NC0000396_Mercury Field Blank Info_20200218

Action History (UTC-05:00) Eastern Time (US & Canada)
Subrrit by Anonymous User 2/18/2020 11:50:17 AM (Supplemental Submittal)
Submit by Thedford, Wren 5/12/2020 9:20:47 AM (Supplemental Info Submittal)
• Thedford, Wren assigned the task to Thedford, Wren 5/12/2020 9:20 AM
• The task was assigned to Thedford, Wren, Bennett, Bradley 2/18/2020 11:50 AM

Initial Review Information
Updated ID#:* IWORTANf:FEVIBAERSl-IOLLDVERFYand revise here ifnecessary.
NCOO00396
How should this project be handled?*
r File r Discard
Information Submitted on 2/18/2020
Submitter Information
Name: Teresa Williams
Vft is subrritting the inforrretion?
Email Address:* [e-mail]
Submittal Information
The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental
information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted
electronically through the eDMR system and should not be submitted here. Division staff will reviewall
uploaded documents and will only maintain required information. Documents such as laboratory reports are not required
to be submitted and will not be maintained in the system.
Project Information:
Rease SUDDly the Dernit nun ber for this
Existing ID#* PerrritNurrber
NCOO00396
Exarrples: NOKxxxxxx or NO&xxxxx
Facility Name:* Asheville Steam Electric Plant
County: Buncombe
Please upload all files that need to be
submited. *
dick the upload button or drag and drop files here to attach docurrent
Dec 19 eDMR Supplemental Data Upload.pdf 5.13MB
Only pdf files are accepted.
Comments about the attachments:
* V By checking the box and signing box below, I certify that:
o I have given true, accurate, and complete information on this form;

• I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the
NC General Statutes (the "Uniform Electronic Transactions Act)
• I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
(the "Uniform Electronic Transactions Act');
• I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
signature; AND
• I intend to electronically sign and submit the Supplemental Information form."
Full Name: Teresa Williams
Signature:
Date Submitted: 02/18/2020

n /� DUKE
ENERGY.,
PROGRESS
Submitted Electronically
File No.: 12520B
February 14, 2020
Memo
To: Central Files
NCDEQ, Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
From: Duke Energy Progress
Asheville Combined Cycle Station
46 Duke Energy Lane
Arden, NC 28704
RE: Asheville Steam Electric Generating Plant
Buncombe County
NPDES Number NC0000396
Discharge Monitoring Report (DMR)
Antonio D. Price, PE
Plant General Manager
Asheville Combined Cycle Station
Duke Energy Progress
ASVL PLT 146 Duke Energy Lane
Arden, NC 28704
o: 828-650-0620
f. 828-650-0701
[e-mail]
In accordance with condition I.A. (18) 1., replaced by electronic signature and submission
guidelines, the December 2019 NPDES eDMR for Duke Energy Progress's Asheville Steam
Electric Plant — NPDES Permit Number NC0000396 has been submitted.
The Outfall 001, Outfall 001 Upstream and Outfall 001 Downstream low-level mercury field
blank samples collected December 5, 10, and 16, 2019 did not meet quality control criteria in
accordance with EPA Method 1631E. Per Division guidance ("NPDES Mercury Requirement -
EPA Method 1631 Additional Information"), the mercury field blank samples have been noted in
the eDMR comments section, and the associated analytical reports are attached to this memo and
uploaded electronically to the eDMR Supplement Data Upload server.
Please contact Ms. Teresa Williams at [phone] or Ms. Mariea Keezel at [phone]
with any questions concerning the data in this submittal.

