NCS000520_MONITORING INFO_20191011

STORMWATER DIVISION CODING SHEET
NCS PERMITS
PERMIT NO.
56�
n/ �S d
/ v
DOC TYPE
❑FINAL PERMIT
MONITORING REPORTS
❑ APPLICATION
❑ COMPLIANCE
❑ OTHER
DOC DATE
❑ �� I I O I I
YYYYMMDD

Alut en -
Feeding the Future -
September 24, 2019
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: Storm Water Discharge Monitoring Report
Bulk Handling Facility Morehead City, N.
PCS Phosphate Company, Inc.kEcElvcD
Permit No. NCO00520 OCT 1
2019
c'�rvrRAL Fr
LES
Attached is the Storm Water Discharge Outfall (SDO) Monitoring Report for the Bulk
Handling Facility located in Morehead City, North Carolina for the September sampling
event.
Please do not hesitate to contact me a [phone], if any additional information is
required. 9
D. Daniel Winstead III
Senior Environmental Enginee
Nutrien
r
1530 NC Hwy 306 South, Aurora, NC USA 27806
_ nutdan.com
1 — Effective January 1, 2018, PCs Phosphate Company, Inc, is an mdreect su65idiary ofNutrieri Ud.-PCS-Phosphate Comp y,-ine —
remains the legal operating entity and permittee.

PC: 12-01-013-03-01 (w/attachments)
Jason Broadwell
Mail Original and one copy to:
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
— Effective January 1, 2018, PCS Phosphate Company, Inc. is an indirect subsidiary of Nutrien Ltd. PCs Phosphate Company, Inc.
remains the legal opemting entity and pL mittoe.

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NCS 000520 or SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
Certificate of Coverage Number: NCG (This monitoring report shall be received by the Division no later than 30 days
from the date the facility receives the sampling results from the laboratory.)
FACILITY NAME PCS Phosphate Bulk Handling Facility -Morehead City COUNTY Carteret
PERSON COLLECTING SAMPLE(S) Jason Broadwell PH E N 252 322 - 8283
CERTIFIED LABORATORY(S) Environment 1 Lab # 10
Lab #
AN XURE OF PERMI TE O 1 1DESIGNE
By this signature, I certi that this report is accura and
complete to the best of my knowledge.
Part A: Specific Monitoring Requirements
Outfall
D t ..
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Sample:::::::::;
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26
6.04
0.63
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of NEW motor oil per month? yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements

STORM EVENT CHARACTERISTICS:
Date: 91912014
Total Event Precipitation (inches): 0.63" at sample time
Event Duration (hours): (only it applicable - see permit.)
(if more than one storm event was sampled)
Date:
Total Event Precipitation (inches):
Event Duration (hours):
(only if applicable - see permit.)
Mail Original and one copy to:
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am athat there are significant penalties for submitting false information, including the possibility of fines and
way
imprisonment for knowing violations."' 7 7
9/
2y 2d�
re of Permittee) (Date)

r4r yM,1vO�r
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No.: N/C/S/0/0/0/512/01 or Certificate of Coverage No.: N/C/G/ / / / / / /
Facility Name: PCS Phosphate Bulk Handling Facility -Morehead City Terminal
County: Carteret Phone No. [phone]
Inspector: Jason Broadwell
Date of Inspection: 9/9/2019
Time of Inspection:
7:i0PM
Total Event Precipitation (inches): 0.63
Was this a Representative Storm Event? (See information below) �X Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event
(requirements vary).
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
:A "Representative Storm Event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at
least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may
icontain up to 10 consecutive -hours -of -no precipitation_- - - - - - - - - - - - - -
sign , I certify that is r port 's Maccuralpncomplete tot best of my knowledge:
_v—
(Signature of Permittee or
1. Outfall Description:
Outfall No. 100
Structure (pipe, ditch, etc.) Pipe (Sampled at Storm Drain Inlet #103)
Receiving Stream: Newport River
Describe the industrial activities that occur within the outfall drainage area: Bulk handling of phosphate related products
2. Color: Describe the color of the discharge using basic color (red, brown, blue, etc.) and tint (light,
medium, dark) as descriptors: Light Brown
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine
odor, etc.): None
Page 1 of 2

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is
very cloudy:
0 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater
discharge, where 1 is no solids and 5 is the surface covered with floating solids:
2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the
stormwater discharge, where I is no solids and 5 is extremely muddy:
0 2 3 4 5
7. Is there any foam in the stormwater discharge'? Yes No
$, Is there an oil sheen in the stormwater discharge'? Yes No
9. Is there evidence of erosion or deposition at the outfall'? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition maybe indicative of pollutant
exposure. These conditions warrant further investigation.
Page 2 of 2

Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No.: NICIS101010/512/0/ or Certificate of Coverage NO.: N/C/C/ / / / / / /
Facility Name: PCS Phosphate Bulk Handling Facility -Morehead City Terminal
County: Carteret Phone No. [phone]
Inspector: Jason Broadwell
Date of Inspection: 9/9/2019
Time of Inspection:
7:20 PM
Total Event Precipitation (inches):
0.63
Was this a Representative Storm Event? (See information below) 1XI Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must be performed during a representative storm event
(requirements vary).
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
;A "Representative Storm Event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at
:least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may
;contain --�u to 10 consecutive hours of no precipitation.
---------- ---------------- - ------------------------------------------------------------------------------------------------------------------
By is sig re, I certify that this repVh is accurst and oomp�f e to the best of my knowledge:
ignature of Permittee or Designee)
I. Outfall Description:
Outfall No. 200
Structure (pipe, ditch, etc.) Pipe (Concrete swell that discharges to pipe)
Receiving Stream: Newport River
Describe the industrial activities that occur within the outfali drainage area: Bulk handling of phosphate related products
2. Color: Describe the color of the discharge using basic color (red, brown, blue, etc.) and tint (light,
medium, dark) as descriptors: Light Brown
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine
odor, etc.): None
Page 1 of 2

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is
very cloudy:
0 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater
discharge, where I is no solids and 5 is the surface covered with floating solids:
0 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the
stormwater discharge, where 1 is no solids and 5 is extremely muddy:
I-'� 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
g, Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant
exposure. These conditions warrant further investigation.
Page 2 of 2

EmAnflumM % hmpumbd
Drinking water ID: 37715
114 OAKMONT DRIVE_ PHONE[phone]
GREENVILLE, N.C. 27858 __ FAX [phone]
NUTRIEN (MOREHEAD PORT)
C/O MR. DANNY WINSTEAD
1530 NC HWY. 306 SOUTH
AURORA ,NC 27806
ID#: 1610
DATE COLLECTED: 09/09/19
DATE REPORTED : 09/18/19
REVIEWED BY:
Stormwater
Stormwater
Analysis
Method
PARAMETERS
100
200
Date
Analyst
Code
COD, mgll
42
Missing
09/13/19
SLJ
H8000-79
Total Suspended Residue, nig/1
62
Missing
09/13/19
H.JO
2540D-II
Ammonia Nitrogen as N, mg/l
27.20
Missing
09/13/19
AKS
350.1 112-93
Total Kjeldahl Nitrogen as N,mg/l
32.90
N-lissing
09/17/19
AKS
351.2 R2-93
Nitrate -,Nitrite as N, mg/l
2.35
Missing
09/13/19
BLD
353.2 R2-93
Total Phosphorus as P, mg/l
51.90
Missing
09/17/I9
SLD
365.4-74
Fluoride, mg/l
1.9
Missing
09/16/19
JMS
4500FC-II
TN = Tx� /v 4 /vf c--
30Z90 + a.ss
= 3S.25
I V1 1217E

Environment 1, Inc. CHAIN OF CUSTODY RECORD
7085. 114 Oakmont Dr. Page 1 of
Greenville. NC 27858
environment] inc.com
DISINFECTION
CHLORINE iVEUTRALIZEDATCOLLECTION
Phone [phone] •Fax [phone]
CHLORINE
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CLIENT: 1610 Week: al
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,ONE
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CHEMICAL PRESERVATION
530 NC HNVY. 306 SOUTH
►URORA NC 27806
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SAMPLE LOCATION
DATE
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Storma'afer (OD
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CLASSIFICATION:
WASTEWATER (NPDES)
Stormwaier 200
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DRINKING WATER
DWMW
Ij SOLID WASTE SECTION
CHAIN OF CUSTODY (SEAL) MAINTAINED
DURING IPMENT/DELIVERY
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SAMPLES COLLECTED BY:
(Please Print)
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SAMPLES RECEIVED IN LAB AT
RELINQUISHED BY (SIG.) (SAMPLER)
DATEMME
RECEIVED (SIG.)
DATE/11ME
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RELINQUISHED BY (SIG.)
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DATEMME
PLEASE READ Instructions for completing this form on the reverse side. Sampler must place a "C" for composite sample or a "G" for
FORM Its Grab sample in the blocks above for each parameter requested. N 0 371022

