NCG030134_DMR_20200403

Thermo Fisher
SCIENTIFIC
RECEIvED
April 3, 2020
APR 2 7 2020
CEN-I W\L FILES
Division of Water Quality DWR SECTION
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RE:Stormwater Analytical Monitoring Results for Thermo Fisher Scientific, LLC
I have attached the analytical monitoring results from stormwater sampling that was collected
on March 23, 2020 at Thermo Fisher Scientific, LLC's four outfalls.
Per our General Storm Water Permit No. NCG03000 requirements of monthly monitoring for
applicable parameters during a storm event, I have sampled each outfall for copper, zinc, pH,
lead, TSS, and Non-Polar Oil/Grease/TPH. Results show that TSS, copper, and zinc were each
above the benchmark values at two of the four outfalls, as noted in Table 3 of the general storm
water permit. All other results were below the benchmark values. We have implemented a Tier
Three response for the site and Thermo Fisher Scientific, LLC has notified the Asheville Regional
Office.Thermo Fisher Scientific, LLC is currently working with an environmental consultant to
help achieve compliance with the benchmark values set forth in the facility's storm water
permit. I have attached the completed Monitoring Report containing the monitoring results
from the four outfalls.
If you have any questions, please feel free to contact me at 828-658-2845.
Jeremy Putnam
Sr. EHS Manager
Attachments: 1

Stormwater Discharge Monitoring Report
for North Carolina Division of Energy, Mineral and Land Resources General Permit No. NCG030000
Date submitted: 04/03/2020
CERTIFICATE OF COVERAGE NO. NCG030134 SAMPLE COLLECTION YEAR
SAMPLE PERIOD _Jan-June July-Dec
FACILITY NAME:Thermo Fisher Scientific(Asheville) LLC Or X Monthly: March
COUNTY: Buncombe DISCHARGING TO CLASS C RIN L_ 1 HQW Xirrout f PNA
PERSON COLLECTING SAMPLES:Jeremy Putnam, EHS nZero-flow fNater Supply DA
LABORATORY: Pace Analytical Lab Cert.# , Other
Comments on sample collection or analysis:
PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 -
Part A: Stormwater Benchmarks and Monitoring Results
1 INo discharge this period?'
Non-Polar O&G/
Date Sample 24-hour rainfall pH, Total Toxic
Outfall No. Collected) amount, Total Suspended Solids Standard units Total Copper Total Lead Total Zinc Total Petroleum 5
Hydrocarbons
(mo/dd/yr) Inches3 Organics
Benchmarks - - 100 mg/L or 50 mg/L4 6.0—9.0 0.010 mg/L 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L
Parameter Code - 46529 C0530 00400 01119 01051 01094 00552 78141
Outfall 1 03/23/2020 0.25 58.7 6.82 0.046 0.0062 0.48 <5 N/A
Outfall 2 03/23/2020 0.25 27.2 6.53 0.0756 <0.005 0.439 <5 N/A
Outfall 3 03/23/2020 0.25 61.1 6.35 <0.005 <0.005 0.0553 <5 N/A
Outfall 4 03/23/2020 0.25 <2.5 6.22 <0.005 <0.005 0.0949 <5 N/A
3 Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
2 For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
3 The total precipitation must be recorded using data from an on-site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
See General Permit, Section B,Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies.
5 Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11;for semiconductor
manufacture use the definition as found in 40 CFR 469.12;for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018
Page 1 of 3

Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO
monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the
General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics(TTO),
I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent
management plan included in the Stormwater Potion Prevertiti n."
J
Name(Print name)'-moo VA--.
1 ACC L-q c
Ili- (Print title)
., --.,,-__. 'e\-k3'))) ).) ))
Signature Date
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non-detect, ND, or other similar non-numerical
format. When results are below the applicable limits,they must be reported in the format, "<XX mg/L",where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
INo discharge this period?2
Outfall No. Date Sample Collected' 24-hour rainfall amount, New Motor Oil or Non-Polar O&G/Total Total Suspended
(mo/dd/yr) Inches' Hydraulic Oil Usage Petroleum Hydrocarbons Solids
Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/L4
Parameter Code - 46529 NCOIL 00552 C0530
Footnotes from Part A also apply to Part B
Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018
Page 2 of 3

FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS.SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL?
YES X NO
IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE?YES NO REGIONAL OFFICE CONTACT NAME: Ms. Laura Herbert
(Asheville Regional Office)
Mail an original copy of this DMR,including all"No Discharge"reports, within 30 days of receipt of the lab results(or at end of monitoring period in the
case of"No Discharge"reports)to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
se persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true, accurate, and complete. I
am a are that there are significant penalties for submitting false information,including the possibility of fines and imprisonment for knowing violations."
o�l0300
Signature of Permittee Date
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised
11/1/2018

Pace Analytical Services,LLC
(AeAnaIicaI Riverside Asheville,NC 2880404
www.pacelabs.com [phone]
April 02, 2020
Mr. Jeremy Putnam
Thermo Electron Corp.
275 Aiken Road
Asheville, NC 28804
RE: Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Dear Mr. Putnam:
Enclosed are the analytical results for sample(s)received by the laboratory on March 23,2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
z - ` REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 13
e'r

Pace Analytical Services,LLC
7PceAnaIyticaI
2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
CERTIFICATIONS
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100,Huntersville,NC 28078 South Carolina Certification#: 99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 Virginia/VELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville, NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#: E87648 South Carolina Certification#:99030001
Massachusetts Certification#: M-NC030 Virginia/VELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 13

Pace Analytical Services,LLC
(.13(eAnalyticar 2225 Riverside
Asheville,NC 2881k04
1
www.pacelabs.com [phone]
SAMPLE ANALYTE COUNT
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92470593001 1-1,2,3 EPA 1664E WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A
SM 2540D-2011 RED 1 PASI-A
92470593002 2-1,2,3 EPA 1664E WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A
SM 2540D-2011 RED 1 PASI-A
92470593003 3-1,2,3 EPA 1664B WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A
SM 2540D-2011 RED 1 PASI-A
92470593004 4-1,2,3 EPA 1664E WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 SH1 3 PASI-A
SM 2540D-2011 RED 1 PASI-A
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 13

Pace Analytical Services,LLC
//: aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
/ www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Sample: 1-1,2,3 Lab ID: 92470593001 Collected: 03/23/20 12:00 Received: 03/23/20 13:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1664 SGT-HEM,TPH Analytical Method:EPA 1664B
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/25/20 09:48
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper 46.0 ug/L 5.0 1 03/27/20 00:56 03/28/20 00:17 7440-50-8
Lead 6.2 ug/L 5.0 1 03/27/20 00:56 03/28/20 00:17 7439-92-1
Zinc 480 ug/L 10.0 1 03/27/20 00:56 03/28/20 00:17 7440-66-6
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 58.7 mg/L 18.1 1 03/27/20 09:50
Sample: 2-1,2,3 Lab ID: 92470593002 Collected: 03/23/20 12:15 Received: 03/23/20 13:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1664 SGT-HEM,TPH Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/25/20 09:48
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper 75.6 ug/L 5.0 1 03/28/20 00:54 03/29/20 21:35 7440-50-8
Lead ND ug/L 5.0 1 03/28/20 00:54 03/29/20 21:35 7439-92-1
Zinc 439 ug/L 10.0 1 03/28/2000:54 03/29/2021:35 7440-66-6 M1,R1
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 27.2 mg/L 6.7 1 03/27/20 09:50
Sample: 3-1,2,3 Lab ID: 92470593003 Collected: 03/23/20 12:30 Received: 03/23/20 13:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1664 SGT-HEM,TPH Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/25/20 09:48
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper ND ug/L 5.0 1 03/28/20 00:54 04/01/20 15:31 7440-50-8
Lead ND ug/L 5.0 1 03/28/20 00:54 04/01/20 15:31 7439-92-1
Zinc 55.3 ug/L 10.0 1 03/28/20 00:54 04/01/20 15:31 7440-66-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 13

