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WQ0014248_Residual Annual Report 2019_20200303
Town of Cheraw Public Utility Department February 26, 2020 Ms. Sonia Gregory NCDENR/DWQ/Water Quality Section Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Dear Ms. Gregory: Enclosed is the annual Biosolids marketing and distribution report. Please contact me if you have any questions or comments. Sincerely, A4Y jumultl— Sherly Turner Town of Cheraw E� IVEQ!NCC�EQ!awR R Non -Desch Uri permitting R.Fr-1=111pr) MAR p 2C2C Post Office Box 219 1 Cheraw, South Carolina 29520 1 843-537-8440 1 F: 843-537-8442 1 www.cheraw.com AniN ua1, LAA1J AYYLIUA 11U1N (;L+'RTIFIUATION t URM Permit#: . WO0014248 County: Facility Name (as shown on permit): Land Application Operator: Chesterfield Town of Cheraw Year: 2019 Phone: (843)537-8440 Land application of residual solids as allowed by the permit occurred during the past calender year? ® Yes ❑ No If No, skip Part A, and Part B and proceed to the certification. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A: Total number of application fields in permit: Total number of fields land application occurred during the year: 3 Total amount of dry tons applied during the year for all application sites: 70.2 Total number of acres land application occurred during the year: 117 Part B: Facility was compliant during calendar year 2019 with all conditions of the land application permit (including but not limited to items 1-12 below) issued by the Division of Water Quality. ® Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in Table 1 of 40 CFR Part 503.13 or the Pollutant Loading Rates in Table 2 of 40 CFR part 503.13 (applicable to 40 CFR Part 503 regulated facilities) 7. All general requirements in 40 CFR Part 503.12 and management practices in 40 CFR Part 503.14 were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 9. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 10. Vegetative cover as specified in the permit was maintained on this site and the crops grown were removed in accordance with the crop management plan. 11. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 12. All buffer requirements as specified on the permit were maintained during each application of residuals. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sherry Turner / Operator -of -Record Permittee Name and Title (type or print) Signature of Preparer* (if different from Permittee) * Preparer is defined in 40 CFR Part 503.9 (r) Z Lb Za Signatur f Permittee date Date Signiture of Land Applier Date (if different from Permittee and Preparer) Author Daryl D. Merritt DENR FORM ACF (7/2002) ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM PERMIT #: WQ0014248 - FACILITY NAME: Town of Cheraw PHONE: (843) 537-8440 COUNTY: Chesterfield' OPERATOR: FACILITY TYPE (please check one): Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? ® Yes []No No If No skin Darts A. B. C and certifv form below f Part A*: Part B*: Month January Sources s (include NPDES # if applicable) Volume (dry tons) Recipient Information Admendmend Bulking Agent Residual In Product Out Name(s) Allan Baucom Volume (dry tons) 28.5 Intended use(s) crops February No Residuals Allan Baucom 19.7 crops March produced during Allan Baucom 2 0 crops April 2019, but distribution May June of residuals from 2018 took place July August September October vovember December Totals: Annual (dry tons): 70.2 Admendment(s) used: I I Bulking Agent(s) used: k If more space than given is required, please attach additional information sheet(s). ❑ Check box if additional sheet(s) are attached Part C: Facility was compliant during calendar year 2019 with all conditions of the. permit (including but not limited to items 1-3 below) issued by the Division of Water Quality. ® Yes ❑ No If No, please provide a written description why the facility was not compliant. �. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached ?. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 3. No contravention of Ground Water Quality Standards occurred at a monitoring well. 'I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false informaiton, including the possibility of fines and imprisonment for knowing viola`tions." jrll,u/ 2- -U. - zo signature of &rmittee - Date Signature of Preparer** Date (if different from Permittee) **Preparer is defined in 40 CFR Part 503.9(r) Author Daryl D. Merritt DENR FORM DMSDF (7/2002) TOWN OF CHERAW WASTEWATER TREATMENT FACILITY BIOSOLIDS REPORT 2019 PRESS DRY CAKE TONS LIME % TOTAL LIME $/ POLY $/ LBS. POLY/ LBS. POLY MONTH HOURS SOLIDS T. USED LIME DRY PROD. TON PROD. TON CAKE TON CAKE USED JAN 191.00 68.26 2.82 192.50 FEB 138.00 42.80 1.93 82.50 MAR 118.00 42.24 2.60 110.00 APR 174.00 69.34 1.59 110.00 MAY 247.00 88.12 2.34 206.25 JUN 250.00 95.84 2.15 .206.25 JUL 248.00 92.04 2.09 192.50 AUG 250.00 85.62 3.11 265.87 SEP 235.00 82.62 1.66 137.50 OCT 260.00 94.11 2.19 206.25 NOV 189.00 76.24 3.61 275.00 DEC 219.00 88.58 3.10 275.00 TOT 2,519.00 925.81 0.00 2,259.62 AVG 209.92 77.15 ERR ERR 35.36 ERR 'ERR 2.44 188.30 MIN 118.00 42.24 ERR ERR ERR ERR ERR 1.59 82.50 MAX 260.00 95.84 ERR ERR ERR ERR ERR 3.61 275.00 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: WQ0014248 L b t Facility Name: NPDES # or WQ#: WWTP Name: Residual Annlveic nata Town of Cheraw SCO020249 Town of Cheraw wwp a ora ory. 1) Davis & Brown nabs 2) Clemson University 3) 4) 5) Sample or Composite Date 1 /17/.19 1 /17/19 3/20/19 3/20/19 5/23/19 5/23/19 7/17/19 7/17/19 9/18/19 9/18/19 11 /20/19 11 /20/1 Percent Solids 71.30 66.35 75.70 79.92 52.90 52.43 58.10 65.65 64.10 60.33 67.80 58.24 Arsenic 3.17 1.62 --0.998 2.72 3.12 2.61 Cadmium Z- 0.991 0.999 0.499 <0.999 L1.99 0.989 Chromium 42.6 58.2 26.9 56.5 43.6 54.2 ,.d Copper 24.4 37.9 29.9 40.4 41.0 27.6 Lead 0.991 -0.999 a0.499 3.04 .--1.99 3.70 Mercury c 0.024 c 0.026 0.024 0.033 0.030 0.042 Molybdenum 19. 8 < 4. 00 c3.99 --3.99 3. 98 ,, 3. 95 Nickel 11.1 17.2 12.1 24.6 30-3 19.8 Selenium 0.991 e-0. 999 t_ 0. 998 ---*0. 999 c0. 995 0. 494 IQ .., Zinc 163 237 134 236 219 212 TKN . 0603 9416 15707 11835 15158 6654 Ammonia -Nitro e 452.2 250.3 267.0 152.3 165.8 0 Nitrate and Nitrite Total Phosphorus 4.80 8018 13.50 5724 46.30 12140 11.40 2292 10.70 10534 44.20 8019 " i certiry, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature if Preparer i - 9 'f . 7, Date Author Daryl D. Merritt DENR FORM RSSF (7/2002) ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Town of Cheraw Total Dry Tons Applied (Annual); 28.5 Permit #: WQ0014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Owner: Acres Used: 42 Acres Permitted: Site #: Prvor_ Field #: Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg % Solids use Raw Percent I j. ample or Corn- 1 /17/ 1 /17/ 2019 2019 posite Date + f % Solids 71.3 66.4 Arsenic 3.17 Cadmium e.991 Chromium 42.6 Copper 24.4 Lead . 991 Mercury & .024 NIolyb- den m �19.8 Nickel 11.1 Selenium -.991 Zinc 163 Total Phos- 8018 chorus Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): 1 certify, under penalty of Iaw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false Information. inciudingpe possibility o�fines and imprisonmentfor knowing violations" Signature of Land Applies #131te' Author Daryl D. Merritt DENR FORM MFLSF (W2002) ANNUAL, LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 28.5 Owner: Operator: Allan Baucom Cation Exchange Capacity (non 503): Site #: Joe Pryor Field #: Acres Utilized-.— Acres Permitted: Q S c`f Totals Per Acre © Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, y Wet, Moist Inches Precip. Past 24 Hrs. A li- pp cation Meth- od** Voli- Lila- nation Rate* Miner- ala- nation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN l PAN 2 Must Select Crop 1 or Crop p P 2 Gal. CuNd. Report Totals ;n Gal. Crop I Crop 2 Jan N/A _N/A .7130 0.68 S 0.5 10603 452.2 4.80 TOTALS: As Cd Cr Cu Pb Mo Ni Se Zn P PAN 1 PAN 2 Lime A lied Annuallbs/acre .0061 0019 .0813 .0465 .00190378 .0212 50019 .3 009 16.'44 Date lbs/ac Current Cumulative lbs/acre JHe .0061 .0019 .0813 .0465 .0019 0378 .0212 .0019 .3109 Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit Ist/2nd Crop .•1 certtty, under penalty or iaw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �-- t=, *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier bate **Volitilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) Boundary 2020 - 57 Joe Pryor Grower: A L Baucom Fann : 57 Joe Pryor Field: 57 Joe Pryor Year: - U11-t Operation: Boundary Crop / Product: NO Product L Op. Instance : Instance - 1 Field - Name 57 Joe Pryor(41.92 ac) Afe l' �-Pd ?moo 6 a, t�, A (35.042091,-80.1971.67) ifli-j -�,ft1bg�� 0,1 2e)-h ,4 1, fd { JU14 a.� �` A Wq &,F10 �,011 cfr f GokrVj (35.040712,-80.200195) 1/31/2020 2:06:47 PM Ag Leader Technology SM5 Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Deport Facility Name: Permit #: Operator: Acres Used: Town of Cheraw Total Dry Tons Applied (Annual): 19.7 WO_Q014248 Cation Exchange Capacity (non 503 only): Site #: Frederick S Field 4: _ Residual Analysis Data (Heavv Metals and Total Phosnhorns iise maAra. 0 fin1j Ae „gn Allan Baucom Owner: 38 Acres Permitted: Total Phos- Annual Heavy Metal Field Loadings (Calculated in Ihcfarre'l- i I Cefulb unaer penalty of taw, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, inacludingffie possibility of fines and imprisonment. for knowing violations" Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL, LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 19.7 Owner: Operator: Allan Baucom Cation Exchange Capacity (non 503): Site #: Frederick S Field #: Acres Utilized: 38 Acres Permitted: A Specify ec Totals Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) Site Cond. Dt y' Wet, Inches Precip. Past 24 Hrs. Appli- cation Meth- od** Voli- tila- zation Rate* Miner- ala- zation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN l PAN 2 Must Select Crop 1 or Crop P P 2 f CuNd. Report Totals in Gal. Crop 1 Crop 2 Feb N/A N/A .7130 0.53 S 0.5 10603 452.2 4.80 TOTALS: As Cd Cr Cu Pb Hg I Mo Ni Se I Zn P PAN 1 PAN 2 Lime Applied Annual lbs/acre . 0047 -0015 .063.3 .0363 c 0015 100004 4 0294 .0165 .0015 .2423 12.81 Date I lbs/ac Current Cumulative Ibs/acre .0047 .0015 .0633 .0363 ' 0015 .00004 `: 0294 .0165 `:0015 .2423 Prior Years Cumulative lbs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop V.K;l ly, Ulf ul 1=11" Ly vi law$ 1.114< tills mmurnenr was prepares unaer my airecuon or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier Date **Volitilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) L Boundary 2008 - 208 Fredrick Sparger Grower: A L Baucom (34.846147,-80.137949) Farm : 208 Fredrick Sparger Field: 208 Fredrick Sparger Year :-29W U11 Operation : Boundary Crop / Product: NO Product Instance : Instance - 1 Field - Name 208 Fredrick 5parger (37.85 ac) li`4 �,CX IL- f Q Vt 1660 ' t 1 `10(9 CYT - Gann- 1/31/2020 1:59:30 PM Ag Leader Technology SMS Advanced Page 1 of 1 ANNUAL METALS FIELD LOADING SUMMARY FORM Attach this form to the corresponding Field Loading Summary Form to he submitted In Annual Report Facility Name: Town of Cheraw Total Dry Tong Applied (Annual): 22.0 Permit #: W00014248 Cation Exchange Capacity (non 503 only): Operator: Allan Baucom Owner: .Acres Used: 37 Acres Permitted: Site #: Anson High Field is Residual .Analysis Data (Heavy Metals and Total Phosphorus use rng/kg, % Solids use Raw Percent #): Sample 3/20/ 3/20/ or Corn - 2019 2019 polite Date % Solids 75.7 79.9 Arsenic 1.62 Cadmium c. 999 Chromium 58.2 Capper 37.9 Lead .999 Mercury .026 hiolyb- den 4.00 Nickel 17.2 Selenium ,'— 999 Zinc 237 Tatal Phas- 5724 harus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): OMEN Total Phos- phorus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including )he possibility !�frmes and imprisonment.for knowing violations" Signature of Land Applier Date Author Daryl D. Merritt DENR FORM MFLSF (7/2002) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH APPLICATION FIELD. PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Town of Cheraw Permit #: WQ0014248 Annual Dry Tons Applied: 22.0 Owner: Operator: Allan Baucom Cation Exchange Capacity (non 503): Site #: Anson High School Field #: Acres Utilized: 37 Acres Permitted: �, s A S ec Totals Per Acre Solids As Deci- Dry Tons Per Acre Residual Sources (Summarize) site Cond. Dry, Wet, MoiSt Inches Precip, Past 24 Hrs. Appli- cation Meth- od** Voli- Lila- zation Rate* Miner- ala- zation Rate TKN Ammo nia- Ni- trogen Ni- trate- Ni- trogen PAN 1 PAN 2 Must Select Crop 1 or Crop P P 2 f Cu.Yd. Report Totals in Gal. Crop I Crop 2 Mar N/A N/A 0.757 0.59 S 0.5 9416 250.3 13.5 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN 1 PAN 2 Lime Applied Annuallbs/acre .0025 1.00114 .0907 .0591 .0014 500004 .0062 .0268 . 014 .3694 8.45 Date lbs/ac Current Cumulative lbs/acre .0025 .0014 .0907 .0591 .0014 0004 . 