NC0000396_Mercury Field Blank Information_20200304

Action History (UTC-05:00) Eastern Time (US & Canada)
Subrrit by Anonymous User 3/4/2020 4:35:59 PM (Supplemental Submittal)
Submit by Thedford, Wren 5/12/2020 9:20:07 AM (Supplemental Info Submittal)
• Thedford, Wren assigned the task to Thedford, Wren 5/12/2020 9:18 AM
• The task was assigned to Thedford, Wren, Bennett, Bradley 3/4/2020 4:36 PM

Initial Review Information
Updated ID#:* IWORTANf:FEVIBAERSl-IOLLDVERFYand revise here ifnecessary.
NC0000396
How should this project be handled?*
r File r Discard
Information Submitted on 3/4/2020
Submitter Information
Name: Teresa Williams
Vft is subrritting the inforrretion?
Email Address:* [e-mail]
Submittal Information
The Division of Water Resources (DWR) is providing this site to allow for the upload of required supplemental
information associated with discharge monitoring reports (DMR). All DMR data is required to be submitted
electronically through the eDMR system and should not be submitted here. Division staff will reviewall
uploaded documents and will only maintain required information. Documents such as laboratory reports are not required
to be submitted and will not be maintained in the system.
Project Information:
Rease SUDDly the Dernit nun ber for this
Existing ID#* PerrritNurrber
NC0000396
Exarrples: NOKxxxxxx or NO&xxxxx
Facility Name:* Asheville Steam Electric Plant
County: Buncombe
Please upload all files that need to be
submited. *
dick the upload button or drag and drop files here to attach docurrent
02-28-20 Jan NPDES DMR.pdf 6.95MB
Only pdf files are accepted.
Comments about the attachments:
* V By checking the box and signing box below, I certify that:
o I have given true, accurate, and complete information on this form;

• I agree that submission of this Supplemental Information form is a "transaction" subject to Chapter 66, Article 40 of the
NC General Statutes (the "Uniform Electronic Transactions Act)
• I agree to conduct this transaction by electronic means pursuant to Chapter 66, Article 40 of the NC General Statutes
(the "Uniform Electronic Transactions Act');
• I understand that an electronic signature has the same legal effect and can be enforced in the same way as a written
signature; AND
• I intend to electronically sign and submit the Supplemental Information form."
Full Name: Teresa Williams
Signature:
Date Submitted: 03/04/2020

n /� DUKE
ENERGY.,
PROGRESS
Submitted Electronically
File No.: 12520B
February 28, 2020
Memo
To: Central Files
NCDEQ, Division of Water Resources
1617 Mail Service Center
Raleigh, NC 27699-1617
From: Duke Energy Progress
Asheville Combined Cycle Station
46 Duke Energy Lane
Arden, NC 28704
RE: Asheville Steam Electric Generating Plant
Buncombe County
NPDES Number NC0000396
Discharge Monitoring Report (DMR)
Antonio D. Price, PE
Plant General Manager
Asheville Combined Cycle Station
Duke Energy Progress
ASVL PLT 146 Duke Energy Lane
Arden, NC 28704
o: 828-650-0620
f. 828-650-0701
[e-mail]
In accordance with condition I.A. (18) 1., replaced by electronic signature and submission
guidelines, the January 2020 NPDES eDMR for Duke Energy Progress's Asheville Steam
Electric Plant — NPDES Permit Number NC0000396 has been submitted.
The Outfall 001 low-level mercury field blank sample collected January 28, 2020 did not meet
quality control criteria in accordance with EPA Method 1631E. Per Division guidance ("NPDES
Mercury Requirement- EPA Method 1631 Additional Information"), the mercury field blank
samples have been noted in the eDMR comments section, and the associated analytical reports
are attached to this memo and uploaded electronically to the eDMR Supplement Data Upload
server.
Please contact Ms. Teresa Williams at [phone] or Ms. Mariea Keezel at [phone]
with any questions concerning the data in this submittal.

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1 PERMIT STATUS. Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields ORC CERT NUMBER: 1003106
GRADE: PC -I ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0 STATUS: Submitted
COMPLIANCE STATUS: Compliant CONTACT PHONE #: [phone] SUBMISSION DATE: 02/27/2020
t a?A U-1_ < 02/27/2020
ORC/C rtifier Signat e: Mariea Keezel E-Mail:mariea.keezel a duke-energy.com Phone #:[phone] Date
By this signature, I certify that this report is accurate and complete to the best of my knowledge.
The permittee shall report to the Director or the appropriate Regional Office any noncompliance that potentially threatens public health or the environment.
Any information shall be provided orally within 24 hours from the time the permittee became aware of the circumstances. A written submission shall also be
provided within 5 days of the time the permittee becomes aware of the circumstances.
If the facility is noncompliant, please attach a list of corrective actions being taken and a time -table for improvements to be made as required by part ILE.6 of
the NPDES permit.
02/27/2020
Perm ittee/Submitter`Signature:*** Andrew Sprague E-Mail:andrew.spraguerrduke-energy.com Phone 4:828-650-0619 Date
Permittee Address: 200 CPL Dr Arden NC 28704 Permit Expiration Date: 11/30/2023
I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who managed the
system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for
knowing violations.
CERTIFIED LABORATORIES
LAB NAME: Asheville Steam Electric Plant, Pace Analytical Services, Inc., Environmental Testing Solutions, Duke Energy Analytical Laboratory
CERTIFIED LAB #: 5055, 40, 12, 37,248
PERSON(s) COLLECTING SAMPLES: Matthew Fields, R.W. Smith, J.M. Swing
PARAMETER CODES
Parameter Code assistance may be obtained by calling the NPDES Unit [phone] or by visiting http://portal.ncdenr.org/web/wq/swp/ps/npdes/forms.
FOOTNOTES
Use only units of measurement designated in the reporting facility's NPDES permit for reporting data.
* No Flow/Discharge From Site: Check this box if no discharge occurs and, as a result, there are no data to be entered for all of the parameters on the DMR
for entire monitoring period.
** ORC on Site?: ORC must visit facility and document visitation of facility as required per 15A NCAC 8G .0204.
*** Signature of Permittee: If signed by other than the permittee, then delegation of the signatory authority must be on file with the state per 15A NCAC 2B
.0506(b)(2)(D).

