WQ0002883_2019 Residual Annual Report_20200414

Initial Review
INITIAL REVIEW
Reviewer Williams, Kendall
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application r Annual Report
what is the submittal r Residual Annual Report
type?* r Additional Information
r Other
Annual Report 2019
Year*
Date Paper Copy 4/14/2020
Received:*
Project Number* WQ0002883
Email Notifications
Does this need review by the hydrogeologist?*
r Yes r No
Regional Office
CO Reviewer
Admin Reviewer [e-mail]

Submitted Form
Project Contact Information
Rease provide information on the person to be contacted by MB Staff regarding electronic subnittal, confirmation of receipt, and other issues.
..........................................................................................................................................................................................................................................................................................................................................................................
Name * Drew Matthews
Email Address*
[e-mail]
Project Information
Submittal Type* r New Permit Application
r Renewal
r Annual Report
r Other
Permit Type * r Wastewater Irrigation
r Other Wastewater
r Closed -Loop Recycle
r Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?
r Yes r Nor N/A
Permit Number* WQ0002883
ApplicantTermittee * City of Elizabeth City
Facility Name * City of Elizabeth City RLAP
Phone Number*
2528839301
r Modification (Major or Minor)
r Additional Information
r Residual Annual Report
r High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Paper copy is being mailed
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Rans, Specifications, Calculations, Etc.)
2019 Elizabeth City Class B Annual Report.pdf 13.84MB
upload only 1 R7F document. NL@iple documents must be combined into one R7F file.

For new and modification permit applications, a paper copy may be required. If you have any questions
about what is required, please contactthe reviewer or Tessa Monday. If a paper 2-pol cation is required,
be advised, applications accepted for pre -review until both the paper and elect-c-ii.- --ol:ies have been
received. The paper copy shall include the following:
o Application Form
o All relevant attachments {talcs, soils report, specs, etc.]
o One full-size engineering plan set
o One 11x17" engineering plan set
o One extra set of specifications
o Fee (if required)
Mailine address:
Division of Water Resources ! Division of Water Resources
Non -Discharge Branch I Non -Discharge Branch
1617 Mail Service Center I Att: Nathaniel Thornburg, P Floor, Office #942W
- =
Raleigh, NC 27699-1617 S12 N.5alisburySt.
For questions or problems contact Tessa Monday attessa.monday@)ncdenr.Qov or 919.707.3560.
* rJ By checking this box I acknowledge that I understand the application will not be accepted
for pre -review until the paper copy (if required) and fee (if required) have been received by
the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with
all parts of the application in correct order (as specified by the application).
Signature
Submission Date 4/7/2020

CITY OF ELIZABETH
CITY
2019 ANNUAL LAND APPLICATION OF
RESIDUAL BIOSOLIDS REPORT
CLASS B PROGRAM
WQ0002883
Submitted by:
Soil Plus
PO Box 1396
Oxford, NC 27565
April 7, 2020
SOIL PLUS

SOIL PLUS
April 7, 2020
NCDEQ-DWR
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2019 LAND APPLICATION ANNUAL REPORT
Elizabeth City "Class B" Program
NC Permit No.: WQ002883
Soil Plus Project No. 200704.A10
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for the City of Elizabeth City on behalf of Atlantic
OBX. Soil Plus compiled this report using data gathered during the compliance year. This
data includes (1) certification form, (2) residual sampling, (3) field loading calculations, (4)
pathogen and vector attraction reduction documentation, (5) standard soil fertility nutrient
analysis.
The City of Elizabeth City conducted application events on permitted fields in Pasquotank
County during 2019. A total of 444.39 dry tons or 2,405,000 gallons of permitted residual
biosolids from the City's WWTP were land applied to permitted fields in WQ002883. An
additional 383.83 dry tons or 1,748,500 gallons were land applied under Atlantic OBX's
Class B permit WQ0000974. A total of 828.22 dry tons or 4,153,500 gallons were
generated by the City of Elizabeth City's WWTP in 2019.
A total of 1,308.20 dry tons or 1,488,500 gallons of permitted residuals from the City's
WTP were land applied as a Class B product to permitted fields in WQ002883. An
additional 2,459.86 dry tons or 2,262,000 gallons of WTP residuals were distributed as a
Class A product under permit numbers WQ0033587 & WQ0040622. No WTP residuals
were taken to the City of Elizabeth City's Surface Disposal Unit (WQ0014808). A total of
3,768.06 dry tons or 3,750,500 gallons were generated by the City of Elizabeth City's WTP
in 2019.
If there is any further information required or questions regarding this annual report please
do not hesitate to contact me or the Elizabeth City (252-337-6626) for further assistance.
Respectfully,
PO Box 1396
Oxford, NC 27565 Drew Matthews, Soil Plus
[phone]
dmatthewsgsoapius.net Amanda Boone, City of Elizabeth City
www.soilplus.net J. Bryan Smith, Atlantic OBX