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
December 12, 2019
Mr. Matthew Fields
Duke Energy Progress, Inc.
RE: Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Dear Mr. Fields:
Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Mariea Keezel, Duke Energy
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92456205001 FIELD BLANK EPA 1631 E
RDT
1
PASI-A
92456205002 OUTFALL 001 2019/12/05 0940 N EPA 1664B
HH
1
PASI-C
EPA 200.7 Rev 4.4 1994
KQ
11
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
SM 254OD-2011
MJP
1
PASI-A
TKN+NO3+NO2 Calculation
DMN
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
EPA 351.2 Rev 2.0 1993
MFO
1
PASI-A
EPA 353.2 Rev 2.0 1993
KDF1
1
PASI-A
EPA 365.1 Rev 2.0 1993
KDF1
1
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Sample: FIELD BLANK Lab ID: 92456205001 Collected: 12/05/19 09:40 Received: 12/05/19 15:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level
Mercury
Date: 12/12/2019 03:08 PM
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
0.515 ng/L 0.50 1 12/10/1916:45 12/11/1913:18 7439-97-6 CO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Sample: OUTFALL Lab ID: 92456205002 Collected: 12/05/19 09:40 Received: 12/05/19 15:15 Matrix: Water
001 _2019/12/05_0940_N
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
200.7 MET ICP
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Zinc
1631E Mercury,Low Level
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
Total Nitrogen Calculation
Total Nitrogen
300.0 IC Anions 28 Days
Bromide
Fluoride
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3 pres.
Nitrogen, NO2 plus NO3
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
Date: 12/12/2019 03:08 PM
Analytical Method: EPA 1664B
ND mg/L
5.0
1
12/11/19 09:58
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
89.0 ug/L
10.0
1 12/07/19 01:18
12/08/19 20:13
7440-38-2
ND ug/L
1.0
1 12/07/19 01:18
12/08/19 20:13
7440-41-7
1.1 ug/L
1.0
1 12/07/19 01:18
12/08/19 20:13
7440-43-9
7.4 ug/L
5.0
1 12/07/19 01:18
12/08/19 20:13
7440-47-3
ND ug/L
5.0
1 12/07/19 01:18
12/08/19 20:13
7440-50-8
ND ug/L
5.0
1 12/07/19 01:18
12/08/19 20:13
7439-92-1
7.8 ug/L
5.0
1 12/07/19 01:18
12/08/19 20:13
7440-02-0
48.5 ug/L
10.0
1 12/07/19 01:18
12/08/19 20:13
7782-49-2
ND ug/L
5.0
1 12/07/19 01:18
12/08/19 20:13
7440-22-4
198000 ug/L
662
1 12/07/19 01:18
12/08/19 20:13
ND ug/L
10.0
1 12/07/19 01:18
12/08/19 20:13
7440-66-6
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
3.67 ng/L
0.50
1 12/10/1916:45
12/11/1915:05
7439-97-6
Analytical Method: SM 2540C-2011
341 mg/L
25.0
1
12/11/1917:44
Analytical Method: SM 254OD-2011
17.5 mg/L
4.2
1
12/07/19 06:21
Analytical Method: TKN+NO3+NO2 Calculation
2.2 mg/L
0.52
1
12/12/1915:06
Analytical Method: EPA 300.0 Rev 2.1 1993
0.21 mg/L
0.10
1
12/07/1918:32
24959-67-9
0.53 mg/L
0.10
1
12/07/1918:32
16984-48-8
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
1.1 mg/L
0.50
1 12/10/19 05:55
12/11/19 03:33
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993
1.1 mg/L
0.040
1
12/12/19 09:02
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
0.067 mg/L
0.050
1 12/10/19 15:38
12/11/19 09:53
7723-14-0
Analytical Method: SM 4500-CI-E-2011
23.0 mg/L
1.0
1
12/10/1918:01
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 514133
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92456205002
METHOD BLANK: 2755523
Matrix: Water
Associated Lab Samples: 92456205002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0
12/11/19 09:51
LABORATORY CONTROL SAMPLE: 2755524
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 35.8
90 78-114
MATRIX SPIKE SAMPLE: 2755525
92455220004 Spike
MS MS % Rec
Parameter
Units
Result Cone.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 40
35.9 87 78-114
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513889
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92456205001, 92456205002
METHOD BLANK: 2754507
Matrix: Water
Associated Lab Samples: 92456205001, 92456205002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1912:17
METHOD BLANK: 2754508
Matrix: Water
Associated Lab Samples: 92456205001, 92456205002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1913:41
METHOD BLANK: 2754509
Matrix: Water
Associated Lab Samples: 92456205001, 92456205002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1915:43
LABORATORY CONTROL SAMPLE: 2754510
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Mercury ng/L
5 5.10
102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754511
2754512
MS MSD
92456146004
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.42
25 25 27.6
28.4 105 108
71-125 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754513 2754514
MS MSD
92456166002
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.63
25 25 27.3
28.8 103 109
71-125 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513506 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92456205002
METHOD BLANK: 2752946
Associated Lab Samples: 92456205002
Parameter
Arsenic
Beryllium
Cadmium
Chromium
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Zinc
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
10.0
12/08/1919:55
ug/L
ND
1.0
12/08/1919:55
ug/L
ND
1.0
12/08/1919:55
ug/L
ND
5.0
12/08/1919:55
ug/L
ND
5.0
12/08/1919:55
ug/L
ND
662
12/08/1919:55
ug/L
ND
5.0
12/08/1919:55
ug/L
ND
5.0
12/08/1919:55
ug/L
ND
10.0
12/08/1919:55
ug/L
ND
5.0
12/08/1919:55
ug/L
ND
10.0
12/08/1919:55
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2752947
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits
Arsenic
ug/L
500
480
96
85-115
Beryllium
ug/L
500
477
95
85-115
Cadmium
ug/L
500
476
95
85-115
Chromium
ug/L
500
479
96
85-115
Copper
ug/L
500
484
97
85-115
Hardness, Total(SM 2340B)
ug/L
33100
31500
95
85-115
Lead
ug/L
500
473
95
85-115
Nickel
ug/L
500
475
95
85-115
Selenium
ug/L
500
466
93
85-115
Silver
ug/L
250
239
96
85-115
Zinc
ug/L
500
461
92
85-115
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2752948
2752949
MS
MSD
92456205002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
89.0
500
500
608
582
104
99
70-130
4
Beryllium
ug/L
ND
500
500
486
466
97
93
70-130
4
Cadmium
ug/L
1.1
500
500
502
480
100
96
70-130
4
Chromium
ug/L
7.4
500
500
494
469
97
92
70-130
5
Copper
ug/L
ND
500
500
497
473
99
94
70-130
5
Hardness, Total(SM 2340B)
ug/L
198000
33100
33100
231000
226000
102
85
70-130
3
Lead
ug/L
ND
500
500
485
463
97
92
70-130
5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2752948
2752949
MS
MSD
92456205002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nickel
ug/L
7.8
500
500
489
465
96
91
70-130
5
Selenium
ug/L
48.5
500
500
561
538
102
98
70-130
4
Silver
ug/L
ND
250
250
245
235
98
94
70-130
4
Zinc
ug/L
ND
500
500
488
461
96
91
70-130
6
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2752950
2752951
MS
MSD
92455679074
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
498
481
99
96
70-130
4
Beryllium
ug/L
ND
500
500
481
474
96
95
70-130
1
Cadmium
ug/L
ND
500
500
492
482
98
96
70-130
2
Chromium
ug/L
1.2J
500
500
484
477
96
95
70-130
1
Copper
ug/L
ND
500
500
484
476
97
95
70-130
2
Hardness, Total(SM 2340B)
ug/L
46800
33100
33100
78600
77800
96
94
70-130
1
Lead
ug/L
ND
500
500
483
472
96
94
70-130
2
Nickel
ug/L
ND
500
500
478
468
96
94
70-130
2
Selenium
ug/L
ND
500
500
505
492
101
98
70-130
3
Silver
ug/L
ND
250
250
243
240
97
96
70-130
1
Zinc
ug/L
ND
500
500
476
467
95
93
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 514304
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Associated Lab Samples: 92456205002
METHOD BLANK: 2756434
Matrix: Water
Associated Lab Samples: 92456205002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND 25.0 12/11/19 17:44
LABORATORY CONTROL SAMPLE: 2756435
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 248
99 90-110
SAMPLE DUPLICATE: 2756436
92456205002 Dup
Parameter
Units
Result Result
RPD Qualifiers
Total Dissolved Solids
mg/L
341 341
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513517
Analysis Method:
SM 2540D-2011
QC Batch Method: SM 254OD-2011
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92456205002
METHOD BLANK: 2752990
Matrix:
Water
Associated Lab Samples: 92456205002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/07/19 06:16
LABORATORY CONTROL SAMPLE: 2752991
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
251
250
100 90-110
SAMPLE DUPLICATE: 2753027
92456098002
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
496
450 10
SAMPLE DUPLICATE: 2753028
92456269001
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
2180
2980 31 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 21

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
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[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513300 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92456205002
METHOD BLANK: 2751783 Matrix: Water
Associated Lab Samples: 92456205002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Bromide mg/L ND 0.10 12/07/1917:02
Fluoride mg/L ND 0.10 12/07/1917:02
LABORATORY CONTROL SAMPLE: 2751784
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Bromide mg/L 2.5 2.4 96 90-110
Fluoride mg/L 2.5 2.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751785
2751786
MS
MSD
92456166001 Spike
Spike
MS
MSD MS
MSD % Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec Limits RPD Qual
Bromide mg/L ND 2.5
2.5
2.4
2.4 94
97 90-110 2
Fluoride mg/L ND 2.5
2.5
2.4
2.4 95
96 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751787
2751788
MS
MSD
92456254009 Spike
Spike
MS
MSD MS
MSD % Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec Limits RPD Qual
Bromide mg/L ND 2.5
2.5
2.4
2.4 96
97 90-110 1
Fluoride mg/L 0.11 2.5
2.5
2.5
2.5 94
95 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 21

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513830
Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993
Analysis Description: 351.2 TKN
Associated Lab Samples: 92456205002
METHOD BLANK: 2754313
Matrix: Water
Associated Lab Samples: 92456205002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
ND 0.50
12/11/19 03:01
LABORATORY CONTROL SAMPLE: 2754314
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Nitrogen, Kjeldahl, Total mg/L
10
9.5
95 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754315
2754316
MS
MSD
92455257001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 0.76
10
10 9.9
9.8 91
90
90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754317
2754318
MS
MSD
92455841001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Nitrogen, Kjeldahl, Total mg/L 6.8
10
10 16.4
16.3 95
95
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 514157
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, preserved
Associated Lab Samples: 92456205002
METHOD BLANK: 2755582
Matrix: Water
Associated Lab Samples: 92456205002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L
ND 0.040
12/12/19 08:41
LABORATORY CONTROL SAMPLE: 2755583
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L
2.5
2.5
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2755584
2755585
MS
MSD
92455674031
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND
2.5
2.5 2.5
2.5 100 99
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2755586
2755587
MS
MSD
92455674032
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec % Rec
Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L ND
2.5
2.5 2.5
2.5 101 101
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 513910
Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description: 365.1 Phosphorus, Total
Associated Lab Samples: 92456205002
METHOD BLANK: 2754589
Matrix: Water
Associated Lab Samples: 92456205002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Phosphorus mg/L
ND 0.050
12/11/19 09:44
LABORATORY CONTROL SAMPLE: 2754590
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Phosphorus mg/L
2.5
2.5
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754591
2754592
MS
MSD
92455674038
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Phosphorus mg/L ND
2.5
2.5 2.5
2.6 100
104
90-110 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754593
2754594
MS
MSD
92456162001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Phosphorus mg/L 0.074
2.5
2.5 2.6
2.6 100
103
90-110 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 21

