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HomeMy WebLinkAboutNC0003425_Report_20180101ROXBORO STEAM ELECTRIC PLANT 2017-2018 ENVIRONMENTAL MONITORING REPORT November 2019 Water Resources DUKE ENERGY Raleigh, North Carolina Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Preface This copy of the report is not a controlled document as detailed in the Environmental Services Biology Program Quality Assurance Manual. Any changes made to the original of this report subsequent to the date of issuance can be obtained from: Water Resources DUKE ENERGY 410 South Wilmington Street Raleigh, North Carolina 27601 Duke Energy Progress i Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table of Contents Page Preface......................................................................................................................................... i Listof Tables............................................................................................................................... iii Listof Figures.............................................................................................................................. iii Listof Appendices....................................................................................................................... iii Metric -English Conversion and Units of Measure...................................................................... v WaterChemistry Abbreviations.................................................................................................. v ExecutiveSummary..................................................................................................................... vi 2017-2018 Environmental Monitoring Report............................................................................ 1 HistoricalOverview............................................................................................................... 1 ReservoirDescription............................................................................................................ 3 Objectivesand Methods........................................................................................................ 3 Environmental Monitoring Results for 2017-2018................................................................ 9 Limnology........................................................................................................................ 9 Temperature and Dissolved Oxygen......................................................................... 9 Water Clarity Constituents........................................................................................ 10 Nutrients and Phytoplankton Biomass....................................................................... 10 Ions, Hardness, and Specific Conductance................................................................ 10 Alkalinityand pH...................................................................................................... 11 TraceElements................................................................................................................ 11 Arsenic....................................................................................................................... 11 Cadmium.................................................................................................................... 12 Copper........................................................................................................................ 12 Manganese................................................................................................................. 13 Mercury...................................................................................................................... 13 Selenium.................................................................................................................... 14 Thallium..................................................................................................................... 14 Fisheries........................................................................................................................... 15 Fish Species Composition.......................................................................................... 15 Fish Abundance, Distribution, and Size Structure..................................................... 15 Balanced Indigenous Community.............................................................................. 18 FishCommunity Health............................................................................................. 19 BiofoulingMonitoring..................................................................................................... 19 Summary and Conclusions.......................................................................................................... 19 References.................................................................................................................................... 20 Duke Energy Progress ii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report List of Tables Table Page 1 Hyco Reservoir environmental monitoring program ............................................... 6 2 Field sampling and laboratory methods utilized in the Hyco Reservoir environmental monitoring program......................................................................... 7 3 Statistical analyses performed on data collected for the Hyco Reservoir environmental monitoring program......................................................................... 8 List of Figures Figure Page 1 Hyco Reservoir sampling locations......................................................................... 5 List of Appendices Appendix Page 1 Depth profiles of water temperature, dissolved oxygen, pH, and specific conductance at Hyco Reservoir during 2017........................................................... 22 2 Depth profiles of water temperature, dissolved oxygen, pH, and specific conductance at Hyco Reservoir during 2018........................................................... 24 3 Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2017....................................................... 26 4 Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2018....................................................... 27 5 Concentrations of chemical variables in surface waters of Hyco Reservoir during 2017.................................................................................... 28 6 Concentrations of chemical variables in surface waters of Hyco Reservoir during 2018.................................................................................... 31 7 Long-term trends of selected parameters at Station B2 from Hyco Reservoir from2009 through 2018.......................................................................................... 34 8 Long-term trends of selected parameters at Station C2 from Hyco Reservoir from 2009 through 2018.......................................................................................... 33 Duke Energy Progress iii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 9 Long-term trends of selected parameters at Station D2 from Hyco Reservoir from 2009 through 2018.......................................................................................... 36 10 Long-term trends of selected parameters at Station F2 from Hyco Reservoir from 2009 through 2018.......................................................................................... 37 11 Means and standard errors of trace element concentrations in sediments and fish by transect from Hyco Reservoir during 2017................................................. 38 12 Means and standard errors of trace element concentrations in sediments and fish by transect from Hyco Reservoir during 2018................................................. 39 13 Long-term trends of selenium concentrations in Bluegill, Largemouth Bass, and White Catfish muscle tissues at Transect C and Transect D from Hyco Reservoir from 2009 through 2018................................................................ 40 14 Total number and weight of fish collected with electrofishing from Hyco Reservoir during 2017 and 2018......................................................................... 15 16 17 19 20 21 22 23 Mean catch per hour of fish collected with electrofishing by transect from Hyco Reservoirduring 2017........................................................................................... Mean catch per hour of fish collected with electrofishing by transect from Hyco Reservoirduring 2018........................................................................................... Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2017.................................................... Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2018................................................ Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2017................................................ Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2018................................................ Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2017................................................ Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2018................................................ 41 42 43 45 46 47 ED Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2017 ............................... 50 24 Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2018 ............................... 51 Duke Energy Progress iv Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 Proportional Size Distribution ranges for balanced populations of Bluegill versus Largemouth Bass and Gizzard Shad versus Largemouth Bass collected from Hyco Reservoir during 2017 and 2018.................................................................... 52 Duke Energy Progress v Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Metric -English Conversion and Units of Measure Length 1 micron (µm) = 4.0 x 10' inch 1 millimeter (mm) = 1000 µm = 0.04 inch 1 centimeter (cm) = 10 mm = 0.4 inch 1 meter (m) = 100 cm = 3.28 feet 1 kilometer (km) = 1000 m = 0.62 mile Area 1 square meter (m2) = 10.76 square feet 1 hectare (ha) = 10,000 m2 = 2.47 acres Volume 1 milliliter (ml) = 0.034 fluid ounce 1 liter = 1000 ml = 0.26 gallon 1 cubic meter = 35.3 cubic feet Weight 1 microgram (µg) = 10-3 mg or 10-6 g = 3.5 x 10-8 ounce 1 milligram (mg) = 3.5 x 10-5 ounce 1 gram (g) = 1000 mg = 0.035 ounce 1 kilogram (kg) = 1000 g = 2.2 pounds 1 metric ton = 1000 kg = 1.1 tons 1 kg/hectare = 0.89 pound/acre Temperature Degrees Celsius (°C) = 5/9 (°F-32) Specific Conductance µS/cm = Microsiemens/centimeter Turbidity NTU = Nephelometric Turbidity Unit Water Chemistry Abbreviations Cl- - Chloride TDS - Total dissolved solids Al - Total aluminum S02"4 - Sulfate TSS - Total suspended solids As - Total arsenic Cat+ - Total calcium TOC - Total organic carbon Cd - Total cadmium Mgt+ - Total magnesium TP - Total phosphorus Cu - Total copper Na+ - Total sodium TN - Total nitrogen Hg - Total mercury TS - Total solids NH3-N - Ammonia nitrogen Se - Total selenium NO3+ NO2-N - Nitrate +nitrite - nitrogen Duke Energy Progress vi Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Executive Summary During 2017 and 2018, surface water temperatures, dissolved oxygen concentrations, pH, specific conductance, and Secchi disk visibility remained within the ranges previously observed in Hyco Reservoir depending on location. A number of limnological variables measured in the reservoir surface waters including calcium, chloride, hardness, total dissolved solids, and specific conductance have stabilized (i.e., trend not increasing) compared to previous years despite some seasonal variation during 2017 and 2018, primarily due to lower power plant dispatch rates and operation of the Flue Gas Desulfurization System. Concentrations of target trace elements, including arsenic, cadmium, copper, mercury, and selenium, measured in the reservoir surface waters remained below water quality criteria during 2017 and 2018. However, selenium concentrations in the muscle tissues of Bluegill, White Catfish, and Largemouth Bass continued to be statistically greater at the monitoring location near the discharge compared to the concentrations at the designated upstream comparison monitoring location during 2017. In 2018, only White Catfish had statistically greater selenium concentrations in muscle tissues at the monitoring location near the discharge compared to the concentrations in the fish located at the upstream monitoring location. Despite receiving a thermal discharge, the fish community in Hyco Reservoir remained a self- sustaining, balanced population of regionally common species during 2017 and 2018. Duke Energy Progress vii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Historical Overview Duke Energy Progress (DEP; formerly Carolina Power & Light) began construction of Hyco Reservoir in 1963 to serve as a cooling water source and receiving water discharges from the Roxboro Steam Electric Plant (Roxboro