NC0004961_Additional Information Received_20170815

V of NG Y.
Julie Grzyb, Supervisor
Complex NPDES Permitting Unit
NC Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
August 15, 2017
RECEIVED/NCDEQjDWR
AUG 17..1017
Water Quality
Permitting section
Subject: Submittal of analytical results
AOW's identified during Spring evaluation
Duke Energy Facilities
Duke Energy has completed the Spring 2017 semi-annual Area of Wetness (AOW) inspections
at it NC facilities. As required in the Plan for Identification ofNew Discharges (DIPs) for the
various facilities, the spring inspections were completed during the months of April and May.
In completing those inspections, new areas of wetness were identified at five of the inspected
facilities. Follow-up AOW sampling occurred, where applicable, in accordance with the
Standard Operating Procedure for Seep Sampling, prepared by Duke Energy (March 24, 2016).
Specific details for the five sites with newly identified AOW's are provided below along with
attached analytical results for any AOW's with enough flow to be sampled.
Rogers Energy Complex (Cliffside), NC0005088 - Reported to NCDEQ on April 19, 2017.
Two AOWs, with coordinates, reported as Areas C and D. Area C was sampled (analytical
results attached). Area D could not be sampled at the time of the inspection due to insufficient
flow.
Cape Fear (NC0003433)- Reported to NCDEQ on April 25, 2017. Four AOWs, with
coordinates, reported as Areas A, B, C and D. Due to insufficient flow, none of the four AOWs
could be sampled during the inspection.
Belews Creek Steam Station (NC0024406)- Reported to NCDEQ on May 17, 2017. One new
AOW, with coordinates, was initially reported as Area AA. Area AA was changed to a S-16
designation and was sampled (analytical results attached).
Riverbend (NC0004961)- Reported to NCDEQ on May 18, 2017. One new AOW, with
coordinates, was reported as S-23. S-23 could not be sampled at the time of the inspection due to
insufficient flow.
Roxboro Steam Plant (NC003425)- Reported to NCDEQ on May 23, 2017. Four AOWs, with
coordinates, reported as AOWs S-20, S-21, S-22 and S-23. AOW S-21 was sampled (analytical
results attached). The remaining three AOWs could not be sampled at the time of the inspection
due to insufficient flow. Further information, relative to the new AOWs at Roxboro, was
submitted to the Division of Water Resources on July 13, 2017 in support of its NPDES renewal
application.

Where applicable, requests for permit coverage have been made under appropriate signatory
submittal. Should further discussions/submittals be required to address any permitting issues
associated with the new AOWs and their respective NPDES permits please let us know.
If there are any questions about this matter please feel free to contact me at [phone] or
shannon.lanale a.duke-energy ,.com.
Sincerely,
E. Shannon Langley
Lead Environmental Specialist
Attachments
Cc: Sergei Chernikov DWR w/attachments via email
Jeff Poupart — DWR w/attachments via email
Chris Hallman — Duke Energy w/attachments via email
Ross Hartfield — Duke Energy w/attachments via email
Robert Wylie — Duke Energy w/attachments via email
Joyce Dishmon — Duke Energy w/attachments via email
Steve Cahoon — Duke Energy w/attachments via email
Brad Loveland — Duke Energy w/attachments via email
Lori Tollie — Duke Energy w/attachments via email
Eurika Rogers/Filenet - Duke Energy w/attachments via email

,& KpE/�±�Analytical Laboratory Pagel of36
� r EVER Y.
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone:[phone] Fax:[phone]
Order Summary Report
J 17060014
BELEWS - NPDES - AOW
Ross Hartfield, Tim Hunsucker,Chris Suttel, Chris Hallman, Kathy Webb, Brando
3195 Pine Hall Rd
Mailcode: Belews Steam Station
Belews Creek, NC 28012
Mary Ann Ogle Phone: [phone]
Mary Ann Ogle
Date:
Please contact the Program Manager (Mary Ann Ogle) with any questions regarding this report.
Data Flags & Calculations:
6/18/2017
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory OC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Date and Time
Sample ID
Plant/Station
2017018245
BELEWS
2017018246
BELEWS
2017018247
BELEWS
3 Total Samples
31-May-17 12:45 PM
31-May-17 1:50 PM
31-May-17 1:50 PM
Collected By
Daniel Youngblood
Daniel Youngblood
Daniel Youngblood
Sample Description
S-16
FIELD BLANK
Trip Blank
Page 2 of 36

Page 3 of 36
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals C Yes ❑ No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. F. Yes 0 No
All laboratory QA/QC requirements are acceptable.
Report Sections Included:
E%**] Job Summary Report
0 Sample Identification
❑ Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
F./� Yes ❑ No
Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
Customer Database Entries
.i❑ Chain of Custody
n Electronic Data Deliverable (EDD) Sent Separatel
Reviewed By: Peggy Kendall Date: 6/18/2017

