - 1000 6.8 - 103 <1 - 5.5 1 <0.1 - 0.3 <25 - 10700 0.0976 - 1.961 <0.0002 - <0.0005 <0.3 - 1.9 2017 Background Threshold Values (Deep Flow Zone)' 4.8- 6.11 1 50 0.2 2 5 515 NE 78 56 10 0.1 71 2 0.0005 1 2019 Background Threshold Values (Deep Flow Zone )2 4.9 - 7.21 2 50 0.6 2 5 1840 12 260 69 15 0.2 107 2 0.0005 11 2019 Background Dataset Range (Deep Flow Zone )2 3.8 - 7.3 <0.1 - 2 <50 - 150 <0.025 - 1.2 <0.5 - 9.9 <0.1 - 6.1 <50 - 3200 1.5 - 13.4 5.2 - 408 6.3 - 70.5 <1 - 18.5 <0.1 - <0.2 <25 - 407 0.017 - 2.323 <0.0005 <0.3 - 12.2 2017 Background Threshold Values (Bedrock Flow Zone)' 5.4- 7.41 1 50 1 0.1 1 4 1 6220 NE 89 107 15 0.2 120 3 0.0005 0.4 2019 Background Threshold Values (Bedrock Flow Zone)2 4.5 - 7.5 1 50 0.7 3 2 7680 11 113 93 17 0.2 120 3 0.0005 1 2019 Background Dataset Range (Bedrock Flow Zone)2 4.8 - 7.6 <0.1 - 1.2 <50 - 83 1 <0.025 - 0.8 <0.5 - 10.5 <0.1 - 2.6 <50 - 11000 1.1 - 7.3 5 - 134 16.6 - 116 <1 - 17.6 <0.1 - 0.5 <25 - 330 0 - 3.46 <0.0005 <0.3 - 1.5 Sample ID Flow Zone Mean, Geomean, or Median Result3 CCR-US-05D Bedrock 6.9 1.1 384 - 0.7 5.4 - 4.5 - - 151 < 0.1 452 < 0.599 - - GWA-02BRA Bedrock 8.2 0.6 85 < 0.025 1.0 0.1 852 5.4 125 117 48 < 0.1 209 1.7 0.0004 0.7 GWA-31BRA Bedrock 7.8 1.7 < 50 0.031 1.0 < 0.1 278 35.3 55 52 112 < 0.1 302 < 0.518 - 0.5 GWA-67BR Bedrock 11.8 - < 50 - - - - - - - - - - - - - GWA-67BRL Bedrock 7.4 0.2 133 < 0.025 < 0.5 0.1 1825 8.8 197 174 76 < 0.1 241 3.7 0.0004 0.4 GWA-68BRL Bedrock 7.7 0.3 68 0.060 < 0.5 0.1 276 9.0 116 306 95 < 0.1 302 1.5 0.0019 0.6 Near or Beyond Compliance Boundary Upgradient of the Ash Basin MW-42S Shallow 5.6 0.2 < 50 2.6 0.3 178 0.5 11 45 7 < 0.1 67 < 0.0005 < 0.3 GWA-45D Deep 8.2 0.9 < 50 < 0.025 1 1.2 0.1 118 - 24 136 27 < 0.1 201 2.6 MW-42DA Deep 7.2 0.7 < 50 0.079 0.8 0.3 152 36.5 43 112 105 < 0.1 302 0.0019 1.0 Downgradient of the Ash Basin GWA-34S Shallow 5.9 0.1 < 50 0.047 < 0.5 0.3 385 0.7 65 19 2 < 0.1 53 < 0.0005 < 0.3 GWA-35S Shallow 5.8 0.7 110 < 0.025 < 0.5 16.9 16040 < 0.5 1692 50 41 0.1 131 - < 0.3 GWA-37S Shallow 5.8 0.9 80 < 0.025 1.3 92.7 15860 0.6 7866 74 71 0.1 182 - 0.3 GWA-56S Shallow 6.1 0.2 < 50 0.383 1.8 2.1 820 1.3 146 66 138 < 0.1 314 0.435 < 0.0005 0.4 MW-34S Shallow 5.2 < 0.1 < 50 0.063 < 0.5 1.2 130 1.2 25 5 < 1 < 0.1 < 25 - < 0.0005 < 0.3 MW-36S Shallow 5.7 0.1 57 0.200 0.6 < 0.1 261 0.4 15 41 10 < 0.1 57 - - 0.4 MW-38S Shallow 5.3 0.1 126 0.540 1.5 3.7 377 1.1 366 81 153 < 0.1 276 0.655 < 0.0005 0.3 MW-40S Shallow 5.5 < 0.1 < 50 0.694 1.2 0.6 356 0.6 28 158 113 < 0.1 247 - - 0.6 GWA-01BRU Deep 7.1 0.1 < 50 0.067 0.6 0.2 795 3.0 59 45 8 < 0.1 95 - < 0.3 GWA-32D Deep 6.0 0.1 < 50 0.097 < 0.5 0.1 124 0.6 10 11 2 < 0.1 27 0.0002 < 0.3 GWA-35D Deep 6.4 0.1 128 < 0.025 < 0.5 0.5 4578 10.5 119 112 63 < 0.1 189 - < 0.3 GWA-37D Deep 5.3 0.2 62 0.685 11.1 1.3 925 11.6 48 587 289 < 0.1 541 - - GWA-56D Deep 6.5 0.2 < 50 < 0.025 1.4 0.6 1547 16.5 290 169 114 < 0.1 312 3.0 < 0.0005 0.3 MW-34BRU Deep 7.4 0.1 < 50 0.028 < 0.5 < 0.1 783 1.3 40 64 12 < 0.1 118 - - < 0.3 MW-36BRU Deep 6.9 < 0.1 < 50 0.026 < 0.5 < 0.1 216 2.9 67 71 7 < 0.1 121 - - < 0.3 MW-38D Deep 5.8 0.2 233 0.109 1.1 2.6 196 7.8 398 211 232 < 0.1 424 1.2 < 0.0005 0.5 MW-40BRU Dee 7.7 0.5 < 50 0.082 < 0.5 < 0.1 159 2.9 196 201 98 < 0.1 298 4.6 - 0.5 GWA-34BR Bedrock 1 8.0 0.1 < 50 < 0.025 < 0.5 0.1 1057 1.5 80 66 28 < 0.1 163 - < 0.0005 < 0.3 MW 38BR Bedrock 16.6 0.8 52 < 0.025 1.0 0.9 2358 16.1 252 378 254 < 0.1 509 3.3 < 0.0005 < 0.3 Notes: Background threshold values were calculated using data from background groundwater samples collected June 2015 to September 2017. Z - Background threshold values were calculated using data from background groundwater samples collected March 2011 to December 2018. 3 - Statistical mean, geomean, or median calculated from data ranging from January 2018 to June 2019. Ash pore water results are not compared to groundwater standards or criteria. Mean or geomean results were used based on the central tendency of the data set. For wells with datasets containing fewer than four valid results, the most recent valid sample data was used. Means were calculated for wells with four or more valid sample results. Sample results were excluded from calculations: 1) if turbidity >10 NTU (for COIs other than boron) 2) for unusable data (RO qualified) 3) if a result was non -detect at a reporting limit (RL) greater than the normal laboratory RL Bold text - Constituent concentration exceeds applicable comparison criteria. 0 - bold highlighted concentration indicates value is greater than the 15A NCAC 02L .0202 Standard or the IMAC. (Effective date for 15A NCAC 02L .0202 Standard and IMAC is April 1, 2013) O - bold highlighted concentration indicates value is greater than greatest background threshold value where there is no regulatory standard, or background threshold values are greater than regulatory standard O - highlighted concentration indicates value is either within range of background threshold values for constituents where there is no regulatory standard/background threshold values are greater than regulatory standard, or within range of background threshold value and the regulatory standard * - Interim Maximum Allowable Concentrations (IMACs) of the 15A NCAC 02L Standard, Appendix 1, April 1, 2013. < - concentration not detected at or above the adjusted reporting limit. - - value not available NE - not established mg/L - milligrams per liter pCi/L - picocuries per liter Ng/L - micrograms per liter S.U. standard unit Prepared by: TJG Checked by: TAW Rev. 1 23 April 2020 Page 2 of 2 TABLE 6-32 COX MANAGEMENT MATRIX UNIT 5 1 NACTIVE ASH BASIN CORRECTIVE ACTION PLAN UPDATE CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS, LLC, MOORESBORO, NC Groundwater Cliffaid. St... C Mean N.robi Piedmont Concentration No,, X.