SAMPLING INSTRUCTIONS AND FORM COMPLETION
FAILURE TO PROPERLY CHILL, CHEMICALLY PRESERVE, COLLECT IN PROPER BOTTLE
TYPES, MEET REQUIRED HOLDING TIMES, NEUTRALIZE CHLORINE IN CHLORINE
SENSITIVE SAMPLES, AND SEAL COOLERS WITH TAPE WILL RESULT IN SAMPLES BEING
REJECTED BY THIS LABORATORY AS PER NORTH CAROLINA REGULATORY CODE.
1) Samples not falling within the required guidelines will need to be re -collected. The client will be contacted and informed of any
deviation and asked to collect another set of samples. The client may request the laboratory to proceed with the analyses of the current
samples. Any samples analyzed outside of the required guidelines will be "qualified". This means that a note will be included on the
sample result and "Chain of Custody" specifying the deviation. The laboratory is also required to send a letter to the State noting the
deviations.
2) Sample Temperature. Samples !or compliance monitoring must be chilled with wet ice to a temperature of 6C or less. Freezing is
not permitted. Samples delivered to the lab shortly after collection may not have had enough time to be chilled below 6C. In this case the
temperature at time of collection must be noted in the space provided. The samples will meet the requirements of the regulation if there
is a temperature drop from the time of collection until received in the lab. Regardless, all samples should be packed in wet ice using as
much ice as will fit in the cooler.
3) Sample Chemical Preservation. Many samples require a chemical preservation such as Sulfuric Acid or Sodium Hydroxide. The
laboratory will either provide the preservative in the sample bottle, or in the case of 40 ml. Volatiles Vials, provide a bottle of Acid with
detailed descriptions on how to collect the sample. Never rinse sample bottles before collecting samples. Any residue or liquid in the
bottle is required for proper chemical preservation. The lab must verify proper chemical preservation upon arrival in the lab and will note
this information in the spaces provided on the front of this form.
4) Chlorine Neutralization. Some samples require that any Total Chlorine Residual be removed at the time of collection. The lab will
provide the proper neutralizing agent in the sample bottle when technically possible. There are some samples (Total Kjeldahl Nitrogen
and Ammonia Nitrogen) where this is not possible due to interferences between the required chemical preservation (Acid) and the
dechlorinating agent. Therefore, these samples must be de -chlorinated at the time of collection before being placed in our sample bottles.
Sodium Thiosulfate is the chemical of choice to neutralize chlorine. It must be added to your sample and then the sample checked for
Total Chlorine before the sample is poured in our bottle. Facilities using chlorine for disinfection should have a means of measuring Total
Chlorine. Non -chlorinated sample sources will not need to be checked. The person neutralizing the chlorine must put his initials in the
"Chlorine Neutralized at Collection" row on the front of this form above the proper parameter. Samples such as Coliforms (which have
Thiosulfate in the bottles shipped from the lab) will be checked for proper neutralization upon arrival in the lab. It is also required that you
note the "Total Chlorine at Collection" on the front of this lorm for any sample locations applicable. This value would be before any
neutralization is performed.
5) A "C" for Composite Sample or a "G" for Grab Sample should be placed in the box for all requested parameters. Grab temperatures
as well as Composite start dates and times can be recorded in the "comments" section.
6) Other information required to be completed by the client are:
Collection Date and Collection Time for each sample location Temperature at Time of Collection
Printed name of person or persons collecting samples Signature, Date, and Time samples are relinquished
Other added sample locations and analyses required Type Of Disinfection
Deletion on the form for any samples which are not needed (example: dry upstream location)
Any other information felt to be pertinent should be included in the "Comments" section
CONSIDERATIONS:
Coliform and Enterococci samples have a holding time of 6 hours from time of collection to time of analysis. Therefore, samples should
be collected as late in the day as possible to allow enough time for transportation, checking in at the lab and analysis.
BOD, Nitrate, Ortho Phosphorus, Settleable Matter, Turbidity, Color, and MBAS samples have a 48 hour holding time. The lab reserves the
right to establish required sample collection and delivery dates in order to meet the required holding times.
CAUTION
Sample bottles may contain acids or other corrosive and potentially harmful chemicals. Laboratories are required to add these chemicals
for certain analyses in order to comply with FPA preservation requirements. Use extreme care when opening and handling the shipping
container and bottles. If any chemical should get into your eyes, on your skin or on your clothes, flush liberally with water and seek medical
attention. Material Safety Data Sheets (MSDS) are available upon request which specify proper handling and personal protection.

