NCG500608_ResponseTo20170617

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j June 15, 2017
RE:Answers to Questions on Email dated June 12,2017 p ort .� nr :tea
HAND DELIVERED TO THE ASHEVILLE REGIONAL OFFICE BY S.JENKINS JUN 15 2017
Ms. Linda Wiggs, Environmental Senior Specialist
1 NCDEQ Division of Water Quality
= 2090 U.S. Hwy. 70
5wannanoa, N.C.28778
Dear Ms.Wiggs:
Thank you for your time in reviewing our stormwater issues.
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In your email(attached)you mentioned Low&Bonar's 2013 rescission of their General NC DEQ permit for industrial
wastewater. I cannot, nor can the new site manager understand the circumstances that lead to this decision. I have to
believe that it was a total misunderstanding of what the permit was. It could have been it was associated with the old
Waste Water Treatment Plant that served this site many years ago.
j
Low&Bonar is not the same company that existed in 2013. There was a complete regime change that occurred in 2014
starting with a new CEO(London)in August 2014. The changes also affected Asheville's on-site personnel. None of the
-1 Bonar personnel that were part of the inspection and request for the Waste Water Permit to be rescinded(Including the
President/Site Manager)are still employed by the company.
To explain how we have come full circle back to the point of interest,The Waste Water Permit, Low& Bonar has
i mandated a program entitled"Project Planet"where Business Sustainability and Corporate Responsibility are a must for
all its manufacturing facilities globally. Part of this initiative is ISO 14001. As you may know ISO 14001 goes beyond
compliance and is the catalyst for continual improvement to processes and procedures to reduce pollution and improve
efficiencies.
i
"! I received funding for the ISO 14001 initiative in December 2016. This enabled me to hire outside consultants to
conduct an in analysis/audit of our environmental compliance obligations to fulfill§6.1.3 of ISO 14001:2015
requirements. This process was the gateway to a facility-wide environmental evaluation. Ultimately, we have
conducted a re-evaluation the basis of need,the monitoring, recordkeeping, and reporting requirements for all of our
!. environmental permits.
The Compliance Obligations audit process consumed the first four months of 2017. As we began realizing that we had
storm water issues,I reached out to Alison Davidson as she was with NCDEQ DEACS in February. I knew she could place
us in contact with the correct personnel to help us resolve our problems. It is unfortunate that I did not realize that
storm water was broken into two entities now. In a previous job I just dealt with one person, Michael Parker,out of the
Mooresville office.
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Upon completion of the Compliance Obligations Audit,we realized we had three areas that needed attention. 1)
stormwater (which with the revelation that wastewater discharge was different,we added the third category.) 2)
POTW sewerage wastewater,and 3)surface wastewater areas. Low and Bonar chose to address those deficiencies in
that order. To date,we have completed NC DEQ stormwater inspection by Darlene Kucken,and the Metropolitan
Sewerage District(MSD)wastewater permit renewal. We are now reaching out to you to address or readdress our
surface wastewater issues with your office.
The following points address questions in your email.
1. Water Conduits
Low and Bonar conducted four recent studies of wastewater and stormwater sources to determine volumes and
pollutant concentrations. Those studies are described below.
j a. ISO 14001--Compliance Obligations
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This clause required us to look at all our activities including effluent management. During this process, Low&
- Bonar initial engineering estimates were that 28,848 to 54,781 gallons of wastewater from various processes are
discharged to the East Ditch conveyance to Hominy Creek. Table 1 lists those preliminary estimates of effluent
sources and volumes. This was our first concrete indication that something was amiss from data in our files.
The ISO study revealed that cooling tower blowdowns are co-mingled with stormwater discharges to the East
Ditch,see Figure 1.
- b. 150 14001—On-site Audit
The extension office of Georgia Tech conducted an ISO 14001 preliminary audit of Low& Bonar in May 2017.
That audit reinforced the water issues and concerns described by our consultant.
C. Metropolitan Sewerage District(MSD)Wastewater Permit Renewal
)
Low&Bonar completed its wastewater discharge permit renewal to MSD in May 2017. This renewal provided a
sharper focus on all wastewater effluents by differentiating between wastewater treatment plant effluents and
surface water discharges. The MSD permit renewal estimates wastewater to range from 18,850 to 21,370
- gallons per day. Table 2 lists those updated effluent sources and volumes. Note,those values are in part
i engineering judgements;they are not data from flow measuring devices.
- d. stormwater Inspection
7
NC DEQ stormwater staff conducted an inspection in May 2017.
1 Our evaluations show that Low&Bonar does discharge to Hominy Creek the following:
I
a. Non-Contact Cooling Waters
- b. Atmospheric Cooling Systems Condensates
i C. Slowdown Wastewaters
d. Exempt Stormwaters
e. Similar wastewaters
3
- 2. Wastewater Piping Video
I do not have any videos of our discharges.
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3. Site/Process Map of Wastewater Discharge Sources
Figure 1 is a Site Map of Wastewater Discharge Sources. This is a recent upgrade of an older figure of stormwater
collection systems. Figure 1 shows individual sources and provides discharge destinations and volumes. Table 3lists
those wastewater sources and volumes ranging from 24,368 to 34,581 gallons per day. Table 3 is not complete; our
facility engineering department has provided estimates of most of the wastewater discharges to the East Ditch and then
to Hominy Creek. However,these are estimates;they are not the definitive measurements that flow measuring devices
j would provide. Tables 1,2,and 3 do provide some continuity; internally,we continue to discuss the actual disposition of
some wastewater streams.
} 4. Stormwater Sampling/Discharge Data
Stormwater Discharge Monitoring Reports for 2015 and 2016 are included in Attachment A. These reports show that
comingied stormwater and wastewater steams in the East Ditch conveyance to Hominy Creek comply with all
stormwater effluents limits and with the Stormwater Permit(NCS000179)effluent limits for Chemical Oxygen Demand
i (COD)and pH.
5. Annual Stormwater Certification Statement
'= Attached with the Monitoring reports is a certification statement table... Bart Austin was the President and Site
Manager during this time. After the full scope regime change, I was uncertain to the validity of what had been
j presented to me regarding non process discharges. I therefore elected to not certify the discharges after August 6, 2014
until I could have a comprehensive evaluation done of our storm water situation. My first year here,I took at face value
what I had been told by Bonar personnel...the ones who ask you for the recession.
j Please contact me to request any other data necessary prior to your site inspection. We are ready to accommodate
your schedule for this inspection.
The ISO 14001 certification process has been very instructive and illuminating for Low&Bonar staff. We have found
that the process does indeed go beyond compliance and is the catalyst for continual improvement to processes and
procedures to reduce pollution and improve efficiencies.
i
Low&Bonar intends to comply with all State and Federal discharge limitations. Ultimately,we believe that an individual
NPDES wastewater permit is appropriate for our site.
i
l
Respectfully Submitted,
Stephen C.Jenk ,,CSPa
HSE Manager North America
i
Attachment A-Stormwater Discharge Monitoring Reports for 2015 and 2016
Attachment B—Lind a Wiggs Email June 12,2017
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September 4, 2015
RE: Permit Number NCS000179
CERTIFIED MAJURETURN RECEIPT
N.C. Division of Water Quality
Attn: DWQ Central Files
`s 1617 Mail Service Center
Raleigh, NC 27699-1617
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Dear Sir or Madam:
Enclosed are the results of our 1 st half 2015 Storm Water Discharge Outfall Monitoring
Report. All outfalls are within the benchmark values. We will conduct our 2nd testing
- during late October or eady November
Please note the delay in getting this to you is due to us wanting to meet the new permit
and it's requirements that is due to be sent to us. In checking the Permit Tracking
Software we see that it was received and entered into your data base during April of
2014. While we are still waiting on our permit renewal to be processed, we will
continue under the 2009 parameters unless we hear otherwise from you or we receive
the new permit.
Respectfully Submitted,
_ Stephen C. Jed#ins, CSP, REM
QHSE Manager
Enclosures (2)
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December 7, 2015
RE: Permit Number NCS000179
] CERTIFIED MAIL/RETURN RECEIPT
N.C. Division of Water Quality
i Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
I
Dear Sir or Madam:
Enclosed are the results of our 2ad half 2015 Storm Water Discharge Outfall Monitoring
Report. All outfalls are within the benchmark values.
Please note we are still operating under our November 1, 2009 — October 31, 2014
permit parameters while we await our renewal permit.
In checking the Permit Tracking Software we see that it was received and entered into
s your database during April of 2014 and indications are it is in review. While we are still
_ waiting on our permit renewal to be processed, we will continue under the 2009
parameters unless we hear otherwise from you or we receive the new permit.
Respectfully Submitted,
l eph`t Steph n CSP, REM
i QHSE Mane e
Enclosures (2)
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cc: Wayne Merritt, Director of Operations-- NAFTA, Bonar
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April 21, 2016
RE: Permit Number NCS000179
i CERTIFIED MAIIJRETURN RECEIPT
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N.C. Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Sir or Madam:
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Enclosed are the results of our 1st half 2016 Storm Water Discharge Outfall Monitoring
Report. All outfalls are within the benchmark values.
Please note we are still operating under our November 1, 2009 — October 31, 2014
permit parameters while we await our renewal permit.
In checking the Permit Tracking Software we see that it was received and entered into
your data base during April of 2014 and indications are it is in review. While we are still
waiting on our permit renewal to be processed, we will continue under the 2009
j parameters unless we hear otherwise from you or we receive the new permit.
Respectfully Submitted,
Stephen C. Jenkins, CSP, REM
QHSE Manager
1
s Enclosures (2)
cc: Wayne Merritt, Director of Operations Bonar, Inc.
i Marc Anton, Group HSE Director— Low & Bonar, London
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Bonar T 828 665 5CV)
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December 29, 2016
RE: Permit Number NCS000179
CERTIFIED MAIURETURN RECEIPT
N.G. Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
7 Raleigh, NC 27699-1617
Dear Sir or Madam:
Due to the extensive extreme drought period for our region,we are delaying our 2nd
' half of 2016 sampling schedule until the tat quarter of 2017, when hopefully we will
have a more favorable weather pattern. Also note, that when precipitation patterns
occurred during this period which produced enough rain to sample, our staff members
who are responsible for sample collection could not be on site to collect them. Our plan
is to obtain 3 samplings for the 2017 year, one for the makeup and two for normal
permit requirements.
Please note we are still operating under our November 1, 2009— October 31, 2014
permit parameters while we await our renewal permit.
In checking the Permit Tracking Software we see that it was received and entered into
your database during April of 2014 and indications are it is in review. While we are still
waiting on our permit renewal to be processed, we will continue under the 2009
parameters unless we hear otherwise from you or we receive the new permit.
Respectfully Submitted,
1
Stephen C. Jean/CS-F, REM
{i HSE Manager
cc: Wayne Merritt, Manufacturing /Site Manager— Low& Bonar Inc.
Clive Macro, Group HSE Director—Low& Bonar PLC, London
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Low&
Bonar
April 18, 2017
RE: Permit Number NCS0001 79
CERTIFIED MAIL/RETURN RECEIPT
N.C. Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Dear Sir or Madam:
Enclosed are the results of our 2.d half 2016 Storm Water Discharge Outlall Monitoring
Report. All outfalls are within the benchmark values.
Due to the extensive extreme drought period for our region,we delayed our 2nd half
2016 sampling until April 3, 2017.
Our plan for 2017 forward is, after appropriate dwell time between sampling events, at
least 60 days, we will obtain 2 more samplings for our normal permit requirements.
Please note we are still operating under our November 1, 2009 — October 31, 2014
permit parameters while we await our renewal permit.
In checking the Permit Tracking Software we see that it was received and entered into
your data base during April of 2014 and indications are it is in review. While we are still
waiting on our permit renewal to be processed, we will continue under the 2009
parameters unless we hear otherwise from you or we receive the new permit.
Respectfully Submitted,
Stephen G. Jenkins, CSP, REM
HSE Manager
cc: Wayne Merritt, Manufacturing Site Manager— Low& Bonar Inc.
Clive Macro, Group HSE Director— Low& Bonar PLC, London

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Stormwater Discharge Outi'all (SDO)
Qualitative Monitoring Report
I
Forguidance onflhrtg out thisform,please visit h4t;2'//p_rtal cd g/�t��pdgs, t t /
Permit No.: ig(�/ /a jv_jPJ_f7/ ( or Certificate of Coverage No.: t{J�J�J_j_/_/_j_j�
Facility Name: rr�nx
3 County: 7 a &bA29z= Phone No. Edo —b2 6=6isaC3
Inspector:
j Date of inspection: I IS'
Time of Inspection: C"
t
Total Event Precipitation(inches): ©• Ig ��
j Was this a"Representative Storm Event'or"Measureable Storm Event"as defined by the permit?
(See information below.)
❑ Yes ❑ No
i
Please verb whether Qualitative Monitoring most be performed during a"representative storm
event'or"measureable storm event"(requirements vary,depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a"representative storm event'or during a"measureable storm event." However,
some permits do not have this requirement. Please refer to these definitions,if applicable.
A"representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. Asingle storm event may contain up to 10 consecutive hours of no
precipitation.
A"measurable storm event'is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hourstorm interval does not apply if the permittee is able to document that a shorter
- interval is representative for local storm events during the sampling period,and the permittee
obtains approval from the local DWQ Regional Office_
3
J By this signature, certify that this report is accurate and complete to the best of my knowledge:
' (Signature of PerGittee or Designeel/
i I
Page 1 of 2
i SK'n-242,6estmodiRvI 10/25/2012

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1. Outfall Description:
` Outfall No. S 0 ` 1 Structure(p e,ditch,etc.)
i 8
Receiving Stream: ,y C' ,� 3
De;tribe the industrial activities'Ctiat occur within the op[fall draipage area: ' y
2. Color: Describe the color of the discharge using basic colors(red,brown,blue,etc.)and tint
(light,medium,dark)as descriptors: iLk, ,.
i
3. Odor: Describe any distinct odors that the discharge may have(i.e.,smells strongly of oil,
I weak chlorine odor,etc.):
4. Clarity: Choose the number which best describes the clarity of the discharge,where 1 is
I clear and 5 is very cloudy:
2 3 4 5
I
S. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge,where 1 is no solids and 5 is the surface covered with floating solids:
1 ) 2 3 4 5
i
6. Suspended Solids: Choose the number which best describes the amount of suspended
7 solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
- 1 } 2 3 4 5
9. Is there any foam in the stormwater discharge? Yes No ,.
1 8. Is there an oil sheen in the stormwater discharge? Yes ` No�
9. Is there evidence of erosion ordeposition at theoutfall? Yes
- 10. Other Obvious indicators ofStormwater Pollud
List and describe
i
Note: Low clarity,high solids,and/or the presence of foam,oil sheen,or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
i
Page 2 of 2
SWU-242.last modified 10/25/2012

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MCDENR
Stormwater Discharge Outfall (SDO)
7 Qualitative Monitoring Report
For guidanceonftlling out thisform,Please visit: htllsl t 1 I &/ �ltttldvs t to /
{
F Permit No.: N/.C;( JQfO/6/�/ 7f / or Certificate of Coverage No.: NfffSaf_f_f_f_f_f_f
Facility Name: Ad�av,_.A�
County: Phone No,
Inspector* /
Date of 114ectiotd
Time of Inspection: ClR
Total Event Precipitation (inches):
Was this a"Representative Storm Event"or"Measureable Storm Event'as defined by the permit?
(See infor ation below.)
Yes ❑ No
7
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= Please verify whether Qualitative Monitoring must be performed during a"represenMdve storm
i
event"or"measureable storm event"(requirements vary,depending on the permit).
Qualitative monitoring requirements vary, Most permits require qualitative monitoring to be
'., performed during a"representative storm event"or during a"measureable storm event" However, i
'..- some permits do not have this requirement, Please refer to these definitions,if applicable.
A-representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
-_ 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
S
A"measurable storm event'is a storm event that results in an actual discharge from the
j ? permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shelter
3 interval is representative for local storm events during the sampling period,and the per i tee
obtains approval from the local DWQ Regional Office.
I
j By this signora e,1 certify that this report i accurate and complete to the best of my knowledge:
j (signature ermittee or Desig ye
1
7 Pagel of 2
P
scvu-zaz,Usa moain�a 10/25/2012 '..

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1. Ontfall Description:
�7
I Outfall No. .�.nn�._ Structure(pipe,ditch,ec.) � 7-5
Receiving Stream: if�2 �eI— y
{ Des nbe the indusmal activities that occur within the of fall i"r ma eaarrfa:
2. Color: Describe the color of tire disch}arge using basic colors(red,brown,blue,etc.)and tint
(light,medium,dark)as descriptors: el
3. Odor: Describe any disHppct odors
that the discharge may have(i.e.,smells strongly of oil,
weak chlorine odor,etc.):
' 4. Clarity; Choose the number which best describes the clarity of the discharge,where l is
clear and 5 is very cloudy:
2 3 4 5
S. Floating Solids: Choose the number which best describes the amount of floating solids in
the stormwater discharge,where 1-is no solids and 5 is the surface covered with floating solids:
1 2 3 4 5
j 6. Suspended Solids; Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and S is extremely muddy:
1
i 2 3 4 5
i
7. Is there any foam in the stormwater discharge? Yes No
t
0. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes (NO
10. Other Obvious Indicators of Stormwater Pollution:
List and describe � ,.�
3
3
t
} Note: Low clarity,high solids,and/or the presence of foam,oil sheen,or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant furtherinvestigation.
Page 2 of 2
bafll- 42,last n1adi0ed 10/25/2012

MCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
ForguldonceonfiUigg outthisform,please visit hltR'//ports ed / g6(1 /11pi [ t
Permit No.: N1.CASJ Q/�J_/2/-,(/1/f1/ or Certificate of Coverage No.:
Facility Name: Zo12r Z7vd.
i County: grcn/Pdm Re: Phone No. B.Ll 666-- -SW Z)
Inspector: fi
Dateoflnspection:__ Qt( ,ryy, _j� aalS
Time of inspection: _0
Total Event Precipitation(inches): %3 a
Was this a`Representative Storm Event"or"Measureable Storm Event"as defined by the permit?
(see ortormation below.)
,_
Yes ❑ No
1
j Please verify whether Qualitative Monitoring must be performed during a"representative storm
event"or"measureable storm event"(requirements vary,depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during "representative storm event"or during a"measureable storm event" However, ;
some permits do not have this requirement. Please refer to these definitions,if applicable.
' A"representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours ofin,
precipitation.
A"measurable storm event"is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period,and the permittee
obtains approval from the local DWQ Regional Office.
i
a
By this signature,I certify that this report is accurate and complete to the best of my knowledge:
3 �
(Stgnatu o Permfttee D igne j
4 Page 1 of 2
SWa-242,Lastmodleed 10125/2012
1
i

I
3 1. Outfall Description:
` Outfalt No. Structure(pipe,dit ,gtc.)
Receiving Stream: TQtt�
j Desc ethfimd'us_triat activities th occur within the outfall drainage area:
i
--f� 11K�—�� .�© �`'' fL.._l=L�- i! �..'�/�I6f✓'IYIL'>j�
2. Color: Describe the color of the discharge�using basic colors(red,brown,blue,etc.)and tint
j (light,medium,dark)as descriptors: 41J--.E� /--cn�
j
3. Odor: Describe any disd ct odors that the discharge may have(i.e.,smells strongly of oil,
d weak chlorine odor,etc.): Q111
7
4. Clarity: Choose the number which best describes the clarity of the discharge,where l is
clear and 5 is very cloudy:
a 1 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in
the stormwater discharge,where i is no solids and 5 is the surface covered with Floating solids:
i
i
2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
1 1 -0 3 4 5
j 7. Is there any foam in the stormwater discharge? Yes No
8. Is there an oil sheen in the stormwater discharge? Yes o�
9. Is there evidence of erosion or deposition at the outfall? Yes
1
10. Other Obvious Indicators of Stormu ater Pollution:
a List and describe
1
I
J
i
3 Note: Low clarity,high solids,and/or the presence of foam,oil sheen,or erosion/deposition '..
may be indicative of pollutant exposure. These conditions warrant further investigation.
3
Page 2 of 2
SWU-242,Lase modified 10/25/2012
t

_ r
t�EN
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Forguidanceonfilling out thisform,please visit http(/,o{�rtal > rg/xeh/i / � ,t, r•_t�,/
i
Permit No.: or Certificate of Coverage No.: j9/S(�/_/_(�/_f�f_/
Facility Name: ��nnJAaP t ta'�
County: u Phone No. -
-Inspector
Date of Inspection:
Time of Inspection: QQ it y l — SU U- 7—
Total Event Precipitation(inches): 3,6 H
Was this a"Representative Storm Event"or"Measureable Storm Event"as defined by the permit?
i
(See information below.)
t(B'Yes ❑ No
Please verify whether Qualitative Monitoring mustbe performed during a"representative storm
event"or"measureable storm event"(requirements vary,depending on the permit).
' Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be -
j performed during a"representative storm event"or during a"measureable storm event" However,
some permits do not have this requirement Please refer to these definitions,if applicable.
A"representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
j precipitation.
4 A"measurable storm event"is a storm event that results in an actual discharge front the
? permitted site outfail. The previous measurable storm event must have been at least 72 hours
{ prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter '
[ interval is representative for local storm events during the sampling period,and the permittee
I.,obtains approval from the local DWQ Regional Office.
i
By this signature,I certify that this re rt is ccurate and complete to the best of my knowledge:
i
i C_ -
] (Signature ermitte ,or,
I
1
Page 1 of 2
SN'U242,Las[modi0¢tl IOf25/20i2
t

I
E 1. Outfall Description: `
Outfall Na ��, Stmclure(pipe,ditch,etc.)
Receiving Stream: ,�i t'eh fm
t Describe the industrial acts 'ties that occur within t e outfall drainage area: _
i
Z, Color: Describe the color of the discharge usin basic colors(red,brown,blue,etc.)and tint
Oight medium,dark)as descriptors:
3
dors that the discharge may have(i,e.,smells strongly of oil,
3. Odor: Describe any dis inet o
weak chlorine odor,etc,): j1drt
4. Clarity: Choose the number which best describes the clarity of the discharge,where 1 is
clear and 5 is very cloudy:
1 2 In4 5
S. Floating Solids: Choose the number which best describes the amount of floating solids in
the stormwater discharge,where 1 is no solids� 5 is the surface covered with floating solids:
3 4 5
6, Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
i
i 1 16) 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
t
j 8. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the anthill? Yes No
S
10, Other Obvious Indicators ofStormwater Pollution:
List and describe <
I
i
3
Note: Low clarity,high solids,and/or the presence of foam,oil sheen,orerosion/deposition
j may be indicative of pollutant exposure. These conditions warrant further investigation.
(? Page 2 of 2 '..
SwU-242,UsMDdified 10/25/2012
i
1
3

i
HCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
j rorguidance onfilling out thisform,please visit httr jp. 1a cdenr or w i nytiles-.rtcn':oater/
1 Permit No.: i�JG/ f / /uJ_/�J_( or Certificate of Coverage No.:
Facility Name:
' County: '` �::e �, sy Phone No. .�-a c
Inspector: , -�i?.:',o 7�7, _
Date of inspection:
3
Time of Inspection:
1 Total Event Precipitation(inches): �• �
i
Was this a'Representative Storm Event"or"Measureable Storm Event"as defined bythe permit?
(See information below.)
I
Yes ❑ No
d Please verify whether Qualitative Monitoring must he performed during a"representative storm
event"or"measureable storm event"(requirements vary,depending on the pertnit).
i
I Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during "representative storm event"or during a"measureable storm event." However,
i
some permits do not have this requirement. Please refer to these definitions,ifapplicable.
- A"representative storm event"is a storm event that measures greater than 0A inches of rainfall
and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
j 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
-- A"measurable storm event"is a storm event that results in an actual discharge from the
permitted site initial). The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events dui ing the sampling period,and the permittee
obtains approval from the local DWQ Regional Office.
{;{ Bythis signature,l certify that this report is accurate and complete to the best of my knowledge:
I
(Signature 4 Permittee or Designee)
i
Page 1 of 2 '..
SM-242,Las[modified 10/25/2012

3
i
1. Outfall Description:
Outfall No. _�c�✓- + Structure(pipe,ditch,etc.) jtix
Receiving Stream:
Des�l9he the industrial activities that occur within the outfali drainage area:
Ali t'.
i
2. Color: Describe the color of the discharge using basic colors(red,brown,blue,etc.)and tint
(light,medium,dark)as descriptors:
1
3. Odor: Describe any distinct odors that the discharge may have(i.e.,smells strongly of oil,
weak chlorine odor,etc.): '"i
3
i
€ 4. Clarity: Choose the number which best describes the clarity of the discharge,where 1 is
clear and 5 is very cloudy:
1, 2 3 4 5
j S. Floating Solids: Choose the number which best describes the amount of floating solids in
- the stormwater discharge,where 1 is no solids and 5 is the surface covered with floating solids:
i
- 1 j 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
1 l 2 3 4 5
i
7. Is there any foam in the stormwater discharge? Yes No+
i 0. is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the mnfall? Yes
10. Other Obvious Indicators ofStormwater Pollution:
List and describe
7
I
j
I
Note: Low clarity,high solids,and/or the presence offoam,oil sheen,or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
j Page 2 of 2
{'I SWU-242,Las[modified 10/2 512 01 2

I
i
i
j M
j NCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance onjllling out thisjorm,please visit h`st}% '/�n aa' �cde rnra(wch llr mdras[orrmi> e�j
Permit No.: LIJG/,2/_/_'/=/�J=%=/ or Certificate of Coverage No.: H/G/Gl—J,_/_/_/_/_/
Facility Name � ,�:.
County: RZT PhooeNO.
f Inspector:
Date of Inspection:
Time of Inspection: 'S:l L-`
1. Total Event Precipitation (inches):
Was this a"Representative Storm Event'or"Measureable Storm Event"as defined by the permit?
I (See information below.)
[]'Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a"representative storm
event"or"measureable storm event"(requirements vary,depending on the permit).
1
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a"representative storm event"or during a"measureable storm event" However,
- some permits do not have this requirement Please refer to these definitions,if applicable.
j
A"representative storm event'is a storm event that measures greater than Od inches of rainfall
- and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A"measurable storm event'is a storm event that results in an actual discharge from the
permitted site c utfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period,and the permittee
' obtains approval from the local DWQ Regional Office. j
F
1
S
{ By this signatm e,I certify that this report is accurate and complete to the best of my knowledge:
(Signature ofPermittee or Designee) '
j Page 1 of 2
i
swu-zsz,w,t maa+Flea to/zs/zotz
3
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3
3
a
J S. Outfall Description:
Outfall No. .-D Structure(pipe,ditch,etc.)
Receiving Sham: .,5� ; i' %``�. �_ ". :'T' •'-�-_Py - a
jDescribe the industrial activities that occur within theoutfall drainage area:
I
2. Color. Describe the color of the discharge using basic colors(red,brown,blue,etc.)and tint
Qight,medium,dark)as descriptors: ,. N
3. Odor: Describe any distinct odors that the discharge may have(i.e.,smells strongly of oil,
weak chlorine odor,etc.); +1' r'P-
4. Clarity: Choose the number which hest describes the clarity of the discharge,where Iis
clear and 5 is very cloudy:
( 2 3 4 5
3'
5. Floating Solids: Choose the number which best describes the amount of floating solids in
• the stormwater discharge,where 1 is no solids and 5 is the surface covered with floating solids:
i
1 .; 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
11^ 2 3 4 5
3
7. Is there any foam in the stormwater discharge? Yes 'No
1 B. Is there an oil sheen in the stormwater discharge? Yes ;No.
9. Is there evidence of erosion or deposi0on at the outfall? Yes 'No ,
10. other Obvious Indicators ofStormwater pollution:
l
j List and describe
,
y
i
a
3
Note: Low clarity,high solids,and/or the presence offoam,oil sheen,or erosion/deposition
j maybe indicative ofpollutantexposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242janmodi io11G/25/2012

i
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
i
Furguidance onfilling out thisform,please visit. lyt4f J(rtm,a( , L [__'-aLi_n u� sstor
j Permit No.: laV/QJ, /6/O/J/t J�J�f or Certificate of Coverage No.: ly/C/f�/_J_/_J_/ J_J
1 Facility Name: J,b kl Y f Cr.7t
County: SLuN&Qr1 RP' Phone No. —aa2 - ?a6S- ;"0,o6
Inspector
Date of Inspection:
i Time of Inspection;
Total Event Precipitation(inches): 1,
? Was this a'Representative Storm Event"or"Measureable Storm Event"as defined by the permit?
(See information below.)
Q�Yes ❑ No
Please verijy whether Qualitative Monitoring must be performed during a "representative storm
event"or"measureable storm event"(requirements vary,depending on the permit).
i
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
f
j performed during a"representative storm event"or during a"measureable storm event" However,
i some permits do not have this requirement Please refer to these definitions,if applicable.
i
j - A"representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
jS and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
' ! A"measurable storm event"is a storm event that results in an actual discharge from the
i
i
permitted site anthill. The previous measurable storm event must have been at least 72 hours
print The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period,and The permtttee
i obtains approval&onn the local DWQ Regional Office.
i
By this signature,I certify that this report is accurate and complete to the best of my knowledge:
(Signature oFPernnittee on'b
ipsignee)
f
t
i
Page 1 of 2
SWU-M US(modlMd 10/25/2012
l

t
I. Outfall Description:
Outfall No. .5 DD ! Structure(pipe,ditch,etc.) tQi -2
Receiving Stream:_ %-i n vn r r r c, �7 R i-F'f•
t' Describe the industrial activities thatoccur within theoutfall drainagearea:. (;<z-� llrrJr
f 4C7-f yir(r'
2. Color: Describe the color of the discharge using basic colors(red,brown,blue,etc.)and tint
(light,medium,dark)as descriptors: L.t�1zs- MPS 'i,F
k
3. Odor: Describe any distinct odor's that the discharge may have(i.e.,smells strongly of oil,
weak chlorine odor,etc.): JUn r
7
4. Clarity: Choose the number which best describes the clarity of the discharge,where l is
clear and 5 is very cloudy:
1 3 4 5
i
:
S. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge,where 1 is no solids and 5 is the surface covered with Floating solids:
2 3 4 S
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge,where 1 is no solids and S is extremely muddy:
1
3 4 5
7. Is there any foam in the stormwater discharge? Yes �No1
8. Is there an oil sheen in tine stormwater discharge? Yes -1
J
9. Is there evidence of erosion or deposition at the outfall? Yes /No
10. Other Obvious Indicators ofStormwater Pollution:
3 Listand describe._01a z
v �
f
i
t
3
i
i
l
Note: Low clarity,high solids,and/or the presence of foam,oil sheen,or erosion/deposition
} may be indicative of pollutant exposure. These conditions warrant further investigation.
i
Page 2 of 2
1-1"'Wifild 10?25/zoi2
's

. ,
MNR
Storrnwater Discharge Outfall (SDO)
Qualitative Monitoring Report
i
i
Forguidonce on/illing out thisform,please vises S6t jmrta!,n e(e_ryq�==JE_ri2J}rin�s3 s-st4�JDs/�_:�:L
' Permit No.: N/�/, /r, /U/G/,�/1/ / or Certificate of Coverage No.:
{ Facility Name:
l County: Phone No. !P —66€� —6 Gd C1
� - _
Inspector:
Date of Inspection:
l Time of inspection:
_ Total Event Precipitation(inches): /, �
Was this a"Representative Storm Event"or"Measureable Storm Event"as defined by the permit?
(See information below.)
71 Yes ❑ No
I
Please verify whether Qualitative Monitoring mustbe performed during a"representative storm
event"or"measureable storm event"(requirements vary,depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
} performed during a"representative storm event"or during a"measureable storm event" However,
some permits do not have this requirement Please refer to these definitions,.if applicable.
i
i A"representative storm event"is a storm event that measures greater than 0.1 inches of rainfall
3 and that is preceded by at least 72 hours(3 days)in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
i
i A"measurable storm event'is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
Interval is representative for local storm events during the sampling period,and the permittee
obtains.approval from the local DWQ Regional Office.
t
s
i 6y this signature,)certify that this report is accurate and complete to the best of my knowledge:
f r L ✓J
(S`Iwnat , of Permitt .ol esignee)
3
3
Page 1 of
3 Swu-242,UA,ln Wjfiil 10i25/2012

3
i
1. Outfall Description:
Outfall No. , 2. Structure(pipe,ditch,etc.) 06
Receiving Stream
Describe the industrial activities that occur within the curtail drainage area: ;i -tTja�f3
i 2. Color. Describe the color of the discharge using basic colors(red,brown,blue,etc.) and tint
7 (light,medium,dark)as descriptors:
4
1
3. Odor: Describe any distinct odors that the discharge may have(i.e.,smells strongly of oil,
weak chlorine odor,etc.): L6A
7
4. Clarity: Choose the number which best describes the clarity of the discharge,where 1 is
clear and 5 is very cloudy:
s 1 3 4 5
5. Floating Solids: Choose the number which best describes the amount of Floating solids in
t the stormwater discharge,where 1 is no solids and 5 is the surface covered with floating solids:
1..1J 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
i solids in the stormwater discharge,where 1 is no solids and 5 is extremely muddy:
i
1 ' 3 4 5
7. Is there any foam in the stormwater discharge? Yes ( o )o )
8. Is there an oil sheen in the stm mwater discharge? Yes '`Na)
3
9. Is there evidence of erosion or deposition at the outfall? Yes `No0
l__-.
18. Other Obvious Indicators ofStormwater Pollution:
r i 7 List and describe �,g' f� ��✓. G�r�=` �L.e�"'"
,J ✓
1
j
I
1
Note: Low clarity,high solids,and/or the presence of foam,ail sheen,or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
341U-242,bot=dificd 10/25/2012
7
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ATTACHMENT B
Linda Wiggs Email June 12, 2017
I
i From:Wiggs, Linda [mailto:[e-mail]]
3
Sent:Monday,June 12,2017 3:32 PM
To:Jenkins,Steve<[e-mail]>
Cc:Davidson, Landon<[e-mail]>; Davidson,Alison<[e-mail]>;
Kucken, Darlene<[e-mail]>; Georgoulias, Bethany
<[e-mail]>; [e-mail]
Subject: Bonar-Enka site
i
1
***WARNING***This is an external e-mail and is not a part of internal communication.
Please use caution when opening attachments or when following embedded links.
Hello Steve,
i
I understand you are now the Environmental Manager for Bonar. I inspected
the Enka site in 2013 when Jeremy Nauert was the Environmental Manager.
j Dan March was acting consultant at that time.
The Enka site has come to my attention again, primarily concerning
wastewater questions but also stormwater questions. These questions relate
to the complexity of this site and the conduits of water; stormwater (SW),
wastewater (WW), comingled (SW/WW), waterbodies, etc. At my inspection
on September 4, 2013, I was informed by Mr. March and Bonar personnel
that it had been determined all conduits of water carrying any type of
wastewater flowed to the lift station and were discharged to Metropolitan
3 Sewage District (MSD). The WW permit (NCG500608) rescission request
j followed and then was granted based on this information. Furthermore, an
ongoing annual Certification as required by your Stormwater Permit (permit
#NCS000179, Part II, Section A 1. e.) remains in effect.
( Please submit to me the final study report that determined the conduits of
water at the Enka facility, including any video recording of those conduits
1 and an up to date map delineating all conduits of water. Also submit the last
j two years of sampling data from the Enka site and most recent signed
1
Certification as required under SW permit (NCS000179; Sampling - Part II
Section B, Certification - Part II, Section A 1. e.). Once I have received these
documents we can arrange an onsite meeting to further discuss.
Thank you,
i
I
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i

I
(1
l
3
Environmental Senior Specialist—Asheville Regional Office
Water Quality Regional Operations Section
NCDEQ— Division of Water Resources
828 296 4500 office
828 299 7043 fax
Email: Iin l_awi9gs{rilncdenr,goy
I
2090 U.S. Hwy. 70
Swannanoa, N.C. 28778
7
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i
E+nail correspondence to and from this address is subject to the
North Carolina Public Records Lew and may,be disclosed to thkd par es.
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i Lod e Ronar lac.
LOW&7 F M 3 1,2 r
Iar+andUmtaccom
3 June 26, 2017
f North Carolina Department of Environmental Quality
' Division Water Resources f
2028 US Highway 70
Swannanoa,NC 28787
'i Attn: Landon Davidson JUh 2 7 2011
Regional Supen�isor ,
L Tinns
I Re: Low and Bonar,Inc.
rl Wastewater Discharge Permit Application !
;. The purpose of this letter is to follow up on an Information Request expressed in our meeting
Friday,June 23 and your subsequent email that addressed additional information needed for
- several areas.
Local and corporate Low&Bonar management take this situation very seriously. We are
'? willinrk with you and your staff to resolve completely our wastewater discharge and
Como lu2e issues.
-? This letter contains:
'1 I. Estimates of the Volume of Wastewater Dischar ed Dail
l
List of process water discharges to the combined stormwater/wastewater waterbody
are included in Table 1. The discharge point is to an un-named tributary to Hominy
3 Creek. The wastewater flows in Table I are either from L&B staff engineering
1 judgement or limited empirical data.
i
Please note that many of the wastewater flow rates contained in this letter are
estimates from our Facility Engineer. The facility-wide wastewater audit(see number
r 5) will include identification and verification of all discharge sources and actual
i measures of each.
I
!.j Currently,the total estimated process wastewater discharge volume ranges from
,. 24,368 to 34,581 gallons per day. Of that range 11,034 to 11,994 gallons per day
,1 contain biocides.
2. List of Biocides and Any Other Additives in Wastewater
Table 2 is a list of biocides from all water treatment chemicals supplied by our
1 contractor Garrett-Callahan that are used in processes that discharge to the combined
_ stormwater/wastewater system to Hominy Creek via the East Ditch(un-named
tributary to Hominy Creek). Three other biocides used in the boiler system are
included for comparison; boilers discharge toMSD. The list includes LD50 and EC50
values as well as discharge rates.
717
I
1

I
(t
3
3. Biocide Worksheets
Calculations of biocide impacts on Hominy Creek using NC DEQ Biocide/Chemical
Pretreatment Worksheet—Form PT101. Those worksheets are included in
Attachment A. We used a 7Q10 value of 21 cubic feet per second in our calculations.
Safety Data Sheets for the Garrett-Callahan water treatment chemicals used at L&B
j are included in Attachment B. Calculation of the flow rates used in Fonn PTI01 are
included in Attachment C.
Please note that the average daily discharge rates used in Form PT101 are the lower
value (i.e. 24,368 gallons per day)of the estimated range. This technique is a more
' conservative evaluation of the impact of biocides on aquatic organisms.
1 Despite using this conservative wastewater flowrate,all the calculations of all biocide
i
impacts to Hominy Creek are well below the calculated regulated limitation.
4. Wastewater Analytical Data
1
3. Table 3 lists analytical results of wastewater samples collected on Monday, June 19,
q2017 and historical sampling data from 2013 for the Metropolitan Sewerage District
discharge. A Discharge Monitoring Reports is included in Attachment D.
These data show that L&B wastewater discharge to MSD is appropriate; COD and
Oil/Grease concentrations are above DEQ's surface water discharge limits.
i
S
Table 3 shows that three internal wastewater sources do have some pollutant
concentrations that are slightly elevated but not over DEQ's surface water discharge
t limits. However,the discharge point(i.e.,the East Ditch) analyses are all in
- compliance with North Carolina's General Permit limits. The Chiller Compressor
I
condensate in particular has a low pH and a high temperature,neither of which are
reflected in the East Ditch discharge.
1 5. Facility-Wide Wastewater Audit
i
- The elements and goals of a wastewater audit are the subject of a meeting at L&B on
Monday, June 26. Attendees included the Plant Manager,Facility HSE Director,
Corporate HSE Director, and two engineering contractors.
The results of this meeting will be conveyed to DEQ shortly. These results will be a
broad outline of a wastewater audit. L&B will work with DEQ to finalize the
elements and goals of an audit in a"Wastewater Audit"document that is approved by
DEQ. ....
' 6. Cost to Point)and Haul Current Wastewater Discharge
4
Costs to dispose of process wastewater discharged to the Hominy,
Ditch are included in Attachment E. Several scenarios are listed it -
i
Low&Borer,Inc.—Wastewater Discharge Permit 2

i
7. Metropolitan Sewerage District Policy on Non-Contact Wastewater
MSD's policy is to not accept non contact Process wastewaters. Their rational is that
(: this type of wastewater stream simply dilutes contents of their treatment basins
without adding any food or nutrients to the micro-organisms. A copy of MSD's
response to accepting non-contact wastewaters is included in Attachment F.
8. Current Wastewater Discharge Quality or Ouantity Changes to NCG500608
The current wastewater discharge amounts from several processes are listed in Table
2. The Notice of Intent that Bonar(Low and Bonar)filed in 2007 projects 86,000
gallons per day would be discharged to Hominy Creek via the East Ditch(see-
Attachment D). Currently,the total estimated wastewater volume ranges from 24,368
1 to 34,581 gallons per day.
Please contact me when you need additional information.
i
Thank you,Ms. Wiggs, and Ms. Kucken for your time and input during last Friday's meeting.
We assure you that Low&Bonar is completely committed to resolving our permitting issue
and to protecting water quality in Hominy Creek. We will work with your staff to ensure
` continuous compliance.
Sincerely,
Stephen C. Jenkins, HSE Manager,North America
CC: Wayne Merritt, L&B,Manufacturing/Site Manager
i Clive Macro, L&B, HSE Director, London
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Low&Bonar, Inc.—Wastewater Discharge Permit 3

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ATTACHMENT A
NC DEQ Biocide/Chemical Pretreatment Worksheet—Form PTI 01
Leo,&Bonn,,Inc.—Wastewater Discharge Peranit

i
1
Low and Bomar
j 1301 Sand Hill Road
j Enka,NC 28728
I Biocide Toxicity Evaluation-NC DEQ Form 101
Sourrea:Coolie Tmvere 1&3,BASF Tower
Date: 5/1/17
i
PERhmTq:N/A
1 RECEIVING STREAM111souggy Greek
'3
I.W.C.%: `z."0.1795
PRODUCT: G-C Formula 3091.1omide
ACTIVE INGREiD1ENT(%):Sadium Hypochlorite Q0.15.5%),Sodium Hydroxide(1-
s Ceroda haia dubia 48-hr
HALF LIFE To DAYS H.L. : 4,11 STEADY STAI£DISC CONC: 0.5079
FC50 OF SELEC FED TOX DATA mg,'L)(h.o. 40'. DEGRADATION FACTOR D.F. : 4.880
DECAY RATE U K : 0,0000 APPLICATION FACTOR: 0.050
DOSAGE RATE mGRAMS/DAY D.R. : 469
AVG DAILY DISCHARGE is MGD A.DD. : >.:a22440 INSTREAM BIOCIDE CONC: 0.0009
VOLUME OF SYSTEM MIL.GALS: .Ob05 T' REGULATED LIMITATION: 2
PASS/FAIl: PASS
3
PRODUCT:G-C Formula 3091-moeide
AC FIVE INGREDIENT(%); Sodium Hypechlorde(10,15.5%),SadiumHydmxideU-
j
Ceroda,M1nia ma na M&W
- HALFLIFE DAYS : '4,00 STEADY STATE DISC CONC: 1 0.5079
j LC5"EC
SO OF SELECTED TOX DATA MG/L: 0.169 DEGRADATION FACTOR: 4x80
DECAY RATE: 0,0000:5Z APPLICATON FACTOR: 0,050
DOSAGE RATE(GRAMS/DA 4&9
1 AVG DAILY DISCHARGE GD: 0.02440 INSTREAM FROCIDE CONC: 0.0009
VOLUME OF SYSTEM(MIL.GAL'S ; : '' 0.005 REGULATED LIMITAION: 0.00845
PASS/FAIL: PASS
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Pisgah Fmmonmenul Services,LLS 9Woodvale A\enuc Asherille,NC 2880.1 838-768-3335 pixgah-aieoNtedv

Biocide/Chemical Pretreatment Worksheet PTiOl.excel Revised May 2009
PART III: Biocide Data and Calculations
DATA ENTRY(has
I bmmmen CALCUATIOR FORMULA USED IN Maharani
aharani.......
.ATIONOOnt In Column 6,
i DESCRIPTION CALCULATION or other notes as appropriate
� POTWnnu apalily Nam :
] "POTWOddridplity Permit
"POTW/M nemalty Average Flow,in MGD: 35?2?y-
^'POTWrli 'polity Reommin Stream Name: 31 yCn...k
t `POTWRd I'pahly Receivn09heam y0lo,in ds- 2f
l
IMusiry Neme: Lc e 8 i?cwr
I Intlustnat User Preheatment Permit OUP)g:
z
€ Average Daily ga victims from water handling system to
€ POTW(ADD),
In in NED MGD. 00254
Percent d Mdestry Flow at PORN influent(Intl IWC@POTW): D.P95",S =IADD/(POTWAVE FLOW*ADD))'100
Nannot Wnde Protlud: Fermata 809i Pmcent composition IN adive Ingredient
Agive ln0radent Sa^:um lyPodParita
Aid.Ingredient ,um Hydro
( Agive hgredieni:
g Active Ingredient: -- - - - - - - --
S
AdlvdIdneRent
r - -- in 11 Fit 8INWINQ On rpp V Wace3 gfam3ls
Feetl Wksm,of t.,han)olwatearmud al rady of Middle GE,O mum Fe Matra: i
Tolalvolnd Midianite
handling PO (VOL),)nn eigioib!addel - _ __---Note:A van..........
ch.escripaoMuye.nolfor mur madom ,holds
I 'midis and discharge point into POTW(VO in tNaons of (syate Wee,do,average cyder per Mowtlown,holtlin,
gallons: 0_005 lagoon Wee,etc.),
pH at handing system is,glare blodde atltlNan.
(it Mike
Life ga,enter red rm
Half
em or eamuiredfor@e feel Stem mentito m ITAL to hall of ita - --- - - -- --
aginal egpcenha0on)(Hy,in tlaya (t unxnoxn.enter NA): 4 Note:Provitleaovrw of tlatn
7 Oeca Rate,at pH level wHhin l2 pH atanEaN unit within hantlling - --
3 system(DK): 0.1725 RHL=NA.Men DK=o,dherwisa DK=(1Mq'0.fi9
Dimma dt.Fada(OFL 5053 -(ADDNOL)+DK OF is mefirsl oMer loss ceeR'ant
Steady Stele Biodde Died,age Cormarde ion in[mainly,
dlsehaga(SSBC@IND), in and, 0.4905 =DR/(DF`VW3785)
Biodtle Comes ra,on @ POTW Influent @ avene,POTW
oontlNon3.in myl: ("W09 -TSSBC@IND)',ND IWC@PO1w)/100
In any information maflede on Me More pedum or adive - - -
t ingredient regarding 0eh potential to cause lnhiNtion of b!obgidd NG
trom,ent pmeasaes at mmidpds? YES a NO If YES,please complete PART IV below
Lowest Inured.Cited.,in mill: - 2,0000 _-- summagcally entered hen Pan IV befaw
Does Rookie COnren0a4on.1 Me POTW influent PASS on rW�O Pau ITbmdtle cencentratire@ POTW Influents Inhibition
Imitator? PASS Coen.
7
A.More melet, rosent in the while Formed or active mgretlied?
t YES orNO»
!s
Yss If YES,please complete PART VII
Do Metals Level at POTW influent PASS? PASS amomafiddly entered fmm Part Vll Metals Worksheet
POTW Ideream Waste Cremeotdtiel(POTW effluent to POTW
,l receiving stream during average POTW flow emtlitiom,and 7QI0 -(POTW AVE FLOWIN)/1(7010'0t-POTW AVE
- receiving an..sotaifions).W 50,0111 FLOW)
aiodde Concentagmn in POTW Rec¢Nmg Stream dunes middle =(Miredde Cone @POTW Influent @ Avg.POTW
POTW Influent flex denied and 7010 receMn,dream conddeand'(POTWIWC@RECEIVINGSTREAM)) /
wnditims,in mgfl: 0,0004 100
Lowed LC50(tent I icddes Toudty Data Worksheed.mgM1 0.is automatically entered from Part V bride.
Highest Amount Allavetl in Receiving Sream(Rac.Ensure =0HL=NA er>4,Pon mount a Wowed=LCM-0.01,
I Regulated Urnitetion), in did: 0.0200 otherwise=LC59.0.05
1 It Naiads Condedem0n in Kecemng Stream less Man or equal to
f Amount allowed in Receive,Sheam,
Bloods Todaty Evaluation Passes: 'ASS
OVERALL SIOCIDE/CHEMICAL STATUS> � Page l oft
RR4tgkFemnd iodtleChemicalPreheamtent Worksheet-PT101 excel Version
2009
Veraion May 2008
3

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Low and Bonar
1301 Sand Hill Road
Enka,NC 28728
j Biocide Toxicity Evaluation -NC DEQ Form 101
Suurces:Cooling Towers 1&3,BASF Tower
Dme: 5/I/I7
PERMIT4:N/A
RECEIVING STREAM flo.my Creek
= 7QI0 cfs: 5:21.00
LW C.% b.1795
S
PRODUCCG-C Formula 2902-Cool'm Water Trealmeot
Sodium Hydroxide(8%),Acrylic'OF
ulym0 "' Sodium
ACTIVE INGRED[ENT(%): Tolplhiazole(3%),Phoaphonic Acid(3%),
Sodium Mol bdalu 1%
Ceroda hnia dabia 96-hr
3 HALF LIFE Gn DAYS) LL. : 4.00 rr' STEADY STATE DISC CONE: 143242
LC50 OF SELECTED TOX DATA m Ie6O: P22:2 DEGRADATION FACTOR .F.: 4880
DECAY RATE D.K. : 0,0000 ' APPLICATION FACTOR: 0.050
DOSAGE RATE in GRAMS/DA D.R. : _.:1322.9-.-
AVGDAILYDISCHARGE(in MGD A.D.D . 0.02440. INSTREAM DIOCIDE CONIC: 0.0257
i, VOLUME'OF SYSTEM MIL.GAL'S : 0.005 3 REGULATED LIMITATION: 1.11
I7 PASS/FAIL: PASS
7 PRODUCT:G-C Formula 2002-Coolin Water Treetmeat
ACTIVE INGREDIENT(°o): Tolyltrlezole(3%),Phosphonio Acid(3%),1{EDP(200),
� Pimc hales romelas 94M1r
i
HALF LIFE(DAYS): 4.00 ''STEADY STA'IT:DISC CONCc 14.3292
LC50/EC50 OF SELECIED TON DATA(MGIL): 903.7 DEGRADATION FACTOR: 4.880
S DECAY RATE: 0.0000 =:APPLICATION FACTOR: 0.050
DOSAGE RATE(GRAMS/DA : '1322.9
j AVG DAILY DISCHARGE MGU: 0.02440' F. INSTREAM BIOCIDE CONC: 0.0257
VOLUME OF SYSTEM MIL.GALS): 0.005<' .- REGULATED LIMITATION: 40.185
PASS/FAQ.: PASS
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Pinga6Environmmial SCmcm,LLS 9Wo vale Avenue AsbwiWl NC288W 82&76&3335 pi,,hair@v, du

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Low and Bomar
1301 Sand Hill Road
Enka,NC 28728
t Biocide Toxicity Evaluation -NC DEQ Form 101
l
Sources:Air lVasMers 4&5,Coolin Towers 1&3,BASF Tmveq AC Tower
Date: 5/1/17
I PERMIT#:N/A
} RECEIVING STREAM: Itomin Cmek
7 10 :
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PRODUCT: G-C Rormula 315-I ioeide
ACTIVE INGREDIENT(%);Magnesium Nitrate Q-3%),Chloromelhylisoffimolm(1-
{. lisot'Wolin <I%,Ma nesium Chloride ,1
3 Ceriode bnia dubia 9&hr
S
IIALF LIFE E.DAYS LL. : 4.00 .:; STEADY STATE DISC CONC: 16.2412
LC50 OF SELECTED TOX DATA m L(bust): Z&A S DEGRADATION FACTOR ,F. : 4,880
i DECAY RATE(D.K.): 0.0000 APPLICA"LION FACTOR: 0.050
DOSAGE RATE IinGRAMS/DA .R. : 1499,9
AVG DAILY DISCHARGE(in MGD A.D.D 0,02440 MSTRFAM BIOCIDE CONE 0.0292
VOLUME OF SYSTEM MIL.GADS : 0.005 2 REGULATED LIMITATION: 0.394
PASSJFAIL: PASS
PRODUCE G-C Formula 315-Bioeide
ACTIVE INGREDIENT(%): Magnesium Nitrate lin(<,ChlorounhiusChloride(1-
2%,MGh lisolhfazolin q%,Ma nesium Chloride <70/
Pime hales p,o.eW 96-hr
HALF LIFE FDAYSE 4.00 STEADY STATE DISC CONE: 16.2412
LC50/EC50 OF SELECTED FOX DATA(MGIL. 9.56.. ;< DEGRADATION FACTOR: 4.880
DECAY RATE: .0.0000 APPLICATION FACTOR: 0,050
DOSAGE RATE GRAMSIDA '.. 1499.97:':
AVG DAILY DISCHARGE MGD: 0,02440 INSTREAMBIOCIDECONC: 0.0292
_ VOLUME OF SYSTEM ML.GALS: 0.003l: REGULATED LIMITATION: 0.478
PASS/TAIL: PASS
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P&gAFX onmenutl Sere,ee,LLS 9Noodvale Aveme AhM1 dle,NC288W 82896W335 pugaM1 eirl tado
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Low and Bonar
1301 Sand Hill Road
Enka,NC 28728
Biocide Toxicity Evaluation -NC DEQ Form 101
Sources:Air Washters 4&5
l
Date: 5/I/17
j PFRMITk:N/A
I RECEIVRJG STRL'AM: Homin Creek
7 10 cfs: 21.00 -
3
PRODUCT:IG-C Formula 314T-Biocide
I ACTIVE INGREDIENT(%): BromoChloroDimethylHydwnoiode(969%)
7
Oachork .bus m kiss 96-hr
HALF LIFE jin DAYS LL. : 4.00 STEADY STATE DISC CONC: 4.0961
LC50 OF SELECTED TOX DATA m , Twat. 0.87_. ': DEGRADATION FACTOR .F. : 4. 880
DECAY RATE .K. : 0.0000 APPLICATION FACTOR: R050
DOSAGE RATE io GRAMS/DAY(D.R. : 378.3 '
AVG DAILY DISCHARGE(in MGD A.D.D 9:02440MSTREAM BIOCIDE CONC: 0.0074
VOLUME OF SYSTEM B,.GAVS : a005 ] REGULATED LIMITATION: 0.0435
PASS/FAIL: PASS
PRODUCT: G-C Formula 314T-Biocide
ACTIVE INGREDIENT(96): BromoChlo.DimethylHydantoiade(9fi%)
I
i Da hoia ma oe(48-kr
HALF LIFE AYS : 4.00 !t STEADY STATE DISC CONC: 4.0961
EC50 OF SELECTED TOX DATA m 0.46 DEGRADATION FACTOR: 4.880
DECAY RATE: 0.0000 ,.:1. APPLICATION FACTOR: 0.050
DOSAGE RATE GRAMS/DAY : 378.3
s AVG DAILY DISCHARGE GD : ,`R02440'- INSTREAM BIOCIDE CONC: 0.0074
j VOLUME OF SYSTEM MIL.GALS : - 0,005 REGULATED LIMITATION: 0.023
PASS/FATU PASS
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'; PisgaM1 Firviromrsulel Seeviees,LLS 9Wo vale Avenue Ashevlllv.NC28804 828.76&3335 pisyah-air&1e4u
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Low and Bonar
1301 Sand Hill Road
Enka,NC 28728
Biocide Toxicity Evaluation-NC DEQ Form 101
Seurcea:AC Tmvev
Date: 5/1/17
- PERMIT#: N/A
RECEIVING STREAM 111..niny Cseek
7 10 cl's : .'f3L00:'=
I.W.C.%:1 0.1795:
i
PRODUCT: G-C Formula 2002LT-Co.H.g Water Treatment
Sodium Hydroxide(7-10%),Acrylic Copolymer(3-6%),
ACTIVE INGREDIENT(%):Sadiom TWyltria ole(2-6-A,Phosphwio Acid Derivitave
4-6% HEDP I-4°!o
Ceroda hnia ma na 96-hr
HALF LIFE in➢AYS FLL, : -4.00 STEADY STATE DISC CONC 3.6865
LD50 OF SELECTED FOX DATA m Imt 1894.6 DEGRADATION FACTOR .F.: 4.880
DECAY RATE .K. : 0.0000 APPLICATION FACTOR: 0.050
j DOSAGE RATE in GRAMS/DAY)D.R. : 340.5:
AVG DAILY DISCHARGE in MGD A.D.D 0.02440 INSTREAMBIOCIDECONC 0,0066
VOLUME OF SYSTEM MIL.GADS: 0.005 REGULATED LIMITATION: 94.73
PASSIFAIL: PASS
PRODUCT:C,-C Formula 2302LT-C.H.z Water Treatment
73 Sodium Hydroxide D.10%),Acrylio Copolymer(3.6%),
)` ACTIVE INGREDIENT(%):Sodium Tolylmiaao1.(2b1A),Phosphoric Acid Derivitave
t 4%)
Pime hales pro.d.s(96-hr)
HALF LIFE DAYS$ 4.00 STEADY STATE MSC CONC: 3.6865
LC50/EC50 OF SELECTED TOX DATA MG/L 1593.2 DEGRADATION FACTOR: 4.880
DECAY RATE: - 0.0000, APPLICATION FACTOR: 0.050
DOSAGE RATE GRAMS/DAY : -340.5
j AVG DAILY DISCHARGE OD: 0,02440 INSTRF.AM BIOCIDE CONC 0A066
VOLUME OF SYSTEM(MIL.GALS): 0.006. ._. REGULATED LIMITATION: 79.66
PASS/FAIL: PASS
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Low and Bonar
1301 Sand Hill Road
Enka,NC 28728
Biocide Toxicity Evaluation-NC DEQ Form 101
Soureea:Boiler
Dato: 5/1/17
PERNBTd:N/A
RECEIVING STREAM:MSD
7210 cfs: .:.;21A0.:
LW.C.% 0.1795
3
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PRODOCT: G-C Formula 159.O en Scavenger
i ACTIVE INGREDIENT(%): Sodium Bisulfitu QM5%),Potassium SuRHa QM59/.)
No data available for this tomduct
HALF LIFE Ea DAYS .L. : Y4 0 '-. STEADY STATE DISC CONC: 2.4987
LC501EC50 OF SELECTED TOX DATA MG/L I 0:1 DEGRADATION FACTOR .F. : 4.880
DECAY RATE .K.: 0,0000 APPLICATION FACTOR: 0.050
DOSAGE RATE inGRAMS/DA Q).R. f 2:0.8
AVG DAILY DISCHARGE inMGD A.D.D. : r.�0.02440 INSTREAM BIOCIDE CONC: 0.0045
VOLUME OF SYSTEM IL.GALS : `:0.005:r: REGULATED LIMITATTON: 0.005
g PASS/FAIL: PASS
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Low and Bonar
1301 Sand Hill Road
Enka,NC 28728
1 Biocide Toxicity Evaluation-NC DEQ Form SOS
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Sources:AC"foxer
I
Ow 511/17
I PERMITk:N/A
RECEIVMGSt'REAM:Homin Creek
7 10 cfs 21.00
I.W.C.%:
i
PRODUCT: G-C Formula 55-PenetrantIDu ersaet
S ACTIVE INGREDIENT(%): Amides N,N-His(Hydroxycthyl)(5%),Melhyl-Oximne
Polymer with Oxirme(5%)
t No D.N Available for this roduct.
HALF LIFE in DAYS H.L. : '4:00 -' STEADY STATE DISC CONCt 0.8192
LCS"-00 OF SELECTED TOX DATA MG/L h <0d - DEGRADATION FACTOR .F. : 4.880
DECAY RATE D.K. : 0.0000 i. APPLICATION FACTOR: 0.050
1 DOSAGE RATE hnGRAMS/DA .R. : �. 43:36
a AVG DAILY DISC11ARGE m MGD A.D.D. : 0,02440 IMSTREAM BIOCIDE CONC: 0.0015
VOLUME OF SYSTEM IL.GAL'S: 0.005 : REGULATED LIMITATION: 0.005
PASSITAIL: PASS
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PisgWi FnvhmmenWServlcea,LL9 9Wo vale Avmue Ashmile,NC288N $28-768-3335 psgA.afy'Je9a
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ATTACHMENT B
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Garratt-Callahan Water Treatment Chemical SDSs
4
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Low&Bonar,Inc.—Wastewater Discharge Permit

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GarratL
CA L LA H A N SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
i
PRODUCT NAME: FORMULA I I S4
I PRODUCT USE: BOILER WATER TREATMENT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
3 sections of this SDS.
UN NUMBER: NOT REGULATED
I
€ PROPER SHIPPING NAME: NOT REGULATED
MANUFACTURER'S NAME: Garratt-Callahan Company
E ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
!_ Outside North America:+I-703-5273887
BUSINESS PHONE: Product Information:650-697-5811
i SDS NUMBER: SDI 154
DATE OF REVISION: 4/2 012 0 1 5
i
I SECTION 2-HAZARDS IDENTIFICATION
7 SIGNAL WORD:WARNING
HAZARD STATEMENT:
1-1315:Causes skin irritation.
( H320:Causes eye irritation.
H335:May cause respiratory irritation.
{
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PRECAUTIONARY STATEMENTS:(PREVENTION)
P101:If medical advice is needed,have product container or label at hand.
PI02:Keep out of reach of children.
PI03:Read label before use.
P260:Do not breathe dusdfume/gashust/vapours/spay.
P264:Wash all exposed skin/bair thoroughly after handling.
I P280:Wear protective gloves/protective clothingleye protection/face protection.
I
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
3
Hazard Scale
o=nmima
I-rknt
2 Moderate HEALTH INSTABILITY
7 RF.AOT{�t1'F`fk4ATAIS}f(yEL3,dt1S'S }F't 4 Severe
-=Chronic hazard
i
OTHER
S
i
i WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 1154 W garattcallahan.com Page I of 5
s

