NCG200360_MONITORING INFO_20190205

VV I -f� "D
STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
�V '�� a Qo, j b D
DOC TYPE
❑HISTORICAL FILE
O'MONITORING REPORTS
DOC DATE
p Q 0 1 �D�D�
YYYYMMDD

Semi-annual Stormwater Discharge Monitoring Report (DMR)
for North Carolina DEMLR General Permit o. CG200000 — Scrap Metal Recycling
Date submitted I, -
CERTIFICATE OF COVERAGE NO. NCG200360
FACILITY NAME Southern Metals Recycling, Inc. — Hwy 421 N
COUNTY New Hanover
PERSON COLLECTING SAMPLES Tom Holden
LABORATORY N A Lab Cert. # N/A
Comments on sample collection or analysis: N/A
Part A: Stormwater Benchmarks and Monitoring Results
SAMPLE COLLECTION YEAR 2018
SAMPLE PERIOD ❑ Jan -June ® July -Dec
RECC A f . or ❑ Monthly' (month)
DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA
FEB 0 b 2019 ❑Zero -flaw ❑Water Supply [:]SA
CENTRAL ®Saltwater ®Other SC
EN AL FILE PLEASE REMEMBER TO SIGN ON THE REVERSE 4
® No discharge this period?z
Outfall No.
Date Sample
Collected
(mo/dd/yr)
24-hour rainfall
amount,
Inches3
Total Suspended
Solids
Chemical Oxygen
Demand
Non -polar oil & grease
EPA Method 1664
(SGS-HEM)
Copper,
Total
Lead,
Total
Zinc,
Total
Benchmarks =_>
_
-
100 mg/L or
50 mg/L°
120 mg/L
15 mg/L
0.010 mg/L or
0.005 mg/L5
0.075 mg/L or
0.210 mg/Ls
0:126 mg/L or
0.090 mg/L5
001
N/A
N/A
No Discharge
No Discharge
No Discharge
No Discharge
No Discharge
No Discharge
1 Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
2 For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
3The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
4 See General Permit text, Table 3 or Table 4, identifying protected receiving water classifications where the more protective TSS benchmark applies.
5 Stormwater discharges into receiving waters classified as saltwater are subject to the second listed benchmark.
Note: Results must be reported in numerical format. For example, do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -
numerical format. When results are below the applicable limits, they must be reported in the format, "<XX mg/L", where XX is the numerical value of the
detection limit, reporting limit, quantitation limit, etc. in mg/L.
Permit Date: 02/02/2015-12/31/2019 SWU-256, last revised 1/28/2015
Page 1 of 2

Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
® No discharge this period?'
Outfall Na. '
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches
Non -polar O&G by EPA
1664 (SGT-HEM)
Total Suspended Solids
Benchmarks
15 mg/L
100 mg/L or 50 mg/L°
N/A
Footnotes from Part A also apply to this Part B
Note: If you report a sample value in excess of the benchmark, you must -implement Tier 1, Tier 2, or Tier 3 responses. See General Permit.
FOR PART A AND PART B MONITORING RESULTS:
• A SINGLE BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDANCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ❑ NO ❑
IF YES, HAVE YOU CONTACTED THE DEMLR REGIONAL OFFICE AS REQUIRED BY THE PERMIT? YES ❑ NO ❑
REGIONAL OFFICE CONTACT NAME:
Mail an oriainal and one coDv of this DMR, includina all "No Discharae" reports, within 30 days of receipt of the lab results (or at end of monitorina period
in the case of "No Discharge" reports) to:
Division of Water Resources
Attn: DWR Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
11 //1
.,. x 2j,
(Sign ure of Permitte
Permit Date: 02/02/2015-12/31/2019
. " /A/)// C?
(Date)
SWU-256, last revised 1/28/2015
Page 2 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
GENERAL PERMIT NO. NCG200000
DISCHARGE MONITORING REPORT(Dh7R)
CERTIFICATE OF COVERAGE NO. NCG200360
FACILITY NAME: Southem Metals
PERSON COLLECTING SAMPLES: Braxton Dawson
CERTIFIED LABORATORY! Pace Analytical Laboratories, Charlotte Lab
Pace Analytical Laboratories, Ht>;ntersvllle Lab
COUNTY: New Hanover Capply
PHONE NO. (210)696.91I6
Part A., Specific Mon Itoring Re uiremenfs
SAMPLES COLLECTED DURING
CALENDAR YEAR: ,2Q14
(This monitoring report isldue at the Division no
later than 30 days from tb� date the facility
receives the sampling restilts from the laboratory_)
Outfall
No.
Date
Sample
Collected
mold r
Tout
Rainfall
Inches
00530
00340
00556
00400
01113
01119
00990
101114
DIU94
Total Suspended
Solids
Chemical Oxygen
Demand
M911
OR & Grease
mrA
pH
s.u.
Cadmium
m
Copper
m
]ton'
rngn
Lead'
i
mgA.
Zinc?
to
Benchmark
-
-
100
120
30
6.0-9.0
0.001
0,007
NIA
0.03
0.067
001
0413012014
0.61
363
63
ND
7.85
ND
0.161)
141
; 0.196
.0.662
If a value is in excess of the benchmark, or otaside the benchmark range (for p11), you must implement the Tier 1 or Tier 2 responses In the General Permit.
Total recoverable,
Only complete Part 8 Ff ibis f reifity uses more Man 55 gallons of new molar offper monlfr.
Part U. Vehicle Maintenance Activity Monitoring Requirements
Outfall
No_
Date
Sample
Collected
moldr
Total
Rainfall
inches
Nev Motor 011
Usage
al/month
00530
00400
00556
Total Suspended
Solids
mWt
pH
s.u.
Oil & Grease
mgp
Benchmark
-
-
100
6.0-9.0
30
RECEIVED
Ea
MAY 3 0 2014
CENTRAL F)LtS
DWQIBQG
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and ail attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the in Formation submitted. Based on my inquiry of tht person or persons who mantrge the system, or thase persons directly responsible for gathering the
information, the information submitted 4, to the best of my knowledge and belief; true, accurate, and complete. I am aware that there are significant penalties ror submitting fal:e information,
including the possibility of fines and imprisonment for knowing violations."
{Sign re o Perinitt {1Da e)
NCG200000 DMR Form 5WU-256
Page I of I

, !F-cs f ruJeo,--^�- Z2-1e11Z7
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling our thisform, please visit: htly:/th2o.enr.state.nc.uslsu/Forms_Documents.htm#miscforms
Permit No.: NICI�I 14)L)o1a101 or Certificate of Coverage No.: NICIGI' 0 012;lJIAI
Facility Name:
County: _0 E IN H6-VV1i. it -,I' Phone No.
Inspector: _ 132;&S�+n bo Wf;t,+n (_ 1 ' a�r��
Date of Inspection: �L - 2�,fl —1 q
Time of Inspection: / !�: 00
Total Event Precipitation (inches):
Was this a Representative Storm Event? (See information below) 14 Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
A "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and that 1
is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has
occurred. A single storm event may co 1n p to 10 consecutive hours of no precipitation.
By this signature, Xfktify tj(at tVs #ort is 4-curate and complete to the best of my knowledge:
(Signature of Permitlee of Designee)
I. Outfall Description:
Outfall No. �I Structure (pipe, ditch, etc.)
Reeeivitrg-5ftam: u ;,r-c ► w -. !•w r,a J S, ;) S
Describe the industrial activities that occur within the outfall drainage area:
S1 CV
2. Color: Describe the color of the discharge u ing bncolors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: i t
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.): lvorue
Page I of 2
S wU-242.1 126o1i