Alutrien-
Feeding the Future -
September 18, 2019
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Ralcigh, North Carolina 27699-1617
S£P 2 0 Z019
CENTRAL t-ILES
DWR SECTION
Subject: Stormwater Discharge Monitoring Report,
Bulk Handling Facility Morehead City, N. C.
Permit No. NCO00520
PCS Phosphate Company, Inc. — Aurora Division
The Bulk Handling Facility located in Morehead City, North Carolina did not experience
a representative rainfall event that could be sampled. The site generated Rainfall Data
Sheet and the Morehead City Tide Tables are provided for reference.
Please do not hesitate to contact me a [phone], if any additional information is
required.
A
D. Daniel Winstead III
Senior Environmental Engineer
PCS Phosphate
1530 NC Hwy 306 South, Aurora, NC USA 27806
1—nut�ien,eom
H:1Reports120191Monthlyli_SeptemberlNC Port Stormwater No Representative Sample Event.docx

PC: 12-01-013-03-01 (w/attachments)
Jason Broadwell
Mail Original and one copy to:
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
H:1Reporls120191Monthlyli_Seplember\NC Port Stonnwater No Representative Sample Event.doex

Morehead City Rainfall Data Sheet
AugustZ01Q
8/2/2019!
0,53:
0.53�
Incoming tide- unable to take sample
8/11/2019�
3.
Event occurred on a Sunday; no staff on site
8/13/20191
8/15/2019
0.161
3.42
1 Incoming tide- unable to take sample
8/16/2019:
3.39
6.�]
Less than 72 hours since last storm event
8/18/20'1'91
0.971
8.5 Less than 72 hours since last storm event
-
_
- --
--'---
- - i ---- -'-
--- ---
----
' -- --- '--
- '
_ - - _- __---__-
*High tide started at 9:26 AM and ended at
13-.28 PM; storm event started at appoximately
1:30 PM
I* *High tide started at 8:40 AM and ended at
PM; Storm even started at approximately
12:30 PM

Morehead City Harbor Tide Tables
Thursday, August 1, 2019. Sun 6:16am-8:09pm. low tide 2:46am (-
0.29ft), high tide 8:33am (3.22ft), low tide 2:34pm (-0.66ft), high tide
9:06pm (4.48ft)
Friday, August 2, 2019. Sun 6:17am-8:08pm. low tide 3:34am (-0.43ft),
high tide 9:26am (3.39ft), low tide 3:29pm (-0.67ft), high tide 9:56pm
(4.42ft)
Saturday, August 3, 2019. Sun 6:18am-8:07pm. low tide 4:22am (-0.50ft),
high tide 10:20am (3.53ft), low tide 4:25pm (-0.57ft), high tide 10:47pm
(4.24ft)
Sunday, August 4, 2019. Sun 6:18am-8:06pm. low tide 5:1lam (-0.50ft),
high tide 11:15am (3.61ft), low tide 5:23pm (-0.38ft), high tide 11:38pm
(3.97ft)
Monday, August 5, 2019. Sun 6:19am-8:05pm. low tide 6:01 am (-0.43ft),
high tide 12:13pm (3.65ft), low tide 6:23pm (-0.12ft)
Tuesday, August 6, 2019. Sun 6:20am-8:04pm. high tide 12:32am
(3.64ft), low tide 6:52am (-0.31ft), high tide 1:13pm (3.66ft), low tide
7:28pm (0.15ft)
Wednesday, August 7, 2019. Sun 6:21am-8:03pm. high tide 1:28am
(3.31ft), low tide 7:46am (-0.16ft), high tide 2:15pm (3.65ft), low tide
8:36pm (0.37ft)
Thursday, August 8, 2019. Sun 6:21am-8:02pm. high tide 2:29am
(3.01 ft), low tide 8:43am (-0.01 ft), high .tide 3:19pm (3.64ft), low tide
9:47pm (0.51 ft)
Friday, August 9, 2019. Sun 6:22am-8:01 pm. high tide 3:33am (2.79ft),
low tide 9:41am (0.12ft), high tide 4:23pm (3.66ft), low tide 10:55pm
(0.55ft)
Saturday, August 10, 2019. Sun 6:23am-8:00pm. high tide 4:37am
(2.67ft), low tide 10:40am (0.19ft), high tide 5:21 pm (3.69ft), low tide
11:55pm (0.53ft)
Sunday, August 11, 2019. Sun 6:24am-7:59pm. high tide 5:37am (2.64ft),
low tide 11:36am (0.22ft), high tide 6:15pm (3.73ft)