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingredients CA EC# 1CSC.# YLT%
i SODIUM HEXAMETAPHOSPHATE 68915-31-1 272-803-3 NE 20.2S
PROPRIETARY POLYMER MIXTURE NE NE <20
1
SECTION 4• FIRST AID MEASURES
Take a copy of this SDS to the health professional with the individual.P312:Call a POISON CENTER or doctor/physician if you feel unwell.
WARNING:Causes skin irritation.Causes eye irritation.May cause respiratory irritation,Also refer to Section I I for symptoms,effects,and likely
routes of exposure for this product.
TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems,
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
i
SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with soap and water.Rinse skin with wxtedshower.Minimum rinsing time is for I S minutes.
7 P362+P364:Take off contaminated clothing,and wash before reuse.P332+P313:If skin irritation occurs:Get medical advice/attention.
3 EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
_ do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes.Minimum rinsing time is for IS minutes.
P337+P313:Get medial adAce/atxmton.
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312:Call a POISON CENTER or docmdphysician if you feel unwell.
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Exposed individual must seek immediate medical attention if any adverse
effect occurs.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable[o
swallow.
i
" MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions Involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
occurs.
j NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
7
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-Flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment.
3
( SPECIFIC HAZARDS ARISING FROM THE Refer to section I0.7hermal decomposition may produce irritating fumes.
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CHEMICAL:
SPECIAL PROTECTIVE EQUIPMENT AND Firefgh[ers should wear fully protective clothing(chemical impermeable,Polly encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure selftomemed breathing apparatus.Do not release run off from fire control
' methods to sewer or waterways.
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a SECTION 6-ACCIDENTAL RELEASE MEASURES
1
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING:Any container expansion or rounding indicates pressure buildup. Use extreme motion.When opening,release pressure slowly
j through opening.
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P391:Collett spillage.
Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
can react with the spilled material.Add dry lien material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.
j SECTION 9-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest,Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics
while handling this product. Avoid breathing vapors,dusts or mists generated by this product.Use in a well-ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
7
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
3 Identified,well-Illuminated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between 50°F(1(°C)- 100°F(37'C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest.Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.P403+P233:Store in a well ventilated place.Keep container tightly closed.
1
SECTION B•EXPOSURE CONTROLS- PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/stored.
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EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME C S ACGIH TLV OSHA PEL OTHE@
TWA STEL TWA
I SODIUM 68915-31-I NE NE NE N/A
HEXAMETAPHOSPHATE
€ PROPRIETARY POLYMER MIXTURE HE NE NE NIA
1
NE=Not Established
INGESTION: Do not eat,drink,smoke,or apply cosmetics when handling this product Wash all exposed skiNhair
( thoroughly after handling.
RESPIRATORY PROTECTION: P261:Avoid breathing dust'fume/gasfmistl apours/spray.P271:Use only outdoors or in a well ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respirators with dust/mist/fume/spay filters are recommended if operations may produce dusts,mists or
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skisthair thoroughly after handling.Wear chemical safety goggles or safety glasses with
side shields.A face shield may also be necessary for splash protection '..
SKIN PROTECTION: P264:Wash all exposed skiMtair thoroughly after handling,P280:Wear protective gloves/protective
iclothing/eye protection face protection.Use chemically-resistant gloves and skin protection,when handling
this product.Use body protection appropriate for task(eg.,lab coat,oyealls).
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j SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
s
APPEARANCE and COLOR; Clear liquid VAPOR PRESSURE.mm Hg@20"C: Not established
ODOR: Odorless VAPOR DENSITY(Air=1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water=1): 1.2- 1.3
PH: 5.5-7.5 SOLUBILITY IN WATER: Complete
1. MELTING/FREEZING POINT: Not applicable PARTITION COEFFICIENT(n-octanolhvater): Not established
BOILING POINT: 212-F(100-C) AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(mBuAc=1): < I VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Notapplicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(In air by volume,%): Not established
4 SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product Is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: See incompatible materials.
CONDITIONS TO AVOID: Freezing temperatures.
INCOMPATIBLE MATERIALS: Strong oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition may result in oxides of carbon and nitrogen.
SECTION 11 -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: SODIUM HEXAMETAPHOSPHATE:
Oral:Ld50,Rat 3053 mg/kg
LIKELY ROUTES OF EXPOSURE: Skinleye contact and inhalation.
RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYEDAMMEDIATEICHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye,respiratory and gaso-oirmsdnal irritation.May be harmful if swallowed.
NUMERICAL MEASURES OF
TOXICITY: Not established for this product
} CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
SECTION 12•ECOLOGICAL INFORMATION
I ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:Dam not available for this product
PERSISTANCE AND DEGRADABILITY:No dam available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No dam available for this product
MOBILITY IN SOIL:No data available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for this product
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: P501:Dispose of corwrts/container in accordance with local/regional/wuonal/intematlonal regulations.Thoroughly draio/empry
? containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.
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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
I DOT: NOT REGULATED
IMDGIIMO: NOT REGULATED
IATAJICAO: NOT REGULATED
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): Not known.
TRANSPORT IN BULK(according to
E annex 11 marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: Not known.
SECTION IS- REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
j reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
'.. Reauthorization Act:
CHEMICAL NAME
SODIUM HEXAMETAPHOSPHATE SARA 302(40 CFR 355,Appendix A)NO
SARA 304(40 CFR Table 302.4)NO
SARA 313(40 CFR 37265)NO
,'- PROPRIETARY POLYMER SARA 302(40 CFR 355,Appendix A)NO
SARA 304(40 CFR Table 302.4)NO
SARA 313(40 CFR 372.65)NO
3
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Qnantides for the components of this product
The default Federal SDS submission and inventory requirement filing threshold of 10.000 Its(4,540 kg)therefore applies,per 40 CFR 370.20,
1 U.S.CERCLA REPORTABLE QUANTITY(RQ):None
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Title 311/312,Hazard Category: Acute Health: NO; Chronic:NO; Fire:NO; Reactive:NO: Sudden Release of Pressure:NO
California Safe Drinking Water and Toxic Enforcement Act(preposition 65): No component of this product is on the Proposition
i 65 list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
listing.
CANADIAN WHMIS CLASSIFICATION:None.
SECTION THER INFORMATION
} PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 4/2 0120 1 5 Supercedes: IM20D9
7
Although reasmuble are has been taken in me preparation of this documem ve extend no onantlas and make no repressmadons as to she accuracy or
amplemness of the informamm contained herein,and assume no responsibility ropmrg tlse suitability of this information for the users intended purpose or for the
consequences of its use. Each in ividual should make a denomination,as w the suitability of she infarmadmi for their panitufar purpose.
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SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 12-L
PRODUCT USE: CLOSED SYSTEM INHIBITOR
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
t UN NUMBER: 3266
1 PROPER SHIPPING NAME: CORROSIVE LIQUID,BASIC, INORGANIC,N.O.S. (SODIUM
NITRITE SOLUTION)8,PGII
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
Outside North America:+1.703-527.3887
BUSINESS PHONE: Product Information:650-697-5811
t
SDS NUMBER: SD6012
DATE OF REVISION: 2/8f2016
1
SECTION 2.HAZARDS IDENTIFICATION
s SIGNAL WORD:DANGER
3
3 HAZARD STATEMENT: ee
H301:Toxic if swallowed. 3
7 H315:Causes skin irritation. 2
4 H320:Causes eye irritation. 26
H333:May be harmful if inhaled.
H402:Harmful to aquatic life. 3
PRECAUTIONARY STATEMENTS:(PREVENTION)
- PI01:if medical advice is needed,have product container or label at hand.
- P102:Keep out of reach of children.
P103:Read label before use.
P264:Wash all exposed sklNhair thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
P280:Wear protective gloveslprotective clothingfeye protectoofface protection.
i
1 NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
I Hoard Scale
--- - - - P-Minimal
�r 1-Slight
3
3_ oJ�rdm HEALTH t„ INSTABILITY
7 r P)4, $RGAL-9 tCk{YEiXtS_4 };:a 4--Severe
IL - -,'i '=Chronic h rd
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FORMULA 12-L www.garrattcallahan.com Page I of 6

SECTION 3- CO MPOSITIONIINFORMATION ON INGREDIENTS
i H daus 1 gC d' is CA S# g9# ICSC#
SODIUM NITRITE 7632-00-0 231-555-9 1120 25-30
1
SODIUM METABORATE 7775-19-I 231-891-6 NE 7- 10
1
SODIUM TOLYLTRIAZOLE 64665-57-2 265-004-9 1091 1 -4
SECTION 4-FIRST AID MEASURES
1 Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
7 individual.P3 10.Immediately all a POISON CENTER or doctor/physician.
DANGER:Toxic if swallowed.Causes skin irritation.Causes eye irritation.May be harmful If inhaled.Harmful to aquatic life.Also refer to Section I I
for symptoms,effects,and likely routes of exposure for this product
I TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
I CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with soap and water.P332+P313:If skin irritation occurs:Get medical aclAce/attendon.P362
+P364:Take off contaminated clothing and wash before reuse.Minimum flushing time is for 15 minutes.
EYE EXPOSURE:P305+P35I+P338c IF IN EYES:Rime cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed Individual"roll"their eyes. Minimum flushing time is for 15
minutes. P337+P313:If eye irritation persists get medical advice/attention.
INHALATION:P304+P312:IF INHALED:Remove vkdm to fresh air and keep at rest in a position comfortable for breathing.
j INGESTION:P301+310:IF SWALLOWED:Call a POISON CENTER or doctor/physician if you feel unwell.P330:Rinse mouth.Never induce
? vomiting or give diluents(milk or water)by mouth to someone who Is unconscious.having convulsions,or unable to swallow.
j MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this produce Exposed individual must seek immediate medical attention if any adverse effect
occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION S-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment
1
j SPECIFIC HAZARDS ARISING FROM THE Nitrites are oxidizers,and in contact with readily oxidized materials will stimulate combustion at
CHEMICAL: high temperatures. Residue from this product may supply oxygen for a fire. Heated product may
3 emit toxic oxides of nitrogen and boron.
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure set&contained breathing apparatus.Do not release run off from Ore control
methods to sewer or waterways.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
j PROCEDURES.
jf WARNING:Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P273:Avoid release to the environment
- Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.P391:Collect spillage.
i
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventllation.Stop leak if without risk.Remove chemicals which
t can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.P391:Collett spillage.
I. SECTION 7-HANDLING AND STORAGE
I
( PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product.Do not eat drink,smoke,or apply cosmetics
[ while handling this product. Avoid breathing vapors,dusts or mists generated by this product.Use in a well-ventilated location. Remove
contaminated clothing immediately,Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Container of this product must be properly labeled.Storage areas of this product should be clearly
identified,welbillummated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
3 ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between 50°F(WC)- I OODF(37°C). Keep
container tightly closed when not In use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for Incompatibilities.
SECTION 8-EXPOSURE CONTROLS- PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
CHEMICAL NAME CAS ACGIH TLV OSHA PEL OTHER
t TWA STEL TWA
SODIUM NITRITE 7632-00-0 NE NE NE N/A
SODIUM METABORATE 7775-19-1 NE NE NE NIA
SODIUM TOLYLTRIAZOLE 6466S.57-2 NE NE NE N/A
7
NE Net Established
€ INGESTION: P264:Wash all exposed skiNhairthoroughly after handling.P270:Do not eap drink or smoke when using this
_ product.
RESPIRATORY PROTECTION: Do not breathe dusohmefgadmist/vapours/spay.Maintain airborne contaminant concentrations below
j guidelines listed above,if applicable. Air-purifying respirators with dust/mist/frandspay filters are
recommended if operations may produce dusts,mists or spays from this product with concentrations at or
above levels posted above,
EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.Wear chemical safety goggles or safety glasses with
side shields.A face shield may also be necessary for splash protection.
SKIN PROTECTION: P264:Wash all exposed skirdhair thoroughly after handling.P280:Wear protective gloves/protective
clothingleye protection/face protection.Use chemically-resistant gloves and skin protection,when handling '..
this product Use body protection appropriate for task(e.g.,lab coat,overalls). '..
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I SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear yellow liquid VAPOR PRESSURE,rem Hg @ 2VC: Not determined
ODOR: Sweet organic VAPOR DENSITY(Air=1): Notapplicable
ODORTHRESHOLD: Not established RELATIVE DENSITY@20°C(water-1): 1,26- 1.28
] PH: 12.5- I4.0 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not Established PARTITION COEFFICIENT(rroctanollwater): Not established
BOILING POINT: >212'F(100°C) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION LATE(n-BuAc=1): Not ombfshml VISCOSITY: Noceamblkhed
FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%):Not applicable
- SECTION ABILITY AND AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: None known
1 CONDITIONS TO AVOID: Do not combine with acidic compounds;a violent reaction will occur forming toxic vapon of nitrogen and
i sulfur oxides.
INCOMPATIBLE MATERIALS: Acids,amines,and oxidling agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition may yield oxides of carbon,nitrogen.
SECTION II -TOXICOLOGICAL INFORMATION
I TOXICOLOGICAL EFFECTS: No dam available for this product
7
? LIKELY ROUTES OF EXPOSURE: Skin/eye contact and inhalation.
RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYEDAMMEDIATEICHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
i NUMERICAL MEASURES OF
j TOXICITY: Not established for this product.
- CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
SECTION 12.ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY: Data not available for this product
PERSISTENCE AND DEGRADABILITY: No data available for this product.
( BIOLOGICAL ACCUMULATION POTENTIAL: No data available for this product
MOBILITYINSOIL: NodaUavailabieforthisproduct-
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer): No data available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(8EIs)have not been determined for this product
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly daWempty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.PSOL
Dispose of contents/container in accordance with Ioai/regional/national/international regulations.
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? SECTION 14-TRANSPORTATION INFORMATION
:
PROPER SHIPPING NAME
DOT: RQ for Totes and 55 gallons:
UN3266.CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
(SODIUM NITRITE SOLUTION)8,PGII
Emergency Response Guidebook,Guide No.: 154
? Passenger Aircraft Qty: IL
Cargo Aircraft Qty.30L '
IMDG/IMO: RQ for Totes and 55 gallons:
UN3266,CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
(SODIUM NITRITE SOLUTION)8,PGII
I IATA/ICAO: RQ for Totes and 55 gallons:
UN3266,CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
(SODIUM NITRITE SOLUTION)8,PGII
7 ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
- TRANSPORT IN BULK(according to
j annex II marpol 73178 and the IBC code): Not applicable,
t PP
SPECIAL PRECAUTIONS FOR USER: None known.
- PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
i
Unfired States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
I CHEMICAL NAME
SODIUM NITRITE SARA 302(40 CFR 355,Appendix A)—NO
' SARA 304(40 CFR Table 302.4)—YES
i
SARA 313(40 CFR 372.65)-YES
SODIUM METABORATE SARA 302(40 CFR 355,Appendix A)—NO
j SARA 304(40 CFR Table 302.4)—NO
SABA 313(40 CFR 372.65)-NO
SODIUM TOLYLTRIAZOLE SARA 302(40 CFR 355,Appendix A)—NO
SARA 304(40 CFR Table 302.4)—NO
SARA 313(40 CFR 372.65)-NO
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are specific Threshold Planning Quantities for the components of this product.The
default Federal SOS submission and Inventory requirement fling threshold of 10,00 Ibs(4,540 kg)therefore applies.per 40 CFR 370.20,
U.S.CERCLA Reportable Quantity(RQ): Sodium Nitrite: 100lbs(45A kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
Section 3111312 Hatard Category:Acute Health:YES CHRONIC YES Fire:NO Reactive:NO Sudden Release of Pressure:NO
j California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): No component of this product is on the Proposition
65 list.
j Intemational Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing
y CANADIAN WHMIS CLASSIFICATION: None.
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SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 2/8/2016 Supercedes: 8/1 012 0 1 5
This product has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OUV3-S994217 when prepared in either the
Addison.Illinois or Burlingame.Calfanda facilities.
3
jAhhough reasonable are has been taken in the preparetion of this document we mendue xarrend.and make rm repoocmadons az to the.,canary or
ompieteness of the lnformadon contained herein.and assume no responsibility regarding the suitability of ties infortnatlon for me user's intended purpose or for the
consequences of its use. Each in ividuzishould make a determination as tome suitability of me Information for their particular purpose.
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AA N SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
i
PRODUCT NAME; FORMULP.55
PRODUCT USE: PENETRANT/DISPERSANT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SOS.
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NOT REGULATED
'_. MANUFACTURER'S NAME: Garrott-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
j EMERGENCY PHONE: North America:GHEMTREC: 1-000-424.9300
Outside North America:+1.703.527.3887
I BUSINESS PHONE: Product Information:650497-5811
SDS NUMBER: SD2055
DATE OF REVISION: 6/8/2015
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SECTION 2-HAZARDS IDENTIFICATION
t
I SIGNAL WORD:WARNING
HAZARD STATEMENT:
H315:Causes skin Irritation. 2
H320:Causes eye irritation. 2B S
H335:May cause respiratory irritation. 3
i PRECAUTIONARY STATEMENTS:(PREVENTION)
a PI01:if medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P261:Avoid breathing dusdfume/gas/mist/vipours/spray.
P264:Wash all exposed skinthair thoroughly after handling.
P271:Use only outdoors or in a well-vendlated area.
P280:Wear protective gloves/protective clothingleye protection/face protection.
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
- Haard Sde
'! 0=Minimal
[-Right
3 geo uestc HEALTH INSTABILITY
`I RLAG'14V{11'HA,TrlyRD;YEI,.t-OW} ,.: 4=Chrorerm hoard
3
OTHER
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i SECTION 3- COMPOSITIONIINFORMATION ON INGREDIENTS
I
Hazardous Ingredients CAStF EC# ICSC# WT
( AMIDES,Cl2-18 AND C1&UNSATURATED, 90622-74-5 N/A NIA 5
N,N-BIS(HYDRO)CYETHYL)
METHYL-OXIRANE POLYMER WITH OXIKANE 9003-11.6 NIA N/A 5
I
7
SECTION 4.FIRST AID MEASURES
7 P312:Call a POISON CENTER or doctor/physician if you feel unwell.Take a copy of this SDS to the health professional with the individual.
i
WARNING:Causes skin and eye irritation.May cause respiratory irritation.Also refer to Section 1 I for symptoms,effects,and likely routes of
] exposure for this product
!I TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
i SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with plenty of water.Minimum flushing time is for 15 minutes.P362+P364:Take off
S contaminated clothing and wash before reuse.P332+P313:If skin irritation occurs:Get medical advicelattention.
EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum rinsing time is for 15 minutes.
P337+P313:if eye irritation persists get medical advice/attention,
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P312:Call a
POISON CENTER or doctor/physician if you Nei unwell.
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never Induce vomiting or give diluents(mllk or water)by mouth to
someone who is unconscious,having convulsions,or unable to swallow.Call a POISON CENTER or doctor/physician if you feel unwell.
i
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorder,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
i occurs.
NOTES TO PHYSICIAN:Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to 1=1 circumstances
EXTINGUISHING MATERIALS: and the surrounding environment Do not use carbon dioxide as an extinguishing material.
SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
( WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
t
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
J procedures.Proper protective equipment should be used, refer to Section 8-exposure controls.P391:Collect spillage.
Small Spill: Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Roma access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
f which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
Ij basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
container and seal.
i SECTION 7-HANDLING AND STORAGE
5
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not Ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product.Use in a well-ventilated to don. Remove
{[ contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
I CONDITIONS FOR SAFE STORAGE:Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,well illuminated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight.away from incompatible materials at temperatures between SWF(10°C)- 1 W F(37°C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.1`403+P233:Store in a well ventilated place.Keep container tightly closed.Keep away from oxidizing and reducing
agents.
SECTION 8-EXPOSURE CONTROLS- PERSONAL PROTECTION
v
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is usedlab re i.
t EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
1 ............................................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PEL OT EER
1 TWA STEL TWA
AMIDES,C12-IS AND CIB- 9062244-5 NE NE NE N/A
UNSATURATED,N,N-
BIS(HYDROXYETHYL)
METHYL-OXIRANE POLYMER 9003-II-6 NE NE NE NIA
a WITH OXIRANE
NE=Not Established
INGESTION: Do not eat drink,smoke or apply cosmetics when handling this produce Wash all exposed skimhair
j thoroughly after handling.
RESPIRATORY PROTECTION: P261:Avoid breathing dusdume/gas/mist/vapours/spmy.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respirators with dusHmist/fume/spray filters are recommended if operations may produce dusts,mists or
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.Wear chemical safety goggles or safety glasses with
side shields.A face shield may also be necessary for splash protection.
i SKIN PROTECTION: P264:Wash all exposed skinmair thoroughly after handling.P280:Wear protective gioves/protective
clothing/eye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
3 this product Use body protection appropriate for task(e.g.,lab coat,overalls).
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SECTION 9•PHYSICAL AND CHEMICAL PROPERTIES
7 APPEARANCE and COLOR Clear water white liquid VAPOR PRESSURE,man HgQ 20°C: Notapplicable
ODOR: Slight VAPOR DENSITY(Au=1): Not applicable
ODOR THRESHOLD: Not established RELATIVE DENSITYQ20-C(water-1): 0.97-1,07
pH: 7.5-10.5 SOLUBILITY IN WATER: Complete
i MELTING/FREEZING POINT: Not established PARTITION COEFFICIENT(n-octanol/water): Not established
BOILING POINT: 212°F(100°C) AUT01GNITION TEMPERATURE: Notapplicable
FLASHPOINT: Nonflammable DECOMPOSITION TEMPERATURE: Noteambl]shal
EVAPORATION RATE(r-BuAc=I): cI VISCOSITY: Not established
i FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%): Not applicable
SECTION IB-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: See incompatible materials.
CONDITIONS TO AVOID: See incompatible materials.
INCOMPATIBLE MATERIALS: Strong oxiditung and reducing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Not established.
SECTION 11 •TOXICOLOGICAL INFORMATION
j TOXICOLOGICAL EFFECTS: No data available for this product
3 LIKELY ROUTES OF EXPOSURE: Skin,and eye contact,Inhalation.
RELATED SYMPTOMS: Skin,eye and respiratory irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHROMIC
EFFECTS FROM SHORT AND
? LONG TERM EXPOSURES: Skin,eye and respiratory irritation.May be harmful if swallowed.
NUMERICAL MEASURES OF
TOXICITY: Notesmbiished for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,]ARC,or regulated by OSHA as carcinogens.
p SECTION 12-ECOLOGICAL INFORMATION
t ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
_ ECOTOXICITY:No data available for this product
PERSISTANCE AND DEGRADABILITY:No data available for this product
BIOLOGICAL ACCUMULATION POTENTIAL No data available for this product
MOBILITY IN SOIL No data available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No data available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for this product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL P501:Dispose of contents/container in accordance with IocallregionaVnational/international regulations.Rinse empty containers with
j water and use the rinse water to prepare the working solution. Refer to Section 8 for exposure controls-personal protection.
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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: NOT REGULATED
IMDG/IMO: NOT REGULATED
IATA/ICAO: NOT REGULATED
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex 11 marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
SECTION I5• REGULATORY INFORMATION
United States and International Regulations
` United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
CHEMICALNAME
AMIDES,C12-I8 AND C 18- SARA 302(40 CFR 355,Appendix A)-NO
UNSATURATED,N,N- SARA 304(40 CFR Table 302.4)-NO
BIS(HYDROXYETHYL) SARA 313(40 CFR 372.65)-NO
METHYL-OXIRANE POLYMER WITH SARA 302(40 CFR 355,Appendix A)-NO
OXIRANE SARA 304(40 CFR Table 302A)-NO
SARA 313(40 CFR 372,65)-NO
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
The default Federal SDS submission and inventory requirement filing threshold of 10,000lbs(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):None.
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Tide 3111312,Hated Category: Acute Health: NO; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
California safe drinking water and toxic enforcement act(proposition 6S): No component of this product is on the Proposition 65
j list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
listing.
CANADIAN WHMIS CLASSIFICATION:None.
i SECTION 16-OTHER INFORMATION
)
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 6/8/2015 Supercedes: 7/23/2014
Formula 55 is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds for
category codes Al,GS.G7;with NSF Reg.No. 133119.
1
f Although reasonable are M1ati been taken to she pre 4 us....
of skis ee pment,y i,ndur ,th xartanties and make no Information
for the us as to the ed purpose
r sor
e
i completeness of the e. Each
Information contained should
m,and assume no responsibility regarding the a infor ry of Nisr theur auon for the user's intended purpose or for the
consequences of its use. facM1 IMiNdual shooltl make a determination as m the suitability of due information for Heir particuhr purpose.
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Garratt
CA L LA H A N SAFETY DATA SHEET
SECTION 1 -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 159
7 PRODUCT USE: OXYGEN SCAVENGER
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
j sections of this SDS.
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NOT REGULATED
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1-800-424-9300
Outside North America:+1.703.527.3887
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SDI559
DATE OF REVISION: 7/292015
i
SECTION 2.HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
GHS HAZARD STATEMENT:
H316:Causes mild skin irritation.
H320:Causes eye inniatlon.
H335:May cause respiratory Gritation.
PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:if medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
' P103:Read label before use.
P261:Avoid breathing du dfume/gas/mist/vapouWspay.
P264:Wash all exposed skip/hair thoroughly after handling.
j! P271:Use only outdoors or in a well-ventilated area.
I
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
HasardSnle
0=Minimal
I=Slight
i * - 2-Moderate _
3-Serious HEALTH INSTABILITY
EE-^RE`AOTPii'Y;V`HA2:A D{YEtb,4jY(} 0 4=severe
k ., *-Chronc Bayard
OTHER
{
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3
SECTION 3- COMPOSITIONIINFORMATION ON INGREDIENTS
Hazardous Ingeed'enes CA S# M ICSC# WTI
1
SODIUM BISULRTE 7631-90-5 231-548-0 N/A 20-25
POTASSIUM SULFITE 10117-38-1 233-321-1 NIA 20-25
SECTION 4-FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
individual.P312:Calla POISON CENTER or ductorlphysician if you feel unwell.
WARNING:Causes mild skin irritation.Causes eye irritation.May cause respiratory irritation.Also refer to Section I I for symptoms,effects,and
likely routes of exposure for this product
TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
j CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE:IF ON SKIN:Wash with water.Minimum rinsing time is for 15 minutes.Take off contaminated clothing and wash before reuse.
1 P332+p313:B skin irritation occurs:Get medical ach,kedatumdon.
EYE EXPOSURE:P305+P35I HP338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing.Use sufficient force to open the eyelids.Have the exposed Individual"roll"their eyes.Minimum rinsing time is for 15 minutes.
P337+1`313:If eye irritation persists get medial adAce/attention.
t INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P312:Cali a
{ POISON CENTER or doctor/physician if you feel unwell.
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give diluents(milk or water)by mouth to
[- someone who is unconscious,having convulsions,or unable to swallow.Call is POISON CENTER or doctor/physician if you feel unwell.
} MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
occurs.
j NOTES TO PHYSICIAN:Treat symptoms as demonstrated by signs and distress in the patient
3
SECTIONS•FIRE FIGHTING MEASURES
j SUITABLE(AND UNSUITABLE) Product is non-8amma6le.Use media appropriate for the surrounding fire.
t EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL:
j SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
j methods to sewer or waterways.
7
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SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures. Proper protective equipment should be used, refer to Section 8-exposure controls.
i
Sma1f Spill: Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container. P391:Collect spillage.
1
Large Spill: Restrict access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
I which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers.
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
container and seal. P391:Collect spillage.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or prolonged
contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics while handling
this product Avoid breathing vapors,dusts or mists generated by this product Use in a well-ventilated location. Remove contaminated clothing
Immediately.Refer to Section 8 for exposure controls.
i
j CONDITIONS FOR SAFE STORAGE: All employees who handle this material should be trained to handle it safely.Open containers slowly
on a stable surface. Containers of this product most be properly labeled,Storage areas of this product should be clearly identified,well-illummated,
clear of obstruction and accessible only to trained and authorized personnel. Stare containers in a cool,dry location,away from direct sunlight,at
temperatures between 50°F(10"C)- 100°F(37°C). Keep container tightly dosed when not in use.P405:Store locked up.Refer to Section 10 for
incompatibilities.
SECTIONS-EXPOSURE CONTROLS- PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower trades is recommended to be
available near where this product Is usedfstnned.
EXPOSURE LIMITS/GUIDELINES: EXPO.SURE. . ..LIMITS. . .IN.AIR.. .....
. . . .. . ..... ... .. . .....
CHEMICAL NAME CAS# ACGIH TLV OSHA PE L OTHER
TWA STEL TWA
3
i SODIUM BISULFITE 7631-90-5 5 mgfm3 NE NE N/A
3
POTASSIUM SULFITE 10117-38-I NE NE NE N/A
s
NE=Not Established
INGESTION: Do not eat drink,smoke,or apply cosmetics when handling this product Wash all exposed skn/hair
thoroughly after handling.
RESPIRATORY PROTECTION: P261:Avoid breathing dusUPome/gas/rdst/vapours/spray.V271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if appliczbfe. Air-purifying
respirators with dusdmisdfumelspray,filters are recommended if operations may produce dusts,mists or
sprays from chit product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skinthdr thoroughly after handling.Wear chemical safety goggles or safety glasses with
side shields.A face shield may also be necessary for splash protection.
SKIN PROTECTION: Wash all exposed skinmair thoroughly after handling.Wear protective gloves/protective clothingleye
protec[iordface protection.Use chemically-resistant gloves and skin protection,when handling this product.
I Use body protection appropriate for[ask(eg.,lab coat,overalls).
1
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear light yellow/water white VAPOR PRESSURE,man Hg@2VC: Not established
ODOR: Slight VAPOR DENSITY(Air=1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20-C(water=1): 1.3- 1.4
PH: 6.0-8.5 SOLUBILITY IN WATER: Complete
5 MELTING/FREEZING POINT: Not established PARTITION COEFFICIENT(moc anol/water): Not established
BOILING POINT: Notestabiblud! AUTOIGNITION TEMPERATURE: Notescablished
j FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): Not established VISCOSITY: Not established
i FLAMMABILITY(SOLID/GAS): VOLATILE ORGANIC COMPOUNDS(%):Not established
i FLAMMABLE LIMITS(in air by volume,%): Not established
SECTION 10-STABILITY AND REACTIVITY
j REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
} HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: Normally stable.Sulfur dioxide also will evolve slowly at ambient temperatures.
j INCOMPATIBLE MATERIALS: Oxidizers:may cause strong exothermic reactions.Acids:releases sulfur dioxide gas which is toxic,corrosive,
and potentially deadly.
HAZARDOUS
DECOMPOSITION PRODUCTS: Sulfur dioxide.
SECTION 1 t -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: No data available for this product
i LIKELY ROUTES OF EXPOSURE: Skin,and eye contact,inhalation.
RELATED SYMPTOMS: Skin,eye and respiratory irritation.May be toxic if swallowed.
DELAYED/IMMEDIATE/CHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye and respiratory irritation.May be toxic if swallowed.
NUMERICAL MEASURES OF
i
TOXICITY: Not established for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
i SECTION 12.ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
Fish:96 hr,LC50,Fathead Minn.,883.9 mg/L
Daphnia:48 hr,LCSO,Daphnia Cuba,507.7 mg/L
PERSISTANCE AND DEGRADABILITY:No data available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No data available for this product
MOBILITY IN SOIL:No data available for this produm
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(SEls)have not been determined for this produm
1
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: P501:Dispose of contents/mnwiner in accordance with local/regional/nauonaltinternational regulations.Thoroughly drain/empty
containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.
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SECTION 14•TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: NOT REGULATED
IMDG/IMO: NOT REGULATED
IATA/ICAO: NOT REGULATED
I ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
1 TRANSPORT IN BULK(according to
annex It marpoi 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
j
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
' reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superhard Amendments and
Reauthorization Act.
CHEMICALNAME
1 SODIUM BISULFITE SARA 302(40 CFR 355.Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
_ SARA 313(40 CFR 372,65)-NO
POTASSIUM SULFITE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
The default Federal SIDS submission and Inventory requirement fling threshold of 10,000 Its(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):Sodium bisulfite(7631-90-5):500016s(2268 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Title 311/312,Harzrd Category: Acute Health: NO; Chronic NO; Fire:NO; Reactive:NO; Pressure:NO
California safe drinking water and toxic enforcement act(proposition 65): No component of this product is on the Proposition 65
List.
3 International Regulations
CANADIAN REGULATIONS:
{ CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
i listing.
CANADIAN WHMIS CLASSIFICATION:Not Classified
SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 7/29/2015 Supercedes: 12/23/2014
FORMULA 159 has been certified by the Orthodox Union as Kosher Pereve under the UK ID number of OUV3-A6E0470 when prepared in either
the Addison,Illinois or Burlingame,California facilities.
I
Although reasonable aare has been one.in the xeparama of da,document,we extend no wam atlas and make no represemadons as to the accuracy or
I completeness of the information contained herein,and assume no responsibility regardi,the suitability of this information for the user's intended purpose or for the
consequences of its use Each iMNiduai 0midd make a detemanstiion as to the suitability of the Informs6en for twir particular purpose.
t
I
WATER TREATMENT EXPERTISE SINCE 1904
i FORMULA 159 www.garrattcallahan.cont Page 5 of 5
3

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Garratt
CA L L A A N SAFETY DATA SHEET
3
SECTION 1 -PRODUCT IDENTIFICATION
I
PRODUCT NAME: FORMULA 314-T
PRODUCT USE: BIOCIDE
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UN3085
PROPER SHIPPING NAME: UN3085,OXIDIZING SOLID,CORROSIVE,N.O.S. (CONTAINS
BROMO-CHLORO-DIMETHYLHYDANTOIN),5.1(8),PG III,
f MARINE POLLUTANT
j MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
i EMERGENCY PHONE: North America:CHEMTREC: 1-800-424.9300
Outside North America:+1.703.527.3887
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: S03314
DATE OF REVISION: 3/29/2016
SECTION 2-HAZARDS IDENTIFICATION
1
) SIGNAL WORD:DANGER
HAZARD STATEMENT:
H272:May intensify fire:oxidizer. 3
H302:Harmful if swallowed. 4 0
1-1314:Causes severe skin bums and eye damage. IA < >
1-1317.May cause an allergic reaction.
H4W:Very toxic to aquatic life. I
f PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:If medical advice Is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
3 P210:Keep away from heatisparks/open flames/hot surfaces-No smoking.
7 P220:Keep/Swm away from clothing/combustible materials.
P260:Do not breathe dust/fume/gas/miso'vapours/spray.
P264:Wash all exposed skinthair thoroughly after handling.
1 P270:Do not eat,drink or smoke when using this product.
P272:Contaminated work clothing should not be allowed out of the workplace.
P273:Avoid release to the environment
j P280:Wear protective gloves/protective clothing/eye protection/face protection.
NFPA RATING
f HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Hoard Sale
i - - 00.Mmimai
I I=susht
j 2=Mademte HEALTH may. _ INSTABILITY
I 3-Senow
<yHYS(G`At,k1AZJSR}}(Yk`LCOW) - 1 4-6evere
'ChronK hoard �X
i
1
{ WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T www.garrettscaliahao.com Page I of 6

i
SECTION 3- CO MPOSITION)INFORMATION ON INGREDIENTS
Haxa d us Ing ed' is CAS# ECG ICSC# WT
i
I-BROMO-3-CHLOR0-5,5-DIMETHYL- 16079A0-2 240-230.0 NE 96
HYDANTOIN
I
3
SECTION 4-FIRST AID MEASURES
I Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
individual.P310.Immediately call a POISON CENTER or doctor/physician.
1
DANGER May rt fire;oxidizer.Harmful if swallowed.Causes severe sole burns and eye damage.May cause an allergic reaction.Very toxic to
3 aquatic life.Also refer to Section I I for sympoms,effecrs,and likely routes of exposure for this product.
TARGETORGANS:
I ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
[ SKIN EXPOSURE:P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.P302+P352:IF ON SKIN:
Wash with soap and water.Minimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not to contaminate the
t eyes.P362+P364:Take off contaminated clothing and wash before reuse.P332+P313:if skin irritation occurs:Get medical advice/atmotian.
EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
1 do—continue rinsing, Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes.P310.Immediately all a POISON CENTER or doctor/physician.
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:Immediately
call a POISON CENTER or doctor/physian.
INGESTION:P301+P330+P33 1:IF SWALLOWED:Rinse mouth.Do NOT Induce vomiting.P30I+p312:IF SWALLOWED:Call a POISON CENTER
or doctor/physician if you feel unwell.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having
1 convulsions,or unable to swallow.P3 10:Immediately call a POISON CENTER or doctor/physician.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
j Organd'may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
occurs.
4
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient.
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) P370+P378:In case of Ore:Use water spray,fog or mist Alcohol-resistant foam.DO NOT use
EXTINGUISHING MATERIALS: CO2 or dry thermals,
i
� SPECIFIC HAZARDS ARISING FROM THE Oxidizing material.Toxic gases/vapours/fumes of.Bromine.Chlorine.Oxides of the following
CHEMICAL: substances:Carbon.Nitrogen.Thermal decomposition or combustion products may include the
following substances:Toxic gases or vapours.
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
3 PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus. Do not release run off from fire control
methods to sewer or waterways.Move containers from fire area if it can be done without risk.
t Control run-off water by containing and keeping it out of sewers and watercourses.
s
WATER TREATMENT EXPERTISE SINCE 1904
( FORMULA 314-T www.garrattcallahan.com Page 2 of
I

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SECTION6•ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING:Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P273:Avoid release to the environment-
i Small Spill:Mop up,or absorb with an inen dry material and place in an appropriate waste disposal container.P391:Collect spillage.
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk Remove chemicals which
can react with the spilled material.Add dry men material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
3 basements or confined areas,dike if needed.Avoid generation of dust Avoid contact with water Ensure that exposure to product is not at a
concentration exceeding regulatory limits. Decontaminate the area thoroughly.Decontaminate all response equipment with soapy water before
returning to service.Place all spill residue in a suitable container and seal.P391:Collect spillage.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors.dusts or mists generated by this product.Use in a well-ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.P210.Keep away from heat/sparks/open
flames/hot surfaces-No smoking.P220:Keep/Store away from clothing/combustible materials.P273:Avoid release to the environment.P280:Wear
protective gloves/protective clothingleye protectionflzce protection.
i
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,well-illuminated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a dean,cool,well
ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between SOT(I VC)- I00'F(37°C). Keep
container tightly closed when not in use.Avoid spilling,skin and eye contact Avoid contact with acids,moisture or combustible materials.Keep
away from heat,sparks and open flames.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
I Section 10 for incompatibilities.
SECTION 8-EXPOSURE CONTROLS•PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety,shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITSIGUIDELINES: EXPOSURE LIMITS IN AIR
.........................................I—...........
...
CHEMICAL NAME
585 ACGIH T OSHA PEL OTHE
STR
TWA $TEL TWA
I-BROMO-3-CHLORO-5,5- 16079411-2 NE NE NE MIA
DIMETHYL-HYDANTOIN
NE=Not Established
INGESTION: P264:Wash all exposed skin/hair thoroughly after handling.P270:Do not eat drink or smoke when using this
7 product.
RESPIRATORY PROTECTION: P260:Do not breathe dusoqume/ges/mist/vapours/spray.Use only outdoors or in a well-ventilated area.
[ Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purildng
] respirators with dust/mist/fume/spray filters are recommended if operations may produce dusts,mists or
' sprays from this product with concentrations at or above levels posted above.
i EYE PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.P280:Wear protective gloves/protective
clothing/eye protection/face protection.Wear chemical safety goggles or safety glasses with side shields.A(ace
shield may also be necessary for splash protection.
j SKIN PROTECTION: P264:Wash all exposed sumhair thoroughly after handling.P272:Contaminated work clothing should not be
allowed out of the workplace.P280:Wear protective gloves/protective clothing/eye protection/face
3 protection.Use chemically-resistant gloves and skin protection,when handling this product Use body
protection appropriate for task(e.g.,lab coat,overalls). '..
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j WATER TREATMENT EXPERTISE SINCE 1904 '..
FORMULA 314-T www.garrattcallahao.com Page 3 of 6 '..

SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: White tooR-white tablet VAPOR PRESSURE: 0.0038 Pa@"C
ODOR: Slight halogen VAPOR DENSITY(Air=1): Notapplicable
7 ODOR THRESHOLD: Not established RELATIVE DENSITY@20'C(water--I): Not applicable
PH: 3.5 @ 0.15%(diluted solution) SOLUBILITY IN WATER: 0.15 @"C slightly soluble
in water
MELTINGIFREEZING POINT: 145-I60°C PARTITION COEFFICIENT(n-octanollwater):log Pow:0.35
BOILING POINT: Not applicable AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Not established DECOMPOSITION TEMPERATURE: Notestablished
EVAPORATION RATE(n-BuAc=1): Not applicable VISCOSITY: Not applicable
' FLAMMABILITY(SOLID/GAS): Not established VOLATILE ORGANIC COMPOUNDS(%): None
FLAMMABLE LIMITS(In air by volume,%): Not established
SECTION I0-STARILITY AND REACTIVITY
REACTIVITY: Material has oxidizing properties.
STABILITY: Stableat normal ambient temperatures.Avoid the following conditions:Moisture.
t POSSIBILITY OF
HAZARDOUS REACTIONS: Will not polymerize.
CONDITIONS TO AVOID: Generates toxic gas in contact with acid.Avoid heat games and other sources of ignition.Avoid excessive
heat for prolonged periods of time.
's INCOMPATIBLE MATERIALS: Strong acids.Strong alkalis.Strong reducing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Toxic gases/vapors/fumes of..Hydrogen bromide(HBr).Bromine.Hyrdogen chloride(MCI).Chlorine.Oxides
j of the following substances:Carbon.Nitrogen.
i
SECTION 11 -TOXICOLOGICAL INFORMATION
1
I TOXICOLOGICAL EFFECTS: There is no evidence that the product can cause cancer.
LIKELY ROUTES OF EXPOSURE: Skin and/or eye contact Ingestion.inhalation.
RELATED SYMPTOMS: Skin and/or eye contact Ingestion.Inhalation,
DELAYED/IMMEDIATEICHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURES:
Inhalation:May cause respiratory system irritation.
Ingestion:Harmful if swallowed.
Skin concact Causes bums.May cause sensitisation by skin contact
Eye contact:Causes burns.
' Acute and chronic health hazards:This product is corrosive.
NUMERICAL MEASURES OF TOXICITY:
Oral:LDSO;rats.578 mgfkg
Dermal:LD50:rabbits,2000mg/kg
Ames test Negative
CARCINOGENICITY: None of the components of this product are listed by the NTR IARC,or regulated by OSHA as carcinogens.
3
SECTION 12-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
i ECOTOXICITY:
a Acute toxicity-fish:
LC%96 hours:0.87 mg/I,Onchorhynchus mykiss(Rainbow trout)
LC50,96 hours:0.87 mg/I,Fish
s Acute toxicity-aquatic.:
EC50,48 hours:0.46 mg/I,Daphnia magna
EC50,48 hours,0.46 mg/l,Daphnia magna
Acute toxicity:
LCS0,96 hours,640 American oyster mgfl
PERSISTENCE AND DEGRADABILITY:Halogens will dissociate in water leaving DMH,DMH is really biodegradable in a CO2 Evolution study
and passes the 10-day window criteria.DMH has also been shown to be apidky degraded in a water/sediment system.
BIOLOGICAL ACCUMULATION POTENTIAL Material is expected to present low bioaccumukation potential.
MOBILITY IN SOIL:No data available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):The product contains a substance which is very toxic to aquatic organisms.
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T www.garrotecallahancom Page 4 of 6

Environmental Hazards:
This pesticide is toxic to fish and aquatic organisms.Do not discharge effluent containing this product into lakes,streams,ponds,estuaries,oceans or
other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System(NPDES)permit and the permitting
( authority has been notified in writing prior to discharge.Do not discharge effluent containing this product into sewer systems without previously
nodfying dte local sewage treatment plant authority,For guidance,contact your State Water Board or Regional Office of the EPA.
I BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(8EIs)have not been determined for the components of this
product.
SECTION 13- DISPOSAL CONSIDERATIONS
1
DISPOSAL: Thoroughly dtaWemp[y containers and offer for reading.Refer to Section 8 for exposure controls-personal protection.P501:
j Dispose ofcontents/contamer in accordance with local/regionaUnationaUinternational regulations.
SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
j DOT: UN3085,OXIDIZING SOLID,CORROSIVE,N.O.S. ,".`
I (CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN), . s
5.1(8),PG III,MARINE POLLUTANT ,�y :s�
i �
Emergency Response Guidebook,Guide No.: 140 §,t
Passenger Aircraft Qtr..25 kg t
Cargo Aircraft Qty: 100 kg
IMDG/IMO: UN3085,OXIDIZING SOLID.CORROSIVE,N.O.S.
(CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN),
5.1(8),PG III,MARINE POLLUTANT
{ IATA/ICAO: UN3085,OXIDIZING SOLID,CORROSIVE,N.O.S.
(CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN),
- S.1(8),PG 111,MARINE POLLUTANT
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): Yes
TRANSPORT IN BULK(according to
annex II marpol 73178 and the IBC code): Not applicable
SPECIAL PRECAUTIONS FOR USER: None known
PRODUCT REQUIRES OXIDIZER,CORROSIVE AND MARINE POLLUTANT LABEL
1
_ SEG710N IS-REGULATORY INFORMATION
United States and International Regulations
i
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this produce are subject to the
treporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
i Reauthorization Act.
i CHEMICAL NAME
-BROMOA-CHLORO-5,5-DIMETHYL- SARA 302(40CFR 355,APPENDIX A)-NO
j HYDANTOIN SARA 304(40CFR TABLE 302.4)-NO
SARA 313 (40CFR 372.65)-NO
i
3 U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components ofthis product. The
] default Federal SDS submission and inventory requirement filing threshold of 10,000 Its(4,540 kg)therefore applies,per 40 CFR 370,20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):Not listed.
I U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA TITLE 311/312 HAZARD CATEGORY:ACUTE:YES CHRONIC: NO FIRE: YES REACTIVITY:YES PRESSURE:NO
1
California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): No component of this product Is on the Proposition 65
list
j
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T ww ,garrattcallahan.com Page 5 of 6
t

FIFRA Information:
j This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under
federal pesticide law.These requirements differ from the classification criteria and hazard information required for safety dam shams.and for
workplace labels of non-pesticide chemicals.Following is the hazard information as required on the pesticide label:
i
DANGER.CORROSIVE.Causes irreversible eye damage and skin bums.Harmful if swallowed.In imdng to nose and throat Do not get in eyes,on
skin,or on clothing.Wear protective eyewear(goggles,face shield,or safety glasses).Wear protective clothing and rubber gloves when handling
this product Avoid breathing dust and fumes.Wash thoroughly with soap and water after handling.Remove contaminated clothing and wash
clothing before reuse.
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
liming.
CANADIAN WHMIS CLASSIFICATION: Not listed.
SECTION Ib•OTHER INFORMATION
1 PREPARED BY: GARRATT CALLAHAN
S
1 DATE OF REVISION: 3C29/2016 Supercedes: 6/I I/2015
Formula 314-T is EPA-registered;with EPA Reg,No.83451-4-8540.Refer to the approved label for details.
Formula 314-T is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds
for category codes G5,G7;with NSF Reg.No. 113139.
1
Although reasonable care has been taken in the preparation of this document,we extend no warranties and make nw representations as to the accuracy or
1 completeness of the information conzined herein,and assume iw responsibility regarding the suitability of this information for the user's intended purpose or for the
ns,muces of ks me. Each individual should make a determin uon as to the suitabiiny of the information for their particular purpose.
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WATER TREATMENT EXPERTISE SINCE 1904
= FORMULA 314-T wvvw.garrattcallahan.com Page 6 of 6

i
jGarratt
G A L L A HA N SAFETY DATA SHEET
SECTION 1 - PRODUCT IDENTIFICATION
I
I. PRODUCT NAME: FORMULA 315
PRODUCT USE: BIOCIDE
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: 3265
PROPER SHIPPING NAME: CORROSIVE LIQUID,ACIDIC,ORGANIC, N.O.S.(5-CHLORO-2-
j METHYL-4-ISOTHIAZOLIN-3-ONE),8,PG II
MANUFACTURER'S NAME: Garratt-Callahan Company
`? ADDRESS: SO Ingold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
Outside North America:+1.703.427.3887
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SD3315
DATE OF REVISION: 2/11/2016
i SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
GHS HAZARD STATEMENT:
H302:Harmful if swallowed. 4
H3IS:Causes skin irritation. 2
3 1-1320:Causes eye irritation. 28
H335:May cause respiratory irritation, 3
i
GHS PREVENTATIVE STATEMENTS:
i P101:if medial advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P261:Avoid breathing dusdfumelgas/mist/vapours/spray.
P264:Wash all exposed skin/hair thoroughly after handling.
1 P270:Do not eat,drink or smoke when using this product
t
P271:Use Only outdoors or in a well-vendiaCed area.
P280:Wear protective gloves/protective clothingleye protettio lfzce protection.
1
i
[t
? NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
t
Hazard Sale
0-5 n,mal
ght
2-Modente HEALTH x" - INSTABILITY
3-Senous
r- t*+A9"i4Rra{YkCLifSY} 9.i 4-Severe
- r-chroak l e,ard
i
OTHER
3
7
{
- WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 315 vv wgarrattcallahan.com Pagel of
i

i
SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients CABS E_C# ICSC# WT
MAGNESIUM NITRATE 10377-60-3 233-826-7 1041 1-3
i
5-CHLORO-2-METHYLA-ISOTHIAZOLIN-3- 26172-55A 247-500-7 NA I-2
ONE
2-METHYLA-ISOTHIAZOLIN-3-ONE 2682-20-4 220-239-6 NA <I
MAGNESIUM CHLORIDE 778b30-3 232-094-6 0764 <I
SECTION 4-FIRST AID MEASURES
P312:Call a POISON CENTER or doctorlphysician if you feel unwell. Take copy of label and SOS to health professional with contaminated individual.
WARNING:This product is a non-flammable,clear yellow green liquid with a pungent odor.Harmful if swallowed,causes skin and eye irritation,
maay muse respiratory irritation.Also refer to Section I I for symptoms,effects,and likely routes of exposure for this product
i
I TARGET ORGANS:
ACUTE irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P302+P352:IF ON SKIN:Wash with soap and water.Minimum flushing is for 15 minutes. P362:Take off contaminated
clothing and wash before reuse,P312:Call a POISON CENTER or doctor/physician if you feel unwell.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse cautiously with water for seven]minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open eyelids. Have contaminated Individual"roll"eyes, Minimum flushing is for 15 minutes.P337+P313:
If eye irritation persists get medical advicelattention.
INHALATION: If vapors,mists,or sprays generated by this product are inhaled,remove contaminated individual to fresh air. Remove or cover
gross contamination to avoid exposure to rescuers.P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable
for breathing.
'- INGESTION: P301+P312.IF SWALLOWED:Call a POISON CENTER or doctodphysiclan if you feel unwell.Do NOT induce vomiting.P330:
Rinse mouth.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions.or unable to
swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"(see Section 3,Hazard Identification)may be aggravated by prolonged overexposures to this producL
'i
NOTES TO PHYSICIAN: Treat symptoms es demonstrated by signs and distress in the patient.
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use media appropriate for the surrounding fire.
EXTINGUISHING MATERIALS:
y SPECIFIC HAZARDS ARISING FROM THE Non-Flammable Liquid.
CHEMICAL Explosion hazards in Presence of Various Substances: Non-Explosive in presence of open flames
j and sparks,or shocks.
Special Remarks on Explosion Hazards: None known
i
} SPECIAL PROTECTIVE EQUIPMENT AND Incipient fire responders should wear eye protection. Structural frefighten muse wear Self-
PRECAUTIONS FOR FIREFIGHTERS: Contained Breathing Apparatus and full protective equipment Isolate materials not yet involved in
5 the fire and protect personnel.Move containers from fire area if this can be done without risk;
j otherwise,cool with carefully applied waxer spray.If possible,prevent runoff water from entering
storm drains,bodies of water,or other environmentally sensitive areas.
1
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 315 wvrw.garrattcallahan.com Page 2 of 6

SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure buildup. Use extreme caution.When opening,release pressure slowly
through opening
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used, refer to Section 8-exposure controls.
I
Small Spill: Mop up.or absorb with an inett dry material and place in an appropriate waste disposal container. P391:Collett spillage.
Large Spill: Restrict access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk. Remove chemicals
which can react with the spilled material. Add dry Inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
container and seal. P391:Collect spillage.
SECTION T-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat.drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product Use in a welf,milated location. Remove
contaminated clothing immediately. Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
_ identified,well-illuminated.clear of obstruction and accessible only to trained and authorized personnel. Store containers in a clean,cool,well
_ ventilated, dry location,away from direct sunlight away from incompatible materials at temperatures between STE(10°C)- 1 W°F(370C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities,P403+P233:Store in a well ventilated place.Keep container tightly closed.
1
3 SECTIONS•EXPOSURE CONTROLS•PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is ustuthoored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS INAIR
............................................................
g CHEMICAL NAME CA SiF ACGIH TLV OSHA PE L OTHER
TWA STEL TWA
MAGNESIUM NITRATE 10377-60-3 NE NE NE NE
S-CHLORO-2-METHYL-4- 26172-55-4 NE NE NE NE
ISOTHIAZOUN-3-ONE
2-11ETHYL-4-ISOTHIAZOUN-3- 2682-20-4 NE NE NE NE
t ONE
MAGNESIUM CHLORIDE 7786-30-3 NE NE NE NE
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NE=Not Established
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INGESTION: P270:Do not eat,drink or smoke when using this product.
RESPIRATORY PROTECTION: P261:Avoid breathing dusdPome/gas/mist/vapours/spray.P27k Use only outdoors or in awe11-ventilated area.
! Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
j respirators with duso'mist/fume filters are recommended if operations may produce mists or sprays from this
product.
s EYE PROTECTION: Safety glasses or safety goggles.If splashing is anticipated,a face shield is recommended. P280:Wear
i protective gloves/protective clothinp/eye protection/face protection.
SKIN PROTECTION: HAND PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective
gloves/protective clothug/aye protectiondface protection.Use chemically-resistant gloves when handling this
' product
i BODY PROTECTION: Use body protection appropriate for task leg.,lab coat overalls,gloves). '..
s
WATER TREATMENT EXPERTISE SINCE 1904 a
FORMULA 315 www.garrattcallahan.com Page 3 of 6
7

SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear yellow/green liquid VAPOR PRESSURE,mm Hg @ 20°C: Not esmblished
ODOR: Pungent VAPOR DENSITY(Air—]): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water=l): 0,95- 1.10
pH: 3.0-6.5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: NA PARTITION COEFFICIENT(a-ocanol/water)Not established
BOILING POINT: 100°C(21ri,) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): < 1 VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%): None
FLAMMABLE LIMITS(in air by volume.%): Not applicable
SECT19N ABILITY AND AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Sable under normal condition of use and storage.
l POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: See incompatible materials.
INCOMPATIBLE MATERIALS: Oxidizing agents,reducing agents,amines,merapmns.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition may yield the following:Hydrogen chloride,oxides of sulfur and nitrogen.
SECTION I i -TOXICOLOGICAL INFORMATION
I TOXICOLOGICAL EFFECTS:No data available for this product.
LIKELY ROUTES OF EXPOSURE:Skin/eye contact and Inhalation.The most significant routes of overexposure for this product are by
inhalation of mists or contact with skin or eyes.
RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT
4 AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will cause burning and irritation.Do not wear contact lenses when using this product.Ingestion will cause
gastric distress and possible depression of the centml nervous system.
CHRONIC:Repeated or prolonged exposure to this product can produce target organ damage.Repeated exposure of the eyes an produce eye
Irritation.Repeated skin exposure can produce local skin destruction,or dermatitis.Repeated inhalation can produce varying degrees of respiratory
irritation or lung damage.
NUMERICAL MEASURES OF TOXICITY:
t Ceriodaphnia dubia(waterflea):48hq LCSOs:8.77 ppm
Ceriodaphnia dui(wateAea):96hr,LC50s:7.88 ppm
Pimephales promelas(fathead minnow):48hr,LC50s:9.84 ppm
Pimephales promelas(fathead minnow):96hr,LCSOs:9,56 ppm
IRRITANCY OF PRODUCT: This product is very irritating to skin,eyes and respiratory system.
j SENSITIZATION TO THE PRODUCT:This product may cause allergic skin reacdons(e.g.,ashes,welts)in sensitive individuals.
CARCINOGENICITY: None of the components of this produttare listed by the NTP,IARC,or regulated by OSHA as carcinogens.
SECTION I2-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:Release of this product to the environment is expected to cause harm to plants and animals. If accidentally released,pretenders
FEmust be taken to protect the environment.
RSIST•NICE AND DEGRADABILITY:Material is considered Mo legradeable.
BIOLOGICAL ACCUMULATION POTENTIAL:No dam available for this product
MOBILITY IN SOIL:No data available for this product.
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product
Environmental Hazards:
3 This pesticide Is toxic to aquatic plants,fish and aquatic invertebrates.Do not discharge effluent containing this product into lakes,streams,ponds.
E estuaries,oceans,or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System(NPDES)permit
and the perm aing authority has been notified In writing prior to discharge.Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority.For guidance contact your State Water Board or Regional Office of the EPA.
Do not contaminate water by cleaning of equipment or disposal of waste.Apply this pesticide only as specified on the label,
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 31S www.garrattcallahan.com Page 4 of 6
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BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEIs)have not been determined for the components of this
product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly drain/empty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.P501:Dispose
of contents/container in accordance with local/regionallnadonallinternational regulations.
SECTION 14-TRANSPORTATION INFORMATION
3
S PROPER SHIPPING NAME
DOT: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC,N.O.S.
{ (5-CHLORO-2-METHYL-41SOTHIAZOLIN-3-ONE),8,PG 11
Emergency Response Guidebook,Guide No.: 153
Passenger Aircraft Qty: I L
Cargo Aircraft Qty.30L
IMDG/IMO: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC,N.O.S.
(5-CHLORO-2-METHYL-4-ISOTHIAZOLIN3-ONE),8,PG II
j IATA/ICAO: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC.N.O.S.
(5-CHLORO-2-METHYL44SOTHIAZOLIN-3-ONE),8,PG II
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex II marpol 73/78 and the IOC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known,
PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
[ United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components ofthis product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
5_
CHEMICAL NAME
MAGNESIUM NITRATE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302A)-NO
SARA 313(40 CFR 372.65)-YES
5-CHLORO-2-METHYL-4- SARA 302(40 CFR 355,Appendix A)-NO
i ISOTHIAZOUN-3-ONE SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
2-METHYL-4-ISOTHIAZOLIN-3-ONE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
MAGNESIUM CHLORIDE SARA 302(40 CFR 355,Appendix A)-NO
z SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372,65)-NO
3
U.S.Regulations
I U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components ofthis product
The default Federal SDS submission and Inventory requirement filing threshold of 10,000 Ins(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCIA REPORTABLE QUANTITY(RQ): Not listed.
TSCA INVENTORY STATUS: The components ofthis product are listed on the TSCA Inventory.
SARA TITLE III Section 3111312 Hazard Category:Acute: YES; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
HFRA Information
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under '..
federal pesticide law.These requirements differ from the classification criteria and pound information required for safety data sheen,and for '..
workplace labels of non-pesticide chemicals.Following is the hazard Information as required on the pesticide label:
WATER TREATMENT EXPERTISE SINCE 1904 '..
FORMULA 315 www.garrattwllahan.com Page 5 of
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3 DANGER.CORROSIVE.Causes irreversible eye damage and skin bums.May cause allergic skin reaction.Harmful if swallowed or absorbed through
the skin.Harmful it inhaled.
i
Do not get in eyes,on skin,or on clothing.Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals.Remove
contaminated clothing and wash clothing before reuse.Mixers,loaders and others exposed to this product must wear:long-sleeved shirt and long
p pants;chemical resistant gloves such as nitrile or butyl rubber;shoes plus socks;gogglrs and face shield;and chemical resistant apron.Discard
I
i clothing or other absorbent materials that have been drenched or heavily contaminated with this product's concentrate.Do not reuse them.
Follow manufacturer's instructions for cleanitg/mainteining PPE.If no such Instructions for washables exists,use detergent and hot water.Keep and
wash PPE separately from other laundry.Users should wash hands before eating,drinking,chewing gum,using tobacco or using the toilet Users
should remove clothing immediately if pesticide gets inside.Then wash thoroughly and put on clean clothing.Users should remove PPE immediately
after handling this product Wash the outside of gloves before removing.As soon as possible,wash thoroughly.
{ California Safe Drinking Water and Toxic Enforcement Act(•roposition 6S): No component of this product is on the Proposition 6S
list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL Inventories or are exempt from listing.
CANADIAN WHMIS CLASSIFICATION:Not classified.
f SECTION Ib HER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 2/11/2016 Supercedes: 6/1 6120 1 5
Formula 315 is EPA-registered:with EPA Reg.No.8540-23.Refer to the approved label for repis.
Almoogh reasonable are has been taken in the preparation of this document we extend no warranties and make ao representations as to me accuracy or
completeness of the information contained herein,and assume no responsibifty regarding the snicabilk,of this mfo rradou for the user's intended purpose or for the
# comequsnces of its use. Each Wividual should make a determination as to the mitability of the information for their partial.,purpose.
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 31 S wwvv garrattcallaha.com Page 6 of 6
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Garratt
C A L L A H A N SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
i PRODUCT NAME: FORMULA 2002
PRODUCT USE: COOLING WATER TREATMENT
1 RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UNI824
PROPER SHIPPING NAME: UNI824,SODIUM HYDROXIDE SOLUTION,S. PGII
7 MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
s EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
1
i Outside North America:+1-703-527.3887
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SD2002
DATE OF REVISION: 10/14/2015
1
SECTION 2•HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER �y
HAZARD STATEMENT: giy
H302:Harmful if swallowed.
H314:Causes severe skin burns and eye damage IA
H335:May cause respiratory irritation. 3
i
PRECAUTIONARY STATEMENTS:(PREVENTION)
P10 h If medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
PI03:Read label before use.
q P260:Do not breathe dust/fume/gea/mist/vapours/spray.
P264:Wash all exposed skinihair thoroughly after handling.
P270:Oo not eat,drink or smoke when using this product
P280:Wear protective gloves/protective clothing/eye protection/face protection.
1
NFPARATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Hazard Scale
° 0=Minimal
1 1=Sl1ght
2=Moseate HEALTH INSTABILITY
3=Serious
i r A TIY4TYpA'ARD(Yk .tfal4) 0'� 4=Severe
-=Chroax haters
OTHER
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 2002 www.garattcallahan.com Page I of 6