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
Report Comments:
Qualifiers included for the following parameters:
MI -Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
to: Outfall 001-Chloride on 01-02-20,Fluoride, Chloride on 01128/20.
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
lg, B - Due to multiple reruns, we have insufficient sample left to reanalyze, Analyte was detected in the associated method blank. (Duplicate analyzed and results averaged )
Applied to Outfall 001 - Hg on 01-07-20
Rl-RPD value was outside control limits
Applied to: Outfall 001-Chloride on 01128120.
Outfall 002 permanently ceased flow from Coal Plant unit boilers once through cooling on 1120/20 at 1430.
The mercury field blank sample from 01/28/20 did not meet quality control criteria. The analytical report is uploaded with the electronic copy of the January 2020 DMR.

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC -I ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001
a
A
r
E
_
z
-
-
x
00010
01002
71870
01025
COa34
01040
60900
11019
COTTER
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
TEMP-C
A. -TOTAL
BROM@E
CD-DISSV
TOT CR CONC
CU-DISSV
TOT TURD
P&DISSV
MERCURY-
141111 c11,,k
deg
ugA
mgd
I ug/l
ugft
ugh
I nlgl
ugt
owl
2
3
4
5
6
7
S
1415
75
<0.1
<0.1
<008
:05
..0i
995
<01
149
9
II
II
12
13
14
15
16
17
IN
19
2u
21
22
23
2J
25
26
27
70
i9
3u
s1
11—thlr A —he Limit:
Monthly A—V:
75
0
0
0
0
0
8.95
0 1
1.49
Ddh Mhsi.—
7 5
0
0
0
0
0
8.95
0
1.49
D.lh Minimums
75
10 10
0 10
10 18.95
10
11.49
:*** No Reporting Reason ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR — No Visitation — adverse Weather; NOFLOW — No Flow; HOLIDAY — No Visitation — Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC -I ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001 (Continue)
c'
E
F
E`
5
a
aX
z
01147
702"
W070
01M
Monthly
Monthly
Monthly
Movably
Gaab
Grab
Grab
Grab
So -TOTAL
RESIDISS
TURBIDTY
7N.DISSV
240n d-k
ugA
mgfl
mu
ugR
3
A
c
7
1415
=01
-.10
42
<r5
9
LII
LI
12
13
14
15
L6
17
16
L9
20
21
22
23
24
25
26
27
28
29
3n
31
hbn" A—g-LW,i
n[an0 h A,e W:
0
0
4.2
0
'
o
0
42
o
Dao6u N.J.—'
U 1
0
4.2
0
• "' No Reporting Reason: ENFRUSE = No Flow-ReuselRccycle; ENV WTHR = No Visitation — Adverse Weather; NOFLOW — No Flow; HOLIDAY = No Visitation — Holiday