Plant). After reaching full pool in 1965, the reservoir was noted as a popular fishery throughout the remainder of the 1960s and most of the 1970s. In 1980, a large-scale fish kill was observed throughout much of the reservoir after the start-up of Unit 4. Biological monitoring conducted by Company biologists showed continued declines in the fishery. Special experimental bioassay studies were conducted and ultimately determined that elevated concentrations of selenium in the water, food chain, and fish tissues were responsible (i.e., reproductive impairment) for the observed sport fishery decline in Hyco Reservoir. As a result of elevated selenium concentrations in fish, the North Carolina Division of Health Services, Department of Health and Human Services, issued an advisory in August 1988 recommending limitations on human consumption of all fish species from Hyco Reservoir. In 1989, DEP completed the constructed a dry ash handling system to reduce selenium input into Hyco Reservoir. After the startup of the dry ash handling system in late 1989, biological monitoring studies conducted under the Roxboro Plant National Pollutant Discharge Elimination System (NPDES) permit demonstrated the effectiveness of the dry fly ash handling system in limiting the amount of selenium entering the reservoir (CP&L 1991 and 2001, PEC 2008). Selenium concentrations quickly decreased in the reservoir after the dry fly ash handling system began operation and have remained below the North Carolina water quality standard of 5µg/liter since 1990. Changes in the aquatic community also reflected the reduced selenium loading into the reservoir. A gradual shift from selenium -tolerant fish species to species more typical of southeastern piedmont impoundments was observed following the commencement of dry ash handling operations. The fish consumption advisory was modified several times during the recovery period to remove species from the consumption advisory list as selenium concentrations in the edible flesh of each individual fish species declined below the established threshold level (i.e., 25 µg/g dry weight at the time; it was revised to 50 µg/g dry weight in the mid-2000s). In August 2001, the fish consumption advisory on reservoir was completely rescinded. Hyco Reservoir limnological variables remained mostly unchanged during the period from 2002 through 2006 and were within the range of values expected for a North Duke Energy Progress 1 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Carolina piedmont impoundment. During 2007, the reservoir was subjected to the most extensive drought on record (based on 110-year USGS streamflow records) in North Carolina, which affected water levels severely. The water levels decreased from full pool of 124.9 meters National Geodetic Vertical Datum (NGVD) during May 2007 to slightly above the critical elevation of 123.4 meters NGVD in October 2007 when a substantial rain event reversed the decreasing trend in reservoir water levels. The drought event and subsequent decrease in lake level was important given that impacts to plant operations begin to occur when reservoir levels reach 123.4 meters NGDV. Despite minimal flushing of the reservoir through most of 2007, no overall changes to limnological variables, including selenium concentrations, were noted that year compared to previous years following dry fly ash operations. However, an increase in the mean selenium concentrations was observed in muscle tissues of fish collected near the power plant discharge to Hyco Reservoir. While no increase in selenium mass loading to Hyco Reservoir occurred during this period due to plant operations, decreased reservoir flushing likely allowed more selenium to enter the food web and thus influenced tissue concentrations in fish and other trophic level species. With the passage of the North Carolina Clean Smokestacks Act of 2002, coal-fired power plants were required to reduce sulfur emissions 73 percent by 2013. To help meet the requirement fleet -wide, Flue Gas Desulfurization (FGD) systems (one on each of the four units) were installed at the Roxboro Plant and wastewater from these treatment systems began discharging in February of 2008. During the period from 2008 until 2016, a number of limnological constituents including calcium, chloride, hardness, and total dissolved solids gradually increased throughout the reservoir until recently. However, trace elements such as arsenic, copper, and selenium in surface waters have continued to remain below water quality criteria and/or below the laboratory reporting limits. Beginning in 2014 with the lower cost of natural gas, the Roxboro Plant annual dispatch rates decreased from the historical 70%-75% range to an average rate of 60% in 2014, 43% in 2015, and even lower dispatch rates through 2018. The lower dispatch rates for the Roxboro Plant have resulted in reduced discharges of constituents from the FGD systems as well as lower overall thermal discharge to the reservoir. With the reduce thermal loading to the reservoir, impacts to the two non-native tilapia species, Blue Tilapia and Redbelly Tilapia, have become apparent with reduce catch of these species during fisheries sampling. Tilapia can help control certain vegetation such as naiad and pondweed It is possible that the reservoir will experience nuisance aquatic vegetation problems as the growth control of these plant species declines along with the tilapia. Duke Energy Progress 2 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Reservoir Description Hyco Reservoir, an impoundment of the Hyco River, is located approximately 5 km south of the North Carolina/Virginia border in Person and Caswell Counties in the northern Piedmont of North Carolina. After impoundment, the reservoir water level reached full pool elevation in 1965. Hyco Reservoir serves as a cooling lake and source of water for the Roxboro Plant. The reservoir has a surface area of 17.6 km2 (1760 ha); a volume of 9.62 x 107 m3; a drainage area of 471 km2; a mean depth of 6.1 in; a normal elevation of 125.1 in NGVD; an average inflow of 5.7 m3/second; and a mean residence time of approximately 6 months. The land use along the 256-km shoreline is primarily residential and secondarily industrial/agricultural. It is classified by the North Carolina Division of Resource as WS-V, B. This is defined as suitable for primary recreation, aquatic life propagation and maintenance, wildlife, and agriculture and is suitable for water supply for use by industry to supply to their employees, but not to municipalities or counties with a raw drinking water supply source. For environmental monitoring purposes, sampling transects and stations throughout the reservoir were selected based on their location relative to the power plant effluents entering the main body of the reservoir at Transect 4 (Figure 1). Transect B is located in the upper reservoir in the North Hyco arm and Transects C and SHHW 1 are located in the upper reservoir in South Hyco arm. Transect F is located in the lower reservoir adjacent to the spillway. Objectives and Methods The primary objective of the Roxboro Plant 2017-2018 environmental monitoring program was to provide an assessment of the effect of power plant operations on the water and aquatic organisms of Hyco Reservoir. Secondary objectives of the program were to document environmental factors impacting the aquatic community that were not attributable to the power plant, as well as the impact of non-native aquatic plant and animal species on the reservoir. These objectives were consistent with the biological monitoring requirements in the NPDES Permit NC0003425. Limnology (water quality, water chemistry, and chlorophyll a) and trace elements in fish tissues and sediments (Transects C and D only) were assessed in the reservoir (Figure 1; Tables 1 and 2), and the results were analyzed using appropriate statistical methods (Table 3). The water chemistry analysis portion of the limnological variables was performed by laboratories certified by the North Carolina Department of Environmental Quality (NCDEQ) in water and wastewater testing. Trace element analyses of sediment and tissues of fish were conducted by an external laboratory using approved analytical Duke Energy Progress 3 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report methods (EPA methods 6020 and 7471). The accuracy and precision of laboratory analyses of water chemistry and trace element data were determined with analytical standards, sample replicates, and reference materials. For calculation of means in this report, concentrations less than the reporting limit and not estimated were assumed to be at one-half the reporting limit. Duke Energy Progress 4 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Roxboro Steam Electric Plant North Hyco River % \ ay Cane Creek Reservoir r Spillway - Cy 6 S � A (Outran #006) Auxiliary Intake -� Main - Dam 5 Discharge D (Outfa ll #003) Intake Canal 4- Gypsum Storage Pad E 4 \ C 8 Dry A, Ash _ ` 1 Landfill Flush Pond Gypsum C) ttliSeng -� Ash J5 Pond Pond s�n \ 1 Person -Caswell 4 - Lake Authority Cobbs Creek 0 0.5 1 2 Miles Figure 1. Hyco Reservoir sampling locations. South Hyco River 0 0.75 1.5 Kilometers 3 Duke Energy Progress 5 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 1. Hyco Reservoir environmental monitoring program. Program Frequency Location Water quality Alternate calendar months (February, April, June, August, October, December) Water chemistry Alternate calendar months (including trace (February, April, June, August, October, elements in water) December) Phytoplankton+ Alternate calendar months (February, April, June, August, October, December) Chlorophyll a Alternate calendar months (February, April, June, August, October, December) Zebra and quagga Alternate calendar months mussels (February, April, June, August, October, December) Electrofishing Once every three calendar months (March, June, September, December) Trace elements Once per calendar year (fish & sediments) Stations B2, C2, D2, F2, SHHW 1 (surface to bottom at 1-m intervals) Stations B2, C2, D2, F2, SHHW 1 (surface) Stations B2, C2, D2, F2 Stations B2, C2, D2, F2 Main intake structure or water quality station buoys Stations Al, A3, 131, B3, Cl, C3, D1, D5, F1, F3 Transects C and D +Phytoplankton samples were collected and preserved but were not identified because all chlorophyll a concentrations measured during 2017 and 2018 were less than 40 mg/L. Duke Energy Progress 6 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 2. Field sampling and laboratory methods utilized in the Hyco Reservoir environmental monitoring program. Program Method Water quality Temperature, dissolved oxygen, pH, and specific conductance were measured with calibrated multiparameter instruments. Measurements were taken from the surface to the bottom at 1-m intervals in accordance with procedure NR-00096 Water clarity was measured with a Secchi disk. Turbidity was measured with a HACH model 2100Q turbidimeter in accordance with procedure WR-00070. Water Surface samples were collected either directly or with a nonmetallic sampler, chemistry transferred to appropriate containers, transported to the laboratory on ice, and analyzed according to USEPA (1979) and APHA 2012. Phytoplankton Samples were collected by two methods. Method one used equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth collected with a Van Dorn beta sampler and mixed in a plastic container. Method two used an integrated depth sampler to collect representative photic zone composite samples from the surface to twice Secchi disk transparency depth. The samples were placed in dark bottles, and transported to the laboratory on ice. Chlorophyll a Samples were collected by two methods. Method one used equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth collected with a Van Dorn beta sampler and mixed in a plastic container. Method two used an integrated depth sampler to collect representative photic zone composite samples from the surface to twice Secchi disk transparency depth. The samples were placed in 1000 mL dark bottles and transported to the laboratory on ice. In the laboratory, 250-mL subsamples were analyzed (NR-00103). Electrofishing Fifteen -minute samples were collected at each station using a Smith -Root Type 7.5 gpp equipped, Wisconsin -design electrofishing boat with pulsed DC current. Fish were identified, measured to nearest mm, weighed to nearest gram, examined for presence of disease and deformities, and released based NR-00080, Rev 1. Trace elements Water, sediments, and muscle tissue of selected fish were analyzed by standard analytical techniques in the laboratory for selected trace metals and metalloids. All media, except water, were homogenized and freeze-dried. All samples were analyzed by an external laboratory using EPA methods 6020 and 7471. Quality control was achieved by analytical standards, replicates, and certified reference materials Mussel surveys Hardened structures such as docks and buoys were visually inspected for the presence of zebra mussels and quagga mussels during