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17060014
Site: S-16
Collection Date: 31-May-17 12:45 PM
Analyse Result Units Qualifiers RDL
OIL AND GREASE IN WATER - SOLID PHASE EXTRACTION
Oil and Grease
< 5
mg/L
5
ALKALINITY - (Analysis Performed by Shealy
Labs
Vendor Parameter
Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric)
< 0.01
mg-N/L
0.01
INORGANIC IONS BY IC
Chloride
2.0
mg/L
0.1
Fluoride
< 0.1
mg/L
0.1
Sulfate
1.1
mg/L
0.1
MERCURY IN WATER - (Analysis
Performed by
Shealy Labs)
Vendor Parameter
Complete
TOTAL RECOVERABLE METALS BY ICP
Aluminum (Al)
2.40
mg/L
0.025
Barium (Ba)
0.025
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Calcium (Ca)
1.85
mg/L
0.01
Iron (Fe)
1.44
mg/L
0.01
Magnesium (Mg)
1.48
mg/L
0.005
Manganese (Mn)
0.033
mg/L
0.005
Potassium (K)
1.72
mg/L
0.1
Sodium (Na)
4.31
mg/L b2,b4;
0.05
Total Hardness (Ca and Mg)
10.7
mg/L
(CaCO3)
Zinc (Zn)
0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP-MS
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Sample #: 2017018245
Matrix: NPDES
Page 4 of 36
DF
Method
Analysis Date/Time
Analyst
1
EPA 1664E
06/07/2017 09:45
CJELLIO
Vendor Method
V SHEALY
1
EPA 353.2
06/07/2017 13:39
JASTOWE
1
EPA 300.0
06/02/2017 12:02
BGN9034
1
EPA 300.0
06/02/2017 12:02
BGN9034
1
EPA 300.0
06/02/2017 12:02
BGN9034
Vendor Method
V_SHEALY
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.7
06/12/2017 11:01
MHH7131
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3
1
EPA 200.8
06/09/2017 16:42
CWSPEN3

Certificate of Laboratory Analysis Page 5 of 36
This report shall not be reproduced, except in full.
Order # A 7060014
Site: S-16 Sample #: 2017018245
Collection Date: 31-May-17 12:45 PM Matrix: NPDES
Analyte
Result
Units Qualifiers RDL
DF
Method Analysis Date/Time Analyst
Field Parameters (certification not covered under DPAL certification)
pH
7.30
SI Units
1
Field Work
Temperature
20.0
°C
1
Field Work
Specific Conductance
66.9
us/cm
1
Field Work
Turbidity
35.4
NTU
1
Field Work
Flow
NM
cfs
1
Field Work
TOTAL DISSOLVED SOLIDS
TDS
59
mg/L 25
1
SM2540C 06/05/201715:00 MGIGANT
TOTAL SUSPENDED SOLIDS
TSS
34
mg/L 5
1
SM2540D 06/02/201710:00 MGIGANT

Certificate of Laboratory Analysis Page 6 of 36
This report shall not be reproduced, except in full.
Order # A 7060014
Site: FIELD BLANK Sample #: 2017018246
Collection Date: 31-May-17 1:50 PM Matrix:. NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
MERCURY IN WATER - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY

Certificate of Laboratory Analysis Page 7 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Site: Trip Blank Sample #: 2017018247
Collection Date: 31-May-17 1:50 PM Matrix: NPDES
Analyte Result Units Qualifiers RDL DF Method Analysis Date/Time Analyst
MERCURY IN WATER - fAnalysis Performed by Shealy Labs)
Vendor Parameter Complete Vendor Method V_SHEALY
Qualifiers:
B2 Target analyte was detected in Method Blank(s) at a concentration greater than the reporting limit but less
than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
B4 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL).

Certificate of Laboratory Analysis Page 8 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060122 1664_SPE OIL AND GREASE IN WATER - SOLID .PHASE EXTRACTION
Blank # 1
Parameter Measured
Final
Oil and Grease
0.0923
LCS # 1
Parameter Measured
Final
Oil and Grease
33.5
MS # 1
Parameter Measured
Final
Oil and Grease
31.2
Units: Dil RDL Relative Concentration
mg/L 1 5 < 1/2 RDL
Qualifier
Units:
Dil Spike
% Recovery LCL UCL Qualifier
mg/L
1 35.7207
93.7 78 114
Parent Sample: J17040194 -- 2017011694
Units:
Dil Spike
% Recovery LCL UCL Qualifier
mg/L
1 33.0333
93 78 114

