WQ0035207_Modification_20200724

Initial Review
Reviewer Thornburg, Nathaniel
Is this submittal an application? (Excluding additional information.)*
r Yes r No
Permit Number (IR)* WQ0035207
Applicant/Permittee Synagro Central, LLC
Applicant/Permittee Address 284 Boger Rd. Mocksville, NC 27028
Is the owner in BIMS? r Yes r No Is the facility in BIMS? r Yes r No
Owner Type Organization
Facility Name Synagro Central DCAR
County Davie
Fee Category Major Fee Amount 395
Is this a complete
application?*
r Yes r No Complete App Date 07/24/2020
Signature Authority
Signature Authority Title
Signature Authority Email
Document Type (if non -application)
Email Notifications
Does this need review bythe hydrogeologist?* r Yes r No
Regional Office
CO Reviewer
Admin Reviewer
Below list any additional email address that need notification about a new project.
Email Address
Comments to be added to email notfication
Comments for Kendall
Comments for RO

Comments for Reviewer
Comments for Applicant

Submittal Form
Project Contact Information
Rease provide information on the person to be contacted by N B Staff
Name * Robert Roth
Email Address*
[e-mail]
electronic subnittal, confirmation of receipt, and other correspondence.
Phone Number*
3364034324
Project Information
........ ......... ........................................................................................................................................ ......... .... ... .... ........ ... ... .... .... .... ... ... ... .... .... .... ... .... .... ......... ......
Application/Document Type* r New (Fee Req ui red)
c Modification - Major (Fee Required)
r Renewal with Major Modification (Fee
Required)
r Annual Report
r Additional Information
r Other
O Modification - Minor
C Renewal
C GW-59, NDMR, NDMLR, NDAR-1,
NDAR-2
r Residual Annual Report
r Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edocs.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:* r Wastewater Irrigation r High -Rate Infiltration
r Other Wastewater r Reclaimed Water
r Closed -Loop Recycle r Residuals
r Single -Family Residence Wastewater r Other
Irrigation
Permit Number:* WO0035207
Fbs Current Existing perrrit number
Applicant/Permittee* Synagro Central, LLC
Applicant/Permittee Address* 284 Boger Rd. Mocksville, NC 27028
Facility Name * Synagro Central DCAR
Please provide comments/notes on your current submittal below.
Major modification.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Tessa Monday at
[e-mail] or [phone].
Please attach all information required or requested for this submittal to be reviewed here.*
(Application Form Engineering Rans, Spec'rfications, Calculations, Rc.)
WQ0035207 Major Mod Combo.pdf 29.58MB
upload only 1 RDF docurrent (less than 250 NS). NL@iple documents nest be corrbined into one RDF file unless file is larger than
upload lirrit.
* W By checking this box, I acknowledge that I understand the application will not be
accepted for pre -review until the fee (if required) has been received by the Non -
Discharge Branch. Application fees must be submitted by check or money order
and made payable to the North Carolina Department of Environmental Quality
(NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature *

Submission Date 7/23/2020
Is filled in autorratically once subrritted.

SYNA
GRO
APPLICATION FOR MODIFICATION OF
PERMIT NO. WQ0035207
DISTRIBUTION OF CLASS A RESIDUALS
SYNAG RO, LLC
Prepared by:
SYNAG RO CENTRAL, LLC
Mocksville, NC 27028
P 3 36-790-1610
July 23rd, 2020

SYNAGRO
July 23rd, 2020
NCDENR-DEQ
Division of Water Resources
Land Application Permitting and Compliance Unit
Aquifer Protection Section
1636 Mail Service Center
Raleigh, NC 27699-1636
ATTENTION: Mr. Nathaniel Thornburg
REFERENCE: MODIFICATION OF PERMIT NO. W00035207
Synagro Central DCAR
Davie County
Dear Mr. Thornburg:
Synagro is submitting an application to modify the company's residuals land application Class
A permit. Requested changes to the current permit include:
• Addition of Graham Mebane Water Treatment Plant as a source.
• Addition of Startex Jackson Wellford Duncan Water District Water Treatment Plant
(SJWD/Duncan WTP) as a source.
• Addition of Siler City Water Treatment Plant as a source.
• Addition of Lake Kilby Water Treatment Plant as a source.
A check for $395.00 is provided as the above request constitutes a "Major Modification".
This application package should contain all information necessary to complete the requested
modification of Synagro's permit. However, if you require additional information or have
further questions, please contact me at [phone] or rroth s na ro.com. Thank you in
advance for the timely and efficient review of this modification application.
Sincerely,
Ad�l— ) *V--
Robert N. Roth
284 Boger Road, Mocksville, NC 27028 • Phone: [phone]

DWR
State of North Carolina
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS
INSTRUCTIONS FOR FORM: DCAR 06-16 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and
supporting documentation
For snore information, visit the YYater• QE1aiity Permitting Section's Non -Discharge Permitting Unit website
General —This application is for treatment, storage, transport, distribution, land application, and/or marketing of Class A (or Equivalent)
residuals under 15A NCAC 02T .1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Distribution of Class A Residuals (FORM: DCAR 06-16):
Submit the completed and appropriately executed Distribution of Class A Residuals (FORM: DCAR 06-16) form. Please do
not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to
the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
® The project name should be consistent on the plans, specifications, etc.
® The Applicant's Certification on Page 3 of this form shall be signed in accordance with 15A NCAC 02T .0106(b�. An alternate
person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A
NCAC 02T .0106 b .
0 If this project is for a modification of an existing permit, submit one copy of the existing permit.
® Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental
Quality (NCDEQ).
Facility Classification I New Permit l Major Modification r
Major (residuals permitted for distribution > 3,000 dry tons/year) $1,310 I $395
Minor (residuals permitted for distribution <3,D00 dry tons/year) $810 $245
r - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
itted.
adds additional residuals sources; or includes the addition of new treatment or storage units/processes not previously perm
There is no fee for minor permit modifications.
C. Cover Vetter (All Application Packages)
® List all items included in the application package, as well as a brief description of the requested permitting action.
INSTRUCTIONS FOR FORM: DCAR 06-16 Pagel of 3

D. Program Information (All Application Packages)
Provide a narrative explaining the following:
® How the materials will be handled and transported from where the residuals were produced to where it will be treated.
® How the residuals will be processed/treated (attach process flow diagram).
® How leachate collection will be handled.
® Where the residuals will be stored until processed.
® How the final product will be distributed (packaging, bulk, etc.)
® What nutrients or other constituents (i.e. nitrogen, phosphorous, aluminum, calcium, etc.) are used or recommended as the
limiting parameter for determination of residuals loading rate to ensure that it does not overload the soil and cause
contravention of surface water or groundwater standards, limit crop growth, or adversely impact soil quality.
® Attach a marketability statement detailing destinations and approximate amounts of the final product to be distributed.
® Provide either a label that shall be affixed to the bagged processed residual or an information sheet that shall be provided to the
person who receives the processed residual. The label or information sheet shall contain, at a minimum, the following
information:
® Name and address of the person who prepared the residual that is sold or given away.
A statement that application of the residuals to the land shall be in accordance with the instructions on the label or
information sheet.
® A statement that the residuals shall not be applied to any site that is flooded, frozen or snow-covered.
® A statement that adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.
Information on all applicable setbacks in accordance with 15A NCAC 02T .1108 b .
A statement that the residuals shall be applied at agronomic or recommended rates for intended uses.
E. Detailed Plans and Specifications (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit detailed plans and specifications that have been signed, sealed, and dated by a NC Professional Engineer per 1 AA
NCAC 02T .1 104a . Specifications for standard equipment may only be omitted for municipalities with approved standard
specifications, but use of the standard specifications must be noted on each sheet of the plans.
❑ Plans must include the following minimum items: a general location map, a topographic map, plan and profile view of the
residuals treatment and storage units as well as the proximity of the residuals treatment and storage units to other utilities and
natural features within 500 feet of all treatment and storage facilities, and detail drawings of all items pertinent to the residuals
treatment and storage units. Depict minimum separations required in 15A NCAC 02T .1108 a on the plans.
❑ Specifications must include, at a minimum, the following for all items pertinent to residuals treatment and storage units:
description of materials to be used, methods of construction, quality of construction testing procedures to ensure the integrity
of the final product in accordance with 15A NCAC 02T .1104 a 2 B , including leakage and pressure testing as appropriate.
❑ Plans and specifications must not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR
CONSTRUCTION, etc.) that indicate that they are anything other than final plans and specifications. However, the plans and
specifications may be labeled with the phrase: FINAL DESIGN —NOT RELEASED FOR CONSTRUCTION.
F. Engineering Calculations (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit all design calculations that have been signed, scaled, and dated by a NC Professional Engineer per 15A NCAC 02T
.1104 a .
G. Environmental Assessments (Maybe Required —See 15A NCAC 1C .0300
❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals
treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for
the construction of the subject facilities.
Page 2 of 3
INSTRUCTIONS FOR FORM: DCAR 06-16

H. Operation and Maintenance Plan (New and Renewal Application Packages)
® For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
® S b *t th O&M Plan in accordance with 15A NCAC 02T .11 I0 and include at a minimum:
u j. e
® Operational functions; describe the operation of the program to show what operations are necessary for the program to function
and by whom the functions are to be conducted.
® Maintenance schedules; may include equipments calibration, maintenance of signs, etc.
® Safety measures; may include safety training program, manuals, signs, etc.
® Spill response plan; including control, containment, remediation, emergency contact information, etc.
inspection plan including the following information;
® Names and titles of personnel responsible for conducting the inspections.
® Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the selected
location(s) and inspection frequency are representative of the residuals management program.
Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event
that noncompliance is observed.
Sampling and monitoring plan including the following information;
® Names and titles of personnel responsible for conducting the sampling and monitoring.
® Detailed description of monitoring procedures including parameters to be monitored.
® Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature, flow,
and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling
plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to meet
pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per year but have an annual
sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected
by cold temperatures.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
By U.S. Postal Service:
1617 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1617
TELEPHONE NUMBER: [phone]
By Courier/Special Deliver :
512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27604
FAX NUMBER: [phone]
INSTRUCTIONS. FOR FORM: DCAR 06-16
Page 3 of 3

Itm;a
State of North Carolina
Department of Environmental Quality
Division of Water Resources
I5A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS
Division of Water Resources FORM: DCAR 06-16
t. APPLICANT INFORMATION:
1. Applicant's name: S na ro Central LLC
Applicant type: ❑ Individual E Corporation ❑ General Partnership ❑ Privately -Owned Public Utility
❑ Federal ❑ State ❑ Municipal ❑ County
Signature authority's name per 15A NCAC 02T .0106: RobertN Roth Title: Technical Services Manager_
Applicant's mailing address: 284 B�'Rd.
City: Mocksville State: NC Zip: 27025-
Telephone number: (336 790-1610 Email Address: rroth s na ro.com
2. Consultant's name: NIA License Number (for P.E.):. I
Affiliation: ❑ On Staff ❑ Retained (Firm: _ )
Consultant's mailing address:
City: State: Zip: -
Telephone number: (_) 1 Email Address:
3. Fee submitted: 395.00 (See Instruction B)
II. PERMIT INFORMATION:
1. Application is for (check all that apply): ❑ new, M modified, ❑ renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: W 0
Date of most -recently issued permit: 3/1/2016
Date of most -recently certified Attachment A (if different than the permit): 3/27/20
I1I. FACILITY INFORMATION:
1. Name of residuals processing facility: Source Specific
City: State: _ i Zip:
Coordinates: Latitude: Longitude:
Datum:, Level of accuracy:
Method of measurement:
County where facility is located'..
2. Facility contact (person familiar with residuals preparation):
Name: Robert Roth Title: Technical Services Manaei
Mailing address: 284 B9er Rd.
City: Mocksville State: NC Zip: 27028-
Telephone number: 336 790-1610 E-mail address: [e-mail]
Page 1 of 3
FORM: DCAR 06-16

3. Is the residual process facility also the generator? ❑ Yes; No
If No, please specify delivery frequency and quantity of residual to be processed: Source Specific
4. Length of residuals storage at facility: Source S ecific days (Note: the Division requires minimum 30 days storage in units that
are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.)
IV. RESIDUALS QUALITY INFORMATION:
Specify how these residuals will be distributed:
❑ sold or given away in bags or other containers; ❑ lawn (bulk); ❑ home garden (bulk);
® other (explain); Land applied by Synagro as bulk residuals at amonomic rates
Note: Bulk residuals shall mean residuals that are transported and not sold or giving away in a bag or other receptacles with a
load capacity of one metric ton or less.
2. Complete the following if residuals are to be mixed with other materials:
93
Approximate amounts of the residuals received and processed at the facility: Source Specific dry tons per year.
4. Approximate amounts of the final product (processed residuals) to be distributed: Source Specific dry tons per year.
5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and
maximum storage times prior to distribution): Source Specific
6. Does the facility have a stormwater management plan? ❑ Yes; ❑ No
Explain whether the treatment and storage areas are under roof or how stormwater runoff will be handled: Source Specific
Y. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the attached Residuals Source Certification and all associated documentation.
El
RSC 06-16.doc
FORM: DCAR 06-16 Page 2 of 3

Professional Engineer's Certification: (Application Involving New or Changes to Treatment or Storage Units)
attest that this application for
has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge
the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package
may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed
this material and have judged it to be consistent with the proposed design.
North Carolina Professional Engineer's Seal, Signature, and Date:
Applicant's Certification:
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
yes ❑ No, Explain;
1, Robert N Roth
(Signature Authority's Name — PLEASE PRINT) (Title)
attest that this application for S na 'o Central LLC
(Facility Name)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes §143-215.6A and § 143-215.613, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which inay include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.
Signature:
l� Date: -VZ
Page 3 of 3
FORM: DCAR 06-1 G

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207 (Synagro Central)
Operational Functions
The operation function of this project is going to involve mixing the lagoon up with either a tractor powered Houle pump
or through the utilization of a dredge to achieve a well -mixed and consistent material that is suitable for land application
from the Pittsboro WTP, Dunn WTP, Franklin WTP, SJWD WTP, Graham Mebane WTP, City of Reidsville WTP,
Mooresville WTP, Charlotte Water Lee S. Dukes WTP, Cone Denim White Oak WWTP, City of Albemarle Tuckertown WTP
and L.B. Stovall WTP . Brunswick NW WTP material will be mixed and pumped to a belt press to press material to a cake
material. This material will be loaded on to tractor trailers and hauled to land application sites. City of Durham,
Williams WTP is going to be hauled to the City of Durham Brown WTP and mixed with the Brown plant alum residuals.
Once the 2 materials are mixed they will be pumped to a belt filter press and dewatered for cake land application. City
of Greensboro WTP residuals will be dredged and dewatered through use of a centrifuge. Piedmont Triad RWA's John F.
Kime WTP material, and Charlotte Water's Walter M. Franklin WTP material will be dewatered via belt filter press. Both
cake materials that are produced will be land applicable. All material is going to be spread at agronomic rates that are
determined by the nutrient and metal sample that is current for that monitoring period. Pittsboro WTP, Dunn WTP,
Franklin WTP, City of Reidsville WTP, Tuckertown WTP, Lee S. Dukes WTP, White Oak WWTP and L.B. Stovall material is
going to be spread with a liquid applicator that will use pressure to spread the material in such a way to achieve a
consistent spread pattern. Brunswick NW WTP, Durham Brown, Williams WTP, John F. Kime WTP, Walter M. Franklin
WTP and Lake Townsend WTP material is going to be dumped in the field and loaded into a cake spreader with a front-
end loader. The spreader will able to spread the material in an even and consistent manner. The material is going to be
land applied on fields that have grass growing on them that are going to either be grazed or cut for hay for animal feed
some fields may be in row crop production and rates will be determined by RYE for the crop that is going to be grown for
animal consumption.
SAFETY MEASURES
Synagro believes in operating in a safety conscious manner and is has all employees participate in quarterly online safety
course that are designed to help its employees recognize safety issues and take steps to prevent accidents from
occurring. In addition all Synagro employees have the authority to stop operations if they think any aspect of the
operation is going to cause environmental or personal harm.
Maintenance Schedule
Synagro will follow the maintenance schedule as recommended by the Synagro fleet manager for the equipment
necessary to complete the job.

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207 (Synagro Central)
Inspection Plan
Inspections for the land application of residuals will be conducted on a weekly basis at the land application site during the land
application activities of this project. The inspection frequency is based on the time frame that it is going to take to complete the
project and the amount of dry tons to be land applied from this facility. The inspections will consist of inspecting a current field
that is being applied as well as inspecting random fields that have been completed. These inspections will consist of:
1. Verifying that the Pre -Operations Check List has been completed and signed by both Operations and Technical staff.
2. Checking the calculated loads to insure the correct amount of residuals are being land applied.
3. Insure that all manned equipment has a copy of the spill control plan, the permit, and the operations and maintenance
plan.
4. Insure that the field has been flagged properly and that all buffers are being adhered to.
5. Insure that the Crop and Landowner Verification form has been filled out.
6. Verifying that the correct number samples of the residuals have been taken and that it meets the criteria for land
application.
7. The records will be kept in the project files in the respective office for the project.
8. The Permittee or Inspector shall report by telephone to the Raleigh Regional Office by Telephone at 919-791-4200
Asheville Regional Office by telephone at 829-296-4500, Wilmington Regional Office at 910-796-7215 ,Winston Salem
Regional Office at 336-776-9800, Mooresville Regional office at 704-663-1699, or Fayetteville Regional Office 910-433-
3300 as soon as possible but no later than 24 hours after or the next working day following the occurrence or the first
knowledge of the occurrence of the following.
• Any occurrence with the distribution program resulting in the land application of significant amounts of material
that is abnormal in quantity or characteristics.
• Any failure of the distribution system that results in the release to surface waters.
• Any time that self -monitoring indicates that the facility has gone out of compliance with the permit.
• Any process failure that results in the system not adequately treating the residuals.
• Any spill or discharge from a vehicle or piping system during residuals transportation.
• Any release that requires immediate reporting outside of normal business hours shall be called in to DENR at 1-
800-662-7956,1-800-858-0368, or 1-919-733-3300. These numbers are to be called in the event of a release to
surface waters, imminent failure of a storage system when the event occurs outside of normal business hours.
• Within 5 days of the first notice of on occurrence a written response in the form of a letter shall be sent to DENR
outlining the actions taken or purposed actions taken to ensure that the problem does not recur. Persons
responsible for inspections on this project are as follows:
Nate Roth; Technical Services Manager, or his designee

OPERATIONS AND MAINTENANCE PLAN
SYNAGRO RESIDUALS LAND APPLICATION FOR WQ0035207
Sampling Plan
Sampling for this project consists of sampling the residuals during the time that land application is occurring. This will
result in one round of sampling to occur before land application commences in order to ensure that the residuals are
suitable for land application. The TCLP sample is only required to be sampled once per year.
The residuals shall be sampled annually for the following: (Regulatory level in milligrams per liter in parentheses.)
Arsenic (5.0)
1, 4-Dichlorobenzene (7.5)
Nitrobenzene (2.0)
Barium (100.0)
1, 2-Dichloroethane (0.5)
Pentachlorophenol (100.0)
Benzene (0.5)
1, 1-Dichloroethylene (0.7)
Pyridine (5.0)
Cadmium (1.0)
2, 4-Dinitrotoiuene (0.13)
Selenium (1.0)
Carbon tetrachloride (0.5)
Endrin (0.02)
Silver ( 5.0
Chlordane (0.03)
Hexachlorobenzene (0.13
Tetra chloroethylene (0.7)
Chlorobenzene (100.0)
Heptachlor (and its hydroxide) (0.008) Toxaphene (0.5)
Chloroform (6.0)
Hexachloro-1,3-butadiene (0.5)
Trichloroethylene (0.5)
Chromium (5.0)
Hexachlorethane (3.0)
2,4,5-Trichlorephenol (400.0)
1200 0
Lead (5.01
2,4,6-Trichlorophenol (2.0)
M-Creso ( )
o-Cresol (200.0)
p-Cresol (200.0)
Cresol (200.0)
2,4-D (10.0)
Lindane (0.4)
Mercury (0.2)
Methoxychlor (10.0)
Methyl ethyl ketone (200.0)
The residuals will also be sampled based on the chart below for the follow!
Dry Tons Generated
,short tons per year)
<319
>319-<1,650
=>1,650-<16,500
Aluminum
Ammonia -Nitrogen
Arsenic
Cadmium
Calcium
Copper
Lead
Sodium Adsorption Ratio (SAR)
2,4,5 TP ( Silvex) (1.0)
Vinyl Chloride (0.2)
constituents based on production per year
Monitoring Frequency
(Established in 40 CFR 503 and 15A NCAC 02T.1111)
1 time per year
1 per Quarter (4 times per year)
1 every 60 days (6 times per year)
1 every month (12 times per year)
Magnesium PH
Mercury Plant Available Nitrogen (calculation)
Molybdenum Selenium
Nickel Sodium
Nitrate -Nitrite Nitrogen %Total Solids
Phosphorous Total Kjeldahl Nitrogen
Potassium Zinc
In order to meet pathogen requirements the material will be sampled for fecals to prove that the residuals have met the
pathogen requirements of the permit. There are no pathogen or vector attraction reduction requirements for INTP sources since
it is water treatment plant residuals with no domestic wastewater contribution to them nor will they be mixed with any other
residuals. Only biological residuals will be tested to comply with pathogen and vector attraction reduction requirements. The
samples will be pulled from the sample points that are designated in the residuals sampling plan. The samples that will be pulled
are a TCLP, nutrient and metals sample and a fecal sample to prove that the material is suitable for land application. Vector
attraction reduction samples will also be pulled when applicable. The nutrient and metal and TCLP sample will be collected
randomly and consist of at least 15 individual samples mixed together in order to get the composite sample for these parameters.
Overall, the material in question are very consistent and there should not be any seasonal fluctuations in these residuals.
The following people are responsible for sampling:
Nate Roth; Technical Services Manager; or his designee.

SPILL RESPONSE PLAN
PROJECT: SYNAGRO CENTRAL Permit W 0035207
IN THE UNLIKELY EVENT OF A SPILL THE FOLLOWING ACTIONS SHALL BE
TAKEN IMMEDIATELY:
1. MANAGEMENT OF SPILL CLEAN-UP ACTIVITIES:
The Operations Manager shall take immediate charge and initiate clean-up activities. Synagro
labor and equipment is to be utilized. In the event additional labor and equipment is required,
assistance may be requested from the Town of Pittsboro, City of Dunn, Town of Franklin,
Brunswick County NC, City of Reidsville, Piedmont Regional Water Authority, Town of
Mooresville, The City of Durham, The City of Greensboro, Town of Mooresville, City of
Charlotte, International Textile Group, Town of Albemarle, or the. NC Department of
Transportation, and other private contractors as necessary.
2. HALT THE SOURCE OF THE SPILL:
Such as a ruptured container or damaged transport unit.
3. CONTAIN THE SPILL:
Form a barrier. Sufficient quantities of straw shall be used for such purposes. Earthen barriers
may be constructed to augment the straw bale containment area of the spill. The Operations
Manager or the person in charge on the spill site will advise the clean-up personnel where to get
the straw, lime, and other items necessary to complete the clean-up operation, i.e., local farmers,
farm supply centers, nurseries, etc.
4. CLEAN-UP:
Employ front-end loaders, vacuum equipment, sludge application vehicles, and/or local septic
tank service to remove as much of the spilled material as possible. Straw and/or sand should be
scattered in the spill area to soak up the remaining material. The straw- and sand -soaked material
will be collected and removed to a disposal area approved by representatives of the state
regulatory agency.
5. FINAL CLEAN-UP:
Employ rotary brush sweeper if needed, and apply lime to the spill area upon the approval of the
clean-up efforts by the state regulatory representative. If the event occurs on private property, the
clean-up will be completed to the satisfaction of the property owner and state regulatory
representatives. The ultimate goal will be to restore the spill area to its original condition if
possible.
6. NOTIFICATION:
As soon as possible after the spill occurs, the Synagro Operations Manager or assistant will notify
the Synagro Central office, and they will then be responsible for notifying other key Synagro
personnel.

7. REPORTING:
Synagro Central personnel will notify the Raleigh regional office of the NCDENR by telephone
(919)-791-4200 for the Pittsboro WTP, Durham WTP's, The Ashville regional office at (828-
296-4500) for the town of Franklin, SJWD WTP, The Wilmington Regional office (910) 796-
7215 for Brunswick NW WTP, the Winston Salem Regional office [phone] for the City of
Reidsville WTP, City of Greensboro, The City of Graham, International Textile Group, and
Piedmont Regional WTP, the Mooresville Regional office for The City of Albemarle
Tuckertown WTP, Town of Mooresville WTP, and City of Charlotte Lee S. Dukes WTP the
Fayetteville Regional Office [phone] for the Dunn WTP. This will be done as soon as
possible, but not more than 24 hours after, or on the next working day following the occurrence.
The Operations Manager shall provide a written report within 48 hours of the spill to the
Technical Services Manager. The report shall list all relative information and actions taken.
Synagro Central personnel will file a written report to the Raleigh, Asheville, Wilmington,
Mooresville, Winston Salem, or Fayetteville Regional office of the NCDENR within 5 days of
the occurrence. For after hours reporting the Division's emergency number shall be called to
report all incidences (800-662-7956 or 800-858-0368 or 919-733-3300)

Graham Mebane Water Treatment Plant
Narrative for Class A Residuals
This project involves the removal of water treatment plant residuals from the
Graham Mebane Water Treatment Plant. These residuals are a product of the
water treatment process. Operationally, Synagro will mix the various storage
lagoons, load taker trucks to transport to the fields, where the material will be
offloaded to liquid applicators for surface application. No additional processes or
treatments will be conducted on the material in question. The residuals will be
land applied to agricultural fields at concentrations below or up to the agronomic
rate based on nitrogen content of the material. The residuals receive no further
treatment after they are placed in the lagoon. Synagro is going to flag the fields
to make sure all buffers are followed as outlined in the permit. Synagro is also
going to spread all the material to further ensure that all buffers are followed.

SYNAGRO
DCAR Marketability Statement
Graham Mebane Water Treatment Plant
Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for
the local farmers who choose to receive residuals. The spreaders will able to spread the material in an
even and consistent manner. The material is going to be land applied on fields that have grass growing
on them that are going to either be grazed or cut for hay for animal feed some fields may be in row crop
production and rates will be determined by RYE for the crop that is going to be grown for animal
consumption. An estimated 300 dry tons will be land applied from the Graham Mebane Water
Treatment Plant.

Synagro Central
Land Application Permit W 35207
Label for Land Application
The residuals that are land applied from Graham -Mebane Water Treatment Plant are produced at: 1824
U.S. 70 Mebane, NC 27302. Mrs. Shelby Smith, Water Treatment Plant Superintendent is the preparer of
the residuals and responsible for the plant operations.
The residuals from Graham -Mebane Water Treatment Plant will be applied to agricultural fields at
agronomic rates based on the RYE rate for the fields and crops to be grown. The residuals will not be
applied to frozen, snow covered or flooded fields. The fields will be flagged with the following buffers to
help prevent runoff from the applied fields:
Residuals produced by Graham -Mebane Water Treatment Plant will be applied to agricultural fields in
bulk and will be applied according this label as well as following all permit conditions as listed in the land
application permit W 00035207.
Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.

