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HomeMy WebLinkAboutNC0005088_Report_20200724 (s DUKE James Wells le' ENERGY Vice President Environmental,Health and Safety Programs&Environmental Sciences 526 South Church Street Charlotte, NC 28202 (980)373-9646 July 24, 2020 Via Overnight Mail H S. Daniel Smith Director of Water Resources JUL 72W 020 North Carolina Department of Environmental Quality 1617 Mail Service Center DIVISION OF WATER RESOURCES Raleigh,NC 27699-1617 DIRECTOR'S OFFI^E Bob Sledge North Carolina Department of Environmental Quality Division of Water Resources Water Quality Permitting Program 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Seep Characterization Report submittal and request for formal certification of seep dispositions Duke Energy Carolinas, LLC—Rogers Energy Complex EMC SOC WQ S 17-009 NPDES Permit NC0005088 Cleveland and Rutherford Counties Dear Messrs. Smith and Sledge: On behalf of Duke Energy Carolinas, LLC (DEC), I am submitting to you the enclosed Rogers Energy Complex(REC)Seep Characterization Report summarizing the findings of the post decant sampling event and requesting formal certification of seep disposition decisions as described in the report. The conclusions from this report and the Department's certifications will be incorporated into the upcoming corrective action plan(CAP)amendment as required by the subject order. Completion of decanting occurred at REC on March 3, 2020. As outlined in the report, all remaining areas previously identified as '`seeps" are proposed for dispositioning based on their characteristics and/or lack of impact to waters of the State. Messrs. Smith and Sledge July 24, 2020 Page 2 Please direct any questions about this submittal to Chris Hallman at(980) 373-7892. I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Sincerely, James Wells Vice President, Environment, Health& Safety Programs and Environmental Sciences Duke Energy Attachment: Rogers Energy Complex 2020 Seep Characterization Report cc: Richard Baker, Duke Energy Robert Wylie/FileNet, Duke Energy Shannon Langley, Duke Energy Chris Hallman, Duke Energy Steve Hodges, Duke Energy Paul Draovitch, Duke Energy Matt Hanchey, Duke Energy Landon Davidson, WQ Regional Supervisor, DEQ Asheville Office synTerra SEEP CHARACTERIZATION REPORT ROGERS ENERGY COMPLEX CLIFFSIDE STEAM STATION EMC SOC WQ S17-009 573 DUKE POWER ROAD MOORESBORO, NC 28114 JULY 2020 PREPARED FOR drelk DUKE ENERGY. CAROUNAS . DUKE ENERGY CAROLINAS, LLC Tim Grant Project Scientist Scott Spinner, NC LG #2243 Project Manager Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra EXECUTIVE SUMMARY SynTerra has prepared this Seep Characterization Report pertaining to the Rogers Energy Complex -Cliffside Steam Station (Cliffside or Site). This report presents an evaluation of whether historical storage of coal ash has affected surface waters downgradient of the active ash basin, the ash storage area, the former Units 1-4 ash basin, and the Unit 5 inactive ash basin. This report was prepared on behalf of Duke Energy Carolinas, LLC (Duke Energy). ES.1 Introduction Special Order by Consent (SOC) WQ S17-009, approved on April 12, 2018, addresses management of seeps from Duke Energy's coal ash basins at Cliffside during the process of basin closure. That process is regulated under the Coal Ash Management Act of 2014 (CAMA), G.S. 130A-309.200 through 130A-309.231 and the federal Coal Combustion Residuals (CCR) rule,40 CFR Parts 257 and 261. In addition to containing monitoring requirements, the SOC includes these compliance requirements: • After completion of decanting, a comprehensive survey of areas downgradient of ash basins is required so that new seeps are identified and the physical characteristics of previously identified seeps are documented. Duke Energy is required to submit a Final Seep Report summarizing the findings of that survey no later than 90 days after completion of decanting. • Additional characterization of seeps not dispositioned in the Final Seep Report will be necessary, and a summary of findings provided within a Seep Characterization Report must be submitted no later than 150 days after completion of decanting. • An amendment to the Corrective Action Plan or Closure Plan describing future seep management must be submitted no later than 210 days after completion of decanting. Decanting of the active ash basin was completed on March 3, 2020. A physical inspection — to identify new seeps and document the physical characteristics of previously identified seeps — was completed in March 2020. A new seep, S-39, was identified during that inspection. Several seeps located southwest, west, and north of the active ash basin were dry or exhibited significantly reduced flow as a result of decanting. The findings of the March 2020 inspection are documented in the Final Seep Report(SynTerra, 2020). The Final Seep Report was submitted on May 27, 2020. Page ES-1 r Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra Observations from seep inspections in November 2019, March 2020, and May 2020 were evaluated to determine whether any remaining seeps identified during the inspection are candidates for dispositioning in accordance with the SOC. Samples were collected in May 2020 from remaining seeps identified downgradient of the ash basins to facilitate additional characterization of those seeps. Seep samples were analyzed for constituents consistent with Attachment B of the SOC. The analytical data were evaluated to determine if any constituents are present in non-dispositioned seeps at concentrations to be considered for corrective action based on comparison with applicable North Carolina Administrative Code (NCAC), Title 15A, Subchapter 02B Surface Water and Wetland Standards (02B). In addition, a review and determination of the jurisdictional status of remaining seeps is included in this report for further characterization. ES.2 Key Findings Key findings regarding the seep characterization presented in this report include: • Fifteen seeps (S-01, S-05, S-08, S-09, S-12, S-13, S-17, S-20, S-22, S-24, S-25, S-26, S- 33, S-34, and S-35) remain in dispositioned status as determined by DWR at issuance of the SOC. • Pursuant to National Pollutant Discharge Elimination System (NPDES) permit NC0005088, approved July 13, 2018 and effective September 1, 2018, discharge flows from constructed seeps S-04 (Outfall 104) and S-06 (Outfall 106) will be monitored per permit requirements. • Inspections have identified eight seeps (S-14, S-15, S-16, S-21, S-27, S-28, S-31, and S-37) that are candidates for dispositioning based on dry or non-flowing conditions observed at these locations for at least three consecutive quarters. • Seep S-07 is a candidate for dispositioning based on analytical results that indicate the seep is no longer impacted by flow from a coal ash basin. Seep S-07 is considered a water of the State (WOS). • Seep S-39 is a candidate for dispositioning based on initial analytical data that indicate the seep is not impacted by flow from a coal ash basin. • Thirteen non-constructed seeps (S-02, S-03, S-10, S-11, S-18, S-19, S-19a, S-23, S-29, S-30, S-32, S-36, and S-38) remain non-dispositioned. In accordance with the SOC, they are subject to being addressed in an amendment to the Corrective Action Plan (CAP) and/or the Closure Plan. Of those, only seeps S-02, S-18, S-19, and S- 19a are preliminarily considered jurisdictional waters. Page ES-2 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra o S-02, S-18, S-19, and S-19A-Seep characterization analytical results indicate that only the reported hardness concentration is greater than 02B standards. However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. o S-03-A preliminary comparison of seep characterization analytical results to 02B standards, including calculated hardness dependent metals, identified only concentrations of dissolved cadmium,hardness, sulfate, and total dissolved solids (TDS) greater than 02B standards. However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. o S-10 and S-11 -These seeps were recently un-dispositioned due to observed flow, although the flow was insufficient to collect a sample during the seep characterization sampling event. o S-23-Seep characterization analytical results indicate that no Attachment B constituent values were greater than 02B standards. o S-29, S-30, S-32, S-36, and S-38-Flow at these locations was insufficient to collect a sample during the seep characterization sampling event. • The quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their 02B standards. • With concurrence from the Director of the NCDEQ DWR on seep jurisdictional and dispositional status and the instream 02B standards compliance, it could be determined that corrective action may not be warranted at any seep locations at Cliffside. Page ES-3 I Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra TABLE OF CONTENTS SECTION PAGE EXECUTIVE SUMMARY ES-1 1.0 INTRODUCTION 1-1 1.1 Decanting Summary 1-2 1.2 Seep Characterization Evaluation 1-2 2.0 FINDINGS 2-4 2.1 Physical Inspection 2-4 2.1.1 Seep Status 2-4 2.2 Seep Sampling 2-5 2.2.1 Data Results 2-6 2.3 Jurisdictional Status of Seeps 2-8 2.4 Dispositional Status of Seeps 2-8 2.4.1 Dispositioned 2-9 2.4.2 Non-Dispositioned 2-10 2.4.3 Changes of Status 2-10 2.5 Decanting Status 2-11 2.6 Ash Basin Closure Status/Corrective Action Plan 2-12 3.0 SEEPS TO BE ADDRESSED 3-1 4.0 CONCLUSION 4-1 5.0 REFERENCES 5-1 Page i Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra LIST OF FIGURES Figure 1 Seep Locations and Inspection Areas LIST OF TABLES Table 1 Seep Locations and Descriptions—March 2020 Inspection Table 2 Seep Sampling Results—May 2020 Table 3 Calculated 02B Hardness-Dependent Standards LIST OF APPENDICES Appendix A March 2020 Seep Photographs Page ii Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra LIST OF ACRONYMS 02B North Carolina Administrative Code, Title 15A, Subchapter 02B, Surface Water and Wetland Standards Cliffside Cliffside Steam Station CAMA Coal Ash Management Act of 2014 CCRs coal combustion residuals CAP Corrective Action Plan DWR Division of Water Resources Duke Energy Duke Energy Carolinas, LLC EMC Environmental Management Commission JD jurisdictional determination mg/L milligrams per liter NCAC North Carolina Administrative Code NCDEQ North Carolina Department of Environmental Quality NC L.G. North Carolina Licensed Geologist NPDES National Pollutant Discharge Elimination System PVC polyvinyl chloride Site Cliffside Steam Station SOC Special Order by Consent SOP standard operating procedure USACE U.S. Army Corps of Engineers USEPA U.S. Environmental Protection Agency WOS water of the State WOTUS Waters of the United States Page iii Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 1.0 INTRODUCTION On March 30, 2020, Scott Spinner (NC L.G. #2243) of SynTerra conducted a comprehensive survey of the Rogers Energy Complex- Cliffside Steam Station (Cliffside or Site) property for existing and potential new seeps. After