4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear
and 5 is very cloudy:
1 2 C3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
I
!O 2 4 S
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 0 4 5
7. Is there any foam in the stormwater discharge? Yes No
8. is there an oil sheen in the stormwater discharge? Yes
9. Is there evidence of erosion or deposition at the outfall? es No
115 a re3,,j4 of S;L--J�!lcw i�� jA' -rv.,,, � S,5a A,d,SK^r`�-Q d'Zz
kv
)OC ca— 75 �3c "�'Pr dot � �Q �! J/�i.,Y't po-tvn aF 11-0 S' k .
10. Other Obvious Indicators of Stormwater Pollution:
List and describe
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
S W U-242-112608

F _.._�___.__.____i
ECS C A R OU N A S, LLP "Setting the Standard for Service"
�. Geotechnical • Construction Materials • Environmental • Facilities hCRetpslarUucnpncLruvtFirmF-tU7R
May 20, 2014
Central Files
Division of Water Quality
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Reference: NPDES Stormwater Monitoring Services
Stormwater General Permit NCG200000
Southern Metals Recycling, Inc.
2923 Highway 421 North
Wilmington, New Hanover County, North Carolina
ECS Project No. 22-19727
To whom it may concern,
ECS has been retained by Mr. Jeremy Alper of Southern Metals Recycling to assist with the
monitoring, sampling, and reporting requirements as per the conditions set forth by the
Stormwater General Permit NCG2000000.
Project Background
The approximate 12-acre site is located at 2923 Highway 421 North in Wilmington, New
Hanover County, North Carolina. The site is identified by the New Hanover County GIS as
Parcel Identification Numbers R03200-004-001-001 and R03200-004-001-002. The site is
currently owned by Alper Company, LLC and Southern Metals Recycling. The facility is
currently operating under North Carolina General Permit No. NCG200000, Discharge of
Stormwater under the National Pollutant Discharge Elimination system (NPDES) and Certificate
of Coverage No. NCG200360.
According to the Storm Water Pollution Prevention Plan dated October 27, 2010, the majority of
the site drainage flows to the southwest, to a stormwater detention pond. During a previous
site visit by the North Carolina Division of Water Resources, a discrete stormwater discharge
location was identified on the northern site boundary (01). Discharge from the stormwater
detention pond was not observed. Additionally, a berm has been constructed along the
southern boundary of the site. A discrete stormwater discharge location was not observed
along the southern boundary of the site. In order to comply with the permit, the facility must
perform semi-annual analytical and qualitative stormwater monitoring at a single point
stormwater discharge outfall during representative storm events.
Site Description
The site is currently occupied by Southern Metals Recycling, a metal recycling facility. Southern
Metals Recycling, Inc. is approximately 12-acres in area and collects, handles, sorts, processes,
and transports nonferrous metals, ferrous metals, and other scrap metal (engine blocks,
transmissions, grilling equipment, etc.).
6714 Netherlands Drive, Wilmington, NC 28405 • T: 910-686-9114 • F: 910-686-9666 • www.ecslimited.com
ECS Carolinas, LLP • ECS Florida, LLC • ECS Midwest, LLC • ECS Mid -Atlantic, LLC • ECS Southeast, LLC • ECS Texas, LLP