SYNAGRO
Startex Jackson Wellford Duncan Water District Water Treatment Plant
Narrative for Class A Residuals
This project involves the removal of water treatment plant residuals from the
Startex Jackson Wellford Duncan Water District Water Treatment Plant. These
residuals are a product of the water treatment process. Operationally, Synagro
will dredge the residuals storage lagoon, load taker trucks to transport to the
fields, where the material will be offloaded to liquid applicators for surface
application. No additional processes or treatments will be conducted on the
material in question. The residuals will be land applied to agricultural fields at
concentrations below or up to the agronomic rate based on nitrogen content of
the material. The residuals receive no further treatment after they are placed in
the lagoon. Synagro is going to flag the fields to make sure all buffers are
followed as outlined in the permit. Synagro is also going to spread all the material
to further ensure that all buffers are followed.

SYNAGRO
DCAR Marketability Statement
Startex Jackson Wellford Duncan Water District
Water Treatment Plant
Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for
the local farmers who choose to receive residuals. The spreaders will able to spread the material in an
even and consistent manner. The material is going to be land applied on fields that have grass growing
on them that are going to either be grazed or cut for hay for animal feed some fields may be in raw crop
production and rates will be determined by RYE for the crop that is going to be grown for animal
consumption. An estimated 700 dry tons will need to be land applied from the Startex Jackson Wellford
Duncan Water District Water Treatment Plant.

Synagro Central
Land Application Permit WQ0035207
Label for Land Application
The residuals that are land applied from Startex Jackson Wellford Duncan Water District Water
Treatment Plant are produced at: 330 Wamsutta Dr, Lyman, SC 29355. Mr. Tommy Staton, Director of
Water Resources and Treatment is the preparer of the residuals and responsible for the plant
operations.
The residuals from Startex Jackson Wellford Duncan Water District Water Treatment Plant will be
applied to agricultural fields at agronomic rates based on the RYE rate for the fields and crops to be
grown. The residuals will not be applied to frozen, snow covered or flooded fields. The fields will be
flagged with the following buffers to help prevent runoff from the applied fields:
Residuals produced by Startex Jackson Wellford Duncan Water District Water Treatment Plant will be
applied to agricultural fields in bulk and will be applied according this label as well as following all permit
conditions as listed in the land application permit WQ0035207.
Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.

Siler City Water Treatment Plant
Narrative for Class A Residuals
This project involves the removal of water treatment plant residuals from the Siler
City Water Treatment Plant. These residuals are a product of the water treatment
process. Operationally, Synagro will mix the storage lagoon, load tanker trucks to
transport to the fields, where the material will be offloaded to liquid applicators
for surface application. No additional processes or treatments will be conducted
on the material in question. The residuals will be land applied to agricultural fields
at concentrations below or up to the agronomic rate based on nitrogen content of
the material. The residuals receive no further treatment after they are placed in
the lagoon. Synagro is going to flag the fields to make sure all buffers are
followed as outlined in the permit. Synagro is also going to spread all the material
to further ensure that all buffers are followed.

SYNAGRO
DCAR Marketability Statement
Siler City Water Treatment Plant
Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for
the local farmers who choose to receive residuals. The spreaders will able to spread the material in an
even and consistent manner. The material is going to be land applied on fields that have grass growing
on them that are going to either be grazed or cut for hay for animal feed some fields may be in row crop
production and rates will be determined by RYE for the crop that is going to be grown for animal
consumption. An estimated 125 dry tons will be land applied from the Siler City Water Treatment Plant.

Synagro Central
Land Application Permit WQ0035207
Label for Land Application
The residuals that are land applied from Siler City Water Treatment Plant are produced at: 950 Water
Plant Rd, Siler City, NC 27344. Mr. Chris McCorquodale, Public Works and Utilities Director is the
preparer of the residuals and responsible for the plant operations.
The residuals from Siler City Water Treatment Plant will be applied to agricultural fields at agronomic
rates based on the RYE rate for the fields and crops to be grown. The residuals will not be applied to
frozen, snow covered or flooded fields. The fields will be flagged with the following buffers to help
prevent runoff from the applied fields:
Residuals produced by Siler City Water Treatment Plant will be applied to agricultural fields in bulk and
will be applied according this label as well as following all permit conditions as listed in the land
application permit W OQ 035207.
Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.

Lake Kilby Water Treatment Plant
Narrative for Class A Residuals
This project involves the removal of water treatment plant residuals from the
Lake Kilby Water Treatment Plant. These residuals are a product of the water
treatment process. Operationally, Synagro will dewater material from the storage
lagoon, load dump trucks or tractor trailers to transport to the fields, where the
material will be dumped. Once offloaded, a loader will load either spreader trucks
or tractor driven spreaders for surface application. No additional processes or
treatments will be conducted on the material in question. The residuals will be
land applied to agricultural fields at concentrations below or up to the agronomic
rate based on nitrogen content of the material. The residuals receive no further
treatment after they are dewatered. Synagro is going to flag the fields to make
sure all buffers are followed as outlined in the permit. Synagro is also going to
spread all the material to further ensure that all buffers are followed.

DCAR Marketability Statement
Lake Kilby Water Treatment Plant
Residuals will be given to local farmers for crop or grass production. Synagro will land apply material for
the local farmers who choose to receive residuals. The spreaders will able to spread the material in an
even and consistent manner. The material is going to be land applied on fields that have grass growing
on them that are going to either be grazed or cut for hay. Also, some fields may be in row crop.
production and rates will be determined by RYE for the crop that is going to be grown for animal
consumption. An estimated 3200 dry tons will be land applied from the Lake Kilby Water Treatment
Plant.

Synagro Central
Land Application Permit WQ0035207
Label for Land Application
The residuals that are land applied from Lake Kilby Water Treatment Plant are produced at: 105 Maury
Place, Suffolk, VA 23434. Mr. Nathan Litteral, Water Plant Manager is the preparer of the residuals and
responsible for the plant operations.
The residuals from Lake Kilby Water Treatment Plant will be applied to agricultural fields at agronomic
rates based on the RYE rate for the fields and crops to be grown. The residuals will not be applied to
frozen, snow covered or flooded fields. The fields will be flagged with the following buffers to help
prevent runoff from the applied fields:
Setback Description
Setback by residual
type (feet)
Liquid
Cake*
Private or public water supply
100
100
Surface waters (streams — intermittent and perennial,
100
25
perennial waterbodies, and wetlands
Surface water diversions (ephemeral streams,
25
0
waterways, ditches)
Groundwater lowering ditches (where the bottom of
25
0
the ditch intersects the S1 WT)
Wells with exception to monitoring wells
100
100
Bedrock outcrops
25
0
Residuals produced by
Lake Kilby Water Treatment Plant will be applied to agricultural fields in bulk and will be applied
according this label as well as following all permit conditions as listed in the land application permit
WQ0035207.
Adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.

State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
Division of Water Resources INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and
supportinIZ documentation
For more information, visit the Water Quality PermittingSection's Non -Discharge Perin itting Unit
General This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
® For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item 1. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: SVnaZrO Central LLC
Maximum Dry Tons Per Year
Status Facility Permit Holder
Facility Name
County Permit Number
Current'
Proposed
Code"
N City of Graham.
Graham Mebane WTP
Alamance NCO045292
0
275
Startex Jackson Wellford
N Duncan Water District
S1WD/Duncan WTP
Spartanburg SC ND0085499
0
700
Water Treatment Plant
0
125
N Town of Siler City
Siler City
ty WTP
Chatham 03-09-010
N City of Portsmouth
Lake Kilby WTP
Suffolk VA0006301
0
3200
a Status Code for source facility are: ♦ N ('New)
4 R (Renewed)
♦ M (Modified) ♦ D (Deleted)
or disposal (i.e, not applicable to new facility).
UThe amount of residuals currently permitted for
distribution, land application,
Page 1
SUMMARY FOR FORM: RSC 06-16

DWR
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
Division of Water Resources
FORM: RSC 06-I6
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Graham Mebane Water Treatment Plant
2. Facility permit holder is: ❑ Federal, ❑ State, 0 Local Government, or ❑ Private.
Facility permit issued by: ® Div. of Water Resources, ❑ Div. of Environmental Health,
or ❑ Other (explain: � I).
3. Facility contact person and title: Shannon Smith, WTP Superintendent
Complete mailing address: 1824 U.S. 70
City: Mebane
Telephone number: [phone]
4. Facility physical address: 1924 U.S. 70
City: Mebane State: NC
Coordinates: Latitude: U- 05' 53"
Datum: NAD83;
State: NC Zip: 27302-
E-mail address: ssmith R OVot raham.com
Zip: 273 02-
Longitude: 79' 19' 45"
Level of accuracy: rS'econds
Method of measurement: MAPJ
5. Purpose of the facility:
❑ treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
® treatment of potable water, ❑ treatment of 100% industrial wastewater,
❑ treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: % industrial and �. % domestic)
U other (explain; ).
6. Does the facility have an approved pretreatment program: Yes ❑ No
7. Facility permitted/design flow: 12.0 MGD and facility average daily flow: 3.88 MOD
8. Average amount of residuals being generated at this facility 'estj 75 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water Treatment Process
Type and volume of residuals storage (i.e., outside of residuals treatment units): 3 lagoons. 0 5 million gallon each
It. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
❑ 40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 0 U.1102 6 as:
❑ Biological N Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
Page 1 of 5
FORM: RSC 06-16

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: ❑ yes 0110,
If yes, list the number(s): I
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: ❑ yes 0 no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Summit Environmental Tech and Date of analysis: 2/4/2020
Passed con•osivity test: ® yes ❑ no. pH: s.u. (2 <pH < 12.5)
Passed ignitability test: ® yes ❑ no. Flashpoint: Non-flammabld OF (> 140°F)
Passed reactivity test: ®yes ❑no. HCN: ND mglkg (<250) & H2S: ND mg/kg (<500)
TCLP Parameter
Limit
Result
TCLP Parameter
Limit
Result
(Mg/1)
(W911)
(mg/1)
(Ing/1)
Arsenic
5.0
ND
Hexachlorobenzene
0.13
ND
Barium
100.0
ND
Hexachloro-1,3-Butadiene
0.5
ND
Benzene
0.5
ND
Hexachloroethane
3.0
ND
Cadmium
1.0
ND
Lead
5.0
ND
Carbon Tetrachloride
0.5
ND
Lindane
0.4
ND
Chlordane
0.03
ND
Mercury
0.2
ND
Chlorobenzene
100.0
ND
Methoxychlor
10.0
ND
Chloroform
6.0
ND
Methyl Ethyl Ketone
200.0
ND
Chromium
5.0
ND
Nitrobenzene
2.0
ND
rn-Cresol
200.0IND
00.0
ND
o-Cresol
200.0
5•0
ND
p-Cresol
200.0
VTetrachloiroethylene
1.0
ND
Cresol
200.0
5.0
ND
2,4-D
10.0
0.7
ND
1,4-Dichlorobenzene
7.5
ND
Toxaphene
0.5
ND
1,2-Dichloroethane
0.5
ND
Trichloroethylene
0.5
1,1-Dichloroethylene
0.7
ND
2,4,5-Trichlorophenol
400.0
IND
2,4-Dinitrotoluene
0.13
ND
2,4,6-Trichlorophenol
2.0
Endrin
0.02
ND
2,4,5-TP (Silvex)
1.0
ND
Heptachlor and its Hydroxide
0.008
ND
Vinyl Chloride
0.2
ND
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under i 5A NCAC 02'T .1105.
a. For Distrib►rtiott/Lattrl A licatiott: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint Anal icat and Date of analysis: 1./22/2020
Parameter
Ceiling
Monthly Average
Result
Concentration Limits
Concentration Limits
(C1assA & ClassB)
(Class A Only)
(tng/kg)
75
(mg/kg)
41
(ing/kg)
<15.2
Arsenic
Cadmium
85
39
<3.03
Copper
4,300
840
57
75
1,500
300
17
n/a
17.1
<9.09
<0.464
<7.58
Lead
Mercury
Molybdenum
Nickel
420
420
14.3
Seienium
100
7,500
100
2,800
<15.2
<37.9
Zinc
b. For Sur ace Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: �_.,� and Date of analysis: I
Distance from Disposal
Arsenic
Chromium
Nickel
Unit to Boundary to
Closest Property Line
(meters, check one)
(tnglkg)
(nrglkg)
(rnglkg)
> 0 but <25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
[] > 100 but < 125
53
360
390
El > 125
62
450
420
Result (mglkg)
FORM: RSC 06-16 Page 3 of 5

5. Nutrient/Micronutrient Determination: Complete the following:
a. Total solids: 3.29 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: WaypDint Anal ticai and Date of analysis: 1/22/2020
C. Using the results listed in Item It. 5b. above, calculate the sodium adsorption ration (SAR): 1.1
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 20 %. This
rate is a (check one): N default value, or ❑ actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method First (1g7 Year PAN Five -Year
Maximum Adjusted PAN
(inglkg) (nrgAg)
Surface 5,095 47,391
Injection/incorporation 7,035 331
Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses: None
FORM: RSC 06-16 Page 4 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For Distributlon/Land Application of Class A or E aivalerrt:
❑ A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
El A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
n Alternative 1 [15A NCAC 02T.1106(b)(3)(A)] - Time/Temperature Compliance.
❑ Alternative 2 [15A NCAC 02T.I106(b)(3)(B)] - Alkaline Treatment.
❑ Alternative 3 [15A NCAC 02T.1106(b)(3)(C)] - Prior Testing for Enteric VirusNiable Helminth Ova.
❑ Alternative 4 [15A NCAC 02T.I106(b)(3)(D)] - No Prior Testing for Enteric VirusNiable flelminth Ova.
❑ Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: ❑ composting, ❑ heat drying, ❑ heat treatment,
❑ thermophilic aerobic digestion, ❑ beta ray irradiation,
❑ gamma ray irradiation, or ❑ pasteurization.
For Land Application of Class B:
Alternative 1 [15A NCAC 02T.I 106(c)(1)] -Fecal Coliform Density Demonstration.
Alternative 2 [15A NCAC 02T.1106(c)(2)] -Process to Significantly Reduce Pathogens (PSRP).
Specify one: ❑ aerobic digestion, air drying, ❑ anaerobic digestion,
composting, or �❑ lime stabilization.
c. For Surface Disposal:
[] Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item 11. 7a. above.
❑ Select One of the Class B or Equivalent pathogen Reduction Alternatives in Item 11. 7b. above.
❑ Exempt -If Daily Cover Alternative is chosen in Item 11.8. below [15A NCAC 02T.1106(a)(2)1.
❑ Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Vector Attraction Reduction VAR : Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
�] Alternative 1 [15A NCAC 02T.I107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
❑ Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-flay Bench Scale Test (Aerobic Digestion).
❑ Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
❑ Alternative 5 [15A NCAC 02T.1 107(a)(5)] - 14-Day Aerobic Processes.
❑ Alternative 6 [15A NCAC 02T. 1107(a)(6)] - Alkaline Stabilization.
❑ Alternative 7 [15A NCAC 02T.1107(a)(7)] - Drying of Stabilized Residuals.
❑ Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabili zed Residuals.
❑ Alternative 9 [15A NCAC 02T.1107(a)(9)] - Injection.
❑ Alternative 10 [15A NCAC 02T. I 107(a)(10)] - Incorporation.
❑ Alternative for Surface Disposal Units Only - Soil/Other Material Cover [I5A NCAC 02T.1 107(b)(2)].
® Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
Page 5 of 5
FORM: RSC 06-16

VICINITY MAP
SYNAGRO
Baptist Church •
I
r River °
munity
lark a Graham Mebane
G� Water Plant Brooks Distribution
-Day Services
yt Church .. 9
' 74
King Auto Salvage Copart - Mebane
Foss Recycling 9 I4
t " Caruso's 74 Wheeleys Paint & Body
iO,Ae st Ext
7 1436
COUNTY: Alamance OWNER(S): Graham Mebane Water Treatinent Plant

prc
i; ess - cSCML UL14
Graham-Me62rle WIP
Process Seheuratic (1fl7-S1(1 S1
Desi01 Cap. 12 MGD
Air„ production 4.5 MGD
Suitt 1976
Expanded 2001-03
tkf5%N&-.2aIq -rS
Itaw Pumps
3x6.0MGD
1 x 3.0
Intake
Inclined NaOH
PlaP.es.• P R C -
NaOH i�
NaOCI
(ea. frlt.) -
Sedim� a
f —
E•-
E• -
Graharn-Mebane Lake 650
ac-250 BY gal
Parwner Op-1
r
F1occulator f f m Os n r
�Crr�G � NaOClla [
Polymer ^ _
.`
Flash Mixer
i000 KW Flocculator
Aux G Set �Sedim� e°�°" Llev.
Full SiteCaPacity its 4 Tank
.�i C•r
NreOH
I I
N-OC/ r Finished Purer s
3 x 4.0 MGD -Graham lust.
Phnsnhrr[e 3.0 MG 3.0 MG 2 x 2.5 - Mebane Svstem
RAWL.1 - I x 3.5 -Mebane
NuOG! Finished WwaterStorage ,
I t ;Fmrronia (�n� i
+ Ammm�ia ,
• Nancl
I
3upermfe to Sack Creek
Sludge to Land Application
$/W 8: Sludge Lagoons
0_ s MG each
DE.N'R ; g(O {F.cvi" y-97) SFde B
Public Wft"r Supply sm[iuu (Keview 4-0f)f
r—

Residuals Sampling Plan
Synagro Residuals Land Application for WQ0035207
Graham Mebane Water Treatment Plant
Nutrients and Metals Analysis
a Sampling Point: Storage Lagoons
a Sampling Frequency: Annually
a Sample Type: Composite
a Lab: Waypoint Analytical
Pathogen Reduction (Not Required)
Vector Attraction Reduction (Not Required)
TCLP
a Sampling Point: Storage Lagoons
a Sampling Frequency: Annually
a Sample Type: Composite
a Lab: Summit Environmental Labs

Quantitative Justification for Residuals Production Rate
Graham. Mebane WTP
Between the years of 2016 and 2019, the City Graham land applied approximately
153.75 dry tons of material each year. It is requested that Graham Mebane WTP be
permitted to land apply a maximum of 275 dry tons per year to account for any plant
fluctuations or future maintenance cleanouts.
Dry tons land applied between 2016 and 2019.
Year
Dry Tons
2016
127
2017
223
2018
202
2019
63

SUMMInt
Semmril Envitanmental Technologies, Inc.
3310 Win St.
ENVIrtON61EN`CALTECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223
Anatytical Labornrorlos TEL: [phone] FAX [phone]
Websile: htt :1Avw r.settek.conr
February 12, 2020
Ryan Copeland
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Graham WTP -REVISED
Dear Ryan Copeland:
Order No.: 20011553
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/24/2020 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
r__
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arktuisas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC F.87688, Georgia E87688, Idaho OH00923, Itlinois
200061, Indiana C-011-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota
409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R 201, Ohio DW, Ohio VAP
C1,0052, Oklahoma 9940, Oregon 011200001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah
OH00923201 I - 1, Virginia VELAP 9456, Washington C891
Page 1 of 33

ErEF, S��� SuttnttifEnviroluttettlalTeclutofogies,Inc Case Narrative
3310 Win Si.
ENv1noNM5NTALTEG14N 0MF.S,INC Cuyahoga Falls, Ohio 44223 WO#: 20011553
Analytical taboratorlov, TU: [phone] FAX [phone] Date: 2/12/2020
fVebsite: htt :/hinviv.settek.cottt
CLIENT: Synagro
Project: Graham WTP -REVISED
WorkOrder Narrative:
20011553: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditationslcertifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Prep Sample Comments:
20011553-OOIA 507141: Prep Comments for MtlPrep TCLP(3010A), Sample 20011553-OOIA:
Sample filtered after digestion.
Analytical Sequence Sample Notes:
20011553-001 A TCLP-VOC-Mstr 8260D: The VOC CCV (Batch RI 08884) exhibited high recovery
for Vinyl chloride; All samples were ND.
20011553-OOIA TCLP-SVOC-CPEST(8081B): Bracketing CCVs failed high for some analytes.
Samples in batch 41806 were non -detect for all analytes.
20011553-OOIA TCLP-SVOC-CPEST(8081B): LCS exhibited high recovery for several analytes;
Sample is ND
Revision v1
Page 2 of 33

SUMMELLJ- Snnrnril Envirownental Teclarologies, luc. Case Narrative
3310 Wirr St.
��SVII ONh1�NTAL �ECfiHOI AG1�S, INN. Crrynlroga Falls, Ohio 44223 WO#: 20011553
Armillyflcal Laborat MS TEL: [phone] FAX: [phone] Date: 2/12/2020
Websile: blip-Aviny,settek.conr
CLIENT: Synagro
Project: Graham WTP -REVISED
20011553-OOIA TCLP-SVOC-HERB_NPW(832113): Sample exhibited high recovery of Surrogate:
DCAA; Sample is non -detect for all analytes of interest.
REVISED REPORT: 2/12/20 includes Narrative for TCLP Pest LCS
Revision v1
Page 3 of 33

Srunttrit Cu+qromnental Technologies, In Qualifiers and Acronyms
U'T 3310 N'iu
E:PdYIRONIdt:NTAL Ti;CHl1(}tAGt>i3, INC Crryalraga Falls. Ohio 442� WO#: 20011553
Arraiytical Laboratories
TEL. [phone] FAY, (330) 253-44E Date: 2/12/2020
N'ebsire: htt :/hvtvivsettek.co
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
L The compound was analyzed for but was not detected.
d The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
g The hold time for sample preparation arid/or analysis was exceeded.
Q The result is reported from a dilution.
R The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
nr Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GUMS.
X The result was not confirmed when GC/MS Analysis was performed.
BIMB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-1+ The CCV recovery failed low (-) or high (+).
RIQDR The RPD was outside of accepted recovery limits.
QL-1+ The LCS or LCSD recovery failed low O or high M.
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-1+ The MS or MSD recovery failed low (-) or high (+).
QIVIR The MSIMSD RPD was outside of accepted recovery limits.
QV-1+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer
to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
MDL
Reporting Limit
Method Detection Limit
QC
Quality Control
Method Blank
LOD
Level of Detection
NIB
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
Practical Quantitation Limit
LCSD
Laboratory Control Sample Duplicate
PQL
CRQL
Contract Required Quantitation Limit
QCS
Quality Control Sample
PL
Permit Limit
DUP
MS
Duplicate
Matrix Spike
RegLvl
Regulatory Limit
Maximum Contamination Limit
MSD
Matrix Spike Duplicate
MCL
MinCL
Minimum Compound Limit
RPD
Relative Percent Different
RA
Reanalysis
1CV
initial Calibration Verification
RE
Reextraetion
ICB
Initial Calibration Blank
TIC
Tentatively identified Compound
CCV
Continuing Calibration Verification
RT
Retention Time
CCB
Continuing Calibration Blank
CIF
Calibration Factor
RLC
Reporting Limit Check
RF
Response Factor
DF
Dilution Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Revision vl
Page 4 of 33

SUMM111
Stuumit ESrrrrotanental Technologies, Inc. Workorder
rn 3310 61'irr Si.
Sample Summary
ENVIRONMENTALTECHNPLOOES, INC Ctr}altoga Falls, Ohio 44223 p
Analyttca! LaboYatarlOs TEL: [phone] FAX: [phone] WO#: 20011553
Webslte: htt :/hvww.settek.com 12-Feb-20
CLIENT: Synagro
Project: Graham WTP -REVISED
Lab SnmpleID Client Sample lD Tag No Date Collected Date Received Matrix
20011553-001 Graharn W3'P 112312020 2: 15:00 PM 1/24/2020 10:20:00 AM Sludge
Page 5 of 33

� '� Stnnnril Lrtviranuerriul Techaalogiesin Se. DATES REPORT
3310 TI7ir Sr.
r7winONIMUTALTECHHOWI-WS,SSG. Cuyahoga Falls, Ohio 44223 WO#' 20011553
/7nalyflcaf Labomforlos 7U: [phone] FAX: [phone]
12-Feb-20
flrehsile: hltn:/wunr.,wrfek.crnn
Client:
Synagro
Project:
Graham WTP -REVISED
Sample ID
Client Sample ID Collection Date Alatris Test Name Leachate Date Prep Date
Analysis Date
2001 1553-001 A Graham 1ir1T 112312020 2:15:00 PM Sludge Ig»tabilily, of Solids (SW-846: 1030)
2)312020 1:00:00 PM
pH (SW9045D)
213/2020 5:22:53 PM
Reactive Cyanide (901417.3.3.2)-Solid
2/612020 3:36:00 PM
Reactive Sulfide (9034)17.3,4-2
2/16/2020 1:15.00 PM
TCLP Herbicides by EPA 832113 1/3112020 5a10:00 PM
217/2020 6A4:00 ANI
TCLP Mercury Analysis (SW1311/7471/31/2020 5:00:00 PM 21412020 9:00:00 AM
214/2020 2:21.00 PM
TCLP Metals Analysis (SW 13I VW 10.113112020 5:00DO PM 21312020 11:35:00 AM
21G12020 11:53:52 AM
TCLP Metals Analysis (SW 131116010-113112020 5:06:00 PM 2/312020 11:35:00 AM
214/2020 7:08:57 PM
TCLP Pesticides Analysis (SW 131 118(1/31/2020 5:00:00 PM 2/312020 10:45:0.0 ANI
21612020 1:3700 AM
TCLP Semi-Volatiles Analysis I131/2020 5:00:00 PM 2/3/2020 10:30:00 AM
2/412020 8:33:00 PM
(S W 131 I18270)
TCLP Vulatiles Analysis 1/3112020 500:00 PM
2/412020 2:31:00 AM
Revision VI
Page 6 of 33