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
QC Batch: 514000
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Associated Lab Samples: 92456205002
METHOD BLANK: 2754992
Matrix: Water
Associated Lab Samples: 92456205002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Chloride mg/L
ND 1.0
12/10/1917:42
LABORATORY CONTROL SAMPLE: 2754993
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Chloride mg/L
20
20.3
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754994
2754995
MS
MSD
92455945001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/L 10.8
10
10 20.9
20.9 101
100
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754996
2754997
MS
MSD
92455945002
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/L 21.6
10
10 30.8
30.9 91
93
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
REPORT OF LABORATORY ANALYSIS
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Date: 12/12/2019 03:08 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: OUTFALL 001 12-5-19
Pace Project No.: 92456205
Lab ID
92456205002
92456205002
92456205001
92456205002
92456205002
92456205002
92456205002
92456205002
92456205002
92456205002
92456205002
92456205002
Sample ID
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
FIELD BLANK
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
OUTFALL
001 _2019/12/05_0940_N
Date: 12/12/2019 03:08 PM
QC Batch Method
EPA 1664B
EPA 200.7 Rev 4.4 1994
EPA 1631 E
EPA 1631 E
SM 254OC-2011
SM 254OD-2011
TKN+NO3+NO2
Calculation
EPA 300.0 Rev 2.1 1993
EPA 351.2 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
SM 4500-CI-E-2011
QC Batch Analytical Method
513506 EPA 200.7 Rev 4.4 1994
513889 EPA 1631E
513889 EPA 1631E
514304
513517
514524
513300
Analytical
Batch
513532
514141
514141
513830 EPA 351.2 Rev 2.0 1993 514092
514157
513910
514000
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 21

�-
�j
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
' ace Analytical'
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving sa les:
Asheville, Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
SampleClient Name: WO# : 92456205
Upon Receipt Project #:
Courier: ❑F d Ex ❑UPS ❑ S J [-]clientII I Ili III I III I I �� II�
❑ Commercial {Pace ❑other: 92456205
Custody Seal Present? Yes [:]No Seals Intact? 10, es ❑No
Packing Material: ❑Bubble Wrap Bubble Bags [-]None ❑ Other
Thermome��te,,�jGun ID: r- `^�`�` I Type of Ice: Vl( wet ❑Blue
V t7 I
Cooler Temp (°C): L ; U Correction Factor: Add/Subtract (°C) . J
Cooler Temp Corrected ('C): L% ------
USDA Regulated Soil (El N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
Oate/Initials Person Examining Contents:
Biological Tissue Frozen?
[]Yes ❑No 0IV/A
❑None
Temp should be above freezing to 6°C
[]53mples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
-.i.,ii —1 o. +., ni—P I—IVae MNa
U7ea UIVU
-- comments/Discrepancy:
Chain of Custody Present?
EhYes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
Yes
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
Dyes
❑No
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
ONo
❑N/A
4.
Sufficient Volume?
Yes
❑No
[]N/A
5.
Correct Containers Used?
Yes
❑No
❑N/A
6.
-Pace Containers Used?
Yes
❑No
[-]N/A
Containers Intact?
Yes
[:]No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
[-]Yes
QJNo
❑N/A
8.
Sample Labels Match COC?
❑1es
❑No
❑N/A
9.
-Includes Date/Time/ID/Analysis Matrix:
10.
Headspace in VOA Vials (>5-6mm)? Dyes ❑No 6N/A
Trip Blank Present?
Dyes
[-]No
N/A
11.
Trip Blank Custody Seals Present?
[-]Yes
❑Na
N/A
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review: !'
Project Manager SRF Review: �1
Date/Time:
Field Data Required? ❑Yes QNo
Date:
Date:
Page 19 of 21

Document Name:
Document Revised: February 7, 2018
/
�'XlIeAnalytical
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
`
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if phi and/or dechlorination is
verified and within the acceptance range for preservation
samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to fist number of bottle
Project h Wp# : 92456205
PM: UP Due Date: 12/12/19
CLIENT: SS -PROGRESS
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pH Adjustment Log for Preserved Samples
Sample ID
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pH upon receipt
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adjusted
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added
Lot 9
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certitication Umce ii.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 20 of 21

