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HomeMy WebLinkAboutNC0001422_Appdx O - Remediation Alternatives Summary_20200814Corrective Action Plan Update August 2020 L.V. Sutton Energy Complex APPENDIX O REMEDIATION ALTERNATIVES SUMMARY SynTerra Remedial Alternatives Remedial Alternative 1 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, and Confirmation Monitoring 14 d la c L d r Q m M d E d Remedial Alternative 1 relies on source excavation, continued a' groundwater extraction and treatment, and confirmation monitoring to reduce COI concentrations over time to meet corrective action goals. Confirmation monitoring measures the effects of natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. For inorganics, these processes include adsorption to soil and bedrock surfaces, precipitation, ion exchange, phyto-attenuation, dilution and dispersion. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC A. Protection of Human Health and the Environment Human Health There is no measurable difference between evaluated Site risk and risk indicated by background concentrations; therefore, no material increase in risks to human health related to the ash basins and FPA have been identified. The assessment conservatively included potential recreational receptors in the Site's NPDES cooling pond (Lake Sutton) and the Cape Fear River. Human receptors are not affected by groundwater from the Site as water supply wells are located upgradient or beyond the hydrological divide. Furthermore, within approximately 0.5 mile of the ash basins compliance boundary, 4 businesses were fitted with water treatment systems, 4 business were connected to county water supply, 1 additional business is planned to be connected to county water supply, and two public water supply wells were abandoned. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. Environment There were no detected concentrations of COIs in the Sutton Cooling Pond that exceeded 02B standards. The 1971 and 1984 ash basins and FPA do not cause an increase in risks to ecological receptors evaluated for the exposure area, based on the results of an ecological risk assessment performed for the Site using USEPA guidance (see Appendix E). B. Compliance with Applicable Federal, State, and Local Regulations Federal Remedial Alternative 1 complies with USEPA CCR Rule specified in 40 Code of Federal Regulations (CFR) § 257. State Remedial Alternative 1 will comply with Coal Ash Management Act of 2014 and 15A NCAC 02L .0106(I). If approved and subject to notification requirements including the NC Department of Transportation and NCDEQ for Sediment and Erosion Control associated with monitoring well installation for effectiveness monitoring. Local N/A Prepared by: GTC Checked by: JEC & WJW Page 1 of 10 Remedial Alternatives Remedial Alternative 1 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, and Confirmation Monitoring 14 d la c L d r Q m M d E Remedial Alternative 1 relies on source excavation, continued a' groundwater extraction and treatment, and confirmation monitoring to reduce COI concentrations over time to meet corrective action goals. Confirmation monitoring measures the effects of natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. For inorganics, these processes include adsorption to soil and bedrock surfaces, precipitation, ion exchange, phyto-attenuation, dilution and dispersion. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC C. Technical & Logistical Feasibility Ability to construct and operate technology There are 244 monitoring wells already installed related to the ash basins and FPA. No significant construction would be required for implementation. Other than potential installation of additional monitoring wells, no significant construction is required for implementation. Reliability of technology The technologies used in Remedial Alternative 1 have been used successfully to achieve remedial objectives for a wide range of COIs and geologic settings either as a stand alone remedy, or in combination with other remediation approaches. The CSM supports the reliability of the excavation, continued extraction, and confirmation monitoring approach. Ease of undertaking additional Remedial Alternatives, if necessary Other remedial technologies have commonly been used in conjunction with continued monitoring. Use of continued monitoring would not adversely impact the implementation of other potential remedial actions; in fact, RA 2 1 contain all elements of Remedial Alternative 1. Ability to monitor effectiveness of remedy Effectiveness is monitored through evaluation of COI concentrations over time in accordance with a post -excavation groundwater effectiveness monitoring program. Ability to coordinate and obtain approvals from other agencies An NPDES permit exists for the facility and currently includes provisions for ongoing groundwater extraction. Availability of services and materials An extensive groundwater monitoring well network already exists. Additional monitoring wells may be required to complete the continued monitoring well network. All services and materials are readily available to support effectiveness monitoring. D. Time Required to Initiate and Implement Requirements for bench scale testing There are no requirements for bench scale testing to implement Remedial Alternative 1. Design The alternative is readily implementable. The existing monitoring well network can be utilized to design the continued monitoring network. Permitting The facility expects an NPDES permit to be issued that will allow them to manage and discharge the water from the interim extraction system contained. The NPDES permit could be modified, if necessary. Soil Erosion and Sediment Control permits are required for land disturbance activities, including well installation. These permits are a straightforward to procure. Prepared by: GTc Checked by: JEC & wJW Page 2 of 10 Remedial Alternatives Remedial Alternative 1 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, and Confirmation Monitoring 14 d la c L d r Q m M d E Remedial Alternative 1 relies on source excavation, continued a' groundwater extraction and treatment, and confirmation monitoring to reduce COI concentrations over time to meet corrective action goals. Confirmation monitoring measures the effects of natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. For inorganics, these processes include adsorption to soil and bedrock surfaces, precipitation, ion exchange, phyto-attenuation, dilution and dispersion. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC E. Short-term Effectiveness IL Protection of Community The community would not be impacted during monitoring activities as they would be performed on Duke Energy property. Any anticipated increase in traffic on roads leading to Sutton due to nature of the work would be de Minimis. Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Worker Protection Work would be performed under a Health & Safety Plan, which identifies risks and mitigation measures to protect workers and the environment. All personal would be require relevant training and supporting documentation to verify competency. Environmental Impacts Some migration of COI affected groundwater would be expected as part of the attenuation process. However, human health and ecological risk assessments do not indicate significant risks. Time Until Action is Complete Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. At the time of CAP Update preparation, only three quarters of post - excavation data were available (September & December 2019, March 2020). No post -excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict natural attenuation. After the five year monitoring period, the models can be refined to accurately predict the time required. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. F. Long-term Effectiveness Adequacy and Reliability of Controls Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users is further mitigated by the connection of 5 businesses to New Hanover County water supply, installation of water filtration systems for water supply wells for 4 businesses, and abandonment of two public water supply wells within a 0.5-mile radius of the ash basin compliance boundaries. Magnitude of Residual Risk Implementation of Remedial Alternative 1 would not result in increased residual risk, as the current state and predicted future state does not indicate unacceptable risk to human health or the environment. Potential risks to groundwater is further controlled by water filtration systems to water supply users within a 0.5-mile radius of the ash basin compliance boundaries. Prepared by: GTc Checked by: JEC & WJW Page 3 of 10 Remedial Alternatives Remedial Alternative 1 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, and Confirmation Monitoring 14 u m c L d r Q m M d E Remedial Alternative 1 relies on source excavation, continued a' groundwater extraction and treatment, and confirmation monitoring to reduce COI concentrations over time to meet corrective action goals. Confirmation monitoring measures the effects of natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. For inorganics, these processes include adsorption to soil and bedrock surfaces, precipitation, ion exchange, phyto-attenuation, dilution and dispersion. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC G. Reduction of Toxicity, Mobility, &Volume Treatment Process Used and Materials Treated Treatment technologies used in Remedial Alternative 1 are source control and ongoing groundwater extraction on the eastern property boundary. Natural attenuation relies on the mechanisms that naturally attenuate the concentrations of CCR inorganic constituents are dilution, dispersion, advection, sorption (including ion exchange and precipitation) and phyto-attenuation Volume of Materials Destroyed or Treated The source of COIs to the groundwater has been removed through excavation. The extraction of groundwater at the eastern boundary has removed COIs from groundwater. Extracted groundwater will be discharged under an NPDES permit in accordance with applicable regulatory requirements. Degree of Expected Reductions There is insufficient post -excavation data following source removal to assess the time for the groundwater to achieve standards by natural attenuation. After the five year effectiveness monitoring period, the model may be refined to accurately predict the time required. Irreversible Treatment None. Natural processes are not anticipated to be reversible based on results of extensive geochemical modeling; however, variations in pH and reduction -oxidation in the geochemical environment can change effectiveness. Type and Quantity of Residuals Remaining Residuals might be present below regulatory standards when standards are met over time, as intended. Residuals removed through groundwater extraction and source removal have been and will be managed in accordance with applicable regulatory requirements. 02L Standards at the Compliance Boundary Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. A robust pump -and -treat system was simulated in the Flow and Transport model (Appendix F). Results of those simulations indicate groundwater extraction and infiltration would not decrease COI concentrations at the compliance boundary faster than what the MNA simulations predict. In fact, the pump -and - treat simulation for selenium indicated concentrations would decrease to less than the 02L standard quicker under natural attenuation. These results are due to the limited post -excavation dataset and the lack of monitoring wells downgradient of the compliance boundary. Insufficient land surface is available to install wells beyond the compliance boundary. The models used conservative assumptions to predict COI concentrations in groundwater beneath the cooling pond. At the time of the CAP Update preparation, only three quarters of post excavation data were available (September & December 2019, March 2020). No post - excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict future COI concentrations in groundwater beyond the compliance boundary. After the five year monitoring period, the models can be refined to accurately predict the time required to reach compliance with regulatory standards. The groundwater system is beginning to reach equilibrium. The geochemical and MNA evaluations identified multiple areas where natural attenuation has already occurred. Recent groundwater sampling results indicate source removal is already providing the chemical environment necessary for attenuation. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching the elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. Natural attenuation is occurring in the areas northwest of the 1984 ash basin, southeast of the 1971 ash basin and FPA, off -Site near SMW-01C, and downgradient of the FADA within the FCPA. Boron and arsenic concentrations in wells on the west side of the ash basins are also showing decreasing trends in some areas. COI concentrations are anticipated to naturally attenuate with time as the groundwater system reaches equilibrium after excavation. Prepared by: GTC Checked by: JEC & WJW Page 4 of 10 Remedial Alternatives Remedial Alternative 1 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, and Confirmation Monitoring 14 d C c L d r Q m M d E d Remedial Alternative 1 relies on source excavation, continued a' groundwater extraction and treatment, and confirmation monitoring to reduce COI concentrations over time to meet corrective action goals. Confirmation monitoring measures the effects of natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. For inorganics, these processes include adsorption to soil and bedrock surfaces, precipitation, ion exchange, phyto-attenuation, dilution and dispersion. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC Costs to Implement Remedial Alternative 1 Capital Costs Not developed Annual Costs Not developed Total Life Cycle Costs Not developed The cost estimate was not developed to reflect the cost of implementing Remedial Alternative 1 for Source Areas 1 and 2. Costs to implement Remedial Alternative 1 include the labor and materials to monitor and maintain appropriate wells and continue operation of the extraction system. This alternative does not include the costs of confirmation monitoring and would be less than the cost estimate of RA2. Life cycle costs are determined using a Net Present Value (NPV) of expenditures for initial Capital costs and annual O&M expenses for the duration of the remedy. A Discount Rate of 5% assumed in developing the cost estimate. Stakeholder Sentiment Regarding Implementation It is expected that there would be positive and negative sentiment about implementation of an alternative that enlists an MNA program. No landowner would be affected and groundwater COIs do not pose an unacceptable risk to potential human or ecological receptors. The property is owned and controlled by Duke Energy. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. Some community stakeholders might consider the time frame to achieve remediation goals to be unacceptable. Until the final corrective action is developed and comments are received and reviewed, assessment of community acceptance will not be fully informed. Prepared by: GTC Checked by: JEC & WJW Page 5 of 10 Remedial Alternatives Remedial Alternative 2 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, Confirmation Monitoring with a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond, and 5 year EMP review N d M m c L Y Q m d E d Remedial Alternative 2 relies on, source excavation, continued groundwater extraction and treatment, and confirmation monitoring. In addition to these methods for reducing COI concentrations in groundwater, institutional controls would also be used to prevent receptor exposure. The institutional control of a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC A. Protection of Human Health and the Environment Human Health There is no measurable difference between evaluated Site risk and risk indicated by background concentrations; therefore, no material increase in risks to human health related to the ash basins and FPA have been identified. The assessment conservatively included potential recreational receptors in the Site's NPDES cooling pond (Lake Sutton) and the Cape Fear River. Human receptors are not affected by groundwater from the Site as water supply wells are located upgradient or beyond the hydrological divide. Furthermore, within approximately 0.5 mile of the ash basins compliance boundary, 4 businesses were fitted with water treatment systems, 4 business were connected to county water supply, 1 additional business is planned to be connected to county water supply, and two public water supply wells were abandoned. A restricted groundwater use designation is an institutional control that would further protect human health. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. If implemented after the five year review period, the contingency plan proposed in Section 5.13 would further protect human health. Environment There were no detected concentrations of COIs in the Sutton Cooling Pond that exceeded 02B standards. The 1971 and 1984 ash basins and FPA do not cause an increase in risks to ecological receptors evaluated for the exposure area, based on the results of an ecological risk assessment performed for the Site using USEPA guidance (see Appendix E). B. Compliance with Applicable Federal, State, and Local Regulations Federal Remedial Alternative 3 complies with USEPA CCR Rule specified in 40 Code of Federal Regulations (CFR) § 257. State Remedial Alternative 2 complies with Coal Ash Management Act of 2014 and 15A NCAC 02L .0106(I). If approved and subject to notification requirements including the NC Department of Transportation and NCDEQ for Sediment and Erosion Control associated with monitoring well installation for effectiveness monitoring. Local A Restricted Groundwater Use Designation can be implemented in compliance with local laws and regulations. Prepared by: GTC Checked by: JEC & WJW Page 6 of 10 Remedial Alternatives Remedial Alternative 2 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, Confirmation Monitoring with a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond, and 5 year EMP review N d m M c L Y Q m M d E d Remedial Alternative 2 relies on, source excavation, continued groundwater extraction and treatment, and confirmation monitoring. In addition to these methods for reducing COI concentrations in groundwater, institutional controls would also be used to prevent receptor exposure. The institutional control of a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC C. Technical & Logistical Feasibility Ability to construct and operate technology There are 244 monitoring wells already installed related to the ash basins and FPA. No significant construction would be required for implementation. Additional monitoring wells may be required for post -excavation monitoring. Reliability of technology The technologies used in Remedial Alternative 2 have been used successfully to achieve remedial objectives for a wide range of COIs and geologic settings either as a stand alone remedy, or in combination with other remediation approaches. The CSM supports the reliability of the excavation, continued extraction, and confirmation monitoring approach. Additional assurances to the reliability of the alternative are made through an effectiveness monitoring plan and a restricted groundwater use designation. Ease of undertaking additional RAs if necessary Remedial Alternative 2 relies on mature technology and have been used to implement cleanup strategies for similar COIs. These technologies are dependent on subsurface conditions and effectiveness of treatment approaches. If a contingency option is deemed necessary, applicable remedial technologies would be screened to determine the most effective technology is available. Ability to monitor effectiveness of remedy Effectiveness is monitored through evaluation of COI concentrations over time in accordance with a post -excavation groundwater effectiveness monitoring program. Ability to coordinate and obtain approvals from other agencies Soil erosion and sediment control permits are relatively straightforward and could be readily obtained from NCDEQ. An NPDES permit exists for the facility and currently includes provisions for ongoing groundwater extraction at the eastern property boundary. A Restricted Groundwater Use Designation could be implemented in compliance with local laws and regulations. Availability of services and materials All services and materials are readily available to support the Remedial Alternative. An extensive groundwater monitoring well network already exists to support effectiveness monitoring. D. Time Required to Initiate and Implement Requirements for bench scale testing There are no requirements for bench scale testing to implement Remedial Alternative 1. Design The alternative is readily implementable. The existing monitoring well network can be utilized to design the continued monitoring network. Permitting The facility expects an NPDES permit to be issued that will allow them to manage and discharge the water from the interim extraction system contained. The NPDES permit could be modified, if necessary. Soil Erosion and Sediment Control permits are required for land disturbance activities, including well installation. These permits are a straightforward to procure. Prepared by: GTc Checked by: JEC & wJW Page 7 of 10 Remedial Alternatives Remedial Alternative 2 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, Confirmation Monitoring with a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond, and 5 year EMP review N d M m c L Q m M d E d Remedial Alternative 2 relies on, source excavation, continued groundwater extraction and treatment, and confirmation monitoring. In addition to these methods for reducing COI concentrations in groundwater, institutional controls would also be used to prevent receptor exposure. The institutional control of a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC E. Short-term Effectiveness in Protection of Community during remediation The community would not be impacted during monitoring activities as they would be performed on Duke Energy property. Any anticipated increase in traffic on roads leading to Sutton due to nature of the work would be de Minimis. Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users could be further controlled by a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond. Protection of workers during remediation Work would be performed under a Health & Safety Plan, which identifies risks and mitigation measures to protect workers and the environment. All personal would be require relevant training and supporting documentation to verify competency. Environmental impacts Some migration of COI affected groundwater would be expected as part of the attenuation process. However, human health and ecological risk assessments do not indicate significant risks. Environmental impacts associated with clearing to install wells and supporting infrastructure would be minimal and work would be performed with a soil erosion and sediment control permit. Time until Remedial Alternative objectives are achieved Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. At the time of CAP Update preparation, only three quarters of post - excavation data were available (September & December 2019, March 2020). No post -excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict natural attenuation. After the five year monitoring period, the models can be refined to accurately predict the time required. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching the elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. F. Long-term Effectiveness Adequacy and reliability of controls Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users is further mitigated by the connection of 5 businesses to New Hanover County water supply, installation of water filtration systems for water supply wells for 4 businesses, and abandonment of two public water supply wells within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of institutional controls may include a restricted groundwater use designation to further protect potential groundwater users. Magnitude of Residual Risk Implementation of Remedial Alternative 2 would not result in increased residual risk, as the current state and predicted future state does not indicate unacceptable risk to human health or environment. Potential risks to groundwater is further controlled by water filtration systems to water supply users within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of an institutional control of a Restricted Groundwater Use Designation would further protect potential groundwater users. Prepared by: GTC Checked by: JEC & WJW Page 8 of 10 Remedial Alternatives Remedial Alternative 2 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, Confirmation Monitoring with a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond, and 5 year EMP review N d M m c d Q m M d E d Remedial Alternative 2 relies on, source excavation, continued groundwater extraction and treatment, and confirmation monitoring. In addition to these methods for reducing COI concentrations in groundwater, institutional controls would also be used to prevent receptor exposure. The institutional control of a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC G. Reduction of Toxicity, Mobility, &Volume Treatment process used and materials treated Treatment technologies used in Remedial Alternative 2 are source control and ongoing groundwater extraction and treatment. The mechanisms that naturally attenuate the concentrations of CCR inorganic constituents are dilution, dispersion, advection, sorption (including ion exchange and precipitation) and phyto-attenuation. Volume of materials destroyed or treated The source of COIs to the groundwater has been removed through excavation. The extraction of groundwater at the eastern boundary has removed COIs from groundwater. Extracted groundwater would be discharged under an NPDES permit in accordance with applicable regulatory requirements. Degree of expected reductions There is insufficient post -excavation data following source removal to assess the time for the groundwater to achieve standards by natural attenuation. After the five year effectiveness monitoring period, the model may be refined to accurately predict the time required. Irreversible Treatment None. Natural processes are not anticipated to be reversible based on results of extensive geochemical modeling; however, variations in pH and reduction -oxidation in the geochemical environment can change effectiveness. Type and quantity of residuals remaining Residuals might be present below regulatory standards when standards are met over time, as intended. Residuals removed through groundwater extraction and source removal have been and will be managed in accordance with applicable regulatory requirements. 02L Standards at the Compliance Boundary Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. A robust pump -and -treat system was simulated in the Flow and Transport model (Appendix F). Results of those simulations indicate groundwater extraction and infiltration would not decrease COI concentrations at the compliance boundary faster than what the MNA simulations predict. In fact, the pump -and - treat simulation for selenium indiated concentrations would decrease to less than the 02L standard quicker under natural attenuation. These results are due to the limited post -excavation dataset and the lack of monitoring wells downgradient of the compliance boundary. Insufficient land surface is available to install wells beyond the compliance boundary. The models used conservative assumptions to predict COI concentrations in groundwater beneath the cooling pond. At the time of the CAP Update preparation, only three quarters of post excavation data were available (September & December 2019, March 2020). No post - excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict future COI concentrations in grouindwater beyond the compliance boundary. After the five year monitoring period, the models can be refined to accurately predict the time required to reach compliance with regulatory standards. The groundwater system is beginning to reach equlibrium. The geochemical and MNA evaluations identified multiple areas where natural attenuation has already occured. Recent groundwater sampling results indicate source removal is already providing the chemical environment necessary for attenuation. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching the elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. Natural attenuation is occurring in the areas northwest of the 1984 ash basin, southeast of the 1971 ash basin and FPA, off -Site near SMW-01C, and downgradient of the FADA within the FCPA. Boron and arsenic concentrations in wells on the west side of the ash basins are also showing decreasing trends in some areas. COI concentrations are anticipated to naturally attenuate with time as the groundwater system reaches equilibrium after excavation. Prepared by: GTC Checked by: JEC & WJW Page 9 of 10 Remedial Alternatives Remedial Alternative 2 Source Control by Excavation, Continued Groundwater Extraction and Treatment at the Eastern Property Line, Confirmation Monitoring with a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond, and 5 year EMP review N d M m c L Q m d E d Remedial Alternative 2 relies on, source excavation, continued groundwater extraction and treatment, and confirmation monitoring. In addition to these methods for reducing COI concentrations in groundwater, institutional controls would also be used to prevent receptor exposure. The institutional control of a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 1 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC Costs to Implement Remedial Alternative 2 Capital Costs $259,000 Operations, Maintenance, and Monitoring Costs $198,000 Total Life Cycle Costs $415,000 The cost estimate was developed to reflect the cost of implementing Remedial Alternative 2 for Source Areas 1 and 2. Costs to implement RA 2 would be based on include the labor and materials to monitor and maintain appropriate wells and continue operation of the extraction system. Life cycle costs are determined using a Net Present Value (NPV) of expenditures for initial Capital costs and annual 0&M expenses for the duration of the remedy. A Discount Rate of 5% assumed in developing the cost estimate. Stakeholder Sentiment Regarding Implementation It is expected that there would be positive and negative sentiment about implementation of an alternative that enlists an MNA program. No landowner would be affected and groundwater Co do not pose an unacceptable risk to potential human or It receptors. The property is owned and controlled by Duke Energy, but a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond would further protect potential groundwater users. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. Some community stakeholders might consider the time frame to achieve remediation goals to be unacceptable. Until the final corrective action is developed and comments are received and reviewed, assessment of community acceptance will not be fully informed. Prepared by: GTC Checked by: JEC & WJW Page 10 of 10 Remediation Alternatives Remediation Alternative 1 Source Control by Excavation and Monitored Natural Attenuation Remediation Alternative 1 relies on, source excavation and natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. 1. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC A. Protection of Human Health and the Environment Human Health There is no measurable difference between evaluated Site risk and risk indicated by background concentrations; therefore, no material increase in risks to human health related to the FADA and FCPA have been identified. The assessment conservatively included potential recreational receptors in the Site's NPDES cooling pond (Lake Sutton) and the Cape Fear River. Human receptors are not affected by groundwater from the Site as water supply wells are located upgradient or beyond the hydrological divide. Furthermore, within approximately 0.5 mile of the ash basins compliance boundary, 4 businesses were fitted with water treatment systems, 4 business were connected to county water supply, 1 additional business is planned to be connected to county water supply, and two public water supply wells were abandoned. A restricted groundwater use designation is an institutional control that would further protect human health. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. Environment There were no detected concentrations of COIs in the Sutton Cooling Pond intake canal that exceeded 02B standards. The FADA and FCPA do not cause an increase in risks to ecological receptors evaluated for the exposure area, based on the results of an ecological risk assessment performed for the Site using USEPA guidance (see Appendix E). B. Compliance with Applicable Federal, State, and Local Regulations Federal Remedial Alternative 1 complies with USEPA CCR Rule specified in 40 Code of Federal Regulations (CFR) § 257. State Remedial Alternative 1 will comply with Coal Ash Management Act of 2014 and 15A NCAC 02L .0106(I). If approved and subject to notification requirements including the NC Department of Transportation and NCDEQ for Sediment and Erosion Control associated with monitoring well installation for effectiveness monitoring. For additional details on MNA see Appendix I. Local MNA would be subject to notification requirements to any affected parties and to County officials per 15A NCAC 02L .0114(b). A Restricted Groundwater Use Designation can be implemented in compliance with local laws and regulations. F'repareo Dy: U I U unecked by: JJEU & wJw Page 1of10 Remediation Alternatives Remediation Alternative 1 Source Control by Excavation and Monitored Natural Attenuation Remediation Alternative 1 relies on, source excavation and natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC C. Technical & Logistical Feasibility Ability to construct and operate technology There are 18 monitoring wells already installed related to the FADA and FCPA. No significant construction would be required for implementation. Other than potential installation of additional monitoring wells, no significant construction is required for implementation. Reliability of technology MNA and the other technologies used in Remedial Alternative 1 have been used successfully to achieve remedial objectives for a wide range of COIs and geologic settings either as a stand alone remedy, or in combination with other remediation approaches. The CSM supports the reliability of an MNA approach. Ease of undertaking additional RAs if necessary Other remedial technologies have commonly been used in conjunction with MNA. Use of MNA would not adversely impact the implementation of other potential remedial actions; in fact, Remedial Alternative 2 contains all elements of Remedial Alternative 1. Ability to monitor effectiveness of remedy Effectiveness is monitored through evaluation of COI concentrations over time in accordance with a post -excavation groundwater effectiveness monitoring program. Ability to coordinate and obtain approvals from other agencies An NPDES permit exists for the facility and currently includes provisions for ongoing groundwater extraction at the site. Restricted Groundwater Use Designations can be readily obtained. Availability of services and materials An extensive groundwater monitoring well network already exists. All services and materials are readily available to support effectiveness monitoring. D. Time Required to Initiate and Implement Requirements for bench scale testing There are no requirements for bench scale testing to implement Remedial Alternative 1. Design MNA is readily implementable. The existing monitoring well network can be utilized to design the MNA network. Permitting The facility expects an NPDES permit to be issued that will allow them to manage and discharge the water contained in the FADA. The NPDES permit could be modified, if necessary. Soil Erosion and Sediment Control permits are required for land disturbance activities, including well installation. These permits are a straightforward to procure. rreparea Dy: uu I tt; c;neCKea oy: itu a wjw Page 2 of 10 Remediation Alternatives Remediation Alternative 1 Source Control by Excavation and Monitored Natural Attenuation Remediation Alternative 1 relies on, source excavation and natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC E. Short-term Effectiveness Protection of Community during remediation The community would not be impacted during active remediation and monitoring activities as they would be performed on Duke Energy property. Any anticipated increase in traffic on roads leading to Sutton due to nature of the work would be de Minimis. Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users could be further controlled by a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond. Work Protection Work would be performed under a Health & Safety Plan, which identifies risks and mitigation measures to protect workers and the environment. All personal will be require relevant training and supporting documentation to verify competency. Environmental impacts Some migration of COI affected groundwater would be expected as part of the attenuation process. However, human health and ecological risk assessments do not indicate significant risks. Time Until Action is Complete Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. At the time of CAP Update preparation, only three quarters of post -excavation data were available (September & December 2019, March 2020). No post -excavation data related to the FPA is available. There is insufficient post - excavation data available to accurately predict MNA. After the five year monitoring period, the models can be refined to accurately predict the time required. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. The proposed contingency option of installing air-sparging wells is expected to have a similar increase in EH. It appears the system is naturally approaching elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five- year post -excavation EMP. F. Long-term Effectiveness Adequacy and reliability of controls Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users is further mitigated by the connection of 5 businesses to New Hanover County water supply, installation of water filtration systems for water supply wells for 4 businesses, and abandonment of two public water supply wells within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of institutional controls may include a restricted groundwater use designation to further protect potential groundwater users. Magnitude of Residual Risk Implementation of Remedial Alternative 1 would not result in increased residual risk, as the current state and predicted future state does not indicate unacceptable risk to human health or environment. Potential risks to groundwater is further controlled by water filtration systems to water supply users within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of an institutional control of a Restricted Groundwater Use Designation would further protect potential groundwater users. rrepareo Dy: u I tt; c:neCKed Dy: etc: a wow Page 3of10 Remediation Alternatives Remediation Alternative 1 Source Control by Excavation and Monitored Natural Attenuation Remediation Alternative 1 relies on, source excavation and natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC G. Reduction of Toxicity, Mobility, & Volume Treatment process used and materials treated Treatment technology used in Remedial Alternative 1 are source control. MNA relies on the mechanisms that naturally attenuate the concentrations of CCR inorganic constituents are dilution, dispersion, advection, sorption (including ion exchange and precipitation) and phyto- attenuation Volume of materials destroyed or treated The source of COIs to the groundwater has been removed through excavation. Degree of expected reductions There is insufficient post -excavation data following source removal to assess the time for the groundwater to achieve standards by MNA. After the five year effectiveness monitoring period, the model may be refined to accurately predict the time required. Irreversible Treatment None. Natural processes are not anticipated to be reversible based on results of extensive geochemical modeling; however, variations in pH and reduction -oxidation in the geochemical environment can change effectiveness. Type and quantity of residuals remaining Residuals may be present below regulatory standards as the system would be intended to meet standards over time. Residuals removed through source removal have been and will be managed in accordance with applicable regulatory requirements. 02L Standards Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. A robust pump -and -treat system was simulated in the Flow and Transport model (Appendix F). Results of those simulations indicate groundwater extraction and infiltration would not decrease COI concentrations at the compliance boundary faster than what the MNA simulations predict. In fact, the pump -and -treat simulation for selenium indicated concentrations would decrease to less than the 02L standard quicker under natural attenuation. These results are due to the limited post -excavation dataset and the lack of monitoring wells downgradient of the compliance boundary. Insufficient land surface is available to install wells beyond the compliance boundary. The models used conservative assumptions to predict COI concentrations in groundwater beneath the cooling pond. At the time of the CAP Update preparation, only three quarters of post excavation data were available (September & December 2019, March 2020). No post - excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict future COI concentrations in groundwater beyond the compliance boundary. After the five year monitoring period, the models can be refined to accurately predict the time required to reach compliance with regulatory standards. The groundwater system is beginning to reach equilibrium. The geochemical and MNA evaluations identified multiple areas where natural attenuation has already occurred. Recent groundwater sampling results indicate source removal is already providing the chemical environment necessary for attenuation. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. Natural attenuation is occurring in the areas northwest of the 1984 ash basin, southeast of the 1971 ash basin and FPA, off -Site near SMW- 01C, and downgradient of the FADA within the FCPA. Boron and arsenic concentrations in wells on the west side of the ash basins are also showing decreasing trends in some areas. COI concentrations are anticipated to naturally attenuate with time as the groundwater system reaches equilibrium after excavation. Prepared by: GTC Checked by: JEC & WJW Page 4 of 10 Remediation Alternatives Remediation Alternative 1 Source Control by Excavation and Monitored Natural Attenuation Remediation Alternative 1 relies on, source excavation and natural attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MNA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC Costs to Implement Remedial Alternative 1 Capital Costs Not developed Annual Costs Not developed Total Life Cycle Costs Not developed The cost estimate was not developed to reflect the cost of implementing Remedial Alternative 1 for Source Areas 1 and 2. Costs to implement Remedial Alternative 1 include the labor and materials to monitor and maintain appropriate wells and continue operation of the extraction system. This alternative does not include the costs of confirmation monitoring and would be less than the cost estimate of RA2. Life cycle costs are determined using a Net Present Value (NPV) of expenditures for initial Capital costs and annual O&M expenses for the duration of the remedy. A Discount Rate of 5% assumed in developing the cost estimate. Prepared by: GTC Checked by: JEC & WJW Page 5of10 I Remediation Alternatives I Remediation Alternative 2 Source Control by Excavation, Monitored Natural Attenuation with a Restricted Groundwater Use Designation of the Former Coal Pile Area, and a 5 year EMP review A ru E Remediation Alternative 2 relies on, source excavation, natural d attenuation mechanisms to reduce COI concentrations over time to IY meet corrective action goals, and a 5 year EMP period. In addition to these methods for reducing COI concentrations in groundwater, institutional controls will also be used to prevent receptor exposure The institutional control of a Restricted Groundwater Use Designation of the Source Area 2 areas not covered by the ash basins compliance boundary would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MINA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC A. Protection of Human Health and the Environment Human Health There is no measurable difference between evaluated Site risk and risk indicated by background concentrations; therefore, no material increase in risks to human health related to the FADA and FCPA have been identified. The assessment conservatively included potential recreational receptors in the Site's NPDES cooling pond (Lake Sutton) and the Cape Fear River. Human receptors are not affected by groundwater from the Site as water supply wells are located upgradient or beyond the hydrological divide. Furthermore, within approximately 0.5 mile of the ash basins compliance boundary, 4 businesses were fitted with water treatment systems, 4 business were connected to county water supply, 1 additional business is planned to be connected to county water supply, and two public water supply wells were abandoned. A restricted groundwater use designation is an institutional control that would further protect human health. The site is an operating gas fired, combined cycle electric power plant and will be in industrial use for the foreseeable future. If implemented after the five year review period, the