City of Elizabeth
City 2019 Annual
Land Application of
Residual Bio s oild s
Report
WQ0002883
Elizabeth City, NC
ANNUAL
CERTIFICATION FORM
Source Summary
Field Loading Summary
RESIDUAL SAMPLING
SUMMARY FORMS
Elizabeth City WTP
Elizabeth City WWTP
FIELD SUMMARY
FORMS
PATHOGEN & VECTOR
REDUCTION FORMS
Elizabeth City WWTP
SOIL SAMPLES

City of Elizabeth City
2019 Class B Annual Report
WQ Permit# WQ0002883
Annual Certification Form
Source Summary
Field Loading Summary

PermitNumber
WQ0002883
i'ear: 2019
ANNUAL LAND APPLICATION CERTIFICATION FORM
FacilityName Land Application Operator County Phone Number
City of Elizabeth City Atlantic OBX Pasquotank [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and yes No
Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how 0 Fal
the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: 64
Total number of fields utilized for land application during the year: 16
Total amount of dry tons applied during the year for all application sites: 1752.58
Total number of acres utilizes for land application during the year: 227.46
Part B - Annual Compiance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water Quality ❑d FMI
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
•ertified laboratory results are attached
.,.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated
facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated
facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water Quality
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
Amanda Boone, Public Utilities Director "A??-Z0
Signature of Permittee Date
t: Perm' ee Name and Title (type or print): 7 - 2Z d Z U r>
0uO P,j� 4/7/2020
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)

Source Summary Report
WWTP L VolumeApplied �Total�
Elizabeth City WTP 1,488,500 1308.20
Elizabeth City WWTP 2,405,000 444.39
Total 3,893,500 1752.58

Site# LL
Site# WB
YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED
CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
33
22.37
383,500
221.75 48.62
50.21
Wheat, Grain
111
43.8%
34
19.88
429,000
262.73 54.86
56.75
Wheat, Grain
111
49.4%
35
20.26
370,500
177.97 67.24
69.21
Wheat, Grain
111
60.6%
36
20.31
292,500
57.33 88.13
90.32
Wheat, Grain
111
79.4%
37
18.33
247,000
48.41 82.46
84.51
Wheat, Grain
111
74.3%
100
11.63
208,000
75.46
93.57
72.67
Soybeans, Full
174
53.8%
Season
101
11.64
201,500
82.13
80.98
63.68
Soybeans, Full
174
46.5%
Season
102
11.7
221,000
85.87
101.03
78.20
Soybeans, Full
174
58.1%
Season
103
11.59
214,500
80.01
101.95
78.69
Soybeans, Full
169
60.3%
Season
104
11.94
241,500
94.90
107.26
83.10
Soybeans, Full
169
63.5%
Season