FEEM S U 'y
er�vtl101AIENtALTEC►tNal.oclF5,INC
A?7aly0caf Lotloratorfe-1
Sr,ravrril Environmental Technologies, Lec.
3310 Win St.
Cu gaha a Falls, Ohio 44223
t g
TEL: [phone] rAX: [phone]
117ebsite: hrra://1 n s,.settek.corn
Analytical Report
{base report)
WO#: 200I1553
Date Reported: 2/12/2020
CLIENT: Synagro
Tag Number:
Matrix: SLUDGE
Collection Date:
1/23/2020 2:15:00 PM
Lab ID: 20011553-OOIA
Project: Graham WTP -REVISED
Client Sample ID Graham WTP
Analyses Result
RL
Qual Units
DT Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW7470A
SW7470A Analyst: MJM
TCLP MERCURY ANALYSIS (SW131117470)
TCLP Mercury
ND
0.00200
mglL
1 214/2020 2:21:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010D
SW3010A Analyst: EAM
TCLP METALS ANALYSIS (SW131116010)
TCLP Arsenic(As)
ND
0.500
mglL
1 2/4/2020 7:08:57 PM
TCLP Barium(Ba)
NO
25.0
mglL
5 2/6/2020 11:53:52 AM
TCLP Cadmium(Cd)
ND
0.100
mg1L
1 2/4/2020 7:08:57 PM
TCLP Chromium(Cr)
ND
0.200
mg1L
1 2/4/2020 7:08:67 PM
TCLP Lead(Pb)
ND
0.500
mglL
1 2/4/2020 7:08:57 PM
TCLP Selenium(Se)
0.0519
0.0500
mg1L
1 2/4/2020 7:08:57 PM
TCLP Silver(Ag)
ND
0.500
mg1L
1 2/4/2020 7:0&57 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270
SW3510C Analyst: SFG
TCLP SEMI-VOLATILES ANALYSIS (SW131118270)
1,4-Dichioroben7eno
ND
0.200
mg1L
2 2/4/2020 8:33:00 PM
2,4,5-Trichlorophenoi
ND
0.500
mglL
2 214/2020 8:33:00 PM
2,4,6-Trichlorophenol
ND
0.500
mg1L
2 2/4/2020 &33:00 PM
2,4-Dinitrotoluene
NO
0.100
mg1L
2 2/4/2020 8:33:00 PM
Cresols, Total
NO
10.0
mg1L
2 2/4/2020 8:33:00 PM
Hexachloro-1,3-butadiene
ND
0.0400
mglL
2 214/2020 8:33:00 PM
Hexachlorobenzene
ND
0A00
mg1L
2 2/4/2020 8:33:00 PM
Hexachloroethane
NO
0.200
mg1L
2 2/4/2020 8:33:00 PM
Nitrobenzene
ND
0.200
mg1L
2 2/4/2020 8:33:00 PM
Pentachlorophenol
NO
0.500
mg1L
2 2/4/2020 8:33:00 PM
Pyridine
NO
0.500
mg1L
2 2/4/2020 8:33:00 PM
Surr: 2-Fluorophen0l
60.2
10 - 109
%Rec
2 2/4/2020 8:33:00 PM
Surr. Phenol-d6
61.7
10 - 109
%Rec
2 214/2020 8:33:00 PM
Surr. Nitrobenzene-d5
65.5
19 - 120
%Rec
2 214/2020 8:33:00 PM
Surr: 2,4,6-Tribrornophenol
89.8
10 - 120
%Rec
2 2/4/2020 8:33:00 PM
Surr: 2-Pluorobiphenyl
65.2
22 - 117
%Rec
2 2/4/2020 8:33:00 PM
Surr: p-Terphenyl-d14
98.4
34 - 116
%Rec
2 21412020 8:33:00 PM
B
Analyte detected in the associated Method Blank
E
Value above quantitation range
Qualifiers:
H
Holding times for preparation or analysis exceeded
M
Manual hitegration used to determine area response
MC
Value is below Minimum Compound Limit.
N
Tentatively identified compounds
ND
Not Detected
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits Revision vI
RL
Reporting Detection Limit
U
Samples with Ca[eVal < MDL
Page 7 of 33

'�
211"rol summ
Tj EJUVIIIONI,fENTAL TecNNat.ni;ttS, LNG
Ana{y rlcal Laboraforlo�
s,«�r�:,tonmenia,Technologies,Inc.
3310 Win St.
Ohio 44223ll Fa
lls, as,
Cuyahogawp{!:
TEL: [phone] FAX: [phone]
Plebsile: hrf :11vu,ii,.sellek.conr
Analytical Report
(base report)
20011453
Date Reported: 2/12/2020
CLIENT: Synagro
Tag Number:
Collection Date:
1/23/2020 2:15:00 PM
Matrix: SLUDGE
Lab ID: 20011553-OOIA
Project: Graham WTP-RE VISED
Client Sample ID Graham WTP
Analyses Result
RL Qual Units
DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW351OC Analyst: SEK
TCLP PESTICIDES ANALYSIS (SW131118081 )
Chlordane, total
ND
0.125
mg1L
5 2/6/2020 1:37:00 AM
Toxaphene
ND
0.250
mg1L
5 2/612020 1:37:00 AM
Endrin
ND
0,0126
dQL+ mglL
5 2/6/2020 1:37:00 AM
gamma-BHC
ND
0.0125
dQC+ mglL
5 2/6/2020 1:37:00 AM
Heptachlor
ND
0.0125iQC+QLimg1L
5 21612020 1:37:00 AM
Heptachlor epoxide
ND
0.0125iQC+QL1mg1L
5 2/6/2020 1:37:00 AM
Methoxychlor
ND
0.01251QC+QLAmgIL
5 2/6/2020 1:37:00 AM
Surr. TCMX
18.3
10 - 119
%Rec
5 2/6/2020 1:37:00 AM
Surr. DCB
24.0
10 - 119
%Rec
5 2/6/2020 1:37:00 AM
TCLP HERBICIDES BY EPA 8321B
SW8321A
SW1311M Analyst: BJH
2,4-D
ND
0.500
mg1L
50 2/7/2020 C)A4:00 AM
2 4 5-TP
ND
0.500
mglL
50 2/7/2020 6:44:00 AM
Surf: 2,4-Oichlorophenylacetic aci
149
70 - 130
S %Rec
50 2/7/2020 6:44:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260
SW1311M Analyst: RMT
TCLP VOLATILES ANALYSIS
1,1-Dichloroelhene
ND
0.500
mglL
100 2/4/2020 2:31:00 AM
1,2-Dichloroethane
ND
0.500
mg1L
100 2/4/2020 2:31:00 AM
ND
10.0
mglL
100 2/4/2020 2:31:00 AM
MEK
ND
0,600
mglL
100 21412020 2:31:00 AM
Benzene
Carbon tetrachloride
ND
0.500
mglL
100 2/4/2020 2:31:00 AM
Chlorobenzene
ND
5.00
mg1L
100 2/4/2020 2:31:00 AM
Chloroform
ND
0.500
mglL
100 2/4/2020 2:31:00 AM
Tetrachloroethene
ND
0.500
mg1L
100 2/4/2020 2:31:00 AM
Trichloroethene
ND
0.500
mg1L
100 2/4/2020 2:31:00 AM
Vinyl chloride
ND
0.200
QC+ m91L
100 2/4/2020 2:31:00 AM
Surr: 4-Bromofluorobenzene
96.7
70 - 130
%Rec
100 2/4/2020 2:31:00 AM
Surr: Dibromofluoromethane
105
70 - 130
%Rec
100 2/4/2020 2:31:00 AM
Surr: Toluene -dB
103
70 - 130
%Rec
100 2/4/2020 2:31:00 AM
B
Analyte detected in the associated Method Blank
E
Value above quantitation range
Qualifiers:
H
Holding times for preparation or analysis exceeded
M
Manual Integration used to determine area response
MC
Value is below Minimum Compound Limit.
Al
Tentatively identified compounds
ND
Not Detected
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits Revision vI
RL
Reporting Detection Limit
U
Samples with CaleVal < MDL
Page 8 of 33

SUe
StraarrilEtlriroronenlal Technologies, lnc.
3310 WIn St.
Analytical Report
(base report)
Cn Yalg Falls, Ohio 44223
ro a
WO#: 20011553
LiJEeavlaONleFI�TaurEGtttJal_ctGits.lrtc
Analyllcal Laborafor'!ts
TEL: [phone] FAX' [phone]
lhebsile: h1tn:/Av)nL,.set1ek.com
Date Reported: 2/12/2020
CLIENT: Synagro
Tag Number:
Matrix: SLUDGE
Collection Date:
1/23/2020 2:15:00 PM
Lab ID: 20011553-001A
Project: Graham WTP -REVISED
Client Sample ID Graham WTP
Analyses Result RL Qual. Units
DF Date Analyzed
RCI-SOLID-WI IGNITABILITY1030
SW9014
Analyst: CXS
REACTIVE CYANIDE (901417.3.3.2)-SOLID
Cyanide, Reactive
ND 11.2 mg/Kg
1 2/6/2020 3:36:00 PM
RCI-SOLID-W/ IGNITABILITY1030
SW1030
Analyst: AJT
IGNITABILITY OF SOLIDS (SW-846: 1030)
Ignitabiliiy non-flammable mmisec
1 2/3/2020 1:00:00 PM
RCI-SOLID WI IGNITABILITY1030
SW9045D
Analyst: VVK
PH (SW9045D)
pH
6.7 s.u.@20.00
1 2/3/2020 5:22!53 PM
RCI-SOLID-W11GNITABILITY1030
SW9034
Analyst: CXS
REACTIVE SULFIDE (9034)17.3.4.2
Sulfide, Reactive
ND 25.0 mg/Kg
1 2/16/2020 1:16:00 PM
I3
Analyte detected in the associated Method Blank
E
a Value 9 uantitation range
QualiTiers:
H
Holding times for preparation or analysis exceeded
M
Manual Integration used to determine area response
MC
Value is below Minimum Compound Limit.
N
'Tentatively identified compounds
{ ND
Not Detected
P
Second column confinnation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits Revision v1
RL
Reporting Detection Limit
U
Samples with CalcVal < MDL
Page 9 of 33

Stn+unif Environmental Technologies, Inc.Accreditation Program
frSumonly
3310 Win& Analytes Report
CNV[nON1AENYAL TE-CHNOL.t}GIES, INC Cuyahoga rafts, 01tio 44223
Anniytical LabtlWIOG TEL: [phone] PAX: [phone] WO#: 2001I553
P8
Website: hff Wwwtr.seffek.con) 12-Feb-20
State: NW
Client: Synagro
Project: Graham WTP -REVISED
Program Name: NC WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
20011553-OOIA Sludge
lgnitability of Solids (SW-846: 1030)
Ignitability
A
Sludge
pH (SW9045D)
hydrogen Ion (pH)
A
Sludge
Reactive Cyanide (9014/73.3.2)-Solid
Cyanide, Reactive
U
Sludge
Reactive Sulfide (9034)/73.4.2
Sulfide, Reactive
U
Sludge
TCLP Herbicides by EPA 9321B
2,4,5-TP
A
Sludge
TCLP Herbicides by EPA 832113
2,4-1)
A
Sludge
TCLP Mercury Analysis (.SW 131117470)
Mercury
A
Sludge
TCLP Metals Analysis (SW131116010)
Arsenic
A
Sludge
TCLP Metals Analysis (SW13 t 116010)
Barium
A
Sludge
TCLP Metals Analysis (SW131116010)
Cadmium
A
Sludge
TCLP Metals Analysis (SW 1311160 10)
Chromium
A
Sludge
TCLP Metals Analysis (SW131116010)
Lead
A
Sludge
TCLP Metals Analysis (SW131116010)
Selenium
A
Sludge
TCLP Metals Analysis (SW]311/6010)
Silver
A
Sludge
TCLP Pesticides Analysis (SW 131118081)
Chlordane, total
A
Sludge
TCLP Pesticides Analysis (SWI31118081)
Endrin
A
Sludge
TCLP Pesticides Analysis (SW131118081)
gamma-BHC
A
Sludge
TCLP Pesticides Analysis (SW 1311/8081)
Heptachlor
A
Sludge
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Sludge
TCLP Pesticides Analysis (SW131118081)
Mcthoxychlor
A
Sludge
TCLP Pesticides Analysis (SWI311/8081)
Toxaphene
A
Sludge
TCLP Semi-Volatiles Analysis (SW1311/8270)
IA-Dichlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW131118270)
2,4,5-Trichlorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131118270)
2,4,6-Trichlo€ophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW131 1l8270)
2,4-Dinitrotoluenc
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131119270)
Cresols, Total
A
Sludge
TCLP Semi.Volatiles Analysis (SW131118270).
Hexachlorobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131118270)
ilexachlorobutadiene
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311/8270)
Hexachloroethanc
A
Sludge
TCLP Semi-Volatiles Analysis (SW 131118270)
Nitrobenzene
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311/8270)
Pentachtorophenol
A
Sludge
TCLP Semi-Volatiles Analysis (SW 1311/8270)
Pyridine
A
Version #3
Page 10 of 33

j:=:CrM S U M Summit Ern=ironnrertlal Teclurologies, 1ne.
t I'` 3310 Wn St.
Accreditation Program
Analytes Report
i
ENVInCHMENTAL MCANOW)MES, INC Cityahoga Falls, Ohio 44223
TEL: [phone] FAX-' [phone]
WO#: 20U11553
An:tlyUcof Laboralorlee
Websile: con,
12-Feb-20
State: NW
Client: Synagro
Program Name: NC WW_SCM
Project: Graham WTP -REVISED
Sample ID Matrix Test Name
Analyte Status
20011553-OOlA Sludge TCLP Volatiles Analysis
1,1-Dichloreethene A
Sludge TCLP Volatiles Analysis
1,2-Dichloroethane A
Sludge TCLP Volatiles Analysis
2-Butanone A
Sludge TCLP Volatiles Analysis
Benzene A
Sludge TCLP Volatiles Analysis
Carbon tetrachloride A
Sludge TCLP Volatiles Analysis
Chlorobenzene A
Sludge TCLP Volatiles Analysis
Chloroform A
Sludge TCLP Volatiles Analysis
Tetrachloroethene A
Sludge TCLP Volatiles Analysis
Trichloroethene A
Sludge TCLP Volatiles Analysis
Vinyl chloride A
Version #3
Page 11 of 33

S U MM surunal Lnerrrum+eninl lechraihigies, Lle. QC SUMMARY REPORT
3310 Win Sr.
TjENVI00NIAFWTALT@CHHQI.0GiES, INC CgIzrhogaFa11s, 0hro 44223 Wo#: 20011553
Analylfcal Luboralorles M,: [phone] VAX.' [phone] 12-Feb20
li'ebsile: htrp:.iirtvu•seHekcam
Client: Synagro
41775
Project: Graham WTP -REVISES RA#chID:
Sample ID: M8-41776
Client ID: PBS
SampType: MBLK
Balch ID: 41776
TeslGode: TCLP VOG-M Units: mglL
TestNo: 5W6260 SW1311M
Prep Date: 113112020
Analysis Dale: 2/412020
RunNo: 106864
SegNo: 2603620
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighUmit RPD Ref Val
%RPD RPDLimit Qual
1,1-01chloroethene
ND
0.0500
1,2-1)ichloroethane
N❑
0.05W
M£K
ND
1.00
Benzene
NO
0,0500
Carbon tetrachloride
ND
0.0600
Chloroben7ene
ND
0.500
Chloroform
NO
0.0500
Tetrachloreethene
ND
0.0500
Trichloroethene
ND
0.0500
QG+
Vinyl chloride
N❑
0.0200
Surr:4-Bromofluorobenzene
492
500.0 98.4 70 130
Sur(: Dibromo0uoromethane
520
500.0 104 70 130
Surr. Toluene-d8
517
500.0 103 70 130
Qualifiers: B Analyte detected in the associated Method Blank
T Analyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
E Value above quantitation range
M Manual integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 12 of 33
H holding limes for preparation or anal}
&IC Value isbelowMinimum Compound RevisionV1
PL Permit Limit
S Spike Recovery outside accepted reco

MmI 5,rrrrrrrlrF�rrror""alaiTeclrrmlu ",Ine. QC SUMMARY REPORT
ffl 3310 IVirr Sf.
ENVIRONMEWAL 7ECHNOLOMF% INC Crgnhoga Foils, Oliio 44223 W09: 20011553
Analytical Lnboraferles YFL: [phone] FAX.' [phone] 12-Feb-20
IVebsire: ham:/hwr�eserfekcnnr
Client: Synagro
BatclrlD: 41795
Project: Graham WTP-RPVtSBD
Sample SD: MS-41795 SampType: M13LK TeslCode: Mtl-TCLP-7(6 Units: mg1L
Client ID: PBS Batch ID: 41795 TestNo: SW6010D SW3010A
Analyte Result PQL SPK value SPK Ref Val
TCLP Arsenic(As)
ND
0.500
TCLP Badum(Ba)
ND
5,00
TCLPCadmium(Cd)
N❑
0.100
TCLP Chromium(Cr)
ND
0.200
TGLP Lead(Pb)
NO
0.500
TCLP Selenium(Se)
ND
0.0500
TCLP Silver(Ag)
ND
0.500
SampType: LCS
TeslCode: MII-TCLP-7(6
Units: mg1L
Sample ID: LCS-41795
Client ID: LCSS
Batch ID: 41795
TestNo: SW6010D
SW3010A
Analyte
Result
PQL
SPKvalue SPK Rat Val
TCLP Arsenic(As)
1.97
0.500
2.000
D
TCLP Barium(Ba)
ND
5.00
2.000
0
TCLP Cadmium(Cd)
2.20
0.100
2.000
0
TCLP Chromium(Cr)
2.06
0.200
2.00D
0
TCLP Lead(Pb)
2.17
0.500
2.000
0
TCLP Selenium(Se)
2.18
0.0500
2.000
0
TCLP Silver(Ag)
2.19
0.500
2,000
0
Qualifiers: B Analyse detected in the associated Method Blank
! Aaalyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
Prep Date: 21312020
Analysis Date: 21412020
%REC LowLimit HighLimit RPD Ref Val
Prep Date: 2/312020
Analysis Date. 21412020
%REG LowLimil HighLimit RPD Ref Val
98.3
80
120
104
80
120
110
Bo
120
103
0o
120
108
80
120
109
80
120
109
80
120
E Value above quanlitali0n range
M Manual lnlegration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection limit
Page 13 of 33
RunNo: 108891
SegNo; 2604322
%RPD RPDLimil Qua]
RunNo: 108891
SegNo: 2604323
0/6RPD RPDLimit Qual
H Holding times for preparation or anal)
MC Value is below Minimum Compound Revision vl
PL Parmit Limit
S Spike Recovery autside accepted reco

Sunni!EnWranniurrfalTechnologies,Inc.
U MM I T 3310 tVin Sr.
QC SUMMARY REPORT
TECHNOLOGIES, INC
Crq¢rboga Falls, Ohio 44223
\Volk: 20011553
LLJENVInONIAENTAL
Analytkcal Labera:orlos 7TL:
[phone] FAX. (330) 253a189
12-Feb-20
f{ ebsUe: lvl1�/Pouwsellek.corn
Client:
Synagro
Project:
Graliarn WTP-RFViSED
Batcld➢: 41814
Sample ID: MB-41814
Client ID: PBS
Analyte
IA-Dichlorobenzene
2,4, 5-Trichlorophenot
2,4,6 Trichlorophenol
2,4-Dinitrotoluene
o-Cresol
Cresols, Total
Hexachloro-1,3-butadiene
Hexachlarobenzene
HexecNoroethane
Nitrobenzene
Pentachlorophenol
Pyridine
Surr: 2-Fluorophenol
Surr: Phenol-d6
Surr. Nitrobenzene-d5
Surr. 2, 4, 6-T rib i o m op he not
Surr. 2-F l u o ro b i ph any I
Surr. p Terphenyl-64
SampType: MBLK
Batch ID: 41814
Result
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
ND
ND
0.450
0.488
0.471
0.812
0,474
0.661
TestCode: SVOC•BNA_T Units: mg1L
TestNo: SW8270 SW3610C
PQL SPK value SPK Ref Val
0.100
0.250
0.250
0.0500
0.250
5,00
0.0200
0-0500
0.100
0.100
0250
0.260
Qualifiers: B Analyte detected in the associated Method Blank
l Analyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
Prep Date: 21312020 RunNo: 108857
Analysis Date, 21412020 SegNo: 2604887
%RLC Lowl.imil Highl-imit RPD Ref Vat °ARPD RPDLimit Dual
1.000
45.0
10
109
1.000
40,8
10
109
1,000
47.1
19
120
1.000
81.2
10
120
1.000
47.4
22
117
1.000
86.1
34
116
E Value above quantitation range
M Manual Integratian used to determine area response
P Second column confirmation exceeds
ELL Reporting Detection Limit
Page 14 of 33
H Holding times For preparation or anal)
MC Valve is below Minimum Compound
Revision V I
PL. Permit Limit
S Spike Recovery outside accepted rcco

Op3370
u 'l
SnnrfnfrE,n+ifs,„xerihll'1'ecbr331Ves, St.
iVin Sf.
QC SUMMARY REPORT
ENVUH)NIAEN7AL 7t:CHN01.0GIFS, INC
CrOrrhoga RdIs, Ohio 14223
WON: 20011553
Anofytical leberatortas
M,: [phone] /,AX..- [phone]
7,7-Teb-20
{velrstre: hfh :omm,� _ r.setrek.con,
Client:
Synagro
BatchlD: 41814
Project:
Graham WTP-REVISFQ
Sample ID: LCS-41814
SampType: LCS
TostCode: SVOC-BNA_T Units: mg1L
Prep Dale:
21312020
Client ID: LCSS
Batch ID: 41814
TestNo: SW8270
SW3510C
Analysis Date:
21412020
Result
PQL
SPK value
SPK Ref Val
%REC
LowLimit Hight.imit
RPD Ref Val
Analyte
1,4-Dichlorobenzene
0.373
0.100
0.0000
0
46.6
36.4
130
2,4,5Trichlorophonol
0.757
0.250
0.8000
0
94.7
31.7
132
2,4,6 Trichlarophenol
0.721
0.250
0.8000
0
90.9
31.1
133
2,4-Dinitrotoluene
0.893
0.0500
0.8000
0
112
43.3
130
0-0fesol
0.564
0.250
0.8000
0
73.0
32.9
130
Cresols, Total
N❑
5.00
1.600
0
74.6
31.7
130
Hexachloro-1,3-buladiene
0.388
0.0200
0.600D
0
48.6
31.4
130
Hexachlorobenzene
0.688
0.0500
0.8000
0
66.0
43.1
130
Hexachloroethane
0,335
0.100
0.800D
0
41.9
36.5
130
Nitfobenzene
0.540
0.100
0.8000
0
67.5
39.5
130
Pentachlorophenal
0.812
0.250
0.8000
0
102
34
130
Pyridine
0.269
0.250
0.8000
0
33.6
10
130
Surr. 2-Fluorophenol
0.631
1.000
63.1
17.1
130
Sum Phenol-d6
0.647
1.000
64.7
10
130
Surr. Nitrobenzene-d5
0.626
1.000
62.6
32.6
130
Sort: 2,4,6 Tribromophenal
1-01
1.000
101
4.43
130
Surr 2-Fluorobiphenyl
0.639
1.000
63.9
41.8
130
Surr. p-Terpheayl-d14
0.937
1.000
93.7
36.4
130
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quamitatinn limits
ND Not Detected
R RPD outside accepted recovery limits
J; Value above quanfliation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 15 of 33
RunNo: 108867
SegNo: 2804888
%RP❑ RPDLimit Oual
H Holding times for preparation or anal3
MC Value is below Minimum Compound Revi$ionV1
PL PennitLimit
S Spike Recovery outside accepted reco

,Srnnmif Lin•irarnueptnl Teclrenl10 W r 81.
33I0 {Vert Sr.
QC SUMMARY REPORT
�C
TECHNOLOGIES, INC
Oe3nhogoT'alls, Ohio 44223
WO#: 20011553
UJENVIIIONIAENTAL
llrmlytical Laboratorlos
TEL: [phone] FAX.* [phone]
I2-Feb-20
0`ehsire: lot rn:%nrnyseAek. conr
Client:
Synagro
Project:
Graham WTP-RP.VISED
RatchID: 41814
Sample ID: 20011447-1101AMS
SampType: MS
Tortcode: SVOc-BNA T Units: mgfL
Prep Date:
21312020 RunNo: 108857
Client ID: BatchQC
Batch ID: 41814
TestNo: SW8270
SW3510C
Analysis Date:
2!4l2020 SegNo: 2606452
Result
PQL
SPK value
SPK Ref Val
%REC
LOwLimit Hight-imit
RPD Ref Val %RP❑ RPDLimil Qual
Analyte
1,4-Dichlotobenzene
0.342
0.200
0.8000
0
42.7
33.8
126
2,4,5 Trichlorophenol
0.782
0.500
0.8000
0
97.8
28.7
144
2,4,6Trichtorophenol
0.850
0.500
0,8000
0
106
12.8
153
2,4-0inilrotoluene
0.729
0.100
0.8000
0
91.1
20.4
155
"resat
0.686
0.500
0.8000
0
83.2
10
148
Cresols, Total
ND
10.0
1.600
0
85.8
10
148
Hexachtoro-1,3-butadiene
0.368
0.0400
0.8000
0
46.0
29
126
Hexachlorohenzene
0.679
0.100
0.8000
0
84.9
33.7
134
Hexachloroethane
0.323
0.200
0.8000
0
40.4
32.8
132
Nitrobenzene
0.562
0.200
0.800D
0
70.2
20
168
Pentachlorophenol
0.937
0.500
0.8000
0
117
10
176
Pyridine
ND
0.500
0.8000
0
44.3
10
130 m
Sur2-Fluorophenal
r.
0
1.000
0
3.39
13G Sd
Surr. Phenol-d6
0.732
1.000
73.2
5
130
Surr. Nitrobenzene-d6
0.648
1.000
64.8
14.5
154
Surr. 2,4,6-Tribromophenol
0.998
1.000
09.8
19.5
130
Surr.2-Fluorobiphenyl
0.713
1.000
71.3
34.4
130
Surr. p-Terphenyl-d14
0,901
1.000
90.1
8.86
156
Qunliferso B Analyte detected in the associated Method Blank
J Anatyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
9 Value above quantitation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 16 of 33
H Holding times for preparation or anal)
MC Value is below Minimum Compound Revision vi
Pl. Permit Limit
S Spike Recovery outside accepted reco