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Page 21 of 21

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
December 12, 2019
Mr. Rick Smith
Duke Energy Progress, Inc.
P.O. Box 1511
PEB4
Raleigh, NC 276021511
RE: Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Dear Mr. Smith:
Enclosed are the analytical results for sample(s) received by the laboratory on December 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Mr. Jason Brown, Duke Energy
Mr. Justin Dycus, Duke Energy
Mr. Ryan Fawcett, Duke Energy
Mr. Reid Garrett, Duke Energy Progress, Inc.
Mr. Jason Green, Duke Energy Progress, Inc.
Derek Henderson, Duke Energy
Mr. Kyle Hussey, Duke Energy
Program Manager, Duke Energy
Mr. Robert Nichols, Duke Energy
Mr. Matt Pulliam, Duke Energy
Mr. Jonathan Stamas, Duke Energy Progress, Inc.
Mr. Mike Swing, Duke Energy Progress, Inc.
Mr. Thomas Thompson, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
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Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
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CERTIFICATIONS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
ASV _INST 12-5-19
92456166
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92456166001
ASV INST DN 1
INST 2019 049
EPA 200.7 Rev 4.4 1994
KQ
1
PASI-A
EPA 200.8 Rev 5.4
JOR
3
PASI-A
EPA 200.8 Rev 5.4
JOR
4
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
92456166002
ASV INST UP 1
INST 2019 051
EPA 200.7 Rev 4.4 1994
KQ
1
PASI-A
EPA 200.8 Rev 5.4
JOR
3
PASI-A
EPA 200.8 Rev 5.4
JOR
4
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 2540C-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
92456166003
ASV INST DN 1
INST 2019 050
EPA 1631 E
RDT
1
PASI-A
92456166004
ASV INST UP 1
INST 2019 052
EPA 1631 E
RDT
1
PASI-A
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ANALYTICAL RESULTS
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Sample: ASV _INST_DN_1_INST_20
Lab ID: 92456166001 Collected: 12/05/19 09:30
Received: 12/05/19 12:45 Matrix: Water
19_049
Parameters
Results Units Report Limit DF
Prepared
Analyzed
CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Hardness, Total(SM 2340B)
10700 ug/L 662 1
12/06/19 01:37
12/08/19 23:37
200.8 MET ICPMS
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Arsenic
ND ug/L 0.10 1
12/06/19 02:35
12/12/19 00:45
7440-38-2
Chromium
ND ug/L 0.50 1
12/06/19 02:35
12/12/19 00:45
7440-47-3
Selenium
ND ug/L 0.50 1
12/06/19 02:35
12/12/19 00:45
7782-49-2
200.8 MET ICPMS, Dissolved
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA200.8 Rev 5.4
Cadmium, Dissolved
ND ug/L 0.080 1
12/06/19 14:39
12/11/19 07:15
7440-43-9
Lead, Dissolved
ND ug/L 0.10 1
12/06/19 14:39
12/11/19 07:15
7439-92-1
Zinc, Dissolved
ND ug/L 5.0 1
12/06/19 14:39
12/11/19 07:15
7440-66-6
Copper, Dissolved
ND ug/L 0.50 1
12/06/19 14:39
12/11/19 07:15
7440-50-8
1631E Mercury,Low Level
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury
1.61 ng/L 0.50 1
12/10/1916:45
12/11/1914:35
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Total Dissolved Solids
22.8 mg/L 10.0 1
12/09/19 23:17
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Bromide
ND mg/L 0.10 1
12/07/1917:32
24959-67-9
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Sample: ASV _INST_UP_1_INST_20
Lab ID: 92456166002 Collected: 12/05/19 08:10
Received: 12/05/19 12:45 Matrix: Water
19_051
Parameters
Results Units Report Limit DF
Prepared
Analyzed
CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Hardness, Total(SM 2340B)
10900 ug/L 662 1
12/06/19 01:37
12/08/19 23:40
200.8 MET ICPMS
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA 200.8 Rev 5.4
Arsenic
ND ug/L 0.10 1
12/06/19 02:35
12/12/19 00:49
7440-38-2
Chromium
ND ug/L 0.50 1
12/06/19 02:35
12/12/19 00:49
7440-47-3
Selenium
ND ug/L 0.50 1
12/06/19 02:35
12/12/19 00:49
7782-49-2
200.8 MET ICPMS, Dissolved
Analytical Method: EPA 200.8 Rev 5.4 Preparation Method: EPA200.8 Rev 5.4
Cadmium, Dissolved
ND ug/L 0.080 1
12/06/19 14:39
12/11/19 07:19
7440-43-9
Lead, Dissolved
ND ug/L 0.10 1
12/06/19 14:39
12/11/19 07:19
7439-92-1
Zinc, Dissolved
ND ug/L 5.0 1
12/06/19 14:39
12/11/19 07:19
7440-66-6
Copper, Dissolved
ND ug/L 0.50 1
12/06/19 14:39
12/11/19 07:19
7440-50-8
1631E Mercury,Low Level
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury
1.63 ng/L 0.50 1
12/10/1916:45
12/11/1914:42
7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Total Dissolved Solids
18.8 mg/L 10.0 1
12/09/19 23:18
D6
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Bromide
ND mg/L 0.10 1
12/07/1918:17
24959-67-9
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Sample: ASV _INST_DN_1_INST_20 Lab ID: 92456166003 Collected: 12/05/19 09:30 Received: 12/05/19 12:45 Matrix: Water
19_050
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury 2.68 ng/L 0.50 1 12/10/1916:45 12/11/1915:55 7439-97-6 CO
Date: 12/12/2019 03:27 PM
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ANALYTICAL RESULTS
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
Sample: ASV _INST_UP_1_INST_20 Lab ID: 92456166004 Collected: 12/05/19 08:10 Received: 12/05/19 12:45 Matrix: Water
19_052
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury 0.505 ng/L 0.50 1 12/10/1916:45 12/11/1913:11 7439-97-6 CO
Date: 12/12/2019 03:27 PM
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QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513889
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92456166001, 92456166002, 92456166003, 92456166004
METHOD BLANK: 2754507
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002, 92456166003, 92456166004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1912:17
METHOD BLANK: 2754508
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002, 92456166003, 92456166004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1913:41
METHOD BLANK: 2754509
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002, 92456166003, 92456166004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/11/1915:43
LABORATORY CONTROL SAMPLE: 2754510
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Mercury ng/L
5 5.10
102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754511
2754512
MS MSD
92456146004
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.42
25 25 27.6
28.4 105 108
71-125 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2754513 2754514
MS MSD
92456166002
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Mercury ng/L 1.63
25 25 27.3
28.8 103 109
71-125 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513274
Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description: 200.7 MET
Associated Lab Samples: 92456166001, 92456166002
METHOD BLANK: 2751734
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Hardness, Total(SM 2340B) ug/L
ND 662
12/08/19 22:12
LABORATORY CONTROL SAMPLE: 2751735
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Hardness, Total(SM 2340B) ug/L
33100
31600
96 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751736
2751737
MS
MSD
92455679057
Spike
Spike MS
MSD MS
MSD % Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec Limits RPD Qual
Hardness, Total(SM 2340B) ug/L 4870
33100
33100 37400
37800 98
100 70-130 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751738
2751739
MS
MSD
92455674032
Spike
Spike MS
MSD MS
MSD % Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec Limits RPD Qual
Hardness, Total(SM 2340B) ug/L ND
33100
33100 32600
33300 99
101 70-130 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513270
Analysis Method: EPA 200.8 Rev 5.4
QC Batch Method: EPA 200.8 Rev 5.4
Analysis Description: 200.8 MET
Associated Lab Samples: 92456166001, 92456166002
METHOD BLANK: 2751710
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed Qualifiers
Arsenic ug/L
ND 0.10
12/11/1915:00
Chromium ug/L
ND 0.50
12/11/1915:00
Selenium ug/L
ND 0.50
12/11/1915:00
LABORATORY CONTROL SAMPLE: 2751711
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits Qualifiers
Arsenic ug/L
10
9.8
98 85-115
Chromium ug/L
50
49.5
99 85-115
Selenium ug/L
50
49.4
99 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751712
2751713
MS
MSD
92455679056
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec % Rec
Limits
RPD Qual
Arsenic ug/L ND
10
10 10.0
9.9 100 99
70-130
1
Chromium ug/L 0.67
50
50 51.6
51.2 102 101
70-130
1
Selenium ug/L ND
50
50 49.5
49.4 99 99
70-130
0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751714
2751715
MS
MSD
92456146002
Spike
Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec % Rec
Limits
RPD Qual
Arsenic ug/L 9.7
10
10 20.6
20.3 109 105
70-130
2
Chromium ug/L ND
50
50 48.5
47.4 97 95
70-130
2
Selenium ug/L ND
50
50 50.3
49.6 100 99
70-130
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
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Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513412 Analysis Method: EPA 200.8 Rev 5.4
QC Batch Method: EPA 200.8 Rev 5.4 Analysis Description: 200.8 MET Dissolved
Associated Lab Samples: 92456166001, 92456166002
METHOD BLANK: 2752348
Associated Lab Samples:
92456166001, 92456166002
Parameter
Units
Cadmium, Dissolved
ug/L
Copper, Dissolved
ug/L
Lead, Dissolved
ug/L
Zinc, Dissolved
ug/L
Matrix: Water
Blank
Reporting
Result
Limit
Analyzed
ND
0.080
12/12/19 01:08
ND
0.50
12/12/19 01:08
ND
0.10
12/12/19 01:08
ND
5.0
12/12/19 01:08
Qualifiers
LABORATORY CONTROL SAMPLE:
2752349
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
Cadmium, Dissolved
ug/L
10
10.0
100
85-115
Copper, Dissolved
ug/L
50
48.7
97
85-115
Lead, Dissolved
ug/L
50
51.2
102
85-115
Zinc, Dissolved
ug/L
50
47.1
94
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2752350
2752351
MS
MSD
92455674032 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Cone.
Cone.
Result
Result
% Rec
% Rec
Limits RPD Qual
Cadmium, Dissolved
ug/L
ND 10
10
9.6
9.7
96
97
70-130 0
Copper, Dissolved
ug/L
ND 50
50
47.0
47.4
94
94
70-130 1
Lead, Dissolved
ug/L
ND 50
50
48.7
49.3
97
99
70-130 1
Zinc, Dissolved
ug/L
ND 50
50
45.9
45.9
89
89
70-130 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513818
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Associated Lab Samples: 92456166001, 92456166002
METHOD BLANK: 2754270
Matrix:
Water
Associated Lab Samples: 92456166001, 92456166002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Dissolved Solids
mg/L
ND
10.0
12/09/19 23:10
LABORATORY CONTROL SAMPLE:
2754271
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250
266
106 80-120
SAMPLE DUPLICATE: 2754272
92455975001
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Dissolved Solids
mg/L
68.4
87.9
25
SAMPLE DUPLICATE: 2754273
92456166002
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Dissolved Solids
mg/L
18.8
26.7
35 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
QC Batch: 513300
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92456166001, 92456166002
METHOD BLANK: 2751783
Matrix: Water
Associated Lab Samples: 92456166001, 92456166002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Bromide mg/L
ND 0.10
12/07/1917:02
LABORATORY CONTROL SAMPLE: 2751784
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Bromide mg/L
2.5
2.4
96 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751785
2751786
MS
MSD
92456166001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L ND
2.5
2.5 2.4
2.4 94
97
90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2751787
2751788
MS
MSD
92456254009
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L ND
2.5
2.5 2.4
2.4 96
97
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: ASV _INST 12-5-19
Pace Project No.: 92456166
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
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aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
ASV _INST 12-5-19
92456166
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92456166001
ASV_INST_DN_1_INST_2019_049
EPA 200.7 Rev 4.4 1994
513274
EPA 200.7 Rev 4.4 1994
513281
92456166002
ASV_INST_UP_1_INST_2019_051
EPA 200.7 Rev 4.4 1994
513274
EPA 200.7 Rev 4.4 1994
513281
92456166001
ASV_INST_DN_1_INST_2019_049
EPA 200.8 Rev 5.4
513270
EPA 200.8 Rev 5.4
513292
92456166002
ASV_INST_UP_1_INST_2019_051
EPA 200.8 Rev 5.4
513270
EPA 200.8 Rev 5.4
513292
92456166001
ASV_INST_DN_1_INST_2019_049
EPA 200.8 Rev 5.4
513412
EPA 200.8 Rev 5.4
513460
92456166002
ASV_INST_UP_1_INST_2019_051
EPA 200.8 Rev 5.4
513412
EPA 200.8 Rev 5.4
513460
92456166001
ASV_INST_DN_1_INST_2019_049
EPA 1631 E
513889
EPA 1631 E
514141
92456166002
ASV_INST_UP_1_INST_2019_051
EPA 1631E
513889
EPA 1631E
514141
92456166003
ASV_INST_DN_1_INST_2019_050
EPA 1631E
513889
EPA 1631E
514141
92456166004
ASV_INST_UP_1_INST_2019_052
EPA 1631E
513889
EPA 1631E
514141
92456166001
ASV_INST_DN_1_INST_2019_049
SM 2540C-2011
513818
92456166002
ASV INST UP 1
INST 2019 051
SM 2540C-2011
513818
92456166001
ASV_INST_DN_1_INST_2019_049
EPA 300.0 Rev 2.1 1993
513300
92456166002
ASV_INST_UP_1_INST_2019_051
EPA 300.0 Rev 2.1 1993
513300
Date: 12/12/2019 03:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 19