SECTION 3 - CO MPOSITIONUINFORMATION ON INGREDIENTS
Hazardous InRredlents C_AS# EC# 10 Wr
SODIUM HYDROXIDE 1310-73-2 215-185-5 0360 8
ACRYLIC COPOLYMER PROPRIETARY NE NE 4
( SODIUM TOLYLTRIAZOLE 64665-574 265-004-9 1091 3
[ PHOSPHONIC ACID DERIVATIVE PROPRIETARY NE NE 3
i
HEOP 2809-21-4 220-552A NE 2
SODIUM MOLYBDATE 7631-95.0 231-5514 1010 1
SECTION 4•FIRST AID MEASURES
i
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this 5D5 to the health professional with the
i individual.P310:Immediately all a POISON CENTER or doctor/physician.
jDANGER:Harmful if swallowed.Causes severe skin burns and eye damage.May cause respiratory Irritation.Also refer to Section I I for symptoms,
effects,and likely routes of exposure for this product.
(' TARGET ORGANS:
€ ACUTE irritation of skin,eyes,respiratory and gastrointestinal systems.
7 CHRONIC irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.Rinse skin with
water/shower.Minimum flushing time is for 15 minutes. Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:
i
Wash contaminated clothing before reuse.P310:Immediately call a POISON CENTER or doctor/physician.
EYE EXPOSURE: P305+P35 I+P338:IF IN EYES:Rinse continuously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes. P310:Immediately all a POISON CENTER or dotter/physician.
INHALATION: P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:Immediately
f all a POISON CENTER or doctor/physician.
INGESTION: P301+P330+P331: IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give diluents(milk or
water)by mouth to someone who is unconscious,haying convulsions,or unable to swallow.P310.Immediately all a POISON CENTER or
doctor/physician.
} MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product.Exposed individual must seek immediate medical attention if any adverse effect
occurs.
i
NOTES TO PHYSICIAN: Treat symptoms as;demonstrated by signs and distress in the padenc
f
7 SECTION 5•FIRE FIGHTING MEASURES
S
tSUITABLE(AND UNSUITABLE) Product is non-flammable.Use media appropriate for the surrounding fire.
EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL:
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.
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i WATER TREATMENT EXPERTISE SINCE 1904 '..
FORMULA 2002 www.garrattcallahan.com Page 2 of 6

SECTION b-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure buildup. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE; Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.
I
j Small Spilt: Mop up,or absorb with an Inert dry material and place in an appropriate waste disposal container. P391:Collect spillage.
Large Spill: Restrict access to the area.Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers.
basements or confined areas,dike if needed. Ensure that exposure to product is not at concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
jcontamerandseal. P391:Collect spillage.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this produce Do not";drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mires generated by this product. Use in a weil-vendlated location. Remove
contaminated clothing Immediately. Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,well-illuminated,clear of obstruction and accessible only to mined and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight away from incompatible materials at temperatures between WE(1(Y°C)-100-F(37°C).Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
3 Section 10(or incompatibilities.
t
SECTIONS-EXPOSURE CONTROLS- PERSONAL PROTECTION
t VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety,shower station is recommended to be
i available near where this product is used/stored.
EXPOSURE LIMITSIGUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PEL OTHER
TWA STEL TWA
SODIUM HYDROXIDE 1310-73-2 NE 2 mg/m' 2 mg/W NIOSH REL
ceiling C-2 mg/m'
ACRYLIC COPOLYMER PROPRIETARY NE NE NE N/A
i
SODIUM TOLYLTRIAZOLE 64665-57-2 NE NE NE N/A
PHOSPHONIC ACID PROPRIETARY NE NE NE N/A
DERIVATIVE
HEDP 2809-214 NE NE NE NIA
SODIUM MOLYeDATE 7631-95-0 5 mgim, NE 5 mg/W N/A
as soluble as soluble NO
s NE Not Established
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 2002 www,garmttcallahan.com Page 3 of 6

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INGESTION: P264:Wash all exposed skin/hair thoroughly after handling.P270:Do not eat,drink or smoke when using this
product.
RESPIRATORY PROTECTION: P260:Do not breathe dust/fume/gas/mistIvapours/spray.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,ifapplimble. Air-purifying
respirators with duatfa isdfume/spray filters are recommended if operations may produce dusts,musts or
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.P280:Wear protective gloves/protective
clothing/eye protection/face protection.Wear chemical safety goggles or safety glasses with side shields. A
face shield may also be necessary for splash protection.
SKIN PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloveelprotective
clothingfeye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(eg.,lab coat,overalls).
SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
S
APPEARANCE and COLOR: Clear dark amber liquid VAPOR PRESSURE,mm Hill @ 20°C: Not established
j ODOR: Sweet organic VAPOR DENSITY(Air=1} Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20-C(watm=1): 1,I2- 1.13
PH: 13.0. 14.0 SOLUBILITY IN WATER: Complete
MELTINGIFREEZING POINT: Not established PARTITION COEFFICIENT(n-octsnol/water)Not established
BOILING POINT: >212°F(100°C) AUTOIGNITION TEMPERATURE: Not established
FIASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Notestabeshed
EVAPORATION RATE(n-BoAc=1): < I VISCO51TY: Not established
FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%): Not established
FLAMMABLE LIMITS(in air by volume,%): Not established
i SECTION I0-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
i
CONDITIONS TO AVOID: Freezing temperatures and incompatible materials.
INCOMPATIBLE MATERIALS: Strong acids,reactive metals,and strong oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: When heated to decomposition product may emittoxicfumes ofoxides ofcarbon,nitrogen and
Phosphorous.
SECTION 11 -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS:No data available for this product.
LIKELY ROUTES OF EXPOSURE:Skin/eye contact and inhalation.
3 RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
3 DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT
? AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will cause burning and irritation.Do not wear contact lenses when using this product.Ingestion will cause
gastric distress.Inhalation of vapor,mist or dust may cause respiratory tact irritation,
CHRONIC:Repeated or prolonged exposure to this product can produce target organ damage.Repeated exposure of the eyes can produce eye
3 Irritation.Repeated skin exposure can produce local skin destruction,or dermatitis.Repeated inhalation can produce varying degrees of respiratory
irritation or lung damage.
NUMERICAL MEASURES OF TOXICITY:Not established for this product
CARCINOGENICITY: None of the components of this product are listed by the NTP,[ARC,or regulated by OSHA as carcinogens.
SECTION I2-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
j Ceriodaphniadubia(Waterflea)96-hr LCSO:22.2 ppm
Ceriodaphniadubia(Waterilea)48-hr LC50:25.5 ppm
Pimephales promelas(Fathead minnow)96-hr LC50:803.7 ppm
Pimephales promelas(Fathead minnow)48-fir LCSO:851.4 ppm
PERSISTENCE AND DEGRADABILITY:No data available for this product
BIOLOGICAL ACCUMULATION POTENTIAL:No data available for this product
1
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 2002 www.garrattcallahan.com Page 4 of
7

MOBILITY IN SOIL:No data available for this product.
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam avallable for this product.
k
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEIs)have not been determined for the components of this
product.
SECTION 13-DISPOSAL CONSIDERATIONS
jDISPOSAL: P501:Dispose of contents/conminer in accordance with local/regional/nationallintermtlonal regulations.Rinse empty conminem with
water and use the rinse water to prepare the working solution. Refer to section 8 for exposure controls-personal protection.
SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
3
DOT: UNI824,SODIUM HYDROXIDE SOLUTION,8,PGII
Emergency Response Guidebook Guide No.: 154
Passenger Aircraft Orr. IL it 3'L
Cargo Aircraft Qty:30L <
3 IMDG/IMO: UNI824,SODIUM HYDROXIDE SOLUTION,8,PGII
IATAIICAO: UNI824.SODIUM HYDROXIDE SOLUTION,8,PGII
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
7 TRANSPORT IN BULK(according to
1111 annex R marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
i PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
1 United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components ofthis product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
CHEMICAL NAME
SODIUM HYDROXIDE SARA 302(40 CPR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
SARA 313(40 CFR 372,65)-NO
1
ACRYLIC COPOLYMER SARA 302(40 CFR 355,Appendix A)-NO
s SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
SODIUM TOLYLTRIAZOLE SARA 302(40 CFft 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
j SARA 313(40 CFR 372,65)-NO
1 PHOSPHONIC ACID DERIVATIVE SARA 302(40 CFR 355,Appendix A)-NO
3 SARA 304(40 CFR Table 302.4)-NO
j SARA 313(40 CFR 372.65)-NO
I HEDP SARA 302(40 CFR 355,Appendix A)-NO
t SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
SODIUM MOLYBDATE SARA 302(40 CFR 355,Appendix A)-NO
S SARA 304(40 CFR Table 302.4)-NO
i SARA 313(40 CFR 372.65)-NO
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`= U.S,Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
( The default Federal SDS submission and inventory requirement filing threshold of 10,000 Ibs(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):None.
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
s SARA Tide 311/312,Hazard Category: Acute Health: YES; Chronic:YES; Fire:NO; Reaaive:NO; Sudden Release of Pressure:NO
California Safe Drinking Water and Toxic Enforcement Act(proposition 6S): No component ofthis product is on the Proposition 65
list
International Regulations
I CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components ofthis product are on the DSL or NDSL Inventories or are exempt from listing.
CANADIAN WHMIS CLASSIFICATION:A component of this product(Sodium Hydroxide,CAS#1310-73-2)has the following W HMIS
I classification of CLASS E(corrosive).
SECTION I6-OTHER INFORMATION
PREPARED RY: GARRATT CALLAHAN
DATE OF REVISION: 1011412015 Supercedes: 10/14/2013
FORMULA 2002 has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OU 13-7ESASA when prepared in
either the Addison,Illinois or Burlingame,California facilides.
i
( Altlsough.,enable one has been taken in the preparation ofthis document we extend no wa.utss and make oo representations as to the acamry or
complepneas of the information conralmd herein,and assume re responsibility regardiq the suitability of this Information for the user's intended purpose or for the
consequences of its use. Each individual should make a derermination as to the subabilb,of the information for their particular purpose.
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GA L L A H A N SAFETY DATA SHEET
SECTION 1 -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 2002-LT
PRODUCT USE: COOLING WATER TREATMENT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UN 1824
PROPER SHIPPING NAME: UN 1824,SODIUM HYDROXIDE SOLUTION,8, PGII
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road, Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: I-800.424.9300
Outside North America:+1-703.527.3887
BUSINESS PHONE: Product Information:65 0-6975 8 1 1
j SOS NUMBER: SD2002LT
DATE OF REVISION: 9/29/2015
SECTION 2•HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
HAZARD STATEMENT:
H302:Harmful if swallowed. 4
H315:Causes skin Irritation. 2 <i>
H320:Causes eye irritation. 2B
H335:May cause respiratory irritation. 3
_ PRECAUTIONARY STATEMENTS:(PREVENTION)
P10I:If medical advice is needed,have product container or label at hand.
j P102:Keep out of reach of children.
PI03:Read label before use.
g P261:Avoid breathing dust/fume/gas/mistNapours/spray.
( P264:Wash all exposed skin/hair thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
P271:Use only outdoors or in a well-
ventilated area.
P280:Wear protective gloves/protective clothing/eye protectlonfface protettion.
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
_ Havard Sale
i O=Minimal
( b 1 Sight
]`Moderate HEALTH / j INSTABILITY
I 3-5enous
i R III 'd d 4-se,ea
41!
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j SECTION B• COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients CA EC# ICSCtt Nm
SODIUM HYDROXIDE 1310-73-2 215-185-5 0360 7-10
PHOSPHONIC ACID DERIVATIVE PROPRIETARY NE NE 4-6
ACRYLIC COPOLYMER PROPRIETARY NE NE 3-6
SODIUM TOLYLTRIAZOLE 6466557-2 265-004-9 1091 2-6
HEDP 2809-21A 220-SS2-8 NE 1-4
t
SECTION 4-FIRSTAIDMEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs. Take a copy of this SIDS to the health professional with the
individual.P312:Call a POISON CENTER or donor/physician if you feel unwell.
WARNING:May be harmful if swallowed.Causes skin and eye irritation.May cause respiratory irritation.Also refer to Section I i for symptoms,
effects,and likely routes of exposure for this product.
I TARGET ORGANS:
} ACUTE Irritation of skin,eyes,respiratory and gastrointestinal systems.
t CHRONIC Irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P302+P352:IF ON SKIN:Wash with soap and water.Minimum flushing time is for 15 minutes.P362+P364:Take off
contaminated clothing and wash before reuse.P332+P313:If skin irritation occurs:Get medical advice/attention.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse continuously with water for several minutes.Remove contact lenses if present and easy to
3 do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed Individual"roll"their eyes. Minimum flushing time is for 15
minutes. P337+P313:If eye irritation persists get medical advice/attention.
INHALATION: P304+P340:IF INHALED:Remove victim to fresh owned keep at rest in a position comfortable for breathing.P312:Calla
POISON CENTER or doctor/physician if you feel unwell.
INGESTION: P301+P312:IF SWALLOWED:Call a POISON CENTER or doctor/physician if you feel unwell..P330:Rinse mouth.Never induce
vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable to swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
j occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient.
7
SECTION 5-FIRE FIGHTING MEASURES
7 SUITABLE(AND UNSUITABLE) Product is nonflammable.Use media appropriate for the surrounding fire.
EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL
I SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear hilly protective clothing(chemical impermeable,fully encapsulated suit)
j PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
3 methods to sewer or waterways.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used, refer to Section 8-exposure controls,
i
j Small Spill: Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container. P391:Collett spillage.
i
f Large Spill: Restrict access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
( container and seal. P391:Collett spillage.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
? it safely.Open containers slowly on a stable surface. As with all chemicals.avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do mat ingest Wash thoroughly after handling this product. Do not eat.drink,smoke,or apply cosmetics
{ while handling this product Avoid breathing vapors,dusts or mists generated by this product Use in a well-ventilated location. Remove
contaminated clothing immediately. Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
# iderefed,well-Illuminated,clear of obstruction and accessible only to trained and authorized personnel. Store containers In a clean,cool,well
7 ventilated, dry location,away from direct sunlight.away from incompatible materials at temperatures between 50°F(10'C)- I OTF(37°C). Keep
container tightly closed when not in use.P405:Store locked up.P403+P233:Store in a well ventilated place.Keep container tightly closed.Do not
ingest Do not breathe vapor mist.Wash hands after handling.Refer to Section 10 for incompatibilities.
SECTION B-EXPOSURE CONTROLS- PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
i ............................................................
3 CHEMICAL NAME 9" ACGIH TLV OSHA PE L OTHER
TWA STEL TWA
SODIUM HYDROXIDE 1310-73-2 NE 2 mg/m' 2 mg/ms NIOSH REL
3 ceiling C-2mg/m'
1
PHOSPHONIC ACID PROPRIETARY NE NE NE N/A
i
DERIVATIVE
] ACRYLIC COPOLYMER PROPRIETARY NE NE HE N/A
SODIUM TOLYLTRIAZOLE 64665-57-2 HE NE NE N/A
HEDP 2809-21A NE HE NE N/A
S
! NE=Net Established
INGESTION: P264:Wash all exposed skini:air thoroughly after handling.P270:Do not eat,drink or smoke when using this
product
RESPIRATORY PROTECTION: P261:Avoid breathing dusdfume/gas/misdvapours/spray.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respirators with dust/mist/fame/spray Raters are recommended if operations may produce dusts,mists or
sprays from this product with concentrations at or above levels posted above,
j EYE PROTECTION: P264:Wash all exposed stunner thoroughly after handling.Wear chemical safety goggles or safety glasses with
I side shields. A face shield may also be necessary for splash protection.
{ SKIN PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.P280:Wear protective gloves/protective
' dothing/eye protectioNface protection.Use chemically-reslstant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat overalls).
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I SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear dark amber liquid VAPOR PRESSURE.num Hg @ 20°C: Not established
ODOR: Sweet organic VAPOR DENSITY(Air=1): Not established
ODOR THRESHOLD: Notestablished RELATIVE DENSITY@20°C(woml---I): 1,12- 1.14
pH: -12.5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not established PARTITION COEFFICIENT(o-ocanol/water)Not established
a BOILING POINT: >212°F(100°C) AUTOIGNITION TEMPERATURE: Not established
( FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): Not established VISCOSITY: Not established
FLAMMABILITY(SOUD/GAS): Not established VOLATILE ORGANIC COMPOUNDS(%): Not established
FLAMMABLE LIMITS(in air by volume.%): Not established
SECTION I0-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
£ HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: Freezing temperatures and incompatible materials.
INCOMPATIBLE MATERIALS: Strong acids,reactive metals,and strong oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition product may yield oxides of carbon,nitrogen and phosphorous.
SECTION I I -TOXICOLOGICAL INFORMATION
j TOXICOLOGICAL EFFECTS:No dam available for this product
7 LIKELY ROUTES OF EXPOSURE:Skin/eye contact and inhalation.
7 RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYEDIIMMEDLATF/CHRONIC EFFECTS FROM SHORT
AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will cause burning and irritation.Do not wear contact lenses when using this product.Ingestion will cause
gastric distress.Inhalation of vapor,mist or dust may cause respiratory tm"irritation.
CHRONIC:Repeated or prolonged exposure to this product can produce target organ damage.Repeated exposure of the eyes can produce eye
Irritation.Repeated skin exposure can produce local skin destruction,or dermatitis.Repeated inhalation can produce varying degrees of respiratory
Irritation or lung damage.
j NUMERICAL MEASURES OF TOXICITY:
LCSO,water8ea(cedodaphnia magna),48 hr..3299.8 mail.
LC50,water8ea(ceriodaphnia magna),96 he 1894.6 mgn.
LC50,fathead minnow(pimephalee promales),48 he 1621.0 mg/L
LCSO,fathead minnow(pimephales promales),96 he 1593.2 mg/I.
Carcinogenicity:None of the components of the product are listed by the NTP.IARC,or regulated by OSHA as carcinogens.
j SECTION 12-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:Dam not available for this product.
PERSISTENCE AND DEGRADABILITY:No dam available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No data available for this product
MOBILITY IN SOIL:No dam available for this product.
1 OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for the components of this
product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: PSO I:Dispose of conrentelcontainer in accordance with local/regionaVnational/international regulations.Rinse empty containers with
water and use the rinse water to prepare the working solution. Refer to section 8 for exposure controls-personal protection.
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SECTION I4-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
Emergency Response Guidebook Guide No.: 154
( Passenger Aircraft Cry: I L
Cargo Aircraft Qry:30L <
IMDG/IMO: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
IATA/ICAO: UN 1824.SODIUM HYDROXIDE SOLUTION,8,PGII +
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex II maipol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
7 PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS- REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorlsatlon Act
i GNEMICAL NAME
SODIUM HYDROXIDE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 3014)-YES
SARA 313(40 CFR 372.65)-NO
PHOSPHONIC ACID DERIVATIVE SARA 302(40 CFR 355,Appendix A)-NO
' SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372,65)-NO
ACRYLIC COPOLYMER SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
SODIUM TOLYLTRIAZOLE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
i SARA 313(40 CFR 37265)-NO
HEDP SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
i SARA 313(40 CFR 372,65)-NO
)_ U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product The
i default Federal SDS submission and inventory requirement filing threshold of 10.000 Its(4,540 kg)therefore applies,per 40 CFR 370.20,
SARA 311/312:Acute:Yes Chronic:No Fire:No Pressure:No Reacdvity:NO
U.S.CERCLA REPORTABLE QUANTITY(RQ):Sodium Hydroxide(CAS# 1310-73-2): 1000 lbs(454 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
j Califomla Safe Drinking Water and Toxic Enforcement Act(proposition 65): No component of this product is on the Proposition 65
list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing
' CANADIAN WHMIS CLASSIFICATION:A component of this product(Sodium Hydroxide,CAS# 131043-2)has a WHMIS classification of E
(corrosive).
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SECTION 16•OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 9/29/2015 Supercedes: 10/9/2013
A ffimgh rmso life are haz been mken in die prepamdon of this documeno we e..M€ro warranties aM make rw represenmtions as m the accunq or
completeness of the informndoo contained herein,and assume no r.s,nni iblliry regarding the suimblliry of this information for the users intended purpose or for the
consequences of its use. Each imiihdual should makes decerminadon az to the suimblliry of the information for Neir partl<ular purpose.
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I
CA L LA H A N SAFETY DATA SHEET
I
SECTION i -PRODUCT IDENTIFICATION
i
PRODUCT NAME: FORMULA 3091
PRODUCT USE: BIOCIDE
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: 1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION,8,PG III
MANUFACTURER'S NAME: Garrim-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010.2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
Outside North America:+1.703.527-3887
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SD3091
DATE OF REVISION: 2/16/2016
SECTION 2.HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER
HAZARD STATEMENT:
3 H290:May be corrosive to metals. I /
H314:Causes severe skin bums and eye damage. IA
z 11318:Causes serious eye damage. I
H335:May cause respiratory Irritation. 3
PRECAUTIONARY STATEMENTS:(PREVENTION)
P101 c if medical advice is needed,have product container or label at hand.
PI02:Keep out of reach of children.
PI03:Read label before use.
I P234:Keep only in original container.
i
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P264:Wash all exposed skinthair thoroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
j P280:Wear protective gloves/protective clothing/eye protection/face protection.
Do not eat,drink or smoke when using this product.
S
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NFPA RATING
j HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
I e sm,ird Scale
0-Minimal
i 1-Light
zMINIM= In 2-Moderate "'
I S rous
HEALTH INSTABILITY
p?iYBI ALtIA7JE {xr<Lti'#Y+t} 41
'=Chronchmrd
OTHER
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7 SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
I Hozardous Ingredients Cam/ 5 EC# ICSC Ma
SODIUM HYPOCHLORITE 7681-52-9 231-668-3 1119 10- 15.5
SODIUM HYDROXIDE 131043-2 215-185-8 0360 1 -5
SECTION 4•FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SOS to the health professional with the
Individual.P310.Immediately calla POISON CENTER or doctor/physician.
DANGER: May be corrosive to metals.Causes severe skin bums and eye damage.Causes serious eye damage.May cause respiratory irritation.Also
qj refer to Section I i for symptoms,effects,and likely routes of exposure for this product
TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.Rinse skin with
I water/shower.Minimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:
Wash contaminated clothing before reuse.P310.Immediately call a POISON CENTER or dottor/physician.
EYE EXPOSURE: P305+P35I-P338:IF IN EYES:Rinse ominously with water for several minutes.Remove contact lenses if present and easy to
1 do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roil"their eyes. Minimum flushing time is for 15
minutes. P310:Immediately call a POISON CENTER or doctor/physician.
INHALATION: P304+P340:IF INHALED:Remove victim to fresh air and keep at rest Ina position comfortable for breathing.P310:Immediately
call a POISON CENTER or doctor/physician.
INGESTION: P301+P330+P33 1:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give diluents(milk or water)
by mouth to someone who is unconscious,having convulsions,or unable to swallow.P310.Immediately call a POISON CENTER or dottor/physician.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed Individual must seek immediate medical attention B any adverse effect
occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Water fog,foam,dry chemical powder and carbon dioxide(002).Use media appropriate to the
EXTINGUISHING MATERIALS: surrounding flre such as water fog or fine spray,alcohol foams,carbon dioxide.Use water with
caution.Contact with water will generate considerable heat Do not use water jet as an
ex inguinher.as this will spread the fire.Do not use dry chemical extinguishing agents.Maleic
j anhydride may react with the basic sodium compounds.Use chemical extinguishing agents with
caution.Some chemical extinguishing agents may react with this material.
E SPECIFIC HAZARDS ARISING FROM THE Not considered flammable.Vapors are heavier than air and may spread along floors.Contact with
jCHEMICAL most metals will generate flammable hydrogen gas.Contact with water will generate considerable
heat Reacts violentdy with a wide variety of organic and inorganic chemicals including alcohol,
carbides,chloretes,filtrates,nitrates and metals.Harmful fumes.gases or vapors may evolve on
burning.Use standard firefighting procedures and consider the harards of other involved materials,
Vapors are heavier than air and may spread along floors.Hatardous combustion products includes
hydrogen gas,hydrogen chloride,chlorine,oxygen and sodium oxides.
t
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable.fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
i methods to sewer or waterway.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
} PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
7
' SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P391:Collect spillage.P390:Absorb spillage to
prevent material-damage.
I Small Spill: Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill: Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk Remove chemicals which
can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike ifneeded.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.
I SECTION 7-HANDLING AND STORAGE
i
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product.Do not eat,drink,smoke,or apply cosmetics
while handling this product. Avoid breathing vapors,dusts or mists generated by this product Use in a well-ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
j CONDITIONS FOR SAFE STORAGE: Containers of this product most be properly labeled.Storage areas of this product should be clearly
I identified,well-illuminated,clear of obstruction and acceuibie only to trained and authorized personnel.Store containers in a clean,tool,well
ventilated,dry location,away from direct sunlight away from incompatible materials at temperatures between STE(10°C)- 100°F(37°C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
j Section 10 for incompatibilities.P234:Keep only in original container.1`403+P233:Store in awell ventilated place.Keep container tightly closed.
P406:Store in a corrosive resistant container with a resistant inner liner.
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SECTION 8-EXPOSURE CONTROLS-PERSONAL PROTECTION
j VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safny shower station is recommended to be
available near where this product Is madlstored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
.................................. .........................
CHEMICAL NAME CASE ACGIH TLV OSHA PE OTHER
3 TWA STEL TWA
SODIUM HYPOCHLORITE 7681-52-9 NE NE NE N/A
SODIUM HYDROXIDE 1310-73-2 NE C 2 mg/m' 2 mglm' NIOSH
C 2 mglm'REL
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NE=Not Established
INGESTION: P264:Wash all exposed skiNhair thoroughly after handling.Do not eat,drink or smoke when usingthis
product.
RESPIRATORY PROTECTION: P260:Do not breathe dust/fume/gas/mistivapours/spray.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respirators with dust/mist/fume/spmy filters are recommended if operations may produce dusts,miss or
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skirdhair thoroughly after handling.P280:Wear protective gloves/protective
- clothingleye protection/face protection.Wear chemical safety goggles or safety glasses with side shields.A face
shield may also be necessary for splash protection.
sSKIN PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloves/protective
ciothingleye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat.overalls).
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Greenish-yellow to yellow liquid VAPOR PRESSURE,mm Hg @ 20OC: 12 mm Hg
ODOR: Pungent.chlorine odor VAPOR DENSITY(Air=1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water--1): 1.16- 1.20
PH: 11 - 13 SOLUBILITY IN WATER: Soluble
MELTING/FREEZING POINT: 7.52-F(-13.6-C) PARTITION COEFFICIENT(n-octenollwater)Not established
BOILING POINT: >104°F(>409C) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Not applicable DECOMPOSITION TEMPERATURE: Not established
i EVAPORATION RATE(n-BuAc=1): Not established VISCOSITY: Notestablished
FLAMMABILITY(SOLIDIGAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%y Not established
{ FLAMMABLE LIMITS(in air by volume,%): Not applicable
3
l SECTIONI0-STABILtTYANDREACTIVITY
REACTIVITY: Contact with most metals will generate flammable hydrogen gas.Contact with water will generate
considerable heat.Reacts with amines and and ammonia compounds to form explosively unstable compounds.
May be corrosive to metals.May be corrosive to:Aluminium,sminless steel,carbon steel,copper,bronze.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
3 HAZARDOUS REACTIONS: Reacts vigorously or violently with many organic and inorganic chemicals such as:acids,acrolein,ac yinnitrile,
chlorinated hydrocarbons(e.g. 1,2 dichlorce hylene),chlorine dioxide,malefic anhydride,nitroethane,
nitroparaffins,2-oitrophenol,nitropropane,phosphorus,potassium persWfate,and tet-shydrofuran(containing
peroxides).
CONDITIONS TO AVOID: Direct sources of heat.Avoid high temperatures.Direct sunlight Avoid contact with incompatible materials.
Do not use in areas without adequate ventilation.Do not allow evaporation to dryness.
INCOMPATIBLE MATERIALS: Metals.Strong oxidizing agents.Acids.Amines Ammonia.Reducing agents.Nitrites.Organic compounds.
HAZARDOUS
( DECOMPOSITION PRODUCTS: in the event of fire the following can be released:Chlorine.Sodium chlorate.
SEC71ON 1 I •TOXICOLOGICAL INFORMATION
_ TOXICOLOGICAL EFFECTS:No data avallable for this product.
LIKELY ROUTES OF EXPOSURE:
7
Inhalation:Prolonged inhalation may be harmful.May cause Irritation to the respiratory system.May cause severe irritation to the nose.throat and
Skin
ComaCauses
tract.
Skin Conga Causes severe skin bums.
Eye Contact Causes serious eye damage.
Ingestion:Causes digestive tract burns.Ingestion may cause severe Irritation of the mouth,the esophagus and the gastrointestinal tract.
RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYED❑MMEDIATE/CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURES:
Corrosive to the eyes and may cause severe damage Including blindness.Symptoms may include stinging,tearing,redness,swellmns,and blurred
vision.Direct skin contact may cause corrosive skin bums,deep ulcerations and possibly permanent scarring.Can cause severe respiratory irritation.
Symptoms may include coughing,choking and wheezing.Inhalation could result in pulmonary edema(fluid accumulation).Symptoms of pulmonary
j edema(chest pain,shortness of breath)may be delayed.May cause severe irritation and corrosive damage in the mouth,throat and stomach.
Symptoms may include abdominal pain,vorandog,bums,perforations,bleeding and eventually death.
NUMERICAL MEASURES OF TOXICITY:
jAcute:
I Dermal:LDSO,Rabbit,>I0,000 mg/kg
Inhalation:LC50,Rat,>5.25 mg/1/4h
Orate IDSO,Rat.8910 mg/kg
CARCINOGENICITY: None of the components of this product are listed by the NTP,]ARC,or regulated by OSHA as carcinogens,
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SECTION 12- ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
Crustacea:EC50,Water flea(Ceriodaphnia dubia),40 mg/l,48 hours
Sodium Hypochlorite:LC50,Western mosquitofish(Gambusia affinis), 125 mg/I,96 hours
Crustacea:ECSO.Water flea(Daphnia magna),0,169 mg/I,48 boors
Fish:LC50,Blueglll(Lepomis macrochirm),0,58 mg/I.96 hours
PERSISTENCE AND DEGRADABILITY:Biodegradation is not applicable to inorganic substances.
BIOLOGICAL ACCUMULATION POTENTIAL:No accumulation in living organisms expected due to high solubility and dissociation
j properties.
77 MOBILITY IN SOIL:High water solubility indicates a high mobility in soil.
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No other adverse environmental effects(e.g.ozone depletion,
photochemical ozone creation potential,endocrine disruption,global warning potential)are expected from this component).
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Environmental Hazards:
This product is toxic to fish and aquatic organisms.Do not discharge effluent containing this product into lakes,streams,ponds,estuaries,oceans,or
other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System,(NPDES),permit and the permitting
authority has been notified in writing prior to discharge.Do not discharge effluent containing this product to sewer systems without previously
} notifying the local sewage treatment plant authority.For guidance contact your State Water Board or Regional Office of the EPA
j BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEN)have not been determined for the components of this
product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly drain/empty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.P501:
Dispose of contents/container in accordance with IocaVreglonal/national/international regulations.
7 SECTION I4-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
3
7 DOT. (RQ:100)UN1791,HYPOCHLORITE SOLUTIONS,8,PGIII
Emergency Response Guidebook Guide No.: 154 4' �"Passenger Aircraft Qty.SLCargo Aircraft Qty.60L
IMDG/IMO: (RQ:100)UN 1791,HYPOCHLORITE SOLUTIONS,8,PGIII
IATA/ICAO: (RQ:100)UN 1791,HYPOCHLORITE SOLUTIONS,8,PGIII +
ENVIRONMENTAL HAZARDS
j (i.e.,MARINE POLLUTANT): Yes.
_ TRANSPORT IN BULK(accortingto
annex 11 marpol 73178 and the IBC code): Not applicable.
1 SPECIAL PRECAUTIONS FOR USER: None known.
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PRODUCT REQUIRES CORROSIVE AND MARINE POLLUTION LABEL
I SECTION IS-REGULATORY INFORMATION
United States and International Regulations
3
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
I reporting as fisted below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
CHEMICALNAME
SODIUM HYPOCHLORITE SARA 302140 CFR 3S5,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
SARA 313(40 CFR 372,65)-NO
1 SODIUM HYDROXIDE SARA 302(40 CFR 355,Appendix A)-NO
' SARA 304(40 CFR Table 302.4)-YES
SARA 313(40 CFR 372.65)-NO
WATER TREATMENT EXPERTISE SINCE 1904
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D.S.Regulations
j U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this
product The default Federal SDS submission and inventory requirement filing threshold of 10,000 Ibs(4,540 kg)therefore applies,
per 40 CAR 370.20.
1 U.S.CERCLA REPORTABLE QUANTITY(R%Sodium Hypochlorite(CAS#7681-52-9): 1001bs(45.4 kg);Sodium Hydroxide
(CAS# 1310-73-2): 1000 Ibs(454 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Title 3111312,Hazard Category: Acute Health: YES; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
1
FIFRA Information:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law.These requirements differ from the classification criteria and hazard information required
for safety data sheets,and for workplace labels of non-pesticide chemicals, Following is the hazard information as required on the
pesticide label:
DANGER.Corrosive.Causes irreversible eye damage or skin burns.Harmful if swallowed or absorbed through skin. Do not get in
eyes,on skin or clothing.Avoid breathing spray mist Wear goggles,or face shield.Wear protective clothing and rubber gloves.
Wash thoroughly with soap and water after handling and before eating,drinking,chewing gum,using tobacco or using the toilet.
( Remove contaminated clothing and wash clothing before reuse.
California Safe Drinking Water and Toxic Enforcement Act(Proposition 65); No component of this product Is on the
Proposition 65 list
International Regulations
CANADIAN REGULATIONS:
{ CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing
CANADIAN WHMIS CLASSIFICATION:Components of this product has a WHMIS classification of Sodium Hydroxide(CAS#1310-73-2):E;
j Sodium Hypochlorits(CAS#7681-52-9):E,
] SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
7
)
DATE OF REVISION: 2/16/2016 Supercedes: 6/10/2015
Formula 3091 is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds for
category codes 3D,BI,82,D I,D2,G4,G7,GX,Q4;with NSF Reg,No. 140845,
Formula 3091 is registered with the NSF to the Nationally Recognized Health Effects Standard(ANSI 60)for chemicals which are used to treat
drinking water,with NSF DCC#DA05595.
Although reasoozble mre has been taken in the preparation of rhiz d«umen4 wa extend no wa U.and make sm representations as to the accurary or
o,ir,ktene,s of die information contained harem,and assume no mi,onsibiiity regarding the suitability of this information for the user's Intended purpose or for We
consequences of i¢use. 6ch indhidual,luand make a deriu miwtion as to she suitability of the information for their pamoular purpose.
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Garratt
CALLAHAN SAFETY DATA SKEET
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SECTION I -PRODUCT IDENTIFICATION
I
PRODUCT NAME: FORMULA 48
PRODUCT USE: CONDENSATE CORRSION INHIBITOR
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UN 2735
PROPER SHIPPING NAME: AMINES,LIQUID,CORROSIVE,N.O.S.(CONTAINS
E CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL),8,PGII
MANUFACTURER'S NAME: Gartatt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
i Outside North America:+1.703.527.3887
I_
BUSINESS PHONE: Product Information:650-697-5811
SOS NUMBER: SD4048
j DATE OF REVISION: 8/1 812 0 1 5
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SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER cr
HAZARD STATEMENT: yP pfv
H302:Harmful if swallowed. 4
H314:Causes severe skin bums and eye damage. IA
H332:Harmful if inhaled. 4
<>
PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:If medical advice Is needed,have product container or label at hand.
3 P102:Keep out of reach of children.
PI03:Read label before use.
P260:Do not breathe dust/fume/gars/mist/vapours/spray.
I P264:Wash all exposed skinfhalr thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protecdoNface protection.
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NFPA RATING
I HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
I Hazard Smle
0=Minimal
' FSllght ,l
a 2-Modemre HEALTH 'ter INSTABILITY
]aSedous '
i-10ACJf}VIT1!�b�i}t'3"AR1Y(Yfitf.QVF} 4-Severe 2'
j "-Chronic hoard
OTHER
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SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ineredients CASK EC# WSJ
DIETHYLAMINO- 100-37-8 202-84S-2 0257 30-35
ETHANOL
I CYCLOHEXYLAMINE 108-9" 203-629-0 0245 B- I2
( SECTION 4.FIRST AID MEASURES
t
i Exposed individuals must be taken for medical attention it any adverse effect occurs.Take a copy of this SDS to the health professional with the
individual.P3I0:Immediately call a POISON CENTER or dottorlphysician.
DANGER:Harmful If swallowed.Causes severe skin burns and eye damage.Harmful if inhaled.Also refer to Section I I for symptoms,effects.and
i likely routes of exposure for this product
TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
( CHRONIC:Indication of skin,eyes,respiratory,kidneys and gastrointestinal systems,
SKIN EXPOSURE:P303*P361+P353:IF ON SKIN(or hair):Removelake off immediately all contaminated clothing.Rinse skin with water/shower.
jMinimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:Wash
contaminated clothing before reuse.The exposed individual must seek medical attention it any adverse effect occurs.
i
EYE EXPOSURE:P30S+P3S I+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing rime is for 15
minutes. The exposed individual must seek immediate medical attention if adverse effect occurs.
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:Immediately
t call a POISON CENTER or doctor/physician.
INGESTION:P301+P330+P331:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.P301+P312:IF SWALLOWED:Call a POISON
CENTER or doctor/physician if you feel unwell.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,
having convulsions,or unable to swallow.
1
(( MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the'Target
7 Organs'may he aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
occurs.
3 NOTES TO PHYSICIAN: Treat symptoms w demonstrated by signs and distress In the patient
SECTION S-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-Flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment
SPECIFIC HAZARDS ARISING FROM THE Non-Flammable liquid.Explosion hazards in Presence of Various Substances:Non-Explosive in
; CHEMICAL: presence of open flames and sparks,of shocks.
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure selGcontamed breathing apparatus Do not release run off from fire control
methods to sewer or waterways.
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1 SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING:Any container expansion or rounding indicates pressure buildup. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.
1 Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.P391:Collett spillage.
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.P391:Collect spillage.
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SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest.Wash thoroughly after handling this product Do not eat,drink,smoke.or apply cosmetics
' while handling this product. Avoid breathing vapors,dusts or mists generated by this product.Use in a welbventilated location. Remove
1 contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Comalners of this product must be properly labeled.Storage areas of this product should be clearly
identified,well-illuminated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight,away from Incompatible materials at temperatures between SO°F(IVC)- I OOIF(370C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
't Section 10 for incompatibilities.
SECTION 8-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety,shower station is recommended to be
available near where this product is umd/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
_ . . . ....................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PIE OTHER
TWA STEL TWA
DIETHYLAMINO- IOO-37-8 2 ppm(skin) NE 10 ppm or TWA NIOSH REL
ETHANOL 50 mg7m'(skin) 10 ppm or 40 mg[W
CYCLOHEXYLAMINE 108-91-8 10 ppm NE NE NIOSH
10 ppm
i
NE Net Established
INGESTION: P264:Wash all exposed skin/hair thoroughly after handling.P270:Do not eat drink or smoke when using this
1 product.
RESPIRATORY PROTECTION: P260:Do not breathe dusdfume/gas/mist{vapours/spray.P271:Use only outdoors or in a well-ventilated area. '..
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying '..
i respirators with dust/mist/fume/spray,filters are recommended if operations may produce dusts,mists or '..
sprays from this product with concentrations at or above levels posted above.
} EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloves/protecove
clothing/eye protectioNFxce protection.Wear chemical safety goggles or safety glasses with side shields.A face '..
j shield may also be necessary for splash protection. '..
c SKIN PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloves/protective
clothing/eye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat,overalls).
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SECTION 9•PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear water while liquid VAPOR PRESSURE,taco Hg@20°C: Not Applicable
ODOR: Ammonia VAPOR DENSITY(Ab=1): Not Applicable
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water=1): 0,95- 1.0
j pH: 12.0- 13.5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not applicable PARTITION COEFFICIENT(noctanol/water): Not established
BOILING POINT: 208°F AUTOIGNITION TEMPERATURE: Not Applicable
FLASHPOINT. Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(,-BuAc=1): Not Applicable VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not Applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%):Not Applicable
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
{ STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
- CONDITIONS TO AVOID: See incompatible materials.
INCOMPATIBLE MATERIALS: Acids,oxidizing agents,halogenated compounds.
HAZARDOUS
DECOMPOSITION PRODUCTS: Ammonia,oxides of nitrogen.
SECTION I I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: CYCLOHEXYLAMINE:
Oral:LDSO,Rat. 1 I m)kg
Dermal:LDSO,Rabbi%17500 mg/kg
DIETHYLAMINOETHANOL
Oral:LDSO, 1300 mg/kg
Dermal:LDSO, 1220 mgdtg
LIKELY ROUTES OF EXPOSURE: Skin/eye contact and inhalation.
RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYEDIIMMEDIATE/CHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
NUMERICAL MEASURES OF
TOXICITY: Not established for this product.
- CARCINOGENICITY: None of the components of this product are listed by the NTP.IARC,or regulated by OSHA as carcinogens.
SECTION 12-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
Fish:96 Hr.LC50 Flathead minnow,824.69 mg/L
Algae:No data available
Daphnia:48 Hr,EC50,Daphnia dubia,522.67 ppm
j PERSISTENCE AND DEGRADABILITY:No dam available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No dam available for this producL
MOBILITY IN SOIL:No data available for this product.
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(SEls)have not been determined for this product.
SECTION 13-DISPOSAL CONSIDERATIONS
_ DISPOSAL: P501:Dispose of contents/container in accordance with local/regional/national/inmmadonai regulations.Rinse empty containers with
water and use the rinse water na prepare the working solution. Refer to Section 8 for exposure controls-personal protection.
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SECTION 14-TRANSPORTATION INFORMATION
1 PROPER SHIPPING NAME
DOT: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
(CONTAINS CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL)8,PGII
Emergency Response Guidebook.Guide No.: 153 1� r
Passenger Aircraft Dry: I L <
Cargo Aircraft Cry:30L
IMDG/IMO: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
I (CONTAINS CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL)8,PGII
IATA/ICAO: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
(CONTAINS CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL)S.PGII
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex II marpol 73178 and the IBC code): Not applicable.
e
- SPECIAL PRECAUTIONS FOR USER: None known.
PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS-REGULATORY INFORMATION
? United States and International Regulations
F
IUnited States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Tide of the Superfund Amendments and
Reauthodtatlon Act:
CHEMICAL NAME
DIETHYLAMINO- SARA 302(40 CFR 355,Appendix A)-NO
ETHANOL SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 37265)-NO
CYCLOHEXYLAMINE SARA 302(40 CFR 355,Appendix A)-YES
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
i
U.S.Regulations
' U5.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantides for the components of this product.
The default Federal SDS submission and inventory requirement filing threshold of 10.000Its(4,540 kg)therefore applies,per 40 CFR 370,20,
U.S.CERCLA REPORTABLE QUANTITY(RQ):Cyclohexylamine(CAS# 10841-8): 10,000 Ibs(4540 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Title 311/312,Hazard Category. Acute Health: YES; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
p California Safe Drinking Water and Toxic Enforcement Act(proposition 65): No component of this product is on the Proposition
65 list,
International Regulations
CANADIAN REGULATIONS:
I CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the OSL or NDSL Inventories or are exempt from
listing.
CANADIAN WHMIS CLASSIFICATION:
Cyclohexylamine(CAS# 108-91-8)is classified by WHMIS as B2,DR.D2B,E;
- Diethylaminoerhanol(CAS# 100A7-8)is clanfied by WHMIS as B3,DIB,E.
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SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
3 DATE OF REVISION: 8/1 812 0 1 5 Supercedes: 8/1/2014
Formula 48 is registered with the NSF to the NSF International Registration Guldelium for Proprietary Substances and Nonfood Compounds for
category codes G6,with NSF Reg.No.045983.
3
FORMULA 48 has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OUY3413IBD08 when prepared in either
the Addison,Illinois or Burlingame,California facilities.
Although reasonable one has been taken in the preparation of this document we extend no warrami.and make no representations as to the accuocy or
completeness of the information contained herein,and assume no responsibility regarding the suitability of this information for the users intended purpose or for the
consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose.
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\
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j ATTACHMENT
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ja_-lz Water Treatment Chemical m»
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} _a_.Inc.—Wastewater Discharge_.

Garreatt
CALL H A N SAFETY DATA SHEET
J SECTION 1 -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 1154
PRODUCT USE: BOILER WATER TREATMENT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: NOT REGULATED
'? PROPER SHIPPING NAME: NOT REGULATED
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1-800-424.9300
Outside North Americs+l-703.527.3887
BUSINESS PHONE: Product Information:650-697-5811
i
SDS NUMBER: SDI 154
DATE OF REVISION: 4/20/2015
4
I
SECTION 2.HAZARDS IDENTIFICATION
j SIGNAL WORD:WARNING
HAZARD STATEMENT:
H3IS:Causes skin Irritation.
H320:Causes eye irritation.
jH335:May cause respiratory Irritation.
PRECAUTIONARY STATEMENTS:(PREVENTION)
Pill:if medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
PI03:Read label before use.
P260:Do not breathe dust/fume/gas/mbuvapoe.hpmy.
P264:Wash all exposed skin/hair thoroughly after handling.
1`280:Wear protective gloves/protecdve clothingleye protection/face protection.
i
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
' Ha=ard Scale
o-Nmimel
{ i 1-Sight 1
e ]-Senooz� HEALTH �% INSTABILITY
f i=REAC71Vj'fY HA'ZARF}(YEGt61M)
`-Chronk lamrd
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FORMULA 1154 vrviw.garrattcallahan.com Page I of 5

SECTION 3- COMPOSITIONIINFORMATION ON INGREDIENTS
's
Hazardous Ingredients CA S# Eft ICSC# "T
SODIUM HEXAMETAPHOSPHATE 68915-31-1 272-803-3 NE 20-25
3 PROPRIETARY POLYMER MIXTURE NE NE <20
i
SECTION 4-FIRST AID MEASURES
Take a copy of this SDS to the health professional with the individual.P312:Call a POISON CENTER or doctor/physician if you feel unwell.
WARNING:Causes skin irritation.Causes eye irritation.May cause respiratory Irritation.Also refer to Section I 1 for symptoms,effects,and likely
routes of exposure for this product.
TARGET ORGANS:
ACUTE:irrhadon of skin,eyes,resph atary and gastrointestiwl systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with soap and water.Rinse skin with water/shower.Minimum rinsing time is for 15 minutes.
( P362+P364:Take off contaminated clothing,and wash before reuse.P332+P313:If skin irritation occurs:Get medical advicelattention.
t
EYE EXPOSURE:P305+p351+p338:IF IN EYES:Rinse cautiously with water for several minutes.Remove coma lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes.Minimum rinsing time is for 15 minutes.
i P337+P313:Get medical advice/attention.
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312:Call a POISON CENTER or doctorlphysician if you feel unwell.
i
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Exposed individual must seek Immediate medical attention if any adverse
( effect occurs.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable to
swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product,Exposed individual must seek immediate medical attention if any adverse effect
occurs.
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NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient.
SECTION 5-FIRE FIGHTING MEASURES
i SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment
SPECIFIC HAZARDS ARISING FROM THE Refer to section 10.Thermal decomposition may produce irritating fumes.
CHEMICAL:
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
i PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.
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SECTION d-ACCIDENTAL RELEASE MEASURES
t
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
1 PROCEDURES.
WARNING:Any container expansion or rounding indicates pressure buildup. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
f procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P391:Collect spillage.
Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk Remove chemicals which
can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
7
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be[rained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product.Use in a wel4ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be dearly
identified,well-illummated,clear of obswction and accessible only to trained and authorized personnel.Store containers In a clean,cool,well
ventilated,dry location,away from direct sunlight away from incompatible materials at temperatures between SVF(10°C)- 100°F(37°C). Keep
_ container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.P403*P233:Store in a well ventilated place.Keep container tightly closed.
SECTIONS-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/swred.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
i .......................................I....................CHEMICAL NAME CAS ACGIH TLV OSHA PE L OTH ER
_ TWA STEL TWA
SODIUM 68915-31-1 NE NE NE N/A
HEXAMETAPHOSPHATE
3 PROPRIETARY POLYMER MIXTURE NE NE NE N/A
NE Not Established
a INGESTION: Do not cat,drink.smoke,or apply cosmetics when handling this product Wash all exposed skin/hair
thoroughly after candling.
RESPIRATORY PROTECTION: P261:Avoid breathing dustlPome/gas/mist/vapours/spray.P271:Use only outdoors or in a well ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
t respirators with dust/mist/fume/spray filters are recommended if operations may produce dusts,misu or
sprays from this product with concentrations at or above levels posted above
EYE PROTECTION: P264:Wash all exposed skiNhair thoroughly after handling.Wear chemical safety goggles or safety glasses with '..
side shields.A face shield may also be necessary for splash protection. '..
SKIN PROTECTION: P264:Wash all exposed skiNhair thoroughly after handling.P280:Wear protective glovestimmective '..
clothing/eye protectioniface protection.Use chemically-resistant gloves and skin protection,when handling '..
j this product Use body protection appropriate for task(e.g.,lab coop overalls). '..
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear liquid VAPOR PRESSURE,rem Hg@2VC: Notestablished
ODOR: Odorless VAPOR DENSITY(Air=1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@2VC(water=l): 1.2- 1.3
PH: 5.5-7.5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not applicable PARTITION COEFFICIENT(noctanol/water): Not established
BOILING POINT: 212-F(100-C) AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): < t VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%): Not establlshed
SECTION 10-STABILITY AND REACTIVITY
_? REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: See incompatible materials.
CONDITIONS TO AVOID: Freezing temperatures.
3 INCOMPATIBLE MATERIALS: Strong oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition may result in oxides oforbon and nitrogen.
- SECTION I I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: SODIUM HEXAMETAPHOSPHATE:
1 Ora:Ld50,Rae 3053 mg/kg
LIKELY ROUTES OF EXPOSURE: Skin/eye contact and inhalation.
RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal Irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHRONIC
' EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye,respiratory and gastrointestinal irritation.May be harmful If swallowed.
j NUMERICAL MEASURES OF
TOXICITY: Not established for this product
I
CARCINOGENICITY: None of the components of this product are listed by the NTR IARC,or regulated by OSHA as carcinogens.
SECTION 12-ECOLOGICAL INFORMATION
"s
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:Dam not available for this product,
PERSISTANCE AND DEGRADABILITY:No dam available for this product
3 BIOLOGICAL ACCUMULATION POTENTIAL•No dam available for this product
MOBILITY IN SOIL:No data available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No data available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEIs)have not been determined for this product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: P501:Dispose of contents/container in accordance with IonUregionai/national/intemational regulations.Thoroughly draiNempty
containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.
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FORMULA 1154 www.garrattrallahan.com Page 4 of S
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SECTION I4-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: NOT REGULATED
IMDG/IMO: NOT REGULATED
{ IATA/ICAO: NOT REGULATED
I ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): Not known.
TRANSPORT IN BULK(according to
annex H marpol 7317E and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: Not known.
I SECTION 15-REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Tide of the Superfund Amendments and
Reauthorization Act:
`t
CHEMICALNAME
SODIUM HEXAMETAPNOSPHATE SARA 302(40 CFR 355,Appendix A)NO
_ SARA 304(40 CFR Table 302.4)NO
SARA 313(40 CFR 372.65)NO
PROPRIETARY POLYMER SARA 302(40 CFR 355,Appendix A)NO
SARA 304(40 CFR Table 302.4)NO
p SARA 313(40 CFR 372.65)NO
(
)
1 U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
The default Federal SDS submission and inventory requirement filing threshold of 10,000Ibs(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):None
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA Title 311/312,Hatard Category: Acute Health: NO; Chronic:NO; Fire:NO: Reactive:NO; Sudden Release of Pressure:NO
California Safe Drinking Water and Toxic Enforcement Act(proposition 65): No component of this product is on the Proposition
65 list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
listing.
CANADIAN WHMIS CLASSIFICATION:None.
I SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 4/20/2015 Supercedes: 1/7/2009
Although reasonable care has been taken in the preparation of this document we extend no warranties and make no representations as to the ammq or
completeness of the information connived herein,and assume an responsibility regarding the suitability of this information for the users intended purpose or for the
consequences of its use. Each iMMdual sMuld make a decerminatwn as m die suitabilhy of the information br their particular purpose.
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Garreatt
CALLAHAN
SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
j PRODUCT NAME; FORMULA 12-L
PRODUCT USE: CLOSED SYSTEM INHIBITOR
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
i UN NUMBER: 3266
PROPER SHIPPING NAME: CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S. (SODIUM
NITRITE SOLUTION)8,PGII
MANUFACTURER'S NAME: Garratt-Callahan Company
s ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1-800-424.9300
Outside North America:+i-703-S27.3887
BUSINESS PHONE: Product Information:650-697-5811
SOS NUMBER: SD6012
DATE OF REVISION: 2/8/2016
SECTION 2-HAZARDS IDENTIFICATION
i
f SIGNAL WORD:DANGER
i
HAZARD STATEMENT: •�
H301:Toxic if swallowed. 3
H315:Causes skin irritation. 2
H320:Causes eye irritation. 2B
H333:May be harmful if inhaled.
1 H402:Harmful to aquatic life. 3
{
PRE6AU I tuNARY STATEMENTS:(PREVENTION)
PI01:If medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
i P103:Read label before use.
= P264:Wash all exposed skin/hair thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
F280:Wear protective gloves/protective clothing/eye protection/face protection.
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
H.d Sale
t U-Mm coal
1 f 1_Sl ght
2-Moderme HEALTH INSTABILITY
PHK51S.'�At,;HA21C�(YkLF<47W} P� 3-Senoas �.
'Chl re
a'GhronlchaIDM
(
OTHER
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FORMULA 12-L vmw.garrattcallahan.com Page 1 of 6

i
SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
I Hazardous In¢redients CA S# E ICSG# '1—✓IX
SODIUM NITRITE 7632-00-0 231-555-9 1120 25-30
SODIUM METABORATE 7775-19-1 231-891-6 NE 7- 10
SODIUM TOLYLTRIAZOLE 64665-57-2 265-004-9 1091 1 -4
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SECTION 4•FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
i individual.P310.Immediately call a POISON CENTER or doctor/physician.
3
DANGER:Toxic if swallowed.Causes skin ittiradon.Causes eye irritation.May be harmful if inhaled.Harmful to aquatic life.Also refer to Section I I
for symptoms,effects,and likely routes of exposure for this product
TARGET ORGANS:
j ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
i
7 SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with soap and water.P332+P313:If skin irritation occurs:Get medical advicefattention.P362
+P364:Take off contaminated clothing and wash before reuse.Minimum flushing time is for 15 minutes.
EYE EXPOSURE:P305+P351+P339:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
p do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes. P337+P313:If eye Irritation persists get medical advicdattention.
INHALATION:P304+P312:IF INHALED:Remove victim to fresh air and keep at rest In a position comfortable for breathing.
INGESTION:P301+310:IF SWALLOWED:Call a POISON CENTER or doctor/physician if you feel unwell.P330:Rinse mouth.Never Induce
vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable to swallow.
I MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the'Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
occura.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment
SPECIFIC HAZARDS ARISING FROM THE Nitrites are oxidizers,and in contact with readily oxidized materials will stimulate combustion at
t CHEMICAL: high temperatures. Residue from this product may supply oxygen for a fire. Heated product may
emit toxic oxides of nitrogen and boron.
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical Impermeable,fully encapsulated suit)
i PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.
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i
SECTIONb•ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
I PROCEDURES.
WARNING:Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
F SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P273:Avoid release to the environment.
R
1 Small Spill:Mop up,or absorb with an Inert dry material and place in an appropriate waste disposal container.P391:Collect spillage.
I
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.P391:Collett spillage.
i SECTION 7-HANDLING AND STORAGE
i
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.Ail employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this produm Do not eat,drink,smoke,or apply cosmetics
while handling this product. Avoid breathing vapors,dusts or mists generated by this product.Use in a well-ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
i identifed,welbillummated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight away from incompatible materials at temperatures between SOF(10`C)- 100 F(3YC). Keep
container tightly dosed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
3 Section 10formcompatiblliti.,
SECTION B-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.EyewasNsafety shower station is recommended to be
available near where this product Is used/stored.
Ss EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PE L OTHER
TWA STEL TWA
SODIUM NITRITE 7632-00-0 NE NE NE N/A
SODIUM METABORATE 7775-19-1 NE NE NE N/A
SODIUM TOLYLTRIAZOLE 6466557-2 NE NE NE NIA
NE=Not Esubimool
INGESTION: P264:Wash all exposed skinlhair thoroughly after handling.P270:Do not eat drink or smoke when using this
product. '..
RESPIRATORY PROTECTION: Do not breathe dust/fume/gas/mist/vapours/spray.Maintain airborne contaminant concentrations below '..
guidelines listed above.if applicable. Air-purifying respirators with du dmist/fume/spray filters are '..
recommended if operations may produce dusts,mists or sprays from this product with concentrations at or '..
above levels posted above. '..
EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.Wear chemical safety goggles or safety glasses with '..
side shields.A face shield may also be necessary for splash protection. '..
1 SKIN PROTECTION: P264:Wash all exposed skinmair thoroughly after handling.P280:Wear protective gloveslprotective
clothingleye protectionifxce protection.Use chemically-reshunt gloves and skin protection,when handling
this product.Use body protection appropriate for task(e.g.,lab coat overalls).
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear yellow liquid VAPOR PRESSURE.mm Mg @ 20OC: Not determined
ODOR: Sweet organic VAPOR DENSITY(Air=l): Not applicable
ODOR THRESHOLD: Notesmblished RELATIVE DENSITY@20°C(water—i): I.26- I.28
i pH: 12.S- 14.0 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not Established PARTITION COEFFICIENT(nrocmnolAvzter): Not established
BOILING POINT: >212-F(100-C) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Nomflammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): Notestablished VISCOSITY: Not established
7a FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
I FLAMMABLE LIMITS(in air by volume,%): Not applicable
SECTION 10•STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: None known
CONDITIONS TO AVOID: Do not combine with acidic compounds:a violent reaction will occur forming toxic vapors of nitrogen and
sulfur oxides.
INCOMPATIBLE MATERIALS: Acids,amines,and oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition may yield oxides of carbon,nitrogen.
3
SECTION I I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: No data available for this product
LIKELY ROUTES OF EXPOSURE: Skinleye contact and inhalation.
RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYEDRMMEDIATEfCHRONIC
j EFFECTS FROM SHORT AND
LONGTERM EXPOSURES: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
NUMERICAL MEASURES OF
TOXICITY: Not established for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
d
j SECTION I2-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
3 ECOTOXICITY: Data not available for this product
's PERSISTENCE AND DEGRADABILITY: No dam available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL: No dam available for this product.
MOBILITY IN SOIL No data available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer): No dam available for this product
i
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices FFb)have not been determined for this product
SECTION 13-DISPOSAL CONSIDERATIONS
i
DISPOSAL: Thoroughly drain/empty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.P50L '..
Dispose of contentsfconminer in accordance with IocaVmgional/national/intemationai regulations. '..
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FORMULA 12-L www.garrattcallahan.com Page 4of6

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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: RQ for Totes and 55 gallons:
y UN3266,CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
1 (SODIUM NITRITE SOLUTION)8,PGII ��y
Emergency Response Guidebook,Guide No.: 154
jPassenger Aircraft Qry: IL
Cargo Aircraft Cry:30L '
IMDG/IMO: RQ for Totes and 55 gallons:
UN3266,CORROSIVE LIQUID,BASIC.INORGANIC,N.O.S.
(SODIUM NITRITE SOLUTION)8,PGII
IATA/ICAO: RQ for Totes and 55 gallons:
UN3266,CORROSIVE LIQUID,BASIC,INORGANIC,N.O.S.
j (SODIUM NITRITE SOLUTION)8,PGII
j ENVIRONMENTAL HAZARDS
f (i.e.,MARINE POLLUTANT): None known.
3 TRANSPORT IN BULK(according to
annex 11 marpol 73178 and the IBC code): Not applicable.
s SPECIAL PRECAUTIONS FOR USER: None known.
PRODUCT REQUIRES CORROSIVE LABEL
SECTION 15- REGULATORY INFORMATION
3
United States and International Regulations
't
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Tide of the Superfund Amendments and
Reauthorization Act:
CHEMICAL NAME
SODIUM NITRITE SARA 302(40 CFR 355,Appendix A)—NO
SARA 304(40 CFR Table 302.4)—YES
SARA 313(40 CFR 372,65)-YES
j SODIUM METABORATE SARA 302(40 CFR 35S,Appendix A)—NO
SARA 304(40 CFR Table 302.4)—NO
SARA 313(40 CFR 372.65)-NO
a
SODIUM TOLYLTRIAZOLE SARA 302(40 CFft 355,Appendix A)—NO
SARA 304(40 CFR Table 302.4)—NO
SARA 313(40 CFR 372.65)-NO
i
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are specific Threshold Planning Quantities for the components of this product.The
default Federal SDS submission and Inventory requirement filing threshold of 10,000 Ras M S40 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA Reportable Quantity(RQ): Sodium Nitrite: 100 Its(45.4 kg).
€ U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
Section 311/312 Hazard Category.Acute Health:YES CHRONIC:YES Fire:NO Reactive:NO Sudden Release of Pressure:NO
t California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): No component of this product is on the Proposition
! 65 list
International Regulations
CANADIAN REGULATIONS:
CANADIAN OSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing.
3 CANADIAN WHMIS CLASSIFICATION: None.
3
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 12-L www.garrattczllahan.com Page 5 of 6

1
SECTION I6.OTHER INFORMATION
j PREPARED BY. GARRATT CALLAHAN
i
- DATE OF REVISION: 2/8/2016 Supersedes: 8l1012015
This product has been certified by the Orthodox Union as Kosher Pareve under the UK 0 number of OUV3-5994217 when prepared in either the
] Addison.Illinois or Burlingame.California facilities.
1
Although reasonable are has been taken in the preparation of this document,we extend no vo randes and make no repreo matiom as to the accuaq or
completeness of the information contained herein.and assume re,responsibility regarding the mhabilmy of this information for the users Intended purpose or for the
consequences ofita use. Cash iiMieidual should make.determination o to the suitability of me Information for their particular purpose.
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FORMULA 12-1 www.garractcallahan.corn Page b of b
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CALLAHANSAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
s PRODUCT NAME: FORMULA 55
PRODUCT USE: PENETRANTIDISPERSANT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: NOT REGULATED
PROPER SHIPPING NAME: NOT REGULATED
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: I-800-424.9300
Outside North America:+1-703.527.3887
BUSINESS PHONE: Product Information:650-697.5011
I SDS NUMBER: SD2055
DATE OF REVISION: 6/8/2015
SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
] HAZARD STATEMENT:
H315:Causes skin irritation. 2
1-1320:Causes eye irritation. 2B
- H335:May cause respiratory irritation. 3
PRECAUTIONARY STATEMENTS:(PREVENTION)
- PI01:if medical advice Is needed,have product container or label at hand.
P 102:Keep out of reach of children.
PI03:Read label before use.
P261:Avoid breathing dust/f cane/gastneadvapours/spray.
i P264:Wash all exposed skinthair thoroughly after handling.
1`271:Use only outdoors or In a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/fece protection.
"t
NFPARATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Havard Scale
1 �� - 0-Minimal
2"Modeace �-
3=Senous HEALTH INSTABILITY
('.REAG`f7YiT5f-HAZARq(YEE�.CSWj 4-Severe
'-Chromc hamrd
i
OTHER
t
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 55 www.garattcallahan com Page 1 of 5
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t3S
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SECTION 3• COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS# EC# IC5C# WTk
AMIDES,C12-18 AND CIR-UNSATURATED, 90622-74-5 NIA N/A 5
N,N-BIS(HYDROXYETHYL)
f METHYL-OXIRANE POLYMER WITH OXIRANE 900341-6 NIA NIA 5
SECTION 4-FIRST AID MEASURES
P311 Call a POISON CENTER or doctor/physician if you feel unwell.Take a copy of this SDS to the health professional with the individual.
WARNING:Causes skin and eye irritation.May cause respiratory irritation.Also refer to Section I I for symptoms,effects,and likely routes of
exposure for this product
S TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE:P302+P352:IF ON SKIN:Wash with plenty of water.Minimum Rushing time is for 15 minutes.P362+P364:Take off
# contaminated clothing and wash before reuse.P332+P313:If skin irritation occurs:Get medical advicelauxu lion.
EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum rinsing time is for 15 minutes.
P337+1`313:If eye irritation persists get medical advice/attention.
INHALATION:P304+p340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P312:Call a
POISON CENTER or doctor/physician If you feel unwell.
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give dilutor,(milk or water)by mouth to
someone who is unconscious,having convulsions,or unable to swallow.Call a POISON CENTER or doctor/physician if you feel unwell.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this produm Exposed indWidual must seek immediate medical attention if any adverse effect
occurs.
E
NOTES TO PHYSICIAN:Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to local circumstances
EXTINGUISHING MATERIALS: and the surrounding environment Do not use carbon dioxide as an extinguishing material.
_ SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL:
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
j PRECAUTIONS FOR FIREFIGHTERS: and positive pressure sel&contained breathing apparatus.Do not release run off from Ore control
i
methods to sewer or waterways.
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA S5 www.garrattcallahan.com Page 2 of 5 '..