routine water quality monitoring. Duke Energy Progress 7 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 3. Statistical analyses performed on data collected for the Hyco Reservoir environmental monitoring program. Program Variable Statistical test(s)/model(s)+ Main effect(s) Water quality Water temperature, specific conductance, Secchi disk transparency depth, and selected chemical variables Water chemistry Selected chemical variables Phytoplankton Chlorophyll a Trace elements Al, As, Cd, Cu, Hg, Se (water) As, Cd, Cu, Hg, Se (sediment and fish) ANOVA, block on month Station ANOVA, block on month Station ANOVA, block on month Station ANOVA, block on month Station ANOVA Transect 'Parametric and non -parametric (rank) one-way Analysis of Variance (ANOVA) statistical models were used. A Type I error rate of 5% (a = 0.05) was used to judge the significance of all tests. Fisher's protected least significant difference (LSD) test was applied to determine where differences in means occurred for significant ANOVA models. Duke Energy Progress 8 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Environmental Monitoring Results for 2017-2018 Limnology Temperature and Dissolved Oxygen • Thermal stratification, defined by changes of at least 2°C per meter of water depth, in Hyco Reservoir was influenced by several factors during 2017 and 2018, including proximity to the plant discharge, variable thermal loading from power plant discharges, summertime use of the auxiliary intake system, and natural ambient conditions and streamflow (Appendices 1 and 2). In Southeastern reservoirs, typically, a pronounced clinograde isotherm (thermocline) is observed throughout hotter months. However, this pronounced thermal stratification pattern was not observed in Hyco Reservoir during 2017 and 2018, in keeping with historical observations. In 2017, no thermal stratification was present in the reservoir during February, August, and December while only weak thermal stratification was observed during April, June, and October. Similarly, during 2018, no thermal stratification was observed during February and October and again, only weak thermal stratification was observed during April, June, August and December. Surface water temperatures at Station D2 near the thermal discharge ranged from 11.3°C in February to 30.6°C in October 2017 (Appendix 3). In 2018, Station D2 ranged from 11.8 in February to 31.8 in August (Appendix 4). The coolest surface water temperature in the reservoir during 2017 was 8.5°C in February at Station SHHW1 and 8.0 during February at Station C2 during 2018. • The annual mean surface temperature at Station D2 was 23.4°C in 2017 and 22.6 in 2018 (Appendices 3 and 4). There were no significant differences in the annual mean surface temperatures among all sampling stations either year, which is a departure from historical temperature patterns in the reservoir. It is likely that lower power plant dispatch rates each year resulted in the similarities of mean temperature measures throughout each year. • All surface water dissolved oxygen concentrations were greater than 5 mg/L throughout Hyco Reservoir during both 2017 and 2018 monitoring events (Appendices 1 and 2). Oxygen depletion below 1 mg/L was observed in only the deeper hypolimnetic waters (typically below approximately 5 meters) of the reservoir during June and October of 2017 and June, August, and October of 2018. This phenomenon usually occurs within monomictic reservoirs of the southeastern United States. However, Hyco Reservoir does not exhibit strong oxygen depletion as with other reservoirs of the southeast due to the use of an auxiliary intake for withdrawal of hypolimnetic cooling water by the Roxboro Plant. Duke Energy Progress 9 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Water Clarity Constituents • Secchi disk transparency was similar among all stations in Hyco Reservoir during 2017 (Appendix 3), however, minor statistical differences among the stations were noted during 2018 (Appendix 4). Hyco Reservoir was moderately clear both years with Secchi disk visibility greater than one meter on average except for the extreme upstream Station SHHW L Mean turbidity values, a related measure of clarity, were also statistically similar among the reservoir stations during both 2017 and 2018. The 2017-2018 turbidity ranges were within ranges observed in previous years (DEP 2017). Nutrients and Phytoplankton Biomass • All aqueous nitrogen constituents during 2017-2018 including annual mean total ammonia, total nitrogen, nitrite -nitrate nitrogen, and total kjeldahl nitrogen concentrations were similar among the stations and varied by relatively small amounts (Appendices 3 and 4). These minor variations of nutrient concentrations among the stations were not considered to be important to the trophic status of the reservoir. Total phosphorus was also similar among the stations during 2017, however, varied statistically during 2018 among the stations throughout the reservoir total organic carbon (TOC) concentrations were low and consistent throughout the reservoir. Taken altogether, the nutrients and TOC reflect the moderate trophic status of Hyco Reservoir (NCDEQ 2015). • The annual mean chlorophyll a (a measure of phytoplankton biomass) concentration at Station D2 was statistically less than the concentrations at Stations B2, C2, and F2 during 2017 (Appendix 3). During 2018, the annual mean chlorophyll a measurement at Station C2 statistically greater than that at Station F2 but was similar to the mean concentrations at the remaining locations (Appendix 4). Chlorophyll a was not measured at SHHW 1 as part of the monitoring plans. All chlorophyll a measurements in Hyco Reservoir during 2017-2018 were below the North Carolina water quality standard of 40 µg/L (15A NCAC 02B.0211, June 2019). Ions, Hardness, Total Dissolved Solids, and Specific Conductance • The annual mean concentrations of most of the major ions, specific conductance (magnitude), total dissolved solids, and total hardness varied statistically among sampling stations during 2017 and 2018 (Appendices 3 and 4). These constituents generally followed a decreasing pattern in concentration with the following order D2—F2>B2>3C2>SHHW1. The concentration and magnitude pattern has been typically observed since the FGD operations commenced in 2008. Over a 10-year period from 2009-2018, fluctuations in concentration of select constituents observed throughout the reservoir reflected various influencing hydrodynamic processes (i.e., inflow, vertical circulation, turnover) and the inconsistent dispatching (i.e., discharge mass) of the Roxboro Plant (Appendices 5-10). Duke Energy Progress 10 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Alkalinity and PH • The annual mean total alkalinity concentrations during 2017 were similar among all the stations on Hyco Reservoir with overlapping concentration ranges (Appendix 3). Individual values ranged from 17 to 38 mg/L in surface waters with the greatest measured value at Station SHHW1. During 2018, the total alkalinity concentrations varied statistically among the stations but these variations were considered to be minor and of no biological importance (Appendix 4). The individual values ranged from 23 to 37 mg/L during 2018. Waters less than 40 mg/L are considered to be soft waters (unrelated to hardness) for biological purposes in terms of productivity (Boyd 1979). These alkalinity concentrations coincide with the moderate trophic status of Hyco Reservoir. • Hyco Reservoir generally exhibited annual median pH values slightly above neutral in most cases with circumneutral ranges within approximately one pH unit of neutral throughout the reservoir longitudinally and vertically during both 2017 and 2018 (Appendices 1-4). While no statistical evaluations of pH for 2017 and 2018 were run, which would be inappropriate for log scale data, annual median values both years were tightly grouped within a few tenths decimal fractions of each other at the stations. Individual surface water pH values ranged from 6.8 at Station SHHW 1 to 8.9 at Station C2 during 2017 and 7.0 at both Stations F2 and SHHW 1 to 8.7 at Station C2 during 2018. Deeper waters of the reservoir generally displayed slightly decreasing pH values from surface waters to bottom waters, reflecting different biological and limnological processes with depth. Trace Elements Arsenic • Annual mean total arsenic concentrations at Station D2 and F2 were statistically greater compared to the concentrations at the upper reservoir Station SHHW1 during 2017 (Appendix 3). Stations B2 and C2 annual mean concentrations were intermediate and statistically similar to all other stations throughout the reservoir. During 2018, a similar pattern was observed with the annual means at D2 and F2 being greatest in concentration among the stations (Appendix 4). While the lower reservoir total arsenic concentrations had slightly elevated concentrations during both years due to the Roxboro Plant FGD operations, all of the arsenic values measured in surface waters at all stations were well below the North Carolina surface water quality 02B standard for human health (10 µg/L; fish consumption). Long-term (10-year) trends of arsenic concentrations from 2009-2018 at all stations exhibited small seasonal fluctuations in concentrations. Duke Energy Progress 11 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • The 2017 annual mean arsenic concentration in the sediments at Transect D near the Roxboro Plant discharge was within concentration range considered to be background (3-13µg/g dry weight) but the 2018 annual mean concentration was elevated slightly above the background concentration range (Forstner and Wittmann 1981; Salomons and F6rstner 1984; and Martin and Hartman 1984) (Appendices 11 and 12). At Transect C during 2017, the annual mean arsenic concentration of 6.2 µg/g was below the Laboratory Reporting Limit (LRL) for that year. In 2018, the annual mean arsenic concentration from samples collected at Transect C was 5.0 µg/g, again within the range of background concentrations. Comparing the 2018 sediment concentrations by location showed significant statistical differences. This pattern of arsenic in sediments continues that observed historically in the reservoir (DEP 2017). • The annual mean arsenic concentration in Largemouth Bass at Transect D was statistically greater compared to the Transect C mean concentration during 2017 (Appendix 11). However, these mean values were only a decimal fraction different when compared, and, when converted to wet weight values they were below the EPA recreational fisherman screening level (i.e., 1.2 µg/g wet weight) for human consumption (NCDENR 2013). Mean concentrations in White Catfish and Bluegill were mostly below the LRL during 2017. Similarly, in 2018 only Largemouth Bass annual mean arsenic concentrations were statistically different between Transect C and D (Appendix 12). The mean arsenic values were almost identical at both transects when comparing 2017 and 2018 results for the three fish species sampled, indicating a consistent concentration pattern. Again, the arsenic values in 2018 were below the EPA recreational fisherman screening level. Cadmium • Annual mean cadmium concentrations in sediments and fish tissues at Transect C and D during 2017 were all below the LRL (Appendix 11). In 2018, only sediments measurements for cadmium were above the LRL (Appendix 12). The annual mean concentration at Transect D near the Roxboro Plant discharge location was statistically greater than the mean concentration upstream at Transect C. Copper • The annual mean total copper concentrations in Hyco Reservoir surface waters were statistically similar among all stations during both 2017 and 2018 (Appendices 3-9). The values were mostly below 2.0 µg/L throughout the reservoir. Duke Energy Progress 12 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • The annual mean copper concentration in sediment near the power plant discharge (Transect D) was statistically similar to the mean copper concentration at Transect C (South Hyco Creek arm) during both 2017 and 2018 (Appendices 11 and 12). • Copper concentrations in Bluegill, White Catfish, and Largemouth Bass muscle tissues during 2017 were comparable to those in recent years (DEP 2013, 2014, 2016, and 2017), however, the concentrations measured in Bluegill muscle at Transect D and Largemouth Bass at both Transect C and D were unexpectedly moderately elevated when compared to those same past years (Appendices 12 and 13). Copper levels in water and sediments at the two locations during 2018 did not suggest a cause for the observed elevated copper in fish tissues. Even so, the copper concentrations measured in the fish tissues were not elevated to the point of being biologically important. Manianese • Annual mean total manganese concentrations in surface waters of Hyco Reservoir were statistically similar among all reservoir stations during 2017 but varied statistically during 2018 (Appendices 2-6). Manganese concentrations ranged widely in the reservoir during