Stormwater Monitoring
Southern Metals Recycling, Inc.
Wilmington, New Hanover County, North Carolina
ECS Project No. 22-19727
May 20, 2014
Field Activities
On April 30, 2014, ECS performed a site visit during a qualifying rain event. Downpour
conditions were noted during the site visit. ECS did not observe stormwater discharge from the
detention pond, or along the southern boundary of the site. At the time of the site visit, the
water level in stormwater detention pond was approximately two to three feet below the top of
the detention pond. According to the on -site rain gauge, it rained 0.67 inches on April 30,
20914. No measurable rainfall during the preceding three days was recorded.
Stormwater discharge was observed from 01. A water sample was collected during our site
reconnaissance.
The water sample was collected using a new pair of nitrite gloves and laboratory prepared
containers. The sample containers were labeled with the project name, sample location and the
date and time that the samples were collected, placed in a cooler containing ice (41C), and
delivered to a State of North Carolina -certified analytical laboratory, Pace Analytical Laboratories,
Inc. (Pace) in Asheville, North Carolina under standard chain -of -custody protocol. The water
samples were analyzed for chemical oxygen demand, total suspended solids, oil & grease using
EPA method 1664A, and metals (cadmium, iron, lead and zinc) using EPA method 200.7. A copy
of the analytical chain of custody is attached. The pH, conductivity, and temperature were
measured by ECS at the time of sample collection. ECS' laboratory certification for these field
parameters is 5487.
The concentrations of total suspended solids, copper, lead, and zinc exceeded the regulatory
benchmark values. A table of the laboratory results are included on the Stormwater Discharge
Outfall (SDO) form. Findings from the qualitative analysis are enclosed.
Tier One Response Actions
1. ECS has conducted as stormwater management inspection of the facility during the field
reconnaissance on April 30, 2014, and in October 2014. The majority of the site
appears to drain to the stormwater detention pond on the southwest portion of the site.
Stormwater discharge 01 appears to collect runoff from the access road along the
northern portion of the site (see Figure 1).
2. The increased concentrations of total suspended solids are a result of stormwater runoff
from an unpaved access road. The site is currently used for metal recycling and was
historically used as a steel manufacturer. The increased concentrations of copper, lead,
and zinc may be from the on -site activity or background concentrations of metals in the
soil.
3. ECS is currently coordinating with the Southern Metals Recycling, Inc. to determine how
to bring the concentrations to within the benchmark range.
4. Step 4 is currently underway.

Stormwater Monitoring
Southern Metals Recycling, Inc.
Wilmington, New Hanover County, North Carolina
ECS Project No. 22-19727
May 20, 2014
Conclusion
ECS understands the concentrations of total suspended solids, copper, lead, and zinc exceeded
the regulatory benchmark values. ECS will continue to coordinate with Southern Metals
Recycling, Inc. and work towards a solution for the matter. If you have any questions or
comments concerning the contents of this report, please contact us at [phone],
Respectfully submitted,
ECS Carolinas, LLP
C. Paul Pascarosa Amy C. chas, REM
Environmental Project Manager Environmental Principal
cc: Mr. Tom Holden, Southern Metals Recycling, Inc.
Mr. David Cox, Division of Water Resources
Enclosures: Figure
SDO Discharge Monitoring Report
SDO Qualitative Monitoring Report
Analytical Results
3

L-0-- k-A.

laneAnalyfical"
WW.P oekbs.c=
May 08, 2014
Braxton Dawson
ECS Carolinas, LLP
7211 Ogden Business Park
Suite 201
Wilmington, NC 28411
RE: Project: SOUTHERN METALS
Pace Project No.: 92199619
Dear Braxton Dawson:
Pate Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
{704)875-9092
Enclosed are the analytical results for sample(s) received by the laboratory on May 02, 2014. The
results relate only to the samples included in this report. Results reported herein conform to the
most current TN standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
o-4)1-�
Angela Baioni
[e-mail]
Project Manager
Enclosures
cc: Ms. Amy Conchas, ECS
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 11

aceAnalytical.
~..pacerabicorn
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: SOUTHERN METALS
Pace Project No.: 92199619
Charlotte Certification (Ds
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
West Virginia Certification #: 357
North Carolina Wastewater Certification #: 12
VirginiaNELAP Certification #: 460221
South Carolina Certification #: 99006001
Asheville Certification IDs
2225 Riverside Dr., Asheville, NC 28804 North Carolina Wastewater Certification #: 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #: M-NCO30 West Virginia Certification #: 356
North Carolina Drinking Water Certification #: 37712 VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, tnc.. Page 2 of 11