Pace Analytical Services,LLC
/fi
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.cam [phone]
ANALYTICAL RESULTS
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Sample: 3-1,2,3 Lab ID: 92470593003 Collected: 03/23/20 12:30 Received: 03/23/20 13:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 61.1 mg/L 13.9 1 03/27/20 09:51
Sample: 4-1,2,3 Lab ID: 92470593004 Collected: 03/23/20 12:45 Received: 03/23/20 13:05 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1664 SGT-HEM,TPH Analytical Method: EPA 1664B
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 03/25/20 09:48
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper ND ug/L 5.0 1 03/28/20 00:54 04/01/20 15:34 7440-50-8
Lead ND ug/L 5.0 1 03/28/20 00:54 04/01/20 15:34 7439-92-1
Zinc 94.9 ug/L 10.0 1 03/28/20 00:54 04/01/20 15:34 7440-66-6
2540D Total Suspended Solids Analytical Method: SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids ND mg/L 2.5 1 03/27/20 09:51
REPORT OF LABORATORY ANALYSIS
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Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 13

Pace Analytical Services,LLC
2225Dr.
aceAnalytical c Asheville,RiversideNC 28 04
NC 28804
www.pacelabs.com [phone]
i
QUALITY CONTROL DATA
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
QC Batch: 532387 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM,TPH
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92470593001,92470593002,92470593003,92470593004
METHOD BLANK: 2841960 Matrix: Water
Associated Lab Samples: 92470593001,92470593002,92470593003,92470593004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons mg/L ND 5.0 03/25/20 09:48
LABORATORY CONTROL SAMPLE: 2841961
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L 20 16.8 84 64-132
MATRIX SPIKE SAMPLE: 2841962
92470773001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L ND 20 21.5 104 64-132
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 13

Pace Analytical Services,LLC
f„„„IeAnalytical 2225 Rivers28
Asheville,NC 2880404
www.pacelabs.cont [phone]
1 r
QUALITY CONTROL DATA
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
QC Batch: 532851 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92470593001
METHOD BLANK: 2844231 Matrix: Water
Associated Lab Samples: 92470593001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Copper ug/L ND 5.0 03/27/20 23:42
Lead ug/L ND 5.0 03/29/20 15:47
Zinc ug/L ND 10.0 03/29/20 15:47
LABORATORY CONTROL SAMPLE: 2844232
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Copper ug/L 500 490 98 85-115
Lead ug/L 500 499 100 85-115
Zinc ug/L 500 508 102 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2844233 2844234
MS MSD
92470472001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 14.9 500 500 547 548 106 107 70-130 0
Lead ug/L ND 500 500 493 500 98 99 70-130 1
Zinc ug/L 126 500 500 632 638 101 102 70-130 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2844235 2844236
MS MSD
92470915001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 6.8 500 500 541 546 107 108 70-130 1
Lead ug/L ND 500 500 511 515 102 103 70-130 1
Zinc ug/L ND 500 500 520 548 103 108 70-130 5
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 13

Pace Analytical Services,LLC
2225Dr.
aceAnalytical c Asheville,RiversideNC28 04
NC 28804
f www.pacelabs.com [phone]
I
QUALITY CONTROL DATA
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
QC Batch: 533073 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92470593002,92470593003,92470593004
METHOD BLANK: 2845834 Matrix: Water
Associated Lab Samples: 92470593002,92470593003,92470593004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Copper ug/L ND 5.0 03/29/20 21:25
Lead ug/L ND 5.0 03/29/20 21:25
Zinc ug/L ND 10.0 03/29/20 21:25
LABORATORY CONTROL SAMPLE: 2845835
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Copper ug/L 500 504 101 85-115
Lead ug/L 500 502 100 85-115
Zinc ug/L 500 494 99 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2845836 2845837
MS MSD
92470593002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 75.6 500 500 606 660 106 117 70-130 8
Lead ug/L ND 500 500 542 502 108 100 70-130 8
Zinc ug/L 439 500 500 1100 881 133 88 70-130 22 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2845838 2845839
MS MSD
92470731003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 54.1 500 500 597 601 109 109 70-130 1
Lead ug/L ND 500 500 495 494 99 99 70-130 0
Zinc ug/L 12.8 500 500 504 497 98 97 70-130 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 13