SECTION 6-ACCIDENTAL RELEASE MEASURES
7 PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
} WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately[rained personnel using pre-planned
procedures.Proper protective equipment should be used, refer to Section 8-exposure controls.P391:Collect spillage.
Small Spill: Mop up,or absorb with an Inert dry material and place in an appropriate waste disposal container.
4 Large Spill: Resvict access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
which can react with the spilled material. Add dry inert material to contain and absorb spilled material, Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limier. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
container and seal.
SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid dire"or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat drink,smoke,or apply cosmetics
7 while handling this product Avoid breathing vapors,dusts or misss generated by this product Use in a well-ventilated location. Remove
contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
E
CONDITIONS FOR SAFE STORAGE:Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,weRAlummated,clear of obs[rurtkm and accessible only to trained and authorized personnel.Stare containers In a clean,cool,well
7 ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between 5VF(KYC)- I00°F(3YC). Keep
container tightly closed when not in use.P405:Store locked up.Do not Ingest.Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.P403+P233:Store in a well ventilated place.Keep container tightly closed.Keep away from oxidizing and reducing
agents.
SECTION 8-EXPOSURE CONTROLS-PERSONAL PROTECTION
i
- VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation Eyewash/afery shower station is recommended to be
available near where this product is usedlstored.
i EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PE L OTHER
3 TWA STEL TWA
- AMIDES,C12-18 AND C18- 90622-74-5 NE NE NE N/A
UNSATURATED,N,N-
BIS(HYDROXYEfHYL)
METHYL-OXIRANE POLYMER 9003-I I-6 NE NE NE WA
WITH OXIRANE
3
I NE=Not Established
,3
INGESTION: Do not eat,drink,smoke,or apply cosmetics when handling this product Wash all exposed skin/hair
thoroughly after handling.
RESPIRATORY PROTECTION: P261:Avoid breathing dust/fhmefgas/mist/vapows/spray.P271:Use only outdoors or in a well-ventilated area.
I Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respimtors with dust/mist/fume/spmy liters are recommended if operations may produce dusts,mists or
j sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skiNheir thoroughly after handling.Wear chemical salary goggles or safety glasses with
side shields.A face shield may also be necessary for splash protection.
SKIN PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloves/protective
clothing/eye protecdon/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat,overalls).
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 55 www.garrattcallahan,com Page 3 of 5

SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear water white liquid VAPOR PRESSURE,mm Hg @ 20"G Not applicable
ODOR: Slight VAPOR DENSITY(Air=[): Not applicable
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water-1): 0.97-1.07
j PH: 7.5-10.5 SOLUBILITY IN WATER: Complete
MELTINGIFREEZING POINT: Not established PARTITION COEFFICIENT(n-octanollwater): Not established
BOILING POINT: 21VF(100-C) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Nonflammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=1): < I VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Notapplicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume.%): Not applicable
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
I POSSIBILITY OF
HAZARDOUS REACTIONS: See incompatible materials.
CONDITIONS TO AVOID: See incompatible materials.
7 INCOMPATIBLE MATERIALS: Strong oxidizing and reducing agents.
HAZARDOUS
- DECOMPOSITION PRODUCTS: Not established.
SECTION i 1 -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: No data available for this product
LIKELY ROUTES OF EXPOSURE: Skin,and eye contact,inhalation.
RELATED SYMPTOMS: Skin,eye and respiratory irritation.May be harmful if swallowed.
j DELAYED/IMMEDIATE/CHRONIC
j EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye and respiratory irritation.May be harmful if swallowed.
NUMERICAL MEASURES OF
TOXICITY: Not established for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,[ARC,or regulated by OSHA as carcinogens.
SECTION 12-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:No data available for this product.
3 PERSISTANCE AND DEGRADABILITY:No data available for this product
BIOLOGICAL ACCUMULATION POTENTIAL No data available for this product.
- MOBILITY IN SOIL:No data available for this product.
j OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No data available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for this product
SECTION 13-DISPOSAL CONSIDERATIONS
i DISPOSAL: P501:Dispose of contents/container in accordance with foal/regionaUmtional/intemational regulations.Rinse empty containers with
water and use the rinse water to prepare the working solution. Refer to Section 8 for exposure controls-personal protection.
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 55 www.garrattwllahan,com Page 4 of 5

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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: NOT REGULATED
IMDG/IMO: NOT REGULATED
IATA/ICAO: NOT REGULATED
i
ENVIRONMENTAL HAZARDS
(!.a,,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex II marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USERS None known.
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
j United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superhard Amendments and
Reauthorization Act:
- CHEMICAL NAME
AMIDES,C12-18 AND C18- SARA 302(40 CFR 355,Appendix A)-NO
UNSATURATED,N,N- SARA 304(40 CFR Table 302.4)-NO
BIS(HYDROXYETHYL) SARA 313(40 CFR 37Z65)-NO
j METHYL-OXIRANE POLYMER WITH SARA 302(40 CFR 355,Appendix A)-NO
OXIRANE SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372,65)-NO
i
U.S.Regulations
- U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product.
The default Federal SDS submission and inventory requirement filing threshold of 10.000 Its(4,540 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):None.
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA inventory.
j
SARA Title 3111312,Harard Category: Acute Health: NO; Chronic:NO; Fire:NO; Reactl NO; Sudden Release of Pressure:NO
California safe drinking water and toxic enforcement act(proposition 65): No component of this product Is on the Proposition 65
( list
1 International Regulations
I CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
listing.
CANADIAN WHMIS CLASSIFICATION:None.
1
] SECTION Ib-OTHER INFORMATION
i
PREPARED BY: GARRATT CALLAHAN
{jt DATE OF REVISION: 6/8/2015 Supercedes: 7/23/2014
j Formula 55 is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds for
i
category codes Al,GS,G7;with NSF Reg,No. 133119.
i
Although ues ,able care has been taken d the h%oula assume
of this doeoment.we exrdin no warranties and makfor representations as to she accuracy e
ompiereness of the information contained herein.and assume no responsibility regarding of
a information
this information for the users incended purpose or for the
consequences of its use. Fach iiMintlud should makes determination astothe suitability of meinformaGon for their patticvWr purpose.
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j FORMULA 55 www.garrattcallahan.com Page 5 of 5

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Garratt
3 C14 i A H A N SAFETY DATA SHEET
SECTION 1 -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 159
I PRODUCT USE: OXYGEN SCAVENGER
RESTRICTIONS ON USE: Refer to label,available technical Information,and other appropriate
# sections of this SOS.
UN NUMBER: NOT REGULATED
3 PROPER SHIPPING NAME: NOT REGULATED
3 MANUFACTURERS NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800.424.9300
Outside North America:+1 J03.527.3887
- BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SDI559
I DATE OF REVISION: 7/29/2015
SECTION 2•HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
GHS HAZARD STATEMENT:
E H316:Causes mild skin irritation.
H320:Causes eye irritation.
H335:May cause respiratory irmadon.
PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:1f medical advice is needed,have product container or label at hand.
I P102:Keep out of reach of children.
- P103:Read label before use.
P261:Avoid breathing dust/fume/gas/mist/vapours/spmy.
P264:Wash all exposed skin/hair thoroughly after handling.
t P271:Use only outdoors or in a well-ventilated area.
i
3
1
- NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
3 Haurd Scale
i 0=Minimal
1=sight
2=Moder°m HEALTH "� � INSTABILITY
3=Serious
CTIXITYA4A `AAD{YYf1t.OXry D 'Severe
*=Clvoni<harard
j
OTHER
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I WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 159 www.garrattcallahan.com Page I of

i
SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingred'ents CAS# EC# ICSC# riT
SODIUM BISULFITE 7631-90-5 231-548-0 N/A 20-25
{ POTASSIUM SULFITE 10117-38-1 233-32I-1 N/A 20-25
i
SECTION 4-FIRST AID MEASURES
Exposed individuals must be taken for medial attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
3 individual.P312:Call a POISON CENTER or doctor/physician if you feel unwell.
WARNING:Causes mild skin irritation.Causes eye irritation.May cause respiratory irritation.Also refer to Section I I for symptoms,effects,and
i
likely routes of exposure for this product,
TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
s
SKIN EXPOSURE:IF ON SKIN:Wash with water.Minimum rinsing time is for 15 minutes.Take off contaminated clothing and wash before reuse.
P332+P313:If skin Indianan occurs:Get medial advice/.ttentima.
EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses Ifpresent and easy to
do—continue rinsing.Use sufficient force to open the eyelids.Have the exposed individual"roll"their eyes.Minimum rinsing time is for 15 minutes.
- P337+P313:If eye irritation persists get medial advice/attendon.
jINHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P312:Call a
- POISON CENTER or doctor/physician if you feel unwell.
INGESTION:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give diluents(milk or water)by mouth to
i someone who is unconscious,having convulsions,or unable to swallow.Call a POISON CENTER or doctor/physician if you feel unwell.
)
3 MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs'may be aggravated by prolonged exposures to this product.Exposed individual must seek Immediate medical attention if any adverse effect
i occurs.
:
a
NOTES TO PHYSICIAN:Treat symptoms m demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
jSUITABLE(AND UNSUITABLE) Product is non-flammable.Use media appropriate for the surrounding flre.
EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
CHEMICAL:
( SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure selfconained breathing apparatus.Do not release run off from fire control
- methods to sewer or waterways.
)
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WATER TREATMENT EXPERTISE SINCE 1904
1 FORMULA 159 www.garrattcallahan.com Page 2 of 5
I

SECTION 6-ACCIDENTAL RELEASE MEASURES
` PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
I PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution,When opening,release pressure slowly
1 through opening,
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures, Proper protective equipment should be used, refer to Section 8-exposure controls.
Small Spill: Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container P391:Collect spillage.
Large Spill: Restrict access to the area. Provide adequate protective equipment and ventilation, Stop leak if without risk. Remove chemicals
which can react with the spilled material, Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
3 the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
container and seal. P391:Collett spillage,
SECTION 7.HANDLING AND STORAGE
Z PRECAUTIONS FOR SAFE HANDLING: As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or prolonged
contact with skin or eyes,Do not Ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics while handling
this product, Avoid breathing vapors,dusts or mists generated by this product. Use in a well-ventilated location. Remove contaminated clothing
immediately.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: All employees who handle this material should be trained to handle it safely.Open containers slowly
on a stable surface. Containers of this product must be properly labeled.Storage areas of this product should be clearly identified,well-illuminated,
clear of obstruction and accessible only to trained and authorized personnel. Store containers in a cool,dry location,away from direct sunlight,at
_ temperatures between 50°F(10°C)- IWF(37°C). Keep container tightly closed when not in use.P405:Store locked up.Refer to Section 10 for
j incompatibilities,
j SECTION B-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation,Eyewash/safety,shower station is recommended to be
available near where this product is used/stored.
j EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
I ............................................................
CHEMICAL NAME CA S# ACGIH TLV OSHA PE L OTHER
TWA STEL TWA
SODIUM BISULHTE 763 1-90-5 5 mg/m3 HE NE NIA
POTASSIUM SULFITE 101f7-38-1 NE NE NE N/A
NE Not Established
INGESTION: Do not eat,drink,smoke,or apply cosmetics when handling this product Wash all exposed skin/hair
thoroughly after handling.
RESPIRATORY PROTECTION: P261:Avoid breathing dust/fume/gas/misyvapours/spray.P271:Use only outdoors or in a well-ventilated area
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purt/ying
I respirators with dust/mist/fumehpray,filters are recommended if operations may produce dusts,mists or
sprays from this product with concentrations at or above levels posted above.
i EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.Wear chemical safety goggles or safety glasses with
3 side shields.A face shield may also be necessary for splash protection.
SKIN PROTECTION: Wash all exposed skin/hair thoroughly after handling.Wear protective gloves/protective clothingleye '..
protection/face protection.Use chemically-resistant gloves and skin protection,when handling this product. '..
Use body protection appropriate for task(eg.,lab coat,overalls). '..
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[ WATER TREATMENT EXPERTISE SINCE 1904
( FORMULA 159 www.garrattcallahaacom Page 3 of 5

SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear light yellow/water white VAPOR PRESSURE,mm Hg Q 20OC: Not established
ODOR: Slight VAPOR DENSITY(Air=1): Not established
! ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water=l): 1.3- 1.4
1
pH: 6.0-8.5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not established PARTITION COEFFICIENT(nottanol/water): Not established
BOILING POINT: Not established AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Non-Bammable DECOMPOSITION TEMPERATURE: Not esmblished
j EVAPORATION RATE(n-BaAc=1): Not established VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%): Not established
i
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
I STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
- HAZARDOUS REACTIONS: None known.
= CONDITIONS TO AVOID: Normally stable.Sulfur dioxide also will evolve slowly at ambient temperatures.
INCOMPATIBLE MATERIALS: Oxidizers:may cause strong exothermic reactions.Acids:releases sulfur dioxide gas which is toxic,corrosive,
and potentially deadly.
HAZARDOUS
DECOMPOSITION PRODUCTS: Sulfur dioxide.
1
'. SECTION I I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS: No dam available for this product
LIKELY ROUTES OF EXPOSURE: Skin,and eye contacc,inhalation.
RELATED SYMPTOMS: Skin,eye and respiratory Irritation.May be toxic if swallowed.
DELAYED/IMMEDIATE/CHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye and respiratory irritation.May be toxic if swallowed.
- NUMERICAL MEASURES OF
TOXICITY: Not established for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
SECTION 12•ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
- Fish:96 hr.LC50,Fathead Minnow,883.9 mg/L
Daphnia:48 hr,LC50,Daphola Dubia,S07.7 mg/L '..
PERSISTANCE AND DEGRADABILITY;No dam available for this produm
_ BIOLOGICAL ACCUMULATION POTENTIAL No data available for this product '..
MOBILITY IN SOIL:No dam available for this protium '..
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No dam available for this product.
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for this product
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: P501:Dispose of contentdconminer in accordance with local/regional/national/international regulations.Thoroughly drainfempty
comainers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.
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? WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 159 wvvw.garrattcallahzn.com Page 4 of 5
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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: NOT REGULATED
IMDGAMO: NOT REGULATED
IATA/ICAO: NOT REGULATED
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
j annex 11 marpol 73/18 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
I SECTION I5- REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are sob)ect to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
j ReauthoNaation Act.
CHEMICAL NAME
SODIUM BISULFITE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302A)-YES
SARA 313(40 CFR 372,65)-NO
POTASSIUM SULFITE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
t SARA 313(40 CFR 37Z65)-NO
3
I
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quanddes for the components of this product
The default Federal SDS submission and inventory requirement filing threshold of MON flis(4,540 kg)therefore applies,per 40 CFR 370,20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):Sodium bisulfite(7631-90-5):50001bs(2268 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
j SARA Title 3111312,Hasard Category: Acute Health: NO; Chronic:NO; Fire:NO; Reactive:NO; Pressure:NO
California safe drinking water and toxic enforcement act(proposition 65): No component of this product is on the Proposition 65
List
International Regulations
CANADIAN REGULATIONS;
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
' listing
i
CANADIAN WHMIS CLASSIFICATION:Not Classified
7
SECTION 16-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 7/29/2015 Supercedes: 12/23/2014
FORMULA 159 has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OUV3-A6E0470 when prepared in either
the Addison,Illinois or Burlingame,California facilities
S
I Although reasonable ore has been taken in the meparadon of the document,we extend no vnrranrles and mike an representations as to the accuracy or
? completeness of the information contained hereln,and assume ao responsibility regarding the suitability of this information for the user's intended purpose or for the '..
consequences of its use. 6ch indiNdual xhould make a determinarion az to the suirabiliry of the information for their partimWr purpose
WATER TREATMENT EXPERTISE SINCE 1904 �u
FORMULA 159 wwwgarmttcallahan.com Page 5 of 5

I
Gan AL
C LLAHAN SAFETY DATA SHEET
i
SECTION I - PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 314-T
PRODUCT USE: BIOCIDE
i
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
I
sections of this SDS.
UN NUMBER: UN3085
PROPER SHIPPING NAME: UN3085,OXIDIZING SOLID,CORROSIVE,N.O.S.(CONTAINS
BROMO-CHLORO-DIMETHYLHYDANTOIN),5.1(8), PG 111,
7 MARINE POLLUTANT
MANUFACTURER'S NAME: Garrett-Callahan Company
ADDRESS: 501ngold Road, Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
- Outside North America:+I.703-527.3887
BUSINESS PHONE; Product Information:6SO-697-5811
SDS NUMBER: SD3314
' DATE OF REVISION: 3/29/2016
i
'. SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER c�
HAZARD STATEMENT:
- H272:May Intensify fire;oxidizer. 3
H302:Harmful if swallowed. 4
- H314:Causes severe skin bums and eye damage. IA
i 1-1317:May cause an allergic reaction.
H400:Very toxic to aquatic life. I
PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:If medical advice is needed,have product container or label at hand. 14-4
PI02:Keep out of reach of children.
PI03:Read label before use.
P210:Keep away from heat/sparks/open famesthot surfaces-No smoking.
P220:Keep/Store away from clothing/combustible materials.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
{ P264:Wash all exposed skinmair thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
i P272:Contaminated work clothing should not be allowed out of the workplace.
f P273:Avoid release to the environment
P280:Wear protective gloves/protective clothing/eye protection/face protection.
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Hazard Sale
I 0-Minimal
1-Slght
2=Moderate HEALTH INSTABILITY
3 5enoes
—PH)iBICISIdffA'2`A1EES(YPLI;g !,.' 4 Chr r �X
�=cmmritnamra
3
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T wvaw.garmucallahan.com Page I of 6

1
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SECTION 3- COMPOSITION/INFORMATION ON INGREpIENTS
i
Hazardous Ing ed'e is CA F ICI 169
j I-BROMO-3-CHLORO-5,5-DIMETHYL- 16079.88-2 240-230.0 NE 96
i HYDANTOIN
i
SECTION 4-FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SOS to the health professional with the
individual P310:immediately call a POISON CENTER or doctor/physician.
DANGER:May intensify fire;oxidizer.Harmful if swallowed.Causes severe skin burns and eye damage.May cause an allergic reaction.Very toxic to
aquatic life.Also refer to Section I I for symptoms,effects,and likely routes of exposure for this product,
i
i TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE:P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.P302+P352:IF ON SKIN:
Wash with soap and water.Minimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not m contaminate the
i
eyes.P362+P364:Take off contaminated clothing and wash before reuse.P332+p313:If skin irritation occurs:Get medical advicelattention.
t
EYE EXPOSURE:P305+p351+p338:IF IN EYES:Rinse cautiously with water for seven)minutes.Remove conga lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes.P310.Immediately call a POISON CENTER or doaodphysicon.
i
? INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310;Immediately
call a POISON CENTER or doctor/physiom.
3
INGESTION:P301+p330+p331:IF SWALLOWED:Rime mouth.Do NOT induce vomiting.P301+p312:IF SWALLOWED:Call a POISON CENTER
or doctor/physician if you feel unwell.Never Induce vomiting or give diluents(milk or water)by mouth to someone who Is unconscious,having
convulsions,or unable to swallow.P310:Immediately call a POISON CENTER or doctodphysician.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders.as well as conditions involving the"Target
jOrgans"may be aggravated by prolonged exposures to this product Exposed Individual must seek immediate medical attention if any adverse effect
ocwrs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) P370+P378:In case of fire:Use water spray,fog or mist Alcohol-resistant foam.DO NOT use
EXTINGUISHING MATERIALS: CO2 or dry chemicals,
3
SPECIFIC HAZARDS ARISING FROM THE Oxidizing material.Toxic gases/vapours/fumes of,Bromine.Chlorine.Oxides of the following
CHEMICAL: substances:Carbon.Nitrogen.Thermal decomposition or combustion products may include the
following substances:Toxic gases or vapours.
I SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure sel&contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.Move containers from fire area If it can be done without risk.
[[3
Control run-off water by containing and keeping it out of sewers and watercourses.
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T www.garrattcaliahan.com Page 2 of 6
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SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING:Any container expansion or rounding Indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
I
SPILL AND LEAK RESPONSE:Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P271 Avoid release to the environment.
3 Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.P391:Collett spillage.
Large Spill:Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
can react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed.Avoid generation of dust Avoid contact with water.Ensure that exposure to product is not at a
concentration exceeding regulatory limits. Decontaminate the area thoroughly.Decontaminate all response equipment with soapy water before
returning to service.Place all spill residue in a suitable container and seal.P391 o Collect spillage.
j SECTION T-HANDLING AND STORAGE
i
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be rained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product.Do not eat.drink smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dus"or mists generated by this product.Use in a well-ventilated location. Remove
1 contaminated clothing immediately,Use only as directed.Refer to Section 8 for exposure controls.P210:Keep away from headsparks/open
flames/hot surfaces-No smoking.P220:Keep/Store may from clothing/combustible materials.P273:Avoid release to the environment P280:Wear
I protective gloves/protective clothing/eye protection/face protection.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,well-illuminated,dear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool,well
ventilated,dry location,may tom direct sunlight,may from Incompatible materials at temperatures between WE(WC)-100°F(37*C). Keep
t container tightly closed when not in use.Avoid spilling,skin and eye contact Avoid contact with acids,moisture or combustible materials.Keep
away from heat,sparks and open flames.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.
j
SECTION B-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CAS ACGIH TLY 05HA PEL OTHER
3 TWA STEL TWA
I-BROMO-3-CHLORO-5,5- 16079-884 NE HE NE N/A
DIMETHYL-HYDANTOIN
1
3 NE=Not Established
I INGESTION: P264:Wash all exposed skin/haft thoroughly after handling.P270:Do not eat,drink or smoke when using this
I
i product.
RESPIRATORY PROTECTION: P260.Do not breathe dusoYume/gadouso'vapoursfspray.Use only outdoors or in awell-ventilated area
I Maintain airborne contaminant concentrations below guidelines listed above.if applicable. Air-purifying
respirators with dust/mistffumelspray(leers are recommended if operadons may produce dusts,mina or
j sprays from this product with concentrations at or above levels posted above. '..
EYE PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.P280:Wear protective gloves/protective '..
3 clothing/eye protection/face protection.Wear chemical safety goggles or safety glasses with side shields.A face '..
shield may also be necessary for splash protection. '..
SKIN PROTECTION: P264:Wash all exposed skinihair thoroughly after handling.P272:Contaminated work clothing should not be
allowed out of the workplace.P280:Wear protective gloves/protective clothingleye protection/face
protection.Use chemically-resbUnt gloves and skin protection,when handling this product Use body
protection appropriate for Usk(e.g.,lab coat.overalls).
3
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T www.garrattcallahan.com Page 3 of 6

SECTION 9•PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: White to off-white tablet VAPOR PRESSURE: 0.0038 Pa @-C
ODOR: Slight halogen VAPOR DENSITY(Air=1): Not applicable
ODOR THRESHOLD: Not established RELATIVE DENSITY@20-C(water=1): Not applicable
pH: 3.5@0.1 S%(diluted solution) SOLUBILITY IN WATER: 0.15@°C slightly soluble
in water
MELTING/FREEZING POINT: 145-I60°C PARTITION COEFFICIENT(o-octanollwater):log Pow.0.35
BOILING POINT: Not applicable AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Not established DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n-BuAc=I): Not applicable VISCOSITY: Not applicable
FLAMMABILITY(SOLID/GAS): Not established VOLATILE ORGANIC COMPOUNDS(%): None
FLAMMABLE LIMITS(in air by volume,%): Not established
SECTION 10•STABILITY AND REACTIVITY
_ REACTIVITY: Material has oxidizing properties.
STABILITY: Stable at normal ambient temperatures.Avoid the following conditions:Moisture.
3 POSSIBILITY OF
HAZARDOUS REACTIONS: Will not polymerize.
i CONDITIONS TO AVOID: Generates toxic gas in contact with acid.Avoid heat flames and other sources of Ignition.Avoid excessive
heat for prolonged periods of time.
INCOMPATIBLE MATERIALS: Strong acids.Strong alkalis.Strong reducing agents.
I HAZARDOUS
DECOMPOSITION PRODUCTS: Toxic gases/vapors/fumes of Hydrogen bromide(HBr).Bromine.Hyrrogen chloride(MCI).Chlorine.Oxides
I of the following substances:Carbon.Nitrogen.
SECTION I I -TOXICOLOGICAL INFORMATION
_ TOXICOLOGICAL EFFECTS: There is no evidence that the product can cause cancer.
LIKELY ROUTES OF EXPOSURE: Skin and/or eye contact Ingestion.Inhalation.
RELATED SYMPTOMS: Skin and/or eye comam Ingestion.Inhalation.
DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURES:
Inhalation:May cause respiratory system irritation.
( Ingestion:Harmful if swallowed.
Skin contact Causes bums.May cause sensitisation by skin contact.
Eye contact.Causes bums.
j Acute and chronic health hazards:This product is corrosive.
NUMERICAL MEASURES OF TOXICITY:
Oral:LD50:rats,578 mg/kg
Dermal:LD50:rabbits,2000mg/kg
Ames test.Negative
CARCINOGENICITY: Nona of the components of this product are listed by the NTP.IARC.or regulated by OSHA as carcinogens.
SECTION I2-ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
Acute toxicity-fish:
LC50,96 hours:0.87 nigh,Onchorhyachus mykiss(Rainbow trout)
LC50,96 hours:0.87 mg/I,Fish
Acute toxicity-aquatic:
EC50,48 hours:0.46 mg/I,Daphnia magma '..
ECS0.48 hours,0.46 mg/I,Daphnia magma '..
Acute toxicity.
LC50,96 hours,640 American oyster mgfl
PERSISTENCE AND DEGRADABILITY:Halogens will dissociate in water leaving DMH.DMH is really biodegradable in a CO2 Evolution study
j and passes the 10-day window criteria.DMH has also been shown to be rapidly degraded in a water/sediment system. '..
BIOLOGICAL ACCUMULATION POTENTIAL:Material is expected to present a low bioaccumulation potential
MOBILITY IN SOIL:No dam available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):The product conmins a substance which is very toxic to aquatic organisms.
WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 314-T www.garrattcallahan.com Page 4 of 6

Environmental Hazards:
This pesticide is toxic to fish and aquatic organisms.Do not discharge effluent containing this product into lakes,streams,ponds,estuaries,oceans or
f other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System(NPDES)permit and the permitting
authority has been notified in writing prior to discharge.Do not discharge effluent containing this product into sewer systems without previously
notifying the local sewage treatment plant authority.For guidance,contact your State Water Board or Regional Office of the EPA.
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for the components of this
product.
SECTION 13 -DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly draiNempty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.PS01:
Dispose of contenimsontainer in accordance with fowl/regional/national/intemauonal regulations.
I SECTION I4-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
i DOT: UN3085,OXIDIZING SOLID,CORROSIVE,N.O.S. z^�`
(CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN),
5.1(8),PG III,MARINE POLLUTANT y v�
i Emergency Response Guidebook,Guide No.: 140
Passenger Aircraft Qry:25 kg $`#
Cargo Aircraft Qry: 100 kg v x'
IMDG/IMO: UN3085,OXIDIZING SOLID.CORROSIVE,N.O.S.
(CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN).
5.1(8),PG III,MARINE POLLUTANT
3 IATA/ICAO: UN3085,OXIDIZING SOLID,CORROSIVE.N.O.S.
z (CONTAINS BROMO-CHLORO-DIMETHYLHYDANTOIN),
S.1(8).PG Ill.MARINE POLLUTANT
t
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): Yes
TRANSPORT IN BULK(according to
i
annex 11 marpol 73178 and the IBC code): Notapplicable
7 SPECIAL PRECAUTIONS FOR USER: None known
3 PRODUCT REQUIRES OXIDIZER,CORROSIVE AND MARINE POLLUTANT LABEL
SECTION 1 S-REGULATORY INFORMATION
I United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components ofthis product are subject to the '..
j reporting as listed below,requirements of Secdons 302,304,and 313 of Title ofthe Superfund Amendments and '..
Reauthorization Act
CHEMICAL NAME
' I-BROMO-3-CHLORO-S,S-DIMETHYL- SARA 302 M0CFR 355,APPENDIX A)-NO '..
HYDANTOIN SARA 304(40CFR TABLE 302.4)-NO
SARA 313 M0CFR 372,65)-NO '..
t
U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quanddes for the components of this product The
default Federal SDS submission and inventory requirement filing threshold of 10,000liies(4,540 kg)therefore applies,per 40 CFR 370.20,
U.S.CERCLA REPORTABLE QUANTITY(RQ):Not listed.
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
SARA TITLE 311/312 HAZARD CATEGORY:ACUTE:YES CHRONIC: NO FIRE: YES REACTIVITY:YES PRESSURE:NO
j California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): No component of this product is on the Proposition 65
list
WATER TREATMENT EXPERTISE SINCE 1904
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5
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- FIFRA Information:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under
federal pesticide law.These requirements differ from the classification criteria and hazard information required for safety data sheets,and for
workplace labels of non-pesticide chemicals.Following is the hazard information as required on the pesticide label:
DANGER.CORROSIVE.Causes irreversible eye damage and skin bums.Harmful if swallowed.Irritating to nose and throat.Do not get in eyes,on
skin,or on clothing.Wear protective eyewear(goggles,face shield,or safety glasses).Wear protective clothing and rubber gloves when handling
this product Avoid breathing dust and fumes.Wash thoroughly with soap and water after handling.Remove contaminated clothing and wash
clothing before reuse.
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
isdr&
f
CANADIAN WHMIS CLASSIFICATION: Not listed,
1 SECTION 16.OTHER INFORMATION
t
PREPARED BY: GARRATT CALLAHAN
DATE OF REviSION: 329/2016 Supercedes: 6/11/2015
Formula 314-T is EPA-registered;with EPA Reg.No.83451-4-8540.Refer to the approved label for details,
Formula 314-T is registered with the NSF to the NSF Intemational Registration Guidelines for Proprietary Substances and Nonfood Compounds
for category codes G5,G7;with NSF Reg.No. 113139.
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Akhough tea..We are has been taken in the prepaaUon of this document we extend no warranties and make no represeradons as to the accuracy or
completeness of the information conalned herein,and assume no responsibility regarding the xuiabiliry of this information for the user N s intended purpose or for e
comocuencesof itsuse. Each individual should make.determination as to the suitability of the information for their particular purpose.
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PGarratt
CA L LA H A N SAFETY DATA SHEET
SECTION 1 -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 315
PRODUCT USE: BIOCIDE
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
` sections of this SDS.
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UN NUMBER: 3265
' PROPER SHIPPING NAME: CORROSIVE LIQUID,ACIDIC,ORGANIC, N.O.S.(S-CHLORO-2-
METHYL-44SOTHIAZOUN-3-ONE),8,PG II
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MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road, Burlingame,CA 94010.2206
EMERGENCY PHONE: North America CHEMTREC: 1.800-424-9300
I Outside North American+l-703-5274887
BUSINESS PHONE: Product Information:650-697-581 I
SOS NUMBER: SD3315
DATE OF REVISION: 2/112016
SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
? GHS HAZARD STATEMENT:
f H302:Harmful if swallowed. 4
H315:Causes skin irritation. 2
H320:Causes eye irritation. 28
H335:May cause respiratory irritation. 3
GHS PREVENTATIVE STATEMENTS:
PI01:If medical advice is needed,have product container or label at hand.
P 102:Keep out of reach of children.
j P103:Read label before use.
f P261:Avoid breathing dust/fume/gas/mist[vapourslspray.
{ P264:Wash all exposed skin/hair thoroughly after handling.
P270:Do not eat drink or smoke when using this product
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothingleye protectlonfface protection.
3
1 NFPA RATING
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HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Harard scale
0.M nimal
f I=Sl ght
2 Modatete HEALTH �,'r;, INSTABILITY
B{YEy+Y3yCrj ', 4—Severe
x—Chronc hazard
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I FORMULA 315 caw v.garmttcailahan.com Page I of 6

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SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous ingred'ents CC EC# ICSC# 2L^T6
MAGNESIUM NITRATE 10377-60-3 233-826-7 1041 1-3
5-CHLORO-2�METHYL-4-ISOTHIAZOLIN-3- 26172-554 247-500-7 NA 1-2
ONE
I 2-METHYL-4-ISOTHIAZOLIN-3-ONE 2682-204 220-239-6 NA <I
i MAGNESIUM CHLORIDE 7786-30-3 232�094-6 0764 1
SECTION 4. FIRST AID MEASURES
P312:Call a POISON CENTER or doctor/physician if you feel unwell. Take copy of label and SDS to health professional with contaminated individual.
1 WARNING:This product is a non-flammable,clear yellow green liquid with a pungent odor.Harmful if swallowed,causes skin and eye irritation.
maay cause respiratory irritation.Also refer to Section I I for symptoms,effects,and likely routes of exposure for this product
TARGET ORGANS:
ACUTE irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC irritation of skin,eyes,respiratory and gastrointestinal systems,
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j SKIN EXPOSURE: P302+P352:IF ON SKIN:Wash with soap and water.Minimum flushing is for 15 minutes. P362:Take off contaminated
clothing and wash before reuse.P312:Call a POISON CENTER or doctor/physician if you feel unwell.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open eyelids. Have contaminated Individual"roll"eyes. Minimum flushing is for ISminums.P337+P313:
If eye irritation persists get medical advicefamention.
INHALATION: If vapors.trusts,or sprays generated by this product are inhaled,remove contaminated individual to fresh air. Remove or cover
gross communication to avoid exposure to rescuers.P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable
Jfor breathing.
1 INGESTION: P301+P312:IF SWALLOWED:Call a POISON CENTER or doctor/physician if you feel unwell.Do NOT induce vomiting.P330:
7 Rinse mouth.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable to
swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders.as well as conditions involving the"Target
Organs'(see Section 3,Hazard Identification)may be aggravated by prolonged overexposures to this product.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION S-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is nonflammable.Use media appropriate for the surrounding fire.
EXTINGUISHING MATERIALS:
s SPECIFIC HAZARDS ARISING FROM THE Non-Flammable Liquid.
CHEMICAL, Explosion hazards in Presence of Various Substances: Non-Explosive in presence of open flames
and sparks,or shocks.
Special Remarks on Explosion Hazards: None known
SPECIAL PROTECTIVE EQUIPMENT AND Incipient fire responders should wear eye protection. Structural firefighters must wear Self-
PRECAUTIONS FOR FIREFIGHTERS: Contained Breathing Apparatus and full protective equipment.Isolate materials not yet involved in
the fire and protect personnel.Move containers from fire area ff this can be done without risk;
jotherwise,cool with carefully applied water spay.If possible,prevent runoff water from entering
storm drains,bodies of water,or other environmentally sensitive areas.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
_ PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES,
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used, refer to Section 8-exposure controls.
Small Spill: Mop up.or absorb with an inert dry material and place in an appropriate waste disposal container. P391:Collett spillage.
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Large Spill: ResVi<t access[o the area. Provide adequate protective equipment and ventilation. Stop leak if without risk. Remove chemicals
which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is octet a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
connainerindseal. P391:Collect spillage.
SECTION 7-HANDLING AND STORAGE
j PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest.Wash thoroughly after handling this product. Do not eat,drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product Use in a welhventilated location. Remove
contaminated clothing immediately. Use only as directed.Refer to Section 8 for exposure controls.
1
j CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
identified,well-Illumimted,clear of obstruction and accessible only to trained and authorized personnel, Store containers in a clean,cool,well
ventilated, dry location,away from direct sunlight away from incompatible materials at temperatures between STF(10°C)- 100°F(37°C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling.Refer to
Section 10 for incompatibilities.P403+P233:Store in a well ventilated place.Keep container tightly closed.
SECTION B-EXPOSURE CONTROLS- PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.EyewesNsafety,shower stated is recommended to be
available near where this product is used/stored,
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CAS ACGIH TIL OSHA PEL OTHER
TWA STEL TWA
MAGNESIUM NITRATE 10377-60-3 NE NE NE NE
5-CHLORO-2-METHYL4 26172-55A NE NE NE NE
ISOTHIAZOUN-3.ONE
j 2-METHYLA-ISOTHIAZOLIN-3- 2682-204 NE NE NE NE
7 ONE
MAGNESIUM CHLORIDE 7786-30-3 NE NE NE NE
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INGESTION: P270:Do not eat,drink or smoke when using this product.
RESPIRATORY PROTECTION: P261:Avoid breathing duso'fume/gas/mist(vapours/spray.P271:Use only outdoors or in a well-ventilated area.
3 Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
Irespirators with dust nosthfume filters are recommended if operations may produce mists or sprays from this
product
EYE PROTECTION: Safety glasses or safety goggles.if splashing is anticipated,a face shield is recommended. P280:Wear
protective gloveslprotective clothingleye protecton/face protection.
SKIN PROTECTION: HAND PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective
_ gloveslprotective clothing/eye protettioNface protection.Use chemically-resinant gloves when handling this
product
j BODY PROTECTION: Use body protection appropriate for task leg.,lab coat overalls,gloves).
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear yellow/green liquid VAPOR PRESSURE,mm Hg@20OC: Not established
j ODOR: Pungent VAPOR DENSITY(An-1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20-C(watm-l): 0.95- 1.10
1 pH: 3.0-6.5 SOLUBILITY IN WATER: Complete
i MELTING/FREEZING POINT: NA PARTITION COEFFICIENT(n-octanol/water)Not established
BOILING POINT: 100°C(212°F) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT-. No:o-Bammable DECOMPOSITION TEMPERATURE: Notesrablished
7 EVAPORATION RATE(n-BuAc=1): < I VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Notapplicable VOLATILE ORGANIC COMPOUNDS(%): None
? FLAMMABLE LIMITS(in air by volume,%):Not applicable
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: See incompatible materials.
INCOMPATIBLE MATERIALS: Oxidizing agents,reducing agents,amines.meroptans.
HAZARDOUS
DECOMPOSITION PRODUCTS; Thermal decomposition may yield the following:Hydrogen chloride,oxides of sulfur and nitrogen.
1
SECTION I 1 •TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS:No data available for this product
LIKELY ROUTES OF EXPOSURE:Skin/eye contact and inhalation.The most significant routes of overexposure for this product are by
inhalation of mists or coma with skin or eyes.
RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT
AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will cause burning and irritation.Do not wear contact lenses when using this product.Ingestion will cause
gastric distress and possible depression of the central nervous system.
CHRONIC:Repeated or prolonged exposure to this product can produce target organ damage.Repeated exposure of the eyes can produce eye
irritation.Repeated skin exposure can produce local skin destruction,or dermatitis.Repeated inhalation can produce varying degrees of respiratory
Irritation or lung damage.
NUMERICAL MEASURES OF TOXICITY:
Ceriodaphnia dubia(waterfiee):48hr,LC50s:8.77 ppm
Ceriodaphnia dubia(water8ea):96hr,LCSOs:7.88 ppm
Pimephales Formulas(fathead minnow):48hr.LCS0a:9.84 ppm
Pimephales promelas(fathead minnow):96hr,LC50z:9.56 ppm
IRRITANCY OF PRODUCT: This product is very Irritating to skin,eyes and respiratory system.
j SENSITIZATION TO THE PRODUCT:This product may cause allergic skin reactions(e.g.,rashes,welts)in sensible individuals.
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CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
S
SECTION 12-ECOLOGICAL INFORMATION
3 ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
' ECOTOXICITY:Release of this product to the environment is expected to cause harm to plants and animals. If accidentally released,precautions
7 must be taken to protect the environment.
i PERSIST-NCE AND DEGRADABILITY:Material is considered biodegradeable.
BIOLOGICAL ACCUMULATION POTENTIAL:No data available for this product
MOBILITY IN SOIL No dam available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No data available for this product
li Environmental Hazards:
This pesticide is toxic to aquatic plants,fish and aquatic invertebrates.Do not discharge effluent containing this product into lakes,streams.Ponds,
estuaries,oceans,or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System(NPOES)permit
and the Permitting authority has been notified in writing prior to discharge.Do not discharge effluent containing this product to sewer systems
without previously notifying the local sewage treatment plant authority.For guidance contact your State Water Board or Regional Office of the EPA.
Do not contaminate water by cleaning of equipment or disposal of waste.Apply this pesticide only as specked on the label.
WATER TREATMENT EXPERTISE SINCE 1904
4 FORMULA 315 www.garratnallahan.com Page 4 of
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BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for the components of this
3 product.
SECTION 13-DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly dnin/empty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.P501:Dispose
of contents/container in accordance with local/regional/nationallinternatlonal regulations.
SECTION I4-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC,N.O.S.
(S-CHLORO-2-11ETHYL-4d50THIAZOLiN-3-ONE),8,PG It
Emergency Response Guidebook.Guide No.: IS3
Passenger Aircraft Qty: I L t '
Cargo Aircraft Qtr..30L
IMDGIIMO: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC.N.O.S.
(5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE),8,PG 11
IATAIICAO: UN3265,CORROSIVE LIQUID,ACIDIC,ORGANIC.N.O.S.
(5-CHLORO-2-METHYL4-ISOTHIAZOLIN-3-ONE),8,PG II
ENVIRONMENTAL HAZARDS
(i.e..MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex 11 marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
} PRODUCT REQUIRES CORROSIVE LABEL
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SECTION 15-REGULATORY INFORMATION
United States and International Regulations
3
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauth rfi ation Am
CHEMICALNAME
3 MAGNESIUM NITRATE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
? SARA 313(40 CFR 372.65)-YES
5-CHLORO-2-METHYL-4- SARA 302(40 CFR 355,Appendix A)-NO
ISOTHIAZOUN-3-ONE SARA 304(40 CFR Table 302A)-NO
I SARA 313(40 OR 37265)-NO
2-METHYL-4-ISOTHIAZOLIN-3-ONE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 37265)-NO
MAGNESIUM CHLORIDE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CPR 372.65)-NO
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3 U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
The default Federal SDS submission and inventory requirement filing threshold of 10,000Ibs(4,540 kg)therefore applies,per 40 CFR 370,20.
U.S.CERCLA REPORTABLE QUANTITY(RQ): Not listed.
TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. '..
SARA TITLE III Section 3111312 Hancod Category:Acute: YES; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO '..
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FIFRA Information '..
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under
federal pesticide law.These requirements differ from the classification criteria and harard information required for safety dam sheets,and for '..
2 workplace labels of non-pesticide chemicals.Following is the hazard information as required on the pesticide label:
WATER TREATMENT EXPERTISE SINCE 1904
( FORMULA 315 www.garrattcallahan.com Page 5 of

DANGER.CORROSIVE.Causes irreversible eye damage and skin burns.May cause allergic skin reaction.Harmful If swallowed or absorbed through
- the skin.Harmful if Inhaled.
Do not get in eyes,on skin,or on clothing.Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals.Remove
contaminated clothing and wash clothing before reuse.Mixers,loaders and others exposed to this product most wear:long-sleeved shirt and long
Paris:chemical resistant gloves such as nitrile or butyl rubber:shoes plus socks;goggles and face shield;and chemical resistant apron.Discard
clothing or other absorbent materials that have been drenched or heavily contaminated with this products concentrate.Do not reuse them.
Follow manufacturer's instructions for cleaning/maiataining PPE If no such instructions for washables exists,use detergent and hot water,Keep and
wash PPE separately from ocher laundry.Users should wash hands before eating,drinking,chewing gum,using tobacco or using the toilet.Users
should remove clothing immediately if pesticide gets inside.Then wash thoroughly and put on clean clothing.Users should remove PPE immediately
after handling this product Wash the outside of gloves before removing.As soon as possible,wash thoroughly.
California Safe Drinking Water and Toxic Enforcement Act(•reposition 65): No component of this product is on the Proposition 65
list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL Inventories or are exempt from listing.
( CANADIAN WHMIS CLASSIFICATION:Not classified.
j SECTION 16-OTHER INFORMATION
]] PREPARED BY: GARRATT CALLAHAN
- DATE OF REVISION: 2/11/2016 Supercedes: 6/16/2015
Formula 315 is EPA-registered:with EPA Reg.No.8540-23.Refer to the approved label for details.
i Although reasonable ore has been taken in the prep ixton of this document,we extend no wamntias and make no representations as to the accumq or
ompletwess of the Information mnoined herein,and assume no responsibility regarding the suitability of this information for the user's intended purpose or for the
consequences of its use. Each i MMdual should make a determimtion as w the smrebility of the information for their particular purpose.
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tGarratt
CA L LA H A N SAFETY DATA SHEET
SECTION I -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 2002
I PRODUCT USE: COOLING WATER TREATMENT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER; UNIS24
PROPER SHIPPING NAME: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
i MANUFACTURER'S NAME: Garrott-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
I
EMERGENCY PHONE: North America CHEMTREC: 1.800-424.9300
Outside North America:+1.703-527-3687
BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SD2002
DATE OF REVISION: 10/14/2015
SECTION 2.HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER q
HAZARD STATEMENT: L p(y
H302:Harmful if swallowed
3 H314:Causes severe skin burns and eye damage. IA
H335:May muse respiratory imitation. 3
PRECAUTIONARY STATEMENTS:(PREVENTION)
PI01:If medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P260:Do not breathe dust hime/gaslitht/vapours/spray.
P164:Wash all exposed skiNhair thoroughly after handling.
} P270:Do not eat drink or smoke when using this product
7 P280:Wear protective gloves/protective clothingleye protection/face protection.
3
NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
3Ax
Havrd Sale
O=Minimal
1 t 1=Slight
.c 3=Seo uzfe HEALTH INSTABILITY
NW_4 {{1/1TYf#AYrA$x(YC-€.g}4tfij Jf 4-Severe
1
OTHER
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WATER TREATMENT EXPERTISE SINCE 1904
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SECTION 3• CO MPOSITIONINFORMATION ON INGREDIENTS
Hazardous Ingredients CA S# Ems' ICS WTT%
SODIUM HYDROXIDE 1310434 215-185-5 0360 8
ACRYLIC COPOLYMER PROPRIETARY NE NE 4
SODIUM TOLYLTRIAZOLE 6466557-2 265-004-9 1091 3
PHOSPHONIC ACID DERIVATIVE PROPRIETARY NE NE 3
HEDP 2809-21-4 220-552-8 NE 2
SODIUM MOLYBDATE 7631-95-0 231-551-7 tofu I
S
SECTION 4-FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
' individual.P3 10:Immediately call a POISON CENTER or doctor/physician.
i
? DANGER:Harmful if swallowed.Causes severe skin bums and eye damage.May cause respiratory irritation.Also refer to Section I I for symptoms,
effects,and likely routes of exposure for this product.
j TARGET ORGANS:
ACUTE irritation of skin,eyes,respiratory and gannaintestinal systems.
CHRONIC irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P303+P36f+P353:IF ON SKIN(or hair):Remove/ake off immediately all contaminated clothing.Rinse skin with
water/shower.Minimum flushing time is for 15 minutes. Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:
Wash contaminated clothing before reuse.P310:Immediately call a POISON CENTER or doctor/physician.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse continuously with water for several minutes.Remove concoct lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes. P310:Immediately calla POISON CENTER or doctor/physician.
INHALATION: P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:Immediately
call a POISON CENTER or doctor/physician.
INGESTION: P301+P330+P331: IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never induce vomiting or give diWents(milk or
water)by mouth to someone who is unconscious,having convulsions,or unable to swallow.P310:Immediately call a POISON CENTER or
doctror/physician.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions Involving the"Target
Organs"may be aggravated by prolonged exposures to this produce Exposed individual must seek immediate medical attention if any adverse effect
occurs.
NOTES TO PHYSICIAN: Treat symptoms az demonstrated by s"igns and distress in the patient.
SECTIONS•FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use media appropriate for the surrounding Ore.
j EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
i CHEMICAL:
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear Polly protective clothing(chemical Impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fre control
t methods to sewer or waterways.
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WATER TREATMENT EXPERTISE SINCE 1904
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)

