WQ0012980_Application_20200114

For Better Results.
Milorganite
January 8, 2020
Department of Environment Quality
Division of Water Resources
Water Quality Permitting Section
Non -Discharge Permitting Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Subject: Distribution of Class A Residual Solids Permit Renewal
Permit WQ0012980
RECEIVEDINCDEO/10WR
JA N 14 2020
Non -Discharge
Permitting Unit;
Please renew the permit for the distribution of Milorganite® fertilizer. A check for $810 is enclosed to pay the
renewal fee. Permit WQ0012980 expires July 31, 2020.
Milorganite® continues to be an exceptional quality biosolids product registered as a specialty fertilizer with
the North Carolina Department of Agriculture and Consumer Services. From home lawns to golf courses,
fertilizing turf remains the primary market for Milorganite® fertilizer. Milorganite® fertilizer is not labelled or
marketed for agricultural use.
The Milwaukee Metropolitan Sewerage District intends to continue marketing and distributing Milorganite®
fertilizer in North Carolina. Distribution will be in 32-pound bags for the home landscaping market and 50-
pound bags the professional landscaping market. In 2019, the retail package changed from 36 to 32 pounds.
The following table shows annual total Milorganite° fertilizer distribution in North Carolina for the last three
years:
Year North Carolina Distribution (tons*)
2016 231
2017 189
2018 210
*Weight as distributed. To obtain dry weight,
multiply by 0.93
Milorganite - MMSD 260 W. Seeboth Street Milwaukee, WI 53204 ���
Phone: [phone] [phone] Fax: [phone] Sustainingu rass Research
T�g Rhtin.,c[n-
[e-mail] www.milorganite.com

Milorganite® Fertilizer Permit Renewal
January 8, 2020
Page 2
The following items are enclosed.
1. Distribution of Class A Residuals Form 06-16
2. Residuals Source Certification 06-16
3. The Milorganite® fertilizer manufacturing process
4. Sampling Frequency by parameter
5. Summary of sample results for 2018
6. A copy of the 32-pound bag
7. A copy of the 50-pound bag
8. A Safety Data Sheet
9. Reports showing distribution in North Carolina by product type and destination for 2016,
2017, and 2018
10. TCLP sample results for March 9, 2019
11. Priority pollutant results for spring and fall of 2019
12. Sample results for November 2019, as an example of the extensive results that are
available.
13. Dioxin, Furan, and PCB results for 2018
If you need any additional information, please contact me at tnowickimmsd.com or
414-225-2243. Thanks for your cooperation.
Sincerely yours,
&? J-01
Thomas A. Nowicki
Staff Attorney
Enclosures

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS
INSTRUCTIONS FOR FORM: DCAR 06-16 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supportine documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit website
General — This application is for treatment, storage, transport, distribution, land application, and/or marketing of Class A (or Equivalent)
residuals under 15A NCAC 02T .1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Distribution of Class A Residuals (FORM: DCAR 06-16):
❑ Submit the completed and appropriately executed Distribution of Class A Residuals (FORM: DCAR 06-16) form. Please do
not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to
the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
❑ The project name should be consistent on the plans, specifications, etc.
❑ The Applicant's Certification on Page 3 of this form shall be signed in accordance with 15A NCAC 02T .01061 b f. An alternate
person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A
NCAC 02T .01061 b .
❑ If this project is for a modification of an existing permit, submit one copy of the existing permit.
❑ Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
❑ Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental
Quality (NCDEQ).
Facility Classification
Major (residuals permitted for distribution > 3,000 dry tons/year)
Minor (residuals permitted for distribution < 3,000 dry tons/year)
New Permit Major Modification'
$1,310 $395
$810 I $245
' - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
adds additional residuals sources; or includes the addition of new treatment or storage units/processes not previously permitted.
There is no fee for minor permit modifications.
C. Cover Letter (All Application Packages)
❑ List all items included in the application package, as well as a brief description of the requested permitting action.
RECEIVEDINCDEWWR
JAN 1 4 2020
Non -Discharge
Permitting Unit
INSTRUCTIONS FOR FORM: DCAR 06-16 Page 1 of 3

D. Program Information (All Application Packages)
❑ Provide a narrative explaining the following:
❑ How the materials will be handled and transported from where the residuals were produced to where it will be treated.
❑ How the residuals will be processed/treated (attach process flow diagram).
❑ How leachate collection will be handled.
❑ Where the residuals will be stored until processed.
❑ How the final product will be distributed (packaging, bulk, etc.)
❑ What nutrients or other constituents (i.e. nitrogen, phosphorous, aluminum, calcium, etc.) are used or recommended as the
limiting parameter for determination of residuals loading rate to ensure that it does not overload the soil and cause
contravention of surface water or groundwater standards, limit crop growth, or adversely impact soil quality.
❑ Attach a marketability statement detailing destinations and approximate amounts of the final product to be distributed.
❑ Provide either a label that shall be affixed to the bagged processed residual or an information sheet that shall be provided to the
person who receives the processed residual. The label or information sheet shall contain, at a minimum, the following
information:
❑ Name and address of the person who prepared the residual that is sold or given away.
❑ A statement that application of the residuals to the land shall be in accordance with the instructions on the label or
information sheet.
❑ A statement that the residuals shall not be applied to any site that is flooded, frozen or snow-covered.
❑ A statement that adequate procedures shall be provided to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.
❑ Information on all applicable setbacks in accordance with 15A NCAC 02T . 1108(b.
❑ A statement that the residuals shall be applied at agronomic or recommended rates for intended uses.
E. Detailed Plans and Specifications (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit detailed plans and specifications that have been signed, sealed, and dated by a NC Professional Engineer per 15A
NCAC 02T .1104(a). Specifications for standard equipment may only be omitted for municipalities with approved standard
specifications, but use of the standard specifications must be noted on each sheet of the plans.
❑ Plans must include the following minimum items: a general location map, a topographic map, plan and profile view of the
residuals treatment and storage units as well as the proximity of the residuals treatment and storage units to other utilities and
natural features within 500 feet of all treatment and storage facilities, and detail drawings of all items pertinent to the residuals
treatment and storage units. Depict minimum separations required in 15A NCAC 02T .1108(a) on the plans.
❑ Specifications must include, at a minimum, the following for all items pertinent to residuals treatment and storage units:
description of materials to be used, methods of construction, quality of construction testing procedures to ensure the integrity
of the final product in accordance with 15A NCAC 02T .1104; a)(2)(B], including leakage and pressure testing as appropriate.
❑ Plans and specifications must not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR
CONSTRUCTION, etc.) that indicate that they are anything other than final plans and specifications. However, the plans and
specifications may be labeled with the phrase: FINAL DESIGN — NOT RELEASED FOR CONSTRUCTION.
F. Engineering Calculations (Application Involving New or Changes to Treatment or Storage Units)
❑ Submit all design calculations that have been signed, sealed, and dated by a NC Professional Engineer per 15A NCAC 02T
.1104(a).
G. Environmental Assessments (Maybe Required— See 15A NCAC 1C .0300)
❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals
treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for
the construction of the subject facilities.
INSTRUCTIONS FOR FORM: DCAR 06-16 Page 2 of 3

H. Operation and Maintenance Plan (New and Renewal Application Packages)
❑ For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
❑ Submit the O&M Plan in accordance with 15A NCAC 02T .1110 and include at a minimum:
❑ Operational functions; describe the operation of the program to show what operations are necessary for the program to function
and by whom the functions are to be conducted.
❑ Maintenance schedules; may include equipments calibration, maintenance of signs, etc.
❑ Safety measures; may include safety training program, manuals, signs, etc.
❑ Spill response plan; including control, containment, remediation, emergency contact information, etc.
❑ Inspection plan including the following information;
❑ Names and titles of personnel responsible for conducting the inspections.
❑ Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the selected
location(s) and inspection frequency are representative of the residuals management program.
❑ Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event
that noncompliance is observed.
❑ Sampling and monitoring plan including the following information;
❑ Names and titles of personnel responsible for conducting the sampling and monitoring.
❑ Detailed description of monitoring procedures including parameters to be monitored.
❑ Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature, now,
and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The sampling
plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to meet
pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per year but have an annual
sampling frequency, may need to sample during winter months when pathogen reduction is most likely to be negatively affected
by cold temperatures.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
B► U.S. Postal Service: By Courier/Special Deliverv:
1617 MAIL SERVICE CENTER 512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27699-1617 RALEIGH, NORTH CAROLINA 27604
TELEPHONE NUMBER: [phone]
FAX NUMBER: [phone]
INSTRUCTIONS FOR FORM: DCAR 06-16 Page 3 of 3

RECEI�EDINCDED°' State of North Carolina
Department of Environmental Quality
DWR JAN 1 4 M0 Division of Water Resources
Division of Water Resources Non-p, -:. ya 15A NCAC 02T .1100 — DISTRIBUTION OF CLASS A RESIDUALS
erMitting Unit FORM: DCAR 06-16
I. APPLICANT INFORMATION:
1. Applicant's name: Milwaukee Metropolitan Sewerage District_
Applicant type: ❑ Individual ❑ Corporation ❑ General Partnership ❑ Privately -Owned Public Utility
❑ Federal ❑ State ® Municipal ❑ County
Signature authority's name per 15A NCAC 02T .0106: Thomas A Nowicki Title: Staff Attorney
Applicant's mailing address: 260 West Seeboth Street
City: Milwaukee State: Wisconsin Zip: 53204-1446
Telephone number: 414
j 225-2243 Email Address: tnowickiCc4mmsd.com
2. Consultant's name: License Number (for P.E.):
Affiliation: ❑ On Staff ❑ Retained (Firm: )
Consultant's mailing address:
City: State: Zip: -
Telephone number: (_) Email Address:
3. Fee submitted: $810 (See Instruction B)
II. PERMIT INFORMATION:
1. Application is for (check all that apply): ❑ new, ❑ modified, ® renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: WO0012980
Date of most -recently issued permit: January 26, 2015
Date of most -recently certified Attachment A (if different than the permit):
III. FACILITY INFORMATION:
1. Name of residuals processing facility: Jones Island Water Reclamation Facility
City: Milwaukee State: Wisconsin Zip: 53207-1091
Coordinates: Latitude: 43' 01' 28.3" Longitude: 83' 53' 36.1"
Datum: Level of accuracy:
Method of measurement:
County where facility is located: Milwaukee
2. Facility contact (person familiar with residuals preparation):
Name: Thomas A Nowicki Title: Staff Attorney
Mailing address: 260 West Seeboth Street
City: Milwaukee State: Wisconsin Zip: 53204-1446
Telephone number: [phone] E-mail address: tnowicki mmsd.com
FORM: DCAR 06-16 Pagel of 3

Professional Engineer's Certification: (Application Involving New or Changes to Treatment or Storage Units)
attest that this application for
has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge
the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package
may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed
this material and have judged it to be consistent with the proposed design.
North Carolina Professional Engineer's Seal, Signature, and Date:
Applicant's Certification:
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
® Yes ❑ No, Explain;
vw.IC;,lc
(Signature Authority's Name — PLEASE PRINT)
attest that this application for
J (Facility Name)
(Title)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes § 143-215.6A and §143-215.6B, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.
Signature: �_ Date: �'1 { ' `�r �� `; 4 p
i
FORM: DCAR 06-16 Page 3 of 3

3. Is the residual process facility also the generator? ® Yes; ❑ No
If No, please specify delivery frequency and quantity of residual to be processed:
4. Length of residuals storage at facility: 70 days (Note: the Division requires minimum 30 days storage in units that are separate
from treatment system, i.e. not in clarifiers, aeration basins, etc.)
IV. RESIDUALS QUALITY INFORMATION:
1. Specify how these residuals will be distributed:
® sold or given away in bags or other containers; ❑ lawn (bulk); ❑ home garden (bulk);
❑ other (explain);
Note: Bulk residuals shall mean residuals that are transported and not sold or giving away in a bag or other receptacles with a
load capacity of one metric ton or less.
2. Complete the following if residuals are to be mixed with other materials:
Type of Materials Amounts to be added
per 1.0 dry ton of residuals (dry ton
3. Approximate amounts of the residuals received and processed at the facility: 44,000 dry tons per year.
4. Approximate amounts of the final product (processed residuals) to be distributed: 300 (North Carolina) dry tons per year.
5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and
maximum storage times prior to distribution): 32-12ound and 50-pound bates
6. Does the facility have a stormwater management plan? ® Yes; ❑ No
Explain whether the treatment and storage areas are under roof or how stormwater runoff will be handled: Under roof
V. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the attached Residuals Source Certification and all associated documentation.
RSC 06-16.doc
FORM: DCAR 06-16 Page 2 of 3

DWR,
State of North Carolina
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two conies of the application and
supporting documentation
For more information, visit the Water Qualify Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
❑ Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
❑ For each source facility, attach the following:
❑ Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
❑ Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
❑ Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
❑ Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
❑ For each source facility, attach the following:
❑ Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
❑ Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

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State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Divislon of Water Resources RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: Jones Island Water Reclamation Facility
2. Facility permit holder is: ❑. Federal, 0 State, ❑ Local Government, or 0 Private.
Facility permit issued by: ❑ Div. of Water Resources, ❑ Div. of Environmental Health,
or Z Other (explain: Wisconsin.Dgpartment of Natural Resources).
3. Facility contact person and title: Thomas A Now- icki
Complete mailing address: 260 WestSeeboth Street
City: Milwaukee State: Wisconsin Zip: 53204-1446
Telephone number: [phone] E-mail address: tnowickiAmmsd.com
4. Facility physical address: 700 East Jones Street
City: Milwaukee State: Wisconsin Zip: 53207-1091
Coordinates: Latitude: 43 01' 28.3" Longitude: 83' 53' 36.1"
Datum: Level of accuracy:
Method of measurement:
5. Purpose of the facility:
0 treatment of municipal wastewater, ❑ treatment of 100% domestic wastewater,
❑ treatment of potable water, ❑ treatment of 100% industrial wastewater,
treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: % industrial and % domestic)
❑ other (explain: ).
6. Does the facility have an approved pretreatment program: ® Yes ❑ No
7. Facility permitted/design flow: 30.0 MGD and facility average daily flow: 80 MGD
8. Average amount of residuals being generated at this facility 44,000 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: 200'tons per day (10. dryers; .20 tons per dryer per days
Type and volume of residuals storage (i.e., outside of residuals treatment units): 14,000 tons (14 silos, 2,000 tons per silo}
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
40 CFR Part 503 or ❑ 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102f 6) as:
Z Biological ❑ Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page 1 of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: ❑ yes no.
If yes, list the number(s):
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: ❑ yes 0 no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Pace Analytical and Date of analysis: March 2019
Passed corrosivity test: ❑ yes ❑ no. pH: s.u. (2 < pH < 12.5)
Passed ignitability test: ❑ yes [] no. Flashpoint: °F (> 140°F)
Passed reactivity test: [] yes ❑no. HCN: mg/kg (<250) & HzS: mg/kg (<500)
TCLP Parameter
Limit
(mg/1)
Result
(mg/1)
TCLP Parameter
Limit
(mg/1)
Result
(mg/1)
Arsenic
5.0
0.11
Hexachlorobenzene
0.13
<0.0532
Barium
100.0
0.47
Hexachloro-1,3-Butadiene
0.5
<0.0492
Benzene
0.5
<0.005
Hexachloroethane
3.0
<0.0532
Cadmium
1.0
<0.0066
Lead
5.0
<0.030
Carbon Tetrachloride
0.5
<0.005
Lindane
0.4
<0.00013
Chlordane
0.03
<0.0044
Mercury
0.2
0.0013
Chlorobenzene
100.0
<0.005
Methoxychlor
10.0
<0.0016
Chloroform
6.0
<0.025
Methyl Ethyl Ketone
200.0
0.146
Chromium
5.0
0.10
Nitrobenzene
2.0
<0.0290
m-Cresol
200.0
<0.0312
Pentachlorophenol
100.0
<0.0287
o-Cresol
200.0
<0.0174
Pyridine
5.0
<0.0358
p-Cresol
200.0
<0.0312
Selenium
1.0
<0.061
Cresol
200.0
<0.0312
Silver
5.0
<0.017
2,4-D
10.0
<0.002
Tetrachloroethylene
0.7
<0.005
1,4-Dichlorobenzene
7.5
<0.0375
Toxaphene
0.5
<0.030
1,2-Dichloroethane
0.5
<0.0017
Trichloroethylene
0.5
<0.0033
1,1-Dichloroethylene
0.7
<0.0041
2,4,5-Trichlorophenol
400.0
<0.0168
2,4-Dinitrotoluene
0.13
<0.0158
2,4,6-Trichlorophenol
2.0
<0.0423
Endrin
0.02
<0.00031
2,4,5-TP (Silvex)
1.0
<0.002
Heptachlor and its Hydroxide
0.008
<0.00026
Vinyl Chloride
0.2
<0.0018
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For DistributionlLand Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Milwaukee Metropolitan Sewerage District and Date of analysis: November 2019 Monthly Average
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(mg/kg)
Monthly Average
Concentration Limits
(Class A Only)
(mg/kg)
Result
(mg/kg)
<18
<0.095
Arsenic
75
41
Cadmium
85
39
Copper
4,300
1,500
230
Lead
840
300
37
Mercury
57
17
0.25
Molybdenum
75
n/a
9.4
Nickel
420
420
27
Selenium
100
100
<4.2
Zinc
7,500
2,800
440
b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: and Date of analysis:
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic
(mg/kg)
Chromium
(mg/kg)
Nickel
(mg/kg)
❑ > 0 but <25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
> 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (mg/kg)
FORM: RSC 06-16 Page 3 of 5

5. Nutrient/Micronutrient Determination: Complete the following:
a. Total solids: 93: %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Milwaukee Metropolitan Sewerage District and Date of analysis: Sample dates as shown
Parameter
Result
(mg/kg)
Aluminum
5,000 (November 9, 2019)
Ammonia -Nitrogen
2,000 (November 9, 2019)
Calcium
24,000 (September 7, 2019)
Magnesium
7,000 (September 7, 2019)
Nitrate -Nitrite Nitrogen
9,500 (November 9, 2019)
pH (Standard Unit)
6.4 (November 9, 2019)
Phosphorus
24,000 (November monthly average)
Potassium
4,100 (November monthly average)
Sodium
1,400 (September 7, 2019)
Total Kjeldahl Nitrogen
58,000 (November 9, 2019)
c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR):
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: %.
This rate is a (check one): E default value, or ❑ actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals:
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method
First (1") Year PAN
Five -Year
Maximum Adjusted PAN
(mg1kg)
(mg/kg)
Surface
rl nj ection/Incorporation
6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses:
FORM: RSC 06-16 Page 4 of 5

7. Patho en Reduction: Per 15A NCAC 02T.11061 specify how residuals will meet the pathogen reduction requirements:
a. For Distribution/Land A lication of Class A or E uivalent:
Z A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
❑ Alternative 1 [15A NCAC 02T.I 106(b)(3)(A)] - Time/Temperature Compliance.
❑ Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
❑ Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
® Alternative 5 [15A NCAC 02T.1106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: ❑ composting, Z heat drying, ❑ heat treatment,
❑ thermophilic aerobic digestion, ❑ beta ray irradiation,
❑ gamma ray irradiation, or ❑ pasteurization.
b. For Land Agglication of Class B:
❑ Alternative 1 [15A NCAC 02T.1106(c)(1)] - Fecal Coliform Density Demonstration.
❑ Alternative 2 [15A NCAC 02T.1106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: ❑ aerobic digestion, ❑ air drying, ❑ anaerobic digestion,
❑ composting, or ❑ lime stabilization.
c. For Surface Disposal:
❑ Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
❑ Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above.
❑ Exempt -If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T.1106(a)(2)].
❑ Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
❑ Alternative 1 [15A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
❑ Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
❑ Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
❑ Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
❑ Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
❑ Alternative 6 [15A NCAC 02T.1107(a)(6)] - Alkaline Stabilization.
Alternative 7 [15A NCAC 02T.1107(a)(7)] - Drying of Stabilized Residuals.
❑ Alternative 8 [15A NCAC 02T.I 107(a)(8)1 - Drying of Unstabilized Residuals.
❑ Alternative 9 [15A NCAC 02T.1107(a)(9)] - Injection.
❑ Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
❑ Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.1107(b)(2)].
❑ Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

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bh,,,,S.LOW-RELEASE
Milorganite
NITROGEN FERTILIZER
The Milorganite® Fertilizer Manufacturing Process
Milorganite® fertilizer is a byproduct of the water reclamation process at the facilities of
the Milwaukee Metropolitan Sewerage District (District). The District serves 1.1 million
people in 28 communities. The District operates two water reclamation facilities, Jones
Island and South Shore. These water reclamation facilities receive wastewater from
residential, commercial, institutional, and industrial sources. At industrial dischargers,
the District enforces effluent limits to prevent the discharge of pollutants that would
interfere with or pass through the water reclamation process or contaminate biosolids.
At each water reclamation facility, a typical flow rate is 80 MGD, but flow rates may
reach 390 MGD during wet weather. Rain, snow melt, and soil moisture levels affect
influent flow rates and pollutant concentrations. As flow rates and pollutant loadings
vary, the solids production rate varies. Also, for treatment chemicals, the feed rates
va ry.
The water reclamation process has four steps. First, screening and settling remove
solid materials. Second, phosphorus is removed biologically at Jones Island and
chemically at South Shore. Third, air is added to promote biological decomposition of
organic materials and then settling occurs to remove solids. Fourth, disinfection
destroys pathogens. After these steps, both Jones Island and South Shore discharge
clean water to Lake Michigan.
Solids are an inevitable byproduct of this treatment process. Solids from the biological
treatment step are the primary component of Milorganite® fertilizer. From the initial step
to remove solids, digested solids are a secondary component. The chemicals added to
remove phosphorus and promote thickening comprise a very small fraction of
Milorganite® fertilizer.
The first water reclamation step produces primary sludge. From both Jones Island and
South Shore, primary sludge goes to anaerobic digestion at South Shore. This step
reduces and stabilizes organic material and produces methane gas, which the District
recovers to generate electricity.
After the biological treatment step, clarifiers remove solids. Much of this material is
recycled to seed the biological treatment step. However, some solids must be removed
from the process. These solids are called "waste activated sludge." At Jones Island,
waste activated sludge goes directly to equalization and blending tanks that feed the
dewatering and drying process. At South Shore, the digested primary sludge and the

waste activated sludge are mixed and pumped to the Jones Island equalization and
blending tanks.
Milorganite(D fertilizer manufacturing starts with the solids from the water reclamation
process. The process involves unit operations that are physical, rather than chemical or
biological. The tasks are separating solids from water and sizing the pellets.
The first step is gravity belt thickening. Solids are mixed with ferric chloride and
polymer. These chemicals agglomerate the solids, enhancing water removal. Gravity
separates the solids.
The next step is belt filter press dewatering. Solids are mixed with polymer and ferric
chloride. As in the previous step, these chemicals agglomerate the solids, enhancing
water removal. The material is spread on a belt. A gravity zone and a compression
zone remove water. The resulting filter cake is 16% to 18% solids.
Drying occurs after dewatering. Filter cake is mixed with recycled dried pellets. On a
dry weight basis, dryer feed is approximately 10% filter cake and 90% recycled dried
pellets. Drying occurs in twelve heated rotary drums in two lines of six dryers. The
dryer residence time is 30 to 40 minutes. Hot air in the range of 425 °C to 500 °C heats
the pellets, achieving a pellet exit temperature greater than 80 °C.
The manufacturing process involves multiple passes through dryers. Three recycling
systems operate continuously. One recycling system directs pellets from one dryer to
the next dryer. A second recycling system collects pellets in centralized bins and
returns them to the drying system. Third, after the recycling bins, oversize pellets are
separated, milled, and returned to the drying system. During limited periods of special
conditions, all discharges from individual dryers are returned to the same dryer.
As a product in the retail fertilizer marketplace, achieving consistent pellet size is critical.
Typically, from the sizing operation, 60-70% of pellets return to the dryers.
The manufacturing process includes multiple redundancies to demonstrate pathogen
destruction. Product temperature is the primary technique for demonstrating pathogen
reduction. At the end of each dryer drum, a detector continuously provides product
temperature. Drums are operated to maintain a product exit temperature greater than
80 'C. For a secondary pathogen destruction demonstration, time and temperature is
continuously measured within the recycling bins. In the rare case where both product
temperature and time and temperature fail to demonstrate pathogen reduction, then the
gate to sizing closes and all product returns to the dryers. If the gate to sizing fails to
close, then product is segregated and either returned to the drying system or sampled
for enteric viruses and helminth ova.
A pellet exit temperature of 80 °C and a moisture content of less than 10% destroys
pathogens. Typically, one pass through the dryer is enough to achieve these goals.
However, as noted above, most pellets are recycled multiple times, providing further
2

pathogen reduction. For moisture, the District analyzes daily composite samples and
weekly composite samples. If moisture exceeds 10%, then production from that day is
segregated and re -processed. The District analyzes for fecal coliform weekly to confirm
pathogen destruction.
Between drying and short-term storage, sampling occurs. The District continuously
collects 24-hour production -weighted composite samples. Depending on the
parameter, the District also collects grab samples, weekly composites, or other types of
samples.
After obtaining sample results, pellets move from short-term storage in day tanks to
long-term storage in silos. Pellets are segregated into storage silos by production date.
Silos contain five to ten days of production. As pellets accumulate in a silo, a lot
number is assigned and nutrient, contaminant characteristics, and pellet size are
recorded and reviewed. These characteristics determine how a product will be
packaged. When necessary, mixing of the contents from two silos occurs to obtain
required nutrient or pollutant concentrations or pellet size distribution.
As shipping occurs, the District collects composite samples and analyzes these
samples for nutrients, pellet size, moisture, bulk density, cadmium, and chromium.
Also, the District applies a very light coating of a dust control agent at a rate of one
gallon per ton of product.
From the Jones Island Water Reclamation Facility, all product leaves in bulk. Almost all
product goes to a packaging contractor in Milwaukee. Occasionally, bulk shipments
occur to customers.
3

