NCG030134_DMR_20200506

Stormwater Discharge Monitoring Report
for North Carolina Division of Energy, Mineral and Land Resources General Permit No. NCG030000
Date submitted: 05/06/2020
CERTIFICATE OF COVERAGE NO. NCG030134 SAMPLE COLLECTION YEAR
SAMPLE PERIOD _Jan-June July-Dec
FACILITY NAME:Thermo Fisher Scientific(Asheville) LLC Or X Monthly: April
COUNTY: Buncombe Rol 1s/� DISCHARGING TO CLASS pi ORW HQW xnrrout nPNA
PERSON COLLECTING SAMPLES:Jeremy Putnam, EHS f Zero-flow [)water Supply I SA
LABORATORY: Pace Analytical Lab Cert.# MAY 1 8 20200 Other
Comments on sample collection or analysis: CENT iI,E�
DWFLSE TIoI\! PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 -
Part A: Stormwater Benchmarks and Monitoring Results
No discharge this period?'
Non-Polar O&G/
Date Sample 24-hour rainfall pH, Total Toxic
Outfall No. Collected) amount, Total Suspended Solids Standard units Total Copper Total Lead Total Zinc Total Petroleum Organics'
Hydrocarbons
(mo/dd/yr) Inches3
Benchmarks - - 100 mg/L or 50 mg/L4 6.0—9.0 0.010 mg/L 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L
Parameter Code - 46529 C0530 00400 01119 01051 01094 00552 78141
Outfall 1 04/23/2020 0.68 9.6 6.72 0.0137 <0.005 0.302 <5 N/A
Outfall 2 04/23/2020 0.68 9.7 6.65 0.0346 <0.005 0.248 <5 N/A
Outfall 3 04/23/2020 0.68 8.1 6.6 0.008 <0.005 0.097 <5 N/A
Outfall 4 04/23/2020 0.68 <2.5 6.45 <0.005 <0.005 0.165 <5 N/A
3 Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
2 For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
3 The total precipitation must be recorded using data from an on-site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
See General Permit, Section B,Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies.
s Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11;for semiconductor
manufacture use the definition as found in 40 CFR 469.12;for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018
Page 1 of 3

Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO
monitoring may be waived.The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the
General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics(TTO),
I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the solvent
management plan included in the Stormwater Pollution Prey Plan."
Name(Print name)
Title(Print title)
Signature Date
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non-detect, ND, or other similar non-numerical
format. When results are below the applicable limits,they must be reported in the format, "<XX mg/L", where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses.See General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
No discharge this period?'
Outfall No. Date Sample Collected' 24-hour rainfall amount, New Motor Oil or Non-Polar O&G/Total Total Suspended
(mo/dd/yr) Inches' Hydraulic Oil Usage Petroleum Hydrocarbons Solids
Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/L4
Parameter Code - 46529 NCOIL 00552 CO530
Footnotes from Part A also apply to Part B
Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses.See General Permit text.
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018
Page 2 of 3

FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS.SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL?
YES X NO
IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE? YES NO REGIONAL OFFICE CONTACT NAME: Ms. Laura Herbert
(Asheville Regional Office)
Mail an original copy of this DMR,including all"No Discharge"reports, within 30 days of receipt of the lab results(or at end of monitoring period in the
case of"No Discharge"reports)to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true, accurate, and complete. I
a are that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Permittee Date
Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised
11/1/2018

Thermo is e
SCIENTIFIC
May 6, 2020
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: Stormwater Analytical Monitoring Results for Thermo Fisher Scientific, LLC
I have attached the analytical monitoring results from stormwater sampling that was collected
on April 23, 2020 at Thermo Fisher Scientific, LLC's four outfalls.
Per our General Storm Water Permit No. NCG03000 requirements of monthly monitoring for
applicable parameters during a storm event, I have sampled each outfall for copper, zinc, pH,
lead,TSS, and Non-Polar Oil/Grease/TPH. Results show that copper was above the benchmark
value at two of the four outfalls and zinc was above the benchmark value at three of the four
outfalls, as noted in Table 3 of the general storm water permit.All other results were below the
benchmark values. We have implemented a Tier Three response for the site and Thermo Fisher
Scientific, LLC has notified the Asheville Regional Office.Thermo Fisher Scientific, LLC is currently
working with an environmental consultant to help achieve compliance with the benchmark
values set forth in the facility's storm water permit. I have attached the completed Monitoring
Report containing the monitoring results from the four outfalls.