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j SECTION 6-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
] SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used.refer to Section 8-exposure controls.
I
! Small Spill: Mop up,or absorb with an inert dry material and place to an appropriate waste disposal container. P391:Collett spillage.
Large Spill: Restrict access to the area.Provide adequate protective equipment and ventilation. Stop leak if without risk Remove chemicals
which can react with the spilled material. Add dry men material to comaln and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas.dike If needed. Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
containerandseal. P391:Collett spillage.
i
= SECTION 7.HANDLING AND STORAGE
l
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product. Do not eat.drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product, Use in a well-ventilated location. Remove
I contaminated clothing immediately. Use only as directed.Refer to Section 8 for exposure controls.
1
- CONDITIONS FOR SAFE STORAGE: Containers of this product most be properly labeled.Storage areas of this product should be clearly
Identified,well illuminated,clear of obstruction and accessible only to trained and authorized personnel,Store containers in a clean,cool,well
ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between SO°F(10"C)- I00 F(37°C).Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist,Wash hands after handling.Refer to
Section 10 for incompatibilities.
SECTION B-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation,Eyewashlsafery shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CAS# ACGIH TLV OSHA PEL 9I}1EH
TWA STEL TWA
SODIUM HYDROXIDE 1310-73-2 NE 2 mg/m' 2 mgfm' NIOSH REL
ceiling C-2 mg/m'
ACRYLIC COPOLYMER PROPRIETARY NE NE NE NIA
SODIUM TOLYLTRIAZOLE 64665-57-2 NE NE NE N/A
PHOSPHONIC ACID PROPRIETARY NE NE NE N/A
DERIVATIVE
E
HEDP 2809-214 NE NE NE NIA
SODIUM MOLYBDATE 7631-95�0 5 mg/m' NE 5 mg/m' N/A
as soluble as soluble MO
(
? NE=Not Established
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INGESTION: P264:Wash all exposed skin/hair thoroughly after handling.P270:Do not at,drink or smoke when using this
product.
RESPIRATORY PROTECTION: P260:Do not breathe dustlfume/gas/misr/vapoursspray.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guldetmes listed above,if applicable. Air-purifying
respirators with dustlmist/fume/spray filters are recommended if operations may produce dusts,mists or
i sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skimmir thoroughly after handling.P280:Wear protective gloves/protective
clothing/eye protection/face protection.Wear chemical safety goggles or safety glasses with side shields. A
face shield may also be necessary for splash protection.
i SKIN PROTECTION: P264:Wash all exposed skiNhair thoroughly after handling,P280:Wear protective gloves/protective
clothingleye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat,overalls).
SECTION 9•PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCEand COLOR Clear dark amber liquid VAPOR PRESSURE,mm Hg@2WC: Not established
ODOR: Sweet organic VAPOR DENSITY(Air=1): Not established
3 ODORTHRESHOLD: Not established RELATIVE DENSITY@20°C(water—1): 1.12- 1.13
pH: 13.0- 14.0 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not established PARTITION COEFFICIENT(n-octanol/water)Not established
BOILING POINT: >212-F(100-C) AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(n.BuAc=1): < 1 VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not applicable VOLATILE ORGANIC COMPOUNDS(%): Not established
FLAMMABLE LIMITS(in air by volume,%): Not established
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
j HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: Freezing temperatures and incompatible materials.
° INCOMPATIBLE MATERIALS: Strong acids,reactive metals,and strong oxidizing agents.
i HAZARDOUS
DECOMPOSITION PRODUCTS: When heated to decomposition product may emit toxic fumes of oxides of carbon,nitrogen and
l phosphorous.
SECTION 11 •TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS:No data available for this product
j LIKELY ROUTES OF EXPOSURE:Skin/eye cornet and inhalation.
7 RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal Irritation.May be harmful if swallowed.
I DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT
AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will cause burning and irritation.Do not wear contact lenses when using this product Ingestion will cause
gastric distress.Inhalation of vapor,mist or dust may cause respiratory tract irritation.
CHRONIC:Repeated or prolonged exposure to this product an produce target organ damage.Repeated exposure of the eyes can produce eye
irritation.Repeated skin exposure can produce local skin destruction,or dermadds.Repeated inhalation on produce varying degrees of respiratory
irritation or lung damage.
r NUMERICAL MEASURES OF TOXICITY:Not established for this product
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
i
SECTION I2-ECOLOGICALINFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION,
ECOTOXICITY:
Ceriodaphniadubia(Wate:9ea)9&hr LCSO:22.2 ppm
Cerlodaphniadubla(Waterflea)4&hr LC50:25.5 ppm
$ Pimephales promelas(Fathead minnow)96-hr LCSO:803.7 ppm
Pimephales promelas(Fathead minnow)48-hr LCSO:851.4 plum
PERSISTENCE AND DEGRADABILITY:No data available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL No data available for this product
a
WATER TREATMENT EXPERTISE SINCE 1904
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i MOBILITY IN SOIL:No dam available for this produce
OTHER ADVERSE EFFECTS(Le,,hazardous to the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for the components of this
product.
SECTION 13 -DISPOSAL CONSIDERATIONS
I DISPOSAL: P501:Dispose of content"/container in accordance with lonVregionaVnationallintemational regulators.Rinse empty containers with
j water and use the rinse water to prepare the working solution. Refer to section 8 for exposure controls-personal protection.
j SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
i Emergency Response Guidebook Guide No.: 154
7 Passenger Aircraft Qry: IL pry dJ
s Cargo Aircraft Qty:30L t
IMDG/IMO: UNI824,SODIUM HYDROXIDE SOLUTION,8,PGII
IATAIICAO: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
annex 11 marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
PRODUCT REQUIRES CORROSIVE LABEL
1
SECTION IS-REGULATORY INFORMATION
3
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are Subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act,
CHEMICAL NAME
- SODIUM HYDROXIDE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
SARA 313(40 CFR 372.65)-NO
ACRYLIC COPOLYMER SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO '..
SARA 313(40 CFR 372,65),NO '..
- SODIUM TOLYLTRIAZOLE SARA 302(40 CFR 355,Appendix A)-NO '..
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372,65)-NO '..
i
PHOSPHONIC ACID DERIVATIVE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
HEDP SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
SODIUM MOLYBDATE SARA 302(40 CFR 355,Appendix A)-NO
t SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372,65)-NO
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U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
The default Federal SDS submission and inventory requirement fling threshold of 10,00016a(4,540 kg)therefore applies,per 40 CfR 370,20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):None.
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
1 SARA Title 311/312,Hazard Category: Acute Health: YES; Chronic:YES; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
i California Safe Drinking Water and Toxic Enforcement Act(proposition 65): No component ofthis product[son the Proposition 65
i list
International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing.
€ CANADIAN WHMIS CLASSIFICATION:A component of this product(Sodium Hydroxide,CAS# 1310.73-2)has the following WHMIS
classification of CLASS E(corrosive).
SECTION 16•OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 10/14/2015 Supercedes: 1011412013
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FORMULA 2002 has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OUV3-7E88A8A when prepared in
either the Addison,Illinois or Burlingame.California facilities.
i
Although reasomble are has been taken in the preparation of this document,we extend no warranties and make no representations as to the accuracy or
completeness of the information contained herein,and assume no responL nlity regarding the suitability of this information for the users intended purpose or for the
4 consequences of its use. Each individual should make a deremonstion as to the suitability of the information for their particular purpose.
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Garratt
Cs4 L LA A N SAFETY DATA SHEET
SECTION i -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 2002-LT
PRODUCT USE: COOLING WATER TREATMENT
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UN 1824
PROPER SHIPPING NAME: UN 1824,SODIUM HYDROXIDE SOLUTION,8, PGII
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngoid Road,Burlingame,CA 94010.2206
EMERGENCY PHONE: North Amerim CHEMTREC: 1.800-424-9300
Outside North America:[phone]
1 BUSINESS PHONE: Product Information:650-697-5811
SDS NUMBER: SD2002LT
DATE OF REVISION: 9/29/2015
j SECTION 2-HAZARDS IDENTIFICATION
SIGNAL WORD:WARNING
HAZARD STATEMENT:
H302:Harmful if swallowed. 4
H315:Causes skin irritation. 2
- H320:Causes eye irritation. 2B
H335:May muse respiratory irritation. 3
1, PRECAUTIONARY STATEMENTS:(PREVENTION)
7 PI01:If medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P261:Avoid breathing dus/f ane/gesmust/vapours/spray.
P264:Wash all exposed skirdhalr thoroughly after handling.
P270:Do not eat,drink or smoke when using this product
P271:Use only outdoors or in a well-ventilated area.
i P280:Wear protective gloves/protective clothing/eye protectioulface protection.
}
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NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Hoard Sda
0=Minimal
1 L — 1=Slight
2-Modeate
a HEALTH INSTABILITY
3=Serous
^'REATIVIT`f--FYAZARD(7t)FtA.4Ylry lt'�;. 4-Severe
a .�. ✓ *-Chroc hoard
41!
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SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous Ingredients CA S# ICSC# WT-7
SODIUM HYDROXIDE 1310J31-2 215-185-5 0360 7-10
PHOSPHONIC ACID DERIVATIVE PROPRIETARY NE NE 4-6
i ACRYLIC COPOLYMER PROPRIETARY NE NE 3-6
SODIUM TOLYLTRIAZOLE 64665-574 265-004-9 1091 2.6
HEDP 2809-214 220-552-8 NE 14
I SECTION 4- FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs. Take a copy of this SDS to the health professional with the
individual.P312:Call a POISON CENTER or doctor/physician if you feel unwell.
WARNING:May be harmful if swallowed.Causes skin and eye irritation.May cause respiratory irritation.Also refer to Section I I for symptoms,
effects.and likely routes of exposure for this product
TARGET ORGANS:
ACUTE irritation of skin,eyes,respiratory and gastrointestinal systems,
CHRONIC irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P302+P352:IF ON SKIN:Wash with soap and water,Minimum flushing time is for 15 minutes.P362+P364:Take off
contaminated clothing and wash before reuse.P332+P313:If skin irritation occurs:Get medical advice/attention.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse continuously with water for several minutes.Remove contact lenses if present and easy to
do—coronae rinsing. Use sufficient force to open the eyelids. Have the exposed individual 'roll"their eyes. Minimum flushing time is for 15
` minutes. P337+P313:If eye irritation persists get medical advice!attention.
)
INHALATION: P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P312:Call a
POISON CENTER or doctor/physician if you feel unwell.
INGESTION: P301+P312:If SWALLOWED:Call a POISON CENTER or doctor(physi<ian if you feel unwell..P330,.Rinse mouth.Never induce
vomiting or give diluents(milk or water)by mouth to someone who is unconscious,having convulsions,or unable to swallow.
- MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medical attention if any adverse effect
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occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
SECTION 5-FIRE FIGHTING MEASURES
SUITABLE(AND UNSUITABLE) Product is non-flammable.Use media appropriate for the surrounding fire.
EXTINGUISHING MATERIALS:
SPECIFIC HAZARDS ARISING FROM THE None known.
i CHEMICAL:
I SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterways.
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SECTION b-ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
jWARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening release pressure slowly
through opening.
j SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used, refer to Section 8-exposure controls.
i
Small Spill: Mop up,or absorb with an inert dry material and place In an appropriate waste disposal container. P391:Collett spillage.
Large Spill: Restrict access to the area. Provide adequate protective equipment and ventilation. Stop leak if without risk. Remove chemicals
which can react with the spilled material. Add dry inert material to contain and absorb spilled material. Prevent entry into surface waters,sewers,
basements or confined areas,dike if needed. Ensure that exposure to product is not at a concentration exceeding regulatory lhea s. Decontaminate
the area thoroughly. Decontaminate all response equipment with soapy water before returning to service. Place all spill residue in a suitable
c.maimerand seal. P391:Collett spillage.
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' SECTION 7-HANDLING AND STORAGE
t
PRECAUTIONS FOR SAFE HANDLING: Keep out of Teach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest-Wash thoroughly after handling this product Do not eat drink,smoke.or apply cosmetics
while handling this product. Avoid breathing vapors,dusts or mists generated by this product Use in a well-ventilated location. Remove
1 contaminated clothing immediately. Use only as directed.Refer to Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
Identified,well-illuminated,clear of obstruction and accessible only to trained and authorized personnel. Store containers in a clean,cool,well
ventilated, dry location,away from direct sunlight,away from incompatible materials at temperatures between WP(10"C)- 100-F(37°C). Keep
t container tightly closed when not in use.P405:Store locked up.P403+P233:Store in a well ventilated place.Keep container tightly closed.Do not
ingest Do not breathe vapor mist.Wash hands after handling.Refer to Section 10 for incompatibilities.
i
SECTION 8-EXPOSURE CONTROLS-PERSONAL PROTECTION
s VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewasldsafety shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
f CHEMICAL NAME CA S# ACGIH IL V OSHA PE L OTHER
TWA STEL TWA
j SODIUM HYDROXIDE 1310-73-2 NE 2 mg1W 2 mg/ml NIOSH REL
i ceiling C-2mg/m'
I PHOSPHONIC ACID PROPRIETARY NE NE NE N/A
DERIVATIVE
ACRYLIC COPOLYMER PROPRIETARY NE NE NE NIA
SODIUM TOLYLTRIAZOLE 64665-57-2 NE NE NE NIA
HEDP 2809-21A NE NE NE NIA
s
NE=Not Established
3
j INGESTION: P264:Wash all exposed skinihair thoroughly after handling.P270:Do not eat,drink or smoke when using this '..
19 product.
RESPIRATORY PROTECTION: P261:Avoid breathing dustlfumelgas/mist/vapours/spray.P271:Use only outdoors or in a well-ventlated area
Maintain airlwme contaminant concentrations below guidelines listed above,if applicable. Air-purifying '..
respirators with dust/mist/f n eispray liters are recommended if operations may produce dusts,miss or
sprays from this product with concentrations at or above levels posted above.
t EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.Wear chemical safety goggles or safety glasses with
{ side shields. A face shield may also be necessary for splash protection. '..
$ SKIN PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective gloves/protective
ciothingleye protecdon/face protection.Use chemically-resi cant gloves and skin protection,when handling
this product.Use body protection appropriate for task(e.g..lab coat overalls).
WATER TREATMENT EXPERTISE SINCE 1904
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear dark amber liquid VAPOR PRESSURE,mm Hg@WC: Not established
ODOR: Sweet organic VAPOR DENSITY(Air-- Not established
ODORTHRESHOLD: Not established RELATIVE DENSITY@20°C(water=l): 1.12- 1.14
PH: >12.5 SOLUBILITY IN WATER: Complete
' MELTINGIFREEZING POINT: Not established PARTITION COEFFICIENT(moctmolMater)Not established
i
BOILING POINT: >212°F(100°C) AUTOIGNITION TEMPERATURE: Not established
FLASHPOINT: Non-flammable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION RATE(neuAc=1): Not established VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not established VOLATILE ORGANIC COMPOUNDS(%): Not established
! FLAMMABLE LIMITS(in air by volume,%): Not established
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Product is notreactive under standard ambient temperature and pressure.
# STABILITY: Stable under normal condition of use and storage.
'1 POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: Freezing temperatures and incompatible materials.
INCOMPATIBLE MATERIALS: Strong acids,reactive metals,and strong oxidizing agents.
HAZARDOUS
DECOMPOSITION PRODUCTS: Thermal decomposition product may yield oxides of carbon,nitrogen and phosphorous.
SECTION 1 I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS:No data available for this product
` LIKELY ROUTES OF EXPOSURE:Skinleye contact and inhalation.
f RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
3
DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT
AND LONG TERM EXPOSURES:
ACUTE:Contact with skin and eyes will use burning and irritation.Do not wear contact lenses when using this product.Ingestion will cause
gamic distress.Inhalation of vapor,mist or dust may cause respiratory,tract irritation.
CHRONIC:Repeated or prolonged exposure to this product can produce target organ damage.Repeated exposure of the eyes can produce eye
irritation.Repeated skin exposure can produce local skin destruction,or dermatitis.Repeated inhalation an produce varying degrees of respiratory
irritation or lung damage.
NUMERICAL MEASURES OF TOXICITY:
- LC50,waterflea(ceriodaphnia magna),48 hr:3299.8 mg/1.
LC50,waterflea(ceriodaphnia magna),96 hr, 1894.6 mgll.
LC50,fathead minnow(pimephales promales),48 he 1621.0 mg/l.
LCSO,fathead minnow(pimephales promales),96 hr: 1593.2 mg/l.
Carorogeniciry:None of the components of the product are listed by the NTP.IARC,or regulated by OSHA as carcinogens.
SECTION 12-ECOLOGICAL INFORMATION
7 ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
i ECOTOXICITY:Dam not available for this product
PERSISTENCE AND DEGRADABILITY:No data available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No dam available for this product
7 MOBILITY IN SOIL:No dam available for this product
OTHER ADVERSE EFFECTS(i.e.,hazardous W the ozone layer):No dam available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biologiml Exposure Indices(BEls)have not been determined for the components of this
product.
SECTION I3-DISPOSAL CONSIDERATIONS
DISPOSAL: P501:Dispose of contenWcoaramer in accordance with local/regionaVnational/inmrnatiowl regulations.Rinse empty containers with
water and use the rinse water to prepare the working solution. Refer to section 8 for exposure controls-personal protection.
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SECTION 14-TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
t
DOT: UNI824,SODIUM HYDROXIDE SOLUTION,B,PGII
Emergency Response Guidebook Guide No.: 154
Passenger Aircraft Qty: IL
t Cargo Aircraft Cry:30L <
IMDG/IMO: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII
IATA#CAO: UN 1824,SODIUM HYDROXIDE SOLUTION,8,PGII +
7 ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): None known.
` TRANSPORT IN BULK(according to
{ annex 11 marpol 73178 and the ISC code): Not applicable.
i
i SPECIAL PRECAUTIONS FOR USER: None knovm.
3
PRODUCT REQUIRES CORROSIVE LABEL
1 SECTION IS• REGULATORY INFORMATION
United States and International Regulations
l United States Regulations: U.S.SABA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
- Reauthorization Acts
CHEMICAL NAME
SODIUM HYDROXIDE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
SARA 313(40 CFR 37265)-NO
PHOSPHONIC ACID DERIVATIVE SARA 302(40 CFR 3SS,Appendix A)-NO
SARA 304(40 CFR Table 302A)-NO
I SARA 313(40 CFR 372.65)-NO
3 ACRYLIC COPOLYMER SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
SODIUM TOLYLTRIAZOLE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
HEDP SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 37265)-NO
# U.S.Regulations
- U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product The
default Federal SDS submission and inventory requirement filing threshold of 10,000 Ibs(4,540 kg)therefore applies,per 40 CFR 370.20.
1 SARA 3111312:Acute:Yes Chronic.No Fire:No Pressure:No Reactivity:NO
U.S.CERCLA REPORTABLE QUANTITY(RQ);Sodium Hydroxide(CAS#1310-73-2): 1000 Ina(454 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
California Sate Drinking Water and Toxic Enforcement Act(proposition 65): No component of this product is on the Proposition 65
'{
IISL
_ International Regulations
CANADIAN REGULATIONS:
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing
( CANADIAN WHMIS CLASSIFICATION:A componentof this product(Sodium Hydroxide,CAS# 1310-73-2)has a WHMIS classification of E '..
(corrosive).
e
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PREPARED BY: GARRATT CALLAHAN
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- DATE OF REVISION: 9/29/2015 Supercedes: 10/9/2013
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Alt en li remomble are has been taken in the preparation of this daumenn vre exwnd no warranties and make as,rep,toreauons as to the at..,or
completeness of the Information conained herein,and assume no responsibility regarding the solubility of this information for the users intended purpose or for the
1 consequences of its use. Each iMiNduil xhould make a decermihwoion as w Ne rviubiliry of We information for their partimWr purpose.
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Garratt
G A L L A H A N SAFETY DATA SHEET
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SECTION i -PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 3091
PRODUCT USE: BIOCIDE
RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: 1791
PROPER SHIPPING NAME: HYPOCHLORITE SOLUTION,8,PG III
J MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 50 Ingold Road,Burlingame,CA 94010-2206
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
Outside North America:+1.703-S27.3887
BUSINESS PHONE: Product Information:650-697-5811
SOS NUMBER: SD3091
DATE OF REVISION: 2/16/2016
SECTION 2-HAZARDS IDENTIFICATION
1 SIGNAL WORD:DANGER
HAZARD STATEMENT:
H290:May be corrosive to metals. 1
1­1314:Causes severe skin bums and eye damage. IA
j 1­1318:Causes serious eye damage. I
H335:May muse respiratory irritation. 3
- PRECAUTIONARY STATEMENTS:(PREVENTION)
j P101:if medical advice Is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P234:Keep only in original container.
P260:Do not breathe dust/fume/gas/mist/vapoum/spay.
P264:Wash all exposed skirdhair thoroughly after handling.
P271:Use only outdoors or in a well-venulated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
Do not eat,drink or smoke when using this product.
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NFPA RATING
i HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
Hazard 5.1.
{ - 0=Minimal
I-S ght
2-Moderate HEALTH INSTABILITY
P44YS1 T oT'sRff CO ,� a-5e.ere
<=cnree�c Hamra
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OTHER
WATER TREATMENT EXPERTISE SINCE 1904
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7 SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
I
i Hazardous Ingredients CA S# EC# IC§C# `ffi_N
f SODIUM HYPOCHLORITE 7681-52-9 231-668-3 1119 10- 15.5
SODIUM HYDROXIDE 1310-73-2 215-18" 0360 1 -5
SECTION 4-FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SIDS to the health professional with the
individual.P310.Immediately call a POISON CENTER or doctor!physician.
7 DANGER: May be corrosive to metals.Causes severe skin bums and eye damage.Causes serious eye damage.May cause respiratory irritation.Also
refer to Section I I for symptoms,effects,and likely routes of exposure for this product
t TARGET ORGANS:
ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:irritation of skin,eyes,respiratory and gastrointestinal systems.
SKIN EXPOSURE: P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.Rinse skin with
water/shower.Minimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:
I Wash contaminated clothing before reuse.P310.Immediately call a POISON CENTER or doctor/physician.
EYE EXPOSURE: P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do—continue rinsing. Use sufficient force to open the eyelids. Have the exposed individual"roll"their eyes. Minimum flushing time is for 15
minutes. P310:Immediately call a POISON CENTER or doctor/physician.
INHALATION: P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:immediately
call a POISON CENTER or doctor/physician.
INGESTION: P301+P330+P331:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.Never Induce vomiting or give diluents(milk or water)
by mouth to someone who is unconscious,having convulsions,or unable to swallow.P310:Immediately calla POISON CENTER or doctor/physician.
j MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this produR Exposed Individual must seek immediate medical attention if any adverse effect
occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient
i SECTION 5-FIRE FIGHTING MEASURES
i
SUITABLE(AND UNSUITABLE) Water fog,foam,dry chemical powder and carbon dioxide(CO2).Use media appropriate to the
EXTINGUISHING MATERIALS: surrounding fire such as water fog or fine spray,alcohol foams,carbon dioxide.Use water with
z caution.Contact with water will generate considerable heat Do not use water jet as an
i extinguisher,as this will spread the fire.Do not use dry chemical extinguishing agents.Malefic
anhydride may react with the basic sodium compounds.Use chemical extinguishing agents with
caution.Some chemical extinguishing agents may react with this material
SPECIFIC HAZARDS ARISING FROM THE Not considered flammable.Vapors are heavier than air and may spread along floors.Contact with
( CHEMICAL: most metals will generate flammable hydrogen gas.Contact with water will generate considerable
4 heat,Reacts violenttly with a wide variety of organic and inorganic chemicals including alcohol,
j carbides,chlorates,picrates,nitrates and metals.Harmful fumes,gases or vapors may evolve on
burning.Use standard firefighting procedures and consider the hamrds of other Involved materials.
Vapors are heavier than air and may spread along floors Hazardous combustion products includes
j hydrogen gas,hydrogen chloride,chlorine,oxygen and sodium oxides.
i SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure self-contained breathing apparatus.Do not release run off from fire control
methods to sewer or waterway.
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SECTION 6-ACCIDENT AL RELEASE MEASURES
PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
WARNING: Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening,
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by appropriately trained personnel using pre-pl
anned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.P391:Collect spillage.P390:Absorb spillage to
prevent material-damage.
Small Spill: Mop up.or absorb with an inett dry material and place in an appropriate waste disposal container,
Large Spill: Restrict access to the area.Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
can react with the spilled material.Add dry inett material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
j basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
container and seal.
SECTION T-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely,Open containers slowly on a stable surface, As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics
while handling this product Avoid breathing vapors,dusts or mists generated by this product.Use in a well-ventilated Location. Remove
contaminated clothing immediately.Use only as directed.Refer an Section 8 for exposure controls.
CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
i idenmed,well-illuminated,clear of obstruction and accessible only to trained and authorized personnel.Store containers in a clean,cool.well
ventilated,dry location,away from direct sunlight,away from incompatible materials at temperatures between 509F(1(yC)- 100'F(3rC). Keep
7 container tightly closed when not in use.P405:Store locked up.Do not ingest Do not breathe vapor mist Wash hands after handling. Refer to
Section 10 for lncompadbilidw.P234:Keep only in original container.P403+P233:Store In a well ventilated place.Keep container tightly closed.
P406:Store in a corrosive resistant container with a resistant inner liner.
s SECTION B-EXPOSURE CONTROLS-PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safety shower station is recommended to be
available near where this product is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
......................................................... R
CHEMICAL NAME CA StE ACGIH OT H E M OSHA PEL
TWA STEL TWA
SODIUM HYPOCHLORITE 7681-52-9 NE NE NE WA
( SODIUM HYDROXIDE 1310-73-2 NE C 2 mgyW 2 raglan' NIOSH
3 C 2 mg/m'REL
)
i ME Not Established
j INGESTION: P264:Wash all exposed skin/hair thoroughly after handling.Do not eat,drink or smoke when using this
1 product.
RESPIRATORY PROTECTION: P260:Do not breathe dust/fume/gas/misWapoure/sproy.P271:Use only outdoors or in a well-ventilated area.
Maintain airbome contaminant concentrations below guidelines listed above,if applicable, Air-purifying
respirators with dustfmist/fume spray filters are recommended if operations may produce dusts,mists or '..
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264:Wash all exposed skin/hair thoroughly after handling.P280:Wear protective glovea/protective
clothing/eye protectionlface protection.Wear chemical safety goggles or safety glasses with side shields.A face '..
shield may also be necessary for splash protection.
SKIN PROTECTION: P264:Wash all exposed skinthair thoroughly after handling.P280:Wear protective gloves/protective
clothingleye protection/face protection.Use chemically-resistant gloves and skin protection,when handling
this product Use body protection appropriate for task(e.g.,lab coat,overalls).
WATER TREATMENT EXPERTISE SINCE 1904
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SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
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APPEARANCE and COLOR: Greenish-yellow to yellow liquid VAPOR PRESSURE.mm Hg@20°C: 12 mm Hg
ODOR: Pungent chlorine odor VAPOR DENSITY(Air-1): Not established
ODOR THRESHOLD: Not established RELATIVE DENSITY@20°C(water-1): 1.16- 1.20
pH: 11 - 13 SOLUBILITY IN WATER: Soluble
MELTING/FREEZING POINT: I.52°F(-13.VC) PARTITION COEFFICIENT(n-octanolMater)Not established
4 BOILING POINT: >I04°F(>40°C) AUTOIGNITION TEMPERATURE: Not applicable
FLASHPOINT: Not applicable DECOMPOSITION TEMPERATURE: Not established
EVAPORATION KATE(n-BuAc=1): Not established VISCOSITY: Not established
FLAMMABILITY(SOLIDIGAS): Notapplicable VOLATILE ORGANIC COMPOUNDS(%): Not established
FLAMMABLE LIMITS(In air by volume,%): Not applicable
SECTION 10-STABILITY AND REACTIVITY
REACTIVITY: Contact with most metals will generate flammable hydrogen gas.Contact with water will generate
j considerable heat Reacts with amines and and ammonia compounds to form explosively unstable compounds.
May be corrosive to metal May be corrosive to:Aluminium,stainless steel,carbon steel,copper,bronze.
STABILITY: Stable under normal condition of use and storage.
POSSIBILITY OF
[ HAZARDOUS REACTIONS: Reacts vigorously or violently with many organic and inorganic chemicals such as:acids.acrolem,acrylonitrile,
chlorinated hydrocarbons(e.g. 1,2 dichloroe hylene),chlorine dioxide,malelc anhydride,nitroethane,
nitroparaRns,2-nitrophenol,mtropropane,phosphorus,potassium persulfate,and tetrahydrofumn(containing
_ peroxides).
CONDITIONS TO AVOID: Direct sources of heat.Avoid high temperatures.Direct sunlight Avoid contact with incompatible materials.
_ Do not use In areas without adequate ventilation.Do not allow evaporation to dryness.
INCOMPATIBLE MATERIALS: Mmik.Strong oxidizing agents.Acids.Amines.Ammonia.Reducing agents.Nitrites.Organic compounds.
a HAZARDOUS
DECOMPOSITION PRODUCTS: in the event of fire the following can be released:Chlorine.Sodium chlorine.
SECTION I I -TOXICOLOGICAL INFORMATION
TOXICOLOGICAL EFFECTS:No data available for this product
LIKELY ROUTES OF EXPOSURE:
Inhalation:Prolonged inhalation may be harmful.May cause irritation to the respiratory system.May cause severe irritation to the nose,throat,and
j respiratory tract.
i Skin Contact.Causes severe skin bums.
Eye Comm s,Causes serious eye damage.
1 Ingestion:Causes digestive tract burns.Ingestion may cause severe irritation of the mouth,the esophagus and the gastrointestinal tract
RELATED SYMPTOMS:Skin,eye,respiratory and gastrointestinal Irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHRONIC EFFECTS FROM SHORT AND LONG TERM EXPOSURES:
Corrosive to the eyes and may cause severe damage including blindness.Symptoms may include stinging,tearing,redness,wellness,and blurred
vision.Direct skin contact may cause corrosive skin bums,deep ulcerations and possibly permanent scarring.Can cause severe respiratory irritation.
Symptoms may include coughing,choking and wheezing.Inhalation could result in pulmonary edema(fluid accumulation).Symptoms of pulmonary
edema(chest pain,shortness of breath)may be delayed.May cause severe irritation and corrosive damage in the mouth,throat and stomach.
Symptoms may include abdominal pain,vomitting,bums,perforations,bleeding and eventually death.
NUMERICAL MEASURES OF TOXICITY:
{ Acute:
Dermal LD50.Rabbit>10,000 mgtkg
Inhalation:LCSO,Rat>5.25 mg/I/4h '..
Oal:LD50,Rat.89I0 mg/kg
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens. '..
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SECTION I2-ECOLOGICAL INFORMATION
1 ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
3
ECOTOXICITY:
j Crustacea:EC50,Water flea(Ceriodaphnla dubia),40 mgll,48 hours
Sodium Hypochlorim:LC50,Western mosquitofish(Gambusia a8inis). 125 mg11,96 hours
Crustacea:EC50,Water flea(Daphnia magna),0.169 mg(1,48 hours
Fish:LC50,gluegili(Lepomis macrochtrus),0.58 mg/l,96 hours
7 PERSISTENCE AND DEGRADABILITY:Biodegradation is not applicable to inorganic substances.
BIOLOGICAL ACCUMULATION POTENTIAL:No accumula0on in living organisms expected due to high solubility and dissociation
properties.
MOBILITY IN SOIL:High water solubility indicates a high mobility in soil.
OTHER ADVERSE EFFECTS(i.e.,hazardous to the ozone layer):No other adverse environmental effects(e.g.ozone depletion,
j photochemical ozone creation potential,endocrine disruption,global worming potential)are expected from this component).
Environmental Hazards:
This product is toxic to fish and aquaoc organisms.Do not discharge effluent containing this product into lakes,streams,ponds,estuaries,oceans,or
other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System,(NPDES),permit and the permitting
authority has been notified in writing prior to discharge,Do not discharge effluent containing this product to sewer systems without previously
nodfying the local sewage treatment plant authority.For guidance contact your State Water Board or Regional Office of the EPA.
{
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEls)have not been determined for the components of this
product,
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SECTION 13•DISPOSAL CONSIDERATIONS
DISPOSAL: Thoroughly drainfempty containers and offer for recycling.Refer to Section 8 for exposure controls-personal protection.P501:
Dispose of contentalcontainer in accordance with IocailreglonaltnationaVinternadonal regulations.
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SECTION 14-TRANSPORTATION INFORMATION
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PROPER SHIPPING NAME
DOT: (RQ:100)UN 1791,HYPOCHLORITE SOLUTIONS,8,PGIII
Emergency Response Guidebook,Guide No.: 154
Passenger Aircraft Qty:St.
Cargo Aircraft Qty.60L <
3 IMDG/IMO: (RQ:100)UN 1791,HYPOCHLORITE SOLUTIONS,8,PGIII
IATAIICAO: (RQ:100)UN 1791,HYPOCHLORFTE SOLUTIONS,8,PGIII +
ENVIRONMENTAL HAZARDS
(i.e.,MARINE POLLUTANT): Yes.
TRANSPORT IN BULK(according to
annex 11 marpol 73178 and the IBC code): Not applicable.
SPECIAL PRECAUTIONS FOR USER: None known.
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PRODUCT REQUIRES CORROSIVE AND MARINE POLLUTION LABEL
SECTION IS-REGULATORY INFORMATION
United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Tide of the Superfund Amendments and
Reauthorization Act
CHEMICAL NAME
SODIUM HYPOCHLORITE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302.4)-YES
' SARA 313(40 CFR 372.65)-NO
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SODIUM HYDROXIDE SARA 302(40 CFR 355,Appendix A)-NO
SARA 304(40 CFR Table 302A)-YES
SARA 313(40 CFR 372,65)-NO
WATER TREATMENT EXPERTISE SINCE 1904
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U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this
product. The default Federal SIDS submission and inventory requirement filing threshold of 10,000 Ibs(4,540 kg)therefore applies,
per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):Sodium Hypochlorite(CAS#7681.52.9): 100 Ibs(45.4 kg);Sodium Hydroxide
(CAS# 1310-73-2): 1000 Ibs(454 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory. '
( SARA Title 3111312,Hazard Category: Acute Health: YES; Chronic:NO; Fire:NO; Reactive;NO; Sudden Release of Pressure:NO
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FIFRA Information:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law.These requirements differ from the classification criteria and hazard information required
for safety data sheets,and for workplace labels of non-pesticide chemicals.Following is the hazard information as required on the
j pesticide label:
DANGER.Corrosive.Causes irreversible eye damage or skin burns.Harmful if swallowed or absorbed through skin. Do not get in
eyes,on skin or clothing.Avoid breathing spray mist Wear goggles,or face shield.Wear protective clothing and rubber gloves.
i Wash thoroughly with soap and water after handling and before eating,drinking,chewing gum,using tobacco or using the toilet.
Remove contaminated clothing and wash clothing before reuse.
California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): No component of this product is on the
Proposition 65 list,
International Regulations
CANADIAN REGULATIONS-.
CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from listing
_ CANADIAN WHMIS CLASSIFICATION:Components of this product has a WHMIS classification of.Sodium Hydroxide(CAS# 1310-73-2):E;
Sodium Hypochlorite(CAS#7681-52-9):E.
SECTIQNI6-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 2/16/2016 Supercedes: 6/10/2015
3 Formula 3091 is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds for
category codes 3D.BI,92,D I,D2,G4,G7,GX,Q4;with NSF Reg.No. 140845.
` Formula 3091 Is registered with the NSF to the Nationally Recognized Health Effects Standard(ANSI 60)for chemicals which are used to treat
drinking water;with NSF DCC#DA05595.
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Although reasonable are has been taken in the preparation of this document we extend no wnrranues and make no representations as to the accumcy or
completeness of the information comai d herein,and assume no responsib;lity regarding she suitability of this information for the user's intended purpose or for the
comequences of its use. Each iMMdual should make a determination as to the sutability of the information for their particular purpose.
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GA L L A H A N SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION
PRODUCT NAME: FORMULA 48
j PRODUCT USE: CONDENSATE CORRSION INHIBITOR
j RESTRICTIONS ON USE: Refer to label,available technical information,and other appropriate
sections of this SDS.
UN NUMBER: UN 2735
PROPER SHIPPING NAME: AMINES,LIQUID,CORROSIVE,N.O.S, (CONTAINS
CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL),8,PGII
MANUFACTURER'S NAME: Garratt-Callahan Company
ADDRESS: 501ngold Road,Burlingame,CA 94010-2206
i
EMERGENCY PHONE: North America:CHEMTREC: 1.800-424.9300
� Outside North American+1-703.527.3887
j BUSINESS PHONE: Product Information:650-697-5811
i
SDS NUMBER: SD4048
DATE OF REVISION: 8/18/2015
SECTION 2.HAZARDS IDENTIFICATION
SIGNAL WORD:DANGER
S
HAZARD STATEMENT:
Lp u
( H302:Harmful if swallowed. 4
H314:Causes severe skin bums and eye damage. IA
H332:Harmful if Inhaled. 4
PRECAUTIONARY STATEMENTS:(PREVENTION)
P101:1f medical advice is needed,have product container or label at hand.
P102:Keep out of reach of children.
P103:Read label before use.
P260:Do not breathe dusUfume/gas/mistNapours/spray.
P264:Wash all exposed skin/hair thoroughly after handling.
1`270:Do not eat,drink or smoke when using this product.
I P271:Use only outdoors or in a mil-ventilated area.
P280:Wear protective gloves/protective clothingleye protection/face protection.
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NFPA RATING
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM FLAMMABILITY
1 Had Sale
0=Minimal
1=Slight
2=Modearo HEALTH INSTABILITY
-
ETyCTIV1TYlA.YAi?(P4G*.) ! ;-i 4-Severe
f
'=Chr..K hazard
S
OTHER
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SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS
H do i d'e a CA ECC# ICSC# WT_Y:
i
j DIETHYLAMINO- 100-37-8 202-845-2 0257 30-35
j ETHANOL
CYCLOHEXYLAMINE 108-91-8 203-629.0 0245 8- 12
d
SECTION 4.FIRST AID MEASURES
Exposed individuals must be taken for medical attention if any adverse effect occurs.Take a copy of this SDS to the health professional with the
individual.P310:Immediately call a POISON CENTER or doctor/physician.
DANGER:Harmful if swallowed.Causes severe skin bums and eye damage.Harmful if inhaled.Also refer to Section I I for symptoms,effects,and
likely routes of exposure for this product
TARGET ORGANS:
S ACUTE:irritation of skin,eyes,respiratory and gastrointestinal systems.
CHRONIC:h—ation of skin,eyes,respiatory,kidneys and gastrointestinal systems.
SKIN EXPOSURE:P303+P361+P353:IF ON SKIN(or hair):Remove/take off immediately all contaminated clothing.Rinse skin with water/shower.
Minimum flushing time is for 15 minutes.Remove exposed or contaminated clothing,taking care not to contaminate the eyes. P363:Wash
contaminated clothing before reuse.The exposed individual must seek medical attention if any adverse effect occurs.
EYE EXPOSURE:P305+P351+P338:IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses if present and easy to
do-continue rinsing. Use sufficient force to open the eyelids. Have the exposed Individual"roll'their eyes. Minimum flushing time is for 15
minutes. The exposed individual must seek immediate medical attention if adverse effect occurs.
INHALATION:P304+P340:IF INHALED:Remove victim to fresh air and keep at rest in a position comfortable for breathing.P310:immediately
- call a POISON CENTER or doctor/physician.
i INGESTION:P301+P330+P331:IF SWALLOWED:Rinse mouth.Do NOT induce vomiting.P301+P312:IF SWALLOWED:Call a POISON
CENTER or doctor/physician if you feel unwell.Never induce vomiting or give diluents(milk or water)by mouth to someone who is unconscious,
having conwlslons,or unable to swallow.
- MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin and respiratory disorders,as well as conditions involving the"Target
Organs"may be aggravated by prolonged exposures to this product Exposed individual must seek immediate medial attention if any adverse effect
occurs.
NOTES TO PHYSICIAN: Treat symptoms as demonstrated by signs and distress in the patient.
SECTION S-FIRE FIGHTING MEASURES
i
i SUITABLE(AND UNSUITABLE) Product is non-flammable.Use extinguishing measures that are appropriate to Iasi circumstances
EXTINGUISHING MATERIALS: and the surrounding environment
SPECIFIC HAZARDS ARISING FROM THE Non-Flammable liquid.Explosion hazards in Presence of Various Substances:Non-Explosive in
CHEMICAL: presence of open flames and sparks,of shocks.
SPECIAL PROTECTIVE EQUIPMENT AND Firefighters should wear fully protective clothing(chemical impermeable,fully encapsulated suit)
PRECAUTIONS FOR FIREFIGHTERS: and positive pressure selkonamed breathing apparatus.Do not release run off from fire control
3 methods to sewer or waterways.
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SECTION 6-ACCIDENTAL RELEASE MEASURES
j PERSONAL PRECAUTIONS,PROTECTIVE EQUIPMENT,ENVIRONMENTAL PRECAUTIONS AND EMERGENCY
PROCEDURES.
I WARNING:Any container expansion or rounding indicates pressure build-up. Use extreme caution.When opening,release pressure slowly
through opening.
i
SPILL AND LEAK RESPONSE:Uncontrolled releares should be responded to by appropriately trained personnel using pre-planned
procedures.Proper protective equipment should be used,refer to Section 8-exposure controls.
Small Spill:Mop up,or absorb with an inert dry material and place in an appropriate waste disposal container.P391;Collect spillage.
Large Spill:Restrict access to the area Provide adequate protective equipment and ventilation.Stop leak if without risk.Remove chemicals which
an react with the spilled material.Add dry inert material to contain and absorb spilled material.Prevent entry into surface waters,sewers,
j basements or confined areas,dike if needed.Ensure that exposure to product is not at a concentration exceeding regulatory limits. Decontaminate
} the area thoroughly.Decontaminate all response equipment with soapy water before returning to service.Place all spill residue in a suitable
' container and seal.P391:Collect spillage.
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SECTION 7-HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Keep out of reach of children.All employees who handle this material should be trained to handle
it safely.Open containers slowly on a stable surface. As with all chemicals,avoid getting this product ON YOU or IN YOU.Avoid direct or
prolonged contact with skin or eyes.Do not ingest.Wash thoroughly after handling this product.Do not eat.drink,smoke,or apply cosmetics
( while handling this product Avoid breathing vapors,dusts or mists generated by this product.Use in a web-ventilated location. Remove
( contaminated clothing immediately.Use only as directed.Refer to Section 8 for exposure controls.
1
e CONDITIONS FOR SAFE STORAGE: Containers of this product must be properly labeled.Storage areas of this product should be clearly
`s identified,well-illuminated.clear of obstruction and accessible only to trained and authorized personnel,Store containers in a dean,cool,well
_ ventilated,dry location,away from direct sunlight,away from Incompatible materials at temperatures between S0"F(WC)- 10T°F(37°C). Keep
container tightly closed when not in use.P405:Store locked up.Do not ingest.Do not breathe vapor mist Wash hands after handling.Refer to
j Section 10 for incompatibilities.
j SECTION 8-EXPOSURE CONTROLS-PERSONAL PROTECTION
3 VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation.Eyewash/safery shower station is recommended to be
available near where this product Is used/stored.
EXPOSURE LIMITS/GUIDELINES: EXPOSURE LIMITS IN AIR
............................................................
CHEMICAL NAME CC $ ACGIH TLV OSHA PEL gig
TWA STEL TWA
{ DIETHYLAMINO. 100-37-8 2 ppm(skin) NE 10 ppm or TWA NIOSH REL
ETHANOL 50 mg/m'(skin) 10 ppm or 40 mg/m'
CYCLOHEXYLAMINE I08-91-8 10 ppm NE NE NIOSH
10 ppm
z
1 NE=Not Established
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3 INGESTION: P264:Wash all exposed skinihair thoroughly after handling.P270:Do not eat,drink or smoke when using this
product.
RESPIRATORY PROTECTION: P260:Do not breathe dustfumefgas/mist/vapours/spray.P271:Use only outdoors or in a well-ventilated area.
Maintain airborne contaminant concentrations below guidelines listed above,if applicable. Air-purifying
respirators with duathustlfume/sprxy fliers are recommended if operations may produce dusts,mists or
sprays from this product with concentrations at or above levels posted above.
EYE PROTECTION: P264;Wash all exposed skin/hair thoroughly after handling.P200:Wear protective gloves/protective
clothing/eye protection/face protection.Wear chemical safety goggles or safety glasses with side shields.A face
shield may also be necessary for splash protection.
SKIN PROTECTION: P264:Wash all exposed skiNhair thoroughly after handling.P280:Wear protective gloves/protective '..
clothingleye protectionists protection.Use chemically-resistant gloves and skin protection,when handling '..
this product.Use body protection appropriate for task(e.g.,lab coat,overalls). '..
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 48 www.garrattwllahan.com Page 3 of 6

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SECTION 4-PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE and COLOR: Clear water white liquid VAPOR PRESSURE.mm Hg @ 209C: Not Applicable
ODOR: Ammonia VAPOR DENSITY(Air=1): Not Applicable
} ODOR THRESHOLD: Not established RELATIVE DENSITY@209C(water=1): 0,95- 1.0
pH: 12.0- 13,5 SOLUBILITY IN WATER: Complete
MELTING/FREEZING POINT: Not applicable PARTITION COEFFICIENT(n-ocumoltwater): Not established
BOILING POINT: 2089F AUTOIGNITION TEMPERATURE: NDt Applicable
FLASHPOINT. Non-flammable DECOMPOSITION TEMPERATURE: Notestabiished
EVAPORATION RATE(n-BuAc=1): Not Applicable VISCOSITY: Not established
FLAMMABILITY(SOLID/GAS): Not Applicable VOLATILE ORGANIC COMPOUNDS(%):Not established
FLAMMABLE LIMITS(in air by volume,%):Not Applicable
j SECTION I0-STABILITY AND REACTIVITY
f
REACTIVITY: Product is not reactive under standard ambient temperature and pressure.
STABILITY: Stable under normal condition of use and storage.
3 POSSIBILITY OF
HAZARDOUS REACTIONS: None known.
CONDITIONS TO AVOID: See Incompatible materials.
i INCOMPATIBLE MATERIALS: Acids,oxidizing agents,halogenated compounds.
HAZARDOUS
! DECOMPOSITION PRODUCTS: Ammonia,oxides of nitrogen.
SECTION i 1 -TOXICOLOGICAL INFORMATION
3 TOXICOLOGICAL EFFECTS: CYCLOHEXYLAMINE:
Ord:LD50,Rat, I I mg/kg
Dermal:LDSO.Rabbiq 4500 mg/kg
DIETHYLAMINOETHANOL:
Oral:LDSO, 130D mg/kg
Dermal:L350, 1220 mVkg
LIKELY ROUTES OF EXPOSURE: Skin/eye contact and inhalation.
_ RELATED SYMPTOMS: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
DELAYED/IMMEDIATE/CHRONIC
EFFECTS FROM SHORT AND
LONG TERM EXPOSURES: Skin,eye,respiratory and gastrointestinal irritation.May be harmful if swallowed.
j NUMERICAL MEASURES OF
TOXICITY: Not established for this product.
CARCINOGENICITY: None of the components of this product are listed by the NTP,IARC,or regulated by OSHA as carcinogens.
1 SECTION 12-"ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ECOTOXICITY:
Fish:96 Hr,LCSO Flathead minnow,824.69 mg1L
jAlgae:No dam available
S Daphnia:48 Hr,EC50,Daphnia dubia,522.67 ppm
PERSISTENCE AND DEGRADABILITY:No data available for this product.
BIOLOGICAL ACCUMULATION POTENTIAL:No dam available for this product
MOBILITY IN SOIL:No data available for this product
OTHER ADVERSE EFFECTS(Le,,hazardous to the ozone layer):No data available for this product
BIOLOGICAL EXPOSURE INDICES: Currently,Biological Exposure Indices(BEis)have not been determined for this product
t
SECTION 13-DISPOSAL CONSIDERATIONS
l DISPOSAL: P501:Dispose of contents/comainer in accordance with local/regiomitnationalMternadonai regulations.Rinse empty containers with '..
water and use the rinse water to prepare the working solution. Refer to Section 8 for exposure controls-personal protection. '..
f
WATER TREATMENT EXPERTISE SINCE 1904 �J
FORMULA 48 www.garmttcallahan.com Page 4 of 6

SECTION 14•TRANSPORTATION INFORMATION
PROPER SHIPPING NAME
DOT: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
(CONTAINS CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL)8,PGII
Emergency Response Guidebook,Guide No.: 153
Passenger Aircraft Qty: I L <
Cargo Aircraft Qty:30L
IMDG/IMO: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
(CONTAINS CYCLOHEXYLAMINE AND OIEfHYLAMINOETHANOL)8,PGII
IATAIICAO: UN2735,AMINES,LIQUID,CORROSIVE,N.O.S.
(CONTAINS CYCLOHEXYLAMINE AND DIETHYLAMINOETHANOL)8,PGII
I
� ENVIRONMENTAL HAZARDS
?_ (Le.,MARINE POLLUTANT): None known.
TRANSPORT IN BULK(according to
j annex 11 marpol 73178 and the IRC code): Not applicable.
3 SPECIAL PRECAUTIONS FOR USER: None known.
PRODUCT REQUIRES CORROSIVE LABEL
SECTION IS-REGULATORY INFORMATION
i United States and International Regulations
United States Regulations: U.S.SARA REPORTING REQUIREMENTS: The components of this product are subject to the
reporting as listed below,requirements of Sections 302,304,and 313 of Title of the Superfund Amendments and
Reauthorization Act:
t CHEMICAL NAME
DIETHYLAMINO- SARA 302(40 CFR 355,Appendix A)-NO
ETHANOL SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
CYCLOHEXYLAMINE SARA 302(40 CFR 355,Appendix A)-YES
SARA 304(40 CFR Table 302.4)-NO
SARA 313(40 CFR 372.65)-NO
s
1 U.S.Regulations
U.S.SARA THRESHOLD PLANNING QUANTITY:There are no specific Threshold Planning Quantities for the components of this product
3 The default Federal SDS submission and inventory requirement filing threshold of 10,00 lbs(4,S40 kg)therefore applies,per 40 CFR 370.20.
U.S.CERCLA REPORTABLE QUANTITY(RQ):Cyclohexylamine(CAS#108-9"): 10,000 Its(4540 kg).
U.S.TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
i SARA Title 3111312,Hazard Category: Acute Health: YES; Chronic:NO; Fire:NO; Reactive:NO; Sudden Release of Pressure:NO
t California Safe Drinking Water and Toxic Enforcement Act(proposition 65): No component of this product is on the Proposition
65 list
F International Regulations
CANADIAN REGULATIONS:
{ CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL or NDSL Inventories or are exempt from
1 isting
CANADIAN WHMIS CLASSIFICATION:
Cydohexylamine(CAS# 108-91-8)is classified by WHMIS as B2,DI B,D2B,E:
Diethylaminoethanol(CAS# 100-37-8)is classfied by WHMIS as B3.D 18,E.
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WATER TREATMENT EXPERTISE SINCE 1904
FORMULA 48 www.garrattcallahan.com Page S of 6

SECTION I6-OTHER INFORMATION
PREPARED BY: GARRATT CALLAHAN
DATE OF REVISION: 8/18/2015 Supercedes: 8/1/2014
Formula 48 Is registered with the NSF to the NSF International Registration Guidelines for Proprietary Substances and Nonfood Compounds for
category codes G6,with NSF Reg.No.045983,
FORMULA 48 has been certified by the Orthodox Union as Kosher Pareve under the UK ID number of OUV3-FB I BDOB when prepared in either
the Addison.Illinois or Burlingame,California facilities.
Although reasomble care has been taken in the preparation of Mis document we extend re,warranties and make no representations to to the accuracy or
completeness of the information conmined herein,and assume no responsibility regarding the suitability of this information for the user's intended purpose or for the
7 ronse9uences of its use. Eacb individual should make a determination as no the suitability of the information for their particular purpose.
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WATER TREATMENT EXPERTISE SINCE 1904
f FORMULA 48 www.garrattcallahan.com Page 6 of '..

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j ATTACHMENT
jCalculation of Flow Rates
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sCalculation of Hominy Creek Flow Rate
Given: 7Q10 = 21 cubic feet per second (cfs)
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Calculate Hominy Creek flow rate in terms of gallons of water per day
Calculation:
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21 ft3/s X 7.48 gaUft3 X 60 s/min X 1440 min/d = 13,572,654 gal/d [13.57 MGD]
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'E
'i ATTACHMENT D
Discharge Monitoring Report
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Low&Better,Inc.—Wastewater Discharge Permit
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EFFLUENT
1
NPDES PERMIT NU. 500000 DISCHARGE NO._001_MONTH_June YEAR_2013_
FACILITY NAME Boner Inc. CLASS_COUNTY Buncombe
CERTIFIED LABORATORY_Pace Analytical Labs CERTIFICATION NO_40
OPERATOR IN RESPONSIBLE C14ARGE(ORC) GRADE N/A_CERTIFICATION NO._N/A
PERSON(S)COLLECTING SAMPLES-p=Dan Much-Pisgah Enuummenlsl Services ORCPHONE
CRECK ROX IF ORC HAS CRANGED L.l NO FLOW/DISCHARGE FROM SITE* X
1
Mail ORIGINAL and ONE COPY to:
ATTN:CENTRALFILES x
DIVISION OF WATER QUALITY ( NA R O PE TOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER EY THIS SIGNATURE,I CERTIFY THAT THIS REPORT IS
RALEIGH, NC 27690-1617 ACCURATE AND COMPLETE TO THE DF%P OF 11Y KNOWLEDGE.
50050 00010 00010 00010 00208 1 00335 1 004H 00552
c FLOW
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12 N R0763 23 N/A N/A 10.2 424 7A 44.8
fmno ROME
NEKS
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22
NINE
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AVERAGE 0.0763 23 N/M N/M <0,2 424 7.4 44.8
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'1 MINmIUM 0.0563 23 N/M NM <0.2 424 7.4 44.8
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munlyQ4mit N/A WA N/A N/A R017 N/A 6-9 20
DWQForm MR-1A(11/04) ',.

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ATTACHMENT E
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Wastewater Disposal Cost Calculations
'.€ • Pump and Ship to Waste Disposal Treatment Plant
•Evaporator
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Low&Bonag Inc.—Wastewater Discharge Permit
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Cost of Operating an Evaporator for 12,000 gallons of Cooling Tower Water Per Day
1 Assume:
Wastewater containing biocides is discharged from four Cooling Towers, two Air Handlers or Washers, and
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some water from the DowTherm system: Total= 12,000 gallons per day.
Calculations:
I 12,000 gal H2O/d x 8496.53 kilojoules/gal H2O x 0.0002778 kWh/l kilojoule x $0.10/kWh—
$2,832/d x 360 d/yr=$1,019,520/y r
12,000 gal H2O/d x 8,092 Btu/gal H2O x 0.000293 kWh/t Btu x$0.10/kWh=
$2,845/d x 360 d/yr=$1,024,252/yr [This equation is a verification of calculation methodology.]
This is the cost for only the processes that contain biocides!
' 88Unle:
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Discharges from four Cooling Towers,two Air Handlers or Washers, and some water from the Dow rherm
system total 12,000 gallons per day;which contain biocides,pins other non-contact or once-through cooling
water: Total 24,369 to 34, 581 gallons per day.
i Calculations:
3
24,368 gal H2O/d x 8496.53 kilojoules/gal H2O x 0.0002778 kWh/1 kilojoule x $0.10/kWh=
$5,752/d x 360 d/yr=$2,070,600/yr
2 34,581 gal H2O/d x 8496.53 kilojoules/gal H2O x 0.0002778 kWh/I kilojoule x $0.10/kWh—
$8,162/d x 360 d/yr=$2,938,420/yi
This is the cost for processes that contain biocides AND other cooling water sources!
Daniel J. March
Pisgah Environmental Services, LLC
j June 23, 2017
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Low&Bonar,Ina—Wastewater Discharge Permit

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Cost of Pumping and Shipping 12,000 gallons of Cooling Tower Water Per Day to a Disposal Facility
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' Assume;
Wastewater containing biocides is discharged from four Cooling Towers, two Air Handlers or Washers, and
some water from the DowTherm system:Total= 12,000 gallons per day.
Calculations:
I
A. Panning
3 12,000 gal H20/d x $0.t/gal= $1,200/d (x 360 d/yr=$43,200/yr)
B. Truck Rental+Mileage+Driver
1 Truck Daily Rental or Use Fee= $5001d
Truck Mileage= $1/mi x200 miles/d= $200/d
j Fuel Surcharge=$0.20/mi x 200 miles/d= $40/d
Truck Driver Rate= $65/hr x 8 hr/d = 520/d
TOTAL = $1,260/d (x 360 d/yr=$378,000/yr)
C. Disposal
12,000 gal H2O/d x$0.95/gal H2O= $1 1,400/d (x 360 d/yr=$2,592,000/yr)
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( D. Total Daily Cost
$1,200+$1,260+$11,400= $13,860/d (x 360 d/yr $4,989,600/yr)
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E. Total Cost for 24,368 gal/d or 34,581 gal/d
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This cost ranges from 2.031 to 2.882 times the disposal cost for 12,000 gallons per day plus the fixed costs of
i Pumping and Trucking.
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g ATTACHMENT
\ MetropolitanSewerage n
jNon-Contact Wastewater_«
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) Low a_.Jac.—Wastewater Discharge Permit

1 a'232017 Moline Teat Mail-Lov&Baer
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Virgi iaTedi lnvenl MOFurutn Daniel March <damarch@ vteclu>
i Low & Bonar
2 messages
Daniel March <[e-mail]> Fit, Jun 23, 2017 at 1:54 PM
To: [e-mail], "Bergeron, Shannon"<[e-mail]>
Mr.Payne/Ms. Bergeron:
My client,Low&Bonar in Enka,has a wastewater discharge permit with MSD. We recently renewed that permitwith the
help of Ms.Bergeron.
Low&Boner is exploring the feasibility ofsending all its wastewater to MSD. Thus,the average non-exempt daily flow
s would likely exceed 25,000 gallons per day.
Would you please help me with a couple questions?
i
' i.It it possible MSD could take an additional 15,000 gallons per dayfrom Low&Bonar? Could Low&Bonarsendupte
7 5o,000 gallons per day?
2.What are the costs of a Significant Industrial User permit?
• Application Fee
• Annual Fee
• Wastewater Treatment Base Fee
• Wastewater Treatment Surcharge Fee(s)
Thank you for your help,
a
Dan March
7
Pisgah Environmental Services, LLC
9 1Plecovale Avenue
7 Asheville, NC 28804
plsgah-air@vtedu-Email
ttwntpisgairalccom-Website
828468-3335� Cell
828-255-1092 - Fax
Bergeron, Shannon <sbergeron@msdb ,org> Fri, Jun 23, 2017 at 2:44 PM
To: Daniel March<[e-mail]>, "Payne, Monty" <[e-mail]>
Dan,
MSD Does not accept rion-contact cooling water per section 5.02.20 of the SUO,and defined in section 1.03.41&
1,03.78 of the SUO.
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Thankyou,
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' Sharman
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J M¢s/Imai.grope.com/mai(WNRi=2&ik=a59eWbBtlBRjsver=r,Z9WGMmGjQen.&Ncw=pf8searclKiMza81h=15�N644ec1af>c61a8siml=15ctl616dci13c3atl&si.,, 112

6=017 uagroa Te h Mail-Lm 8Bm r
Shannon M. Bergeron
Industrial Pretreatment Coordinator
MSD Buncombe County
2028 Riverside Drive
Asheville, NC 28804
Office: [phone]
Cell: [phone]
Fax: [phone]
[e-mail]
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i From: Daniel March [mailto:[e-mail]]
J Sent: Friday,June 23, 20171:54 PM
To: Payne,Monty; Bergeron,Shannon
Subject: Low&Bonar
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Mlpsl/mail.google.canhnal/WO'Ae=28ik=a59e07L2tle&jsver=rZ9otGMmGjO.ai.Bvier-p85eard>=iNnc8tlr=1C>�849eclaec87a3sim1=15cd616dc113c3a08si... 22

i
Sewer Use Ordinance Metropolitan Sewerage District of Buncombe County, North Carolina
(Feb 3,2012)
j Section 5.02 Specific Prohibited Wastes
No user shall discharge or deposit any of the following materials,waste materials,waste gases,or liquids into any
sanitary sewer forming a part of the MSD Sewerage System:
5.02.20 Any unpolluted wastewater as defined in Subsection 1.03.78 except as specifically permitted by the General
Manager.
i Section 1.03 Definitions
The following words,terms and phrases,wherever used in this Ordinance,shall have the meanings respectively ascribed
to them in this section unless the context plainly indicates otherwise or that a more restricted or extended meaning is
I
intended.
S 1.03.41 Non-contact cooling water: Water used for cooling which does not come into direct contact with any raw
material,intermediate product,waste product,or finished product.
1.03.78 Unpolluted Wastewater: Any wastewater,which is substantially free of pollutants and is discharged from the
following:
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3i A.Rain downspouts and drains,or;
B.Footing drains,or;
C. Storm Drains,or,
D.Cooling Water systems,or;
i E.Aquifer restoration or well development activities.
7
Unpolluted Wastewater shall contain, by definition,none of the following-
A.BOD in excess of 10 mg/L,or;
B. Total Suspended Solids in excess of 10 mg/L,or;
C.Free or emulsified greases or oils,or;
D.Acids or alkalis,or;
E. Phenols or other substances imparting taste or odor to Receiving Stream,or;
i F.Toxic or poisonous substances,or,
G.Noxious or odorous gases,or,
R.Temperature which exceeds 660C(151 OF)at its introduction into a sewer or which exceeds 400C U 04°F)at its
introduction into a receiving stream.
1.Unpolluted wastewater shall also mean any wastewaters judged by DENR to be admissible to Watercourses under the
jurisdiction of DENR and in accordance with the standards of water quality established by DENR for the particular
watercourse into which such unpolluted wastewater is to be discharged.
littp:lftvww.msdbe.ol-p;'policies policyordinance.pllp
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Low&Bonar,Inc. Wastewater Discharge Permit
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ATTACHMENT G
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Wastewater Permit Application Notice of Intent—
I • 2002
• 2007
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Low&Bonar,Inc.—Wastewater Discharge Permit

RIMA
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jNCDENR FEB 2 8 2007
North Carolina Department of Environment and N to ai R sources
Division of Water Oust,, WATER QUALITY SECTION
pip q OFFICE
Michael F.Easley,Governor t re ty
NOTICE OF RENEWAL INTENT �-
3
Application for renewal of existing coverage under General Permit NCG300000
Existing Certificate of Coverage (CoC): NCG500 (po8
j (Please print or type)
1) Mailing address of facility owner/operator:
Company Name Cq/ Bomb liiC• -
Owner Name srREM`( A/AUER.-r
Street Address 13oi SAND HtLL &'b.
city E'A1k A state Al C ZIPal?
Code ;07 z
Telephone Number FAW 6(0S• 5'0$9 Fax: 46 S-- $-oo 2—
Email address d&ttis)' A/AUerg.-rLa COL'8or,1D•Conw
s
Address to which all permit correspondence should be mailed
2) Location of facility producing discharge:
Facility Name nL&N>,. INC,
Facility Contact 1rS�EYay Alla{UE1LT
_ Street Address 1301 sAwb RD
City Q&A State Al0— ZIP Code 2?
County _ CbYII B>✓
Telephone Number 66 S• ,$"D 17q - Fax: 64 S" $-Do 2
Email address .�df.�"W/ .UeuaYL-Y a� L'mLRsNb .ochn
1
3) Description of Discharge:
a) Is the discharge directly to the receiving stream? 0 Yea fif No
(If no,submit a site map with the pathway to the potential receiving waters dearly marked.This Includes tracing the pathway of the
storm sewer to the discharge point,H the storm sewer is the only viable means of discharge.)
b) Number of discharge outfalls(ditches,pipes,channels,etc.that convey wastewater from the property):
c) What type of wastewater is discharged?Indicate which discharge points,if more than one.
/Non-contact cooling water Outfall(s)N:
LT/Boiler Slowdown Outfall(s)N:
7
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NCGr500000 renewal application
f /
[[f Cooling Tower Slowdown Outfall(s70:
t/Condensate Outfall(a)#:
{ Other Outfall(s)#:
(Please describe"Other") AIL ('bnl'PZ.SS'SDR CooLlnl6y
d) Volume of discharge per each discharge point(in GPD):
#001: Doo #002: O #003i #004
4) Please check the type of chemical(a]added to the wastewater for treatment,per each separate discharge.
point(if applicable,use separate sheet).
❑Chlorine [11`413iocidea ❑Corrosion inhibitors ❑Algaecide ❑ Other
j ❑ None
j 5) If any box in item(4)above[other than None]was checked,a completed.Biocide 101 Form and
manufacturers'information on the additive must be submitted to the following address for approval:
NO DENR/DWQ/Environmental Sciences Section
Aquatic Toxicology Unit
1621 Mail Service Center
Raleigh,NC 27699-1621
6) Is there any type of treatment being provided to the wastewater before discharge(i.e.,retention ponds,
settling ponds,etc.)? OYes Jl
(If yes,please Include design speoli cs(i.e.,design voteme,retention time,surface area,etc.)with submittal package. E)dsling
treatment IsCHINOS Should no dsecdEed in detail.)
7) Discharge Frequency: -
a) The discharge is:VContinus. ❑Intermittent ❑ Seasonal*
E i) If the discharge is intermittent,describe when the discharge will Seoul
i ii) "Check the month(s)the discharge occurs: dJan 11 Feb fd"Mar. dApr D Uay 6 Jun dial
] dAug. [A-Pt. G(Oct. f3INov. C/Dec.
b) How many days per week is there a discharge?
c) Please check the days discharge occurs: CJ'Sat. C�Sun. Mon ATue. PI W d. m Thu. dFri.
i
S) Receiving stresual
t a) To what body or bodies of water(creek,stream,river,lake,etc.)does the facility discharge
wastewater? If the site discharges wastewater to a separate storm sewer system(49),name the
operator of the 48(e.g.City of Raleigh). #A inFf (jR.E�IG
b) Stream Classification: C
Page 2 of 3

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I NCG500000 renewal application
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Additional Application Requirements:
The following information must be included in triplicate[original+2 copies]with this application or it will
be returned as incomplete.
➢ Site map. If the discharge is not directly to a stream,the pathway to the receiving stream must
be clearly indicated, This includes treeing the pathway of a storm sewer to its discharge point.
➢ Authorization for representatives. If this application will be submitted by a consulting
engineer(or engineering firm),include documentation from the Permittee showing that the
consultant submitting the application has-been designated an Authorized Representative of the
applicant.
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3
Certification
I certify that I am familiar with the information contained in this application and that to the best of my
{ knowledge and belief such information is true,complete,and accurate,
i -7�—
Printed Name of Person Signing: U Eby AMUE ct
i Title: 95-C MA i.P
(Signatur lie t) (Date Signed)
North ar General Statute 143-215.6 b(i)provides that:
Any person who knowingly makes any false statement,romesi mean,or osuration in any appgcatim,record,report,plan or other document
filed or required to be maintained under Arthile 21 or regulations or the Enviranmemal Management Cammisdon implementing that Adds.or who
falsill tampers With or knowingly functions inaccurate any recording or monitoring device or method required to be operated ormairgalned under
Amcle 21 or regulations of the Environmental Management Comrdsslon Implenomfol that Article,shag be guilty of a misdemeanor punishable by
I a fine not to exceed$25,O00,or by Imprisonment not to exceed six months,or by both(18 U.S.C.Sedbn 1001 provides a punishment by a fine
of not more than$25,000 or imprisonment rat more than 5 years,or both,fora similar offense.)
't
3
This Notice of itenewal Intent does NOT require a separate fee
The permitted facility alteadypays an annual fee for coverage under NCG500000
{ j Mail the original and two copies of the entire package to:
( Mr, Charles H. Weaver
' NC DENR/DWQ/NPDES
l 1617 Mail Service Center
I
j ! Raleigh, North Carolina 27699-1617
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40