Document Name:
Sample Condition Upon Recefpt(SCUR)
Docurnent Revised: February 7, 2018
Page 1 of 2
aceAnaly al
Document No.:
F-CAR-CS-033-Rev.06
Issuing Authority:
Pace Carolinas Quality Office
Laboratory receiving sa pies:
Asheville ! Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
ConditionSample Client Name: WO# : 92456166
Upon Receipt 1/Project #:
Courier: ❑Fed Ex [:JulS ❑115P5 I ❑Client Il 111 11� 1111 I I1 II ill
❑ Commercial ❑Pace ❑Other: 92455156
Custody Seal Present? '6yes [:]No Seals Intact? ❑Yes ONO
Date/Initials Person Examining Contents J
12'S—)
Packing Material: ❑Bubble Wrap r/ Hubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑Nc,�/A
/j•�rb%� Type of Ice: Wet ❑Blue ❑None
PrIRGunIQ: rl LLL���
Cooler Temp (°C); f, Correction Factor: Add/Subtract (°C) 0
Temp should be above freezing to VC
Cooler Temp Corrected (°C): j _,____ ❑samples out of temp criteria, samples on ice, cooling process
has begun
USDA Regulated Soil (l—li N/A, water sample)
Did samples originate in a quarantine zone within the United Skates: CA, NY, or SC (check maps)? Did sarnples originate from a foreign source (internationally,
nv— MNI , including Hawaii and Puerto Rico)? ❑Yes [:]No
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analys
Headspace in VOA Vials (>5-6mm)
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTI
Person contacted:
OLUTION
Yes []No
❑N/A
1.
Yes ❑No
❑N/A
2.
Yes No
❑N/A
3.
Yes No
_[]N/A
4.
Yes ❑No
❑N/A
5.
Yes ONO
❑N/A
6,
©Yes ❑No ❑N/A 7.
[-]Yes No ❑N/A 8.
EjYes ❑No ❑N/A 9•
U./ I
❑Yes []NO Q]N/A 10.
❑Yes [--]No N/A 11.
Date/Time:
Lot ID of split containers:
Field Data Required? []Yes 01
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:'
Page 16 of 19

Document Name:
Document Revised: February 7, 2018
/
/ (�Pt�CBA17ciIlGc�l
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Dffice
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # WO# : 92456166
PM: UP Due Date: 12/12/19
CLIENT: 92-Duke Ener
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, cut of temp, incorrect containers.
Page 17 of 19

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DO (mg1L)
Cond (uSlcm)
pH (SI)
i Do Saturation
Salinity (ppm)
Secchi(m)
Turgidity (NTU)
Logger_Depth (m)
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Page 19 of 19

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
December 17, 2019
Mr. Matthew Fields
Duke Energy Progress, Inc.
RE: Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
Dear Mr. Fields:
Enclosed are the analytical results for sample(s) received by the laboratory on December 10, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Mariea Keezel, Duke Energy
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92456754001 FIELD BLANK EPA 1631 E
RDT
1
PASI-A
92456754002 OUTFALL 001 2019/12/10 0750 N EPA 1664B
HH
1
PASI-C
EPA200.7 Rev 4.4 1994
SH1
11
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
SM 254OD-2011
CJL
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
Sample: FIELD BLANK Lab ID: 92456754001 Collected: 12/10/19 07:50 Received: 12/10/19 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level
Mercury
Date: 12/17/2019 04:25 PM
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
0.683 ng/L 0.50 1 12/11/1915:52 12/17/1911:54 7439-97-6 CO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
Sample: OUTFALL Lab ID: 92456754002 Collected: 12/10/19 07:50 Received: 12/10/19 14:25 Matrix: Water
001 _2019/12/10_0750_N
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
200.7 MET ICP
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Zinc
1631E Mercury,Low Level
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
300.0 IC Anions 28 Days
Bromide
Fluoride
4500 Chloride
Chloride
Date: 12/17/2019 04:25 PM
Analytical Method: EPA 1664B
ND mg/L
5.0
1
12/16/1910:37
Analytical Method: EPA 200.7 Rev 4.4 1994
Preparation Method: EPA 200.7 Rev 4.4 1994
120 ug/L
10.0
1
12/11/19 01:06
12/12/19 02:27
7440-38-2
ND ug/L
1.0
1
12/11/19 01:06
12/12/19 02:27
7440-41-7
1.6 ug/L
1.0
1
12/11/19 01:06
12/12/19 02:27
7440-43-9
9.6 ug/L
5.0
1
12/11/19 01:06
12/12/19 02:27
7440-47-3
ND ug/L
5.0
1
12/11/19 01:06
12/12/19 02:27
7440-50-8
ND ug/L
5.0
1
12/11/19 01:06
12/12/19 02:27
7439-92-1
ND ug/L
5.0
1
12/11/19 01:06
12/12/19 02:27
7440-02-0
56.9 ug/L
10.0
1
12/11/19 01:06
12/12/19 02:27
7782-49-2
ND ug/L
5.0
1
12/11/19 01:06
12/12/19 02:27
7440-22-4
187000 ug/L
662
1
12/11/19 01:06
12/12/19 02:27
ND ug/L
10.0
1
12/11/19 01:06
12/12/19 02:27
7440-66-6
Analytical Method: EPA 1631 E Preparation
Method: EPA 1631 E
1.99 ng/L
0.50
1
12/11/1915:52
12/16/1916:24
7439-97-6
Analytical Method: SM 2540C-2011
347 mg/L
25.0
1
12/13/1912:57
Analytical Method: SM 254OD-2011
11.2 mg/L
3.3
1
12/13/19 20:06
Analytical Method: EPA 300.0 Rev 2.1 1993
0.25 mg/L
0.10
1
12/12/1912:36
24959-67-9
0.89 mg/L
0.10
1
12/12/1912:36
16984-48-8
Analytical Method: SM 4500-CI-E-2011
22.1 mg/L
1.0
1
12/16/19 21:58
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 18