both years with the greatest concentrations observed in surface waters at Station D2 during December of 2017 and Station SHHW 1 during August of 2018. These observations reflect biogeochemical processes governing manganese that are variable from year to year and are unrelated to power plant operations. Mercury • The annual mean total mercury concentrations in surface waters were statistically similar among all stations during both 2017 and 2018 (Appendices 3 and 4). Also, all of the individual total mercury concentrations measured each year throughout the reservoir were below the North Carolina 15A NCAC 02B water quality standard of 12 ng/L. • Annual mean mercury concentrations in sediments at Transects C and D were less than the LRL of 3.6 µg/g during 2017 (Appendix 11). In 2018, a change in the laboratory methodology for mercury in sediments led to valid measurements below 1 µg/g. The mean values were statistically greater at Transect D compared to transect C during 2018 (Appendix 12). However, mean concentrations measured at both locations were very low and were not considered to be biologically important. • Annual mean mercury concentrations in Bluegill muscle tissues were statistically different between Transect C and Transect D during 2017 and 2018 (Appendices 11 and 12). The mean mercury Duke Energy Progress 13 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report concentrations in White Catfish and Largemouth Bass were similar between the two locations each year. Converting the mercury measurements to fresh weight concentrations resulted in all annual mean and individual measured mercury concentrations in muscle tissues during 2017 and 2018 being below the North Carolina Health Director's screening value of 0.4 µg/g fresh weight and the EPA's water quality criterion for methylmercury in fish tissues of 0.3 µg/g fresh weight (NCDENR 2013). Selenium • During both 2017 and 2018, the annual mean total selenium concentrations in surface waters of Hyco Reservoir were statistically similar among all stations, continuing a finding observed in 2016 (DEP 2017) (Appendices 3 and 4). Further, all annual mean selenium concentrations were below 1 µg/L reservoir -wide, which is well below the North Carolina 15A NCAC 02B water quality standard of 5 µg/L for freshwater. • During 2017, the mean selenium concentrations in sediments were statistically similar between Transects C and D while in 2018, the mean selenium concentrations were statistically greater at Transect D than at Transect C (Appendices 11 and 12). All mean selenium concentrations in the muscle tissues of Bluegill, White Catfish, and Largemouth Bass were statistically greater at Transect D near the power plant discharge compared to upstream at Transect C during 2017. During 2018, the mean concentrations in Bluegill muscle were significantly greater at Transect D compared to Transect C. No differences in selenium concentrations of muscle tissue from White Catfish and Largemouth Bass were noted in 2018. The selenium concentrations in the three species continued to trend lower at Transect D since approximately 2013 (Appendix 13). All the selenium values (converted to wet weight concentrations) in edible flesh during 10-year observation period from 2009 through 2018, were well below the North Carolina human health consumption advisory level (10 µg/g wet weight). Thallium • All thallium measurements were below the LRL of 0.1 µg/L during 2017 and 2018 (Appendices 3-6). Duke Energy Progress 14 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Fisheries Fish Species Composition • There were 24 fish species in 2017 and 21 fish species in 2018, belonging to seven families, collected from Hyco Reservoir with electrofishing (Appendix 14). As a whole, the sunfish family (Centrarchidae) dominated the fish population with six fish species present in the reservoir both years. The bullhead catfishes (Ictaluridae), minnows (Cyprinidae) and Catostomidae (suckers) traded with each other in number of species between 2017 and 2018. The fish assemblage observed in Hyco Reservoir was typical of piedmont impoundments in the Southeast. Largemouth Bass was the primary apex predator in the reservoir both years and Black Crappie and Channel Catfish were also prevalent predators during 2017 and 2018. Yellow Perch were collected in reasonably good numbers. The open water schooling species Gizzard Shad and Threadfin Shad were abundant in Hyco Reservoir providing ample forage for the predator species during 2017 and 2018. • As with most man-made reservoirs, the fish assemblage in Hyco Reservoir consisted of species considered widely distributed and common in the Southeastern United States except for introduced species including Blue Tilapia and Threadfin Shad (Appendices 15 and 16). The presence of these introduced species in Hyco Reservoir was unrelated to the operation of the Roxboro Plant except for the heated effluent which allowed for their overwintering. Blue Tilapia, in particular, are likely to decline in numbers due to their intolerance of cold water temperatures as the Roxboro Plant continues to be dispatched at lower rates. Threadfin Shad may also be somewhat affected due to their intolerance of long-term exposure to low temperatures (Strawn 1965). The remaining fish species in Hyco Reservoir were either indigenous or typically found in piedmont reservoirs of North Carolina. • The greatest number of fish species was observed at Transect C both years with 19 species during 2017 and 16 species during 2018 (Appendices 15 and 16). The Transects followed a pattern of species richness both years as follows: C>B>A>D=F. Transects D and F had the lowest species richness likely due to limited shoreline habitat with more open water areas. Fish Abundance, Distribution, and Size Structure • Centrarchidae (sunfishes) were the most the abundant fish group in Hyco Reservoir followed in order by Clupeidae (herrings), Ictaluridae (bullhead catfishes), Cyprinidae (minnows), Catastomidae (suckers), Percidae (perches), and Cichlidae (tilapia) during 2017 and 2018 (Appendix 14). The sunfish family comprised 78% of the total annual electrofishing catch in 2017 and 88% total annual Duke Energy Progress 15 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report electrofishing catch in 2018. Herrings comprised 15% and 8% of the total fish catch while bullhead catfishes comprised 2% both years of the total fish catch during 2017 and 2018, respectively. • Bluegill was the single most abundant fish species present with 53% of the total catch during 2017 and 70% during 2018 (Appendix 14). Largemouth bass was the second most abundant fish species during both 2017 and 2018 with 13% and 10% of the total fish numbers and comprising 33% and 46% of the of the total biomass, respectively. Gizzard Shad was the third most abundant species with 9% during 2017 and 5% during 2018 of the total catch each comprising 16% and 11% of the total biomass. Total fish number and biomass reservoir -wide during 2017 and 2018 were consistent with values observed in recent years (DEP 2017). • Bluegill were most abundant based on electrofishing at Transects A (Cobbs Creek) and D during 2017 and at Transect B during 2018 (Appendix 15 and 16). The mean Bluegill electrofishing catch by transect arranged in approximate decreasing order were Transects A>D>C>F>B during 2017. During 2018, the mean Bluegill catch in approximate decreasing order was B>D>A>C>F. • As in previous years (DEP 2017), Bluegill reproduction continued be good throughout the reservoir in both 2017 and 2018 as indicated by their length -frequency distributions at all transects, except at Transect B during 2017 (Appendices 17 and 18). Transect B is characterized as large flat open areas with little cover for hiding from predators and likely the reason for fewer small Bluegill (< 80 mm) being collected. Also, there is a limited amount of shoreline rip rap habitat in shallow areas of this transect that can provide cover as well, therefore, small fish may be under represented annually in the electrofishing catch. The size class distributions of Bluegill were similar among all transects except at Transect B during 2017 where most fish were greater than 75 mm. This pattern of fewer small Bluegill at Transect B is typical of the electrofishing catches at this reservoir location (DEP 2017). However, in a departure from past monitoring, the electrofishing catch from 2018 at Transect B exhibited a reasonably large number of smaller Bluegill. The appearance of many smaller individuals is not understood completely but could suggest changes to the habitat (e.g., possible vegetation growth) that are not apparent from the reservoir surface. • The mean Relative Weight (Wr) values, which is an indirect measure of health condition, reservoir - wide were 83 during both 2017 and 2018, respectively (Appendices 23 and 24). A Wr of 100 is optimal for a species and suboptimal Wr values, in the absences of diseases or other health related Duke Energy Progress 16 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report factors, may be related to competition for food and the mesotrophic status of Hyco Reservoir for this numerically dominant species. Most fish do not achieve optimal condition in natural settings. • Largemouth Bass of all size classes were well -represented throughout the reservoir during 2017 and 2018 (Appendices 15 and 16). Adequate reproductive success was noted both years as represented by the presence of reasonable numbers of individual fish less than 150 mm at most transects. Transect D near the power plant discharge had the most smaller fish present in electrofishing catches during 2017 while Transect A had the most in 2018. The average size of Largemouth Bass was consistent throughout the reservoir within year and between years having an overall reservoir mean length of 267 mm for 2017 and 251 mm for 2018. • The mean Wr for Largemouth Bass in Hyco Reservoir during 2017 (Wr =85) was slightly lower than the mean Wr during 2018 (Wr=89) (Appendices 23 and 24). Again, the productivity level for the reservoir as a mesotrophic system is probably one of the main influences of suboptimal condition of fish, particularly an apex predator such as Largemouth Bass. • Gizzard Shad were well represented and collected in similar numbers throughout Hyco Reservoir during both years except at Transect F during 2018, where the numbers were somewhat lower (Appendices 15 and 16). Consistent with previous years, Gizzard Shad collected from the reservoir were mostly greater than 200 mm each year. Generally, young -of -year Gizzard Shad are not efficiently collected by electrofishing due to the inherent geartype bias against smaller schooling fish. However, occasionally, schools of small Gizzard Shad are encountered during electrofishing sampling such as occurred at Transect C during 2018. This event illustrates the random nature of encountering a large school of small shad at a particular location while sampling. It is likely that isolated schools like this are randomly located throughout Hyco Reservoir but are seldom encountered. • The mean Wr values of 88 and 92 for Gizzard Shad in Hyco reservoir during 2017 and 2018, respectively, were considered to be reasonably good in terms of health condition (Appendices 23 and 24). This factor along with good numbers collected throughout the reservoir, as noted above, represents a substantial prey base for predator species and a basic sustainability requirement of aquatic communities. Duke Energy Progress 17 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • Redear Sunfish was reasonably well distributed throughout Hyco Reservoir during 2017 and 2018 (Appendices 15 and 16). Green Sunfish was more abundant downstream of the power plant discharge while Yellow Perch, Black Crappie, and Satinfin Shiner were collected in greater numbers upstream of the plant during each year. Balanced, Indigenous Community • Hyco Reservoir represents a balanced, self-sustaining community. To demonstrate balance, an aquatic population/community must contain both predator and prey species in relative balanced numbers to each other reflecting the overall trophic status of the system. Both fish groups must be reproducing and recruiting adequately to produce the proper balance. Several regionally common predator species including adult Largemouth Bass, Black Crappie, and Channel Catfish continued to exist in Hyco Reservoir during 2017 and 2018 (Appendices 14-17). The apex predator Largemouth Bass, an integral part of the aquatic community, exhibited both adequate reproduction and recruitment for a self-sustaining population based on the presence of sufficient numbers of young -of -year (generally < 150 mm fish) and year class 1+ fish (generally > 150 mm to 250 mm fish) throughout the reservoir. Many forage species existed throughout the reservoir as well, including the primary prey species Bluegill and sustaining prey species Gizzard Shad and Threadfin Shad. Bluegill exhibited the necessary presence of young -of -year (generally < 80 mm fish) and year class 1+ fish (generally > 80 mm to 