(-0R AGIIiCr ltaaaNLY
axc R%eJ
' Division a[Water aG t Water Y.
i Qta ty Quality S€etion
cesfe.dc.
NCDENR
National Pollutant Diachargs Elimination Systcaa m... ,
A
77' NOTICE DFfeerVerr
7 National pollutant Mactinme Elimination Systion appiketh,far€overage under General Permit
NC050000d:Nort•caatact(noting water.better b1me down,sooting tower bloavown, Seta,and
slmgar¢ofnt souread -
(PEeass print or type)
i t) Matting addinswi at ownor7opatator.
t Company Noma Colboid Inc.
S owner Name ACPFdIb _ _..........--
y Street Address 1401 Sand Hill Road, P.8oHex 1057 -
City L'nka. State NC ZIP Code28728 --
Yelepnra�z No, 8g 565-5089 -
� Fax: BZH= 655-5002
`Apdress'a whkh eaPR. . x4lb msYsd - . -
2) L—at-of facility Praduchto d
i F'aciRyName r€2hn d T S,
3 Facifty Contact H Prakke
- Street Address 1301. Sand Hill Read
3 City Enka State AC ZIPCade, 28728
County. Buncombe
Talephwse No. _ uit 665-5089 Fax [phone] ��
3 3) PhYshaiit location Information:.
a
Please provide a neoatwe desrxipiion of how to gat 10 the faskfy(tse anneal recruit,state road starless,
and tlatafrre and Oned-M from ataadway Entaeaeciwn). 1-40 Rest take Bait 44, Soutli on
Highway 14_23. Ga 2 miles 7 £t t t aEfic Ztall 1 wile. an left.
Wn§Ya`aurmS�PwtlSRS Wdd Shell e�tadaY Jkv�ea aimerrAa __...ranirstate roman arts npPrcatimp
4) This NPd7ES permit aPpH€a6an apjalf"to which of the kagmaling t
t 0 New or Proposed
t €`l I locOe a wn
Please das(rn'be the maditk:ation Cooling cover water atY w h fi 6 t c
G Renews[ exehanger& being ramov¢d Crow
s Pieria SPK*existing Permit number and adginai Issue date.
a a
5) Does this lecildiy,have any other NPBES pouts?
0 No
I 0 Yea
It yea,list the p0mSt numbers tar all current NPDES parmrts far this fits y: Nfs000179
6) What is the nature of the business applying for this permit? Produear e= v' lea i eater sienna.
-g v1gB_aengknthetir m- d r osigll 6te3,t e2tca8jon goo 3}c_
' Page 1 of 4
i swusrz�aeta�
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j N+dGS(I0000 m.o.f.
7) fh�aoriptfon W Discfiargs:
i
a) Is the discharge directly to the receiving water! 6 Yes ER No
0 no,su4mit a sine trap with the Pathway to the potential receiving waters claarly marked This
includes tracing the Pathway of ft starch sewer to the dischargb point,h his storm Sawa,is the ony
viable means of discharge.
1 _ b) Nnrrobar of discharge points(ditchss,Pipes,charineN,eto.that Mosey wastewater from the Properly);
c) What type of wastawaterisdischarged?frtdgato which discharge points,A.rttwethan one. See Attacfnen
? 7 Non-cvnfacf cooling water Discharge poses)a; A
G Bailor Slowdown Dischen3e po nI(s)C
®C,%Ang Tower Biowdown DWwge pomt(a)
E3 Condensate Onnamge POW(s)d:
' Cal Mae Dischage point(s)c
# (f'faass daaor#le'gthar') 0ver[luv frrnz air vaah ra sa d" •harge point as above.
j d Vohmne of discharge par each diSchar"Point(in PaPD):
Ai:--- e2:--- :_ #4 His Charge Pain[ A = 20,000 GPI}
a) Please deserfi ,the We of Process P.O.,c WVrsssor,A/C unk cheer,boner,ate.)the bastewater is
} being orscharged from,Pro each separate dish ntla Perse AR aWkwule,use separate sheet};
Sssgl ior�ZRNx A' ft h and Heat ezchanaers
8) FMase check dra type of chemical added to file wastewater for agair ,t,pet each ,n mte diecherga
pow{N Flimble,use separate eneet}:.
' IS Blocides
Name: GC Jl?. d 6C 315 lead: Carratt-Callihan
Cd Corrosion elhlbaces Name;,GC 200x ,T Marton.; Garrxtt-C 11^t
C]chlorineName. Manor.:
C.7AlgrorsideNoma: _hkanut;
Cl Other Nam,;—,-... �-
(7 None _ Marton.:
i g) h any box in brim(d)above,offer than"Ast..was chocked;a con Phaad Bfoeids 10, Fo re and
I manufat"ans'ktferrnatiun on the additim is requited to He Submitted with the appdcatl0h for the
,
(XNislon's review.
10) is Ptars any floc of treatment being Provided to He,wastewater before d merge(i.s.,retention porMa,
+*3 Ponds,etc.}? 0 Yes 0 No
If Yes,Please include rasigr specdats(I.o.,design veto",ratemdon time,sudaee area,etc.)with
Submhtai package. Exichol;H,,,h000t facilities should be in dated. [losigi orheria and
oPeratcnal data(including calculations should be provxlod to attYur©that ttm taelldy car comply with hto
# ragxramonts of the General Pemgt The treatment shall be sufficient to net the Fruits sat by the general
i Permits.
i
l Note: Cmstrwhon of any wastewater treatment Whiles;requires submission of three(0)sob
Of plans and sPe M=fiWs akmg with the appt don. Design of treatment faciddos must
comply with the requirements of 15A NCAC 2H .0139. if mosHection applies to this
discharge, Include th=_throe sets of plans and specificat'.vns with this application.
SY/i121t4HI2tea Page 2 of 4
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NCG500000 HAI,
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t if Discharge Fr uency:
a) The dls`'t''ugo Continuoes fJ Inte rri tient O Seasnnab
j 1) if the discharge is intermftent,describe when Fire dscharge Will occur:
j 1) if seasonal check Um mardin(s)the riNctrarge rrrs: 0 Jan. .0 Feb. © liar. 4 Apr.
May [)Jun- 11 JUL 1) Aug, 0 Scot, Gf Oct, ® Nov, ® Roo,
b) How many days par Wreak is Huge a discharge? -_ 7
' o) Manse check the days fifarceshIth,occurs:
M Sat. gl Sun. b Mon; 0 Too, El Wed [a Thu. Ci rd-
1?J pdkutants=
Ptasye W any known Paeetents that are present in the dechargo.par arch seyarata discharge Point(if
opplicame,.use swarate shoat): None.
13) Rort0fiVing warm:
a) What s use name of the body Of I)Ddles of were,(peak,stream,ri urr:lake,ab,) that the faoiffty
wastewater d1whargas end UP in? if the site w®staereer discameas to a separate Storm sewer
system(4S),namo the oparatM of ate 4S(®.g.Cfty,of Raleigh)- a3nv ,:reek _
b) Shoam Clusi ication:_!GT_ _ �-
14)Aftamatives,toDetectDischarge,
Address the feasibility of impiatrrentksg each of the fallowing trmeaflscharge alternatives
a) Conovadan to a Regional Sewer Collection,System
b) Subsurfacedisposal(including 1114IN IOn tleid,infiltration gariery,Iftloo iori Welts:etc.).
= of Spay krigatio r
The dlterraftvas to dfsohari a analysis should mciune on"logsandlor other infonnatiart brokering that a
cubsodace straight s her rer feasib"'nor practical as well as Month indicating that ,
3 corn edlon to a PDTW is not an opUan, it shauttl Stan Include a prawn,value of clots onaP/ss es
)
outfaced ar the DNfsioWe'Guidahze For We Evahrvtiva of Waafewafa 0hpgsatANerrla{ives'.
15) Additional Appflaadnn Aaqufrearani o
For rrew or proposed discharges,the following Infr nrnanon must be included in bipaCaie wilt this
- application or it split be nuumed as oconhplate.
a) 7.5 m rtrta nodes USGS"fraphic map(ar a photocopied Milan thereof)wlih rkcharge tocaf m
clearly indicated.
b) Sate maP,a 111e discharge is not dlrnetly 10 a stream,the palWay10 the(ocaivuhg steam nner,be
clearly indicated. Thus imtdas tracing the path"y of a afam aewer to its dsolnego PollL
1 n) tf the application is being snbnufted by a txmsuftdrg Gigs,,,(or engineering firm),include
c
documentation horn the applicant airowptg that gre engineer(OF Firm)sulirnFiiing the applicator has
! been designated an authorized philg"atuative of the appkanL
di Final(clans for the Ifeatrirem sus tern i(( appticanle). The prate must be signodsnd sealed by a Nonh
Cara 'a"regisnoed Professional Engineer and a mped-'Final Design-Blot released to cwnsoa^tinn•.
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� ®®��ppRp ((yyg�ryryMa�9 airy
1 NCG500000 la o.i.
I
e) Pima specRioations for all major treatment cwnponanl.(if applicable). The spaOMicatftxts must be
sgned and soared by a North Cana registered Professlatai En flo9er and shall include a narrative
desonfr"On of the treatment system to be consimK#ed,
1 certify that 1 am famiflar with the infomiation aehMMed in this application and that to tfla hest at my
k9awtatlge and belief such infarmati0o Is has.Complete,and assurem.
's
Printed Name Of Pefswr SignxxP Rick Roberson
3 s
Date
North Garellesa Cjansent Statute 143.215.6 is(1)provides tbw
Any Person who rcawrngly makes any false stag repwanialiom. Or caegro'arfon in any
i appNcaliOn,record, MPOII,Plan Pr other document read u required m be remirtalftad taaar Artk(a 29
Or regulations Of the SmWratmental Manager mi C.ommission t ng that AMose, or wtio
j
("buss, mrnpars with or immvingty renders IMAccagata any f'acattlrng w monitoring rfavkzew rrreiifad
required to be Operated Or rnafntatm t under Ancele $1 or. reyudations Of the en irommantai
- Maregament Gorrunissian hTMIUMON009 that ArWo,shall be guilty of a Misdemeanor pwfthabl,by a
fine not to exceed $10,000,.or by imprisonment rat to exceed sus maraha ar by bam. (19 U.S:G.
Section 1941 provides a Punishment by a fine of mot mars then$10,000 or Imprisonment nd more
than 5.years,or both, for a skew effluent
i
a Notice Of fnle M must be accom(tartfed by a ebaek or rmohoy,order for Samoa made payable te:
NOD8p1011
i
rose base(3)capies of the venue package to;
Starrawater.and General(rermftr,Unit
Division of Water quality
i
1617 Meg Service Center
GaiOtgt,North Carolina 27699-1617
i pinal GFttdlst
j Th(a apptfoatlon wgl tie returned as in tm9asa Ott of that®!#owlefg 3P.ems have been
include
0 Chack for$89 made Payable to NCDENR
s Cl 3 GOPWS Of county Meg or USGS quad sheet with location of facility clearly marked on map
®3 GoPlas of this completed application and all SLPp tag documents '
0 3 sets of plans and sPaarfiGanons steed and Mind by a North Carolina P.E.
a Thorough msfumses to ileums 1-7 an.this application
i Afternativas analysis faun mg Present valun of costs for all attamerivas
MIND
i The submission of this document does not guarantee the issuance of an NPVeS Permit
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i - OIOCIDECHEMICAL TREATMENT
WORKSHEET-FORM 181
The following calculations are to be perronned M any b; dal pradw;i3 ultimately dischangwt to the surface watefs of North
4
i Camllra. This worksheet must be completed separetay for each bkxirial Product in use This wader t is W be roomed
i
With oil SlVuli nme data entered into ime designated areas with cataaladans parfroused as im6iated.
i
I_ Faci ty Name_ _Colbana Inc,
NPDES#NC 001151# 8 (Cooling.Tower)
County Buncombe (Attachment A)
r Recarsng Stream ttaminv ire-k _7Q16 23 (efs)
(All above inforrnatian supplied by the Warm of WaWr 4 ')
What is the Avgaage gaily Dischi mge(A.RD)volume of the water hartQ5n s g tom?
j g ySW to the to wake
j AD.D.= ig05 (n M.G.D.) -
i Please calculate the msBoarn Waste t Concentrafiten IBAC in percent)of ji,disdr ergs using the Data entered abovo.
1
lbVC (A.t - X 100 C 10$ X 100 0
(7010)(0,646)+(ADD) r ( 230.646) + (,pp$
7 This vaue(MtlD)represems the waste n5c2nira6ort for the Lewin,Micarn during law flow moons,
p
ti. V"Ime is the name Of the whole product obehiml treatmentptapa,ad for use,in tttz discharge ideniiCted in Part t?
Garratc—Calahan F.M 1 312
= Please list the active ingradiams and percent compossion
Glr a 45 %
New
Methanol '�� �rv�— ingredient?
Nmat teed or dosage rate P-P)is used in Time appiiCe ion?The abuse most he converted to maximum trams
x
Of whale product need in a 24ta period. Chris Hale says the feed rate is 5 gallons per day now, This is
D.R.- 29� �1m7t equal to 18915 grams per day. Is this correct? Is this volume
' necessary?That is about 65X the amount in 2002,
Please note,fluid ounces(a volume)must be converted W grome(a mass). The trauma for this wnvarslan is:
Gram of product= 8ukt az of product% -hM% 8 34 lo X spook 9M M Of modem X 453-42g,
I 128 0.oz 1 gal.Water 1 lb,
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Ftity Nama. C ih d T — NPDESg: .NC.
Esfimate t0aAl WIVMQ of the water halting system betwm entry of blbadal Product and NPDES discharge&Dint.
On an 04adhad sheet Pleas provide justification for this estimate fsystarn where,average cycles Per lowdown,
7 holding Iagme size,etc.).
3
uowme; :0n1 rolkbn g�fars
What is the AH d the handfmg system poor to biocide additian7 h ufl]ah0 e.enter N!A N/A
What is the decay Pate(D K of the) produa? If urlMrpwn,assur_o rro decay(D.ICa0}uric tirvePed lA asterisk. The
` dogred"dion most he stated at PH level w"112 PH sbndaMbnR Within handling systan. Enter the half the(Hall
Life is the torte re"ued for the initial product to&Vracki to half of Its orightal cwmrrfraGon). Phmse prooMe
cop!"Gl ehe ao of 0ft dam,
nab poede:nit I,the
tH.I.. 0.i pays 4---- value ae need Io
j wmpletelheanal"is.
3 The decay rate is seiner to H X 0.69 = I.38 =0 y Rate(t7.K.)
t CaktAais dewinhil an WW(D.F.), This IS the first order loss coaea jent.
•O.F. -.LAD _ + AK),
(Volwne) (.002 )
3
Catenate Steady&fate Discharge Ganiz'sliaigbn;
LNschg CanF m..-ApPP)(iloWme)(3785) ( 3.88 fH7 P2j(3765) R —_ -,..---M9A
Cakrdate mncantrst wt of Wodtle insheam devi ng law fiav correm om
(RweNing&seats CoflW Indion)
ssdr-ig.Conc.Y % (NYG%) �9µ96) x f:0's4j .0034
j 100 100 -DA
Receiving StreamConceniradon
j all, Calmness MGUWted kmitafion.
7 List all L050 and€C50 dats avakatde for ft whale product aawdN to fhe folumng coWM& (Note that wads
should bo lo mcyhl. Piease provide coytea of the sources W this cats.
Quwahim TaSt Our" L9501EC50/mm
Rainbov TCoul 96 itra. .2
u�Fachead;Ninnov S.d
Davhnta Naana {g fi; , i e
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{ 3).N .Ifutnt 101Ib/Z46Q1 . . 1
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Fasiaty Neme: EolLond r c,
Choose fhe bftst LC601EC50 feted above:
Enter the LCMEC50: 5
It the had 16 (HI)is(a$$then 4 days,Parf-- the fonwii
n9 cabulatlo-n.
Re9Watad L4nitahon = 005 x LC50
S
H 1ilE haBlHe (H.L.)is greater Nan of equal 104 days or unkfrovm,Barn tithe fogoeng atUtation.
ROW40ted UnUEHon > 0.01 x LC60
Ct ar>se fire"Otne oto
imjulatad 1nfaWkd hand the raar}atiens n ead"tety ahned aid place in this hlsrtic
i 0.25 _..__rngy6teY
t
From Pan It ants the ferepr q atraefn fxanceniratlaS;
i
- Iv. Analyels.
if the moeenng stream +�traQan is greater than Ne cukalated red ed iimdatkn,Man Nts is
- unacceptabk kx use.
Peou n in Responsible Charge
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E _t€cx�nn P �kk
t)
ftfmtaa _.
bats
Person C"Pleling This VAXW�g(€f different fro ,above)
_ff"Ard-taLl ex_
RJanre(aunt)
0gnat - ..Date
€
Please,$"on yro, Dwision of M ter quafity '..
Aq aric roxfaoloyy Ung
1621 Amd smku Center
ReAilgh,No 21OW1621
Aen_Todd Chnslgnsrn
1 1>.KQ.Farm rot(W400)
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jLoci&Bonar[tic.
9E Bonar
f T , ,.,
November 29,2017 C 5.-._-
. lo'rrandha�ar.conr
t North Carolina Department of Environmental Quality
Division Water Resources
2028 US Highway 70
Swannanoa, NC 28787
1 Attn: Landon Davidson
Regional Supervisor
Re: Low and Bonar Inc.
Discharged Water Permit Application Report 3
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t Mr. Davidson:
{ The purpose of this letter is to present the results of Low&Bonar Inc.'s fourth discharged water sampling and
analysis event. This effort was completed to demonstrate the effects of actions taken to mitigate and address
,j discharges of cooling tower blowdowns, condensate waters, and once-through cooling waters to Hominy
t Creek.
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over the past six months Low& Bonar has made significant infrastructure changes to reduce impacts to
surface waters. These changes include:
',. 1. Reduced non-contact cooling water through Cooling Towers.
2. Reduced non-contact cooling water through Extruders.
3. Recycled non-contact boiler condensate water.
'1 4. Installed water flow meters.
5. Installed a dechlorination system.
i
[ We believe that this report—and the reports for the three previous sampling events— demonstrates that Low
and Bonar is now and has been substantially in compliance with North Carolina Surface Water Pollutant
Discharge Limits. Moreover,this report shows that Low& Bonar has, based upon preliminary data,reduced
its purchased water and discharged water.
i Please review the results of our infrastructure and operational changes. We believe that you will agree that a
General Permit is appropriate for our facility. .
Contact me Steve.Jenkinsr uLowandBonar.com or at 828-707-5805 with questions or comments.
Sincerely,
Stephen C. Jenkins, I�-/EMa'�'ager,North America '..
CC: Wayne Merritt, L&B, Manufacturing/Site Manager '..
Clive Macro, L&B, HSE Director, London '..

j
DISCHARGED WATER STUDY
E REPORT 3
j
FOR
LOW&
Bonar
Low & Bonar Inc.
' 1302 Sandhill Road
Enka, North Carolina 27105
1
1
Prepared For:
l Landon Davidson, Regional Supervisor, Division of Water Resources
Linda Wiggs, Environmental Senior Specialist, Division of Water Resources
North Carolina Department of Environmental Quality
Water Quality Regional Operations Section
2090 US Highway 70
Swannanoa, NC 28778
j
Date:
November 29, 2017

{
}
DISCHARGED WATER STUDY
REPORT 3
FOR
LOW&
BOnar
Low & Bonar Inc.
1302 Sandhill Road
Enka, North Carolina 27105
a
i
Prepared For:
Stephen C. Jenkins, HSE Manager, North America
1 1302 Sandhill Road
Enka, North Carolina 27105
I
,( Prepared By:
pljGtqH
ENVIR4NME_NTpL KRVICEU LLC
9 Woodvale Avenue
Asheville,NC 28804
PROJECT NO. 1 107140
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Table of Contents
EXECUTIVE SUMMARY—DISCHARGED WATER STUDY..............................................1
CHRONOLOGY............................................................................................................................3
3
CONTACT VS.NON-CONTACT COOLING WATER...........................................................4
CoolingWater...................................................................................................................4
BoilerCondensates....................................—....................................................................4
'. Air Condensates................................................................................................................4
[ Process Condensates...................................—...................................................................4
2
GROUNDWATER.........................................................................................................................5
Groundwateras Cooling Water......................................................................................5
1 Groundwater as a Heat Sink................................................-..........................................5
i
DISCHARGED WATER FLOW RATES...................................................................................6
FACILITY IMPROVEMENTS...................................................................................................8
BOILERCONDENSATE.............................................................................................................8
CHILLER COOLING TOWER 058 SYSTEM......................................—................................9
COOPER COOLING TOWER SYSTEM..................................................................................9
COMPRESSOR COOLING TOWER 054 SYSTEM...............................................................9
SLIM TANK—NEW COMPLIANCE POINT...........................................................................9
s ROOF STORMWATER DRAIN PIPING...............—.........................................................I......9
1 FLOW METERS...........................................................................................................................9
DECHLORINATION SYSTEM................................................................................................10
jIMPROVEMENT COSTS.......................................—...............................................................11
i
DISCHARGED WATER SAMPLING RESULTS............................................................I......12
SCOPEOF FUTURE TESTING...............................................................................................13
CONCLUSION............................................................................................................................13
E
1
Low&Bon.Ina-MES Discharged Water Rcpon 3 i
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Figures
1. Combined Cooling Water and Groundwater Discharge
2. Dechlorination System Process Flow Diagram
i 3. Low&Bonar Inc.MSD and Stonnwater Piping Systems(in cover pocket)
i
- Tables
s
( 1. Discharged Water: Process Cooling Water and Groundwater Infiltration
2. L&B Discharged Water Equipment Purchases,Installations,and Engineering Costs
i
1 3. Discharge Water Sampling Analytical Results—October 19,2017
I 4. Discharge Water Sampling Analytical Results—August 2,2017
5. Discharge Water Sampling Analytical Results—July 6 and 1,2017
t
E Exhibits
Attachments
A. Pace Analytical Laboratory Analysis Report
B. Discharge Water and Groundwater Infiltration Flow Measurements and Calculations
C. Punch Lists/Purchase Orders
i D. Sampling Records/Weather Station Records/Purchased Water Records
E. Equipment Information: Flow Meters and Dechlorination System
F. Safety Data Sheets
G. North Carolina Surface Water Standards
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I Low&Bonar Inc.—NPDES Discharged Water Report 3 if
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EXECUTIVE SUMMARY-DISCHARGED WATER STUDY
Low&Bonar Inc.has compiled additional information regarding water discharges to surface waters of
the State for review by the North Carolina Department of Environmental Quality's Water Resources
Section. This information comprises a comprehensive water discharge evaluation developed from several
I internal staff meetings representing Engineering,Facilities,Maintenance,and Environmental divisions
with our environmental consultant Pisgah Environmental Services.
This report of a sampling and analysis campaign on October 19,2017, is the cumulation of intense study,
discussion,infrastructure changes,equipment changes and repairs,and procedural changes through the
efforts of staff and contractors over the past six months. This report is preceded by three other sampling
and reporting campaigns. Reports of July 5, July 9,and August 2 campaigns were previously reported to
# 0ie Water Resources Section.
L&B owns and operates a complex 88-year old facility that has had several ownership changes. One
spin-off industrial manufacturing facility under its own administrative control remains on-site as do 14
tenants. Despite these obstacles,this report is a complete water discharge evaluation of L&B's current
discharged water situation.
i This report provides discharge water pollutant concentrations from four(4)sources or intermediate
points. Three of these discharge water sample locations are the same as in all previous campaigns:
Manhole 3,Slim Tank,and the East Ditch. Over the course of all our activities over the last six months
the relative pollutant concentrations at these locations have not substantially changed.
i This report includes two important equipment additions at the Slim Tank—the new discharged water
$ permit compliance point—and the Flood Gate—the new stornwater permit compliance point:
i
j 1. Flow Meter Installation in the Slim Tank and the Flood Gate.
2. De-Chlorination System Installation in the Slim Tank.
1
This report—as with three previous reports—demonstrates that water discharges from the Low&Bonar
Inc.facility substantially comply with North Carolina ISA NCAC 02B Surface Water Standards and
Protective Values. Exceptions to this statement are addressed below.
3
j I. Two metals—copper and zinc—are discharged at values exceeding regulatory limits.
s
I Copper and zinc concentrations in the new dischm ge compliance point(i.e.,Slim Tank)are at
t concentrations of0.0381 mid 0.561 milli 'ams er liter m
Bi p ( g/L)respectively;the acute regulatory
limits are 0,0036 and 0.036 mg/L respectively. Of note are that City Water copper and zinc
' concentrations of North Fork reservoir water are 0.0076 and 0.210 mg/L respectively. Thus, City
I Water supplied to L&B exceeds the State regulatory discharge limits.
t
s
J Both copper and zinc are considered to have water system supply and infrastmcture sources
rather than processsources,
Another metal—molybdenum—was previously discharged from the facility. Molybdenum's only
source was a water treatment chemical used in the Cooling Towers. Our water treatment supplier
of this chemical used molybdenum as a tracer(i.e.,as molybdenum concentration values decrease '..
the supplier adds more of the entire formulation). The water treatment chemical supplier has
removed molybdenum from this formulation.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 I
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i 2. Totalizing flow meters were installed in the Slim Tank and in the Flood Gate on October 31;i.e.,
since the October 19 sampling campaign. The metered flow data confirm that significant
discharge reductions have been realized from recent equipment changes to the 21 extruder
cooling water points,seven(7)cooling towers,and 10 boiler condensate receivers.
Discharge water flow,rates in this report are based upon flow meter averages over the first two
weeks of operation. These values differ from direct measurements on October 19;which vary
i greatly on minute-to-minute basis and daily.
t The first two weeks of flow monitoring show that our previously reported flow rate calculations
' were generally correct. Thus,the totalizer flow rates me used in calculating mass pollutant
effluent rates. In the future,totalizer flows may also be used for Wasteland Allocation
calculations if necessary.
3. Total Residual Chlorine is discharged from multiple sources;some are once-through cooling
waters that discharge essentially City Water(e.g.,extruders),most are cooling tower blowdowns,
and some are boiler condensates. Note that City Water—which is used in all three processes—
Total Residual Chlorine concentration averages about 1.4 milligrams per liter(mg/L).
7
Prior to installation of the de-chlorination system,Total Residual Chlorine concentrations in the
new discharge compliance point(i.e.,Slim Tank)ranged from 0.4 to 0.8 milligrams per liter
3
i (mg/L);the regulatory limit is 0.017 mg/L.
Recently,after installation of the de-chlorination system,Total Residual Chlorine at the Slim
Tank and Flood gate compliance points has been at concentrations of less than 0.017 mg/L at
7 both points(see Figure 2 for sampling locations).
Our conclusion is that Low&Boner Inc. is in compliance with the Total Residual Chlorine
standard in the Slim Tank;which is an internal sampling point that is being proposed as the new
' ..compliance point'.
i
4. Boiler steam condensate water was discharged from several receivers and condensate drip legs to
i the stortnwater collection/discharge system. Boiler condensates have now all been returned to the
boiler(i.e.,recycled)or rerouted to MSD.
The net result was that Total Residual Chlorine mass effluent rate was significantly reduced by
changes to the extruders,cooling towers,and the boiler system that reduced their discharges.
Now that the de-chlorination system is operational Total Residual Chlorine concentrations have
dropped to Tess than the analytical detection limit.
4 5. With reductions of water discharged from the Cooling Towers,Extruders,and Boiler
Condensates the amount of purchased City Water has decreased. See purchased water records in
Attachment D.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 2
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3
3
I CHRONOLOGY
On May 22,2017,Low&Bonar Inc. conducted a Low&Bonar-facility-wide requested inspection with
North Carolina Department of Environmental Quality staff concerning compliance with stormwater
regulations.
During that inspection,several other discharged water issues arose. As a follow-up to that inspection Ms.
Linda Wiggs of the Division of Water Resources sent to Low&Bonar Inc. in a June 12 email an
j Information Request for water discharge sources,rates, and pollutant concentrations. A response to D WR
from Low&Bonar was dated June IS.
On June 19,the Water Resources Section issued a Notice of Violation and Intent to Assess Civil Penalty
(NOV-2017-DV-0148,Incident No.: 201701034)to Low&Bonar Inc.
Low&Bonar Inc. attended a meeting with Water Resources Section staff on June 23. During that
meeting Water Resources Section staff clarified the scope of Ms. Wiggs' requested information and Mr.
Landon Davidson identified other tasks in an Information Request dated June 23. Those data,including
estimates of the volume of wastewater discharged daily, list of biocides and any other additives in
wastewater,biocide worksheets,wastewater analytical data,facility-wide wastewater audit,cost to pump
and haul current wastewater discharge,metropolitan sewerage district policy on non-contact wastewater,
s and current wastewater discharge quality or quantity changes to NCG500608 were conveyed to Mr.
= Davidson in a letter from Low&Bonar dated June 26.
= Ms. Wiggs conducted a Water Resources Section facility-wide inspection of the Low&Bonar Inc.site on
July 6. During that inspection samples were collected from three sources:Slim Tank,Jarden Steam
Heating Condensate,and the East Ditch, On July 13,Low&Bonar Inc.collected samples from three(3)
additional sources:Manhole 3,Manhole 25,and the Cooper Compressor as well as from one(1)
j stormwater source: Poly Cooling Building. The results of those two evaluations were conveyed to the
3 Water Resources Section in a letter report dated July 25,
a
The results of third evaluation,conducted August 2,were conveyed to the Water Resources Section in a
j letter report dated August 31.
I This report describes the results of a sampling and analysis campaign conducted October 19. Samples
were collected from four(4)sources: Manhole 3,Slim Tank,Floodgate(new stormwater sampling point),
l and the East Ditch(previous discharged water sampling point).
7
Flow meters installed Oct 31. Slim Tank meter functional immediately.
i
System plumbing,equipment installation,and electrical connections completed November 10.
Flood Gate flow meter functional November 15.
� De-chlorination system installed November 20.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 3 '..
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CONTACT VS. NON-CONTACT COOLING WATER
L&B has determined that discharged waters to Hominy Creek are exclusive)g y y"non-contact cooling
water", "once-through cooling water",condensed water from creature comfort and room cooling for
heat/moisture sensitive electronics equipment,or oil-less air compressor system condensates. Extruder
waters,cooling tower blowdowns,and boiler condensates are all considered"non-contact cooling water',
"once-through cooling water",or permissible discharges respectively. Each type of discharged water is
discussed below.
3 Cooling Water
L&B extruders and cooling towers are examples of"non-contact cooling water"or"once-through cooling
water". For example,City Water is piped through an extruder head or gear box to indirectly cool the
mechanism or to prevent the product from becoming too hot. This is a type of non-contact cooling water.
-i Specifically,water used in cooling the extruder throat and gear boxes is`once-through cooling water'.
S Residual chlorine content of both processes is equal to that of City Water and other chemical
i characteristics are the same. Thus,extruder and cooling tower waters impart chlorine to discharged
7 waters. L&B has installed a dechlorination system to address residual chlorine. This is discussed in a
7 later section.
Boiler Condensates
Condensates from boiler steam are classified as non-process water. These waters do not contain the
inorganic components of boiler treatment chemicals, but they do contain chlorine.
The decision to recycle boiler condensates rather than discharge them is more an economic decision than
an environmental decision. L&B calculates that every 100 gallons of boiler condensates discharged daily
costs$456 per year.
Air Condensates
Condensates from compressed air systems are classified as non-process water. Although compressed air
is used, for example,to move thread through tubing or to spread thread on the Fleecing table,the
! condensed water that remains in the pressurized lines is never in contact with product(s)or raw materials.
Moreover,this air is produced by"oil-less"compressors;thus,no oil can be in condensed water.
'. Therefore,condensate from these lines is considered"non-contact"and is permitted to be discharged to
surface waters.Compressed air system water is directed to the Slim Tank and hence to Hominy Creek.
Air handling units(AHUs)create condensates from atmospheric vapor.This is considered non-contact
water(i.e.,does not contact product).
Process Condensates
One type of AHU air does contact products. In this evaluation,yam quench and room cooling air
condensates were classified as"process water". For example,quenching the recently formed yam strands
with cool air releases nylon or PET monomers to room air. This air is then mixed with room cooling air.
Although these monomers are not in concentrations to be detected as total suspended solids they are still
"process water". Consequently,these waters were replrmbed to MSD.
L&B identified several true"contact"process water discharges and has routed them all to the
Metropolitan Sewerage District(MSD)of Buncombe County sewerage system. These sources include:
I
• Die Oven cleaning
• Maintenance wash sinks(other than solvent parts washers)
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Low&Bonar Inc.—NPDES Discharged Water Report 3 4 '..

€
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}
3
e Laboratory water
GROUNDWATER
Groundwater as Cooling Water
{ Instead of using City Water in cooling towers and to cool extruders,L&B explored using ground water
stored in three large flooded ventilation tubes under the Fleecing Department floor to either cool the water
circulated through these systems or as the cooling water itself. The benefit of this option is that it would
{ only require the purchase of a pump and installation of some piping. Several unused heat exchangers
Ij around the plant are available to be put into service for this application.
3 To test this option the flooded ventilation system was pumped to MSD—with their permission—at a rate
of about 44,000 gallons per day(gal/d)for about four(4)hours—a total of 7,890 gallons. This rate is
approximately the overall groundwater infiltration rate from the site into all the stormwater piping
discharge at the East Ditch. The water level in the ventilation system dropped by 4.59 inches. Thus,the
3 pumping rate exceeded the recharge rate.
The next day,on October 5,we pumped about 3,210 gallons from the ventilation system over six(6)
hours. This rate—12,845 gal/d(8.92 gal/min)—is approximately the amount necessary to replace City
Water that cools the 21 extruders. The water level in the ventilation system dropped by 1.31 inches.
i Again,the pumping rate exceeded the recharge rate.
Note that these results are an evaluation of groundwater at a moderately low level. In the preceding 20
1
days prior to testing the site had received 0.3 inches of rain in a single event. Thus,this is not even close
to the most severe drought conditions the region has experienced over the past five years. So,unless the
site is experiencing almost flood conditions,there is not enough water entering the flooded ventilation
shafts to supply process cooling water or to act as a heat sink for process cooling.
Ultimately,we conclude that the groundwater recharge rate in the flooded ventilation shaft is not
sufficient to replace even the smallest cooling water consumer of City Water in the entire facility.
Groundwater as a Heat Sink
3
During out examination of using ventilation shaft water for direct cooling we considered it for indirect
cooling. In this treatment scenario extruder cooling water would be pumped through heat exchangers that
I use ventilation shaft water as a cooling agent.
t
t Since ventilation shaft water is not recharged quickly it was determined that the transferred heat would
jbuild up in the water. Ultimately,the ventilation shaft water would attain the same temperature as the
extruder water it was intended to cool. Therefore,this option was abandoned.
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Low&Sonar lac.—NPDES Discharged Water Report 3 5
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DISCHARGED WATER FLOW RATES
L&B has continued to refine our process discharge water production evaluations. Table 1 lists our current
measured discharge water contributions—including groundwater—to L&B's discharge to Hominy Creek.
The new totalizing flow meters in the discharge water system(see Exhibits 9 and 11)are dynamic
calculations;measured water flows are five-minute averages that are averaged into hourly values. These
i flows vary daroughout the day depending on work load,temperature,humidity,and a host of other
production factors. For example,during our August 2 sampling campaign discharge water flows from
only the extruders into the Slim Tank varied by a factor of three(3)over a 20-minute period. Other
r inputs to the Slim Tank varied as well.
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3 Calculations of Groundwater Infiltration also vary due to rainfall amounts at the site and upstream in the
Hominy Creek drainage. These factors are beyond our control. However,with metered discharge water
' data we are able to evaluate Groundwaterinfiltration more accurately.
i
Three conditions are of note in our calculations:
j L The process wastewater values of maximum discharge were taken from measured discharge
rates during periods of high production,medium to high fall temperatures,and low humidity
during mid-October.
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2. Groundwater was at a low point; no rainfall events at the facility for the 96 hours preceding
sampling and flow measurements(see Attachment D).
3. All cooling water streams have been routed through the'Slim Tank' and then through the
'Flood Gate'and hence to Hominy Creek via the East Ditch. This configuration allows all
'non-contact' cooling waters to be sampled from a single point.
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l Table 1. Discharged Water:Process Cooling Water and Groundwater Infiltration
3
r
Flow Measurin Device
3 Source Description al/hour i' ab'da
Slim Tank Non-Contact Cooling Waters 10.8 15,552
Non-Contact Cooling Waters+ 15,552
Flood Gate Groundwater Infiltration+ 24.3 X
- Phase 7 Pumped Groundwater2 6366
7 TOTAL X=35 030
! 'Extruder cooling and Cooling Towers blowdown water.
Phase 7(see Figure 2)groundwater pumped at 6,366 gaVday.
i
Groundwater infiltration into the combined discharge water/stormwater system is calculated by the
difference between the flow through the Flood Gate and contributions from Process Cooling Water and
Pumped Groundwater from Phase 7. We calculate that 37 percent of the discharged water through the
Flood Gate is groundwater infiltration.
JThe infiltration rate relates to the length of concrete piping installed below the groundwater table.
Approximately 2,340 feet of main trunk stormwater lines lie below the groundwater table in addition to
the relatively shallow collection lines from roof drains and surface level drop inlets that are above the
groundwater table. Figure 2 shows all the stomwater lines but the differences between those below
groundwater table and surficial collection lines is not delineated. Figure I shows the approximately 772
j linear feet of deeper,main trunk stormwater lines between the Slim Tank and die Flood Gate.
Approximately 1,560 linear feet of additional submerged stonnwater piping is upstream of the Slim Tank.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 6 '..
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l e ,
4
I i
i i F
C6J.1ln NARP
( 1
suc � e J
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!
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r �Fl G t SC d�
j VACANT
s
O
v VACANT
( PHASE 7 ,
Storm.ter � 'zu
Collation Lmo -
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Figure 1. Combined Cooling Water and Groundwater Discharge
Low&Boau Inc.—NPDES Discharged Water Report 3
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FACILITY IMPROVEMENTS
Facilities,Engineering,and Maintenance staff identified several water issues that must be changed to
bring the facility into total compliance with NC Surface Water regulations. These issues and tasks were
s ranked by:
1. Impact on surface water quality,
j 2. Schedule to completion,
' 3. Availability of motors and pumps,and
I
- 4. Availability ofL&B staff or contract staffing.
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i First among issues was to return all treated and heated boiler condensates to the boiler system. Losing
boiler condensate to the East Ditch or to MSD is a waste of water treatment chemicals,heat energy,and
purchased water.
z
Low&Bomar Inc. has installed or performed the actions described in the previous sections. Table 2 is a
summary of the equipment mid labor costs as of November 1. Note:The list does not include costs for
completion of the permit application and ancillary evaluations."Punch Lists"of identified tasks to bring
discharge water into compliance are listed in seven(7)weekly reports in Attachment C.
The following sections describe actions L&B has embarked upon to minimize impacts to surface waters.
7
i BOILER CONDENSATE
Over the years the L&B Boiler Condensate System has developed many connections and discharges to
i the ston water system that flows to Hominy Creek via the East Ditch or to the Metropolitan Sewerage
District(MSD)system. Neither discharge reflects the condensate system's initial design. The Boiler
Condensate System was designed to capture and recycle all boiler steam condensate. To this end 10
condensate receivers were installed around the facility.
I The system was originally designed to work in the following manner: Boiler steam condenses in transfer
t piping and flows via gravity to a receiver. These receivers store the condensate until the container is fill
and then pump the liquid to a height that allows it to flow by gravity to the boiler condensate storage in
the boiler room. The condensate is heated again in the boiler and the process repeats.
7
In order to repaidreplumb and once again capture and recycle all boiler steam condensates,the following
tasks have been completed:
I
1. Repaired or replaced cooling tower pumps,motors, floats,and switches(see Table 2).
2. Removed all boiler steam receiver and drip line piping connections to MSD or to the
stonmvater system(see Table 2)and Exhibits 4 and 5.
3. Installed bypass piping upstream of receivers for maintenance activities(see Exhibit 3).
4. Fabricated two wheeled metal tanks to collect boiler condensates during maintenance '..
- activities. Tank contents will be returned to the boiler condensate system or to MSD via a
dedicated drain.
The pace of work involved can be followed in the "Punch Lists" included in Attachment C.
3 These lists contain completion dates for specific tasks.
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3 Low&Bonar Inc.—NPDES Discharged Water Report 3 g
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CHILLER COOLING TOWER 058 SYSTEM
Replaced two Chiller Room Cooling Tower 0-58 water pumps and motors(see Exhibit 13). Re-attached the
effluent line to the central discharge point—the Slim Tank—in the DowTherm room. This repair re-routed
the Chiller Cooling Tower blowdown to the stormwater collection system via the Slim Tank rather than
directly to the stormwater collection system.
I
This change was necessary to have all stormwater collection system discharges fiom a single point. Having
i a single point for flow monitoring and sampling is necessary to demonstrate compliance with permit
j conditions. It also provides a single location for dechlorination.
1
j A purchase order for a replace pump/motor is included in Attachment C.
COOPER COOLING TOWER SYSTEM
Replaced two Cooper Cooling Tower water pumps and motors. Re-attached the effluent line to the piping
system to the Slim Tank central discharge point in the DowTherm room. This repair re-routed the Cooper
j Cooling Tower blowdown to the stonnwater collection system via the Slim Tank rather than directly to the
stormwater collection system. Again,this change was necessary to have all stormwater collection system
discharges and dechlorination are conducted from a single point.
`s
COMPRESSOR COOLING TOWER 054 SYSTEM
Replaced two float valves.
A purchase order for a float valve is included in Attachment C.
SLIM TANK—NEW COMPLIANCE POINT
Replumbed the central discharge point-the Slim Tank-in the DowTherm room so that all inputs are on the
upstream side of the weir(see Exhibit 11). [Two lines were moved about 3 feet upstream.] In this report and
in the furore,all permit compliance monitoring for water discharged to Hominy Creek via the East Ditch will
be conducted at the Slim Tank discharge point.
ROOF STORMWATER DRAIN PIPING
Low&Bonar Inc.replumhed the stonmvater drain system in the main processing areas—all six(6)levels of
the tower,winding fleecing,Enkamat, and Colback—so that drains contain only rain water and condensates
j from creature comfort cooling—NO PROCESS WATER. Abandoned lines have been spray painted orange
and tags attached to direct our contractor to"cut and cap"all the marked lines(see Exhibits 4 and 5).
i
FLOW METERS
Low&Bonar Inc, installed discharged water flow monitors in the follow,locations:
3
o Central water discharge point—the Slim Tank—in the DowTherm room(see Exhibit IL.
o Floodgate directly upstream of the head of the East Ditch(see Exhibits 8,9,and 10).
Flow meters record discharge water flow rates every 15 seconds and then compute hourly and daily totals.
Ultimately,the two flow meters compute monthly discharged water flows. '..
- The flow meter vendor initially installed a 30-inch Cipoletti weir in the Flood Gate exit. This flow device is '..
too large for the volume of water going through the Flood Gate;the readings by the flow sensor ranged from
about 0.05 to 0.10 inches. This range is too small for the sensor to accurately measure. Therefore,L&B
installed a 60 degreed V-notch weir on top of the Cipoletti weir. This weir generates readings by the flow
sensor ranging from 3 to 5 inches;which is easily in the capacity of the sensor to monitor. L&B plans to
s
L.&Bonar.Inc.—NPDES Discharged water Report 3 9

permanently install a 60-degree V-notch weir in this location after enough flow data is generated to file a
permit application.
Attachment E contains the schematics and operational manuals for the flow sensors.
Table 1 lists PRELIMINARY discharged water flows from the two monitoring points from October 31 to
November 7. During the period October I 1 to November 13 L&B purchased—on average—98,645 gal/day.
These data indicate that discharged water is 15.8 percent of the water purchased over the same period.
i Attachment D contains the purchased water volumes over the same period.
I
Moreover,the PRELIMINARY purchased from July 12 to August 10 was 155,093 gal/day. During that time
discharged water was 35.6 percent of purchased water.Thus,PRELIMINARY CALCULATIONS of water
! reductions from our replmnbing actions and cooling water use indicate that L&B has reduced its water use
j significantly. Water purchasing records and water discharge records over the next several months will
provide more statistically significant data.
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DECHLORINATION SYSTEM
3
Low&Bonar installed a dechlorination system in the Slim Tank and a Secondary Tank. All chlorinated
E water used in the extruders and the seven(7)cooling towers flows through these two tanks. Figure 2 is a
process flow diagram of the dechlorination system, Exhibit 12 is an image of the instrumentation
installation.
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1 llG Gallon Slim Tank ( - �'
{� 1
1
ada Galion ndary Tank
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2
`E
Figure 2. Dechlorination System Process Flow Diagram
The L&B water chemical supplier,Garrett-Callahan,estimates that on a daily average the dechlorination
system will consume about 1.47 pounds of their Formula 6600 sodium bisulfite solution. This amount is
based upon previous daily discharges of up to 55,000 gal/d. Since the discharged water has been reduced to
1 about 15,500 gal/d,the dose rate should be reduced to about 0.41 Ib/d. A Safety Data Sheet for Formula
6600 is included in Attachment F.
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' Low&Donor Inc.—NPDES Discharged Water Report 3 10
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IMPROVEMENT COSTS
L&B has expended significant resources to bring its discharged water practices into compliance. This has
been a several-month process involving L&B staff,contractors,consultants,and vendor equipment
specialists.
i
Table 2. L&B Discharged Water Equipment Purchases,Installations,and Engineering Costs
i
1 Equipment
E ui meat
CasC $
l Chiller Cooling Tower
Pumps and Motors 8,769
'3 Other Modifications
Cooper Cooling Tower
Pumps and Motors 4,209
Other Modifications
I Compressor Cooling Tower
Valve 200
Boiler Condensate
Pumps,Motors,and Receivers 16,835
' Ancilla Pat1s askets,floats,switches
Flow Measurement—Heyward
7 Slim Tank 15,800
Flood Gate
DeChlorination System—Garrett-Callahan
Probes
Sodium Bisulfate Tank 12,628
Controller and Pump
3 Labor
Labor Cos $S
i Process Modifications
a
g Re-Route Process Waters—Congruent 114,824
Electrical—ME Haynes 6,744
Iron Curbing—Production Welding 8,132
{ Asbestos Removal—American Global Environmental 920
Cleaning—Mountain Environmental 5,479
Labels Stormwater,Non-Contact Wastewater MSD 400
I Environmental Engineering
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j Pisgah Environmental Services 152,507
1 Howard Earley(Previous Facilities Manager) 14,800
S
Fred Bailey(Previous Facility Electrical Engineer) 5,146
_ Ed Ho Ian(Drafting) 444
Low&Bonar Staff TBD
TOTAL 8367,837
3
Purchase Orders for major equipment purchases are also included in Attachment C.
Future costs include permit application generation and fees.
Low&Bonar Inc.—NPDES Discharged Water Report 3 I l

DISCHARGED WATER SAMPLING RESULTS
Table 3 lists the analytical results from samples collected on October 19,2017, The 96 hours prior to
sampling were dry(i.e.,no measurable rainfall). Copies of the site weather station records for October are
included in Attachment D. Table 3 sources and discharges are in the order of flow to Surface Waters. Figure
' 1 shows the sampling locations. Figure shows how each sampling location is linked in the discharge water
flow to Surface Waters. Tables 4 and 5 are discharged water results from the July 6 and 14 campaigns and
j the August 2 campaign respectively. These fatter two tables are included for perspective.
Table 3 pollutants in most cases are less than the North Carolina 15A NCAC 02B Surface Water Standards
and Protective Values. Of particular note are the copper and zinc concentrations. Based upon a review of
water treatment chemical Safety Data Sheets and raw materials used at L&B we conclude that the source of
copper and zinc are from City Water and infrastructure. Our professional judgement is that supplied City
Water in concert with building and water conveyance materials contribute most of these metals to discharge
waters.
- Our judgement is based in part upon the copper and zinc concentrations of less than(<)0.005 and 0.210
milligrams per liter(mg/L)respectively in City Water within the building. Copper is monitored by the City
of Asheville and their annual report of April 2017lists a maximum system-wide concentration of 0.005
mg/L. Although zinc is not addressed in the report,conversations with Mary Grimes of the Asheville Water
Department revealed that distribution system zinc concentrations ranged from 0.20 to 0.17 mg/L on July 28
and October 19 respectively at the North Fork Water Treatment Plant. Thus,it is conceivable that the zinc
3 concentration in the inlet water is 0.210 milligrams per liter and that concentration is not related to
infrastructure. If so,we should correct all discharge water zinc concentrations by the'background'
concentration of approximately 0.20 mg/L. That correction is not included in this report.
i
Molybdenum is no longer in discharge wafers due to its use as a 'tracer chemical' in our water treatment
chemicals supplied by Garrett-Callahan. Our water treatment contractor Garrett-Callahan has modified their
? water treatment formulation to not include molybdenum. This and future discharge water analyses should
j reflect this change.
1
Chloroform is in City Water at a concentration of 0.0195 mg/L and in Manhole 3 and the Slim Tank at
concentrations of 0.0021 and 0.0052 mg1L respectively. However,chloroform is not detected in any other
discharge source.
i
Other pollutants tested are less than State 02B Surface Water Standards or are at concentrations less than the
analytical detection limits.
Figure 2 is a site layout that shows the four(4)October 19 sampling locations. Tables 3,4,and 5 address
only those pollutants that were detected in any of the four discharge samples. All other pollutants were
reported by the laboratory at"less than the analytical method detection limit". Pace Laboratories' report is
included in Attachment A.
Table 3 lists pollutant discharge rates from the new compliance point(i.e.,the Slim Tank in the DowTherm
Room),the new stormwater sampling point(i.e, Flood Gate at head of East Ditch),and the previous
compliance point(i.e,the East Ditch)(see Figure 2). These discharge rates demonstrate that—considering
instantaneous flow variations—the Slim Tank discharge rates are in the same concentration range as the
other two points.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 12

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SCOPE OF FUTURE TESTING
Low&Bonar Inc.has evaluated its water discharge sources,their pollutants,and volume balances through
four sampling campaigns: July 6,July 13, August 2,and October 19. We believe that these evaluations meet
the stated expectations of DWR staff,which is to completely characterize discharged water quality over a
range of time and operating conditions. Therefore,we do not expect to conduct additional sampling
j campaigns.
t
? The data contained in this report should serve to form the basis of a discharged water permit application.
Ultimately,we believe this discussion will lead to a decision that a General Permit is appropriate for Low&
planar.
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' CONCLUSION
i
`. Low&Bonar intends to comply with all State and Federal discharge limitations. This third report—
encompassing four sampling campaigns—demonstrates that pollutant concentrations in the current
compliance point effluent—the Slim Tank—are below any Division of Water Resources regulatory limit or
North Carolina Surface Water Quality Standards;which are included in Attachment G.
Please approve Low&Bonar's request to complete a General Permit application for re-issuance of a
National Pollutant Discharge and Elimination System permit.
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Low&Bonar Inc.—NPDES Discharged Water Report 3 13

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Table 3. Discharge Water Sampling Analytical Results-October 19,2017
"s
Flood Gate NC DEQ/
Manhole 3-U (New DWR Water
(Upstream Stu water Quality
ofsite) Manhole Slim Took Point) East Ditch Standard'
Pollutant m ° m m m m m
Copper NA' <0.005' 0.0381' 0.0079 0.0074 0.0036(A),
i 0.0027 C
Molybdenum NA <0.005 <0.005 <0.005 <0.005 N/A
i
Zinc NA 0.101 0.561 0.146 0,143 0.036(A),
0.036 C
t Hardness NA 19.900 10.300 17.600 18.10 N/A
Total Dissolved Solids NA 78.0 99.0 58.0 63.0 TBD'
_ Total Suspended Solids NA <2.5 18,9 <2.5 <2.5 TBD7
Bromodichloromethane NA <0.002 <0.002 <6002 <0.002 N/A
Chloroform NA 0.0021 0.0052 <0.002 <0.002 N/A
t Butylbenzyl plahalate NA <0.005 <0.005 <0.005 <0.005 0.019
Oil&Grease NA 15.0 <5.0 <5.0 <5.0 TBDa
Total Nitrogen NA 2.1 0.86 1.1 0.49 N/A
Ammonia Nitrogen NA 0.6 <0.10 0.25 0.27 N/A
Total K'eldahl Nitrogen NA 1.6 0.56 0.63 <0.50 N/A
Nitrogen,
Nitrate+Nitrite NA 0.46 0.30 0.51 0.49 N/A
Chemical gen Demand NA <25 <25 <25 <25 N/A
_ Phosphorus NA 0.8 L3 0.46 0.41 N/A
Total Residual Chlorine 0.057 0.216 0.472 0.080 0. 117 0.017
H NA 6.0 6.0 5.90 5.16 6-9
t
Temperature NA 21.5 21.3 19.9 17.8 N/A
s DNA=Not Analyzed.
'Less than values(i.e.,<)reported as die analytical method detection limit and highlighted yellow.
'Bolded values exceed the NC DEQ1DWR Treshwater'Water Quality Standards of 1SA NCAC 2B-see Attachment G.
4 Units converted to milligrams per liter for ease of comparison.
1 'A=Acute,C=Chronic.
i 6 Based upon wasteload allocation calculation.Typically,not permit limited. Limit is 500 mg/L for Water Supply Waters.
'Based upon wasteload allocation calculation.Typically,limit is 50 to 100 mg/L. Limit is 10 for Drinking Waters or 20 High
Quality Waters.
'Based upon wasteload allocation calculation.Typically,limit is 10 to 20 mg/L.
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_ Low&Bomar lnc.-NPOES Discharged Water Report 14

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j EXHIBITS
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Receiver
InsGM,,e
Pipe
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Exhibit I.Boiler Condensate Receiver 4
If -
Noe
�`a'o
Z contain leaks or ,;
pas C
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Exhibit 2.Boiler Condensate Receiver 28
Low&Bonar Inc.—NPDES Discharge Water

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Dp aeam Dnm Pipi,
c,Wh led Tank
diam,Msnter.
Divemimu
Nt :cmbto
"en""'
leaks or
't1lstsnow \
utalted.
I
i Exhibit 3.Boiler Condensate Receiver 31
3
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i
- tutu narge m�e
m I m,teta
Nate ed oa ng syslemt -
Peint "
S(o,mx2ler
discharge ling
1 Appmpdate
1 disehmge line
(i.a,compressed '.
the stotmaremr - �
� wllwaon system - i
Exhibit 4.Stormwater Drainage Downcomer
i
3
i
Low&Bonar Inc.—NPDES Discharge Water
I
i
I

Capped discharge
line t.as,
Note orange nart
Exhibit S.Stormwater Drainage at Colorer,N281NQ,
td
� Fast Ditch.
Previous East Dnch
Stormsvaterand Non-
C.;Aad C.hr,
M/atuEnwharge,1cac
mingling ofdmhage
waw ard ditch al,
rot rocs Sandhill
Road and,k.".
Exhibit 6.Cooling Water Discharge Point(East Ditch)—Before Modificattions
Lew&Firm,Inc.—NPDES Discharge Water

3
' h Fast Ditch Flood Gate
FlmwdatsoUer, jr
6t! .l
t Eazt Ditch t iato
_t 4i tormwamrcomPlieoca
point}
i
} F tDitch Flood Gale
jj (hi.smrmwater
mpliwee point).
3
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9 Exhibit 7.Installation of Weir in Stormwater Discharge Point(Flood Gate)
9}
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Exhibit 8.East Ditch Flood Gate Flow Datalogger
3
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{ Low&Bomr Ina—NPDES Discharge Water
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s
�f
MCH Model
U53
`- Ultrasonic
�. FlowSrnsor
i Exhibit 9.East Ditch Flood Gate Flow Sensor and Trapezoidal Cipolletti Weir
- t
j Exhibit 10.East Ditch Flood Gate 60-Degree V-Notch Weir '..
[NOTE:Photographed at an angle;the weir is horizontal.]
3
j Low&Bonar Inc.—NPDES Discharge Water
I
1

i HACK Model _ �' lv � '
az
( Flow
t
pjwwing Plate between
a (mete Piper and
Weir
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Exhibit ll. Slim Tarilc Flow Sensor
f
No Chl e
7Atf4 "k' > 2otomelar
Outlet Chlonne
Probe and
- - Rotometer
i
1 Sri'
1 {
3
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I Sodium nisWfate
Sd i and ad TPump TaNr '.
i
i Exhibit 12.Installation of De-Chlorination System at Slim Tank by Qarrett-Callahan
7
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Low&Bona,Inc.—NPDES Discharge Water
i

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Exhibit 13.Chiller Room Pumps/Motors
All input mo
u.wtt.t
'tcsA5 tffi
end in ank,
Flin,
t.,al.,ndc
D-1101juni
s ulcus
Ulutuninw.n,
"ller liwr
A,
Exhibit 14.Slim Tank—New L&B Discharged Water Compliance Point
Low&Bonar Inc.—NPDES Discharge Water

1
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ti ATTACHMENT A
' Pace Analytical Laboratory Analysis Report
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Lory&Boyar Inc.—NPDES Discharge Water
3

tt
Pace Analytkal Servloes,LLC
i aCeAnlalytical a zzzs Nivers0e o,.
3 nh*rv�»aMn Asheville,NC 288M
(828)2W178
1
i
November 01, 2017
I
j Mc Dan March
Pisgah Environmental Services
9 Woodvale
t Asheville, NC 28804
I
RE: Project: Low& Boner 1210140
Pace Project No.: 92359949
j
i
Dear Mr. March:
Enclosed are the analytical results for sample(s) received by the laboratory on October 19, 2017.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
i
g Sincerely,
Chris Derouen
j [e-mail]
[phone]
Project Manager
a
i
Enclosures '..
I
71
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REPORT OF LABORATORY ANALYSIS WThisupon anal)not rewoau<ea.except In rml,
,9 vnNoct the When consent of PaceAnoO.1 Senix 9s,LLC. Page i of 45
09s
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3 Pace Analyffcal SeMces,LLC
S aceAnalAcal e =5 RNendde°r_
Asheville,NO 288M
exw.ps¢k5iom
(828)2547176
3
CERTIFICATIONS
i
3 Project: Low&Sonar 1210140
Pace Project No.: 92359949
i
Charlotte Cediflostion 10s
9800 Kincey,Ave.Ste 100,Huntenewile,NC 28078 South Caroline Certification#:99006001
Louisiana/NELAP Certifca0on#LAI70028 FlondafNELAP Certification#.E87627
North Carolina Drinking Water Certification M 37706 Kentucky UST Certification If:84
North Carolina Field Services Certification If:5312 urginiaArELAP Certification#:460221
North Carolina Wastewater Certification 1:12
j
Asheville Codification Me
i 2225 Riverside Dave,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Cemfcstion#:M-NC030 Vrginla7VELAP Conduction#:460222
North Carolina Drinking Water Certification#:37712
3
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REPORT OF LABORATORY ANALYSIS
Thls repot ehall not be reproduced except in foil,
Mahout the wGnen wnsent of Pace Amtrucel 8.1ces,LLC, Page 2 of 45

i
JIV Pace Analytical Services,LLC
1 .dCe A .�I a 2225 Rivaaka Dr,
! .�a l'v//V/ ly+
1 �Ds�Dxran Asheville,NC2a604
7 - (828)2547176
i
SAMPLE ANALYTE COUNT
i
Project: LowB Sonar 1210140
Pace Project No.: 92359949
Anatytes
Lab ID Sample IS Method Analysts Reported Laboratory
I 92369949001 Manhole EPA16648 JMS i PASI-C
EPA200] SHi 14 PASI-A
} EPA 2451 WAS 1 PASI-A
a
EPA625 Bpi 62 PASI-C
EPA624 GAW 36 PASI-C
SM 2540C NAL 1 PASI-A
SM 2540D MVC 1 PASI-A
TKN+NO3+NO2 Calculation EWS 1 PASI-A
EPA 350.11993 Rev 2.0 CJHi i PASI-A
EPA351.2 BRJ 1 PASI-A
EPA353.2 DMN 3 PAS4A
j EPA365.1 CJHi 1 PASI-A
I7 SM 5220D NAL I PASI-A
j 92359949002 Slim Tank EPA1664B JMS 1 PASI-C
t EPA2003 SHi 14 PASI-A
EPA245.1 WAR 1 PAS4A
EPA625 Bpi 62 PASLC
EPA624 GAW 36 PASI-C
SM 2540C NAL 1 PASI-A
SM 2540D MVC 1 PASI-A
TKN+NO3+NO2 Calculation EWS i PASI-A
EPA 350.41993 Rev 2.0 CJHi 1 PASI-A
EPA351.2 BRJ 1 PASI-A
EPA353.2 DMN 3 PASI-A
1
EPA 365.1 CJHi i PAS4A
SM 5220D NAL 1 PASI-A
i 92359M9003 Flood Gate EPA1664B JMS 1 PASI-C
EPA2003 SHi 14 PASI-A
EPA245.1 WAS i PASI-A
EPA625 Bpi fit PASI-C
i
1 EPA624 GAW 36 PASI-C
SM 2540C NAL 1 PASI-A
1 SM 2540D MVC 1 PASI A
? TKN+NO3+NO2 Calculation EWS 1 PASI-A
t
EPA 350.11993 Rev 2.0 CJHi 1 PASI-A
1 EPA 351.2 BRJ i PAS4A
1
'- EPA353.2 DMN 3 PASI-A
i
REPORT OF LABORATORY ANALYSIS
This Moon stall rat Ix,sapra.'IucN,except in Nil,
wiNwt the vmitten wnsent Of Pace M.".1 Ser4 .LLC. Page 3 o145

t
Pace Analytical Services,LLC
aceAna1ytica1
5 2225 R,NC 28a9
a Dr.
xw.r ettn Aahevilk NC a
(828)284817e
I
7
SAMPLE ANALYTE COUNT
Project: LowBBonar1210140
Pace Project No.: 92359949
Arealyters
Lab ID Sarnple 10 Method Analysts Reported Laboratory
EPA365.1 CJH1 t PASI-A
SM 5220D NAL 1 PASbA
92359949004 East Ditch EPA 1664E JMS 1 PASI-C
EPA2W.7 SHi 14 PASI-A
EPA245.1 WAB 1 PASIA
i EPA625 Bpi 62 PASI-C
EPA624 GAW 36 PASkG
SM 2540C NAL 1 PASI-A
SM2540D MVC 1 PASI-A
TKN+NO3+NO2 Calculation EWS i PASI-A
EPA 350.11993 Rev 2.0 CJH1 1 PASI-A
EPA351.2 BRJ 1 PASI-A
l
EPA353.2 DMN 3 PASI-A
i EPA 365.1 CJHi i PASI-A
SM 5220D NAL 1 PASI A
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REPORT OF LABORATORY ANALYSIS
This toped shall not be rerxodu a,except in fiul,
Wflosit the ended wnsenl0 Pace AnaFAical Services,LLC, Page 4 o(45