11T srarmul Errrirnrrrnerttal Y'eclnrolagies, fry.
3310 Whr Sr.
SUMM
QC SUMMARY REPORT
F"`=
161
ENVInOJJMENTALTECHHOLAn{ES,St2C
nha a Fa71.z Ohio 44223
Cu S S
253-8211 d AX [phone]
WOfi: 2901I553
Anolytica11aboraiorics 7TiL:
(330)
72-I e8-20
IVebsile: hrtp://,r,vusetfekcom
Client:
Synagro
Project:
Graham WTP -REVISED
BatchID: 41814
Sample ID: 20011447-007AMSD
Samp7ype: MSD
TmtCode: SVOC-BNA_T Units: m9tL
Prep Date:
21312020
RunNo: 108857
Client ID: BalchQC
Balch ID: 41814
Tes1No: SW8270
SW3510C
Analysis Date:
214t2020
SegNo: 2606453
Result
PQL
SPK value
SPK Ref Val
-AREC
LowLlmit Hiphi-imil
RPD
Ref Val
ARPD RPDLimit
Analyte
1,4-Dichlorobenzene
0.302
0.200
0.6000
0
37.8
33.8
126
0.3416
12.2 30
2,4,5-Trichlarophenol
0,715
0.500
0.8000
0
89.4
28.7
144
0,7820
8.9a 30
2,4,6-T(chlcfophanDl
0.804
0.500
0.8000
0
101
12.8
153
0.8504
5.56 30
2,4-DifArotoiuene
0.729
0.100
0.8000
0
91.2
20.4
165
0.7288
0.0549 30
o-Cresol
Q641
0.500
0.8000
0
80.2
10
148
0,6656
3.73 30
Cresols, Total
NO
10.0
1.600
0
81.5
10
148
0
0 30
Hexachloro-1,3-butadiene
0.360
0.0400
0.8000
0
45.0
29
126
0.3680
2.20 30
Hexachlorobenzene
0,632
0.100
0.8000
0
79.0
33.1
134
0.6792
7.20 30
Hexachlorcethane
0.274
0.200
0,6000
0
34.3
32.8
132
0.3228
16.4 30
Nitrobenzene
0.539
0.200
0.8000
0
67.4
20
155
0.5620
4.22 30
Pentachlorophenol
0.909
0.500
0.8000
0
114
10
176
0.9372
3.03 3o
Pyridine
ND
0.500
0.8000
0
44.8
10
130
0
0 30
Sure 2-Pluomphenol
0
1.DD0
0
3.39
130
0
Surf: Phenol-d6
0.667
1.000
66.7
10
130
0
Sum Nitrobenzene-d5
0.632
1.00o
63.2
14.5
154
0
Surr.2,4,6-Tribromophenot
0.957
1.000
95.7
%5
130
0
Surr.2-riuorobiphanyl
0.700
1000
70.0
34.4
130
0
Sum p-TerphenyW14
0.847
1.000
84.7
8.86
156
0
Qualifiers: 13 Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
E Value above quantitatim range
M Mannal Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 17 of 33
H Holding times for preparation or anal)
MC Value is below Minimum Compound
PL Permit Limit
S Spike Recovery outside accepted mco
Qual
m
Sd
Revision v1

t,»,e»1a1Tec1malagiesinSt QC SUMMARY REPORT
3310 {{rrrr Sr.
EASymONIAENTALTECHNOLOGIFS,INC Cit) hagaFall;Uhio41223 WQ#: 200I1553
Analytical Laboraferlas TFM: [phone] FAX: [phone]
I2-Feb-10
Websife: loin:/nvnm,xeuek.ca»
Client: Synagro
Project: Graham WTI' -REVISED Batch ID: 41818
Sample ID: MB-41818 SampType: MBLK TeslCode: HG_TCLP(74 Units: PPM Prep Dale: 2/412020 RunNo: 108886
Client ID: PBS Batch ID: 41818 TestNo: SW7470A SW7470A Analysis Date: 21412020 SegNo: 2603657
Analyle Result PQL SPK value SPK Ref Val °/,REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury NO 0.00200
Sample ID: LC841818
Client ID: LCSS
Analyte
TCLP Mercury
SampType: LCS TestCodo: HG_TCLP(74 Units: PPM
Batch ID: 41818 TestNo: SW7470A SW7478A
Result POL SPK value SPK Ref Val
0.00402 0.00200 0.00400 0
Sample ID: 20011609.00IAMS SampType: MS
Client ID: Balch= Batch ID; 41818
Analyte Result
TCLP Mercury 0.00424
Sample ID: 20011609-001AMSD SampType: MSD
Client ID: BatchQC Batch ID: 41815
Analyte Result
TCLP Mercury 0.00436
TestCode: HG_TCLP(74 Units: PPM
TestNo: SW7470A SW7470A
PQL SPKvalue SPKRefVal
0.00200 0.00400 0
TeslCode: HG_TCLP(74 Units: PPM
TestNo: SW7470A SW7470A
PQL SPK value SPK Ref Val
0.00200 0.00400 0
Qualifiers: B. Analyte detected in the assmiated Method Blank
) Analyte detected belowquanlitalion limits
ND Not Detected
R RPD outside accepted recovery limits
Prep Dale: 214/2020
Analysis Date: 21412020
%REC Lowl-imit HighLimit RPD Ref Val
101 80 120
Prep Date: 21412020
Analysis Date: W412020
%REC LowLitnit HighLimit RPD Ref Val
106 75 125
Prep Date: 2/412020
Analysis Date: 21412020
%REC Lowl-imit HighLimit RPD Ref Vat
109 75 125 0.00424
C Value above quantitation range
M Manual integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page; 18 of 33
RunNo: 108886
SegNo 2603658
%RPD RPDLimit Qual
RunNo: 108886
SegNo: 2603668
%RPD RPDLimit Qual
RunNo: 108886
SegNo: 2603669
%RPD RPDLimit Qual
2.79 20
H holding times for preparation or anal]
MC Value is below Minimum Compound Revision vi
PL Permit Lim-sl
S Spike Recovery outside accepted reco

UM111 Snnnai7lanira+0aenlnl Teclnrnlogies, bre.
3310 lI rn Sr.
QC SUMMARY REPORT
EN111110NMENTALTECNNOLOGIES, INC
Cf"hoga Palls, Otero 44223
W09: 20011553
Anntytical Laborararles TEL:
[phone] FAX..• (330J 253d4S9
72-Feb-2t7
R+eBslre: bun:/rirn�rsekek.com
Client:
Synagro
Project:
Graham WIT -REVISED
BatchLl):
41818
Sample ID: 20011609-OOIAMSD SampType: MSD
TeslCode: HG_TCLP(74 Units: PPM
Prep Date, 21412020
Run No: 108886
Client 1D:
SatchQC Batch ID: 41818
TestNo' SW7470A SW7470A
Analysis Date: 21412020
SegNo: 2603669
Analyte
Resuit
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref V0
%RPD RPDLimil Qual
Sample ID: MB2-41818 SampType: MBLK
TeslCode: HQ_TCLP(74 Units: PPM
Prep Date: 2/412020
RunNo: 108886
Client ID,
PBS Batch ID: 41818
TestNo: SW7470A SW7470A
Analysis Date: V412020
SegNo: 2603670
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Vat
%RPD RPDLImit Qual
TCLP Mercury ND
0.00200
Sample ID: TCLP BLANK 2-3-20 SampType: MBLK TeslCode: H(3TCLP(74 Units: PPM Prep Date: 2/412020 RunNo: 100886
Client ID: PBS Batch ID: 41818 TestNo: SW7470A SW7470A Analysis Dale: 2/412020 SegNo: 2603678
Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imil HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Mercury ND 0,00200
Qualifiers: B Analyte detected in the associated Method Blank
1 Analyte detected below quanthation limits
ND Not Detected
R RPD outside accepted recovery limits
B Value above quantitation range
M Manual integration used to detemline area msponse
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 19 of 33
H Holding times for preparation or anal}
MC Value isbelow Minimum Compound
Revision V]
PL Permit Limit
S Spike Recovery outside accepted reco

„snito,rr......a/T",rrrolo1,e
S U M M' 11
b”.
33I0 JViu S1.
QC SUMMARY REPORT
LLJENVIn0NMF!NTAL
TECHNGLOGIE9, INC Crgxrlrngn Falls, Ohio 44223
Analytical Laboratories TEL: [phone] FAX: [phone]
IYebsife: hgP:Qmrwuaseaek cw�r
WOO: 20011553
12_Feh-20
Client:
Projeet:
Synagro
Graham WTP -REVISED
I3aEcL1Il; R108839
Sample ID: LCS-RIO8839 SampType: LCS
Client ID: LCSS Batch ID: R108339
TeslCode: Ignitability_S Units, mmisec
TestNo: SW1030
Prep Date:
Analysis Dale:
RunNo: 108839
2/312020 SegNo: 2601828
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowtimil Hight.imil RPD Ref Val %RPD RPDLimit Qual
Ignilability
B,29
7.240 0 115
70
130
Sample ID: 20010917-OOIADUP SampType: DUP
Client 1D: BatchQC Batch fD: R108839
TestCode: Ignitahility_S Units: mmisec
TestNo: SW1030
Prep Dale:
Analysis Date:
RunNo: 148839
21312020 SegNo: 2601830
'
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability
non-flammable
0 0 20
Sample ID: 20011093-001ADUP SampType: DUP
Client ID: BatchQC Batch ID: R108839
TestCode' lgnitabilify_S Units: mmisec
TestNo: SW1030
Prep pate:
Analysis Date:
RunNo: 108839
2131202D SegNo: 2601832
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignilability
non-flammable
0 0 20
Sample lD: 29011093.002ADUP SampType: DUP
Client ID: BatchQC Batch ID: R108839
TestCode: lgnitablI1ty_S Units: mmisec
TestNo: SW1030
Prep Date:
Analysis Date:
RunNo: 108839
21312020 SegNo: 2601834
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitability
non-flammable
0 0 20
Qualifiers:
B Analyte detected in the associated Method Blank E Value above quantitation range
J Analyte detected below quantitalion limits m Ivfanual Integration used to determine
Nb Not Detected P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
BTM response
H Holding times for preparation or anal}
MC Valuc is below Minimum Compound Revision vl
PL permit Limit
S Spike Recovery outside accepted reco
Page 20 of 33

Sunnnil F.'rn'irmnnenlal
U M M'
Tecfnrologfes, 1uc.
3310 1Yirr St.
QC SUMMARY REPORT
ENVIRONtAENTALTECHNp OOKS• INC CuyahuNrcrFnllx, Ohio-1a223
Analytical Laboralarfes M. 030) 253-8211 TAX.(330) 253-44R7
Tyehsile: hl1n:/ns•ivir.sellek.cam
WD#: 20011553
12-I eL-20
Client:
Project:
Synagro
Graham WIT -REVISED
BatchiD: R108839
Sample ID: 20011093-002ADUP SampType: DUP
Client ID: BatchQC Batch ID: R108839
TestCode: Ignitabllity_S Units: mmfsec
TeslNo: SW1030
Prep Date: RunNo: 108839
Analysis DoW 2f312020 SegNo. 2601834
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowUrnit HighLimit RPD Ref Val %RPD RPDLImit Qual
Sample ID: 20011324-OOIADUP SampType: OUP
Client ID: BatchQC Batch ID: R108839
TestCode: ignitability_S Units: mmisec
TeslNo: SW1030
Prep Date: RunNo: 108839
Analysis Date: V312020 SegNo: 260183E
Analyte
Result
PQL SPKvalue SPK Rel Val
%RFC Lowl-imit HighLimit RPD Ref Val "ARPD RPDLimit Qual
Ignitability
non-flammable
0 0 20
Sample ID: 20011551-001ADUP SampType: DUP TestCode: Ignitabllity_S Units: mtnlsec Prep Date: RunNo: 108839
Client ID: BatchQC Batch ID: R10BB39 TeslNo: SW1030 Analysis Date: 2012020 SegNo: 2601838
Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual
Ignitabiftty non-flammable 0 0 20
Sample ID: 20011552.001ADUP SampType: DUP TestCode: Ignllability_S Units: mmisec Prep Date: RunNo: 100839
Client ID: BatchQC Hatch ID: R108839 TeslNo: SW11030 Analysis Date: 21312020 SegNo: 2601840
Analyte Result PQL SPK value SPK Ref Val %REC LowLimil HighLimit RPD Ref Val %RPD RPDLimit Qua)
Ignitability non-flammable 0 0 20
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantilatim range
H
Holding times for preparation or anal)
7 Analytedetectedbelow quantilationlimits
M Manual Integration used to determine arm response
MC
ValueisbelnwMinimumCumpound Revision VI
ND Not Detected
P Second column co�rmation exceeds
PL
Pcrmit Limit
R RPD outside accepted recovery limits
RL Reporting Detection Limit
S
Spike Recovery outside accepted reco
Page 21 of 33

F.r+r'franmeula!Tec'laral10 i St.
33f 0 Win St.
QC SUMMARY REPORT
MSUMMITS1111111fil
ENVtIt0NMENTAL TECHNbWGIFS, INC Ce3'alragu Falls, Ohio 44223
AnnlyNcal Laborawrles lEL. (330) 2SM211 FAX' (330) 253-448Y
lyebsite: Irftu'/irvnryv setfek--tour
WOO: 20011553
12-Feb20
Client:
Project:
$ynagro
Graham WTP -REVISED
BatchID: R108839
Sample ID: 20011553-OOIADUP SampType: DUP
Client ID: Graham WTP Balch ID: R108839
TestCode: Ignitability_S Units: mmisec
TeslNo: SW1030
Prep Dale:
Analysis Dale: 21312020
RunNo. 108839
SegNo: 2601842
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
lgnitability,
non-flammable
0
0 20
Sample ID: 20011412-001ADUP SampType: OUP
Client 10: BatchQC Batch ID: R108839
TestCode: Ignitability_S Units: mmisec
TestNo: SW1030
Prep Date:
Analysis Date: 2I312020
RunNo; 108839
SegNo: 2601644
Analyte
Result
PQL SPKvaEue SPKRefVal
%REC LowLimit HighLimit RPDRefVal
%RPD RPDLimit Quai
lgnitability
non flammable
0
0 20
Sample ID: 20011412-001ATRIP SampType: DUP
Client ID: BatcllQG Batch ID: R10BS39
TesiCode: Ignitabllity_S Units: mmisec
TestNo: SW1030
Prep Dale:
Analysis Dale: 21312020
RunNo: 108839
SegNo: 2601845
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
lgnitability
non flammable
0
0 20
Sample ID: 20011412-002ADUP SampType: DUP
Client ID: BalchQC Balch ID: R108839
TestCodo: Ignitability_S Units: mmisec
TestNo: SW1030
Prep Date:
Analysis Dale: 2/312020
RunNo: 108839
SegNo; 2601847
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
lgnitability
R450
0.4100
9.30 20
Qualifiers: B Analyte detected in the associated Method Blank
1 Analyte detected below quamilation limits
ND Not Detected
R RP➢ outside accepted recovery limits
E Value above quantitatim range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 22 of 33
H Holding limes for preparation or anal)
HIC Value isbelmvMinimum Campouad Revision VI
PL Permit Limit
S Spike Recovery outside accepted reco

FL�ASUMM1�
smmrf,r:,r.iro,lr„e,,,�l;eeb,�rogfe5.r+,�.
33101{7irSr.
QC SUMMARY REPORT
TJEMVIIt0Nh1ENTALTECIINOL0GIES,MC
CrgxrhogaFalls, Ohio 44223
WO#: 20011553
finofyllcal Laboramrlos T'8L: (330)
253-8211 FAX, [phone]
12-Feb-20
{f ebrife: rrf ://�saewselfek.cam
Client:
Synagro
BBtchID: It108839
Project:
Graham WIT -REVISED
Sample ID: 20017412-902ABUP SampType: DUP
TestCode: ignitabilfhr— S Units: mmisec
Prep Date:
Run No: 108839
Client ID:
BatcltiQC Balch ID: Ri08839
TestNO: SW1030
Analysis Date:
260184
21312020 SegNo: 601847
Rosull
PQL SPK value SPK Ref Val %REC
LowLimil HighLimit RPD Ref Val %RPD RPDLlmlt Qual
Analyle
Sample iD: 20011412-002ATftIP SampTyp e DUP
TestGade: Ignitability_5 Units: mmfsec
Prep Date:
Runl4a: 108039
Client ID:
BatchQC Batch ID: R108839
TeslNo: SW1030
Analysis Date:
21312020 SegNo: 2601848
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPU Ref Val %RPD RPDLimit Oval
Analyte
0.4100 4.76 20
ignifabildy
0.430
TestGade: ]gnitability_5 Units: mmisec
Prep Date:
RunNo: 108839
Sample ID: 20011412-003ADUP SampType: DUP
Client 1D;
BatehQC Batch ID: R108939
TeslNo: SW1030
Analysis Date:
2012020 SegNo: 2601860
Result
PQL SPK value SPK Ref Val %REC
LowUnvt HigWmit
RPD Ref Val %RPD RPDLimit Oval
Analyle
0 0 20
Ignilabiltty
non-flammable
Sample ID: 20011412-004ADUP SampType: DUP
TestCode: lgnitabill ty— S Units: mmisec
Prep Date:
RuntJo: 108839
Client ID:
BatchQC Batch ID: R108839
TeslNo: SW1030
Analysis Date:
21312020 SegNo: 2601852
Result
PDL SPK value SPK Ref Val %REC
Lowl-imit HighLimit
RPD Ref Val %RPD RPDLimit Qual
Analyte
0 0 20
Ignitabifity
non-flammable
H Holding times For preparation or anal)
Qualifiers:
B Analyte detected in IUe associated Method Blank & Value above quan[itatian range
MC Value is below Minimum Compound
3 Analyte detected below quantitation limits
M Manual Integration used to determine
area response
Revision vi
ND Not Detected
P Second column confirmation exceeds
PL Pennit Limit
S Spike Recovery outside accepted reca
R IiPD outside accepted recovery limits
RL Reporting Detection Limit
P :3
Page 23 of 33

S„nrtnf! Litrerauuenmr'I'ncbtrnlagles,
UMM1�
In,
3310II'mSt.
QC SUMMARY REPORT
C,rynlmgaFalls,Ohin-1J223
Woo: 20011553
UJ€NYkitONtdEtiTALTECHHgIOGIFS.INC
Artnly!lcal Lab0f0f0rles TEL, (330)
253-8211 FAX., (330) 253-44,39
12-Feb-20
1Vebsfle: !t!i ::/Avrvr,
Client:
Synagro
13atchID: R108839
Project:
Graham WTI' -REVISED
Sample ID: 20011412-DOSADUP SampType: DUP
TeslCodw Ignitabiltty_S Units: mmisec
Prep Dale: RunNo: 108839
Client ID:
BaIchQC Balch 1D: R108839
TestNo: SW1030
Analysis Date: 21312020 SegNo: 2601854
Result
PQL SPK value SPK RefVal
%RFC Lowurnit Highl-imit RPD RefVal °%RPD RPDLimit Qual
Analyte
0 0 20
Ignitability
non-flammable
Qualifiers: B Analyte detected in the associated Method Blank
1 Analyte detected below quamitaiion limits
ND Not Detected
R RPD outside accepted recovery limits
E Value above quantitalion range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 24 of 33
H Holding times for preparation or anal}
MC Value is below Mininmm Compound RevisionvI
PL Permit Limit
S Spike Recovery outside acccpled reco

'
,Srrnnrri! Lnireupuerdol 7irhnologtes, Inc.
331O {Yin St.
QC SUMMARY REPORT
TECHNOLOGIES, INC
Creyahogu a1Js. Ohi,)44223
wok; 20011553
LLJENvinouLAENTAL
Analytleal Leboratcrles
TEL: [phone] FAX.- [phone]
12-Feb 20
Website: hit
Client:
Synagro
Ba#chID: 12108855
Project:
Graham WTP -REVISED
Sample ID: CHECK 7 Sampfype: LCS TestCode: pH_S(8045D) Units: [e-mail] Prep Date: RunNo: 108855
Client 11Y LCSS Ratch ID: R108855 Tes1No: SW8045D Ana$ysis Date: 20312020 SegNo- 2602205
Analyle Result PQL SPK value SPK Ref Val °.6REC LowLimii HighLlmit RPD Ref Val % RPD RPDLimit Qual
PH 7.0 7.0 0 100 90 110
Qualifiers: B Analyle detected in the associated Method Blank
1 Analyte detected below quantitation limits
ND Not Detected
R RFD outside accepted recovery limits
E Value above quantitalion range
M Manual Integration used to detemune area response
P Second column confinnation exceeds
RI. Reporting Detection Limit
Page 25 of 33
If Holding limes for preparation or anal)
MC Value isbelmvMinimumCompound Revision Vl
PL Pemtil Limit
S Spike Recovery outside accepted reco

summilF:mlrur,rrren,nl7eehrwTogles,lx.
QC SUMMARY REPORT
MMOrA
SUMMIT
33I0 fYirm Sr.
Caynlrog,l Fe1Lr, Ohio 44223
WDii: 20011553
Annlytfcal i9boralorlss
7T-,L: [phone] FAX.- [phone]
12-Feb-20
fYebsite: bi1r:/ r nr.sellek.-ru
Client:
Synagro
BatchlD: 11108855
Project:
Graham WTP -REVISED
Sample ID: 1-CS-111108855 SampType: LC5 TestCade: pH_Oil[9045D Units: s,u.@20.6C Prep Date:
RunNo: 108655
Client lg: LCSW Batch ID: R108855 Tes1No: SW9045D Analysis Date: 21312020 SagNo: 2601986
Analyte Result PQL SPK value SPK Ref Val °AREC Lowl-imit High Limit RPD Ref Val %RPD RPDLimit Qual
pH 7.0 7.0 0 100 90 110
Sample ID: 20020071.001ADUP
SampType: DUP
TestCode; pH_Oil(9045D Units: 5.u,@20.1C Prep Date:
RurtNm 108855
Client ID: DatchQC
Balch ID: R10B856
TestNo: SW9046D Analysis Date: 213f2020
SegNo: 2601952
Result
PDL SPK value SPK Ref Val %REC Lowt-imil Highl-imil RPD Ref Val
°ARPD RPDLimit Qual
Analyte
6,9
0 0 R8
0.6 10
pH
Qualifiers: H Analytedetected inthe associated Method 131ank
1 Analyle detected below quanlitation limits
ND Not Detected
R RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 26 of 33
H Holding limes for preparation or anal)
MC Value is belmy Minimum Compound Revisi0n Vl
PL Permit Limit
S Spike Recovery outside accepted reco

VMM'Er QC SUMMARY REPORT
ffq 3310 Win St.
UJENvinONMENTAL TECHNOLOGIES, INC Czj)rrb(?gaFalls, Ohio 44223 WO#: 20011553
Analydral Laboraterlos T1i1.: [phone] FAX: [phone]-Feh-20
Mebsile, LUX,'
Client: Synagro
BatchiD: R108855
Project: Graham WTP -REVISED
Sample ID: CHECK 7 SampType: LCS TestCode: pH_NPW[450 Units: s.u.@20.4C Prep Gale:
RunNo: 108855
Client ID: LCSW Batch ID: R108855 TeslNo: SW9045D Analysis Date: 2/312020 SegNo: 2602212
Analyte Result PQL SPK vatue SPK Ref Val %REC LowLimit High Limit RPD Ref Val %RPD RPDLimit Qual
pH 7.0 7.0 0 104 96.6 101.4
Qualifiers: B knalyte detected in the associated Method Blank
3 Analyle detected below quanlitalionlimits
ND Not Detected
R RPP outside accepted recovery limits
E Value above quantilation range
M Manual lnlegration used to determine area response
P Second column confirmation exceeds
RL Reporting Deteclinnlimit
Page 27 of 33
H Holding times for preparation or anal)
MC Value is below Minimum Compound Revisionvl
PL Permit Limit
S Spike Recovery outside accepted reco

Surrrn,ir
L}rrirmrnrerNal Technologies, hrc
QC SUMMARY REPORT
SUMIR111
33100nSr.
TECHHOLQW£9, IRC
Croulroga Falls, Ohio 44223
woo: 20011553
UJENvinONMENTAL
Analyilcal Laboraiorfes TLL: [phone] FAX., [phone]
12-Teb ZO
IVehsrrr: berm:/hrnreseifek.cnrrr
Client:
Synagro
Batchrm R109221
Project:
Graham WTP -REVISED
Sam T e: MBLK
Sample lD: MB-R109221 P yP
TestCode: Cyanide,Rea Units: mg1Kg
Prep Date: RunNo: 109221
Client ID:
PBS Hatch ID: R109221
TestNo: SW9014
Analysis Date: 21612020 SegNo: 2620714
Result
PQL SPK value SPK Ref Val
-/.REC LowLimik HighLimit RPD Ref Val °ARPD RPDLimit Qua)
Analyte
Cyanide, Reactive N❑
10.7
Sample ID: LCS-R109221 SampType: LCS
Client 1D: LCSS Batch ID: R109221
Analyte Result
Cyanide, Reactive ND
Sample ID' RLC-RIO9221 SampType: RLC
Client 113: BatchQC Batch 1D: R109221
Analyte Result
Cyanide, Reactive ND
Sample iD: 20011287-008AMS SampType: MS
Ciisnt 1D: BatohQC Batch ID: R109221
Analyte Result
Cyanide, Reactive ND
TestCoda: Cyanide,Rea Units: m911K9
TestNo: SW9014
PQL SPK value SPK Ref Val
12.5 10.00 0
TestCode: Cyanlde,Rea Units: mg1Kg
TestNo: SW9014
PQL SPK value SPK Ref Val
12A 0.5000 0
Testoode: Cyanide,Rea Units: mg1Kg
TestNo: SW9014
PQL SPK value SPK Ref Val
12.1 10.00 0
Qualifiers: B Analyle detected in the associated Method Blank
1 Analyte detected below quantitation limits
ND Not Detected
R RPD outside accepted recovery limits
Prep Date:
Analysis Date: 216/2020
%REC Lowurnit HighLimit RPD Ref Val
96.9 85 110
Prep Dale:
Analysis Date: 2/612020
%REC Lowun it HighLimit RPD Ref Val
125 50 150
Prep Dale:
Analysis Dale: 2J612020
%REC Lowl.imit HighLimit RPD Ref Val
95.3 81.6 122
E Value above quentitation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
RL Reporting DetectionLlmit
Page 28 of 33
RunNo: 100221
SegNo: 2620715
%RPD RPDLimit Qual
RuoNo: 109221
SegNo: 2620717
%RPD RPDLimit Qua1
RunNo: 109221
SeglVo: 2620724
%RPD RPDLimit Qual
H Holding timcs for preparation Or anal}
MC Vahue is below Minimum Compound ReVlSlon V i
PL Permit Limit
S Spike Recovery outside accepted reco

srrr>a>„r E+mo-o+++++eerinl Tech++nloWInc. QC SUMMARY REPORT
r
a .,, 3310 Win
in Si.
4'r�
ENYIAPNtdENTAL'M"NPLOGIn'lNC ('+gnl+ogrr Falls, Ohio 47223 WOH' 200t 1553
Artafyticaf Laboraforfrrs T@'L: [phone] FA.r• (330) 253- 489 12-Feb-20
Wehsirc: h( oie seyek.enm
Ctient: Synagro
BatchID: Rt09221
Project: Graham W'rp-REVISED
Sample ID: 20011287-OORAMS SampType: MS
Client lD: BatahQC Batch ID: R109221
Analyte
Result
TestCode: Cyanlde,Rea Units: mgfKg Prep Date: RunNo: 109221
TeslNm SW9014 Analysis Date: 21612020 SegNo: 2620724
PQL SPK value SPK Ref Val %RFC LowLimil High Limit RPD Ref Val %RPD RPDLimit Qual
Sample ID, 20011287-008AMSD
SampTypa: MSD
TestCode: Cyanlde,Rea Units: mg1Kg
Prep Date:
Runrto: 109221
Client ID: BatchQC
Batch ID: R109221
TestNo: SW9014
Analysis Date: 2/612020
SegNo: 2620726
Result
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qua$
Analyle
Cyanide, Reactive
ND
12.1 10.00 0
96.2 81.6 127 0
0 5
Qualifiers: B Analyte detected in the associated Method Blank
7 Analyte detected below quaMitation limits
ND Not Detected
K RPD outside accepted recovery limits
E Value above quantitation range
M Manual Integration used to determine area response
P Second column confirmation exceeds
ILL Reparting Detection Limit
Page 29 of 33
11 Holding limes for preparation or analy
MC Value is below Minimum Compmmd Revision vI
PL Permit Limit
S Spike Recovery outside accepted reca

smmi.if,1 ViW.„....n] I,"/ or�xies. r„�. QC SUMMARY REPORT
s u mm' 3310 Win Sr-
ENVIaOMAENTAL TECHNOLOGIES, INC L'tgnhogaFo11s. Ohio 44223 W09: 20011553
Arralyflcaf Labataforlas TEL: [phone]•:4X.' [phone]
iPehxire: hrrr�:/iiruuser7ekcanr 12-Feb-24
Client: Synagro
Praject: Graham WTP -REVISED BatehlD: R109223
Sample ID: 20011287.008AMS SampType: MS TestCode: 8ulfide,React Units: mg/Kg Prep Date: RunNo. 109223
Client ID: BatchQC Batch ID: R109223 TestNo: SWS034 Analysis Date: 211612020 SegNo: 2620766
Analyte Result PQL SPK value SPK Ref Val %RFC Lowl-imit HighUmit RPD Ref Val %RPD RPDLimit Qua]
Sulfide, Reactive 4580 25.0. 4800 0 95.4 80 120 H
Sample ID: 20011287-OOBAMSD
SampType: MSD
TestCode: Sulfide,React Units: mgfKg
Prep Dale:
RunNo: 109223
Client ID: BatrhQC
Batch ID: R109223
TestNo: SW9034
Analysis Date: 211612020
SegW., 2620767
Analyte
Result
PDL SPK value SPK Ref Val
%REC LowrUmit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive
4540
25.0 4800 0
94.6 80 120 4580
U877 30 H
Qualffiers: B Analyte detected in tha associated Methnd Blank
7 Analyte detected below quantitalion limits
ND Not Deteoted
R RPD outside accepted recovery limits
E Value above goantitation range
M Manual Integration used to detennine area response
P Second column confirmation exceeds
RL Reporting Detection Limit
Page 30 of 33
H Holding times for preparation or anal}
MC Value is below Minimum Compound
RCVISIOR VI
PI, PermitLimit
S Spike Recovery outside accepted reco