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514986
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92456754002
METHOD BLANK: 2759820
Matrix: Water
Associated Lab Samples: 92456754002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0
12/16/19 10:34
LABORATORY CONTROL SAMPLE: 2759821
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 31.6
79 78-114
MATRIX SPIKE SAMPLE: 2759822
35517420002 Spike
MS MS % Rec
Parameter
Units
Result Cone.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
2.1J 40
48.1 115 78-114 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/17/2019 04:25 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 18

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514163
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92456754001, 92456754002
METHOD BLANK: 2755639
Matrix: Water
Associated Lab Samples: 92456754001, 92456754002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/16/1915:05
METHOD BLANK: 2755649
Matrix: Water
Associated Lab Samples: 92456754001, 92456754002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/16/1915:58
METHOD BLANK: 2755650
Matrix: Water
Associated Lab Samples: 92456754001, 92456754002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/16/1917:02
LABORATORY CONTROL SAMPLE: 2755651
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Mercury ng/L
5 5.27
105 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2755652 2755653
MS MSD
92456754002
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury ng/L 1.99
25 25 29.6
28.2 110 105 71-125 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/17/2019 04:25 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 18

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514077
Analysis Method:
EPA 200.7 Rev 4.4
1994
QC Batch Method: EPA 200.7 Rev 4.4 1994
Analysis Description:
200.7 MET
Associated Lab Samples: 92456754002
METHOD BLANK: 2755395
Matrix: Water
Associated Lab Samples: 92456754002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Arsenic
ug/L
ND
10.0
12/12/19 01:33
Beryllium
ug/L
ND
1.0
12/12/19 01:33
Cadmium
ug/L
ND
1.0
12/12/19 01:33
Chromium
ug/L
ND
5.0
12/12/19 01:33
Copper
ug/L
ND
5.0
12/12/19 01:33
Hardness, Total(SM 2340B)
ug/L
ND
662
12/12/19 01:33
Lead
ug/L
ND
5.0
12/12/19 01:33
Nickel
ug/L
ND
5.0
12/12/19 01:33
Selenium
ug/L
ND
10.0
12/12/19 01:33
Silver
ug/L
ND
5.0
12/12/19 01:33
Zinc
ug/L
ND
10.0
12/12/19 01:33
LABORATORY CONTROL SAMPLE:
2755396
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
Arsenic
ug/L
500
476
95
85-115
Beryllium
ug/L
500
488
98
85-115
Cadmium
ug/L
500
461
92
85-115
Chromium
ug/L
500
484
97
85-115
Copper
ug/L
500
487
97
85-115
Hardness, Total(SM 2340B)
ug/L
33100
32000
97
85-115
Lead
ug/L
500
468
94
85-115
Nickel
ug/L
500
463
93
85-115
Selenium
ug/L
500
452
90
85-115
Silver
ug/L
250
243
97
85-115
Zinc
ug/L
500
462
92
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2755397
2755398
MS
MSD
92456606001
Spike
Spike
MS
MSD MS MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result % Rec
% Rec
Limits RPD Qual
Arsenic
ug/L
ND
500
500
526
511
105 102
70-130 3
Beryllium
ug/L
ND
500
500
518
513
104 103
70-130 1
Cadmium
ug/L
ND
500
500
505
498
101 100
70-130 1
Chromium
ug/L
ND
500
500
509
504
102 101
70-130 1
Copper
ug/L
3.OJ
500
500
521
515
104 102
70-130 1
Hardness, Total(SM 2340B)
ug/L
115000
33100
33100
150000
147000
104 96
70-130 2
Lead
ug/L
ND
500
500
498
491
100 98
70-130 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2755397
2755398
MS
MSD
92456606001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nickel ug/L
ND
500
500
491
483
98
96
70-130
2
Selenium ug/L
ND
500
500
520
509
104
102
70-130
2
Silver ug/L
ND
250
250
257
256
103
102
70-130
0
Zinc ug/L
ND
500
500
501
490
100
98
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514668
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Associated Lab Samples: 92456754002
METHOD BLANK: 2758356
Matrix:
Water
Associated Lab Samples: 92456754002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
12/13/19 12:57
LABORATORY CONTROL SAMPLE: 2758357
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
246
99
90-110
SAMPLE DUPLICATE: 2758358
92456810003
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
ND
ND
SAMPLE DUPLICATE: 2758359
92456609028
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
578
565
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514781
Analysis Method:
SM 2540D-2011
QC Batch Method: SM 254OD-2011
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92456754002
METHOD BLANK: 2759046
Matrix:
Water
Associated Lab Samples: 92456754002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/13/19 20:05
LABORATORY CONTROL SAMPLE: 2759047
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250
236
94 90-110
SAMPLE DUPLICATE: 2759048
92457077001
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
169
166 2
SAMPLE DUPLICATE: 2759049
92456738002
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
197
187 5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 514072 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92456754002
METHOD BLANK: 2755381 Matrix: Water
Associated Lab Samples: 92456754002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Bromide mg/L ND 0.10 12/12/19 06:50
Fluoride mg/L ND 0.10 12/12/19 06:50
LABORATORY CONTROL SAMPLE: 2755382
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Bromide mg/L 2.5 2.6 103 90-110
Fluoride mg/L 2.5 2.7 109 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2755383
2755384
MS
MSD
92456609014 Spike
Spike
MS
MSD MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L 0.0951 2.5
2.5
2.9
2.9 113
114
90-110 0 M1
Fluoride mg/L 0.12 2.5
2.5
3.0
3.1 116
117
90-110 1 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2755385
2755386
MS
MSD
92456731001 Spike
Spike
MS
MSD MS
MSD % Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec Limits RPD Qual
Bromide mg/L ND 2.5
2.5
ND
ND 0
0 90-110 M1
Fluoride mg/L ND 2.5
2.5
3.6
3.6 102
101 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/17/2019 04:25 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
QC Batch: 515103
Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description: 4500 Chloride
Associated Lab Samples: 92456754002
METHOD BLANK: 2760461
Matrix: Water
Associated Lab Samples: 92456754002
Blank
Reporting
Parameter Units
Result
Limit
Analyzed
Qualifiers
Chloride mg/L
ND 1.0
12/16/19 21:56
LABORATORY CONTROL SAMPLE: 2760462
Spike
LCS
LCS % Rec
Parameter Units
Cone.
Result
% Rec Limits
Qualifiers
Chloride mg/L
20
20.7
103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2760463
2760464
MS
MSD
92456754002
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/L 22.1
10
10 32.3
32.5 102
104
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2760465
2760466
MS
MSD
92456799001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Chloride mg/L ND
10
10 10.2
10.2 98
98
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/17/2019 04:25 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 18