YEAR TO DATE FIELD LOADING SUMMARY
CROPS USED AND VOLUME APPLIED
PERMITTED CROPS AND LOADING RATES
Acres
Volume
Crop 1 PAN Crop 2 PAN
Total P
Crop 1
PAN 1 Crop 2 PAN 2
Field
Used
Applied
Total DT
lbs/Ac. lbs/Ac.
lbs/Ac.
Crop 1 Name
PAN
Used Crop 2 Name PAN Used
105
11.82
234,000
88.15
108.30
83.65
Soybeans, Full
169
64.1%
Season
106
9.92
135,500
56.02
69.55
54.11
Soybeans, Full
169
41.2%
Season
96
11.4
143,000
128.80
0.81
5.74
Soybeans, Double
147
0.6%
Crop
97
11.59
169,000
152.22
0.94
6.67
Soybeans, Double
147
0.6%
Crop
98
11.55
201,500
70.42
94.14
72.88
Soybeans, Full
174
54.1%
Season
99
11.53
201,500
70.42
94.30
73.01
Soybeans, Full
174
54.2%
Season
Total 3,893,500

City of Elizabeth City
2019 Class B Annual Report
WQ Permit# WQ0002883
Residual Sampling Summary Forms
Elizabeth City W fP
Elizabeth City WTP
Field Loading Calculations
2019 Analytical
2019 TCLP

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0002883 Facility Name City of Elizabeth City Source Permit No. NCO025011 Source Name Elizabeth City WWTP
Laboratory 1
Laboratory 2
Sample of CompositeDate
Parameter (mg/Kg) Class A Clas B
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analytical
3/15/2019
4/26/2019
7/12/2019
10/4/2019
Aluminum
N/A
N/A
14,600
15,900
12,700
14,300
Ammonia Nitrogen
N/A
N/A
989
17,000
2,720
1,980
Arsenic
41
75
7.1
13
15.7
12.2
Cadmium
39
85
1.8
1.4
1.7
1.2
Calcium
N/A
N/A
94,300
88,000
133,000
160,000
Copper
1,500
4,300
233
252
226
175
Lead
300
840
18.3
18.1
17.3
15.7
Magnesium
N/A
N/A
5,780
6,050
6,020
6,130
Mercury
17
57
0.29
0.29
1.2
0.27
Molybdenum
N/A
75
3.8
6.5
7.8
6.1
Nickel
420
420
11
10
94
12.4
10.9
Nitrate -Nitrite Nitrogen
N/A
N/A
83
80
62
Percent Solids
N/A
N/A
4.70
4.20
4.90
6.40
pH (no units)
N/A
N/A
Phosphorus
N/A
N/A
16,000
16,200
21,500
17,000
Potassium
N/A
N/A
4,890
6,510
7,840
6,100
PAN (Inj./Inc.)
N/A
N/A
16,103
30,054
14,404
11,228
PAN (Surface)
N/A
N/A
15,611
21,554
13,044
10,238
Selenium
100
100
5.8
13
15.7
12.2
Sodium
N/A
N/A
2,880
6,510
7,840
6,100
SAR
N/A
N/A
0.53
1.17
1.26
1.03
TKN
N/A
N/A
51,100
60,200
41,400
32,600
Zinc
2,800
7,500
757
830
717
578
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false informatioy,-yf�ludj4glthe possibility of fines and imprisonment for knowing violations."
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

1 ,
yr,WID. .
Facility Elizabeth City WWTP
FIELD LOADING ESTIMATES
Sampling Date 3/15/2019
Solids 4.7
Mineralization Rate 0.3
Gallons per DT 5,102.30
pH
Sodium Absorpotion 0.53 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 51,100 lbs./1,000 gal 20.03
Ammonia Nitrogen (mg/Kg) 989.00 lbs./1,000 gal 0.39
Nitrate -Nitrite (mg/Kg) 83.00 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 15,611 lbs./1,000 gal 6.12
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 16,105 lbs./1,000 gal 6.31
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 1.92
Phosphorus lbs./1,000 gal 6.27
Calcium lbs./1,000 gal 36.96
Magnesium lbs./1,000 gal 2.27
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
7.10
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.80
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
233.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
18.30
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.29
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
11.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
5.80
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
757.00
Zinc lbs./1,000 gal
0.30
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
51,100
15,611 31.22
35,489
51,100
16,105 32.21
34,995
35,489
5,323 10.65
30,166
34,995
5,249 10.50
29,745
30,166
2,262 4.52
27,903
29,745
2,231 4.46
27,515
27,903
1,046 2.09
26,857
27,515
1,032 2.06
26,483
26,857
504 1.01
26,353
26,483
497 0.99
25,986
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 24,747 49.49
Total 25,114 50.23