Certificate of Laboratory Analysis Page 9 of 36
This report shall not be reproduced, except in full.
Order # A 7060014
Level II QC Summary
Q17060147 C_NO2NO3 NITRITE + NITRATE (COLORIMETRIC)
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0021
0.0021
mg -NIL
1
0.01
< 112 RDL
(Colorimetric)
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0026
0.0026
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 3
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0036
0.0036
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
Blank # 4
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Nitrite + Nitrate
0.0018
0.0018
mg-N/L
1
0.01
< 1/2 RDL
(Colorimetric)
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.299
2.99
mg-N/L
10
3.01
99.2 90
110
(Colorimetric)
LCS # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.299
2.99
mg-N/L
10
3.01
99.3 90
110
(Colorimetric)
LCS # 3
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.297
2.97
mg-N/L
10
3.01
98.8 90
110
(Colorimetric)
LCS # 4
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.299
2.99
mg-N/L
10
3.01
99.4 90
110
(Colorimetric)
MS # 1
Parent Sample:
J17050155
-- 2017015216
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery LCL
UCL
Qualifier
Nitrite + Nitrate
0.311
0.311
mg-N/L
1
0.25
98 90
110
-
(Colorimetric)
MSD # 1
Parent Sample:
J17050155 -- 2017015216
Parameter
Measured
Final
Units:
Dil
S ilce
% Recovery LCL
UCL
RPD Qualifier
Nitrite + Nitrate
0.312
0.312
mg-N/L
1
0.25
98.3 90
110
0.193
(Colorimetric)

Certificate of Laboratory Analysis Page 10of36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060147 C_NO2NO3 NITRITE + NITRAT.E (COLORIMETRIC)
MS # 2 Parent Sample: J17050777 -- 2017018040
Parameter Measured Final Units:
Nitrite + Nitrate 0.336 0.336 mg-N/L
(Colorimetric)
MSD # 2
Parameter Measured Final
Nitrite + Nitrate 0.324 0.324
(Colorimetric)
MS # 3
Parameter
Measured
Final
Nitrite + Nitrate
0.245
0.245
(Colorimetric)
MSD # 3
Parameter
Measured
Final
Nitrite + Nitrate
0.245
0.245
(Colorimetric)
MS # 4
Parameter
Measured
Final
Nitrite + Nitrate
0.259
0.259
(Colorimetric)
MSD # 4
Parameter
Measured
Final
Nitrite + Nitrate
0.259
0.259
(Colorimetric)
Units:
mg-N/L
Dil Spike % Recovery LCL UCL Qualifier
1 0.25 103 90 110
Parent Sample: J17050777 -- 2017018040
Dil Spike % Recovery LCL UCL RPD Qualifier
1 0.25 97.8 90 110 3.58
Parent Sample: J17060014 -- 2017018245
Units: Dil Spike % Recovery LCL UCL Qualifier
mg-N/L 1 0.25 96 90 110
Parent Sample: J17060014 -- 2017018245
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
mg-N/L 1 0.25 96 90 110 0.0408 -
Parent Sample: J17050190 -- 2017015339
Units: Dil Spike % Recovery LCL UCL Qualifier
mg-N/L 1 0.25 98.9 90 110
Parent Sample: J17050190 -- 2017015339
Units: Dil Spike % Recovery LCL UCL RPD Qualifier
mg-N/L 1 0.25 99 90 110 0.116

Certificate of Laboratory Analysis Page 11 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060036 Dionex
INORGANIC IONS
BY IC
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Chloride
0.0329
0.0329
mg/L
1
0.1
< 1/2 RDL
Fluoride
0.0348
0.0348
mg/L
1
0.1
< 1/2 RDL
Sulfate
0.0045
0.0045
mg/L
1
0.1
< 1/2 RDL
-
IS # 1
Parameter
Measured
Fin I
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
7.04
7.04
mg/L
1
5
100
80
120
Fluoride
5.09
5.09
mg/L
1
5
100
80
120
Sulfate
6.21
6.21
mg/L
1
5
102
80
120
ISD # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
7.04
7.04
mg/L
1
5
100
80
120
0.167
Fluoride
5.1
5.1
mg/L
1
5
101
80
120
0.329
Sulfate
6.22
6.22
mg/L
1
5
102
80
120
0.211
IS # 2
Parameter
Measured
Final
Units:
Dil
Spike
/ Recovery
LCL
UCL
Qualifier
Chloride
5.87
29.3
mg/L
5
25
103
80
120
Fluoride
5.18
25.9
mg/L
5
25
103
80
120
Sulfate
6.85
34.3
mg/L
5
25
102
80
120
ISD # 2
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
RPD
Qualifier
Chloride
5.9
29.5
mg/L
5
25
104
80
120
0.583
Fluoride
5.22
26.1
mg/L
5
25
103
80
120
0.719
Sulfate
6.9
34.5
mg/L
5
25
103
80
120
0.952
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL
Qualifier
Chloride
4.99
4.99
mg/L
1
5
99.7
90
110
Fluoride
5.03
5.03
mg/L
1
5
101
90
110
Sulfate
4.97
4.97
mg/L
1
5
99.4
90
110