SLOW -RELEASE
M"Ilorgan'ite'
in --
NITROGEN FERTILIZER
Sample Frequency
Parameter
Frequency
As, Cd, Cu, Fe, K, Mo, Ni, P, Pb, Se, Zn
Daily
Al, B, Cr
Monthly
Hg
Weekly
Fecal Coliform
Weekly
PCB Aroclors
Daily
Dioxin Toxic Equivalents: Dioxins, Furans, and PCBs
Monthly
Priority Pollutants
Semi-annually
Nitrogen: ammonia, nitrate, total, water insoluble
Monthly
Total volatile solids
Monthly
Moisture
Daily

SLOW -RELEASE
MilorganiMt
e
NITROGEN FERTILIZER
Summary of Sample Results
2018
Parameter
Units
Highest
Day
13
Annual
Average
Federal
Limit
Arsenic
mg/kg
<6.31
41
Cadmium
mg/kg
1.1
0.38
39
Chromium
mg/kg
230
185
Copper
mg/kg
240
204
1,500
Lead
mg/kg
77
40
300
Mercury
mg/kg
0.36
0.13
17
Molybdenum
mg/kg
13
10
75
Nickel
mg/kg
52
29
420
Selenium
mg/kg
13
<6.71
100
Zinc
mg/kg
570
440
2,800
PCB Aroclors (total)
mg/kg
0.22
0.02
Dioxin TEQZ
pg/g
60
19
1. These annual averages were below the level of detection
2. TEQ is the sum of the concentrations of various dioxins, furans, and
polychlorinated biphenyls multiplied by individual toxic equivalency
factors, as established by the U.S. Environmental Protection Agency

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LUSH LAWNS
ABUNDANT GARDENS
TRUSTED FOR OVER 90 YEARS
0
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RESULTS.
6-44-0
{ .- Net wt. 32 1 bs 14.5 k
Covers up to 2,500 sq ft { g} ,
_ • ¢¢i Jved I— regtied eullltrn[s qr od ucvd
FL 5,200 ,sq ftIll. k-
" ey sne wafer reeiamaelon yioev�a
RNING
MI I
organ, y
NOWBU_
�.d�. •�c3�il�r: sites}G ���'.;..t:,��.ti..e��:,:: 'La3C •._-4d:i:ii iri �ii JvC• ..'�i.:�-:.� �:.1��.�1i� L • t. � � - . . 'r.• �. �:ic.�1, 1 �- - .r.-�•: �:....5:• . i � .. _:�

I ..
NITROGEN FERTILIZER
ALL PURPOSE • NON -BURNING
IRON FOR ENHANCED GREENING
LONG LASTING
HOW MANY BAGS TO USE
To calculate how many bags of Milorganite to use, measure the
length and width ofyour lawn. Multiply these dimensions to obtain
square feet. Divide this by 2,500 and you will have calculated the
number of bags to use
CUANTAS BOLSAS DE USAR low+
Calcular cuantas bolsas de Milorganite a utilizer, medir IS longitud y IS anchors de so cesped.
Multiplicar Estes dimensiones pare obtener los pies cuadrados. Decidir esto por los 230 y Ids
qua se han calculado el nGmero de bolsas a utilizer.
SPREADER SETTINGS AND APPLICATION
1 Mow your lawn and allow clippings to remain on the lawn. Grass clippings recycle the
nutrients back into the soil.
2 Spread the Milorganite onto your lawn.
3 To get uniform distribution, divide the correct amount of total fertilizer to be used in half
and apply that half of the fertilizer walking in the North and South direction. Apply the
remainder of fertilizer walking in the East and West direction.
4 In case of spillage, rake or sweep up the fertilizer and spread it over the lawn.
5 Avoid direct applications to steep slopes, in areas that flood, wetlands, or into surface water.
6 Wash hands after use.
ESPARCIDOR DE CONFIGURACI6N Y APLICAC16N
J. Corte el cesped y permitir qua IDS recortes se mantienen en el cesped. Los recortes
CIE hierba the rec-claje de los nutdentes an el suelo.
2 Difundir el Milorganite en so cesped.
3 Para obtener una distribution uniforme, divide IS cantidad correcta del total de fertilizante
pars ser usado en Is milled y aplicar qua Is mitad de los fertilizantes que cammar en el
Norte y el Sur direction. A continuaci6n, aplicar el resto de los fertilizantes que caminar an
el Este y el Oeste.
4 En case de derrame, el rastrillo o IS barra de los fertilizantes y IS extendi6 sobre el cesped.
5 Evitar aplicaciones directas an las empinadas laderas, an [as areas de inundacidn,
humedales, o an IS superficie del ague.
6 Lavese las manos despuds de, su uso.
Regular Feeding New Lawns
SPREADER MODEL (2,500 sgftperbaM (1,250sgftpecbag)
The production of Milorganite® is one of the
NATION'S OLDEST and LARGEST recycling efforts.
Since 1926, Milwaukee has recycled nutrients resulting from the city's water reclamation
process into Milorganite Slow -Release Nitrogen Fertilizer. Consumers can apply these
valuable recycled nutrients with plant growing power in the form of Milorganite.
Milorganite DIRECTIONS/1NSTRUCCIONES
APPLICATION RATES Please read carefully before using. Apply accordingto label directions. LAS TASAS DE APLICA016N Par Favor, lea cuidadosameme antes she
Avoid direct application to sleep slopes in areas that flood, on wetlands, or into surface usar. Si! splice de acuerdo a las instructions de Is etiquela. Evitar to
water. Wash hands after use For mommfarmalion and tips visit MUO`anite.eom aphcacion climate an las ennomidas laderas an zonal clue se inundan, en
' FL. Me & Mt: Apply f0huganlfe two (Imes ayear at Pe rate or32 tbs per S,20osq 2 los humedales, o an Is superficie del aqua. Lavese las mars despul s de
FL—Idenfs, check Wth local county nuffinces as so ferdilrer blackoottlu2'p0r`1q Mt apializinku, so use Para scene, mas informacl5n y eonse)os visit. miloreanite.com
Eadhway EV-N-Spred (1950, 2000A, 2000AP, 2030) 19 19 (2 passes)
Scotts Basic, EdgeGuard (Pia, MIN), Lawn Pro, Standard 111h d1 % (2 passes)
Scotts Easy Green 29 29 (2 passes)
Scotts Speedy Green (series 1000, 2000, 3000) 1114 1144 (2 passes)
The above spreader settings will vary according to the rate of walk and the mechanical condition
of the spreader. Adjustment to the spreader may be required to apply the proper amount. L
Spreader settings are to be used as a guide. If your spreader is not listed visit our website. For F
best results calibrate your spreader using steps found at milorganite.com \
6-4-0
GUARANTEED ANALYSIS
0"
N
O
W
NORTHERN
Memarl.IDay 321bs per 2.500 eq ft
4th ofluly 32 be per 2 500 sq ft
Labor Day 321bc per 2,500 sq ft
litkegiwng(dormant reed) 321be per 2 500 sq ft
SOUTHERN
Easter(sherturfbreaksdo .mx) 32 Ibs per 2.500 sqR
Memanal Day 3216s per 2.500 sq ft
Labor Day 32 Ibs per 2,500 sq ft
Early October 32 His per 2,500 sq ft
FL residents, apply two times pmyear at the rate of 32 lb, per
5200 ski ft Check with your local county ordinates as to fertilizer
blackout dates prior to application.
NEW LAWNS
Mix into top of sail before seeding or sodding. Attar 3rd
wing of the raw lawn. apply two 361b bags of Mdorganite per
2,500 sq ft. In the state of Virginia apply 32 be per 2,500 sit ft.
Rates not applicable in the state of FL.
Seed Be
641be per 2,500 so ft
sodding or Sprigging 64 Its per 2.500 eq ft
TREES
E3(abllelmd 5lbs per inch of trunk diameter. Pour into
holes (1' widex 12 chap) spaced 2 tt apart
along drip line
hansplanted 1/ lb per it ofnee height. Mix with soil at bottom
of hole prior to insertm&transplanted Use
SHRUBS
Establlshed 5Its per 100 zq it Scatter over the soil
surface, work in with rake
7rensplanted '/2 lb par it of shrub height Mix with soil
at bottom of hole prior to inserting
transplanted shrub
ANNUALS
hl-mo soil when preparing flower had or container When flower
buds form, apply an additional application.
spring 1 Ya be t4 Ya cups) per 50 so ft
Summer 1 lb (3 cups) per 50 sq It
' PERENNIALS
f Mix into sail when preparing flower bed When flower buds form
a apply an additional application
Springer 2 Y: Ibs (7 vz cups) per 50 sq It
Summ 2 % be (7 V2 cUps) per 50 sq ft
ROSES
Established 1It, (3 cups) per 50 so, ft
4-S—Ielater 1 Ib(3 cups) per 50 sq ft
VEGETABLES
Mix into soil to rooting depth 'Per plant rate %cup
Prior N planting 4 V. Ibs (13 Vs cups) per 50 eq ft
o nor. c i L. = u s.— yr Ivnwnr.... m
GROWING BEAUTIFUL LAWNS, TREES, SHRUBS AND FLOWERS SINCE 1926. Ifyou have questions regardingthe proper use ofthis brosolads fertilizer derived fmm recycled nutrients
produced bythe water reclamation process please visumilorgance com or use'MilorganiW' to search the internetto see whatother gardeners say aboutMilargamts Caution. Store Milorganite in
tool. dry place, away tmm children and pets Some dogs are attracted to Milorganite Consumption of large amounts may cause gastna,tation. After faMbang, monitor your dog to determine
interest To reduce attraction, water after application and limityour our dogs —as for 24 hours Milorganite is non -toxic &,Warning -This product can expose you to chemicals, including lead known to
the State of California to cause cancer and birth defects or aMerreproducbve harm. For more information, go to www.p65wamings ca.gov No awdence indicates any actual additional nsk of canoe,
birth defects or other reproductive harm when this product is used as directed, Use according to directions: Apply only to actively growing turf Do not apply near water. storm drams or drainage
ditches. Donut
applyif heavy rmn is expected Apply Nis product only to your lawn and sweep any product that lands in the drivewaysidewalkor street. back onto your lawn Check with your local
Cooperative Extension Agemymobtainspecificinfoimationonlocalturfbestmenagementpmcdces Checkwithynurcounty.,cipigovemmenttodetermineifthere are local regulations forferblizeruse
"Bum proofwhen used according to the label direeUans
NORTE
Dia de Conmemoracidn de lea Cadets 14,5 Ike par 230 m�
4dedulfo
14.5 kg or 230 m1
Dia del trabfador
14.5 kg par 230.'-
Dia de Acclin de Greclas
14 5 kg par 230 mz
(momdn irwcbva)
SUR
Pascua
14,5 kg par 230 m,
l—doel ise—ps la in —me is)
Dfa de Conmemoracldn de los Ce ides 14 5 kg por 230 me
Dia del babaisdor
145 kg par 230 m'
A pnncipros de, octubre
14.5 kg par 230 mr
SIEMBRAS NUEVAS
Mezdar an Is parts superior de 2.5 cm as sued antes the Is emmbm
o einsured, Desp,ds de la tar ... a sego, at cesped nuevo, se aph.
an dos 14,5 kg bolses de Milorganite par 230 me. En el estado de
Virginia se a.i,..n 145 kg par 230 m'.
Sem(llero 29 kg por 230 m'
Plantation As cesped o 29 kg P.
230 in
are
miness an as to ones o rfzomas
ARBOLES
r� �L
all-
Arrargados
2,3 kg par calla 2.5 cm de diametro de taro
Vmrta an agirjems it, 2.5 cm de anchox 3C cm
de profundided distended -a 60 cm a la largo
de la line. de nag.
Tresplantedos
230g par cad a 30 cm it, alto del arbol. Mezcle
on Berra al fordo del agujero antes it, inserter
al arbol traspiantado
ARBUSTOS
Arrafgadaa
2,3 kg par catla 9 3 mz Disbihuya snore la
superficie d, le Berra y trabijelu ten tin
rastrillo par. que pent,,
Taspiantados 230 g par cada 30 cm tle alto del irbol.
Mlezcle can tierra al rondo del agujera antes
on i.... tar el arbusto trespl.m.do
ANUALES
Mezcla el abono
y la tierra del ... 1, o del comenedor donde hs
floras se van
Una ves las flares empiezan a Former se
:plantar
adicianar mas abono
Primavem
17{
e80 g (4 59 tazas) por cada 4.5 mz
{
Versno
450 g(3 tazas) par cada 4,5 m'
j
PERENNES
Mazda d abono
y la terra del suela donde las flares se vaapI-"a'
Una ves las flares empiezan a former se. adicianar mas abn ono
Pnmavera
1,2 kg (7'h lazes) par catla 4 5 m= 7
Versno
1.2 Ike (7 i4 tazas) par cada 4 5 — I
ROSAS
Armigadas 450 g(3 tazas) par cada 45 m-'
4-6semanasmastarde 450g(3tazas)pm,ada4.5V
VEGETALES
Adlonar media ;4 taza its abono par plant, Meta, la tierra hasta
one profundidad par detain tle las rafces
Antesdosembra 2 kg(13% false) par tads 4,5 ni'
NOTA:1 LIBRA (454 G) = 3 TAZAS DE MILORGANITE
ZERO PHOSPHORUS TURF LAWS: New Yeric Mdorganite cannot be applied to a lawn unless a sal test In-
dicates that addibonal phosphorus is needed far growth of the lawn or non-agricultural tun, or the fertilizer is used
for a newly established lawn or non-agncultural turf during the first growing season Maryland: Providing nutrients to
specific sails and target vegetation as determined to be necessary in accordance with a soil lest that was conducted
by a laboratoryidentified under 8-803 7 of the Agricultural Article, Annotated Code of Maryland performed no more
than 3 years before the application.
Information regarding the contents and levels of metals m this product is evadable on the internal at
fuirmaaefca erg/metals.html
Manufactured by: Milwaukee Metropolitan Sewerage District
Net wt. 32lbs 260WSeebothSt, Milwaukee, WI53204 MADE IN THE USA

3
SLOW -RELEASE
M,10 aniot
e
NITROGEN FERTILIZER
PROFESSIONAL Ea GRADE
TURFGRASS FERTILIZER
FOR GREENS, TEES & FAIRWAYS
NON -BURNING* SLOW -RELEASE NITROGEN
RICH IN
6®4=0 -CONTAINS IWATER-INSOLUBLE IRON FOR ENHANCED GREENING
s SMALL GRANULE —EASILY DROPS TO SOIL SURFACE
COVERS 3,000 SQ FT AT 1 LB NITROGEN RATE
Application Rates: Ibs Nitrogen to Material per sq ft
ea]IbN a.5016N Io,li,14 1.5p IbN
6.5M ssO 17 in 251M
per 1,000 epa par 1.000"ft pw 1.000,R I1 P.
1.0w'gR
NarpR.,l In IaY1,000 •a n
liamTGrL Spread wdlh M 2A in
Ewllnwr Bn 12 15 28
Leew BM1 F H R
P. agbd I H K X
Swa,R. 9fl J(-71 M(ewe7) X(wne 7)
And—SR20WNAP2000 9fl J(tune 71 M(-7) X(wne 1)
spyew 9fl 4 5 9
Lety(Hola 8, 4 'A, ZOO)
Ley(Hob 8.4%mph) 400 a a-iX
Nole•: 7Mwe•9„n.pub•f.nliur•pwrpan•¢wlOa Gwa anwmultl d•,ea nN neMNnlrowmf ,.Pal••
nr wrNaN �.a. per�au nwb.wWu n..ne.en lrw..Mdt.Ilw�we.e. lerrN�t.nemm.e...e.. nmrw�nl
b�emMlsuam ywrwn•e.rwms m.mymp.r.nwnmwnpon.mmvunam•xYwnnr—
Environmental Respect
o�r• wee�en.. rww.e hdadG. Mpeq.eG• p�pn• paarmwt us. Emimnn.mN Pmbumn w•rNv, �mp�N
arpwsalNn•.ta.l,.m..1M e.dpn.pa.m..peW Mmmrn•pnau<t..,naw.d.rry.br. r.nswr: nwmm.bw.
Xnp•n n Mmgedb• aeeic.•nler•• da•y, puw•nMi q.!ary neEnp p•rial. TAb tlw nNw mmitlmue pwnGl wnnmm�W
Inp¢1 hwn rurmR a MIx41er!'di/ imo pivrad r,•Ir.
p,•nwr9n/b 4V Ybw:ww44'wat•pplLNlwamp,nw,rra„c•,.N••p Yaq•.rw XW AOW. xvpvm, w4M aurnw walr.
AM ub.p MaaprYn•, YnN hmd•re mmuure Pbeudb•rm,erY•n•,BppN eayb nwl Ro+v'9
mH.0. wl •pp � maw•Yr. perm L,Nn, wbvml,• eIW,,. pp M,ppty XMM ral i• WCeG. AppY pe, P.G.1 wlrmywmrt, uN
•wep •M pmsid tlullrtle w e• dmma'M. dG+•Ik wpn,t p•ekeriep Yapwd. Ch,G Ykr rmvloel Ceepmiw Emrbn Apwcy b
ppMb,p.pXd ieam.bn w ba e.rp.N mruprnwlpnRnw rneumtm Y•vrwnMY way pewmmmnmGWrm• a uNn.e bwl
nqui8em M bnY"¢xwe. mWrmp Tha pionrw u+mbow rnu m memiel,, arrl,6rp 4w. Yno�n n Nn SW N C•aeM• b ann
wnarW WPQ•n,nrper•rl,proOutMlwm. Fa nv4eprmeppn, pem.Np Mpram Yrwb•rry xl•I
•eeauN Atdvim, arm eNeeb,wol' r•PoeuaM hrmwnn ml•ppardb nM n6Mtl.
MMmnlan rw Wtppw mMeM re l,w, N mNd. b mb prpeVct I• nNl•el• pn a.ImemN w.....�....-�.s.
aunP'edea,nrse,e,ae%pbw NpYd.C,.
Valores de to aplicaci6n: librae de Nitr6geno sobre of material por pie'
0.33Ilbras X ..So Ilbr•s N t" lbr• N 1 5011bns N
S,Sfbrw 8.58bne 171bne 256bee
por l,WOpb• por 1.-0ee por 1,000 Ph' pa"_yM
NK-_/rn /n abr//n,000 pl/'
FaealTldgf Ancho d•omo pacldn iLa L12 in
EerCn-ay B"s 12 1s 28
Leew 8 pies F H R
pros slow 9p(a• H K X
S. R8A 9 pies J [cow 7) M — 7) X (cam 7)
AYderson, aR2VOV et Ml00o 9pw J(-7) M(mm7) xlwm 7)
apnrer B pb• 4 s s
L*(Kn5,4%mph) 20 pbe - 5 8
LNr Mons. 4 x mph) 40 pee - e e-2X
Nobs: E,m wnlXea•,,en vn. pva. u.p.lwaan e. bHwnn• w 4.4 pnw w Ir nmNMe.• G rm rd�, ae web r e.!n
... tr wrde.ee. r d wlena.rb e..p!wrm wnn ee •w.np .1n wrdawm. amppr, r pw• G wN.
L• wmawe a. rsx%n. a.waw eN arwwr ••pwrNw,wee•n mrrw w w.m pw%we.dm.n w wmbeen,0•w5•a
H m•WT nwlVdm, a§w, w upraew wrmo %.r•mnwe•den,r e,IM1biume pw• wqurrN G•eaden, o meb •
AspectosAmbientales
E pm4udw vwrgwb•,mae,erde, inra,eee lw pmNm,faerpnG•prpiBrwneb wnpl•n Wnonnr 0�.'GgwNe
Empmn,YGbp rcie•Pnrrc]dn MbwW ee b, ENaG, Un:w�u�mr•na .E.beWen•ehr
pre4ws•WbyNY wpNtlen wrm wahii,rluyrewde xremn• u,o de Ae byre.
E1mmNepweG In peeuA WaywL•wlAenlerlCnmiw.yan@adpwl•rp•pe4oe G,an,nwetlri Ftle NmpbnH
m rNpXrmNimp•,m,nWrW•pM-Glo•vunwNr NNp•eonn GnWlmb.MNgw u:pwr4+•.
1lplhw Iw p•dude• Mllpr/•NN• G rwNe wn Ir Mdrvalwr G I• NI4wb. EA M •ywrin bm•b w wgrllgw
',nprmr,tll,,, hdw prmuri Wa Nu ye w WMn, p.rWro• e n N •pa xganc�Y.0.epWe G unr� , Mre In nuw
r,•ee N pM�w w•eobjo•eetrni8w Yde In mamm n w N•5roY „e•.
mAawbnra EN. pm4Wb wns.n. �m.e..eN.laer a. wNrrm, pdm*n we r %• rmpw w-n,.>: yrx.c an.m. p.
m e eMe •n d Nome n etlw. Em •wa!• NiNm,• maven gdiw w• cpresnwmr •,1Errtl• o mpeGrru pr•
9wb•manipubcM w,•rB.Wwma wenvi•m.u•m•••em.b•YFbnbnrNWmtle.peL n•M1wm.pWun
'nqe G r1rv, deltlm G nwbe•me a emte n d d•bm• npeeuc'rn.
Pu,G mmW V NMncen rmn Y wMCa Y W naNn G. mwYn eN PnCacb en IrNmN en d,IL'a ....��
64.0 3 6-4 R
Milarganitaa Proraaalonal Grade Milorganite• an311/Is garentindo B
Guaranlead Analysis de caiidad proraslonal
Total N"en(N]_._.._..._.......__..._............._.............. 6.0 Y. N'Ibogano Tolal(N).....»_.._......__ ........._..._...._... 6,0%
2.0 % Wat. SduNa N'drpgen Mantlbebl,d by. 2.0 %Nih,59.o ralubl. en aqua
4.0 % WSW lnsok"a NNo . Mllwauk// Mabepelaan e/w/ng/ olaolet 4,0 %Ntldgem insolubla en ague•
Available PhoaphsN (PYO,j.......... __.._.... ............ _.... 4.0 % 2a0 w ae . sL MilNavtee,.'W" Foslab disponible(P:O,)._._..._.._........_...__...._...4.0 %
CaVum(Ca) .. .1.2% (e00)2a7-sWS wwwmmsd.mm Calua(Ca)...._.._.._....._.._.._..._.._.._......_....._........ 1,2%
Hlenoe.._...___..._.......__.__......_..0 .._............. 2.5% Ilon(Fa).._................... _................__.._.................._.2.5 Y. )—1,o]ee pmeea/d
�p sevrepe NaaE Ix TXE Y9a Oedvada do aguM
•4.0 %Skmy •wLbb Nbvpen dented han pmmaM sexege •4.4%lMareraib H4epeb eebtle G grrwbbpv�
Net wt. 50 Ibs (22,68 kg) Peso noto de 50 Ilbras (22,68 kg)

0 0 0 NO ME , : 0 0
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Page 119
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Product Identifier
Reviewed on 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Relevant identified uses of the substance or mixture and uses advised against:
Product Description A fetilizer product manufactured from various microbes used to digest sewage sludge.
Details of the Supplier of the Safety Data Sheet:
Manufacturer/Supplier:
Milwaukee Metropolitan Sewerage District
260 W. Seeboth Street
Milwaukee, WI 53204
Telephone: [phone]
Emergency telephone number: 1-800-304-6204
Classification of the substance or mixture:
I GHS07
•
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Aquatic Acute 2 H401 Toxic to aquatic life.
Label elements:
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms:
•
GHS07
Signal word: Warning
Hazard -determining components of labeling:
Activated Sewage Sludge (biosolids, dried microbes)
Calcium Carbonate
Hazard statements:
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Toxic to aquatic life.
Precautionary statements:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well -ventilated area.
Wear protective gloves.
Wear eye protection / face protection.
Avoid release to the environment.
Wash thoroughly after handling.
(Contd. on page 2)

Page 219
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Reviewed on 1012612015
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well -ventilated place. Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 1
Fire = 0
Reactivity = 0
HMIS-ratings (scale 0 - 4)
Health = 1
a Fire = 0
Reac-Tivrry o? Reactivity = 0
Hazard(s) not otherwise classified (HNOC): None known
i
Chemical characterization: Mixtures
Description: Mixture of substances listed below with non -hazardous additions.
Dangerous Components:
8049-99-8 Activated Sewage Sludge (biosolids, dried microbes) 100%
Q Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320; Aquatic Acute 2, H401
Additional information:
Trace metals and volatile organics can be detected in quantities less that 1.0%, most less than 0.1%. These
components and pathogenic agents are of a low quantity to allow this product to meet US EPA 40CFR Part
503 Class A Exceptional Quality biosolid requirements.
Description of first aid measures:
After inhalation: Remove affected person to fresh air. Seek medical attention if symptoms persist.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Remove contact lenses at once. Rinse opened eye under running water for at least 15 minutes. If irritation
persists, seek medical attention.
After swallowing: If suffering gastrointestinal discomfort, treat symptomatically.
Information for doctor:
Most important symptoms and effects, both acute and delayed:
Asthmatics exposed to excessive dusts may have trouble breathing.
Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
(Contd. on page 3)