Pace Analytical Services,LLC
,fi, aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
QC Batch: 532831 Analysis Method: SM 2540D-2011
QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92470593001,92470593002, 92470593003,92470593004
METHOD BLANK: 2844156 Matrix: Water
Associated Lab Samples: 92470593001,92470593002,92470593003,92470593004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 03/27/20 09:45
LABORATORY CONTROL SAMPLE: 2844157
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Suspended Solids mg/L 250 240 96 90-110
SAMPLE DUPLICATE: 2844158
92470863001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 269 180 39 D6
SAMPLE DUPLICATE: 2844159
92470914003 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 1700 1420 18
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 13

Pace Analytical Services,LLC
Analytical NC 2225 Riverside
76:441Ce Asheville,NC 28804
t www.pacelabs.com [phone]
QUALIFIERS
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
DEFINITIONS
DF-Dilution Factor,if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 13

Pace Analytical Services,LLC
2225 Riverside Dr.
AeAnalytical Asheville,NC 28804
www.pacelabs.eom [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MARCH 2020 SW 3-23-20
Pace Project No.: 92470593
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92470593001 1-1,2,3 EPA 1664B 532387
92470593002 2-1,2,3 EPA 1664E 532387
92470593003 3-1,2,3 EPA 1664E 532387
92470593004 4-1,2,3 EPA 1664B 532387
92470593001 1-1,2,3 EPA 200.7 Rev 4.4 1994 532851 EPA 200.7 Rev 4.4 1994 532870
92470593002 2-1,2,3 EPA 200.7 Rev 4.4 1994 533073 EPA 200.7 Rev 4.4 1994 533094
92470593003 3-1,2,3 EPA 200.7 Rev 4.4 1994 533073 EPA 200.7 Rev 4.4 1994 533094
92470593004 4-1,2,3 EPA 200.7 Rev 4.4 1994 533073 EPA 200.7 Rev 4.4 1994 533094
92470593001 1-1,2,3 SM 2540D-2011 • 532831
92470593002 2-1,2,3 SM 2540D-2011 532831
92470593003 3-1,2,3 SM 2540D-2011 532831
92470593004 4-1,2,3 SM 2540D-2011 532831
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:04/02/2020 04:14 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 13