acMnalyflcal
wwwpacelabs.corn
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: SOUTHERN METALS
Pace Project No.: 92199619
Sample: SW-1 Lab ID: 92199619001 Collected: 04130/14 15:00 Received: 05/02/14 09:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. 4uai
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L
5.0
1
05/05/14 08:28
200.7 MET ICP
Analytical Method: EPA 200.7 Preparation
Method: EPA
200.7
Cadmium
ND ug/L
1.0
1
05/06/14 11:15
05/08/14 12:22
7440-43-9
Copper
160 ug/L
5.0
1
05/06/14 11:15
05/07/14 1915
7440-50-8
Iron
14100 ug/L
50.0
1
05/06/14 11:15
05/07/14 19:15
7439-89-6
Lead
196 ug/L
5.0
1
05/06/14 11 A 5
05/07/14 19.15
7439-92-1
Zinc
662 ug/L
10.0
1
05/06114 11:15
05/07/14 19:15
7440-66-6
25400 Total Suspended Solids
Analytical Method: SM 2540D
Total Suspended Solids
363 mg1L
25.0
1
05/07/14 16:53
5220D COD
Analytical Method: SM 5220D
Chemical Oxygen Demand
83.0 mg1L
25.0
1
05/07/14 17:10
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
Date: 05/08/2014 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 3 of 11

(�Iacmnalyficalo
www.Perglabxcnm
Project: SOUTHERN METALS
Pace Project No.: 92199619
QC Batch: GCSV117465
QC Batch Method: EPA 1664B
Associated Lab Samples: 92199619001
METHOD BLANK: 1191081
Associated Lab Samples: 92199619001
Parameter Units
Oil and Grease mg/L
QUALITY CONTROL DATA
Analysis Method: EPA 1664B
Analysis Description: 1664 HEM, Oil and Grease
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 05/05/14 08:27
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huniersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
1191082
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Oil and Grease
mg1L
40 38.2
96
78-114
MATRIX SPIKE SAMPLE:
1191083
92199449001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg/L
ND 41.2
38.6
94 78-114
Date: 05/0812014 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 11

aceAnalyiical
wwwpecafa6acom
Project: SOUTHERN METALS
Pace Project No.: 92199619
QC Batch: MPRP115870
QC Batch Method: EPA 200.7
Associated Lab Samples: 92199619001
METHOD BLANK: 1191605
Associated Lab Samples: 92199619001
Parameter
Units
Cadmium
ug/L
Copper
ug1L
Iron
ug/L
Lead
ug/L
Zinc
uglL
QUALITY CONTROL DATA
Analysis Method: EPA 200.7
Analysis Description: 200.7 MET
Matrix: Water
Blank
Reporting
Result
Limit
Analyzed
NO
1.0
05/07/1418:01
NO
5.0
05/07/1418:01
ND
50.0
05107/1418:01
NO
5.0
05/07/1418:01
ND
10.0
05/07/141&01
Qualifiers
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
1191606
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Cadmium
ug/L
500
480
96
85-115
Copper
ug/L
500
480
96
85-115
Iron
ug/L
5000
4710
94
85-115
Lead
ug/L
500
488
98
85-115
Zinc
ug/L
500
481
96
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1191607
1191608
MS
MSD
92199542010
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Cadmium
ug/L
NO
500
500
484
480
97
96
70-130
1
Copper
ug/L
NO
500
500
488
485
97
96
70-130
1
Iron
ug/L
0.42
5000
5000
5280
5250
97
97
70-130
0
mg/L
Lead
ug/L
NO
500
500
485
482
97
96
70-130
1
Zinc
ug/L
NO
500
500
483
478
96
95
70-130
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1191609
1191610
MS
MSD
92199469001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Cadmium
ug1L
ND
500
500
489
482
98
96
70-130
1
Copper
ug/L
0,37
500
500
846
846
96
96
70-130
0
mg1L
Iron
ug/L
0A5
5000
5000
5000
4920
97
95
70-130
2
mg1L
Lead
ug/L
0.0099
500
500
497
492
97
97
70-130
1
mg/L
Zinc
ug/L
0.024
500
500
513
510
98
97
70-130
1
mg/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2014 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 5 of 11