Page 319
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Reviewed on 1012612015
Extinguishing media:
Suitable extinguishing agents:
CO,,, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture:
At high temperatures, this type of fertilizer can give off undefined fumes. Fine dust dispersion in air may form
an explosive mixture. Bulk wetted material may generate heat upon storage. Use of TEFC electrical
equipment is advised to aid in control of dust -caused explosions. Control fugitive dust at its' source by
containment or treating Milorganite with a dust suppressant.
Advice for firefighters:
Do not breathe fumes. Prevent runoff from entering drains, sewers or any body of water. Becomes slippery
when wet, guard against falls.
Protective equipment:
As in any fire, wear self-contained breathing apparatus pressure -demand (NIOSH approved or equivalent)
and full protective gear to prevent contact with skin and eyes.
Personal precautions, protective equipment and emergency procedures: Not required.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Sweep, vacuum or shovel material into labeled container. If at all possible, reuse product. Ensure that
disposal is in compliance with local, state or federal regulations.
Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Handling
Precautions for safe handling:
Avoid breathing dust. Wash after handling. Do not contaminate water by disposal of equipment washwaters.
Do not allow to become wet during storage.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities:
Storage
Requirements to be met by storerooms and receptacles:
Store in the original container.
Store in a cool, dry area out of reach of children and animals. Keep dry. Bulk wetted material may generate
heat upon storage.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Some coprophagic canines (fecal eating dogs) may be attracted by the odor of biosolids, transfer their fecal
attraction to Milorganite® 5-2-0 fertilizer, rip open bags in storage and over eat. A dog may be sick for 24 to 48
hours, beginning with vomiting that can lead to dehydration, incontinence (stiffness in the hind legs), atrophy,
depression, and black stools due to the high carbon content of Milorganite® 5-2-0. In most cases,
symptomatic care prescribed by a veterinarian will relieve these symptoms.
Specific end use(s): No further relevant information available.
(Contd. on page 4)

Page 419
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Reviewed on 1012612015
Additional information about design of technical systems: No further data; see section 7.
Control parameters:
Components with occupational exposure limits:
The product does not contain any relevant quantities of materials with critical values that have to be monitored
at the workplace.
Additional information: The lists that were valid during the creation of this SIDS were used as basis.
Exposure controls:
Provide general ventilation in processing and storage. Provide local exhaust if necessary to reduce dust
levels below acceptable limits.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing and wash before reuse.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment: Not required.
Protection of hands:
(5 Protective gloves
Eye protection:
0 Tightly sealed goggles
Information on basic physical and chemical properties
General Information
Appearance:
Form:
Granulate
Color:
Dark
Odor.
Earthy
Odor threshold:
Not determined.
pH -value:
Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
Flash point:
Flammability (solid, gaseous):
Ignition temperature:
Decomposition temperature:
Slightly acidic (9 parts water to 1 part Milorganite)
Not determined.
Not determined.
None
Not determined.
Not determined.
(Contd. on page 5)

Page 519
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Auto igniting:
Danger of explosion:
Explosion limits:
Lower:
Upper:
Vapor pressure:
Density:
Reviewed on 1012612015
Product is not self -igniting.
Product does not present an explosion hazard.
Not determined.
Not determined.
Not applicable.
Relative density:
Not determined.
Vapor density:
Not applicable.
Evaporation rate:
Not applicable.
Solubility in / Miscibility with:
Water:
Slightly soluble.
Partition coefficient (n-octanol/wafer):
Not determined.
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
Other information: Bulk Density: 50-51 Ibs/ft3
Reactivity. No further relevant information available.
Chemical stability: Stable under normal conditions.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions: No dangerous reactions known.
Conditions to avoid: Excessive heat; absorbs moisture in highly humid areas.
Incompatible materials: Strong acids, alkalis and oxidizing agents.
Hazardous decomposition products:
Expected to emit the same types of toxic smoke as would be released during combustion of other organic
materials.
Information on toxicological effects:
Acute toxicity:
Primary irritant effect:
On the skin: Irritant to skin and mucous membranes.
On the eye:
Irritating effect.
Causes serious eye irritation.
Additional toxicological information:
As a recycled product made by a municipal water reclamation facility, biosolids have the potential to contain
various pollutants. The U.S. Environmental Protection Agency has extensively analyzed the risk from these
pollutants. These analyses have considered over 400 compounds, including metals, volatile and semi -
volatile organic compounds, pesticides, furans, dioxins, polychlorinated biphenyls, and polybrominated
diphenyl ethers. These analyses have concluded that only metals present significant risks at the levels likely
to be found in biosolids. In response, the U.S. Environmental Protection Agency has established limits for
nine metals (40 CFR 503.13(b)). Metals concentrations in MilorganiteO are consistently far below the
applicable limits (40 CFR 503.13(b)(1)Table3).
In biosolids, pathogens may present a risk. In response, the U.S. Environmental Protection Agency has
(Contd. on page 6)

Page 619
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Reviewed on 1012612015
established pathogen limits. To destroy pathogens, Milorganite® is heated to 1760 F and dried to a moisture
content of less than 10%, which ensures compliance with the applicable limits (40 CFR 503.32(a)(7)).
Carcinogenic categories:
IARC (international Agency for Research on Cancer):
None of the ingredients are listed.
----
NTP (National Toxicology Program):
None of the ingredients are listed.
OSHA -Ca (Occupational Safety & Health Administration):
None of the ingredients are listed.
Toxicity:
Aquatic toxicity: No further relevant information available.
Persistence and degradability: No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential: No further relevant information available.
Mobility in soil: No further relevant information available.
Additional ecological information:
General notes:
Do not allow product to reach ground water, water course or sewage system.
Harmful to aquatic organisms
Results of PBT and vPvB assessment:
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects: No further relevant information available.
Waste treatment methods:
Recommendation:
Sweep, vacuum or shovel material into labeled container. If at all possible, reuse product. Material is a
fertilizer and should be used as such. Keep out of any body of water. Ensure that disposal is in compliance
with local, state or federal regulations. Bulk wetted material may generate heat upon storage.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
UN -Number:
DOT, ADR, ADN, IMDG, IATA
UN proper shipping name:
DOT, ADR, ADN, IMDG, IATA
Transport hazard class(es):
DOT, ADR, ADN, IMDG, IATA
Class:
Packing group:
DOT, ADR, IMDG, IATA
Environmental hazards:
Special precautions for user:
Non -Regulated Material
Non -Regulated Material
Non -Regulated Material
Non -Regulated Material
Not applicable.
Not applicable.
(Contd. on page 7)

Page 719
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Transport in bulk according to Annex I/ of
MARPOL73178 and the IBC Code: Not applicable.
UN "Model Regulation": Non -Regulated Material
Reviewed on 1012612015
Safety, health and environmental regulations/legislation specific for the substance or mixture:
SARA (Superfund Amendments and Reauthorization):
Section 355 (extremely hazardous substances). -
None of the ingredients are listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients are listed.
TSCA (Toxic Substances Control Act):
7705-08-0 iron trichloride
10028-22-5 diiron tris(sulphate)
471-34-1 Calcium Carbonate
7732-18-5 Water, distilled water, deionized water
California Proposition 65:
Chemicals known to cause cancer:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients are listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients are listed.
Chemicals known to cause developmental toxicity:
None of the ingredients are listed.
Carcinogenic categories:
EPA (Environmental Protection Agency):
None of the ingredients are listed.
TLV (Threshold Limit Value established by ACGIH):
None of the ingredients are listed.
-
NIOSH-Ca (National Institute for Occupational Safety and Health):
None of the ingredients are listed.
GHS label elements
The product is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms:
•
GHS07
Signal word: Warning
Hazard -determining components of labeling:
Activated Sewage Sludge (biosolids, dried microbes)
(Contd. on page 8)

Page 819
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 64-0 Fertilizer
Reviewed on 1012612015
Calcium Carbonate
Hazard statements:
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Toxic to aquatic life.
Precautionary statements:
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well -ventilated area.
Wear protective gloves.
Wear eye protection / face protection.
Avoid release to the environment.
Wash thoroughly after handling.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Specific treatment (see supplementary first aid instructions on this Safety Data Sheet).
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER/doctor if you feel unwell.
If skin irritation occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Wash with plenty of water.
Take off contaminated clothing and wash it before reuse.
Store locked up.
Store in a well -ventilated place. Keep container tightly closed.
Dispose of contents/container in accordance with local/regional/national/international regulations.
National regulations:
The product is subject to be classified according with the latest version of the regulations on hazardous
substances.
State Right to Know:
8049-99-8 Activated Sewage Sludge (biosolids, dried microbes) 100%
< Skin Irrit. 2, H315; STOT SE 3, H335; Eye Irrit. 2B, H320; Aquatic Acute 2, H401
All ingredients are listed.
Chemica! safety assessment: A Chemical Safety Assessment has not been carried out.
The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as
of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied, and shall not
establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of
this information and the suitability of the material or product for any particular purpose.
Date of preparation / last revision: 10/26/2015 18
Abbreviations and acronyms:
ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road
ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
(Contd. on page 9)

Page 919
Safety Data Sheet (SDS)
OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03.
Issue date 1012612015
Trade name: Milorganite® 6-4-0 Fertilizer
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A
Eye Irrit. 213: Serious eye damage/eye irritation, Hazard Category 2B
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
Aquatic Acute 2: Hazardous to the aquatic environment - AcuteHazard, Category 2
Reviewed on 1012612015
* Data compared to the previous version altered.
SDS created by MSDS Authoring Services www.msdsauthoring.com [phone]

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NO. 0 0

M AM nk MS6001,
PARTNERS FOR A CLEANER ENVIRONMENT
March 29, 2019
TO: Tom Nowicki
FROM: Zach Vogel
Memorandum
COPY: A. Sotomayor, S. Mertens, S. Unger, J. Spence, Lab File
SUBJECT: Milorganite TCLP Analyses to Meet Special State Requirements of North Carolina
Attached is the analytical report for the Milorganite sample collected in 2019 to meet the special
requirements of North Carolina. The sample analyses were performed by Pace Analytical Services, Inc. in
Green Bay, Wisconsin and Pace Analytical in Mt. Juliet, Tennessee.
Please contact the Central Laboratory if there are any questions or comments regarding these data.
Thank you.
Data/Report Review By:
Zach Vogel Date
Laboratory Project Manager
Milwaukee Metropolitan Sewerage District
260 West Seeboth Street, Milwaukee, WI 53204

PaceAnalj&al
www.pacela6s.com
March 27, 2019
Sharon Mertens
Milwaukee Metropolitan Sewerage
250 W. Seeboth Street
P.O. Box 3049
Milwaukee, WI 532041446
RE: Project: PACMIPP_19107
Pace Project No.: 40184019
Dear Sharon Mertens:
Pace Analytical Services, LLC
1241 Bellevue Street -Suite 9
Green Bay, WI 54302
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNUNELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Brian Basten
[e-mail]
[phone]
Project Manager
Enclosures
cc: Jessica Nanes, MMSD
Alfredo Sotomayor, MMSD
Zach Vogel, Milwaukee Metropolitan Sewerage District
Kim Walden, MMSD
&V
2 c REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
B
Page 1 of 45

aceAnalXical
—pacelaba.cam
Project: PACMIPP_19107
Pace Project No.: 40184019
Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky UST Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
New York Certification #: 12064
North Dakota Certification #: R-150
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
CERTIFICATIONS
Virginia VELAP ID: 460263
South Carolina Certification #: 83006001
Texas Certification #: T104704529-14-1
Wisconsin Certification #: 405132750
Wisconsin DATCP Certification #: 105-444
USDA Soil Permit #: P330-16-00157
Federal Fish & Wildlife Permit #: LE51774A-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 45

v ,>'
PaceAnalytical
www.pacelabs.com
Project: PACMIPP_19107
Pace Project No.: 40184019
Lab ID Sample ID
SAMPLE SUMMARY
Matrix Date Collected Date Received
40184019001 19002892/964 Solid 03/09/19 05:00 03/11/19 15:00
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 45

PaceAnalytical
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SAMPLE ANALYTE COUNT
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Analytes
Lab ID Sample ID Method Analysts Reported
40184019001 190028921964 EPA 8081
DMH
9
EPA 6010
TXW
7
EPA 7470
AJT
1
EPA 8270
RJN
17
EPA 8260
LAP
13
ASTM D2974-87
PCG
1
EPA 9045
ALY
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 45

r
/PaceAnalytical 99
www.pacelabs.com
+j
I
Project: PACMIPP_19107
Pace Project No.: 40184019
PROJECT NARRATIVE
Method: EPA 8081
Description: 8081 GCS Pesticides, TCLP
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 8081. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3510 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
QC Batch: 315787
CH: The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased high.
•19002892/964 (Lab ID:40184019001)
• Chlordane (Technical)
• Endrin
•Toxaphene
• BLANK (Lab ID: 1836921)
• Chlordane (Technical)
• Endrin
•Toxaphene
• LB (Lab ID: 1834551)
• Chlordane (Technical)
• Endrin
•Toxaphene
• LCS (Lab ID: 1836922)
• Chlordane (Technical)
• Endrin
•Toxaphene
• MS (Lab ID: 1836923)
• Chlordane (Technical)
• Endrin
•Toxaphene
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 45

aceAnaljftal
wm.pacelabs.com
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 8081
Description: 8081 GCS Pesticides, TCLP
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27. 2019
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 45

r� PmAnalX calm
www.pacelabs.com
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 6010
Description: 6010 MET ICP, TCLP
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3010 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: 315523
1q: Analyte was detected in the associated leach blank at a concentration of 0.042 mg/L.
• 19002892/964 (Lab ID: 40184019001)
• Arsenic
2q: Analyte was detected in the associated method blank at a concentration of 0.012 mg/L.
• 19002892/964 (Lab ID: 40184019001)
• Arsenic
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 7 of 45

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..pacelahs.com
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 7470
Description: 7470 Mercury, TCLP
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 7470. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7470 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 8 of 45

FaceAnalytical
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I
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 8270
Description: 8270 MSSV TCLP Sep Funnel
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 8270. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3510 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 9 of 45

7aceAnalytical
I www.pacelabs.com
I
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 8260
Description: 8260 MSV TCLP
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 8260. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Surrogates:
All surrogates were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 10 of 45

PaceAnalytical
www.pacelabs.com
PROJECT NARRATIVE
Project: PACMIPP_19107
Pace Project No.: 40184019
Method: EPA 9045
Description: 9045 pH Soil
Client: MILWAUKEE METROPOLITAN SEWERAGE DISTRICT
Date: March 27, 2019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
General Information:
1 sample was analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1­16: Analysis initiated outside of the 15 minute EPA required holding time.
• 19002892/964 (Lab ID: 40184019001)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Duplicate Sample:
All duplicate sample results were within method acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 11 of 45

PaceAnalytical
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ANALYTICAL RESULTS
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street -Suite 9
Green Bay, WI 54302
[phone]
Sample: 190028921964 Lab ID: 40184019001 Collected: 03/09/19 05:00 Received: 03/11/19 15:00 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
8081 GCS Pesticides, TCLP
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
8270 MSSV TCLP Sep Funnel
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-M ethyl phen of (o-Cresol)
3&4-Methylphenol(m&p Cresol)
Nitrobenzene
Pentachlorophenol
Phenol
Pyridine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
2,4,6-Tribromophenol (S)
Date: 03/27/2019 08:00 AM
Results Units LOQ LOD DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/13/19 12:58
<0.13
ug/L
0.42
0.13
1 03/19/19 07:30
03/21/19 01:43
58-89-9
<4.4
ug/L
14.5
4.4
1 03/19/19 07:30
03/21/19 01:43
57-74-9
CH
<0.31
ug/L
1.0
0.31
1 03/19/19 07:30
03/21/19 01:43
72-20-8
CH
<0.13
ug/L
0.44
0.13
1 03/19/19 07:30
03/21/19 01:43
76-44-8
<0.26
ug/L
0.87
0.26
1 03/19/19 07:30
03/21/19 01:43
1024-57-3
<1.6
ug/L
5.4
1.6
1 03/19/19 07:30
03/21/19 01:43
72-43-5
<30.0
ug/L
60.0
30.0
1 03/19/19 07:30
03/21/19 01:43
8001-35-2
CH
51
%
10-108
1 03/19/19 07:30
03/21/19 01:43
2051-24-3
90
%
45-112
1 03/19/19 07:30
03/21/19 01:43
877-09-8
Analytical Method: EPA 6010 Preparation Method:
EPA 3010
Leachate Method/Date: EPA 1311; 03/13/19 12:58
0.11J
mg/L
0.12
0.042
1 03/14/1914:24
03115/1911:30
7440-38-2
lq,2q
0.47
mg/L
0.075
0.025
1 03/14/1914:24
03/15/1911:30
7440-39-3
<0.0066
mg/L
0.025
0.0066
1 0311411914:24
03/15/1911:30
7440-43-9
0.10
mg/L
0.050
0.013
1 03114/1914:24
03/15/1911:30
7440-47-3
<0.030
mg/L
0.098
0.030
1 03114/1914:24
03/1511911:30
7439-92-1
<0.061
mg/L
0.25
0.061
1 03114/1914:24
03/1511911:30
7782-49-2
<0.017
mg/L
0.050
0.017
1 03/1411914:24
03/1511911:30
7440-22-4
Analytical Method: EPA 7470 Preparation
Method:
EPA 7470
Leachate Method/Date:
EPA 1311; 03/13/19 12:58
1.3
ug/L
0.56
0.17
1 03/20/19 13:15
03/21/19 09:14
7439-97-6
Analytical Method: EPA8270 Preparation
Method:
EPA3510
Leachate Method/Date:
EPA 1311; 03/13/19 12:58
<37.5
ug/L
125
37.5
1 03/14/19 08:08
03/14/19 19:34
106-46-7
<15.8
ug/L
52.8
15.8
1 03/14/19 08:08
03/14/19 19:34
121-14-2
<49.2
ug/L
164
49.2
1 03/14/19 08:08
03/14/19 19:34
87-68-3
<33.9
ug/L
113
33.9
1 03/14/19 08:08
03/14/19 19:34
118-74-1
<53.2
ug/L
177
53.2
1 03/14/19 08:08
03/14/19 19:34
67-72-1
<17.4
ug/L
57.8
17.4
1 03/14/19 08:08
03/14/19 19:34
95-48-7
<31.2
ug/L
104
31.2
1 03/14/19 08:08
03/14/19 19:34
<29.0
ug/L
96.6
29.0
1 03/14/19 08:08
03/14/19 19:34
98-95-3
<28.7
ug/L
95.6
28.7
1 03/14/19 08:08
03/14/19 19:34
87-86-5
<12.0
ug/L
40.0
12.0
1 03/14/19 08:08
03114/19 19:34
108-95-2
<35.8
ug/L
119
35.8
1 03/14/19 08:08
03114/19 19:34
110-86-1
<16.8
ug/L
56.0
16.8
1 03/14/19 08:08
03/14/19 19:34
95-95-4
<42.3
ug/L
141
42.3
1 03/14/19 08:08
03/14/19 19:34
88-06-2
86
%
51-108
1 03/14/19 08:08
03/14/19 19:34
4165-60-0
83
%
47-105
1 03/14/19 08:08
03/14/19 19:34
321-60-8
124
%
57-131
1 03/14/19 08:08
03/14/19 19:34
118-79-6
REPORT
OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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PaceAnalytical
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Project: PACMIPP_19107
Pace Project No.: 40184019
Sample: 190028921964 Lab ID: 40184019001 Collected: 03/09/19 05:00 Received: 03/11/19 15:00 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units LOQ LOD DF Prepared Analyzed CAS No. Qual
8270 MSSV TCLP Sep Funnel Analytical Method: EPA 8270 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 03/13/19 12:58
Surrogates
Phenol-d6 (S)
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Dibromofluoromethane (S)
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
Date: 03/27/2019 08:00 AM
34
%
18-120
1
03/14/19 08:08 03/14/19 19:34 13127-88-3
Analytical
Method: EPA
8260 Leachate Method/Date: EPA 1311; 03/18/19 12:24
<5.0
ug/L
10.0
5.0
10
03/19/1910:37 71-43-2
146J
ug/L
200
29.8
10
03/19/1910:37 78-93-3
<5.0
ug/L
10.0
5.0
10
03119/1910:37 56-23-5
<5.0
ug/L
10.0
5.0
10
03119/1910:37 108-90-7
<25.0
ug/L
50.0
25.0
10
0311911910:37 67-66-3
<1.7
ug/L
10.0
1.7
10
0311911910:37 107-06-2
<4.1
ug/L
10.0
4.1
10
03119/1910:37 75-35-4
<5.0
ug/L
10.0
5.0
10
03/19/1910:37 127-18-4
<3.3
ug/L
10.0
3.3
10
03119/1910:37 79-01-6
<1.8
ug/L
10.0
1.8
10
03/19/1910:37 75-01-4
103
%
70-130
10
03/19/1910:37 2037-26-5
89
%
70-130
10
03/19/1910:37 460-00-4
93
%
70-130
10
0311911910:37 1868-53-7
Analytical
Method: ASTM D2974-87
5.4
%
0.10
0.10
1
03112/1916:52
Analytical
Method: EPA 9045
6.24
Std. Units
0.100
0.0100
1
03/13/19 09:47 H6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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aceAnalyt cal
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Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315965
QC Batch Method: EPA 7470
Associated Lab Samples: 40184019001
METHOD BLANK: 1837730
Associated Lab Samples: 40184019001
Parameter Units
Mercury ug/L
METHOD BLANK: 1834549
Associated Lab Samples: 40184019001
Parameter Units
Mercury ug/L
METHOD BLANK: 1837176
Associated Lab Samples: 40184019001
Parameter Units
Mercury ug/L
QUALITY CONTROL DATA
Analysis Method: EPA 7470
Analysis Description: 7470 Mercury TCLP
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
<0.084 0.28 03/21/19 08:53
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
<0.084 0.28 03/21/19 09:11
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
<0.084 0.28 03/21/19 09:04
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
LABORATORY CONTROL SAMPLE: 1837731
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury ug/L 5 4.6 92 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1837732 1837733
MS MSD
40184156001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mercury ug/L <0.000084 5 5 5.7 5.7 115 115 85-115 0 20
mg/L
MATRIX SPIKE SAMPLE: 1837734
40184145001 Spike MS MS % Rec
Parameter Units Result Conc. Result % Rec Limits Qualifiers
Mercury ug/L <0.084 5 5.7 114 85-115
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 45

��,�ceAnalXical"
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f
Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315523
QC Batch Method: EPA 3010
Associated Lab Samples: 40184019001
METHOD BLANK: 1835473
Associated Lab Samples: 40184019001
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
METHOD BLANK: 1834545
Associated Lab Samples: 40184019001
Parameter
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
QUALITY CONTROL DATA
Analysis Method: EPA6010
Analysis Description: 6010 MET TCLP
Matrix:
Water
Blank
Reporting
Units
Result
Limit
Analyzed
mg/L
0.012J
0.025
03/15/1911:15
mg/L
<0.0050
0.015
03/15/1911:15
mg/L
<0.0013
0.0050
03/15/1911:15
mg/L
<0.0025
0.010
03/15/1911:15
mg/L
0.0066J
0.020
0311511911:15
mg/L
<0.012
0.050
03/15/1911:15
mg/L
<0.0033
0.010
03/15/1911:15
Matrix:
Solid
Blank
Reporting
Units
Result
Limit
Analyzed
mg/L
<0.042
0.12
03/15/1911:27
mg/L
<0.025
0.075
03/15/1911:27
mg/L
<0.0066
0.025
03/15/1911:27
mg/L
<0.013
0.050
03115/1911:27
mg/L
<0.030
0.098
03/1511911:27
mg/L
<0.061
0.25
03/15/1911:27
mg/L
<0.017
0.050
03/15/1911:27
METHOD BLANK: 1834546
Matrix:
Solid
Associated Lab Samples: 40184019001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
<0.0083
0.025
03115/1911:45
Barium
mg/L
<0.0050
0.015
03/15/1911:45
Cadmium
mg/L
<0.0013
0.0050
03/15/1911:45
Chromium
mg/L
<0.0025
0.010
03/15/1911:45
Lead
mg/L
<0.0059
0.020
03115/1911:45
Selenium
mg/L
0.0181
0.050
03/1511911:45
Silver
mg/L
<0.0033
0.010
03/15/1911:45
Qualifiers
Qualifiers
Qualifiers
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 45

x,
�aceAnalytical
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
1241 Bellevue Street -Suite 9
Green Bay, WI 54302
[phone]
Project: PACMIPP_19107
Pace Project No.: 40184019
METHOD BLANK: 1834547
Matrix: Solid
Associated Lab Samples: 40184019001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Arsenic
mg/L
0.042J 0.12
03115/1911:32
Barium
mg/L
<0.025 0.075
03/1511911:32
Cadmium
mg/L
<0.0066 0.025
03/15/1911:32
Chromium
mg/L
<0.013 0.050
03/15/1911:32
Lead
mg/L
<0.030 0.098
03/15/1911:32
Selenium
mg/L
0.070J 0.25
03/15/1911:32
Silver
mg1L
<0.017 0.050
03/15/1911:32
METHOD BLANK: 1834577
Matrix: Solid
Associated Lab Samples: 40184019001
Blank Reporting
Parameter
Units
Result Limit
Analyzed
Qualifiers
Arsenic
mg/L
0.021J 0.025
03/15/1911:50
Barium
mg/L
<0.0050 0.015
03/15/1911:50
Cadmium
mg/L
<0.0013 0.0050
03/1511911:50
Chromium
mg/L
<0.0025 0.010
03/15/1911:50
Lead
mg/L
<0.0059 0.020
03/15/1911:50
Selenium
mg/L
<0.012 0.050
03/15/1911:50
Silver
mg/L
<0.0033 0.010
03/15/1911:50
LABORATORY CONTROL SAMPLE: 1835474
Spike LCS
LCS %
Rec
Parameter
Units
Conc. Result
% Rec Limits
Qualifiers
Arsenic
mg/L
0.5 0.47
95
80-120
Barium
mg/L
0.5 0.49
99
80-120
Cadmium
mg/L
0.5 0.50
100
80-120
Chromium
mg/L
0.5 0.50
100
80-120
Lead
mg/L
0.5 0.49
99
80-120
Selenium
mg/L
0.5 0.52
103
80-120
Silver
mg/L
0.25 0.25
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1835475 1835476
MS MSD
40183650001
Spike Spike MS
MSD MS
MSD
% Rec Max
Parameter Units
Result
Conc. Conc. Result
Result % Rec
% Rec
Limits RPD RPD Qual
Arsenic mg/L
0.079J
2.5 2.5 2.4
2.4
92 91
75-125 1 20
Barium mg/L
0.46
2.5 2.5 2.8
2.9
95 97
75-125 2 20
Cadmium mg/L
<0.0066
2.5 2.5 2.4
2.4
98 98
75-125 0 20
Chromium mg/L
<0.013
2.5 2.5 2.4
2.5
98 100
75-125 2 20
Lead mg/L
0.18
2.5 2.5 2.5
2.6
94 96
75-125 2 20
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM
without
the written consent of Pace Analytical
Services, LLC.
Page 16 of 45

PaceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street -Suite 9
Green Bay, VVI 54302
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1835475
1835476
MS
MSD
40183650001 Spike
Spike
MS
MSD MS
MSD % Rec
Max
Parameter Units Result Cone.
Cone.
Result
Result % Rec
% Rec Limits
RPD RPD Qua]
Selenium mg/L <0.061 2.5
2.5
2.5
2.5 97
99 75-125
3 20
Silver mg/L <0.017 1.2
1.2
1.3
1.3 100
101 75-125
1 20
MATRIX SPIKE SAMPLE:
Parameter
1835477
Units
40183727002
Result
Spike
Cone.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Arsenic
mg/L
0.067J
2.5
2.4
91
75-125
Barium
mg/L
<0.025
2.5
2.5
99
75-125
Cadmium
mg/L
<0.0066
2.5
2.5
98
75-125
Chromium
mg/L
6.0
2.5
8.6
106
75-125
Lead
mg/L
0.13
2.5
2.6
97
75-125
Selenium
mg/L
<0.061
2.5
2.7
105
75-125
Silver
mg/L
<0.017
1.2
1.2
99
75-125
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 45

aceAnalXical
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QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315776 Analysis Method: EPA 8260
QC Batch Method: EPA 8260 Analysis Description: 8260 MSV TCLP
Associated Lab Samples: 40184019001
METHOD BLANK: 1836880
Associated Lab Samples: 40184019001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1-Dichloroethene
ug/L
<0.41
1.0
0311911907:18
1,2-Dichloroethane
ug/L
<0.17
1.0
03/1911907:18
2-Butanone (MEK)
ug/L
<3.0
20.0
03/19/19 07:18
Benzene
ug/L
<0.50
1.0
03/19/19 07:18
Carbon tetrachloride
ug/L
<0.50
1.0
03/19/19 07:18
Chlorobenzene
ug/L
<0.50
1.0
03/19/19 07:18
Chloroform
ug/L
<2.5
5.0
03/19/19 07:18
Tetrachloroethene
ug/L
<0.50
1.0
03119/19 07:18
Trichloroethene
ug/L
<0.33
1.0
03/19/19 07:18
Vinyl chloride
ug/L
<0.18
1.0
03/19/19 07:18
4-Bromofluorobenzene (S)
%
90
70-130
03/19/19 07:18
Dibromofluoromethane (S)
%
91
70-130
03/19/19 07:18
Toluene-d8 (S)
%
105
70-130
03/19/19 07:18
METHOD BLANK: 1836718
Associated Lab Samples: 40184019001
Parameter
Units
Matrix:
Blank
Result
Solid
Reporting
Limit
Analyzed
1,1-Dichloroethene
ug/L
<4.1
10.0
03/19/19 07:40
1,2-Dichloroethane
ug/L
<1.7
10.0
03119/1907:40
2-Butanone (MEK)
ug/L
<29.8
200
03/19/19 07:40
Benzene
ug/L
<5.0
10.0
03/19/19 07:40
Carbon tetrachloride
ug/L
<5.0
10.0
03/19/19 07:40
Chlorobenzene
ug/L
<5.0
10.0
03/19/19 07:40
Chloroform
ug/L
<25.0
50.0
03/19/19 07:40
Tetra chi oroethene
ug/L
<5.0
10.0
03/19/19 07:40
Trichloroethene
ug/L
<3.3
10.0
03/19/19 07:40
Vinyl chloride
ug/L
<1.8
10.0
03/19/19 07:40
4-Bromofluorobenzene (S)
%
91
70-130
03/19/19 07:40
Dibromofluoromethane (S)
%
92
70-130
03/19/19 07:40
Toluene-d8 (S)
%
102
70-130
03/19/19 07:40
LABORATORY CONTROL SAMPLE: 1836881
Qualifiers
Qualifiers
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,1-Dichloroethene ug/L 50 44.6 89 75-132
1,2-Dichloroethane ug/L 50 55.9 112 73-134
Benzene ug/L 50 56.2 112 69-137
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 18 of 45

V �
AaceAnalytical
wwwpacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Project: PACMIPP_19107
Pace Project No.: 40184019
LABORATORY CONTROL SAMPLE: 1836881
Parameter Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Qualifiers
Carbon tetrachloride
ug/L
50
55.8
112
73-142
Chlorobenzene
ug/L
50
55.0
110
70-130
Chloroform
ug/L
50
48.0
96
80-129
Tetrachloroethene
ug/L
50
52.1
104
70-130
Trichloroethene
ug/L
50
53.8
108
70-130
Vinyl chloride
ug/L
50
37.5
75
48-134
4-Bromofluorobenzene (S)
%
102
70-130
Dibromofluoromethane (S)
%
95
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1836896
1836897
MS
MSD
40184034001
Spike
Spike
MS
MSD
MS MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec % Rec
Limits
RPD
RPD Qual
1,1-Dichloroethene
ug/L
<0.0041
500
500
439
449
88
90
72-137
2
20
mg/L
1,2-Dichloroethane
ug/L
<0.0017
500
500
558
573
112
115
71-137
3
20
mg/L
Benzene
ug/L
<0.0050
500
500
567
574
113
115
66-143
1
20
mg/L
Carbon tetrachloride
ug/L
<0.0050
500
500
567
561
113
112
73-142
1
20
mg/L
Chlorobenzene
ug/L
<0.0050
500
500
555
551
111
110
70-130
1
20
mg/L
Chloroform
ug/L
<0.025
500
500
487
488
97
97
80-131
0
20
mg/L
Tetrachloroethene
ug/L
<0.0050
500
500
520
516
104
103
70-132
1
20
mg/L
Trichloroethene
ug/L
<0.0033
500
500
542
546
108
109
70-131
1
20
mg/L
Vinyl chloride
ug/L
<0.0018
500
500
357
370
71
74
46-134
4
20
mg/L
4-Bromofluorobenzene (S)
%
103
101
70-130
Dibromofluoromethane (S)
%
95
94
70-130
Toluene-d8 (S)
%
102
101
70-130
MATRIX SPIKE SAMPLE:
1836898
40184145001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1-Dichloroethene
ug/L
<4.1
500
442
88
72-137
1,2-Dichloroethane
ug/L
<1.7
500
565
113
71-137
Benzene
ug/L
<5.0
500
571
114
66-143
Carbon tetrachloride
ug/L
<5.0
500
576
115
73-142
Chlorobenzene
ug/L
<5.0
500
566
113
70-130
Chloroform
ug/L
<25.0
500
461
92
80-131
Tetrachloroethene
ug/L
<5.0
500
531
106
70-132
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 19 of 45

f
PaceAnalXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, VIA 54302
[phone]
Project: PACMIPP_19107
Pace Project No.: 40184019
MATRIX SPIKE SAMPLE:
1836898
40184145001 Spike
MS MS
% Rec
Parameter
Units
Result Conc.
Result % Rec
Limits Qualifiers
Trichloroethene
ug/L
<3.3 500
545 109
70-131
Vinyl chloride
ug/L
<1.8 500
362 72
46-134
4-Bromofluorobenzene (S)
%
104
70-130
Dibromofluoromethane (S)
%
94
70-130
Toluene-d8 (S)
%
103
70-130
Results presented on this page are In the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 20 of 45

PaceAnalXical
www.pacel8bs.com
1
QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315787 Analysis Method: EPA 8081
QC Batch Method: EPA 3510 Analysis Description: 8081 GCS TCLP Pesticides
Associated Lab Samples: 40184019001
METHOD BLANK: 1836921
Associated Lab Samples: 40184019001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
Qualifiers
Chlordane (Technical)
ug/L
<0.44
1.5
03/20/19 21:13
CH
Endrin
ug/L
<0.031
0.10
03/20/19 21:13
CH
gamma-BHC (Lindane)
ug/L
<0.013
0.042
03/20/19 21:13
Heptachlor
ug/L
<0.013
0.044
03/20/19 21:13
Heptachlor epoxide
ug/L
<0.026
0.087
03/20/19 21:13
Methoxychlor
ug/L
<0.16
0.54
03/20/19 21:13
Toxaphene
ug/L
<3.0
6.0
03/20/19 21:13
CH
Decachlorobiphenyl (S)
%
74
10-108
03/20/19 21:13
Tetrachloro-m-xylene (S)
%
91
45-112
03/20/19 21:13
METHOD BLANK: 1834551
Matrix:
Water
Associated Lab Samples: 40184019001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
Chlordane (Technical)
ug/L
<2.2
7.3
03/21/19 01:25
CH
Endrin
ug/L
<0.16
0.52
03/21/19 01:25
CH
gamma-BHC (Lindane)
ug/L
<0.063
0.21
03/21/19 01:25
Heptachlor
ug/L
<0.065
0.22
03/21/19 01:25
Heptachlor epoxide
ug/L
<0.13
0.43
03/21/19 01:25
Methoxychlor
ug/L
<0.81
2.7
03/21/19 01:25
Toxaphene
ug/L
<15.0
30.0
03/21/19 01:25
CH
Decachlorobiphenyl (S)
%
95
10-108
03/21/19 01:25
Tetrachloro-m-xylene (S)
%
96
45-112
03/21/19 01:25
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, VVI 54302
[phone]
LABORATORY CONTROL SAMPLE:
Parameter
1836922
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Chlordane (Technical)
ug/L
<0.44
CH
Endrin
ug/L
0.8
0.88
111
72-125 CH
gamma-BHC (Lindane)
ug/L
0.4
0.46
115
79-119
Heptachlor
ug/L
0.4
0.42
105
69-122
Heptachlor epoxide
ug/L
0.4
0.45
113
76-118
Methoxychlor
ug/L
4
4.9
122
73-130
Toxaphene
ug/L
<3.0
CH
Decachlorobiphenyl (S)
%
83
10-108
Tetrachloro-m-xylene (S)
%
96
45-112
Results presented on this page are in the units indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 21 of 45

7acieAnaij6dal"
www.pacelabs.com
f
QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 64302
[phone]
MATRIX SPIKE SAMPLE:
Parameter
1836923
Units
40184019001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Chlordane (Technical)
ug/L
<4.4
<4.4
CH
Endrin
ug/L
<0.31
8
9.5
119
72-125 CH
gamma-BHC (Lindane)
ug/L
<0.13
4
4.3
108
79-119
Heptachlor
ug/L
<0.13
4
3.8
96
69-122
Heptachlor epoxide
ug/L
<0.26
4
3.8
96
76-118
Methoxychlor
ug/L
<1.6
40
48.4
121
73-130
Toxaphene
ug/L
<30.0
<30.0
CH
Decachlorobiphenyl (S)
%
38
10-108
Tetrachloro-m-xylene (S)
%
87
45-112
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 22 of 45

/�PiceAnalytical
f
mvwpacelabs.com
QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315450
Analysis Method: EPA 8270
QC Batch Method: EPA3510
Analysis Description: 8270TCLP
MSSV
Associated Lab Samples: 40184019001
METHOD BLANK: 1835264
Matrix: Water
Associated Lab Samples: 40184019001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dichlorobenzene
ug/L
<3.8
12.5
03114/1912:56
2,4,5-Trichlorophenol
ug/L
<1.7
5.6
03/14/19 12:56
2,4,6-Trichlorophenol
ug/L
<4.2
14.1
03/14/19 12:56
2,4-Dinitrotoluene
ug/L
<1.6
5.3
03114/1912:56
2-Methylphenol(o-Cresol)
ug/L
<1.7
5.8
03/1411912:56
3&4-Methylphenol(m&p Cresol)
ug/L
<3.1
10.4
03/14/19 12:56
Hexachloro-1,3-butadiene
ug/L
<4.9
16.4
03114/1912:56
Hexachlorobenzene
ug/L
<3.4
11.3
03/14/19 12:56
Hexachloroethane
ug/L
<5.3
17.7
03114/1912:56
Nitrobenzene
ug/L
<2.9
9.7
03/14/19 12:56
Pentachlorophenol
ug/L
<2.9
9.6
03/14/19 12:56
Phenol
ug/L
<1.2
4.0
03/14/19 12:56
Pyridine
ug/L
<3.6
11.9
03/14/19 12:56
2,4,6-Tribromophenol (S)
%
106
57-131
03/14/19 12:56
2-Fluorobiphenyl (S)
%
68
47-105
03/14/19 12:56
Nitrobenzene-d5 (S)
%
68
51-108
03/14/19 12:56
Phenol-d6 (S)
%
31
18-120
03/14/19 12:56
METHOD BLANK: 1834548
Matrix: Water
Associated Lab Samples: 40184019001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dichlorobe nzene
ug/L
<18.8
62.5
03/14/19 20:18
2,4,5-Trichlorophenol
ug/L
<8.4
28.0
03/14/19 20:18
2,4,6-Trichlorophenol
ug/L
<21.1
70.4
03/14/19 20:18
2,4-Dinitrotoluene
ug/L
<7.9
26.4
03/14/19 20:18
2-Methylphenol(o-Cresol)
ug/L
<8.7
28.9
03/14/19 20:18
3&4-Methylphenol(m&p Cresol)
ug/L
<15.6
52.0
03/14/19 20:18
Hexachloro-1,3-butadiene
ug/L
<24.6
82.0
03/14/19 20:18
Hexachlorobenzene
ug/L
<16.9
56.4
03/14/19 20:18
Hexachloroethane
ug/L
<26.6
88.6
03/14/19 20:18
Nitrobenzene
ug/L
<14.5
48.3
03/14/19 20:18
Pentachlorophenol
ug/L
<14.3
47.8
03/14/19 20:18
Phenol
ug/L
<6.0
20.0
03/14/19 20:18
Pyridine
ug/L
<17.9
59.6
03/14/19 20:18
2,4,6-Tribromophenol (S)
%
116
57-131
03/14/19 20:18
2-Fluorobiphenyl (S)
%
79
47-105
03/14/19 20:18
Nitrobenzene-d5 (S)
%
85
51-108
03/14/19 20:18
Phenol-d6 (S)
%
31
18-120
03/14/19 20:18
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 45

- .aceAnalXical
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QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
METHOD BLANK: 1834747
Matrix:
Water
Associated Lab Samples: 40184019001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
<18.8
62.5
03114/1920:40
2,4,5-Trichlorophenol
ug/L
<8.4
28.0
03/14/19 20:40
2,4,6-Trichlorophenol
ug/L
<21.1
70.4
03/14/19 20:40
2,4-Dinitrotoluene
ug/L
<7.9
26.4
03/14/19 20:40
2-Methylphenol(o-Cresol)
ug/L
<8.7
28.9
03/14/19 20:40
3&4-Methylphenol(m&p Cresol)
ug/L
<15.6
52.0
03/14/19 20:40
Hexachloro-1,3-butadiene
ug/L
<24.6
82.0
03/14/19 20:40
Hexachlorobenzene
ug/L
<16.9
56.4
03/14/19 20:40
Hexachloroethane
ug/L
<26.6
88.6
03/14/19 20:40
Nitrobenzene
ug/L
<14.5
48.3
03/14/19 20:40
Pentachlorophenol
ug/L
<14.3
47.8
03114/19 20:40
Phenol
ug/L
<6.0
20.0
03/14/19 20:40
Pyridine
ug/L
<17.9
59.6
03/14/19 20:40
2,4,6-Tribromophenol (S)
%
116
57-131
03/14/19 20:40
2-Fluorobiphenyl (S)
%
82
47-105
03/14/19 20:40
Nitrobenzene-d5 (S)
%
89
51-108
03/14/19 20:40
Phenol-d6 (S)
%
29
18-120
03/14/19 20:40
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
1835265
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
50
37.6
75
57-120
2,4,5-Trichlorophenol
ug/L
50
42.5
85
59-124
2,4,6-Trichlorophenol
ug/L
50
42.1
84
64-125
2,4-Dinitrotoluene
ug/L
50
50.7
101
70-132
2-Methylphenol(o-Cresol)
ug/L
50
39.8
80
45-107
3&4-Methylphenol(m&p Cresol)
ug/L
50
34.9
70
39-130
Hexachloro-1,3-butadiene
ug/L
50
43.5
87
63-107
Hexachlorobenzene
ug/L
50
54.5
109
70-124
Hexachloroethane
ug/L
50
32.8
66
50-130
Nitrobenzene
ug/L
50
42.6
85
70-130
Pentachlorophenol
ug/L
50
42.9
86
61-113
Phenol
ug/L
50
17.4
35
25-120
Pyridine
ug/L
50
24.0
48
10-78
2,4,6-Tribromophenol (S)
%
115
57-131
2-Fluorobiphenyl (S)
%
73
47-105
Nitrobenzene-d5 (S)
%
85
51-108
Phenol-d6 (S)
%
32
18-120
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, W 54302
[phone]
Qualifiers
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 24 of 45

aceAnalyiical
www.pacelabs.com
QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
MATRIX SPIKE SAMPLE:
Parameter
1835266
Units
40183991002
Result
Spike
Cone.
MS
Result
MS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
<18.8
250
195
78
55-120
2,4,5-Trichlorophenol
ug/L
<8.4
250
240
96
26-124
2,4,6-Trichlorophenol
ug/L
<21.1
250
248
99
29-125
2,4-Dinitrotoluene
ug/L
<7.9
250
250
100
32-143
2-Methylphenol(o-Cresol)
ug/L
<8.7
250
205
82
25-107
3&4-Methylphenol(m&p Cresol)
ug/L
<15.6
250
175
70
21-130
Hexachloro-1,3-butadiene
ug/L
<24.6
250
215
86
63-109
Hexachlorobenzene
ug/L
<16.9
250
268
107
57-124
Hexachloroethane
ug/L
<26.6
250
174
70
50-130
Nitrobenzene
ug/L
<14.5
250
227
91
23-147
Pentachlorophenol
ug/L
<14.3
250
233
93
10-200
Phenol
ug/L
<6.0
250
94.5
37
20-120
Pyridine
ug/L
<17.9
250
103
41
10-78
2,4,6-Tribromophenol (S)
%
114
57-131
2-Fluorobiphenyl (S)
%
79
47-105
Nitrobenzene-d5 (S)
%
85
51-108
Phenol-d6 (S)
%
34
18-120
MATRIX SPIKE SAMPLE:
Parameter
1835267
Units
40183991007
Result
Spike
Cone.
MS
Result
MS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
<18.8
250
193
77
55-120
2,4,5-Trichlorophenol
ug/L
<8.4
250
228
91
26-124
2,4,6-Trichlorophenol
ug/L
<21.1
250
240
96
29-125
2,4-Dinitrotoluene
ug/L
<7.9
250
256
102
32-143
2-Methylphenol(o-Cresol)
ug/L
<8.7
250
206
82
25-107
3&4-Methylphenol(m&p Cresol)
ug/L
<15.6
250
184
74
21-130
Hexachloro-1,3-butadiene
ug/L
<24.6
250
218
87
63-109
Hexachlorobenzene
ug/L
<16.9
250
259
104
57-124
Hexachloroethane
ug/L
<26.6
250
178
71
50-130
Nitrobenzene
ug/L
<14.5
250
189
76
23-147
Pentachlorophenol
ug/L
<14.3
250
228
91
10-200
Phenol
ug/L
<6.0
250
90.6
35
20-120
Pyridine
ug/L
<17.9
250
146
59
10-78
2,4,6-Tribromophenol (S)
%
116
57-131
2-Fluorobiphenyl (S)
%
83
47-105
Nitrobenzene-d5 (S)
%
80
51-108
Phenol-d6 (S)
%
34
18-120
MATRIX SPIKE SAMPLE: 1835268
Qualifiers
Qualifiers
40184034001 Spike MS MS % Rec
Parameter Units Result Cone. Result % Rec Limits Qualifiers
1,4-Dichlorobenzene ug/L <0.019 mg/L 250 202 81 55-120
2,4,5-Trichlorophenol ug/L <0.0084 mg/L 250 246 98 26-124
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC.
Page 25 of 45

ID
I
PaceAnalXical
www.pacelabs.com
Project: PACMIPP_19107
Pace Project No.: 40184019
MATRIX SPIKE SAMPLE:
Parameter
2,4,6-Tri chlorophenol
2,4-Dinitrotoluene
2-Methylphenol(o-Cresol)
3&4-Methylphenol(m&p Cresol)
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
Nitrobenzene
Pentachlorophenol
Phenol
Pyridine
2,4,6-Tribromophenol (S)
2-Fluorobiphenyl (S)
Nitrobenzene-d5 (S)
Phenol-d6 (S)
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
QUALITY CONTROL DATA
1835268
Units
40184034001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
ug/L
<0.021 mg/L
250
250
100
29-125
ug/L
<0.0079 mg/L
250
253
101
32-143
ug/L
<0.0087 mg/L
250
219
88
25-107
ug/L
<0.016 mg/L
250
192
77
21-130
ug/L
<0.025 mg/L
250
221
89
63-109
ug/L
<0.017 mg/L
250
264
105
57-124
ug/L
<0.027 mg/L
250
187
75
50-130
ug/L
<0.015 mg/L
250
224
89
23-147
ug/L
<0.014 mg/L
250
214
86
10-200
ug/L
<6.0
250
82.8
33
20-120
ug/L
<0.018 mg/L
250
95.9
38
10-78
%
115
57-131
%
87
47-105
%
92
51-108
%
33
18-120
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 45

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QUALITY CONTROL DATA
Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315332 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 40184019001
Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
Green Bay, WI 54302
[phone]
SAMPLE DUPLICATE: 1834528
40184019001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Percent Moisture % 5.4 5.5 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 45

PaceAnalytical
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Project: PACMIPP_19107
Pace Project No.: 40184019
QC Batch: 315361
QC Batch Method: EPA 9045
Associated Lab Samples: 40184019001
SAMPLE DUPLICATE: 1834624
Parameter Units
pH at 25 Degrees C Std. Units
Pace Analytical Services, LLC
1241 Bellevue Street- Suite 9
Green Bay, WI 54302
[phone]
QUALITY CONTROL DATA
Analysis Method: EPA 9045
Analysis Description: 9045 pH
40184033002 Dup Max
Result Result RPD RPD Qualifiers
8.28 8.24 0 5 H6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 45

Pace Analytical Services, LLC
1241 Bellevue Street - Suite 9
PaceAnalX cal ® Green Bay, W 54302
www.pacelabs.com [phone]
QUALIFIERS
Project: PACMIPP_19107
Pace Project No.: 40184019
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above LOD.
J - Estimated concentration at or above the LOD and below the LOQ.
LOD - Limit of Detection adjusted for dilution factor, percent moisture, initial weight and final volume.
LOQ - Limit of Quantitation adjusted for dilution factor, percent moisture, initial weight and final volume.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected at or above the adjusted LOD.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
1q Analyte was detected in the associated leach blank at a concentration of 0.042 mg/L.
2q Analyte was detected in the associated method blank at a concentration of 0.012 mg/L.
CH The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The results may be biased
high.
H6 Analysis initiated outside of the 15 minute EPA required holding time.
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2019 08:00 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 45

aceAnalytica!
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: PACMIPP_19107
Pace Project No.: 40184019
Pace Analytical Services, LLC
1241 Bellevue Street -Suite 9
Green Bay, WI 54302
[phone]
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
40184019001
190028921964
EPA 3510
315787
EPA 8081
40184019001
19002892/964
EPA 3010
315523
EPA 6010
40184019001
190028921964
EPA 7470
315965
EPA 7470
40184019001
190028921964
EPA 3510
315450
EPA 8270
40184019001
19002892/964
EPA 8260
315776
40184019001
19002892/964
ASTM D2974-87
315332
40184019001
19002892/964
EPA 9045
315361
Date: 03/27/2019 08:00 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
315866
315639
316024
315528
Page 30 of 45