062 .0268 014 .3694 Prior Years Cumulative Ibs/acre Permitted C. P. L. R. * * * Permit PAN Limit 1 st/2nd Crop ••i certify, under penalty of law, that triis document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." z zZ w *Application Method: S - Surface, IN - Injection, INC - Incorporation Signature of Land Applier 6ate **Volitilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 ***C.P.L.R.: Cumulative Pollutant Loading Rate Author Daryl D. Merritt DENR FORM FSF (7/2002) i Boundary 2020 - 55 Anson High School (34.963666,-W,146755) Grower: A L Baucom Farm: 55 ANSON HIGH SCHOOL Field: 55 Anson High School Year: 0( Operation : Boundary Crop / Product: NO Product Op. Instance : Instance - 1 Field - Name 10 55 Anson High school (51.92 ac) 14Z 4 a V 6�j4 t9 n A -3q m4n5 ,iolq c for c6nn 1/31/2020 2:37:17 PM Ag Leader Technology SMS Advanced Page 1 of 1 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: January 16, 2019 Biosolids Maximum Maximum Maximum Maximum Metal Allowable Allowable Application Application Content, Metal App. Rate, Rate, Rate, METALS porn Content, ppm #/Acre/Yr. DT/Acre/Yr. WT/Acre/Yr. Arsenic, Total 2.98 41.00 1.80 200.17 301.68 Cadmium, Total 0.93 ' 39.00 1.70 604.72 911.41 Chromium, Total 40.09 1200.00 134.00 .1108.85 1671.21 Copper, Total 22.96 1500.00 67.00 967.97 1458.89 Lead, Total 0.93 300.00 13.00 4624.32 6969.58 Mercury, Total 0.02 ' 17.00 0.75 11016.10 16603.02 Molybdenum, Total 18.63 ' 18.00 0.80 14.24 21.47 Nickel, Total 10.45 420.00 18.70 593.88 895.07 Selenium, Total 0.93 36.00 4.50 1600.73 2412.55 Zinc, Total 153.40 1525.00 125.00 270.33 407.44 PCB BRL 1.60 ` Actual metal content less than amount indicated Biosolids Biosolids Maximum Maximum Nutrient Nutrient Crop/Soil Application Application Content, Content, Requirement, Rate, Rate, ppm % #/Acre " DT/Acre/Yr. WT/Acre/Yr. Ammonium Nitrogen 300.00 0.03 Organic Nitrogen 6735.00 0.67 Incorporated Available Nitrogen 4335.00 0.43 120.00 9.18 13.84 Surface Available Nitrogen 4245.00 0.42 120.00 9.38 14.13 Phosphorus as P2O5 5320.00 0.53 80.00 4.99 7.52 Potassium as K2O 2240.00 0.22 50.00 7.41 11.16 Calcium, Total 218105.00 21.81 Calcium as CaO 305347.00 30.53 Calcium as CaCO3 (CCE) 5190.00 0.52 2000.00 127.84 192.68 Magnesium, Total 1790.00 0.18 Manganese 65.00 0.01 Sodium 380.00 0.04 Percent Moisture 33.65 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Public Utility Director P. O. Box 219: Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 17-Jan-19 Client #: 168 Report Date: 25-Jan-19 Sample Date: 17-Jan-19 SDG #: SDG-129278 Parameter LSID-285352 Total Organic Carbon LSID-285353 Total Organic Carbon Result 1-17-19-RAW 3.9 1-17-19-FIN 2.2 Reporting Limit Unit Approved By: fJ+.- Van Ward Lab Director Method 0.5 mg/L SM 531 OB-2011 0.5 mg/L SM 531 OB-2011 Flag Date 1/21/2019 1/21/2019 Time Analyst 11:20 SF 11:20 SF LSID-285354 1-16-19-0500 BIOSOLIDS Acid Digestion (Solids) YES EPA 200.2 1/21/2019 9:00 AE Selenium, Total <0.991 0.991 mg/kg EPA 7010 / 601OD 1/22/2019 12:28 AE Percent Moisture 28.7 0.1 wt% SW846 3540 1/18/2019 14:40 NIL Aluminum, Total 6470 19.8 mg/kg SW846 6010D 1/23/2019 10:41 JR Arsenic, Total 3.17 0.991 mg/kg SW846 6010D 1/22/2019 12:28 AE Cadmium, Total <0.991 0.991 mg/kg SW846 6010D 1/21/2019 13:51 AE Chromium, Total 42.6 0.991 mg/kg SW846 6010D 1/21/2019 13:51 AE Copper, Total 24.4 0.991 mg/kg SW846 6010D 1/21/2019 13:51 AE Lead, Total <0.991 0.991 mg/kg SW846 6010D 1/21/2019 13:51 AE Molybdenum, Total <19.8 19.8 mg/kg SW846 6010D 1/23/2019 10:41 JR Nickel, Total 11.1 0.01 mg/.kg SW846 6010D 1/21/2019 13:51 AE Zinc, Total 163 0.991 mg/kg SW846 6010D 1/21/2019 13:51 AE Mercury, Total <0.024 0.024 mg/kg SW846 7470A 1/23/2019 12:30 CG Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843)665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 16-Jan-19 SDG #: SDG-129278 - - -- --- ----- -- Reporting Parameter Result Limit unit PCB BRL mg kg Page 2 South Carolina Certification Number: 21117 Receipt Date: 17-Jan-19 Report Date: 25-Jan-19 Approved By: tf �✓ Van Ward Lab Director Method Flag Date Time Analyst SW8468082A S11A 1,23/2019 10:48 UH AccEs ANALYTICAL, INC. ANALYTICAL REPORT r' RINRrr Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 285354 LABORATORY REPORT NUMBER 1901G36 DATE January 24, 2019 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford ' Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCNI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed 'to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315 4243 Page 1 of 4 - (� DAVISQ_ h,A, 124 W. Mclver Road PH_ 843-6654746 PAGE# _OF C■I lr l■7 DAYS & BROWN Florence, SC 29501 FAX 845-65&2208 REGULATORY: '/F_S NC CHAIN OF CUSTODY RECORD SRNTIME. —STANDARD RUSH - CLIENT: SAUIPLE,ANAL I31:= �HaUESTED ! z < p i .,SEE COOES TO WOICTAiE F SAMPLE WAS ='L-EREC CR PRESERVED A = HNO, B = HCL O - H,SO, F = FILTRATION C=NAOH E=NAr3,0, G=ZINCACETATE Presetva4ca ti o c E U rj a > r w Z U U O # F l f I ADDRESS; PRCGRAM.AREA : D = DRINKING WATER G =GROUNDWATER 5 = SOUO SL =SLUDGE W=WASTEWATER O=OTHER PLEASE PRINT LEGIBLY SHADED AREAS FOR LAB USE ONLY PHONE: FAX:JIMENIIAL SANIPLc 10 =AT E NQTES LAB IQ Fill in the 1,11, of Containers for EACH Test SAMPLER SIGNATURE FLOWWFO ICE '!ES NO PACK ECEiPT TEMP: �ao C Relinqu a ale' The: ✓i Rellnw hed ny Date: Time: P.zlirgwi hed by: Oale. lime: - _— Recai `IData: Tame. ., o. y Received by Cata: Tlme: Peceived ey' Date. Comments: �h%f i6 I95UtU: NUVEMULR 2012 Page 2 of 4 Analytical Environmental Services, Inc Date: 24-Jan-19 Client: Davis & Brown Client Sample ID: 285354 Project Name: 285354 Collection Date: 1/16/2019 10:55:00 AM Lab ID: 1901G36-001 Matrix: Soil Analyses Result Reporting Quul Limit Units Dilution BatchID Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 48 uorK; dry 273241 1 01/23/2019 1048 UH Aroclor 1221 BRL 48 ugiKg-dry 273241 1 01/23/2019 1048 UH Aroclor 1232 BRL 48 ugK dry 273241 1 01/23/2019 10.48 UH Aroclor 1242 BRL 43 ucKg-dry 273241 1 01/23/2019 1048 UH Aroclor 1248 BRL 48 u= Kg -dry 273241 1 01/23/2019 10-48 UH Aroclor 1254 BRL 48 u& Kg -dry 273241 1 0IY23/2019 10.48 UH Aroclor 1260 BRL 48 ugiKg-dry 273241 1 01/23/2019 10-48 UH Surr: Decachlorobiphenyl 425 45 7-140 S %R-EC 273241 1 01/23/2019 1048 UH Surr- Tetrachloro-m .Yylene 53 1 45 3-126 %REC 273241 1 01/23/2019 10:48 UH PERCENT MOISTURE D2216 Percent Moisture 300 0 wt% R389257 1 01/20/2019 15 00 JW Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nair Sze case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 `tV:fI1 ncu. AES �YGD3ONhtfi1§-1'.1L ERViC.RB. cvc. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. 2. Carrier: Fed Ex UPS _ USPS7 Client' Courier_ Othei 3. 4, 5. 6. 7. 8. 9. 10. 11. 12. AES Work Order Number: 190111336 Clear Save as axa Shipping container/cooler received in good condition? • damaged _ .eak;nq - other Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? • Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for temperature recordings.] O ® ® Cooling initiated for recently collected samples / ice present Chain of Custody (COC) present? • Chain of Custogsignel,, dated, and timed when relinquished and received? • ' Sampler nameignature an COC? Were all samved within holding time? U. VIEfo �TTndicated, TAT marked C? proceeded with standard TAT per Terms & Conditions. �. 13. Cooler 1 Temperature 3.7 14. Cooler 5 Temperature 15, Comments: 1-6. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3Temperature °C Cooler 4 Temperature °C °C Cooler 6. Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). AP 1/18/19 r mm—t, Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals Intact on sample containers? Do sample container labels match the COC? E) ® ® incomplete info = illegible no label _ other _ Are analyses requested indicated on the COC? - Were all of the samples listed on the CDC received? O ® ® samples received but not listed on COC samples listed on COC not received Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? Were samples received n appropriate containers? 111 Were VOA samples received without headspace (< 1/4" bubbleP?Were trip blanks submitted? listed on COC not listed on COC 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). checked at Sample Receipt. Yes No N/A Details Comments 28, 29. 30. EW 1/18/19 Have containers needing chemical preservation been checked?' Containers meet preservation guidelines? Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. I certify that 1 have completed sections 28-30 (dated initials) EW 1/18119 Checklist 6.9.17 Rev 2 g"�6keri Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 11 South Carolina Lab Certification Number: 96026; 9603 l ; 98001; 73006; 98016; 99006001 Note: S11A indicates AES Laboratory (98016); S11G indicates GCAL Laboratory (73006); S11P indicates Pace Analytical (96042001); S 11TS indicates Test America Savannah (98'001) SI ITP indicates Test America Pittsburg (89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 cl4 I ,S'outh Cproli��aLab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S18 S outh Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Revaton 08118 Dataqual (SuKahs)p2 «pd wy 124 W. McIver Roar) PH: 843-665.6746 PAGE # OF p BROWN DAVIS R N V l-� V [% YS! Florence,SC 229501 842-656.2208 U REGULATORY: YES NO nl�FAX.' CHAINOF CUSTODY RECORD TURNARPOUNO TIME P1 _STANDARD RUSH _p2 CLIENT: SAMPLE ANALYSIS REQUESTED USE CODES TO INDICTATE IF SAMPLE WAS Fteservalive �. (1 � I\�1`h� FILTERED OR PRESERVED: A = HNOi 1 l.r\.l� n ��^ K. 5= HCL D = HAD. F =FILTRATION ADDRESS: m _ � a: u! C=NAOH E=NA z5z0� G=ZINCACETATE Z F PROGRAM AREA: D=DRINKING'NATER E ZO E ¢ G=GROUNDWATER S=SOLID SLe SLUDGE U U W = WASTEWATER O=OTHER a Q LL a of PLEASE PRINT LEGIBLY PHONE: FAX: LU a II-- Q) 0 a SAMPLE ID DATE TIME INITIAL NOTES LAB ID Fill in the Number of Contamens for EACH Test -► - 1-►-►-I to sT C, 1 1-11- cl los—b (a 1 2_'8S3S3 Scawl;d.s rej4.� 4 �PlRsc SO-6 l-6-t9 loss ca 1 �.� to y rcn(�r. SAMPLER SIGNATURE FLOWINFO LOB`: ICE YES ?O PACK RECEIP7 TEMP. Relmquished by: Date. Tme• Refnguished by Date, Time. Relinquished by, Dale, Time: CL ed to: Time: Received by Date: Time, Received by: Date Time. 1ReCe Comments: oia.� 'TO}y e , 0/0rn0 s�"q-C �ytT b$� \ liD}wl ArSeniCtToM}C rn:ti•mljaaa\ C�nros�.i .M,Tp�a\ !00c .FtAE A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 10102 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29250 ACCOUNT COMRLBR DATE 01/30/2019 STOLSON@CHERAW.COM SAMPLE NO. 11619500 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.03 % 0.60 Organic Nitrogen 0.67 % 13.47 Nitrate Nitrogen ---------------------------------------------------------------- 31.85 ppm 0.06 INCORPORATED AVAILABLE NITROGEN ESTIMATE 8.67 SURFACE AVAILABLE NITROGEN ESTIMATE 8.49 --------------------------------------------------------------- Phosphorus as P205 0.53 % 10.64 Potassium as K20 0.22 % 4.48 Calcium 21.81 % 436.21 Magnesium 0.18 % 3.58 Sulfur 0.19 % 3.72 Zinc 89.58 ppm 0.18 Copper 41.80 ppm 0.08 Manganese 67.02 ppm 0.13 Sodium 378.22 ppm 0.76 Moisture 33.65 % -- Calcium Carbonate Equivalency' 0.52 % 10.38 ' ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure.will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of application. The Agricultural Service Laboratory is a public service of Clemson University, an affirmative action and equal opportunity educational institution. ** http://www.clemson.edu/agsrvlb ** % moisture % solids lbs. solids/ton lbs. solids/500 tons 33.65 66.35 1327 663500 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.03 300 0.6 0.045215 452.1477 0.904295 Organic Nitrogen 0.6735 6735 13.47 1.015072 10150.72 20.30143 Nitrate Nitrogen 0.003185 31.85 0.0637 0.004800 48.00301 0.096006 Incorporated Available Nitrogen Estimate 0.4335 4335 8.67 0.653353 6533.534 13.06707 Surface Available Nitrogen Estimate 0.4245 4245 8.49 0.639789 6397.89 12.79578 Phosphorus as P2O5 0.532 5320 10.64 0.801809 8018.086 16.03617 Potassium as K2O 0.224 2240 4.48 0.337604 3376.036 6.752072 Calcium 21.8105 218105 436.21 32.87189 328718.9 657.4378 Magnesium 0.179 1790 3.58 0.269781 2697.815 5.395629 Sulfur 0.186 1860 3.72 0.280332 2803.316 5.606631 Zinc 0.008958 89.58 0.17916 0.013501 135.0113 0.270023 Copper 0.00418 41.8 0.0836 0.0063 62.99925 0.125998 Manganese 0.006702 67.02 0.13404 0.010101 101.0098 0.20202 Sodium 0.037822 378.22 0.75644 0.057004 570.0377 1.140075 Calcium Carbonate Equivalency 0.519 5190 10.38 0.782216 7822.155 15.64431 January 2019 -� Cj 4�l CHERAW ALKALINE BIOSOLIDS SOILAMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: March 20, 2019 METALS Biosolicis Metal Content, ppm Maximum Allowable Metal. - Content, ppm Maximum Allowable App. Rate, #/Acre/Yr. Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 1.44 41.00 1.80 500.91 626.76 Cadmium, Total 0.89 " 39.00 1.70 767.15 959.90 Chromium, Total 51.59 1200.00 134.00 1037.96 1298.75 Copper, Total 33.59 1500.00 67.00 796.96 997.19 Lead, Total 0.89 ' 300.00 13.00 5866.47 7340.43 Mercury, Total 0.23 ' 17.00 0.75 1300.43 1627.16 Molybdenum, Total 3.55 18.00 0.80 90.16 112.82 Nickel, Total 15.25 420.00 18.70 490.13 613.28 Selenium, Total 0.89 ' 36.00 4.50 2030.70 2540.92 Zinc, Total 210.08 1525.00 125.00 237.77 297.51 PCB BRL 1.60 * Actual metal content less than amount indicated Biosolids Nutrient Content, ppm Biosolids Nutrient Content, % Crop/Soil Requirement, #/Acre'* Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 200.00 0.02 Organic Nitrogen 7325.00 0.73 Incorporated Available Nitrogen 4730.00 0.47 120.00 10.14 12.68 Surface Available Nitrogen 4670.00 0.47 120.00 10.27 12.85 Phosphorus as P205 4575.00 0.46 80.00 6.99 8.74 Potassium as K20 4140.00 0.41 50.00 4.83 6.04 Calcium, Total 231455.00 23.15 Calcium as CaO 324037.00 32.40 Calcium as CaCO3 (CCE) 5965.00 0.60 2000.00 133.98 167.64 Magnesium, Total 1840.00 0.18 Manganese 50.00 .0.01 Sodium 535.00 0.05 Percent. Moisture 20.08 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraws Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Public Utility Director P.O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: - ---- INTENDED USE: LOCATION OF USE: QUANTITY RECEIVED: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 21-Mar-19 Client #: 168 Report Date: 05-Apr-19 Sample Date: 21-Mar-19 SDG #: SDG-130328 Parameter LSID-287659 Approved By: Reporting Result Limit Unit Method 3-20-19-001 INF Biochemical Oxygen Demand 435 2 mg/L SM 5210B LSID-287660 3-20-19-002 EFF Biochemical Oxygen Demand 8.1 2 mg/L SM 5210B LSID-287661 Ignitability TCLP Extraction (Solids) Acid Digestion (Solids) Selenium, Total TCLP Percent Moisture Aluminum, Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Molybdenum, Total 3-20-19-0500 BIOSOLIDS >180 Deg. F. D93 / 1010A YES EPA 1311 YES EPA 200.2 <0.999 0.999 mg/kg EPA 7010 / 6010D PASS P/F SW-846 24.3 0.1 Wt% SW846 3540 6450 20 mg/kg SW846 6010D 1.62 0.999 mg/kg SW846 6010D <0.999 0.999 mg/kg SW846 6010D 58.2 0.999 mg/kg SW846 6010D 37.9 0.999 mg/kg SW846 6010D <0.999 0.999 mg/kg SW846 6010D <4.00 4 mg/kg SW846 601OD Page 1 tom` ice. Van Ward Lab Director Flag Date Time Analyst 3/21/2019 10:32 AE 3/21/2019 10:32 AE S11A 3/26/2019 0:00 SK SIIA 3/25/2019 8:30 AE 3/25/2019 13:09 JR 4/1/2019 13:43 WSF 9/22/2019 14:21 NIL 3/26/2019 14:59 JR 3/25/2019 13:09 JR 3/25/2019 13:48 AE 3/25/2019 13:48 AE 3/25/2019 13:48 AE 3/25/2019 13:48 AE 3/26/2019 11:41 JR Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis South Carolina Certification Number: 21117 Receipt Date: 21-Mar-19 Report Date: 05-Apr-19 Sample Date: 20-Mar-19 Approved By: SDG #: SDG-130328 Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Nickel, Total 17.2 0.999 mg/kg SW846 6010D 3/25/2019 13:48 AE Zinc, Total 237 0.999 mg/kg SW846 6010D 3/25/2019 13:48 AE Mercury, Total <0.026 0.026 mg/kg SW846 7470A 3/26/2019 12:15 CG PCB BRL mg/kg SW8468082A S11A 3/28/2019 16:18 UH Reactivity, Cyanide <0.962 0.962 mg/kg SW846 9010/9012 S 11A 3/29/2019 15:00 AT Reactivity, Sulfide <100 100 mg/kg SW8469030/9034 S11A 3/27/2019 17:30 AT Paint Filter PASS P/F SW846 9095B S11A 3/27/2019 18:20 AA Page 2 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 287661 LABORATORY REPORT NUMBER 1903N72 DATE April 01, 2019 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803 781.4243 or toll fee at 883.315.4243 4 Page 1 of 6 { I -JN]3 V' BROWN 124 W. McIver Road PH: 843-665-6746 PAGE # _OF_ ® DAVIS Florence, SC 29501 FAX: 843-656-2208 REGULATORY: YES NO CHAIN OF CUSTODY RECORD TURNAROUND TIME: pi _STANDARD RUSH _P2 CLIENT: �l1 �� Sa.\.:-._ �:vq�ti SiS < N o USE CODES TO INDICTA TE IF SAMPLE WAS FILTERED OR PRESERVED: A = HN% 8=HCL D -H,SO, F=FILTRATION C = NAOH E = NAi$,C, G = ZINCACETATE Ptaservatfve .n 1 E U e S a y i Z O O ,� v O J O Y ' l J + T� dL ! I ADDRESS: PP.CGRAMAREA: ❑=DRINKING WATER G=GROUNDWATER S=SOLID SL=SLUDGE W= WAS?EWATER O=OTHER PLEASE PRINT LEGIBLY SHADED. AREAS FOR'LAS USE ONLY PHONE: FAX: SAMPLE `D DATE TIME INITIAL Fill in,tfieNumher of Containers for EACHTest _ TT I . SAMPLER SIGNATURE FLOW INFO IC� YES NO PACK RECEIPT " TEMP: J-3—o C Rellnti .e y: eie: Timep 11-1 I (a RIInquished by Date: Time: Relinquisned try: Date: Time: Receiv y: Data: Time: Received by Date Date1 Tme: Comments: Page 2 of 6 Analytical Environmental Services, Inc Date: I-Apr-19 Client: Davis & Brown Client Sample ID: 287661 Project Name: 287661 Collection Date: 3/20/2019 9:40:00 AM Lab ID: 1903N72-001 Matrix: Solid Analyses Result Reporting Limit Qual Units BatchlD Dilution Factor Date Analyzed Analyst VOLATILES,TCLP SW1311/8260D (SW503013) 1,1-Dichloroethene BRL 0.10 mg/L 276491 20 03/27/201918:36 CC 1,2-Dichloroethane BRL 010 mg/L 276491 20 03/27/201918:36 CC 2-Butanone BRL 0.20 mg/L 276491 20 03/27/20191836 CC Benzene BRL 010 mg/L 276491 20 03/27/2019 18 36 CC Carbon tetrachloride BRL 010 mg/L 276491 20 03/27/2019 1836 CC Chlorobenzene BRL 0.10 mg/L 276491 20 03/27/2019 1836 CC Chloroform BRL 010 mg/L 276491 20 03/27/201918.36 CC Tetrachloroethene BRL 0.10 mg/L 276491 20 03/27/201918:36 CC Trichloroethene BRL 010 mg/L 276491 20 03/27/2019 18 36 CC Vinyl chloride BRL 0 040 mg/L 276491 20 03/27/2019 18 36 CC Surr- 4-Bromofluorobenzene 102 63 1-120 %REC 276491 20 03/27/2019 1836 CC Surr: Dibromofluoromethane 101 76 1-126 %REC 276491 20 03/27/2019 18 36 CC Surr: Toluene-d8 102 75 3-119 %REC 276491 20 03/27/2019 18:36 CC Sulfide, Reactive SW846-7.3 (SW7.3.4.2) Sulfide, Reactive BRL 100 mg/Kg 276649 l 03/27/2019 17:30 AT SEMIVOLATILES ORGANICS, TCLP SW1311/8270E (SW3510C) 1,4-Dichlorobenzene BRL 010 mg/L 276448 1 03/27/2019 18 51 YH 2,4,5-Trichlorophenol BRL 010 mg/L 276448 1 03/27/201918:51 YH 2,4,6-Trichlorophenol BRL 0.10 mg/L 276448 1 03/27/201918.51 YH 2,4-Dmitrotoluene BRL 010 mg/L 276448 1 03/27/20191851 YH Hexachlorobenzene BRL 0.10 mg/L 276448 1 03/27/201918:51 YH Hexachlorobutadiene BRL 010 mg/L 276448 l 03/27/201918:51 YH Hexachloroethane BRL 010 mg/L 276448 1 03/27/20191851 YH m,p-Cresol BRL 010 mg/L 276448 1 03/27/201918.51 YH Nitrobenzene BRL 010 mg/L 276448 1 03/27/201918:51 YH o-Cresol BRL 010 mg/L 276448 1 03/27/201918-51 YH Pentachlorophenol BRL 050 mg/L 276448 1 03/27/2019 18-51 YH Pyridme BRL 0.10 mg/L 276448 1 03/27/201918.51 YH Cresols, Total BRL 010 mg/L 276448 1 03/27/2019 1851 YH Surr: 2,4,6-Tribromophenol 121 49 6-128 %REC 276448 l 03/27/2019 18:51 YH Surr. 2-Fluorobiphenyl 97.8 52 2-124 %REC 276448 1 03/27/2019 18.51 YH Sun. 2-Fluorophenol 89 1 44-129 %REC 276448 1 03/27/2019 18 51 YH Sun: 4-Terphenyl-dl4 984 63 2-145 %REC 276448 1 03/27/2019 1851 YH Surr: Nitrobenzene-d5 110 53.6-124 %REC 276448 1 03/27/2019 1851 YH Surr Phenol-d5 92.5 50 6-125 %REC 276448 1 03/27/2019 1851 YH POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 47 ag/Ko dry 276589 1 03/28/2019 16 18 UH Aroclor 1221 BRL 47 ug/Ko dry 276589 1 03/28/2019 16 18 UH Qualifiers: ' Value exceeds maximum contaminant level E Estimated (value above quanntation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Greater than Result value 1 Estimated value detected below Reporting Limit Page 3 of 6 Analytical Environmental Services, Inc Date: 1-Apr-19 Client: Davis & Brown Client Sample ID: 287661 Project Name: 287661 Collection Date: 3/20/2019 9:40:00 AM Lab ID: 1903N72-001 Matrix: Solid Analyses Result Reporting Qual Limit Dilution Units BatchID Factor Date Analyzed Analyst . POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1232 BRL 47 ug/Kg-dry 276589 1 03/28/2019 16:18 UH Aroclor 1242 BRL 47 ug/Kg-dry 276589 1 03/28/2019 16:18 UH Aroclor 1248 BRL 47 ug/Kg-dry 276589 1 03/28/2019 16:18 UH Aroclor 1254 BRL 47 ug/Kg-dry 276589 1 03/28/2019 16:18 UH Aroclor 1260 BRL 47 ug/Kg-dry 276589 1 03/28/2019 16:18 UH Surr: Decachlorobiphenyl 47.1 45.7-140 %REC 276589 1 03/28/2019 16:18 UH Surf: Tetrachloro-m-xylene 46.6 45.3-126 %REC 276589 1 03/28/2019 16:18 UH Paint Filter Liquids Test E9095B Free Liquid NEGATIVE 0 ml R394347 1 03/27/2019 18:20 AA MERCURY, TCLP SW1311/7470A (SW7470A) Mercury BRL 0.00400 mg/L 276572 1 03/27/2019 23:25 CD Ignitability SW1010A Ignitability 180 0 > T R394212 1 03/26/2019 00:00 SK ICP METALS, TCLP SW 1311/6010D (SW3010A) Arsenic BRL 0.250 mg/L 276525 1 03/27/2019 14:49 DG Barium BRL 0.500 mg. L 276525 1 03/27/2019 14:49 DG Cadmium BRL 0.0250 mg L 276525 1 03/27/2019 14:49 DG Chromium BRL 0.0500 mg/L 276525 1 03/27/2019 14:49 DG Lead BRL 0.0500 mg/L 276525 1 03/27/2019 14:49 DG Selenium BRL 0.100 mg/L 276525 1 03/27/2019 14:49 DG Silver BRL 0.0250 mg/L 276525 1 03/27/2019 14:49 DG Cyanide, Reactive SW846-7.3 (SW7.3.3.2) Cyanide, Reactive BRL 0.962 mg/Kg 276735 1 03/29/2019 15:00 AT PERCENT MOISTURE D2216 Percent Moisture 28.4 0 WN R394186 1 03/26/2019 14:00. JW Qualifiers: ' Value exceeds maximum contanunant level E Estimated (value above cluantitation range) BRL Below reporting limit S Spike Recovery outside limits due to matrix H Holding times for preparation or analysis exceeded Narr See case narrative N Analyte not NELAC certified NC Not confirmed B Analyte detected in the associated method blank < Less than Result value > Crater than Result value J Estimated value detected below Reporting Limit Page 4 of 6 i, A.YAumcAL FNI7HONhtF_tiT1L AES .SCsRlRC.&4, LYC. SAMPLE/COOLER RECEIPT CHECKLIST 1. client Name: ACCESS ANALYTICAL, INC. 2. Carrier: fedFx G UPS L' USPS❑ Client' CourierL; Othei Yes No N/A Details AES Work order Number: 1903N72 Clear Save as Comments Shipping container/cooler received in good condition? • damaged - leaking other Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? • Cooler temperature(s) within limits of 04C? [See item 13 and 14 for temperature recordings.] O ® O Cooling initiated for recently collected samples / ice present Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? Sampler name and/or signature on COC? Were all samples received within holding time? TAT marked on the'COC7 If no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 2.3 14. Cooler 5 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 2 Temperature °C Cooler 3 Temperature oC Cooler 4 Temperature °C °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). EW 3/22/19 Yes No N/A Details Comments Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC? © ® incomplete info illegible _ ❑ label _ other Are analyses requested indicated on the COC? • Were all of the samples listed on the CDC received? e ® o samples received but not listed on CDC samples listed on CDC not received Was the sample collection date/time noted? Did we receive sufficient sample volume for indicated analyses? Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? listed on COC not listed on COC 27. Comments: This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). checked at Sample Receipt. Yes No N/A Details Comments 28. 29. 30. EW 3/22/19 Have containers needing chemical preservation been checked? Containers meet preservation guidelines? Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & GreasefTPH. ____�.........___..._ __ 1 certify that I have completed sections 2830 (dated initials) EW 3/22/19 Checklist 6.9.17 Rev 2 Page 5 of 6 Analytical Environmental Services, Inc Client: Davis & Brown Project Name: 287661 Lab Order: 1903N72 Lab Sample ID Client Sample ID Collection Date Matrix Teat Name 1903N72-001A 287661 3/20/2019 9:40:OOAM Solid VOLATILES, TCLP Leached 1903N72-001B 287661 3/20/2019 9:40:00AM Solid TCLP SEMIVOLATILES ORGANICS 1903N72-001B 287661 3/20/2019 9:40:OOAM Solid MERCURY, TCLP Leached 1903N72-001B 287661 3/20/2019 9:40:OOAM Solid ICP METALS, TCLP Leached 1903N72-001C 287661 3/202019 9:40:OOAM Solid IGNITABILITY 1903N72-001C 287661 3/202019 940:OOAM Solid Cyanide, Reactive 1903N72-001C 287661 3/202019 9:40:OOAM Solid Sulfide, Reactive 1903N72-001C 287661 3202019 9:40:OOAM Solid POLYCHLORINATED BIPHENYLS 1903N72-001C 287661 3/20/2019 9:40:OOAM Solid Paint Filter Liquids Test 1903N72-001C 287661 3/202019 9:40:OOAM Solid PERCENT MOISTURE Date: 1-Apr-19 Dates Report TCLP Date Prep Date 03/26/2019 3126/2019 10:27:OOAM 03/26/2019 3/26/2019 11:00:00AM 03/26/2019 3/27/2019 5:15:OOPM 03/26/2019 3/27/2019 11:50:OOAM 3/292019 10:00:OOAM 3/27/2019 9:15:OOAM 3/28/2019 10:00:OOAM Analysis Date 03127/2019 03/27/2019 03/27/2019 03/27/2019 0312WO19 03292019 03272019 0328/2019 03272019 03262019 Page 6 of 6 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 1 lA indicates AES Laboratory (98016); S 1 I G indicates GCAL Laboratory (73006); SI 1P indicates Pace Analytical (96042001); S1 ITS indicates Test America Savannah (98001) S 1 I TP indicates Test America Pittsburg89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Revision 08/18 Dataqual (SuKabs)p2 i�pd KM DAVIS & BROWN 124 W. MCIVef Road PH: 843-665.6746 Ff°rence, Sc 29601 FAX: 843.65E-2208 PAGE # ` OF 3 Z TURNA ..UND TIME: _Pi CHAIN OF CUSTODY v STANDARD RUSH REGULATORY: YES NO ,RECORD _P2 SAMPLE ANALYSIS REQUESTED USE CODES TO INDICTATE IF SAMPLE WAS CLIENT: FILTERED OR PRESERVED: A= HNq Preservative' •'` _ F_ �r' _s f.�. ., ,� "� "r,; �.•� j'. ���X.• lJ W lJ y C=NADN E=NA1Slq G=DNCACETATE ADDRESS: m z PROGRAMAREA: D=DRINKING WATER EZ to U G=GROUNDWATER S=SOLID SL=SLUDGE CJ O W = WASTEWATER C=OTHER PLEASE PRINT LEGIBLY m o ' " rQ 0 PHONE: FAX: !— O NOTES LAB ID SAMPLE 10 Flll in•the Number of Contalners4or EACH Test 3-aa}i ��-< 1q° 4.ATEIMEINITIAL .�4A-, se, ar,Qq'D� Rr� Cs1Gr, c-,Pb 2,�)Jt,Dtp S C ( LPl SrtiJ;faTi7.�r a.