aceAnalytical
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205 East Meadow Road - Suite A
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[phone]
QUALIFIERS
Project: OUTFALL 001 12-10-19
Pace Project No.: 92456754
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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205 East Meadow Road - Suite A
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
OUTFALL 001 12-10-19
92456754
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92456754002
OUTFALL
EPA 1664B
514986
001 _2019/12/10_0750_N
92456754002
OUTFALL
EPA 200.7 Rev 4.4 1994
514077
EPA 200.7 Rev 4.4 1994
514094
001 _2019/12/10_0750_N
92456754001
FIELD BLANK
EPA 1631 E
514163
EPA 1631 E
514294
92456754002
OUTFALL
EPA 1631E
514163
EPA 1631E
514294
001 _2019/12/10_0750_N
92456754002
OUTFALL
SM 254OC-2011
514668
001 _2019/12/10_0750_N
92456754002
OUTFALL
SM 254OD-2011
514781
001 _2019/12/10_0750_N
92456754002
OUTFALL
EPA 300.0 Rev 2.1 1993
514072
001 _2019/12/10_0750_N
92456754002
OUTFALL
SM 4500-CI-E-2011
515103
001 _2019/12/10_0750_N
REPORT OF LABORATORY ANALYSIS
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Document Name:
Document Revised: February 7, 2018
�WceAnapical'
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville Eden[-] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
WO#'92456754
Courier:
❑ Commercial
Custody Seal Present?
Client Name: •
Dlk- re re 5 S Project #:
[]Fed Ex ❑UPS [JUSpV ❑Client
,Pace ❑other: 92455754
/ZYes [:]No Seals Intact? oes ❑No
Packing Material: ❑Bubble Wrap ZB bhle Bags ❑None ❑ other
Thermometer: w b p Type of Ice: 13'iVet ❑Blue
OR Gun ID: 93
Cooler Temp VQ J / Correction Factor: Add/Subtract (°C) 4)y
Cooler Temp Corrected (°C): 7 f
USDA Regulated Soil (�N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
Date/Initials Person Examining Contents: J
Biological Tissue Frozen?
❑Yes ❑No E—N/A
[]None
Temp should be above freezing to 6°C
E]5amples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
Dyes [:]No
inciuoirg staeran an❑ ruesiunMur1 1 11— L-",-
Comments/Discrepancy:
Chain of Custody Present?
Yes
❑No
❑N/A
1.
Samples Arrived within Hold Time?
Yes
❑Nc
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
[-]Yes
o
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
o
❑N/A
4.
Sufficient Volume?
yes
[]NO
❑N/A
5.
Correct Containers Used?
Yes
[]No
El N/A
6.
-Pace Containers Used?
Yes
[-]No
[_]N/A
Containers Intact?
Yes
❑Na
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
rNNo
[]N/A
8.
Sample Labels Match CDC?
ZrYes
❑No
❑N/A
9.
-Includes Date/Time/ID/Analysis Matrix:
w�
Headspace in VOA Vials (>5-6mm)?
Oyes
❑No
N/A
10.
Trip Blank Present?
❑Yes
❑No
N/A
TN/A
11.
Trip Blank Custody Seals Present?
❑Yes
ONO
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Lot ID of split containers:
Date:
Date:
Field Data Required? ❑Yes RfAo
Page 16 of 18

Document Name:
Document Revised: February 7, 2018
,f
-PkeARaMical
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechiorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # Wp# ; 92456754
PM: UP Due Date: 12/17/19
CLIENT: 95-PROGRESS
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot If
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form tiaiil be sent to the North Carolina DEHNn Ceroticanon GTnte ii.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 17 of 18

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Page 18 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
December 26, 2019
Mr. Matthew Fields
Duke Energy Progress, Inc.
RE: Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
Dear Mr. Fields:
Enclosed are the analytical results for sample(s) received by the laboratory on December 16, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Mariea Keezel, Duke Energy
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
Page 2 of 18

aceAnalytical
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92457552001 FIELD BLANK EPA 1631 E
RDT
1
PASI-A
92457552002 OUTFALL 001 2019/12/16 1040 N EPA 1664B
HH
1
PASI-C
EPA200.7 Rev 4.4 1994
SH1
11
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
SM 254OD-2011
CEH
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
SM 4500-CI-E-2011
MDW
1
PASI-A
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
Sample: FIELD BLANK Lab ID: 92457552001 Collected: 12/16/19 10:40 Received: 12/16/19 14:37 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level
Mercury
Date: 12/26/2019 02:21 PM
Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
0.666 ng/L 0.50 1 12/18/1916:52 12/19/1914:54 7439-97-6 CO
REPORT OF LABORATORY ANALYSIS
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Page 4 of 18