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1 of 45

yolfq o / 9
Milwaukee Metropolitan
Contract Lab Request Report
Sewerage District
Pace -gig
Date samples sent:
3/11/19
Filename: PACmipp_19107.mdb
Original Sample
19002892
19002892 964 319119
34
1208
TCLP 6010 Metals (Milo)
SW846: 6010
19002892 964 3l9/19
36
1211
TCLP Pesticides by m.8081 (Milo)
SW846: 8081 G
19002892 964 3/9/19
37
1212
TCLP Herbicides by m.8151 (Milo)
SW846: 8151 0
19002892
964
3/9/19
33
1170
Mercury, TCLP
SW846:.7470
19002892
964
3/9119
35
1178
Final pH (2:1 vol/wt), TCLP
EPA 150.1
(J
19002892
964
3/9119
40
1192"
' Solids for dry weight determination (Pace)
ASTM D2974-87
0
19002892
964
3/9/19
49
1137
chlordane, TCLP
SW846: 8081
❑
19002892
964
3/9119
50
1138
endrin, TCLP
SW846: 8081
19002892
964
319/19
51
1139
g-BHC, TCLP
SW846: 8081
11
19002892
964
319/19
52
1140
heptachlor epoxide, TCLP
SW846: 8081
❑
19002892
964
3/9/19
53
1141
heptachlor, TCLP
SW846: 8081
El
19002892
964
3/9/19
54
1142
Methoxychlor, TCLP
SW846: 8081
19002892
964
3/9/19
55
1143
toxaphene, TCLP
SW846: 8081
19002892
964
319/19
56
1144
2,4,5-TP, TCLP
SW846: 8260
19002892
964
3/9119
57
1145
2,4-D, TCLP
SW846: 8260
19002892
964
3/9119
58
1146
1,1-dichloroethylene, TCLP
SW846: 8260
it
19002892
964
3/9119
59
1147
1,2-dichloroethane, TCLP
SW846: 8260
11
19002892
964
3/9/19
60
1148
1,4-dichlorobenzene, TCLP
SW846: 8260
❑
19002892
964
3/9/19
61
1149
benzene, TCLP
SW846: 8260
❑
19002892
964
3/9119
62
1150
Carbon Tetrachloride, TCLP
SW846: 8260
El
19002892
964
3/9/19
63
1151
Chlorobenzene, TCLP
SW846: 8260
El
19002892
964
3/9/19
64
1152
Chloroform, TCLP
SW846: 8260
19002892
964
3/9/19
65
1153
Methyl Ethyl Ketone, TCLP
SW846: 8260
19002892
964
319/19
66
1154
tetrachloroethylene, TCLP
SW846: 8260
19002892
964
319119
67
1155
trichloroethylene, TCLP
SW846: 8260
19002892
964
3/9119
68
1156
Vinyl Chloride, TCLP
SW846: 8260
19002892
964
3/9/19
69
1157
2,4,5-Trichlorophenol, TCLP
SW846: 8270
19002892
964
3/9/19
70
1158
2,4,6-Trichlorophenol, TCLP
SW846: 8270
19002892
964
3/9119
71
1159
2,4-Dinitrotoluene, TCLP
SW846: 8270
❑
19002892
964
319/19
72
1160
hexachlorobenzene, TCLP
SW846: 8270
19002892
964
3/9/19
73
1161
hexachlorobutadiene, TCLP
SW846: 8270
19002892
964
3/9/19
74
1162
hexachloroethane, TCLP
SW846: 8270
El
19002892
964
3/9/19
75
1163
m & p-Cresol, TCLP (3 & 4-Methylphenol)
SW846: 8270
19002892
964
319/19
76
1164
nitrobenzene, TCLP
SW846: 8270
(�
Page 1 or 2
GUIrptContractLab 6/8/17 t/ Printed.' V27/19 09:51
Page 32 of 45

Milwaukee Metropolitan
Sewerage District
Date samples sent: 3111/19 Filename: PACmipp_19107.mdb
Volsq019
Contract Lab Request Report
Pace -GB
Original Sample
19002892
F
19002892
964
3/9/19
3/9119
77
78
1165
1166
MCI
o-Cresol, TCLP (2-Methylphenol)
pentachlorophenol, TCLP
SW846: 8270
SW846: 8270
El
19002892
964
964
964
19002892
19002892
319/19
319/19
79
80
1167
1168
phenol, TCLP
Pyridine, TCLP
Total Cresol, TCLP
Arsenic, TCLP
Barium, TCLP
Cadmium, TCLP
Chromium, TCLP
SW846: 8270
SW846: 8270
El
19002811
92
19002892
19002892
19002892
19002892
19002892
964
964
964
964
964
3/9/19
3/9/19
3/9/19
3/9/19
3/9/19
81
82
83
84
85
1169
1171
1172
1173
1174
SW846: 8270
SW846: 6010
SW846: 6010
11
SW846: 6010
SW846: 6010
El
964 3/9/19 86 1175 Lead, TCLP
19002892 964 3/9/19 87 1176 Selenium, TCLP
19002892 964 319119 88 1177 Silver, TCLP
SW846: 6010
SW846: 6010
SW846: 6010
C
^I^
Ll
NOTE: A check mark in the Group field indicates that this item is the billable test name. This item will appear in the electronic data file, but does
not need data recorded. MMSD LIMS must identify that this test has been completed on upload. The associated analytes for the group will not
have a check mark, but will have the same method.
GU/fpfConfraciLab W17 tj Page 2 of 2
Printed''7Vage r33 of 45

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Document Name:
aCeAnalytical'" Sample Condition Upon Receipt (SOUR) Document Revised: 25Apr201E
I Document No.: Issuing Authority:
1241 Bellevue Street, Green Bay WI 54302 F-GB-C-031-Rev.07 Pace Green Bay Quality Office
Sample Condition Upon Receipt Form (SCUR)
Client Name: MWp Project #' ` W a # : 4018401 g
Courier: r CS Logistics j7 Fed Ex f— Speedee r: UPS Imo- Waltco
r Client )Pace Other:
Tracking #: 40184019
Custody Seal on Cooler/Box Present: 0< yes r.. no Seals intact: V yes r no f
Custody Seal on Samples Present: r yes V no Seals intact: r yes r no
Packing Material: j""`' Bubble Wrap Bubble Bags r` None r Other
Thermometer Used SR - Type of Ice: Eet Blue Dry None Samples on ice, cooling process has begun
Cooler Temperature Uncorr: YjA/Corr:
Temp Blank Present: r yes [)(no Biological Tissue is Frozen: r yesr" no
Temp should be above freezing to 6°C.
Biota Samples may be received at :5 0°C.
Ch VYes ❑No ❑NIA 1,
Chain of Custody Filled Out: Dyes D& ❑N/A 2, '
Chain of Custody Relinquished: eyes ❑No ❑N/A 3,
ampler Named natq- n COC: Dyes *o ❑N/A 4.
Samples Arrived within Hold Time: Yes ❑No 5.
- VOA Samples frozen upon receipt Dyes ❑No Datefrime:
Short Hold Time Analysis (<72hr): Dyes IVNo 6,
Rush Turn Around Time Requested: Dyes KNo 7,
Sufficient Volume: $
For Analysis: es ❑No MS/MSD: Dyes qNo ❑NIA
Correct Containers Used: ZYes ❑No g.
-Pace Containers Used: Dyes ON- ❑NIA
-Pace IR Containers Used: Dyes LNNo ❑N/A
Containers Intact: LlYes ❑No 10.
Filtered volume received for Dissolved tests Dyes QONo ❑N/A 11.
Sample Labels match COC: IXIYes ❑No ❑N/A 12. M it Y1/L11, fA - i -31 It it
-Includes date/time/ID/Analysis Matrix:
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
Client Notification/ Resolution:
Person Contacted:
Comments/ Resolution: lr4_4_._
Dyes ❑No bN/A 13.
Dyes ❑No �INlA
Person Tit
ing contents:
Date: (t
Initials:
All t
If checked, see attached form for additional comments
Date/Time:
FA
Project Manager Review: Date: H/ /,
Page L P8?'& of 45

aceAnal Ica/ ® ANALYTICAL REPORT
National Center for Testing & Innovation March 26, 2019
r
Pace Analytical - Green Bay, WI
Sample Delivery Group: L1080230
Samples Received: 03/19/2019
Project Number: 40184019
Description: PACMIPP_19107
Report To: Brian Basten
1241 Bellvue Street, Suite 9
Green Bay, WI 54302
Entire Report Reviewed By:
Nancy McLain
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National
is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.
... 'Aft.:* ��

TABLE OF CONTENTS ONE LAB. NATIONWIDE.
Cp: Coven Page
1
,Cp
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
r qS
19002892/964 L1080230-01
5
Qc: Quality Control Summary
6
Rn
Chlorinated Acid Herbicides (GC) by Method 8151A
6
Isr
GI: Glossary of Terms
7
Al: Accreditations & Locations
8
R
Sc: Sample Chain of Custody
9
GI
1711
FC
Page 37 of 45
ACCOUNT: PROJECT: SDG: DATEMME: PAGE:
Pace Analytical - Green Bay, WI 40184019 L1080230 03/26/1912:05 2 of 10

SAMPLE SUMMARY ONE LAB. NATIONWIDE.
Collected by Collected date/time Received date/time
19002892/964 L1080230-01 Waste 03/09/1905:00 03/19/1908:30
Method
Batch
Dilution Preparation
Analysis Analyst
date/time
date/time
Preparation by Method 1311
WG1253413
1 03/21/1914:51
03/21/1914:51 CGD
Chlorinated Acid Herbicides (GC) by Method 8151A
WG1254854
1 03/25/19 07:03
03/25/19 20:44 MTJ
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Pace Analytical - Green Bay, WI
40184019
L1080230
03/26/1912:05
Location
Mt. Juliet, TN
Mt. Juliet, TN
Page 38 of 45
PAGE:
3 of10

CASE NARRATIVE ONE LAB. NATIONWIDE.
All sample aliquots were received at the correct temperature, in the proper containers, with the
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Nancy McLain
Project Manager
Page 39 of 45
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
Pace Analytical - Green Bay, WI 40184019 L1080230 03/2611912:05 4 of 10

19002892/964 SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE.
Collected date/time: 03/09/19 05:00 L1080230
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
- 3/21/2019 2:51:13 PM
WG1253413
Fluid
1 3/21/2019 2.51:13 PM
WG1253413
Initial pH
6.36 3/21/2019 2:51.13 PM
WG1253413
Final pH
5.29 3/21/2019 2:51:13 PM
WG1253413
Chlorinated Acid
Herbicides (GC) by Method 8151A
Result
Qualifier RDL Limit
Dilution Analysis
Batch
Analyte mg/I
mg/l mg/I
date / time
2,4,5-TP (Silvex) ND
0.00200 1
1 03/25/2019 20:44
WG1254854
2,4-D ND
0.00200 10
1 03/25/2019 20:44
WG1254854
(S)2,4-DichloiophenylAceticAcid 121
14.0-158
031251201920.44
WG1254854
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
Pace Analytical -Green Bay, WI
40184019
L1080230
03/26/1912:05
Page 40 of 45
PAGE:
5of10

WG1254854 QUALITY CONTROL SUMMARY
Chlorinated Acid Herbicides (GC) by Method 8151A L1090230-01
Method Blank (PAB)
(MB) R3395113-1 03/25/19 16:58
MB Result
Analyte mgA
2,4-D U
2,4,5-TP (Silvex) U
(5)2,4-Dichloropheny/Acetic 56.6
Acid
MB Qualifier M8 MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3395113-2 03/25/1917:13
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mgA
mgA
%
%
2,4-D 0.0500
0.0390
78.0
50.0-120
2,4,5-TP (Sllvex) 0.0500
0.0421
84.2
50.0-125
(5) 2,4-0ichlorophenyl Acetic
74.2
14.0-158
Acid
L1079918-01 Original Sample (OS) • Matrix Spike (i`AS) • Matrix Spike Duplicate (MSD
(OS) L1079918-01 03/25/19 17:27 • (MS) R3395113-3 03/25/19 17.41 • (MSD) R3395113-4 03/2511917:55
Spike Amount
Original Result MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mgA
mgA mgll
mg/I
%
%
A
2,4-D
0,0500
ND 0.0395
0.0387
790
77.4
1 50.0-120
2.4.5-TP (Silvex)
0,0500
ND 0.0425
0.0419
85.0
83.8
1 50.0-125
(5)24-DichlorophenyAcetic
Acid
730
75.6
14.0-158
ACCOUNT: PROJECT: SDG:
Pace Analytical- Green Bay, WI 40184019 L1080230
ONE LAB NATIONWIDE #
MS Qualifier MSD Qualifier RPD RPD Limits
2.05 20
142 20
Page 41 of 45
DATE/TIME' PAGE:
03126/1912:05 6 of 10

GLOSSARY OF TERMS ONE LAB. NATIONWIDE.
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Abbreviations and Definitions
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
RDL
Reported Detection Limit.
Rec.
Recovery.
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
The remainder of this page intentionally left blank, there are no qualifiers applied to this SDG
Page 42 of 45
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Pace Analytical - Green Bay, WI 40184019 L1080230 03/26/1912:05 7 of 10

ACCREDITATIONS & LOCATIONS ONE LAB, NATIONWIDE.
Pace National is the only environmental laboratory accredftedkertified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as
accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals ofthe network
laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing
turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE.
*Not all certifications held by the laboratory are applicable to the results reported in the attached report.
*Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National.
State Accreditations
Alabama 40660 Nebraska NE-OS-15-05
Alaska 17-026 Nevada TN-03-2002-34
Arizona AZ0612 New Hampshire 2975
Arkansas 88-0469 New Jersey—NELAP TNO02
California 2932 New Mexico' n/a
Colorado TN00003 New York 11742
Connecticut PH-0197 North Carolina Env375
Florida E87487 North CarolinaDW21704
Georgia NELAP North Carolina' 41
Georgia' 923 North Dakota R-140
Idaho TN00003 Ohio—VAP CL0069
Illinois 200008 Oklahoma 9915
Indiana C-TN-01 Oregon TN200002
Iowa 364 Pennsylvania 68-02979
Kansas E-10277 Rhode Island LA000356
Kentucky' 6 90010 South Carolina 84004
Kentucky' 16 South Dakota n/a
Louisiana A130792 Tennessee' ° 2006
Louisiana' LA180010 Texas T104704245-18-15
Maine TN0002 Texas' LA80152
Maryland 324 Utah TN00003
Massachusetts M-TNO03 Vermont VT2006
Michigan 9958 Virginia 460132
Minnesota 047-999-395 Washington C847
Mississippi TN00003 West Virginia 233
Missouri 340 Wisconsin 9980939910
Montana CERT0086 Wyoming A2LA
Third Party Federal Accrec!itations
A2LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789
A2LA — ISO 17025' 1461.02 DOD 1461.01
Canada 1461.01 USDA P330-15-00234
EPA—Crypto TN00003
' Drinking Water z Underground Storage Tanks ' Aquatic Toxicity ° Chemical/Microbiological ' Mold 6 Wastewater n/a Accreditation not applicable
Our Locations
Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of oursupport offices, please contact
our main office. Pace National performs all testing at our central laboratory.
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Page 43 of 45
ACCOUNT: PROJECT: S DG: DATE/TIM E: PAGE:
Pace Analytical - Green Bay, WI 40184019 L1080230 03/26/1912:05 8 of 1O

Chain of Custody
Workorder; 40184019
Workorder Name: PACMIPP_1910-1
z part i invoice 70 --
I -Subcontract To
— — _
Can Basler,
PO
Pace Analytical Green Bay
-�
Pace National
1241 Bellevus Street
Suite 9
I
i Green Bay VGA 54302
Phone [phone]
Erna+1: [e-mail]
state of sample Origin:
N1 LO©ILOQ
pr
Collect
Se-m Sample ID
4aterllme
Lab ID
,Matrix
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Page 44 of 45

Page 45 of 45

" 1'Il' 1' rn I 1
PARTNERS FOR A CLEANER ENVIRONMENT
April 24, 2019
TO: Tom Nowicki
FROM: Zach Vogel
COPY: S. Unger, J. Spence, E. Stroik, S. Mertens, A. Sotomayor, Lab File
SUBJECT: Milorganite Priority Pollutant and VOC analyses: Spring 2019
Attached are the analytical reports from the spring of 2019 Milorganite samples. All sample analyses
were performed by Test America Laboratories, Inc. in Amherst, NY (Wisconsin State Certification ID:
998310390).
Please note: Sample ID # 19002892/964 was a composite sample collected March 3, 2019 through
March 9, 2019.
Please contact the Central Laboratory if there are any questions or comments regarding these data.
Thank you.
Data/Report Review By:
Zach Vogel Date
Laboratory Project Manager
Milwaukee Metropolitan Sewerage District
260 West Seeboth Street, Milwaukee, WI 53204

Milorganite Priority Pollunant and VOC Analysis
� �
Spring 2019
row
�$r'il7.5 f$I � I.iItLR ikii3+-'.Ng%M�
964
Milo. Priority Pollutant Sample
3/9/19 SU
WMC10
19002892
Sample Date Site Code
Customer ID
LIMS Number
1253
1,2,4-Trichlorobenzene Dry wt.
< 360 ug/kg D.W.
360
4900
3/18/19
8270D
Test America B 3
1315
1,2-Diphenylhydrazine Dry wt.
< 280 ug/kg D.W.
280
4900
3/18/19
8270D
Test America B 3
1234
2,4,6-Trichlorophenol Dry wt.
< 510 ug/kg D.W.
510
2500
3/18/19
8270D
Test America B 3
1226
2,4-Dichlorophenol Dry wt.
< 270 ug/kg D.W.
270
2500
3/18/19
8270D
Test America B 3
1227
2,4-Dimethylphenol Dry wt.
< 610 ug/kg D.W.
610
2500
3/18119
8270D
Test America B 3
1229
2,4-Dinitrophenol Dry wt.
< 12000 ug/kg D.W.
12000
25000
3/18/19
8270D
Test America B 3
1252
2,4-Dinitrotoluene Dry wt.
< 520 ug/kg D.W.
520
2500
3/18/19
8270D
Test America B 3
1317
2,6-Dinitrotoluene Dry wt.
< 300 ug/kg D.W.
300
2500
3/18/19
8270D
Test America B 3
1249
2-Chloronaphthalene Dry wt.
< 420 ug/kg D.W.
420
2500
3/18/19
8270D
Test America B 3
1225
2-Chlorophenol Dry wt.
< 460 ug/kg D.W.
460
2500
3/18/19
8270D
Test America B 3
1230
2-Nitrophenol Dry wt.
< 720 ug/kg D.W.
720
2500
3/18/19
8270D
Test America B 3
1324
3,3'-Dichlorobenzidine Dry wt.
< 3000 ug/kg D.W.
3000
4900
3/18/19
8270D
Test America B 3
1260 4,4-DDD Dry wt. 130 ug/kg D.W. 17 87
1259
4,4-DDE Dry wt.
< 18 ug/kg D.W.
18
87
1258
4,4-DDT Dry wt.
< 20 ug/kg D.W.
20
87
1228
4,6-Dinitro-o-Cresol Dry wt.
< 2500 ug/kg D.W.
2500
4900
1247
4-Bromophenyl Phenyl Ether Dry wt.
< 360 ug/kg D.W.
360
2500
1250
4-Chloro-phenyl-phenyl ether Dry wt. < 310 ug/kg D.W.
310
2500
1231
4-Nitrophenol Dry wt.
< 1800 ug/kg D.W.
1800
4900
3/20/19 8081B Test America B 3
3/20/19 8081B Test America B 3
3/20/19 8081E Test America B 3
3/18/19 8270D Test America B 3
3/18/19 8270D Test America B 3
3/18/19 8270D Test America B 3
3/18/19 8270D Test America B 3
1254
A-BHC-Alpha Dry wt.
< 16 ug/kg D.W.
16
87
3120/19
8081B
Test America B 3
1235
1318
Acenaphthene Dry wt.
Acenaphthylene Dry wt.
< 370 ug/kg D.W.
< 330 ug/kg D.W.
370
330
2500
2500
3/18/19
3/18/19
8270D
8270D
Test America B 3
Test America B 3
1304
Aldrin Dry wt.
< 21 ug/kg D.W.
21
87
3/20/19
8081B
Test America B 3
524
ALUMINUM ICP Dry wt.
4200 mg/kg D.W.
4.6
10
3/18/19
6010C
Test America B 3
1236
Anthracene Dry wt.
< 630 ug/kg D.W.
630
2500
3/18/19
8270D
Test America B 3
545
ANTIMONY ICP Dry wt.
3.7 mg/kg D.W.
0.42
16
3
3/18/19
6010C
Test America B 3
525
ARSENIC ICP Dry wt.
4.6 mg/kg D.W.
0.42
2.1
3/18/19
6010C
Test America B 3
1255
B-BHC-Beta Dry wt.
< 16 ug/kg D.W.
16
87
3/20/19
8081B
Test America B 3
1237
Benzidine Dry wt. <
32000 ug/kg D.W.
32000
75000
3/18/19
8270D
Test America B 3
1238
Benzo(a)Anthracene Dry wt.
< 250 ug/kg D.W.
250
2500
3/18/19
8270D
Test America B 3
1239
Benzo(a)Pyrene Dry wt.
< 370 ug/kg D.W.
370
2500
3/18/19
8270D
Test America B 3
1240
Benzo(b)Fluoranthene Dry wt.
780 ug/kg D.W.
400
2500
3
3/18/19
8270D
Test America B 3
1241
Benzo(g,h,i)Perylene Dry wt.
< 270 ug/kg D.W.
270
2500
3/18/19
8270D
Test America B 3
1242
Benzo(k)Fluoranthene Dry wt.
< 330 ug/kg D.W.
330
2500
3/18119
8270D
Test America B 3
528
BERYLLIUM ICP Dry wt.
0.067 mg/kg D.W.
0.029
0.21
3
3/18/19
6010C
Test America B 3
1256
BHC-Delta Dry wt.
< 16 ug/kg D.W.
16
87
3/20/19
8081B
Test America B 3
1243
Bis(2-Chloroethoxy)Methane Dry wt.
< 540 ug/kg D.W.
540
2500
3/18/19
8270D
Test America B 3
1244
Bis(2-Chlo roethyl) Ether Dry wt.
< 330 ug/kg D.W.
330
2500
3/18/19
8270D
Test America B 3
1245
Bis(2-Chloroisopropyl)Ether Dry wt.
< 510 ug/kg D.W.
510
2500
3/18/19
8270D
Test America B 3
1246
Bis(2-Ethylhexyl)Phthalate Dry wt.
11000 ug/kg D.W.
870
2500
3/18119
8270D
Test America B 3
526
BORON ICP Dry wt.
14 mg/kg D.W.
0.2
2.1
3/18/19
6010C
Test America B 3
1248
Butyl Benzyl Phthalate Dry wt.
< 420 ug/kg D.W.
420
2500
3/18/19
8270D
Test America B 3
530
CADMIUM ICP Dry wt.
0.67 mg/kg D.W.
0.031
0.21
3/18/19
6010C
Test America B 3
529
CALCIUM ICP Dry wt.
22000 mg/kg D.W.
3.5
52
AX.
3/18/19
6010C
Test America B 3
SYSrrpt5Genefic3
4111114 tl
Page 1 of 4
Printed: 424119 08:39