NPDES PERMIT NO.: NC0000396
PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC
ORC: Matthew Holcomb Fields
GRADE: PC-1
ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020)
VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO
A
E
=
v
s
F=
E
O
=
Y
O
O
F
a
X
lullM
oo4oa
CW30
C0604
CD665
.100E
u1012
71STU
01927
Weekly
Weekly
Weekly
Monthly
Monthly
Weekly
Weekly
Weekly
Weekly
Instantaneous
Grab
Grab
Grab
Grab
Grab
Grab -
Grab
Grab
FLOW
pit
TSS-Coot
TOTALN-
TOTALP-Cnnc
Ar TOTAL
BERYLIUSI
BROMIDE
CADS1Nar
14ou rkd
Hn
24110 dad
Hn
YIBIN
mgd
so
mgR
mgli
mgl
U94
LIM
me_/1
u gAl
I
N
2
600
9.8
Y
0.99
8 1
3 3
3 2
0 17
24.2
< 1
0 54
< I
3
N
J
N
5
N
6
N
7
600
8.8
Y
Sat
78
64
565
-. 1
017
<1
600
92
Y
°
N
o
N
It
N
12
N
13
N
18
600
9.5
Y
1 13
76
:5
244
<1
<0.1
<:
15
N
16
600
9.2
Y
81
17
N
18
N
19
N
20
N
21
N
2'
N
-'3
600
11.5
Y
1 27
8 l
3 8
< 10
-- 1
1 2
< I
{
N
i5
N
26
N
27
1 N
'-x
600
10.2
Y
1 42
7 7
3 5
-'. 10
< 1
024
< 1
Y9
N
3u
N
31
N
Monthly A—g,, Lim11:
30
M...hh A.—E.,:
1 852
3.4
3.2
0.17 12102
10
10.43
0
D.ih Muirrr—
445
8.1
6.4
3.2
0.17
56.5
0
11
0
Dain arnirr—
'
0.99
7.6
it
13.2
10.17
0
0
0
0
**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR = No Visitation -- Adverse Wealher, NOFLOW = No Flow; HOLIDAY — No Visitation — Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power P1antCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC -I ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO (Continue)
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F
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=
5
40940
01034
01042
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aiu67
BOM6
TGP3n
DI 147
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Weekly
Weekly
Weekly
Weekly
Weekly
Weekly
Weekly
Weekly
Monthly
Weekly
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
CHLORIDE
CrvTOTAL
COPPER
F-TOTAL
TOT HARD
LEAD
MERCURY.
NICKEL
Ol4CRSE
CER170PF
Se -TOTAL
241111 d rk
nr,
una rlurk
lir
Y!&N
mgll
u
ug.l
mg l
mgll
ugll
nwi
vyl
.0
pass/rail
1
N
2
1
500
98
Y
344
<5
<5
026
116
<5
IH
6.3
1<49
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3
N
4
IN
5
N
6
N
7
600
88
Y
23.1
<5
<5
0.32
195
=5
1.87
1L5
15
14.5
%
600
9 2
Y
9
N
n
N
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13
N
14
600
9.5
Y
27.9
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<5
023
138
155
11.7
20
1
11.2
S
N
16
600
9.2
Y
]7
N
Is
N
19
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2e
N
21
N
22
N
B
600
11.5
Y
876
<5
81
027
130
c5
g,64
9.9
15
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13
N
25
N
26
N
27
N
-'a
600
102
Y
422
<5
<5
<01
117
30b
159*-4.B
<10
29
N
311
N
31
N
Monlhl3 A—V Limit:
IS
Mnn16h' Average.
43.04
0
L62
0216
1372
0
2646
F 1.26
4
1
5.14
Daih M.".­'
87.6
0
8.1
0.32
185
0
5.64
16.9
20
]
]45
o.lh nrnim�m:
'
23.1
0
0
0
116
0
f.11
69 1D
]
0
**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR — No Visitation -- Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation — Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC
GRADE: PC- l
eDMR PERIOD: 01-2020 (January 2020)
ORC: Matthew Holcomb Fields ORC CERT NUMBER: 1003106
ORC HAS CHANGED: No
VERSION: 1-0
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001 NO DISCHARGE*: NO (Continue)
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Grab
Grab
SILVER
RrstDlss
TDRBIDTY
ZINC
CER7DCHV
2400 Mock
H.
2400 Mack
Hn
VISIN
ug2l
MEA
Mu
u
percent
I
N
2
600
98
Y
< 5
280
1.4
10.6
3
N
4
N
i
N
6
N
7
600
88
Y
<S
358
14
107
e
600
92
Y
9
N
In
N
11
N
12
N
13
N
14
600
9.5
Y
-' S
339
16
-: 10
15
N
16
600
19.2
1'
IT
N
l8
N
19
N
20
N
21
N
22
N
23
600
11.5
Y
<5
396:1
562
2A
N
25
N
26
N
27
N
2s
609
102
IY
1
< 5
247
< 1
75.8
29
N
3ti
N
31
N
M—tkiy A—V Limit:
M1luethlr AvenOe:
0
324
0 38
30.66
Daih Marlmum:
'
0
396
1.6
75.8
D+ih hlieimum:
D
247 10
0
**** No Reporting Reason: ENFRUSE =No Flow-Reuse/Recycle; ENVWTHR —No Visitation— Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation— Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 10
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: UPSTREAM DISCHARGE NO.: 001
E
E
z
z'
nanln
91002
71870
01025
C0054
01070
109on
01649
CONIER
Monibly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Grab
Grab
Grab
Grab
Crab
Grab
Grab
Grab
Grab
TEMP-C
As TOTAL
BROMIDE
Cn-DIssv
TOT CR CONC
CU-DI5Sv
TOT HARD
PB-DIssV
I MERCURY-
24110 `" -k
&L c
ug l
mg 1
ug%I
ugA
ugA
mg-0
ug,l
ngIl
s
S
6
7
s
1215
7.1
<0.1
<0.1
<0.08
=U5
057
18S9
:01
U885
9
10
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1!
IJ
IS
16
17
Is
19
20
21
22
23
24
25
26
17
is
29
lu
31
Monlhl2 A-mge Limit:
Alnnihty w.m�:
71
0
0
0
0
0.57
8.89
0
0.885
D.ily dlsimum:
71
0
0
0
0
0.57
8,89
0
0.885
Dni7 htin;mnm:
'
71 10
10
10
0
0.57
8,89
0
0.885
•;• t No Reporting Reason: ENFRUSE = No Flow-ReuselRecycle; ENV WTHR = No Visitation — Adverse Weather; NOFLOW — No Flow; HOLIDAY = No Visitation — Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: UPSTREAM DISCHARGE NO.: 001 (Continue)
-
E
F
E
!1
Y
x
z
ot147
70295
a116711
0111"
Monthly
Monthly
Monthly
Monthly
Grab
Grab
Grab
Grab
Se TOTAL
RESID15S
TUREWTV
ZN-D1SSV
24110 Murk
ugll
M10
ntu
UFA
l
3
J
6
7
S
1145
<0.5
208
5S
<5
9
111
Il
12
13
14
15
16
17
18
19
21)
21
22
23
ZJ
2S
26
27
28
29
30
it
afonthh Aren�e Limih
alanf6h A.erare:
0
20 $
5.5
0
Daih M..[. :
'
0
20_a
5.5
0
0 I
20.a 15
s
o
•i0i No Reporting Reason: ENFRUSE = No Flow•ReuselRecycle; ENVWTHR - No Visitation - Adt'erse Weather; NOFLOW = No Flow; HOLIDAY= No Visitation - Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC
GRADE: PC-1
eDMR PERIOD: 0I-2020 (January 2020)
ORC: Matthew Holcomb Fields ORC CERT NUMBER: [003106
ORC HAS CHANGED: No
VERSION: 1.0
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: OOIA NO DISCHARGE*: NO
u
7
P
=
^
u
z
z
SnnSn
C0530
oossf
Monthly
Monthly
Monthly
Estimate
Grab
Grab
rLOW
TS5-C.—
OIL-GaSE
2400 deck
Hr
2400 d-k
H.
Y/0rN
rngd
MM
MO
I
N
-
600
9.8
Y
3
N
4
N
5
N
6
N
7
600
8 8
Y
n
600
92
Y
049
34
14.8
7
III
11
N
12
N
13
N
14
600
9.5
IY
15
N
16
600
9.2
Y
17
N
IN
N
19
N
20
N
21
N
22
N
23
bU0
I1.5
Y
21
N
25
N
26
N
27
N
28
600
10.2
Y
29
N
30
N
31
%Wwhh A—pLimit:
30
rS
h1�nlh1, A+rrye�:
048
3.4
0
DAL, nl,cim—
0 48
34
0
Daih lcni—:
049
3.4
0
r«•• No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR = No Visitation -- Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation — Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001B NO DISCHARGE*: NO
C
E
,E
O
1 O
O
Z
sooso
C0531
n1356
Monthly
Monthly
Monthly
Estimate
Grab
Grab
FLOW
Tss -C.-
ott:GRSL
2401t cluck
H.
2411a clock
Hrs
YIBN
mgd
mVl
mglj
t
N
600
9.6
1 Y
3
N
i
N
5
N
6
N
7
600
as
Y
s
600
9.2
Y
1
0.01
<25_33
N
n
N
N
N
13
N
14
600
91.5
Y
15
N
16
600
9 2
1'
17
N
Is
N
19
N
20
N
21
N
22
N
23
600
11 S
Y
23
N
25
N
26
N
z7
N
29
aou
10 2
Y
29
N
31
N
3t
N
Moo16h A—p Limit:
30
15
Mouthlr A—V:
0.01
0
0
Dallr Maalmum:
'
0.01 10
0
D.ib Mielmum:
0.01
0 10
`••• No Reporling Reason, ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR — No Visitation — Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation — Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power P1antCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC
GRADE: PC- I
eDMR PERIOD: 01-2020 (January 2020)
ORC: Matthew Holcomb Fields ORC CERT NUMBER: 1003106
ORC HAS CHANGED: No
VERSION: 1.0
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001C NO DISCHARGE*: YES
a
tE
E
U
-=
—
F
o
v19
E
O
€
Ld
O
S
L
K
z
50050
COi30
0"54
monthly
Monthly
Monthly
Estimate
Grab
Grab
FLOW
T55-conr
OIGGRSE
2400 eInck
H.
2400 d-k
Hrs
VAYN
nlgd
m
-9A
t
N
2
600
9 &
Y
2
N
A
I
N
s
N
6
N
7
600
98
Y
„
600
92
ly
9
N
to
N
11
N
1'-
N
12
N
to
600
9.5
Y
U
N
16
600
9.2
Y
17
N
IN
N
19
N
21
N
21
N
--
N
23
600
I1.5 jy
24
N
25
N
26
N
27
N
2h
6110
102
Y
27
N
3i1
N
31
t
tiLnlhly A+v pLtmii:
30
Is
ltunnl)A-2r :
11aity M,iimum:
Daih Rfinimem:
. ••• No Reporting Reason: ENFRUSE = No Flow-Reuse[Recycle; ENV WTHR = No Visitation - Adverse Weather; NOFLOW - No Flow; HOLIDAY = No Visitation - Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power P1antCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC- l ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 001D NO DISCHARGE*: NO
C
g
fi
cJ
~
F=
_
O
O
O
V
O
r
z
Z
ssoso
cos3o
o-o-ss6
Monthly
Monthly
Monthly
Estimate
Grah
Glab
FLOW
Ts5-Cunc
OIL-GRSE
2400 cluck
H.
241111 dick
Hn
1'IRI\
mgd
-0
msA
I
N
2
0600
98
Y
s
N
4
N
N
G
N
7
600
8.8
Y
8
600
9.2
Y
0.00245
2.6
= 4 8
9
N
10
N
II
N
12
N
13
N
14
60G
9.5
Y
Is
N
16
600
92
Y
17
N
IN
N
19
N
211
N
21
N
22
N
23
600
11.5
Y
24
N
25
N
26
N
27
N
28
600
10.2
Y
29
N
m
N
31
N
N1.n1Ll3 A,—za UmN:
311
Is
amarof. A. enxe:
0.00245
26
0
o.n, nm�imum:
'
0.00245
2,6
0
Oa Or Minimum:
'
0.00245
126
0
"" No Reporting Reason ENFRUSE - No Flow-Reuse;Recycle; ENV WTHR - No Visitation - Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation - Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC -I
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: DOWNSTREAM DISCHARGE NO.: 001E
po
H
is
's
a
5
t
'
a
z
u0o10
Monthly
Grab
TEDIP-C
2400 clock
deg c
1
2
3
1
R
7
X
ioa>
6S
9
111
I
I:
13
Il
IS
1!
17
IN
19
24
21
22
23
24
25
26
27
29
29
lu
31
.M-11,1, Limit
�Inrhl+ A+enlac:
6.5
Daih NI-imum:
6.5
Dailr SDnimum:
6.5
**** No Reporting Reason: ENFRUSE = No Flow-ReuselRecycle; ENVWTHR = No Visitation — Adverse Weather; NOFLOW = No Flow; HOLIDAY — No Visitation — Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC -I ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 002 NO DISCHARGE*: NO
oa
B
t=
x
O
_E
O
o`
C
a
_
i
56050
Hue 10
0040H
5on6n
73739
5 X week
5 X week
Weekly
5 X week
5 X week
Calculated
Recorder
Grab
Grab
Calculated
FLOW
TEMP-C
pH
CHLORINE
CL DHRTN
24on click
H.
2400 dock
Wr
l,B;N
mgd
deg
su
ugA
minutes
I
N
183.6
I8.7
p
=
600
98
Y
1836
17.6
7.5
0
3
N
183.6
17.1
0
J
N
1836
17.3
p
5
N
183.6
16.7
0
6
N
151 24
19.7
0
7
600
a 8
Y
92 88
22, 2
74
0
s
600
9.2
Y
92.88
20.6
0
9
N
92.88
22.1
0
to
N
92.88
21.4
0
I I
N
92.88
13 1
0
12
N
92.88
13
0
Is
N
92.88
NJ 1
0
14
600
9 5
Y
92.98
13.3
7.4
0
15
N
92.88
L3.4
0
15
600
9.2
Y
92.88
L3.3
0
17
N
92.98
12.5
0
16
N
9288
12.2
0
19
N
92.8
I L.7
0
-
N
60.33
10-6
0
21
N
0
0
0
22
N
0
0
0
21
600
IL5
Y
0
0
0
2,4
N
0
0
0
25
1
N
0
0
0
26
N
0
a
0
21
N
0
0
0
28
0600
10 ?
Y
0
0
0
29
N
0
0
0
39
N
0
0
0
31
IN
1
0
0
0
&J-1hh A --,,a Limit:
JJ.J
hmamn A,.r.p.
75.394839
10.309677
0
Daft+ hfaximum:
'
183.6
22.2
7.5
p
D+ib htinl-
0 10
17.4
0
**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; F.NVWTHR - No Visitation - Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation - Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC- l ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: LO
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: ]003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 004 NO DISCHARGE*: YES
m=@
E
E
—
•
E
a
`
O
p_
P
p
y
u
p
u
x
Z
5[II15Y
01942
ale*_S
Once per discharge
Once per dtschar a
Once per discharge
Instanlwn us
Instanlaneaus
Grab
FLOW
COPPER
IRON
24HO dock
Hn
2*01 dock
K.
VAIN
mgd
rng'1
mg%I
3
a
5
6
7
H
7
In
tl
Q
13
IA
15
16
17
IA
19
-II
21
22
13
24
25
26
27
28
29
311
31
At-nrht, A—& Limit:
r
1
\tonthtr A—V:
13afk kl-Imam:
o.u, %1i.(—:
**** No Reporting Reason: ENFRUSE = No Flow-RcuselRecycle; ENVWTHR=No Visitation — Adverse Weather; NOFLOW — No Flow; HOLIDAY = No Visitation— Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC
GRADE: PC-1
eDMR PERIOD: 01-2020 (January 2020)
ORC: Matthew Holcomb Fields ORC CERT NUMBER: 1003106
ORC HAS CHANGED: No
VERSION: 1.0
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 005 NO DISCHARGE*: YES
E
E
�
'R
a
`y
N
u
O
X
s68s6
Cos"
01002
COMER
0663o
01117
Monthly
Monthly
Quarterly
Quarterly
Quanerly
Quarterly
Instantaneous
Grab
Grab
Grab
Grab
Grab
FLOW
Tss-Coot
M TOTAL
MERCURY-0—
NO2&NO3
S.-TOTAL
2400 elnek
H.
2400 e1.&
H.
YMIN
mgd
rngvll
µgel
nm
w I
ugli
1
2
3
A
S
a
r
8
9
10
11
12
13
1e
IS
16
Or
Ili
19
20
21
22
23
21
25
26
21
20
29
30
31
Munrhh AsereA� Limn:
30
61..thb A,en=r.
D.Hr M..imum:
Deity Minimum:
**** No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENV WTHR = No Visitation - Adverse Weather; NOFLOW - No Flow; HOLIDAY - No Visitation - Holiday