Monday, August 12, 2019. Sun 6:24am-7:58pm. low tide 12:48am
(0.47ft), high tide 6:30am (2.68ft), low tide 12:27pm (0.22ft), high tide
7:02pm (3.'76ft)
Tuesday, August 13, 2019. Sun 6:25am-7:57pm. low tide 1:34am (0.41ft),
high tide 7:1Bam (2.74ft), low tide 1:13pm (0.20ft), high tide 7:45pm
(3.78ft)
Wednesday, August 14, 2019. Sun 6:26am-7:56pm. low tide 2:15am
(0.35ft), high tide 8:00am (2.82ft), low tide 1:56pm (0.18ft), high tide
8:25pm (3.78ft)
Thursday, August. 15, 2019. Sun 6:27am-7:55pm. low tide 2:52am
(0.32ft), high tide 8:40am (2.90ft), low tide 2:36pm (0.18ft), high tide
9 :02 pm (3.75ft )
Friday, August 16, 2019. Sun 6:27am-7:53pm. low tide 3:27am (0.30ft),
high tide 9:17am (2.97ft), low tide 3:14pm (0.22ft), high tide 9:37pm
(3.68ft)
Saturday, August 17, 2019. Sun 6:28am-7:52pm. low tide 4:00am
(0.30ft), high tide 9:54am (3.02ft),' low tide 3:53pm (0.29ft), high tide
10:11 pm (3.56ft)
Sunday, August 18, 2019. Sun 6:29am-7:51 pm. low tide 4:32am (0.34ft),
high tide 10:30am (3.06ft), low tide 4:31 pm (0.40ft), high tide 10:45pm
(3.42ft)
Monday, August 19, 2019. Sun 6:30am-7:50pm. low tide 5:04am (0.39ft),
high tide 1107am (3.08ft), low tide 5:11 pm (0.54ft), high tide 11:19pm
(3.25ft)
Tuesday, August 20, 2019. Sun 6:30am-7:48pm. low tide 5:37am (0.45ft),
high tide 11:46am (3.11ft), low tide 5:53pm (0.68ft), high tide 11:56pm
(3.06ft)
Wednesday, August 21, 2Q19. Sun -6:31 am-7:47pm. low tide 6:1lam
(0.50ft), high tide 12:29pm (3.15ft), low tide 6:41 pm (0.81 ft)
Thursday, August 22, 2019. Sun 6:32am-7:46pm. high tide 12:37am
(2.89ft), low tide 6:50am (0.54ft), high tide 1:16pm (3.21ft), low tide
7:34pm (0.90ft)

Friday, August 23, 2019. Sun 6:33am-7:45pm. high tide 1:24am (2.74ft),
low tide 7:35am (0.55ft), high tide 2:09pm (3.30ft), low tide 8:35pm
(0.93ft)
Saturday, August 24, 2019. Sun 6:33am-7:44pm.'-high tide 2:18am
(2.65ft), low tide 8:27am (0.51ft), high tide 3:09pm (3.45ft), low tide
9:40pm (0.88ft)
Sunday, August 25, 2019. Sun 6:34am-7:42pm. high tide 3:20am (2.63ft),
low tide 9:26am (0.40ft), high tide 4:10pm-(3.65ft), low tide 10:45pm
(0.72ft)
Monday, August 26, 2019. Sun 6:35am-7:41 pm. high tide 4:24am (2.71 ft),
low tide 10:28am (0.22ft), high tide 5:11pm (3.90ft), low tide 11:45pm
(0.50ft)
Tuesday, August 27, 2019. Sun 6:36am-7:40pm. high tide 5:26am
(2.90ft), low tide 11:29am (-0.02ft), high tide 6:08pm (4.15ft)
Wednesday, August 28, 2019. Sun 6:36am-7:38pm. low tide 12:39am
(0.23ft), high tide 6:25am (3.15ft), low tide 12:29pm (-0.27ft), high tide
7:03pm (4.36ft)
Thursday, August 29, 2019. Sun 6:37am-7:37pm. low tide 1:30am (-
0.03ft), high tide 7:20am (3.44ft), low tide 1:26pm (-0.48ft), high tide
7:55pm (4.49ft)
Friday, August 30, 2019. Sun 6:38am-7:36pm. low tide 209am (-0.25ft),
high tide 8:14am (3.71ft), low tide 2:22pm (-0.61ft), high tide 8:46pm
(4.51ft)
Saturday, August 31, 2019. Sun 6:38am-7:34pm. low tide 3:06am (-
0.40ft), high tide 9:07am (3.94ft), low tide 3:17pm (-0.62ft), high tide
9:35pm (4.41ft)
< < <August, 2019