�r• o , FLOW INFO IC ICE SAMPLER SIGNATURE NO PACK a �I 1% � , _ _ JG�'"`"� TEMP: q o TEMP: 1 •J� C R 'nquished Date: Z�-r Timer � �• Relmqui ed by D le: Time. Relinquished by: �i � � q (•� J s Dale: Time: Received 3 Datyl -L T[�f�•O'7 y Tlme: Reeerved by: l Dale: Time: v Comments: ISSUED: NUvtmttR ,v is A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 30472 Clemson University TURNER, SHERRY ACCOUNT 'COMRLBR PO BOX 219 DATE 04/01/2019 CHERAW SC29520 STOLSON@CHERAW.COM SAMPLE NO. 03201950 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS---------------------- lbs/ton Ammonium Nitrogen 0.02 % 0.40 Organic Nitrogen 0.73 % 14.65 Nitrate Nitrogen --------------------------------------------------------------- 107.90 ppm 0.22 INCORPORATED AVAILABLE NITROGEN ESTIMATE 9.46 SURFACE AVAILABLE NITROGEN ESTIMATE 9.34 --------------------------------------------------------------- Phosphorus as P205 0.46 % 9.15 Potassium as K20 0.41 % 8.28 Calcium 23.15 % 462.91 Magnesium 0.18 % 3.68 Sulfur 0.18 % 3.52 Zinc 196.61 ppm 0.39 Copper 31.97 ppm 0.06 Manganese 50.35 ppm 0.10 Sodium 536.28 ppm 1.07 Moisture 20.08 % Calcium Carbonate Equivalency 0.60 % 11.93 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all first year, its availability should be fertilizers. of the phosphorous is available in the comparable to that in commercial The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 20.08 79.92 1598.4 799200 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.02 200 0.4 0.025025 250.2503 0.500501 Organic Nitrogen 0.7325 7325 14.65 0.916542 9165.415 18.33083 Nitrate Nitrogen 0.010790 107.9 0.2158 0.013501 135.01 0.27002 Incorporated Available Nitrogen Estimate 0.473 4730 9.46 0.591842 5918.418 11.83684 Surface Available Nitrogen Estimate 0.467 4670 9.34 0.584334 5843.343 11.68669 Phosphorus as P2O5 0.4575 4575 9.15 0.572447 5724.474 11.44895 Potassium as K2O 0.414 4140 8.28 0.518018 5180.18 10.36036 Calcium 23.1455 231455 462.91 28.96084 289608.4 579.2167 Magnesium 0.184 1840 3.68 0.23023 2302.302 4.604605 Sulfur 0.176 1760 3.52 0.22022 2202.202 4.404404 Zinc 0.019661 196.61 0.39322 0.024601 246.0085 0.492017 Copper 0.003197 31.97 0.06394 0.004 40.0025 0.080005 Manganese 0.005035 50.35 0.1007 0.0063 63.0005 0.126001 Sodium 0.053628 536.28 1.07256 0.067102 671.021 1.342042 Calcium Carbonate Equivalency 0.5965 5965 11.93 0.746371 7463.714 14.92743 March 2019 CHERAW ALKALINE BIOSOLIDS SOILAMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: May 23, 2019 Biosolids Maximum Maximum Maximum Maximum Metal Allowable Allowable Application Application Content, Metal App. Rate, Rate, Rate, METALS ppm Content, ppm #/Acre/Yr. DT/Acre/Yr. WT/Acre/Yr. Arsenic, Total 1.27 ' 41.00 1.80 372.76 710.96 Cadmium, Total 0.63 39.00 1.70 704.10 1342.92 Chromium, Total 34.12 1200.00 134.00 1029.52 1963.61 Copper, Total 37.93 1500.00 67.00 463.11 883.30 Lead, Total 0.63 ' 300.00 13.00 5384.26 10269.42 Mercury, Total 0.03 17.00 0.75 6458.52 12318.37 Molybdenum, Total 5.06 ' 18.00 0.80 41.44 79.04 Nickel, Total 15.35 420.00 18.70 319.40 609.20 Selenium, Total 1.27 ' 36.00 4.50 931.89 1777.40 Zinc, Total 169.97 1525.00 125.00 192.79 367.71 PCB BRL 1.60 ' Actual metal content less than amount indicated Biosolids Biosolids Maximum Maximum Nutrient Nutrient Crop/Soil Application Application Content, Content, Requirement, Rate, Rate, ppm % #/Acre " DT/Acre/Yr. WT/Acre/Yr. Ammonium Nitrogen 140.00 0.01 Organic Nitrogen 8095.00 0.81 Incorporated Available Nitrogen 5355.00 0.54 120.00 5.87 11.20 Surface Available Nitrogen 5315.00 0.53 120.00 5.92 11.29 Phosphorus as P205 6365.00 0.64 80.00 3.29 6.28 Potassium as K20 2085.00 0.21 50.00 6.29 11.99 Calcium, Total 142825.00 14.28 Calcium as CaO 199955.00 20.00 Calcium as CaCO3 (CCE) 2560.00 0.26 2000.00 204.80 390.63 Magnesium, Total 1415.00 0.14 Manganese 80.00 0.01 Sodium 345.00 0.03 Percent Moisture 47.57 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a "Class A' product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations." THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Director of Operations P. O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: LOCATION OF USE: OUANTITY RECEIVED: Davis & Brown PO Boa 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 22-May-19 SDG #: SDG-131390 Parameter Result LSID-289980 5-21-19-010 Biochemical Oxygen Demand 317 South Carolina Certification Number: 21117 Receipt Date: 23-May-19 Report Date: 31-May-19 Approved By: 4VAft— Van Ward Lab Director Reporting - --- Limit Unit Method Flag Date 2 mg/L SM 5210B 5/23/2019 LSID-289981 5-23-19-0500 BIOSOLIDS Acid Digestion (Solids) Selenium, Total Percent Moisture Aluminum, Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Molybdenum Total Nickel, Total Zinc, Total Mercury, Total PCB YES EPA 200.2 5/27/2019 <0.998 0.998 mg/kg EPA 7010 / 6010D 5/28/2019 47.1 0.1 wt% SW846 3540 5/27/2019 4110 200 mg/kg SW846 6010D 5/28/2019 <0.998 0.998 mg/kg SW846 6010D 5/28/2019 <0.499 0.499 mg/kg SW846 601OD 5/27/2019 26.9 0.499 mg/kg SW846 6010D _ 5/27/2019 29.9 0.499 mg/kg SW846 6010D 5/27/2019 <0.499 0.499 mg/kg SW846 6010D 5/27/2019 <3.99 3.99 mg/kg SW846 6010D 5/28/2019 12.1 0.499 mg/kg SW846 6010D 5/27/2019 134 0.499 mg/kg SW846 601OD 5/27/2019 0.024 0.023 mg/kg SW846 7470A 5/29/2019 BRL 1.6 mg/kg SW846 8082A Sl1A\D 5/24/2019 Page 1 Time Analyst 10:41 AE 10:00 AE 9:31 JR 10:25 ML 14:13 JR 9:31 JR 15:38 AE 15:38 AE 15:38 AE 15:38 AE 12:38 JR 15:38 AE 15:38 AE 12:30 CG 14:31 UH AcCsS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT iD 289981 LABORATORY REPORT NUMBER 1905062 DATE May 29, 2019 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 l9bs0(D'z f WMcIRoadvPH,er843-@65-6746 ® DAVIS � BROWN PAGE # _OF _ Florence, SC 29601 FAX. 843-856-2208 REGULATORY: YES NO CHAIN OF CUSTODY RECORD TURNAROUND TIME __Pt DUEN'i: _ STANDARD RUSH P2 SAWLE A XALYSIS REQUES'ED USE CODES TO INDICTA TE IF SAMPLE NAS �1TERED OR PRESERVED: A - HNOx rT I V;S Hx80, F=FILTRATION DRESS: Z I C= NAOH E= NAxSxOx G= 7INCACETATE PRCGRAMAREA: D - DRINKING'NATER EF U i G=GROUNDWATER S=SOLID SL-SLUDGE D e9 ti se i W=WASTEWATER O.OTHER PHONE: FAX: PLEASE PWNT LEGIBLY a � i ! I o SHADED AREAS FOR L" USE QMLY SAMPLE IC CA? THE INI-IAL NOTES LAB ID 2 �9 ri -60 Fin In the Wzftw of Gcntsi om for EACH TM I � � 4 { I I I � ( 1 i i t E T 7- SAMPLER SIGNATURE FLOWINFO PACK ' 0 0.0 Raltngai a: ( t Time: S(13! t q f rN RaCmaufahed hY Data Time: Rehrquished hy. Date: Time: —� R8�'v Y Date: Time: Yt '� 2sf 1 Received aJ Cate: Tima: Received Dy: Date: Time: Carom r3s: '$SUED[ NOVEMBER 2012 Page 2 of 4 Analytical Environmental Services, Inc Date: 29-May-19 . Client: Davis & Brown Client Sample ID: 289981 Project Name: 289981 Collection Date: 5/23/2019 7:30:00 AM Lab ID: 1905062-001 ;Matrix: Solid Analyses Result Reporting Qual Limit `nits BatchlD Dilution Date Analyzed Analyst Factor POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 37 ulp Kg -dry 279626 1 05/24/2019 14:31 UH Aroclor 1221 BRL 37 ulp Kg -dry 279626 l 05/24/2019 14:31 UH Aroclor 1232 BRL 37 ug/Kg-dry 279626 1 05/24/2019 14:31 UH Aroclor 1242 BRL 37 ug!Kg-dry 279626 1 05/24/2019 14:31 UH Aroclor 1248 BRL 37 ugXg-dry 279626 1 05/24/2019 14:31 UH Aroclor 1254 BRL 37 ug/Kg-dry 279626 1 05/24/2019 14:31 UH Aroclor 1260 BRL 37 ug/Kg-dry 279626 1 05/24/2019 14:31 UH Surr: Decachlorobiphenyl 53.4 45.7-140 %REC 279626 1 05/24/2019 14:31 UH Surr: Tetrachloro-m-xylene 56.5 45.3-126 %REC 279626 1 05/24/2019 14:31 UH PERCENT MOISTURE D2216 Percent Moisture 10.3 0 wt"iu P399182 1 05/29/2019 13:45 JW Qualifiers: • Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quan6tation range) S Spike Recovery outside limits due to matrix Narr See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 .� AxAm, r1cA1 �.F1V�•7HONhiH\'I'hI. AFS SFaj-tcF_s. flit. 1. Client Name: Access Analytical, Inc. 2. Carrier: FedEx Li, UPS❑. USPS❑ Client Courier[,_,, Othei 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Clear Save as SAMPLE/COOLER RECEIPT CHECKLIST AES Work Order Number: 1905062 Yes N. N/A n-il. Shipping container/cooler received in good condition? • 0 0 ld-,iged leaking _ other_ Custody seals present on shipping container? Custody seals intact on shipping container? Temperature blanks present? • Cooler temperatures) within limits of 04C? [See item 13 and 14 for temperature recordings.] Q ® Q Cooling initiated for recently collected samples / ice present ❑ Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? • Were all samples received within holding. time? IIf TAT marked on the COC? • no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 0.8 °C Cooler 2 Temperature °C Cooler 3 Temperature °C Cooler 4 Temperature °C 14. Cooler 5 Temperature °C Cooler 6 Temperature °C Cooler 7 Temperature °C Cooler 8 Temperature ic 15. Comments: I certify that I have completed sections 1-15 (dated initials). AS 5/24,19 Ve< Nn N/A r -1. r........ e...� Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC. O ® ® incomplete info C illegible El no label ❑ other ❑ Are analyses requested indicated on the COC? • Were all of the samples listed on the CDC received? Q (D ® samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • Ilisted on CDC ^ not listed on COC '.. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. Comments: This section only applies to samples where pH can be 1 certify that I have completed sections 16-27 (dated initials). HB 5/24/19 checked at Sample Receipt. yes No N/A Details Comments 28. Have containers needing chemical preserv 29. 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. He s/za/19 I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 ation been checked? Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? " Page 4 of 4 Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by a data qualifier or a flag next to the result. This table summarizes the possible Data Qualifiers that may be associated with this report. A BOD result showed toxic tendencies. B The BOD data is suspect due to a failed quality control check (GGA). C The BOD data is suspect due to a failed quality control check (Blanks). D Results are reported on a dry weight basis. H Sample was analyzed beyond the accepted holding time 7 Estimated value. Presence of the compound was confirmed but less than the reported detection limit. L Results based on colony counts outside the acceptable range. The ideal range for the fecal colifonn test is 20 - 60 colonies. MS Sample matrix spike percent recovery was outside the accepted range. Sampled, but analysis lost or not performed P Sample was not properly preserved upon receipt. G LCS or MS exceeds the control limits. S Sample was analyzed by another SC certified Lab. SC Seed Correction outside the accepted range of 0.60 - 1.4 mg/L. (BOD) Seed Correction outside the accepted range of 0.60 - 1.4 mg/L (CBOD) SD Results reported are derived from suspect data. SS BOD results derived from supersaturated D.O. values. Sample(s) were aerated per the supersaturation procedure in Standard Methods 5210B SDF Sample Dilutions did not meet the requirement of DO depletion of at least 2.0 mg/L, or the sample dilutions did not meet the requirement of DO residual of at least 1.0 mg/L. Davis & Brown is reporting these results as valid data. 1 Storage Condition: Temperature above 60 C due to power outage. V Analyte detected in the associated method blank. Note: the value in the blank shall not be subtracted from the sample result. Revision 04/17 WSF Dataqual.wpd DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S11A indicates AES Laboratory (98016); S11G indicates GCAL Laboratory (73006); S11P indicates Pace Analytical (96042001); S11TS indicates Test America Savannah (98001) SI ITP indicates Test America Pittsburg (89014) S12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S 3 1 South Carolina Lab Certification Number: 32576 Re�won OS/18 Dataqual (SubLabs)p2 %%pd 124 W McIver Road PH: 843.665.6746 PAGE # , OF F DAVIS & BROWN Florence, SC 29501 FAX: 843-656-2208 in 13! D TURNAROUND TIME: —PI CHAIN OF CUSTODY RECORD RUSH REGULATORY: YES NO _STANDARD _P2 CLIENT: SAMPLE ANALYSIS REQUESTED USE CODES TO INDICTATE IF SAMPLE WAS Presen•aGve F'L TEPED OR PRESERVED: A=HNO� e ra L) B = HCL D = H,SO: F = FILTRATION C = NAOH E = NA;S,O, G = ZINCACETATE m y ADDRESS: ?R9r?AM AR=�`a; D=DRINKING WATER. Q o c G=GROUNDWATER S=50U0 SL=SLUOGE U p C W= WASTEWATER O=OTHER U ._ PLEASE PRINT LEGIBLY C7 p i✓; < s PHONE: FAX: W �- O —= O 1;0 O z SAN4PLE ID DATE TIME NITtAL NOTES LAS ID Pill in the Number of Containers for EACH Test 9-00 a �q uBlo C I Z 1 q /�(� (�dnt521et\'urr I /k d umintLr�1 O S 23- 1 �i IW v 1 �-t se.«C uwL eop�t-rtLead,JYloly enwxlil c[¢/2 j Z�nc��e�C�rYIf�C$ i 2 `JCt��% I I SAMPLER SIGNATURE FLOW INFO (CE. ICE Y S NO PACK ` �' WW RECEIPT j,' TEMP. .S ' cC P, quished by: �n Date. ':ime: 5cv�r-ram— -7 Reliryu hed by Date Time. �a-� -aa� a'� ReUmc,uished by Date: T''me: 5-a -! Received n Data: Time: by Dale" Time. Received by: Date: Time: -.