MMOU smm
u ill
55immlllhviro,met+lal7Gchuofagies,Inc. 33I0 fVin S(. QC SUMMARY REPORT
ENVIRONMENTAL TECHNOLOGIES, IN(- Cr)nhogn Fall.; Ohio 44223
iVOi{: 20011553
Analyf[cal Caborafortas TEL: [phone] FAX. [phone]
1Vehsite: hOU:/.iv�ws•selfek.co+x I2-Feh-20
Client: Synagro
Project: Graham WTP-REVISED Batchll): R109223
Sample ID' MB-R109223
SampType: MBLK
TestCcdo: 5ulfide,React Units: mg1L
Prep Dale:
RunNo: 109223
Client ID: PBW
Batch ID: R109223
TestNo: SW9034
Analysis Dale: 2116/2020
SegNo: 2620768
Analyte
Result
PQL SPK value SPK Ref Val
%REC LowLimil HighLimit RPD Ref Val
%RPD RPDLimft Qual
Sulfide, Reactive ND 25,0
Sample ID: LCS-R109223
SampType: LCS
TestCode: Sulfide,React Units: mglL
Prep Date:
RunNo: 109223
Client ID: LCSW
Batch ID: R109223
TestNo' SW9034
Analysis Dale: 2/1612020
SegNo: 2620769
Analyte
Result
PQL SPK value SPK Ref Val
°! REC LowLlmit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive 4560 25.0 4800 0 95.0 85 115
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitntion range H Holding times for preparation or ana13
] Analyte detected below quantitation limits M Manual integration used to delermine area response MC Value is below Minimum Compound
ND Not Detected P Second column confirmation exceeds PL Permit Limit Revision v1
R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco
Page 31 of 33

m
w
0
41
w
w
DBPix Evaluation
Summit Environmental Technologies, lnc.
33t0 Win Street
Cuyahoga Falls, Ohio 44223
PDF created with pdfFactory Pro trial version www.pdffactory.com
Analysis RequesllChaw of Custody
Far Summit Environmental Technologies' I. use on1
Page -Of.
�taiu of Sample Pckric,� NO
L.nF:t-ls;•ipUnNCe Yf-5
G�;! nFIC.19'LC;.1 RL•0U1r -,D Y[.S "o
RL!'oR'i'rOST:tl'L(DWONLY, Y1,S NU
S7'[ I, :i toll
',r •:. o ni'M L'w. S0'I; 1sa. acwss-x =1�": i• niagpli: ull� auJ
www.ammara.com

MIT T Sunrmi! Ertrivarrrnenla! Technologies, Inc.
SUM3310 TVirr St.
f ENUNt4NMr:N'rALTEGHN0t.0C3l 5,iNC, Cuyahoga Falls, Ohio44223 Sample Log -In Check List
Lij1 AnafyUcal caboraforres TEL: [phone] fAX.� (330) 253-44,59
TT'ebsite: h8 .11inviv.settek.corn
Client Name: SYN-NC-27020 Work Order Number: 20011553 RcptNlo: 1
Logged by: John A.Semenik
Completed By: John A.Semenik
Reviewed By: Jennifer Woolf
1124/2020 10:20:00 AM
1/2412020 3:24:36 PM
1/31/2020 3.41:52 PM
Chain of Custod
1.
Is Chain of Custody complete? Yes❑ No ❑ Not Present El
2. How was the sample delivered? UPS
Low In
Yes❑
No ❑
NA ❑
3.
Coolers are present?
4.
Shipping container/cooler in good condition?
Yes
0
❑
No ❑
No ❑
Not Present
Custody seals intact on shipping containerlcooler?
Yes
No. Seal Date:
Signed By:
❑
No ❑
NA ❑
5.
Was an attempt made to cool the samples?
Yes
6.
Were all samples received at a temperature of >0' C to 6.0°C
Yes
No ❑
NA ❑
7.
Sample(s) in proper container(s)?
Yes
No ❑
g,
Sufficient sample volume for indicated test(s)?
Yes
©
No ❑
g.
Are samples (except VOA and ONG) properly preserved?
Yes
No ❑
10.
Was preservative added to bottles?
Yes
❑
No
NA ❑
1 J Is the headspace in the VOA vials less than 114 inch or 6 mm?
Yes ❑
No ❑ No VOA Vials V
.
12. Were any sample containers received broken?
Yes ❑
V❑
No
No ❑
13. Does paperwork match bottle labels?
Yes
(Note discrepancies on chain of custody)
Yes 0
No ❑
14. Are matrices correctly identified on Chain of Custody?
❑//
No ❑
15. Is it clear what analyses were requested?
Yes
16. Were all holding limes able to be met?
Yes
No ❑
(If no, notify customer for authorization.)
Special Handling if applicable)
El
No ❑ NA 0
17. Was client notified of all discrepancies with this order?
Yes
Date:
Person Notified:
By Whom: Via:
❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
Cooler information _
Cooler No iem °C Condition Seal Intact Seal No Seal Date Signed B
d Not Present
Page 33 of 33

0
Waypoint�
ANALYTICAL
1/27/2020
Synagro Central LLC! Graham
Mary Brewer #R51-0025
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 20-017-0003
Project Description: Graham WTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanaiytical.com
Dear Mary Brewer #51-0025:
Waypoint Analytical Virginia, Inc. received sample(s) on 1/17/2020 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
P,w:. a' 6&7-'
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 6

waypoint-(2)
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www,waypointanalyUcal.com
Sample Summary Table
Report Number:
20-01.7-0003
Client Project Description:
Graham WTP
Lab No Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
SM-4500-NH3C
WP MTN
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
9045D
WP MTN
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
4500NO3F-2011
WP MTN
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
6010D
WP MTN
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
SW-7471B
WP MTN
70198 Graham WTP
Solids
01/16/2020 13:25
01/17/2020
SM-4500-NH3C TKN
WP MTN
70198 Graham WTP
solids
01/16/2020 13:25
01/17/2020
SM-254OG
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 6

0
Waypoint 762i Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
ANALYTICAL www.waypointanalVHcal.com
46457
Synagro Central LLC/ Graham Ryan
Mary Brewer #51-0025 Project Graham WReceived TP Report Date : 01/
284 Boger Road Information : : 01/17/2020
7/2020
Mocksville , NC 27028
Pam«
Submitted By : Ryan Pauric McGroary
Report Number : 20-017-0003 REPORT OEANALYSIS Agronomist
Lab No: 70198 Matrix: Solids
Sample ID : Graham WTP Sampled: 1/16/2020 13:25
Test Results Units MQL DF Date ITime By Analytical
Analyzed Method
Moisture 96.7 % 0.010 1 01/22/2016:23 ADM SM-2540G
Test Results Units MQL DF Date 1 Time By Analytical
Analyzed Method
Ammonia Nitrogen
3880
mg/Kg - dry
3030
1
01/24/20 13:30
JPJ
SM-4500-NH3C
Nitrate+ N itrite-N
171
mg/Kg - dry
143
1
01/24/20 13:35
ZBD
4500NO3F-2011
Organic N
14900
mg/Kg - dry
7580
1
01/24/20 10:00
CALCULATION
pH
7.6
S.U.
1
01/23/20 05:46
JSL
9045D
Total Solids
3.29
%
0.010
1
01/22/20 16:23
ADM
SM-2540G
Total Kjeldahl Nitrogen
18800
mg/Kg - dry
7580
1
01/24/20 10:00
JPJ ;M-4500-NH3C-TKP
Phosphorus
321
mg/Kg - dry
152
1
01/22/20 23:42
JTR
6010D
Aluminum
1460
mg/Kg - dry
152
1
01/22/20 23:42
JTR
6010D
Arsenic
<15.2
mg/Kg - dry
15.2
1
01/22/20 23:42
JTR
6010D
Calcium
776
mg/Kg - dry
758
1
01/22/20 23:42
JTR
6010D
Cadmium
<3.03
mg/Kg - dry
3.03
1
01/22/20 23:42
JTR
6010D
Chromium
<7.58
mg/Kg - dry
7.58
1
01/22/20 23:42
JTR
6010D
Copper
17.1
mg/Kg - dry
7.58
1
01/22/20 23:42
JTR
6010D
Iron
53300
mg/Kg - dry
152
1
01/22/20 23:42
KKM
6010D
Lead
<9.09
mg/Kg - dry
9.09
1
01/22/20 23:42
JTR
6010D
Magnesium
243
mg/Kg - dry
152
1
01/22/20 23:42
JTR
6010D
Manganese
2970
mg/Kg - dry
15.2
1
01/22/20 23:42
JTR
6010D
Qualifiers/ DF
Dilution Factor
L
Limit Exceeded
Definitions MQL
Method Quantitation Limit
Page 3 of 6

•
•
Waypoint
7621 Whitepine
Road, Richmond, VA 23237
Main 804-743-94011 Fax [phone]
ANALYTICAL
www.waypointanalytical.com
46457
Synagro Central LLC/ Graham
Ryan
Mary Brewer #51-0025
Project
Graham
WTP
Report Date : 01/27/2020
284 Boger Road
information :
Received : 01/17/2020
Macksville , NC 27028
Pam« m= 64wr
Submitted By : Ryan
Pauric McGry
Report Number : 20-017-0003
REPORT OFANAL YSTS
Agronomist
Lab No : 70198
Matrix: Solids
Sample ID : Graham WTP
Sampled: 1/16/2020 13:25
Test
Results
Units
MQL
DF Date! Time By Analytical
Analyzed Method
Mercury
<0,464
mg/Kg - dry
0.464
1 01/22/20 14:08 TJS SW-7471B
Molybdenum
<7.58
mg/Kg - dry
7.58
1 01/22/20 23:42 JTR 6010D
Nickel
14.3
mg/Kg - dry
7.58
1 01/22/20 23:42 JTR 6010D
Potassium
182
mg/Kg - dry
152
1 01/22/20 23:42 JTR 6010D
Selenium
<15.2
mg/Kg - dry
15.2
1 01/22/20 23:42 JTR 6010D
Sodium
<758
mg/Kg - dry
758
1 01/22/20 23:42 JTR 6010D
Zinc
<37.9
mg/Kg - dry
37.9
1 01/22/20 23:42 JTR 6010D
Sulfur
1120
mg/Kg - dry
152
1 01/22/20 23:42 JTR 6010D
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
L Limit Exceeded
Page 4 of 6

0
Waypoint
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanaiyticaI.com
Shipment Receipt Form
Customer Number: 46457
Customer Name: Synagro Central LLC/ Graham
Report Number: 20-017-0003
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
�—
Shipping container/cooler uncompromised?
0 Yes
0 No
Number of coolers/boxes received
1
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
0 Yes
0 No
COC agrees with sample label(s)?
0 Yes
0 No
COC properly completed
0 Yes
0 No
Samples in proper containers?
0 Yes
0 No
Sample containers intact?
0 Yes
0 No
Sufficient sample volume for indicated test(s)?
0 Yes
0 No
All samples received within holding time?
0 Yes
0 No
Cooler temperature in compliance?
0 Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
0 Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
NIA
Water - VOA vials free of headspace
0 Yes
0 No
NIA
Trip Blanks received with VOAs
0 Yes
0 No
NIA
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
NIA
High concentration container (48 hr) F_ Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes 49 No
Comments:
Signature: Brandi Watson --------- ] Date & Time: 01/17/2020 10:56:
Page 5 of 6

SAMPLING LOG # AI
�s
s Rli
PROJECT MANAGER:
Phone: ( 33b ) W7
A & L CUSTOMER SAMPLING
LAB # SAMPLE I.U. LOCATION
Rellnqulshed by Sampler. NrQ C-W
Rellnqulshed by:
Ill111111111mill lllllll III IlllIN11lllNIIIIIIII1©�;��3 41N OF CUSTODY
$vnaa,aCenlral LLCf Graham 105027 ;ORD 8e ANALYSIS
Graham WTP
SAMPLE
# OF
TYPE
CONTAWEERS
SL'IIC.am?
I
Date Time
Recleved by:
Date Time
Reolevo by:
RECORD
t attest that the proper f id sampling procedures
were used during the collection of these samples.
SAMPLER
SAMPLINGS METHOD METHOD
DATE TIME PRESERVED SHIPPED
13: z� LV Its l�l
REMARKS:
Rellnqulshed by: bate I Time Reoleved by:
SPECIAL INSTRUCTIONS: TOE r
-JD q- For ' " monitoring purpasaa. J`" , r PON,.
ANALYSIS REQUEST
SAMPLEU nn1:i�
CaCOs Vofstlle
I U SLi SLR NHq M N0,14 NIPb As HE; 5e PH ulv, Sodlde Mo CI NOp N
SLi: Total Sollda (Moisture), Toted Kfeldahl Nitrogen, Phosphorue, and Potasslum
SLa: Baslo Test SLI plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zino
Page 6 of 6

DWR
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
Division of Water Resources INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and
supportine documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC I I-15) form. Please do not
make any unauthorized content changes to this form. if necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
® For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
® Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land A lication Permits".
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item 1. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: SYnaVO Central LLC
Maximum Dry Tons Per Year
Facility Permit Holder
Facility Name
County Permit Number
Current b
Proposed
KStatus
e"
City of Graham
Graham Mebane WTP
Alamance NC0045292
0
275
Startex Jackson Wellford
N Duncan Water District
SJWDIDuncan WTP
Spartanburg SC ND0085499
Q
700
Water Treatment Plant
D
125
N Town of Siler City
Siler City WTP
Chatham 03-09-010
N City of Portsmouth
Lake Kilb WTP
�'
Suffolk VA0006301
0
3200
a Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted)
land or disposal (Le, not applicable to new facility).
b The amount of residuals currently permitted for
distribution, application,
Page 1
SUMMARY FOR FORM: RSC 06-16

State of North Carolina
Department of Environmental Quality
DWR Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
Division of Water Resources
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Startex JacEcson Wellford Duncan Water District Water Treatment Plant
2. Facility permit holder is: ❑ Federal, ❑ State, 2 Local Government, or ❑ Private.
Facility permit issued by: ® Div. of Water Resources, ❑ Div. of Environmental Health,
or ❑ Other (explain:).
3. Facility contact person and title: Tommy Staton. Director of Water Resources and Treatment
Complete mailing address: 330 Wamsutta Dr.
City: Lyman State: SC Zip: 29365-
Telephone number: (864) 553-16l l E-mail address: [e-mail]
4. Facility physical address: 330 Wamsutta Dr.
City: Lyman State: SC Zip: 29365-
Coordinates: Latitude: 34°56' 06" Longitude: 82' 07' 04"
Datum: NAD83. Level of accuracy: Seconds
Method of measurement: MAP
5. Purpose of the facility:
❑ treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
treatment of potable water, ❑ treatment of 100% industrial wastewater,
❑ treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: °fin mausurai ana ro uo,ueNL1U)
❑ other (explain: ).
6. Does the facility have an approved pretreatment program: ® Yes ❑ No
7. Facility permitted/design flow: 20.0 MGD and facility average daily flow: 7_7MGD
8. Average amount of residuals being generated at this facility restj00 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water Treatment Process
Type and volume of residuals storage (i.e., outside of residuals treatment units): 1 la o in estimated 2 million gallons ca .
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
[l 40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102 6 as:
0 Biological 0 Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page i of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: [A yes no.
1f yes, list the number(s):
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: ❑ yes IR no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability., and reactivity:
Laboratory: Pace Analytical and Date of analysis: 6/18/2020
Passed corrosivity test: R yes ❑ no. pH: s.u. (2 < pH < 12.5)
Passed ignitability test: 0 yes ❑ no. Flashpoint >140 OF (> t40'F)
Passed reactivity test: M yes Ejno. HCN: NO mg/kg (<250) & HzS: ND mg/kg (<500)
TCLP Parameter
Limit
Result
TCLP Parameter
Limit
Result
(mg/l)
(rng/l)
(mg/l)
(rrrg/l)
Arsenic
5.0
ND
Hexachlorobenzene
0.13
ND
Barium
100.0
ND
Hexachloro-1,3-Butadiene
0.5
ND
Benzene
0.5
ND
Hexachloroethane
3.0
ND
Cadmium
1.0
ND
Lead
5.0
ND
Carbon Tetrachloride
0.5
ND
Lindane
0.4
ND
Chlordane
0.03
ND
Mercury
0.2
ND
Chlorobenzene
100.0
ND
Methoxychlor
10.0
ND
Chloroform
6.0
ND
Methyl Ethyl Ketone
200.0
ND
Chromium
5.0
ND
Nitrobenzene
2.0
ND
m-Cresol
200.0
ND
Pentachlorophenol
100.0
ND
o-Cresol
200.0
ND
Pyridine
5.0
ND
p-Cresol
200.0
ND
Selenium
1.0
ND
Cresol
200.0
ND
Silver
5.0
ND
2,4-D
10.0
ND
Tetrachloroethylene
0.7
ND
1,4-Dichlorobenzene
7.5
ND
Toxaphene
0.5
ND
l,2-Dichloroethane
0.5
ND
Trichloroethylene
0.5
ND
1,1-Dichloroethylene
0.7
ND
2,4,5-Trichlorophenol
400.0
ND
2,4-Dinitrotoluene
0.13
ND
2,4,6-Trichlorophenol
2.0
ND
Endrin
0.02
ND
2,4,5-TP (Silvex)
1.0
ND
Heptachlor and its Hydroxide
0.008
ND
Vinyl Chloride
0.2
ND
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For DlstributlonlLand Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Pace Analytical and Date of analysis: 4/22/2020
Parameter
Ceiling
Monthly Average
Result
Concentration Limits
Concentration Limits
(C1assA & ClassB)
(Class A Only)
(mglkg)
(mglkg)
(rnglk)
Arsenic
75
41
13
Cadmium
85
39
ND
Copper
4,300
1,500
430
Lead
840
300
43
Mercury
57
17
ND
Molybdenum
75
n/a
ND
Nickel
420
420
29
Selenium
100
100
ND
Zinc
7,500
2,800
170
b. For Sur ace Dis osal Unit land rll : Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: i` . and Date of analysis:
L
Distance from Disposal
Arsenic
Chromium
Nickel
Unit to Boundary to
Closest Property Line
(meters, check one)
(mg/kg)
(rnglkg)
(mglkg)
> 0 but < 25
30
200
210
> 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (mglkg)
FORM: RSC 06-16 Page 3 of 5

5. NutrientlMicronutrient Determination: Complete the following:
a. Total solids: 2.13 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Pace Analytical and Date of analysis: 4/22/2020
Using the results listed in Item 1I. 5b. above, calculate the sodium adsorption ration (SAR): 1.07
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 20 %, This
rate is a (check one): R default value, or ❑ actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method First (11) Year PAN Five -Year
Maximum Adjusted PAN
(ing/kg) (mg/kg)
Surface 1,110 1,733
Injectionllncorporation 1 1,385 2,008
Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses: None
FORM: RSC 06-16 Page 4 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For DistributfonlLand Application of Class A or Eattivalen
A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
❑ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
❑ Alternative 1 [15A NCAC. 02T. I 106(b)(3)(A)] - Time/Temperature Compliance.
❑ Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
Alternative 3 [15A NCAC 02T. 1106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
El Alternative 4 [15A NCAC 02T.1106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 5 [15A NCAC 02T. I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: ❑ composting, ❑ heat drying, ❑ heat treatment,
EJ thennophilic aerobic digestion, ❑ beta ray irradiation,
El gamma ray irradiation, or ❑ pasteurization.
b. For LandApplicallon of Class B:
Alternative 1 [15A NCAC 02T. 1 106(c)(1)] - Fecal Colifonn Density Demonstration.
Alternative 2 [15A NCAC 02T. 1106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: [] aerobic digestion, air drying, [] anaerobic digestion,
El composting, or ❑ lime stabilization.
c, For Surface Dis osa
Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item It. 7a. above.
[] Select One of the Class B or Equivalent Pathogen Reduction Alternatives in item II. 7b. above.
Exempt -If Daily Cover Alternative is chosen in Item 11.8, below [15A NCAC 02T. I 106(a)(2)].
Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction AR :Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
p Alternative 1 [15A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
Alternative 2 [15A NCAC 02T. I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
[� Alternative 3 [15A NCAC 02T.1107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
Alternative 4 [15A NCAC 02T. 1107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
0 Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
�] Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization.
[� Alternative 7 [15A NCAC 02T. 1 107(a)(7)] - Drying of Stabilized Residuals.
[] Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals.
Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection.
[] Alternative 10 [I5A NCAC 02T.I107(a)(10)] - Incorporation.
Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T. 1 107(b)(2)].
Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

VICINITY M"
#p
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& m
$
%
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/
SYNAGRO
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41,
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rR I!|a|OnLyman k
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COUNTY: Spartanburg OWNER(S): Startex Jackson Wellford Duncan Wks
District Water Treatment Pat

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INFIRM
C4flFokuEO TO ADOEWIF
RECORD DRAWING

Quantitative Justification for Residuals Production Rate
Startex Jackson Wellford Duncan. Water Distract Water Treatment Plant
Between the years of 2016 and 2019, overall land application of Startex Jackson
Wellford Duncan Water District Water Treatment Plant residuals has fluctuated quite a
bit from year to year due to weather and other unanticipated operational issues. It is
requested that Startex Jackson Wellford Duncan. Water District Water Treatment Plant be
permitted to land apply a maximum of 700 dry tons per year to account for any plant
fluctuations and any backlogged material in storage.
Dry tons land applied between 2016 and 2019.
Year
Dry Tons
2016
623
2017
111
2018
0
2019
41

Residuals Sampling Plan
Synagro Residuals Land Application for WQ0035207
Startex Jackson Wellford Duncan Water District Water Treatment
Plant
Nutrients and Metals Analysis
• Sampling Point: Storage Lagoon
• Sampling Frequency: Quarterly (Dry Ton Dependent)
• Sample Type: Composite
• Lab: Shealy Environmental Labs Inc.
Pathogen Reduction (Not Required)
Vector Attraction Reduction (Not Required)
TCLP
Sampling Point: Storage Lagoon
a Sampling Frequency: Annually
+ Sample Type: Composite
• Lab: Shealy Environmental Labs Inc.

aceAnalytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Erika Lamb
Project Name: SJWD Lyman
Project Number: 52-2182
Lot Number:VF11039
Date Completed:0612212020
Project Manager:Lucas Odom
06/24/2020 10:00 AM
Approved and released by:
Project Manager: Kelly M. Nance
ANSI Nrxon�I,SmeP+hnon ewrd
A CC RED IT E D
B — —
SESTM 1,00RAIMY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29472
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 10

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: VP11039
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance
Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies, Any exceptions to
the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W°
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
PCBs
Sample -001 had one surrogate recovered outside of the acceptance limits. No corrective action was
required as the method only requires one surrogate to recover within limits.
Inorganic Non -Metals
The pH analysis associated with the sample -001 was performed after the method recommended 15
minute holding time.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, WC.)
106 Vantage Point Drive West Columbia, SG 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 10

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Synagro
Lot Number: VF11039
Sample Number Sample ID
001 SJW❑ Lyman
sample)
Matrix Date Sampled Date Received
Solid 06110120201000 06/11/2020
pace Analytical Services, LLC (formerly Shealy Environmental Services, InC.)
106 Vantage point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelibs.com
Page 3 of 10

Client:Synagro
Description: SJWD Lyman
Date Sampled:0611012020 1000
Date Received:06/1112020
Laboratory ID:VF11039.001
Matrix: Solid
% Solids: 3.19 06/11/2020 2315
inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Ignitability) 1010A
1 0611812020 2208 HET
57448
1
(Paint Filter) 9095E
1 06/18/2020 2239 HET
1
(Reactive Cya) 7.3.3
1 06/17/2020 1417 KFE
06111612020 2319
1
(Reactive Sul) 7.3.4
1 06/17/2020 1925 HET
06/16/2020 2319
1
(Soil pH meas) 9045❑
1 06/11/2020 2000 SRB
66701
CAS Analytical
Number Method
Result Q
LOQ
Units
Run
Parameter
Ignitability (Pensky-Martens Closed -Cup)
1010A
>140
140
o F
1
Paint Filter Test
9095E
Fail
pass/fall
1
Reactive Cyanide
7.3.3
NO
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 22.4 ° C
9045D
6.4
su
1
TCLP Volatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 131115030B
8260D
10 06118120201154 TML
57352 06/16120201700
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
NO
0.050
mg1L
1
2-Butanone (MEK)
78-93-3 8260D
NO
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg1L
1
Chloroform
67-66-3 8260D
NO
0.050
mg1L
1
1,2-Dichloroethane
107-06-2 8260D
NO
0.050
mg/L
1
11-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mglL
1
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg1L
Vinyl chloride
75-01-4 8260D
NO
0.010
mg1L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
104 70-130
1,2-Dichloroethane-d4
92 70-130
Toluene-d8
105 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 06/18/2020 1615 SCD
06/16/2020 1713 57156 06/15/2020 2230
CAS Analytical
Parameter
Number Method
Result Q
LOQ Units Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040 mg1L 1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080 mg/L 1
LQQ = Limit of Quantitation a = Detected in the method blank E = Quantilation of compound exceeded the calibration range
ND = Not detected at or above the MQ N = Recovery is out of criteria P = The RPn between two GC columns exceeds 40%
H = out of holding time W = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Fnvironmenfai Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 10

Laboratory ID:VF11039-001
Client:Synagro
Description: SJWD Lyman
Matrix: Solid
Date Sampled: 0611012020 1000
% Solids: 3.19 06/1112020
2315
Date Received:06111/2020
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 06/18/2020 1615 SCD
06/16/2020 1713 57156 06/15/2020 2230
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg1L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mglL
1
Hexachloroethane
67-72-1 8270E
ND
0,040
mg1L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg1L
i
3+4-Methyl phenol
106-44-5 8270E
ND
0.040
mglL
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg1L
1
Pentachiorophenol
87-86-5 8270E
N❑
0.20
mglL
1
Pyridine
110-86-1 8270E
ND
0.040
mglL
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg1L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg1L
1
Runt Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
88 37-129
2-Fluorophenol
60 24-127
Nitrobenzene-d5
75 38-127
Phenol-d5
86 28-128
Terphenyi-d14
97 10-148
2,4,6-Tribromophenol
77 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 131 i18151A
8151A 1 06/19/2020 2352 JJG
06/19/2020 0023 57449 06/15/2020 2230
CAS Analytical
Parameter
Number Method
Result Q
LOQ Units Run
2 4-D
94-75-7 8151A
ND
0.020 mglL 1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0,0050 mg1L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
71 50-112
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prop Date Batch
i 3550C 3660B/3665A 8082A 1 06119/2020 1059 NCM 06/17/2020 2248 57303
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units Run
Aroclor 1016
12674-11-2
8082A
ND
530
uglkg 1
Aroclor 1221
11104-28-2
8082A
ND
530
uglkg 1
Aroclor 1232
11141-16-5
8082A
ND
530
uglkg 1
LOQ = Limit or Quantilation B = Detected in the method blank E = ouantitatlon of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40%
H = Out of holding time W - Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5of10