—d— ""' Criterion —Ird— Monitoring Wells With COX Content C.—inarmill a le.g.l.t.u, on. Statistical) Y Stintiall= nd Near or ratio. (2018 CSA Updl Criterion Derived B1.m..d .(.A , Background or Beyond Beyond Flow cones) "t"'t V.I.. Range C01JJ Ratio Great., Th.. C.Innioreltiv. Ciri— C.I.Pli.— Bo,,d,W Bo —dun,, Fl— Z... Cou—tit ... t Standard, and Value, - 02L Criterion J* ry -1 o e"' I %to Li... of Evidence (LOE) - 02L Criterion Rationale for Selection of COX, for Corrective Action Evaluation (for.... tit ... t. where no means ... greater then comparative criteria in all flow ....s and/or multiple Ii..s of evidence support that Constituent occurrences ,, not related to the ,,,,e area, no corrective action is warranted) Rationale - 02L Criterion m ene, ii—te, than 02L trund,im! n ..... beyond wmpli,nm Inuundem, m are -ter than 02L -rdI n ..... beyond complimmuce bound., b. mean, gre,ter than 02L trund,im! n ..... beyond compli,me boundary N: m an, gre,ter than 02L tend,rd, In ...... tumbn gre,ter than the beckground I, a potential indicator f,,h al ini (Figure 6-75,) N m.— gnal than 02L etardind, h ... w, a— gnal than the mckg—rd �.Iu. ia . potential imli-or ofirlih tublin imi (Figure 6-75b) No n— g,,t,, than 02L Mi-dend, however a— greate, than the b,,kg,und �alu, I, a potential i.di,,t,, dfai tralain mfhu— (Fill 6-75t) -at., than b.tkg-u.d re.1.1 ll complimmuce Inuumd.- nN.in— On. mean gnal the, 02L -nd m, ,I,td —Irence, oon�iouant not nt g ter than ,mp ... ti—rid,II, Tn sel, ,... —ter (Fill 6-76) No —ime g—ter than 02L -rdI n ..... beyond complimmuce bound., m..n�g-.t.,th.nb.-g-und�.'�....I.lb ... nd compli.me boundary V,,,N One mean �—Ier than batoground e, omdit,ent not pelient great,, than background v,l,e in ,h pone at,,, ,an 1, 1,, Ithin renge of deep fi— on, be ko—nd omoin—on, detected at Cliftid, (Ficen, 6-77) No n— greater than background! ,I,, ne—r beyond connulimuce inund,ry Multiple munine grenter than bouk.-und value nubr— bell —plieno. bound.- and ..hibi- diacarrebl. plum. 'Figne, 6-1..) On, mean grenter than be kg,,nd mine nem— beyond romplinno, b-nd­ a.hirit, di—murible plum, (Figure 6-79b) No n— grant,, than b,,kg,und v,l,, n ..... beyond campli,me Inuundem, Mu�:ipp�: m are grental bae,1.m.rd �.I.. —1.1 beyond C—Pli.r.c. a.urdI ..hibil diace-1:1. plum. lFigne, 6-81.) M i m,,n,g,,t,,th,nb,ckg�nd�,lu,n,,,,,by,ndc,mpli,nc,b,und,�,.d,.hibi�di,m�,bi,pl,m,(Fig,m6-glb) one ,,, g,,t,, the, b,,kg,u,d ,I ........ beyond campli,ma Inuumnlim,, ohibit, di,c .... bl, plum, (11116-81,) No r— gre I., than 02L -ndent nulan., bell compliance bound.-, �uhel great., than a.tkg-umd..Iu. -.Pp.d (1116-133.) 0 mean gre,ter than 02L tend,ndl n ..... beyond compli,me teumudem,, ohibit, di—m,bl, plum, (Fill 6-83b) 0 g,,t,,th,, 021--rdI ...... beyond complimmuce Inuumnlim,, ohibit, di,c .... bl, plum, (IIII 6-8l No r— gres ., than 02L -nd.- nulan., bell compliance bound.-, T.S gre.tarthl beckground �alu. m.pp.d,Fig.- 6--.) 0 , ,,, g,,t,, the, 021--rdI ...... beyond complimme b ... d­ ohibit, di,c .... bl, plum, (IIII 6-84b) On, mean gre,ter than 02L trund,im! n ..... beyond compli,me teumudem,, ohibit, di—m,bl, plum, (Fill 6-8l 11111 111,111111111111111111 111 iiiiiiiiiiiiiiijilli III I Jill 11 111 Jill I Rationale - IMAC Criterion Or. 9—ter than b.,k9m.rd value near., beyond mumplience bound.-, e.hibit, dia-milible pi— 1149tre, 6-7.) No m an, greater than b,,kg,und ,I,e ne .... beyond compliame boundary No mean, gre ter than b,,kg,und ,I,e ne .... beyond compli,me Inuundery C ne .... beyond compli,me Inuundem, No m::n: gg,,:::,:hh:n:M N n r n M C near or beyond campli,me boundary mean, No greater than 'MAC re—r beyond campli.muce bound., No mean greater than b:,kkgg,und , lue near or beyond compli,me Inuundem, No -Zm greater the, b ro rd �.I.e re—r beyond campli.me bound., No mean, greater than b,,kg,,nd ,I,e near or beyond compli,me boundary Constituent Standards and Values - Background Criterion Lines of Evidence (LOE) - Background Criterion Rationale - Background Criterion One rn—g—terthum background! v,l,,near,rbey,nd oamar=bmmd­ out- probably not Influenced by,oh tuoln, di —able plurne-lit, lthin the e boundar' IN une 5-80b) Oem... g—terthern b,,kg,,,d val"erear or beyond compliance alu"i (Figurne 6-80c) Multiple mean, tire tarthan blu,kg-und value near or beyond mumplience a—dar, and a.ribite diommuribl, plum, (Figure 6-82,) Multiple n— greaterthi b,ckg,und uu, n ... or beyond c—ph-ce boundary and e,hiblite di —able plum, (Figure III On, ,an g ter than background value near or beyond oannuir,mol, inuund­ e,hibit, ch n,ble plum, (Figure 6-82c) No me— greater than background value near or beyond to pli—inudird., --e—grentertivi-bark round blue ... ur at 1—timin, GWA-56D and —40BRIJ, ­0 ime umide the d,t Mble b,,n pl,me and therefore probably not indiketive f,,h no,in influenre. C—tituent not P—M, in an mure ater dureater than bark—nd mine. N.meamiligne.-thumb kgg nd n::r b nd me b. 'nd:, me— greater than b:ck und v:�u or b:,.nd I, b nd -1-- 0"0--­Vr' b—d rn qr.11-1�1 I� hal, --t— .A Rev. 1 23 April 2020