125 mm fish) (Appendices 17 and 18). Gizzard Shad and Threadfin Shad were also present in the reservoir with good numbers of adult fish each year. Without adequate reproduction and recruitment of this prey species, the adult shad would not continue to be present in similar numbers compared to previous years. Also, as noted above, a random encounter with a large school of small Gizzard Shad at Transect C during 2018 supports the likelihood of adequate reproduction recruitment of this species in the reservoir. • Fish populations in good balance can indicated by comparing the Proportional Size Distribution (PSD) index values of select predator and prey species. PSD values for balanced populations of Largemouth Bass range from 40 to 70 and for Bluegill from 20 to 60 (Gabelhouse 1984). In Hyco Reservoir, a balanced population for Largemouth Bass population during 2017 and 2018 existed in the reservoir while Bluegill population was balanced in 2017 but fell out of the range for balanced populations during 2018 (Appendix 25). No balance range has been determined for Gizzard Shad populations but plotting the PSD values for both Largemouth Bass and Gizzard Shad during 2017 and 2018 shows an interesting relationship of the stock and quality size fish of each species in Hyco Duke Energy Progress 18 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Reservoir. Fish Community Health • No significant disease or pathological anomalies were observed in fish collected by Company Biologists during 2017 or 2018. Winter kills of tilapia were observed in both 2017 and 2018 but were expected with the low dispatch of the Roxboro Plant. No other fish kills were observed or reported from Hyco Reservoir during 2017 and 2018. Biofouling Monitoring • No zebra mussels (Dreissena polymorpha) or quagga mussels (D. bugensis) were found in Hyco Reservoir during 2017 and 2018. These mussels are potentially serious biofouling organisms to power plant operations. Neither species has been collected from Hyco Reservoir. Asiatic clams (Corbicula fluminea) are known to exist in Hyco Reservoir as in many other Southeastern reservoirs; however, no significant power plant operational issues have been caused by their presence. Summary and Conclusions Hyco Reservoir thermal stratification patterns and water temperature extremes continued to be dependent on the local meteorological conditions, the proximity to the discharge canal outfall area, the influence of the circulating water of the auxiliary intake system, and the inverted siphon (part of the old discharge canal to Cobbs Creek) on the South Hyco Creek arm of the reservoir during 2017 and 2018. The 2017-2018 annual mean reservoir temperatures in surface waters continued to be within the ranges typically observed in Hyco Reservoir. Despite low dispatch of the Roxboro Plant, FGD system operations continued to affect several water chemistry parameters nearer the power plant discharge compared to those at historical background stations in Hyco Reservoir during 2017 and 2018. However, concentrations of a number of constituents have decreased with decreasing FGD discharges over the last several years. In fish tissues, selenium concentrations continued to trend down in Bluegill, White Catfish, and Largemouth Bass in both 2017 and 2018. The edible flesh selenium concentrations of all fish species sampled remained well below the North Carolina consumption advisory level of 10 µg/g wet weight (50 µg/g dry weight). Fish species composition, abundance, and distribution in Hyco Reservoir during 2017 and 2018 Duke Energy Progress 19 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report were similar to that of previous years. Bluegill remained the dominate fish species followed by Largemouth Bass, Gizzard Shad, Redear Sunfish, and Black Crappie within the reservoir both years. The fish community tended to be slightly less diverse in the open -water habitat of the middle and downstream portions of the reservoir compared to the upper, riverine-like areas of Hyco Reservoir. Hyco Reservoir, a man-made water body, contained a fish community that was balanced, and self- sustaining, which indicates a balanced aquatic community characteristic of a mesotrophic piedmont impoundments located in Southeastern United States. References APHA. 2012. Standard methods for the examination of water and wastewater. 22th Ed. American Public Health Association, Washington, DC. Boyd 1979. Water quality in warmwater fish ponds. Agricultural Experiment Station, Auburn University, Aurburn, AL. CP&L. 1991. Roxboro Steam Electric Plant 1990 environmental monitoring report. Carolina Power & Light Company, New Hill, NC. 2001. Roxboro Steam Electric Plant 2000 environmental monitoring report. Carolina Power & Light Company, New Hill, NC. DEP. 2013. Roxboro Steam Electric Plant 2012 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2014. Roxboro Steam Electric Plant 2013 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2016. Roxboro Steam Electric Plant 2014-2015 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2017. Roxboro Steam Electric Plant 2016 environmental monitoring report. Duke Energy Progress, Raleigh, NC. Duke Energy Progress 20 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Gabelhouse, D. W., Jr. 1984. A length -categorization system to asses fish stocks. N. Amer. J. Fish. Manag. 4:371-3 84. North Carolina Administrative Code. 2019. Title 15A NACA 02B Water Quality Standards for Surface Waters. June 10, 2019. NCDENR. 2013. Standard Operating Procedures; Fish Tissue Assessments. North Carolina Department of Environment and Natural Resources. Intensive Survey Branch. Raleigh, NC. NCDEQ. 2015. Roanoke River basinwide assessment report. North Carolina Department of Environmental Quality. Intensive Survey Branch. Raleigh, NC. Page, L. M., H. Espinsoa-P6rez, L T. Findley, C. R. Gilbert, R. N. Lea, N. E. Mandrak, R. L. Mayden, and J. S. Nelson. 2013. Common and scientific names of fishes from the United States, Canada, and Mexico. 7th edition. American Fisheries Society, Special Publication 34, Bethesda, Maryland. PEC. 2008. Roxboro Steam Electric Plant 2007 environmental monitoring report. Progress Energy Carolinas, Raleigh, NC. Salomons, W., and U. Forstner. 1984. Metals in the hydrocycle. Springer-Verlag, New York, NY. Strawn, K. 1965. Resistance of Threadfin Shad to low temperatures. Proceedings of the Annual Conference Southeastern Association of Game and Fish Commissioners 17(1963):290-293. USEPA. 1979. Methods for the chemical analysis of water and wastes. U.S. Environmental Protection Agency, EPA-60/4-79-020, Cincinnati, OH. Duke Energy Progress 21 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 1. Depth profiles of the water temperature (IC), dissolved oxygen (mg/L), pH, and specific conductance (µS/cm) at Hyco Reservoir during 2017. Depth B2 0.2 10.3 1.0 8.7 2.0 8.6 3.0 8.6 4.0 8.6 5.0 8.5 6.0 8.5 7.0 8.7 8.0 9.0 10.0 11.0 Depth 0.2 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 Depth 0.2 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 B2 19.4 17.9 17.3 15.8 14.9 14.2 14.2 B2 28.1 28.1 27.9 27.8 27.0 26.1 24.5 23.1 Temperature C2 D2 F2 SHHWI 8.8 11.3 10.3 8.5 8.6 11.1 10.2 7.3 8.1 11.1 10.0 7.0 8.0 11.1 9.8 6.8 8.0 11.1 8.0 11.1 8.0 11.0 7.9 11.0 10.9 10.9 10.9 10.9 Temperature C2 D2 F2 SHHWI 21.6 23.9 21.7 21.5 19.1 22.6 20.3 19.4 17.5 21.3 19.7 18.2 16.7 20.4 18.8 16.9 16.0 17.6 15.4 17.6 15.3 16.5 15.3 15.9 15.6 15.3 15.1 Temperature C2 D2 F2 SHHWI 27.9 30.4 29.4 28.0 27.9 30.1 29.2 27.0 27.4 29.6 28.7 26.5 26.4 29.4 28.6 25.6 25.3 28.9 23.0 27.4 19.9 26.7 19.5 23.6 21.6 18.5 17.2 February 1, 2017 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHWI B2 C2 D2 6B SHHWI 10.2 9.2 10.2 10.8 10.6 7.2 7.0 7.4 7.6 7.3 115 75 179 179 83 9.5 9.1 10.1 10.7 10.7 7.1 7.0 7.4 7.6 7.2 109 74 180 179 83 9.4 9.2 10.1 10.4 10.2 7.1 7.0 7.4 7.5 7.2 108 74 180 179 83 9.4 9.1 10.1 10.3 10.1 7.1 7.0 7.4 7.5 7.2 107 74 180 179 85 9.4 9.1 10.1 7.1 7.0 7.4 106 74 180 9.3 9.1 10.1 7.1 7.0 7.4 103 74 180 9.3 9 10.1 7.1 7.0 7.4 102 74 180 9.2 9 10.1 7.1 7.0 7.4 102 74 180 10 7.4 181 10 7.4 181 10 7.3 181 9.9 7.3 181 April 28, 2017 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHWI 8.7 8.7 7.5 8.8 8.2 7.2 6.9 6.9 7.1 6.8 75 70 147 143 77 7.9 7.9 7.4 8.2 7.4 6.8 6.7 6.9 7.0 6.7 62 68 138 140 77 7.8 7.7 7.4 7.7 6.5 6.7 6.7 6.8 7.0 6.6 55 64 129 144 73 7.7 7.2 7.4 7.2 6.5 6.6 6.9 6.9 6.5 46 64 127 150 70 7.5 6.9 7.4 6.2 6.5 6.8 43 63 110 7.5 6.7 7.4 6.1 6.5 6.8 43 62 109 7.2 7.0 7.5 6.0 6.4 6.8 43 62 95 6.7 7.5 6.4 6.7 62 84 7.4 6.7 82 7.3 6.6 73 6.8 6.5 67 June 27, 2017 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHWI 8.7 10.0 7.5 7.7 9.3 8.3 8.5 7.4 7.5 7.8 113 73 125 130 75 8.7 10.0 7.2 7.5 8.8 8.3 8.4 7.3 7.4 7.5 113 73 124 130 74 8.6 9.0 6.4 7.2 6.8 8.2 8.0 7.1 7.3 6.9 112 72 124 129 83 8.6 4.2 6.0 6.9 2.7 8.2 6.6 7.0 7.2 6.6 109 69 123 130 92 5.7 0.5 5.1 7.1 6.3 6.9 100 68 121 1.9 0.4 3.8 6.7 6.4 6.7 92 75 112 0.5 0.4 3.2 6.6 6.6 6.7 89 122 109 0.4 0.4 0.6 6.7 6.6 6.5 89 129 98 0.4 6.5 96 0.4 6.8 130 0.4 6.9 144 Duke Energy Progress 22 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 1. (continued) August 29, 2017 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 0.2 27.4 26.6 27.9 27.6 24.7 7.1 6.4 6.8 6.7 7.4 7.4 7.2 7.3 7.3 7.4 175 118 206 180 105 1.0 27.4 26.2 27.9 27.6 24.7 7.1 6.3 6.8 6.6 7.3 7.4 7.2 7.3 7.3 7.3 175 118 206 180 105 2.0 27.4 26.2 27.9 27.6 24.7 7.1 6.3 6.7 6.6 7.1 7.4 7.2 7.3 7.3 7.3 175 118 206 180 105 3.0 27.4 26.2 27.8 26.8 7.1 6.3 6.7 6.6 7.4 7.2 7.3 7.3 175 118 207 179 4.0 27.4 26.2 27.8 7.1 6.3 6.7 7.4 7.2 7.3 175 118 207 5.0 27.3 26.1 27.8 7.1 5.9 6.7 7.4 7.1 7.3 174 118 207 6.0 27.0 27.8 6.9 6.7 7.3 7.3 174 207 7.0 27.7 6.8 7.3 211 8.0 27.7 6.8 7.3 211 9.0 27.8 6.8 7.3 209 10.0 27.6 6.8 7.3 213 October 11, 2017 Temperature Dissolved oxygen Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 0.2 26.2 26.7 30.6 27.3 26.3 9.4 10.6 7.0 8.4 9.8 8.3 8.9 1.0 26.1 25.8 30.1 26.6 24.4 9.4 10.8 6.9 8.3 10.0 8.4 8.9 2.0 25.7 24.4 29.5 26.4 22.8 9.2 8.6 6.9 7.8 1.5 8.3 8.1 3.0 25.1 23.3 28.5 26.2 8.2 5.7 7.0 7.1 7.8 7.6 4.0 24.5 22.6 26.3 7.2 1.8 6.8 7.5 7.1 5.0 23.7 22.1 25.8 3.7 0.3 6.5 7.0 7.1 6.0 23.5 25.6 2.3 5.7 6.9 7.0 24.8 4.3 8.0 24.2 3.3 9.0 23.6 2.0 10.0 23.5 0.5 Temperature Depth B2 C2 D2 F2 SHHW1 0.2 12.8 11.2 16.1 14.5 10.6 1.0 12.8 11.2 16.1 14.5 10.6 2.0 12.8 11.1 16.1 14.5 10.5 3.0 12.7 11.0 15.7 14.5 10.5 4.0 12.5 10.7 15.4 5.0 12.3 10.7 15.4 6.0 11.9 15.2 7.0 15.2 8.0 15.0 9.0 14.0 10.0 13.3 December 6, 2017 Dissolved oxygen B2 C2 D2 F2 SHHW1 B2 10.2 10.3 8.1 9.4 11.0 7.5 10.2 10.3 8.1 9.3 10.9 7.5 10.2 10.3 8.0 9.2 10.8 7.5 10.1 10.1 7.4 9.2 10.9 7.5 9.5 9.4 7.4 7.3 8.9 9.4 7.4 7.2 7.5 7.3 7.1 7.2 6.9 6.3 5.1 pH Specific conductance D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 7.7 8.0 8.5 199 144 214 206 122 7.6 7.9 8.6 199 142 212 206 122 7.6 7.8 7.2 199 148 210 206 137 7.6 7.6 197 146 208 205 7.5 194 140 206 7.4 194 144 205 7.4 194 203 7.2 200 7.1 200 7.0 200 7.2 204 pH Specific conductance C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 7.3 7.2 7.4 7.6 204 175 217 208 159 7.3 7.2 7.4 7.5 204 175 216 208 159 7.3 7.2 7.4 7.5 204 175 216 208 157 7.2 7.1 7.4 7.5 204 172 213 208 158 7.1 7.1 202 172 211 7.1 7.1 202 172 211 7.1 196 210 7.0 210 7.0 209 7.0 206 7.0 204 Duke Energy Progress 23 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 2. Depth profiles of the water temperature (IC), dissolved oxygen (mg/L), pH, and specific conductance (µS/cm) at Hyco Reservoir during 2018. Depth B2 0.2 9.7 1.0 9.7 2.0 9.6 3.0 9.6 4.0 9.5 5.0 8.5 6.0 7.7 7.0 7.4 8.0 9.0 10.0 Depth 0.2 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 Depth 0.2 1.0 2.0 3.0 4.0 5.0 6.0 7.0 8.0 9.0 10.0 B2 15.8 13.0 12.7 10.3 11.9 11.1 10.8 10.8 B2 27.9 27.9 27.7 27.5 26.8 25.9 24.5 23.4 Temperature C2 D2 F2 SHHW1 8.0 11.8 12.6 9.1 8.0 11.8 12.7 9.1 8.0 11.8 12.7 9.0 8.0 11.8 12.0 7.6 7.9 11.8 7.6 11.8 7.6 11.7 7.5 11.7 11.6 11.4 11.1 Temperature C2 D2 F2 SHHW1 14.8 14.8 14.8 17.2 14.8 14.1 14.8 16.1 13.0 14.0 14.6 13.1 11.2 13.3 14.4 11.5 10.7 13.1 10.3 13.0 10.1 12.9 12.7 12.6 12.3 11.8 Temperature C2 D2 F2 SHHW1 28.8 28.8 29.5 27.9 27.6 28.5 28.7 26.9 26.8 27.8 28.4 26.2 26.0 27.6 28.2 24.9 22.7 27.5 18.9 27.0 16.8 25.4 16.4 22.6 19.9 17.1 16.0 February 13, 2018 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 11.1 11.0 10.2 10.7 10.6 7.4 7.1 7.4 7.5 7.0 210 127 260 256 107 11.1 10.9 10.1 10.4 10.5 7.4 7.1 7.4 7.5 7.0 208 126 260 256 106 11.0 10.8 10.1 10.3 9.9 7.3 7.1 7.3 7.5 7.0 140 127 260 256 107 11.0 10.7 10.0 10.1 8.8 7.3 7.1 7.3 7.4 6.9 175 126 260 255 112 10.9 10.5 10.0 7.3 7.1 7.3 159 127 260 10.4 9.8 10.0 7.2 7.1 7.3 119 127 260 10.2 9.9 10.0 7.1 7.1 7.3 120 128 260 10.1 10.1 10.0 7.1 7.1 7.3 106 131 259 9.9 7.3 257 9.8 7.3 253 9.7 7.2 249 April 2, 2018 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 12.6 11.4 11.1 11.4 12.5 8.3 8.0 7.7 8.0 8.4 118 NA 237 238 86 11.2 11.9 11.0 11.5 12.4 7.4 7.8 7.7 8.0 8.2 113 82 237 238 87 11.0 10.7 10.9 11.4 10.2 7.4 7.3 7.7 8.0 7.2 112 81 237 239 81 6.8 8.7 10.0 10.9 7.2 6.8 7.0 7.4 7.7 6.9 83 85 232 239 81 10.3 7.6 9.8 7.3 6.9 7.4 147 84 231 9.5 6.7 9.7 7.2 6.8 7.3 130 83 230 8.6 6.2 9.5 7.1 6.8 7.3 121 83 229 8.6 9.4 7.1 7.3 121 226 9.2 7.3 223 8.9 7.2 219 7.9 7.1 220 June 6, 2018 Dissolved oxygen pH Specific conductance B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 8.7 8.4 8.5 8.2 8.7 7.8 7.8 7.8 7.8 7.7 87 152 152 157 87 8.4 8.7 7.5 8.1 8.0 8.1 8.1 7.5 7.8 7.5 134 85 152 156 87 8.1 6.3 5.9 7.8 4.7 8.0 7.2 7.1 7.6 7.0 134 85 150 156 91 7.2 1.9 5.8 6.9 0.9 7.5 6.8 7.1 7.3 6.8 137 88 150 155 100 3.7 0.2 5.7 7.0 6.8 7.1 127 99 150 0.7 0.2 4.6 6.8 6.9 6.9 119 145 145 0.2 0.3 2.2 6.9 6.8 6.8 123 164 131 0.2 0.3 0.3 6.9 6.8 6.6 137 168 116 0.3 6.6 119 0.2 6.8 195 0.2 6.9 220 Duke Energy Progress 24 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 2. (cont.) August 1, 2018 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SH11W1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 0.2 29.3 29.2 31.8 30.1 29.4 6.7 7.6 7.0 7.6 6.6 7.5 7.8 7.4 7.5 7.4 160 114 186 171 111 1.0 29.3 29.2 31.7 30.0 29.3 6.7 7.6 7.0 7.6 6.5 7.4 7.7 7.4 7.5 7.4 160 114 186 172 111 2.0 29.3 29.1 31.6 29.9 28.8 6.7 7.4 6.8 7.5 4.0 7.5 7.7 7.4 7.5 7.1 160 114 186 173 112 3.0 29.3 28.8 31.5 29.8 28.6 6.7 6.3 6.4 7.5 2.1 7.4 7.3 7.2 7.4 6.9 160 116 185 171 115 4.0 29.3 26.1 30.1 6.6 0.3 4.3 7.4 6.7 7.0 160 148 174 5.0 29.2 22.4 29.6 6.5 0.3 3.1 7.4 6.8 6.8 160 201 170 6.0 28.6 19.1 29.2 0.5 0.4 2.3 6.9 6.5 6.8 159 230 168 7.0 28.1 28.6 0.4 0.8 6.9 6.7 171 163 8.0 27.8 0.2 6.8 166 9.0 24.4 0.3 7.4 218 10.0 20.6 0.3 7.7 267 October 2, 2018 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHWl B2 C2 D2 F2 SHHWl B2 C2 D2 F2 SHHWl B2 C2 D2 F2 SHHW1 0.2 26.7 26.7 28.7 27.3 25.6 10. 