Pace Analyacal6a slew,LLC
' aceAnalytical® 2 25 Riverside
* ems Ash ile,NC 21AW
i (a28)25C7176
3
ANALYTICAL RESULTS
Project: Low&Sonar 1210140
I Pace Project No.: 92359949
Sample: Manh,193 Lab On 92359949001 Collected: 1 011 9/1 7 16:57 Received: 10/19/1717;50 Matnx:Wafer
! Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664E
5 Oil and Grease NO mgr- 5.0 1 10/31/17 05:32
I 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
7 Antimony NO hill 5.0 / 10/28/1714:55 10130/1715:57 7440-3"
Arsenic NO ugd- 10.0 1 1012811714:55 10/30/17 15:57 7440-38-2
1 Beryllium ND ug/L 1.0 1 1012811714:55 1013011715:57 744041-7
j Cadmium NO ug/L 1.0 1 1028/1714:55 10/30117 16 57 744043-9
Chromium NO ug/L 5.0 1 1028/1714:65 1013011715:57 7440473
Copper NO ug/L 5.0 1 10/2811714:55 10130/1715:57 744050E
Lead NO ug/L 5.0 1 1012811714:55 1013011715:67 7439-92-1
Molybdenum NO ugh- 5.0 1 1MM1714:55 1013111717:16 7439-98-7
Nickel ND u9/L 50 1 102811714:55 10/3011715:57 7440-02-0
Selenium NO uglL 10.0 1 102811714:55 1013011715:57 778249-2
Silver ND ug/L 5.0 1 1012811714:65 10/30/1715:57 7"01-224
Thallium NO ug/L 10.0 1 1012811714:65 10130/1715:67 7440-28-0
7 Hardness,Total(SM 2340B) 18900 ug/L 662 1 10/28/17 14:55 1013011716:57
Zinc 101 uglL 10.0 1 10/28/1714:55 10130/1715:57 7440E65
3
245.1 Mercury Analytical Method:EPA 245.1 Preparation Method:EPA245.1
2 Mercury NO u9/1- 0.20 1 1026/1714.45 10126/1713:55 7439-97-6
625 MSSV Analytical Method:EPA625 Preparation Method:EPA625
Acenaphthene ND ug/L 5.0 1 1012311716:30 1012811723:53 8332-9
j Acemphthylene ND ug/L 50 1 1023//716:30 10/2811723:53 208-96E
Anthracene NO u91L 5.0 1 10/23/1716:30 10/2811723:53 120-124
Benzo(a)aothracene ND ug/L 5.0 1 i=3/1716:30 1028/1723:53 56-55-3
Benzo(a)pyrene NO ug/L 5.0 1 1023/1716:30 1012611723:53 5032-8
Bemo(b)Ouamnlhene NO ug/L 5.0 1 1012311716:30 10/2811723:53 205-99-2
7 Benzo(g,h,i)parylene NO uglL 5.0 1 1012311716:30 10/2811723:53 191-24-2
Benzo(k)8uoranlhene ND ug/L 5.0 1 102311716:30 10/2811723:53 207-08-9
4-Bmmophenylphenyl ether NO u91L 5.0 1 10123/1716:30 102811723:53 10155.3
Butylbemyludhalale ND no& 5.0 1 1023/1716:30 10128/1723:53 8558-7
4-Chlom-3-methylphenol NO ug/L 5.0 1 Ill 16:30 10128W 23:53 59-50-7
bie(2-Chloroelhoxy)methane NO hill 10.0 1 102311716:30 10/2811723:63 111-91-1
bis(2-Chlomelhyl)ether NO ugdL 5.0 1 1012311716:30 10/2811723:53 111444
2-Chloronaphthalene NO hill 5.0 1 102311716:30 10128/1723:53 91-58-7
2Chlorophenol NO ug/L 5.0 1 102W1716:30 10/28/1723:53 95-57-8
' 4-Chlorophenyiphenyl ether NO ug/L 5.0 1 102311716:30 10128/1723:53 7005-72-3
3
3 Chrysene NO ug/L 5.0 1 1023/1716:30 fill 723:53 218-01-9
Dibenz(a,h)anthracene NO ug/L 5.0 1 1012311716:30 1012811723:63 53-70-3
1,3-Dichlorobenzene NO ugll 5.0 1 102311716:30 10128/1723:53 MI-73-1
1,4-Dichlorobenzene ND ug/L 5.0 1 1023/1716:30 10/28/1723:53 IM46-7
1 3,T-Dichlorobenzidine ND u9/1- 25.0 1 10123/1716:30 101 91-94-1
2,4-Dichlomphenol NO ug/L 5.0 1 10/23/1716:30 1028/1723:53 120.83-2
Diethylphlhalate NO ug/L 5.0 1 1012311716:30 102811723:53 84-66-2
2kDimelhylphenol NO ug7L 10.0 1 1012311716:30 10128/1723:53 105E7-9
`_. REPORT OF LABORATORY ANALYSIS
s
This report shall not m Wroduce4.except in full,
Date:11/01/201712:38 PM wffiwt the Mu"0ansent of Pace Analytical Services,LLC, Page 5ot 45

PaoeAmdyMcal Sm1ces,LLC
aceARal1]f,/.q'e 225R erskeDr.
I 1'i LY� trU Asheville,NC 2""
(828)2547178
- ANALYTICAL RESULTS
Projed: Nov,B Bonar 1210140
Pace Pmjed No.: 92359949
7! Sample: Manhole Lab ID: 92369949001 Colleded: 101191171657 Recelved: 1 0/1911 7 1 7:50 Matrix:Water
Parameters Results Units Repoli Limit OF Prepared Analyzed CAS No. Oual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA625
Dimethylphthalate NO ug/L 5.0 1 1012311716:30 10128/1723:53 131AI-3
Di-n-butylphthalate NO ug/L SO 1 1012311716:30 10/2811723:53 8444-2
4,6-Dinitro-2-melhylphenol NO ug/L 20.0 1 10/2311716:30 1012811723:63 534-52-1
2,4-Dinitrophenol NO ug/L 60.0 1 102311716:30 1028/1723:53 51-28-5
2,4-DiNirotoluene NO ug/L 5.0 1 102311716:30 1029/1723:53 121-14-2
2,6-DiniUulpluene NO ug/L 5.0 1 1012311716:30 1028/1723:53 606-20-2
Di-n-octylphlhalale NO ug/L 50 / 10123/17 16:30 10/28/1723:53 11744-0
1,2-Diphenylhydrazine NO ug/L &0 1 1012311716:30 10128/1723:53 12246&7
bis(2-Ethyihexygphthalale NO ug/L 5.0 1 1023/1716:30 1012811723;53 117-814
Fluoranihene NO ug/L 5.0 1 1023/1716:30 10/2811723:53 2064
Flumece NO ug/L 5.0 1 1012311716:30 10/2afl723:53 86-734
I Hexachloro-1,3-butadiene NO ug/L 5.0 1 1012311716:30 1028/1723:53 87-66B
_ Hexachlorobenzene NO ug/L 5.0 1 102311716:30 1012811723:53 118-744
Hexachlorocydopenladiene NO ug/L 10.0 1 1023/1716:30 1012811723:53 77474
- Hexachlormumne NO ugh. 5.0 1 1023/1716:30 10/28/1723:53 67-72-1
Indeno(1,2,3-oW)pymne NO ug/L 5.0 1 10123/1716:30 10128/1723:53 193-39Z
Isophoroce NO ug/L 10.0 1 1012311716:30 1028/1723:53 78-59-1
384-Methylphenol(mBp Cresol) NO U91L 10.0 1 1012311716:30 1028/1723:53 15831-104
Naphthalene NO ug/L &0 1 10123/1716:30 1012811723:53 91-20-3
Nitrobenzene NO ug/L 5.0 1 10/23/17 16:30 10128/1723:53 98-95�3
2-Nihophenol NO uglL 5.0 1 102311716:30 10/28/1723:63 88-75-5
4-Ndropherwl NO ug/L 50.0 1 102311716:30 10/2811723:53 100-02.7
N-Nitrosodimeihytarnme NO ug/L 5.0 1 1012311716:30 102811723:53 62-7&9
N-Nihow-ch-n-propylamine NO ug/L SA 1 10123/1716:30 1012811723:53 621-64-7
N-Nilrosotliphenylamine NO ug/L 10.0 1 10123/1716:30 10/2811723:53 W-30-6
2,2-Oxybis(lchloropropane) NO ug/L 6.0 1 10123/1716:30 10/2811723:53 108-60-1
- Pentachlorophenol NO uglL 10.0 1 1012311716:30 1028/1723:63 87-86-5
- Phenanlhrene NO ug/L 5.0 1 1012311716:30 10/28/1723:53 85A1-8
Phenol NO ug/L 5.0 1 10/2311716:30 1012811723:53 108-95-2
Pylons NO ug/L &0 1 1W2311716:30 102811723:53 129-00-0
- 1,2,4dnMl robenzene NO ug/L 5.0 1 1WN1716:30 102811723:53 120-82-1
2,4,6-Trichlorophenol NO uglL 10.0 1 101231171630 1012811723:53 88-06.2
€ Surrogates
mtrobenzened5(S) 70 % 10-120 1 1012311716:30 10120/1723:53 4165-60-0
2-Fluorobipheny)(S) 76 % 15-120 1 10/23/17 16:30 10/28/17 23:53 321-60-8
Teryhenybdl4(S) 92 % 11-131 1 1023/1716:30 10/2all723:53 1718-51-0
PhenoW6(S) 24 % 10-120 1 102311716:30 IOMW1723:53 13127-88-3
2-Fiuorophenol(S) 35 % 10-120 1 1012311716:30 1012811723:53 367-124
2,4,6-Tnbromophenol(S) 109 % 10-137 1 10123/17 16:30 1028117 23:53 118-79-6
624 Volatile Organics Analytical Method:EPA624
Agolein NO ug1L 5.0 1 1012611714:53 107-02-fl
Acrylonitrile NO ug/L 50.0 1 10126/1714:53 107-13-1
Benzece ND ug/L 2.0 1 1012611714:53 7143-2 '..
Bromadichleromethane NO ug/L 2P / 10/26/17 14:53 75-274
Bromofoml NO mill- 2.0 1 1026/1714:63 75-25-2
1 Bromomethane NO ug/L 2.0 1 10126/1714:63 74-83-9
j
REPORT OF LABORATORY ANALYSIS
This report shall rwl be reoraaaca4.except in full.
t} Date:11101/201712:38 PM WaNuA the wtlhen.narl of Pace AnsWcal S kax ,LLC. Page 6of 45
3

' Paae Analy6ca16ervlces,LLC
f or
1740aceAnalyficalv 2225 Rivs Me for,
xme moan Ashmfils,NC28804
[phone]
ANALYTICAL RESULTS
Project: Low&Better 1210140
Pace Project No,: 92359949
I Sample: Ma laole3 Lab ID: 92359949001 Collected: 1011911 7 1 6:57 Received: 1011911717:50 Matra:Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. 0ual
i _
624 Volatile Organics Analytical Method:EPA624
Carbon tetrachloride NO ug/L 2A 1 10/26/1714:53 58-23-5
Chlorabenzene NO ufi/L 2.0 1 10126t1714:53 108-90-7
1 Chlomelhane NO ufi/L 2.0 i 10126H714:53 75-0D3
Chloroform 2.1 ug/l. 2.0 1 10126/1714:53 67-663
Chimomethane NO uglL 20 1 10126/1714:53 7487-3
Dibromochiortmethane ND ug/L 2,0 1 1012611714S3 12448-1
j 1,24Dichlorobenzene ND u0/l 2.0 1 1012611714:53 95-50-1
1,3Dlchlorobemene NO ug/L 2.0 1 10/26/1714:53 541-73-1
i 1,40ichlmobenzene NO ug/L 2.0 1 1012611714:53 10646�7
- 1,1-Dichlomethane ND ug/L 2.0 1 10/26/1714:53 75-343
1,2-Dichloroelhane NO "fill 21 1 10/2611714:53 107-06-2
1,1-Dichercelhene NO ug/L 2.0 1 10/26/17 14:53 75-354
as-1,2-Dirhloroethene ND u91L 2.0 1 1012611714:53 156-59-2
trans-1,2-Dichimoethene NO u9/L 2.0 1 10/2611714:53 156-60.5
1,2-Dichlompropane NO ug/L 2.0 1 10126/1714:53 78-875
ds-1,3-Dichlompropene ND ug/L 2.0 1 10/2611714:53 10061-015
transd,e-Oichloropropeue NO uglL 2.0 1 10/26A714:53 IONI-02-6
Et viourozene NO ug/1- 2.0 1 W126/1714:63 100-014
Methylene Chloride ND uglL 2A 1 1012611714:53 7539-2
7,1,2,2-Tetrachloroeihane NO ug/L 2.0 1 10126/1714:63 79345
- Tehachitumelhene NO US& 2.0 1 1012611714:53 127-184
3 Toluene ND ugil 2.0 1 10/2011714:63 108-88-3
/,1,1-Trichioroethane NO "fill 2.0 1 IDMOI1714:53 71-55-6
L1,2-Tiichloroefnue ND uBIL 2.0 1 10128117 14:53 79-UO-5
Tnchloroethene ND ug(L 2.0 1 1012611714:53 79�015
Tdchioro0uorome to ne ND ug/L 2.0 1 1012611714:53 75.694
j Vinyl chloride NO ug/L 2.0 1 10/2611714:53 75-014
Surrogates
4-Bromofluorobenzene(S) 98 % 70430 i 10/28/77 74:53 460-004
Toluene-d8(S) 101 % 70-130 1 10126/1714:53 2037-26-5
1,2-Oichloroeihamed4(8) 96 % 70-130 1 10126/1714:53 17060-07-o
j 2640C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 78.0 mg/L 25.0 1 10/25/1702:21
` 2640D Total Suspended Solids Analytical Methotl:SM 2540D
S
Total Suspended Solids NO mg/L 2,5 1 10/24/1718:57
Total Nitrogen Calculation Analytical Method:TKNtNO3+NO2 Calculation
i
Total Nitrogen 2.1 mg/L 0.12 1 1013111711:15 '.
350.1 Ammonia Analytical Method:EPA 350.1 1993 Rev 2A
Nibogen,Ammonia 0.60 mg/L 0,10 1 10/2611703:10 7664-41-7
361.2 Total Kjaldahl Nitrogen Analytical Method:EPA 351.2
t
Nitrogen,Kjeldahl,Total 1.6 mg/L 0.60 1 10/31/170:47 772R37-9
REPORT OF LABORATORY ANALYSIS
- This repot shoe rot be reproduced except in Nit.
Date: 11/01/201712:38PM without the iticen convert of Pace Aneiylicel Se o,LLQ Page 7of 46

' Pace Analytkal Services,LLC
t ceAnal A'Ca(e 2225 Riverside 0r.
Y r Asheville,NC 2NN
1 r+.«rwrntaxon
(828)269-717a
1
3
ANALYTICAL RESULTS
3
Project: Low&donor 1210140
i PaceProject No.: 92359949
' Sample: Manhole3 Lab ID: 92359949001 Collected: 1 0119/1 7 1667 Received: 1011911717:50 Matra:Water
I
7 Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua]
353.2 Nitrogen,NO2/NO3 unpres Analytical Method:EPA 353.2
Nitrogen,Nitrate 0.46 mg/L 0.020 1 10120/1709:16
j Nitrogen,Nitrite NO mg/L 0.020 1 10/20/1709:16
Nitrogen,NO2 plus NO3 0.46 mg/L 0.020 1 10/20/17 09:16
366.1 Phosphorus,Total Analytical Method:EPA 365.1
3 Phosphorus 0.80 mg/L 0.050 1 10124/1705:02 7723-14-0
! 52200 COD Analytical Method:SM 5220D
Chemical Oxygen Demand NO mg/L 25.0 1 1012711720:49
3
3 Sample: Slim Tank Lab ID: 92359949002 Collected: 10/1911716:32 Received: 1011911717:50 Matra:Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
-_ HEM,Oil and Grease Analytical Method:EPA 1664B
Oil and Grease NO mg/L 5.0 1 1013111705:33
- 200.7 MET ICP Analytical Method:EPA200.7 Preparation Method:EPA200.7
3
Antimony NO ug/L 5.0 t 10/28/1714:55 10/30/1716:06 7440-36-0
Arsenic NO ug/L 10.0 1 W128/1714:55 1013011718:20 7440-38-2
Beryllium NO ug/L 7.0 1 1028/1714:55 10/30/1716:06 744041-7
Cadmium NO uglL 1.0 1 1028/1714:55 10/3011716:06 744043-9
Chromium NO ug& 5.0 1 1012811714:55 1013011716:06 744047-3
i Copper 38.1 ug/L 5.0 1 10/28/17 14:55 10/30/17 16:06 7440-50-8
Lead NO ug/L 5.0 1 10/2811714:55 1013011718:20 7439-92-1
Molybdenum NO ug/L 5.0 1 10/2811714:55 10/3111717:19 7439-98-7
3 Nickel NO ug/L 6.0 1 10/2811714:65 1013011716:06 7440-02-0
Selenium NO ug/L 10.0 1 10/28/1714:55 10/30/1718:20 778249-2
Silver NO uglL 5.0 1 1012811714:55 1013011716:06 7440-224
Thallium NO ug/L 10.0 1 10Q8/1714:55 10/30/1716:06 7440-28-0
Hardness,Total(SM 2340S) 10300 ug/L 662 1 10/28M714:55 1013011716:06
Zinc 661 ug/L 10.0 1 1012811714:55 10/30117 16:06 7440.6"
{
245.1 Mercury Analyligl Method:EPA 2454 Preparation Method:EPA 245.1
Mercury NO u9/L 0,20 1 102511714:45 1012611713:57 7439-97S
- 625 MSSV Analytical Method:EPA625 Preparation Method:EPA625
Acenaphthene NO ug1L 5.0 1 10123/1716:30 1029/1700:22 83-32-9
j Acenaphthylene NO ugll. 5.0 1 1012311716:30 10Q9/17 D0:22 208-96-8
Anthracene NO ug/L 5.0 1 1012311716:30 1012911700:22 120-12-7
Benzo(a)anfhmcene NO ug/L 5.0 1 1012311716:30 1012911700:22 56-55J
Benzo(a)pyrene NO ug/L 5.0 1 1012311716:30 10/29/1700:22 50-328
Benzo(b)flumardhene NO ug/L 5.0 1 10/23/1716:30 1012911700:22 205-99-2 '..
BeozogLitidperylene NO ug/L 5.0 1 102311716:30 10/29/170022 191-24-2
s Senzo(k)fluoranthene NO ug/L 5.0 1 1012311716:30 1029/1700:22 207-0&9
S
REPORT OF LABORATORY ANALYSIS
This report shall not be Weduced,except N full,
Date:11/01/201712:38 PM WNW the written consent of Pace Analytical Services,LLC, Page 8 of 45
i
t

Pace Analytical Semlces,LLC
' aceAnalytical a Me RNerside Or.
Asheville,NC 288N
(828)25 7176
f
3 ANALYTICAL RESULTS
Project: Low&Bonarl210140
I Pace Project No.: 92359949
Sample: Sllm Tank Lab ID: 92359949002 Collected: 10/19/1716:32 Received: 1 011 911 7 17:50 Matrbt:Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Dual
F 625 MSSV Analytical Method:EPA 625 Preparation Method:EPA625
4Bromophenylphenyl ether ND ug/L 5.0 1 10123/1716:30 1012911700:22 101-55-3
Butylbenzylphlhalale NO u91L 5.0 1 10/2311716:30 102911700:22 8568-7
t 4-Chloro-3-melhylphenol NO ug/L 5.0 1 102311716:30 1029/1700:22 59-50-7
bis(2-Chloroethoxy)melhane NO ug& 10.0 1 102311716:30 1O2911700:22 111-91-1
bis(2-Chloroethyq ether ND ug/L 5.0 1 1023/1716:30 1029/1700:22 111-,P14
3l 2-Chloronaphthalene NO ug& 5.0 1 10,TX1716:30 10129/1700:22 91-68-7
3 2-Chlomphenol ND ug/L 5.0 1 1012311716:30 1029/1700:22 95-57-8
4-Chlorophenyiphenyl ether NO uglL 5.0 1 10/2311716:30 102911700:22 7005-72-3
Chrysene NO ug/l. 5.0 1 1023/1716:30 102911700:22 218-01-9
Dibenz(a.h)anlhracene ND ug/L 5.0 1 1023/1716:30 1012911700:22 53-703
1,3-Dichlprobenzene ND u91L 5.0 1 102311716:30 1029/1700:22 541-73-1
3 IA-Dichlombenzene ND ug/L 5.0 1 10123I1716:30 1012911700:22 10646-7
30-Dichlorobenzidine ND ug& 25.0 1 10I23/1716:30 1029/1700:22 91-94-1
7 2,4Dichiomphenol ND uglL 5.0 1 10/23/1716:30 102911700:22 12033-2
Dielhylphthalate NO ug/L 5.0 1 1023/1716:30 1012911700:22 84-66-2
2,4-Dimethylphenol NO ug/L 10.0 1 10/2311716:30 10129/1700:22 10567-9
Dimethylphmalate NO uga 5.0 1 10/2311716:30 1012911700:22 131-11-3
j Di-n-butylphthalate ND uglL 5.0 1 1012311716:30 1012911700:22 M474-2
4,&Dinitro-2-methylphenol NO ua 20.0 1 10123/1716:30 1012911700:22 534-52-1
2,4-Dinitrophenot ND uglL 50.0 1 10123/1716:30 1029/1700:22 51-28-5
2,4-Dinilrotoluene NO uglL 5.0 1 1023/1716:30 102911700:22 121-14-2
2,6-Dinitrotoluene NO ug/L 5.0 1 102311716:30 102911700:22 60&20-2
Do-n-octylphtholate NO uyL 5.0 1 10/2311716:30 102911700:22 11744-0
1,2-Diphenylhydrazine ND u91L 5.0 1 1012311716:30 10/2911700:22 12266-7
_ bis(2-Ethy1hexy)phlhalale ND ug/L 5.0 1 10123/1716:30 102911700:22 117-81-7
Fluoranthene NO ug/L &0 1 10123/1716:30 1029/1700:22 206,44-0
Moraine NO uglL 5.0 1 1023/1716:30 1012911700:22 86-73-7
Hexachloro-1,3-1butadiene ND ug/L 5.0 1 102311716:30 10/29/1700:22 876&3
Hexachlorobenzene NO uglL 5.0 1 10/23M 16:30 1029/1700:22 118-74-1
Hexachloroc clopentadietre ND high- 10.0 1 1012311716:30 102911700:22 77474
Hexachloroelhane NO U91L 5.0 1 10123/1716:30 102911700:22 6742-1
Indeno(1,2,3-cd)pyrene NO ug/L 5.0 1 1012311716:30 10129/1700:22 193-39-5
.j isophorone NO ug/L 10.0 1 10/23/1716:30 1012911700:22 78-59A
3&4-Methylphenof(m&p Cresoh NO ug/L 10.0 1 1012311716:30 1012911700:22 15831-104
Naphthalene NO uglL 5.0 1 1023/1716:30 1012911700:22 et-20-3
Nitrobenzene ND ug/L 5.0 1 1012311716:30 1012911700:22 98-95.3
2-Nilrophenoi ND ug/L 5.0 1 1023/1716:30 1029/1700:22 8&75-5
4-Nltrophenil NO ug7L 50.0 1 10123/1716:30 1012911700:22 IM02-7
s N-Nihasodimethylamine NO ug1L 5.0 1 102311716:30 10/29/1700:22 6245-9
N-Nitrosodi-n-propylamine NO uglL 5.0 1 1023/1716:30 1012911700:22 62164-7
F N-Nitrosodiphenylamine NO ugli. 10.0 1 10/2311716:30 102911700:22 86-30-6
2,21-Oxybis(i-chloropropane) ND ug/L 5.0 1 10R3/1716:30 /029/1700:22 10"0-1 '..
Pentachlorophenol NO uglL 10.0 1 10123/1716:30 1012911700:22 87-86.5
Phenanmretle NO ug/L 5.0 1 10123/1716:30 102911700:22 85-01-8
' Phenol NO ug/L 5.0 1 10/2311716:30 1012911700:22 108.9&2
j Pyrene NO ug/L 5.0 1 1023/1716:30 10/2911700:22 129-00-0
j 1,2,44richlorobrimene ND ugh- 5.0 1 1012311716:30 10129/1700:22 12&824
REPORT OF LABORATORY ANALYSIS
This reapd shall rwt be mpniou ,except in on.
Date:111011201712:38 PM 14lhoutthewdnanronsentof Pace Anit,o.IServices,LLC. Page 9of 45
3

j BAn �yt a rcle Pace Analytical Service,LLC
2Ck l =5 RNen Dr.
-. 4P1 ly! Aele ille,NC 2880f
xrrn.< xmm (82e)254-7176
ANALYTICAL RESULTS
Project: Low&Bonar1210140
Pace Project No.: 92359949
l Sample: Slim Tank Lab ID: 92359949002 Collected: 10/19/1716:32 Received: 1011911 7 1 7:50 Mahm-water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Goal
_j 625 MSSV Analytical Method:EPA 625 Preparation Method:EPA625
1 2,4,6-Triahiorophenoi NO offs- 10A i 10/2311716:30 1029/1700:22 88A6-2
j Surrogares
I Nitrobenzened5(S) 43 % 10-120 1 10123/1716:30 10/2911700:22 416560-0
2-Fluombiphenyl(S) 44 % 15-120 1 10123/1716:30 1012911700:22 321-60.8
Terphenyl-E74(S) 84 % 11-131 1 102311716:30 1012911700:22 17t8-51-0
PhenoIA6(S) 14 % 10-120 1 102311716:30 1012911700:22 13127-88-3
2-Fluomphenol(8) 20 % 10-120 1 102311716:30 10129/1700:22 367-124
2,4,64dbromophencl(8) 90 % 10-137 1 102311716:30 102911700:22 118-79-6
7 624 Volatile Organics Analytical Method:EPA 624
Acrolem ND ug/L 5.0 1 102611715:11 107-02-8
j Acrylonitrile NO ugll. 50.0 1 1012611715:11 107-13-1
Benzene NO ug/L 2.0 1 1026/1715:11 71432
Bromodichloromelhane NO ug/L 2.0 1 10/2611715:11 75-274
Smmoform NO ug/l. 2.0 1 10/26/17 15:11 75-25-2
Bromomethane ND ugsL 2.0 1 1012611715:11 74-63-9
Carbon tetrachloride ND offs- 2.0 1 10/26/1715:11 56-235
Chlowtenzene ND uglL 2.0 1 10/26/17 15:it 108-90-7
Chlomethane NO ug/L 20 1 10126/1715:11 75-W3
Chloroform 5.2 ug/L 2,0 1 1026/1715:11 67-66-3
Chlommelhane NO ug/L 2.0 1 102611715:11 74-87-3
( Mbromochloromelhene ND ug/L 2.0 1 102611715:11 124484
- 1,2-Dichlombenzene ND ug/L 2.0 1 1026/17 15:11 95-60-1
$ 1,3-Dichiorobenzene ND ugh. 2.0 1 10126/1715:11 541-73-1
1,4-Dichlorobanzene NO ug/L 2.0 1 10126/1715:11 10646-7
1,1-Dichloroethane NO ug/L 2.0 1 1012611715:11 75-34-3
1,2-Dichusoelhane NO uglL 2.0 1 1012611715:11 107-06-2
1,10chior"Iftene NO u91L 2.0 1 1026/1715:11 75-354
cis-1,2-Dirhloroethene ND ug/. 2.0 1 10126/1715:11 156-59-2
transl,2-Dichlamethene ND offs. 2.0 1 10126/1715:11 156-W5
_ /,2-Dirhloropropane NO ug/L 2.0 1 1012611715:11 78A75
cis-1,3-Dichloropropene NO ug7L 2.0 1 10/2611715:11 10061-015
j trans4,3-Dichioropropene NO ug/L 2.0 1 1026/1715:11 10061-02-6
Ethylbenzene NO ug/L 2.0 1 102611715:11 100414
Methylene Chloride ND ug/L 2.0 1 11126/1715:11 76-09-2
1,1,2,2-1e1rachlor0ethan, ND ug/L 2.0 1 1026/1715:11 79-34-5
Tefrachiomethene ND ug/L 2.0 1 1012611715:11 127-184
Toluene NO uglL 20 1 102611715:11 108-88-3
7 1,1,1-Trichloreethane NO ug/L 2.0 1 1=6117 15:11 71-55E
j 1,1,2-Trichlomelhane NO ug/L 2.0 1 1026/1715:11 79-00-5
j Trithiuroethene ND ug/L 2.0 1 1012611715:11 79-01-6
I Trichlomfluoromethane ND ug/L 2.0 1 1012611716:11 75594
Vinyl chloride ND ugs- 2.0 1 1012611715:11 7"14
Sur`ogates
4-Bmmollumobenzene(S) 96 % 70-130 1 1026//715:11 460.004
Toluene-d8(8) 103 % 70-130 1 1026/17 15:11 2037-26-6
- /,2-Dichlorcethane-d4(S) 97 % 70-130 1 10/2611715:11 17060-07-0
7 REPORT OF LABORATORY ANALYSIS
This revert shell not be reprwo,ea.except in fwl,
Dale:11/011201712:38 PM a9houl the write.ooment of Pace AnaMiml$a.,LLC. Page 10 of 45
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i Pace Anely6ce18erviws,LLC
aceAna(ytical s 2225 Riverside @.
I xrx%lasatan Asheville,NC 28804
[phone]
1
ANALYTICAL RESULTS
I
Project: Low&Bona,1210140
Pace Project No.: 92359949
Sample: Slim Tank Lab ID: 92359849002 Collected: 10/19/1716:32 Received: 1 0119/1 7 1 7:50 Matra: Wafer
j Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua]
--
( 2540C Total Dissolved Solids Analyfied Method:SM 2540C
Total Dissolved Solids 09.0 mg/L 25.0 1 10125/1702'21
25413D Total Suspended Solids Analytical Method:SM 2640D
Total Suspended Solids 18.9 mg/L 2.7 1 10/24/t718:58
Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation
- Total Nitrogen 0.86 mg/L 0.12 1 10131/1711:15
350.1 Ammonia Analytical Method:EPA 350.11993 Rev 2.0
Nitrogen,Ammonia NO mgtL 0.10 t VV2611703:11 766441-7
351.2 Total Kjeltlahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeltlahl,Total 0.56 mg/L 0.50 1 10131/1700.47 7727-37-9
363.2 Nitrogen,NOVN03 unpres Analytical Method:EPA 353.2
Nitrogen,Nitrate 0.30 mgA- 0.020 1 10/2011709:17
Nitrogen,Herb, NO mg/L 0.020 1 10/2011709:17
Nitrogen,NO2 plus NO3 0.30 mg/L 0.020 1 10/20/17 09:17
365.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 1.3 mg/L 0.050 7 70/24/1705:03 7723-14-0
52201)COD Analytical Method:SM 5220D
Chemical Oxygen Demand NO mg/L 25.D 1 1012711720:49
3
j Sample: Flood Gate Lab ID: 92359949003 Cailedetl: 10/79/1710:15 Received: 10/19/17 17:50 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
- HEM,Oil and Grease Analytical Method:EPA 16645
i
( Oil and Grease NO mg/L 5.0 1 10/31/1705:33
Z00.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 2003
Antimony NO ug/L 5.0 1 10al)(1714:55 1013011716:09 7440-36-0
Arsenic NO atilt 10.0 1 1012811714:55 1013011718:23 7440-38-2
Beryllium NO uglL 1.0 1 1012811714:55 1013011716:09 744041-7
Cadmium NO ug/L 1.0 1 10rz8/1714:55 10/3011716:09 744043-9
Chromium NO ug/L 5.0 1 10/2811714:55 10/3011710:09 744047-3
Copper 7.9 ug& 5.0 1 1012811714:55 W130/1716:09 7440-50-8
Lead NO u9/L 5.0 1 tOrz8/1714:55 1013011718:23 7439-92-1
Molybdenum NO ug/L 5.0 1 10128/1714:55 10/31W 17:22 7439-W7
Nickel NO ug/L 50 1 10/2811714:55 1013011716:09 7440-02-0
Selenium NO ug/L 10.0 1 10/2ft 14:55 10130/171823 778249-2
Silver NO ug/L 5.0 1 10/28/1714:55 1013011716:09 7"0-224
j
REPORT OF LABORATORY ANALYSIS
1 This report shall not be reproducetl,except in rail,
Date:11/01/201712:38 PM mniout mevvlaen oanssutof Paw Analytical Serves.LLC, Page 11 of 45
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j

j Pace Analytical Services,LLC
aceAnalytical e =6 Riverside Or
# xwnryceUSxwm Asha,Ve,NC 28804
(028)2547V(i
ANALYTICAL RESULTS
s
Project: Low&Bonar 1210140
I Pace Project No.: 92359949
t
Sample: Flood Gate LablO: 92359949003 Collected: 1 011911 7 1 0:15 Received: 10A911717:50 Matoc:Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua)
3
2007MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 2003
Thallium NO ug/L 10.0 1 10/28/1714:55 1013011716:09 7440-286
Hardness,Total(SM 2340B) 17600 ug/L 662 1 10/2811714:55 10/30/17 16:09
Zinc 146 ug/L 10.0 1 10/28/17 14:55 10/30/17 16:09 74406641
245.1 Mercury Maly(ieal Method:EPA 245A Preparation Method:EPA 245.1
Mercury NO ug/L 0.20 1 10/25/1714:45 1012611713:59 7439-9741
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphlhene ND ug/L 5.0 1 10/23/1716:30 1029/1700:51 83-32-9
Acenaphihylene ND U911- 5.0 1 1012311716:30 1012911700:51 208-966
- Anthracene NO ugg. 5.0 1 10123/1716:30 1012911700:51 120-12-7
8ensa(a)anlhracene NO ug/L 5.0 1 102311716:30 1012911700:61 56-55-3
Bensohdieyrene ND ugo. 5.0 1 1023/1716:30 1029/1700:51 50-32-8
Benzo(b)8uoranlhene NO ug/l 5.0 1 1023/1716:30 10/2911700:51 205-99-2
Benzo(9,h,i)perylene ND ugg. 5.0 1 1023/1716:30 1029/1700:51 191-24-2
- Seozo(k)6uoranthene NO ugh- 5.0 1 1012311716:30 10/29/1700:51 207-W9
4-Bromophenylphenyl ether NO ug/L 5.0 1 10/2311716:30 1012911700:51 10155-3
Butyllonzylphlhalme NO ug/L 5.0 1 1012311716:30 102911700:51 8568-7
4-Chlow3melhylphenol ND ug/L 5.0 1 1012311716:30 1029/1700:51 59-50-7
3 bis(2-Chloreelhoxy)mehane NO ug& 10.0 1 t0/23/1716:30 1029/1700:51 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 10123/1716:30 1029/1700:51 111-044
2-Chloronaphthalene NO uglL 5.0 1 1012311716:30 1012911700:51 91-58-7
' 2-Chlomphenol NO ug/L 5.0 1 102311716:30 1012911700:51 95-57-8
4-Chlorophenylphenyl ether NO ug/L 5.0 1 1012W1716:30 1012911700;51 7005-72-3
j Chryinum ND ugll. 5.0 1 1012311716:30 102911700:51 218-01-9
7 Dileenz(a,lihnlhricene NO ug/L 5.0 1 10123/1716:30 10/2911700:51 63-70-3
i 1,3-Dlchlorabenzene NO ugg. 5.0 i 1012311716:30 1029/1700:51 541-73-1
' 1,4-Dichlorobenzene NO ugg- 5.0 1 10/2311716:30 102911700:51 10646-7
3,3'-Dichlorebenzidine ND ug/L 25.0 1 102W1716:30 102911700:51 91-94-1
i 2,4-Dichlarophenol NO ug/L 5.0 1 10/23/17 16:30 1029/17110:51 120-83.2
Diethylphthalate ND ug4 5.0 1 1012311716:30 102911700:51 8466-2
2,4-Dimeledionenol NO ug/L 10.0 1 10123/1716:30 t0129/1700:51 10567-9
Dimelhyiphthalale NO ug/L 5.0 1 1023/1716:30 1029/1700:61 131-11-3
Di-n-butyiphthalale NO uglL 5.0 1 102311716:30 102911700:51 84-74-2
4,6-Dinilro-2-methylphenoi ND ug/L 20.0 1 102311716:30 10/2911700:51 5M-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 10123/1716:30 10129/1700:51 51-28-5
2,4-Dinilrololuene NO u9/L &0 1 1012311716:30 10129/1700:51 121-14-2
2,6Dinitrotoluene NO ugli. 5.0 1 1012311716:30 1012911700:51 606-20-2
i Di-n-oc I hthalate ND ty p uglL 5.0 1 1023/17 16:30 10/29/ 7 00:51 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 102311716:30 1012911700:51 12266-7
- 1,is(2-Elhy1hexyl)phthalale NO 4/L 5.0 1 1023/1716:30 1029/1700:61 117-81-7
Fluoranthene NO ug/L 5.0 1 1012311716:30 1012911700:61 206-44-0 '..
Plumene, NO uglL 5.0 1 1012311716:30 10129[1700:51 86-73-7
j Hexachloro-1,3-0uladiene ND ugll. 5.0 1 1023/1716:30 10/2911700:51 8768-3
Hezachlombenzene NO ug/L 5.0 1 1012311716:30 10129/1700:61 118-74-1
Hexachlorocydopentadiene NO ug/L 10.0 1 10123/1716:30 102911700:51 77474
REPORT OF LABORATORY ANALYSIS
Truie repot shell not be reprMuces,exce c in lull,
Date:11/011201712:38 PM without the vmtom oanaent or Pace Matiocai 3anoaa,LLC, Page 12 of 45
a

Pace Analytical 6ervlces,LLC
llj
aceAnalyjmjfs 2 SRrvere tla pr.
xxnaran Asheville,NC 288oh
- (82e)26a7176
i
ANALYTICAL RESULTS
Project: Low&Bonarl210140
Pace Project No.: 92359949
Sample: Flood Gate LAID: 92359949003 Collected: 1 0/1 911 7 1 0:15 Received: 10119/1 7 1 7:50 Matrix:Water
` Parameters Results Units Report Limit OF Prepared Amdyzed CAS No Coal
I
625 MSSV Analyewl Method:EPA 625 Preparation Method:EPA625
Hexachloroethane NO ug/L 5.0 1 1012311716:30 10291/701151 67a2-1
moeno(1,2,4�hpyrene NO ug/L 5D 1 1023/1716:30 1012911700:51 193-39-5
tsophomne NO ug/L 10.0 1 102311716:30 102911700:51 78-59-1
} 3&4-Methylphenol(m&p Cresol) NO ug/L 10.0 1 1023/1716:30 1029/1700:51 15831-104
Naphthalene NO ug/L 5.0 1 10/23/1716:30 10129/1700:51 91-20-3
NBrobenzene NO u9/L 5.0 1 W23/171630 1029/1700'51 98-953
2-Nitrophenei NO ug/L 50 1 10123M716:30 1012911700:51 88-753
4-Nitrophenol NO LWL 50D 1 1012311716:30 1012911700:51 100-02-7
N-Nitrosodimethylamme NO ug/L 5D 1 1=311716:30 102911700:51 6295-9
N-Nihoso-di-n-propylamine NO ug/L 5.0 1 1023/1716:30 1029/1700:61 6216 -7
N-Nitrosodiphenylamine NO ug/L 10.0 t 10123117 16:30 102911700:51 86.3046
j 2,2'-Oxybis(1-chdropmpane) NO ug/L 5.0 1 I(23/1716:30 1012911700:51 101604
I Pentachiorophenol NO ug/L 10.0 1 102311716:30 1029W 00:61 87-863
Phenanthrene NO ug/L 5.0 1 102311716:30 1012911700:51 85-01-8
Phenol NO ug/L 5D 1 101231171630 10129W 00:51 108-95-2
Pyrene NO ugA- 5D 1 1012311716:30 102911700:51 129-00-0
1,2,4-Trichlorobenzene NO uglL 5D 1 102311716:30 102911700:51 120-82-1
2,4,6-Tdchlorophenol NO ug/L 10.0 1 1023/1716:30 10/29/1700:51 88-06-2
Schrager"
Nitrobenzene-0(8) 66 % 10.120 1 10123/1716:30 10129/1700:51 4165-60-0
2-Plumobiphenyl(S) 68 % 15-120 1 10123/1716:30 1012911700:51 321-60-8
Telphenyl414(S) 78 % 11-131 1 101231171630 101291170051 1718-51-0
Phenol46(S) 23 % 10420 1 10/231171610 1012911700:51 13127-88-3
2-Fluorophenol(S) 33 % 10120 1 1012311716:30 1029/1700:51 367-124
2,4,6-Tnbromophenoi(S) 96 % 10-137 1 10/2311716:30 10/29M700:51 118-79.6
I 624 Volatile Organics Analytical Method:EPA 624
Acmiein NO ug/L 5.0 1 t0/26/1715:28 107-02-8
Acrylonitdle NO ug/L 50.0 1 10261171628 107-13-1
Benzene NO ug/L 2.0 1 1012611716:28 7143-2
Bromishchioromethane ND uglL 2A 1 102611715:28 75-274
Enmedorm NO ug/L 2.0 1 102611715:28 75-25-2
' Bromomethane NO ug/L 2D 1 1026/171528 74. 3-9
l Carbon tetrachende NO ug/L 2.0 1 1026/1715:28 56-23.5
Chlarebenzene NO ug/L 2.0 1 10126/1715:28 108-90J
{ Chloroethane NO uglL 2.0 1 1012611716:28 754()0.3
' Chloroform NO ug/L 2.0 1 1012611715:28 67.66.3
Chtorometbane NO uglL 2.0 1 102611715:28 74-87J
Dibromochioromethane NO ug/L 2D 1 102611715:28 124-48-1
s 1,2-Dichlorobenzene NO u91L 2.0 1 1026/17 15:28 9550.1
1,3-Dichlorobenzene NO ug8- 2.0 i 10/26/1715:28 541-73A
1,4-Dichtorobenzene NO ugl1. 2.0 1 10/26/17 15:28 10646-7
1,1-Dichloroethane NO ni 2.0 1 10126117 16 28 75-34-3
1,2.Dichlomethane NO ug/L 2.0 1 10/261t7 15:28 107-06-2
1,1-DiMloroelhene NO ug/L 2.0 1 102611715:26 75354
da-1,2-Dichloroethene NO ug/L 20 1 1026/1715:28 1%-59-2
trans4,2-Dictdoroethene NO ug/L 2D 1 102611716:28 156410-5 '..
i
j REPORT OF LABORATORY ANALYSIS '..
I3 This repot shah na be mprWucad.except in full,
t Date:11/011201712:38 PM xiNwt Ne vmnen oansent of Pace Analyliwi ServicesLLD. Page 13 of 45
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7 Pace Anelyflwl Services,LLC
€ _ aceft(Xicala 22251tivereate Dr.
i Aehavllle,NC 28801
[phone]
i
1
1
ANALYTICAL RESULTS
I
I
Project, Lon,&Bonn,1210140
f Pace Project No.: 92359949
Semple: Flood Gale Lab ID: 92368849003 Collected: 10119/1710:15 Received: 1 0119117 1 7:50 Matrx:Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Ouai
624 Volatile Organics Analytical Method:EPA 624
1,2-Dichloropropene NO uglL 2.0 1 1012611715:28 78-87-5
cis-1,3-Dichloropropene NO uglL 2.0 1 1012611715:28 10061-01-5
trans-1,3-Dichlmoproperm NO ug/L 2.0 1 10126/1715:28 10061-028
Ethylbeneene NO uglL 2.0 1 1012W1715:28 iD0414
Methylene Chloride NO ug[l. 2.0 1 102611715.28 75-09-2
1,1,2,2-TetrochNwel1ane NO ug1L 2,0 1 1026/171528 79-34-5
Tenachlumethene NO ug1L 2.0 1 102611715:28 127ABA
Toluene NO ug/L 2.0 1 10126/1715:28 108-88-3
11,1-Tdchloroelhane NO ug/L 2.0 1 10261/715:28 71-55-6
1,1,2-Trichloroethane NO W1 2.0 1 102611715:28 79-005
Tdchlorcethene NO ug/L 2.0 1 1012611715:28 7""
Tnchioroflummurethane NO UAL 2.0 1 102611715:28 75-69-4
1 Vinyl chloride NO ugIL 2.0 1 1012M1715:28 75A14
Surrogates
4-Bromofluprobenzene(8) 98 % 70-130 1 102611715:28 460-004
Toluene-d8(S) 103 % 70-130 1 10/26/17 15:26 2037-26-5
1,2-Dichloroethane-04(S) 96 % 70-130 1 101261171518 17060-07-0
3 2540C Total Dissolved Solids Analytical Method:SM 2540C
3
Total Dissolved Solids 58.0 mglL 25.0 i 1025/17072/
j 2640D Total Suspended Solids Analytical Method;SM 2540D
I Total Suspended Solids NO mg/L 2.5 1 10124/1718:58
Total Nitrogen Calculation Analytical Method:TKN+NO3+NO2 Calculation
j Total Nitrogen 1.1 mg1L 0.12 1 10131/1711:15
I 350.1 Ammonia Ana 1 tylical Method:EPA 350.1 1993 Rev 2.0
i Nitrogen,Ammonia 0.25 mg/L 0.10 1 1012611703:46 7664-41-1
351.2 Total Kjoldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjerdahl,Total 0.63 mglL 0,50 1 1013111700:48 7727-37-9
3 353.2 Nitrogen,NO2IN03 unpres Analylical Method:EPA 353.2
Nitrogen,Nitrate 0.51 mglL 0.020 1 10/2011709:18
Nitrogen,Nine NO mglL 0.020 1 1012011709:18
( Nitrogen,NO2 plus NO3 0.51 mg/L 0.020 1 1020117 00:18
365.1 Phosphorus,Total Anahliwl Method:EPA 365A '..
{ Phosphorus 0.46 mglL (.050 1 10124/1705:05 7723A4-0
5220D COD Analytical Method:SM 6220D
Chemical Oxygen Demand NO mg/L 25.0 1 10/27/1720:49
REPORT OF LABORATORY ANALYSIS
3 This mixer vend)me be reproduced,except in Nit,
Dale: 11101/201712:38 PM ximout me venen consent of Pere Analytical Services,LLC. Page 14 of 45

Ar
/ Pace Analyucal Services,LLC
} ace AMIXicaI Q 2225 Riversitle 0,
3 nrnr➢ %cwn Minevile,NO 28804
(828)2544176
t
i
7 ANALYTICAL RESULTS
I
Project: Low&Bonarl210140
f Pace Project No.: 92359949
Sample: East Ditch LabtO: 92359949OU Collected: 10/191170930 ReCohrod: 1011911717:50 Matrix:Wafer
i
3 Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual
7
HEM,Oil and Grease Analytical Method:EPA 16649
Oil and Grease NO mg/L 5.0 1 1013111705:34
t
j 200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA20D.7
l
Antimony NO ug/L 5.0 1 1028/1714:55 70130/1718:12 7440-38-0
I Arsenic NO ug& 10.0 1 10128/1714:55 10130/1718:26 7440-38-2
Beryllium NO ug/L 1.0 1 1012811714:65 10130/1716:12 744041-7
Cadmium NO ug0. 1.0 1 10128/1714:65 1013011716:12 7440A3-9
i Chromium ND u91L 5.0 1 1012811714:55 10/30/1716:12 7440473
- Copper 7.4 opal. &0 1 102811714:55 10130/1716:12 7440-5P8
- Lead NO ug/L 5.0 1 1028/1714:55 10130/1718:26 7439.92-1
Molybdenum NO ugd- 5.0 1 10/28/1714:55 10131/1717:25 7439-984
Nickel NO ugr- 5.0 1 1028/1714:55 1013011716:12 7440-02-0
Selenium NO no& 10.0 1 10128/1714:55 10/3011718:26 778249.2
Silver ND uglL &0 1 10128/1714:55 10/3011716:12 7440-224
Thallium NO unit. 10.0 1 102811714:65 1013011716:12 7440-28-0
Hardness,Total(SM 23408) 18100 u9/L 662 1 102811714:55 10/3011716:12
Zinc 143 ugf- 10.0 1 1028/1714:55 1013011716:12 7440.66-6
l
245.1 Mercury Analytical Methotl:EPA 245.1 Preparation Method:EPA 245.t
Mercury NO ug1L 0,20 1 1012511714:45 1026W 14:02 7439-97-6
625 MSSV Analytical Method:EPA625 Preparation Method:EPA625
Acenaphlhene NO ug/L 5.0 1 10/2311716:30 1012911701:19 8332-9
} Acenaphthylene NO ug/L 5.0 1 102T1716:30 1029/1701:19 208-96-8
Anlhracene NO ug/L 5.0 1 1012311716:30 102911701:19 12042-7
Senzo(a)anlhracene NO ug/L 5.0 1 1012311716:30 10/29/1701:19 56.55.3
Benzoadpyrene NO 4L 5.0 1 10/23/1716:30 1029/1701:19 5032.8
Benzo(b)Ouoranthene NO u91L 5.0 1 10/23/1716:30 102911701:19 206.99.2
Beuzc(9.h,i)perylene NO ug/L 6.0 1 102311716:30 1012911701:19 191-24-2
Benzo(k)0uoranthene NO ug/L 5.0 1 1012311716:30 102911701:19 207-08-9
- 4-Bmmopharylphenyl ether NO ug/L 5.0 1 1012311716:30 10/29/1701:19 101-55-3
Butyibenzylphthalate NO ug/L 5.0 1 102311716:30 1029/1701:19 85.68-7
9 4-Chlom-3-methyiphenol NO ug/L 5.0 1 1012311716:30 1012911701:19 59-50.7
Ij bis(2-CMproethoxy)methane NO ag/L 10.0 1 1023/1716:30 1012911701:19 111-914
bis(2-Chlorcelhyt)ether NO ug/L 5.0 1 10123/1716:30 102911701:19 111- 14
2-Chioronaphlhalene NO ugh- 5.0 1 1012311716:30 10/2911701A9 91-58V
2-Chlorophenol NO ug/L &0 1 10123M716:30 10129/1701:19 95-57-e
4Ahlmophenylphenyl ether NO ug1L 5.0 1 102311716:30 1029/1701:19 7005-72-3
- Chrysene NO ug/L SO 1 IW3/1716:30 102911701:19 2/8-01-9
Dibenz(a,h)anthracene NO ug/L 5.0 1 10/23/1716:30 102911701:19 53-70-3
1,3-Dichlmobenzece NO ug/L 5.0 1 102W1716:30 1012911701:19 541-73-1
1,4-Dichlombenzene ND uglL 5.0 1 10/2311716:30 102911701:19 10646-7
I 3,3'Dichlorobem,dme NO uglL 25.0 1 10/2311716:30 10/29/1701:19 91-94-1
2,4-Dichimardrnol ND u911. 5.0 1 1023/1716:30 1029/1701:19 120-83-2
Dielhylphthalate NO ug/L 5.0 t 10123117 1 6:30 1012911701:19 84-66-2
j 2,4-Dimethylphenol NO ug/L 10.0 1 10231V 16:30 1029117 WAS 105-87-9
j
i REPORT OF LABORATORY ANALYSIS
I Thi>repwl"I ra w'"'odumd,except in full,
Date:111011201712:38 PM without the widen moment of Pace AmlyBcal Services,LLC. Page 15 of 45
1
a
3

7 Pace Analytical service%uo
aeektalytical a 2225 Rireislde Dr.
nxxpareraaxam AsheHle,NC Spin
(9243)25 7176
I
ANALYTICAL RESULTS
Project: Low&Bonar1210140
Pace Project No.: 92359949
Sample: East Ditch Lab ID: 92359949004 Collected: 101191170930 Received: 1011911717:50 MabIz:vvafer
Parameters Results Units Report Llmft OF Prepared Analyzed CAS No. Qua[
7
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
} Dimelhylphthalate NO ugh- 5.0 1 102311716:30 102911701:19 131-11-3
- 01-n-0utylpMhalale NO Still- 5.0 1 1012311716:30 1O29/1701:19 84-74-2
' 4,6-Dinilro-2-melhylphenol NO Still- 20.0 1 102311716:30 1029/1701:19 534-52-1
2,4-DiniVophenol NO ug/L 50.0 1 10123/1716:30 102911701:19 51-213-5
2,4-Dinitrololuene NO ug/L 5.0 1 1012311716:30 1029/1701:19 121-14-2
2,6-Dinilrololuene NO ug/L 5.0 1 1012311716:30 1012911701:19 606-204
Di-ewctyiphthalate NO ug/L 6.0 1 101231171630 1012911701:19 117-84-0
1,2-Dipheny1hydrazine NO Ug/l. 5.0 1 1012311716:30 10MI1701:19 12266-7
- lxS(2-Elhy1hexy1)phlha1ate NO u9/1- 5.0 1 1023/1716:30 10129/1701:19 117-81-7
Fluoranthene NO ug/L 5.0 1 10/2311716:30 1029/1701:19 20844-0
_ Fharrome NO ug/L 5.0 1 10/2311716:30 1012911701A9 86-734
Hexachloro-1,3-butadiene NO uglL 5.0 1 1023M716:30 102911701:19 87$8-3
Hexachlorobeneene NO IV& 5.0 1 1012311716:30 1012911701:19 118-74-1
' Hexachlorecydopentadiene NO Sg/L 10.0 1 10123/1716:30 102911701:19 77474
1 Hexachloroethane NO ug/L 5.0 1 102311716:30 102911701:19 6742-1
phhdu(1,2,3-cd)pyrane NO ug/L 5.0 1 10/2311716:30 10129/1701:19 193-3M
leophorone NO ug/L 10.0 1 1012311716:30 1029/1701d9 78,59-1
3&4-Methyiphenol(m&p Crosol) NO ug/L 10.0 1 1012311716:30 102911701:19 15831-104
Naphthalene NO S9/1- 6.0 1 10123/1716:30 1012911701:19 91-20-3
Mrobenzene NO U111 5.0 1 1012311716:30 1012911701:19 98-95-3
2-Nilrophenol NO util 5.0 1 1023/1716:30 10/29/1701:19 88-7&5
4-Nitrophenol NO Still- 50.0 1 10MI1716:30 102911701:19 100.02-7
NNdrosodimethylamine NO ug/L 5.0 1 1012311716:30 1012911701:19 82-75-9
N-Mboso-din-propylamine NO Sg/1. 5.0 1 10/2311716:30 1012911701:19 621-64-7
` N-Nitrosodiphenylamine NO ug/L 10.0 1 10/2311716:30 1012911701:19 86-306
2,7Oxybis(1-chloropropane) ND u /L
9 5.0 1 10/23/1716:30 10291701:19 108-6,5
i Pentachlarophenol NO Still- t0.0 i 1023/1716:30 102911701:19 87-865
Phenanthrene NO ug/L 5.0 1 1012311716:30 1012911701:19 85-01-8
Phenol NO ug/L 5.0 1 1023/1716:30 1012911701:/9 108-95-2
Pymne NO ug/L 5.0 1 102311716:30 1029/1701:19 129-00-0
j 1,2,4-Trichlorobenzene NO Still- 5.0 1 1023/1716:30 1029/1701:19 120-82-1
j 2,4,6-Trichioropheno1 NO ug1L 10.0 1 1012311716:30 1012911701:19 88-06-2
Surrogates
Nitrobenzene-05(S) 71 % 10-120 1 1012311716:30 10/2911701:19 4165-00-0
2-Fluorobiphenyi(S) 76 % 15-120 1 10/23117 16:30 10129117 Of 19321-60-8
Terphenyl-d14(S) 81 % 11-131 1 102311716:30 102911701:19 1718-51-0
Phenol-06(8) 23 % 10-120 1 10123/1716:30 10129/1701:19 13127-88-3
j 2-Fluorophenoi(8) 33 % 10A20 1 1012311716:30 1012911701:19 367-124
- 2,4,6-Tribromophenol(8) 94 % 10-137 1 10/2311716:30 102911701:19 118-79-6
1 624 Volatile Organics Analieal Method:EPA 624
i Acrolein ND Still- 5.0 i 10126/17 15:46 107-02-8
j Acrylonitnle NO ug/L 50.0 1 10/2611715:46 107-13-1
1 Benzene NO ug/L 2.0 1 102611715:46 7143-2
Bromotichloromelhane NO ug/L 2n 1 1012611715:46 75-274
- Bmmoform NO Still- 2.0 1 102611715:46 75-2&2
Bromomethane NO ug/L 2.0 1 10/2611715:46 74-83-9
f
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except in mit,
{ Date:111011201712:38 PM without the ennen cement of Pace AnafS lS.W.,LLG
2 Page 16 of 45
4

Pace Analytical Services,LLC
aceAnalXical a 2 25 Rive s de Dc
Asheville,NC 2ee94
- (928)25d-]1]6
ANALYTICAL RESULTS
Project: L6wR8onar1210140
1 Pace Project No.: 92359949
Semple: East Ditch Lab ID: 92359949004 Collected: 10/1911709:30 Received: 1 011 911 7 17:50 Matrix:Water
i
Parameters Results Units Report Limit DP Prepared Analyzed CAB No Chat
624 Volatile Organics Analytical Method:EPA624
Carbon tetrachloride NO ug/L 2.0 i 1026/1115:46 56-28-5
Chlorobenzene NO ug/L 2.0 1 10/26/1715.46 108-90-7
Chloroelhane NO rg/L 2.0 1 1026/1715:46 75.00-3
Chloroform NO no& 2.0 1 1O2611715:46 67.66-3
j Chloromeffirme NO ug/L 2.0 1 102611715:46 74-87-3
Dibromochlorometharle NO ug/L 20 1 1012611715AB 12448-1
1,2)ichlorobenzene NO ug/L 2.0 1 1012611715,46 95-50-1
1,3.01ohlombeozene NO ug/L 2.0 1 10126/17 16A6 541-73-1
1,4-Dichlorobenzene NO ug/L 2.0 1 10126/1715:46 10646-7
1,1-Dichloroethane NO ug/L 2.0 1 1026117 15:46 75-34-3
1,2-Oichloroethane NO ug/L 2.0 1 10/26/171 SAS 107-06-2
i,i-Dichloroethene NO ug/L 2.0 1 10/26/1715.46 75-354
dsA,2-Didl1oroelhene ND uglL 2.0 1 1O2611716.46 IW59-2
S bans-1,24Xchlomethene NO ugh. 2.0 1 10/26/17 1546 156£0-5
1,2-Dichioropropane NO ug/L 2.0 1 10/26/17 ISA6 78-875
ds4,3-Oichloropropene NO ug/L 2.0 1 10/26/17 15:46 10061-01-5
trans-1,3-01chioropropene ND ug/L 2.0 1 102611715:46 100614t2-6
Ethylbenzene NO ug/L 2.0 1 102611715,46 100414
3 Methylene Chloride NO ugn. 2.0 1 1012611715:46 75-09-2
1,12,2-Tefrachloroethane NO ugd- 2.0 i 10/28/17 15:46 79-34-5
- Tetrachloroethene NO ug/L 2.0 1 1020715:46 127-184
Toluene ND ug/L 2.0 1 102611715:46 IW88-3
1,1,1-Trichereelhane ND ug/L 2.0 1 102611715A6 71-55-6
1,12-Trichloroelhane ND ug/L 2.0 1 1026/1715:46 79-015
3 Trichioroelhene NO ugd- 2.0 1 10126/1715:46 79-015
I Tric6brolluoromethane NO ug/L 2.0 1 10/26/17 15:46 75-694
7 Vinyl chloride NO ug/L 2.0 1 10/26W 15:46 75-014
Surrogates
4-Bromofluorobenzene(S) 101 % 70-130 1 1WOM7 16:46 460-004
Toluene-de(S) 108 % 70-130 1 10/26/17 15:46 2037-265
1,2-Dichleroethane44(S) 100 % 70-130 1 10/26/17 15:46 17060-07-0
3
` 2540C Total Dissolved Solids Analytical Method:SM 2540G
- Total Dissolved Solids 63.0 mg/L 25.0 1 10/25/17 02:21
} 2640D Total Suspended Solids Analytical Method:SM 2540D
Total Suspended Solids NO mg/L 2.6 1 10/24/1718:58
i
j Total Nitrogen Calculation Analytical Method;TKN+NO3.NO2 Calculation
Total Nitrogen 0.49 mg/L 0.12 1 10/31/17 11.15
360.1 Ammonia Analytical Method:EPA350.11993 Rev 2.0
Nitrogen,Ammonia 0,27 mg;& 0.10 1 ID1261170348 766441-7 '.
3
° 351.2 Total Kjeldahl Nitrogen Analyeeal Method:EPA 351.2
1
3 Nitrogen,Kjeltlahl,Total NO mg/L 0.50 1 10/31/1700:49 7727-37-9
l
t REPORT OF LABORATORY ANALYSIS
{ This repwt shell ad be reproduced,except in full,
Date: 11101/201712:38 PM wi1hout the wnhenocns.ru of Pace AnaMicel Services,LLC. Page 17 of 45
3

I
® Pace Anaytcal Services.LLC
aceAnaVical 2 5R RN.We or.
I xm
Asheville,NC 20M
1
ANALYTICAL RESULTS
3I3 Project: Low&Boner 1210140
3 Pace Project No.: 92359949
I Sample: East Ditch Lab ID: 92359M0004 C011ected: 1 0119/17 0 9:30 Recened: 1 011 9/17 1 7:50 Matrix:Water
Parameters Result. Units Report Limit OF Prepared Analyzed CAS No. Oual
j 353.2 almagen,N021NO3 unpres Analytical Method:EPA 353.2
s Nitrogen.Nitrate 0.49 mg/L 0.020 1 1012011709:19
j Nitrogen,Nitrite NO mg/L 0.020 1 10/20/1709:19
Nitrogen,NO2 plus NO3 0.49 mg/L 0.020 1 1012011709:19
t
365.1 Phosphorus,Tonal Analytical Method:EPA 365.1
Phosphorus 0.41 mg/L 0.050 1 10124/1705A6 7723-14-0
j5220D COD Analygcal Method:SM 5220D
Chemical Oxygen Demand NO mg/L 25.0 1 1012711720:49
i
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j
REPORT OF LABORATORY ANALYSIS
This report shall rwt be repaiuce4,except in fua,
j Date:11/011201712:38PM Wthout the wnnen sonsem of Pace AsolA.1 serv:»s,LLC, Page 18 ot45

or
j �] �1 5 Pace Analytical Services,LLC
/ 4riP/'tn(7 tC8l Riverside D�
Ashville.NC 28804
1 (828)2W176
i
QUALITY CONTROL DATA
Project: Low&Sonar 1210140
i Pace Projed No.: 92359949
j QC Batch: 384601 Analysis Method: EPA1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
METHOD BLANK: 2131721 Matrix: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reporting
-. Parameter Unite Result Limit Analyzed Qualifiers
Oil and Grease m91L ND 5.0 101311110530
j LABORATORY CONTROL SAMPLE: 2131722
Spike LCS LCS %Rec
Parameter Units Cone, Result %Rec Limits Qualifiers
j Oil aM Grease mg/L 40 37.0 92 78414
j
MATRIX SPIKE SAMPLE: 2131723
923599381102 Spike MS MS %Rec
Parameter Units Result Cone. Result %Rec Limits Qualifiers
OW and Grease mg/L NO q0 39.1 95 78-174
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3
'= REPORT OF LABORATORY ANALYSIS
This relays shall tKK be repraduw0,except in Ma
Date:11101/201712:38 PM ,Wawa the,reen consent of Pace AMMLeal secause LC' Page 19 of 45
v