ace Analytical
www.pacelsbs.cem
Project: SOUTHERN METALS
Pace Project No.: 92199619
QC Batch: WET130898
QC Batch Method: SM 2540D
Associated Lab Samples. 92199619001
METHOD BLANK: 1193552
Associated Lab Samples: 92199619001
Parameter Units
Total Suspended Solids mglL
LABORATORY CONTROL SAMPLE: 1193553
Parameter Units
Total Suspended Solids mglL
SAMPLE DUPLICATE: 1193554
Parameter Units
Total Suspended Solids mg/L
SAMPLE DUPLICATE: 1193555
Parameter Units
Total Suspended Solids mg/L
Date: 05/08/2014 04:00 PM
Pace Analytical Services, Inc.
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Analysis Method: SM 2540D
Analysis Description: 2540D Total Suspended Solids
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.5 05/07/1416:43
Spike LCS LCS % Rec
Conc. Result % Rec. Limits Qualifiers
250 240 96 80-120
92199425001 Dup
Result Result
ND ND
92199485005 Dup
Result Result
ND ND
RPD Qualifiers
RPD Qualifiers
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 6 of 11

aceAnalytical
www.pacelab&cnrn
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
SOUTHERN METALS
Pace Project No.:
92199619
QC Batch:
WETAl18889 Analysis Method: SM 5220D
QC Batch Method:
SM 5220D Analysis Description: 5220D COD
Associated Lab Samples: 92199619001
METHOD BLANK: 1191647
Associated Lab Samples: 92199619001
Parameter Units
Chemical Oxygen Demand mglL
LABORATORY CONTROL SAMPLE: 1191648
Parameter Units
Chemical Oxygen Demand mg1L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 05/07/1417:10
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
750 735 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1191649 1191650
MS MSD
92199473001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 721 750 750 1390 1380 89 88 75-125 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1191651 1191652
MS MSD
92199029013 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L NO 750 750 763 772 99 100 75-125 1
Date: 05/08/2014 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wntten consent of Pace Analytical Services, Inc..
Page 7 of 11

ace Analytical
"M..pacelabs.own
QUALIFIERS
Project: SOUTHERN METALS
Pace Project No.: 92199619
DEFINITIONS
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huniersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to changes in sample preparation, dilution of
the sample aliquot, or moisture content.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PRL - Pace Reporting Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine (8270 listed analyte) decomposes to Azobenzene.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270, The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chioroethylvinyl ether, Styrene, and Vinyl chloride.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/08/2014 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 11

aceAnalytical
www.Peoelah3.0=
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: SOUTHERN METALS
Pace Project No.: 921,39619
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab 10
Sample ID
QC Batch Method
QC Batch Analytical Method
92199619001
SW-1
EPA 1664E
GCSV117465
92199619001
SW-1
EPA 200.7
MPRP115870 EPA 200.7
92199619001
SW-1
SM 2540D
WET130898
92199619001
SW-1
SM 5220D
WETA118889
Date: 05108/2014 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report Shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Analytical
Batch
ICPI14369
Page 9 of 11