the seep inspection, SynTerra prepared a Final Seep Report (SynTerra, 2020) documenting the findings of the seep inspection as required by the North Carolina Environmental Management Commission (EMC) Special Order by Consent (SOC) WQ S17-009. This requirement can be found in the Additional Compliance Measures (Section 2.c.4) of the SOC. After submittal of the Final Seep Report, the SOC requires characterization of those seeps not certified as dispositioned following completion of decanting (Section 2.d). That section of the SOC describes requirements for seep characterization as follows: "Following completion of decanting, if any seeps (including both constructed and non-constructed seeps) have not been certified by the Director of DWR as dispositioned..., Duke Energy shall conduct a characterization of those seeps. Duke Energy shall submit a report on the findings of these characterizations ("Seep Characterization Report") to the Director of DWR within 150 days of completion of decanting at each Facility (i.e., within 60 days of the submittal of the Final Seep Report). The Seep Characterization Report must include all sampling datafor En ergy's g each remaining seep as well as Duke Energy s evaluation of the jurisdictional status of all seeps at the relevant Facility. The determination regarding whether a surface water feature is a classified water of the State rests with DWR." In May 2020, SynTerra collected samples for analysis from non-dispositioned seep locations identified in the Final Seep Report(Table 1). Seep samples were analyzed for constituents consistent with Attachment B of the SOC. Samples were collected in accordance with Duke Energy's Standard Operating Procedure (SOP) for Seep Sampling (Duke Energy, 2016). Several locations were not sampled due to dry or stagnant conditions, insufficient flow, or other observed conditions that would preclude the ability to collect a valid, representative sample as outlined in Duke Energy's 2016 SOP for seep sampling. The May 2020 seep sampling was conducted to facilitate characterization of seeps as required by the SOC. Results are provided in Table 2. Page 1-1 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra This Seep Characterization Report documents the inspection and analysis results as well as a preliminary evaluation of the jurisdictional status of all remaining seeps at Cliffside. 1.1 Decanting Summary Wastewater inflows ceased, and decanting of free water from the active ash basin began, on March 31, 2019. Duke Energy provided a Notification for Completion of Decanting letter to the North Carolina Department of Environmental Quality (NCDEQ) Division of Water Resources (DWR) on April 2, 2020. The notification indicated that decanting of the active ash basin was completed on March 3, 2020. The March 2020 annual seep inspection occurred 27 days after the completion of decanting, approximately one year after wastewater inflows to the active ash basin ceased and decanting began. 1.2 Seep Characterization Evaluation The purpose of seep characterization is to evaluate whether historical storage of coal ash has affected surface waters downgradient of the ash basins. This includes evaluation of the physical status, chemical composition, and jurisdictional determination of the seeps. The following methods were used in this evaluation: Physical Inspection On March 30, 2020, SynTerra conducted a comprehensive survey of areas downgradient of the ash basins to identify new seeps and to document the physical characteristics of previously documented seeps. That survey included identification of the seeps by approximate latitude and longitude and date-stamped photographs of their appearance (Appendix A). The seeps were evaluated based on appearance, current flow conditions, and comparison with historical physical conditions. A summary of the findings of the survey are included in the Final Seep Report (SynTerra, 2020). Chemical Composition In May 2020, SynTerra collected samples from non-dispositioned seep locations for analysis of constituents listed in Attachment B of the SOC. Samples were not collected from locations where there were dry or stagnant conditions, insufficient flow, or other observed conditions that would preclude the ability to collect a valid, representative sample as outlined in Duke Energy's March 2016 SOP for seep sampling. Data collected from the remaining seeps were evaluated to determine whether concentrations of coal combustion residual(CCR) constituents meet State criteria. This evaluation is based on Page 1-2 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra preliminary comparison with North Carolina Administrative Code, Title 15A, Subchapter 02B, Surface Water and Wetland Standards (02B). Jurisdictional Determination At the time of report issuance, a Waters of the United States (WOTUS) delineation at the Site, submitted December 1, 2017,has not been approved by the U.S. Army Corps of Engineers (USACE). SynTerra compared non-dispositioned seep locations to preliminary wetland and stream boundaries (Amec Foster Wheeler, 2015). In addition, the known surface water feature existing near seep S-07,not identified on the preliminary jurisdictional determination (JD), was evaluated and identified as a perennial water per the DWR Methodology for Identification of Intermittent and Perennial Streams and Their Origins. The final determination of jurisdictional status of a surface water feature as a classified water of the State (WOS) or WOTUS rests with the DWR and USACE. Page 1-3 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 2.0 FINDINGS 2.1 Physical Inspection On March 30, 2020, Scott Spinner (NC L.G. #2243) with SynTerra conducted a comprehensive survey of areas downgradient of the ash basins identifying new seeps and documenting the physical characteristics of previously identified seeps. Inspection activities were performed in accordance with SOC requirements. All locations listed in Table 1 of the SOC were observed and documented with photographs during the inspection (Appendix A). The inspection included observations in the following areas (Figure 1): • Along the Broad River, north of the Unit 5 inactive ash basin • Between the Unit 5 inactive ash basin and the Unit 5 power plant • Along the Broad River,northeast of the former Units 1-4 ash basin • Along the Broad River,north of the ash storage area • Along the Broad River,north of the active ash basin • Along the eastern bank of Suck Creek, adjacent to the active ash basin • Areas along and downgradient of the ash basins 2.1.1 Seep Status Seep locations and inspection areas are shown on Figure 1. Observations noted during the March 2020 inspection are summarized on Table 1. Details of the physical seep inspection include: • Several seeps located southwest, west, and north of the active ash basin are dry or exhibit significantly reduced flow as a result of decanting. • Seeps unaffected by decanting of the active ash basin were found to be generally similar to observed conditions inprevious inspections. g Y P • A new seep, S-39,was identified west of the Unit 5 inactive ash basin with flow that reaches an unnamed tributary to the Broad River. Due to the intermittent nature of some seeps, there were differences in physical characteristics of seeps S-05, S-10, and S-11 between the March 2020 inspection Page 2-4 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra and the subsequent May 2020 seep characterization sampling event. The differences noted are: • Seep S-05 was dry during the March 2020 inspection. S-05 was flowing to the Broad River and exhibited sufficient flow to sample during the May 2020 seep characterization event. • Seeps S-10 and S-11, originally dispositioned at issuance of the SOC due to non-flowing conditions, were flowing to the Broad River during the March 2020 inspection and no longer deemed dispositioned. S-10 and S-11 were significantly drier and not flowing to the Broad River in May 2020. 2.2 Seep Sampling On May 11 and 12, 2020, SynTerra collected samples for analysis from non- dispositioned seep locations identified in the Final Seep Report (Table 1), except for locations where there were dry or stagnant conditions, insufficient flow, or other observed conditions that would preclude the ability to collect a valid, representative sample as outlined in Duke Energy's March 2016 SOP for seep sampling. Samples were collected in accordance with the March 2016 SOP. Seep sample locations are provided on Figure 1. Seep locations not sampled, along with observations that would preclude the ability to collect a valid, representative sample, are provided below: • S-04 and S-06 — Former seeps that are now National Pollutant Discharge Elimination System (NPDES) outfalls and sampled in accordance with NPDES Permit No. NC0005088 • S-10 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-11 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-14 — Seep was dry • S-15 — Seep was dry • S-16 — Seep was dry • S-21 — Seep was dry • S-27 — Seep was dry Page 2-5 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra • S-28 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-29 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-30 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-31 — Seep was dry • S-32 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-36 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) • S-37 — Seep was dry • S-38 — Insufficient flow to collect representative sample (less than a quarter-inch of depth over PVC pipe barrier) 2.2.1 Data Results Seep samples collected at the Site in May 2020 were analyzed for constituents listed in Attachment B of the SOC. Those data were collected in order to characterize the potential for corrective action for seeps not certified as dispositioned after the completion of decanting as described in SOC Section 2.d. The analytical results of the seep samples collected at the Site in May 2020 are included in Table 2. Seep sample locations are provided on Figure 1. Oil and grease samples were not collected at seeps S-23 and S-39. Those seeps exhibited sufficient flow to sample via PVC pipe barrier and tubing,but water was not deep enough to sample for oil and grease without disturbing sediment. It is notable that all seep pH values observed are within the range of background groundwater pH values at the Site. Groundwater pH values naturally occur between 4.0 and 7.5 standard units (SynTerra, 2019). The pH values recorded at S-03 and S-23, while outside the range of 02B standard values, are considered naturally occurring and not affected by CCRs. In addition, 02B standards for select dissolved metals are hardness-dependent and are calculated based on actual in-stream values as developed and approved by the North Carolina EMC and approved by the U.S. Environmental Protection Agency (USEPA). Page 2-6 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 15A NCAC 02B .0211 (11)(d) states: "Hardness-dependent freshwater metals standards shall be derived using the equations