contingency plan proposed in Section 5.13 would further protect human health. Environment There were no detected concentrations of COIs in the Sutton Cooling Pond intake canal that exceeded 02B standards. The FADA and FCPA do not cause an increase in risks to ecological receptors evaluated for the exposure area, based on the results of an ecological risk assessment performed for the Site using USEPA guidance (see Appendix E). B. Compliance with Applicable Federal, State, and Local Regulations Federal Remedial Alternative 2 complies with USEPA CCR Rule specified in 40 Code of Federal Regulations (CFR) § 257. State Remedial Alternative 2 complies with the Coal Ash Management Act of 2014,15A NCAC 02L regulations and NCAC 02B regulations. NPDES permitted discharge is in place. Local MNA would be subject to notification requirements to any affected parties and to County officials per 15A NCAC 02L .0114(b). A Restricted Groundwater Use Designation can be implemented in compliance with local laws and regulations. Prepared by: GTC Checked by: JEC & WJW Page 6of10 I Remediation Alternatives I Remediation Alternative 2 Source Control by Excavation, Monitored Natural Attenuation with a Restricted Groundwater Use Designation of the Former Coal Pile Area, and a 5 year EMP review to ru E Remediation Alternative 2 relies on, source excavation, natural d attenuation mechanisms to reduce COI concentrations over time to iY meet corrective action goals, and a 5 year EMP period. In addition to these methods for reducing COI concentrations in groundwater, institutional controls will also be used to prevent receptor exposure The institutional control of a Restricted Groundwater Use Designation of the Source Area 2 areas not covered by the ash basins compliance boundary would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MINA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC C. Technical & Logistical Feasibility Ability to construct and operate technology There are 18 monitoring wells already installed related to the FADA and FCPA. No significant construction would be required for implementation. Other than potential installation of additional monitoring wells, no significant construction is required for implementation. Reliability of technology MNA and the other technologies used in Remedial Alternative 2 have been used successfully to achieve remedial objectives for a wide range of COIs and geologic settings either as a stand alone remedy, or in combination with other remediation approaches. The CSM supports the reliability of an MNA approach. Ease of undertaking additional RAs if necessary Remedial Alternative 2 relies on mature technology and have been used to implement cleanup strategies for similar COIs. These technologies are dependent on subsurface conditions and effectiveness of treatment approaches. Ability to monitor effectiveness of remedy Effectiveness is monitored through evaluation of COI concentrations over time in accordance with a groundwater effectiveness monitoring program. Ability to coordinate and obtain approvals from other agencies Soil erosion and sediment control permits are relatively straightforward and could be readily obtained from NCDEQ. An NPDES permit exists for the facility and currently includes provisions for ongoing groundwater extraction at the eastern property boundary. A Restricted Groundwater Use Designation could be implemented in compliance with local laws and regulations. Availability of services and materials All services and materials are readily available to support the remediation alternative. An extensive groundwater monitoring well network already exists to support effectiveness monitoring. D. Time Required to Initiate and Implement Requirements for bench scale testing There are no requirements for bench scale testing to implement Remedial Alternative 2. Design MNA is readily implementable. The existing monitoring well network can be utilized to design the MNA network. Permitting The facility expects an NPDES permit to be issued that will allow them to manage and discharge the water in the FADA. The NPDES permit could be modified, if necessary. Soil Erosion and Sediment Control permits are required for land disturbance activities, including well installation. These permits are a straightforward to procure. Prepared by: GTC Checked by: JEC & WJW Page 7of10 I Remediation Alternatives I Remediation Alternative 2 Source Control by Excavation, Monitored Natural Attenuation with a Restricted Groundwater Use Designation of the Former Coal Pile Area, and a 5 year EMP review A rV E Remediation Alternative 2 relies on, source excavation, natural d attenuation mechanisms to reduce COI concentrations over time to iY meet corrective action goals, and a 5 year EMP period. In addition to these methods for reducing COI concentrations in groundwater, institutional controls will also be used to prevent receptor exposure The institutional control of a Restricted Groundwater Use Designation of the Source Area 2 areas not covered by the ash basins compliance boundary would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MINA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC E. Short-term Effectiveness Protection of Community during remediation The community would not be impacted during active remediation and monitoring activities as they would be performed on Duke Energy property. Any anticipated increase in traffic on roads leading to Sutton due to nature of the work would be de Minimis. Implementation and maintenance of an effectiveness monitoring program would be in place to evaluate variations from expected conditions. Alternative measures could be taken to address variations. Potential risks to groundwater users could be further controlled by a Restricted Groundwater Use Designation over a small portion of the Site's cooling pond. Protection of workers during remediation Work would be performed under a Health & Safety Plan, which identifies risks and mitigation measures to protect workers and the environment. All personal will be require relevant training and supporting documentation to verify competency. Environmental impacts Some migration of COI affected groundwater would be expected as part of the attenuation process. However, human health and ecological risk assessments do not indicate significant risks. In addition to the energy consumption required to operate the existing extraction and treatment system at the eastern property boundary, remedial Alternative 2 has increased energy consumption to pump water from the discharge canal to the excavated FADA. Time until RA objectives are achieved Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. At the time of CAP Update preparation, only three quarters of post -excavation data were available (September & December 2019, March 2020). No post -excavation data related to the FPA is available. There is insufficient post - excavation data available to accurately predict MNA. After the five year monitoring period, the models can be refined to accurately predict the time required. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. F. Long-term Effectiveness Adequacy and reliability of controls Implementation and maintenance of an effectiveness monitoring program will be in place to evaluate variations from expected conditions. Alternative measures can be taken to address variations. Potential risks to groundwater users is further controlled by the installation of water filtration systems for water supply well within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of institutional controls will include a deed restriction and Restricted Designation to further protect potential groundwater users. Magnitude of Residual Risk Implementation of Remedial Alternative 2 would not result in increased residual risk, as the current state and predicted future state does not indicate unacceptable risk to human health or environment. Potential risks to groundwater is further controlled by water filtration systems to water supply users within a 0.5-mile radius of the ash basin compliance boundaries. Implementation of an institutional control of a Restricted Groundwater Use Designation would further protect potential groundwater users. vreparec Dy: u I L, l;neCKea Dy: dtl: & wjw Page 8of10 I Remediation Alternatives I Remediation Alternative 2 Source Control by Excavation, Monitored Natural Attenuation with a Restricted Groundwater Use Designation of the Former Coal Pile Area, and a 5 year EMP review A rV E Remediation Alternative 2 relies on, source excavation, natural d attenuation mechanisms to reduce COI concentrations over time to 19 meet corrective action goals, and a 5 year EMP period. In addition to these methods for reducing COI concentrations in groundwater, institutional controls will also be used to prevent receptor exposure The institutional control of a Restricted Groundwater Use Designation of the Source Area 2 areas not covered by the ash basins compliance boundary would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MINA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC G. Reduction of Toxicity, Mobility, & Volume Treatment process used and materials treated Treatment technology used in Remedial Alternative 2 is source control. The mechanisms that naturally attenuate the concentrations of CCR inorganic constituents are dilution, dispersion, advection, sorption (including ion exchange and precipitation) and phyto-attenuation. Volume of materials destroyed or treated The source of COIs to the groundwater has been removed through excavation. Extracted groundwater would be discharged under an NPDES permit in accordance with applicable regulatory requirements. Degree of expected reductions There is insufficient post -excavation data following source removal to assess the time for the groundwater to achieve standards by MNA. After the five year effectiveness monitoring period, the model may be refined to accurately predict the time required. Irreversible Treatment None. Natural processes are not anticipated to be reversible based on results of extensive geochemical modeling; however, variations in pH and reduction -oxidation in the geochemical environment can change effectiveness. Type and quantity of residuals remaining Residuals may be present below regulatory standards as the system would be intended to meet standards over time. Residuals removed through source removal have been and will be managed in accordance with applicable regulatory requirements. 02L Standards Predictive modeling indicates compliance to regulatory standards at the compliance boundary would not be achieved in 500 years. This is likely due to conservative assumptions in the models. A robust pump -and -treat system was simulated in the Flow and Transport model (Appendix F). Results of those simulations indicate groundwater extraction and infiltration would not decrease COI concentrations at the compliance boundary faster than what the MNA simulations predict. In fact, the pump -and -treat simulation for selenium indiated concentrations would decrease to less than the 02L standard quicker under natural attenuation. These results are due to the limited post -excavation dataset and the lack of monitoring wells downgradient of the compliance boundary. Insufficient land surface is available to install wells beyond the compliance boundary. The models used conservative assumptions to predict COI concentrations in groundwater beneath the cooling pond. At the time of the CAP Update preparation, only three quarters of post excavation data were available (September & December 2019, March 2020). No post - excavation data related to the FPA is available. There is insufficient post -excavation data available to accurately predict future COI concentrations in grouindwater beyond the compliance boundary. After the five year monitoring period, the models can be refined to accurately predict the time required to reach compliance with regulatory standards. The groundwater system is beginning to reach equlibrium. The geochemical and MNA evaluations identified multiple areas where natural attenuation has already occured. Recent groundwater sampling results indicate source removal is already providing the chemical environment necessary for attenuation. Groundwater sampling results over the past year demonstrate that while the pH is remaining relatively stable within each flow zone, there is a notable increase in the EH of groundwater. This increase in EH might lead to the oxidation of Fe(II) to Fe(III) and potentially the precipitation of ferrihydrite, which would provide additional sorption sites for COI attenuation. It appears the system is naturally approaching elevated EH values. Though not confirmed, the increased EH might be due to the large flux of infiltrating rainwater after excavation. These observations can be confirmed with the proposed five-year post -excavation EMP. Natural attenuation is occurring in the areas northwest of the 1984 ash basin, southeast of the 1971 ash basin and FPA, off -Site near SMW- 01C, and downgradient of the FADA within the FCPA. Boron and arsenic concentrations in wells on the west side of the ash basins are also showing decreasing trends in some areas. COI concentrations are anticipated to naturally attenuate with time as the groundwater system reaches equilibrium after excavation. Prepared by: GTC Checked by: Page 9 of 10 I Remediation Alternatives I Remediation Alternative 2 Source Control by Excavation, Monitored Natural Attenuation with a Restricted Groundwater Use Designation of the Former Coal Pile Area, and a 5 year EMP review to ru E Remediation Alternative 2 relies on, source excavation, natural d attenuation mechanisms to reduce COI concentrations over time to meet corrective action goals, and a 5 year EMP period. In addition to these methods for reducing COI concentrations in groundwater, institutional controls will also be used to prevent receptor exposure The institutional control of a Restricted Groundwater Use Designation of the Source Area 2 areas not covered by the ash basins compliance boundary would further protect potential groundwater users. Notes: CCR - coal combustion residuals CFR - Code of Federal Regulations COI - constituent of interest CSM - conceptual site model LRB - Lined Retention Basin MINA - monitored natural attenuation NCAC - North Carolina Administrative Code NCDEQ - North Carolina Department of Environmental Quality NPDES - National Pollution Discharge Elimination System NPV - net present value O&M - operation and maintenance UIC - Underground Injection Control USEPA - U.S. Environmental Protection Agency APPENDIX O REMEDIATION ALTERNATIVES SUMMARY - SOURCE AREA 2 CORRECTIVE ACTION PLAN UPDATE L.V. SUTTON ENERGY COMPLEX DUKE ENERGY PROGRESS, LLC, WILMINGTON, NC Costs to Implement Remedial Alternative 2 Capital Costs $259,000 Operations, Maintenance, and Monitoring $198,000 Costs Total Life Cycle Costs $415,000 The cost estimate was developed to reflect the cost of implementing Remedial Alternative 2 for Source Areas 1 and 2. Costs to implement RA 2 would be based on include the labor and materials to monitor and maintain appropriate wells and continue operation of the extraction system. Life cycle costs are determined using a Net Present Value (NPV) of expenditures for initial Capital costs and annual 0&M expenses for the duration of the remedy. A Discount Rate of 5% assumed in developing the cost estimate. Page 10 of 10