If you have any questions, please feel free to contact me at 828-658-2845.
Jeremy Putnam
Sr. EHS Manager
Attachments: 1

Pace Analytical Services,LLC
2225/
Ri
de Dr.
aceAnalytical V Asheville,NC 128 04
www.pacelabs.com
[phone]
May 05, 2020
Mr. Jeremy Putnam
Thermo Electron Corp.
275 Aiken Road
Asheville, NC 28804
RE: Project: APRIL 2020 SW
Pace Project No.: 92474759
Dear Mr. Putnam:
Enclosed are the analytical results for sample(s)received by the laboratory on April 23,2020. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services-Asheville
• Pace Analytical Services-Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
PC�Oye
? REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services,LLC. Page 1 of 15

Pace Analytical Services,LLC
Dr.
/.2e Analytical p 2225 RiversideNC28
Asheville,NC 2880404
www.pacelabs.com [phone]
CERTIFICATIONS
Project: APRIL 2020 SW
Pace Project No.: 92474759
Pace Analytical Services Charlotte
9800 Kincey Ave.Ste 100,Huntersville, NC 28078 South Carolina Certification#:99006001
Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 Virginia/VELAP Certification#:460221
North Carolina Wastewater Certification#: 12
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 Virginia/VELAP Certification#:460222
North Carolina Drinking Water Certification#:37712
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
c
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.corn
[phone]
•
SAMPLE ANALYTE COUNT
Project: APRIL 2020 SW
Pace Project No.: 92474759
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92474759001 1-1,2,3 EPA 1664E WAM 1 PASI-C
EPA 1664E WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A
SM 2540D-2011 JNS 1 PASI-A
92474759002 2-1,2,3 EPA 1664B WAM 1 PASI-C
EPA 1664B WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A
SM 2540D-2011 JNS 1 PASI-A
92474759003 3-1,2,3 EPA 1664B WAM 1 PASI-C
EPA 1664E WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A
SM 2540D-2011 JNS 1 PASI-A
92474759004 4-1,2,3 EPA 1664B WAM 1 PASI-C
EPA 1664B WAM 1 PASI-C
EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A
SM 2540D-2011 JNS 1 PASI-A
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
•
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
Dr.
aceAnalytical 2225 RiversideNC28
Asheville,NC 2880404
www.pacelabs.cam [phone]
ANALYTICAL RESULTS
Project: APRIL 2020 SW
Pace Project No.: 92474759
Sample: 1-1,2,3 Lab ID: 92474759001 Collected: 04/23/20 08:00 Received: 04/23/20 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 5.0 1 04/27/20 10:07
1664 SGT-HEM,TPH Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 04/27/20 10:07
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper 13.7 ug/L 5.0 1 05/01/20 02:04 05/04/20 12:30 7440-50-8
Lead ND ug/L 5.0 1 05/01/20 02:04 05/04/20 12:30 7439-92-1
Zinc 302 ug/L 10.0 1 05/01/20 02:04 05/04/20 12:30 7440-66-6
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 9.6 mg/L 5.0 1 04/27/20 14:07
Sample: 2-1,2,3 Lab ID: 92474759002 Collected: 04/23/20 08:15 Received: 04/23/20 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 5.0 1 04/27/20 10:07
1664 SGT-HEM,TPH Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 04/27/20 10:07
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper 34.6 ug/L 5.0 1 05/01/20 02:04 05/04/20 12:33 7440-50-8
Lead ND ug/L 5.0 1 05/01/20 02:04 05/04/20 12:33 7439-92-1
Zinc 248 ug/L 10.0 1 05/01/20 02:04 05/04/20 12:33 7440-66-6
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 9.7 mg/L 4.2 1 04/27/20 14:07
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 26804
www.pacelebs.com
[phone]
ANALYTICAL RESULTS
Project: APRIL 2020 SW
Pace Project No.: 92474759
Sample: 3-1,2,3 Lab ID: 92474759003 Collected: 04/23/20 08:30 Received: 04/23/20 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 5.0 1 04/28/20 10:24
1664 SGT-HEM,TPH Analytical Method:EPA 1664B
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 04/28/20 10:24
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper 8.0 ug/L 5.0 1 05/01/20 02:04 05/04/20 12:36 7440-50-8