specified in Table A: Dissolved Freshwater Standards for Hardness-Dependent Metals. If the actual instream hardness (expressed as CaCO3 or Ca+Mg) is less than 400 mg/L, standards shall be calculated based upon the actual instream hardness. If the instream hardness is greater than 400 mg/L, the maximum applicable hardness shall be 400 mg/L." Reported seep sample hardness values were used to calculate the hardness- dependent dissolved metals standards. The hardness values ranged from 10.2 mg/Lto 554 mg/Lduringthe May2 2 0 0 g sam lin event. sampling Calculations from Table A in 15A NCAC 02B .0211 (11) (d) were performed for dissolved cadmium, dissolved chromium, dissolved copper, dissolved lead, dissolved nickel, and dissolved zinc based on actual in-stream hardness values for each seep location (Table 3). With the exception of dissolved cadmium at seep S-03, the concentrations of the hardness-dependent dissolved metals reported during the May 2020 seep sampling event were less than the calculated 02B standards. In addition to dissolved cadmium;hardness, sulfate, and total dissolved solids (TDS) were reported at concentrations greater than their 02B standards at seep S- 03 during the seep characterization sampling event. However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. Analytical results from S-07, S-23, and S-39 indicate that all constituents meet State criteria. Constituent concentrations from S-02, S-18, S-19, and S-19a meet State criteria for all constituents except hardness. There is no human health or aquatic life concern with increased hardness. Water quality standards for hardness have only been established in waters classified as Water Supply because hardness is considered undesirable for economic or aesthetic reasons. The quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1),located in the Page 2-7 T Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. 2.3 Jurisdictional Status of Seeps At the time of report issuance, a WOTUS delineation at the Site, submitted December 1, 2017,has not been approved by the USACE. SynTerra compared non-dispositioned seep locations to preliminary wetland and stream boundaries (Amec Foster Wheeler, 2015). In addition, the known surface water feature existing near seep S-07, not identified on the preliminary JD, was evaluated and identified as a perennial water per the DWR Methodology for Identification of Intermittent and Perennial Streams and Their Origins. The final determination of jurisdictional status of a surface water feature as a classified WOS or WOTUS rests with the DWR and USACE. Stream and wetland data derived from the preliminary JD are included on Figure 1. Based on this evaluation,non-dispositioned seeps S-02, S-07, S-18, S-19, and S-19a are considered jurisdictional waters. 2.4 Dispositional Status of Seeps During the March 30, 2020 seep inspection, Mr. Spinner with SynTerra inspected each seep to evaluate whether it met requirements to be dispositioned in accordance with the SOC. The requirements for dispositioning a seep are as follows: "For purposes of this Special Order, "dispositioned" includes the following: (1) the seep is dry for at least three consecutive quarters; (2) the seep does not constitute, and does not flow to, waters of the State or Waters of the United States for three consecutive quarters; (3) the seep is no longer impacted by flow from any coal ash basin such that concentrations of all pollutants listed in Attachment B meet State criteria for four consecutive sampling events with at least seven days separating each event; or(4) the seep has been otherwise eliminated (e.g., through an engineering solution). If a seep that has been dispositioned through drying up reappears in any subsequent survey, such a seep will no longer be deemed dispositioned and can be subsequently re-dispositioned as specified above." A discussion of the dispositional status of each seep is provided in the following sections. Page 2-8 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 2.4.1 Dispositioned No seeps have been dispositioned since the SOC became effective in April 2018. However, several seeps were dispositioned prior to the effective date, as noted in the SOC and on Table 1. Those seeps are: • S-01 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-05 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-08 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-09 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • _ — _ 10 S Seep is no longer present after the Units 1 4 ash basin excavation and toe drain removals. o During the March 2020 inspection, S-10 was observed to be flowing and reaching the Broad River. S-10 is now considered non- dispositioned. • S-11 — Seep is no longer present after the Units 1-4 ash basin excavation and toe drain removals. o During the March 2020 inspection, S-11 was observed to be flowing and reaching the Broad River. S-11 is now considered non- dispositioned. • S-12 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-13 — Seep is no longer present after the Units 1-4 ash basin excavation. • S-17 — Seep below the ordinary high water level of Broad River. • S-20 — Seep dispositioned via repair. • S-22 — Seep dispositioned via repair;pipe has been plugged; discharge eliminated. • S-24 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-25 — No measurable flow has been observed during routine inspections. Page 2-9 r , Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra • S-26 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-33 — Seep is no longer present after the Units 1-4 ash basin excavation. • S-34 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. • S-35 — Location previously investigated as a seep. Monitoring has not indicated the presence of CCRs. 2.4.2 Non-Dispositioned With the exception of the seeps discussed in Section 2.4.1, seeps listed on Table 1 are currently considered non-dispositioned. During the March 2020 inspection, seeps S-10 and S-11 were observed flowing to the Broad River. This was documented in the Final Seep Report, and those seeps are now considered non- dispositioned. 2.4.3 Changes of Status An evaluation of changes in seep physical characteristics over time indicate that several non-dispositioned seeps documented in Table 1 are considered eligible to be dispositioned based on the SOC requirements for dispositioning. These considerations are based on seep inspections performed by SynTerra in November 2019 (concurrent with quarterly SOC sampling), March 2020 (Final Seep Report inspection), and May 2020 (concurrent with seep characterization sampling event). In the terms of the SOC, "dispositioned" includes: (1) The seep is dry for at least three consecutive quarters. (2) The seep does not constitute, and does not flow to, waters of the State or WOTUS for three consecutive quarters. (3) The seep is no longer impacted by flow from any coal ash basin such that concentrations of all pollutants listed in Attachment B meet State criteria for four consecutive sampling events with at least seven days separating each event. (4) The seep has otherwise been eliminated (e.g., through an engineering solution). Page 2-10 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra Those seeps requested for dispositioning, along with supporting evidence, are: • Analytical results from S-07 have met State criteria for greater than four consecutive sampling events — consider dispositioning based on (3) above. • S-14 has been dry for at least three consecutive quarters — consider dispositioning based on (1) above. • S-15 has been dry for at least three consecutive quarters — consider dispositioning based on (1) above. • S-16 has been dry for at least three consecutive quarters — consider dispositioning based on (1) above. • S-21 has been dry for at least three consecutive quarters — consider dispositioning based on (1) above. • S-27 has been dry for at least three consecutive quarters — consider dispositioning based on(1) above. • S-28 has been dry and/or has not flowed to WOTUS for at least three consecutive quarters — consider dispositioning based on (1) and (2) above. • S-31 has been dry for at least three consecutive quarters — consider dispositioning based on (1) above. • S-37 was discovered after the SOC went in effect,but has been dry and/or has not flowed to WOTUS for at least three consecutive quarters — consider dispositioning based on (1) and (2) above. • S-39 was discovered after the SOC went in effect, and was sampled during the May 2020 seep characterization sampling event. Sampling data from that event indicate no detectable concentrations of CCR indicator parameters such as boron. 2.5 Decanting Status Decanting of free water from the active ash basin began and wastewater inflows to the active ash basin ceased on March 31, 2019. Decanting of the active ash basin was completed on March 3, 2020. Decanting of the active ash basin has caused several notable changes to seep status: • Southwest of the active ash basin, seeps S-28, S-31, and S-37 are now dry. Page 2-11 � 1 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra • Southwest of the active ash basin, seeps S-29, S-30, and S-32 exhibit reduced flow compared to pre-decanting conditions. • West of the active ash basin, near the toe of the upstream dam, seeps S-14, S-15, S-16, S-21, and S-27 are now dry. • North of the active ash basin, seeps S-24 and S-25 exhibit reduced flow compared to pre-decanting conditions. 