� Y t -%' 'p Comments ISSUEU: IVVV-c LV![ A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 50781 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29520 ACCOUNT COMRLBR DATE 06/04/2019 STOLSON@CHERAW.COM SAMPLE NO. 05151950 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton pi Ammonium Nitrogen 0.01 % 0.28 pi Organic Nitrogen 0.81 % 16.19 pi Nitrate Nitrogen --------------------------------------------------------------- 242.76 ppm 0.49 INCORPORATED AVAILABLE NITROGEN ESTIMATE 10.71 SURFACE AVAILABLE NITROGEN'ESTIMATE 10.63 dw/sa --------------------------------------------------------------- Phosphorus as P205 0_64 % 12.73 dw/sa Potassium as K20 0.21 % 4.17 dw/sa Calcium 14.28 % 285.65 dw/sa Magnesium 0.14 % 2.83 dw/sa Sulfur 0.20 % 4.09 Zinc 216.02 ppm 0.43 Copper 37.75 ppm 0.08 Manganese 82.32 ppm 0.16 Sodium 345.00 ppm 0.69 Moisture 47.57 % Calcium Carbonate Equivalency 0.26 % 5.12 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste i.s used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 47.57 52.43 1048.6 524300 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.014 140 0.28 0.026702 267.0227 0.534045 Organic Nitrogen 0.8095 8095 16.19 1.543963 15439.63 30.87927 Nitrate Nitrogen 0.024276 242.76 0.48552 0.046302 463.0174 0.926035 Incorporated Available Nitrogen Estimate 0.5355 5355 10.71 1.021362 10213.62 20.42724 Surface Available Nitrogen Estimate 0.5315 5315 10.63 1.013733 10137.33 20.27465 Phosphorus as P2O5 0.6365 6365 12.73 1.214 12140 24.27999 Potassium as K2O 0.2085 2085 4.17 0.397673 3976.731 7.953462 Calcium 14.2825 142825 285.65 27.24108 272410.8 544.8217 Magnesium 0.1415 1415 2.83 0.269884 2698.837 5.397673 Sulfur 0.2045 2045 4.09 0.390044 3900.439 7.800877 Zinc 0.021602 216.02 0.43204 0.041202 412.016 0.824032 Copper 0.003775 37.75 0.0755 0.0072 72.00076 0.144002 Manganese 0.008232 82.32 0.16464 0.015701 157.0093 0.314019 Sodium 0.0345 345 0.69 0.065802 658.0202 1.31604 Calcium Carbonate Equivalency 0.256 2560 5.12 0.48827 4882.701 9.765401 May 2019 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: July 17, 2019 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. - Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 3.14 41.00 1.80 188.09 286.50 Cadmium, Total 1.15 " 39.00 1.70 483.66 736.73 Chromium, Total 65.25 1200.00 134.00 674.09 1026.79 Copper, Total 46.66 1500.00 67.00 471.36 717.99 Lead, Total 3.51 300.00 13.00 1215.42 1851.37 Mercury, Total 0.04 17.00 0.75 6459.60 9839.45 Molybdenum, Total 4.61 18.00 0.80 56.99 86.80 Nickel, Total 28.41 420.00 18.70 216.06 329.10 Selenium, Total 1.15 36.00 4.50 1280.28 1950.16 Zinc, Total 272.56 1525.00 125.00 150.54 229.31 PCB BRL 1.60 " Actual metal content less than amount indicated. Biosolids Biosolids Nutrient Nutrient Content, Content, ppm % Crop/Soil Requirement, #/Acre " Maximum Application Rate, DT/Acre/Yr. Maximum Application. Rate, WT/Acre/Yr. Ammonium Nitrogen 100.00 0.01 Organic Nitrogen 7670.00 0.77 Incorporated Available Nitrogen 4805.00 0.48 120.00 8.20 12.49 Surface Available Nitrogen 4775.00 0.48 120.00 8.25 12.57 Phosphorus as P205 1505.00 0.15 80.00 17.45 26.58 Potassium as K20 475.00 0.05 50.00 34.55 52.63 Calcium, Total 38865.00 3.89 Calcium as CaO 54411.00 5.44 Calcium as CaCO3 (CCE) 2715.00 0.27 2000.00 241.80 368.32 Magnesium, Total 330.00 0.03 Manganese 20.00 0.00 Sodium 80.00 0.01 Percent Moisture 34.35 These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a 'Class A' product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled 'Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Public Utility Director P. O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: INTENDED USE: LOCATION OF USE: QUANTITY RECEIVED: RECEIVED BY: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 17-Jul-19 SDG #: SDG-132326 South Carolina Certification Number: 21117 Receipt Date: 19-Jul-19 Report Date: 02-Aug-19 Approved By: Z41.— w Van Ward Lab Director Reporting Parameter Result Limit Unit Method Flag Date Time Analyst LSID-291909 7-17-19-0500 BIO Acid Digestion (Solids) YES EPA 200.2 Selenium, Total <0.999 0.999 mg/kg EPA 7010 / 6010D Percent Moisture 41.9 0.1 wt% SW846 3540 Aluminum, Total 6860 2 mg/kg SW846 6010D Arsenic, Total 2.72 0.999 mg/kg SW846 6010D Cadmium, Total <0.999 0.999 mg/kg SW846 6010D Chromium, Total 56.5 0.999 mg/kg SW846 6010D Copper, Total 40.4 0.999 mg/kg SW846 6010D Lead, Total 3.04 0.999 mg/kg SW846 601OD Molybdenum, Total <3.99 3.99 mg/kg SW846 6010D Nickel, Total 24.6 0.999 mg/kg SW846 601OD Zinc, Total 236 0.999 mg/kg SW846 6010D Mercury, Total 0.033 0.023 mg/kg SW846 7470A PCB BRL mg/kg SW846 8082A 35 S11A LSID-291910 7-1749-001INF Biochemical Oxygen Demand 970 2 mg/L SM 5210B LSID-291911 7-17-19-002 EFF 7/22/2019 9:30 JR 7/23/2019 10:59 AE 7/23/2019 11:52 ML 7/23/2019 14:51 JR 7/23/2019 10:59 AE 7/22/2019 16:08 JR 7/22/2019 16:08 JR 7/22/2019 16:08 JR 7/22/2019 16:08 JR 7/23/2019 13:28 JR 7/22/2019 16:08 JR 7/22/2019 16:08 JR 7/31/2019 12:05 CG 7/26/2019 14:45 HB 7/19/2019 10:32 AE Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 19-Jul-19 Client #: 168 ReportDate: 02-Aug-19 Sample Date: 18-Jul-19 Approved By: SDG #: SDG-132326 Van Ward Lab Director — --— -- ----- ---- Reporting Parameter Result Limit Unit Method Flag Date Time Analyst Acid Digestion (Liquids) YES EPA 200.2 7/22/2019 1:00 JR Copper, Total <0.005 0.005 mg/L EPA 200.7 7/22/2019 12:54 JR Lead, Total <0.005 0.005 mg/L EPA 200.7 7/22/2019 12:54 JR Biochemical Oxygen Demand 10.9 2 mg/L SM 5210B 7/19/2019 10:32 AE LSID-291912 SOURCE WATER Total Organic Carbon 5.7 0.5 mg/L SM 5310B-2011 7/23/2019 12:08 SF LSID-291913 FINISHED WATER Total Organic Carbon 2.5 0.5 mg/L SM 531OB-2011 7/23/2019 12:08 SF Page 2 A%NALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT M 291909 LABORATORY REPORT NUMBER 1907L48 DATE July 31, 2019 Primary Data Review By Secondary Data Review By Ashley Amick Chris Pafford Project Manager, Access Analytical Project Manager, AES aamick@axs-inc.com PLEASE NOTE: - Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. - AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 - AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. - Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 Access (Aes P , (DO_ la, -a- t 15D t'�°7Lye In DAVIS & BROWN { 124 W. Mcfver Road PH: 843-665-6746 PAGE # -OF Florence, SC 29501 FAX: J43-666-2205 REGI:LATORY: YES NO - CHAIN OF CRECORD � TURNAROUND TIME: P9USTQDY _TrANDARD RUSH _p2 CLIENT. SAMPLE ANA.YSIS REQUESTED i J ' I( 15 i § i o a_ USE CODES TO 1NDICTATE IF SAMPLE WAS FILTERED OR PRESERVED A-HNO, S=HCL C=HiSO. F=FILTRATION C=NACH E=NAZS;O, G=ZNCACETATE Preservative I � j W E U U co a r t0 f { I Q ' i i I { { I i j ADDRESS: PROGRAMAREA: O= DRINKNG'NATER G=GROUNDWATER S=SCUD SL=SLUDGE W=WASTEWATER O=OTHER PLEASEPRWLF6�8LY SHADED AREAS FOR LAS USE ONLY PHONE: FAX: SAMIPLE IC DATE TIME INITAL NOTES LAS ID F•ili In Ire Number of ContLiners for EACH Test I I 1 , ; SAMPLER SIGNATURE FLOW INFO 10E NO PACK RECEIPT TEMP: I' l oG Reanqu' �ew: ( Time: t y • =LGLt�JS RelinquM ed by Doc: ilme: ReangL:jhed by; Octal Pme: ReceMed by: � Date: Time: Wu[to, o:to Received by � DaLs. Time: Rncgrrod by. Date; Time: Comments; _PAne2nf9___ Analytical Environmental Services, Inc Date: 31-Jul-19 Client: Davis & Brown Client Sample ID: 291909 Project Name: 291909 Collection Date: 7/17/2019 11:05:00 AM Lab ID: 19071,48-001 Matrix: Soil Analyses Result Reporting Qual Limit Units Dilution BatchID Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 54 ug/Kg-dry 282546 1 07/26/2019 1445 HB Aroclor 1221 BRL 54 ug/Kg-dry 282546 1 07/26/2019 14.45 HB Aroclor 1232 BRL 54 ug/Kg-dry 282546 1 07/26/2019 1445 HB Aroclor 1242 BRL 54 ug/Kg-dry 282546 1 07/26/2019 14.45 HB Aroclor 1248 BRL 54 ug/Kg-dry 282546 1 07/26/2019 14.45 HB Aroclor 1254 BRL 54 ug/Kg-dry 282546 1 07/26/2019 14-45 HB Aroclor 1260 BRL 54 ug/Kg-dry 282546 1 07/26/2019 14:45 HB Surr: Decachlorobiphenyl 56.2 45 7-140 %REC 282546 1 07/26/2019 1445 HB Surr: Tetrachloro-m-xylene 679 45 3-126 %REC 282546 1 07/26/2019 14.45 HB PERCENT MOISTURE D2216 Percent Moisture 38 1 0 wt% R403536 1 07/29/2019 09:30 JW Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitanon range) S Spike Recovery outside limits due to matrix Nair See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 Clear Save as I AN v s1'icc u. 'gaO Aa6S F SLAvtcEs, tNc SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. AES Work Order Number 19O71.48 2. Carrier: FedEz 0 UPS ❑ USPS❑ Client Courler❑ Other Yes No N/A Details 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Shipping container/cooler received in good condition? • damaged,❑ leaking ❑ other - Custody seals present on shipping container? noCustody seals intact on shipping container? Temperature blanks present? • Cooler temperature(s) within limits of O-GPC? [See item 13 and 14 for temperature recordings.] ® ® Cooling initiated for recently collected samples / ice present Chain of Custody (CDC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampier name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? If no TAT indicated, proceeded with standard TAT per Terms & Conditions. ■ 13. Cooler 1 Temperature 4.9 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that i have completed sections 1-15 (dated initials). MJ 7/24/19 ......,. Comments Were sample containers intact upon receipt? no Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC? G) ® ® incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? • Were all of the samples listed on the COC received? Q ® ® samples received but not listed on COC ❑ samples listed on COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • Ilisted on CDC ❑ not listed on COC ❑ 27. Comments: certify that i have completed sections 16-27 (dated initials). EW 7/25/19 This section only applies to samples where pH can be ,h-Berl of Q-1. P-int vow Nn N/A Details Comments 28. nave containers needing chemical preservation oeen cnecaea r - 29. Containers meet preservation guidelines? 30. Was pH adjusted at Sample Receipt? I U 1 • Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Colifomis, VOCs and Oil & Grease/TPH. EW 7/25/19 I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2 LoCkb Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S11A indicates AES Laboratory (98016); S11G indicates GCAL Laboratory (73006); S 11P indicates Pace Analytical (96042001); S 11TS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg 89014) S 12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Rcvisnn 08/18 Dataqual(SubLabs)p2 wpd A N I M A L WASTE ANALYSI S R E P O R T Agricultural Service Laboratory LAB No. 71009 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29520 ACCOUNT COMRLBR DATE 07/26/2019 STOLSON@CHERAW.COM SAMPLE NO. 07171950 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton pi Ammonium Nitrogen 0.01 % 0.20 pi Organic Nitrogen 0.77 % 15.34 pi Nitrate Nitrogen --------------------------------------------------------------- 74.85 ppm 0.15 INCORPORATED AVAILABLE NITROGEN ESTIMATE 9.61 SURFACE AVAILABLE NITROGEN ESTIMATE 9.55 dw/sa --------------------------------------------------------------- Phosphorus as P205 0.15 % 3.01 dw/sa Potassium as K20 0.05 % 0.95 dw/sa Calcium , 3.89 % 77.73 dw/sa Magnesium 0.03 % 0.66 dw/sa Sulfur 0.04 % 0.79 Zinc 57.12 ppm 0.11 Copper 11.16 ppm 0.02 Manganese 17.73 ppm 0.04 Sodium 82.07 ppm 0.16 Moisture 34.35 % Calcium Carbonate Equivalency 0.27 % 5.43 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 34.35 65.65 1313 656500 % ppm lbs/ton % ppm lbs/ton as-sam led as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.01 100 0.2 0.015232 152.3229 0.304646 Organic Nitrogen 0.767 7670 15.34 1.168317 11683.17 23.36634 Nitrate Nitrogen 0.007485 74.85 0.1497 0.011401 114.0137 0.228027 Incorporated Available Nitrogen Estimate 0.4805 4805 9.61 0.731912 7319.117 14.63823 Surface Available Nitrogen Estimate 0.4775 4775 9.55 0.727342 7273.42 14.54684 Phosphorus as P205 0.1505 1505 3.01 0.229246 2292.46 4.58492 Potassium as K20 0.0475 475 0.95 0.072353 723.5339 1.447068 Calcium 3.8865 38865 77.73 5.92003 59200.3 118.4006 Magnesium 0.033 330 0.66 0.050267 502.6657 1.005331 Sulfur 0.0395 395 0.79 0.060168 601.6756 1.203351 Zinc 0.005712 57.12 0.11424 0.008701 87.00685 0.174014 Copper 0.001116 11.16 0.02232 0.0017 16.99924 0.033998 Manganese 0.001773 17.73 0.03546 0.002701 27.00685 0.054014 Sodium 0.008207 82.07 0.16414 0.012501 125.0114 0.250023 Calcium Carbonate Equivalency 0.2715 2715 5.43 0.413557 4135.567 8.271135 July 2019 -CKPl t-_)( `5 CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: September 18, 2019 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 3.27 41.00 1.80 166.25 275.56 Cadmium, Total 2.08 ' 39.00 1.70 246.17 408.04 Chromium, Total 45.64 1200.00 134.00 885.64 1467.99 Copper, Total 42.92 1500.00 67.00 470.90 780.54 Lead, Total 2.08 ' 300.00 13.00 1882.47 3120.30 Mercury, Total 0.03 17.00 0.75 7204.09 11941.13 Molybdenum, Total 4.17 ' 18.00 0.80 57.92 96.01 Nickel, Total 31.72 420.00 18.70 177.84 294.78 Selenium, Total 1.04 ' 36.00 4.50 1303.25 2160.20 Zinc, Total 229.25 1525.00 125.00 164.48 272.63 PCB BRL 1.60 "Actual metal content less than amount indicated Biosolids Biosolids Maximum Maximum Nutrient Nutrient Crop/Soil Application Application Content, Content, Requirement, Rate, Rate, ppm % #/Acre'" DT/Acre/Yr. WT/Acre/Yr. Ammonium Nitrogen 100.00 0.01 Organic Nitrogen 9045.00 0.90 Incorporated Available Nitrogen 5610.00 0.56 120.00 6.45 10.70 Surface Available Nitrogen 5580.00 0.56 120.00 6.49 10.75 Phosphorus as P205 6355.00 0.64 80.00 3.80 6.29 Potassium as K20 1455.00 0.15 50.00 10.37 17.18 Calcium, Total 205845.00 20.58 Calcium as CaO 288183.00 28.82 Calcium as CaCO3 (CCE) 1505.00 0.15 2000.00 400.86 664.45 Magnesium, Total 1510.00 0.15 Manganese 75.00 0.01 Sodium 300.00 0.03 Percent Moisture 39.67 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw's Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a 'Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Public Utility Director P.O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: ADDRESS: INTENDED USE: LOCATION OF USE: QUANTITY RECEIVED: - -- RECEIVED BY: --_- - -- ---- - - Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Receipt Date: 19-Sep-19 Client #: 168 Report Date: 08-Oct-19 Sample Date: 18-Sep-19 SDG #: SDG-133360 Parameter LSID-294093 Acid Digestion (Solids) Selenium, Total Percent Moisture Aluminum, Total Arsenic, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Molybdenum, Total Nickel, Total Zinc, Total Mercury, Total PCB Approved By: Z 41,— Van Ward Lab Director Reporting Result Limit Unit Method Flag Date Time Analyst 9-1849-0500 BIO SOLIDS YES EPA 200.2 <0.995 0.995 mg/kg EPA 7010 / 6010D 35.9 0.1 wt% SW846 3540 5840 3.98 mg/kg SW846 6010D 3.12 0.995 mg/kg SW846 6010D <1.99 1.99 mg/kg SW846 601OD 43.6 1.99 mg/kg SW846 6010D 41.0 1.99 mg/kg SW846 601OD <1.99 1.99 mg/kg SW846 601OD <3.98 3.98 mg/kg SW846 6010D 30.3 1.99 mg/kg SW846 6010D 219 1.99 mg/kg SW846 6010D 0.030 0.022 mg/kg SW846 7470A BRL mg/kg SW846 8082A S11A LSID-294094 9-18-19-001INF Biochemical Oxygen Demand 780 2 mg/L SM 5210B LSID-294095 9-18-19-002 EFF 9/23/2019 10:15 AE 9/24/2019 11:27 AE 9/23/2019 10:14 ML 9/30/2019 12:50 JR 9/24/2019 11:27 AE . 