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HomeMy WebLinkAboutNCG030134_DMR_20200221 Thermo Fi r SCI E. NTI FIC February 21, 2020 Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Stormwater Analytical Monitoring Results for Thermo Fisher Scientific, LLC I have attached the analytical monitoring results from stormwater sampling that was collected on February 5, 2020 at Thermo Fisher Scientific, LLC's four outfalls. Per our General Storm Water Permit No. NCG03000 requirements of monthly monitoring for applicable parameters during a storm event, I have sampled each outfall for copper, zinc, pH, lead,TSS, and Non-Polar Oil/Grease/TPH. Results show that zinc at one of the four outfalls was above the benchmark value, as noted in Table 3 of the general storm water permit.All other results were below the benchmark values. We have implemented a Tier Three response for the site and Thermo Fisher Scientific, LLC has notified the Asheville Regional Office.Thermo Fisher Scientific, LLC is currently working with an environmental consultant to help achieve compliance with the benchmark values set forth in the facility's storm water permit. I have attached the completed Monitoring Report containing the monitoring results from the four outfalls. If you have any questions, please feel free to contact me at 828-658-2845. Jeremy Putnam Sr. EHS Manager Attachments: 1 Stormwater Discharge Monitoring Report for North Carolina Division of Energy, Mineral and Land Resources General Permit No. NCG030000 Date submitted: 02/21/2020 CERTIFICATE OF COVERAGE NO. NCG030134 SAMPLE COLLECTION YEAR SAMPLE PERIOD _Jan-June July-Dec FACILITY NAME:Thermo Fisher Scientific(Asheville) LLC Or X Monthly: February COUNTY: Buncombe DISCHARGING TO CLASS OR* n HQW [X Trout n PNA PERSON COLLECTING SAMPLES:Jeremy Putnam, EHS nZero-flow [Hater Supply I ISA LABORATORY: Pace Analytical Lab Cert.# Other Comments on sample collection or analysis: PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 - Part A: Stormwater Benchmarks and Monitoring Results INo discharge this period?' Non-Polar O&G/ Date Sample 24-hour rainfall pH, Total Toxic Outfall No. Collected) amount, Total Suspended Solids Standard units Total Copper Total Lead Total Zinc Total Petroleum Hydrocarbons Organics5 (mo/dd/yr) Inches; Benchmarks - - 100 mg/L or 50 mg/L4 6.0—9.0 0.010 mg/L 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L Parameter Code - 46529 C0530 00400 01119 01051 01094 00552 78141 Outfall 1 02/05/2020 0.6 5 6.93 <0.005 <0.005 .121 <5 N/A Outfall 2 02/05/2020 0.6 2.6 6.98 .0059 <0.005 .101 <5 N/A Outfall 3 02/05/2020 0.6 8.9 6.45 <0.005 <0.005 0.0349 <5 N/A Outfall 4 02/05/2020 0.6 3.5 6.32 <0.005 <0.005 0.16 <5 N/A = Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 2 For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here. 3 The total precipitation must be recorded using data from an on-site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. See General Permit, Section B,Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies. s Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11;for semiconductor manufacture use the definition as found in 40 CFR 469.12;for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray tube manufacture use the definition found in 40 CFR 469.31). Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 1 of 3 Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities electing to employ the TTO monitoring waiver,the discharger shall sign the following certification statement: "Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics(TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or stormwater runoff has occurred since filing the last discharge monitoring report.I further certify that this facility is implementing the all the provisions of the solvent management plan included in the Stormwater Pollution Prev Plan. Name(Print name) Print title) al a'a, Signat re Date Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non-detect, ND, or other similar non-numerical format. When results are below the applicable limits, they must be reported in the format, "<XX mg/L",where XX is the numerical value of the detection limit, reporting limit, etc. in mg/L. Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month. No discharge this period?2 Outfall No. Date Sample Collected) 24-hour rainfall amount, New Motor Oil or Non-Polar O&G/Total Total Suspended (mo/dd/yr) Inches; Hydraulic Oil Usage Petroleum Hydrocarbons Solids Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/L4 Parameter Code - 46529 NCOIL 00552 C0530 Footnotes from Part A also apply to Part B Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text. Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 2 of 3 FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES X NO IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE? YES NO REGIONAL OFFICE CONTACT NAME: Ms. Laura Herbert (Asheville Regional Office) Mail an original copy of this DMR,including all"No Discharge"reports, within 30 days of receipt of the lab results(or at end of monitoring period in the case of"No Discharge"reports)to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief, true, accurate, and complete. I a away hat th re significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." C )N\ '\ Signature of Permittee Date • Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Pace Analytical Services,LLC 2225 Dr aceAnalytical Asheville,RiversideNC28 04 NC 28804 1 www.pacelabs.com (828)254-7176 J i February 19, 2020 Mr. Jeremy Putnam Thermo Electron Corp. 275 Aiken Road Asheville, NC 28804 RE: Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Dear Mr. Putnam: Enclosed are the analytical results for sample(s) received by the laboratory on February 06, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Chris Derouen christopher.derouen@pacelabs.com (828)254-7176 Project Manager Enclosures _ REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. '� ® Y� Page 1 of 12 Pace Analytical Services,LLC aceAnalytical 2225 Riverside Dr. P`,, Asheville,NC 28804 www.pacelabs.corn (828)254-7176 CERTIFICATIONS Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Pace Analytical Services Charlotte 9800 Kincey Ave.Ste 100, Huntersville,NC 28078 South Carolina Certification#:99006001 Louisiana/NELAP Certification#LA170028 Florida/NELAP Certification#:E87627 North Carolina Drinking Water Certification#: 37706 Kentucky UST Certification#:84 North Carolina Field Services Certification#:5342 Virginia/VELAP Certification#:460221 North Carolina Wastewater Certification#: 12 Pace Analytical Services Asheville 2225 Riverside Drive,Asheville, NC 28804 North Carolina Wastewater Certification#:40 Florida/NELAP Certification#: E87648 South Carolina Certification#:99030001 Massachusetts Certification#: M-NC030 Virginia/VELAP Certification#:460222 North Carolina Drinking Water Certification#:37712 REPORT OF LABORATORY ANALYSIS This reporl shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 2 of 12 Pace Analytical Services,LLC ii",PaceAnalytical 2225 Riverside Dr. Asheville,NC 28804 www.pacelabs.com (828)254-7176 f3 SAMPLE ANALYTE COUNT Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92463900001 1-1,2,3 EPA 1664B WAM 1 PASI-C EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A SM 2540D-2011 CJL 1 PASI-A 92463900002 2-1,2,3 EPA 1664B WAM 1 PASI-C EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A SM 2540D-2011 CJL 1 PASI-A 92463900003 3-1,2,3 EPA 1664B WAM 1 PASI-C EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A SM 2540D-2011 CJL 1 PASI-A 92463900004 4-1,2,3 EPA 1664E WAM 1 PASI-C EPA 200.7 Rev 4.4 1994 RDT 3 PASI-A SM 2540D-2011 CJL 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 3 of 12 Pace Analytical Services,LLC 71.:" 2225 Riverside Dr. aceAnalytical Asheville,NC 28804 , www.pacelabs.com (828)254-7176 i ANALYTICAL RESULTS Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Sample: 1-1,2,3 Lab ID: 92463900001 Collected: 02/05/20 10:00 Received: 02/06/20 09:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM,TPH Analytical Method:EPA 1664B Total Petroleum Hydrocarbons ND mg/L 5.0 1 02/19/20 09:03 200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:24 7440-50-8 Lead ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:24 7439-92-1 Zinc 121 ug/L 10.0 1 02/18/20 01:01 02/18/20 22:24 7440-66-6 2540D Total Suspended Solids Analytical Method:SM 2540D-2011 Total Suspended Solids 5.0 mg/L 2.5 1 02/07/20 18:03 Sample: 2-1,2,3 Lab ID: 92463900002 Collected: 02/05/20 10:15 Received: 02/06/20 09:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM,TPH Analytical Method:EPA 1664E Total Petroleum Hydrocarbons ND mg/L 5.0 1 02/19/20 09:03 200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper 5.9 ug/L 5.0 1 02/18/20 01:01 02/18/20 22:34 7440-50-8 Lead ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:34 7439-92-1 Zinc 101 ug/L 10.0 1 02/18/20 01:01 02/18/20 22:34 7440-66-6 2540D Total Suspended Solids Analytical Method:SM 2540D-2011 Total Suspended Solids 2.6 mg/L 2.5 1 02/07/20 18:03 Sample: 3-1,2,3 Lab ID: 92463900003 Collected: 02/05/20 10:30 Received: 02/06/20 09:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM,TPH Analytical Method: EPA 1664E Total Petroleum Hydrocarbons ND mg/L 5.0 1 02/19/20 09:03 200.7 MET ICP Analytical Method:EPA 200.7 Rev 4.4 1994 Preparation Method:EPA 200.7 Rev 4.4 1994 Copper ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:37 7440-50-8 Lead ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:37 7439-92-1 Zinc 34.9 ug/L 10.0 1 02/18/20 01:01 02/18/20 22:37 7440-66-6 2540D Total Suspended Solids Analytical Method:SM 2540D-2011 Total Suspended Solids 8.9 mg/L 2.5 1 02/07/20 18:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 12 Pace Analytical Services,LLC aceAnalytical 2225 Riverside Dr. i _t.:„ Asheville,NC 28804 www.pacelabs.com (828)254-7176 t 1 ANALYTICAL RESULTS Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Sample: 4-1,2,3 Lab ID: 92463900004 Collected: 02/05/20 10:45 Received: 02/06/20 09:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 1664 SGT-HEM,TPH Analytical Method:EPA 1664B Total Petroleum Hydrocarbons ND mg/L 5.0 1 02/19/20 09:03 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:40 7440-50-8 Lead ND ug/L 5.0 1 02/18/20 01:01 02/18/20 22:40 7439-92-1 Zinc 160 ug/L 10.0 1 02/18/20 01:01 02/18/20 22:40 7440-66-6 2540D Total Suspended Solids Analytical Method:SM 2540D-2011 Total Suspended Solids 3.5 mg/L 2.5 1 02/07/20 18:03 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 12 Pace Analytical Services,LLC 2225 Riverside Dr. („)liceAnalyticar Asheville,NC 28804 www.pacelabs.com (828)254-7176 1 QUALITY CONTROL DATA Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 QC Batch: 525853 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM,TPH Associated Lab Samples: 92463900001,92463900002,92463900003,92463900004 METHOD BLANK: 2810601 Matrix: Water Associated Lab Samples: 92463900001,92463900002,92463900003,92463900004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 5.0 02/19/20 09:03 LABORATORY CONTROL SAMPLE: 2810602 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 20 14.7 74 64-132 MATRIX SPIKE SAMPLE: 2810603 92464393001 Spike MS MS %Rec Parameter Units Result Conc. Result %Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L ND 20 6.1 25 64-132 M1 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 12 Pace Analytical Services,LLC Dr. 1/1/..:PaceAnalytical 2225 RiversNC2e 04 Asheville,NC 28804 f www.pacelabs.com (828)254-7176 i QUALITY CONTROL DATA Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 QC Batch: 525571 Analysis Method: EPA 200.7 Rev 4.4 1994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Associated Lab Samples: 92463900001,92463900002,92463900003,92463900004 METHOD BLANK: 2809393 Matrix: Water Associated Lab Samples: 92463900001,92463900002,92463900003,92463900004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper ug/L ND 5.0 02/18/20 22:18 Lead ug/L ND 5.0 02/18/20 22:18 Zinc ug/L ND 10.0 02/18/20 22:18 LABORATORY CONTROL SAMPLE: 2809394 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Copper ug/L 500 501 100 85-115 Lead ug/L 500 482 96 85-115 Zinc ug/L 500 460 92 85-115 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2809395 2809396 MS MSD 92463900001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec % Rec Limits RPD Qual Copper ug/L ND 500 500 526 513 105 102 70-130 3 Lead ug/L ND 500 500 514 502 103 100 70-130 3 Zinc ug/L 121 500 500 621 604 100 97 70-130 3 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2809397 2809398 MS MSD 92464074001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Copper ug/L <5.0 500 500 518 522 103 104 70-130 1 Lead ug/L <5.0 500 500 484 492 97 98 70-130 2 Zinc ug/L <10.0 500 500 475 480 94 95 70-130 1 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 12 Pace Analytical Services,LLC 2225 Riverside Dr. .::131eAnalytical Asheville,NC 28804 www.pacelabs.com (828)254-7176 QUALITY CONTROL DATA Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 QC Batch: 523820 Analysis Method: SM 2540D-2011 QC Batch Method: SM 2540D-2011 Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92463900001,92463900002,92463900003,92463900004 METHOD BLANK: 2800614 Matrix: Water Associated Lab Samples: 92463900001, 92463900002,92463900003,92463900004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 02/07/20 18:02 LABORATORY CONTROL SAMPLE&LCSD: 2800615 2800628 Spike LCS LCSD LCS LCSD %Rec Max Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers Total Suspended Solids mg/L 251 236 252 94 100 90-110 7 25 SAMPLE DUPLICATE: 2800629 92463620004 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 286 279 3 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 12 Pace Analytical Services,LLC Dr. aceAnalytical Asheville,RiversideNC28 04 NC 28804 ((,, www.pacelabs.com (828)254-7176 QUALIFIERS Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 DEFINITIONS DF-Dilution Factor,if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit. TNTC-Too Numerous To Count J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S-Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in 5W846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. LABORATORIES PAST-A Pace Analytical Services-Asheville PAST-C Pace Analytical Services-Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 12 Pace Analytical Services,LLC 2225 Riverside Dr. (.„,filiceAnalytical Asheville,NC 28804 www.pacelabs.com (828)254-7176 t i QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: MONTHLY 2-6-2020 Pace Project No.: 92463900 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92463900001 1-1,2,3 EPA 1664E 525853 92463900002 2-1,2,3 EPA 1664E 525853 92463900003 3-1,2,3 EPA 1664E 525853 92463900004 4-1,2,3 EPA 1664B 525853 92463900001 1-1,2,3 EPA 200.7 Rev 4.4 1994 525571 EPA 200.7 Rev 4.4 1994 525597 92463900002 2-1,2,3 EPA 200.7 Rev 4.4 1994 525571 EPA 200.7 Rev 4.4 1994 525597 92463900003 3-1,2,3 EPA 200.7 Rev 4.4 1994 525571 EPA 200.7 Rev 4.4 1994 525597 92463900004 4-1,2,3 EPA 200.7 Rev 4.4 1994 525571 EPA 200.7 Rev 4.4 1994 525597 92463900001 1-1,2,3 SM 2540D-2011 523820 92463900002 2-1,2,3 SM 2540D-2011 523820 92463900003 3-1,2,3 SM 25400-2011 523820 92463900004 4-1,2,3 SM 2540D-2011 523820 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:02/19/2020 03:44 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 12 CHAIN-OF-CUSTODY Analytical Request Document LAB USE WO# : 92463900 imberor cm Pace Analytical Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields III III il III 1 III III III fo -a Company: Billing Information: II hext/Vl s e r 92463900 co Address: Containe. - 2'l S Ai geo. l I 1 tit 3 Re ort To: Email To: 1 ' Preservative types:(1)nitric acid,(2)sulfuric acid,13)hydrochloric add,(4)sodium hydroxide,(5)zinc acetate, je ,{., ,f PULA-n ek,fY'1 Y V l./i i-�� `G-44` E''v cl ''C��W (C)methanol,(7)sodium bisulfate,(8)sodium thiosutfate,(9)hexane (A)ascorbic acid,(B)ammonium sulfate, Copy To: 3 4y '.Cite Collection Info/Address: t (C)ammonium hydroxide.(D)TSP,NHUnpreserved,(0)Other _.._.. .14 Ai(_27n T-t, Analyses Lab Profile/Line: Customertt Project Name/Number: State: County/City: Time Zone Collected: x.uo Sample Receipt Checklist: �.lah;,t„ftt�y(, 2..c. _i..J SW fVC/rircitt5tft^ I )PT) )MT( )CT [,4 ET Custody Seals Present/Intact Y 1 NA :Phone:t2.6.1n5 -'2 4rs Site/Facility ID tf: Compliance Monitoring? q S.- Custody Signatures Present Y ti NA Email: (Y[ Yes [ )No itlCollector Signature Present " N NA Bottles Intact �' N NA Collected By(print): Purchase Order if: DW PWS ID II: '� Q/ Correct Bottles ( N NA �^y Quote ft: DW Location Code: t, Sufficient Volume N NA y Samples Received on Ice t N NA_ Co 'clod Fay'sii;naturc): Turnaround Date Required: Immediately Packed on Ice: �„ +a VOA - Headspace Acceptable Y H A t/ ,,,,. '4, f USDA Regulated Soda 7i1'� ,A [�(jYes [ 1No n}w Samples in Holding Time �ftd N _ Sample Disposal: Hush: Field Filtered(if applicable): ( ✓ l - ?9 Residual Chlorine Present. y N ft). I I Dispose as appropriate ( J Return ( I Same Day ( J Next Day [ 1 Yes ( )No 'V ci Strips: f I Archive.__rn ...._ [ I2 Day [ )3 Day [ Ill Day [ J 5 Day "+ Sample pits Acceptable NA I I Hold:_ - (Expedite Charges Apply) Analysis: _.__�_. Q �';1" pH Strips t _ a� „_,_,,LT. N Ec f7 Sr— ( r Sulfide Present Y rf "Matrix Codes(Insert in Matrix box below):Drinking Water(DW),Ground Water(GW),Wastewater(WW), . }--" 9 Lead Acetate Strips: ___ ____ \f Product(P),Soil/Solid(SL),Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) J LAB USE ONLY: Comp/ Collected(or Res II of r "� `t r� Lab Sample // / Comments: Composite End ;„ 5. Customer Sample ID Matrix" Grab Composite Start) Cl Ctns q�� /sq �y'"S Date Time Date Time ,-l !o �j 0 1-i o - .C7PA _2/s io-00 i 1 1 1 .� —0 0 1 i - !O,t3U 1 .,14._> 2-2.. F 10:15 i 2.- 3 i 10:IS 1 ..� 3 _I i0:'p ) t 1 3 > i 0:3i) i • ---Th- --ct-zif y-1 1 i0=°f i i t Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: SeD Blue Dry None SHORT HOLDS PRESENT(<72 hours): Y N/A Lab Sample Temperature Info: �,,,I Temp Blank Recei f4:�- Y tbi NA Packing Material Used: i/'; b1 Lab Tracking if: 2 4 2 7 0 7 Therm 1DM ',�, /Jb�) (C{J '' Cooler 1 Temp Uponl_ Receipt: �.CbC Samples received via: Cooler 1 Therm Corr.Factor: """`oC Radchem sample(s)screened(<500 cpm): Y N NA FEpEX UPS Courier Pace Courier Cooler 1 Corrected Temp: .(7 oC Re-fil . fished by/Company:(Signature) Date/Time: Received by/Company:(Signature) DateJTime: t MT L LAB USE ONLY Comments: - ' . Oalc)•,, r sr;—. � G tom_ //?Grp J c ��/- �J Table if: �J^- �7!/.x►''J _.G f� Acctnum: Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: Template: Trip Tri Blank Received: Y NA HCL McOH TSP ther Prelogin: Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Conforma ): Page: PB: YES / i. of: __ ei CHAIN-OF-CUSTODY Analytical Request Document LAB USE ONLY-Aff WO# ; 92463900 Pace Analytical N Chain-of-Custody is a LEGAL DOCUMENT-Complete all relevent fields PM: CD! Due Date: 02/20/20 i,AlCompany: i J ``Billing Information: ALL! CLIENT: 93-Thermo a y ��W V- S`� `o�"�� ' PAl Container Presery Address• y y 2-fi t`-t-tA. i J , U 1 1 1 1 1 1 1 Reriort To:"",�,4 /� y, Email To: { ,s '.Preservative Types:(I)nitric.acid,(2)sulfuric acid,(3)hydrochloric acid,(4)sodium hydroxide,(5)zinc acetate, Je r et ev t Yi,tr+vt(.L,i'a/L.. +�1i'✓2- •P,ktilitAAO r Vtt'Y'wtLh`S •f" ,s-s (6)methanol,Ill sodium bisulfate,(8)sodium thiusultate,(9)hexane.(A)ascorbic acid,(B)ammonium sulfate, Copy To. 1 Site Collection Info/Address: +� (C)ammonium hydroxide,(0)TSP,(U)Unpreserved,(0)Other _.,,,,,,,_._.- 2-1 S Ai � R4:J. Analyses Lab Profile/Line: Customer Project Name/Number: State: County/City: Time Zone Collected: Lab Sample Receipt Checklist: • Jlt((ikk6 - `, S Vu Nit./ t , (t.'i-. I IPTI IMT( ICT rET OZ� custody Seal:; Present/Intact Y 1} NA $2 Phone: i-Irict+—LF,i,-tS Site/Facility ION: Compliance Monitoring? ,'' 1?! Custody Signatures Present Y t1 NA Email: viYes I )No 'S'` Collector Signature Present N NA Bottles Intact N NA Collected By(print): Purchase Order N: DW PWS ID N: VI .(r.v. Correct Bottles N NA tttnnn...��,��A j'1 Sufficient Volume td NA f1.lt�LxA1� Quote II: DW Location Code: Samples Received on Ice N N .Coll -ted By( rgnature): Turnaround Date Required' Immediately Packed on Ice: VOA - fteadspace Acceptable X N Vt. USDA Regulated Soils N dA (t((Ves [ I No , Samples in holding Time N � Sample Disposal: Rush: Field Filtered(if applicable): .vl Residual Chlorine Present Y N k ( I Dispose as appropriate I )Return [ )Same Day I I Next Day ( I Yes I )No 7) Cl Strips: N,-,-...-- I I Archive: [ ]2 Day [ 13 Day I 14 Day I 15 Day LA t -#. Sample pH Acceptable N NA I 1 (ExpediteY _.. -- .- pH Strips: Hold: Analysis: �-.-..,�!7� Charges Apply) :A.- Sulfide Present Y N NA .Matrix Codes(Insert in Matrix box below):Drinking Water(OW),Ground Water(GW),Wastewater(WW), t •— Lead Acetate Strips: Product(P),Soil/Solid(SO,Oil(OL),Wipe(WP),Air(AR),Tissue(TS),Bioassay(B),Vapor(V),Other(OT) _ ,?—K LAB USE ONLY: Comp/ Collected(or Res N of Lab Sample # / Comments Customer Sample ID Matrix` Grab Composite Start) Composite End Cl Ctns Q C 472 Y.,/,.)1.7 tr Date Time Date Time a -z c i GR z/s 10r‘-15 1 I --0oy Customer Remarks/Special Conditions/Possible Hazards: Type of Ice Used: Wet Blue Dry None SHORT HOLDS PRESENT(<72 hours):, Y t N) N/A Lab Sample Temperature Info: /� / Temp Blank Recel ed Y�N NA Packing Material Used: eV r! - / Lab Tracking N: Therm IDN: ���6 1 J' oC 2 4 Samples received via: Cooler 1 Therm Corr.Factor:3-4 oC Radchem sample(s)screened(<500 cpm) Y N N Cooler 1 Temp Upon Receipt:FEDCX UPS Courier Pace Courier Cooler 1 Corrected Temp: -ti© oC iN‘lie'nquished by/Company:(Signature) Date/Time: Pig 1 Receivedbyy/Company:(Signature) /' Date/Time: , MTJL LAB USE ONLY Comments: �'� 1;& CI�.i, \44C4 r:s/`�� 4Ejr at -/ (iJ 2t /2O i Table N: / Acctnum• (//'1 Relinquished by/Company.(Signature) Date/Time: Received by/Company:(Signature) Date/Time: Template Trip Blank Received: Y N' NA Preingin: HCL McOH TSP Other Relinquished by/Company:(Signature) Date/Time: Received by/Company:(Signature) Date/Time: PM: Non Conformance(s): Page:___-, PE: YES / of: __.._.__.__.. FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES X NO IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE?YES NO REGIONAL OFFICE CONTACT NAME: Ms. Laura Herbert (Asheville Regional Office) Mail an original copy of this DMR,including all"No Discharge"reports, within 30 days of receipt of the lab results(or at end of monitoring period in the case of"No Discharge"reports)to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law,that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief,true, accurate, and complete. I are that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 0 gik --.., 3'\ )' '3 Signature of Permittee Date Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement: "Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics(TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or stormwater runoff has occurred since filing the last discharge onitoring report. I further certify that this facility is implementing the all the provisions of the solvent management plan included in the Stormwater Pollution Prevent' n an." Name(Print name) T' e(Print title) oa)a� Signature Date Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non-detect, ND, or other similar non-numerical format. When results are below the applicable limits, they must be reported in the format, "<XX mg/L",where XX is the numerical value of the detection limit, reporting limit, etc. in mg/L. Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses.See General Permit text. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month. INo discharge this period?' Outfall No. Date Sample Collected'. 24-hour rainfall amount, New Motor Oil or Non-Polar O&G/Total Total Suspended (mo/dd/yr) Inches' Hydraulic Oil Usage Petroleum Hydrocarbons Solids Benchmarks - - - 15 mg/L 100 mg/L or 50 mg/L° Parameter Code - 46529 NCOIL 00552 CO530 Footnotes from Part A also apply to Part B Note:If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses.See General Permit text. Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 2 of 3 Stormwater Discharge Monitoring Report for North Carolina Division of Energy, Mineral and Land Resources General Permit No. NCG030000 Date submitted: 02/21/2020 CERTIFICATE OF COVERAGE NO. NCG030134 SAMPLE COLLECTION YEAR SAMPLE PERIOD _Jan-June July-Dec FACILITY NAME:Thermo Fisher Scientific(Asheville) LLC Or X Monthly: January COUNTY: Buncombe DISCHARGING TO CLASS J ORW 1 HQW {trout fPNA PERSON COLLECTING SAMPLES:Jeremy Putnam, EHS REC FR/ D fZero- low fNater Supply I ISA LABORATORY: Pace Analytical Lab Cert.# Other Comments on sample collection or analysis: MAR 0 3 '2020 ENTRJ L FILES PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 - DWR SECTION Part A: Stormwater Benchmarks and Monitoring Results X No discharge this period?' Non-Polar O&G/ Date Sample 24-hour rainfall pH, Total Toxic Outfall No. Collected) amount, Total Suspended Solids Standard units Total Copper Total Lead Total Zinc Total Petroleum Organics5 Hydrocarbons (mo/dd/yr) Inches' Benchmarks - - 100 mg/L or 50 mg/14 6.0—9.0 0.010 mg/L 0.075 mg/L 0.126 mg/L 15 mg/L 1 mg/L Parameter Code - 46529 C0530 00400 01119 01051 01094 00552 78141 Outfall 1 Outfall 2 Outfall 3 Outfall 4 Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here. 3 The total precipitation must be recorded using data from an on-site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. See General Permit, Section B, Table 1 to identify the especially sensitive receiving water classifications where the more protective benchmark applies. 5 Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11;for semiconductor manufacture use the definition as found in 40 CFR 469.12;for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray tube manufacture use the definition found in 40 CFR 469.31). Permit Date: 11/1/2018-05/31/2021 SWU-245, last revised 11/1/2018 Page 1 of 3