2.6 Ash Basin Closure Status/Corrective Action Plan Excavation of the former Units 1-4 ash basin began in October 2015 and was completed in February 2018. The footprint of the former Units 1-4 ash basin has been re-graded and is now the location of lined retention basins and a wastewater treatment plant. Closure plans for the active ash basin, the ash storage area, and the Unit 5 inactive ash basin were submitted to NCDEQ DWR in December 2019 and are currently under review. On December 31, 2019, Duke Energy submitted a Corrective Action Plan (CAP) Update report (SynTerra, 2019) to the NCDEQ DWR. In accordance with the Coal Ash Management Act of 2014 (CAMA), the CAP Update addresses remediation of affected groundwater associated with the active ash basin, the ash storage area, the former Units 1-4 ash basin, and the Unit 5 inactive ash basin. Corrective action pertaining to the active ash basin and the ash storage area includes groundwater extraction and clean water infiltration within the excavated footprint of the ash storage area to address constituents that have migrated beyond the geographic limitation. The geographic limitation is defined as 500 feet from the ash basin waste boundary, at the property boundary, or the boundary of a water body, whichever is closer. Proposed corrective action pertaining to the former Units 1-4 ash basin consists of phytoremediation trees and tree wells north and northeast of the former ash basin. Proposed corrective action pertaining to the Unit 5 inactive ash basin includes groundwater extraction and a source control trench northeast of the ash basin to address constituents migrating toward the geographic limitation. Page 2-12 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 3.0 SEEPS TO BE ADDRESSED Seeps were evaluated for disposition based on the physical status, chemical composition, and jurisdictional determination as described in previous sections of this report and listed in Section 2.4.3. Any seep not certified as dispositioned shall be characterized for management in a manner that will be sufficient to protect public health, safety, welfare, the environment, and natural resources (SOC Section 2.d). The following seeps have not been dispositioned and do not currently meet criteria to be dispositioned: • S-02, S-18, S-19, and S-19a — Seep characterization analytical results indicate that only the hardness value is greater than 02B standards (Tables 2 and 3). However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1 , located in the Broad River downstream of all seepdischarges ( Su ) g from the Site, indicate that reported hardness values are less than the 02B standard. • S-03 — Seep characterization sampling data indicate that hardness, sulfate, TDS, and dissolved cadmium are greater than 02B standards (Tables 2 and 3). However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their 02B standards. • S-10, S-11, S-29, S-30, S-32, S-36, and S-38 — Seeps were unable to be sampled during the seep characterization sampling event. Current analytical data is not available. However, the quarterly SOC monitoring data collected at instream monitoring location C_1_DN, located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. • S-23 — Seep characterization analytical results indicate that only the pH value is outside the range of 02B standards (Table 2). However, as discussed in Section 2.2.1, the reported pH is within the range of calculated groundwater background values for the Site. Furthermore, pH is less than the 02B standard at the SOC instream monitoring location C_1_DN, downstream of all seep discharges from the Site. Page 3-1 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 4.0 CONCLUSION In accordance with requirements set forth in the SOC, SynTerra (on behalf of Duke Energy) performed an evaluation of all seeps downgradient of the ash basins at Cliffside. The purpose of this evaluation is to determine seep status with regard to the preliminary JD and characterization of those seeps not dispositioned after decanting of the active ash basin. The evaluation included: • A comprehensive survey in March 2020 to identify any new seeps downgradient of the ash basins after decanting and to document the physical characteristics of previously identified seeps • An evaluation of May 2020 seep sampling data, for constituents listed in Attachment B of the SOC, to determine whether any constituents are present in non-dispositioned seeps that have the potential to be considered for corrective action based on comparison to applicable 02B surface water standards • A review of preliminary jurisdictional stream and wetland determinations at the Site Based on the findings from evaluations presented in this report, the following conclusions have been developed: • Fifteen seeps (S-01, S-05, S-08, S-09, S-12, S-13, S-17, S-20, S-22, S-24, S-25, S-26, S- 33, S-34, and S-35) remain in dispositioned status as determined by DWR at issuance of the SOC. • Thirteen non-constructed seeps (S-02, S-03, S-10, S-11, S-18, S-19, S-19a, S-23, S-29, S-30, S-32, S-36, and S-38) remain non-dispositioned. • Pursuant to National Pollutant Discharge Elimination System (NPDES) permit NC0005088, approved July 13, 2018 and effective September 1, 2018, discharge flows from constructed seeps S-04 (Outfall 104) and S-06 (Outfall 106) will be monitored per permit requirements. • Inspections have identified eight seeps (S-14, S-15, S-16, S-21, S-27, S-28, S-31, and S-37) that are candidates for dispositioning based on dry or non-flowing conditions observed at those locations for at least three consecutive quarters. • Two seeps (S-07 and S-39) are candidates for dispositioning based on analytical results that indicate they are not impacted by flow from a coal ash basin. Page 4-1 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra • The quarterly SOC monitoring data collected at instream monitoring location C_1_DN (Figure 1), located in the Broad River downstream of all seep discharges from the Site, indicates that all Attachment B constituents are less than their respective 02B standards. • With concurrence from the Director of the NCDEQ DWR on seep jurisdictional and dispositional status and instream 02B standards compliance, it could be determined that corrective action may not be warranted at any seep locations at Cliffside. Page 4-2 T Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 5.0 REFERENCES Amec Foster Wheeler (2015). Natural Resources Technical Report- Cliffside Steam Station - Cleveland and Rutherford Counties, NC.June 2015. Duke Energy (2016). Standard Operating Procedure for Seep Sampling. March 2016. North Carolina Department of Environmental Quality (2018). Special Order by Consent EMC SOC WQ S17-009. April 2018. SynTerra (2019). Corrective Action Plan Update—Cliffside Steam Station. December 2019. SynTerra (2020).2020 Final Seep Report—Cliffside Steam Station. May 2020. Page 5-1 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra FIGURE 1 • /• ' ( / aA a LEGEND . nq" .. AREA yS NPoE9 CONSTRUCTED SEEP N1' A e • NON CONSTRUCTED SEEP '}- • OSPOSRpNED SEEP I ` C WSTREAM SURFACE WATER LOCATION PER SOC f ~mil ��aw+^ °y _ —ASH BASIN WASTEBOUNDARV ,' / \ -�ASM STORAGE AREA BOUNDARY —.DUKE ENERGY CAROLINAS PROPERTY ONE 0�p—�STREAM IAMEC NRTR 2015) T�WETLAND CAMEO NETS ROCS) • 31 SPECIALORDER BY CONSENT(SAC)INSPECTION AREA / SURFACE WATER FLAN DIRECTION ••••••• ,__,... _ rmt ..,.....N...,.....N. 4 we aED .P EaO _a cOMSENT IsoDn�AT o.�weoescR s®.E.oaxTo I,009 RF„E,.T«Ars,Re,M F>:.,roRE GENT FIED,D,AOENTrosA,IM k'y ` R R M T wAT aM SYSER IwDEe.DDARDNS - . ---* ERTUNDSANDSTREAMS BOUNDARIES EERE=TIEDFRDM STREAM AND ':: wsER«EE RNR NFN, \-� N N M REST 7 PROPERTY BOUNDARY FRO>DEOBY UKEENERGY CARO.NA, - �° •. STNEW.TENSOFTNEusDE�NEATON„.sNOTSEEN.PRROYEDs.TNE \\ \` gAYOMN16A9AAERM0TCSBO AaY Is AOME MAP ON `' , ••� ,/ P,AN"R025RO a VEZIEET Ab3327.5=MOFMORTNOARa,M..E,. FIGURE 1 0 r,' ( "'' < ENERuY �>• A << SEEP LOCATIONSANO INSPECTION AREAS SEEP CHARACTERIZATION REPORT /••� 1 .a.- ROGERS ENERGY COMPLEX r- !1 µ 1 �,,'. �, (CLIFFSIUE STEAM STATION) / \ ` syfl d »,ME srIOUA2P P MOORESBORO,NORTH CAROLINA Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra TABLES TABLE 1 SEEP LOCATIONS AND DESCRIPTIONS-MARCH 2020 INSPECTION SEEP CHARACTERIZATION REPORT ROGERS ENERGY COMPLEX-CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESSORO,NC Location Coordinate. Receiving Fscil ty Swaps ID Waterbody Description""" SOC Monitoring Interim Action Leval Notes from March 2020 Inspection Latitude LongHtrde WebrOotly Classification Steady flow within 3 toot wide stream touted northwest of Iron oxidizing bacteria apparent on substrate near the outlet of Cllflslde S-01" 35.215639 -81.775344 Broad River WS-Iv ante S inactive ash Eosin. NA-Seep Dispositloned NA-Seep Dispositloned the draw.Steady flow consistently observed within a well- defined channel. Seep drainage in wetland area via 1-2 foot wide stream pH 5-10 S.U. channel,located north of the Unit 5 inactive ash basin. Hardness 800 mg/L Monitoring at established UT II*Bread Drainage collects seep flows from 5-18,5-19 and 5-19A. Mercury 0.1 pg/L Row is steady and dear.Orange aerobic bacteHa/floc/iron- Cliflsitle S-02 35.217217 -81.]68678 Nver WS-N Flows north to the Broad River at a point approximately 50 Duke Energy 5-02 Sulfates 500 mg/L oxidation apparent on substrate. feet downstream of the former Unit 5 inactive ash basin monitoring site TDS 1000 mg/L discharge outfall. Thallium 0.5 pg/L Three pipes observed from the bank.Two pipes are 6- Minor seepage and groundwater influence from former Units terracotta and are dry.One pipe Is a 30'cortugated steel pipe Cllffside S-03 35.22001 -81.7577 Broad River WS-N 1-4 ash basin area to sample point within former condenser Broad River Instream NA-20 Standards that has corroded at the base.Seepage emerges from the circulating water discharge anal for retired Units 1-4. Monitoring Apply bank below the pipe.Flow is steady from below the steel pipe and orange aerobic bacteria/floc/Iron-oxidation Is apparent on substrate.White precipitate observed. • CliRslde S-05" 35.218147 -81.749844 Broad River WS-IV Diffuse flow emerging horna small area along the banker NA-Seep Dispositloned NA-Seep Dispositloned No flow or wetness observed. the Broad River and base of the active ash basin. • UT[v Broad Steady,clear and braided flow in a relatively level area Monitoring at established Flaw Infiltrates a[berm between river and Me seep.Overland Clif aide S-07 35.218642 -81.745975 River WS-N northeast of the active ash basin at edge of property lire. Duke Energy 5-07 pH 5-10 S.U. flow discharge to the river was not observed. • Flow Is north to Broad River. monitoring she CliRslde S-08" 35.208547 -81.755781 Suck Creek WS-IV Natural conveyance tributary to Suck Creek NA-Seep Dispositloned NA-Seep Dispositloned Silty and sandy substrate with no apparent floc/Iron-oxidation. Similar to previous inspections. CliRslde 5-09" 35.217122 -81.754244 Sock Creek WS.N Minor,diffuse flow to Suck Creek near confluence with Broad NA-Seep Dispositloned NA-Seep Dlsposlooned Flow observed on rock face entering Suck Creek.Orange River. aerobic bacteria/floc/iron-oxidation apparent on substrate. Seep located near bank of Broad River,adjacent to former Braided flow from 4 to 5 locations.Sandy and silty substrate Broad River Instreaat NA-28 Standards • CliRslde S-10 35.219472 -81.756731 Broad River WS-IV Units 1-4 ash basin.Minor flow in distinct or braided with apparent orange aerobic bacteria/floc/Iron-oxidation. channels. Monitoring Apply (Seep no longer considered disposltloned due to flow.) Seep touted near bank of Broad River,adjacent to former Sandy and silty substrate with slight orange aerobic OMside 5-11 35.2194 -81.756617 Broad River WS-N Units 1-4 ash basin.Minor flow In distinct or braided Broad River Instream NA-28 Standards bacerla/floUlron-oxidation observed.Flow race Is a trickle with ciannals. Monitoring Apply seepage from 3 or 4 locations below rip-rap.