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[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
Sample: OUTFALL Lab ID: 92457552002 Collected: 12/16/19 10:40 Received: 12/16/19 14:37 Matrix: Water
001 _2019/12/16_1040_N
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
200.7 MET ICP
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Zinc
1631E Mercury,Low Level
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
300.0 IC Anions 28 Days
Bromide
Fluoride
4500 Chloride
Chloride
Date: 12/26/2019 02:21 PM
Analytical Method: EPA 1664B
ND mg/L
4.8
1
12/20/19 09:13
Analytical Method: EPA 200.7 Rev 4.4 1994
Preparation Method: EPA 200.7 Rev 4.4 1994
85.8 ug/L
10.0
1
12/18/19 01:18
12/19/19 03:15
7440-38-2
ND ug/L
1.0
1
12/18/19 01:18
12/19/19 03:15
7440-41-7
ND ug/L
1.0
1
12/18/19 01:18
12/19/19 03:15
7440-43-9
5.9 ug/L
5.0
1
12/18/19 01:18
12/19/19 03:15
7440-47-3
ND ug/L
5.0
1
12/18/19 01:18
12/19/19 03:15
7440-50-8
ND ug/L
5.0
1
12/18/19 01:18
12/19/19 03:15
7439-92-1
6.8 ug/L
5.0
1
12/18/19 01:18
12/19/19 03:15
7440-02-0
43.2 ug/L
10.0
1
12/18/19 01:18
12/19/19 03:15
7782-49-2
ND ug/L
5.0
1
12/18/19 01:18
12/19/19 03:15
7440-22-4
168000 ug/L
662
1
12/18/19 01:18
12/19/19 03:15
32.3 ug/L
10.0
1
12/18/19 01:18
12/19/19 03:15
7440-66-6
Analytical Method: EPA 1631 E Preparation
Method: EPA 1631 E
3.44 ng/L
0.50
1
12/18/1916:52
12/19/1913:47
7439-97-6
Analytical Method: SM 2540C-2011
309 mg/L
25.0
1
12/23/1919:10
Analytical Method: SM 254OD-2011
12.6 mg/L
2.5
1
12/19/19 05:53
Analytical Method: EPA 300.0 Rev 2.1 1993
0.11 mg/L
0.10
1
12/18/19 08:31
24959-67-9
0.62 mg/L
0.10
1
12/18/19 08:31
16984-48-8
Analytical Method: SM 4500-CI-E-2011
22.9 mg/L
1.0
1
12/20/19 21:38
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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205 East Meadow Road - Suite A
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[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 515959
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92457552002
METHOD BLANK: 2764710
Matrix: Water
Associated Lab Samples: 92457552002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0
12/20/19 07:37
LABORATORY CONTROL SAMPLE: 2764711
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
38.5 38.5
100 78-114
MATRIX SPIKE SAMPLE: 2764712
92456978001 Spike
MS MS % Rec
Parameter
Units
Result Cone.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 38.5
9.9 16 78-114 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 515316
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92457552001, 92457552002
METHOD BLANK: 2761400
Matrix: Water
Associated Lab Samples: 92457552001, 92457552002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/19/1910:39
METHOD BLANK: 2761401
Matrix: Water
Associated Lab Samples: 92457552001, 92457552002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/19/1911:40
METHOD BLANK: 2761402
Matrix: Water
Associated Lab Samples: 92457552001, 92457552002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
12/19/1914:40
LABORATORY CONTROL SAMPLE: 2761403
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Mercury ng/L
5 5.76
115 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761404 2761405
MS MSD
92457552002
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury ng/L 3.44
25 25 33.1
34.1 119 123 71-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/26/2019 02:21 PM without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 515396 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92457552002
METHOD BLANK: 2761889
Associated Lab Samples: 92457552002
Parameter
Arsenic
Beryllium
Cadmium
Chromium
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Zinc
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
10.0
12/19/19 03:03
ug/L
ND
1.0
12/19/19 03:03
ug/L
ND
1.0
12/19/19 03:03
ug/L
ND
5.0
12/19/19 03:03
ug/L
ND
5.0
12/19/19 03:03
ug/L
ND
662
12/19/19 03:03
ug/L
ND
5.0
12/19/19 03:03
ug/L
ND
5.0
12/19/19 03:03
ug/L
ND
10.0
12/19/19 03:03
ug/L
ND
5.0
12/19/19 03:03
ug/L
ND
10.0
12/19/19 03:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2761890
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits
Arsenic
ug/L
500
501
100
85-115
Beryllium
ug/L
500
501
100
85-115
Cadmium
ug/L
500
493
99
85-115
Chromium
ug/L
500
489
98
85-115
Copper
ug/L
500
492
98
85-115
Hardness, Total(SM 2340B)
ug/L
33100
32300
98
85-115
Lead
ug/L
500
500
100
85-115
Nickel
ug/L
500
493
99
85-115
Selenium
ug/L
500
493
99
85-115
Silver
ug/L
250
251
100
85-115
Zinc
ug/L
500
492
98
85-115
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2761891
2761892
MS
MSD
92457552002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
85.8
500
500
600
607
103
104
70-130
1
Beryllium
ug/L
ND
500
500
497
501
99
100
70-130
1
Cadmium
ug/L
ND
500
500
505
511
101
102
70-130
1
Chromium
ug/L
5.9
500
500
496
501
98
99
70-130
1
Copper
ug/L
ND
500
500
495
499
98
99
70-130
1
Hardness, Total(SM 2340B)
ug/L
168000
33100
33100
195000
194000
80
79
70-130
0
Lead
ug/L
ND
500
500
495
507
99
101
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/26/2019 02:21 PM without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2761891
2761892
MS
MSD
92457552002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Nickel ug/L
6.8
500
500
493
503
97
99
70-130
2
Selenium ug/L
43.2
500
500
556
572
103
106
70-130
3
Silver ug/L
ND
250
250
250
252
100
101
70-130
1
Zinc ug/L
32.3
500
500
525
537
99
101
70-130
2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 516110
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Associated Lab Samples: 92457552002
METHOD BLANK: 2765479
Matrix:
Water
Associated Lab Samples: 92457552002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
12/20/19 17:20
LABORATORY CONTROL SAMPLE: 2765480
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
251
262
104
90-110
SAMPLE DUPLICATE: 2765481
92457542003
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
76.0
76.0
0
SAMPLE DUPLICATE: 2765482
92457994001
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
161
157
3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 515681
Analysis Method:
SM 2540D-2011
QC Batch Method: SM 254OD-2011
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92457552002
METHOD BLANK: 2763259
Matrix:
Water
Associated Lab Samples: 92457552002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 12/19/19 05:53
LABORATORY CONTROL SAMPLE: 2763260
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
Total Suspended Solids
mg/L
250
236
94 90-110
SAMPLE DUPLICATE: 2763290
92457843003
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
38.3
41.4 8
SAMPLE DUPLICATE: 2763291
92457795001
Dup
Parameter
Units
Result
Result
RPD Qualifiers
Total Suspended Solids
mg/L
870
855 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 515388 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92457552002
METHOD BLANK: 2761863 Matrix: Water
Associated Lab Samples: 92457552002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Bromide mg/L ND 0.10 12/18/19 06:49
Fluoride mg/L ND 0.10 12/18/19 06:49
LABORATORY CONTROL SAMPLE: 2761864
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Bromide mg/L 2.5 2.7 109 90-110
Fluoride mg/L 2.5 2.7 110 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761865
2761866
MS
MSD
92457516001 Spike
Spike
MS
MSD MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L ND 2.5
2.5
2.9
2.9 117
117
90-110 0 M1
Fluoride mg/L ND 2.5
2.5
3.0
2.9 120
118
90-110 2 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2761941
2761942
MS
MSD
92457377003 Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result
% Rec % Rec
Limits RPD Qual
Bromide mg/L 1.1 2.5
2.5
4.2
4.2
123 126
90-110 2 M1
Fluoride mg/L 1.2 2.5
2.5
4.0
4.1
110 113
90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 12/26/2019 02:21 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
QC Batch: 516122 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Associated Lab Samples: 92457552002
METHOD BLANK: 2765752 Matrix: Water
Associated Lab Samples: 92457552002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 12/20/19 21:36
LABORATORY CONTROL SAMPLE: 2765753
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.4 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2765754 2765755
MS MSD
92457552002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 22.9 10 10 32.7 32.3 99 94 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 13 of 18

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Project: OUTFALL 001 12-16-19
Pace Project No.: 92457552
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
CO Result confirmed by second analysis.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
OUTFALL 001 12-16-19
92457552
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92457552002
OUTFALL
EPA 1664B
515959
001 _2019/12/16_1040_N
92457552002
OUTFALL
EPA 200.7 Rev 4.4 1994
515396
EPA 200.7 Rev 4.4 1994
515422
001 _2019/12/16_1040_N
92457552001
FIELD BLANK
EPA 1631 E
515316
EPA 1631 E
515639
92457552002
OUTFALL
EPA 1631E
515316
EPA 1631E
515639
001 _2019/12/16_1040_N
92457552002
OUTFALL
SM 254OC-2011
516110
001 _2019/12/16_1040_N
92457552002
OUTFALL
SM 254OD-2011
515681
001 _2019/12/16_1040_N
92457552002
OUTFALL
EPA 300.0 Rev 2.1 1993
515388
001 _2019/12/16_1040_N
92457552002
OUTFALL
SM 4500-CI-E-2011
516122
001 _2019/12/16_1040_N
REPORT OF LABORATORY ANALYSIS
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OF Sample Condition Upon Receipt(SCUR} Page 1 of 2
- ceAnalytical' Document No.: Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville Eden[:] ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
ConditionSample Client Name: WO# :92457552
.. R. Project #:
�nk� �rp r�ss
Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client 11111111111111111111111111111
❑ Commercial dace ❑Other: 92457552
Custody Seal Present? ples ❑No Seals Intact? es []No
/ Date/Initials Person Examining Contents:
/ 2
Packing Material: []Bubble Wrap Zubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: []Yes❑No ON/A
� �,2./%n J� � Typu of Ice: Wet ❑Blue ❑None
1"' g Gun ID: "� ,l
Cooler Temp (°C): �� Correction Factor: Add/Subtract (°C} �ry
q Temp should be above freezing to 6°C
Cooler Temp Corrected (°C): [_ []Samples out of temp criteria. Samples on ice, cooiing process
has begun
USDA Regulated Soil (eN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source {Internationally,
FYes MNo including Hawaii and Puerto RicoP ❑Yes [:]No
Chain of Custody Present?
Yes
❑No
❑NIA
1.
Samples Arrived within Hold Time?
ves
❑No
❑NIA
2.
Short Hold Time Analysis (<72 hr.)?
❑Yes
No
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
No
❑N/A
4.
Sufficient Volume?
Yes
[]No
❑N/A
5.
Correct Containers Used?
Yes
[--]No
El
6.
-Pace Containers Used?
Yes
❑N❑
❑N/A
Containers Intact?
Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
ETNo
❑N/A
B.
Sample Labels Match COC?
Wes
[-]No
❑N/A
9.
-Includes Date/Time;'lD/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
TriD Blank Custodv Seal:; Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
❑Yes [:]No N/A 10.
❑Yes ❑No N/A 11,
I-1Yes F—INo N/A
Lot ID of split containers:
Field Data Required? ❑Yes *NO
Person contacted: Date/Time:
Project Manager SCURF Review: Date: t i Ll�l
i GI
r Id -
Project Manager SRF Review: Date: 1 [
Page 16 of 18

cument-Ram
7 2018
1:Sample
'aceArralytical
Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
-
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project #! WO# : 92457552
PM: UP Due Date: 12/23/19
CLIENT: 95—PROGRESS
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Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will to sent to the North Carolira DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, Out of temp, incorrect containers.
Page 17 of 18

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