NPDES PERMIT NO.: NCO000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED: No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: YES
A
E
t=
-
tJ
$
v
E
F
-
50010
00010
00400
co510
01002
01007
61022
71870
01027
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Estimate
Grab
Grab
Grab
Grab
Grab
Gab
Grab
Grab
FLOW
TEMP-C
pH
TNS - Cone
As -TOTAL
BARIUM
6oRl7N
11HOM1nE
CAUMINNI
2400c1.ek
Hrs
140*.I.ek
It.
Y7H/N
mgd
&g a
su
mg1
ug11
mgA
ugll
mgA
ugA
3
J
5
6
7
N
9
10
14
12
13
14
IS
16
17
is
19
20
21
22
23
24
25
26
27
28
29
311
31
Mlonthh AiemAe Limir:
311
montnn A .... V:
D.Ils M.elmum-
o.ib) Minimum:
**** No Reporting Reason: ENFRUSE = No Flaw-Reuse/Recycle; ENVWTHR - No Visitation - Adverse Weather; NOFLOW -No Flow; HOLIDAY = No Visitation - Holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1 PERMIT STATUS: Active
FACILITY NAME: Asheville Steam Electric Power PlantCLASS: PC-1 COUNTY: Buncombe
OWNER NAME: Duke Energy Progress LLC
GRADE: PC-1
eDMR PERIOD: 01-2020 (January 2020)
ORC: Matthew Holcomb Fields ORC CERT NUMBER: 1003106
ORC HAS CHANGED: No
VERSION: 1.0
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: YES (Continue)
E
!+
E
7
Fv
a
In
t-
o
3i
r7
K
z
00960
C0034
ON96
01042
009i1
00990
01051
COMER
01067
00630
005M
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Monthly
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Crab
Grab
Grab
Grab
CHLORIDE
TOT CR
CNDUCTW
COPPER
F-TOTAL
TOTHARD
LEAD
MERCURY-
NICKEL
N0=&NO3
I 01L-GRSE
241Ho c1°ck
11s
2400 clock
H.
YIBlN
-91
ugA
umhoslcm
up/l
m94
mpJl
U-0
n
-Vl
mgn
mgll
2
3
A
3
r,
7
a
7
In
I]
I1
IJ
15
16
17
1h
19
20
21
22
21
24
2i
26
27
28
29
30
31
1ltoemlr A -mg, Llmk:
230
29
is
M.otkh A—p:
Da1W hlscimvm:
➢rile Minimum:
****No Reporting Reason: ENFRUSE = No Flow-Reuse/Recycle; ENVWTHR=No Visitation —Adverse Weather; NOFLOW=No Flow; HOLIDAY=NoVisitation— holiday