Feeding the Future -
August 8, 2019
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
RECEIVED
AUG 19 2019
CEN t tKAL FILES
DWR SECTION
Subject: Storm Water Discharge Monitoring Report
Bulk Handling Facility Morehead City, N. C.
PCS Phosphate Company, Inc. 1
Permit No. NC000520
Attached is the Storm Water Discharge Outfall (SDO) Monitoring Report for the Bulk
Handling Facility located in Morehead City, North Carolina for the July sampling event.
Please do not hesitate to contact me a [phone], if any additional information is
required.
- ba'4ULP
D. Daniel Winstead III
Senior Environmental Engineer
Nutrien
1630 NC Hwy 306 South, Aurora. NC USA 27806
nutrien.com
1 - Effective January 1, 2018, PCS Fhosphate Company, {nc, is an indir- ct"subsidiary"7`Nutrien-Ltd.-PCs-Phosphate Company,-[m. --
remains the legal operating entity and pennittee.

Pc: 12-01-013-03-01 (wlattachments)
Jason Broadwell
Mail Original and one copy to:
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
l — Effective January 1, 20 M PCs Phosphate Company, Inc. is an indirect subsidiary of Nutrien I_.td. PCs Phosphate Company, Inc,
remains the legal operating entity and permittee.

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
Permit Number: NCS 000520 or
Certificate of Coverage Number: NCG
FACILITY NAME PCS Phosphate Bulk Handling Facility -Morehead C_ 4_
PERSON COLLECTING SAMPLE(S) Jason Broadwell _
CERTIFIED LABORATORY(S) Environment 1 Lab 9 10
Lab #
Part A: Specific Monitoring Requirements
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report shall be received by the Division no later than 30 days
from the date the facility receives the sampling results from the laboratory.)
COUNTY Carteret
252)
JZN 2 - 82.f i►'S.d/IO �1
(SIGNATURE OF PERMITTEE OR DESIGNEE
By this signature, I certify that this report is curate and
complete to the best of my knowledge.
a
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100
1 718119
24
67
56
54
52
56
1.70
26.9
6.29
0.14
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of NEW motor oil per month? yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity Monitoring Requirements

STORM EVENT CHARACTERISTICS:
Date: 71R17n19
Total Event Precipitation (inches):
Event Duration (hours):
0.14" at sample time
(only if applicable - see permit.)
(if more than one storm event was sampled)
Date:
Total Event Precipitation (inches):
Event Duration (hours):
(only if applicable - see permit.)
Mail Original and one copy to:
Division of Water Quality
Surface Water Protection Section
Attn: Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and
belief, true, accurate, and complete. I am aware that there are significant penalties for submitting falseinformation, including the possibility of fines and
imprisonment for knowing violations."'
ffA
atu re
(Date)

Permit NO.: N/C/S/0/0/0/5/2/0/
Stormwater Discharge Outfall (SDQ)
Qualitative Monitoring Report
or Certificate of Coverage No.: N/C/C/ 1 1 l I I l
Facility Name: PCS Phosphate Bulk Handling Facility -Morehead City Terminal
County: Carteret Phone No. [phone]
Inspector: Jason Broadwell
Date of Inspection: 7/8/2019
Time of Inspection: 6:15 PM
Total Event Precipitation (inches)
0.14
Was this a Representative Storm Event? (See information below) �X Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must he Performed during a representative storm event
(requirements vaty).
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -------------------------
,A "Representative Storm Event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at
least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may
contain up to 10 consecutive hours of no reci i[ation.
------------------- --------------------------------Q---------------------------------------------------------------------------------------------- ---:
By th' signatu , I certify that this reporyisa urate and
(Signature of Permittee or Designee)
1. Outfall Description:
Outfall No. 100
P the best of my knowledge:
Structure (pipe, ditch, etc.) Pipe (Sampled at Storm Drain Inlet #103)
Receiving Stream: Newport River
Describe the industrial activities that occur within the outfall drainage area: Bulk handling of phosphate related products
2. Color: Describe the color of the discharge using basic color (red, brown, blue, etc.) and tint (light,
medium, dark) as descriptors: Lim Brown
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine
odor, etc.): None
Page 1 of 2

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is
very cloudy:
I 1 1 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater
discharge, where 1 is no solids and 5 is the surface covered with floating solids:
0 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the
stormwater discharge, where 1 is no solids and 5 is extremely muddy:
0 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
8. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition maybe indicative of pollutant
exposure. These conditions warrant further investigation.
Page 2 of 2

Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Permit No.: N/C/S/0/0/0/5/2/0/ or Certificate of Coverage No.: N/C/G/ l l l l l l
Facility Name: PCS Phosphate Bulk Handling Facility -Morehead City Terminal
County: Carteret Phone No. [phone]
Inspector: Jason Broadwell
Date of Inspection: 7/8/2019
Time of inspection: 6:10 PM
Total Event Precipitation (inches): 0.14
Was this a Representative Storm Event? (See information below) �X Yes No
Please check your permit to verify if Qualitative Monitoring must he performed during a representative storm event
(requirements vary).
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
!A "Representative Storm Event is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at
least 72 hours Q days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may
;contain up to 10 consecutive hours of nopreci�itation.
----- ------------------------------------------ ------------------------------------------------------------------------------------------------------- -
By thisigna re, I certify that this report yas accurate and com�yete to the best of my knowledge:
/�
(Signature of Permittee or Designee)
1. Outfall Description:
Outfall No. 200
Structure (pipe, ditch, etc.) Pipe (Concrete swell that discharges to pipe)
Receiving Stream: Newport River _
Describe the industrial activities that occur within the outfall drainage area: Bulk handling of phosphate related products
2. Color: Describe the color of the discharge using basic color (red, brown, blue, etc.) and tint (light,
medium, dark) as descriptors: Li�rown
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine
odor, etc.): None
Page t of 2

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is
very cloudy:
1 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater
discharge, where 1 is no solids and 5 is the surface covered with floating solids:
0 2 3 4 5
b. Suspended Solids: Choose the number which best describes the amount of suspended solids in the
stormwatcr discharge, where i is no solids and 5 is extremely muddy:
0 2 3 4 5
7, Is there any foam in the stormwater discharge'? Yes No
$, Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
]Vote: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition maybe indicative of pollutant
exposure. These conditions warrant further investigation.
Page 2 of 2

p
114 OAKMONT DRIVE PHONE [phone]
GREENVILLE, N.C. 27858 _ FAX [phone]
NUTRIEN (MOREHEAD PORT)
C/O MR. DANNY WINSTEAD
1530 NC HWY. 306 SOUTH
AURORA ,NC 27806
Stormwater Analysis Method
PARAMETERS 100 Date Analyst Code
COD, mg/I 120
Total Suspended Residue, mg/1 100
Ammonia Nitrogen as N, mg/I
Total Kjeldahl Nitrogen as N,mg/I
Nitrate -Nitrite as N, mg/l
Total Phosphorus as P, mg/l 2
Fluoride, mg/I
56
07/15/19
SEJ
H8000-79
24
07/12/19
MAR
2540D-11
52.30
07/08/19
BLD
350.1 112-93
53.76
07/16/19
AKS
351.2 112-93
1.82
07/12/19
AKS
353.2 R2-93
66.80
07/16/19
TLH
365.4-74
1.7
07/19/19
KDS
4500FC-I i
TkA /- -4-
4
ID#: 1610
DATE COLLECTED: 07/08/19
DATE REPORTED : 07/24/19
REVIEWED BY:
077-2A-Tr -- 'Ni t21 7C
/191�

Environment f, Inc. CHAIN OF CUSTODY RECORD
P.O. Box 7085. 114 Oakmont Dr. Page 1 of
Greenville, NC 27858
environment I inc.�prr►
DISINFECTION
CHLORINE NEUTRALJZED AT COLLECTION
Phone (252) • Fax [phone]
CHLORINE
Ij
pH CHECK (LAB)
CLIENT: 1610 Week: 2$
Ij UV
P
P
P
P
P
P
P
CONTAINER TYPE, PIG
gUTRIEN (MOREHEAD PORT)
NONE
Ll
'_/O MR. DANNY WINSTEAD
.530 NC HWY. 306 SOUTH
,URORA NC 27806
C
A
C
C
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A
CHEMICAL PRESERVATION
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CE-G NATHIOSULFATE
SAMPLE LOCATION
Stormwater 1 00
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CLASSIFICATION:
X WASTEWATE»(NPDI=S)
rmwater 2 Sto 00
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DRINKINGWA-I"ERIME
DWRlGW
SOLID WASTE SECTION
CHAIN Of CUSTODY (SEAL) MAINTAINED
DURING PMENT/DELIVERY
N
SAMPLES COLLECTED BY:
(Please Print)
SAMPLES RECEIVED IN LAB AT °C
RELINQUISHED BY (SIG.) (SAMPLER)
DATEIIIME
RECEIVED G.)
ATErMME
COMMENTS:
I1
Z
RELINQUISHED BY (SIG.)
DATEMME
RECEIV D BY .)
DATE+TiME
RELINQUISHED BY (SIG.)
DATEIIIME
RECEIVED BY (SIG.)
DATE(TIME
PLEASE READ Instructions for completing this form on the reverse side. Sampler must place a "C for composite sample or a "G" for
FORM #5 Grab sample in the blocks above for each parameter requested. N 0 3 6 9 2 a 8