10.8 6.2 8.5 10.5 8.4 8.7 7.1 7.7 8.4 165 93 175 180 92 1.0 26.6 26.1 28.7 27.2 25.1 10. 10.7 6.4 8.5 10.3 8.5 8.7 7.1 7.6 8.4 165 92 174 179 90 2.0 26.1 25.5 28.5 27.1 24.0 10. 9.8 6.4 8.4 6.9 8.4 8.4 7.1 7.6 7.6 165 92 173 179 92 3.0 25.4 24.5 27.1 26.3 8.3 6.1 3.8 6.3 7.7 7.5 6.9 7.2 162 91 164 177 4.0 25.3 24.1 26.5 8.1 2.5 3.1 7.5 7.1 6.8 157 90 160 5.0 25.2 23.8 25.8 7.8 0.4 1.3 7.4 6.9 6.7 161 107 144 6.0 24.8 25.4 3.0 0.7 7.0 6.6 143 126 7.0 25.2 0.6 6.6 122 8.0 25.0 0.4 6.6 118 9.0 24.6 0.2 6.6 102 10.0 23.9 0.1 6.7 132 Temperature Depth B2 C2 D2 6B SHHW1 B2 0.2 11.0 8.3 19.6 13.4 8.3 9.8 1.0 11.0 8.3 19.3 13.4 8.3 9.8 2.0 11.0 8.3 19.2 13.4 8.3 9.8 3.0 11.0 8.2 18.0 13.4 8.3 9.8 4.0 10.9 8.1 16.4 9.8 5.0 8.7 8.0 12.6 9.4 6.0 7.7 11.5 8.7 7.0 11.7 8.0 11.3 9.0 9.6 10.0 9.4 December 5, 2018 Dissolved oxygen pH C2 D2 6B SHHWl B2 C2 D2 10.0 8.3 8.2 9.7 7.4 7.2 7.1 10.0 8.2 8.2 9.7 7.2 7.1 7.1 10.0 8.2 8.2 9.7 7.2 7.1 7.1 10.0 8.1 8.2 9.7 7.1 7.0 7.1 10.0 7.8 7.1 7.0 7.0 10.0 7.7 7.0 6.9 6.9 7.7 7.0 6.9 7.8 6.9 6.7 6.9 6.8 6.8 6.8 6.8 Specific conductance 6B SHHW1 B2 C2 D2 F2 SHHW1 7.0 7.1 94 72 116 108 82 7.0 7.1 94 72 116 108 82 7.0 7.1 94 72 116 108 82 7.0 7.3 94 72 111 108 82 91 72 109 79 73 103 72 102 100 82 81 80 Duke Energy Progress 25 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 3. Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2017.+ & Station B2 Station C2 Station D2 Station F2 Station SHHW1 Variable Mean Range Mean Range Mean Range Mean Range Mean Range Temperature (°C) 20.7 12.8-28.1 20.5 11.2-27.9 23.4 11.3-30.6 21.8 14.5-29.4 29.9 8.5-28.0 Dissolved oxygen (mg/L) 9.0 7.1-10.2 9.2 6.4-10.6 7.8 6.8-10.2 8.6 6.7-10.8 9.4 7.4-11.0 pH (median value) 7.5 7.2-8.3 7.3 6.9-8.9 7.3 6.9-7.7 7.4 7.1-8.0 7.6 6.8-8.5 Total dissolved solids (mg/L) 109ab 73-145 82ab 47-123 123a 86-153 122a 88-141 74b 59-118 Turbidity (NTU) 19 2-64 17 5-40 8 2-21 5 2-15 15 6-24 Secchi disk transparency (m) 1.3 0.5-1.9 0.7 0.5-1.1 1.5 0.6-2.3 1.6 0.8-2.3 0.7 0.7-0.7 Chlorophyll a (µg/L) 8.5ab 6.3-16 18a 4.8-37 3.9b 1.5-5.1 5.2ab 3.6-7.5 N/A Nutrients (mg/L) Ammonia-N 0.01 < 0.01-0.03 0.01 < 0.01-0.03 0.02 < 0.01-0.05 0.01 < 0.01-0.02 < 0.01 N/A Nitrate + Nitrite N 0.04 < 0.02-0.11 0.08 < 0.02-0.26 0.08 < 0.02-0.19 0.05 < 0.02-0.13 0.06 < 0.02-0.23 Total nitrogen 0.31 < 0.12-0.75 0.48 0.28-0.85 0.34 0.21-0.56 0.28 0.12-0.53 0.45 0.28-0.78 Total Kjeldahl Nitrogen 0.20 < 0.10-0.35 0.37 0.23-0.65 0.22 < 0.10-0.41 0.19 0.12-0.25 0.36 0.22-0.51 Total phosphorus 0.043 < 0.005-0.110 0.041 0.022-0.071 0.043 0.006-0.170 0.016 < 0.005-0.035 0.040 0.021-0.063 Total organic carbon (mg/L) 7.1 4.9-10.9 6.8 4.9-8.5 5.8 4.6-6.9 5.8 4.6-7.4 7.0 5.1-8.3 Ions (mg/L) Calcium 13ab 6.4-19 10 b 5.7-16 16a 10-20 16ab 11-19 9b 6.3-15 Chloride 19ab 6.0-30 job 3.0-23 25a 14-32 24a 15-31 8.1b 2.9-20 Magnesium 5.9ab 3.1-8.2 4.3b 2.7-6.9 7.3a 5.0-8.7 7.0a 5.2-8.5 4.ob 2.8-6.4 Sodium < 5.0 N/A < 5.0 N/A < 5.0 N/A < 5.0 N/A < 5.0 N/A Sulfate 14ab 6-20 8.2b 3.8-15.8 l9a 14-22 18a 15-21 7.1b 4.2-13.3 Total alkalinity (mg/L as 25 17-31 26 20-34 26 23-30 26 18-30 29 24-38 CaCO3) Hardness (mg equiv. CaCO3/L) 57ab 29-81 4 1 b 26-68 71' 46-86 68a 49-83 39b 27-63 Specific conductance(µS/cm) 153ab 75-204 116ab 70-175 182a 125-217 173' 130-208 108b 75-159 Trace elements (µg/L) Arsenic 1.lab 0.6-1.5 0.8ab 0.4-1.1 1.4a 1.0-1.8 1.4' 0.9-1.7 0.6b 0.3-0.9 Boron 400ab 94-772 192ab < 50-580 562' 309-838 535a 317-780 127b < 50-422 Copper 2.1 1.1-4.2 1.7 0.6-2.7 1.7 1.0-2.6 1.6 0.9-2.1 1.3 < 1.0-2.3 Manganese 61 31-96 88 43-143 151 82-276 101 49-210 127 59-200 Mercury§ 1.98 < 0.50-9.28 1.51 < 0.50-7.08 1.14 < 0.50-3.32 0.85 < 0.50-2.46 1.17 < 0.50-4.59 Selenium 0.6 < 0.5-1.1 < 0.5 < 0.5 0.7 0.6-1.0 0.7 < 0.5-1.1 < 0.5 N/A Thallium < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A 'Unless otherwise noted, all measurements were taken from the surface. Fisher's protected Least Significant Difference (LSD) test was applied only if the overall F test for the treatment was significant. Means followed by different superscripts were significantly different from each other (P = 0.05). The rows where significant differences occurred are shaded. Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. The variable pH was reported as a median value and was not subjected to statistical analysis. Sample size equaled 6 unless otherwise noted. Statistical testing was conducted on surface water means only. N/A means not applicable and NS means not sampled. 'Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably quantified. Statistical analyses were utilized only when mean concentrations were above the highest analytical LRL and where LRL values occurred, means were calculated by utilizing one half of the absolute value of each LRL. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 26 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 4. Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2018.+ & Station B2 Station C2 Station D2 Station F2 Station SHHW1 Variable Mean Range Mean Range Mean Range Mean Range Mean Range Temperature (°C) 20.1 9.7-29.3 19.3 8.0-29.2 22.6 11.8-31.8 21.3 12.6-30.1 21.8 8.3-29.4 Dissolved oxygen (mg/L) 9.9 6.7-12.6 9.9 7.6-11.4 8.6 7.0-11.1 9.1 7.6-11.4 9.8 6.6-12.5 pH (median value) 7.8 7.4-8.4 7.1 7.4-8.7 7.4 7.1-7.8 7.7 7.0-8.0 7.7 7.0-8.4 Turbidity (NTU) 15 3-35 13 5-25 7.3 2.2-22.9 6.1 1.6-23.2 18 10-36 Secchi disk transparency (m) 1.Oab 0.4-1.7 0.8ab 0.5-1.0 1.3ab 0.7-1.9 1.7a 0.7-2.6 0.6b 0.5-0.7 Total dissolved solids (mg/L) 120' 98-155 8lb 73-88 137' 101-175 137' 108-183 84b 72-105 Turbidity (NTU) 15 3-35 13 5-25 7 2-23 6 2-23 18 10-36 Chlorophyll a (µg/L) 15 ab 7.8-31 22' 7.2-45 6.5ab 2.1-17 4.9b 1.5-9.0 N/A Nutrients (mg/L) Ammonia-N 0.02 <0.01-0.05 0.02 <0.01-0.09 0.04 <0.01-0.13 0.03 <0.01-0.11 0.02 <0.01-0.07 Nitrate + Nitrite N 0.05 <0.02-0.15 0.07 <0.02-0.23 0.10 <0.02-0.22 0.06 <0.02-0.17 0.09 <0.02-0.27 Total nitrogen 0.55 0.21-1.30 0.56 0.19-0.77 0.48 0.20-0.82 0.44 <0.12-0.74 0.57 0.37-0.83 Total Kjeldahl Nitrogen 0.50 0.11-1.20 0.49 0.10-0.77 0.38 <0.10-0.61 0.40 <0.10-0.73 0.49 0.25-0.67 Total phosphorus 0.052ab 0.027-0.095 0.047ab 0.034-0.072 0.028ab 0.015-0.061 0.023b 0.009-0.060 0.057' 0.044-0.068 Total organic carbon (mg/L) 7.5 5.8-9.2 8.2 5.5-11.5 6.5 4.8-8.1 6.1 4.8-8.1 7.7 6.0-11.5 Ions (mg/L) Calcium 12ab 8.0-20 7.3b 5.5-10 16' 9.5-23 16a 9.6-23 7.3b 6.3-8.6 Chloride 18ab 9-32 6.9b 4.0-12.8 27a 12-44 27a 11-44 5.8b 4.1-9.5 Magnesium 5.4ab 3.5-7.8 3.3b 2.5-4.4 7.0 a 4.2-9.7 6.8a 4.0-9.7 3.3b 2.9-3.8 Sodium < 5 N/A < 5 N/A < 5 N/A < 5 N/A < 5 N/A Sulfate 14a 8-21 5.7b 4.0-9.3 19a 10-27 19a 9-27 5.2b 3.7-8.8 Total alkalinity (mg/L as 27ab 23-30 30ab 25-35 27ab 25-28 27b 25-28 32a 28-37 CaCO3) Hardness (mg equiv. CaCO3/L) 53ab 34-81 32b 24-44 68a 41-98 67a 40-98 32b 28-37 Specific conductance(µS/cm) 139ab 87-210 133ab 72-238 188, 116-260 185, 108-256 94b 82-111 Trace elements (µg/L) Arsenic 0.9ab 0.6-1.3 0.5b < 0.5-0.9 1.11 0.8-1.5 l.la 0.8-1.4 0.5b < 0.5-1.0 Boron 367ab 181-674 72b < 50-142 592' 277-1070 584a 239-1020 36b < 50-94 Copper 1.9 1.2-2.8 1.5 0.9-1.8 1.6 1.1-2.2 1.5 1.0-2.2 1.5 0.8-2.2 Manganese 56b 24-81 73ab 47-108 97ab 62-149 64ab 34-123 119a 87-186 Mercury,(ng/L) 2.14 <0.50-4.54 2.71 0.91-4.73 1.78 0.99-4.16 1.75 0.91-4.31 2.68 1.19-5.45 Selenium < 0.5 N/A < 0.5 N/A 0.8 0.6-1.2 0.8 0.6-1.4 < 0.5 N/A Thallium < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A 'Unless otherwise noted, all measurements were taken from the surface. Fisher's protected Least Significant Difference (LSD) test was applied only if the overall F test for the treatment was significant. Means followed by different superscripts were significantly different from each other (P = 0.05). The rows where significant differences occurred are shaded. Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. The variable pH was reported as a median value and was not subjected to statistical analysis. Sample size equaled 6 unless otherwise noted. Statistical testing was conducted on surface water means only. N/A means not applicable and NS means not sampled. 'Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably quantified. Statistical analyses were utilized only when mean concentrations were above the highest analytical LRL and where LRL values occurred, means were calculated by utilizing one half of the absolute value of each LRL. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 27 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 5. Concentrations of chemical variables in surface waters of Hyco Reservoir during 2017.'1 Station B2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NOi -N TN TP TN:TP TOC depth Feb 111 33 0.5 14 0.03 0.11 0.75 0.110 6.8 9.0 Apr 85 64 6.3 < 0.01 0.06 0.23 0.094 2.4 11 Jun 73 5.3 1.2 16 < 0.01 < 0.02 0.35 0.016 22 6.0 Aug 108 6.1 1.0 0.0 < 0.01 < 0.02 0.29 0.016 18 5.9 Oct 131 2.4 1.9 7.8 < 0.01 0.02 < 0.12 < 0.005 5.8 Dec 145 2.6 1.8 7.5 0.01 0.04 0.16 0.017 9.4 4.9 Month Cat+ Cl- Mg2+ Na S042" Alkalinity Hardness As B Cu Feb 9.7 13 4.6 < 5.0 10 25 43 0.6 173 3.0 Apr 6.4 5.8 3.1 < 5.0 6.0 17 29 0.9 94 4.2 Jun 9.4 11 4.5 < 5.0 11 23 42 0.9 244 1.9 Aug 16 22 6.9 < 5.0 18 26 67 1.4 504 1.3 Oct 19 30 7.9 < 5.0 19 28 79 1.5 611 1.1 Dec 19 29 8.5 5.9 20 31 81 1.4 772 1.2 Month Hg§ Se Mn Tl TKN Feb 4.4 < 0.5 96 < 0.10 Apr 4.3 < 0.5 78 < 0.10 0.2 Jun 0.6 < 0.5 42 < 0.10 0.4 Aug 0.4 0.8 56 < 0.10 0.3 Oct 0.03 1.1 31 < 0.10 < 0.1 Dec < 0.50 0.7 65 < 0.10 0.1 Station C2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NO2 -N TN TP TN:TP TOC depth Feb 74 40 0.5 4.8 0.03 0.26 0.85 0.071 12 8.0 Apr 74 32 0.5 13 < 0.01 0.12 0.35 0.067 5.2 8.5 Jun 47 12 0.5 37 < 0.01 < 0.02 0.65 0.036 18 6.2 Aug 80 10 0.7 16 0.03 < 0.02 0.45 0.023 20 6.2 Oct 94 4.6 1.1 20 < 0.01 < 0.02 0.30 0.022 14 7.1 Dec 123 6.1 1.1 15 < 0.01 0.04 0.28 0.026 11 4.9 Month Ca' Cl- Mg2+ Na S042- Alkalinity Hardness As B Cu Feb 64 4.7 3.0 < 5.0 5.8 21 28 0.4 < 50 2.5 Apr 58 3.3 2.7 < 5.0 4.7 20 26 0.5 < 50 2.2 Jun 61 3.2 2.8 < 5.0 3.8 21 27 0.7 < 50 2.7 Aug 103 10 4.7 < 5.0 8.7 30 45 1.1 187 1.0 Oct 128 17 5.4 < 5.0 10 34 54 0.9 309 0.6 Dec 159 23 6.9 5.8 16 31 68 1.0 580 1.0 Month Hg§ Se Mn Tl TKN Feb 3.290 < 0.5 92 < 0.10 Apr 2.305 < 0.5 97 < 0.10 0.2 Jun 0.800 < 0.5 43 < 0.10 0.7 Aug 0.335 < 0.5 143 < 0.10 0.5 Oct 0.013 < 0.5 64 < 0.10 0.3 Dec 0.083 0.5 91 < 0.10 0.2 Duke Energy Progress 28 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 5. (cont.) Station D2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3-+ NOi -N TN TP TN:TP TOC depth Feb 103 4.8 < 0.01 0.12 0.56 0.019 29 5.4 Apr 123 21 0.6 1.5 0.03 0.08 0.22 0.036 6.1 6.9 Jun 86 7.4 0.9 5.1 < 0.01 < 0.02 0.41 0.018 23 6.0 Aug 135 3.1 1.7 3.6 0.03 0.03 0.36 0.006 63 6.3 Oct 139 2.3 2.3 4.5 0.02 0.19 0.21 0.008 28 5.4 Dec 153 3.8 1.7 3.9 0.05 0.08 0.26 0.170 1.5 4.6 Month Ca 21 C17 Mgt+ Na S042- Alkalinity Hardness As B Cu Feb 17 26 81 < 5.0 18 26 76 1.4 510 2.3 Apr 14 19 62 < 5.0 16 25 59 1.0 396 2.6 Jun 10 14 50 < 5.0 14 23 46 1.1 309 1.8 Aug 19 28 82 < 5.0 22 26 81 1.8 636 1.2 Oct 19 32 79 < 5.0 20 29 80 1.6 685 1.0 Dec 20 32 87 5.9 22 30 86 1.7 838 1.6 Month Hg Se Mn Tl TKN Feb 1.4100 0.8 86 < 0.10 Apr 2.8400 0.7 84 < 0.10 0.1 Jun 0.5700 0.6 173 < 0.10 0.4 Aug 0.5450 1.0 205 < 0.10 0.3 Oct 0.1415 0.7 82 < 0.10 < 0.1 Dec 0.3250 0.8 276 < 0.10 0.2 Station F2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NOi -N TN TP TN:TP TOC depth Feb 134 6.3 1.6 7.5 < 0.01 0.13 0.53 0.018 29 5.5 Apr 108 15 0.8 6.6 < 0.01 0.05 0.25 0.035 7.1 7.4 Jun 88 3.0 1.5 5.4 < 0.01 < 0.02 0.24 < 0.005 5.7 Aug 126 3.1 1.5 3.6 0.02 0.03 0.28 < 0.005 6.3 Oct 137 2.0 2.3 4.8 < 0.01 < 0.02 0.12 < 0.005 5.5 Dec 141 2.9 2.0 3.6 < 0.01 0.08 0.24 0.035 6.9 4.6 Month CaZ+ Cl- Mg2+ Na S042- Alkalinity Hardness As B Cu Feb 17 26 8.0 < 5.0 18 26 76 1.4 533 2.1 Apr 13 17 5.8 < 5.0 15 25 56 0.9 366 2.0 Jun 11 15 5.2 < 5.0 15 18 49 0.9 317 1.7 Aug 16 24 6.9 < 5.0 19 25 68 1.7 540 1.1 Oct 18 31 7.6 5.2 20 30 76 1.7 673 0.9 Dec 19 30 8.5 5.7 21 30 83 1.7 780 1.5 Month Hg§ Se Mn Tl TKN Feb 0.9800 < 0.5 70 < 0.10 Apr 0.7650 < 0.5 63 < 0.10 0.2 Jun 1.0765 0.6 61 < 0.10 0.2 Aug 0.2065 1.0 210 < 0.10 0.3 Oct 0.0445 1.1 49 < 0.10 0.1 Dec 0.1675 0.8 152 < 0.10 0.2 Duke Energy Progress 29 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 5. (cont.) Station SHHW1 Month TDS Turbidity Secchi Chlorophyll a NH3-N NOi + NOi -N TN TP TN:TP TOC depth Feb 59 22 < 0.01 0.23 0.78 0.050 16 5.8 Apr 59 24 < 0.01 0.11 0.33 0.063 5.2 8.3 Jun 59 10 0.7 < 0.01 < 0.02 0.28 0.033 8.5 7.8 Aug 68 20 < 0.01 < 0.02 0.51 0.021 24 7.4 Oct 81 11 0.7 < 0.01 < 0.02 0.49 0.041 12 7.7 Dec 118 5.9 < 0.01 < 0.02 0.32 0.031 10 5.1 Month Cat+ Cl- Mg2+ Na S042- Alkalinity Hardness As B Cu Feb 7.1 4.5 3.4 < 5.0 6.2 26 32 0.3 < 50 1.8 Apr 6.5 3.4 3.1 < 5.0 5.3 24 29 0.4 < 50 2.3 Jun 6.3 2.9 2.8 < 5.0 4.2 24 27 0.5 < 50 1.5 Aug 8.8 7.4 4.0 < 5.0 6.9 30 38 0.9 114 1.1 Oct 10.7 11 4.5 5.4 6.6 38 45 0.7 151 0.8 Dec 14.6 20 6.4 5.2 13 34 63 0.8 422 < 1.0 Month Hg§ Se Mn Tl Feb 2.1 < 0.5 126 < 0.10 Apr 1.1 < 0.5 128 < 0.10 Jun 0.8 <0.5 101 <0.10 Aug 0.6 < 0.5 200 < 0.10 Oct 0.1 < 0.5 149 < 0.10 Dec 0.1 < 0.10 +Units are in mg/L except for most trace elements (µg/L) turbidity (NTU), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaCO3/L). Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. NS means not sampled. 91All variables are surface measurements. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 30 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 6. Concentrations of chemical variables in surface waters of Hyco Reservoir during 2018." Station B2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NOs'+ NOi -N TN TP TN:TP TOC depth Feb 155 12 0.9 8.1 0.02 0.10 0.21 0.033 6.4 5.8 Apr 117 35 0.4 31 < 0.01 < 0.02 1.30 0.095 14 9.2 Jun 108 4.3 1.3 14 0.03 < 0.02 0.37 6.6 Aug 118 4.1 1.3 7.8 < 0.01 < 0.02 0.37 0.027 14 6.3 Oct 123 2.8 1.7 17 < 0.01 < 0.02 0.32 0.027 12 8.4 Dec 98 30 0.5 9.0 0.05 0.15 0.75 0.078 9.6 8.6 Month Caz+ Cl- Mg2+ Na S042' Alkalinity Hardness As B Cu Feb 20 32 7.8 5.8 21 29 81 1.0 674 1.6 Apr 8.3 13 4.2 5.5 9.8 26 38 0.6 186 2.8 Jun 12 14 5.0 < 5.0 12 28 50 0.7 268 2.1 Aug 12 19 5.6 5.7 15 30 54 1.3 433 1.2 Oct 13 22 6.3 < 5.0 16 28 59 1.2 457 1.2 Dec 8.0 9.0 3.5 < 5.0 7.8 23 34 0.8 181 2.7 Month Hg§ Se Mn Tl TKN Feb 1.7 0.8 63 < 0.10 0.1 Apr 4.5 < 0.5 56 < 0.10 1.2 Jun 1.6 < 0.5 40 < 0.10 0.4 Aug 0.3 0.5 81 < 0.10 0.4 Oct 1.3 0.5 24 < 0.10 0.3 Dec 4.4 < 0.5 71 < 0.10 0.6 Station C2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NOs + NOi -N TN TP TN:TP TOC depth Feb 88 16 0.9 7.2 0.01 0.09 0.19 0.034 5.6 5.5 Apr 76 21 0.6 22 < 0.01 0.08 0.60 0.056 11 7.9 Jun 73 6.3 1.0 24 0.03 < 0.02 0.68 8.4 Aug 83 5.4 0.9 26 < 0.01 < 0.02 0.32 0.034 9.4 8.4 Oct 81 6.2 45 0.01 < 0.02 0.77 0.040 19 12 Dec 85 25 0.5 7.2 0.09 0.23 0.77 0.072 11 7.7 Month Cat+ Cl- Mgz+ Na SO42- Alkalinity Hardness As B Cu Feb 10 13 4.4 6.7 9.3 33 44 < 0.5 137 1.4 Apr 6.0 5.6 2.9 5.2 5.5 27 27 0.4 < 50 1.7 Jun 7.2 4.1 3.0 < 5.0 4.0 31 30 0.6 < 50 1.8 Aug 8.7 8.5 3.9 5.7 6.1 35 38 0.9 142 0.9 Oct 6.2 6.2 3.3 < 5.0 5.3 29 29 0.7 80 1.3 Dec 5.5 4.0 2.5 < 5.0 4.2 25 24 0.4 < 50 1.7 Month Hg§ Se Mn Tl TKN Feb 2.7 < 0.5 93 < 0.10 0.1 Apr 2.6 <0.5 59 <0.10 0.5 Jun 2.3 < 0.5 47 < 0.10 0.7 Aug 0.9 < 0.5 108 < 0.10 0.3 Oct 2.9 <0.5 51 <0.10 0.8 Dec 4.7 < 0.5 78 < 0.10 0.5 Duke Energy Progress 31 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 6. (cont.) Station D2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NO2 -N depth Feb 175 3.9 1.6 2.1 0.02 0.10 Apr 154 5.3 1.3 6.9 < 0.01 0.05 Jun 114 5.0 1.1 17 0.04 < 0.02 Aug 137 2.2 1.9 3.6 < 0.01 < 0.02 Oct 138 4.2 6.0 0.02 0.22 Dec 101 23 0.7 3.3 0.13 0.18 Month Ca2+ Cl- Mg2+ Na S042- Alkalinity Feb 23 44 9.7 5.9 27 28 Apr 19 41 8.6 5.9 25 28 Jun 14 17 5.7 < 5.0 15 28 Aug 14 24 6.8 5.7 18 27 Oct 14 24 6.9 < 5.0 17 26 Dec 10 12 4.2 < 5.0 9.9 25 Month Hg§ Se Mn Tl TKN Feb 1.4 1.2 149 < 0.10 < 0.1 Apr 1.0 0.9 62 < 0.10 0.2 Jun 1.8 0.6 90 < 0.10 0.4 Aug 1.1 0.6 76 < 0.10 0.3 Oct 1.2 0.6 106 < 0.10 0.6 Dec 4.2 0.6 98 < 0.10 0.6 Station F2 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NO2 -N depth Feb 183 2.6 2.3 1.8 0.01 0.10 Apr 148 4.1 6.6 < 0.01 0.04 Jun 119 2.8 1.3 9.0 0.03 < 0.02 Aug 124 1.6 2.6 5.1 < 0.01 < 0.02 Oct 138 2.2 5.7 < 0.01 < 0.02 Dec 108 23 0.7 1.5 0.11 0.17 Month Cat+ Cl- Mg2+ Na S042- Alkalinity Feb 23 42 9.7 5.7 27 27 Apr 20 44 8.4 5.9 25 28 Jun 14 18 5.7 5.0 16 28 Aug 13 22 6.4 5.8 17 26 Oct 14 25 6.8 < 5.0 18 26 Dec 9.6 11 4.0 < 5.0 8.9 25 Month Hg§ Se Mn Tl TKN Feb 1.0 1.4 123 < 0.10 < 0.1 Apr 0.9 0.9 54 < 0.10 0.3 Jun 1.4 0.6 34 < 0.10 0.4 Aug 0.9 0.6 45 < 0.10 0.4 Oct 2.0 0.6 39 < 0.10 0.7 Dec 4.3 0.6 91 < 0.10 0.6 TN TP TN:TP TOC 0.20 0.015 13 4.8 0.29 0.020 15 5.2 0.42 6.8 0.35 0.024 15 6.2 0.82 0.021 39 8.0 0.78 0.061 13 8.1 Hardness As B Cu 98 1.3 1070 1.3 83 1.0 803 1.4 57 0.8 327 2.1 64 1.4 595 1.1 64 1.5 480 1.3 41 0.9 277 2.2 TN TP TN:TP TOC < 0.12 0.009 4.8 0.32 0.011 29 4.8 0.39 6.2 0.38 0.015 25 6.0 0.73 0.018 41 6.8 0.74 0.060 12 8.1 Hardness As B Cu 98 1.3 1020 1.2 83 1.1 820 1.3 58 0.8 351 1.8 60 1.4 535 1.2 63 1.4 536 1.0 40 0.9 239 2.2 Duke Energy Progress 32 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 6. (cont.) Station SHHW1 Month TDS Turbidity Secchi Chlorophyll a NH3-N NO3 + NO2 -N depth Feb 105 36 0.5 0.03 0.20 Apr 72 18 0.6 < 0.01 0.02 Jun 77 9.6 0.7 0.02 < 0.02 Aug 84 11 0.6 < 0.01 < 0.02 Oct 81 11 < 0.01 < 0.02 Dec 83 22 0.6 0.07 0.27 Month Cat+ Cl- Mgz+ Na S042- Alkalinity Feb 8.1 9.5 3.7 6.6 8.8 28 Apr 6.3 5.2 3.0 5.4 5.4 28 Jun 7.4 4.1 3.2 < 5.0 3.9 33 Aug 8.6 7.2 3.8 5.5 4.7 37 Oct 7.0 4.7 3.3 < 5.0 3.7 33 Dec 6.4 4.1 2.9 < 5.0 4.7 30 Month Hg§ Se Mn Tl TKN Feb 5.4 115 < 0.10 0.3 Apr 2.1 <0.5 87 <0.10 0.4 Jun 2.3 < 0.5 95 < 0.10 0.5 Aug 1.2 <0.5 186 <0.10 0.6 Oct 1.8 < 0.5 126 < 0.10 0.7 Dec 3.3 < 0.5 106 < 0.10 0.6 TN TP TN:TP TOC 0.45 0.061 7.4 6.1 0.37 0.044 8.4 7.1 0.54 7.5 0.58 0.060 9.7 7.7 0.67 0.068 9.9 12 0.83 0.053 16 6.0 Hardness As B Cu 35 <0.5 <50 2.2 28 0.4 <50 1.5 31 0.6 <50 1.5 37 1.0 94 0.8 31 0.6 <50 1.2 28 0.3 <50 1.5 +Units are in mg/L except for most trace elements (µg/L) turbidity (NTU), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaCO3/L). Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. NS means not sampled. 91All variables are surface measurements. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 33 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 200 J 175 O7 150 c O 125 100 N c 75 O U 50 255 #---------------------------- 4--------- ----- _----- 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 250 J 200 150 c 0 100 O U a 50 U 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Copper 15 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids 500 J 6�400 E O u. i 6 - - U100--------------------------------------------------------- 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 J 4 O1 1 c 3 O c2----------------------------------------- ---------------------------------------------- O U O U1 --- ---- -- ---- --- --- --- --- --- ---- 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 6 4 m ZL c O 3 CU 2 U c O U 1 0 1. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 7. Long-term trends of selected parameters at Station B2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 34 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 100 J 0) E 75 0 50 c O U 0 O () 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 225 J200___________________________________________________________________________________ 175--------------------------------------------------- EO 150------------------------------ ------------------------------------------------- O 125--------------------- ------ - ------ ----------------------------------------- 100-------------- ---- - ---- ---- ----- - ---------------------------------------- U O U50 --- -- ---- ----- -------------- -- -- -- --- --- - --- --- ------ - ----- 25 ------------------------ -------------------------- ----- 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Copper 25 20 p 15 1) 10 U C 0 U 5 0 - 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids 600 J 500 E r_ 400 0 T 300 c O c 200 0 U 100 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 J4 o3 m 0 2 U c O M 0 n 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium c � 3 c O 2 0 0 U 1 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 8. Long-term trends of selected parameters at Station C2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 35 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 150 125 E C 100 0 75 C N C 50 O U 25 i i------------- I----------- o 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness N1.111 a)200 E 0 150 2 0 100 U C 0 U 50 0 i. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year 15 J 0) 1 C10 O C 41 C 5 O i Total Copper 0 ! 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids J 500 400 0 .-�6 300 C 0 0 200 C 0 U 100 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 J a74 C '0 3 C U 2 C O U 1 0 i. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 0 1. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 9. Long-term trends of selected parameters at Station D2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 36 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 150 125 E 100 0 75 c N c 50 0 U 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 250 J E200 C O 8 150 C 0 U 100 C 0 U 50 0 i. 2009 2010 2011 2012 2012 2014 2015 2016 2017 2018 Year Total Copper 20 J m s 15 U 5 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids 400 J 01 300 E 0 200 0 100 U 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 0 i. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 0 1t 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 10. Long-term trends of selected parameters at Station F2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 37 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 11. Means and standard errors of trace element concentrations (µg/g dry weight) in sediments and fish by transect from Hyco Reservoir during 2017. (Values in parentheses are the corresponding wet weight values.)ql Matrix n Transect Element Arsenic Cadmium Copper Mercury Selenium Sediments 3 C <6.2 < 2.9 (1.1) 75 (28) f 0.5 (0.2) < 3.6 (1.3) 2.2 (0.8) f 0.2 (0.07) 3 D 6.2 (3.9) t 1.6 (1.0) < 2.9 (1.8) 85 (53) t 2.6 (1.6) < 3.6 (2.2) 2.7 (1.7) t 0.1 (0.09) Fish muscle White Catfish 10 C < 0.2 (0.04) < 2.0 (0.4) 0.6 (0.1) t 0.3 (0.05) 0.6 (0.1)t 0.06 (0.011) 3.16 (0.6) t 0.9 (0.08) 10 D < 0.2 (0.04) < 2.0 (0.4) 0.9 (0.2) f 0.3 (0.05) 0.5 (0.1) f 0.06 (0.01) 6.3a (1.1) t 0.4 (0.3) Bluegill 10 C < 0.2 (0.04) < 2.0 (0.3) 2.6- (0.5) t 0.7 (0.1) 0.9- (0.2)t 0.06 (0.011) 4.16 (0.7) t 0.6 (0.1) 10 D 0.6 (0.1) t 0.1 (0.03) < 2.0 (0.4) 0.4e (0.07) t 0.08 (0.02) 0.4e (0.07) t 0.04 (0.008) 9.9a (0.5) t 1.9 (0.1) Largemouth Bass 10 C 0.56 (0.1) t 0.08 (0.02) < 2.0 (0.4) 0.3 (0.2) t 0.09 (0.02) 1.1 (0.2) t 0.08 (0.02) 4.26 (0.9) t 0.2 (0.04) 10 D 0.8a (0.2) t 0.06 (0.01) 1 < 2.0 (0.4) 10.3 (0.07) t 0.06 (0.013) 1.1 (0.2) t 0.1 (0.02) 8.6a (1.7) + 0.5 (0.1) + To convert to mean dry weight concentrations, divide the mean wet weight concentration by the appropriate mean dry -to -fresh weight ratio as follows: sediments-Transect C0.36, Transect D-0.62, White Catfish muscle-0.18, Bluegill muscle-0.19, and Largemouth Bass muscle- 0.20. "Standard errors and statistical analyses are given when mean concentrations were at or above the laboratory reporting limit. Laboratory reporting limits varied between samples. Means separation procedures were applied only if the overall test for transect was significant. Means for each element followed by different superscripts were significantly different at the P = 0.05 level and were shaded gray to denote significant results between transects. Duke Energy Progress 38 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 12. Means and standard errors of trace element concentrations (µg/g dry weight) in sediments and fish by transect from Hyco Reservoir during 2018. (Values in parentheses are the corresponding wet weight values.)ql Matrix n Transect Element Arsenic Cadmium Copper Mercury Selenium Sediments 3 C 5.0" (1.9) f 0.03 (0.01) 0.09e (0.03) f 0.002 (0.001) 56 (21) f 0.8 (0.3) 0.08e (0.03) f 0.002 (0.001) 4.4e (2.0) f 0.2 (0.08) 3 D 16- (5.8) t 0.7 (0.25) 0.14a (0.05) t 0.01 (0.004) 88 (32) t 2.5 (0.91) 0.16a (0.06) t 0.007 (0.002) 7.6- (3.0) t 0.4 (0.2) Fish muscle White Catfish 4 C < 0.5 (< 0.1) < 0.5 (< 0.1) < 4.7 (< 0.9) 0.7 (0.1) f 0.2 (0.01) 1.8 (0.3) t 0.1 (0.02) 6 D < 0.5 (< 0.1) < 0.5 (< 0.1) 3.9 (0.7) t 1.7 (0.3) 0.4 (0.1) t 0.07 (0.01) 3.4 (0.6) t 1.2 (0.2) Blueglll 8 C < 0.5 (< 0.1) < 0.5 (< 0.1) < 4.7 (0.9) 0.4- (0.07) t 0.03 (0.01) 1.9e (0.4) t 0.2 (0.04) 10 D 0.7 (0.1)f 0.09 (0.02) < 0.5 (< 0.1) 10 (1.9) t 3.8 (0.7) 0.3e (0.05) t 0.02 (0.004) 7.2' (1.4) t 0.4 (0.09) Largemouth 9mr- Bass 10 C 0.5" (0.1) t 0.05 (0.01) < 0.5 (< 0.1) 13 (2.5) t 4.1 (0.8) 1.1 (0.2) t 0.07 (0.01) 3.1 (0.6) t 0.08 (0.02) 10 D 0.8a (0.2) t 0.08 (0.02) < 0.5 (< 0.1) 13 (2.5) t 2.0 (0.4) 1.1 (0.2) t 0.1 (0.02) 1 5.5 (1.0) t 0.4 (0.08) + To convert to mean dry weight concentrations, divide the mean wet weight concentration by the appropriate mean dry -to -fresh weight ratio as follows: sediments0.36, White Catfish muscle 0.19, Bluegill muscle-0.19, and Largemouth Bass muscle-0.19. 