Milorganite Priority Pollunant and VOC Analysis
Spring 2019
1305
Chlordane Dry wt.
< 190 ug/kg D.W.
190
870
3/20/19
8081B
Test America B 3
532
CHROMIUM ICP Dry wt.
210 mg/kg D.W.
0.21
0.52
3/18/19
6010C
Test America B 3
1251
Chrysene Dry wt.
670 ug/kg D.W.
570
2500 3
3/18/19
8270D
Test America B 3
531
COBALT ICP Dry wt.
4.2 mg/kg D.W.
0.052
0.52
3118/19
6010C
Test America B 3
533
COPPER ICP Dry wt.
230 mg/kg D.W.
0.22
1
3/18/19
6010C
Test America B 3
263
Cyanide - Total (solids)
5 mg/kg D.W.
0.49
1 AX.
3/26/19
9012B
Test America B 3
1325
Dibenzo(a,h)Anthracene Dry wt.
< 450 ug/kg D.W.
450
2500
3/18/19
8270D
Test America B 3
1306
Dieldrin Dry wt.
< 21 ug/kg D.W.
21
87
3/20/19
80818
Test America B 3
1314
Diethyl Phthalate Dry wt.
< 330 ug/kg D.W.
330
2500
3/18/19
8270D
Test America B 3
1328
Dimethyl Phthalate Dry wt.
< 300 ug/kg D.W.
300
2500
3/18/19
8270D
Test America B 3
1320
Di-n-Butylphthalate Dry wt.
< 430 ug/kg D.W.
430
2500
3/18/19
8270D
Test America B 3
1323
Di-n-octyl phthalate Dry wt.
< 300 ug/kg D.W.
300
2500
3/18/19
8270D
Test America B 3
1261
Endosulfan alpha Dry wt.
< 17 ug/kg D.W.
17
87
3/20/19
8081B
Test America B 3
1262
Endosulfan beta Dry wt.
< 16 ug/kg D.W.
16
87
3120/19
8081B
Test America B 3
1263
Endosulfan Sulfate Dry wt.
< 16 ug/kg D.W.
16
87
3/20/19
80816
Test America B 3
1265
Endrin Aldehyde Dry wt.
< 22 ug/kg D.W.
22
87
3/20/19
8081E
Test America B 3
1264
Endrin Dry wt.
< 17 ug/kg D.W.
17
87
3/20/19
8081B
Test America B 3
1321
Fluoranthene Dry wt.
950 ug/kg D.W.
270
2500 3
3/18/19
8270D
Test America B 3
1316
Fluorene Dry wt.
< 300 ug/kg D.W.
300
2500
3/18/19
8270D
Test America B 3
1266
Heptachlor Dry wt.
< 19 ug/kg D.W.
19
87
3/20/19
8081B
Test America 8 3
1267
Heptachlorepoxide Dry wt.
< 22 ug/kg D.W.
22
87
3/20/19
8081B
Test America B 3
1330
Hexachlorobenzene Dry wt.
< 340 ug/kg D.W.
340
2500
3/18/19
8270D
Test America B 3
1327
Hexachlorobutadiene Dry wt.
< 370 ug/kg D.W.
370
2500
3/18/19
8270D
Test America B 3
1308
Hexachlorocyclopentadiene Dry wt.
< 340 ug/kg D.W.
340
2500
3/18/19
8270D
Test America B 3
1329
Hexachloroethane Dry wt.
< 330 ug/kg D.W.
330
2500
3/18/19
8270D
Test America B 3
1326
Indeno(1,2,3-cd)Pyrene Dry Wt.
< 310 ug/kg D.W.
310
2500
3/18/19
8270D
Test America B 3
534
IRON ICP Dry wt.
31000 mg/kg D.W.
3.7
10 AX.
3/18/19
6010C
Test America B 3
1311
Isophorone Dry wt.
< 540 ug/kg D.W.
540
2500
3/18/19
8270D
Test America B 3
544
LEAD ICP Dry wt.
35 mg/kg D.W.
0.25
1
3/18/19
6010C
Test America B 3
538
MAGNESIUM ICP Dry wt.
6400 mg/kg D.W.
0.97
21
3/18/19
601DC
Test America B 3
539
MANGANESE ICP Dry wt.
2100 mg/kg D.W.
0.034
0.21 AX.
3/18/19
6010C
Test America B 3
428
MERCURY by M. 7471 (sludge)
0.28 mg/kg D.W.
0.0083
0.021
3/18/19
7471B
Test America B 3
540
MOLYBDENUM ICP Dry wt.
9.3 mg/kg D.W.
0.14
1
3/18/19
6010C
Test America B 3
1312
Naphthalene Dry wt.
< 330 ug/kg D.W.
330
2500
3/18/19
8270D
Test America B 3
542
NICKEL ICP Dry wt.
32 mg/kg D.W.
0.24
5.2
3/18/19
6010C
Test America B 3
1310
Nitrobenzene Dry wt.
< 280 ug/kg D.W.
280
2500
3/18/19
8270D
Test America B 3
1307
N-Nitrosodimethylamine Dry wt.
< 1100 ug/kg D.W.
1100
4900
3/18/19
8270D
Test America B 3
1309
N-Nitrosodi-n-propylamine Dry wt.
< 430 ug/kg D.W.
430
2500
3/18/19
8270D
Test America B 3
1313
N-Nitrosodiphenylamine Dry wt.
< 2100 ug/kg D.W.
2100
2500
3/18/19
8270D
Test America B 3
678
PCB-1016
< 0.041 mg/kg D.W.
0.041
0.21
3/17/19
8082A
Test America B 3
674
PCB-1221
<0.041 mg/kg D.W.
0.041
0.21
3/17/19
8082A
Test America B 3
675
PCB-1232
< 0.041 mg/kg D.W.
0.041
0.21
3/17/19
8082A
Test America B 3
672
PCB-1242
< 0.041 mg/kg D.W.
0.041
0.21
3/17/19
8082A
Test America B 3
676
PCB-1248
< 0.041 mg/kg D.W.
0.041
0.21
3/17/19
8082A
Test America B 3
673
PCB-1254
< 0.099 mg/kg D.W.
0.099
0.21
3/17/19
8082A
Test America B 3
677
PCB-1260
< 0.099 mg/kg D.W.
0.099
0.21
3/17/19
8082A
Test America B 3
1224
p-Chloro-m-Cresol Dry wt.
< 630 ug/kg D.W.
630
2500
3/18/19
8270D
Test America B 3
1232
Pentachlorophenol Dry wt.
< 2500 ug/kg D.W.
2500
4900
3/18/19
8270D
Test America B 3
1319
Phenanthrene Dry wt.
390 ug/kg D.W.
370
2500 3
3/18/19
8270D
Test America B 3
1233
Phenol Dry wt.
< 390 ug/kg D.W.
390
2500
3/18/19
8270D
Test America B 3
Page 2 of 4
SYVrpt5Generic3 4(11114 tJ
Printed: 424119 08:39

1414SD
PONE' q±t I CH0919 E fila^Rllf M°
543 PHOSPHORUS ICP Dry wt.
17000 mg/kg D.W.
Milorganite Priority Pollunant and VOC Analysis
Spring 2019
130 330 3/25/19 SM 4500 P E Test America B 3
1322
Pyrene Dry wt.
740 ug/kg D.W.
300
2500
3
3/18/19
8270D
Test America B 3
546
SELENIUM ICP Dry wt.
4.6 mg/kg D.W.
0.42
4.2
3/18/19
6010C
Test America B 3
523
541
SILVER ICP Dry wt.
SODIUM ICP Dry wt.
2.3 mg/kg D.W.
1600 mg/kg D.W.
0.21
14
0.63
150
3/18/19
3/18/19
6010C
6010C
Test America B 3
Test America B 3
1187
Solids for dry weight determination
(T 95 %
**
***
3/18/19
Moisture
Test America B 3
1187
Solids for dry weight determination
(T 96 %
3/18/19
Moisture
Test America B 3
1187
Solids for dry weight determination
(T 96 %
**
-
3/18/19
Moisture
Test America B 3
550
THALLIUM ICP Dry wt.
< 0.31 mg/kg D.W.
0.31
6.3
3/18/19
6010C
Test America B 3
697
1268
Total PCB Aroclors
Toxaphene Dry wt.! `
< 0.099 mg/kg D.W.
< 500 ug/kg D.W.
0.099
500
0.21
870
3/17/19
3/20/19
8082A
8081E
Test America B 3
Test America B 3
1257
Y-BHC-Gamma(Lindane) Dry wt.
< 16 ug/kg D.W.
16
87
3/20/19
8081E
Test America B 3
552
ZINC ICP Dry wt.
410 mg/kg D.W.
0.67
2.1
3/18/19
6010C
Test America B 3
3/11/19 su
Sample Date Site Code
1341` 1,1,1-Trichloroethane Dry wt.
1350 1,1,2,2-Tetrachloroethane Dry wt.
WMC10
Customer ID
< 1.7 ug/kg D.W.
< 3.8 ug/kg D.W.
1.7
3.8
23
23
AX.
AX.
3/14/19
3/14/19
8260C
8260C
19003869
LIMS Number
Test America 8 3
Test America B 3
1348
1,1,2-Trichloroethane Dry wt.
< 3 ug/kg D.W.
3
23
AX.
3/14/19
8260C
Test America B 3
1338
1,1-Dichloroethane Dry wt.
< 2.8 ug/kg D.W.
2.8
23
AX.
3/14/19
8260C
Test America B 3
1336
1,1-Dichloroethylene Dry wt.
< 2.8 ug/kg D.W.
2.8
23
AX.
3/14/19
8260C
Test America B 3
1355
1,2-Dichlorobenzene Dry Wt.
< 1.8 ug/kg D.W.
1.8
23
AX.
3/14/19
8260C
Test America B 3
1340
1,2-Dichloroethane Dry wt.
< 1.2 ug/kg D.W.
1.2
23
AX.
3/14/19
8260C
Test America B 3
1222
1,2-Dichloropropane Dry wt.
< 12 ug/kg D.W.
12
23
AX.
3/14/19
8260C
Test America B 3
1356
1,3-Dichlorobenzene Dry Wt.
< 1.2 ug/kg D.W.
1.2
23
AX.
3/14/19
8260C
Test America B 3
1357
1,4-Dichlorobenzene Dry Wt.
< 3.3 ug/kg D.W.
3.3
23
AX.
3/14/19
8260C
Test America B 3
1337
2-Chloroethylvinyl Ether Dry wt.
< 12 ug/kg D.W.
12
46
AX.
3/14/19
8260C
Test America B 3
1334
Acrolein Dry wt.
< 37 ug/kg D.W.
37
120
AX.
3/14/19
8260C
Test America B 3
1335
Acrylonitrile Dry wt.
< 21 ug/kg D.W.
21
120
AX.
3/14/19
8260C
Test America B 3
1346
Benzene Dry wt.
1.9 ug/kg D.W.
1.1
23
3 AX
3/14/19
8260C
Test America B 3
1343
Bromodichloromethane Dry wt.
< 3.1 ug/kg D.W.
3.1
23
AX.
3/14/19
8260C
Test America B 3
1219
1342
Bromoform Dry wt.
Carbon Tetrachloride Dry wt.
< 12 ug/kg D.W.
< 2.2 ug/kg D.W.
12
2.2
23
23
AX.
AX.
3/14/19
w 3/14/19
8260C
8260C
Test America B 3
Test America B 3
1352
Chlorobenzene Dry wt.
< 3.1 ug/kg D.W.
3.1
23
AX.
3/14/19
8260C
Test America B 3
1220
Chloroethane Dry wt.
< 5.2 ug/kg D.W.
5.2
23
AX.
3/14/19
8260C
Test America B 3
1339
Chloroform Dry wt.
1.4 ug/kg D.W.
1.4
23
3 AX
3/14/19
8260C
Test America B 3
1344
cis-1,3-Dichloropropene Dry wt.
< 3.3 ug/kg D.W.
3.3
23
AX.
3/14/19
8260C
Test America B 3
1347
Dibromochloromethane Dry wt.
< 3 ug/kg D.W.
3
23
AX.
3/14/19
8260C
Test America B 3
1353
Ethylbenzene Dry wt.
< 1.6 ug/kg D.W.
1.6
23
AX.
3/14/19
8260C
Test America B 3
1331
Methyl Bromide Dry wt.
< 2.1 ug/kg D.W.
2.1
23
AX.
3/14/19
8260C
Test America B 3
1354
Methyl Chloride dry wt.
< 1.4 ug/kg D.W.
1.4
23
AX.
3/14/19
8260C
Test America B 3
1333
1187
Methylene Chloride Dry wt. 14 ug/kg D.W.
Solids for dry weight determination (T 94 %
11
-
23
-
3 AX
3114/19
3/14/19
8260C
Moisture
Test America B 3
Test America B 3
1349
Tetrachloroethylene Dry wt.
< 3.1 ug/kg D.W.
3.1
23
AX.
3/14/19
8260C
Test America B 3
1351
Toluene Dry wt.
4.9 ug/kg D.W.
1.8
23
3 AX
3/14/19
8260C
Test America B 3
1221
Trans- 1, 2-Dich loroethyle ne Dry wt.
< 2.4 ug/kg D.W.
2.4
23
AX.
3/14/19
8260C
Test America B 3
1223
Trans-1,3-Dichloropropene Dry wt.
< 10 ug/kg D.W.
10
23
AX.
3/14/19
8260C
Test America B 3
1345
Trichloroethylene Dry wt.
< 5.1 ug/kg D.W.
5.1
23
AX.
3/14/19
8260C
Test America B 3
SYS1rpt5Geneac3 4111114 tj
Page 3 of 4
Printed: 4124119 08:39

1332 Vinyl Chloride Dry cot.
< 2.8 ug/kg D.W
Milorganite Priority Pollunant and VOC Analysis
Spring 2019
2.8
23 AX. 3/14/19 8260C TestAmericaB 3
** The MDL for this testis the lowest level of precision shown, example: 4.1 would be "G. Ill.
*** The LOQ for this testis the lowest level of precision shown, example: 4.1 would be "0.1".
N.A. The MDL/LOQ is Not Available or Not Applicable for this test.
Column S: Test Status. Not Started=8, Intermediate=7, Final=3, Analyst Approved=12, Not Reportable=15.
Flag Descriptions
AO Other -- Flag requires additional explanation
AX Qualified data - see contract lab report
B3 Target analyte detected in method blank > 10% of sample
concentration.
B7 LCS recovery was above control limits.
B8 LCS recovery was below control limits.
89 Low Level CCV recovery was outside of method acceptance limits
CQ Data used for calculation of result was qualified
D1 Duplicate precision control limit was exceeded.
D2 Matrix spike precision control limit was exceeded.
D3 Sample is heterogeneous. Sample homogeneity could not be readily
achieved using routine laboratory practices.
D4 Sample matrix interferences did not allow completing the analysis.
DS The reported result is an estimate because the concentration of
HEM in this sample exceeded the maximum allowed in the method
for the sample volume collected.
Hi Sample was received past holding time.
H3 Analysis performed beyond holding time. f
H4 Initial analysis within holding time. Reanalysis for the required
dilution was past holding time.
HS Analysis performed beyond holding time.
IS Insufficient sample volume for analysis.
] Estimated concentration above the adjusted method detection limit
and below the adjusted reporting limit
LA Not analyzed - lab accident.
Mi Too numerous to count.
M2 Sample incubation period outside method requirement.
M3 Spreading colonies - unable to determine result.
M4 Results are an approximation due to spreading colonies.
MS Incubator/water bath temperature was outside method
requirements.
M7 Micro sample received without adequate headspace.
M9 Target organism detected in associated method blank.
NR Not usable data. (Water Quality only.)
NU Not usable Data.
P2 Sample received with improper or inadequate chemical preservation.
Q2 Matrix spike recovery for this sample was above control limits.
Q3 Matrix spike recovery for this sample was below control limits. _
RT Sample temperature upon receipt exceeded regulatory or project
requirements.
SS Reading was not confirmed by a constant weight measurement
SD Supplemental details provided.(Water Quality only.)
T3 The dilution water D.O. depletion was > 0.2 mg/L.
T4 GGA BOD was below method acceptance criteria.
TS GGA BOD was above method acceptance criteria.
T7 The dilution water D.O. increase was > 0.2 mg/L.
TS Sample matrix did not allow adjusting sample pH for BOD.
T9 Sample exceeded prescribed method temperature range.
140
Page 4 or 4
SYS/rpt5Generic3 4111114 t] Printed: 424119 08:39

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PARTNERS FOR A CLEANER ENVIRONMENT
November 20, 2019
TO: Tom Nowicki
FROM: Zach Vogel
COPY: S. Unger, J. Spence, E. Stroik, S. Mertens, A. Sotomayor, Lab File
SUBJECT: Milorganite Priority Pollutant and VOC analyses: Fall 2019
Attached are the analytical reports from the September 2019 Milorganite samples. All sample analyses
were performed by Test America Laboratories, Inc. in Amherst, NY (Wisconsin State Certification ID:
998310390).
Please note: Sample ID # 19019216/964 was a composite sample collected September 1, 2019 through
September 7, 2019.
Please contact the Central Laboratory if there are any questions or comments regarding these data.
Thank you.
Data/Report Review By:
_ 1 I - z o
Zach Vogel Date
Laboratory Project Manager
Milwaukee Metropolitan Sewerage District
260 West Seeboth Street, Milwaukee, WI 53204

'�MMSDFall
�WRRI i911 iil4tf& [vth;N4iM'
September
Monthly Milorganite: Priority Pollutant and VOC Analysis
2019
1,2,4-Trichlorobenzene Dry wt.
Rate Aroil—d.
9/20/19
< 2400 ug/kg D.W.
2400
Milo. Priority
166 -
8270D
Pollutant Sample
190192'6
Test America Buffalo
1,2-Diphenylhydrazine Dry wt.
9120/19
< 1900 ug/kg D.W.
1900
8270D
Test America Buffalo
2,4,6-Trichlorophenol Dry wt.
9/20/19
< 3400 ug/kg D.W.
3400
8270D
Test America Buffalo
2,4-Dichlorophenol Dry wt.
2,4-Dimethylphenol Dry wt.
2,4-Dinitrophenol Dry wt.
9/20/19
9/20/19
9/20/19
< 1800 ug/kg D.W.
< 4100 ug/kg D.W.
< 78000 ug/kg D.W.
1800
4100
78000
8270D
8270D
8270D
Test America Buffalo
Test America Buffalo
Test America Buffalo
2,4-Dinitrotoluene Dry wt.
9/20/19
< 3500 ug/kg D.W.
3500
8270D
Test America Buffalo
2,6-Dinitrotoluene Dry wt.
9/20/19
< 2000 ug/kg D.W.
2000
8270D
Test America Buffalo
2-Chloronaphthalene Dry wt.
9/20/19
< 2800 ug/kg D.W.
2800
8270D
Test America Buffalo
2-Chlorophenol Dry wt.
9/20/19
< 3100 ug/kg D.W.
3100
8270D
Test America Buffalo
2-Nitrophenol Dry wt.
3,3'-Dichlorobenzidine Dry wt.
4,4-DDD Dry wt.
4,4-DDE Dry wt.
4,4-DDT Dry wt.
9/20/19
9/20/19
9/20/19
9/20/19
9/20/19
< 4800 ug/kg D.W.
< 20000 ug/kg D.W.
< 3.3 ug/kg D.W.
< 3.5 ug/kg D.W.
< 3.9 ug/kg D.W.
4800
20000
3.3
3.5
3.9
8270D
8270D
8081B
8081B
8081B
Test America Buffalo
Test America Buffalo
Test America Buffalo
Test America Buffalo
Test America Buffalo
4,6-Dinitro-o-Cresol Dry wt.
9/20/19
< 17000 ug/kg D.W.
17000
8270D
Test America Buffalo
4-Bromophenyl Phenyl Ether Dry wt.
9/20/19
< 2400 ug/kg D.W.
2400
8270D
Test America Buffalo
4-Chloro-phenyl-phenyl ether Dry wt.
9/20/19
< 2100 ug/kg D.W.
2100
8270D
Test America Buffalo
4-Nitrophenol Dry wt.
9/20/19
< 12000 ug/kg D.W.
12000
8270D
Test America Buffalo
A-BHC-Alpha Dry wt.
9/20/19
4.7 ug/kg D.W.
3
J AX
8081B
Test America Buffalo
Acenaphthene Dry wt.
Acenaphthylene Dry wt.
Aldrin Dry wt.
9/20/19
9/20/19
9/20/19
< 2500 ug/kg D.W.
< 2200 ug/kg D.W.
< 4.2 ug/kg D.W.
2500
2200
4.2
8270D
8270D
8081B
Test America Buffalo
Test America Buffalo
Test America Buffalo
ALUMINUM ICP Dry wt.
Anthracene Dry wt.
9/17/19
9/20/19
4700 mg/kg D.W.
< 4200 ug/kg D.W.
4.6
4200
6010C
8270D
Test America Buffalo
Test America Buffalo
ANTIMONY ICP Dry wt.
9/16/19
3.9 mg/kg D.W.
0.42
J
6010C
Test America Buffalo
ARSENIC ICP Dry wt.
9/16/19
5.1 mg/kg D.W.
0.42
6010C
Test America Buffalo
B-BHC-Beta Dry wt.
9/20/19
< 3 ug/kg D.W.
3
8081B
Test America Buffalo
Benzidine Dry wt.
9/20/19
< 210000 ug/kg D.W.
210000
8270D
Test America Buffalo
Benzo(a)Anthracene Dry wt.
9/20/19
< 1700 ug/kg D.W.
1700
8270D
Test America Buffalo
Benzo(a)Pyrene Dry wt.
9/20/19
< 2500 ug/kg D.W.
2500
8270D
Test America Buffalo
Benzo(b)Fluoranthene Dry wt.
9/20/19
< 2700 ug/kg D.W.
2700
8270D
Test America Buffalo
Benzo(g,h,i)Perylene Dry wt.
9/20/19
< 1800 ug/kg D.W.
1800
8270D
Test America Buffalo
Benzo(k)Fluoranthene Dry wt.
9/20/19
< 2200 ug/kg D.W.
2200
8270D
Test America Buffalo
BERYLLIUM ICP Dry wt.
9/16/19
0.12 mg/kg D.W.
0.029
J
6010C
Test America Buffalo
BHC-Delta Dry wt.
9/20/19
4.5 ug/kg D.W.
3.1
J AX
8081B
Test America Buffalo
Bis(2-Chloroethoxy)Methane Dry wt.
9/20/19
< 3600 ug/kg D.W.
3600
8270D
Test America Buffalo
Bis(2-Ch loroethyl) Ether Dry wt.
9/20/19
< 2200 ug/kg D.W.
2200
8270D
Test America Buffalo
Bis(2-Chloroisopropyl)Ether Dry wt.
9/20/19
< 3400 ug/kg D.W.
3400
8270D
Test America Buffalo
Bis(2-Ethylhexyl)Phthalate Dry wt.
9/20/19
6300 ug/kg D.W.
5800
J
8270D
Test America Buffalo
BORON ICP Dry wt.
9/16/19
20 mg/kg D.W.
0.2
AX.
6010C
Test America Buffalo
Butyl Benzyl Phthalate Dry wt.
9/20/19
< 2800 ug/kg D.W.
2800
8270D
Test America Buffalo
CADMIUM ICP Dry wt.
CALCIUM ICP Dry wt.
9/16/19
9/16/19
0.33 mg/kg D.W.
24000 mg/kg D.W.
0.031
3.5
6010C
6010C
Test America Buffalo
Test America Buffalo
SYS/rptl MiloPP 1110113 tj
Page 1 of 5
Printed: 11120119 08:32

Monthly Milorganite: Priority Pollutant and VOC Analysis
t MMSD
Fall2019
September
Milo. Priority Pollutant Sample
19019216
-771
Chlordane Dry wt.
9/20/19
< 37 ug/kg D.W.
37
80816 Test America Buffalo
CHROMIUM ICP Dry wt.
9116/19
190 mg/kg D.W.
0.21
6010C Test America Buffalo
Chrysene Dry wt.
9/20/19
< 3800 ug/kg D.W.
3800
8270D Test America Buffalo
COBALT ICP Drywt.
9/16/19
3.4 mg/kg D.W.
0.052
6010C Test America Buffalo
COPPER ICP Dry wt.
9/16119
220 mg/kg D.W.
0.22
6010C Test America Buffalo
Cyanide - Total (solids)
9/26/19
4 mg/kg D.W.
0.48 AX.
9012B Test America Buffalo
Dibenzo(a,h)Anthracene Dry wt.
9/20/19
< 3000 ug/kg D.W.
3000
8270D Test America Buffalo
Dieldrin Dry wt.
Diethyl Phthalate Dry wt.
Dimethyl Phthalate Dry wt.
Di-n-Butylphthalate Dry wt.
Di-n-octyl phthalate Dry wt.
Endosulfan alpha Dry wt.
Endosulfan beta Dry wt.
Endosulfan Sulfate Dry wt.
Endrin Aldehyde Dry wt.
Endrin Dry wt.
Fluoranthene Dry wt.
9/20/19
< 4.1
ug/kg
D.W.
4.1
9/20/19
< 2200
ug/kg
D.W.
2200
9/20/19
< 2000
ug/kg
D.W.
2000
9/20/19
< 2900
ug/kg
D.W.
2900
9/20/19
< 2000
ug/kg
D.W.
2000
8081B Test America Buffalo
8270D Test America Buffalo
8270D Test America Buffalo
8270D Test America Buffalo
8270D Test America Buffalo
9/20/19
< 3.2 ug/kg D.W.
3.2
8081B
Test America Buffalo
9/20/19
< 3 ug/kg D.W.
3
8081B
Test America Buffalo
9/20/19
6.6 ug/kg D.W.
3.1 J
8081B
Test America Buffalo
9/20/19
5.1 ug/kg D.W.
4.3 J AX
8081B
Test America Buffalo
9/20/19
<3.3 ug/kg D.W.
3.3
8081E
Test America Buffalo
9/20/19
< 1800 ug/kg D.W.
1800
8270D
Test America Buffalo
Fluorene Dry wt.
9/20/19
< 2000 ug/kg D.W.
2000
8270D
Test America Buffalo
Heptachlor Dry wt.
Heptachlorepoxide Dry wt.
Hexachlorobenzene Dry wt.
Hexachlorobutadiene Dry wt.
9/20/19
9/20/19
9/20/19
9/20/19
< 3.7 ug/kg D.W.
< 4.4 ug/kg D.W.
< 2300 ug/kg D.W.
< 2500 ug/kg D.W.
3.7
4.4
2300
2500
80818
8081B
8270D
8270D
Test America Buffalo
Test America Buffalo
Test America Buffalo
Test America Buffalo
Hexachlorocyclopentadiene Dry wt.
Hexachloroethane Dry wt.
Indeno(1,2,3-cd)Pyrene Dry Wt.
9/20/19
9/20/19
9/20/19
< 2300 ug/kg D.W.
< 2200 ug/kg D.W.
< 2100 ug/kg D.W.
2300
2200
2100
8270D
8270D
8270D
Test America Buffalo
Test America Buffalo
Test America Buffalo
IRON ICP Dry wt.
9/16/19
42000 mg/kg D.W.
3.7
6010C
Test America Buffalo
Isophorone Dry wt.
9/20/19
< 3600 ug/kg D.W.
3600
8270D
Test America Buffalo
LEAD ICP Dry wt.
MAGNESIUM ICP Dry wt.
MANGANESE ICP Dry wt.
MERCURY by M. 7471 (sludge)
MOLYBDENUM ICP Dry wt.
9/16/19
9/16/19
9/16/19
9/17/19
9/16/19
35 mg/kg D.W.
7000 mg/kg D.W.
1800 mg/kg D.W.
0.25 mg/kg D.W.
9.4 mg/kg D.W.
0.25
0.97
0.034
0.0083
0.14 AX.
6010C
6010C
6010C
7471B
6010C
Test America Buffalo
Test America Buffalo
Test America Buffalo
Test America Buffalo
Test America Buffalo
Naphthalene Dry wt.
9/20/19
< 2200 ug/kg D.W.
2200
8270D
Test America Buffalo
NICKEL ICP Dry wt.
9/16/19
23 mg/kg D.W.
0.24
6010C
Test America Buffalo
Nitrobenzene Dry wt.
9/20/19
< 1900 ug/kg D.W.
1900
8270D
Test America Buffalo
N-Nitrosodimethylamine Dry wt.
9/20/19
< 7200 ug/kg D.W.
7200
8270D
Test America Buffalo
N-Nitrosodi-n-propylamine Dry wt.
9/20/19
< 2900 ug/kg D.W.
2900
8270D
Test America Buffalo
N-Nitrosodiphenylamine Dry wt.
9/20/19
< 14000 ug/kg D.W.
14000
8270D
Test America Buffalo
PCB-1016
9/17/19
< 0.043 mg/kg D.W.
0.043
8082A
Test America Buffalo
PCB-1221
9/17/19
< 0.043 mg/kg D.W.
0.043
8082A
Test America Buffalo
PCB-1232
9/17/19
< 0.043 mg/kg D.W.
0.043
8082A
Test America Buffalo
PCB-1242
9/17/19
< 0.043 mg/kg D.W.
0.043
8082A
Test America Buffalo
PCB-1248
9/17/19
< 0.043 mg/kg D.W.
0.043
8082A
Test America Buffalo
SYS11pt1M110PP 1110113 tl
Page 2 of 5
Printed: 1112011908,32