Lead ND ug/L 5.0 1 05/01/20 02:04 05/04/20 12:36 7439-92-1
Zinc 97.0 ug/L 10.0 1 05/01/20 02:04 05/04/20 12:36 7440-66-6
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids 8.1 mg/L 3.0 1 04/27/20 14:08
Sample: 4-1,2,3 Lab ID: 92474759004 Collected: 04/23/20 08:45 Received: 04/23/20 09:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 5.0 1 04/28/20 10:24
1664 SGT-HEM,TPH Analytical Method:EPA 1664E
Pace Analytical Services-Charlotte
Total Petroleum Hydrocarbons ND mg/L 5.0 1 04/28/20 10:24
200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Copper ND ug/L 5.0 1 05/01/20 02:04 05/04/20 12:39 7440-50-8
Lead ND ug/L 5.0 1 05/01/20 02:04 05/04/20 12:39 7439-92-1
Zinc 165 ug/L 10.0 1 05/01/20 02:04 05/04/20 12:39 7440-66-6
2540D Total Suspended Solids Analytical Method:SM 2540D-2011
Pace Analytical Services-Asheville
Total Suspended Solids ND mg/L 2.7 1 04/27/20 14:08
REPORT OF LABORATORY ANALYSIS
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Date:05/05/2020 12:47 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 15

Pace Analytical Services,LLC
ace ^na 2225 Riverside Dr.
lr(i Hf I ly ilrcal Asheville,NC 28804
www.pacelabs.com [phone]
i
i
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 538289 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM,Oil and Grease
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92474759001,92474759002
METHOD BLANK: 2870089 Matrix: Water
Associated Lab Samples: 92474759001,92474759002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 04/27/20 10:07
LABORATORY CONTROL SAMPLE: 2870090
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 38.2 96 78-114
MATRIX SPIKE SAMPLE: 2870091
2631309001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 40 39.9 97 78-114
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 2225 Riverside Dr.
Asheville,NC 28804
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 538519 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92474759003,92474759004
METHOD BLANK: 2871259 Matrix: Water
Associated Lab Samples: 92474759003,92474759004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 04/28/20 10:24
LABORATORY CONTROL SAMPLE: 2871260
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 36.2 90 78-114
MATRIX SPIKE SAMPLE: 2871261
2631285001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 40 12.2 23 78-114 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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a n/��7 + j Pace Analytical Services,LLC
2225
aceAf ta/ytica Asheville,NC Riverside28 04
www.pecelabs.cam [phone]
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 538281 Analysis Method: EPA 1664E
QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM,TPH
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92474759001,92474759002
METHOD BLANK: 2870048 Matrix: Water
Associated Lab Samples: 92474759001,92474759002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons mg/L ND 5.0 04/27/20 10:07
LABORATORY CONTROL SAMPLE: 2870049
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L 20 16.5 82 64-132
MATRIX SPIKE SAMPLE: 2870050
2631309001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L ND 20 18.3 86 64-132
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical Riverside Dr.
Asheville,NC 28804
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 538516 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM,TPH
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92474759003,92474759004
METHOD BLANK: 2871175 Matrix: Water
Associated Lab Samples: 92474759003,92474759004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Petroleum Hydrocarbons mg/L ND 5.0 04/28/20 10:24
LABORATORY CONTROL SAMPLE: 2871176
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L 20 18.5 92 64-132
MATRIX SPIKE SAMPLE: 2871177
92474965003 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Total Petroleum Hydrocarbons mg/L ND 20 21.7 106 64-132
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
Dr.