NPDES PERMIT NO.: NC0000396 PERMIT VERSION: 3.1
FACILITY NAME: Asheville Steam Electric Power P1antCLASS: PC-1
OWNER NAME: Duke Energy Progress LLC ORC: Matthew Holcomb Fields
GRADE: PC-1 ORC HAS CHANGED; No
eDMR PERIOD: 01-2020 (January 2020) VERSION: 1.0
PERMIT STATUS: Active
COUNTY: Buncombe
ORC CERT NUMBER: 1003106
STATUS: Submitted
SAMPLING LOCATION: EFFLUENT DISCHARGE NO.: 101 NO DISCHARGE*: YES (Continue)
o'
E
E
E
~
E
i.
H
-
C
O
"
o
O
U
O
M
z
01147
7u295
009*.5
01959
a1091
Monthly
Monthly
Monthly
Monthly
Monthly
Grab
Grab
Grab
Grab
Grab
Sr TOTAL
RESMiss
SULFATE
THALLIUM
ZINC
24011 .A
Fin
SJaoclock
Hn
V!&N
ugl]
mgA
myl
ug4
uPA
1
2
S
*
5
6
T
N
9
10
11
12
13
1*
15
16
17
18
19
20
21
22
23
24
25
26
27
20
29
30
31
Monthly A,o ge Limit:
5
225.T
Monthly A. KT t
D>.ib NI-i.—
Daik htlntmvm:
****No Reporting Reason ENFRUSE — No Flow-ReuselRecycle; ENV WTHR = No Visitation —Adverse Weather; NOFLOW = No Flow; HOLIDAY = No Visitation —Holiday

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
February 05, 2020
Mr. Matthew Fields
Duke Energy Progress, Inc.
RE: Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
Dear Mr. Fields:
Enclosed are the analytical results for sample(s) received by the laboratory on January 29, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
7��
Lorri Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Mariea Keezel, Duke Energy
Program Manager, Duke Energy
Ms. Teresa Williams, Duke Energy Progress, Inc.
Mr. Robert Wylie, Duke Energy Progress, Inc.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
SAMPLE ANALYTE COUNT
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92462775001 FIELD BLANK EPA 1631 E
RDT
1
PASI-A
92462775002 OUTFALL 001 2020/01/28 1010 N EPA 1664B
HH
1
PASI-C
EPA 200.7 Rev 4.4 1994
DS
11
PASI-A
EPA 1631 E
RDT
1
PASI-A
SM 254OC-2011
CJL
1
PASI-A
SM 254OD-2011
MJP
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
SM 4500-CI-E-2011
DMN
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
Sample: FIELD BLANK Lab ID: 92462775001 Collected: 01/28/20 10:10 Received: 01/29/20 14:40 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E
Mercury 0.860 ng/L 0.50 1 01/30/2013:44 01/31/2014:12 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/05/2020 03:01 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 18

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
ANALYTICAL RESULTS
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
Sample: OUTFALL Lab ID: 92462775002 Collected: 01/28/20 10:10 Received: 01/29/20 14:40 Matrix: Water
001 _2020/01 /28_1010_N
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM, Oil and Grease
Oil and Grease
200.7 MET ICP
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Zinc
1631E Mercury,Low Level
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
2540D Total Suspended Solids
Total Suspended Solids
300.0 IC Anions 28 Days
Bromide
Fluoride
4500 Chloride
Chloride
Date: 02/05/2020 03:01 PM
Analytical Method: EPA 1664B
ND mg/L
4.8
1
01/31/2016:05
Analytical Method: EPA 200.7 Rev 4.4 1994
Preparation
Method: EPA 200.7 Rev 4.4 1994
ND ug/L
10.0
1
01/31/20 01:09
02/02/20 23:59
7440-38-2
ND ug/L
1.0
1
01/31/20 01:09
02/02/20 23:59
7440-41-7
ND ug/L
1.0
1
01/31/20 01:09
02/02/20 23:59
7440-43-9
ND ug/L
5.0
1
01/31/20 01:09
02/02/20 23:59
7440-47-3
ND ug/L
5.0
1
01/31/20 01:09
02/02/20 23:59
7440-50-8
ND ug/L
5.0
1
01/31/20 01:09
02/02/20 23:59
7439-92-1
16.9 ug/L
5.0
1
01/31/20 01:09
02/02/20 23:59
7440-02-0
ND ug/L
10.0
1
01/31/20 01:09
02/02/20 23:59
7782-49-2
ND ug/L
5.0
1
01/31/20 01:09
02/02/20 23:59
7440-22-4
117000 ug/L
662
1
01/31/20 01:09
02/02/20 23:59
75.8 ug/L
10.0
1
01/31/20 01:09
02/02/20 23:59
7440-66-6
Analytical Method: EPA 1631 E Preparation
Method: EPA 1631 E
3.06 ng/L
0.50
1
01/30/2013:44
01/31/2014:57
7439-97-6
Analytical Method: SM 2540C-2011
247 mg/L
25.0
1
02/04/2015:08
Analytical Method: SM 254OD-2011
3.5 mg/L
2.5
1
02/04/20 06:00
Analytical Method: EPA 300.0 Rev 2.1 1993
0.24 mg/L
0.10
1
01/30/20 03:06
24959-67-9
ND mg/L
0.10
1
01/30/20 03:06
16984-48-8 M1
Analytical Method: SM 4500-CI-E-2011
42.2 mg/L
2.0
2
02/03/2013:59
16887-00-6 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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aceAnalytical
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205 East Meadow Road - Suite A
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[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522594
Analysis Method:
EPA 1664B
QC Batch Method: EPA 1664B
Analysis Description:
1664 HEM, Oil and Grease
Associated Lab Samples: 92462775002
METHOD BLANK: 2795051
Matrix: Water
Associated Lab Samples: 92462775002
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Oil and Grease
mg/L
ND 5.0
01/31/20 16:01
LABORATORY CONTROL SAMPLE: 2795052
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Oil and Grease
mg/L
40 38.2
96 78-114
MATRIX SPIKE SAMPLE: 2795053
2628413001 Spike
MS MS % Rec
Parameter
Units
Result Cone.
Result % Rec Limits Qualifiers
Oil and Grease
mg/L
ND 38.5
34.9 90 78-114
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522307
Analysis Method: EPA 1631 E
QC Batch Method: EPA 1631 E
Analysis Description: 1631E Mercury,Low Level
Associated Lab Samples: 92462775001, 92462775002
METHOD BLANK: 2793545
Matrix: Water
Associated Lab Samples: 92462775001, 92462775002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
02/03/2011:56
METHOD BLANK: 2793546
Matrix: Water
Associated Lab Samples: 92462775001, 92462775002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
02/03/2012:04
METHOD BLANK: 2793547
Matrix: Water
Associated Lab Samples: 92462775001, 92462775002
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Mercury ng/L
ND 0.50
02/03/2012:12
LABORATORY CONTROL SAMPLE: 2793548
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Mercury ng/L
5 5.56
111 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2793549 2793550
MS MSD
92462775002
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury ng/L 3.06
25 25 28.7
29.3 103 105 71-125 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 7 of 18

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522437 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92462775002
METHOD BLANK: 2794381
Associated Lab Samples: 92462775002
Parameter
Arsenic
Beryllium
Cadmium
Chromium
Copper
Hardness, Total(SM 2340B)
Lead
Nickel
Selenium
Silver
Zinc
Matrix: Water
Units
Blank
Result
Reporting
Limit
Analyzed
ug/L
ND
10.0
02/02/20 23:02
ug/L
ND
1.0
02/02/20 23:02
ug/L
ND
1.0
02/02/20 23:02
ug/L
ND
5.0
02/02/20 23:02
ug/L
ND
5.0
02/02/20 23:02
ug/L
ND
662
02/02/20 23:02
ug/L
ND
5.0
02/02/20 23:02
ug/L
ND
5.0
02/02/20 23:02
ug/L
ND
10.0
02/02/20 23:02
ug/L
ND
5.0
02/02/20 23:02
ug/L
ND
10.0
02/02/20 23:02
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2794382
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits
Arsenic
ug/L
500
482
96
85-115
Beryllium
ug/L
500
485
97
85-115
Cadmium
ug/L
500
483
97
85-115
Chromium
ug/L
500
467
93
85-115
Copper
ug/L
500
488
98
85-115
Hardness, Total(SM 2340B)
ug/L
33100
32800
99
85-115
Lead
ug/L
500
505
101
85-115
Nickel
ug/L
500
490
98
85-115
Selenium
ug/L
500
491
98
85-115
Silver
ug/L
250
240
96
85-115
Zinc
ug/L
500
488
98
85-115
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2794383
2794384
MS
MSD
92461879015
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
515
511
103
102
70-130
1
Beryllium
ug/L
ND
500
500
487
476
97
95
70-130
2
Cadmium
ug/L
ND
500
500
512
503
102
101
70-130
2
Chromium
ug/L
ND
500
500
455
442
91
88
70-130
3
Copper
ug/L
6.3
500
500
523
520
103
103
70-130
1
Hardness, Total(SM 2340B)
ug/L
174000
33100
33100
1740000
1760000
-10
60
70-130
1
0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2794383
2794384
MS
MSD
92461879015
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Lead
ug/L
10.2
500
500
491
475
96
93
70-130
3
Nickel
ug/L
45.2
500
500
517
502
94
91
70-130
3
Selenium
ug/L
ND
500
500
528
523
106
105
70-130
1
Silver
ug/L
ND
250
250
256
252
103
101
70-130
2
Zinc
ug/L
86.8
500
500
563
533
95
89
70-130
5
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2794385
2794386
MS
MSD
92462775002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
526
534
105
106
70-130
1
Beryllium
ug/L
ND
500
500
500
506
100
101
70-130
1
Cadmium
ug/L
ND
500
500
520
525
104
105
70-130
1
Chromium
ug/L
ND
500
500
480
488
96
98
70-130
2
Copper
ug/L
ND
500
500
522
521
104
104
70-130
0
Hardness, Total(SM 2340B)
ug/L
117000
33100
33100
149000
156000
96
117
70-130
4
Lead
ug/L
ND
500
500
521
530
104
106
70-130
2
Nickel
ug/L
16.9
500
500
522
531
101
103
70-130
2
Selenium
ug/L
ND
500
500
555
561
111
112
70-130
1
Silver
ug/L
ND
250
250
254
257
102
103
70-130
1
Zinc
ug/L
75.8
500
500
579
600
101
105
70-130
4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522965
Analysis Method:
SM 2540C-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Associated Lab Samples: 92462775002
METHOD BLANK: 2796737
Matrix:
Water
Associated Lab Samples: 92462775002
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Total Dissolved Solids
mg/L
ND
25.0
02/04/20 15:07
LABORATORY CONTROL SAMPLE: 2796738
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Total Dissolved Solids
mg/L
250
250
100
90-110
SAMPLE DUPLICATE: 2796739
92461517155
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
109
103
6
SAMPLE DUPLICATE: 2796740
92462771002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
Total Dissolved Solids
mg/L
2150
2300
7
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522966
Analysis Method:
SM 2540D-2011
QC Batch Method: SM 254OD-2011
Analysis Description:
2540D Total Suspended Solids
Associated Lab Samples: 92462775002
METHOD BLANK: 2796741
Matrix:
Water
Associated Lab Samples: 92462775002
Blank
Reporting
Parameter
Units
Result
Limit Analyzed Qualifiers
Total Suspended Solids
mg/L
ND
2.5 02/04/20 05:54
LABORATORY CONTROL SAMPLE: 2796742
Spike
LCS LCS % Rec
Parameter
Units
Cone.
Result % Rec Limits Qualifiers
Total Suspended Solids
mg/L
250
260 104 90-110
SAMPLE DUPLICATE: 2796745
92462657001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Suspended Solids
mg/L
1680
3120 60 D6
SAMPLE DUPLICATE: 2796746
92462659001
Dup
Parameter
Units
Result
Result RPD Qualifiers
Total Suspended Solids
mg/L
2630
2230 16
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522187 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92462775002
METHOD BLANK: 2793056 Matrix: Water
Associated Lab Samples: 92462775002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Bromide mg/L ND 0.10 01/30/20 02:38
Fluoride mg/L ND 0.10 01/30/20 02:38
LABORATORY CONTROL SAMPLE: 2793057
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Bromide mg/L 2.5 2.4 98 90-110
Fluoride mg/L 2.5 2.4 98 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2793058
2793059
MS
MSD
92462775002 Spike
Spike
MS
MSD MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L 0.24 2.5
2.5
2.7
2.8 100
104
90-110 4
Fluoride mg/L ND 2.5
2.5
2.9
3.1 115
120
90-110 4 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2793060
2793061
MS
MSD
92461517136 Spike
Spike
MS
MSD MS
MSD
% Rec
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec
Limits RPD Qual
Bromide mg/L ND 2.5
2.5
2.6
2.6 100
101
90-110 1
Fluoride mg/L 0.24 2.5
2.5
3.2
3.2 119
120
90-110 0 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/05/2020 03:01 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 18