SAMPLING INSTRUCTIONS AND FORM COMPLETION
FAILURE TO PROPERLY CHILL, CHEMICALLY PRESERVE, COLLECT IN PROPER BOTTLE
TYPE, MEET REQUIRED HOLDING TIMES, NEUTRALIZE CHLORINE IN CHLORINE
SENSITIVE SAMPLES, AND SEAL COOLERS WITH TAPE WILL RESULT IN SAMPLES BEING
REJ14,TED BY THIS LABORATORY AS PER NORTH CAROLINA REGULATORY CODE.
1) Samples not falling within the required guidelines will need to be re -collected. The client will be contacted and informed of any
deviation and asked to collect another set of samples. The client may request the laboratory to proceed with the analyses of the current
samples. Any samples analyzed outside of the required guidelines will be "qualified". This means that a note will be included on the
sample result and "Chain of Custody" specifying the deviation. The laboratory is also required to send a letter to the State noting the
deviations.
2) Sample Temperature. Samples for compliance monitoring must be chilled with wet ice to a temperature of 6C or less. Freezing is
not permitted. Samples delivered to the lab shortly after collection may not have had enough time to be chilled below 6C. In this case the
temperature at time of collection must be noted in the space provided. The samples will meet the requirements of the regulation if there
is a temperature drop from the time of collection until received in the lab. Regardless, all samples should be packed in wet ice using as
much ice as will fit in the cooler.
3) Sample Chemical Preservation. Many samples require a chemical preservation such as Sulfuric Acid or Sodium Hydroxide. The
laboratory will either provide the preservative in the sample bottle, or in the case of 40 ml. Volatiles Vials, provide a bottle of Acid with
detailed descriptions on how to collect the sample. Never rinse sample bottles before collecting samples. Any residue or liquid in the
bottle is required for proper chemical preservation. The lab must verify proper chemical preservation upon arrival in the lab and will note
this information in the spaces provided on the front of this form.
4) Chlorine Neutralization. Some samples require that any Total Chlorine Residual be removed at the time of collection. The lab will
provide the proper neutralizing agent in the sample bottle when technically possible. There are some samples (Total Kjeldahl Nitrogen
and Ammonia Nitrogen) where this is not possible due to interferences between the required chemical preservation (Acid) and the
dechlorinating agent. Therefore, these samples must be de -chlorinated at the time of collection before being placed in our sample bottles.
Sodium Thiosulfate is the chemical of choice to neutralize chlorine. It must be added to your sample and then the sample checked for
Total Chlorine before the sample is poured in our bottle. Facilities using chlorine for disinfection should have a means of measuring Total
Chlorine. Non -chlorinated sample sources will not need to be checked. The person neutralizing the chlorine must put his initials in the
"Chlorine Neutralized at Collection" row on the front of this form above the proper parameter. Samples such as Coliforms (which have
Thiosulfate in the bottles shipped from the lab) will be checked for proper neutralization upon arrival in the lab. It is also required that you
note the "Total Chlorine at Collection" on the front of this form for any sample locations applicable. This value would be before any
neutralization is performed.
5) A "C" for Composite Sample or a "G" for Grab Sample should be placed in the box for all requested parameters. Grab temperatures
as well as Composite start dates and times can be recorded in the "comments" section.
6) Other information required to be completed by the client are:
Collection Date and Collection Time for each sample location Temperature at Time of Collection
Printed name of person or persons collecting samples Signature, Date, and Time samples are relinquished
Other added sample locations and analyses required Type Of Disinfection
Deletion on the form for any samples which are not needed (example: dry upstream location)
Any other information felt to be pertinent should be included in the "Comments" section
CONSIDERATIONS:
Coliform and Enterococci samples have a holding time of 6 hours from time of collection to time of analysis. Therefore, samples should
be collected as late in the day as possible to allow enough time for transportation, checking in at the lab and analysis.
BOD, Nitrate, Ortho Phosphorus, Settleable Matter, Turbidity, Color, and MBAS samples have a 48 hour holding time. The lab reserves the
right to establish required sample collection and delivery dates in order to meet the required holding times.
CAUTION
Sample bottles may contain acids or other corrosive and potentially harmful chemicals. Laboratories are required to add these chemicals
for certain analyses in order to comply with EPA preservation requirements. Use extreme care when opening and handling the shipping
container and bottles. If any chemical should get into your eyes, on your skin or on your clothes, flush liberally with water and seek medical
attention. Material Safety Data Sheets (MSDS) are available upon request which specify proper handling and personal protection.