9'Standard errors and statistical analyses are given when mean concentrations were at or above the laboratory reporting limit. Laboratory reporting limits varied between samples. Means separation procedures were applied only if the overall test for transect was significant. Means for each element followed by different superscripts were significantly different at the P = 0.05 level and were shaded gray to denote significant results between transects. Duke Energy Progress 39 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 an tw 20 3 15 0 U E 10 3 °J 5 v 0 d 25 oa to 3 �15 0 U E10 0 .E °J 5 v 0 at to M _=�15 U C U10 G=. Bluegill 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year —*--Transect C —IF—Transect D 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year —4--Transect C --*--Transect D White Catfish 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year —4—Transect C —IF—Transect D Appendix 13. Long-term trends of selenium concentrations (dw) in Bluegill, Largemouth Bass, and White Catfish muscle tissues at Transect C and Transect D from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 40 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 14. Total number and weight (kilograms) of fish collected with electrofishing from Hyco Reservoir during 2017 and 2018. 2017 2018 Scientific name' Common name Total Number Total weight k Total number Total weight k lupeidae Herrings Dorosoma cepedianum Gizzard Shad 228 51.1 168 30.1 Dorosoma petenense Threadin Shad 152 0.6 75 0.2 yprinidae Minnows Notemigonus crysoleucas Golden Shiner 2 0.1 2 < 0.1 Cyprinella analostana Satinfin Shiner 40 0.1 30 0.1 Notropis hudsonius Spottail Shiner 0 0.0 6 < 0.1 Cyprinus carpio Common Carp 2 10.5 1 7.0 atostomfdae Suckers Erimyzon oblongus Creek Chubsucker 1 0.3 3 1.0 Moxostoma collapsum Notchlip Redhorse 29 31.2 13 12.8 Moxostoma erythrurum Golden Redhorse 7 3.3 2 1.6 Moxostoma pappillosum V-lip Redhorse 2 1.1 0 0.0 Moxostoma commersonii White Sucker 1 0.4 0 0.0 ctaluridae Bullhead catfishes Ameiurus catus White Catfish 12 4.7 34 0.7 Ameiurus platycephalus Flat Bullhead 10 0.9 5 0.7 ktalurus punctatus Channel Catfish 39 35.0 25 27.1 Ameiurus natalis Snail Bullhead 1 < 0.1 1 0.3 entrarchidae Sunfishes Lepomis cyanellus Green Sunfish 38 0.9 20 0.4 Lepomis gulosus Warmouth 5 0.2 4 0.2 Lepomis macrochirus Bluegill 1385 29.4 2,233 29.2 Lepomis microlophus Redear Sunfish 191 25.9 160 24.6 Lepomis hybrid Hybrid Sunfish 11 0.7 1 0.4 Micropterus salmoides Largemouth Bass 349 106.1 330 120.8 Pomoxis nigromaculatus Black Crappie 60 13.1 45 4.7 ercidae Perches Perca flavescens Yellow Perch 31 0.9 34 0.8 Morone chrysops White Bass 2 0.8 0 0.0 Etheostoma nigrum Johnny Darter 1 0.1 0 0.0 ichlidae Cichlids Tilapia aurea Blue Tilapia 5 1.5 4 0.5 otall 2,606 319.0 3,173 263.4 Total Species 24 21 'Taxonomic nomenclature follows Page et al. (2013). 9ITotals include only fish identified to species level. Duke Energy Progress 41 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 15. Mean catch per hour (CPUE) of fish collected with electrofishing by transect from Hyco Reservoir during 2017. Common Name Transect Reservoir mean A B C D F Gizzard Shad 19 42 12 22 20 22 Threadfin Shad 2 < 1 74 0 0 15 Satinfin Shiner 7 2 10 0 0 4 Golden Shiner 0 0 1 0 0 < 1 Common Carp 0 < 1 0 < 1 0 < 1 Creek Chubsucker 0 0 < 1 0 0 < 1 Notchlip Redhorse 0 2 12 0 0 3 Golden Redhorse < 1 3 < 1 0 0 < 1 V-lip Redhorse 0 < 1 < 1 0 0 < 1 White Sucker 0 0 < 1 0 0 < 1 White Catfish 1 3 1 < 1 0 1 Flat Bullhead < 1 0 3 0 2 < 1 Snail Bullhead 0 0 0 0 < 1 < 1 Channel Catfish 1 4 8 2 3 4 Yellow Bullhead < 1 0 0 0 0 < 1 Green Sunfish 1 0 3 6 9 4 Warmouth < 1 0 0 1 < 1 < 1 Bluegill 203 42 155 199 77 135 Redbreast Sunfish 0 < 1 0 0 0 < 1 Redear Sunfish 21 38 16 10 9 19 Hybrid Sunfish 0 0 0 4 2 1 Largemouth Bass 36 26 40 34 35 34 Black Crappie 9 12 8 0 < 1 6 Yellow Perch < 1 < 1 14 0 0 3 White Bass 0 0 1 0 0 < 1 Blue Tilapia 0 < 1 0 2 0 < 1 Johnny Darter 0 < 1 0 0 0 < 1 Total CPUE' 302 175 360 281 159 254 Total number of speciesT 15 17 19 10 10 26 'Total catch per unit effort (CPUE) may vary from column sums due to rounding. 9ITotal number of species does not include hybrid sunfish. Duke Energy Progress 42 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 16. Mean catch per hour (CPUE) of fish collected with electrofishing by transect from Hyco Reservoir during 2018. Common Name Transect Reservoir mean A B C D F Gizzard Shad 18 22 24 16 6 17 Threadfin Shad 1 3 14 6 14 8 Satinfin Shiner 6 2 6 0 0 3 Spottail Shiner 0 2 1 0 0 < 1 Golden Shiner 0 < 1 0 0 0 < 1 Common carp 0 0 < 1 0 0 < 1 Creek Chubsucker 1 < 1 0 0 0 < 1 Notchlip Redhorse 0 < 1 6 0 0 1 Golden Redhorse 1 0 0 0 0 < 1 White Catfish < 1 1 0 < 1 < 1 < 1 Flat Bullhead 1 0 0 0 2 < 1 Snail Bullhead 0 0 < 1 0 2 < 1 Channel Catfish < 1 5 2 3 2 2 Green Sunfish 0 0 2 1 7 2 Warmouth 0 0 < 1 < 1 1 < 1 Bluegill 221 367 182 258 126 227 Redbreast Sunfish 0 0 < 1 0 0 < 1 Redear Sunfish 24 34 4 15 6 16 Hybrid Sunfish 0 0 < 1 2 0 < 1 Largemouth Bass 34 16 44 42 30 34 Black Crappie 12 10 2 < 1 0 5 Yellow Perch 2 8 2 4 2 4 Blue Tilapia 0 0 0 2 0 < 1 Total CPUE' 322 472 293 350 196 323 Total number of species9t 13 14 16 12 12 22 + Total catch per unit effort (CPUE) may vary from column sums due to rounding. 'Total number of species does not include hybrid sunfish. Duke Energy Progress 43 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 15 Transect A (Year = 2017) 10 Bluegill, n=414 Mean = 87 5 - -MILE 0 INNINNINEENEREb. ..... I I I O Ln O Ln O Ln O Ln o N Ln n O Length (mm) 15 Transect B (Year = 2017) Bluegill, n=85 10 Mean = 132 5 0 o Ln o Ln O Ln O Ln O N Ln r, O N Ln n O rIj 15 Length (mm) Transect C (Year = 2017) 10 Bluegill, n=311 Mean = 149 5 No o Ln o Ln O Ln O Ln N Ln r, 15 Length (mm) Transect D (Year = 2017) 10 Bluegill, n=415 }, Mean = 91 C= v 5 a 0 o Ln Ln Ln o Ln Ln Ln o N Ln in r` O rIj 15 Length (mm) Transect F (Year = 2017) Bluegill, n=160 10 Mean = 102 5 0 ■ ��—�--■ -- o Ln o Ln o Ln O Ln o N Ln O N Ln r, CD.-- ` i N 10 Length (mm) Transects Combined (Year = 2017) . Bluegill n=1385 Mean = 100 mm 5 X O Ln o Ln o Ln o Ln o N Ln N Ln r` O N Length (mm) Appendix 17. Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2017. Duke Energy Progress 44 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 15 Transect A (Year = 2018) Bluegill, n=441 Mean = 80 10 5 o Ln o f Ln O Ln O Ln O N Ln r, O N Ln r\ O .--� •--� •--� .--i N Transect B (Year = 2018) 15 Bluegill, n=654 Mean = 98 10 0 O Ln O Ln O Ln O Ln N Ln 15 Transect C (Year = 2018) Bluegill, n=364 10 Mean = 93 N 5 ■■ ■ ■■■����—■---- UO . . . . . . . . . . . . . IN L O Ln O Ln O Ln O Ln N Ln r, n 15 Transect D (Year = 2018) Bluegill, n=515 Mean = 94 10 5 0 O Ln O Ln O Ln O Ln O N Ln r, O N Ln r\ O .--� •--� •--� •--� N 15 Transect F (Year = 2018) Bluegill, n=251 10 Mean = 81 5 0 MEN -- — O Ln O Ln o Ln o Ln o N Ln r, O N Lff r\ O 15 Transects combined (Year = 2018) Bluegill, n=2225 Mean = 88 10 5 0 — o Ln O Ln O Ln O Ln o N Ln r\ O N r, CD .--� `� •--� •--� N Appendix 18. Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2018. Duke Energy Progress 45 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 15 Transect A (Year = 2017) Largemouth Bass, n=73 Mean = 265 10 5 0 ■■ .■■. ■ 11 111■■.■ 0 0 0 0 O O O O O O Ln O N Ln CD Ln OM M I Length (mm) Transect B (Year = 2017) 15 Largemouth Bass, n=53 Mean = 283 10 5 0 ■■ ■■ ■ ■ ■ ■■■■ ■■ ■■■■■ ■■ ■ ■ O O O O O O O O O O O Ln o Ln o irn O u) O N M M 7 7 Lr) Length (mm) T t C Y = 2017 15 10 5 � 0 U 0 o Ln Oo N oo Ln Ln N M M N Length (mm) "-15 10 5 0 1 �1� ■■ O O O O CD CD O CD CCD D Ln O .�-i ON N OM M 7 Length (mm) 15 10 5 0 MIMES 0 Ln 0 0 u, O u� 105 0 0 0 Ln N N Length (mm) 0 0 M ransec ( ear ) Largemouth Bass n=79 Mean = 255 0 0 0 o Ln o � Ln Transect D (Year = 2017) Largemouth Bass n=71 Mean = 216 ■ ■ ■■ O 0 0 Ln O Ln CY Ln Ln Transect F (Year = 2017) Largemouth Bass, n=73 Mean = 241 0 0 Ln O M 7 Transects Combined (Year= 2017) Largemouth Bass n=349 Mean = 251 0 ! -- — o CD CD0 o O O O O o 0 0 Ln O CD N OM M 7 V_ LnLn Length (mm) Appendix 19. Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2047. Duke Energy Progress 46 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 10 Transect A (Year = 2018) Largemouth Bass, n=69 Mean = 250 5 0 1 Lon 0 0 0 0 0 0 O O 0 0 O 15 Largemouth Bass, n=28 Mean = 296 10 5 0 0 0 0 0 0 0 0 0 0 In O .Ln-i ON Ln N OM M 7 4.1 415 Transect C Year= 2018 Largemouth Bass, n=89 U Mean = 261 �510 d 5 O o O o O o 0 o C. In O Ln ON N OM M 7 15 Transect D (Year = 2018) Largemouth Bass, n=85 Mean = 281 10 5 0 0 0 0 0 0 0 O O 0 0 0 0 In O „may 0 Ln C3 Ln Ln Ln N N OM M 7 7 VOI Ln 15 Transect F (Year = 2018) Largemouth, Bass n=59 Mean = 258 10 5 0 1� 11 �� 0 0 0 0 0 0 0 o O o in o Ln o Ln O M C. in N M rn 7 7 10 Largemouth Bass, n=330 Mean = 267 5 0 0 O o 0 0 0 0 0 0 0 0 0 In O ti ON N OM M 7 7 In M Appendix 20. Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2018. Duke Energy Progress 47 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 20 Transect A (Year = 2017) Gizzard Shad n=39 15 Mean = 264 10 5 0 0 0 0 0 0 0 0 Ln o in CDLn o Length (MM) 25 20 Transect B (Year = 2017) Gizzard Shad, n=77 15 Mean = 283 10 5 0 C. 0 0 0 0 0 0 Ln CDLn CDLn o 25 Length (MM) 20 Transect C (Year = 2017) Gizzard Shad n=25 15 Mean = 250 10 C: 5 N U 0 k" o 0C:) CD o voi o CD LO o n I..L 25 Length (MM) 20 Transect D (Year = 2017) Gizzard Shad, n=45 15 Mean = 278 10 5 0 0 0 0 0 0 0 0 in o CD in CD+--i .Q N N M 25 Length (MM) 20 Transect F (Year = 2017) Gizzard Shad, n=42 15 Mean = 299 10 5 0 0 0 0 0 0 0 0 0 o �, CD Ln o Ln M 20 Length (MM) 15 Transects Combined (Year = 2017) Gizzard Shad; n=228 10 Mean=278 mm 5 0 0 0 0 0 0 0 0 0 o o Ln o Ln N N M M Length (mm) Appendix 21. Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2047. Duke Energy Progress 48 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 Transect A (year-2018) 20 Gizzard Shad, n=37 15 Mean = 260 10 5 0 0 0 0 Ln o .ti 25 Transect B (Year = 2018) 20 Gizzard Shad, n=39 15 Mean = 266 10 5 0 0 0 0 C. Ln o Ln 25 Transect C (year= 2018) 20 Gizzard, Shad n=48 Mean = 192 15 10 L 5 oil a 0 0 0 Cl in o rl 40 Transect D (Year=2018) Gizzard Shad, n=33 30 Mean =277 20 10 0 0 Ln 0 in o .ti 40 Transect F (Year = 2018) Gizzard Shad, n=11 30 Mean = 287 20 10 0 0 0 0 15 10 5 0 0 Ln o Transects combined (Year = 2018) Gizzard Shad, n=168 Mean = 247 0 0 Ln o .ti 0 .ti 0 0 0 0 in o Ln o N N M MENE 1 0MM 0 0 0 o Ln o N N M 0 0 0 0 n O Ln o 0 Ln 0 0 0 O Ln o N N M 0 minim 0 0 0 o N Ln N o M 0 0 0 o Ln o N N M Appendix 22. Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2018. Duke Energy Progress 49 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Bluegill L 140 120 t 100 80 �— 60 40 Meag value = 83 ± 9 (SD), n = 679 • M • • • or 75 100 125 150 175 200 225 Length (mm) Gizzard Shad L 140 Mean value = 88 ± 10 (SD), n = 228 120 100 > 80 60 40 150 175 200 225 250 275 300 325 350 375 Length (mm) _ 140 Largemouth bass i Mann vali is = Rd4 + R ignI n = 7RFi �- 120 f _al 100 j 80 d) 60 40 125 150 175 200 225 250 275 300 325 350 375 400 425 450 Length (mm) Appendix 23. Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2017. Duke Energy Progress 50 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 140 120 T 100 80 c� 60 ID 40 bluegill •: • • Mean value = 83 ± 11 (SD), n = 616 •• • 41 00 •• see•s . oo so 75 100 125 150 175 200 225 Length (mm) Gizzard Shad 140 Mean value = 92 ± 9 (SD), n = 147 120 • 100 •� • •• • •; • �' • ': 'i:': •• •. a� 80 • • • •' �. •.. • • •• • i • • 60 40 1 1 ' 150 175 200 225 250 275 300 325 350 375 Length (mm) Largemouth bass L 140 Mean value = 89 ± 9 (SD), n = 273 120 • ' ' •AL j gel •�• « • • a� 80� j'M• • • • •' '� • • 60 40 ' 125 175 225 275 325 375 425 475 525 575 Length (mm) Appendix 24. Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2018. Duke Energy Progress 51 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Will 60 a) m d 40 20 40 E M S u 100 +100 :f CZ W 60 CZ N_ 0 40 d 20 40 60 80 100 PSD Largemouth Bass ♦--Bluegill versus Largemouth Bass for 2017 *--Gizzard Shad* versus Largemouth Bass for 2017 O--Bluegill versus Largemouth Bass for 2018 o--Gizzard Shad* versus Largemouth Bass for 2018 Appendix 25. Proportional Size Distribution (PSD) ranges for balanced populations of Bluegill versus Largemouth Bass and Gizzard Shad versus Largemouth Bass collected from Hyco Reservoir during 2017 and 2018 (No true "balance" range has been determined for Gizzard Shad). Duke Energy Progress 52 Water Resources