9/23/2019 16:35 AE 9/23/2019 16:35 AE 9/23/2019 16:35 AE 9/23/2019 16:35 AE 9/30/2019 12:50 JR 9/23/2019 16:35 AE 9/23/2019 16:35 AE 10/2/2019 9:45 CG 9/25/2019 20:53 UH 9/19/2019 10:27 AE Page 1 Davis & Brown PO Bog 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF South Carolina Certification Number: 21117 P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 19-Sep-19 SDG #: SDG-133360 Parameter Result Biochemical Oxygen Demand 22.0 Receipt Date: 19-Sep-19 Report Date: 08-Oct-19 Approved By: Reporting Limit Unit Method 2 mg/L SM 5210B Page 2 G'' 4s— tea/ a14.f Van Ward Lab Director Flag Date Time Analyst 9/19/2019 10:27 AE ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT iD 294093 LABORATORY REPORT NUMBER 1909J43 DATE September 26, 2019 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PCM Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust Wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 "-J� IMDAVIS O 124 W. Mover Rned PH.,W-666-B746 PAGE # _ OF WN Florence, SC 29501 FAX: M-656-2208 REGULATORY: YES NO �t - CHAIN OF CUSTODY RECORD TURNAROUND 77ME' P± STANCARC RUSH P2 CLIENT: 14 1t //yy G i I SAMPLE ANAL'r SIS REQLESTEC S a USE CODES TO (NDICT4: F IF SAMPLEWAS FIL e.RED OR PRESERVED: A = HNO, S=HCL D=H'SO, F- FILTRATION C = NAOH E = NAzS;Os G = ANCACS-ATE prumve" m E CD7 2 0 (L , 2 w 2 U O tl ( I i I I G i ADDRESS: PROGRAM AREA: ❑=DRINKING WATER G=GROUNDWATER S-SOLID SL-SLUDGE W- WASTEWATER O.OTHER PLEAgEPR)NTLEGIBLY SHAVED AREAS FOR LAB USEONLY PHONE: FAX. SAMPLE 10 GATE nMF ;NMAL NOTES LAB IC �} FIR to the Number o! Coms(ners W EACH Test I i I I I I i t SAMPLER SIGNATURE FLOW INFO ICE NO PACK £�Ct7F+7 Tmw: �-Y c Rdin9+riah e: rme: RSknGUlehoc by Data: Time: Rellmuished 'gy: Date: ono: Rue Y: Date: limo: Reemod ny date: T'me: Roce'ed by: Dete: 4I e: Comments: ISSUED: NOVEMSER ZU`Z Page 2 of 4 Analytical Environmental Services, Inc Date: 26-Sep-19 Client: Davis & Brown Client Sample ID: 294093 Project Name: 294093 Collection Date: 9/18/2019 8:55:00 AM Lab ID: 1909J43-001 Matrix: Soil Analyses Result Reporting Limit Qual Units BatchID Dilution Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 53 ug/Kg-dry 285435 1 09/25/2019 20:53 UH Aroclor 1221 BRL 53 ❑g/Kg-dry 285435 1 09/25/2019 20 53 UH Aroclor 1232 BRL 53 ug/Kg-dry 285435 1 09/25/2019 20 53 UH Aroclor 1242 BRL 53 ug/Kg-dry 285435 1 09/25/2019 20 53 UH Aroclor 1248 BRL 53 ug/Kg-dry 285435 1 09/25/2019 20-53 UH Aroclor 1254 BRL 53 ug/Kg-dry 285435 1 09/25/2019 20:53 UH Aroclor 1260 BRL 53 ug(Kg-dry 285435 1 09/25/2019 20.53 UH Surr: Decachlorobiphenyl 54.7 45 7-140 %REC 285435 1 09/25/2019 20 53 UH Surr: Tetrachloro-m-xylene 55.6 45.3-126 %REC 285435 1 09/25/2019 20 53 UH PERCENT MOISTURE D2216 Percent Moisture 367 0 wt% R407664 1 09/24/2019 00:00 JW Qualifiers: " value exceeds maximum contaminant level BRL Below reporting lima H Holding times for preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nair See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 Clear Save as IAN�trnay. 1ENvr3torafEN�rat. AFS SER-.tCf 1PiC. SAMPLE/COOLER RECEIPT CHECKLIST 1. Client Name: Access Analytical, Inc. AES Work Order Number: 1909.143 2. Carrier: Fed& 0 UPS ❑ USPS ❑ Client ❑ Courier❑ Othei Yes No N/A Details Comments Shipping container/cooler received in good condition? • damaged ❑ leaking ❑ other❑ Custody seals present on shipping container? • Custody seals intact on shipping container? Temperature blanks present? • Cooler temperature(s) within limits of 0-O C? (See item 13 and 14 for temperature recordings.] E) ® 0 Cooling initiated for recently collected samples / ice present ! Chain of Custody (COC) present? • Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on COC? • Were all samples received within holding time? • TAT marked on the COC? • If no TAT indicated, proceeded with standard TAT per Terms &Conditions. 13. Cooler 1 Temperature 0.4 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24 25 26 °C Cooler3Temperature °C Cooler 4 Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C 1 certify that I have completed sections 1-15 (dated initials). MJ 9/20/19 fnm antc . . Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the COC? O Q 0 incomplete info ❑ illegible ❑ no label ❑ other ❑ Are analyses requested indicated on the COC? • 0 Q ® samples received but not listed on CDC Were all of the samples listed on the COC received. samples listed an COC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? • Were samples received in appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? . Were trip blanks submitted? • listed on COC L not listed on COC 27. Comments: I certify that I have completed sections 16-27 (dated initials). MDP 9/20/19 This section only applies to samples where pH can be ... Comments 28. 29. 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Colifonns. VOCs and Oil & GreaserTPH. I certify that I have completed sections 28-30 (dated initials 'd Checklist 6.9.17 Rev 2 al [} Have containers needing chemical preservation been checked?' Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? I G I U 1 • MDP 9/20/19 Page 4 of 4 27. Comments: I certify that I have completed sections 16-27 (dated initials). MDP 9/20/19 This section only applies to samples where pH can be ... Comments 28. 29. 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Colifonns. VOCs and Oil & GreaserTPH. I certify that I have completed sections 28-30 (dated initials 'd Checklist 6.9.17 Rev 2 al [} Have containers needing chemical preservation been checked?' Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? I G I U 1 • MDP 9/20/19 Page 4 of 4 MDP 9/20/19 Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016; 99006001 Note: S 11A indicates AES Laboratory (98016); S 11 G indicates GCAL Laboratory (73006); SI IP indicates Pace Analytical (96042001); S11TS indicates Test America Savannah (98001) S 11 TP indicates Test America Pittsburg 89014) S121 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 9603 7001 S 18 I South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 S29 South Carolina Lab Certification Number: 32566 S30 Galbraith Laboratories, Inc. Knoxville TN S31 South Carolina Lab Certification Number: 32576 Rrn bn08/18 Dataqual(SubLabs)p2 wpd DAVIS &BROWN 124 IN. McIver Road PH: 843-665.6746 PAGE # OFIn _ Florence, SC 29501 FAX: 843-656-2208 �-711/ME: REGULATORY: YES No CHAIN OF CUSTQDY. RECDRD _P7 STANDARD RUSH P2 TURNAROUND CLIENT: ( LL% SAMPLE ,' NALYSIS REQUESTED I L r 4 < a USE COCES TO WDICTATE IF SAMPLE WAS FILTERED OR PRESEPVED: A=HNO, B - HCL D = H_SO4 F = FILTRATION C = NAOH E = NA,S20, G = 21NCACETATE Preservative v o V U m w O U ° s ,�.- ? ADDR SS; PROGRAMAREA: D=DRINKING 'WATER G=GROUNDWATER S=SOLID SL=SLUDGE W =WASTEWATER O=OTHER PLEASE PRINT LEGIBLY PHONE: FAX: SAMPLE ID DATE TIME NITtAL NOTES LA8 ID 13SC w'k"6S Fill in the Numberof Containers for EACH Test Acca Uigc's 5<< c crc �IG "4S I-i°t 19 0-?Lp aI 2agog4 9-0 1of e-75`l C C � I V11 2°t�to�is SAMPLERSIGNATURE ^^ FLOWINFO i ICE YE"C, PACK RECEIPT TEMP : 2f- •p2 a C Relinquished by: _ Dates R.eli fished ty Date: Tia Ralincuished by Date: Time: Received by: Date: t' ed by Date: Time Received by. Date: Time: Comments L A N I M A L W A S T E A N A L Y S I S R E P O R T Agricultural Service Laboratory LAB No. 91209 Clemson University TURNER, SHERRY PO BOX 219 CHERAW SC29520 ACCOUNT COMRLBR DATE 10/03/2019 STOLSON@CHERAW.COM SAMPLE NO. 09181950 MANURE: OTHER STORAGE: COVERED = ----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton pi Ammonium Nitrogen 0.01 % 0.20 pi Organic Nitrogen 0.90 % 18.09 pi Nitrate Nitrogen --------------------------------------------------------------- 64.55 ppm 0.13 INCORPORATED AVAILABLE NITROGEN ESTIMATE 11.22 SURFACE AVAILABLE NITROGEN ESTIMATE 11.16 dw/sa --------------------------------------------------------------- Phosphorus as P205 0.64 % 12.71 dw/sa Potassium as K20 0.15 % 2.91 dw/sa Calcium 20.58 % 411.69 dw/sa Magnesium 0.15 % 3.02 dw/sa Sulfur 0.18 % 3.62 Zinc 293.20 ppm 0.59 Copper 42.83 ppm 0.09 Manganese 73.00 ppm 0.15 Sodium 301.05 ppm 0.60 Moisture 39.67 % Calcium Carbonate Equivalency 0.30 % 6.01 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 39.67 60.33 1206.6 603300 % ppm lbs/ton % ppm lbs/ton as -sampled as -sampled as -sampled dry ton dry ton dry Ammonium Nitrogen 0.01 100 0.2 0.016576 165.755 0.33151 Organic Nitrogen 0.9045 9045 18.09 1.499254 14992.54 29.98508 Nitrate Nitrogen 0.006455 64.55 0.1291 0.010699 106.9949 0.21399 Incorporated Available Nitrogen Estimate 0.561 5610 11.22 0.929886 9298.856 18.59771 Surface Available Nitrogen Estimate 0.558 5580 11.16 0.924913 9249.13 18.49826 Phosphorus as P2O5 0.6355 6355 12.71 1.053373 10533.73 21.06746 Potassium as K2O 0.1455 1455 2.91 0.241 174 2411.735 4.823471 Calcium 20.5845 205845 411.69 34.11984 341198.4 682.3968 Magnesium 0.151 1510 3.02 0.25029 2502.901 5.005801 Sulfur 0.181 1810 3.62 0.300017 3000.166 6.000332 Zinc 0.02932 293.2 0.5864 0.048599 485.9937 0.971987 Copper 0.004283 42.83 0.08566 0.007099 70,99287 0.141986 Manganese 0.0073 73 0.146 0.0121 121.0012 0.242002 Sodium 0.030105 301.05 0.6021 0.049901 499.0055 0.998011 Calcium Carbonate Equivalency 0.3005 3005 6.01 0.498094 4980.938 9.961876 September 2019 i CHERAW ALKALINE BIOSOLIDS SOIL AMENDMENT CHEMICAL CHARACTERISTICS AND LAND APPLICATION RATES BIOSOLIDS SAMPLE DATE: November 20, 2019 METALS Biosolids Metal Content, ppm Maximum Allowable Metal Content, ppm Maximum Maximum Allowable Application App. Rate, Rate, #/Acre/Yr. DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Arsenic, Total 2.88 41.00 1.80 182.27 312.97 Cadmium, Total 1.09 39.00 1.70 454.30 780.04 Chromium, Total 59.72 1200.00 134.00 653.42 1121.94 Copper, Total 30.41 1500.00 67.00 641.58 1101.62 Lead, Total 4.08 300.00 13.00 928.60 1594.43 Mercury, Total 0.05 17.00 0.75 4404.89 7563.34 Molybdenum, Total 4.35 ' 18.00 0.80 53.53 91.91 Nickel, Total 21.82 420.00 18.70 249.61 428.59 Selenium, Total 0.54 ' 36.00 4.50 2407.53 4133.81 Zinc, Total 233.58 1525.00 125.00 155.83 267.57 PCB BRL 1.60 ` Actual metal content less than amount indicated Biosolids Nutrient Content, ppm Biosolids Nutrient Content, % Crop/Soil Requirement, #/Acre " Maximum Application Rate, DT/Acre/Yr. Maximum Application Rate, WT/Acre/Yr. Ammonium Nitrogen 0.00 0.00 Organic Nitrogen 3875.00 0.39 Incorporated Available Nitrogen 2740.00 0.27 120.00 12.75 21.90 Surface Available Nitrogen 2740.00 0.27 120.00 12.75 21.90 Phosphorus as P205 4670.00 0.47 80.00 4.99 8.57 Potassium as K20 560.00 0.06 50.00 26.00 44.64 Calcium, Total 150775.00 15.08 Calcium as CaO, 211085.00 21.11 Calcium as CaCO3 (CCE) 3015.00 0.30 2000.00 193.17 331.67 Magnesium, Total 1920.00 0.19 Manganese 45.00 0.00 Sodium 125.00 0.01 Percent Moisture 41.76 " These are typical values and must be adjusted based upon specific site conditions DT is Dry Tons of Biosolids. - WT is Wet Tons of Biosolids. CERTIFICATION: This biosolid product has been produced by the Town of Cheraw s Wastewater Treatment Plant by a treatment process that pasteurized plant residual solids using high temperature and lime (calcium oxide). The Town of Cheraw certifies that this biosolid complies with the Environmental Protection Agency regulations 40 CFR Part 503 for a 'Class A" product and has a metal and nutrient content as presented above. DIRECTIONS FOR USE: This biosolid is intneded to be used as a soil amendment. The biosolid land application rate shall not exceed the most restrictive Maximum Application Rate as indicated in the table above. The