7 ® Pace Alienation Sam]=,LLC
2CBAnalXical zz s R ersae or
Asheville,NC 28801
1 ewx.(�tl. 1CSTn (828)2!W7176
QUALITY CONTROL DATA
Projed: Low&Sonarl210140
Pace Project No.: 92359949
QC Batch: 383897 Analysis Method: EPA245.1
OC 8atch Method: EPA245.1 Analysis Description: 245.1 Mercury
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
METHOD BLANK: 2127652 Matrix: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
j Mercury ug/L ND 0.20 10/28/1772:09
LABORATORY CONTROL SAMPLE: 2127653
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Mercury u91L 2.5 2.4 98 85-115
7
- MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2127654 2127655
MS MSD
9235ON8004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Conc. Result Result %Rec %Rec Limits RPD Qual
Mercury ug/L 4.7 2S 2.6 13.6 11.6 354 274 70.130 16 M1
s MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2127656 2127657
i
MS MSD
92360129001 Spike Spike MS MSD MS MSD %Rec
39 Parameter Units Result Conc Conc. Result Result %Rec %Bee Limits RPD Quad
i Mercury uglL NO 2.5 2,5 2.3 3.0 91 116 70-130 24 R1
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I
REPORT OF LABORATORY ANALYSIS
- Twee'd shall Not be reproduceQ except in fait
' Date:11/011201712:38 PM wimoulthevrtinenconsentd Paw AnalyBcel Service,LLC.
7j Page 20 of 45
3

® Pace Analytical Services,LLC
FI ace Analyhca' 2225 Rivenud.Dr,
/ Aaha ills,NC 28804
yaW sm
(828)254717e
"4
t QUALITY CONTROL DATA
i
Project: Low&Sonar 1210140
Pace Project No.: 92359949
QC Batch: 384206 Analysis Method EPA200.7
1 QC Batch Method: EPA200.7 Analysis Descriptum: 200.7 MET
Associated Lab Samples: 92359949001,92359949002,92359949003,923599490M
METHOD BLANK: 2129479 Mainz: Water
I Associated Lab Samples: 92359949001.92359949002,92359949003,92359949004
Blank Reporting
j Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 10130/1715:19
Arsenic ug/L NO 10A 10130/17 15:19
Beryllium ug/L NO 1.0 1013011715:19
Cadmium ug1L NO 1.0 10130/1715.19
Chromium ug/L ND 5.0 10/30M715:19
Copper ug1L ND 5.0 1013011715:19
Hardness,Total(SM 2340B) ug/L NO 662 10130117 16 29
Lead ug/L NO 5.0 10130/1716:19
Molybdenum ug/L NO 5.0 10131/1716:53
3 Nickel uglL NO 5.0 10/30/17 15:19
Selenium ug/L ND 10.0 10/30/17 16:19
Siver ug/L NO 6.0 1013011715:19
1 Thallium u9/L ND 10.0 1013011715:19
Zinc ug/L NO 10B 1013011716:29
3
LABORATORY CONTROL SAMPLE: 2129480
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
}_ Antimony utt 500 474 95 85-115
Arsenic ug/L 500 467 93 85-115
Beryllium u91 Soo 470 94 85-115
Cadmium ug/L Soo 466 93 85-115
Chromium ug/L 500 451 90 85-115
Copper ug/L Soo 473 95 85-115
Hardness,Total(SM 2340B) ug/L 30000
Lead ug/L Soo 466 93 85-115
Molybdenum ug& 500 493 99 85-115
Nickel ugk 500 453 91 85A15
Selenium ug/L 500 472 94 85A15
Silver ug/L 250 234 93 85-115
Thallium ug/L 500 462 92 85-115
Zinc ug/L 500 470 94 85-116
1
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I
l REPORT OF LABORATORY ANALYSIS
1 This repod shall not be reproduced,except Intuit,
Data:11/011201712:38 PM v401cul Mewddsu cnrt¢ntof Pace AnalyBcal Services,LLC, Page 21 of 45 '..
j

i e Pace Analytical Servlees,LLC
aceAnalytical 2225 RiversAe Dr.
b - � Auncila,NC 288W
(828)251,7176
3l
I
QUALITY CONTROL DATA
t
Project: Low&Bonar1210140
Pace Project No.: 92359949
j MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2129481 2129482
MS MSD
9235NO3001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rae Limits RPD Dual
Antimony ug/L 0.78 500 600 1250 1220 93 88 70.130 2
a mg/L
I Arsenic ug/L ND 500 600 468 464 93 92 70-130 1
? Beryllium ug/L ND Soo Soo 461 461 92 92 70-130 0
Cadmium ug/L ND 600 500 456 454 91 91 70-130 0
Chromium ug/L ND 500 500 442 439 88 87 70-130 1
Copper ug/L 0,0069 500 500 473 475 93 94 70-130 0
mI
Hardness,Total ISM 23408) ug/L 30.2 689M 67800
2
m N
Lead uglL ND 500 500 442 439 88 87 70.130 1
Molybdenum ug/L ND 500 500 458 458 91 91 70-130 0
7 Nickel ug/L ND 500 500 434 432 86 86 70-130 0
Selenium aRL ND 500 Soo 463 466 93 93 70-130 1
Silver ug/L ND 250 260 228 226 91 90 70-130 1
j Thallium ug/L ND 500 500 410 410 82 82 70-130 0
} Zinc ug/L 0.15 500 500 616 612 92 92 70.130 1
m91L
I
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2129483 2129464
MS MSD
92360131002 Spike Spike MS MSD MS MSD %Rec -
- Parameter Units Result Cone. Cone, Result Result %Rec %Rec Limits RED Dual
Antimony ug/L ND San Soo 474 472 95 94 70-130 0
Arsenic ug/L ND 50D 500 474 474 95 94 70-130 0
Beryllium ug/L ND 500 500 471 469 94 94 70430 1
1 Cadmium ug/L ND 500 500 462 459 92 92 70-130 1
Chromium ug/L ND 500 500 "a 4I 89 88 70130 2
Copper uglL ND 500 500 470 466 93 93 70130 1
i Hardness,Total ISM 2340B) ug/L 27300 55900 55900
0
- Lead ug/L ND 500 500 460 457 92 91 70.130 1
Molybdenum ug/L ND 500 500 466 463 93 93 70-130 1
Nickel ug/L ND 500 500 462 445 90 89 70-130 2
Selenium ug/L ND 500 500 481 471 96 94 700.130 2
Silver ug/L ND 250 250 230 228 92 91 70-130 0
Thallium ug/L ND 500 500 449 448 90 89 70-130 0
Zinc ug/L ND 500 500 479 476 95 94 70-130 1
7
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I
REPORT OF LABORATORY ANALYSIS
Thla report shall not be repmonlv3,except In rea,
7 Dale:11/011201712:38 PM vfrrcNthe written wassat of PawAnalytiwl Servkas,LLC, Page 22 of 45

Pace Analytical Services,LW
awna r lcala 2225 inverses 9r.
�Yr Ashevile,NO 2e886
(828)2897176
3
QUALITY CONTROL DATA
Project: Low&Bonar 1210140
Pace Project No.: 92359M
QC Balch: 384120 Analysis Method: EPA624
j QC Batch Method: EPA624 Analysis Description: 624 MSV
t Associated Lab Samples: 92359949001,92359949002,92359949003,923599490M
METHOD BLANK: 2128896 Matrix: Water
Associated Lab Samples: 92359949001,92359949002,92359949W3,92359949004
Blank Refunding
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-1fnchomelh re, ugh. NO 2.0 1012W1709:19
1,1,2,2-1etrachioroethane ug/L NO 2.0 1012611709:19
1,1,24dchloroethene uglL NO 2.0 10126/1709:19
1,T-Dichimoe0atle U9I1- NO 2.0 10/26/1709:19
1,1-Dichlomudhene ug/L NO 2.0 102611709:19
1,2-Dichlorobenzene ug/L NO 2.0 1012611709:19
lZICuchloroethane ug/L NO 2.0 10/26/170919
1,2-Dirhkimpropane ug/L NO 2.0 10/26/1709:19
1,3-Dichlorobenzene ug1L NO 2.0 1012611709:19
1,4-Didtlorabeazene ug/L NO 2.0 1026/1709:19
Acmlem ug/L ND 5.0 1012611709:19
Acrylonitude ug/L NO 50B 1012611709:19
Benzene uglL NO 20 1012611709:19
- Bramodichlommethane ug/L NO 20 1026/1709:19
Bromide. ug/L NO 2.0 1026/1709:19
Bromomelhane ug/L ND 2.0 10/2611709:19
Carbon tetrachloride uglL NO 2D 1026/1709:19
1 Chkimbenzene ug& ND 20 1012611709:19
S Chlomethane ug/L NO 2.0 1026117 B9:19
- Chloroform upr- NO 2.0 1012611709:19
Chioromethane uglL NO 2.0 1026A709:19
cis-1,2-Dichlomelhene ug/L NO 2.0 1012611709:19
cis-1,3-Dichloropropene ug/L NO 2A 10/26/1709:19
Dibromochloromethane ug/L NO 2.0 10/2611709:19
- Ethyibenzene ug/L NO 2.0 102611709:19
Methylene Chloride ug/L NO 2.0 1026/1709:19
Telrachloroelhene uge- NO 2.0 1012611709:19
j Toluene ug/L ND 20 1012611709:19
trans-1,2-Dichloroethene ug/L NO 2.0 1028I1709:19
trans-1,3-Dichloropropene ug/L NO 2.0 102611709:19
Tichlomethene uga- ND 2.0 102611709:19
Trichlomfluoromethane uglL NO 2.0 1026/1709:19
Vinyl chionde ug/L NO 20 102611709:19
j 1yDichlowethane-d4(S) % 95 70-130 10261170919
4-Bromofluorobenzene(5) % 98 70-130 10/2611709:19
Toluen"It(S) % 116 70-130 1012611709:19
I
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REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date: 11/01/201712:38 PM wiNoul the rmaen cmuent of Pace Anabirod Sarnma,L-C. Page 23 of 45
3

! a Pace Analy6Nal Services,LLC
i aceAnalytical 2225 Rirersss Dr.
'scoteln Ashville,NC 2ae04
porg250-7176
t
I
i QUALITY CONTROL DATA
f
Pitied: Low&Bona,1210140
Pace Prgect NO.: 92359949
1
LABORATORY CONTROL SAMPLE: 2128897
i Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Oualifers
1,1,1-Tn0gomethane ug& 20 20.1 1W) 52-162
1,1,2,2-Tetraddoroethane uglL 20 17.7 89 46-157
1,1,2-Tnchloroethane ug/L 20 18.8 94 52-150
1,1-Dichlomethane uglL 20 19.3 96 59-155
1,1-Dichloroethene u91L 20 20L0 100 1-234
12-ONWorobenzene ug/L 20 %2 96 W190
12-DieMoroe[hane ug/L 20 19.0 95 49-155
1,2-Dichloropropane ug/L 20 19.3 97 1-210
1,3-Dichlorobenzene ug/L 20 20.0 10D 59-166
1,4-Dichlorobenzene ug/L 20 19.8 99 18-190
Acrolein ug/L 100 144 144 15-152
Acrylonildle ug/L 100 100 100 75-132
Benzene u9/1- 20 18.7 93 37-151
Bromodichloromethane ug/L 20 19.1 95 35-155
- Brothers. ug/L 20 20.7 103 45-169
Bromomelhane ug/L 20 26.5 132 1-242
Carbon tetrachloride ug16 20 20.1 100 70-140
Chlorobenzeine uglL 20 19.4 97 37-160
Chloroethane ug/L 20 18.7 93 14-230
Chloroform ug/L 20 17.9 89 51-138
Chloromelhane ugll- 20 20S 104 1-273
cs-1,2-Dichlormunne ug/L 20 19.6 98 68-146
cis-1,3-Dichloropropene ug/L 20 204 101 1-227
Dibromochlommelhane ug/L 20 19.5 97 53-149
Ethylbenzene ug/L 20 18.9 95 37462
Methylene Chloride ug/L 20 16.5 93 1-221
- Tetrachlomethene upt- 20 20.5 102 84-148
Toluene U91L 20 18.7 94 47-150
trans-1,2-Dichloroelhene ug/L 20 20.9 104 59-156
trans-1,3-Dichloropropene ug/L 20 19A 97 17-183
Trichlaroethere ug/L 20 197 99 71-157
Trichloro8uoromethane uglL 20 20.5 102 17-181
I Vinyl chloride ug/L 20 21.3 107 1-251
€ L2-Dichloroethmm-d4(S) % 96 70-130
4-Dromo9uorobanzene(S) % 97 70d30
Toluene-d8(S) % 96 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128898 2128899
1
MS MSD
92359566002 Spike Spike MS MSD MS MSD %Rec '..
Parameter Units Result Conc. Cone. Result Result %Rec %Rec Limits RPD Oual
1,1,1-Tdchlomethane ug/L NO 200 200 208 222 104 Ill 46-171 7
1,1,2,2-Tehachloroethane ugn. NO 200 200 177 182 88 91 73A59 3 '..
1,1,2Jrichloroethaoe upl- NO 200 200 198 198 99 99 64-152 0
11-Dieflomelhane Wit- NO 200 200 195 205 97 102 43A72 5
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7
' REPORT OF LABORATORY ANALYSIS
i
This report shall too be except in Nit,
Date:111011201712:38 PM withoutthewmercommulof Pace Anatutal Services,LLC. Page 24 of 45

i
} Pace Analylleal S.Ims,LLC
aceAnatyticaf a 225 R ers tle Dr.
Ashenlia,NC 2UN
xwxp'weOAxam
- (826)250.]1]6
3
QUALITY CONTROL DATA
a Project: Low&Sonar 1210140
Pace Project No.: 92359949
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128898 2128899
MS MSD
92359566002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conn Cow Result Result %Rec %Rec Limits RPD Qual
3
1 t,1-D7chloroelhene uglL NO 200 200 274 231 107 115 48-189 7
3` 1,2-Dichlorobenzene ug/L NO 200 200 196 198 98 99 54-054 1
I 1,2-Dichloroethane ug/L ND 200 200 192 208 96 104 42-171 8
- 12-Dichloropropane ug/L NO 200 200 197 205 99 102 W157 4
1,3-Dichlorobenzene MM_ NO 200 200 198 200 99 100 57-148 1
j 1,4-Dichlorobenzene ugll NO 200 200 196 200 98 100 58-149 2
Acrolein ugg- NO 1000 1000 1320 1430 132 143 70-130 8 M1
Acrylonildle uglL NO 1000 1000 978 1060 98 108 70-130 10
Benzene uglL NO 200 200 192 197 96 99 54-163 2
Bromodichloromelhane u9I1- NO 200 200 194 200 97 100 56-152 3
} Bromolorm ug/L NO 200 200 /81 192 91 96 53-151 6
Bromomelhane ug/L NO 200 200 167 219 83 109 10-200 27
3 Carbon tetrachloride ug/L NO 200 200 207 212 104 106 41-175 2
Chlorobenzene ug/L NO 200 200 202 201 101 100 67-162 1
Chioroelhane high- NO 200 200 190 208 95 104 23-200 9
Chloroform ug/L 114 200 200 309 315 98 101 51-166 2
Chlommethane uglL NO 200 200 171 179 86 90 40-175 5
cia-1,2-01chloroethene ug/L NO 200 200 205 215 103 108 45-174 5
- cs-1,3-Dichimopropene u9/L NO 200 200 196 203 98 102 38-146 4
Dlbromocbbromelhane ug/L NO 200 200 196 194 98 97 65-144 1
Ethylbenzene ug/L NO 200 200 211 214 105 107 57-162 1
Methylene Chloride u90. NO 200 200 205 217 102 108 40-167 6
Telrachloroethene ug4. NO 200 200 214 223 107 ill 59-155 4
Toluene "gill. ND 200 200 190 191 95 95 47-162 0
transAZDichloroelhene ugA_ NO 200 200 207 221 104 110 47-178 6
trons4,3-Dichloroprapene ugll. NO 200 200 190 197 95 99 39-148 4
s Trichioroelhene ug/L NO 200 200 205 219 103 110 60-153 7
Tdchloro0uoromelhane ug/L NO 200 200 220 237 110 119 42-199 8
i Vinyl chloride u9/L NO 200 200 224 230 112 115 46-176 2
1,244chlomethane-d4(S) % 99 102 70-130
4 Bmmol uorobenzene(S) % 101 103 70130
Toluene-d8(S) % 91 92 76130
's
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REPORT OF LABORATORY ANALYSIS
This report shaibrot be reoixf ed,except in lull,
Date:11101/201712:38 PM wMeut Me written omsent of Pace Analytical Seniors,LLC. Page 25 of 45
7

t
Pace Analytical Se Iced,LLC
aceftlyical e 2225 Riverside
Asheville,NC 28804
xxwµxe'a6sRm
[phone]
1
QUALITY CONTROL DATA
I
Project: Loe&Boner 1210140
i Pace Project No.: 92359949
i
t! QC Belch: 383560 Analysis Method: EPA 825
{ OC Batch Method: EPA625 Analysis Description: 625 MSS
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
METHOD BLANK: 2125770 Matrix: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
t't Blank Reporting
'g Parameter Units Result Limit Analyzed Qualifiers
1,44Jachiorothemom a ug& ND 5.0 10/26/17 21:25
1,2-Diphenylhydrazine Mill ND 5.0 1028/1721:25
1,&Dichlorosenzene ug/L ND 5.0 1012611721:25
1,4-Dichlorobenzene ug/i. NO 5.0 10126/1721:25
2,Y-0xybis(1-chloropropme) ug/L NO 5.0 10/26/1721:25
2,4,6-Tdchlorophenol ugA- NO 10.0 1012611721:26
2,4-Dichlorophenol ug/L NO 5.0 1012611721:25
2,4-Dimelhylphenol ug/L NO 10A 102611721:25
2,4-Dinilrophenol will. NO 50.0 10/2611721:25
2,4-Dim rotoluene ug/L ND 5.0 1026117 2125
2,6-Dinitrotoluene ug/L NO 5.0 1026/1721:25
I 2-Chtoronaphthalene ug/L ND 5.0 1012611721:25
2-Chlorophenol ug/L ND 5.0 10R6/1721:25
2-Nitrophenal ug/L NO 5.0 1028/1721:25
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 10126/1721:25
3,T-Dichlorobenzidine ug/L NO 25.0 1012611721:26
4,6-Dlnitro-2-methylphenol ug/L NO 20.0 1012611721:25
j 4-Bromophenyiphenyl ether ug/L NO 5.0 10126/1721:25
4-Chioro-3-methylphenol ug/L NO 5.0 IG26/1721:25
4-Chlorophenylphenyl ether ug/L ND 5.0 10261172125
4-Nitrophenol ug/L NO 50.0 10/26/1721:25
Acenaphlhese ug/L ND 5.0 1026/1721:25
Atinaphthymne ug/L NO 5.0 102611721:25
Anthracene uglL NO 5.0 1012611721;25
Benzo(a)aNhracene ug/L NO 5.0 1012611721:25
Benzo(a)pyrene ug/L NO 5.0 10261172125
Berizo(b)fluomnthene ug/L NO 5.0 1012611721:25
Senzo(g,h,i)perylene ug/L NO 5.0 1026/1721:25
6enzo(p6umaNhene Mill NO 5.0 1026/1721:25 '..
t bis(2-Chlomethoxy)methane ugll NO 10.0 1026/1721:25
bis(2-Chloroelhy0 ether ug/L NO 5.0 1028//72125
bis(2-Ethylhexyl)phlhalete ug/L. NO 5.0 1026/172125
Butyibenzylphthalate ug/L ND &0 1012&1721:25 '.
Chrysene og/L NO 5.0 1026/172125 '..
3 Di -hutylpnthalate ug/L ND 5.0 1012611721:25
Di-n-ochlphthalate ug/L NO SO 102611721:25
Dibenz(a,h)anthrecene ugA- NO 5.0 102611721:25
Dlethyiphthalate uga- ND 5.0 10/26/1721:25
Dimethylphthalale ug/L NO 6.0 RV26/172125 '..
j Fluorenthene ug/L ND 5.0 10126/1721:25
} Formene tag/L NO SO 10126/172125 '..
i aesuae preseme00n INS page are In the units iMIcated by m.-MNh-comma oeeepl xMre on anemete N0l is"biees tome more onk,ryoNt.
REPORT OF LABORATORY ANALYSIS
7N$repot(shall not be reproduced,except In MI,
j Date: 11/)11201712:38 PM Wthoot the"Va..1 or Pam Analytical Setviuu,LLC. Page 26 of 45
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1
� Pace Analytical Smdi ,LLC
i1 / ; eAnalXicale 2.ika. G28Cr.
ASM1evilk,NC 288(N
w....yaacmn
(828)254]1]8
1
QUALITY CONTROL DATA
3
i
Project: Low&Bonar 1210140
Pace Project No.: 92359949
i
� METHOD BLANK: 2125770 Matrix: Water
Associated Lab Samples: 9235994gOD1,92359949002,92359949c03,923599490D4
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloro-1,341utadiene ug/L NO 5.0 1012611721:25
Hexachlorobenzene ug/L NO 5.0 101261172125
Hexachlorogdopentodien, Ug/L NO 10.0 1012611721:25
Hexachloruethane ug/L NO 5.0 10/26/1721:25
Indeno(1,2,3cd)pyrene ug/L ND 5.0 10126/1721:25
Isophorone ug/L NO 10.0 10126/172125
3 N-Nitrom-din-propylamine ug/L ND 5.0 1012W1721:25
N-Nitrosatlimethylamine ug/L ND 5.0 1012611721:25
N-Nitrosodiphenylamine ug/L ND 10.0 1012611721:25
Naphthalene Ig/L NO 6.0 1026/1721:25
j Nitrobenzene ug/L NO 5.0 102611721:25
Pentachlorophenol ug/L NO 10.0 1026/1721:25
Phenanthrons ug/i. NO SO 1026/1721:25
Phenol ug/L ND 6.0 10126/172126
Pymne ug/L NO 5B 1012611721:25
2,4,6-Tribromophenol(S) % 91 10-137 10/26/1721:25
2-Fluombiphenyl(8) % 75 15-120 10/261172125
:j 2-Fluorophenol(S) % 35 10-120 10261172125
Nilrobenzene-a5(S) % 68 10-120 Ili 2125
PhenoWh;(S) % 25 10-120 1026/172125
1 TerphenyW14(S) % 88 11-131 10/26/172125
LABORATORY CONTROL SAMPLE: 2125771
Spike LCS LCS %Ras
Parameter Units Cons. Result %Rao Limits Qualifiers
1,2,4-Tdchlorobenzene ug/L 50 31.3 63 44-142
1,240iphenylhydrazine ugn- 50 38A 76 25-150
i 1,3-Dichlorobenzene ug/L 50 27.7 55 /-172
( IA-Dichlorobenzene ug/L 50 28.3 57 20-124
j 2,2-Oxybis(1-chloropropane) ug/L 50 22.6 45 36-165
2,4,6-Tdchlorophenol ug/L 50 47.6 95 37-144
2,4-Dicidorophenol ug/L 50 42.6 85 1-191
7 2A-Dimethylphenol ug/L 50 44.4 89 32-119
2,4-Dinilropitenol ug/L 250 237 95 1-181
t 2,4�Dinitrololuene ug/L 50 50S 102 39-139
2,6-Din0rotoluene UgIL 50 53.4 107 50-158
2Chloronaphthalene Ug/L 50 38.7 77 60418
2-Chlomphenol ug/L 50 35.5 71 23-134
2-Nitrophenol ug/L 50 52.2 104 29-182
3&4-Methylp1en gp&p Cresson ug/L 50 29.4 59 25-150
3,3'-Dichlarobenzidine uglL 100 83.5 84 1-262
4,6-Dinitro-2-melhylphenol ug/L 100 102 102 1-181
I 4-Bromophenylphenyl ether ug/L 50 4 A 89 53-127
4-Chioro3-methylphenol U9/L 100 80.9 81 22-147
Resugz presaNM on lNz page areln MnunMs In®wleEey Oe"UMIs"column eznpl xfien anallemele uNlbprezaMeJfo NerlpM qNe maWt '.
REPORT OF LABORATORY ANALYSIS
i
( This report 9r1S0 not Ys repro4uced,except in foil,
Dale: 11/Oi/201]12:38 PM MUsut the wdaen consent or Pax Anatylkol Services,LLC. Page 27 of 45
)

- Pace Analytical Services,LLC
aceAna(ytical e 5 Riv rs de
AaM1avilk.NC 28084
metPa<ootteamc
j [phone]
i
j QUALITY CONTROL DATA
Project: Low&Boner 1210140
Pace PlojeO No.: 92359949
i
LABORATORY CONTROL SAMPLE: 2125771
Spike CS LCS %Rec
Parameter Units Cooc. Result %Rec Limits Qualifiers
4-Chlorophenylpheny)ether ug/L 50 39.1 78 25-158
j 4-Nitrophenol ug/L 250 83.1 33 1-132
Acenaphthene ug/L 50 40.1 80 47-145
Acenaphthylene mfl- 50 41 3 83 33-145
Anthracene ugb- 50 44.0 88 1-166
Benzo(a)anthrsome, uglL 50 45.6 91 33143
j Benzo(a)pyrene uglL 50 39.5 79 17-163
Benzo(b)fluorenthene ug/L 50 38.5 77 24-159
Benw(g,h,i)perylene ug/L 50 40.2 80 1-219
Beneo(kpoomnthene ug/L 50 38.2 76 11-162
bis(2-Chhhoeth ncy)methane ug/L 50 40.1 80 33-181
bis(2-Chloroelhy0 ether ug/L 50 34.7 69 12-158
bis(2-EOylhexyi)phthalale ug/L 50 47.9 96 8-158
Butylbentylphthelate ug/L 50 49.4 99 1-152
Chrysene ug/L 50 45.1 90 17-168
Di-n-0utyiphthalate ug/L 50 43,7 87 1418
Di-n-octylphthalate ug/L 50 521 105 4-146
Dibenz(a,hpirthrawne ug/L 50 42.3 85 1-227
Diethylphlhalate ug/L 50 41.3 83 1414
Dimethyiphthatate ug/L 50 42.3 85 1-112
Flnoranthene upt. 50 43.1 86 26137
Fluorene ugr- 50 41.4 83 59-121
Hexachloro-1,3�butediene ug/L 50 27.4 55 24-116
- Hexachlorobenzene ug/L 5o 44.5 89 1-162
3 Haxachlorocyclopenladiene ug/L 50 32.2 64 25-150
Hann chloroethane u911- 50 25S 52 40-113
- indeno(L2,3-cd)pyrene ug/L 50 41.0 82 1-171
isophorone ug/L 50 40A 81 21-196
N-Nitrosodi-n-propybraine ug/l 50 40.7 81 1-230
( N-Nltrosodimethylamle min- 50 21.3 43 26-150
N-Nitrosreiphenylamine ug/L 50 44.6 89 25-150
Naphthalene ug/L 50 34.8 70 21-133
Nitrobenzene ug/L 50 37.0 74 35-180
Pentachlorophenol ug/L 100 107 107 14-176
Phenanihrene ug/L 50 43.0 86 54-120
Phenol ug/L 50 16.2 32 5-112
Pyrene ugt- 50 43.3 87 52-115
2,4,6.Tdbromaphenol(S) % 109 10A37
2-Flucrobiphenyl(S) % 80 15-120
2-Fluomphenol(S) % 39 10.720
' Nibobenzened5(S) % 76 10-120
Pherei(S) % 29 10-120
I Terphenyldl4(8) % 80 11-131
j
Revulle motowed en ohl,page Bro In in.una6 Indicated by the-urv18"munch except whme en Bttemele unit is presented to the debt of the result.
)
j
REPORT OF LABORATORY ANALYSIS
I Thia hoped thW W be Iepoplem0,except in MI,
Date:111011201712:38 PM wnhcut ure weinen omaent of Paw Analytical Smvkes,LLC. Page 28 of 45

Pace Analytical Services,LLC
I / ,(( eAnpj6ca. I =5Rivenke Dr.
i Dxmn Asheville,NC 28804
xSns
- - [phone]
QUALITY CONTROL DATA
Project Low&Sonar 1210140
( Pace Project No, 92359949
MATRIX SPIKE SAMPLE: 2125772
35342210002 Spike MS MS %Rec
Parameter Units Result Cone Result %Rec Limits Qualities
-{ 1,2,4-Trichlorobenzene uglL 0,96U 50 20.4 41 44442 M1
S 1,2-Diphenylhyrlrazilw ug/L 0.9oU 50 32.4 65 25-150
1,3-Dichlorobenzene ugr- 0.81U 50 18.8 38 1.172
1,4-Dichiorobenzene ugA- 0.95U 50 %0 38 20-124
2,2-0xybis(1-chloropropane) ugll. 0.951.1 50 16.3 33 36-166 M1
2,4,6-Trichlorophenol ugaL 1.31.1 50 33.6 67 37-144
- 2,4-Dichlorophenol U91L 1.7U 50 24,8 50 1-191
2,4-Dimelhy)pheuol ug& 1.2U 50 27.1 54 32-119
2,4-Dinitrophenol ug/L 9.01.1 250 230 92 1481
2,4-Dinitrololuene ug/L 0.90U 50 47.2 94 39-139
2,6-Dinitrotoluene ug/L 0.981.1 50 "A 89 50-158
2-Chloranaphthakne ug/L 0.981.1 50 25.5 51 60-118 Mt
( 2-Chlorophenol u91 1.31.1 50 21,0 42 23.134
?_ 2-Nitrophenol ug/L 0.911.) 50 30A 61 29482
384-Methylphenol(mBp Cresol) U91L 2.01.1 50 16.4 33 25450
3,T-Dichlorobenzirline ug/L 2.1U 100 75.6 76 1-262
4,6-Dinitro-2-methylphenol ug/L 2.6U 100 102 102 1-181
4-Bmmophenylphenyl ether ug/L 0.8211 50 37.7 75 5&127
I 4-Chlow-3-methylphenol ug/L 3.7U 100 58.5 58 22-147
j 4-Chlorophenylphenyl ether ug/L 0.871.1 50 30.7 61 25.158
4-Nitrophenol ug/L 4AU 250 81.3 33 1-132
Acenaphthene ug/L 0.251.1 50 29A 58 47-145
- Acenaphthylene ug/L 021U 50 29.5 59 33A45
Anlhracane ug/L 01 50 41.7 83 1-166
Benzo(a)anthracene ug/L 0.331J 50 45.3 91 33-143
Benzo(a)pyrene ug/L 0.301.1 50 39.6 79 17-163
Benzo(b)fluomnlhene ug& 0.28U 50 38.9 78 24459
Benzo(g,h,i)perylene ug/L 0.381.1 50 40A 81 1-219
j Benzo(k)guoranthene ugA- 0.431.) 50 37.8 76 11-162
bis(2-ChImoethoxy)melhene real- 0.92U 50 22.8 46 31184
bis(2-Chlrroethyl)ether egg. 1.01.1 50 20.8 42 12A58
3 bis(2-Ethylhexyl)phlhahte ugA. 0.7911 60 48.9 98 6.158
Butylbenzylphthelate ugA- 079U 50 50.0 100 1-152
f Chrysene ug/L 0.21U 50 452 90 17-168
i Di-n-butylphlhalale ug/L 0,75U 50 43.8 88 1-118
t Di-n-octylphthalate ug/L 0.66U 50 53.4 107 4-146
i
Dibenz(a,h)anlhracene ug/L 0.55U 50 42.0 84 1-227
7 Dielhylphlhalale ugaL 0.581.1 50 38A 77 1-114
j Dimelhylphthalate ug/L 0.76U 60 36.0 72 1-112
Fluoranthene ug/L 0.2111 50 43.3 87 26-137
] Fluorene ug/L 0.21U 50 33.6 67 59-121
Hexachloro-1,3-butadiene U91L 0.941.) 50 17.9 36 24-116
Hexachlorobenzene U91L 0.721.1 50 40.1 80 1-152
Hexachlorogdopenta4iene ug/L 0.881.1 50 20.5 41 25A50
Hexachlomethane ug/L 1.1U 50 17.1 34 40-113 M1
Ineen0(1,2,3-mpyrene ug/L 0.291.1 50 41.4 83 IA71
- Isophorone ugh. 0.891.1 50 23.4 47 21A96
Reruns msma a onteapp am in me unna 4,m atae byun-umm-<aumn amWeemanaim-meurnlsmame ato tNn ornre mun.
t
REPORT OF LABORATORY ANALYSIS
This report shell nW be mplm4 ,except in Me,
7 Date:11101/201712:38 PM wMout they en mnseut or Pem Malytlml 3ervims,LLC- Page 29 oi45

j Pace An.W.]Services.LLC
aceAnalXical® As2n25 e.NG 2 0,Or.
t he a Riverew.
1 arcxp�'a4spxn (828)254-]1]a
QUALITY CONTROL DATA
i Project: Low&Sonar 1210140
Pace Project No.: 92359949
MATRIX SPIKE SAMPLE: 2125772
35342210002 Spike MS MS %Rae
Parameter Units Result Cone. Result %Rec Umhs Qualifiers
j N-Nihesodbn-propylamine ug/L 0.99U 50 23.0 46 1-230
N-Nirosodimethylamine ug/L 0.91U 50 13.0 26 25-150
i N-Nitrosodiphenylamine uglL 1.0U 50 4DO 80 25-150
Naphthalene ug/L DMU 50 22.0 44 21-133
Nitrobenzene ug/L 1AU 50 22.5 45 35-180
Pentactiorophenol ugA 4.6U too 108 108 14-176
Phenamhmne ug/L 0.22U 50 40.7 81 54-120
3 Phenol ugn- 1.9U 50 9.0 18 5-112
Pymne ug/L 0.19U 50 43.3 87 52-115
- 2,4,&Tribromophenol(8) % 99 10.137
2-Fluorobiphenyl(S) % 49 15420
2-Fluomphenol(8) % 23 10-120
- NOrobenzene-05(S) % 45 10-120
9 Phenol-06(8) % 16 10-120
Terphenyl-014(S) % 57 11-131
SAMPLE DUPLICATE: 2125773
35342561002 Dup
Parameter Units Result Result RPD Qualifiers
1,44-Tridtlorobenzene ug/L 0.98U NO
1,2-Diphenylhydrazine ug/L 0.90U NO
1,3-Dichlorobenzene ugA- 0.81U NO
1,4-Dichlorobenzene ug/L 0.95U NO
3 2,2041 is(lchloropropane) ug/L 0.95U NO
2,4,6-Tdchlorophenoi ug/L 1.3U NO
2,4-Dichiorophenol ugn- 1.7U NO
2,4-Dimelhylphenol unit- 1.2U NO
2,4-Dinitrophenol ug/L 9.OU NO
2,4-Din0rotoluene U9I1- R90U NO
f 2,6-Dinitrololuene ug/L 0.98U NO
2-Chloronaphthalene ug/L 0.98U NO
2-Chlorophenol ugf- 1.3U NO
2-Nitrophenol ug/L ORIU NO
s 384-Methylpe,nol(mBp Cresol) ug/L 2.OU ND
? 303 Dichiorobenzidine owl- 2.1U NO
4,6-Dinitro-2methylphenal ug/L 2.6U NO
4-8romophenylphenyi ether ug/L 0.82U NO
4-Chloro3-methylphenol ug/L 3.7U NO
3 4-Chlorophenyiphenyl ether uglL 0.87U NO
4-Narophenol ugn- 4.1U NO
- Acenaphthene ug/L 0.25U NO
Acenaphihylene ug/L 0.21U ND
Anlhmcene unit- D14U NO
Benza(a)anthracene ug/L D33U NO
Benm(a)pyrene ug/L 0.30U NO '..
ft...prvx.d on uxe pa fie ere M Me uMte l n2ealea oy.-Unets' en anmub aor to yresmlea to are noes arm rxrtlL
- REPORT OF LABORATORY ANALYSIS
This report shah not 0e repr H,...pt is fun,
} Dale:it/Oi/201]12:38 PM wih tthe written reason of Pace Anaynme Services,LLQ Page 30 of 45
i
i

i
} Pace Analytlaal Servlpsa,LLC
aceAnalytical®Ar
2235 R 2II Dr.
Asheville,.N NC C 28804
: s'rx dsmn (e2e)254-7176
k
I
QUALITY CONTROL DATA
Project Low&Bonar 1210140
- Pace Project No.: 92359949
SAMPLE DUPLICATE: 2125773
35342661002 Drip
Parameter We Result Result RPD Qualifiers
Benzo(b)8uomnthene ug/1. 0.2813 NO
Benzc(g,h,pperylene ug/L 0.38U ND
Benzo(k)tluoranthece ug/L 0.43U ND
bis(2-Chloroethoxy)melhane upt, 092U ND
§ bis(2-ChlorceUyl)ether ug/L 1.OU ND
bis(2-E(hylhexyl)phthalate ug/L 0.79U NO
Butylbenzylphlhalate ug/L 0.79U NO
i Chrysene ug/L 0.21U ND
Di-nbutylphlhalate ug/L 0.751) ND
Di-n-oatyiphthalate ug/L 0.661) NO
Dibenz(a,eanthracene uglL 0.55U NO
Diethylphthalare ug/L 0.5811 NO
Dimethylphthalale ug/L 0.76U ND
Fiuoranlhene ug/L 0.21U ND
Fluorene ug/L 021U ND
_ Hexachloro-lgbuwdiene ug/L 0.941) ND
Hexachlorobenzene ug/L 0.72U NO
j Hexachlorocyclopentadiene ug/L 0.88U ND
Hexachlorcethane ug/L 1.1U NO
Imleno(1,2,3-cd)pyrene ug/L 0.2911 NO
_- Isophorone ug/L 0.89U NO
N-Nilrosodi-rvpropylamine ug/L 0.99U ND
i
N-Nilrosodimethylamine ug/L 0.911) NO
a N-Nilrosodiphenylamine u9/l 1.0U NO
Naphthalene ug(L 0.34U ND
Nitrobenzene ug/i. 1.1U ND
Pentachlorophenoi ug4 4.61.1 ND
Phenanthrene ug/L 0.22U ND
Phenol ug/L 1.9U NO
Pymne ug/L 0.19U ND
2,4,6-Tribromophenol(S) % 106 84 24
2-Fhiowlxphenyi(S) % 65 46 35
2-Fiuomphenol(S) % 31 22 34
NitrobenzeneA5(S) % 62 46 28
{ Phena4d6(5) % 21 15 34
[ Terpheny"14(8) % 64 46 34
3
7
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f
1
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j REPORT OF LABORATORY ANALYSIS
3
3
This repM shall rKK be reproduced,axcepl in MI,
Date:11/DiY101]12:38 PM wNrwtthe written mnsent of Paw AnalytiWl Servkce,LLG Page 31 of 45
j

i
Pace Analytical Services,LLC
[ aceAnalyhcal® 2225eRiverside NCies
3
Asheville,NC28Ba4
� [phone]
l
QUALITY CONTROL DATA
1
Project: Lob,&Better 1210140
Pace Project No.: 92359949
QG Batch: 383805 Analysis Method: SM 2540C
QC Batch Method: SM 2540C Analysis Desaiplion: 2540C Total Dissolved Solids
Amounted Lab Samples: 92359949001,92359949002,92359949003,92359949004
t METHODBLANK: 2127224 Mainz: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
j Total Dissolved Solids high- ND 25.0 1012511702:21
1 LABORATORY CONTROL SAMPLE: 2127225
] Spike 1-CS LCS %Rec
Parameter Units Co... Result %Rec Limits Qualifiers
j Total Dissolved Solids mglL 250 250 100 90-110
i
i SAMPLE DUPLICATE: 2127226
92359872004 Cup
Parameter Units Result Result RED Qualifiers
Total Dissolved Solids mg/L NO NO
i
SAMPLE DUPLICATE: 2127227
92359962001 Dole
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mglL No 855 1
I
I
I
I
I
I
Reath.1rv,vM1d on Mls case are in Me units lnMnlen by Me'Unite Column exeepl"am an eaemtle unit is presented to tho ngM or the mus.
j
REPORT OF LABORATORY ANALYSIS
This return shell not be reproduced,except in not,
Date:111011201712:38 PM vitt Me carmen consent or Pam Anal,bral saema,LLC. Page 32 of 45

j Pace ARatyliml Services,LLC
eAnalytical® 4225RivetsiJe Dr.
Asheville,NC 28884
(828)2tW7176
3
}
QUALITY CONTROL DATA
7
I
Project Low 8 Sonar 1216140
i Pace Project No.: 92359949
QC Bath: 383793 Analysis Method: SM 2540D
QC Batch Method: SM 2540D Analysis Onalunption: 2540D Total Suspended Solids
3 Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
] METHODSLANK: 2127190 Manx: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
_ Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Suspended Solitls mg/L ND 2.5 1012411718:52
LABORATORY CONTROL SAMPLE: 2127191
Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Oualifiers
Total Suspended Solids mglL 250 236 94 90-110
SAMPLE DUPLICATE: 2127192
92360112001 Dup
Parameter Units Result Result RPD Qualifiers
Total Suspended Solids rags. 2330 2480 6 U6
SAMPLE DUPLICATE: 2127193
92359921001 Bull
j Parameter Units Result Result RPD Qualifiers
y Total Suspended Solids mg/L NO NO
4
a
j
j
r
i
S
3 l
f Recua,presented on thla pageere Is the units l.doaled by the"un8e`colemn rsttpt x SM an ehemato that IS presented to the path orth,noun.
I
REPORT OF LABORATORY ANALYSIS
1 This report shall not the reproducad,except in Nil,
Date:111011201712:38 PM vithom the minen mdsent 0 Paw Analytical Serves,LLC, Page 33 of45

3
Pacegnalyllcai Services,LLC
t 2225 Riverskle Oc
If - aceAnalytical6 Aah vide,NC2e904
x'< ftam (92e)2547176
i QUALITY CONTROL DATA
Project: Low&Better 1210140
Pace Prged No.: 92359949
QC Batch: 383650 Analysis Method: EPA 350.11993 Rev 2.0
QC Batch Method: EPA 350.11993 Rev 2.0 Analysis Desorption: 350.1 Ammonia
Associated Lab Samples: 92 3 5 9 94 9 001,92359949002,92359949003,92359949004
j
E METHODBLANK: 2126191 Maine: Water
! Associated Lab Samples: 92359949001,92359949002,92359949003.92359949004
Blank Reporting
j Parameter Units Result Limit Analyzed Coalition,
! NiUolien,Ammo al m9/1- ND 0.10 10126/1702:51
i
LABORATORY CONTROL SAMPLE 2126192
Spike LCS LCS %Roc
i Parameter Units Conc. Result %Rev Limits Qualifiers
1 Nitrogen,Ammonia mg/L 5 5.0 IN 90-110
i
i
- MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 2126193 2126194
MS MSD
92359835002 Spike Spike MS MSD MS MSD %Rise
Parameter Units Result Conc. Conc, Result Result %Res %Roc Limits RPD Qual
J Nitrogen,Ammonia mg/L 14.4 5 5 19.8 19.3 107 98 90-110 2
1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126195 2126196
[ MS MSD
li 92359MB001 Spike Spike MS MSD MS MSD %Roc
( Parameter Units Result Conc. Can.. Result Result %Roc %Roc Limits RPD Qua)
Nitrogen,Ammonia mgll. ND 5 5 5.2 5.3 103 105 90-110 2
i
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3
I_
REPORT OF LABORATORY ANALYSIS
t
Thin report
vnive. l 1 ereproduced.eal SannfWl, '..
Dale:l7lOt1201712:38 PM vMhout Ne wmlen mnsemMPacegnatyarnl5wvies,LLC. Page 34 of 45 '..

Pace Analytical earvlceg LLC
aceAnalytical e 2235 Rmersde Asheville,NC 288M84
1 � [phone]
QUALITY CONTROL DATA
i
Project; Low&Bonar1210140
1 Pace Projad No.: 92359949
QC Batch: 384089 Analysis Method: EPA 351.2
QC Batch Method: EPA351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92359949001.92359949002,92359949003,9235994901M
METHOD BLANK: 2128653 Malnx: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reporting
Parameter Units Result Limit Analyzed QualiBem
Nitrogen,Kjeldahl,Total mg/L NO 0.50 10131/1700:23
i
LABORATORY CONTROL SAMPLE: 2126654
- Spike LCS LCS %Rec
j Parameter Units Conc. Result %Rec Limits Chalmers
a Nitrogen,Kjeldahl,Total moll- 10 9.6 96 90410
3
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128655 21286%
MS MSD
92360524002 Spike Spike MS MSD MS MSD %Rec
_ Parameter Units Result Cone. Cons Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L NO 10 10 9.1 10.5 87 101 90-110 14 M1,R1
7
3 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126657 2128658
1
MS MSD
- 92359894001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L 20.0 10 10 11.5 11.5 .85 -85 90-110 0 Mi
t
I
F
1
j
j
I
3
flee...pmenled on thle 11.ere In the unYs Indwlatl by the"Unite"cs.ot. aepl wham an eaemaro We yroeote410 the fight or the ream.
j
REPORT OF LABORATORY ANALYSIS
The report shall Mt be unewuwd,except In tali,
( Date:11/01/201712:38 PM wiva.t the though weisem of Paw Analytical Services,LL6, Page 35 of 45

1
1
Pace Analytical Services,LLC
aceAnalAlll ftale 225Re kOr.
.Y A.h.nik,NC 261
n M
- (828)250.]1]8
QUALITY CONTROL DATA
i
Project: Low&Bonar1210140
Pace Project No.: 92359 p19
OC Batch: 383240 Analysis Method: EPA 353.2
QC Batch Method: EPA353.2 Analysis Description: 353.2 Nitrate 4 Nitrite,Unpres.
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
j METHOD BLANK: 2124121 Matrix: Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reporting
'j Parameter Units Result Limit Analyzed Qualifiers;
Nitrogen,Nitrate mg/L ND 0.020 W20/170821
Nitrogen,Nitrite mg/L NO 0,020 10120/1708:21
Nitrogen,NO2 plus NO3 m9/1. ND 0,020 10/20/1708:21
i
1
LABORATORY CONTROL SAMPLE: 2124122
Spike LCS LCS %Rao
3 Parameter Units Conc. Result %Rao Limits Qualifiers
Nitrogen,Nitrate mg/L 2.5 2.4 96 90-110
r Nitrogen,Nitnte nlg/L 1 0.98 98 90-110
1 Nitrogen,NO2 plus NO3 mg/L 2.5 2.4 96 90-110
I
3 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2129123 2124124
j MS MSD
l 92359898001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qua]
Nitrogen,Nitrate mglL 7.7 2.5 2.5 11.3 11.2 146 141 90-110 1 Mt
Nitrogen,Nitme mg/l- ND 1 1 1.0 1.0 102 102 90-110 0
Nitrogen,NO2 plus NO3 mg/L 7.7 2.5 2.5 11.3 11.2 146 141 90-110 1 Mt
r
i
1
g�
I Rai yreaemeeomnU raise,am In the units mdulea by the-Unite=aWmr.am am.......Ia unit 1.presentee term miss Darn..,wt.
i
c
[ REPORT OF LABORATORY ANALYSIS
This repwl shea not be repro4ucetl,exceptin full,
Date:11/01/201712:38 PM wiNwtrewntlen epneenlef Pann Ams"cal Services,I.I.C. Page 36 of 45

Pace Araly1cal Services,LLC
aceAnalyi ical s Me R cords Or
Asheville,NC 288a9
n'nw;at�'4cmn
- (828)251-]1]8
3
QUALITY CONTROL DATA
Project: Low&Better 1210140
1 Pace ProjectNP: 92359949
3
QC Batch: 393637 Analysis Method: EPAW5.1
i QC Balch Method: EPA365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92359949001.92359949002,92359949W3,92359949004
METHOD BLANK: 2126131 Mobil Water
Associated Lab Samples: 92359949001,92359949002,92359949003,92359949004
Blank Reloading
Parameter Units Result Limit Analyzed Cheapens
Phosphorus mg]L NO 0.050 10124/1704:53
i
i
3 LABORATORY CONTROL SAMPLE: 2126132
Spike LCS LCS %Rec
Parameter Units Cone. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.6 2.6 106 90-110
3
2
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126133 2126IN
I MS MSD
92360058001 Spike Spike MS MSD MS MSD %Rec
1 Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
Phosphorus high. 0.14 2.5 2.5 2.8 2.7 106 102 90410 4
i
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2126135 2126136
MS MSD
92360010001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cana Cone. Result Result %Rec %Rec Limits RED Qual
Phosphorus mg/l 8.0 2.5 2.5 9.8 10.7 73 85 90.110 3Mi
s
3
3
j
I
p
a
3
"t
I aeeues pmaenled on this pope are In Me units Indicated by es,'Vnaa"column except byrom an memtle unit Is bummed to the ran area ounce,
REPORT OF LABORATORY ANALYSIS
TMs repM shell na be mproduced,except in talk
S Date:11/0112017 12:38 PM xtMoutereuiitlen caaentar Pace Analyncal servkes,LLC. Page 37 of 45
t

Pace Analytical S wllas.LLC
MS Session Dr.
aceAnalyticale a Asheville,NC 2eee4
xPaam&,axu
(828)254]t]6
QUALITY CONTROL DATA
Project: Low&Boner 1210140
Pace Project No.: 92359949
QC Batch: 384020 Analysis Method: SM 5220D
j OC Batch Method: SM 5220D Analysis Description: 6220D COD
Associated Lab Samples: 92359949001
METHOD BLANK: 2128391 Monte: Wale,
Associated Lab Samples: 92359949001
_ Blank Reporting
Parameter Units Result Limit Analyzed Districts
Chemical Oxygen Demand mgh- NO 2&0 10127/1720:49
LABORATORY CONTROL SAMPLE: 2128392
Spike LCS LCS %Rec
Parameter Units Conn. Result %Rec Units Qualifiers
Chemical Oxygen Demand ml 750 764 101 90.110
3
i
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128393 2128394
MS MSD
j 92359569001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone. Cone.. Result Result %Bee %Rec Limits RPD Dual
i Chemical Oxygen Demand mgli. 111 760 750 1230 1240 149 151 90-110 1 M1
i
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128395 21263M
MS MSD
1 92359752001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cone, Conn. Result Result %Rec %Rec Limits RPD Qual
i Chemical Oxygen Demand m9/L 27.0 760 750 796 803 103 103 90-110 1
3
i
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a
3
3
3
t
t1 mmum;prashmad on Mm papa are in the tines lMlWteO by the Vnlb'column except µTare an almmals nMl is presented to the rlQM Nthe result.
I
3 REPORT OF LABORATORY ANALYSIS
This repot shall nA be reprdlaad,exaplin Nil,
Date:11milzu1712:38 PM ai8routthe"Iten consent of Paa Analytical Services.U-C, Page 38 of 45
i

3 Pace Analytical Services,LLC
ace Analytical® 2225 Riverside 0
/ AahavNle,NC 2880
4
(828)2!W7176
3
QUALITY CONTROL DATA
{ Project: Low&Bonar 1210140
Pace Project No.: 92359949
QC Batch: 384021 Analysis Method: SM 5220D
OC Batch Method: SM 52200 Analysis Description: 5220D COD
Associated Lab Samples: 92359949002,92359949003,92359949004
I
METHOD BLANK: 2128397 Matrix: Water
3 Associated Lab Samples: 92359949002,92359949003,92359949004
? Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chemieal Oxygen Demand mill- NO 25.0 10127/1720:49
{
LABORATORY CONTROL SAMPLE: 2128398
Spike LCS LCS %Rec
jParameter Units Cone. Result %Rec Limits Qualifiers
Chemical Oxygen Demand mg/L 750 754 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128399 2128400
MS MSD
92359949002 Spike Spike M$ MSD MS MSD %Rec
Parameter Units Result Cone. Cons. Result Result %Rec %Rec Limits RPD Qual
Chemical Oxygen Demand mg/L ND 760 750 794 792 105 105 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 2128401 2128402
MS MSD
92360289001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Cora Conc. Result Result %Rec %Rec Limits RPD qual
j Chemical Oxygen Demand mg/L 65.0 750 750 866 859 107 106 90-110 1
7
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Restart Presented on INS Page are in the arras Notated eyN.^Unur eNhe—.11 where an aamnae oot1.Preteneammeright crthc reatar.
i
REPORT OF LABORATORY ANALYSIS
} This report shall not be repotlucetl,exceptin Na,
Date:11101/201712:38 PM wilM1an@ewMem mrsentot Pam Nnnlyecal Servkes U-C. Page 39 of 46

I Pace Analytical Services,LLC
4
8C8/118lyfiCBl a 2225 hearses Dr.
Aahevil a,NO 281
awns Yatvaxa
[phone]
)
j QUALIFIERS
t
Project. Low&Bamu1210140
f Pace Project No.: 92359949
DEFINITIONS
j DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
i ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous TO Count
J-Estimated concenlration above the adjusted method detection limit and below the adjusted rationing limit.
MDL-Adjusted Method Detection Limit.
1 PQL-Practical Quantitation Limit.
i RL-Reporting Limit.
5-Surrogate
- 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each anayte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
i
MS(D)-Matrix Spike(Duplicate)
3 DUP-Sdmpls Duplicate
RPD-Relative Percent Difference
t NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
( A separate vial pre kswed to a pH of 4-5 is recommended in SW846 Chapter for the analysis ofAmilein and Awylonitdle by EPA
3 Method 826D.
N-Ndros aliph unylamine decomposes antl cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
_ Pace Analytical is TNl accredited.Conrad your Pace PM for the coment list of accredited anaytes.
TNL The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Sundaes-Asheville
i PASI-C Pace Analytical Seraces-Charlotte
E
i ANALYTE QUALIFIERS
j D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
Mi Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory conirol sample(LCS)recovery.
RI RPD value was outside control limits.
f3
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i REPORT OF LABORATORY ANALYSIS
This retest shall not hareprotluxxi,except in full,
7 Date:1110112017 12:38 PM xiawime wdnen amaeddPaceMalytirelsmvxesLLC. Page 40 of 45
3

i Pace analytical Si LLC
1 ace!1An lyitli =5 Rivenl.Dr.
Asheville,NC 288c4
o
(826)25i7178
S
QUALITY CONTROL DATA CROSS REFERENCE TABLE
I Project: Low B Bmm l210140
j Pace Project No.: 92369949
Analytical
Lab ID Sample lD QC Batch Method QC Batch Analytical Method Batch
92369949001 Manhole 3 EPA 1664B 384601
l 923699490D2 Slim Tank EPA1664B 384601
92359949003 Flood Gate EPA1664B 384601
92359949004 East Ditch EPA1664B 384601
i
92359949001 Manhole EPA200.7 384206 EPA200.7 384413
92369949002 Slim Tank EPA 200.7 384206 EPA200.7 384413
92359949003 Flood Gate EPA200.7 384206 EPA 200.7 384413
92359949004 East Ditch EPA 200.7 384206 EPA 200] 384413
92359949001 Manhole EPA245.1 383897 EPA245A 383926
92358949002 Sllm Tank EPA246.1 383897 EPA245.1 383926
92359949003 Flood Gate EPA245.1 383897 EPA245.1 383926
92359949004 East Ditch EPA245.1 383897 EPA245.1 383926
j 82359849007 Manhole EPA625 383560 EPA625 384122
92359949002 Slim Tank EPA625 383560 EPA625 384122
923599490D3 Flood Gate EPA625 383560 EPA625 384122
92359949004 East Ditch EPA625 383560 EPA625 3M122
92359949001 Manhole EPA624 384120
92359049002 Slim Tank EPA624 364120
92359949003 Flood Gate EPA624 3M120
92359949004 East Ditch EPA624 384120
92359949001 Manhole 3 SM 2540C 383805
92359949002 Slim Tank SM 2540C 383805
i 92358949003 Flood Gate SM 2540C 383805
- 92359949004 East Ditch SM 2540C 383805
j 92359949001 Manhole Si 383793
I 92359949002 Slim Tank SM25400 383793
92359949003 Flood Gate SM 26401) 383793
3 92359949004 East Ditch SM 2540D 383793
92359949001 Manhole TKN+1,103+NO2 384653
Calculation
92359949002 Slim Tank TKN+1403+1,102 384653
1 Calwiation
92359949003 Flood Gate TKN+1,103+1,102 304653
calculates,
92369949004 East Ditch TKN+NO3+NO2 384653
Calculation
92359949001 Manhole EPA 350.11993 Rev 2.0 3836W
- 92359949002 Slim Tank EPA 350.11993 Rev 2D 383650
j 92369949003 Flood Gate EPA 350.11993 Rev 2.0 383650
I 02359949004 East Ditch EPA350.11993 Rev 2.0 38MW
02359949001 Manhole EPA351.2 394089
92359949002 Slim Tank EPA351.2 384089
9 92369949003 Flood Gate EPA 351.2 384089
92369949004 East Dllch EPA 361.2 384089
92359949001 Manhole EPA 353.2 383240
i
j REPORT OF LABORATORY ANALYSIS '..
This report shall not he lepfoeuced except in ss.
Date:ill011201712:38 PM utthout the When mneem of Pace An.10.1 Services,LLC. Page 41 of 45
i
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i
ior ® Pace Amd dical Services,LLC
ace Analytical b.il ft,NC 28 Dr.
x Wjo a n AMevilk,NC 28804
(828)2&1-7175
QUALITY CONTROL DATA CROSS REFERENCE TABLE
i
Project: Low&Bonar1210140
Pace Project No.: 92359949
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92359949002 Slim Tank EPA 353.2 383240
j 92359949003 Flood Gate EPA353.2 383240
92369949004 East DRch EPA353.2 383240
j 92359949001 Manhole 3 EPA365.1 383637
l9 92359949002 Slim Tank EPA365.1 383637
92359949003 Flood Gate EPA365.1 383637
92369949004 East Ditch EPA365.1 383637
} 92359949001 Manhole 3 SM 5220D 384020
92369949002 Slim Tank SM 5220D 384021
92369949003 Flood Gat. SM 5220D 384021
3 92359949004 East Ditch SM 52200 384021
3
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3
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1
3
I
1
j
1
REPORT OF LABORATORY ANALYSIS
TNs repro shall not 5a mpnxlu ,except in full,
Date:11/0112017 12:38 PM ximart mew en omsentof Pace Analytical Se lcae,LLC, Page 42 of 45
t
t

t
Document name: Document Revised;My 25,2017
1, hd Gam Ie Condition Upon R¢cei t(SCUP Pa e1of2
_ aceAmylcaje Document No.: Issuing Authority:
F�CAR•CS�033-Rev,03 Pace Quali Ofli[e
t laboratory receiving sampl
Ashevllle�den❑ Greenwood❑ HuntersvUle❑ Raleigh[] Mechanicsv ❑ille
I Pro
Client Name: �n WO# : 92359949 ject
Courlen Fed ELJ UPS ❑Us Sa ?
❑Commercial []pace ❑Other._ 92359949
Custody seal Present? ❑Yes QNe--sealslNact7 Dyes „0 I(?���I1
j Date/Initials VerznE Ilaonenis
Packing Material: ❑gobble Wrap _ e9ags ❑None ❑ Other Biological Tissue Froz ?
3 Thermometric CJ wet ❑Blue Opera, []Yes ❑N N/A
❑IR Gun 10: Type o(1[a: ^�
Correction Factor: Cooler Temp Corrected(°Cj: Z L Tempshou!d be above freezing to 6°C
l � ern,should
abov freezing
Samples on ke,cooling pmresz
has begun
USDA Regulated Sp /A;watersample)
Did samples originate In a quarantine zone within the United States:CA,NV,or5C(meek maps)? Did umples originate from a foreign source(Internationally,
Yes ❑No including Hawaiian'[Puert.sparr❑yes ON.
Comments/Discrepancy:
)
Chain of Custody Present? Jain. N/A 1.
Samples Arrived Within Held Time yes No ❑x/p 2.
Short Hold Time AnalysisiQ2hr.)t Yes Ne!' ❑are 3.
j Push Turn Around Time flequestetl7 Yex N/A 4.
SvHitlent Volume2 ON. N/A S.
Correct Containers Used? ,A4a, ❑No ❑N/A 6.
-Pace Contelners Used? No N/A
Containers Intact? No N/A ?.
Dissolved anal,I,:Samples Field Filtered? Yes 6 N/A a.
t Sample Labels Match COC? 0�,— []No ❑N/A 9.
LN\A/
-Includes Date/Time/ID/Anal sis Matrix:
Heads a[e in VOA Vials(>56mm? Yes No ❑WA 10,
i Trip Blank Present? ❑Yea �Md'� ❑N/A/A-- 11.
sTrip Blank Custody5eals Present? OYez No MWA
CLIENT NOTIFICATION/RESOLUTION ikid Oata Requlree ❑Yes ❑No
Person Contacted: Date/lime:
i Comments/Sample Discrepancy:
7
j
3
i Prefect Manager SCURF Review: Date: C r�
Project Manager SHE Review: `-�� Date:
Note: Whenever there is a d6aepancraffectirm North Carolina compliance samples.a copy ofthlsformwObe sent tothe North Carolina DEHNR Certification Office(i.e.
Out of hold,incorrect preservative,out of temp,inmrrectrontalnen)
j
j Page 43 of 45
3

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Document Name: Document RevlsedJuly 25,2017
IL Sam le[ondtdonU on Reset tISCURi Page 2 of
Document No.: Issuing Amhotlry:
7 PdsyR-CS­033,Revo3 {{((,, Pace Quality ONde
"Check mark top half of box if pH and/or dechlorination Project W®N : 92359949
j is verified and within the acceptance range for PM: COI Due Date: 11/02/17
preservation samples. CLIENT: 93-Pis9ahEbv
*Bottom half of box is to list number of bottles
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as I
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] pH Adjustment Log for Preserved Samples
7 Samplela Type of Preservative pRuponreaelpt Date preservatlon adjusted Timepruen""on Amountof preservative Leta
Iadjwtetl adead
3
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Page 44 of 45
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