WO# : 92470593
, 150 CHAIN-OF-CUSTODY Analytical Request Document <order Number or co
Pace Analytical N
Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields 111111 I III I I II 111111 Ill 7r;)
Cc mpany: Billing Information: 92470593 c.
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-1\10-01n 4- kV" .5.:4-42Ati—.fic., A-660-v\IA,rS ftej--A,-- 0_
Addres: Container Preservative Type" Lao ProteLt via veer:
K
(VIe3.... Rxe.....c 5 k k kA I
Rerrt To: Email To: servative Types:(1)nitric acid,(2)sulfuric acid,(3)hydrochloric acid,(4)sodium hydroxide,(5)zinc acetate,
e ev- wt.t.i evt trio,AA k ei-eiev...1 ,p;,.4-Aliscwv,..etilver151.--il,Sher,4-1.-',vx` *G)rUrterithanol,(7),ociiiiin bisulfate,(8)sodium thiesuifate,(9)hexane,(A)ascorbic acid,(B)ammonium sulfate,
C py To: .--f Slie CollectiOtInfo/Address: , (C)ammonium hydroxide,(D)TSP,(U)thtpreserved,(0)Other_......__ _....
ll le-r*-ivN -... " Analyses Lab Profile/Line:
CAstorner Project Name/Number: State: County/City: Time Zone Collected: Lab Sample Receipt Checklist:
Maraft 2 "C>2 -jc 9/4 /NJ c....11424,c1 l.)Z., [ 1 PT I 1 MT f I CT [ LT
It Custody Seals Present/Intact Y tl NA
P tone:eVe.4,-,s el-2_54 c Site/Facility ID Si: Compliance Monitoring? A Custody Signatures Present Y NA
1 Erna& I47es I (No (----_Z. ...2.fr, ..L.. Collector Signature Present N NA
I . if? Bottles. intact Ccillected By(print): Purchase Order 0: OW PWS ID II: Lt A; .7' Correct Bottles NNA
4+t Ns_P,
-tr• '''''''
- ire*V4..) PvAliAckork Quote II; DW Location Code: — ::> ,' Sufent Volume N NA
c, 1 ,,,,,7 Samples Received on ice 14 NA
'Coll cted By(signature): 1 ur naround Date Required: Immediately Packed on Ice: : v- '*) <5 - a
vq.,
,,..J ''AO VOA - Headspce Acceptable Y N 1• c1,1,
...,—...„
NE9Yes I I No rt) C41... 44"---,,, USDA Regulated Soils Y N ;OA
Samples in Holding Time )1/14 NA
Sample Disposal: Rush: Field Filtered(if applicable): i,......, Residual Chlorine Present Y N przf
(Dispose as appropriate I I Retail n 1 1 Same Day [ j Next Day I (Yes I I No t. ,_,-, 7 , , Cl, Strips: -
I 'Archive: 1 1 2 Day I ]3 Day [ 14 Day j I 5 Day ...e .;\**
*. ..) .1-- s,,,, Sample pH Acceptable i 2?-t1 NA
[ 1 Hold: (Expedite Charges Apply) Analysis: ....2,...) ,-z I, \::.„3 ,...„,,. . pulls Strps: _ 2-321.1 Li
Suf ide Present Y N pA/
t---- .— '
'Matrix Codes(Insert in Matrix box below):Drinking Water(DW),Ground Water(OWL Wastewater(WW), Lead Acetate Strips:
Product(P),Soil/Solid(SL),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(0T) .?;!.--4, „ , - ---
''4. .', , -_,) -..- LAB USE ONLY:
Camp/ Collected(or Res t)of 1 . " Lab Sample * / Comments i
Composite End
Customer Sample ID Matrix' Grab Composite Start) CI Cuts ..="'"s '`• ,.,--,
2,4....) ...s '\
Date Time Date Time Z. ••.;, ( ('22i.1*7-b sc
1 -1 t--c-. • G g.k13.3/2:s is,oi,;,• 1 1 —0, I
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k 1
'4 1 '‘ . . . .. ...._
il-'53 1 i. 1. 1, „-.0 0 3
'
„...,, 0 3
• ' i . _ „
.._.........______........... , ----0 0 Li
Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: Vitt Blue Dry None SHORT HOLDS PRESENT(<72 hours): Y i{ N/A Lab Sample Temperature Info:
Packing Material Used: Lab Tracking tr: Temp Blank Regiveir);,.. Y el( NA
2427164 Therm ID)): if 0 6 I
Cooler 1 Temp Upon ReceiP7: ./4",oC
C Radchem sample(s)screened(<500 cpm): Y N /
Samples received via: Cooler 1 Therm Corr,Factor: ;7--oC
- ---. „ --- — ---. IV,
FEDEX UPS Cent Courier Pace Courier
Cooler 1 Corrected Temp: --ri ToC
li'quit)e by/Company:(Signature) Date/Time: Received by/Company:(,Signature) Date/Time: KUL LAB USE ONLY Comments:
.
V.- ''- ;-..,i‘, '
n ),,,tV.L. 311:3K0 II 0 ( Table IR
ilelinqui hed by/C tan, gnature) Date/Time: eceived by/Company:iiii,nature) Date/Time: ctnum:
Template: Trip Blank Received: Y A NA
Prelogin: HCL Me0H TSP Other
Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Conforrnance(s): Page:_
PB: YES / V6 of:
, ..