Certificate of Laboratory Analysis Page 12 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY
ICP
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Aluminum (AI)
0.0002
mg/L
1
0.005
< 1/2 RDL
Barium (Be)
0.000242
0.000242
mg/L
1
0.005
< 1/2 RDL
Boron (B)
-0.00943
-0.00943
mg/L
1
0.05
< 1/2 RDL
Calcium (Ca)
0.00329
0.00329
mg/L
1
0.01
< 1/2 RDL
Iron (Fe)
0.00192
0.00192
mg/L
1
0.01
< 1/2 RDL
-
Magnesium (Mg)
0.0012
0.0012
mg/L
1
0.005
< 1/2 RDL
-
Manganese (Mn)
0.00046
0.00046
mg/L
1
0.005
< 1/2 RDL
-
Potassium (K)
-0.0104
-0.0104
mg/L
1
0.1
< 1/2 RDL
-
Sodium (Na)
0.0274
0.0274
mg/L
1
0.05
> 1/2 RDL
b2,b4
Zinc (Zn)
0.00096
0.00096
mg/L
1
0.005
< 1/2 RDL
LCS # 1
Parameter
Measured
Final
Units:
Dil
S ike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
4.79
mg/L
1
5
95.8
85
115
Barium (Ba)
4.9
4.9
mg/L
1
5
97.9
85
115
Boron (B)
4.89
4.89
mg/L
1
5
97.8
85
115
Calcium (Ca)
4.89
4.89
mg/L
1
5
97.8
85
115
Iron (Fe)
4.9
4.9
mg/L
1
5
97.9
85
115
Magnesium (Mg)
4.87
4.87
mg/L
1
5
97.3
85
115
Manganese (Mn)
4.9
4.9
mg/L
1
5
98
85
115
Potassium (K)
4.82
4.82
mg/L
1
5
96.4
85
115
Sodium (Na)
4.83
4.83
mg/L
1
5
96.5
85
115
Zinc (Zn)
4.9
4.9
mg/L
1
5
98
85
115
MS # 1
Parent Sample:
J17060014 -- 2017018245
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Aluminum (AI)
5.64
28.2
mg/L
1
25
103
70
130
Barium (Ba)
5.03
5.03
mg/L
1
5
100
70
130
Boron (B)
5.01
5.01
mg/L
1
5
100
70
130
Calcium (Ca)
6.83
6.83
mg/L
1
5
99.8
70
130
Iron (Fe)
6.49
6.49
mg/L
1
5
101
70
130
Magnesium (Mg)
6.42
6.42
mg/L
1
5
98.8
70
130
Manganese (Mn)
5.04
5.04
mg/L
1
5
100
70
130
Potassium (K)
6.7
6.7
mg/L
1
5
99.5
70
130 -
Sodium (Na)
9.16
9.16
mg/L
1
5
97.1
70
130
Zinc (Zn)
5
5
mg/L
1
5
99.9
70
130
MSD # 1
Parent Sample:
J17060014
-- 2017018245
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL RPD Quallfier
Aluminum (AI)
5.32
26.6
mg/L
1
25
96.8
70
130 6.4

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060212 ICP_TRM TOTAL RECOVERABLE METALS BY ICP
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Barium (Ba)
4.75
4.75
mg/L
1
5
Boron (B)
4.64
4.64
mg/L
1
5
Calcium (Ca)
6.51
6.51
mg/L
1
5
Iron (Fe)
6.2
6.2
mg/L
1
5
Magnesium (Mg)
6.16
6.16
mg/L
1
5
Manganese (Mn)
4.76
4.76
mg/L
1
5
Potassium (K)
6.4
6.4
mg/L
1
5
Sodium (Na)
8.82
8.82
mg/L
1
5
Zinc (Zn)
4.72
4.72
mg/L
1
5
Qualifiers:
Page 13 of 36
Parent Sample: J17060014 -- 2017018245
Recovery
LCL
UCL
R DD Qualifier
94.5
70
130
5.84
92.9
70
130
7.66
93.4
70
130
6.63
95.3
70
130
5.95
93.7
70
130
5.32
94.5
70
130
5.75
93.6
70
130
6.15
90.3
70
130
7.3
94.3
70
130
5.75
B2 Target analyte was detected in Method Blank(s) at a concentration greater than 1/2 the reporting limit but less
than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes.
1134 Continuing Calibration Blank (CCB) is greater than Reporting Limit (RL).