(Seep no longer considered dispositloned due to flow.) Diffuse seepage to area of wetness with no defined channel Water relatively dear with flow at a trickle.Orange aerobic Cliffside S-12" 35.217658 -81.7517E13 Broad River WS-N on bank of Broad River below ash storage area.Area of NA-Seep Dispositloned NA-Seep Dispositloned bacteria/floc/Iark an datlon apparent on substrate.Flaw wetness does not reach surface waters. emerging from bank and flowing toward,but not reaching the Broad River. • Minor flow was located at bank of Broad River,adjacent to CliRslde S-13"" 35.218353 -81.754942 Broad River WS-IV former Units 1-4 ash basin.Following ash basin excavation, NA-Seep Dlspositioned NA-Seep Dlsposltbned No flow or wetness observed. seep has disappeared. Seepage located along toe of the active ash basin upstream Suck Creek Instream NA-28 Standards Offside S-14 35.214511 -81.755844 Suck Creek W5-IV dam.Area.No Rowing water observed.Any lbw would move Monitoring Apply Pooled water by sign,but no now[vivant Suck Creek. toward Suck Creek. • Second seepage area located along toe of the active eon Suck Creek Instream NA-26 Standards Offside 5-15 35.214297 -81.756117 Suck Creek WS-IV basin upstream dam.No flowing water observed.Any flow Monitoring Apply No flow or wetness observed. could move via poorly incised channel toward Suck Creek. Third seepage area looted along toe of the active ash basin Sufic Creek Inztream NA-2B Standards Clifhide S-16 35.2191 -81.756208 Suck Creek WS-IV upstream dam.Any minor flow could move via channelized Manitpnq q No flow or wetness observed. area toward Suck Creek. g pp y TABLE 1 SEEP LOCATIONS AND DESCRIPTIONS-MARCH 2020 INSPECTION SEEP CHARACTERIZATION REPORT ROGERS ENERGY COMPLEX-CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC Location Coordinates Receiving Facility Semple ID RecWNeiving irbod Watarbady De•cAPtien • SOC Monitoring Interim Action Levels Notes from March 2010 Inspection 'anew. Longitude y ClaaaKlwtion Offside S-17•• 35.217192 -81.769272 Broad River WS-N Minor seep at river edge and below the ordinary water NA-Seep Disposltloned NA-Seep Disposllloned No flow or wetness observed. level of Broad River,west(upstream)of 5-02. UT to Broad Seepage from npraP at toe of Unit 5 Inactive ash basin main Monitoring at S-02 Flow converges to create 5-02,then on to Broad River.Orange Offside 5-18 35.216439 -81.768564 River dam.Flows north Into wetland area draining to sampling site monitoring site Sea 5-02 aerobic bacteria/flaUiron-oxidation apparent on substrate. 5-02. Seepage from wooded area at toe of Unit 5 Inactive ash basin UT to Broad Monitoring at 5-02 Flow converges to create 5-02,Men on to Broad River.Orange Cllflside 5.19 35.216361 -81.768681 River Flows nor area main dam.Flth Into wetland draining to monitoring site Set 5-02 aerobic battens/floc/iron-oxidation apparent on substrate. sampling site 5-02. Seepage from wooded area at toe of Unit 5 InactlW ash basin Monitoring at S-02 Flow converges to create 5-02,then on to Broad River.Orange Offside 5-19A 35.216581 -81.769217 Broad River WS-ry main dam.Flows north Into wetland area draining to monitoring site See 5-02 aerobic bacteria/Roc/Iron-oxidation apparent on substrate. sampling site 5-02. Cliffside S-2044 35.215856 -81.765217 Broad River WS-N Stagnant seep at toe of Unit S Inactive ash basin saddle dam. NA-Seep Olspotwoned NA-Seep Dlspositloned Seep not visible In area of rip-rap repair.Water exists ditch Seep dlspasitloned via repair. farther downgradient near the cooling tower. Seep located along toe of the active ash basin upstream dam. Suck Creek Instream NA-2B Standards Offside 5-21 35.214625 -81.755953 Suds Creek WS-IS Area of wetness-no flowing water observed.Any flow would Monitoring Apply No flow or wetness observed. move toward Suck Creek. Offside 5-22•• 35.218278 -81.748258 WS-IV Pipe has been plugged;discharge eliminated. NA-Seep Disposltioned NA-Seep DlsposNoned Mpe IS plugged and not visible,no discharge. Soap to pooled area adjacent to the Broad River,located Fended water present at seep emergence.Visible Rows Offside S-23 35.217994 -81.750208 Broad River WS-ry north of Me active ash basin.Minor seepage from pool Broad River Instream NA-2B Stantlaros reaching Broad River to the east of where this flow is casualty emerges with any minor flow draining north to the Broad Monitoring Apply observed. River. Offside 5-24• 35.218139 -81.749428 Broad Rover WS-ry Minor seepage near bank of Broad River and north of acme NA-Seep DlsposMoned NA-Seep Dispositloned Sandy and silty substrate.Stable with less flaw than usually ash basin. observed.Flow reaching the Broad River. Minor seepage north at ash storage area.No measurable flow Wet with flow near the placard,then Infiltrates the ground Cllflside 5-25•• 35.217689 -81.751894 Broad River WS-N has been observed throughout site history. NA-Seep Dlspositioned NA-Seep Dlsposiboned prior to readying the Broad River. Less flow fhan previous Inspections. Seepage from steep bank and eroded head cut near bank of Sandy and silty substrate with rock outcrops.Flow is a trickle OIH'de 5-26• 35.217425 -81.753931 Suck Creek WS-IV Suds Creek. NA-Seep Disposltloned NA-Seep oisposiboned emanating from rock outcrop.Flow in channel does not enter Suds Creek. Seep located along toe of the active ash basin upstream dam. Suck Creek Instreem NA-2B Standards Offside 5-27 35.21383 -81.756478 Suck Creek WS-W Area of wetness-no flowing water observed.Any flow would Monitoring Apply No flow or wetness observed. move toward Suck Creek. Cliffside 5-28 35.211677 -81.753876 Suck Creak WS-IV Minor diffuse groundwater seepage along steep Dank of Suck Suck Creek Intreem NA-2B Sta ndards No now or wetness observed. Creek,west of the active ash basin. Monitoring Apply Minor diffuse groundwater seepage along steep bank of Suds Suck Creek Instreaw NA-28 Standards Fbw is lo and dear.Orange aec Dacteria/fiuc/iron- OiRside 5-29 35.211542 -81.753993 Suck Creek WS-N oxidation w apwrent on substrate.lerobiss flow Man previous Creek,west of Me active ash basin. Monimrirg Apply Inspections;water trickles over rock to Suck Creek. Minor d0100e groundwater see Ion steepFlow discharges across several areas toward Suds Creek over Offside 5-30 35.211496 -81.75391 Suck Creek WS-N 9roun page Wong bank of Sufic Sufic Creek Intreem NA-2B Standards rocks and as drip faces along the bank. Less flow than Creek,west of the active ash basin. Monitoring Apply previous inspections. Offside 5-31 35.211482 -81.753887 Suck Creek WS-N Minor diffuse groundwater seepage along steep bank of Sufic Suck Creek Inrtream NA-28 Standaros No flow or wetness observed. Creek,west o/the active ash basin. Monitoring APPly hreia3 • TABLE 1 SEEP LOCATIONS AND DESCRIPTIONS-MARCH 2020 INSPECTION SEEP CHARACTERIZATION REPORT ROGERS ENERGY COMPLEX-CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC Loatlon Coordinates Bac I I Receiving — Facility Sample ID Wabrbedy doodad on r SOC Monitoring Interim Action Lanais Not.from March 2020 Impaction Latitude Longitude Wat 'IdY Classification 011ldde 5-32 35.211258 -81.753646 Suck Creek WS-IV Minor diffuse groundwater seepage along steep bank of Suck Suck Creek Instream NA-2B Standards Area Is wet but not flowing.Wetness does not reach Suck Creek,west of the aNve ash basin. Monitoring Apply Creek. Seep was located at bank of Broad flyer,adjacent to former Offside S-33r' 35.218272 -81.754754 Broad RWer WS-IV Units ash basin.Following ash basin excavation and NA-Seep Dispotltinned NA-Seep Dlspositioned No flow or wetness observed. construction of NPOES outfall structure,seep has disappeared. Cliffside S-34r 35.217556 -81.753725 Suck Creek WS-N Seepage front steep bank and eroded head cut near bank of A Seep Dispositloned NA-Seep Dispositioned No flow or wetness observed. Suck Creek. Infiltrates prior to entering tributary.Sandy and silty with Clifside S-35r 35.208203 -81.755703 Suck Creek WS-IV Natural conveyance near bank of Suck Creek. NA-Seep Olsposltloned NA-Seep Dbposltloned minor amounts of iron-oxidizing bacteria observed at the confluence of the tributary. Minor diffuse groundwater seepage along bank of Suck Suck Creek Instream NA-2B Standards Offside 5-36 35.210258 -81.753983 Suck Creek WS-N Creels,southwest of Me active ash basin. Monitoring MDh Steady Sickle flow from three drip faces. Seep located approximately 20 feet downstream of 5-36 and Cllf/slde 5-37 35.210266 -81.753827 Suck Creak WS-IV southwest of the actve ash basin.Flow emerges 25 feet from Suck Creek Instream NA-2B Standards Notable iron atalning and floc present.Ponded water at point Suck Creek as standing water whldh becomes shallow, Monitoring Apply of amanatlon but no flow toward or Into Suck Creek. flowing,and somewhat diffuse as it flows toward Suck Creek. Seep emerges near the ordinary high water mark of the Cllffsltle S-38 35.217759 -81.752742 Broad River WS-N Broad River north of the active ash basin.Flow Is low and Broad River Instream NA-213 Standards Flow Is low and not apparent when river levels are high.Iron travels through multiple channels In sandy shoreline Monitoring Apply staining Present on sandy substrate.Flaw reaches Broad River. substrate toward the Broad River. Soaps Diocorared Darin"2020 Impaction Flow emerges from three locations along bank of unnamed Flow emerges from three locations along bank of unnamed UT to Broad Broad River Instream NA-2B Standards Offside 5-39 35.217759 -81.752742 RiverWS-N tributary to the Broad River.Flow is a trickle from each Monitoring Apply tributary to the Broad River. Flow is a trickle from each emergent point. emergent point.Insufficient volume to sample. NPDES Loratluna Seepage from bank downgradient of active ash basin and ash Steady flow consistently within a well-defined rip-rap channel. Outfall 104 35.21]641 -81.752596 Broad River WS-N Discharge Limlt storage area to a channel flowing toward the Broad River. NA-Monitored per Terms NA-NPDES Permit Offside Silty and clayey sand beneath rip-rap.Orange aerobic (formedy 5-04) Outfall has been Improved with riprapatlons reinforcement along of the NPDES Permit bacteria/floc/Iron oxidizing bacteria apparent on rip-rap banks and flows through a V-notch weir. Apply substrate along channel. Steady stream with moderate flow volume within well-defined NA-NPDES Permit Steady moderate flow.Water Is dear.Seepage observed at toe Outfall 106 NA-Monitored Per Terms of the dam at/near the rip-rap pile.Vegetation conceals some Olffdtle 35.21844 -81.748266 Broad River WS-N channel at toe drain for active ash basin downstream dam, Disdurge Limitations (formerly S-O6) near the confluence with the Broad River, of the NPDES Permit Apply flaw.Orange aerobic bacterial/floc/iron-oxidation oxidation apparent on substrate along channel,especially apparent in eddies. Prepared by xor Camel by:GTC kens.dr.SAS Checked p:TIG .,orcN • a �a.no.arre •• bey updated!ram ate Original nrd mwwthe oC uummant Avuek ror accuracy anatn mtnI ed.ed m ner NA riot Applicable SOC Specal kJ, unn.,nea Aare t ofr TABLE 2 SEEP SAMPLING RESULTS-MAY 2020 • SEEP CHARACTERIZATION REPORT CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC net,ea warre. .11.1.0.5.51.NOM=(TOTAL C.150111113.11,001) WNW. OW41* wane.Fweenw we T.•••••••• illonana • nen1WW. new Are* 64.0 Saw M.. CaleNan MM.Ow.. 1.11.rms..WNW.awnedease Oat. pnommbi mmm ••• m•Pmfm. mML •nr am mho arm_ y0/L e/1. N.1. ./1. ww/l. 41.1. ann. nagn. Lost.01 LanWen I. $nd. 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U.5 triad..1.41 Wan 3021631.e .61.756141109 05/11/2020 10 333 147 352 19.5 4.91 <1 57 131 <190 <0.1 .1 4.6 1.07 <1 <O./ 5.1.95 Wooded area N to•Man 4.1. 