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Goodwin
Pace Project No.: 92421481
Sample: 1st Quarter Sludge
Lab ID: 92421481001 Collected:
03/15/19 10:43 Received: 03/15/19 11:00 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture,
sample size and any dilutions.
Parameters
Results Units Report Limit
DF Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
14600 mg/kg
57.7
1 03/26/1911:07
03/27/1917:52
7429-90-5 M1
Arsenic
7.1 mg/kg
5.8
1 03/26/1911:07
03/27/1917:52
7440-38-2
Cadmium
1.8 mg/kg
0.58
1 03/26/1911:07
03/27/1917:52
7440-43-9
Calcium
94300 mg/kg
288
5 03/26/1911:07
03/28/1916:25
7440-70-2 M1
Chromium
21.3 mg/kg
2.9
1 03/26/1911:07
03/27/1917:52
7440-47-3
Copper
233 mg/kg
2.9
1 03/26/1911:07
03/27/1917:52
7440-50-8
Lead
18.3 mg/kg
2.9
1 03/26/1911:07
03/27/1917:52
7439-92-1
Magnesium
5780 mg/kg
57.7
1 03/26/1911:07
03/27/1917:52
7439-95-4
Molybdenum
3.8 mg/kg
2.9
1 03/26/1911:07
03/27/1917:52
7439-98-7
Nickel
11.0 mg/kg
2.9
1 03/26/1911:07
03/27/1917:52
7440-02-0
Potassium
4890 mg/kg
2880
1 03/26/1911:07
03/27/1917:52
7440-09-7
Selenium
ND mg/kg
5.8
1 03/26/1911:07
03/27/1917:52
7782-49-2
Sodium
ND mg/kg
2880
1 03/26/1911:07
03/27/1917:52
7440-23-5
Zinc
757 mg/kg
5.8
1 03/26/1911:07
03/27/1917:52
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
0.29 mg/kg
0.10
1 03/21/1919:08
03/22/1915:50
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
4.7 %
0.10
1
03/21/19 13:51
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
95.3 %
0.10
1
03/21/19 13:42
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
989 mg/kg
149
1 03/18/19 15:02
03/19/19 15:14
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
51100 mg/kg
3700
5 03/20/19 14:00
03/21/19 01:12
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
83.0
1 03/17/19 09:30
03/17/19 09:56
Nitrogen, Nitrate
ND mg/kg
83.0
1 03/17/19 09:30
03/17/19 09:56
14797-55-8
Nitrogen, Nitrite
ND mg/kg
83.0
1 03/17/19 09:30
03/17/19 09:56
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
16000 mg/kg
925
50 03/20/19 21:14
03/20/19 23:40
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
5380 mg/kg
210
1 03/18/1912:01
03/18/1916:45
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
Sulfate
75.1 mg/kg
49.7
1 03/20/1913:13
03/23/1914:57
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/01/2019 11:30 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 25