Client: Synagro
Description: SJWD Lyman
Date Sampled:0611012020 1000
Date Received:0611112020
Laboratory ID:VF11039-001
Matrix: Solid
% Solids: 3A9 06111/2020 2316
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 3660B13665A 8082A 1 06/19/2020 1059 NCM 06117/2020 2248 57303
Parameter
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
Surrogate
Decachlorobiphenyl
Tetrachiam-m-xylene
Run Prep Method
1 131113520C
Parameter
gamma-BHC (Lindane)
Chlordane
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogate
Decachlorobiphenyl
Tetrachloro-m-xylene
Run Prep Method
1 131113010A
1 131117470A
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
CAS Analytical
Number Method
53469-21-9
8082A
12672-29-6
8082A
11097-69-1
8082A
11096-82-5
8082A
Run 1 Acceptance
Q % Recovery Limits
58 41-132
N 34 35-106
Result Q
LOQ
Units Run
NO
530
uglkg 1
ND
530
uglkg 1
ND
530
uglkg 1
ND
530
uglkg 1
TCLP Pesticides
Analytical Method Dilution Analysis Date Analyst Prep Date Batch Lear -hate Date
8081B 1 06/1712020 1903 DAL1 06/16/2020 1600 57155 06/15/2020 2230
CAS Analytical
Number Method
58-89-9
8081 B
57-74-9
8081B
72-20-8
8081 B
76-44-8
8081B
1024-57-3
8081 B
72-43-5
8081B
8001-35-2
8081E
Run 1 Acceptance
Q % Recovery Limits
66 20-131
94 26-132
Result Q
LOQ
Units
Run
ND
0.00040
mglL
1
ND
0.0040
mglL
1
ND
0.00040
mg/L
1
ND
0,00040
mglL
1
ND
0.00040
mg1L
1
ND
0.0016
mglL
1
ND
0.0080
mglL
1
TCLP Metals
Analytical Method Dilution Analysts Date Analyst
Prep Date Batch Leachate Date
601 OD 1 06118/2020 1244 KSH2
O619712020 1510 57244 06/15/2020 2230
7470A 1 06118120201444 KSH2
06/18/20200747 57316 06115120202230
GAS Analytical
Number Method
Result Q LOQ
Units
Run
7440-38-2 601OD
ND 0.15
mglL
1
7440-39-3 601OD
ND 0.25
mg1L
1
7440-43-9 601OD
ND 0.050
mg1L
1
7440-47-3 601OD
ND 0.10
mglL
1
7439-92-1 6010D
ND 0.10
mglL
1
7439-97-6 7470A
ND 0.0020
mglL
1
LOO = Limit of Quanlitalion 0 - Detected in the method blank F = Quanlllation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40%
H = Out of holding time W = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www,pacelabs.com
Page 6 of 10

Client:Synagro Laboratory ID: VF11039.001
Description: SJWD Lyman Matrix: Solid
Date Sampled:0611012020 1000 % Solids: 3.19 06/1112020 2315
Date Received:0611112020
TCL.P Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 131113010A 601OD 1 06/18/2020 1244 KSH2 O611712020 1510 57244 06/15/2020 2230
1 131117470A 7470A 1 06/18/2020 1444 KSH2 O611812020 0747 57316 06/1512020 2230
GAS
Analytical
Parameter
Number
Method Result R L04
Units Run
Selenium
7782-49-2
601OD ND 0.20
mg]L 1
Silver
7440-22-4
6010D ND 0A0
mg1L 1
Footnote(s): 'Paint Filter: 20mL collected;
LoQ = Limit of Quantitation 0 - Detected in the method blank E = Quanlitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P - The RP❑ between. two GC columns exceeds 40%
H = Out of holding time W = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.corn
Page 7 of 10

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-97oo Fax [phone] www.pacelabs.com
Page 8 of 10

PACE ANALYTICAL SERVICES3 LLC
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Pace Analytical Services, LLC {formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www,pacelabs.com
Page 9 of 10

PACE ANALYTICAL SERVICES LLC
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I v,cumem INtarrla'J r; IAW)I SC: 1d uwiima nkio: nrbaaaA
Sample Receipt Cheek liSI (SRC)
Client; Syneglb C'O(Aur Inspacted hyfda#e: WOO / 0611 1f2nO Lot g., VF11034
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mts at receipt:) SEsi C[e11t uP$ [] rrdl x L] Dthcr:
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Strip ID; NA _ Ulor[ne $#rip ID; NA Tented by, NA
ginal temporatlue Upon receipt/ Derived (Ctimc tcd) temperature upon ret:oipt `Y%Hd `Snap -Cuts (1): 20-302
1 t.4 PC ETA /NA uC NA f elf# aC NA /NA or_
Mrffiod: [a'1'elt1peluiure 13Jank C]Agahil&i 13urt1es 1R Gtln JD; _ IR Gun CoTTectlian Faulor _a..... °C
Mediad of crlotalar 0 Wet Iee ❑ lee 111 ❑ Dry Ice ❑ Nunc
Yvs
❑ No
®NA
� • It tempt nature 01 any arloler exoedded {1,4 C, was Project Mdaagcr Natif e.d7
PM wry Notified by: phone I en liail i -race-w-tace (circle una).
0 Ytg
❑-No
0 N A
4. dsthe commercialcouricr's paddiagslip attuc):ed to this form`?
® Yes©
No
S. Wcre Ianpxr cuslody procedures (rralingtlEsbod1mccived) fnllowcd7
® Yes
In
6. Welt =11pl4IUa listed on the CLOG?
® �'es
❑ No
7. Wcre samplo IiDs listed un ail samples containcr.,a -
0 Yes
❑ No
S. Was collwinn date & tima listed on the C OC?
�'as
®No
9. 6Yuy collection dale & time listed on all yrrinple cnntaineu3? �
e .pNn
F
10. Did n11 containerlaLvl illf*rma[iau (ID, dire, time)egrccwith the C OC7
es
❑N)
11. Weratosts to ba perfbrme4 listed an tiro t'UC,'
Yes
❑ No
12• Did n[I samples affive ill ft proper• corilainers for euh test and/or ut good condition
(tinbroker), lids on, etc-)? _
® Yes
ONO
13. VVr,s ndcauaw s rrArr volume ayslilsahle7
❑ Nu
14. Were nl[ temples received Withlrt Y. the �holding time or 49=�Gurs, whichever Comas first?
EEZ'eqs'
No
1s. Were any samples contalness rrrimingJexcess (cu'cle cme) l�tmpJes Not listed nr. COZC
❑ No
WINA
16. For VOA and RSE 175 I.arnple3, were bubbles prescnt �jtett•sixo" (%"Or 6mnt in dittrncicr)
m any ofthe VOA vialst
rn.
:i LJ call 11411 r 1_ %VP41e UIL LJKIJi maral3+nlln'lelllsamUles reC(31Y41i rtt a pH Ut-'r: 12
s No & NA I$, W= all cyanide sans les received ai: a pH -- 1213ndauliidasrtmptesreceivedsataptI.,D�s ❑ No 0 NA Were a I app Icat}Ic IVH3T['KN'uyanl a }hrnnI1625 (<Q�mg+L) mmplcE free ofrq�ualciiiorin�?s ❑ No i1 NA 2�. Were r knt r murkslreqursls (1.e. requos Icd dilutions, M5J.l40 desi,rlati©n8, etc—)
cor,icrly hauscribcd from the C:UC ink) the comrnentsectiolf in LIMW
CHY-011 0 No 121. SFAS the quole number lWad out like container (Abel? Ityes, Ouote tt NA
Sample Pre nervation (Must lie uompletwJ for any sarr:ph*) hl4DOfJectly preserved or with hctldspace.)
Sample(s) NA were recclved :ticonnrotly presorved wad were ad)ustcd atocordlrlg)y
in sample Ieceiving with NA t3tiL tsf oino!e one: H2SO4, iiNi13, I iCl, NaOH using SR ti NA _
[mo oi'prescrvxlion NA _ If more tllnii one pmervative is rimalcd, plemo note ir. I :olnmenlr b01aw.
Sample(s) SSA -- received with bubblm >6 min in diameter.
Saniplcs(O NAY -- w" received with TRO f 0.5 i9 no) and were
4usLud aoonrdingly in simple receiviull;with sodium thlosulfam ( a5S.G3) u•ilh Shealy lD: NA —
Sii harcode labels applied yy: B1s9Cs Daw. 06AU2.020
Comments:
I
i.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 10

aceAnalytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Erika Lamb
Project Name: SJWD Lyman
Project Number: 52-2182
Lot Number:VD16058
Date Completed:04124/2020
I
W.
04/29/2020 3:31 PM
Approved and released by:
Lab Director - Greenville: Lucas Odom
4W.-W
ANSI W1Iwn11AMMAWn i.
A C C H E D I T E D
Q -�-
TFOUGLABCKATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 18

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: VD16058
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance
Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies. Any exceptions to
the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Sulfur
The anlaysis for sulfur has been performed by Pace Asheville. This data is located on Pace Asheville
report L1210823.
Pace Analytical Services, LLC (formerly Shealy Fnvironmelal Services, Inc.)
166 Vantage Point Drive West Columbia, SC 29172 (803) 791-97oo Fax [phone] www.pacelabs.com
Page 2 of 18

Client: Synagro
Description: SJWD
Date Sampled:0411512020 1100
Date Received: 0411612020
Run Prep Method
1
1 350.1
1
1
1
1
1 351.4
Ino
Analytical Method
Dilution
(% Solids) SM 2540G
1
(Ammonia - N ) 350A
1
(Nitrate - N ) 9056A
1
(Nitrite - N ) 9056A
1
(Phosphorus) 365.1
2
(Soil pH meas) 9045D
1
(TKN) 351.2
1
anic non-metals
Analysis Date Analyst
04/16/2020 2309 HET
04122120201426 DMA
04/22/2020 0136 HKL
04/2212020 0136 HKL
04121/20201258 DMA
04/17/2020 2354 SRB
04124120201348 DMA
Laboratory ID: VD16058-001
Matrix: Solid
% Solids: 2.13 04/16/2020 2309
Prep Date Batch
51299
51633
51749
51750
0412l /2020 0838 51601
51421
04/23/2020 0939 51890
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
2.13
%
1
Ammonia- N (gas diffusion)
350.1
550
47
24
mglkg
1
Nitrate - N (soluble)
9056A
20 J
23
1.2
mglkg
1
Nitrite - N (soluble)
9056A
5.2 J
9.4
0.90
mglkg
1
Phosphorus
7723-14-0 365.1
2100
470
94
mglkg
1
Soil pH measured in water @ 18.1 o C
9045D
6.4
su
1
351.2
4600
1200
1200
mglkg
1
TKN
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date Batch
1 7471 B
7471 B
1 04/17/2020 1144 KSH2
O4117/2020 0435 51306
CAS Analytical
Parameter
Number Method
Result Q LOQ
DL
Units
Run
Mercury
7439-97-6 7474E
ND 3.6
0.88
mglkg
1
ICP-AE5
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date Batch
1 3050B
601OD
1 04/20120201130 LLL
04/18/20201241 51310
2 3050B
601 OD
1 04/23/2020 2152 LLL.
04122/2020 1552 51840
CAS Analytical
Number Method
Result Q LOQ
DL
Units
Run
Parameter
7429-90-5 6010D
310000 910
340
mglkg
1
Aluminum
7440-38-2 6010D
13 J 32
11
mglkg
2
Arsenic
7440-43-9 601OD
ND 11
2.9
mglkg
1
Cadmium
7440-70-2 601OD
3300 J 11000
1400
mglkg
1
Calcium
Chromium
7440-47-3 6010D
120 23
5.7
mglkg
1
Copper
7440-50-8 601OD
430 23
10
mglkg
1
Iron
7439-89.6 6010D
170000 230
100
mglkg
1
Lead
7439-92-1 601OD
43 23
10
mglkg
1
Magnesium
7439-95-4 6010D
2900 J 11000
1400
mg/kg
1
Manganese
7439-96-5 6010D
16000 34
13
mglkg
1
Molybdenum
7439-98-7 6010D
ND 91
23
mglkg
1
LOO = Limit of Quantitalion B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND = Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GO columns exceeds 401/6 S = Estimated result < LOQ and > DL
H = Out of holding time VN = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
e06 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 19

Client: Synagro
Description: SJWD
Date Sampled:04/1612020 1100
Date Received: 0411612020
Laboratory ID: VD16058-001
Matrix: Solid
% Solids: 2.13 04/1612020 2309
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date Batch
1 3050B
601OD 1 04/20/20201130 LLL
04118120201241 51310
2 3050B
601 OD 1 04/23/2020 2152 LLL
04/22/2020 1552 51840
CAS Analytical
Parameter
Number Method
Result Q LOQ
Nickel
7440-02.0 6010❑
29 J 91
Potassium
7440-09-7 6010D .
3400 J 11000
Selenium
7782-49-2 6010D
ND 45
Sodium
7440-23-5 6010D
2400 J 11000
Zinc
7440-66-6 601OD
170 110
DL
Units Run
24
mglkg 1
1400
mg/kg 1
18
mg/kg 1
1400
mglkg 1
28
mg/kg 1
LOQ - Limit of Quantitation 8 - Detected in the method blank E = Quantitation of compound exceeded the calibration range bL = Detection Limit
ND = Not detected at of above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result [ LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 18

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Paint Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 18

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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 18

PACE ANALYTICAL SERVICES LLC
alwvl,' Qnxirmm.cn1_1 Survicw, lac puss I nrl
riniYlgPlA idumlxl IJ, �'t'rIIRC:-Id of wive nPIL; A124,7:111
Sample Receipt Checklist (SRQ
Gli�Tl: SYNAGRO Con lerins eztedbyJdttle:WI611 -0 loot#: YD16058
A,4rr-nc rA %1?%1 M t'IICnt 11PS F-1 Fedgx t t th'eP .- .._
❑ Yss Fj No t. Wcra caswd • seals resent on the cuulcl'?
n Yes []No ® NA 2. 1 f custa$y seals wcrc nr . VTIt, Al' a they intact and i nbrnken?
1H Strip 1D: kIA C1rlarine SS*ip 1Li: NA 'rested try,, NA
Delg1'rial temperature upon rmript,' Derived (Corrceted) lumperature upoit receipt "Molid Snap -Cuts ID- 19-2i?43
7..1 12.1 oC NA !NA eC t,1A f1,4jL oC NA !NA oC ^--
Moilted: 0Tempermre Blank ❑Against Bottles 1R Gttn 113, 6 IR Gull Correction Pnator: U °C
Mcibod of cUola i 1: V1 Wet Icc ❑ Ice Pecks © Dry Ice ❑ Warn: _
Tf to mpmUre of ally scaler cxcftde t fiVC, ways Project ManagcrNoli-F—wA?
❑ Yes El No DNA VM was Nodfivd by: phone i email!face-to-free (Circle One).
I —I Yr-v f] Mar t7 NA 4. Is the commm rial coliriw's packitlg slip attached to this famn?
® YC3
No
16.
Wurr: dimple IDs listed on the COO
0 Yeti
❑ Nu
7, Wm sam :e IDs listed on all snlnple coniainors7
® k es
[3 No
--..-
8. Was caltection date & brae limcd an dle COC7
Yes
❑ NG
9. Was collection drite & time listed on all sarnplc vrintainers?
� Yts;
C1 Na
10. Did till eonlainer tabcl inrbmia?ion (ID, date, thile) c with the CDC?
�[ Ycs
❑ Na
I I. Were tests to be pufarmcd listed On the COO
12. Did all samplcs arrive in the proper oontainen for each test and/or in good condition
❑ Na
1(—brakcnl lids on, etc]? .-- ___--
Yes
- ❑ No
13. Was adequate simple vulume available?
Yes
Nfo
14. Were all samples received within Ys the holding time ar 48 hours, whioliever catres flrat?
W
N0
15. Wcro airy slm, ]es Lontablen iltissingJexcces (GIMIQ one) Spnl les Not listed on tsOM
16. Pot' VOA and R.SK-175 samples, were babbleR prescnt>'rpcu-size' (Y:'ar 61nnt in diameter}
p yes
❑u,
[ra
.
In Atiy a the VOA vials?
Yes
Io
NA
17. 1Varc all UK{1lrltcltllsitiutrient samples received at I pl-T of <2?
[] Ycs
❑ 1a
NA
1 B. tiVere sll cyanide samplos n uivebd at a I4 :- 12 and sulfide m les received at a pli 9?
,n t� � ....r1 /Pllitir+r,`nirlr/nhrnnlF[i)Sr<n.Stnp f.lsamnes reap raSrdual
©YPA ❑ No 91 NA t lllui'flte?
20. Were renta_rksr'regnests (i.e, mgite5ted dilutirms, lvtSIMSD Jvsigau tt_,us; em...)
❑Ycs 0 No ® NA correctly transcribed f:arn the COC into the *Omrrent Section in L IMS?
Yes. No 21, Waste ttntr.. number 5,5Lv3 oi the auntaitier laWl? If Bch uota 1i NA _
Sample Pre5erva(Must Must be earnpintcd for tutl' StutlFte(s) incomrily pre-erYed or Wit?1 lent space.)
Samples) NA _were reuciveJ incorrectly preserved and were adjusted accordingly
ill sample rcccitZrtg wilh NA triL of circle one; l4i5( , HNO3, HU, Nn011 using 8K tr 1tiA
Time ofpnesetvation NA Irmcna Elan one prxsetuative is needed, please natn in tlic commortts below.
Sainple(s) NA were received willi l ul:llke >6 min in diameter,
5alttp�es(s}opt -- _ wcrcreceivedwlth 7RC>0.5IDWI_.0r919 is"fl)artdWCO
tuljugW acconxliligiv in sample racaiving wigs sodium thiostilfatt, (NkS,03) With Shealy ID. Net _� i
Sft krcode labels applied by; 2SH Dane: OAJl r2t1'Lil
Comments:
Pace Analytical Services, LLC {formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 18

II i 'L
V71
State of North Carolina
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the ARplicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non-Dischar e Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
® For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
® Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Man Guidance for
Residuals Land Application Permits'.
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item 1. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: Synagro Central LLC
Status
Codes
N
Facility Permit Holder
City of Graham
N
N
Startex Jackson Wellford
Duncan Water District
Water Treatment Plant
Town of Siler City
N
City of Portsmouth
a Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (iJeleted}
v The amount of residuals currently permitted for distribution, land application, or disposal (i.e, not applicable to new facility).
SUMMARY FOR FORM: RSC 06-16 Page 1

Division of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Siler City Water Treatment Plant
2. Facility permit holder is: ❑ Federal, El State, N Local Government, or ❑ Private.
Facility permit issued by: ® Div. of Water Resources, ❑ Div. of Environmental Health,
or ❑ Other (explain: LLi).
3. Facility contact person and title: Chris McCorquodale, Utilities Director
Complete mailing address: 311 N 2nd Ave
City: Siler City State: NC Zip: 27344-
Telephone number: (919)-742-4731 E-mail address: emccor uodale silerci .ol•
4. Facility physical address: 950 Water Plant Rd.
City: Siler Ci State: NC Zip: 27344-
Coordinates: Latitude: L5'45' 39" Longitude: 790 27' 43"
Datum: NAD$3, Level of accuracy: Seconds
Method of measurement: MAP
5. Purpose of the facility:
r] treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
Z treatment of potable water, ❑ treatment of 100% industrial wastewater,
❑ treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: K J % industrial and % domestic)
❑ other (explain: ).
6. Does the facility have an approved pretreatment program. ® Yes ❑ No
7. Facility permitted/design flow: 440 MGD and facility average daily flow: 1I7MGD
S. Average amount of residuals being generated at this facilityesYJ 100 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water Treatment Process
Type and volume of residuals storage (i.e., outside of residuals treatment units): 1 lagoon estimated'/z million gallons cap.
H. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
❑ 40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102(61 as:
Biological 2 Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page 1 of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% n on -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: d yes M no.
If yes, list the number(s): L-
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: ❑ yes ® no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Pace Analytical and Date of analysis: 7/22/2020
Passed corrosivity test: ® yes ❑ no. pH: s.u. (2 < pH < 12.5)
Passed ignitability test: ® yes ❑ no. Flashpoint: > 140 °F (> 140°F)
Passed reactivity test: ®yes ❑no. HCN: ND mg/kg (<250) & H2S: ND mg/kg (<500)
TCLP Parameter
Limit
Result
TCLP Parameter
Limit
Result
Ong/l)
(mg/1)
(Ing/1)
(ntg/1)
Arsenic
5.0
ND
Hexachlorobenzene
0.13
ND
Barium
100.0
ND
Hexacbloro-1,3-Butadiene
0.5
ND
Benzene
0.5
ND
Hexachloroethane
3.0
ND
Cadmium
1.0
ND
Lead
5.0
ND
Carbon Tetrachloride
0.5
ND
Lindane
0.4
ND
Chlordane
0.03
ND
Mercury
0.2
ND
Chlorobenzene
100.0
ND
Methoxychlor
10.0
ND
Chloroform
6.0
ND
Methyl Ethyl Ketone
200.0
ND
Chromium
5.0
ND
Nitrobenzene
2.0
ND
m-Cresol
200.0
ND
Pentachlorophenol
100.0
ND
o-Cresol
200.0
ND
Pyridine
5.0
ND
p-Cresol
200.0
ND
Selenium
1.0
ND
Cresol
200.0
ND
Silver
5.0
ND
2,4-D
10.0
ND
Tetrachloroethylene
0.7
ND
1,4-Dichlorobenzene
7.5
ND
Toxaphene
0.5.
ND
1,2-Dichloroethane
0.5
ND
Trichloroethylene
0.5
ND
1,1-Dichloroethylene
0.7
ND
2,4,5-Trichlorophenol
400.0
ND
2,4-Dinitrotoluene
0.13
ND
2,4,6-Trichlorophenol
2.0
ND
Endrin
0.02
ND
2,4,5-TP (Silvex)
1.0
ND
Heptachlor and its Hydroxide
0.008
ND
Vinyl Chloride
0.2
ND
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For DistributionlLand Anplicatiou Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint Analytic and Date of analysis: 2/5/2020
Parameter
Ceiling
Monthly Average
Result
Concentration Limits
Concentration Limits
(ClassA & Classl3)
(Class A Only)
(rng/kg)
(mg/kg)
(mg/kg)
Arsenic
75
41
<19.2
Cadmium
85
39
<3, 85
Copper
4,300
1,500
<9.62
Lead
840
300
<11.5
Mercury
57
17
<0.562
Molybdenum
75
n/a
<9.62
Nickel
420
420
39.2
Selenium
100
100
<19.2
Zinc
7,500
2,800
<48.1
b. For Surface Disposal Unit (lnlrtIft-IJI: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: [ and Date of analysis:
Distance from Disposal
Arsenic
Chromium
Nickel
Unit to Boundary to
Closest Property Line
(meters; check one)
(mg/kg)
(mg/l(g)
(ing/kg)
❑ > 0 but < 25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (mg/kg)
FORM: RSC 06-16 Page 3 of 5

5. NutrientlMicronutrient Determination: Complete the following:
a. Total solids: 2.59 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Waypoint Analytical and Date of analysis: 5/05/2020
Parameter
Result
Ong/kg)
Aluminum
4,500
Ammonia -Nitrogen
<3850
Calcium
1,220
Magnesium
431
Nitrate -Nitrite Nitrogen
<186
pH (Standard Unit)
6.6
Phosphorus
1,350
Potassium
419
Sodium
1,400
Total Kjeldahl Nitrogen
I6,400
c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 1.41
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 20 %. This
rate is a (check one): 2 default value, or d actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method
First (V) Year PAN
Five -Year
Maximum Adjusted PAN
(ing/kg)
(ing/kg)
Surface
4,621
6,552
injection/incorporation
6,546
8,477
6. Other Pollutants Determination:Specify whether or not there are any other pollutants of concern in the residuals and provide
_
the results of the latest analyses: bn '
FORM: RSC 06-16 Page 4 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For DistrlbutronlLand Application of Class A or Equivalent:
❑ A fecal colifonn density that is demonstrated to be less than 1,000 MPN per grain of total dry solids,
or
EJ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
d Alternative 1 [15A NCAC 02T.1106(b)(3)(A)] - Time/Temperature Compliance.
[] Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
d Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 4 [15A NCAC 02T.1106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
EJ Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: 0 composting, ❑ heat drying, ❑ heat treatment,
d thermophilic aerobic digestion, ❑ beta ray irradiation,
d gamma ray irradiation, or ❑ pasteurization.
For Land Application of Class B:
❑ Alternative 1 [15A NCAC 02T.I 106(c)(1)] - Fecal Colifonn Density Demonstration.
❑ Alternative 2 [15A NCAC 02T. 1106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: ❑ aerobic digestion, El air drying, a anaerobic digestion,
0 composting, or ❑ lime stabilization.
c. For Surface Dis osgl:
❑ Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
❑ Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item Il. 7b. above.
❑ Exempt - If Daily Cover Alternative is chosen in Item I1.8. below [15A NCAC 02T.1106(a)(2)].
❑ Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8, Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
❑ Alternative 1 [I5A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
❑ Alternative 2 [ 15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
❑ Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
❑ Alternative 4 [15A NCAC 02T. 1107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
❑ Alternative 5 [15A NCAC 02T.1107(a)(5)] - 14-Day Aerobic Processes.
❑ Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization.
❑ Alternative 7 [15A NCAC 02T.I 107(a)(7)] - Drying of Stabilized Residuals.
❑ Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals.
❑ Alternative 9 [15A NCAC 02T.1107(a)(9)] - Injection.
❑ Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
❑ Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.I 107(b)(2)].
® Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

VICINITY MAP SYNAGRO
40'
tlr-l3r.'I 1.11 -
�2l
t`
1:31d
pshtrin Gt �
� 4h
;7
«4 T i -. Water Plant Rd k
@� Siler City, NC 27344
il5.760633,-79.462763
COUNTY: Chatham OWNER(S): Siler City Water Treatment Plant

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rb
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3
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Quantitative Justification for Residuals Production Rate
Siler City WTP
Between the years of 2016 and 2019, the Siler City WTP has land applied
approximately 65.25 dry tons of material each year. It is requested that Siler City WTP be
permitted to land apply a maximum of 125 dry tons per year to account for any plant
fluctuations or future maintenance cleanouts.
Dry tons land applied between 2016 and 2019.
Year
Dry Tons
2016
57
2017
44
2018
54
2019
106

Residuals Sampling Plan
Synagro Residuals Land Application for WQ0035207
Siler City Water Treatment Plant
Nutrients and Metals Analysis
• Sampling Point: Storage Lagoon
• Sampling Frequency: Annually
a Sample Type: Composite
• Lab: Waypoint Analytical
Pathogen Reduction (Not Required)
Vector Attraction Reduction (Not Required)
TCLP
• Sampling Point: Storage Lagoon
• Sampling Frequency: Annually
• Sample Type: Composite
• Lab: Summit Environmental Labs

aceAnalytical
Report of Analysis
Synagro
12701 Lancaster Hwy
Pineville, NC 28134
Attention: Nate Roth
Project Name: Siler City
Lot Number:VG08007
Date Completed:07123/2020
07/23/2020 11:41 AM
Approved and released by:
Project Manager ll: Lucas Odom
z A4II
ANdf NTfPoml A(ufdllrUon dorrd
A C C P E D 17 E D
-�
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel:[phone] Fax:[phone] www.pacelabs.com
Page 1 of 8

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Synagro
Lot Number: VG08007
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Pace Analytical Services, LLC ("Pace") Quality Assurance
Management Plan (QAMP), standard operating procedures (SOPS), and Pace policies. Any exceptions to
the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W ,
qualifier
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
TCLP VOCs
The laboratory control sample (LCS) for analytical batch 60829 exceeded acceptance criteria for the
following analytes: Carbon Tetrachloride and 1, 1 -Dichloroethene . These analytes were biased high but
were not detected in the samples affected..
Pace Analytical Services, LLC {formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive west Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 2 of 8