1,5 5 Inart...51 Warm' 33.21431390 .41.769941. 05/11/2020 6.3 16 317 7.65 157 31.2 0.1 ILI <1 53 115 <200 <O./ 71 6.4 <1 .2 11 01 Mr Wawa.,.01 aver An.AN 0Wn Wear 35.211110511-01.74904201 05/12/202.3 15 10.90 164 .2 2. 0.19 <1 00 131 DO <0.1 7.55 II 2.311 <0.I .2 W e11/11 AS.Mene to 0.0 Una 5 Iracen.11.11 W.. 352134 41.77385 05/111211. 07 15 11-21 110 323 15.7 1.37 <1 35 <Al <1.00 <OA 2.35 02 1.40 <1 <ILI 11.9 SOL 01.51112014 04.1.0 LOCATION 9101.111411/1.11.1.1110 ...545.M.N.OWNS 50115.1.11.0141 II mmm I 35.2190800I-1111.739KLIM I9.30020 05 I 07 I 1145I I 151 I ..1II I<H I 1. I no I 4.13 I Co I <I I <1 I 00.1 I 17.2 139 SAW.WW1. POLO 1.114.1401111. 0nN,0fl10Li1 0171.1101412W111.011310) Mg FINS Wank 100.2 011/12/1020 . NM NM NM NM NM N14 144 NA NA 1. MMMMM - 00/11/2020 11/4 NM 1114 VW NM NS MN /09 later sank 1.0-05._ ./12/2020 NM N14 11011 1N4 NM MMM latt /Ip Wan 95/12(2020 1N4 1114 WI NM NM NoSan ' fossoloca Oxygen and<timidity are nOt requIrea paraineters per SOL Attacnowolt 5. -Mercury stana•rto of 0 0 L2o9/1.momenta a ohm.,value. 0.solo ea chrohourn seandand of II us,reprosen.a.ran,Yalu•speak dlasolVed chromiuM 121aaolved chromnan male. haranan..wmant a.an wan.,rri 7.14 DisatOlVis1 chromium conowntraflor.horn Me May.20 sampan°avant reprasent total dissotred chromium conarratIons. =aioe ho,rnt.cella indicate ooncentoations greater IN,fop..conearycieve I re,.Ac 02.,c]aaa voS,eundamig.mantrad oxygen ane nannolan.l.indicate Is nuc 028(gam alanaaras. ISA NOAC 020(Class C.WS-1,41-ISA IICAC On.0200 Sa.anIrpc Can C,WS-IV Sui/ao•wawa el Tanpet analytic.diconed,n meth.piano at or abova Oa reporting Tanpat concentrabon sawn.war nag.aan 1911 the caolcantration,n method Wank.4ialyte oancentrabon nano ea not irlf•clici by...no contaminabon. .0,e“ G.•pnons anon •1.1.5 02S(Om C,WS-151 lartana nranrant ea:*on calculatbn using actual Ln-aolown Kann.nine.sem rable 1. ,rnnewon-anon.,Per -aware.par lur ask-millionths par at. NA.Not anatyotal NCAC-Nom, AOrranistrallve Code nE•Nor entanan. nn-nnt measurea -NapholomotrIc Tannin units SOC-aralai Oran ay Consent • raw.12 TABLE 2 SEEP SAMPLING RESULTS-MAY 2020 SEEP CHARACTERIZATION REPORT CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC uuLTnw MMLTO(TOTAL LONC1.1.1W1340 n(01500219.0 CoNCSNTYTION) TM. Tata S.NTaui O..wer z..S NOSax.. Haw{ NMN . NNrr 5w.r n01Sr..o.wW.P S F.rS.S v.L uw10 (9.19) a8.4.) (0..10 la NMM ar. (SwO.) (au.) IaMN) l5.uy)(o..aN)laM.)(aMP) P.wNy.. AWL 911E2 M/L M/L mPN/L OWL Ns .NEL M/5 .105 .YL M/L M/L M/L AWL M/L M/L AWL AWL [U lain2O Iae.S..O..ON.r SwbM UDR W �. LWrOal.r.. WMMiNwb a r rvnp MIMI < Mill0 ui. < 5/.1020 <1 1.5 < el < < 5-10 Maw rN rata.01135.9. << < << .: ; E m 9.0.1 Rear Ufa Inatire 5ssin Water 253154 e!IU U e .001St1x <5 <.(TOTAL<xn.ODTTMTION55CONLSNTMna11.1n5n02O 0.215 I 1.. 0..1.I .11 m�I V n. I . 3 5.5 I 4O.2 I 55 I . I <5 <I .02 I Pw I I <O.2 I .5 yC lP.RS P55u5nANALVTICAL RESULTS(TOTAL CONm0TR.5TION) 111111LRICILL MOULTS(05MOL090 CONm.TPAnON) rq 21.0 eww m-ox -• .-- -•• 05//42010 NA NA .0.905 T,y N.N, _. _ waw -- ... 55/12n020 Nx M 40.00. Nn NA NA AL NA NA N. NA NA NA NA N5 NA NA NA ALPram.n p:726 Ch.M.INC e19wnot w.a4n w 90C MAMA.B. 291/rt NiOneee. chronic.N 10 mat Atear . anaN.Wt..at ...aq.e a ISO 1 M L M.O. .O 2*5*0*0 ?.w.a1mnN.r..we(LOT?r..10000 dver m(0*0 C.W..9).+101t.* 00(0010 N.O.505*0em. 000005 o..N.emm.wmrmnenoN15 NCACw)0 2020(C,0mwOw«.N nOra.m mrN a®N.e ammw�n m.ronrw.. i.TIPS.a 9 a as mir...0 n..ra a. Ilm.as mnwr.NW.15 NC AC OZS(a..C.ws rv)Nuq.ra.Orq.N o.yo.n rare 5N ngnig0m uiN iiwue mrmOwam is ONn pgwp.mwr.wW.1s ncwc oxf(ae c,ws-rvl.mnOxm. a.2.0aer.O.MWa C. ze(Om<,WSM•MxCio2 fltoosvq.SP.o.c,TwatSUN0 MN. -.O.n.Cab.O.S.manOe eun.a.aa..a.navtNp Orria TvOnaW..uvNNSm q.MpNaOW.>0r.n lOx..mivw5.n g5r..rau.x MAIL nruM.meumw.n q..mW.arwt ame.e h blank mam.nm Op C•e.11on.0 e uc0.n poNrraN n SWNM par mlnuta ox0 Mass 4 wf-M+m.e.q 0 nWnw Mone.ra Owe on ognNNn mqf.Oua.-awur NwOr.au..Sr Nmx.Wan•2.1n pranerwNr .2•944999 Pa xm laa 90-92-miNa.n w.w MOi. NE-Nat alteNis. Neu-Nyn.m.acnrmeq um+ 50C-5.161 Ora.by Cm.M 5.U.-M mnam umm TABLE 3 CALCULATED 02B HARDNESS-DEPENDENT STANDARDS SEEP CHARACTERIZATION REPORT CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC Cadmium(Dissolved) Chromium(Dissolved)* Hardness Value Hardness Value In-Stream Calculated 028 Calculated 025 Cadmium In-Stream Calculated 0213 Calculated 028 Chromium Used for 0213 Used for 025 LootlOn ID Hardness Calculation Acute Standard Chronic Standard (Dissolved) Location ID Hardness Acute Standard Chronic Standard (Dissolved) (m9/L)3 (p9/L)3 (p9/L)' (p9/L)° Calculation (mg/L)' (m9/L)' (m9/L)' (p9/L)' (p9/L)' (p9/L)` 5-02 215 215 5.33 0.76 imi<0.1 5-02 215 215 1066.50 138.73 <1 S-03 554 400 9.15 1.20 5-03 554 400 1773.30 230.67 <1 5-07 14.1 14.1 0.50 0.10 <0.1 S-07 14.1 14.1 114.53 14.90 <1 5-18 216 216 5.36 0.76 <0.1 5-18 216 216 1070.56 139.26 <1 5-19 185 185 4.68 0.67 <0.1 5-19 185 185 942.99 122.66 <1 5-19A 280 280 6.71 0.92 <0.1 S-19A 280 280 1324.09 172.24 <1 5-23 42.2 42.2 1.29 0.22 <0.1 5-23 42.2 42.2 281.08 36.56 <1 5-39 11.9 11.9 0.43 0.08 <0.1 S-39 11.9 11.9 99.67 12.97 <1 C_1_DN 17.2 17.2 0.59 0.11 <0.1 C_1_DN 17.2 17.2 134.77 17.53 <1 Copper(Dissolved) Lead(Dissolved) In-Stream Hardness Value Calculated 025 Calculated 020 Co Hardness Value Used for 028 Copper In-Strum Calculated 020 Calculated 0213 Lead 0213 Location ID Hardness Acute Standard Chronic StandardUsed for ion Calculation (Dissolved) Location ID Hardness Acute Standard Chronic Standard (Dissolved) (n39/L)' (p9/L)' (p9/L)' (p9/L)` m /L)' Calculation (m9/L)' ( 9 (m9/L) (p9/L)' (p9/L)' (p9/L)` 5-02 215 215 27.64 17.23 <1 5-02 215 215 146.99 5.73 <0.2 5-03 554 400 49.62 29.28 <1 S-03 554 400 280.85 10.94 0.924 5-07 14.1 14.1 2.12 1.68 <1 5-07 14.1 14.1 7.26 0.28 <0.2 5-18 216 216 27.76 17.29 <1 5-18 216 216 147.71 5.76 <0.2 5-19 185 185 23.99 15.15 <1 S-19 185 185 125.31 4.88 <0.2 5-19A 280 280 35.46 21.59 <1 S-19A 280 280 194.09 7.56 <0.2 5-23 42.2 42.2 5.96 4.28 <1 S-23 42.2 42.2 24.96 0.97 <0.2 5-39 11.9 11.9 1.81 1.45 <1 5-39 11.9 11.9 5.98 0.23 <0.2 C_1 ON 17.2 17.2 2.56 1.99 <1 C_I_DN 17.2 17.2 9.10 0.35 <0.2 Page 1 of 2 P TABLE 3 CALCULATED 02B HARDNESS-DEPENDENT STANDARDS SEEP CHARACTERIZATION REPORT CLIFFSIDE STEAM STATION DUKE ENERGY CAROLINAS,LLC,MOORESBORO,NC Nickel(Dissolved) Zinc(Dissolved) In-Stream Hardness Value Calculated 02B Calculated 02B Nickel In-Stream Hardness Value Calculated 02B Calculated 02B Zinc Used for 02B used for 02B Location ID Hardness Acute Standard Chronic Standard (Dissolved) Location ID Hardness Acute Standard Chronic Standard (Dissolved) Calculation Calculation (mg/L)' (m9/U' (pg/L)3 (p9/L)' (pg/L). (mg/L)' (m9/L): (p9/L)' (pg/L)' (P9/L)' • 5-02 215 215 894.76 99.38 8.96 5-02 215 215 224.15 225.98 <5 5-03 554 400 1512.89 168.04 162 S-03 554 400 379.30 382.40 302 5-07 14.1 14.1 89.27 9.92 <1 5-07 14.1 14.1 22.28 22.47 <5 S-18 216 216 898.28 99.77 15.5 5-18 216 216 225.03 226.87 7.78 5-19 185 185 787.94 87.52 <1 5-19 185 185 197.35 198.96 <5 S-19A 280 280 1118.82 124.27 3.69 S-19A 280 280 280.37 282.66 <5 5-23 42.2 42.2 225.67 25.07 1.54 5-23 42.2 42.2 56.41 56.87 <5 5-39 11.9 11.9 77.34 8.59 <1 S-39 11.9 11.9 19.30 19.46 <5 C_1_DN 17.2 17.2 105.61 11.73 <1 C_3_DN 17.2 17.2 26.37 26.59 <5 Prepared by:IL Checked by:2PC H9W1 '-Actual in-stream hardness analytical result from May 2020 sampling event '-Hardness value used for calculation based on regulation In 15A NCAC 02B.0211(11)(d) 3-Calculations for 0213 acute and chronic hardness-dependent standards were performed in accordance with calculations presented in Table A of 15A NCAC 02B.0211(11)(d) '-Analytical result from May 2020 sampling event '-Calculated hardness-dependent dissolved chromium values are specific to Chromium(III).The standards for dissolved Chromium(VI)are not hardness-dependent and are equal to 16 pg/L(acute)and 11 pg/L(chronic). Analytical results from the May 2020 sampling event represent total dissolved chromium concentrations. ®-Blue highlighted cells indicate concentration greater than applicable calculated acute or chronic 02B standard. -Concentration not detected at or above the adjusted reporting limit. 02B-North Carolina Administrative Code Title 15A,Subchapter 028-Surface Water and Wetland Standards pg/L-micrograms per liter mg/L-milligrams per liter Page 2 of 2 Seep Characterization Report July 2020 Rogers Energy Complex—Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra APPENDIX A MARCH 2020 SEEP PHOTOGRAPHS Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE 300 330 0 30 60 . I • I • I • I • I • I • I • I • I • I • I • I • I • I ® 353°N (T) OO 35°13.004'N, 81°46.481'W ±16ft ♦ 686ft Yt'4 1�'.,,� " ytic t�-t ',, s .. "{i,+ • _ ate,, y" .z t' �Y v " ,i,. min�rw :a'' 'f� Y.: '�jr wee; ,�i ter,,, z-44xi, F 1 dery ...0.4104r, . ..„ rf i t ' pra s.- q A.O. Ill/. S_1 :` tyy tl: ''� fir �e .L ,Y, f ,,i it ' 30- . „„I 04140, Q,t2"4Q, Y, S-01 View of dispositioned seep location facing north. ' Page 1 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra 1! N NE E 0 30 60 90 120 0 54°NE (I) OO 35°13.030'N, 81°46.127'W ±16ft A 656ft I"' , . ., ,, � ,_ :t. A A r +Y1 d r `"„tom a ,,,, :.� : t t -! S c 2 14,. A • it�N i ;s{; M ♦ '` : -fit - 2/. N I $ v 020, 14:18:02 S-02 View of seep and SOC sample location facing northeast. Page 2 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra S : w W 180 210 240 270 • I • I • I • I • I • I • I • 1 • I • I • I • I I • 1 c 224°SW (T) OO 35°13.202'N, 81°45.465'W ±45ft • 683ft 41. ,gig �„•, _ P • f , 4. ♦ _ (_ y x S-03 View of seep location facing southwest. Page 3 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE 0 300 330 0 30 r: 342°N (T) OO 35°13.061'N, 81°45.162'W ±16ft ♦ 648ft t 1, 1,14. ` 7, I i ii.4 1 r , 1► , 4 > ; w s 4 i'. 1 f r 'r r 8 t Outfall 104 View of NPDES Outfall 104 facing north-northwest. (formerly S-04) Page 4 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE 300 330 0 30 60 • 1 • 1 • I • 1 • I • I • i • I • 1 • I • I • I • I_ • I 0 353°N (T) CD, 35°13.083'N, 81°45.078'W ±32ft ♦ 642ft f / .d fir +-Aw 7 1- - .?-' • d4 7 ,ter wY" 1 ,, 11 .fir a- .- :�- .. .• ,' it p+f 4d' Y.'"" - ."'+fin �.- H - _ / ,,. , r .t. .t j r "".. �4 • xa. ,.+ a .,*. -. ,,,..4,4.,' 7:‘,.!IN_ ',' ;i64.4 -16 4, 4"4"',, .t. ir.' 7 " -1- „...1,___-:-. .' � i_ f ; *" " - .,- +- Y r `''- 30 Mar 2020, 18:15:22 S-05 View of dispositioned seep location facing north. Page 5 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N GO 330 0 30 NE 60 00 1 • 1 • 1 • 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 . 1 • 0 25°NE(T) OO 35°13.1061N,81°44.899'W±32ft A 672ft t 1 1 - 4 « ,- t I 1 l'P)''' ,*' k s ` 30 Mar 2020. 18 t'... Outfall 106 View of NPDES Outfall 106 facing north-northeast. (formerly S-06) -- •E S S1Y ' W NW . 150 180 210 240 270 300 i • I • I • I • I • I • I • I • I • I • I • I • I • I • I • I • 1 • I ,•, i 0 228°SW (T) OO 35°13.111'N,81°44.756'W ±16ft ♦ 710ft '" *gy p» 30 Mar 2020 18�0:2/ ram . . S-07 View of seep and SOC sample location facing southwest. Page 6 of 55 i Seep Characterization Report July 2020 DukeEnergyCarolinas,LLC SynTerra Rogers Energy Complex-Cliffside Steam Stationyn NW N NE 300 330 0 30 ® 344°N (T) OO 35°12.514'N, 81°45.392'W ±32ft ♦ 788ft v*, 4:• f %� .