�c /l na/ tical" Asheville,225 RiversideNC28 04
t� �jl f YtIC+ NC 28804
www.pacelabs.com [phone]
•
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 539165 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92474759001,92474759002,92474759003,92474759004
METHOD BLANK: 2874316 Matrix: Water
Associated Lab Samples: 92474759001,92474759002,92474759003,92474759004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Copper ug/L ND 5.0 05/04/20 12:00
Lead ug/L ND 5.0 05/04/20 12:00
Zinc ug/L ND 10.0 05/04/20 12:00
LABORATORY CONTROL SAMPLE: 2874317
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Copper ug/L 500 491 98 85-115
Lead ug/L 500 484 97 85-115
Zinc ug/L 500 470 94 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2874318 2874319
MS MSD
92474722004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 140 500 500 671 658 106 104 70-130 2
Lead ug/L 50.3 500 500 552 549 100 100 70-130 1
Zinc ug/L 1340 500 500 1860 1830 105 97 70-130 2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2874320 2874321
MS MSD
92475041001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Copper ug/L 7.1 500 500 541 520 107 103 70-130 4
Lead ug/L ND 500 500 507 488 101 98 70-130 4
Zinc ug/L 12.2 500 500 521 503 102 98 70-130 4
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aceAnalytical 2225 Rivers 2e 04
Asheville,NC 28804
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: APRIL 2020 SW
Pace Project No.: 92474759
QC Batch: 538274 Analysis Method: SM 2540D-2011
QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92474759001,92474759002,92474759003,92474759004
METHOD BLANK: 2870031 Matrix: Water
Associated Lab Samples: 92474759001,92474759002,92474759003,92474759004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solids mg/L ND 2.5 04/27/20 14:02
LABORATORY CONTROL SAMPLE&LCSD: 2870032 2870033
Spike LCS LCSD LCS LCSD %Rec Max
Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers
Total Suspended Solids mg/L 251 236 234 94 93 90-110 1 25
SAMPLE DUPLICATE: 2870034
92474777001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids mg/L 430 455 6
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services,LLC
aCG /l n�ytica j' Asheville,Riverside 04
l+4/�I! + lr I NC 28804
www.pacelabs.com [phone]
QUALIFIERS
Project: APRIL 2020 SW
Pace Project No.: 92474759
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2020 12:47 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 15

Pace Analytical Services,LLC
ace A n�ryticaI` 2225 Riverside Dr.
li H�/ I li Asheville,NC 28804
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: APRIL 2020 SW
Pace Project No.: 92474759
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92474759001 1-1,2,3 EPA 1664B 538289
92474759002 2-1,2,3 EPA 1664B 538289
92474759003 3-1,2,3 EPA 1664E 538519
92474759004 4-1,2,3 EPA 1664B 538519
92474759001 1-1,2,3 EPA 1664B 538281
92474759002 2-1,2,3 EPA 1664E 538281
92474759003 3-1,2,3 EPA 1664B 538516
92474759004 4-1,2,3 EPA 1664E 538516
92474759001 1-1,2,3 EPA 200.7 Rev 4.4 1994 539165 EPA 200.7 Rev 4.4 1994 539182
92474759002 2-1,2,3 EPA 200.7 Rev 4.4 1994 539165 EPA 200.7 Rev 4.4 1994 539182
92474759003 3-1,2,3 EPA 200.7 Rev 4.4 1994 539165 EPA 200.7 Rev 4.4 1994 539182
92474759004 4-1,2,3 EPA 200.7 Rev 4.4 1994 539165 EPA 200.7 Rev 4.4 1994 539182
92474759001 1-1,2,3 SM 2540D-2011 538274
92474759002 2-1,2,3 SM 2540D-2011 538274
92474759003 3-1,2,3 SM 2540D-2011 538274
92474759004 4-1,2,3 SM 2540D-2011 538274
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:05/05/2020 12:47 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 15

Co CHAIN-OF-CUSTODY Analytical Request Document LAB USEol W0## : 92474759 beror in
Pace Analytical ( Nr
Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields I 1
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Company: Billing Information:
Te.+Yrio 1�s ,'.4' `.�;,iti 1'f4<: 92474759 �
Address: r~ vL�tt�tflCLl?li'
Z1r /IVY rN i Container 1-
Report To: Email To: ^'Preservative.Types:(1)nitric acid,(2)sulfuric acid,(3)hydrochloric sod,(a)sodium hydroxide,(5)zinc acetate,
Jett (In,C'V1+<�ts't't tlr ✓vt ;r'trt i lttcvi H etttoRS�€r;i,
C'. (6)methanol,(7)sodium bisulfate,(8)sodium thiosulfate,(9)hexane,(A)ascorbic acid,(n)ammonium sulfate,
Copy to: ite Caller ion Info/Address: t (C)ammonium hydroxide,(D)TSP,(U)Unpreserved,(0)Other
2"15 j1:�2.iN. le ,4 Analyses Lab Profile/Line:
Customer Project Name/Number: State: County/City: Time Zone Collected: Lab Sample Receipt Checkli:et;
r 1rt! •L.. .) :SUS 1"t✓/Ac ilIC. I (PT[ IMT[ (Cr (zET .-.