DOCtrr Ont Name: Sample Condition Upon Document Roviscd: June it, 2013
j f,..f��lCb'/iI181y[!c8/ Receipt SCUR fare 1 of 2
"'""" `""' Dorunrenl No.: Issuing Aulhorifies:
F-ASV-CS-003-rr:v.11 Paco Asheville Quality Office
nt Name:
77
Clie_ �Y ,:.,.;'V
Where Roceived: Hllllt(1r5VIllD LJ"f shcville J Eden #J Raleigh
Courier (Circle): l;r:d Ex UPS USPS Client Commercial Paco Other__
Custody Seal on Cooler/Box Present: J, yes ('/ no Seals intact: ❑ yes Q no
Packing Matorinl: 0' Bubble Wrap Bubblo Bags 0 None ❑ Other
Circle Thermometer Used: I(2 Gun#3 •130265903 Type of Ice: (Wet 81ue None a/Samples or) ice, cooling prorwrss lids begun
1R Gun 112- EW_ M?IO;f9
Tenn Correction ll Add ! Subtract C
i ;;'r
Corrected Cooler Temp,: t C
'
Biological Tissue is Frozen: Yes No 15'A
Dato and lnillalsbf person okrrmtning
, ..
��' �;
,•
contents:_, 1 I ' P
Tcrnp should be above freezing 10 G'C
f
Comments:
_l:r
i
C.;hnin of Custody Presenl:
C}Ye:;,0140
ONM
1.
Chain of Custody Fined Out:
OY06�ONo
❑wA
2.
Chain of Custody Relinquished:
C1Yos"01•10
❑NIA
3.
Samplr'r Name i Signallrre on COC:
L'1Yc3 'l
❑wA
4.
Samples Arrived within Hold Time
hJYes LINO �0 1A
S.
Short Hold Time Analysis (<72hr):
Dyes El o't5NlA
G.
Rush Turn Around Time Requested:
DYes.tJNo
DwA
7.
Sufficient Volume:
/
f7Yca''0No
❑wA
8.
Correct Containers Used:
0Yes ,ONO
ON1A
9.
-Pace Containers Used:
❑Yes=ONo
❑NIA
Containers Intar'l:
/
C1Yes ❑Na
ll
10.
Filtered volume received for Dissolved tests
E1Yep' (ONo
0 wA
11,
Sanmplo Labels match COC:
Dyes ONo
❑wA
12.
-includes date/timoliDIAnalysis Matrix:
i
All containers needing preservation have been chucked.
OYas ,3] o
©wA
13,
All containers needing preservation are found to be in
/
L1Y. [-]No
0WA
con7plfancn -.0h EPA recommendation.
r
❑Yraj
uxcoplions: VOA, callus In, TOC, O&G, WI-DRO (tvator)
No
Saunptes checked for dechlorina[ion:
UYes ONo
❑con
14,
Headspaco in VOA Vials >Gmm :
❑Yus ❑No
0 A
,15.
Trip Blank Present:
❑Yes ONa
ONIA
16.
r`
Trip Slank Custody Seals Present
ll ❑No
0 IA
Puce'frip Blank Lot !! (if ptrrrhased):
Client Notification! Resolution:
Person Contacted: Date/Time:
Comments! Resolution:
SCURF R©viowd P� IDato:
Sill R vfow: I thm IDate:
Note: Whenever there is a discrepancy affecting North Carolina
Compliance Samples, ti copy of this form will be sent to the North
Carolina DEHNR Ce.rtifiration OHico ( i.e out of hold, incorrect
preservative, out of temp, incorrect containers)
Field Data Required? Y I N
Place label hero
Handwrlto project number
(If no label available)
gzt��c�i�
Page 10 of 11

PkpAnalvtical
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chaird-Cus•,ady is a LEGAL DOCUMENT. Alt relovant ticlds must be completed accuraLety.
.r. pailts'..0m
P,ae
Section A section B Section C
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Required Cant lr;orr..�yen: Required Project Infom.tauon: Invoico Information:
Company. R'•P0.: TO: AltenSial: Q,J Lr
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REGULATORY AGENCY
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Analysis
Filtered
(YIN)
Section D Matrix Codas
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COLLECTED
Preservatives
:
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DATE
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ANPiE CONDMONS
SAMPLER NAME ANO SIGNATURE
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SIGNATURE asAt:,Plt¢t� jy-/C!j
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