application rate for nitrogen, phosphorus, potassium, and calcium is dependent upon the crop grown and site soil characteristics. The user should contact the Clemson Extension Service (843-623-2134) and/or the Soil Conservation Service (843-623-2187) for assistance in determining the proper application rate for each crop and site. In no case shall the land application rate exceed the agronomic rate for the crop grown. User should also refer to the Clemson Extension Service Circular #476 titled "Lime and Fertilizer Recommendations.' THIS PRODUCT IS HIGHLY ALKALINE AND SHOULD BE HANDLED ACCORDINGLY. AVOID PROLONGED CONTACT WITH THE SKIN. AVOID CONTACT WITH THE EYES. THE TOWN OF CHERAW IS NOT RESPONSIBLE FOR IMPROPER USE OR HANDLING OF THIS BIOSOLID PRODUCT. Mr. John D. Stowe, Public Utility Director P. O. Box 219; Cheraw, SC 29520 Telephone: 843-537-8440 FAX: 843-537-8442 PRODUCT USER NAME: INTENDED USE: LOCATION OF USE: QUANTITY RECEIVED: Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 21-Nov-19 SDG #: SDG-134432 South Carolina Certification Number: 21117 Receipt Date: 21-Nov-19 Report Date: 06-Dec-19 Approved By: Scott Fields Lab Director Reporting Parameter Result Limit Unit Method LSID-296485 11-20-19-001 INF Biochemical Oxygen Demand 550 2 mg/L SM 5210B LSID-296486 11-20-19-002 EFF Biochemical Oxygen Demand 75.4 2 mg/L SM 5210B LSID-296487 11-20-19-0500 BIO Acid Digestion (Solids) YES EPA 200.2 Selenium, Total <0.494 0.494 mg/kg EPA 7010 / 6010D Percent Moisture 39.1 0.1 Wt% SW846 3540 Aluminum, Total 5990 39.6 mg/kg SW846 601OD Arsenic, Total 2.61 0.494 mg/kg SW846 6010D Cadmium, Total <0.989 0.989 mg/kg SW846 601OD Chromium, Total 54.2 0.989 mg/kg SW846 6010D Copper, Total 27.6 0.989 mg/kg SW846 6010D Lead, Total 3.70 0.989 mg/kg SW846 6010D Molybdenum, Total <3.95 3.95 mg/kg SW846 6010D Nickel, Total 19.8 0.989 mg/kg SW846 6010D Zinc, Total 212 0.989 mg/kg SW846 6010D Mercury, Total 0.042 0.026 mg/kg SW846 7470A Flag Date Time Analyst 11/21/2019 10:23 AE 11/21/2019 10:23 AE 11/25/2019 9:30 AE 11/25/2019 15:02 AE 11/25/2019 16:00 ML 11/26/2019 11:24 JR 11/25/2019 15:02 AE 12/4/2019 11:06 JR 12/4/2019 11:06 JR 12/4/2019 11:06 JR 12/4/2019 11:06 JR 11/26/2019 11:06 JR 12/4/2019 11:06 JR 12/4/2019 11:06 JR 12/4/2019 12:45 CG Page 1 Davis & Brown PO Box 15038 Quinby, SC 29506 (843) 665-6746 FAX: (843) 629-1444 Certificate of Analysis Client: CHERAW, TOWN OF P.O.BOX 219 CHERAW, SC 29520 Contact: SHERRY TURNER Client #: 168 Sample Date: 20-Nov-19 SDG #: SDG-134432 Parameter PCB South Carolina Certification Number: 21117 Receipt Date: 21-Nov-19 Report Date: 06-Dec-19 Approved By:� Scott Fields Lab Director Reporting Result Limit Unit Method BRL mg/kg SW846 8082A Page 2 Flag Date Time Analyst S11A 11/27/2019 15:57 UH ANALYTICAL. L. INC. ANALYTICAL REPORT CLIENT Davis & Brown P.O. Box 15038 Quinby SC 29506 ATTENTION Scott Fields PROJECT ID 296487 LABORATORY REPORT NUMBER 1911N38 DATE November 29, 2019 Primary Data Review By Secondary Data Review By Chris Pafford Project Manager, AES PLEASE NOTE: Ashley Amick Project Manager, Access Analytical aamick@axs-inc.com Unless otherwise noted, all analysis on this report performed at Analytical Environmental Services Inc. (AES Inc), 3080 Presidential Drive, Atlanta, GA 30340. AES is SCDHEC certified laboratory # 98016, NCDENR certified lab # 562, GA certified lab # FL-E87582, NELAP certified laboratory # E87582 AIHA-LAP,LLC Laboratory ID:100671 for Industrial Hygiene samples (Organics, Metals, PC1NI Asbestos, Gravimetric), Environmental Lead (Paint, Soil, Dust wipes, Air), and Environmental Microbiology (Fungal) Direct Examination. Local support services for this project are provided by Access Analytical, Inc. Access Analytical is a representative of AES serving client in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll fee at 883.315.4243 Page 1 of 4 1q ►t N3g ja DAVIS & BROWN Y24Flo en e, SC Road PH: Y43-656-6746 -2208 PAGE # _ OF _ Florence, SC 20501 FAX Y47.666-22YY REGULATORY: YES NO CHAIN OF CUSTODY RECORD TURNAROUND TIME: WI STANDARD RUSH — _P2 CLIENT: +^� {L SAMPLE ANALYSIS RECUES ED z 0 a USE CODES TO INDICTATE IF SAMPLC WAS FILTERED OR PRESERVED: A=HNO, B=HCL D=HzSO, F=FILTRATION C - NAOH E = NA,S,O, G-ZINCACETATE Prcservallve sJ E EE L d y w z H OZ L) u m o H I ADDRESS: RC �GRAMAREA: D - DRINKING WATER G=GROUNDWATER S=SOLID SL=SLUDGE W = WASTEWATER O=OTHER PLEASE PRINT LEGIBLY SHADED AREAS FOR LAB USE ONLY PHONE: Fax; SAMPLE ID DATE TIME INITIAL NOTES LAB IC FIII In the Number of Containers for EACH Test Y SAMPLER SIGNATURE FLOWINFO ! ICE YES` NO PACK RECEIPT TEMP: � ,�o C Rellnqui Oatn Time: Relinquished by Data: Time: Relinquished by: Date: Time: Received by: Del,.: Time: Recs= j Def Time: Received by: Dele: nme: Comments: Analytical Environmental Services, Inc Date: 29-Nov-19 Client: Davis & Brown Client Sample ID: 296487 Project Name: 296487 Collection Date: 11/20/2019 10:10:00 AM Lab ID: 1911N38-001 Matrix: Soil Analyses y Result Reporting Limit Qual Units BatchlD Dilution Factor Date Analyzed Analyst POLYCHLORINATED BIPHENYLS SW8082A (SW3550C) Aroclor 1016 BRL 49 ug/Kg-dry 288718 1 11/27/2019 15:57 UH Aroclor 1221 BRL 49 ugfKg-dry 288718 1 11/27/2019 15:57 UH Aroclor 1232 BRL 49 ug[Kg-dry 288718 1 11/27/2019 1557 UH Aroclor 1242 BRL 49 ug/Kg-dry 288718 1 11/27/2019 15 57 UH Aroclor 1248 BRL 49 ug/Kg-dry 288718 1 11/27/2019 1557 UH Aroclor 1254 BRL 49 ug/Kg-dry 288718 1 11/27/2019 15.57 UH Aroclor 1260 BRL 49 ug/Kg-dry 288718 1 11/27/2019 1557 UH Surf: Decachlorobiphenyl 579 45 7-140 %REC 288718 1 11/27/2019 1557 UH Sun: Tetrachloro-m-xylene 75.7 45.3-126 %REC 288718 1 11/27/2019 15:57 UH PERCENT MOISTURE D2216 Percent Moisture 323 0 wt°/ R412464 1 11/25/2019 09.00 JW Qualifiers: * Value exceeds maximum contaminant level BRL Below reporting limit H Holding times For preparation or analysis exceeded N Analyte not NELAC certified B Analyte detected in the associated method blank > Greater than Result value E Estimated (value above quantitation range) S Spike Recovery outside limits due to matrix Nair See case narrative NC Not confirmed < Less than Result value J Estimated value detected below Reporting Limit Page 3 of 4 IA�+-x,,,Lyncou .ENVIRONMENTAL AES SLILVICHS, INC. 1. Client Name: Access Analytical, Inc. 2. Carrier: Fed Ex •❑ UPS ❑ USPS❑ Client Courier❑ Othel _ SAMPLE/COOLER RECEIPT CHECKLIST AES Work order Number 1911N38 Comments Saves$ Shipping container/cooler received in good condition) •n I Jdamaged _ leaking ❑ other-7 Custody seals present on shipping container? 0• Custody seals intact on shipping container? Temperature blanks present? 0 • Cooler temperature(s) within limits of 0-6°C? (See item 13 and 14 for temperature recordings.) G ® ® Cooling initiated for recently collected samples / ice present Chain of Custody (CDC) present? U. Chain of Custody signed, dated, and timed when relinquished and received? • Sampler name and/or signature on CDC? no Were all samples received within holding time7 • TAT marked on the CDC? Ilf no TAT indicated, proceeded with standard TAT per Terms & Conditions. 13. Cooler 1 Temperature 1.6 °C Cooler 2 Temperature 14. Cooler 5 Temperature °C Cooler 6 Temperature 15. Comments: 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. °C Cooler 3 Temperature °C Cooler 4 Temperature °C °C Cooler 7 Temperature °C Cooler 8 Temperature °C I certify that I have completed sections 1-15 (dated initials). AS 11/22/19 n,,..a. r-Monts Were sample containers intact upon receipt? • Custody seals present on sample containers? Custody seals intact on sample containers? Do sample container labels match the CDC? ® 10samples incomplete info ❑ illegible El no label ❑ other ❑ Are analyses requested indicated on the CDC? • Were all of the samples listed on the CDC received? 0 ® received but not listed on CDC ❑ samples listed on CDC not received ❑ Was the sample collection date/time noted? • Did we receive sufficient sample volume for indicated analyses? Were samples received In appropriate containers? Were VOA samples received without headspace (< 1/4" bubble)? Were trip blanks submitted? • listed on COC ❑ not listed on CDC ❑ 27. Comments: I certify that I have completed sections 16-27 (dated initials). D511/22/19 This section only applies to samples where pH can be 28. 29. 30. Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & GreasafTPH. I certify that I have completed sections 28-30 (dated initials). Checklist 6.9.17 Rev 2-.�w....r.tmte'.'< Have containers needing chemical preservation been checked? Containers meet preservation guidelines? Was pH adjusted at Sample Receipt? • DS 11/22/19 Page 4 of 4 DAVIS & BROWN Data Qualifiers Within the attached report, some analytical data may be reported as Qualified Data as indicated by Data Qualifier or flag next to the result. The data qualifier "S" indicates that the analysis was performed by another South Carolina certified lab. This table summarizes the South Carolina Lab Certification Numbers for those laboratories. S South Carolina Lab Certification Number: 23101 S 1 South Carolina Lab Certification Number: 93013 S2 South Carolina Lab Certification Number: 23105 S3 South Carolina Lab Certification Number: 10120 S4 South Carolina Lab Certification Number: 84002 S5 South Carolina Lab Certification Number: 32117 S6 Agricultural Service Laboratory Clemson University S7 South Carolina Lab Certification Number: 36001 S8 Lab samples were subcontracted. See attached documentation. S9 South Carolina Lab Certification Number: 94014001; 94014002 S 10 South Carolina Lab Certification Number: 84009 S11 South Carolina Lab Certification Number: 96026; 96031; 98001; 73006; 98016 Note: S 11 A indicates AES Laboratory; S 11 G indicates GCAL Laboratory S12 AASHTO R18 Certified S 13 South Carolina Lab Certification Number: 96012 S 14 South Carolina Lab Certification Number: 89002 S15 S 16 South Carolina Lab Certification Number: 84004 S 17 South Carolina Lab Certification Number: 96037001 S 18 South Carolina Lab Certification Number: 95005 S 19 South Carolina Lab Certification Number: 23104 S20 South Carolina Lab Certification Number: 96027001 S21 South Carolina Lab Certification Number: 21005 S22 South Carolina Lab Certification Number: 24110 S23 South Carolina Lab Certification Number: 84001001 S24 South Carolina Lab Certification Number: 82014001 S25 Sample was analyzed by Microsee s, Inc Laboratory S26 North Carolina Lab Certification Number: 21 (Wilson Division NC00120) S27 South Carolina Lab Certification Number: 40569 S28 South Carolina Lab Certification Number: 32571 Revision 05/13 Dataqual (subLabs) .wpd r A N I M A L WASTE ANALYS IS R E P O R T Agricultural Service Laboratory LAB No. 121390 Clemson University TURNER, SHERRY ACCOUNT COMRLBR PO BOX 219 DATE 12/13/2019 CHERAW SC 29520 STOLSON@CHERAW.COM SAMPLE NO. 11201950 MANURE: OTHER STORAGE: COVERED -----------------RESULTS REPORTED ON AN AS -SAMPLED BASIS ---------------------- ANALYST lbs/ton pi Ammonium Nitrogen 0.00 % 0.00 pi Organic Nitrogen 0.39 % 7.75 pi Nitrate Nitrogen --------------------------------------------------------------- 257.40 ppm 0.51 INCORPORATED AVAILABLE NITROGEN ESTIMATE 5.48 SURFACE AVAILABLE NITROGEN ESTIMATE 5.48 dw/sa --------------------------------------------------------------- Phosphorus as P205 0.47 % 9.34 dw/sa Potassium as K20 0.06 % 1.12 dw/sa Calcium 15.08 % 301.55 dw/sa Magnesium 0.19 % 3.84 dw/sa Sulfur 0.11 % 2.21 Zinc 182.28 ppm 0.36 Copper 25.04 ppm 0.05 Manganese 45.42 ppm 0.09 Sodium 126.37 ppm 0.25 Moisture 41.76 % Calcium Carbonate Equivalency 0.30 % 6.03 ------------------------------------------------------------------------------ INCORPORATED PLANT AVAILABLE NITROGEN ESTIMATE - 80% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be incorporated into the soil within hours of application. Assumes some loss of ammonium-N during application and prior to incorporation. SURFACE PLANT AVAILABLE NITROGEN ESTIMATE - 50% of ammonium-N, 60% of organic-N, and 100% of nitrate-N (if determined). Assumes the manure will be left on the surface of the soil with no incorporation by plowing or irrigation. Available nitrogen calculations are estimates and if nitrate-N was not re- quested the amount of available nitrogen may be slightly more than reported. Also, the actual amount may be more or less than the estimate depending on the composition of the manure, soil type, and environmental conditions. All of the potash in the animal waste should be plant available in the first year of application. Although not all of the phosphorous is available in the first year, its availability should be comparable to that in commercial fertilizers. The rate of animal waste to apply for crop production is dependent on the nutrient content of the waste, method of application and incorporation, soil test, crop to be grown, and previous manure applications. In most cases, the plant available nitrogen content of the waste is used to determine the rate of % moisture % solids lbs. solids/ton lbs. solids/500 tons 41.76 58.24 1164.8 582400 % ppm lbs/ton % ppm lbs/ton as-sam led as -sampled as -sampled d ton d ton dry Ammonium Nitrogen 0 0 0 0 0 0 Organic Nitrogen 0.3875 3875 7.75 0.66535 6653.503 13.30701 Nitrate Nitrogen 0.025740 257.4 0.5148 0.044196 441.9643 0.883929 Incorporated Available Nitrogen Estimate 0.274 2740 5.48 0.470467 4704.67 9.409341 Surface Available Nitrogen Estimate 0.274 2740 5.48 0.470467 4704.67 9.409341 Phosphorus as P205 0.467 4670 9.34 0.801854 8018.544 16.03709 Potassium as K20 0.056 560 1.12 0.096154 961.5385 1.923077 Calcium 15.0775 150775 301.55 25.88856 258885.6 517.7713 Magnesium 0.192 1920 3.84 0.32967 3296.703 6.593407 Sulfur 0.1105 1105 2.21 0.189732 1897.321 3.794643 Zinc 0.018228 182.28 0.36456 0.031298 312.9808 0.625962 Copper 0.002504 25.04 0.05008 0.004299 42.99451 0.085989 Manganese 0.004542 45.42 0.09084 0.007799 77.98764 0.155975 Sodium 0.012637 126.37 0.25274 0.021698 216.9815 0.433963 Calcium Carbonate Equivalency 0.3015 3015 6.03 0.517685 5176.854 10.35371 November 2019 tH1r1rutiLrtilriVVL'1\ t11r11 Vr$.1%in 111 1A.A%-II%jl,1 ICl'jju%.,11V1V Jr"K1V1 Facility Name: Town of Cheraw Permit Number: WQ0014248 WWTP Name: Town of Cheraw WWrP NPDES Number: SCO020249 Monitoring Period: From 01 /01 /19 To 12/31 /19 Pathogen Reduction (40 CFR 503.32) - Please indicate level achieved and alternative performed: Class A: Alternative 1 ❑ Alternative 2 ❑ I Alternative 3 ❑ Alternative 40 1 Alternative 5 ® I Alternative 6 ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost ❑ Heat Drying ❑ Heat Treatment ❑ Thermophilic ❑ Beta Ray ❑ Gamma Ray ❑ I Pasteurization Class B: Alternative 1 ❑ 7 Alternative 2 ❑ 1 Alternative 3 ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ Air Drying ❑ Composting ❑ Aerobic Digestion ❑ Anaerobic Digestion[] If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Level in Qh A -A Pathogen Density Number o Excee- dences Frequency of Analysis Sample Type Analytical Tech-nique Minimum Geo. Mean Maximurr Units Fecal Coliform 2 x 10 to the 6th power MPN per gram of total solids or 2 x 10 to the 6th power CFU per gram of 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (40 CFR 503.33) - Please indicate option performed: Option 1 ❑ Option 2 ❑ Option 3 ❑ Option 4 ❑ 1 Option 5 ❑ Option 6 ® Option 7 ❑ Option 8 ❑ Option 9 ❑ 10ption 10 ❑ No vector attraction reduction options were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) ® "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32 and the vector attraction reduction requirement in 40 CFR 503.33 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Sherry Turner/Operator-of-Record Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) ZF 20 Signattge of Preparer ate Signature of Land Applier (if applicable) Date Author Daryl D. Merritt DENR FORM RF (7/2002) 11 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution / 10 ml sample 10' dilution / 1.0 ml sample Single Strength Single Strength 10''- dilution / 1.0 ml sample 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: -1(t-1 -t)o1NU Date/ Time Test Read:-17-I9t z, 111 o� Time Placed in Incubator: I Incubator Temp: 35, Q Time Transferred to Water Bath: LH Water Bath Temp: Lf q,& ' C, Operator : a . Media Lot # : al q (T74-5' % Solids 10 . S Jw Sample # : I -1 Ce') R_ 05D0 MPN Fecal Coliform = 10 x MPN Index / 100 ml = (� per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date Time I Q"S Op. C',B FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)x100 C -B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : D S-nO Weight of dried residue + dish: Duplicate weight of dried residue + dish : Weight of empty dish Weight of wet sample + dish : % Total Solids = --7 0. 5 0/0 1. '�3'U ' . �7 .. °I 3 �3 3'�.--� 7c00 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-dilution / 10 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength Single Strength 10-2dilution / 1.0 ml sample 10' dilution / 0.1 ml sample Date/Time Test Set -Up: - 9 10 d S Time Placed in Incubator: I b A S Date/ Time Test Read: Incubator Temp: Time Transferred to Water Bath: Water Bath Temp: L Operator : a Media Lot # r % Solids (_05 , DO Sample # : Q-a'D--\9 - C&DO MPN Fecal Coliform = 10 x MPN Index / 100 ml = D per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date a, 0)ID'19 Time Op, J. qvtso OVA C FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids _ (A-B)x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # :��-�g- Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = (-01 �J a•�61q-,2, 4(n S FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-' dilution / 10 ml sample Single Strength 10-' dilution / 1.0 ml sample Single Strength 10''- dilution / 1.0 ml sample Single Strength 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: 3`ADI-1Time, Placed in Incubator: o\-( a Time Transferred to Water Bath: 3 q c-) Operator a % Solids Date/ Time Test Read: 3-9-1-) '� 09 0 3 Incubator Temp: 3 q' c� a C Water Bath Temp: Media Lot # (5,i , o / '�- ) Sample # 3 - a 01 "':) - b S00 MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 3'aC� - C'j Time Op. �s ? -ally �w FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids _ ,(A-B)x100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : 3 " �ZD ,i 9 — DSOD Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = AS L4-7,°1la� 33 - as Ll5, IRQ3CIP 0 11 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution / 10 ml sample 10' dilution / 1.0 ml sample Single Strength Single Strength 10 dilution / 1.0 ml sample 10' dilution / 0.1 ml sample Date/Time Test Set -Up: -1 - Of f 3 Date/ Time Test Read: " ( - I a - I q ) ) 1 y3 Time Placed in Incubator: i (¢ 3 Incubator Temp: Z q . S Time Transferred to Water Bath: 7 ; H 3 Water Bath Temp: 9 Operator C- �aq, �,p Media Lot # D� Fc, ! $ { 50 % Solids Sample # �-1 Z c, MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date - " % 6 Time 6 0 (/ 31 Op. C U FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids = (A - B) x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample#: (t-(*7-(j-500 Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = I 3 ,�12z 7 13_tizZ7 7_1 22- . o �5-9 y 0/0 11 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10' dilution / 10 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength Single Strength 10' dilution / 1.0 ml sample 10-2 dilution / 0.1 ml sample Date/Time Test Set -Up:.- 15Os- Time Placed in Incubator: I a Time Transferred to Water Bath: I q 00 Operator % Solids Date/ Time Test Read: Incubator Temp: 3 5 , 5 Water Bath Temp: `fq . 5 aC- Media Lot # : ' `i �( o % 219 0-7 4 S Sample#-IS-19-os00 MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results 0 Biosolids Collection: Date IS- IS -1 9 Time ) VO0 0p. C FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids _ (A-B)XI00 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : - 6 -19 _0 5D O Weight of dried residue + dish: Duplicate weight of dried residue + dish : Weight of empty dish Weight of wet sample + dish : Total Solids = ,0 9) r] U a� 3 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10-1 dilution / 10 nil sample 10-1 dilution / 1.0 ml sample Single Strength Single Strength 10' dilution / 1.0 ml sample 10-' dilution / 0.1 ml sample Date/Time Test Set -Up: (.2i9-t'Ll 14D S Date/ Time Test Read: Co'19'ITl l Time Placed in Incubator: Ko (75 Incubator Temp:�,� C" aC Time Transferred to Water Bath: 1900 Water Bath Temp: q{ , S Operator A- � k yS Media Lot # : '%O i % Solids S_�P •off �)O Sample # : (Q -«-1,� — MPN Fecal Coliform = per Gram Total Solids 10 x MPN Index / 100 ml = Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results BiosolidsCollection: Date Le-�'�41=t Time Dl��5D Op. Cb FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample#: (-e-kQA9—O5D0 Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = 5(, ' aJ/0 a . 0 --7 11 11 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS . A-1 Medium Double Strength 10-' dilution / 10 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10-' dilution / 1.0 ml sample Single Strength 10-' dilution / 0.1 ml sample Date/Time Test Set -Up: -21c� )�5 Time Placed in Incubator: 1 �),Q5 Date/ Time Test Read: -%-Jk-14/i 13 u Incubator Temp: 3H 1,3 C Time Transferred to Water Bath: A3 Water Bath Temp: 14q . -5 y L Operator A S Q,"— Media Lot # : 7)1 f'!C C, ( o-7 cJ S- a/ % Solids LQA ,�] Sample # :11 % J^7-1 0 C� MPN Fecal Coliform = 10 x NUN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date-1-1'7-1'1 Time i I D'�; Op. CL FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)x100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : �7 -0 4 9 (D DO Weight of dried residue + dish: OV . 39 L(i Duplicate weight of dried residue + dish: �9D Weight of empty dish ';S 3 Weight of wet sample + dish 4001 ` ( % Total Solids El,�V] 11 IJ E FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10-' dilution / 10 ml sample Single Strength 10"1 dilution / 1.0 ml sample Single Strength 10-' dilution / 1.0 ml sample Single Strength 10"Z dilution / 0.1 ml sample Date/Time Test Set -Up: -,),1-19 3 Date/ Time Test Read:S-d a 19 O �0 ( 3 Time Placed in Incubator: ) j' 3 Incubator Temp: �51 aJ �(�j D C Time Transferred to Water Bath: �� ('� Water Bath Temp: `T`1'c (�� Operator : Q - SJL� Media Lot # : <:�y 19 D "7 �i 'S % Solids JS9 1 ` 1 /0 Sample # 19 r Cl — DS Z:-' 0 MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date-)0 Time Op. ee) FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids (A-B)xl00 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : D `,� � - � 9 -o S-b 0 Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = 5c, 1 / �459 11 11 Lj FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength 10'' dilution / 10 ml sample Single Strength 10'' dilution / 1.0 ml sample r- Single Strength 10'2 dilution / 1.0 ml sample Single Strength 10'Z dilution / 0.1 ml sample Date/Time Test Set -Up: '3-1 �5-N)09 C) c� Time Placed in Incubator: j 9 (D Date/ Time Test Read: j -1 9 -(R Os ) C1 Incubator Temp: 5 J C_ Time Transferred to Water Bath: Water Bath Temp:�C- Operator : �l� Media Lot # : PiCC 0 S1I 10 74 5 % Solids Sample # MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 9 - I � -19 Time O � 5 4S FORMULA: Where: CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE % Total Solids = (A - B) x 100 C-B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : I " t -1 9 - 0 5 O0 Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish % Total Solids = LAH,L2,'- III FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10'1 dilution / 10 ml sample 10-' dilution / 1.0 ml sample Single Strength Single Strength 10'2 dilution / 1.0 ml sample 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: Ib-jk-I`j� `AP,0 Date/ Time Test Read: I -( -7-j I1 Time Placed in Incubator: � as Incubator Temp: z Time Transferred to Water Bath: 15 1 --I Water Bath Temp: Operator _ Media Lot # 9 %Solids Sample# MPN Fecal Coliform = 10 x MPN Index / 100 ml = Tj per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 10 -j U-) 9 Time Q 5 S Op. k 5 FORMULA: Where: CALCULATION FOR TOTAL, SOLIDS IN BIOSOLIDS SAMPLE % Total Solids = (A - B) Y l00 C -B A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample#: b7(e-i9-24OCR Weight of dried residue + dish: Duplicate weight of dried residue + dish: Weight of empty dish Weight of wet sample + dish : % Total Solids = '� r L� j @@D FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Double Strength Single Strength 10' dilution / 10 ml sample 10' dilution / 1.0 ml sample Single Strength 10' dilution / 1.0 ml sample Single Strength 10' dilution / 0.1 ml sample r- Date/Time Test Set -Up: -' Io'�Date/ Time Test Read: Time Placed in Incubator: } �L-o Incubator Temp: 35 , j v [- Time Transferred to Water Bath: j q5 D, Water Bath Temp: Operator Media Lot # % Solids 7 0/0 Sample # MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids lJ NOTE: + indicates positive results ; - indicates negative results Biosolids Collection: Date 1- Time 1 U I D Op.- CALCULATION FOR TOTAL SOLIDS IN BIOSOLIDS SAMPLE FORMULA: % Total Solids = (A - B) x l OO C-B Where: A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample #: i l -- ° 19 0 SC,, Weight of dried residue + dish: Duplicate weight of dried residue + dish Weight of empty dish Weight of wet sample + dish : % Total Solids L[3 e (D�q 353 \� , co s- --, °/v [7 FECAL COLIFORM FOR MUNICIPAL BIOSOLIDS A-1 Medium Single Strength 10'2 dilution / 1.0 ml sample Single Strength 10'2 dilution / 0.1 ml sample Date/Time Test Set -Up: I -I $-(9 1/1 1 10 Date/ Time Test Read: Time Placed in Incubator: (I 0 Incubator Temp:35 Time Transferred to Water Bath: 1 S Water Bath Temp: � Operator : _ Media Lot # Q g'cj(�od— Solids c 1pal(� Sample # r7- C7`1 DC� MPN Fecal Coliform = 10 x MPN Index / 100 ml = per Gram Total Solids Largest Volume x % Dry Solids NOTE: + indicates positive results ; - indicates negative results 6 Biosolids Collection: Date I a_� R-1 9 Time a() Op /4S CALCULATION FOR TOTAL SOLIDS N BIOSOLIDS SAMPLE FoRivIULA: % Total Solids = (A - B) x 100 C -B Where: A = Weight of dried residue + dish (mg) B = Weight of empty dish (mg) C = Weight of wet sample + dish (mg) Sample # : Weight of dried residue -P dish: Duplicate weight of dried residue + dish: Weight of empty dish �' U 4 Weight of wet sample + dish /a Total Sol ids