WO# : 92470593
c CHAIN-OF-CUSTODY Analytical Request Document LAB USE -amber or
PaceAnalytical PM: CDC; Due Date: 04/06/20 M
Chain-of-Custody is a LEGAL DOCUMENT•Complete all relevent fields CLIENT: 93—Thermo N
Company: Billing Information: ta
ii -i k V ;:Ar:' 1'1 e„,
Address '"' S `� Li
t., Container Preservative Type** Lab Project Manager:
2-`' S l k-yea... r! .P 1 i I VI
Report To: y'! Email To: /'' (� ..Preservative Types:(I)nitric acid,(2)sulfuric acid,(3)hydrochloric acid,(A)sodium hydroxide,(S)zinc acetate,
iTeArtVW)
1 L'.' �. Wl.'�'� 'VAS 1O•frie�'f '�'r"4viS) 5 i'vee.•Eo�'t''c (6)methanol(7)sodium bisulfate,(R)sodium thiosutfate,(9)hexane,(Al ascorbic acid,(t3)ammonium sulfate,
Copy To: ite Collection Info/Address: (C)ammonium hydroxide,(0)TSP.(U)ilnpreserved,(0)Other
Analyses Lab Profile/Line:
Customer Project Name/Number: State: County/City: Time Zone Collected: Lab Sample Receipt Checklist:
via i 3 t,i) S lh! 0(i'/ j\--- tnevi ikr„- [ 1 P r I (MT C 1 CT J ET .)
,� custody Seals Present/Intact Y NA
Mope:92,t—i458"-2,,'e Site/Facility ID It: Compliance Monitoring? 1 n Custody Signatures Present Y NA
Email: (pYes I I No 1 Collector Signature Present Y N NA
Collected ByBottles Intact : N NA
(print : Purchase Order fi: OW PWS ID#: 4w ea) Correct Bottles : N NA
Quote th. OW Location Code: `7 Sufficient nt Voleme N NA
I i `�' r Samples Received on Ice Y N NA
ected By'signature): Turnaround Date Required: Immediately Packed on Ice: �^�cy/ ^+.f+ VOA - Ne tdspace Acceptable Y N.245
�^r .%-."" Yes [ j No *- USDA Regulated Soils Y N i�A
rarr�a le_xs i n Holding z ime x N NA
tplc Disposal: Rush: Field Filtered(if applicable]: Residual chlorine i resent: r N tTxsl
( Dispose
e as appropriate I I Return [ (Same Day I I Next Day I (Yes ( I No . N? Cl Strips
[ (2 Day ( )3 Day ( (1 Day [ (5 Day
lj I HoldSample pti Arcep TZTe j7`/ �iP N NA
Analysis: c- .2 +r` � pH Strips 2, 25 i, v
(Expedite Charges Apply) i^' �-�.-. ry Sulfide Present Y N
Matrix Codes(Insert in Matrix box below):Drinking Water(OW),Ground Water(GW),Wastewater(WW), i K .:1Lead Acetate St rips: _ _, __
Product(P),Soil/Solid(St),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) 7 --"1- "� LAB USE ONLY:
t Comp/ Collected(or Res #of c^ W Lab Sample # / Comments:
ustomer Sample ID Matrix Composite End
P Grab Composite Start) CI Ctns w 3J (
Date Time Date Time -'� ""� r V� `,1 3-j,}59
" �- tzr C f F 3 2, I 2-=i, 9 t 1 1 _ _pt.?`i
Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: W Blue Dry None SHORT HOLDS PRESENT(<72 hours): Y 4 N/A Lab Sample Temperature Info:
Packing Material Used: Lab Tracking It: �} ¢ Temp Blank Recei�vedy: Y pd NA
L L1 Therm ID#: , 7 ff vb I
Cooler 1 Temp Upon Receipt:4•.,2,foC
Radchem sample(s)screened(<500 cpm): Y N Samples received Via: Cooler 1 Therm Corr.Factor:i" oC
If"�i FEDEX UPS C Courier Pace Courier Cooler 1 Corrected Temp: 4,2.oC
R 4inq tufted by/Company:(Signature) Date/Time:
� Date/Time t �( Per lived by/Company:(Slpnature) Date/Time:: MTJI.LAB USF.ONLY Comments:
(--\ � ;`, '), I� t// ��� � ( Tableft;
Relinqui had by/Company:(Signature) Date/Time: Rerrived by/Coro any:(Si{,. ature) Date/Time: Template: Trip Blank Received: Y N NA
Prelogi r HCL McOH TSP Other
Relinquished by/Company:(Signature) Date/Time: Received by/Company:{Signature) Date/Time: PM:
Non Confermanre(s): Page:_________
PB: YES / NO of: