WQ0032016_Monitoring - 03-2020_20200430 (2)

GW-59A COMPLIANCE REPORT FORM Permit # WO, 00"3201 `P
(.Submit one each monitoring period with GW-59 forms.)
1
Enter date monitoring results were due. ( ) Will this monitoring report (GW-59 and GW59A)
YES
O
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
p
IF the answer to question I or 2 is "YES ; list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
O
identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Ofce for guidance.
4
Are. any monitored constituents equal to or above the established standards? -
YES
O
If the answer to question 4 is "NO' skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentrations)
exceeding standards in the space provided below.
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is "NO' skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
6
Are the monitoring wells listed in section 5located at or beyond the review boundary?
YES
NO
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO" monitoring wells maybe improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
NO
groundwater quality problem?
If the answer to question 7 is "YES", describethose actions in the space provided below.
If the answer to question 7 is "NO" contact the Regional Office within 90 days: an evaluation may be
required to determine the impact the waste disposal system is having at the review and compliance
boundaries surrounding this facility. Failure to do so may subject the permittee to a Notice of Violation,
fines, and/or penalties.
g
The person completing this portion (GW-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
MIMI" His
Signature of Permitee (or Authorized Agent) Date
GW-59A 12/8/2003

• rnr�rt �rvu
-R QUALITY MONITORING:
REPORT FORM
Facility Name: Rose Hill Plantation Development, LLC
Permit Name (if different): Rose Hill Plantation Development, LLC
Facility Address: 3041 New Leicester Highway
Leicester s" NC 28748 County Buncombe
act Person: Bob Barr Telephone#: [phone]
Location/Site Name: Well #1(MW A on GW-1 b) No. of wells to be sampled: 3
!RMIT Number: Expiration Date: 2/Zt5/2U22
n-Discharge UIC
IDES Other W00032016
'PE OF PERMITTED OPERATION BEING MONITORED
❑ Lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump N Other: Surface Irrigation
WELL
WELL ID NUMBER (from Permit): Well #1 Upgradient
Well Depth: 69 ft.
Depth to Water Level: 31.75 ft. below measuring point
Measuring Point is 2.5 ft. above land surface
Volume of water pumped/bailed before sampling:
Samples for metals were collected unfiltered: ❑YES
Date sample collected: 3/30/20
Well Diameter: 2" in.
Screened Interval: 49 ft. to 69 ft.
Relative M.P. Elevation: k.
gallons
❑ NO and field acidified: ❑ YES ❑ NO
FIELD ANALYSES:
pH 6.7 units Temp. 17.9 °C
Spec. Cond. µMhos
Odor None
Appearance Clear
WAS
DRY at
time of
sampling,
check
here: ❑
LABORATORY INFORMATION
Date sample analyzed: 3/30/20 to 4/10/20
Laboratory Name: Pace Analytical
Certification No. 40
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I
Nitrite (NO2) as N
mg/I
Pb - Lead mg/I
Coliform: MF Fecal <1.0 /100ml
Nitrate (NO3) as N
<0.040 mg"
Zn -Zinc mg/I
Coliform: MF Total /100ml
Phosphorus: Total as P
0.067 mg/I
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Other (Specify Compounds and Concentration Units):
Dissolved Solids: Total 59.0 mg/I
Al - Aluminum
mg/I
pH (when analyzed) units -
Be - Barium
mg/I
TOC <1.0 mg/I
Ca -:Calcium
mg/I
Chloride <1.0 mg/I
Cd- Cadmium
mg/I
Arsenic mg/I
Chromium: Total
mg/I
Grease and Oils mg/I
Cu - Copper
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Phenol mg/I
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate mg/I
Hg - Mercury
mg/I
Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance µMhos
K- Potassium
mg/I
VOC method #
Total Ammonia <0.10 mg/I
Mg - Magnesium
mg/1
,method #
(Ammonia Nitrogen; NHsas N; Ammonia Nitrogen, Total)
Mn - Manganese
mg/I
method #
TKN as N mg/I
Ni - Nickel
mg/I
, method #
ror Kemearation systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Bob Barr, Authorized Agent VV-V---/ 4-30-U
Pemtittee (or Authorized Agent) Name and Title - Please print or type Signature of Permittee (or Authorized Apart) (Date)
GW-59 Rev. 112007

?R QUALITY MONITORING:
REPORT FORM
Name: Rose Hill Plantation Development, LLC
Name (if different): Rose Hill Plantation Development, LLC
Address: 3041 New Leicester Highway
ster NC 28748 County Buncombe
act Person: Bob Barr Telephone#: [phone]
Location/Site Name: Well #2(MW B on GW-1 b) No. of wells to be sampled: 3
Number: Expiration Date: z/Ztf/Z(
harge UIC
Other W00032016
'PE OF PERMITTED OPERATION BEING MONITORED
❑ lagoon ❑ Remediation: Infiltration Gallery
❑ Spray Field ❑ Remediation:
❑ Rotary Distributor ❑ Land Application of Sludge
❑ Water Source Heat Pump © Other: Surface Irrigation
LID NUMBER (from Permit): Well #2downgradient Date sample collected: 3-30-20
FIELD ANALYSES:
WAS
Depth: 30 ft.
Well Diameter: 2" in.
pH 5.6 units Temp. 13.5 °C
DRY at
h to Water Level: 7.81 ft. below measuring point
Screened Interval: 10 ft. to 30 ft.
Spec. Cond. µMhos
time of
curing Point is 2.5 ft. above land surface
Relative M.P. Elevation: ft.
Odor None
sampling,
check
ne of water pumped/bailed before sampling:
gallons -
Appearance Cloudy
here: El
for metals were collected unfiltered: DYES
❑ NO and field acidified ❑ YFC ❑ NO
sample analyzed: 3/30/20 to 4/10/20
AMETERS NOTE: Values should reflect dissolv
COD mg/I
Coliform: ME Fecal 2.0 /100ml
Coliform: ME Total /100ml
(Note: Use MPN method for highly turbid samples)
Dissolved Solids: Total
46.0 ni
pH (when analyzed)
units
TOC
<1.0 mg/I
Chloride
3.0 mg/I
Arsenic
mg/I
Grease and Oils
mg/I
Phenol
mg/I
Sulfate
mg/I
Specific Conductance
µMhos
Total Ammonia
<0.10 mg/I
(Ammonia Nitrogen; N119as N; Ammonia Nitrogen, Total) -
TKN as N
Laboratory Name: Pace Analytical
Certification No. 40
colloidal concentrations.
Nitrite (NO2) as N
mg/I
Pb - Lead mg/I
Nitrate (NO3) as N
1.1 mg/I
Zn - Zinc mg/I
Phosphorus: Total as P
<0.050 mgn
Orthophosphate
mg/I
Other (Specify Compounds and Concentration Units):
AI - Aluminum
mg/I
Be - Barium
mg/I
Ca - Calcium
mg/I
Cd - Cadmium
mg/I
Chromium: Total
mg/I
Cu - Copper
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Hg - Mercury
mg/I
Report Attached? ❑ Yes (1) ❑ No (0)
K - Potassium
mg/I
VOC , method #
Mg - Magnesium
mg/I
method #
Mn - Manganese
mg/I
method #
Ni - Nickel
mg/I
, method #
ror Remearanon systems unry (wttacn Lan Reports): mtluent Total VOOs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Bob Barr, Authorized Agent v"/,4i,--- 4-30-?,O
Permutes (or Authorized Agent) Name and Title - Please print or type Signature of Pennittee (or Authorized Agent) (Date)
GW-59 Rev. 1/2007

LL ID NUMBER (from Permit): Well #3-New Down
Date sample collected:
3/30/20
FIELD ANALYSES:
WAS
I Depth: 14 ft.
Well Diameter:
2" in.
pH 6.6 units Temp.
12.3 °C
DRY at
th to Water Level: 3.91 ft. below measuring point
Screened Interval:
4 ft. to 14 ft.
Spec. Cond.
µMhos
time of
Isurin Point is 0
g ft. above land surface
Relative M.P. Elevation:
ft.
Odor none
sampling,
me of water pumped/bailed before sampling:
gallons
Appearance Cloudy
check
here:
t les for metals were collected unfiltered: DYES
❑ NO and field acidified: ❑
YES ❑ NO
❑
iORATORY INFORMATION
sample analyzed: 3/30/20 to 4/10/20
Laboratory Name: Pace Analytical
Certification No.
40
tAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD mg/I
Nitrite (NO,) as N
mg/I
Pb - Lead
mg/1
Coliform: MF Fecal <1.0 /100ml
Nitrate (NO3) as N
<0.040 TO
Zn - Zinc
mg/I
Coliform: MF Total 1100ml
Phosphorus: Total as P
0.56 mg/1
(Note: Use MPN method for highly turbid samples)
Orthophosphate
mg/I
Other (Specify Compounds and Concentration Units):
Dissolved Solids: Total 91.0 mg/I
Al - Aluminum
mg/I
pH (when analyzed) units
Ba - Barium
mg/I
TOC <1.0 mg/I
Ca - Calcium
mg/I
Chloride 3.1 mg/I
Cd - Cadmium
mg/I
Arsenic mg/I
Chromium: Total
mg/1
Grease and Oils
mg/I
Cu - Copper
mg/I
ORGANICS: (by GC, GC/MS, HPLC)
Phenol
mg/I
Fe - Iron
mg/I
(Specify test and method #. ATTACH LAB REPORT.)
Sulfate
mg/I
Hg - Mercury
mg/I
Report Attached? ❑ Yes (1) ❑ No (0)
Specific Conductance
µMhos
K- Potassium
mg/I
VOC , method #
Total Ammonia
<0.10 mg/I
Mg - Magnesium
mg/I
#
(Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total)
Mn - Manganese
,method
mg/I
, method #
TKN as N
mg/I
Ni - Nickel
mg/I
, method #
Bob Barr, Authorized Agent
Pennittee (or Authorized Agent) Name and Title- Please print or type
GW-59 Rev. 1/2007

- - aceArralyticat ®-- - -- -
April 10, 2020
Mr. Robert Barr
RPB Systems Inc.
P.O. Box 1325
Asheville, NC 28802
RE: Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
Dear Mr. Barr:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville.NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 30, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Chris Derouen
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, I.I.C.
Page 1 of 18

Pace Analytical Services, LLC
2225 28ide 0
r.
Asheville,e, NC NC 28804
[phone]
I
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification M 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification M 84
VirginiaNELAP Certification #: 460221
2225 Riverside Drive, Asheville, NC 28804 North Carolina Wastewater Certification M 40
Florida/NELAP Certification #: E87648 South Carolina Certification #: 99030001
Massachusetts Certification #i M-NC030 UrginiaNELAP Certification #: 460222
North Carolina Drinkinq Water Certification M 37712
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, -I-C.
Page 2 of 18

I
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
Lab ID Sample ID
92471698001 MW-1
92471598002 MW-2
92471598003 MW-3
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
SAMPLE ANALYTE COUNT
Method
SM 254OC-2011
SM 9222D-2006
EPA 350.1 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
SM 4500-CI-E-2011
SM 531OB-2011
SM 254OC-2011
SM 9222D-2006
EPA 350.1 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
SM 4500-CI-E-2011
SM 531OB-2011
SM 2540C-2011
SM 9222D-2006
EPA 350.1 Rev 2.0 1993
EPA 353.2 Rev 2.0 1993
EPA 365.1 Rev 2.0 1993
SM 4500-CI-E-2011
SM 531OB-2011
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC-28804 -
[phone]
Analysts
Analytes
Reported
Laboratory
JNS
1
PASI-A
ECH
1
PASI-A
KDF1
1
PASI-A
KDF1
1
PASI-A
MDW
1
PASI-A
KDF1
1
PASI-A
ECH
1
PASI-A
JNS
1
PASI-A
ECH
1
PASI-A
KDF1
1
PASI-A
KDFl
1
PASI-A
MDW
1
PASI-A
KDF1
1
PASI-A
ECH
1
PASI-A
JNS
1
PASI-A
ECH
1
PASI-A
KDF1
1
PASI-A
KDF1
1
PASI-A
MDW
1
PASI-A
KDF1
1
PASI-A
ECH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 18

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC-28804—.
[phone]
ANALYTICAL RESULTS
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
Sample: MW-1
Lab ID: 92471698001 Collected: 03/30/20 14:10 Received: 03/30/2015:30 Matrix: Water
Parameters-
Results Units Report Limit
DF Prepared
Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
-
Pace Analytical Services - Charlotte
Collected By
Mark
1
03/30/20 14:10
Swann
Collected Date
3/30120
1
03/30/20 14:10
Collected Time
14:10
1
03/30/20 14:10
pH
_ -.6.7 _ Std._Units
1
03/3012014:10 .
Temperature
17.9 deg C
1
03/30/20 14:10
Static Water Level
31.75 feet
1
03/30/20 14:10
Specific Conductance
58 umhos/cm
1
03/30/20 14:10
Turbidity
4.05 NTU
1
03/3012014:10
Odor
No Odor
1
03/30/2014:10
Appearance
Clear
1
03/3012014:10
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2011
Pace Analytical Services - Asheville_
Total Dissolved Solids
59.0 mg/L 25.0
1
04/03/20 09:58
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation
Method: SM 9222D-2006
Pace Analytical Services - Asheville
Fecal Coliforms
- ND CFU/100 mL 1.0
1 03/30/20 17:32
03/31/20 15:36
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
ND mg/L 0.10
1
04/10/20 09:32 7664-41-7
353.2 Nitrogen, NO2IN03 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
NO mg/L 0.040
1
04/01/20 08:13 14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Phosphorus
0.067 mg/L 0.050
1 03/31/20 22:00
04/01/20 22:29 7723-14-0
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
NO mg/L 1.0
1
04106/2015:14 16887-00-6
5310B TOC
Analytical Method: SM 631OB-2011
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L 1.0
1
04/09/20 20:35 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

aceftlytical e
__ wwrvpacelecs.caic-."_ _.
l
ANALYTICAL RESULTS
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-2 Lab ID: 92471598002 Collected: 03/30/20 14:30 Received: 03/30/20 15:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
Monitoring Well Data
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Turbidity
Odor
Appearance
2540C Total Dissolved Solids
Total Dissolved Solids
MBIO 9222D Fecal Coliform AVL
Fecal Coliforms
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
365.1 Phosphorus, Total
Phosphorus
4500 Chloride
Chloride
5310E TOC
Total Organic Carbon
Date: 04/10/2020 04:56 PM
Analytical Method:
Pace Analytical Services - Charlotte
Mark
1
03/30/20 14:30
Swann
3130120
1
03/30/20 14:30
14:30
1
03/30/20 14:30
5.6 Std. Units
1
03/30/20 14:30
13.5 deg C
1
03/30/20 14:30
7.81 feet
1
03/30/20 14:30
32 umhos/cm
1
03/3012014:30
62.13 NTU
1
03/3012014:30
No Odor
1
03/30/20 14:30
Cloudy
1
03/30/20 14:30
Analytical Method: SM 254OC-2011
Pace Analytical Services -Asheville
46.0 mg/L 25.0
1
04/03/20 09:58
Analytical Method: SM 9222D-2006 Preparation
Method:
SM 9222D-2006
Pace Analytical Services - Asheville
2.0 CFU/100 mL 1.0
1
03/30/20 17:32 03/31/20 15:36
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
NO mg/L - 0.10
1
- 04/10/20 09:33 1664-41-7
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
1.1 mg/L 0.040
1
04/01/20 08:14 14797-55-8
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
ND mg/L 0.050
1
03/31/20 22:00 04/01/20 21:33 7723-14-0
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
3.0 mg/L 1.0
1
04/06/2015:15 16887-00-6
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
NO mg/L 1.0
1
04/09/2020:53 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, L-C.
Page 5 of 18

e
aceAnalyiical_
GNII1.IIaCaO AC0111- -
I
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville NC-28804
(828)2547776
Project: RPB ROSE HILL MW S 033020 -
Pace Project No.: 92471598 -
Sample: MW-3 - Lab ID: 92471598003 Collected: 03/30/20 14:50 Received: 03/30/20 15:30 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Collected By
Mark
1
03/30/20 14:50
Swann
Collected Date
3130120
1
03/30/20 14:50
Collected Time
14:50
1
03/30/20 14:50
pH
6.6 Std. Units
1.
03/30/20 14:50
Temperature
12.3 deg C
1
03/30/20 14:50
Static Water Level
3.91 feet
1
03/30/20 14:50
Specific Conductance
98 umhos/cm
1
03/30/20 14:50
Turbidity
9.08 NTU
1
03130/2014:50
Odor
No Odor
1
03/3012014:50
Appearance
Clear
1
03/30/20 14:50
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
91.0 mg/L 25.0
1
04/03/20 09:58
MBIO 9222D Fecal Coliform AVL
Analytical Method: SM 9222D-2006 Preparation
Method:
SM 9222D-2006
Pace Analytical Services -Asheville
Fecal Coliforms
ND CFU/100 mL 1.0
1
03/30/20 17:32 03/31/20 15:36
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services - Asheville
" Nitrogen, Ammonia -
NO mg/L 0.10
1
04/10/20 09:35 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
NO mg/L 0.040
1
04/01/20 08:15 14797-55-8
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
0.56 mg/L 0.050
1
03/31/20 22:00 04/01/20 21:33 7723-14-0
4500Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
3.1 mg/L 1.0
1
04/06/2015:16 16887-00-6
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
ND mg/L 1.0
1
04/09/20 21:45 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 18

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville. NC 28804
QUALITY CONTROL DATA
Project: RPB ROSE HILL MW S 033020
Pace Project No.: 92471598
QC Batch: 534232
Analysis Method:
SM 254OC-2011
QC Batch Method: SM 254OC-2011
Analysis Description:
2540C Total Dissolved Solids
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2851064
Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units
Result Limit
Analyzed. Qualifiers
Total Dissolved Solids mg/L
ND 25.0 04/03120 09:56
LABORATORY CONTROL SAMPLE: 2851065
Spike LCS LCS % Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 250 100 90-110
SAMPLE DUPLICATE: 2851066
92471601001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 2380 2380 0
SAMPLE DUPLICATE: 2851067
92471661002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 320 327 2
Results presentee on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, L-C. Page 7 of 18

— aceAnalyticat
---wvarpedle6s.wm
QUALITY CONTROL DATA
Project: RIPS ROSE HILL MW'S 033020
Pace Project No.: 92471598
Pace Analytical Services, LLC
2225 Riverside Dr.
' Asheville NC-28804
[phone]
QC Batch: 533325 Analysis Method: SM 9222D-2006
QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) -AVL
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2847235 Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Fecal Coliforms - CFU/100 mL NO 1.0 '03131120 15:36
SAMPLE DUPLICATE: 2847236
Parameter
Fecal Coliforms
92471475005
Units Result
CFU/100 mL 116
Dup
Result RPD Qualifiers
124 7
Results presented on this page are In the units indicated by the "Units" column except where an altemate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 18

Pace Analytical services, LLC
• ® 2225 Riverside Dr.
(ClAnaJ Kcal Ashevllle NC 28804— — --
weatpaeele6s.eum __- _. ---:_ [phone]
QUALITY CONTROL DATA
Project: RPB ROSE HILL MW S 033020
- -
Pace Project No.: 92471598
QC Batch: 535236
Analysis Method:
EPA 350.1 Rev 2.0 1993 -
QC Batch Method: EPA 350.1 Rev 2.0 1993
Analysis Description:
350.1 Ammonia -
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2855956
Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Ammonia mg/L
NO 0.10 04/10120 09:04 -
LABORATORY CONTROL SAMPLE: 2855957
_
Spike LCS
LCS % Rec
Parameter Units
Cone Result
% Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
5 5.1
102 90.110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2865958 2855959 -.
MS MSD
92471048001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Quat
Nitrogen, Ammonia mg/L 2.5
5 5 7.5
7.5 100 99 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2855960 2865961
MS MSD
92471475002 Spike - Spike MS MSD MS MSD % Rae
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Ammonia mg/L 16.3 5 5 21.5 21.3 102 99 90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, L-C.
Page 9 of 18

UeAnaIjitjcal__ _.
www.pacelaba.wm
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville NC 28804
[phone] —
Project: RPB ROSE HILL MW S 033020
Pace Project No.: 92471598
QC Batch: 533637
Analysis Method:
EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description:
353.2 Nitrate + Nitrite, Unpres.
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2848447
Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Nitrogen, Nitrate mg/L
ND 0.040 04/01120 08:02
LABORATORY CONTROL SAMPLE: 2848448
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rae Limits Qualifiers
Nitrogen, Nitrate mg/L
1.5 1.5
103 90-110
'MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2848449 2848450
MS MSD
92471518001
Spike Spike MS
MSD MS MSD %Rec
Parameter Units Result
Cone. Cone. Result
Result %Rec %Rec Limits RPD Qua]
Nitrogen, Nitrate mg/L 1.9
1.5 1.5 3.4 3.4 104 101 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2848451 2848452
MS MSD
92471698003 Spike Spike MS MSD MS MSD %Rec
.Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, Nitrate mg/L _ ND 1.5 1.5 1.6 1.6 107 109 90-110 2
Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not: be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 18

® Pace Analytical Services, LLC
�UV/'II/G��URI 2225 Riverside Dr. -
Asheville,-NC__28B04
- altvia.pfiratatissam — — _ _____ -.: _ _
[phone]
QUALITY CONTROL DATA
Project: RPB ROSE HILL MW S 033020
Pace Project No.: 92471598
QC Batch: 533623
Analysis Method:
EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993
Analysis Description:
365.1 Phosphorus, Total
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2848398
Matrix: Water
Associated Lab Samples: 92471598001, 92471598002,
92471598003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Phosphorus - mg/L
ND 0.050 04/01/20 21:15
LABORATORY CONTROL SAMPLE:
2848399
-
Spike
LIDS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Phosphorus
mg/L
2.5
2.5
100
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2848400
2848401
MS
MSD
92471575001
Spike
Spike MS
MSD
MS MSD % Rec
Parameter
Units Result
Conc.
Conc. Result
Result
% Rec % Rec Limits RPD Qual
Phosphorus
mg/L 0.10
2.5
2.5 2.7
2.7
102 102 90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2848402 2848403
MS MSD
92471575002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Phosphorus mg/L 0.14 2.5 2.5 2.7 2.7 102 103 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 18

aceA_
urmpacelebswcem
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
_Asheville NC28804 ----
[phone]
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
QC Batch: 534473
Analysis Method:
SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011
Analysis Description:
4500 Chloride
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2852266
Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chloride - mg/L
NO - 1.0 04/0612014:52
LABORATORY CONTROL SAMPLE: 2852267
-
Spike
LCS
LCS
% Rec
Parameter Units
Cone.
Result
% Rec
Limits Qualifiers
Chloride mg/L
20
20.1
100
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2852268
2852269
MS
MSD
-
92471579002
Spike
Spike MS
MSD
MS MSD % Rec
Parameter Units Result
Cone.
Cone. Result
Result
% Rec % Rec Limits RPD Qual
Chloride mg/L 23.7
10
10 32.8
32.7
90 89 90-110 0 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2852270 2852271
MS MSD
92471485001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec - Limits RPD Qual
Chloride mg/L 21.8 10 10 31.3 31.4 95 96 90-110 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 18

!�g j Pace Analytical Services, LLC
Asheville,
2225 RiversideY�%Iac
_ Asheville NC_28804
04 _...
wwr.paeele6s.cata [phone]
I
QUALITY CONTROL DATA
Project: RPB ROSE HILL MW S 033020
Pace Project No.: 92471598
QC Batch: 535284 Analysis Method:
QC Batch Method: SM 531OB-2011 Analysis Description:
Laboratory:
Associated Lab Samples: 92471598001, 92471598002, 92471598003
METHOD BLANK: 2856092 Matrix: Water
Associated Lab Samples: 92471598001, 92471598002, 92471598003
Blank Reporting
Parameter Units Result Limit Analyzed
Total Organic Carbon - mg/L - NO 1.0 04/0912018:55
SM 531OB-2011
5310B TOC
Pace Analytical Services -Asheville
Qualifiers
LABORATORY CONTROL SAMPLE:
2856093
Spike
LCS
LCS
% Rae
Parameter
Units
Cone.
Result
% Rae
Limits
Qualifiers
Total Organic Carbon
mg/L
25
23.0
92
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2856094
2856095
MS
MSD
92472188012
Spike
Spike
MS
MSD
MS
MSD
% Rae
Parameter
Units Result
Cone.
Cone.
Result
Result
% Rae
% Rae
Limits RPD Qual
Total Organic Carbon
mg/L NO
25
25
23.3
23.3
92
92
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2856096 -
2856097
MS
MSD
92472558004
Spike
Spike
MS
MSD
MS
MSD
% Rae
Parameter
Units Result
Cone.
Cone.
Result
Result
% Rae
% Rae
Limits RPD Qual
Total Organic Carbon
mg/L NO
25
25
23.3
23.1
92
91
90-110 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 18

Pace Analytical services, LLC
2225 Riverside Dr.
.Asheville NC-28864 _.—
www.pecslebs.eem
I
[phone]
QUALIFIERS
Project: RPB ROSE HILL MW'S 033020
Pace Project No.: 92471598
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC -Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit. -
RL- Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias fora -specific analyte in a specific matrix.
S - Surrogate .
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration. _
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate).
MS(D) - Matrix Spike (Duplicate)
DUP- Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitdle by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TIN accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
Mt Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 04/10/2020 04:56 PM without the written consent of Pace Analytical Services, U.C. Page 14 of 16

air I
aceAwlytbl
I
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
-- [phone]
Project:
Pace Project No.:
RPB ROSE HILL WS 033020
92471598
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92471598001
MWA
92471598002
MW-2
92471698003
MW-3
92471598001
111
SM 254OC-2011
534232
92471598002.
MW-2
SM 254OC-2011
534232
92471598003
MW-3
SM 254OC-2011
534232
92471598001
MW-1
SM 9222D-2006
533325
SM 92220-2006
533326
92471598002
MW-2
SM 9222D-2006
533325
SM 9222D-2006
533326
92471598003
MW-3
SM 9222D-2006
533325
SM 9222D-2006
533326
92471598001
1
EPA 350.1 Rev 2.01993
535236
92471598002
MW-2
EPA 350.1 Rev 2.01993
535236
92471598003
MW-3
EPA 350.1 Rev 2.01993
535236
92471598001
MW-1
EPA 353.2 Rev 2.01993
533637
92471598002
MW-2
EPA 353.2 Rev 2.01993
533637
92471598003
MW-3
EPA 353.2 Rev 2.0 1993
533637
92471598001
MW-1
EPA 365.1 Rev 2.0 1993
533623
EPA 365.1 Rev 2.0 1993
533644
92471598002
MW-2
EPA 365.1 Rev 2.0 1993
533623
EPA 365.1 Rev 2.0 1993
533644
92471598003
MW-3
EPA 365.1 Rev 2.0 1993
533623
EPA 365.1 Rev 2.0 1993
533644
92471598001
1
SM 4500-CI-E-2011
534473
92471598002
111
SM 4500-CI-E-2011 -
534473
92471598003
MW-3 -
SM 4500-CI-E-2011
534473
92471598001
MW-1
SM 531 OB-2011
535284
92471598002
MW-2
-SM 531OB-2011
535284 `
---
92471598003
MW-3
SM 531OB-2011
535284
Date: 04/10/2020 04:56 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 18

WQ#=92471598
4€a/yicaf"
's
CHAIN -OF -CUSTODY Analytical Request Document
ChainroiCUstodv As a.IEGAl6DLDv�Nf-ComPIete all relevant tietd5
$itlin&Informailon:ta
r64� ,,-1PzA�ce
sY ;:
9$7 W '` c u
Preservative Type'.'
C;optainer
'toject Name/NUmbee/r. state: Cobrty/City: time Zone Collected:
.d aenJc IJ,CG ^A/, -j WC .6'G.ve C 1.PT[ IMTI ICT ( i'er
SitetFFacility 10�(#: Compliance Monitoring?
R Rp1¢ J / )A/'A [ 1 ple-s [ ]No
'y[printP 1PUrdWeOrder#: DW PWSM#:
I'Jf.",W . Cwcte#: DW location Code:
[ I Retpm: [ I Sarne Day. [ I Ne"ay I I ves (: 1
_ [ 12 Day [ 13 Day I, 14 Day [ 15.Day n.,er
Matrix*` Grata. (. Compo17 site Start) I Composite E#id I -
Conditions / Possible Hazards:

*Check mark top halt of box if pH and/or dechlorination is
verlfied and Within the acceptance range for preservation
samples.
Biceptions: VOA, Coliform, TOC, Oil and Grease, ORO(8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Propect # W a 921471598
PM: Cot out Date:: 04/13/20
CLIENT: 83-HPB
PH Adjustment Log for Preserved sampies
Sample
Type*fpreservativis
pH upon recelpt
Date preservation adjusted.
flmepresersstlon
adjusted
- AmountofPresemative:
added
- Lot#-
Note: Wh"anever there is.a,dkorepancy affecting North Carolina compliance samples, a copy or mis loan will wt to the North Carolina uenrvn txrnDcanon umw pq.
Out of hold, Incormct preservative, cut of temp, incorrect containers. - -
Page 17 of 18

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Pace Analytical Ser0ces, Inc
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