+ /ice• t—-s i ° ! Ili K 5 8 $: ,. r .,. .wt -, M jk ,. s 'tea. /_ ,rY9r ``� ,§ 3' ' 1ar 2020, 16:1/119 I S-08 View of dispositioned seep location facing north-northwest. ,... Page 7 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SE SW 120 150 180 210 240 s 0186°S (T) O 35°13.044'N,81°45.243'W ±32ft ♦ 676ft Id :*..-44top,:: • - i 30 Mar 2020, 12:1 S-09 View of dispositioned seep location facing south. Page 8 of 55 P Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra E E SE S 60 90 120 150 180 • I • I • 1 • 1 • I • I • I • I • I • I • I • I • I • I 0 114°SE (T) • 35°13.167'N, 81°45.401'W ±16ft ♦ 645ft " c- + , Fir' .it • ,. R X a - ' R~ is S-10 View of seep location facing east-southeast. Page 9 of 55 1 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W W N_. 270 300 I 330 :..lu. • 1 • I • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • I • I • I Ct 14°NW (T) OO 35°13.163'N, 81°45.398'W ±16ft ♦ 642ft _ ;101 , .. t .5 moo, it - _ �p �ti , f ., '')- ,.., d Y^i.' heo. ' — `. .A-. W. _. *1 , to- 1 t. A. .a ur f . °a ➢fib .� 6 s N� F;1 :* t.l. p ' 1 �Y.' , R v+- r- 30 Mar 202 s AA S-10 View of seep location facing northwest. Page 10 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW V NE 300 330 0 30 60 1 • I ' I • I • I • I . I • I • I . I . I • I ) 358°N (T) r 35°13.159'N, 81°45.383'W ±16ft ♦ 658ft 6.4 4 S-11 View of seep location facing north. Page 11 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra .w W NW N 240 27 ; 0 • 1 • 1 • i • I • 1 • 1 • I . 1 . I • I 0 293°W (T) 035°13.162'N, 81°45.390'W ±16ft A 653ft 0011 .vier h l i"" -om' 1154 ,Moa ,.. : t , t •R � ;.. , 4 t A / , k tir ts ti „ F 441 I, ,,., ,, . ,‘ . _ .1 1 44:: '-,. s1 MO7. ' ,. ,,F 020, 11:44:30 5-11 View of seep location facing west-northwest. Page 12 of 55 i 1 2 Seep Characterization Report July 20 0 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE E • 300 330 0 I • I • I • I • I • I • I • I • I • I • I • I • I • I 1 • I • I • i • 012°N (T) 40, 35°13.053'N, 81°45.121'W±16ft • 699ft 11 $tki*# •t M, is i -iota / : � w. -,.' 1,- - --tr. - . • ...,,„..,,-_ . , - ' , 7,.. 0.2: t-- -‘1, A, 1 4*, ' ' 't `fir. : �•' r; 4 \ -- 4, S .._,,:... ,.., ,. ' ,\ • >x**. � S . - ...r-- _-_ , .,, „ ., r 4 iti'";.167,1" ''..,,,_"t'')p.,!...7.-• " , .4 , , S-12 I View of dispositioned seep location facing north. Page 13 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra a 180°S (T) • 35°13.055'N, 81°45.116'W ±32ft ♦ 668ft sic N' 11 . 1.4) -111 it'''';‘110.. ".rr-..:*--1.7,47,r; fgAgiv,,,:l ,,..„,":-' ....4.---"to.':-;1,40,14 , ' W.‘,..,:.. ,,,,„..“ '''' .„ 1„,'") .,,v!,,,,,,,-. - 16'. .twt �F� ��' . , 1 yam\ _ a a `t'''i{t� ;},,` ate k, '` `� {w f, ," •A -=,aye ..tie : Tt- y`t'>:� l'tilt ' xg d "4 +E `�.'91 „, ?,�*' al fit, w. s. 1,,,,, t: i *k 41 ,f ,41 . ./*.T. Yl -/ « r -r. yet. -' \ - ma ~, ` �' ,,IC� '. 1R► r "a. t„ s Mt 5,::i .,, Y'w�41 * <,.. t PPP, • . t f' 4 /1h y �t . 30 ivig- 202-0, 1 5 _ S-12 View of dispositioned seep location facing south Page 14 of 55 I Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra w N NE E 330 0 30 60 90 • 1 • I • I • I • I I • I • I • I I • I • I • I • I ® 23°NE{(T) 0 35°13.107'N, 81°45.300'W ±16ft ♦ 676ft fm)fiiii ,r y V., ,. if,..e .• '5 'm* r,,-, .,4Airt:it*r It , .,y4" lit ....1'..‘e a ` • �.. l O� Y'RJ 8Y S • ' r6' � i«• �� ii. ' i b. i # jimeterk 4 k i''' A .:,..., ' • ) -4 rik4- ., ,„ , , ,„,....,... , „I. i, k Y Ili' ' A. 4 30 Mar 2020 +12:01:40 Y 2. 4 a ? M 1 i ti S-13 View of dispositioned seep location facing north-northeast. Page 15 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W NW N 270 300 )30 0 30 r i • I • I • I • I • I • I • I • I • f • I • I • I • 0 0 o 0 327 NWT 0 35 12.867 N 81 4 4_ ( ) 5 3 3 W ±32ft • 741ft r", + A .... 'apt , �. '. _ t, A .k ,Y. r { aW. • .r ...e., - '. A. �` 4.- .4 S-A 4 7 a.7 t' 1 I 1 1 J Re., 30 Mar 2020. 17:23:38 S-14 View of seep location facing northwest. 1 f Page 16 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SW W NW 240 270 300 330 • I • I • I • I • I • 1 • I • I • I • I • I • I • I • I ® 284°W (T) * 35°12.858'N, 81°45.362'W ±16ft ♦ 745ft . r S-15 pp4 `% - • saknr 4 4. Oki t ,.e aI 3tp. ;n' ,. h ':',t. `:/' '. _ $ ' 41( ,� 'f 4' ' ' g5 � � 4'� '1 / K AAAy¢t {- .y t } y 1r£ P.. ' kRt a`' , n i i t • ' 1... 7 tt 30,�v1 r Z02te'r0, 17'20.36 --- _4 - - S-15 View of seep location facing west. Page 17 of 55 SeepCharacterization Report July p Y 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SW W NW N 240 270 300 330 0 ® 292°W (T) ;i 35°12.858'N, 81°45.364'W ±16ft ♦ 726ft 1 k. a r a.. y. ,x " e y x Y rir it , •, x / r �- f.= ' �,. • .,ti�i 2: a r04,_ s r 4 �.' s , Mar 2q t`' . :30 1 S-15 I View of seep location facing west-northwest. Page 18 of 55 r Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W NW N 240 270 00 330 0 I • I • I . I • I • II I • I • I • I • I • 0 297°NW (T) 4. 35°12.847'N, 81°45.363'W ±16ft ♦ 748ft -. ,� I .0 VV. -16 c • ® n r - �y O ',. " -. "E` t'.. —1'11 3 t- - err . ' ar" ` � '• 30 (Mar 2020 7.18.32'' S-16 View of seep location facing west-northwest. Page 19 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SW W NW 240 270 300 330 I I • I • I • 1 • I • I • I • I • I • I • I • I • I • I • I ® 290°W (T) • 35°12.849'N, 81°45.368'W ±16ft ♦ 735ft 6 < ' i . rs ; , slit , e' > . a,. , ")...'"..t„ . :'4 / :•toms �[y ,fps f+ a.p • S-16 View of seep location facing west-northwest. Page 20 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SIB,' W NW N 240 330 0 I • i • I • i • 1 • i • I • I • I • I • i • t • I • I • ! I • 1 • 1 • 1 • 0 294°NW (T) • 35°13.033'N,81°46.156'W ±32ft ♦ 643ft aw 116. 4 30 Mar 202IA 4 15.09 S-17 View of dispositioned seep location facing west-northwest. SE S SW W 120 1SO 180 10 240 270 301 • I • i • 1 • 1 • 1 • i • I • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 0 207°SW (T) • 35°13.041'N,81°46.159'W ±16ft ♦ 692ft • 30 Mar 2020.09:59.15 S-17 View of dispositioned seep location facing south-southwest. Page 21 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W NW N N 270 300 330 0 30 • I . I • I • I • I . 0 335°NW (T) • 35°12.989'N, 81°46.102'W ±16ft A 664ft • �an j r w .a yy qq 5y p .*f aR ?_ r ) y „ p 30 tar 2020, '1-. 0 S-18 View of seep location facing north-northwest. Page 22 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station Duke Energy Carolinas,LLC SynTerra W NW N N, 270 300 330 0 30 1 • I • I • I • I I I • i • I • I • I I • 1 • I • 336°NW (T) U 35°12.986'N,yy81°46.119'W ±16ft p♦ 672ft : ,..,,, l..„,...... \k, ,. ,tittoStjt;; ,firV4iN,t'''' � K ..V `,4' �� r , , 7 0' - .1.:.`0°'''‘ • /`4t; '''''''.4C`,";7-'1i 9 - ,' . / - \ : , , _..., ,A,,,,,,i,„ . ..._,,,,,7,7, .. „,,,, x t �r�f_,,,,,,er/ ) ` v 117 • ¢gyp '�' y. ^rtR w �r. �♦e '�. ,M.`K' � 4` t tr ... 4. S-19 View of seep location facing north northwest. Page 23 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE 0 300 330 0 30 • 1 • I • 1 • 1 • i • I • 1 . I 342°N (T} a 35°12.989'N, 81°46.143'W ±16ft ♦ 686ft vt g ti , 4 ,',,' 0 k,,' ,9 y' y 4R?a. 4 , i m. 4 i:e 41,E P 3 P{ w ` ,,tea ����. +TP• � � �: as .+4, .. , `?`5" '^,. 30 Mar 2020, 14 1+�" S-19A View of seep location facing.north-n rthwr4t. Page 24 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra S SW W 150 180 210 240 270 • •I I • I I I • I 1 • I • I t I I I ® 215°SW (T) OO 35°12.963'N, 81°45.913'W ±16ft ♦ 715ft rR p p r a 401 ti a wl Y S-20 View of dispositioned seep location facing southwest. Page 25 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SV W NW N 270 300 330 0 • I • I • I . 1 • i • I • I • I • I • I • I • I • I • I • I • I . 1 • I • 295°NV» (T) J 35°12.878'N,81°45.356'W±16ft ♦ 706ft Aar S-2.1 H ;.'e a *'. Lip .to S-21 View of seep location facing west-northwest. NE E SE S 30 -C' 90 120 150 8U • 1 • I • I • I • I • I • I • I • I • I • I • I • I I • l • I i I • 0 97°E (T) %- 35°13.072'N,81°44.898'W ±16ft A 668ft 4 « 30 Mar 2020, 18.42:22 • S-22 View of dispositioned seep location facing east. Page 26 of 55 Seep Characterization Report July 2020 Rogers Energy Complex Cliffside Steam Station Duke Energy Carolinas,LLC SynTerra E SE S SW 90 120 150 180 210 240 • I • • I • I • ! • 173°S (T) Q 35°13.082'N,81°45.031'W±16ft ♦ 651ft , z .� . .: _'a.a'. ..� * t, yaw �.` �..�,�/�df 2�2U, ��0 S-23 View of seep location facing south. Page 27 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W NW N N• 270 300 330 0 30 1 • i • (p ; 1 • 1 1 • I • 1 • 1 • I I • I • I • I • ® 337°NW (T) OO 35°13.071'N, 81°45.021'W ±32ft ♦ 658ft 116 4 k•. ,y • s 3 S- ,3 View of seep location facing north-northwest. Page 28 of 55 Seep Characterization Report July 2020 Rogers Energy Complex Cliffside Steam Station Duke Energy Carolinas,LLC SynTerra S sv W 180 210 240 270 31 I • I ! I • I • I • i I I • I • I • I • I • I ®229°SW (T) C� 35°13.088'N, 81°44.976'W ±98ft ♦ 663ft 1. ifµ F tSL p- nt C Jf�QF*' I'" '!. W st w a ` "yam'of 'rM. s„ +S 'a. _ fix.'.,'. '"" ' " "r • "A. . i..yam 1 r' x x• "wz,.: dad "p a'" ai" i `.. • . • 4 : r 7^sue"/ m -_I-,', . `.,1.,,1A -, w 4 *y .b xy y rt ` t • #. *; `+fie,T�1°" < j�`�. YFY" ti • q Ar r ,'';. 'd tea „ , ��� $ i@,Y-�.,,,.u.,�, < yam, � 1 _tS7 ��. A " At v w. f c �" k • • . v� � Mil ti# ' � Q Mar 2Q 0, 0�~()8 S-24 View of dispositioned seep location facing southwest. Page 29 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra S SW W 15( 1<i) 21 C 21i) 2/1 I • I • I • I • I • I • I • I • I • I • I • I • I • I • 0 218°SW (T) O 35°13.108'N, 81°44.975'W±98ft ♦ 669ft • - ^z, 1" 4, \\� t 4 t �j r + I t - ''''''4?: ** Ilk i ' r - I,-, ip„l .44 rxi \ S-24 View of dispositioned seep location facing southwest. Page 30 of 55 f Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra N NE E 33U 0 30 60 90 ® 34°NE (T) n 35°13.057'N, 81°45.137'W ±32ft ♦ 690ft : A.0 .W S-25 �� t /i;:,, � Ai Rtt w\ tia ./"'i Tii d o � 4' 1 1' 7 / .ir IF"' 4 ,,,,, ...,, , ,.,,.... ,..t , '..---... _____1,„.../:"..0.,:, i \ i f,____..)6t.>N itk ' i ' - N, ,,, , , , , -„, - ,,,,,„, - •,,,,,,,,,,,, 4\ ;,,,-,,, ----, f 3I - ., .* ",, -',a :tit . S-25 View of dispositioned seep location facing northeast. Page 31 of 55 L Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra Nit , - - NE E 330 0 30 60 90 i I • I • 1 • I • 1 • I • 1 1 i . • • 0 • I • I • I • I • , ) , 0 27°NE (T) • 35°13.057'N, 81°451._)2W ±16ft A 693ft ,,- ', • ' ' 0 tr ,°`, ''''',1' 4° • / ,i:a4,e'. '-1.J,\\ .;.. n?3, '''''.....,...!>.:- • . , , . ,...,,,,... ,•'r 41.“''.'.,2 -4.•.,- .:.° , ',,,, - , •- , 7. - _ ,.. - . --I. ° .• .4'1' -, , • ' • • ... , - --. ,4 ,-.4 \ i -, - -'• . t et '* „ . , (..., * 4- . ‘:4 e t"--.S. ' "444 3;_!...;1',1. .,, ei, „4, ,• , • if....e i,'.,.,',.'•,,,,,...-; Aerh•.%1'...rii .6**-4 . '• , ,. ' ., ' 't-.. ' 4 ' , ft, • ,, Ps "fir , n -1I /,.,„Ii..-4qi‘.--r4:,,,,s/t q"..0•,'l'•-,..t,i.,-4liv,.4,0k4-;.•.,--,.:,.,l.,..14_A-4 sti,,,,t,ox,. '.•,.', ,14I- 4tt;-,-•I•, .i 4",1 , .40 . 1ki41.4t, . . , '• ' ,ff )) 'i ' ' i. N '4 • % Cj - : „,,,,,,,,.,,4I..t,:`_1f-'i•t,..t-7i,,,., ,,..A,v ,.., • 7 it l'.'74,*,, I... 