7 _ c•-, Custody Seals Present/Intact Y 1� NA
Phone: -t- 5 u' .J?`�cs Site/Facility ID it: Compliance Monitoring? !.' _ "-.- Custody Signatures Present Y j NA
Email: j Yes [ I No ^a Collector Signature Present N NA
S �. fattiest Intact N NA
Collected By(print): Purchase Order tt: OW PWS ID It: r Correct Bottles ' N NA
Sw Sufficient Volume N NA
t t-nee'. Quote II: DW Location Code: < J
C t- �7 €� Samples Received on ice Ni
C Merit: By Turnaround Date Required: Immediately Packed on Ice: °'w..t <.,_y V r.,y) VOA - tte�dspar Acceptable I N
a -`✓ `�z USDA Regulated Soils Y N A
i f_i Yes [ No may. c„ Samples in Raiding Time N
Sample Disposal: Rush: Field Filtered(if applicable): ie xdua Chlorine ne present Y N �ars
I I Dispose as appropriate I I Return [ ]Same Day ( j Next Day [ )Yes [ [No xy? -- -� Cl Strips
Archive: Sample pH Acceptable Y N A
I _.__ __ f }z Day I ]3 Day I ]�Day [ I s Day '+ -!�-� �,.,, �' .�
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Hold. . .. (Expedite Charges Apply) �— .,St ;C:'
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k""_ Sulfide Present Y r0
*Matrix Codes(Insert in Matrix box below):Drinking Water(OW),Ground Water(GW),Wastewater(WW), y Lead Acetate Strips: _
Product(P),Soil/Solid(SO,Oil(OL),Wipe(WP),Air(AR) Tissue(TS),Bioassay(B),Vapor(V),Other)OT) -,. . Lilt USE ONLY:
Comp/ Collected(or Res tt of S�.-.S 4'"' " ,' r Lab Sample * / Comments
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Date Time Date Time Z. L,I "'� / f -,tiJ
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Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: 43 Blue Dry None SHORT HOLDS PRESENT(<72 hours): Y N N/A Lab Sample Temperature Info:
Packing Material Used: 11� Lab Tracking ll: Temp Blank Rec " r Y NA
CJ 0 Therm IDII VVV
Cooler 1 Temp UponlAoC
Radchem sample(s)screened(<SOO cpm): Y N NA Samples received via: Cooler 1 Therm Corr.Factor _oC
FEDEX UPS Mb Courier Pace Courier Cooler 1 Corrected Temp. /'� oC
Swished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: 073 0 MTJL LAB USE ONLY Comments:
, bik, „-• ck130,) A/v--)711(.,f,A,,, \.1).2.3h.,b „„ble P!
Accenum:
Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: Template: TripBlank Received: Y N NA
Prelogin: HCL McOH TSP ther
Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Conform): Page:,_...._•..____.
PB: YES / of:

CHAIN-OF-CUSTODY Analytical Request Document LAB USE t WO# : 92474759 nber or r
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Pace Analytical
Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields PM: CD1 Due Date: 05/07/20 m
Company: Billing Information: `- CLIENT: 93—Thermo d
}e.y no R5 )Qr Sc-ievItihc �.(.eia,dll3 PG1,1 GL t•�„
Address: ,J Containe.