Ciient:Synagro
Laboratory ID:VG08007-001
Description: Slier City WTP
Matrix:
Solid
Date Sampled:0710612020 1400
% Solids:
2.52 07/08/2020 2344
Date Received:0710812020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(% Solids) SM 2540G
1 07/08/2020 2344 HET
59380
1
(Ignilability) 1010A
1 07/22/2020 1357 MSG
60982
1
(Reactive Cya) 7.3.3
1 07/1512020 1520 KFE
07/15/2020 0830
1
(Reactive Sul) 7.3.4
1 07/15/2020 2006 HET
07/15/2020 0830
1
(Soil pH meas) 9045D
1 07/09/2020 1836 SRB
59637
GAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
% Solids
SM 254OG
2.52
%
1
Ignitability (Pensky-Martens Closed
-Cup)
1010A
>140
140
0
° F
1
Reactive Cyanide
7.3.3
ND
50
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
5o
mg/kg
1
Soil pH measured in water @ 21.9 ° C
9045D
6.4
su
1
TCLP Volatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/6030B
8260D
10 07/22/2020 0146 JTH
60829
07/20/2020 2302
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Benzene
71-43-2 8260D
ND
0.050
0.0040
mg1L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
0.020
mg1L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
0.0040
mglL
1
Chlorobenzene
108-90-7 8260D
ND
0.050
0,0040
mglL
1
Chloroform
67-66-3 8260D
ND
0.050
0.0040
mg1L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
0.0040
m91L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
0.0040
mg1L
1
Tetra chloroethene
127-18-4 8260D
ND
0.050
0.0040
mg1L
1
Trichloroethene
79-01-6 8260D
ND
0.050
0.0040
mg/L
1
Vinyl chloride
75-01-4 8260D
NO
0.010
0.0040
mg1L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
97 70-130
1,2-Dichloroethane-d4
104 70-130
Toluene-0
100 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8270E
1 07/20/2020 1858 JCG
07/16/2020 1708 60349
07/13/2020 1906
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
0.0050
mg1L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
0.0050
mglL
1
LOQ = Limit of Quantitalion B - Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
ND - Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40% J = Estimated result , LOQ and a DL
H = Out of holding time W = Reported on wet weight desis
ice Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Dive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs,com
Page 3 of 8

Client:Synagro Laboratory ID:VG08007-001
Description: Siler City WTP Matrix: Solid
Date Sampled:07/06t2020 1400 % Solids: 2.52 07/0812020 2344
Date Received:0710812020
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 131113520C
8270F 1 07/20/2020 1858 JCG
07/16/2020 1708 60349
07/13/2020 1906
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Hexachlorobenzene
118-74-1 8270E
ND
0.040
0.0050
mglL
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
0.0050
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
0.010
mglL
1
2-Methylphenol
95-48-7 8270E
ND
0.040
0.010
mg1L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
0.015
mg1L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
0.015
mglL
1
Pentachlorophenol
87--86-5 8270E
ND
0.20
0.020
mglL
1
Pyridine
110-86-1 8270E
ND
0.040
0.0050
mglL
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
0.0050
mglt-
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
0.0050
rnglL
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
50 37-129
2-Fluorophenol
26 24-127
Nitrobenzene-d5
50 38-127
Phenol-d5
35 28-128
Terphenyl-d 14
79 10-148
2,4,6-Tribromophenol
73 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/8151A
8151A
1 07/20/2020 0217 JJG
07/17/2020 0021 60308
07/13/2020 1906
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
0.0050
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
0.0013
mg1L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
❑CAA
93 50-112
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 1311/3520C
8081E
1 07117120201719 DAL1
07115120201600
60196
07113120201906
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
gamma-SHC (Lindane)
58-89-9 8081B
ND
0.00040
0.00017
mg1L
1
Chlordane
57-74-9 8081B
ND
0.0040
0.0015
mglL
1
Endrin
72-20-8 8081B
ND
0.00040
0.00015
mglL
1
LOQ = Limit of Quanlitation B = Detecled in the method blank E = Quanlitalion of compound exceeded the calibration range DL = Detection Limit
ND - Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GO columns exceeds 40% J = Estimated result < LOQ and > DL
H = Oul of holding time W = Reported on wet weight basis
ace Analytical Services, LLC (formerly Shealy Environmental Services, lnc.J
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www,pacelabs.com
Page 4 of 8

Client:Synagro
Laboratory ID:VG08007-001
Description: Siler City WTP
Matrix: Solid
Date Sampled:07/0612020 1400
% Solids: 2.52 07/0812020
2344
Date Received:0710812020
TCLP Pesticides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081B 1 07/17/2020 1719 DAL1
07/15/2020 1600
60196 07/13/2020 1906
CAS Analytical
Parameter
Number Method
Result Q
LOQ DL
Units
Run
Heptachlor
76-44-8 8081B
ND
0.00040 0.00015
mglL
1
Heptachlor epoxide
1024-57-3 8081E
ND
0,00040 0.00016
mglL
1
Methoxychlor
72-43-5 8081B
NO
0.0016 0,00021
mg/L
1
Toxaphene
8001-35-2 8081E
NO
0.0080 0.0030
mglL
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
38 20-131
Tetrachloro-m-xylene
48 26-132
TCLP Metals
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
Leachate Date
1 131113010A
601OD 1 07/16/2020 1236 KSH2
O7/15/2020 1457 60162
07/13/2020 1906
1 131117470A
7470A 1 07/15/2020 1523 JAB2
07/15/2020 1130 60085
07/13/2020 1906
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Arsenic
7440-38-2 6010D
NO
0.15
0.025
mg1L
1
Barium
7440.39-3 601OD
0.27
0.25
0.031
mg1L
1
Cadmium
7440-43-9 6010D
ND
0.050
0.0060
mglL
1
Chromium
7440-47-3 601OD
NO
0.10
0.013
mg1L
1
Lead
7439-92-1 601OD
ND
0.10
0.047
mglL
1
Mercury
7439-97-6 7470A
NO
0,0020
0.00091
mg1L
1
Selenium
77B2-49-2 601OD
ND
0.20
0.085
mglL
1
Silver
7440-22-4 6010D
ND
0.10
0.021
mg/L
1
LOQ = Limit of Quantitation 8 = Detected in the method blank E = Quanhtation of compound exceeded the calibration range ❑L = Detection Limit
ND = Not detected at or above the DL N = Recovery is out o1 criteria P - The RPD between two GC columns exceeds 40% J = Estimated result < LOQ and > DL
H = Out of holding lime W = Reported on wet weight basis
ice Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 8

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs,com
Page 6 or

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive
West Columbia, SC 29172
[phone]
Fax [phone] www.pacelabs.com
Page 7 of 8
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pH Strip ID: Chlorine Strip ID: -rez tl by, i,fVk,
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I
❑No
5. were roper custody procedures (relitiqui�l[edrrcccived) fallowed7
❑No
G. Wcrc sample IDs 1fisted nn the COO(
-No
1. WOVe SAM 1e IDS listed Uri ail ,xrrrpia Container8` 7+_
❑ No
8. W'as collection date& time ]fisted oft the MCI
-2%
9. Was [collection (lu(c & time listed on all sample eonlairxets?
i+lu
M, Did all container label infomiation 01), date, Hme) agree with Ilse 000 �1/rtJ eQ.�n
—
laVes
❑ Nn
11. Wero tests to be performed listctl on the COL - —
12. Did lilt srttttples arrive 1❑ the prober COW niner4 foreach teat antfor in good condition
(tlrrbrokeu, Ii:ls on, dc.)?
R'yds
0 No
J' Yes
❑ No
13- Was odoquatc sample volume avoilabla? �.
Yes;NoA
14. 4Wercf al sa,n Ics rece=vedwiffit sf dw hulling time or 4S hours, whlohevcw comes first?
MM'6 uur �WIIPIC6 caatalncrimissin laxce cicolc on(t) samples Not listed on COU
l 6,1{or VOA anu RSK-175 goMples. woro bubbles preseait>:`pee-sirx ' (A"orGmm in diameter)
rn uny of the V0A vials?
Yes15.
❑ Yos
17. Were all DROfmc;ais{nutrionr se,][1[1m rnoeiycd at n pR of<2?
❑ Yes18.
W= till cynnide sampler received At a pl i } 17, and sulfdo sumpim received at apH > 97
Yes19,Wem
sill appl lcabin N RiT cyanr ally renatG25 (s Um r L} samples tree ofPCmI u
❑ Yc3
❑No
CJ"NA
20. WUM clicntrcmnrksrrequestsQ.e. requiWcd dilutions, MNMSD dcrsiL[mtions, etc.,.)
eorrucl'.ytrmnscribcAfrom the C'.00intothe commentSaUiuuiiII.1MS?
Was the qUOtO liu:nbl'r listed on the container label? lf'vcs, Ouote ft NA
Sample Preserveti[)u (Mus: bo completed for any snmplc(s) incorcocdy lir served nr with headspace.) .—
;,ampla(s) were teenive. i inc:ormcthrpreserved widwcrc adjusted accardingly
in sample raceivbig wtidi ml. o= cimla one: MS44, }114O3, H CI, NaOH using SR tl
Tbile of pnawrva6wi r If more than one prescrvad 4 c is needed, please note in the comments bolow,
Stkmpla S) AA wen roceiued with hubblos �-G milt in diamoter.
Samples(s) 1' _ wort received wilt! TRC > 0.5 tnglL (lf it 19 is irm) and were
djusred accordingly in sampie receiviiog Willi st,dFrrm thiosulfate (NNS-201) With Shealy ID:
Sit b4[uA lahcis applied by: _ _ I�! ` bate.
C�nrrlcn4s:
Pace Analytical Services, l-GC (formerly Shealy Environmental Services, inv.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] t www.pacelabs.com
Page 8 of 8

Waypointo
ANALYTICAL
2/7/2020
Synagro Central LLC/ Siler City
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 20-030-0001
Project Description: Siler City WTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received sample(s) on 1/30/2020 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CF'R 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Q,M,;. ir 0•7-
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 7

waypoint'(2)
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° FaH 804-271-6446
www.waypointanalytical.com
Sample Summary Table
Report Number: 20-030-0001
Client Project Description: Siler City WTP
Lab No
Client Sample ID
Matrix
Date Collected
Date Received
Method
Lab ID
70319
[e-mail]
Solids
01/2B/202011:22
01/30/2020
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
SM-4500-NH3C
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
9045D
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
4500NO3F-2011
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
6010D
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
SW-7471B
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
SM-4500-NH3C TKN
WP MTN
70319
[e-mail]
Solids
01/28/2020 11:22
01/30/2020
SM-2540G
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 7

r
•
Waypoint 7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
ANALYTICAL www.waypointanalVtical.com
46490
Synagro Central LLC/ Siler City Ryan Copeland
Mary Brewer Project Siler City WTP Report Date : Q2/07/Z024
284 Boger Road Information : Received : 01/30/2020
Mocksville . NC 27028 MC 614Xr
submitted By : Ryan Copeland Pauric McGroary
Report Number: 20-030-0001 REPORT OFANALYSIS Agronomist
Lab No : 70319 Matrix: Solids
Sample ID : [e-mail] Sampled: 1/28/2020 11:22
Test Results Units MQL DF Date ITime By Analytical
Analyzed Method
Moisture 97.4 % 0.010 1 02/04/2016:39 CIR SM-254OG
Test Results Units MQL DF Date ITime By Analytical
Analyzed Method
Ammonia Nitrogen
<31350
mg/Kg - dry
3850
1
02/06/20 13:00
JPJ
SM-4500-NH3C
Nitrate+Nitrite-N
<1B6
mg/Kg - dry
186
1
02/04/20 14:20
ZBD
4500NO3F-2011
Organic N
16400
mg/Kg - dry
9620
1
02/06/20 09:00
CALCULATION
PH
6.6
S.U.
1
02/05/20 06:10
JSL
9045D
Total Solids
2.59
%
0.010
1
02/04/20 16:39
CIR
SM-254OG
Total Kjeldahl Nitrogen
16400
mg/Kg - dry
9620
1
02/06/20 09:00
JPJ ;M-4500-NH3C-TKP
Phosphorus
1350
mg/Kg - dry
192
1
02/04/20 01:33
KKM
60101)
Aluminum
4500
mg/Kg - dry
192
1
02/05/20 00:32
KKM
6010D
Arsenic
<19.2
mg/Kg - dry
19.2
1
02/04/20 01:33
KKM
6010D
Calcium
1220
mg/Kg - dry
962
1
02/05/20 00:32
KKM
6010D
Cadmium
<3.85
mg/Kg - dry
335
1
02/04/20 01:33
KKM
6010D
Chromium
20.4
mg/Kg - dry
9.62
1
02/04/20 01:33
KKM
6010D
Copper
<9.62
mg/Kg - dry
9.62
1
D2/05/20 00:32
KKM
6010D
Iron
396000
mg/Kg - dry
962
5
02/05/20 01:05
KKM
60101)
Lead
<11.5
mg/Kg - dry
11.5
1
02/05/20 00:32
KKM
6010D
Magnesium
431
mg/Kg - dry
192
1
02/04/20 01:33
KKM
6010D
Manganese
6000
mg/Kg - dry
19.2
1
02/05/20 00:32
KKM
6010D
Qualifiers/ DF
Dilution Factor
L
Limit Exceeded
Definitions MQL
Method Quantitation Limit
Page 3 of 7

Waypointo
ANALYTICAL
46490
7621 Whitepine Road, Richmond, VA 23237
Main 804-743.9401 0 Fax [phone]
www.waypointanalytical.com
Synagro Central LLC/ Slier City Ryan Copeland
Mary Brewer Project Slier City WTP
284 Boger Road Information
Mocksville , NC 27028
Submitted By : Ryan Copeland
Report Number: 20-030-0001
Lab No : 70319
Sample ID : [e-mail]
Test
REPORT OF ANAL YSTS
Results Units MQL
Report Date : 02/07/2020
Received ; 01/30/2020
Pauric McGroary
Agronomist
Matrix: Solids
Sampled: 1 / 28/2020 11.22
DF Date / Time By Analytical
Analyzed Method
Mercury
<0.562
mg/Kg - dry
0.562
1
02/03/20 13:11
T.1S
SW-7471B
Molybdenum
<9.62
mg/Kg - dry
9.62
1
02/04/20 01:33
KKM
6010D
Nickel
39.2
mg/Kg - dry
9.62
1
02/04/20 01:33
KKM
6010D
Potassium
419
mg/Kg - dry
192
1
02/04/20 01:33
KKM
6010D
Selenium
<19.2
mg/Kg - dry
19.2
1
02/04/20 01:33
KKM
6010D
Sodium
1400
mg/Kg - dry
962
1
02/04/20 01:33
KKM
6010D
Zinc
<48.1
mg/Kg - dry
48.1
1
02/04/20 01:33
KKM
6010D
Sulfur
6150
mg/Kg - dry
192
1
02/05/20 00:32
KKM
6010D
Qualifiers/ Dp Dilution Factor
Definitions MQL Method Quantitation Limit
L Limit Exceeded
Page 4 0£ 7

Waypointo
ANALYTICAL
Client: Synagro Central LLCI Siler City
Project: Siler City V11TP
Lab Report Number: 20-030-0001
Date: 2/6/2020
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 70319 ([e-mail])
Analyte: Iron
QC Batch No: 1-47603911-475628
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 5 of 7

(b
WayPAo Int,
NALYTICAL
7621 Whltepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
wwwmaypo i nta na lytica I -com
Shipment Receipt Form
Customer Number: 46490
Customer Name: Synagro Central LLCI Slier City
Report Number: 20-030-0001
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
UPS 0 Client 0 Courier
Shipping container/cooler uncompromised?
Number of coolerslboxes received
Yes
0 Other:
Thermometer ID:
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Yes
0 No
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved
0 Yes
0 No
NIA
Water - VOA vials free of headspace
0 Yes
0 No
NIA
Trip Blanks received with VOAs
0 Yes
0 No
NIA
Soil VOA method 5035 -- compliance criteria met
0 Yes
0 No
NIA
High concentration container (48 hr)
Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14
d) Low conc pre -weighed
vials (Sod Bis -14 d)
Special precautions or instructions included?
Comments:
0 Yes 0 No
Signature: Brandi Watson Date &Time: 1/30/2020 12:5214
Page 6 of 7

L 30 4 abL-d
SAtyPLiNPa LOG #
I111IIIII�III 11111111111 ll111V1111111111111M1IN
'°
LLG S,iw CITY
SY-I
46490 Q o CHAn�Ne OF CUSTODYAA■NII
_
filar CJWTP
C.I.flaaroCVTP
12.5057 li�.,ltitt��® Sc MN/41r.,YS11.0tii
PRCJCGT MANAGER: y lj(U
l-OPCND
1 attest that the proper field sampling procedures
were used during the colloctlon of those samples.
m
Phonra; �s16 ) 6d-7 1 4
U,
,A'�
&tj cp'oeu
A & L CUSTOMER
LAB it SAMPLE I.D.
SAMPLING
LOCATlOIV
5AMPLE # OF
TYP,E
r�/`.J
SAMPLER
SAMPLING METHOD METHOD
CONTAINERS
DATE! TIME PRESERVED SHIPPER
Sitor- LIFY WT4'
L4NOv
SL/ump
1%2�/z�
U P5
Rallnqulshed by Sampler: 97
f�Yl1N
CoDEJ
Date 77me �,� Reclovod by;
REMARKS:
F�r�o
1 z6 L� t 15-`5`
RaUnqulahad by:
D ie Time R ved by:
I . P-O
Relinquished by:
to Tlmo Roo eyed by:
SPECIAL. INSTRUCTIONS:
h
, Far F `� manitaring purposes. PO#:
n
SAMPLt: ANALYSis nEQUEBT
SL•1 81-2 Nl-I,-N NO9 N or.anlc Cd CP W1 Pb As yS so PH
S1�ER L1r; '
CUCO3 Volatile
M❑nquy, Solids CI NCia•Vl
I . M
SL1: Total Solids (Moisture), Total Icjeldahl Nitrogen, Phosphorus, and Potassium
SL2: 13asla Test SL-I Pius Sulfur, Calolum, Magnos[um, Sodlum, Iron, Aluminum, Manganass, Copper and Zinc

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Qzrality Permitting Section's Non-Dischar e Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
® Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
® For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
® Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
® For each source facility, attach the following:
® Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Mqp Guidance for
Residuals Land Application Permits".
® Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
® Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item 1. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
® Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
® For each source facility, attach the following:
® Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
® Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of I

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: Synaaro Central LLC
Maximum Dry Tons Per Year
Status Facility Permit Holder
Facility Name County
Permit Number
Current a
Proposed
Code'
N City of Graham
Graham Mebane WTP Alamance
NCO045292
0
275
Startex Jackson Wellford
N Duncan Water District
SJWD/Duncan WTP Spartanburg SC
ND0085499
0
700
Water Treatment Plant
N Town of Siler City
Siler City WTP Chatham
03-09-010
0
125
N City of Portsmouth
Lake Kilby WTP Suffolk
VA0006301
0
3200
a Status Code for source facility are: ♦ N (New)
♦ R (Renewed) ♦ M (Modified) ♦ D {Deleted}
e The amount of residuals currently permitted for
distribution, land application, or disposal (Le, not applicable
to new facility).
Page 1
Pa
SUMMARY FOR FORM: RSC 06-16

Division of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Lake KiIby Water Treatment Plant
2. Facility permit holder is: ❑ Federal, ❑ State, Z Local Government, or ❑ Private.
Facility permit issued by: ® Div. of Water Resources, ❑ Div. of Environmental Health,
or ❑ Other (explain: ' �).
3. Facility contact person and title: Nathan Litteral, Water Plant Manager
Complete mailing address: 105 Maury Place
City: Suffolk State: VA Zip: 23434-
Telephone number: (757)-539-2201 E-mail address: [e-mail]
4. Facility physical address: 105 Maury Place
City: Suffolk State: VA Zip: 23434-
Coordinates: Latitude: 36043' 37" Longitude: 76' 36' 06"
Datum: NAD83 Level of accuracy: Seconds
Method of measurement: 7 W
5. Purpose of the facility:
❑ treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
® treatment of potable water, ❑ treatment of 100% industrial wastewater,
❑ treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: = % industrial and L—:_ % domestic)
❑ other (explain: ).
6. Does the facility have an approved pretreatment program: ® Yes ❑ No
7. Facility permitted/design flow: 33.OMGD and facility average daily flow: 18 MGD
8. Average amount of residuals being generated at this facility e9t] 2500 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water Treatment Process
Type and volume of residuals storage (i.e., outside of residuals treatment units): 1 lagoon approximately 20 acres
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
❑ 40 CFR Part 503 or r 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under I5A NCAC 02T.1102(6) as:
( ❑ Biological M Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page i of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: ❑ yes ® no.
If yes, list the number(s):
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: ❑ yes 0 no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability; and reactivity:
Laboratory: Microbac Labs and Date of analysis: 7/07/2020
Passed corrosivity test: ® yes ❑ no. pH: sm. (2 < pH < 12.5)
Passed ignitability test: ® yes ❑ no. Flashpoint; Will not ignite T (> 140T)
Passed reactivity test: ® yes Ono. HCN: ND mg/kg (<250) & H2S: ND mg/kg (<500)
TCLP Parameter
Limit
(r11g/1)
Result
(1119/1)
TCLP Parameter
Limit
(rng/I)
Result
(mg/1)
Arsenic
5.0
ND
Hexachlorobenzene
0.t3
ND
Barium
100.0
ND
Hexachloro-1,3-Butadiene
0.5
ND
Benzene
0.5
ND
Hexacbloroethane
3.0
ND
Cadmium
1.0
ND
Lead
5.0
ND
Carbon Tetrachloride
0.5
ND
Lindane
0.4
ND
Chlordane
0.03
ND
Mercury
0,2
ND
Chtorobenzene
100.0
ND
Methoxychlor
10.0
ND
Chloroform
6.0
ND
Methyl Ethyl Ketone
200.0
ND
Chromium
5.0
ND
Nitrobenzene
2.0
ND
m-Creso.l
200.0
ND
Pentachlorophenol
100.0
ND
o-Cresol
200.0
ND
Pyridine
5.0
ND
p-Cresol
200.0
ND
Selenium
1.0
ND
Cresol
200.0
ND
Silver
5.0
ND
2,4-D
10.0
ND
Tetrachloroethyiene
0.7
ND
114-Dichlorobenzene
7.5
ND
Toxaphene
0.5
ND
1,2-Dichlorcethane
0.5
ND
Trichloroethylene
0.5
ND
1,I-Dichioroethylene
0.7
ND
2,4,5-Trichlorophenol
400.0
ND
2,4-Dinitrotoluene
0.13
ND
2,4,6-Trichlorophenol
2.0
ND
Endrin
0.02
ND
2,4,5-TP (Silvex)
1.0
ND
Heptachlor and its Hydroxide
0.008
ND
Vinyl Chloride
0.2
ND
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For Distribrition/Lruad Appllcaltolt: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint Analytical and Date of analysis: 11/07/2019
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(1ng/kg)
Monthly Average
Concentration Limits
(Class A Only)
(mg/kg)
Result
(ing/kg)
Arsenic
75
41
13.4
Cadmium
85
39
<0.599
Copper
4,300
1,500
194
Lead
840
300
13.0
Mercury
57
17
<0.0910
Molybdenum
75
n/a
2.8
Nickel
420
420
12.1
Selenium
100
100
<2.99
Zinc
1 7,500
2,800
160
b. For Surface Disposal Unit (land Ill : Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: L__j and Date of analysis:
Distance from Disposal
Unit to Boundary to
Closest Property Line
(Ineters, check one)
Arsenic
Ong/kg)
Chromium
(Inglkg)
Nickel
(mg/kg)
❑ > 0 but <25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
.39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (ingAg)
FORM: RSC 06-16 Page 3 of 5

5. NutrientlMicronutrient Determination: Complete the following:
a. Total solids: 17.6 %.
b. Fill in the following table with the results of the latest analyses (i,e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Wa oint Analytical and Date of analysis: 11/07/2019
Parameter
Result
(mg/kg)
Aluminum
166,000
Ammonia -Nitrogen
796
Calcium
1,870
Magnesium
599
Nitrate -Nitrite Nitrogen
<27.7
pH (Standard Unit)
6.8
Phosphorus
1,650
Potassium
272
Sodium
354
Total Kjeldahl Nitrogen
19,200
c. Using the results listed in Item 1I. 5b. above, calculate the sodium adsorption ration (SAR): 0.74
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 20 %. This
rate is a (check one): E default value, or ❑ actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals: Water Treatment Process
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method First (V) Year PAN Five -Year
Maximum Adjusted PAN
(ing/kg) (mg/kg)
Surface 4,127 6,974
Injection/Incorporation 4,525 7,372
Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses: No4
FORM: RSC 06-16 Page 4 of 5

7. Path o en Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For DistributionlLandApplication of Class A or Equivalent:
❑ A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
❑ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
Alternative 1 [15A NCAC 02T. I 106(b)(3)(A)] - Time/Temperature Compliance.
Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
Alternative 3 [15A NCAC 02T. 1106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 4 [15A NCAC 02T. 1 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
0 Alternative 5 [15A NCAC 02T. 1106(b)(3)(E)-(K)] - Process to Furtber Reduce Pathogens (PFRP).
Specify one: ❑ composting, ❑ heat drying, ❑ heat treatment,
❑ thermophilic aerobic digestion, ❑ beta ray irradiation,
❑ gamma ray irradiation, or ❑ pasteurization.
b. For LandAppileation of Class B:
EJ Alternative 1 [15A NCAC 02T. 1 106(c)(I )] - Fecal Cotiform Density Demonstration.
Alternative 2 [15A NCAC 02T.I 106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: ❑ aerobic digestion, ❑ air drying, ❑ anaerobic digestion,
❑ composting, or ❑ lime stabilization.
c. For Surface Disposal:
FJ Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above.
El Exempt - If Daily Cover Alternative is chosen in Item 1I.8. below [15A NCAC 02T. I 106(a)(2)].
E] Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
❑ Alternative I [15A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
❑ Alternative 2 [15A NCAC 02T.I 107(a)(2)1 - 40-Day Bench Scale Test (Anaerobic Digestion).
❑ Alternative 3 [15A NCAC 02T.1107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
[] Alternative 4 [15A NCAC 02T.1107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
❑ Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
❑ Alternative 6 [15A NCAC 02T.1107(a)(6)] - Alkaline Stabilization.
❑ Alternative 7 [15A NCAC 02T. 1 107(a)(7)] - Drying of Stabilized Residuals.
❑ Alternative 8 [15A NCAC 02T. 1 107(a)(8)] - Drying of Unstabilized Residuals.
Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection.
Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.1107(b)(2)].
M Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

VICINITY MAP SYNAGRO
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FILENAME: ocoba HOOt 460NIaaN PLOTCATE: 3B1 M2

Quantitative Justification Lake Kilby WTP
Lake Kilby WTP
Between the years of 2018 and 2019, an average of 2,241 dzy tons of residuals
have been land applied from the Lake Kilby WTP. It is requested that the Lake Kilby
WTP be permitted to land apply a maximum of 3200 dry tons per year to account for any
plant fluctuations or future maintenance cleanouts.
Dry tons land applied between 2018 and 2019.
Year
Dry Tons
2018
2335.2
2019
2148.4

