HomeMy WebLinkAboutNCG030251_DMR_20200227 February 27, 2020
Division of Water Quality
1617 Mail Service Center
Raleigh,NC 27699
RE: Semi-Annual Stormwater Discharge Monitoring Report
Certificate of Coverage Number NCG030251 RECEIVED
Watts Water Technologies
100 Watts Rd. MAR X 0 Z020
Spindale,NC 28160 CENTRAL FILES
DWR SECTION
To Whom It May Concern:
Due to the 2nd 2019 stormwater analytical results, in which the copper result indicated the second
consecutive exceedance of the permitted benchmark, this exceedance triggered a Tier Two
response per the stormwater permit and translated to monthly monitoring being required until
three consecutive results are below the benchmark values or within the benchmark range. In
accordance with the North Carolina Department of Environment and Natural Resources(NC
DENR) stormwater discharge permit, ARM Environmental Services, Inc. collected the second
Tier Two stormwater samples at the referenced facility on January 24, 2020 as a result
The Stormwater Discharge Monitoring Report(SDO), which also shows the analytical results for
the outfall is attached. Please contact Tiffany Crosby, Sr. EHS Engineer via phone (910) 865-
6235 or email tiffanv.crosby@wattswater.com with any questions.
Sincerely,
Brad Bowen
Operations Manager
Stormwater Discharge Monitoring Report
for North Carolina Division of Energy, Mineral and_ Land Resources General Permit No. NCG030000
Date submitted C€LiI c c. , i )—(.2--L.
CERTIFICATE O COVERAGE NO. NCG03'3 2
SAMPLE COLLECTION YEAR c:2,J
.. SAMPLE PERIOD 0 Jan-June ❑July-Dec
FACILITY I l�ME �,�C`���s -}�1 r7 ��� �'c (� or 0 Monthly 1) (month)
COUNTY �e-a,�a,= a��. ,� � r _�� � r DISCHARGING TO CLASS I IORW �HQW"' I Trout �PNA
PERSON COLLE ING SAMPLES % ' 41'f"i. (' _ (x� f
LABORATORY , ,.\4,,t!`l\'',r0-4442 Lab Cert.# 3 29 I Zero-flow I 'Water Supply I ISA
Comments on sampletollection or analysis: I lOther
PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 -*
Part A:Stormwater Benchmarks and Monitoring Results
I I No discharge this period?2
Non-Polar O&G/ Total Toxic
Date Sample 24-hour rainfall Total Suspended Solids pH, Total Copper Total Lead Total Zinc Total Petroleum
Outfall No. Collected' amount, p Standard units Organics'
Hydrocarbons
(mo/dd/yr) Inches'
Benchmarks _ - 100 mg/L or 50 mg/L4 6.0—9.0 0.010 mg/I 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L
Parameter Cade - 46529 C0530 00400 01119 01051 01094 00552 78141
' Monthly sampling(instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
?For sampling periods with no discharge at any single outfall,you must still submit this discharge monitoring report with a checkmark here.
'The total precipitation must be recorded using data from an on-site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
4 See General Permit, Section B,Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies.
'Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals,or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample(for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor
manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date:11/1/2018-05/31/2021 SWU-245,last revised 11/1/2018
Page 1 of 3
Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify,and the requirement for TTO monitoring
may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General
Permit. For those facilities electing to employ the TTO monitoring waiver,the discharger shall sign the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics
(TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the
solvent management plan included in the Stormwater Pollution Prevention Plan."