'A.4 PI-(:•4 'ilit,--,*:. ," ,,.. ' ,p :1..,..,.'1 /, - . t ,' -,4.- :. - 4 .le `• , .. . — .e Mar 202 eltis' • .......;,.., , ,3 , • 43 ‘ S-25 View of dispositioned seep location facing north-northeast. Page 32 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW I I NE 300 330 30 60 I • I ' I • I ' I • I • I • I • I • I • I • I • I • I • 0 360°N (T) • 35°13.061'N, 81°45.228'W ±16ft ♦ 690ft ti ae, y. * S Y' '.i :- , �! ' 7-, ' . - • `AA, , --p., ,ii,,,,,.... ..., v., ,- ,A.-lfr . ,..--044,14. .44 _ 4 \\ . ' . 401,1,4'' -'-''''.‘4''.4....„„, ; ,:--# ,,,,'"--,g, Yellikitik,.., _....e: ,- Utz `" '.f` 1 op i ° — °#: .Nrl' . " asps., 30.Mar 2020, 12:23:32 S-26 View of dispositioned seep location facing north. Page 33 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SE S SW 120 150 180 210 3 I • I • I • 1 • I • I 1 • 1 • I • I • I • I • 1 • 1 • 0166°S (T) '• 35°13.055'N, 81°45.228'W ±16ft ♦ 680ft 1 y .. a -�- ' ` r. ,,,,,, 44,:::::.,:,,,,i ,, , .,-„ ,' . - , 4'^ ti i c Vt,*, \,.,, _ .,.,,,..i.k:. :,..:400. 1 ,voit, ..5i: . , - Ne -1. ; F. kg�' - , 30 Mar 2020', 12.24:12 S-26 View of dispositioned seep location facing south. Page 34 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra W NW N 40 270 300 330 0 I • I • I • I • I • I • I • I • I • I • I • I • I • I • I ° 35°12.835'N, ° 0 310 NWT 0 81 45.384 W ±32ft • 710ft rtfi U ' �•. ��"''` S vle .4 ` ' r 7 fit f 0` 4 ` -, Y r , y h V .�• ♦ `� r ". e r !�4.° "bra �n y r-ro +' ,',"pq 41 „y , 1 41 `4,,,..8.0'' ' : , ' .f,,'''. .., ' , "''. '‘. :kii:*14t140, '*,1e, 't If 0,''''',.'' 'irci40:1 '''' ":" ..,'1 30 Mar 2020, 17:15:33 ataw .-27 View of seep location facing northwest. Page 35 of 55 i, Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra S SW W N 180 210 240 270 300 I • 1 • I • I • I • I • I • 1 • I • I • I • I • I • I • ' 0 246°SW (T) it 35°12.698'N, 81°45.244'W ±16ft ♦ 770ft I Sao- At r ,0( 1Vg:14.1*,:i ;f l ,),N, r•' iIAlb • • ,+ z�. • . 1 �,0,,...,:. .... . • ' -L s 14 ; ;r 04; - _',-• < > / '� .8� 7 - 30- 'R S-28 View of seep location facing west-southwest Page 36 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE 330 0 30 60 I • I • I • I e I e 1 e I e I • I . I a I • I • I • 0 18°N (T) * 35°12.698'N, 81°45.247'W ±16ft ♦ 759ft ',_ y' i ,` * q,■ y4 �•. ; ,' r A 1. 7 , d . j . , ` • wr> f I z r _ « .k i slots 3` 10`r,_a pt S•,., s 'q..,' 7J ' z a4'` 'r il►/ its o A 4n� {}' e r 1,4 � A jai r ssr ,, Iiiktv:".0 �''s + `�;.+.���f!y�}'��; y `ter �,��1� �1 �)_. t It'' � .' v.ems -141,411L ems/✓'" ) - r -'; y- Pt 4. r ii+t' ��r,' •,f axa •\ • *`A+, k sat .• ; tit . , lb .,� z a � �Y w ` ' / A' �' . . 'If / . S-28 View of seep location facing north. Page 37 of 55 SeepJCharacterization C a acterization Report ul 2020 Y Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SW W NW I 240 270 300 330 282°W (T) OO 35°12.693'N, 81°45.240'W ±16ft A 750ft t r ' ,f ; . . � a'. -.,,� "- ate, ,. `' j+ 3 it 1■ __ „, , „ ,„..,,, ,:„,,„... , _ ..i- : 1,,,, , ..,.)4" ,, .4'0,. n' 4' t .A , . t ..' 4 Alaid .44 ( )1 P yP � r tl i V i, *. 1 � ..„ . , 4-\54! lik... ,A.,, v i . , , ' ' -. - % 1 .-r‘,.*44WN.7.1, if s' \. ' , - '' , '" 'WWI $ 0 t .r ' p S-29 View of seep location facing west. Page 38 of 55 I Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE '0 300 330 0 30 • 1 • 1 • 1 • 1 • 1 .. 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 • 1 0 341°N (T) OO 35°12.694'N, 81°45.241'W ±16ft ♦ 743ft ,yam r _. ,.. _ ;r } y i'r- ` tea{ - I t,,,, _ li,+� s 'a# 4' ro s. ' ' 1 may, 4i. ..,...4.,,,,,"4•1Pf4:1„.,,,,-,4.-, -',,t. ,, _4,-4 !#,,, :A , .117: 40: i 1 w 0"- ' :• 4 ' iy r '` [ as.. s ( . D .. � s �4- k ,tl.' a` 5- f Cr i • It r rid .r r ' I at: +sit \ • i+ ' `1,4 gichb, i ., 1 t '1,4--: 30 Mar 2 0,, .02.26 S-29 View of seep location facing north-northwest. Page 39 of 55 l Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke EnergyCarolinas,LLC SynTerra Yn SW W NW 210 240 270 300 331 • I • I • I • I • I • I • I • I : ., Y • 1 • I • I • I • I I 0 262°W (T) OO 35°12.691'N, 81°45.249'W ±16ft A 815ft ! i s OW'': �� fe I ! ...4,... ,A, , , 4 * w � op �l % 1m . {Fy r ° , ITS,!/' ,,,,r, ei ,i'',;I ", <.'" 0 .7.16, i.i ' S' • �e'%i', ' ( ` 1 \- i s , ,,r--. • 7 r , / — L},. / ,•�N dV. * `. i,„ ,i a� `\ I r�x y 4 �7 y ;' } ..4 ,it ,. -....: - , , . ..., . , P . .. • ' y ., i-ir- , -,- f e. 11.7: , N 1-1.44, ii, •'''.., 410' '44 ,--:.,te, --,-,,,,o, 4.., ,..44 .0,6„ __-_ , , ,i ,,,, ..,r, A.. 4•ems, .11,wr: ";'Y �a °i! 3 - ram' ,,e.K.-:. 4. . 't, '�"'t "4', _ . �+. , r'. `r,,, sir1� 441, , � . k I, , T 4 .•1 a S-30 View of seep location facing west. Page 40 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NW N NE E 33G 30 60 90 120 I • I • I . 1 • I • I • I • 1 • I • 1 • I • I • I • 1 • I • I • 1 • 1 • I ®40°NE(T) OO 35°12.690'N,81°45.244'W±16ft •761ft C wS � _ w S-30 View of seep location facing northeast. Page 41 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra S E SE 150 180 60 90 120 I • I • I • 1 I I • I • I • I • I • I i I • I . 0129°SE (T) O 35°12.684'N, 81°45.231'W±32ft ♦ 761ft i l L . ,, c A ._,...„ �dv 4%� t; . - pi, ", •• fib a yy A~ , \I s +: 't . ' t irie°', - '''' s 4 , \ ' l. .7 ^i. �_rcd � = - a ,r. y „ a'''''' . �y*'"+' ce.' : * i�� ✓ 30 Mar 2020r16 b6:3 S-31 View of seep location facing southeast. Page 42 of 55 Seep Characterization Report July 2020 Rogers Energy Complex Cliffside Steam Station Duke Energy Carolinas,LLC SynTerra E SE S 60 90 120 150 180 I • I • 1 • I . I • I • I I I I I i 1 I • 0 128°SE (T) O 35°12.677'N,81°45.212'W ±16ft ♦ 784ft 'Ap K 3 i � fir. +' �• ,•'• :3, r Rs q ' _i S-32 View of seep location facing southeast. Page 43 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NE I` , ,. SE 4,,,,,.• - 4.... , i,. . , % 120 60 "'4.. - IL, ' . ' - ' -, • i' ' ' I ` °V • I "' i'.4,*. 400,- i :a if • Iiii - , i• Ier - I • I 0 75°E (T) .I 35°12.676'N, 81°45 212W ±16ft • 779ft ,'Z-;,F"' , ; ' 1 •'. ' \ ; ' 4 c-; .- ;0 . 1 Alt.,Itp*, - ' " i'':...- . - ^ I 1' ; ;14\ . '. ' '''...'• '''' .'.4"' ' 4'"7"-:- ..' Sr.r. 11'. ' e • N' - rp,---. _...r , "' -7.•• •,,, •..", 1'- •-•.7`••• i1 V - • •,- -. 14,, ,-,,,s,..,•,,,oci. • - e ,...;,k ' - A, i4i - it ..-1..' ,..• - ..•.- 1,...C1..-: 4011. -'4...* , • - . ' :,•ro.tr. '•If. '''' 1k' .' '(//_, ••••... •...:,-. • ,fr-7 ..: .fr fry. ; < ,,- ,' „ :,,,,,,,,s‘.,.1‘ ,, ..... .. : - ? :. .. ,,..... .„. .,, .„ ,....,.., .k‘. -43,.7 , ..:,,, .:%,,4.....,.. _I 4,4.,,,,4",‘ ,'....'''' 4:' . , .7;''',..; . .- .,,A,,,k.':.„..... .1.1 ,. "4-.0::;,,,,,,I .,.'... •-, .,„,,,....`..,. , .. 'E., ::. ,,,.... S-32 \ 1,,, of -,,..'ci, 14',..)1..iuti i41,111,.„-!, 4,•E-Ht Page 44 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NE E SE c,u 90 120 150 I • I • I • I • I • I • I • I • I • I • I • I • I • I • ®87°E (T) 0 35°13.096'N, 81°45.287'W ±16ft A 664ft -,Y� A1, Et' �, g'• ,Cf x n - . 1 ; "-,..',.. '!i 1004*_,, ,,,,,,04 , , I0 - `AV;wv. .,yam_'` l ;. I *. . \ . -4 , .. ,7. . , . * ., ' , , , 1p, _,., .r 020, 018'Q S-33 View of dispositioned seep location facing east. Page 45 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra E SE S 90 120 180 210 . 1 . I . I • I • I • I • I • 1 • I • l • I • I • 1 0 143°SE (T) • 35°13.061'N, 81°45.222'W ±16ft ♦ 685ft I ..��.. 14 �- welz AO.W. 4AVL, -.10K 30 ar"2• .! ►f4-, S-34 View of dispositioned seep location facing southeast. Page 46 of 55 i Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra N NE E sE 0 30 60 90 120 150 • I • I • I • I • I • I • 1 • I • I • I • I • I • I . I • 1 • I • I • I • I 0 78°E (T) OO 35°12.482'N,81°45.378'W±32ft ♦ 870ft c.4 _ ' , ,''.• __r � , ^r.'"r-'' ✓ A.O.W .` , "y ,' ' -. fir, S s .�, 1-21 s-35 f 4 w 4.• ... get w • , ilk .4} 1" ai` *r".',., - w. -. r y r k L.4-4".` r • #1 e c.. riI, ""��,; i z ,rye . . , 'S- •_ _ MI6a fir i►� a `S, �w "L" J" � 1�. 1-ih-.4k.‘,„,c,.., ,. .7,----, - 4..,„,*il•-'"1".". • ,..r,, ' .5,r-:...,.s. •,.. Iv: ,, .1,, ,',1,.,4.6 : - ?" 10i � 3. �S s _ , ,., ot. ''tV :r, .. "d'. ar 20''0.16 05:16 S-35 I View of dispositioned seep location facing east. Page 47 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NE E SE 30 60 90 120 150 I • I • I • I • I • I • I • I • I • I • I • I • I • I • 0 99°E (T) O 35°12.620'N, 81°45.233'W ±32ft ♦ 765ft V4 • :. -, = ' .7, -itr-, .4x-- . ,,,,_ - -Or , f '" • k iliw t .30 Mar 202 16:23 41 S-36 View of seep location facing east. Page 48 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra E SE S 90 120 50 180 210 0147°SE (T) OO 35°12.619'N, 81°45.233'W ±16ft ♦ 801ft / ' ?a c 1L w dry"4, ti < s ri ra d 16.2 3.51, S-36 View of seep location facing southeast. Page 49 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra �. dSE S SVV 120 150 180 210 24. • 1 . 1 . 1 . I • I • I • I • I • I I • I • I • I I ' O 172°S (T) ' ) 35°12.612'N, 81°45.222'W ±32ft ♦ 744ft t i ` i { �.■a 'L if. d f4tN`°aL ''y Y* i zy _. x o ,w= s .. L. w .. i f i! �' : , 30 Mar 2020, 16.25:03 S-37 View of seep location facing south. Page 50 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra SW N NW 210 240 270 300 330 t' I • I • I • I • I • I • I • I • I • I • I • I • I ♦ 0 267°W (T) 4.1 35°13.0611N, 81°45.169'W ±32ft ♦ 661ft a� +�N�..11�. .P ; 1 _l\ sue. =_.._..^ �� N. t ip \ P • lam` ., • , 1 , .,, \--. ••. l ' 30 Mar 2020, 18:29:28 S-38 View of seep location facing west. iz Page 51 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra ��+. S 1 8 210 J W 240 g 0 227°SW (T) • 35°12.804'N, 81°46.431'W ±16ft ♦ 764ft e. « ,. Ids . c v w t ,ate }� - ,, , t * > , ai r , t ti� a - t 3 �.a v i 0 • _ aMar ib 1 5-39 View of seep location facing southwest. Page 52 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NE E SE 60 90 120 150 • I • I • I • I • I • I • I • I • I • I • I . I •. I • I 0103°F (T) O 35°12.813'N, 81°46.434'W ±32ft A 746ft 4 3a 9r1 �.p y � b "`Y•, '`..1;.5 b - ter+^ ,,„ .., 'jay, i�a If ,-..,,,4"-,..— :,.. ,.;,.' .1 , •.,— .'..,:, ' ''- ' . :74fif. ..tt. '''77;1,71". " . . ! w ® w a e ;; _ ` '... � .. b.�,e -J`. r vUY�. � ,.. '.y , s * „ K " .. r x '" .': " 0 a . r r t'' ..; 30 Mar' 2020, 14:57:52 S-39 View of seep location facing east. Page 53 of 55 Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra N _ N E __� E 0 3U 60 90 120 • I • I • 1 • I • 1 • I • 1 • I • 1 • 1 • I • 1 • I • I 0 53°NE (T) ',J 35°12.812'N, 81°46.439'W ±16ft ♦ 766ft ,:,. :":1;,, - --''' .. ',LVi':r,'-'4"r7,•-2.:;:,4*,';":f-t4E:*1,--' °,':-71, .,-*=-„..'''.::::'.;:7''' -' - - = * , ,;... c w +w , *ra t`, l'fi '` Y.k k" o sa' wS ''m . bre'' . :;. • r �� ^' 4 r r pA� ' . . t \; '. # 3" 5-39 View of seep location facing northeast Page 54 of 55 i Seep Characterization Report July 2020 Rogers Energy Complex-Cliffside Steam Station-Duke Energy Carolinas,LLC SynTerra NE E SE ;, 30 60 90 120 150 I • I • I • I • I • I • I • I • I • I • I • I • I • I • ® 99°E (T) I 35°12.801'N, 81°46.434'W ±16ft ♦ 755ft sr' g" 1 r s.4 4i 'I. , - j .:.am ® a _ r « y . ,i 4. ,' .. ti t f t y+�am,-� __` A �' , C �. ^' ^ It .44 . 41t iS. i' ,`' ,,•. 1,, a 20, 14:59:44 _. .. .,� ...te _. . _ _ ..�► -•• "1 S-39 View of seep location facing east. Page 55 of 55 t