Monthly Milorganite: Priority Pollutant and VOC Analysis
iej
1414SD
Fall 2019
��?'14f ii f 9i i [I;L�18 �Y�ii!:N►i[Y'
September
Milo. Priority Pollutant Sample
19099�96
Test Cesdipfion
■.
6APlag
AllalyetcFlamw-
PCB-1254
9/17/19
< 0.1 mg/kg D.W.
0.1
8082A
Test America Buffalo
PCB-1260
9/17/19
< 0.1 mg/kg D.W.
0.1
8082A
Test America Buffalo
p-Chloro-m-Cresol Dry wt.
9/20/19
< 4200 ug/kg D.W.
4200
8270D
Test America Buffalo
Pentachlorophenol Dry wt.
9/20/19
< 17000 ug/kg D.W.
17000
8270D
Test America Buffalo
Phenanthrene Dry wt.
9/20/19
< 2500 ug/kg D.W.
2500
8270D
Test America Buffalo
Phenol Dry wt.
9/20/19
< 2600 ug/kg D.W.
2600
8270D
Test America Buffalo
PHOSPHORUS ICP Dry wt.
9/21/19
15000 mg/kg D.W.
140
SM 4500 P E
Test America Buffalo
POTASSIUM ICP Dry wt.
9/16/19
3000 mg/kg D.W.
21
6010C
Test America Buffalo
Pyrene Dry wt.
9/20/19
< 2000 ug/kg D.W.
2000
8270D
Test America Buffalo
SELENIUM ICP Dry wt.
9/16/19
2.6 mg/kg D.W.
0.42 J
6010C
Test America Buffalo
SILVER ICP Dry wt.
9/16/19
1.9 mg/kg D.W.
0.21
6010C
Test America Buffalo
SODIUM ICP Dry wt.
9/16/19
1400 mg/kg D.W.
14
6010C
Test America Buffalo
Solids for dry weight determination (Test America)
9/13/19
97 %
0.1
Moisture
Test America Buffalo
Solids for dry weight determination (Test America)
M %
N/A
Calculated value
DEFAULT
THALLIUM ICP Dry wt.
9/16/19
1.1 mg/kg D.W.
0.31 J
6010C
Test America Buffalo
Total PCB Aroclors
9/17/19
< 0.1 mg/kg D.W.
0.1
8082A
Test America Buffalo
Toxaphene Dry wt.
9/20/19
< 98 ug/kg D.W.
98
8081B
Test America Buffalo
Y-BHC-Gamma(Undane) Dry wt.
9/20/19
< 3.1 ug/kg D.W.
3.1
8081B
Test America Buffalo
ZINC ICP Dry wt.
9/16/19
370 mg/kg D.W.
0.67
6010C
Test America Buffalo
Page 3 of 5
SYSirptimiloPP 1110113 q Printed: 11120119 08:32

"
Monthly Milorganite: Priority Pollutant and VOC Analysis
'
Fall 2019
September
9/9/19
Milo. Priority Pollutant Sample
190/9217
1,1,1-Trichloroethane Dry wt.
9/23/19
< 59 ug/kg D.W.
59
8260C
Test America Buffalo
1,1,2,2-Tetrachloroethane Dry wt.
9/23/19
< 34 ug/kg D.W.
34
8260C
Test America Buffalo
1,1,2-Trichloroethane Dry wt.
9/23/19
< 45 ug/kg D.W.
45
8260C
Test America Buffalo
1,1-Dichloroethane Dry wt.
9/23/19
< 66 ug/kg D.W.
66
8260C
Test America Buffalo
1,1-Dichloroethylene Dry wt.
9/23/19
< 73 ug/kg D.W.
73
8260C
Test America Buffalo
1,2-Dichlorobe nzene Dry Wt.
9/23/19
< 54 ug/kg D.W.
54
8260C
Test America Buffalo
1,2-Dichloroethane Dry wt.
9/23/19
< 87 ug/kg D.W.
87
8260C
Test America Buffalo
1,2-Dichloropropane Dry wt.
9/23/19
< 34 ug/kg D.W.
34
8260C
Test America Buffalo
1,3-Dichlorobenzene Dry Wt.
9/23/19
< 57 ug/kg D.W.
57
8260C
Test America Buffalo
1,4-Dichlorobenzene Dry Wt.
9/23/19
< 30 ug/kg D.W.
30
8260C
Test America Buffalo
2-Chloroethylvinyl Ether Dry wt.
9/23/19
< 68 ug/kg D.W.
68
8260C
Test America Buffalo
Acrolein Dry wt.
9/23119
< 430 ug/kg D.W.
430
8260C
Test America Buffalo
Acrylonitrile Dry wt.
9/23/19
< 530 ug/kg D.W.
530
8260C
Test America Buffalo
Benzene Dry wt.
9/23/19
< 40 ug/kg D.W.
40
8260C
Test America Buffalo
Bromodichloromethane Dry wt.
9/23/19
< 42 ug/kg D.W.
42
8260C
Test America Buffalo
Bromoform Dry wt.
9/23/19
< 110 ug/kg D.W.
110
8260C
Test America Buffalo
Carbon Tetrachloride Dry wt.
9/23/19
< 54 ug/kg D.W.
54
8260C
Test America Buffalo
Chlorobenzene Dry wt.
9/23/19
< 28 ug/kg D.W.
28
8260C
Test America Buffalo
Chloroethane Dry wt.
9/23/19
< 44 ug/kg D.W.
44
8260C
Test America Buffalo
Chloroform Dry wt.
9/23/19
< 150 ug/kg D.W.
150
8260C
Test America Buffalo
cis- 1,3-Dichloropropene Dry wt.
9/23/19
< 51 ug/kg D.W.
51
8260C
Test America Buffalo
Dibromochloromethane Dry wt.
9/23/19
< 100 ug/kg D.W.
100
8260C
Test America Buffalo
Ethylbenzene Dry wt.
9/23/19
< 62 ug/kg D.W.
62
8260C
Test America Buffalo
Methyl Bromide Dry wt.
9/23/19
< 47 ug/kg D.W.
47
8260C
Test America Buffalo
Methyl Chloride dry wt.
9/23/19
< 51 ug/kg D.W.
51
8260C
Test America Buffalo
Methylene Chloride Dry wt.
9/23/19
< 42 ug/kg D.W.
42
8260C
Test America Buffalo
Solids for dry weight determination (Test America)
9/12/19
92 %
0.1
Moisture
Test America Buffalo
Tetrachloroethylene Dry wt.
9/23/19
< 29 ug/kg D.W.
29
8260C
Test America Buffalo
Toluene Dry wt.
9/23/19
160 ug/kg D.W.
57 ]
8260C
Test America Buffalo
Trans- 1,2-Dichloroethylene Dry wt.
9/23/19
< 50 ug/kg D.W.
50
8260C
Test America Buffalo
Trans-1,3-Dichloropropene Dry wt.
9/23/19
< 21 ug/kg D.W.
21
8260C
Test America Buffalo
Trichloroethylene Dry wt.
9/23/19
< 59 ug/kg D.W.
59
8260C
Test America Buffalo
Vinyl Chloride Dry wt.
9/23/19
< 71 ug/kg D.W.
71
8260C
Test America Buffalo
Page 4 of 5
SYShptlMiloPP 1110113 tj Printed: 11120119 08:32

Monthly Milorganite: Priority Pollutant and VOC Analysis
Fall 2019
i €f €'Dd I€€WR €Wnr K-117
Flag Descriptions
AO Other -- Flag requires additional explanation
AX Qualified data - see contract laboratory report
B3 Target analyte detected in method blank > 10% of sample
concentration.
B7 LCS recovery was above control limits.
B8 LCS recovery was below control limits.
B9 Low Level CCV recovery was outside of method acceptance limits
CQ Data used for calculation of result was qualified
D1 Duplicate precision control limit was exceeded.
D2 Matrix spike precision control limit was exceeded.
D3 Sample is heterogeneous. Sample homogeneity could not be readily
achieved using routine laboratory practices.
D4 Sample matrix interferences did not allow completing the analysis.
DS The reported result is an estimate because the concentration of
HEM in this sample exceeded the maximum allowed in the method
for the sample volume collected.
HI Sample was received past holding time.
H3 Analysis performed beyond holding time.
H4 Initial analysis within holding time. Reanalysis for the required
dilution was past holding time.
HS Analysis performed beyond holding time.
IS Insufficient sample volume for analysis.
7 Estimated concentration above the adjusted method detection limit
and below the adjusted reporting limit
LA Not analyzed - laboratory accident.
M1 Too numerous to count.
M2 Sample incubation period outside method requirement.
M3 Spreading colonies - unable to determine result.
N14 Results are an approximation due to spreading colonies.
MS Incubator/water bath temperature was outside method
_ requirements.
M7 Microbiology sample received without adequate headspace.
M9 Target organism detected in associated method blank.
NR Not usable data. (Water Quality only.)
NU Not usable Data.
P2 Sample received with improper or inadequate chemical preservation.
Q2 Matrix spike recovery for this sample was above control limits.
Q3 Matrix spike recovery for this sample was below control limits.
RT Sample temperature upon receipt exceeded regulatory or project
requirements. _
S5 Reading was not confirmed by a constant weight measurement
SD Supplemental details provided.(Water Quality only.)
T3 The BOD dilution water D.O. depletion was > 0.2 mg/L.
T4 GGA BOD was below method acceptance criteria.
T5 GGA BOD was above method acceptance criteria.
T7 The BOD dilution water D.O. increase was > 0.2 mg/L.
T8 Sample matrix did not allow adjusting sample pH for BOD.
T9 Sample is outside of the prescribed method temperature range.
140
Page 5 of 5
SYSIrptiMiloPP 1110113 y Primed: 1120/19 08.32

If]
HNSO
PARTNERS FOR A CIEANER ENVIRONMENT
December 13, 2019
Memorandum
TO: Brett Kelly, Todd Schwingle, Dion Doege, Jacob Holbert, and Sam Lieven
FROM: Zach Vogel
Laboratory Project Manager
COPY: Richard Vincent, Steve Unger, Sid Arora, Jaime Staufenbeil, Tom Nowicki, Beth
Stroik, Kim Walden, Kori Kenney, Ethan Guyant, Lab File
SUBJECT: Milorganite Monthly Data — November 2019
Attached is the MMSD Central Lab analytical report for Milorganite data for the month of November
2019. The boron analysis was performed by CT Laboratories, in Baraboo, Wisconsin (Wisconsin
Certification ID# 157066030). The mercury analyses were performed by CT Laboratories, in Baraboo,
Wisconsin (Wisconsin Certification ID# 157066030) and by Pace Analytical Services, Inc. in Green Bay,
Wisconsin (Wisconsin Certification #: 405132750). All other analyses were performed by Milwaukee
Metropolitan Sewerage District in Milwaukee, WI (Wisconsin Certification #: 241325920, Florida NELAP
Certification #: E571010).
Please contact the Central Laboratory if there are any questions or comments regarding these data.
Thank you.
Data Review By:
Rich Vincent Date
Laboratory Supervisor
Data/Report Review By:
Zach Vogel Date
Laboratory Project Manager
Milwaukee Metropolitan Sewerage District
260 West Seeboth Street, Milwaukee, WI 53204

" -
I MSD
PUTARi f9t) CUM fiff[£ w(F
ARSENIC ICP Dry wt.
,.
11/01/19 DM1101/19022183
< 18 mg/kg D.W.
18
O,
70
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
SW846: 6010C MMSD
11/02/19
DM1102119022194
< 17 mg/kg D.W.
17
70
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
< 17 mg/kg D.W.
17
70
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
< 18 mg/kg D.W.
18
70
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/06/19
DM1106119022391
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
< 17 mg/kg D.W.
17
70
SW846: 6010C
MMSD
11/11/19
DM1111/19022991
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/12/19
11/13/19
DM1112/19023017
DM1113/19023033
< 17 mg/kg D.W.
< 17 mg/kg D.W.
17
17
70
68
T
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/14/19
DM1114/19023645
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
< 17 mg/kg D.W.
17
69
Q3.
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
< 17 mg/kg D.W.
17
70
Q3.
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
< 17 mg/kg D.W.
17
70
SW846: 6010C
MMSD
11/19/19
11/20/19
DM1119/19023797
DM1120/19023964
< 17 mg/kg D.W.
< 17 mg/kg D.W.
17
17
69
70
Q3.
Q3.
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/21/19
DM1121/19023996
< 17 mg/kg D.W.
17
69
Q3.
SW846: 6010C
MMSD
11/22/19
DM1122/19024012
< 17 mg/kg D.W.
17
69
Q3.
SW846: 6010C
MMSD
11/23/19
DM1123/19024023
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/24/19
11/25/19
DM1124119024220
DM1125/19024233
< 17 mg/kg D.W.
< 17 mg/kg D.W.
17
17
69
69
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/26/19
DM1126119024576
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
< 17 mg/kg D.W.
17
68
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
< 17 mg/kg D.W.
17
69
SW846: 6010C
MMSD
Avg Result: 0 mg/kg D.W.
Min LOD:
17 mg/kg D.W.
Page 1 of le
SYS/rptlMiloMonthlyDW 4126119 tj Printed: 1211311914:31

Monthly Milorganite Report DW
AnAftaft ICES
November 2019
au
"111W wt A, cum kVINIllklF
Milorganite Daily Composite
CADMIUM ICP Dry wt.
ilkm
11/01/19 DM1101119022183 < 0.95 mg/kg D.W. 0.95 3.6 SW846: 6010C MMSD
11/02/19 DM1102/19022194 < 0.95 mg/kg D.W. 0.95 3.6 SW846: 6010C MMSD
11/03/19
11/04/19
DM1103/19022213
DM1104/19022226
< 0.95 mg/kg D.W.
< 0.95 mg/kg D.W.
0.95
0.95
3.6
3.6
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/05/19
DM1105/19022376
< 0.94 mg/kg D.W.
0.94
3.6
SW846: 6010C
MMSD
11/06/19
DM1106119022391
< 0.93 mg/kg D.W.
0.93
3.5
SW846: 6010C
MMSD
11/07/19
DM1107119022933
< 0.92 mg/kg D.W.
0.92
3.5
SW846: 6010C
MMSD
11/08/19
DM1108119022948
< 0.93 mg/kg D.W.
0.93
3.5
SW846: 6010C
MMSD
11/09/19
11/10/19
DM1109/19022959
DM1110119022978
< 0.93 mg/kg D.W.
< 0.94 mg/kg D.W.
0.93
0.94
IS
3.6
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/11/19
11/12/19
DM1111119022991
D M 1112119023017
< 0.94 mg/kg D.W.
< 0.95 mg/kg D.W.
0.94
0.95
3.6
3.6
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113119023033
< 0.92 mg/kg D.W.
0.92
3.5
SW846: 6010C
MMSD
11/14/19
11/15/19
D M 1114119023645
DM1115/19023660
< 0.93 mg/kg D.W.
< 0.93 mg/kg D.W.
0.93
0.93
3.5
3.5
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/16/19
DM1116119023738
< 0.95 mg/kg D.W.
0.95
3.6
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
< 0.93 mg/kg D.W.
0.93
3.5
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
< 0.95 mg/kg D.W.
0.95
3.6
SW846: 6010C
MMSD
11/19/19
11/20/19
DM1119119023797
DM1120/19023964
< 0.94 mg/kg D.W.
< 0.94 mg/kg D.W.
0.94
0.94
3.6
3.6
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/21/19
11/22/19
11/23/19
11/24/19
11/25/19
DM1121/19023996
DM1122/19024012
DM1123/19024023
DM1124119024220
DM1125/19024233
< 0.94 mg/kg D.W.
< 0.94 mg/kg D.W.
< 0.93 mg/kg D.W.
< 0.94 mg/kg D.W.
< 0.94 mg/kg D.W.
0.94
0.94
0.93
0.94
0.94
3.6
3.6
3.5
3.6
3.6
SW846: 6010C
SW846: 6010C
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
MMSD
MMSD
11/26/19
DM1126/19024576
< 0.93 mg/kg D.W.
0.93
3.5
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
< 0.93 mg/kg D.W.
0.93
3.5
SW846: 6010C
MMSD
11/28/19
11/29/19
11/30/19
DM1128119024644
DM1129/19024659
DM1130/19024670
< 0.94 mg/kg D.W.
< 0.94 mg/kg D.W.
< 0.94 mg/kg D.W.
0.94
0.94
0.94
3.6
3.6
3.6
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
Avg Result: 0 mg/kg D.W.
Min LOD: 0.92 mg/kg
D.W.
Page 2 of 16
SYS/rptlMrloMonthlyDW 4126119 U Printed: 1211311914:31

M-S.0
rARM M A tHAM EI UNWI R
COPPER ICP Dry wt.
Sarimple Date Sample ID
11/01/19 DM1101119022183
Result
220 mg/kg D.W.
6.9
26
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
SW846: 6010C MMSD
11/02/19
DM1102/19022194
220 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/03/19
DM1103119022213
220 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/04/19
DM1104119022226
220 mg/kg D.W.
6.9
26
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
230 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
230 mg/kg D.W.
6.7
26
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
240 mg/kg D.W.
6.7
25
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
250 mg/kg D.W.
6.7
26
SW846: 6010C
MMSD
11/10/19
DM1110119022978
250 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111/19022991
DM1112119023017
250 mg/kg D.W.
250 mg/kg D.W.
6.8
6.9
26
26
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
240 mg/kg D.W.
6.7
26
SW846: 6010C
MMSD
11/14/19
11/15/19
DM1114/19023645
DM1115119023660
240 mg/kg D.W.
230 mg/kg D.W.
6.7
6.8
26
26
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/16/19
DM1116/19023738
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/17/19
DM1117119023757
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/19/19
DM1119/19023797
220 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/20/19
11/21/19
DM1120/19023964
DM1121/19023996
240 mg/kg D.W.
240 mg/kg D.W.
6.8
6.8
26
26
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/22/19
11/23/19
DM1122/19024012
DM1123/19024023
200 mg/kg D.W.
240 mg/kg D.W.
6.8
6.7
26
26
Q3. SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/24/19
DM1124/19024220
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
240 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
210 mg/kg D.W.
6.7
26
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
240 mg/kg D.W.
6.7
26
SW846: 6010C
MMSD
11/28/19
DM1128119024644
210 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/29/19
DM1129119024659
210 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
11/30/19
DM1130119024670
210 mg/kg D.W.
6.8
26
SW846: 6010C
MMSD
Avg Result: 230 mg/kg D.W.
Min LOD: 6.7 mg/kg D.W.
Max Result: 250 mg/kg D.W.
Page 3 of1E
SYS/rptlMiloMonthlyDW 4126119 tj Printed:17./13/1914:31

J
Monthly Milorganite Report DW
i
HSD
November 2019
P3l61? M ttR a Ctula INEAWIF
Milorganite Daily Composite
IRON ICP Dry wt.
Da -
OD
LOQ
11/01/19
DM1101/19022183
44000 mg/kg D.W.
550
2000
SW846: 6010C
MMSD
11/02/19
DM1102/19022194
45000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
44000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/04/19
DM1104119022226
47000 mg/kg D.W.
550
2000
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
43000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/06/19
DM1106119022391
45000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
45000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/08/19
DM1108119022948
45000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
45000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
46000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/11/19
DM1111/19022991
47000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/12/19
DM1112119023017
47000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/13/19
DM1113/19023033
51000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/14/19
DM1114119023645
59000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
52000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
48000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
48000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
48000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/19/19
DM1119/19023797
48000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/20/19
DM1120/19023964
51000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/21/19
DM1121/19023996
51000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/22/19
DM1122/19024012
43000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/23/19
DM1123/19024023
50000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/24/19
DM1124/19024220
48000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
46000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
45000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
44000 mg/kg D.W.
530
1900
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
45000 mg/kg D.W.
540
2000
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
46000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
50000 mg/kg D.W.
540
1900
SW846: 6010C
MMSD
Avg Result: 47000 mg/kg D.W.
Min LOD:
530 mg/kg D.W.
Max Result: 59000 mg/kg D.W.
Page 4 of 16
5Y5/rpt1 MWoMonthlyDW 4126119 tj Printed: 1211311914:31

r
2 Monthly Milorganite Report DW
HNSD November 2019
9I1E1R U RR I ClflAlR E11 INIF
Milorganite Daily Composite
LEAD ICP Dry wt.
Sample Oate. Sample ID R"uft O. LQQ Q•
11/01/19 DM1101/19022183 51 mg/kg D.W. 3 8.9 SW846: 6010C f MMSD
11/02/19 DM1102119022194 50 mg/kg D.W. 2.9 8.8 SW846: 6010C MMSD
11/03/19
DM1103/19022213
45 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/04/19
DM1104119022226
45 mg/kg D.W.
3
8.9
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
41 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
40 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
39 mg/kg D.W.
2.9
8.6
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
42 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
41 mg/kg D.W.
2.9
8.6
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
41 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111/19022991
DM1112/19023017
40 mg/kg D.W.
39 mg/kg D.W.
2.9
2.9
8.8
8.8
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
38 mg/kg D.W.
2.9
8.6
SW846: 6010C
MMSD
11/14/19
DM1114/19023645
39 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
35 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/16/19
DM1116119023738
33 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/17/19
DM1117119023757
33 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
33 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/19/19
DM1119/19023797
33 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/20/19
DM1120/19023964
44 mg/kg D.W.
2.9
8.8
SW846: 6010C
MMSD
11/21/19
DM1121/19023996
30 mg/kg D.W.
2.9
8.7
SW846: 6010C
MMSD
11/22/19 DM1122/19024012 26 mg/kg D.W. 2.9 8.8
11/23/19 DM1123/19024023 30 mg/kg D.W. 2.9 8.7
11/24/19 DM1124/19024220 31 mg/kg D.W. 2.9 8.7
SW846: 6010C MMSD
SW846: 6010C MMSD
SW846: 6010C MMSD
11/25/19 DM1125/19024233 30 mg/kg D.W. 2.9 8.7 SW846: 6010C MMSD
11/26/19 DM1 126/1 9024576 35 mg/kg D.W. 2.9 8.6 SW846: 6010C MMSD
11/27/19 DM1127/19024593 32 mg/kg D.W. 2.9 8.7 SW846: 6010C MMSD
11/28/19 DM1128/19024644 36 mg/kg D.W. 2.9 8.8 SW846: 6010C MMSD
11/29/19 DM1129/19024659 33 mg/kg D.W. 2.9 8.7 SW846: 6010C MMSD
11/30/19 DM1130/19024670 33 mg/kg D.W. 2.9 8.8 SW846: 6010C MMSD
Avg Result: 37 mg/kg D.W. Min LOD: 2.9 mg/kg D.W. Max Result: 51 mg/kg D.W.
Page S of 16
SYS/rptlMi/oMonthlyDW 4126119 tj Printed., 1211311914:31