Name(Print name)
Title(Print title)
Signature Date
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non-detect, ND, or other similar non-numerical
format. When results are below the applicable limits,they must be reported in the format, "<XX mg/I",where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
No discharge this period?2
Date Sample Collected' 24-hour rainfall amount, New Motor Oil or Non-Polar O&G/Total Total Suspended
Outfall No. (mo/dd/yr) Inches' Hydraulic Oil Usage Petroleum Hydrocarbons Solids
Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/L4
Parameter Code - 46529 NCOIL 00552 C0530
Footnotes from Part A also apply to Part B
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
Permit Date:11/1/2018-05/31/2021 SWU-245,last revised 11/1/2018
Page 2 of 3
FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ❑NO ❑
IF YES,HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE? YES NO❑
REGIONAL OFFICE CONTACT NAME:
Mail an original copy of this DMR, including all"No Discharge"reports, within 30 days of receipt of the lab results(or at end of monitoring period in the
case of"No Discharge"reports)to:
Division of Water Quality
Attn:DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify,under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or
those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true,accurate,and complete. I
am aware that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
7/.2,
Signature of Permittee Da e
Permit Date:11/1/2018-05/31/2021 SWU-245,last revised 11/1/2018
Page 3 of 3
I C.
Environmental
Quality
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form,please visit https://deq.nc.gov/abouUdivisions/energy-mineral-land-resources/
npdes-stormwater-gps
Permit No.: N/Ck/OC3 /0/v/a/O/ or Certificate of Coverage No.: N/C/G/C)/.3/0/2/6///
Facility Name: L (tJ,K14-- "Ti i t ! i le -
County: t1 Phone No. 0 C 0 — j S-- LT '\_"
Inspector: e C if,i )
Date of Inspection: // _q/ .c. 2-Z)
Time of Inspection: /0> . I S'
Total Event Precipitation(inches): a), '/
All permits require qualitative monitoring to be performed during a"measurable storm event."
A"measurable storm event"is a storm event that results in an actual discharge from the permitted site
outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm
interval does not apply if the permittee is able to document that a shorter interval is representative for
local storm events during the sampling period,and the permittee obtains approval from the local DEMLR
Regional Office.
By this ' ature,I certify that this report is accurate and complete to the best of my knowledge:
//9,p6Z,4_____77444/t t
//LA V'ers (detli-ck, te- -4..t.e4 1
(Signature of Permittee or Designee)
1. Outfall Description: 4
Outfall No. 33 --- Structure(pipe,ditch,etc.):p,pe,
Receivi }Strea C *I k) eks c 14/;64-es /41 /} Q
De cube the ndustrial activities that occur within the outfall drainage area: •a t ;
,-a l i of C 1-1:)0+ - — l nt fkrvi o vs Sc (- 67. r �F ►- s ��.s r.�
Page 1 of 2
SWU-242.Last modified 06/O1/2018
2. Color: Describe the color of the dischar a using basic colors(red,brown,blue,etc.)and tint
(light,medium, dark)as descriptors: 1.-.< 7-t �-�/�,
3. Odor: Describe any distinct odors that the discharge may have(i.e., smells strongly of oil,weak
chlorine odor,etc.):
4. Clarity: Choose the number which best describes the clarity of the discharge,where 1 is clear
and 5 is very cloudy:
C-1) 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge,where 1 is no solids and 5 is the surface covered with floating solids:
7-D 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
71) 2 3 4 5
7. Is there any foam in the stormwater discharge? 0 Yes S No.
8. Is there an oil sheen in the stormwater discharge? °Yes S No.
9. Is there evidence of erosion or deposition at the outfall? 0 Yes a No.
10. Other Obvious Indicators of Stormwater Pollution:
List and describe
Note: Low clarity,high solids, and/or the presence of foam,oil sheen,or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242,Last modified 06,01/2018
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
ARM Environmental Services, Inc.
11164 Downs Road
Pineville, NC 28134
Attention: Tim McCorkle
Project Name: Watts Water Spindale
Lot Number:VA27042
Date Cornpleted:02/06/2020
Az> ,,t,4--- C"--
02/06/2020 4:40 PM
Approved and released by:
Lab Director- Greenville: Lucas Odom
4Se ,CCAE"1, s
a
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced,except in its entirety,without the written approval of Shealy Environmental Services, Inc.
Shealy Environmental Services.Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab com
Page 1 of II
SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No: 5639
Case Narrative
ARM Environmental Services, Inc.