2-1 S it k in R,:.GkC1 1 1 1 k/1 1 1 1 1 ( 1 1
Report To: �'} Email To: j., °•preservative Types:(1)nitric.acid,(2)sulfuric acid,(3)hydrschloric acid,(A)sadiuei hydroxide,(S)zinc acetate.
U - ti 'l S'tiJ ' x VYf •eirei L1.�{ rttf iria A te('K1.1iR51he✓"•C,h(6)methanol,(7).sodium bisulfate,(8)sodium thiosuifate,(9)hexane,(Al ascorbic acid,1B)ammonium sulfate,
Copy To: 'ito Collect Con Info/Address: (C)ammonium hydroxide,(n)TSP,(U)tlnpreserved,(0)Other__
9 14 A VI I —I Analyses Lab Profile/Line:
Customer Project Naa1me/Num�ber: j State: County/City: Time Zone Collected: Lab Sample Receipt Checklist:
AT t� G l^��t—tJ of
N GJ J�'1 evt 1 ( J PT[ ]MT( J CT ( T r,: `-„> custody Seals Present/Intact r p NA
Phone:e2.`,-i✓c -2el. ' Site/Facility ID tt: '1 h. Compliance Monitoring? -i „.S) "V Custody Signatures Present Y k NA
Email: (,,j,jYes ( J No ..� Collector Signature Present N NA
1� Bottles Intact N NA
Collected By(print): Purchase Order it: DW PWS ID It: 4) Correct Bottles N NA
y Quote it: DW Location Code: .....
Sufficient Volume N NA
�D' �4l t V ILLWt -- samples Received on Ice :6
Cu em ted y( •n,aturel: Turnaround Date Required: Immediately Packed on Ice: ,p,.1 QJ� .4... VOA - Headspace Acceptable Y
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�fr [ Yes ( ]No '.,y USDA Regulated Soils Y
Sampler; in Holding Time 'Z:)N NA
Sample Disposal: Rush: Field Filtered(if applicable): -.-- Residual Chlorine Present sent 5 NC,
I )Dispose as appropriate ( I Return [ I Same Day [ 1 Next Day [ (Yes ( J No ...L-- . * Cl Strips: �•t
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I )Archly _ ( ]2 Day [ 13 Day I 1 4 Day [ 15 Day "`" • SSample pHrAcceptable esent Y N
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.._._....._ (Expedite Charges Apply) l ta
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"Matrix Codes(Insert in Matrix box below):Drinking Water(DW),Ground Water(OW),Wastewater(WW), - �.� Lead Acetate Strips:
Product(P),Soil/Solid(SL),Oil(0L),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) '"`'
V — LAB USE ONLY:
Comp/ Collected(or Res It of C ..- Lab Sample # / Comments:
Customer Sample ID Matrix' Grab Compo,r 4. 2,,,site Start) Composite End CI Ctns - [..�
Date Time Date Time 1 �� � )T 1
Customer Remarks/Special Conditions/Possible Hazards: Type of Ire Used:(ZttVe/ Blue Dry None SHORT HOLDS PRESENT(</2 hours): Y N/A Lab Sample Temperature Info:
Packing Material Used: ey[,b/ p _� Lab Tracking tt: Temp Blank Recei Y cll NA
V 1 1`r►��t�Jt2427021 Therm IN: _
Cooler 1 Temp Upon Receipt:l Aq oC
r,.'N� Samples received via: Cooler 1 Therm Corr,Factor oC
Radchem sample(s)screened(<500 corn): Y N CJ
FEDEX UPS liens Courier Pace Courier Cooler 1 Corrected Temp: i 1 1 0C
Rlik uts /Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: +^,�V MTIL I.AB USE ONLY Comments:
tot1 Cll.3 y��V r✓ -/F4e-r -- llZ4/� �t Table it:
Acctnum:
Relinquished by/Company:(Signature) Date/lime: Received by/C mpany:(Signature) Date/Time: Template: Trip Blank Received: Y N NA
Pretogin: HCL McOH TSP Other
Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Confer tan :(s); Page:_
PB: YES / NO of: _