Certificate of Laboratory Analysis Page 14 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
Antimony (Sb)
-0.033
-0.033
ug/L
1
1
< 1/2 RDL
Arsenic (As)
0.016
0.016
ug/L
1
1
< 1/2 RDL
Cadmium (Cd)
0.013
0.013
ug/L
1
1
< 1/2 RDL
Chromium (Cr)
0.031
0.031
ug/L
1
1
< 1/2 RDL
Copper (Cu)
-0.028
-0.028
ug/L
1
1
< 1/2 RDL
-
Lead (Pb)
0.012
0.012
ug/L
1
1
< 1/2 RDL
-
Molybdenum (Mo)
0.006
0.006
ug/L
1
1
< 1/2 RDL
-
Nickel (Ni)
-0.029
-0.029
ug/L
1
1
< 1/2 RDL
-
Selenium (Se)
0.014
0.014
ug/L
1
1
< 1/2 RDL
-
Thallium (TI) Low Level
-0.007
-0.007
ug/L
1
0.2
< 1/2 RDL
-
LCS # 1
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Qualifier
Antimony (Sb)
48.9
48.9
ug/L
1
50
97.9
85
115
Arsenic (As)
49.4
49.4
ug/L
1
50
98.8
85
115
Cadmium (Cd)
50.2
50.2
ug/L
1
50
100
85
115
Chromium (Cr)
50.9
50.9
ug/L
1
50
102
85
115
Copper (Cu)
50.1
50.1
ug/L
1
50
100
85
115
Lead (Pb)
49.4
49.4
ug/L
1
50
98.8
85
115
Molybdenum (Mo)
50.4
50.4
ug/L
1
50
101
85
115
Nickel (Ni)
49.7
49.7
ug/L
1
50
99.4
85
115
Selenium (Se)
48.8
48.8
ug/L
1
50
97.7
85
115
Thallium (TI) Low Level
48.9
48.9
ug/L
1
50
97.9
85
115
MS # 1
Parent Sample:
J17050090 -- 2017014781
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL Quallfier
Antimony (Sb)
50.5
506
ug/L
1
500
101
70
130
Arsenic (As)
51.4
514
ug/L
1
500
102
70
130
Cadmium (Cd)
48.5
485
ug/L
1
500
97
70
130
Chromium (Cr)
48.9
489
ug/L
1
500
97.5
70
130
Copper (Cu)
49.1
491
ug/L
1
500
97.8
70
130
Lead (Pb)
50
500
ug/L
1
500
99.9
70
130
Molybdenum (Mo)
253
2530
ug/L
1
2500
93.3
70
130
Nickel (Ni)
49.9
499
ug/L
1
500
98.9
70
130
Selenium (Se)
154
1540
ug/L
1
500
120
70
130
Thallium (TI) Low Level
46.1
461
ug/L
1
500
92.2
70
130
MSD # 1
Parent Sample:
J17050090 -- 2017014781
Parameter
Measured
Final
Units:
Dil
Spike
% Recovery
LCL
UCL RPD Qualifier
Antimony (Sb)
48
480
ug/L
1
500
95.9
70
130 5.26

Certificate of Laboratory Analysis Page 15 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060220 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS
MSD # 1
Parameter
Measured
Final
Units:
Dil
Spike
Arsenic (As)
48.9
489
ug/L
1
500
Cadmium (Cd)
46.1
461
ug/L
1
500
Chromium (Cr)
46.4
464
ug/L
1
500
Copper(Cu)
46.4
464
ug/L
1
500
Lead (Pb)
47.3
473
ug/L
1
500
Molybdenum (Mo)
244
2440
ug/L
1
2500
Nickel (Ni)
47.3
473
ug/L
1
500
Selenium (Se)
146
1460
ug/L
1
500
Thallium (TI) Low Level
44.5
445
ug/L
1
500
Parent Sample: J17050090 -- 2017014781
% Recovery
LCL
UCL
RPD Qualifier
97.5
70
130
4.96
92.1
70
130
5.18
92.5
70
130
5.27
92.5
70
130
5.57
94.6
70
130
5.44
89.7
70
130
3.91
93.7
70
130
5.39
104
70
130
14.1
89
70
130
3.52 -

Certificate of Laboratory Analysis Page 16 of 36
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060061 TDS TOTAL DISSOLVED SOLIDS
Blank # 1
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TDS
0
0
mg/L
1
25
< 1/2 RDL
Blank # 2
Parameter
Measured
Final
Units:
Dil
RDL
Relative Concentration
Qualifier
TDS
0
0
mg/L
1
25
< 1/2 RDL
Duplicate # 1
Parent Sample:
J17050329 -- 2017015953
Parameter
Measured
Final
Units:
Dil
RPD Qualifier
TDS
140
140
mg/L
1
0.717
Duplicate # 2
Parent Sample:
J17050329 -- 2017015954
Parameter
Measured
Final
Units:
Dil
RPD Qualifier
TDS
53
53
mg/L
1
7.84
Duplicate # 3
Parent Sample:
J17050329 -- 2017015955
Parameter
Measured
Final
Units:
Dil
RPD Qualifier
TDS
140
140
mg/L
1
1.42
LCS # 1
Parameter
Measured
Final
Units:
Dil
Soike
% Recovery LCL
UCL Qualifier
TDS
103
103
mg/L
1
100
103 90
110

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J17060014
Level II QC Summary
Q17060035 TSS TOTAL SUSPENDED SOLIDS
Blank # 1
Parameter Measured Final
TSS 0 0
Blank # 2
Parameter
Measured
Final
TSS
0
0
Duplicate # 1
Parameter
Measured
Final
TSS
4.6
4.6
Duplicate # 2
Parameter
Measured
Final
TSS
2.8
2.8
Duplicate # 3
Parameter
Measured
Final
TSS
2.8
2.8
LCS # 1
Parameter Measured Final
TSS 47.2 47.2
Page 17 of 36
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
5
< 1/2 RDL
Units:
Dil
RDL
Relative Concentration
Qualifier
mg/L
1
5
< 1/2 RDL
Parent Sample:
J17040222 -- 2017011810
Units:
Dil
RPD Qualifier
mg/L
1
8.33
Parent Sample:
J17050779 2017018053
Units:
Dil
RPD Qualifier
mg/L
1
0
Parent Sample:
J17050779 -- 2017018054
Units:
Dil
RPD Qualifier
mg/L
1
19.4
Units:
Dil
SAike
% Recovery LCL
UCL Qualifier
mg/L
1
50
94.4 90
110

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: Belews Creek NPDES AOW
Project Number:J17060014
Lot Number:SF02014
Date Completed:06/11/2017
Grant Wilton
Project Manager
ICL�
LABORATORY
ACCREDITATION
BU/yREyAU�t
i�k.Ll71CVlF�W'.�k'N'fCr:i3F'4S
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: SF02014
Project Name: Belews Creek NPDES AOW
Project Number: J17060014
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPs), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
Low Level Mercury Analysis - Method 1631 E
Sample -001: The sample, MS and MSD were run straight and twice at an 8x dilution. The maxtrix spike was recovered below the control limit in
each of the three runs. A blank was analyzed between the sample, the MS and MSD for the second 8X dilution run.
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: SF02014
Project Name: Belews Creek NPDES AOW
Project Number: J17060014
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2017018245
Aqueous
05/31/20171245
06/02/2017
002
2017018246
Aqueous
05/31/20171350
06/02/2017
003
2017018247
Aqueous
05/31/20171350
06/02/2017
(3 samples)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: SF02014
Project Name: Belews Creek NPDES AOW
Project Number: A 7060014
Sample Sample ID
Matrix Parameter Method Result Q
Units Page
001 2017018245
Aqueous Alkalinity SM 2320B- 17
mg/L 5
001 2017018245
Aqueous Bicarbonate Alkalinity SM 2320B- 17
mg/L 5
001 2017018245
Aqueous Mercury (CVAFS) 1631E 6.45 S
ng/L 6
(3 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: SF02014-001
Description: 2017018245 Matrix: Aqueous
Date Sampled:05/31/2017 1245 Project Name: Belews Creek NPDES AOW
Date Received:06/02/2017 Project Number: J17060014
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 06/06/2017 1041 BWS 43560
1 (Bicarbonate) SM 2320B-2011 1 06/06/2017 1041 BWS
1 (Carbonate AI) SM 2320B-2011 1 06/06/2017 1041 BWS
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
17
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
17
10
mg1L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantization limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure
No = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria L = LCS/LCSD failure
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure
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Mercury (CVAFS)
Client: Duke Energy Laboratory I D: S F02014-001
Description: 2017018245 Matrix: Aqueous
Date Sampled:05/31/2017 1245 Project Name: Belews Creek NPDES AOW
Date Received:06/02/2017 Project Number: J17060014
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 1631E 8 06/08/2017 1950 SLS 06/02/2017 2324 43419
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS) 7439-97-6 1631E 6.45 S 4.00 ng/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quamitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L - LCS/LCSD failure
Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a "W" S = MS/MSD failure
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Mercury (CVAFS)
Client: Duke Energy Laboratory ID: SF02014-002
Description: 2017018246 Matrix: Aqueous
Date Sampled:05/31/2017 1350 Project Name: Belews Creek NPDES AOW
Date Received:06/02/2017 Project Number: J17060014
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 06/06/2017 2207 SLS 06/02/2017 2324 43419
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1
PQL = Practical cluamkation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure
ND = Not detected at or above the PQL J = Estimated result < PQL and 2 MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L = LCS/LCSD failure
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MS/MSD failure
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Mercury (CVAFS)
Client: Duke Energy Laboratory ID: SF02014-003
Description: 2017018247 Matrix: Aqueous
Date Sampled:05/31/2017 1350 Project Name: Belews Creek NPDES AOW
Date Received: 06102/2017 Project Number: J17060014
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631 E 1 06/06/2017 2211 SLS 06/02/2017 2324 43419
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Mercury (CVAFS) 7439-97-6 1631 E ND 0.500 ng/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quanitation of compound exceeded the calibration range H = Out of holding time Q = Surrogate failure
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria L - LCSILCSD failure
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W" S = MSIMSD failure
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MB
Sample ID: SQ43560-001 Matrix: Aqueous
Batch:43560
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 06/06/2017 0917
PQL = Practical quantitation limit
P = The RPD between two GC columns exceeds 40%
ND - Not detected at or above the PQL J = Estimated result < PQL and> MDL
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
N = Recovery is out of criteria
+ = RPD is out of criteria
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - LCS
Sample ID: SQ43560-002 Matrix: Aqueous
Batch:43560
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (m /L) (m /L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 98 1 98 90-110 06/06/2017 0924
PQL = Practical quantization limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + - RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W'
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Mercury (CVAFS) - MB
Sample ID: SQ43419-001 Matrix: Aqueous
Batch:43419 Prep Method: 1631E
Analytical Method: 1631E Prep Date: 06/02/2017 2324
Parameter Result Q Dil PQL Units Analysis Date
Mercury (CVAFS) ND 1 0.500 ng/L 06/06/2017 2055
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and 2t MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Mercury (CVAFS) - LCS
Sample ID: SQ43419-002 Matrix: Aqueous
Batch:43419 Prep Method: 1631E
Analytical Method: 1631E Prep Date: 06/02/2017 2324
Spike
Amount Result % Rec
Parameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date
Mercury (CVAFS) 5.00 4.93 1 99 75-125 06106/2017 2104
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless Flagged with a °W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Mercury (CVAFS) - MS
Sample ID: SF02014-001MS Matrix: Aqueous
Batch:43419 Prep Method: 1631 E
Analytical Method: 1631E Prep Date: 06/02/2017 2324
Sample Spike
Amount Amount Result % Rec
Parameter (ng/L) (n /L) (n /L) Q Dil % Rec Limit
Analysis Date
Mercury (CVAFS) 6.45 40.0 33.8 N 8 68 71-125 06/08/20171955
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a 'W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Mercury (CVAFS) - MSD
Sample ID: SF02014-001MD
Matrix: Aqueous
Batch:43419
Prep Method: 1631E
Analytical Method: 1631E
Prep Date: 06/02/2017 2324
Sample
Spike
Amount
Amount
Result % Rec % RPD
Parameter
(n /L)
(ng/L)
(ng/L) Q Dill % Rec % RPD Limit Limit Analysis Date
Mercury (CVAFS)
6.45
40.0
37.8 8 78 11 71-125 24 06/08/2017 1959
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W'
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: SF02014
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Chain of Custody
,. ■
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
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SAMPle Remipt Cheddilrt (SM-)
Cliont: C',t)uler lmspccted byidrAe: `_.oUI V: < +'
hlanns of receipt: ❑ SDI © Clint€ =, I,PS -3 FedEa tlttr /li6a/
I , Were cu�y seals present on the �. olve
Yes r1 PNo
Yes � NA /1 2, Ifctlstad • seals were pnscat wlvre. d►ey Jtitrct and unbrokcta?
pH scrap T33; __._. 0 ship ID.
Cooler ID/Origirat teem+ permure (upojn'teeceipt/DcTivcd (corrected) temperature upon raccipt:
+
i41efl1od: to Temperature Blank J4 Against Battles 1R iaWt 1D;-10 __ [R Cain Correction Factor: -jD OC
NIctliod of coolaof: wet ice lb 131w Ice 0 Dry Ice Nane� iLt��t
yez n Na o hh 3, ll'tcmperature of any cooler exceeded 6_OOC, -as Project Alanager Notified?
RM wms Nad117ed bv; p hone f Ma3I I face-to-face (circlet ane).
yes CI = N 4. is the Commercial cuurlees packing slip attactied to this fonn7
Yr,� No r� 5. Were -—
PmPcr custody Procedures {relin uished1received) fallov� e ?
Yea,a N c3 C Were sample IDs listed on the i- OC ?
Yes No 0
7. Were sample Ills listed on all .wmnte containers"
1':s15 No u
8, WAS ea?lection dale & tume listed on the COC1
v fl
19. Was collection date & titne listed an All sample: cQiYt,AlaaerS?
iies! ? c, 0
10. Did all container label infortnatitm (1D7 date, time) it$Itie with the CQC?
V C322 No r3
! I. Were tests to be perf tittered li sf:,ed on the COC?
Yes c N , „ -
i"
1'2. Liid ali smples arrive in ti a proper cr nlairim for each test and+tit ir1 grx cl condition
[ui n. lid-4 on, etc.)?
Yes Non
1.3. Was adequatc sample volume mmilable:'
ye;,;" Nei o
14. Were all samp6 received within % the Bolding Bette or ho —hours, whichever comes firs[.?
Yes o No.:
15- Were ,any samples corttain= missilig a Nc.ess (circle One) samples les Aloe listed on COC?
Yes 0 NO c3
NA ig 16. Werebubbles peesent>"pe"ire , %"or dflim ice diameter) in anyVC}f1 vials?
Yes a t+tta 0
NA l7. were all DR UrnetaWntm•ient samples receltie l tat a pH ot`ev
Yes 12 No u
Nf} 18. Were all cyanide ,"mples received at a pH > 12 and sulfi& samples received at a p1-1 > 4?
Yes o No .0
NA I l 4• were all appliicable, NH31rXNIc;,Amidm'phetaoL'BNA (= 0.5m& Lj :,ampler Fret: of residual
'? 0 Nei 0
NA it 20, 4' trc collection temperatures documented on the COC, for NC samples.?
Yes C No o
1'A 21. Were client remark-Iregwsts (Le. requesuld diluiians, MS/MSD designations, etc...)
correctly transcribed fralm the COC into the comment section in LIMS?
Yes 17 N.4
122. W. the quote number used taken from the container label?
Sample Preservation (Matt he completed for any •sarn lc s incoPrectl
) y preserved or with ficaads are.)
Sarriple[sj
Aam 1i: Troe1�14'ith
were received incurrecdy preserved and were adjtrtad accordingly in
,�(T•tr_3' , ii� O.%, MCI, NaOH) usin SB. #
Sant
_ wemrecei�•ed w�it#t bui7blcs>6 loin in diameter.
ICS()__--
5srraplss(s)
djusted atcirrdin 1
were received with TRC a 0.5 mWL (If #21 is No) and were
In sample receivingwttlt }cilium throsulfate [?1tk:SJ) WWI Shealy !T);
C Drinking 1t+star Project Samples) pH verified to be � 2 by Date.
Issiample
awn le(s) were Nutt received at a Ii of<2 and there adi usted acccrdin�ly usin Sty# Labels applied
01- Leafed by: _ _ Date &tz /2
Comm zrtts: •E XA ,� _( m 'a h '
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

CHAIN Of CUSTODY RECORD AND ANALYSIS REQUEST FORM
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1?i$TiliilOhi f7R1{lMht
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rvoc— iJ.r 1-- . _ ..1 — ,R. +r ._ Cae�ki Wes+ ael;o" x. i
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a�u ueE dsr x L.acaf m 10 Cps I.a N*" M;uiMucafioa� ate '
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El R4! NT9 MaX MCP (i3N7oJ!!r6 ' iql Cw; Fl+a. M�, t e, MMIg, Mn, Mt. Mis, + "a copy I'm Hun%vt tamp •xto M5UR � i `UMMb®r� _ �,,,,
Aaltl, Wip Ap*'

Legals
Public Notice
North Carolina Environmental Management Commission/NPDES Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Notice of Intent to Issue a NPDES Wastewater Permit
The North Carolina Environmental Management Commission proposes to issue a
NPDES wastewater discharge permit to the person(s) listed below. Written comments
regarding the proposed permit will be accepted until 30 days after the publish date of
this notice. The Director of the NC Division of Water Resources (DWR) may hold a
public hearing should there be a significant degree of public interest. Please mail
comments and/or information requests to DWR at the above address. Interested
persons may visit the DWR at 512 N. Salisbury Street, Raleigh, NC to review
information on file. Additional information on NPDES permits and this notice may be
found on our website: http://deq.nc.gov/about/divisions/water-resources/water-
resources-permit... by calling [phone]. Tuckaseigee Water & Sewer Authority
requested renewal of NCO063321 for Plant #3 (Cashiers) in Jackson County; this
permitted discharge is treated domestic wastewater to an unnamed tributary of the
Chattooga River, in the Savannah River Basin.
363593 08/16/2017