Lot Number: VA27042
This Report of Analysis contains the analytical result(s)for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality
Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy policies. Any
exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or
discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the
cover page.
TSS
VA27042-001 yielded low residual mass. Because the sample was consumed, it will not be re-analyzed
and results will be uploaded.
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia.SC 29172(803)791-9700 Fax(803)791-9111 www.shealytab.com
Page 2 of 11
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
ARM Environmental Services, Inc.
Lot Number: VA27042
Sample Number Sample ID Matrix Date Sampled Date Received
001 002 Aqueous 01/24/2020 1015 01/27/2020
(1 sample)
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 3 of 11
SHEALY ENVIRONMENTAL SERVICES, INC.
Detection Summary
ARM Environmental Services, Inc.
Lot Number: VA27042
Sample Sample ID Matrix Parameter Method Result Q Units Page
001 002 Aqueous Zinc 200.8 23 ug/L 8
(1 detection)
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 4 of L 1
Client:ARM Environmental Services,Inc. Laboratory ID:VA27042-001
Description:002 Matrix:Aqueous
Date Sampled:01/24/2020 1015
Date Received 01127/2020
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (TSS)SM 2540D-2011 1 01/29/2020 1900 MOM 43279
1 (SGT-HEM(n)16648 1 02/05/2020 1708 SMA 43992
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
TSS SM 2540D- ND 1.8 mg/L 1
SGT-HEM(non-polar material) 16648 ND 5.0 mgiL 1
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 624.1 624.1 1 01/29/20201101 TML 43216
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acrolein 107-02-8 624.1 ND 5.0 ug/L 1
Acrylonitrile 107-13-1 624.1 ND 5.0 ug/L 1
Benzene 71-43-2 624.1 ND 1.0 ug/L 1
Bromodichloromethane 75-27-4 624.1 ND 1.0 ug/L 1
Bromoform 75-25-2 624.1 ND 1.0 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 624.1 ND 2.0 ug/L 1
Carbon tetrachloride 56-23-5 624.1 ND 1.0 ug/L 1
Chlorobenzene 108-90-7 624.1 ND 1.0 ug/L 1
Chloroethane 75-00-3 624.1 ND 2.0 ug/L 1
2-Chloroethylvinylether 110-75-8 624.1 ND 5.0 ug/L 1
Chloroform 67-66-3 624.1 ND 1.0 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 624.1 ND 2.0 ug/L 1
Dibromochloromethane 124-48-1 624.1 ND 1.0 ug/L 1
1,2-Dichlorobenzene 95-50-1 624.1 ND 1.0 ug/L 1
1,3-Dichlorobenzene 541-73-1 624.1 ND 1.0 ug/L 1
1,4-Dichlorobenzene 106-46-7 624.1 ND 1.0 ug/L 1
Dichlorodifluoromethane 75-71-8 624.1 ND 2.0 ug/L 1
1,1-Dichloroethane 75-34-3 624.1 ND 1.0 ug/L 1
1,2-Dichloroethane 107-06-2 624.1 ND 1.0 ug/L 1
1,1-Dichloroethene 75-35-4 624.1 ND 1.0 ug/L 1
cis-1,2-Dichloroethene 156-59-2 624.1 ND 1.0 ug/L 1
trans-1,2-Dichloroethene 156-60-5 624.1 ND 1.0 ug/L 1
1,2-Dichloropropane 78-87-5 624.1 ND 1.0 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 624.1 ND 1.0 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 624.1 ND 1.0 ug/L 1
Ethylbenzene 100-41-4 624.1 ND 1.0 ug/L 1
Methylene chloride 75-09-2 624.1 ND 1.0 ug/L 1
1,1,2.2-Tetrachloroethane 79-34-5 624.1 ND 1.0 ug/L 1
Tetrachloroethene 127-18-4 624.1 ND 1.0 ug/L 1
Toluene 108-88-3 624.1 ND 1.0 ug/L 1
LOQ=Limit of Quantitation 8=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
Shealy Environmental Services.Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 5 of 1 1
Client:ARM Environmental Services,Inc. Laboratory ID:VA27042-001
Description:002 Matrix:Aqueous
Date Sampled:01/2412020 1015
Date Received:01/27/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 624.1 624.1 1 01/29/20201101 TML 43216
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
1,2,4-Trichlorobenzene 120-82-1 624.1 ND 1.0 ug/L 1
1,1,1-Trichloroethane 71-55-6 624.1 ND 1.0 ug/L 1
1,1,2-Trichloroethane 79-00-5 624.1 ND 1.0 ug/L 1
Trichloroethene 79-01-6 624.1 ND 1.0 ug/L 1
Trichlorofluoromethane 75-69-4 624.1 ND 1.0 ug/L 1
Vinyl chloride 75-01-4 624.1 ND 1.0 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
Bromofluorobenzene 102 70-130
1,2-Dichloroethane-d4 101 70-130
Toluene-d8 103 70-130
Semivolatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 625.1 625.1 1 02/04/2020 1943 JCG 01/29/2020 1543 43252
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acenaphthene 83-32-9 625.1 ND 1.6 ug/L 1
Acenaphthylene 208-96-8 625.1 ND 1.6 ug/L 1
Anthracene 120-12-7 625.1 ND 1.6 ug/L 1
Benzidine 92-87-5 625.1 ND 8.0 ug/L 1
Benzo(a)anthracene 56-55-3 625.1 ND 1.6 ug/L 1
Benzo(a)pyrene 50-32-8 625.1 ND 1.6 ug/L 1
Benzo(b)fluoranthene 205-99-2 625.1 ND 1.6 ug/L 1
Benzo(g,h,i)perylene 191-24-2 625.1 ND 1.6 ug/L 1
Benzo(k)fluoranthene 207-08-9 625.1 ND 1.6 ug/L 1
4-Bromophenyl phenyl ether 101-55-3 625.1 ND 1.6 ug/L 1
Butyl benzyl phthalate 85-68-7 625.1 ND 1.6 ug/L 1
bis(2-Chloro-1-methylethyl)ether 108-60-1 625.1 ND 1.6 ug/L 1
4-Chloro-3-methyl phenol 59-50-7 625.1 ND 1.6 ug/L 1
bis(2-Chloroethoxy)methane 111-91-1 625.1 ND 1.6 ug/L 1
bis(2-Chloroethyl)ether 111-44-4 625.1 ND 1.6 ug/L 1
2-Chloronaphthalene 91-58-7 625.1 ND 1.6 ug/L 1
2-Chlorophenol 95-57-8 625.1 ND 1.6 ug/L 1
4-Chlorophenyl phenyl ether 7005-72-3 625.1 ND 1.6 ug/L 1
Chrysene 218-01-9 625.1 ND 1.6 ug/L 1
Dibenzo(a,h)anthracene 53-70-3 625.1 ND 1.6 ug/L 1
3,3'-Dichlorobenzidine 91-94-1 625.1 ND 8.0 ug/L 1
2,4-Dichlorophenol 120-83-2 625.1 ND 1.6 ug/L 1
LOQ=Limit of Quantitatlon B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 6 of 11
Client:ARM Environmental Services,Inc. Laboratory ID:VA27042-001
Description:002 Matrix: Aqueous
Date Sampled:01/24/2020 1015
Date Received:01/27/2020
Semivolatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 625.1 625.1 1 02/04/2020 1943 JCG 01/29/2020 1543 43252
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Diethylphthalate 84-66-2 625.1 ND 1.6 ug/L 1
Dimethyl phthalate 131-11-3 625.1 ND 1.6 ug/L 1
2,4-Dimethylphenol 105-67-9 625.1 ND 1.6 ugiL 1
Di-n-butyl phthalate 84-74-2 625.1 ND 1.6 ugiL 1
4,6-Dinitro-2-methylphenol 534-52-1 625.1 ND 8.0 ugiL 1
2,4-Dinitrophenol 51-28-5 625.1 ND 8.0 ug/L 1
2,4-Dinitrotoluene 121-14-2 625.1 ND 3.2 ug/L 1
2,6-Dinitrotoluene 606-20-2 625.1 ND 3.2 ugiL 1
Di-n-octylphthalate 117-84-0 625.1 ND 1.6 ug/L 1
1,2-Diphenylhydrazine(as azobenzene) 103-33-3 625.1 ND 1.6 ug/L 1
bis(2-Ethylhexyl)phthalate 117-81-7 625.1 ND 8.0 ug/L 1
Fluoranthene 206-44-0 625.1 ND 1.6 ug/L 1
Fluorene 86-73-7 625.1 ND 1.6 ug/L 1
Hexachlorobenzene 118-74-1 625.1 ND 1.6 ug/L 1
Hexachlorobutadiene 87-68-3 625.1 ND 1.6 ug/L 1
Hexachlorocyclopentadiene 77-47-4 625.1 ND 8.0 ug/L 1
Hexachloroethane 67-72-1 625.1 ND 1.6 ug/L 1
Indeno(1,2,3-c,d)pyrene 193-39-5 625.1 ND 1.6 ug/L 1
Isophorone 78-59-1 625.1 ND 1.6 ug/L 1
Naphthalene 91-20-3 625.1 ND 1.6 ug/L 1
Nitrobenzene 98-95-3 625.1 ND 1.6 ug/L 1
2-Nitrophenol 88-75-5 625.1 ND 3.2 ug/L 1
4-Nitrophenol 100-02-7 625.1 ND 8.0 ug/L 1
N-Nitrosodimethylamine 62-75-9 625.1 ND 1.6 ug/L 1
N-Nitrosodi-n-propylamine 621-64-7 625.1 ND 1.6 ug/L 1
N-Nitrosodiphenylamine(Diphenylamine) 86-30-6 625.1 ND 1.6 ug/L 1
Pentachlorophenol 87-86-5 625.1 ND 8.0 ug/L 1
Phenanthrene 85-01-8 625.1 ND 1.6 ug/L 1
Phenol 108-95-2 625.1 ND 1.6 ug/L 1
Pyrene 129-00-0 625.1 ND 1.6 ug/L 1
2,4,6-Trichlorophenol 88-06-2 625.1 ND 1.6 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
2-Fluorobiphenyl 88 37-129
2-Fluorophenol 89 24-127
Nitrobenzene-d5 93 38-127
Phenol-d5 108 28-128
Terphenyl-d14 110 10-148
2,4.6-Tribromophenol 99 41-144
LOQ=Limit of Quantitatlon 8=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPO between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 7 of 11
Client:ARM Environmental Services,Inc. Laboratory ID:VA27042-001
Description:002 Matrix:Aqueous
Date Sampled:01/24/2020 1015
Date Received:01/27/2020
Organochlorine Pesticides and PCBs
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 608.3 3665A 608.3 1 01/30/2020 1328 DAL1 01/28/2020 1300 43081
2 608.3 3665A 608.3 1 01/30/2020 2359 DAL1 01/28/2020 1300 43081
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aldrin 309-00-2 608.3 ND 0.040 ugrl 1
Aroclor 1016 12674-11-2 608.3 ND 0.40 ug/L 2
Aroclor 1221 11104-28-2 608.3 ND 0.40 ug/L 2
Aroclor 1232 11141-16-5 608.3 ND 0.40 ug/L 2
Aroclor 1242 53469-21-9 608.3 ND 0.40 ug/L 2
Aroclor 1248 12672-29-6 608.3 ND 0.40 ug/L 2
Aroclor 1254 11097-69-1 608.3 ND 0.40 ug/L 2
Aroclor 1260 11096-82-5 608.3 ND 0.40 ug/L 2
gamma-BHC(Lindane) 58-89-9 608.3 ND 0.040 ug/L 1
alpha-BHC 319-84-6 608.3 ND 0.040 ug/L 1
beta-BHC 319-85-7 608.3 ND 0.040 ug/L 1
delta-BHC 319-86-8 608.3 ND 0.040 ug/L 1
Chlordane 57-74-9 608.3 ND 0.40 ug/L 1
4.4'-DDD 72-54-8 608.3 ND 0.040 ug/L 1
4,4'-DDE 72-55-9 608.3 ND 0.040 ug/L 1
4,4'-DDT 50-29-3 608.3 ND 0.040 ug/L 1
Dieldrin 60-57-1 608.3 ND 0.040 ug/L 1
Endosulfan I 959-98-8 608.3 ND 0.040 ug/L 1
Endosulfan II 33213-65-9 608.3 ND 0.040 ug/L 1
Endosulfan sulfate 1031-07-8 608.3 ND 0.040 ug/L 1
Endrin 72-20-8 608.3 ND 0.040 ug/L 1
Endrin aldehyde 7421-93-4 608.3 ND 0.040 ug/L 1
Heptachlor 76-44-8 608.3 ND 0.040 ug/L 1
Heptachlor epoxide 1024-57-3 608.3 ND 0.040 ug/L 1
Toxaphene 8001-35-2 608.3 ND 0.40 ug/L 1
Run 1 Acceptance Run 2 Acceptance
Surrogate Q % Recovery Limits Q %Recovery Limits
Decachlorobiphenyl 43 20-131 39 20-131
Tetrachloro-m-xylene 69 30-132 91 30-132
ICP-MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 200.2 200.8 1 02/03/2020 1741 BNW 01/29/2020 1644 43165
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Copper 7440-50-8 200.8 ND 10 ug/L 1
Lead 7439-92-1 200.8 ND 2.0 ug/L 1
Zinc 7440-66-6 200.8 23 10 ug/L 1
LOQ=Limit of Quantitation 8=Detected in the method blank E=Quantilation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of cntena P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 8 of II
Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 9 of 11
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a T r/R'N"N SHEALY ENVIRONMENTAL SERVICES, INC.
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. a SHEALY Chain of Custody Record foe VanLego PnifiL Drfre•Wes:CoWirt:a,SC f>91,ik Number I 023 3 9
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sit.,ly Env,trIrrevi1S:ivicArs.,ac. Net 1 of.
0o.!MUNI:TM:et.VW:II 111:C.14 a/CPV:Inerr it.,2:211$
Sample Receipt Checklist (SRC)
Clic"- ARM Cooler In eted by;datc.;4.e'c, ., 01;274202C Lot#: VA?7,f,42
lycfiz.s of ri.s.ceiarIntc10 Client 0 11PS El Fe4E A. Fi but=
ci Yrs 1-f-A Nu I.1V-::te custody seals present on the ctiolztl
, ri YL:s 17 No rij NA 2.!roust-I:kilo seals wen:present. theywere cy intact and_A-woken'?
)01 Strip:D: 19-2351 Chlorine Strap ID: NA Tested b,. •EA,:c=i
• igirm:-..emperatute upon receipt f Deriv-51(Con ected)temperature upon receipt cASo.“1 .•iiari-i'lir. 11 i :.,.A
2.a t 2,8 "c NA ;NA •Jc NA ,NA '"C NA iNA_0(t.
Method:0 Temperature Blark El Agitiiast Boir.cs IR Gun irk_ 6 lit(r.:n Correaion I-acto:.
o-trod of coolant iZi Wet lee 0 lee Packs 0 pre Ice El None
- _
3. If temperature of any ccoler exoeetied 6.0C.was Pro.;ezt Mariager,NOtilled7
i.._ Vei No El co NA
PM wa,Notified lr...:phone./etnail 1 face-to-face(circk one).
Ll Vc 3 o.'„ 0 NA 4. Is the commercial oourives packinz siip attached al lf..i form':
.., .,
0 No ,5. Were pcoper custody proctsiurc.s.(ise...inquistiedireceived)followed?
Yes II No k.'i %lien:...arrplz Ds Iisici.!Lin the C0f;?
, 7 Y-:,-..c... 0 No 7 Were sampIc It) listed on all satriph:containers?
Z Yes—0 NO111.1111S. War c:ollectio6 dale&tone listed on the°Cie?
TA Yes C No 9. Ww.collection date&two listal on all sample containers?
0 'es 0 N 10.Did all container label infoniultion(11);;lair,time)agz.ee with the COC?
0 Yes. 0No 11.Were tests to le performed l',•;!e(1.on the COC?
1 0
12. Did all samples arrive in the proper containers for each test and/or in good condition 0 YCA No
(unbroken,tits of.,etc Y.'
i -
'4 Yes 0 No smut 13.Was acequa sampk volume avai:able?
• Vsr, Z No MN 14. Were all samples re.;eived within 17.the holding Lintz or 48 hour ,Ivhichevt.T:tomes firc''
II Yes 0)4o11111111 IN. Were an Amtples containers missing/excess(circle one)sant , N,Not lived or,COC?..,
El Yes n No DNA
16.For VOA and RSK-17 santpks,wen.bubbles present'---"pea-size"(1.4"or 6mitt in tliamcie:'..
ki
i in any of the VOA vials?
1 rii Yes No micz3 17.Were all DROhnetabditulnent sam ries received at a pH of<29
...._
0 \-,,, Elt-,,, IZ NA III.'Wete al witde sa-npies re‘..eived at a i> 12 and strIfik sami les received at 4 W.,9?
19.' ere c!31)0(.4111e Y14311KNIoyanklef eno11625(4:th5rit*I1A samples Tree of residual
! L)Yes a No 0 NA
chlorine?
,I in MI: 6...1 No 0 NA 10 Were clicat requests(i.e.requested dihrions,ktfif,MSD designations,.etc.
•
correctly transcribed from the COC into the common section in LIMS?
103 !I NU 21. Was ne note itU41:34.7 Lsted or he ;..s.oriLainerlane`?if w 5.4-LO:c., NA 1
---- --
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:S2 mpk Preservation (must he complerecl far any sainplets)inconectly arc.serve:lor with'::tradspaec.)
Sample(s) NA were oxvived incorrectly pn..-..cenzri and were adiusAxl accarclir.g;y
in sample receiving with NA__ rilL of circle one:1.12SO4.1-1N( z,lid.NaOH using SR tr
----- -
nine of preset Vill ion NA . If inure than one prescnial ive is needed,.please note in the comments below.
Stunple(s) N-A _ _ __were received with hubblos>6 mm in diameter.
_
Sarnptest:s) NA _ were received wittilliC 4 0_5 mgiL(L-4-1)k I10):lite wt.rt
:Icljusteti ucixrdingly in sample receiving with sodium thiosullate(Na,S,03)v.ith Shealy ID: NA .
_
SR biutorte Iabels rgiplied by: RMG Date 01127.1,42C,
_. ----
Commentl:
— _
....
Shealy Environmental Services,Inc.
106 Vantage Point Drive West Columbia,SC 29172 (803)791-9700 Fax(803)791-9111 www.shealylab.com
Page 11 of II
Table 1. Stormwater Sampling Results
Stormwater Outfall 2 Benchmark
Parameters Units
Oil And Grease mg/L ND 15
pH s.u. 6.5-field Within 6.0-9.0
Total mg/L ND 100
Suspended
Solids
Copper mg/L ND 0.010
Lead mg/L ND 0.075
Zinc mg/L .023 0.126
Total Toxic mg/L ND; See 1
Organics analytical
Total Rainfall inches 0.42 -
Storm Duration minutes 720 -
Total Flow gallons/ 1.0 -
minute
ND = Not Detected
mg/L = milligrams per liter (parts per million equivalent)
s.u.= standard pH units