Monthly Milorganite Report DW
HSDNovember
2019
PART US fCIA CUM E1PR 111
Milorganite Daily Composite
MOLYBDENUM ICP Dry wt.
1- i_,Xarnple1
Result
LOD
LOQ
i-
11/01/19
DM1101/19022183
8.8 mg/kg D.W.
4.6
18
3.
SW846: 6010C
--
MMSD
11/02/19
DM1102/19022194
8.8 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/03/19
DM1103119022213
9.4 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
9.5 mg/kg D.W.
4.6
18
3.
SW846: 6010C
MMSD
11/05/19
DM1105119022376
8.6 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
8.8 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
8.4 mg/kg D.W.
4.4
17
1
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
9.3 mg/kg D.W.
4.5
17
1.
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
9.6 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
9.7 mg/kg D.W.
4.6
17
1
SW846: 6010C
MMSD
11/11/19
DM1111/19022991
9.6 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/12/19
DM1112/19023017
9.4mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/13/19
DM1113/19023033
9.8 mg/kg D.W.
4.5
17
1.
SW846: 6010C
MMSD
11/14/19
DM1114/19023645
9.9 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
9.8 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
9 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/17/19
DM1117119023757
9.4 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/18/19
DM1118119023770
9.1 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/19/19
DM1119119023797
9.2 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/20/19
DM1120119023964
10 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/21/19
DM1121119023996
13 mg/kg D.W.
4.5
17
3, Q3.
SW846: 6010C
MMSD
11/22/19
DM1122/19024012
8 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/23/19
DM1123/19024023
8.7 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/24/19
DM1124/19024220
8.6 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
8.8 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
9.9 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
9.4 mg/kg D.W.
4.5
17
3.
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
10 mg/kg D.W.
4.6
17
3.
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
9.7 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
9.7 mg/kg D.W.
4.5
17
1
SW846: 6010C
MMSD
Avg Result: 9.4 mg/kg D.W.
Min LOD:
4.4 mg/kg D.W.
Max Result: 13 mg/kg D.W.
Page 6 of 16
SYS/rptlMi1oMoMM1yDW 4126119 U Printed. 1211311914:31

ef,NSD
PMi f x ElE 4k ENiIIGNNEEIif
NICKEL ICP Dry wt.
Dam Sampfe 10
11/01/19 DM1101/19022183
Result
26 mg/kg D.W.
LOD
3.3
LOQ
9.9
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
s-
SW846: 6010C MMSD
11/02/19
DM1102/19022194
26 mg/kg D.W.
3.3
9.8
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
26 mg/kg D.W.
3.3
9.8
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
25 mg/kg D.W.
3.3
9.9
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
24 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
24 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
24 mg/kg D.W.
3.2
9.5
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
26 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/09/19
DM1109119022959
26 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
26 mg/kg D.W.
3.2
9.8
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111/19022991
DM1112/19023017
26 mg/kg D.W.
26 mg/kg D.W.
3.2
3.3
9.7
9.8
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
26 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/14/19
11/15/19
DM1114/19023645
DM1115119023660
31 mg/kg D.W.
28 mg/kg D.W.
3.2
3.2
9.6
9.7
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/16/19
DM1116119023738
26 mg/kg D.W.
3.3
9.8
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
26 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
27 mg/kg D.W.
3.3
9.8
SW846: 6010C
MMSD
11/19/19
DM1119119023797
27 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/20/19
DM1120/19023964
28 mg/kg D.W.
3.2
9.8
SW846: 6010C
MMSD
11/21/19
DM1121/19023996
31 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/22/19
11/23/19
DM1122/19024012
DM1123/19024023
20 mg/kg D.W.
29 mg/kg D.W.
3.2
3.2
9.7
9.6
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/24/19
DM1124/19024220
28 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
29 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/26/19
DM1126119024576
28 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
29 mg/kg D.W.
3.2
9.6
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
29 mg/kg D.W.
3.2
9.8
SW846: 6010C
MMSD
11/29/19
DM1129119024659
28 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
28 mg/kg D.W.
3.2
9.7
SW846: 6010C
MMSD
Avg Result: 27 mg/kg D.W.
Min LOD: 3.2 mg/kg D.W.
Max Result: 31 mg/kg D.W.
Page 7 of 16
5Y5/r.pt1N11oMonth/yDW 4126119 tj Printed: 121131191421

;j
Monthly Milorganite Report DW
NNSOD
November 2019
,1
PARM fix Ct?, w ff#IKAWIW
Milorganite Daily Composite
PHOSPHORUS ICP Dry wt.
IN
11/01/19
DM1101/19022183
23000 mg/kg D.W.
24
92
SW846: 6010C
MMSD
11/02/19
DM1102t19022194
23000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
23000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
23000 mg/kg D.W.
24
92
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
22000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
23000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
23000 mg/kg D.W.
23
89
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
24000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
23000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/10/19
DM1110119022978
24000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/11/19
DM1111119022991
24000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/12/19
DM1112/19023017
24000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/13/19
DM1113/19023033
25000 mg/kg D.W.
23
89
SW846: 6010C
MMSD
11/14/19
DM1114119023645
26000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
26000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
24000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
25000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
25000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/19/19
DM1119119023797
25000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/20/19
DM1120119023964
26000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/21/19
DM1121/19023996
25000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/22/19
DM1122/19024012
21000 mg/kq.D.W.
24
91
Q2. SW846: 6010C
MMSD
11/23/19
DM1123/19024023
25000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/24/19
DM1124/19024220
25000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/25/19
DM1125119024233
24000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
24000 mg/kg D.W.
23
90
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
24000 mg/kg D.W.
24
90
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
25000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
25000 mg/kg D.W.
24
91
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
25000 mg/kg D.W.
24
91
SW845: 6010C
MMSD
Avg Result: 24000 mg/kg D.W.
Min LOD: 23 mg/kg D.W.
Max Result: 26000 mg/kg D.W.
Page 8 of lE
SY5/rpt1Ni10M017th1yDW 4126119 U Printed: 1211311914:31

r.
14MSD
PAW Wt �, (two EyttlMNiNii`
POTASSIUM ICP Dry wt.
Sampl[e ID
11/01/19 DM1101/19022183
Result
4700 mg/kg D.W.
ra
300
LOQ
890
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
QA Flags Analytical Mehod
SW846: 6010C MMSD
11/02/19
DM1102119022194
5100 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/03/19
DM1103119022213
4800 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/04/19
DM1104119022226
4700 mg/kg D.W.
300
890
SW846: 6010C
MMSD
11/05/19
DM1105119022376
4400 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
4100 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
4000 mg/kg D.W.
290
860
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
4100 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
3900 mg/kg D.W.
290
860
SW846: 6010C
MMSD
n/10/19
DM1110/19022978
3900 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111/19022991
DM1112/19023017
3700 mg/kg D.W.
3800 mg/kg D.W.
290
290
880
880
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
3500 mg/kg D.W.
290
860
SW846: 6010C
MMSD
11/14/19
DM1114/19023645
3500 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
3800 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
4000 mg/kg D.W.
290
880
Q2. SW846: 6010C
MMSD
11/17/19
DM1117/19023757
3700 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/18/19
DM1118119023770
4000 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/19/19
DM1119119023797
3700 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/20/19
DM1120119023964
3600 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/21/19
DM1121/19023996
3300 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/22/19
11/23/19
DM1122/19024012
DM1123/19024023
3200 mg/kg D.W.
4900 mg/kg D.W.
290
290
880
870
Q2. SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/24/19
DM1124/19024220
4800 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
5000 mg/kg D.W.
290
870
Q2. SW846: 6010C
MMSD
11/26/19
DM1126/19024576
4400 mg/kg D.W.
290
860
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
4100 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
4700 mg/kg D.W.
290
880
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
4600 mg/kg D.W.
290
870
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
4000 mg/kg D.W.
290
880
SW846: 6010C
MMSD
Avg Result: 4100 mg/kg D.W.
Min LOD: 290 mg/kg D.W.
Max Result: 5100 mg/kg D.W.
Page 9 of 16
5Y5/rpt1Mi10MonthtyDW 4126119 tj Printed: 12/1311914:31

11/02/19
DM1102/19022194
5.5 mg/kg D.W.
4.2
13
1
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
5.2 mg/kg D.W.
4.2
13
J.
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
6.1 mg/kg D.W.
4.3
13
J.
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
<4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/06/19
11/07/19
DM1106/19022391
DM1107/19022933
< 4.2 mg/kg D.W.
<4.1 mg/kg D.W.
4.2
4.1
13
13
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/08/19
DM1108119022948
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/10/19
DM1110/19022978
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/11/19
11/12/19
11/13/19
DM1111119022991
DM1112/19023017
DM1113/19023033
< 4.2 mg/kg D.W.
< 4.2 mg/kg D.W.
<4.1 mg/kg D.W.
4.2
4.2
4.1
13
13
13
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
11/14/19
DM1114/19023645
11 mg/kg D.W.
4.2
13
J.
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/18/19
11/19/19
11/20/19
DM1118/19023770
DM1119/19023797
DM1120119023964
4.6 mg/kg D.W.
< 4.2 mg/kg D.W.
5.5 mg/kg D.W.
4.2
4.2
4.2
13
13
13
J.
J.
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
11/21/19
DM1121/19023996
< 4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/22/19
11/23/19
11/24/19
D M 1122/19024012
DM1123119024023
DM1124/19024220
< 4.2 mg/kg D.W.
<4.2 mg/kg D.W.
4.3 mg/kg D.W.
4.2
4.2
4.2
13
13
13
J.
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
11/25/19
DM1125/19024233
<4.2 mg/kg D.W.
4.2
13
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
6.3 mg/kg D.W.
4.2
13
J, Q2.
SW846: 6010C
MMSD
11/27/19
11/28/19
11/29/19
11/30/19
DM1127/19024593
DM1128/19024644
DM1129/19024659
DM1130/19024670
Avg Result: 2.9 mg/kg D.W.
4.7 mg/kg D.W. 4.2 13
11 mg/kg D.W. 4.2 13
9.8 mg/kg D.W. 4.2 13
9.3 mg/kg D.W. 4.2 13
Min LOD: 4.1 mg/kg D.W.
J.
J.
J.
J.
SW846: 6010C
SW846: 6010C
SW846: 6010C
SW846: 6010C
Max Result: 11 mg/kg D.W.
MMSD
MMSD
MMSD
MMSD
Page 10 of 16
SYS/rptIMiloMonthlyDW 4126119 0 Printed: I2/1311914:31

r'
MMSD
PiSTNIU f0t A cam ffitN9 wEll
Solids (% Moisture)
Date Sample ID
11/01/19 DM1101/19022183
Resutt
8.9 %
LOD
0.1
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
LOQ QA Flags- - -
SM 2540 G (1997) MMSD
11/02/19
DM1102/19022194
8.1 %
0.1
SM 2540 G (1997)
MMSD
11/03/19
DM1103/19022213
8.2 %
0.1
SM 2540 G (1997)
MMSD
11/04/19
DM1104/19022226
8.9 %
0.1
SM 2540 G (1997)
MMSD
11/05/19
DM1105/19022376
7.6 %
0.1
SM 2540 G (1997)
MMSD
11/06/19
DM1106/19022391
6.5 %
0.1
SM 2540 G (1997)
MMSD
11/07/19
DM1107/19022933
5.7 %
0.1
SM 2540 G (1997)
MMSD
11/08/19
DM1108/19022948
6.8 %
0.1
SM 2540 G (1997)
MMSD
11/09/19
DM1109/19022959
6.4 %
0.1
SM 2540 G (1997)
MMSD
11/10/19
DM1110/19022978
7.9 %
0.1
SM 2540 G (1997)
MMSD
11/11/19
DM1111119022991
7.6 %
0.1
SM 2540 G (1997)
MMSD
11/12/19
DM1112/19023017
8.2 %
0.1
SM 2540 G (1997)
MMSD
11/13/19
DM1113/19023033
6 %
0.1
SM 2540 G (1997)
MMSD
11/14/19
DM1114/19023645
6.6 %
0.1
SM 2540 G (1997)
MMSD
11/15/19
DM1115119023660
6.8 %
0.1
SM 2540 G (1997)
MMSD
11/16/19
DM1116/19023738
8.1 %
0.1
SM 2540 G (1997)
MMSD
11/17/19
DM1117119023757
6.9 %
0.1
SM 2540 G (1997)
MMSD
11/18/19
DM1118119023770
8 %
0.1
SM 2540 G (1997)
MMSD
11/19/19
DM1119/19023797
7.3 %
0.1
SM 2540 G (1997)
MMSD
11/20/19
DM1120/19023964
8 %
0.1
SM 2540 G (1997)
MMSD
11/21/19
DM1121119023996
7.3 %
0.1
SM 2540 G (1997)
MMSD
11/22/19
11/23/19
DM1122/19024012
DM1123119024023
7.6 %
6.5 %
0.1
0.1
SM 2540 G (1997)
SM 2540 G (1997)
MMSD
MMSD
11/24/19
DM1124/19024220
7.2 %
0.1
SM 2540 G (1997)
MMSD
11/25/19
DM1125/19024233
7.2 %
0.1
SM 2540 G (1997)
MMSD
11/26/19
DM1126/19024576
6.3 %
0.1
SM 2540 G (1997)
MMSD
11/27/19
DM1127/19024593
6.5 %
0.1
SM 2540 G (1997)
MMSD
11/28/19
DM1128/19024644
7.7 %
0.1
SM 2540 G (1997)
MMSD
11/29/19
11/30/19
DM1129/19024659
DM1130/19024670
7.3 %
7.7 %
0.1
0.1
SM 2540 G (1997)
SM 2540 G (1997)
MMSD
MMSD
Avg Result: 7.3 %
Min LOD. 0.1 %
Max Result: 8.9 0/6
Page 11 of 16
SYS/rptlMiloMonthlyOW 4126119 tj Printed: 1211311914:31

r:
-= r
f
NSD
P�R?AFRi ifs A Ct14�it 6!►l3sCAR[18
ZINC ICP Dry wt.
,. -
..
Monthly Milorganite Report DW
November 2019
Milorganite Daily Composite
11/01/19
DM1101/19022183
450 mg/kg D.W.
19
56
SW846: 6010C
MMSD
11/02/19
DM1102/19022194
440 mg/kg D.W.
18
56
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
430 mg/kg D.W.
18
56
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
430 mg/kg D.W.
19
56
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
400 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/06/19
DM1106/19022391
420 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/07/19
DM1107119022933
420 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/08/19
DM1108/19022948
460 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/09/19
DM1109/19022959
450 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/10/19
DM1110119022978
460 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111/19022991
DM1112/19023017
460 mg/kg D.W.
440 mg/kg D.W.
18
18
55
56
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
460 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/14/19
DM1114/19023645
480 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
460 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/16/19
DM1116119023738
430 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/17/19
DM1117/19023757
440 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
440 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/19/19
DM1119/19023797
430 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/20/19
DM1120/19023964
470 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/21/19
11/22/19
11/23/19
DM1121/19023996
DM1122119024012
DM1123/19024023
430 mg/kg D.W.
350 mg/kg D.W.
450 mg/kg D.W.
18
18
18
55
55
54
SW846: 6010C
SW846: 6010C
SW846: 6010C
MMSD
MMSD
MMSD
11/24/19
DM1124/19024220
450 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
440 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
450 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/27/19
DM1127119024593
420 mg/kg D.W.
18
54
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
430 mg/kg D.W.
18
55
SW846: 6010C
MMSD
11/29/19
11/30/19
DM1129119024659
DM1130/19024670
Avg Result: 440 mg/kg D.W.
430 mg/kg D.W. 18 55
440 mg/kg D.W. 18 55
Min LOD: 18 mg/kg D.W.
SW846: 6010C
SW846: 6010C
Max Result: 480 mg/kg D.W.
MMSD
MMSD
Page 12 of 16
SYS1rpt1MiloMonth1yDW 4126119 q Printed: 12/13/1914.31

NMSDNovember
P1110 ratas:UAM MIWI
Phosphorus - Total % DW (Calc.)
11/01/19 DM1101119022183
2.3 % D.W.
0.1
0.1
Monthly Milorganite Report DW
2019
Milorganite Daily Composite
SW846: 6010C MMSD
11/02/19
DM1102/19022194
2.3 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/03/19
DM1103/19022213
2.3 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/04/19
DM1104/19022226
2.3 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/05/19
DM1105/19022376
2.2 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/06/19
DM1106119022391
2.3 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/07/19
DM1107/19022933
2.3 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/08/19
11/09/19
DM1108/19022948
DM1109/19022959
2.4 % D.W.
2.3 % D.W.
0.1
0.1
0.1
0.1
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/10/19
DM1110/19022978
2.4 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/11/19
11/12/19
DM1111119022991
DM1112/19023017
2.4 % D.W.
2.4 % D.W.
0.1
0.1
0.1
0.1
SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/13/19
DM1113/19023033
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/14/19
DM1114119023645
2.6 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/15/19
DM1115/19023660
2.6 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/16/19
DM1116/19023738
2.4 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/17/19
DM1117119023757
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/18/19
DM1118/19023770
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/19/19
DM1119119023797
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/20/19
DM1120/19023964
2.6 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/21/19
DM1121119023996
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/22/19
11/23/19
DM1122/19024012
DM1123119024023
2.1 % D.W.
2.5 % D.W.
0.1
0.1
0.1
0.1
Q2. SW846: 6010C
SW846: 6010C
MMSD
MMSD
11/24/19
DM1124/19024220
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/25/19
DM1125/19024233
2.4 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/26/19
DM1126/19024576
2.4 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/27/19
DM1127/19024593
2.4 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/28/19
DM1128/19024644
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/29/19
DM1129/19024659
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
11/30/19
DM1130/19024670
2.5 % D.W.
0.1
0.1
SW846: 6010C
MMSD
Avg Result: 2.4 % D.W.
Min LOD:
0.1 % D.W.
Max Result: 2.6 % D.W.
Milorganite Weekly
Composite
ALUMINUM ICP Dry wt.
11/09/19
WMC45/19023019
5000 mg/kg D.W.
57
200
B8. SW846: 6010C
MMSD
Avg Result: 5000 mg/kg D.W.
Min LOD:
57 mg/kg D.W.
(Milo) Ammonia in Fertilizer
Sample In
..
11/09/19
1,F
AOAC (13) 2.065
MMSD
WMC45/19023019
0.2 %
0.11
0.37
Avg Result: 0.2 % Min LOD: 0.11
Page 13 of 16
SY5/rpt1M1/aMonth/yDW 4126119 tj Printed., 1211311914:31

1NSD
i�ffINEiS if4d,t t1U�#R E!FliNAi?�'
Monthly Milorganite Report DW
November 2019
Milorganite Weekly Composite
BORON ICP Dry wt.
11/09/19 WMC45119023019 20 mg/kg D.W. 1.2 3.8 SW846: 6010C CT Lab
Avg Result: 20 mg/kg D.W. Min LOD: 1.2 mg/kg D.W.
CHROMIUM Dry wt.
19WMC45/19023019 :1 mg/kg 6010C MMSD
Avg Result: 180 mg/kg D.W. Min LOD: 1.6 mg/kg D.W.
COBALTDry wt.
;Sample F)afe Sarirpte ICI r " x_ Resu[t LOD E©t f QA F[ t.� /lt�aca't Meihod 1' Lab'
19WMC45/19023019 mg/kg D.W. 1 6010C MMSD
Avg Result: 1.9 mg/kg D.W. Min LOD: 0.28 mg/kg D.W.
MERCURY by M. 7471 (sludge)
1
t-T01
!A III, J
11/02/19
WMC44/19022228
0.14 mg/kg D.W.
0.014
0.049 EPA 7471E Cr i ab
11/09/19
WMC45119023019
0.31 mg/kg D.W.
0.015
0.05 EPA 7471B CT Lab
11/16/19
WMC46/19023799
0.28 mg/kg D.W.
0.014
0.047 EPA 7471E CT Lab
11/23/19 WMC47/19024235 0.29 mg/kg D.W. 0.022 0.072
11/30/19 WMC48/19024704 0.21 mg/kg D.W. 0.024 0.079
Avg Result: 0.25 mg/kg D.W. Min LOD: 0.014 mg/kg D.W.
EPA 7471
EPA 7471
Max Result: 0.31 mg/kg D.W.
Pace -GB
Pace -GB
NITRATE NITROGEN
11/09/19 WMC45/19023019 0.95 % 0.5 AOAC (16) 936.01 MMSD
Avg Result: 0.95
Min LOD: 0.5 %
NITROGEN-Total(Manual)
-
11/09/19 WMC45/19023019 5.6 % 0.11
Avg Result: 5.8 o/u Min LOD: 0.11 %
NITROGEN -Water Insoluble
11/09/19 WMC45/19023019
Avg Result: 4.4 %
pH -Solids
11/02/19
11/09/19
WMC44/19022228
WMC45/19023019
11/16/19
WMC46119023799
11/23/19
WMC47/19024235
11/30/19
WMC48/19024704
Avg Result: 6.4 Stnd. Units
4.4 % 0.5
Min LOD: 0.5 %
{-will[
RIJr 11i/.
6.22 Stnd. Units
0.1
6.4 Stnd. Units
0.1
6.54 Stnd. Units
0.1
6.45 Stnd. Units
0.1
6.42 Stnd. Units 0.1
Min LOD: 0.1 Stnd. Units
TPIT... - ` .ri.
AOAC (16) 955.04 MMSD
AOAC (16) 945.01 MMSD
SW846:9045D
MMSD
SW846:9045D
MMSD
SW846:9045D
MMSD
SW846:9045D
MMSD
SW846:9045D
MMSD
Max Result: 6.54 Stnd. Units
Page 14 of.I
SY5/rptlMiloMonffiIyDW 4126119 tj Printed: 121131191421

f'
Monthly Milorganite Report DW
MNSDNovember
2019
vacs M folr A cum [4 IKA111F
Milorganite Weekly Composite
Solids (% Moisture)
LOQ
11/02/19 WMC44119022228
7.4 %
..
0.1
..
SM 2540 G (1997) MMSD
11/09/19 WMC45/19023019
7.1 %
0.1
SM 2540 G (1997) MMSD
11/16/19 WMC46/19023799
7.2 %
0.1
SM 2540 G (1997) MMSD
11/23/19 WMC47/19024235
7.3 %
0.1
SM 2540 G (1997) MMSD
11/30/19 WMC48/19024704
7.3 %
0.1
SM 2540 G (1997) MMSD
Min LOD: 0.1
Solids (% Volatile)
• r a. •a s•
11/09/19 WMC45/19023019 70 % 0.1 SM 2540 G (1997) MMSD
Avg Result: 70 % Min LOD: 0.1
Solids (% Total)
-?s Rwult .. LOO
11/09/19 WMC45/19023019 93 % 0.1 SM 2540 G (1997) MMSD
Avg Result: 93 % Min LOD: 0.1 %
Milorganite (Outfall 006) PRODUCTION
FECAL COLIFORM SLUDGE
11/05/19
19024612
< 0.2 MPN/g TS
0.2
EPA 1680 MMSD
11/12/19
19025081
0.21 MPN/g TS
0.19
EPA 1680 MMSD
11/19/19
19025549
< 0.2 MPN/g TS
0.2
Q3. EPA 1680 MMSD
11/26/19
19025878
0.99 MPN/g TS
0.19
EPA 1680 MMSD
Min LOD: 0.19 MPN/g TS
Solids (% Total)
11/05/19 19024612 92 % 0.1 SM 2540 G (1997) MMSD
11/12/19 19025081 94 % 0.1 SM 2540 G (1997) MMSD
11/19/19 19025549 91 % 0.1 5M 2540 G (1997) MMSD
11/26/19 19025878 94 % 0.1 5M 2540 G (1997) MMSD
Avg Result: 93 % Min LOD: 0.1 % Max Result: 94 %
Milorganite (Outfall 009) BAGGING
FECAL COLIFORM SLUDGE
11/12/19 19025083 < 0.19 MPN/g TS 0.19 EPA 1680 MMSD
Min LOD: 0.19 MPN/g TS
Page 15 of 16
SY5/rpt1M11oMonth/yDW 4126119 U Printed: 1211311914:31

FECAL COLIFORM SLUDGE
11/12/19 19025082
< 0.19 MPN/g TS 0.19
Min LOD: 0.19 MPN/g TS
Milorganite (Outfall 008) SHIPPING
EPA 1680 MMSD
Solids (0/o Total)
annple as to s Sample ID ;':N z fRe"sult _ r ' LODI LOi� " QA':Fla9s s Ana i"Mlethod Lab
_:,:-.._,.ems:. ,._-�_,. x�;-�.�,•;
11/12/19
•125nR,2 93% 0.1 SM 2540 D
Avg Result: 93
Min LOD: 0.1
Z.
AO Other Flag requires additional explanation IS InsufFlcient sample volume for analysis.
AX Qualified data - see contract laboratory report J Estimated concentration above the adjusted method detection limit
B3 Target analyte detected in method blank > 10% of sample and below the adjusted reporting limit
concentration. LA Not analyzed - laboratory accident.
B7 LCS recovery was above control limits. M3 Too numerous to count.
B8 LCS recovery was below control limits.
B9 Low Level CCV recovery was outside of method acceptance limits
CQ Data used for calculation of result was qualified
DI Duplicate precision control limit was exceeded.
D2 Matrix spike precision control limit was exceeded.
D3 Sample is heterogeneous. Sample homogeneity could not be readily
achieved using routine laboratory practices.
D4 Sample matrix interferences did not allow completing the analysis.
DS The reported result is an estimate because the concentration of
HEM in this sample exceeded the maximum allowed in the method
for the sample volume collected.
H1 Sample was received past holding time.
H3 Analysis performed beyond holding time.
H4 Initial analysis within holding time. Reanalysis for the required
dilution was past holding time.
HS Analysis performed beyond holding time.
M2 Sample incubation period outside method requirement.
M3 Spreading colonies - unable to determine result. _
M4 Results are an approximation due to spreading colonies.
M5 Incubator/water bath temperature was outside method
requirements. _
M7 Microbiology sample received without adequate headspace.
M9 Target organism detected in associated method blank.
NR Not usable data. (Water Quality only.)
NU Not usable Data.
P2 Sample received with improper or inadequate chemical preservation.
Q2 Matrix spike recovery for this sample was above control limits.
Q3 Matrix spike recovery for this sample was below control limits.
RT Sample temperature upon receipt exceeded regulatory or project
requirements.
SS Reading was not confirmed by a constant weight measurement
SD Supplemental details provided.(Water Quality only.)
T3 The BOD dilution water D.O. depletion was > 0.2 mg/L.
T4 GGA BOD was below method acceptance criteria.
TS GGA BOD was above method acceptance criteria.
T7 The BOD dilution water D.O. increase was > 0.2 mg/L.
T8 Sample matrix did not allow adjusting sample pH for BOD.
T9 Sample is outside of the prescribed method temperature range.
Page 16 of IE
SY5/rptlMifoMonthtyDW 4126119 tj Printed: 1211311914.31

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