Residuals Sampling Plan
Synagro Residuals Land Application for WQ0035207
Lake Kilby Water Treatment Plant
Nutrients and Metals Analysis
• Sampling Point: Storage Lagoon
Sampling Frequency: 6x/yr
• Sample Type: Composite
• Lab: Waypoint Analytical
Pathogen Reduction (Not Required)
Vector Attraction Reduction (Not Required)
TCLP
• Sampling Point: Storage Lagoon
• Sampling Frequency: Annually
Sample Type: Composite
Lab: Summit Environmental Labs

VMICROBAC ®
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOG0139
Project Description
VA Landfill
For:
Michelle Thomas
Synagro
435 Williams CT
Baltimore, MD 21220
Project Manager
Alicia Walker
Friday, July 17, 2020
Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories, Review and compilation of
your report was completed by Microbac Laboratories Inc., - Marietta, OH. If you have any questions, comments, or require
further assistance regarding this report, please contact your service representative listed above.
I certify that all test results meet ali of the requirements of the accrediting authority listed within this report. Analytical results are
reported on a 'as received' basis unless specified otherwise. Analytical results for solids with units ending in (dry) are reported
on a dry weight basis. A statement of uncertainty for each analysis is available upon request. This laboratory report shall not be
reproduced, except in full, without the written approval of Microbac Laboratories. The reported results are related only to the
samples analyzed as received.
Microbac Laboratories, Inc.
158 Starlito Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

VMICROBAC`p
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
M000139
Synagro Project Name: VA Landfill
Michelle Thomas Project I PO Number: NIA
435 Williams CT Received: 07/02/2020
Baltimore, MD 21220 Reported: 0711712020
Sample Summary Report
Sample Name
Laboratory 1D
Client Matrix
Sample Type Sample Reain Sample Taken
Lab Received
Portsmouth -Lake Kilby
MOGO139-01
Solid
06/28/20 14:00
07/02/20 08:45
Portsmouth -Lake Kilby
MOG0139-02
Solid
06/28/20 14:00
07/02/20 08:45
Portsmouth -Lake Kilby
M0O0139-03
Solid
06/28/20 14:00
07/02/20 08:45

VMICROBAC"
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
M000139
Analytical Testing Parameters
Client Sample ID: Portsmouth -Lake Kilby
Sample Matrix: Solid
Lab Sample ID: MOG0139-01
Collection Date: 0612812020 14:00
Inorganics Total
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
EPA 7.3.3.2
Reactive Cyanide
<10.0
10.0
mg/kg
1
Y1
07/07/20 0749
07107120 1502
APH
EPA 7.3.4.2
Reactive Sulfide
<100
100
mg/kg
1
Y1
o7107120 1708
07/07/20 1721
EPT
EPA 9045D
pH
7.6
S.U.
1
H4
07106120 1629
07106/20 1738
APH
EPA 9071BIEPA 9071B
Oil & Grease
<209
209
mg/kg
105
Y
07/09120 1310
07110/20 1110
JDH
EPA 909513
Free Liquid (Paint Filter Test)
Free Liquids
NA
1
07106/20 1636
07/06/20 1640
EPT
General Parameters
Result
RL
Units
Dilution
Note
Prepared
Analyzed
Analyst
ASTM D2216-10
Percent Solids
3.97
1.00
% (by wt.)
1
Y
07/06/20 1053
07/07120 0630
ERP
EPA 1030
Method Notes:
F1
lgnitability of Solids
<2.2
2.2
mmisec
1
07/06/20 0845
JDH
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

VMICROBAC°
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOG0139
Client Sample ID: Portsmouth -Lake Kilby
Sample Matrix: Solid
Lab Sample ID: M000139-02
Inorganics Total
EPA 13111EPA 1311
pH Final Leachate
pH Inital Leachate
Metals TCLP by AA
EPA 7470A
Mercury
Metals TCLP by 1CP
EPA 3015A1EPA 60108
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Collection Date: 06/2812020 14:00
Result RL Units
Dilution
Note
Prepared
Analyzed
Analy
5.0 S.U.
1
Y
07/06/20 1553
07/07120 0910
ARC
7.3 S.U.
1
Y
07/06/20 1553
07107120 0910
ARC
Result RL Units
Dilution
Note
Prepared
Analyzed
Analy
<0.00200 0.00200 mg1L
1
07108/20 0716
07108120 1148
TMM
Result
RL
Units
Dilution Note
<0.200
0.200
mglL
1
0.460
0.100
mg1L
1
<0.0200
0,0200
mg1L
1
<0.0500
0.0500
mg1L
1
<0.200
0.200
mglL
1
<0.350
0.350
mg1L
1
<0.100
0.100
mglL
1
Prepared Analyzed Analyst
07108/20 0636
07/08/21) 1336
KHL
07/08/20 0636
07/08/20 1336
KHL
07/08/20 0636
07/08120 1336
KHL
07/08/20 0636
07108/20 1336
KHL
(17/08120 0636
07/08/20 1336
KHL
07/08/20 0636
07/08/20 1336
KHL
o7108120 0636
07/08/20 1336
KHL
Volatile Organic Compounds TCLP
by GCMS
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
EPA 5030CIEPA 8260E
Benzene
<50.0
50.0
ug)L
10
071071201812
EEA
2-Butanone
<100
100
uglL
10
07/07120 1812
FEA
Carbon tetrachloride
<50.0
50.0
uglL
10
07107120 1812
EEA
Chlorobenzene
<50.0
50.0
ug1L
10
07107/201812
EEA
Chloroform
<50.0
50.0
ug1L
10
071071201812
EEA
12-Dichloroethane
<50.0
50.0
ug1L
10
07/07/20 1812
EEA
1,1-Dichloroethene
<50.0
50.0
ug1L
10
071071201812
EEA
Tetrachloroethene
<50.0
50.0
ug1L
10
07107/20 1812
EEA
Trichloroethene
<50.0
50.0
ug1L
10
071071201812
EEA
Vinyl chloride
<100
100
ug1L
10
07/07/20 1812
EEA
Surrogate: 4-Bromofluorobenzene
95.3
Limit: 86-115
% Rec
10
07/07/20 1912
EEA
Surrogate: Dibromofluoromethane
96.9
Limil: 86-118
% Rec
10
07/07/20 1812
EEA
Surrogate: 1,2-Dichloroethane-d4
97.5
Limit: 80-120
% Rec
10
07/07/20 1812
EEA
Surrogate: Toluene-d8
102
Limit: 88-110
% Rec
10
07107/20 1812
EEA
Herbicides TCLP by GCIEC❑
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
EPA 8151AIEPA 8151A
2,4,5-TP (Silvex)
<2.00
2.00
ug1L
1
07/09120 1600
07110120 2047
ECL
2,4-D
<20.0
20.0
ug1L
1
07109120 1600
07/10/20 2047
ECL
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800.373.4071 p I www.microbac.com

(!�iMICROBAC`
Microbac Laboratories Inc., -
Marietta, OH
CERTIFICATE OF ANALYSIS
MOG0139
Client Sample ID: Portsmouth -Lake Kiiby
Sample Matrix: Solid
Lab Sample ID: MOG0139-02
Collection Date: 06128/2020 14:00
Herbicides TCLP by GCIECD
Result RL Units
Dllution Note
Prepared
Analyzed
Analyst
Surrogate: 2,4-Dichloropenylacetic acid
53.0 Limit: 20-144 % Rec
1
07/09/20 1600
07110/20 2047
ECL
Pesticides TCLP by GCIECD
Result RL Units
Dilution Note
Prepared
Analyzed
Analyst
EPA 351 OCIEPA 8081A
alpha -Chlordane [2C]
40.500 0.500 uglL
1
07/07/20 0900
07108/20 1340
ECL
E;ndrin [2C]
<0.500 0.500 ug/L
1
07/07120 0000
07/08/20 1340
ECL
gamma Chlordane [2C]
<0.500 0.500 ug1L
1
07/07/20 0900
07/08120 1340
ECL
gamma-BHC (Lindane) [2C]
<0.500 0.500 uglL
1
07107/20 0900
07/08/20 1340
ECL
Heptachlor [2C]
<0.500 0.500 uglL
1
07/07/20 0900
07/08120 1340
ECL
Heptachlor epoxide [2C]
<0.500 0.500 ug1L
1
07/07120 0900
07/08/20 1340
ECL
Methoxychlor [2C]
<0.500 0.500 uglL
1
07/07120 0900
07/08/20 1340
ECL
Toxaphene [2C]
<10.0 10.0 ug1L
1
07/07120 0900
07108/20 1340
ECL
Chlordane (tech.) [2C]
<10.0 10.0 uglL
1
07107/20 0900
07/08120 1340
ECL
Surrogate: 2,4,5,6-Tetrachloro-m-xylene
120 Limit: 20A30 % Rec
1
07/07/20 0900
07/08120 1340
ECL
[2C]
Surrogate: Decachlorobiphenyl
72.6 Limit: 25-140 % Rec
1
07/07/20 0900
07/08/20 1340
ECL
(BZ-209) [2C]
Semivolatile Organic Compounds
TCLP by GCMS
EPA 3510CIEPA 8270C
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
2-Methylphenol
3-,4-Methylphenol
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Surrogate: 2-Fluorobiphenyl
Surrogate: 2-Fiuorophenol
Surrogate: Nitrobenzene-d5
Surrogate: Phenol-d5
Surrogate: p-Terphenyl-d14
Surrogate: 2,4,6-Tribromophonol
Result
RL
Units
Dilution Note
Prepared
Analyzed
Analyst
<50.0
50.0
ug1L
1
07/07/20 1115
07/07/20 1734
SCB
<50.0
50.0
uglL
1
07/07/20 1115
07/07120 1734
SCB
<50.0
50.0
ug/L
1
07107120 1115
07/07120 1734
SCB
<50.0
50.0
ug1L
1
07/07/20 1115
07/07/20 1734
SCB
<50.0
50.0
uglL
1
07/07/20 1115
07/07/20 1734
SCB
<50.0
50.0
uglL
1
07/07/20 1115
07/07120 1734
SCB
<50.0
50.0
uglL
1
07/07120 1115
07/07/20 1734
SCB
<50.0
50.0
ug1L
1
07/07/20 1115
07/07/20 1734
SCB
<250
250
uglL
1
07107/20 1115
071071201734
SCS
<250
250
uglL
i 03
07/07/20 1115
07/07/20 1734
SCB
<50.0
50.0
ug1L
1
07/07/20 1115
07/07/20 1734
SCB
<50.0
50.0
uglL
1
07/07/20 1115
07/07/20 1734
SCB
71.9
Limit: 43-116
% Rec
1
07/07/20 1115
07/07/20 1734
SCB
51.0
Limit: 19-119
% Rec
1
07/07/20 1115
07107/20 1734
SCB
75A
Limit: 35-114
% Rec
1
07/07/20 1115
07/07/20 1734
SCB
32.5
Limit: 10-120
% Rec
1
07/07/20 1115
07/07/20 1734
SCB
64.9
Limit: 10-130
% Rec
1
07/07/20 1115
07/07/20 1734
SCB
99.6
Limit: 22-142
% Rec
1
07107/20 1115
07/07/20 1734
SCB
Microhac Laboratories, Inc.
158 Starlite Drive i Marietta, OH 45750 1800.373.4071 p I www.mir-robac.com

�DMICROBAC@'
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOG0139
Client Sample ID: Portsmouth -Lake Kilby
Sample Matrix: Solid
Lab Sample ID: MOG0139-03 Collection Date: 06l28l2020 14:00
Inorganics ASTM D3987 Result RL Units Dilution Note Prepared Analyzed Analyst
EPA1664A
Oil & Grease <5.0 5.0 mg1L 1 07/14/20 0626 07/14/20 0801 JRH
Definitions
(by wt.): Percent by Weight
D1: Dilution was performed due to matrix interference.
F1: Did not ignite.
H4: The test was performed outside of the EPA recommended holding time of 15 minutes.
mglkg: Milligrams per Kilogram
mglL: Milligrams per Liter
mmisec: Millimeter per Second
NA: Not Applicable
Q3: LCS recovery is below acceptance limits. The reported value is estimated.
RL: Reporting Limit
S.U.: Standard Units
S7: Surrogate recovery is above acceptance limits.
uglL: Micrograms per Liter
ug1mL: Micrograms per Milliliter
Y: This analyte is not on the laboratory's current scope of accreditation.
Y1: Accreditation is not offered by the accrediting body for this analyte.
Cooler Receipt Log
Cooler ID: Default Cooler Temp: 3.2°C
Cooler Inspection Checklist
Ice Present or not required? Yes Shipping containers sealed or not required?
Yes
Custody seals intact or not required? Yes Chain of Custody (COC) Present?
Yes
COG includes customer information? Yes Relinquished and received signature on COG?
Yes
Sample collector identified on COC? Yes Sample type identified on COG?
Yes
Correct type of Containers Received Yes Correct number of containers listed on COC?
Yes
Containers Intact? Yes COC includes requested analyses?
Yes
Enough sample volume for indicated tests received? Yes Sample labels match COC (Name, Date & Time?)
No
Samples arrived within hold time? Yes Correct preservatives on COG or not required?
Yes
Chemical preservations checked or not required? Yes Preservation checks meet method requirements?
Yes
VOA vials have zero headspace, or not reed.? Yes
Project Requested Certification(s)
Microbac Laboratories Inc., - Marietta, OH
460187
Virginia Department of General Services
Microbac Laboratories, Inc.
158 Starlite Drive I Marietta, OH 45750 1800,373.4071 p i www.microbac.com

�VMICROBAC"
Microbac Laboratories Inc., - Marietta, OH
CERTIFICATE OF ANALYSIS
MOG0139
Report Comments
Samples were received in proper condition and the reported results conform to
applicable accreditation standard unless otherwise noted.
The data and information on this, and other accompanying documents, represents only the
sample(s) analyzed. This report is incomplete unless all pages indicated in the footnote are
present and an authorized signature is included. The services were provided under and
subject to Microbac's standard ferns and conditions which can be located and
reviewedat <https•IAvww.mkrobac.cam/standard-terms-conditions>.
Reviewed and Approved By:
Alicia Walker
Project Manager
Reported: 07117/2020 09:09
Microbac Laboratories, Inc.
158 Starlite Drive i Marietta, OH 45750 1800.373.4071 p i www.microbac.com

Inshvcuons for compleEng the Chain of Custody Record On back.
�PMICRO BAC Page Of
158 StarlKD Drive, Mariem Ohio 45750 Chain of Custody Record
--- ..
LProject information Turn Around Time CompiianceO Name: Portsmouth - Lake Kilby0Standard RUSH* Yes No
pahannDCk Blvd. Numher.Needed sy: Agency.nnock, VA 22560 PO:
Sampler Report Options QC pacakge
Contact ©Level I
Name: Allen Guilliams ❑ EDD
Name: Carolanne Whiteside Q Level II**
Phone: [phone] Email [cgwMhjteside 5 na ro.COm
Numder. SD4-466-5007 0 Level M**
❑ Fax
Email cwhiteside s na ro.cOm CertlD:— O Level Iv**
in
ate.+
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CD
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Client Sample ID
o
06128/24
ZOOPM
1 X
-Lake 1Silby
S
X
Comments
Sample Disposal [ X] Dispose asappropriate [ ] Return
t 1 Arcnwe
Recah�e,�,°alx'!+e�
_ _ _-
5ample 'Ely(signature) p d►Uneeias[5ldlon -
Da�iiFlme
-- — —
UP51 7/1/2020 0:00
Allen GuilliarnslSynagro
T1120 10:00Am
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ReceivedBy(signature)
1�$� �v
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page 1 of 1
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Please notify lab prior to drop off. '
— Surcharge May Apply to adO CC Packages Please send certificate of analysis to the following: Ctripp@synagro.r_om, and [e-mail] Rev 141512018
Matrix - Sludge 1 Soil

Tests required for VA/NC landfills
RCI
Flashpoint
Reactive Cyanide
Reactive Sulfide
Corrosivity test
—.Ignitability test
Paint Filter
Free Liquids
TCLP Metals
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
TCLP Mercu
Mercury
TCLP Pesticides
Chlordane, total
Toxaphene
Endrin
gamma BHC (Lindane)
Heptachlor
Heptachlor epoxide
Methox chlor
TCLP
1, 1-Dichloroethene
1, 2- Dichloroethane
MEK
Benzene
Carbon tetrachloride
Chlorobenzene
Chloroform
Tetrachlorethene
Trichloroethene
Vin 1 chloride
TCLP BNA
1, 4-Dichlorobenzene
2, 4, 5-Trichlorophenol
2, 4, 6-Trichlorophenol
Cresols, Total
Hexacloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorphenol
Pyridine
Oil & Grease
Oil & Grease, Total
Oil & Grease, Water Extract
TCLP Herbicides
2,4-D
2, 4, 5-TP
2,4-Denitrotoluene

&)MICROBAC-
Work Order #
� 1 COOLER TEMP >60 C LOG
Bottle 1 Bottle 2 Bottle 3 Bottle 4 Bottle 5 Bottle 6
SAMPLE ID °C °C °C °C °C °C
1 I
J%
it
PH Lat # pH Exceptions
SAMPLE ID Bottle 1 Bottle 2 Bottle 3 Bottle 4 Bottle 5 Bottle 6
— cap f
KVA I IV rd
I Tzrr-pirinNs.-
1
d
i
ONE
Document Control # 1957 AS NOTED Issued to: Document Master File
Last 04-10-2019 '

WayPAoint..
NALYTICAL
11/12/2019
Denali Water
Jeff Retzke
1001 Fraser Ave
Huntsville, AL, 35801
Ref: Analytical Testing
Report Number: 19-308-0006
Project Description: Lake Kilby WTP 2019 1 of 6
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www,waypointanalydcal.com
Dear Jeff Retzke:
Waypoint Analytical Virginia, Inc. received sample(s) on 11/4/2019 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
P.d. 00 6-7-
Pauric McGroary
Agron`amist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Pace 1 of 7

Waypoint,o
ANALYTICAL
Client: Denali Water
Project: Lake Kilby WTP 2019 1 of 6
Lab Report Number: 19-308-0006
Date: 11/12/2019
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 69509
Analyte: Aluminum
QC Batch No: L463362
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Calcium
QC Batch No: L463096
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Analyte: Iron
QC Batch No: L463096
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: L463362
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges_ No matrix interference is suspected.
Analyte: Sulfur
QC Batch No: L463096
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Paqe 2 of 7

Waypoint(D
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fex 804-271-6446
www.waypointanalytical.com
Sample Summary Table
Report Number: 19-308-0006
Client Project Description: lake Kilby VJTP 20191 of 6
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
SM-2540G
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
SW-7471B
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
5M-4500-NH3C-TKN
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
4500NO3F-2011
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
6010D
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
SM-4500-NH3C
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
9045D
WTN
69508
1 of 6
Solids
11/02/2019 10:00
11/04/2019
AOAC 955.01
WTN
WTN: Waypoint Analytical - TN, Memphis, TN
Paqe 3 of 7

r
7621 Whitepine Read, Richmond, VA 23237
Waypoint,
Main 804-743.9401 ° Fax [phone]
ANALYTICAL www.waypointanalyticahcam
07274
Denali Water
Jeff Retzke Project Lake Kilby WTP 2019 1 of 6
1001 Fraser Ave Information
Huntsville , AL 35801
Report Number :19-308-0006 REPORT OFANALYSIS
Lab No: 69508
Sample ID : 1 of 6
Report Date: 11/12/2019
Received : 11/04/2019
Pauric McGroary
Agronomist
Matrix: Solids
Sampled: 11/ 2/ 2019 10:00
Moisture
83.3
%
0.010
1 11/06/1917:12 ADM
SM-254OG
Selenium
<2.99
mg/Kg - dry
2.99
1 11/07/19 04:55 BKN
6010D
Total Solids
16.7
%
0.010
1 11/06/19 17:12 ADM
SM-254OG
Total Kjeldahl Nitrogen
19200
mg/Kg - dry
1500
1 11/11/19 09:00 JPJ ;M-4500-NH3C-TK1`
Phosphorus
1650
mg/Kg - dry
29.9
1 11/07/19 04:55 BKN
6010D
Potassium
272
mg/Kg - dry
29.9
1 11/07/19 04:55 BKN
6010D
Sulfur
15300
m9/Kg - dry
29.9
1 11/07/19 04:55 BKN
6010D
Calcium
1870
mg/Kg - dry
150
1 11/07/19 04:55 BKN
6010D
Magnesium
599
mg/Kg - dry
29.9
1 11/07/19 04:55 BKN
6010D
Iron
22600
mg/Kg - dry
29.9
1 11/07/19 04:55 BKN
6010D
Manganese
4960
mg/Kg - dry
29.9
10 11/08/19 10:52 BKN
6010D
Copper
194
mg/Kg - dry
1.50
1 11/07/19 04:55 BKN
6010D
Organic N
16400
mg/Kg - dry
1500
I
1 11/11/19 09:001 DH
CALCULATION
Nitrate+Nitrite-N
<27.7
mg/Kg - dry
27.7
1 11/06/19 14:23 ZBD
4500NO3F-2011
Nickel
12.1
mg/Kg - dry
1.50
1 11/07/19 04:55 BKN
6010D
Mercury
<0.0910
mg/Kg - dry
0.0910
1 11/07/19 12:10 TJS
SW-74718
pH
6.8
S.U.
1 11/08/19 05:47 ISL
9045D
Calcium Carbonate Equivalent
14.7
% - dry
0.1
1 11/08/19 13:43 DXT
AOAC 955.01
Total Volatile Solids
45.8
%
0.010
1 11/06/19 17:12 ADM
SM-2540G
Qualifiers/
Outside QC Limit
B
Analyte detected in blank
Definitions
C
GCMS Confirmation Analysis
E
Result above cal range
g
GGA Outside QC Limits
H
Beyond holding time
J
Estimated value
M
Minimum value
NA
Not on Scope of Accreditation
NC
Not confirmed
Q
RPD >400% dual column results
T
Sample exhibits toxicity
U
Unconfirmed
Refer to cover letter.
Paqe 4 of 7

Waypoeint
7621 Whitepine
Road, Richmond, VA 23237
Main 804-743-9401 ° Fax $04-272-6446
ANALYTICAL
www.waypointanalytical.com
07274
Denali Water
]off Retzke
Project
Lake Kilby
WTP 2019 1
of 6
Report Date : 11/12/2019
1001 Fraser Ave
Information :
Received : 11/04/2019
Huntsville , AL 35801
Pam« or 60wr
Pauric McGroary
Report Number: 19-308-0006
REPORT OF ANALYSIS
Agronomist
Lab No: 69SOS
Matrix:
Solids
Sample ID : 1 of 6
Sampled: 11/2/2019 10:00
Test
Results
Units
MQL
DF
Date I Time
By Analytical
Analyzed
Method
Ammonia Nitrogen
796
mg/Kg - dry
599
1
11/11/19 14:30
3P3 SM-4500-NH3C
Aluminum
166000
mg/Kg - dry
299
10
11/08/19 10:52
BKN 6010D
Arsenic
13.4
mg/Kg - dry
2.99
1
11/07/19 04:55
BKN 6010D
Cadmium
<0.599
mg/Kg - dry
0.599
1
11/07/19 04:55
8KN 6010D
Chromium
138
mg/Kg - dry
1.50
1
11/07/19 04:55
BKN 6010D
Lead
13.0
mg/Kg - dry
1.80
1
11/07/19 04:55
BKN 6010❑
Molybdenum
2.80
mg/Kg - dry
1.50
1
11/07/19 04:55
BKN 6010D
Sodium Absorption Ratio
0.74
1
CALCULATION
Sodium
354
mg/Kg - dry
150
1
11/07/19 04:55
BKN 6010D
Zinc
160
mg/Kg - dry
7.49
1
11/07/19 04:55
BKN 6010D
Qualifiers/ B Analyte detected in blank H Beyond holding time
Definitions
Paae 5 of 7

(D
WayPAo�ntM
NALYTICAL
7621 whitepine Road, Richmond, VA 23237
Main 804-743.9401 ° Fax 804-271-&M6
www.waypointanalytical.com
Cooler Receipt Form
Customer Number: 07274
Customer Name: Denali Water
Report Number: 19-308-0006
Shipping Method
Fed Ex US Postal Lab
UPS Client Courier
Other
Thermometer ID:
Shipping container/cooler uncompromised?
Yes
No
Number of coolers received
1
Custody seals intact on shipping container/cooler?
Yes
No
0 Not Required
Custody seals intact on sample bottles?
Yes
No
0 Not Required
Chain of Custody (COC) present?
Yes
No
COC agrees with sample label(s)?
Yes
No
COC properly completed
Yes
No
Samples in proper containers?
Yes
No
Sample containers intact?
0 Yes
No
Sufficient sample volume for indicated test(s)?
0 Yes
No
All samples received within holding time?
0 Yes
No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as coaling
process had begun.
Yes
• No
Water - Sample containers properly preserved
Yes
No
0 NIA
Water - VOA vials free of headspace
Yes
No
• NIA
Trip Blanks received with VOAs
Yes
No
NIA
Soil VOA method 5035 — compliance criteria met
Yes
No
NIA
High concentration container (48 hr) Low concentration EnCore samplers (48 hr)
High concentration pre -weighed (methanol -14 d) Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or Instructions included?
Yes
0 No
Comments.
Signature: Brandi Watson Date & Time: L11I04/2019 14:32:25 1
Paoe 6 of 7

SAMPLE TRA
f, 7621 Whilcptnc Rand Richmond VA 23237
91305-0006
4�1111 1�11llil�l■I���I�If111� 07274
Lake 1(1itm WTP 2319 r el 6
►DY
!�ajaleastcm,cam
Account#
Submitted By Charge To
Copy To
Jeff Retzke/Denali Water PO: DEW
jeff.retzkeedenaliwater.com
35 Refreshment Place
aeff's cell: 256.503.4300
Decatur, AL 35601
Project Lake Kilby WTP 2019 la62a of 6
Sam le Information
Lab Number
Collection inform Ilion
Container IMormallon
Please Check Dashed Testa
Sample 1D
(Lab Use
Number
503
Nitrogen
Volatile
only)
Type
Dale
Time
ofBolfles
Typo
Volume
SLt
SL2
Metals
Series
PH
CCE
Ag
CI
Sollda
Crthers
1d
..,,C
Grob
X
1
_Glass
x
Oa
x—.pint
standard Cwpoa
v/Aluminum, CCE
1 ,'
composite
1
�/
Qr0
— Plastic
_GI
and 3.h.R,
Za
x Grab
1'.t'�-J
i�
t
Gloss
X plastic
oz
—xnt pi
Sarno an above
Com sells
— Grob
Glass
— oz
_
Plastic
—pint
Composite
—
1
— Grab
Glass
— oz
_
Pfaetic
mint
II shed 01t5gasturelDate
Time
Recelved By: SI nature
Dale
Time
i
Teat Peck- a Da ils
Special Instructions or Remarks
81,1s Total Solids (Moisfurc)'roud Kieldehl Niupgcp, Phosphorus and Potsi mm
SL2: Hssic Test SLI plus Sulfur, Calcium, Magnesium,Sodium, Iran, Aluminum, Manganese, Copper And Zinc
503 Mistalic Arsenic, Cadmium, Chromium, Mercury, Molybdenum. Lead. Nickel. Selenium.
(Capper & Zinc Included In SI2)
NhrMeR Series: Tolnl K}eldnhl. Ammanau n. Nnmle & Organic Nurogen.
CCE; Coldum Carbonate Equivalent or Total neulralfzation Value (For Lime Treated Sludfla)