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
QC Batch: 522824 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Associated Lab Samples: 92462775002
METHOD BLANK: 2796062 Matrix: Water
Associated Lab Samples: 92462775002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chloride mg/L ND 1.0 02/03/2013:51
LABORATORY CONTROL SAMPLE: 2796063
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Chloride mg/L 20 20.4 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2796064 2796065
MS MSD
92462775002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 42.2 10 10 44.9 60.2 27 180 90-110 29 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Page 13 of 18

aceAnalytical
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Pace Analytical Services, LLC
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALIFIERS
Project: OUTFALL 001 1/28/20
Pace Project No.: 92462775
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
D6 The precision between the sample and sample duplicate exceeded laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
OUTFALL 001 1/28/20
92462775
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92462775002
OUTFALL
EPA 1664B
522594
001 _2020/01 /28_1010_N
92462775002
OUTFALL
EPA 200.7 Rev 4.4 1994
522437
EPA 200.7 Rev 4.4 1994
522460
001_2020/01/28_1010_N
92462775001
FIELD BLANK
EPA 1631 E
522307
EPA 1631 E
522539
92462775002
OUTFALL
EPA 1631E
522307
EPA 1631E
522539
001 _2020/01 /28_1010_N
92462775002
OUTFALL
SM 254OC-2011
522965
001 _2020/01 /28_1010_N
92462775002
OUTFALL
SM 254OD-2011
522966
001 _2020/01 /28_1010_N
92462775002
OUTFALL
EPA 300.0 Rev 2.1 1993
522187
001 _2020/01 /28_1010_N
92462775002
OUTFALL
SM 4500-CI-E-2011
522824
001 _2020/01 /28_1010_N
REPORT OF LABORATORY ANALYSIS
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Document Name: Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR) Page 1 of 2
8CBAnalytICc?I Document No.: Issuing Authority:
f-CAR-CS-433-Rev.06 Pace Carolinas Quality Office
Laboratory receiving sa ples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[] Mechanicsville❑
WQ#'92462775
Courier:
❑ Commercial
Custody Seal Present?
Client Name: `
pW �C/1GT ^�c s Project #: I `
[]Fed Ex []UPS ❑btPs �l J []Client
ff�rpnce ❑other: 92462775
/Yes ❑No Seals Intact? (yes ❑No
Packing Material. ❑Bubble Wrap PLbbte Bags ❑None ❑ other
Thermometer T) Type of Ice: owet ❑Blue
IR Gun ID:
Cooler Temp (°C): Correction Factor: Add/Subtract CC) D'
Cooler Temp Corrected (°C):
Date/Initials Person Examining Contents:.) o
I JZ9121)
Biological Tissue Frozen.
❑Yes ❑No,,aN/A
❑None
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil (a NIA, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
nYes nNo including Hawaii and Puerto Rico)? ❑Yes ❑No
Chain of Custody Present?
Samples Arrived within Hold Time?
short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
Heads pace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trio Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
Yes
❑No
❑N/A
1.
Yes
❑No
[-]N/A
2.
❑Yes
❑No
❑N/A
3.
❑Yes
,E�'No
[]N/A
4.
[I]Yes
❑No
❑N/A
I S.
Yes
No
❑No
❑NIA
6.
Yes
❑N/A
Yes
ON-
❑N/A
7.
[]Yes
,OfVo
❑N/A
S.
aes
❑No
❑N/A
9.
W7
❑Yes
❑No
NIA
10.
❑Yes
❑No
Q1
N/A
11.
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Field Data Required? ❑Yes '.
Date/Time:
Project Manager SCURF Review: Date: i t�� v
Project Manager SRF Review:
Date:
Page 16 of 18

Document Name:
Document Revised: February 7, 2D18
2cehialXical
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # Wa# ■ 92462775
PM: UP Due Date: 02/05/20
CLIENT: 95—PROGRESS
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot k
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the !North Carolina DEHNR Certification Orrice (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 17 of 18

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Page 18 of 18