ace Analytical "
City of Elizabeth City
450 Knobbs Creek
Yasheka Brothers
Rebecca Miller
Quarterly Sludge,._ 1 S
(2S2)337-3331
By
CHAIN -OF -CUSTODY Analytical Request Document
is a LEGAL DOCUMENT -Complete all relevent fields
Billing Information:
Email To:
Site Collection Info/Address:
Elizabeth City, NC 27909
WO# : 92421481 e1Nor[<arderNumber ar
111111 III 111111111111111111 III
92421481 JSE ONLY
Container Preservative Type • • 0 1
•` Preservatme Type: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate,
(6) methanol, (7) sodium bisulfate, (a) sodium thlosulfate, (9) hexane, (A) ascorbic acid, (B) ammonium sulfate,
(C) ammonium hydroxide, (D) TSP, (U) Unpreserved, (0) Other
Analyses jLab Profile/Line:
11-11
Ti
IQ
Lab Sample Receipt Checklist:
Custody Seals Present/Intact Y N NA
tility tD #:
Compliance Monitoring?
,
Custody Signatures Present Y N NA
[ ) Yes ] ]No
. Q
'�
�l /
Collector signature Present Y N NA
Bottles intact Y N NA
se Order # :
D W P WS ID #!;
#:
DW Location Code:
?
Q
Z
`
Correct Battles Y N NA
Sufficient Volume Y N NA
Samples Received on Ice Y N NA
ound Date Required:
Immediately Packed on Ice: I
I Yes [ ENO
>C
O
'J'
;
VOA - Headspace Acceptable Y N NA
USDA Regulated Soils Y N NA
S m 1 H ld'
ie Filtered (if applicable):
[ ) Dispose as appropriate ( )Return
[ ] Same Day [ ] Next Day
[ ] Yes I ] No
Q
\
a .p es 1n o xnq me Y N NA
Residual Chlorine Present Y N NA
[ ] Archlve:
( J Hord:
( ] z Day [ } 3 Day [ 4 Day [ ] 5 Day
-.
Cl Strips:
(Expedite Charges Apply)
Analysis:
�
cj�-
co
0
73
O
fq
Sample pH Acceptable Y N NA
pH Strips:
sulfide Present Y N NA
Matrix Codes (Insert In Matrix box below); Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tlssue (TS), Bioassay (13), Vapor (V), Other (OT)
`N
LU
F-
Lead Acetate strips:
Q
Z
Q
w
I AS axe oNLx:
Customer Sample [D
Matrix'
COMP/
Grab
Collected (or
Composite
Composite End
Res
# of
Start)
Cl
Ctns
Lab Sample Q / Comments:
Date
Time
Date
T me
EL
a
j
2
U
U)
WW PLANT SLUDGE SL
Customer Remarks / Special Conditions / Possib?e Hazards; Type of Ice Used: Wet Blue Dry None
la r l Cd ? CQ [ Cj(' j �( /I, I Packing Material Used:
Radchem sample(s) screened (<500 cpm): Y n N NA
I � l I' V I, rL.1 1/,'�, —
R m fished by/Company: (Signature} Date/r-r e: Rece ved by/Company: (signature)
m
V
C Relinquished by/Company: (Signatufe) Date/Time: Received by/Company: (Signature)
N
N
SHORT HOLDS PRESENT ([72 hours) : Y N N/A
Lab Tracking ff:
Samples received via:
FEDEX UPS Client Courler Pace Courier
Date/Time: r j MTJL LAB USE ONLY
--1 ' { c) i TaWe ff:
Dateli'Ime: Acctnum: Trip Blank Received: Y N NA
HCL McOH TSP Other
Non Conformance(s): Page:
YES / NO of:
Date/Time:
Sample Temperature Info:
p Blank Received: Y N NA
rm IDH:
ter 1 Temp Upon Receipt: oc
ler 1 Them Carr, Factor; cc
ter 1 Corrected Terp: _—oC
:rents:

1 ,
yr,WID. .
Facility Elizabeth City WWTP
FIELD LOADING ESTIMATES
Sampling Date 4/26/2019
Solids 4.2
Mineralization Rate 0.3
Gallons per DT 5,709.72
pH
Sodium Absorpotion 1.17 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 60,200 lbs./1,000 gal 21.09
Ammonia Nitrogen (mg/Kg) 17,000.00 lbs./1,000 gal 5.95
Nitrate -Nitrite (mg/Kg) 94.10 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 21,554 lbs./1,000 gal 7.55
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 30,054 lbs./1,000 gal 10.53
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.28
Phosphorus lbs./1,000 gal 5.67
Calcium lbs./1,000 gal 30.82
Magnesium lbs./1,000 gal 2.12
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
13.00
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
1.40
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
252.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
18.10
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.29
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
10.00
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
13.00
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
830.00
Zinc lbs./1,000 gal
0.29
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
60,200
21,554 43.11
38,646
60,200
30,054 60.11
30,146
38,646
5,797 11.59
32,849
30,146
4,522 9.04
25,624
32,849
2,464 4.93
30,385
25,624
1,922 3.84
23,702
30,385
1,139 2.28
29,246
23,702
889 1.78
22,813
29,246
548 1.10
28,698
22,813
428 0.86
22,386
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 31,502 63.00
Total 37,814 75.63

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Quarterly Sludge
Pace Project No.: 92426972
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW Plant sludge Lab ID: 92426972001 Collected: 04/26/19 08:36 Received: 04/26/19 12:15 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 05/10/2019 02:31 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
15900
mg/kg
130
1
05/08/1916:40
05/09/1915:48
7429-90-5
ND
mg/kg
13.0
1
05/08/1916:40
05/09/1915:48
7440-38-2
1.4
mg/kg
1.3
1
05/08/1916:40
05/09/1915:48
7440-43-9
88000
mg/kg
130
1
05/08/1916:40
05/09/1915:48
7440-70-2
23.6
mg/kg
6.5
1
05/08/1916:40
05/09/1915:48
7440-47-3
252
mg/kg
6.5
1
05/08/1916:40
05/09/1915:48
7440-50-8
18.1
mg/kg
6.5
1
05/08/1916:40
05/09/1915:48
7439-92-1
6050
mg/kg
130
1
05/08/1916:40
05/09/1915:48
7439-95-4
ND
mg/kg
6.5
1
05/08/1916:40
05/09/1915:48
7439-98-7
10
mg/kg
6.5
1
05/08/1916:40
05/09/1915:48
7440-02-0
ND
mg/kg
6510
1
05/08/1916:40
05/09/1915:48
7440-09-7
ND
mg/kg
13.0
1
05/08/1916:40
05/09/1915:48
7782-49-2
ND
mg/kg
6510
1
05/08/1916:40
05/09/1915:48
7440-23-5
830
mg/kg
13.0
1
05/08/1916:40
05/09/1915:48
7440-66-6
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
0.29
mg/kg
0.12
1
04/30/1912:09
04/30/1917:14
7439-97-6
Analytical Method: SM 254OG-2011
4.2
%
0.10
1
04/30/1917:43
Analytical Method: ASTM D2974-87
95.8
%
0.10
1
04/30/1917:36
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation
Method:
EPA 350.1 Rev 2.0
1993 Mod.
17000
mg/kg
204
1
05/01/19 17:21
05/01/19 22:53
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
60200
mg/kg
4390
5
05/01/19 04:39
05/01/19 14:35
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
94.1
1
04/30/19 16:30
05/01/19 08:30
H1,H2
ND
mg/kg
94.1
1
04/30/19 16:30
05/01/19 08:30
14797-55-8 H1,H2
ND
mg/kg
94.1
1
04/30/19 16:30
05/01/19 08:30
14797-65-0 H1,H2
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
16200
mg/kg
349
20
04/29/19 20:20
04/30/19 00:53
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
7470
mg/kg
232
1
05/07/19 18:05
05/07/19 21:50
16887-00-6
Analytical Method: EPA 9056 Preparation
Method: EPA 9056
1950
mg/kg
1180
1
05/01/19 08:25
05/02/19 08:25
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 17

WN : 92426972 xderNumber or
1y 1111111 y111 y 11111111
92426972 4 LY
CHAIN -OF -CUSTODY Analytical Request Document
aceAnalytical U
Chain -of -Custody is a LEGAL DOCUMENT- Complete ail reievent fields
City of Elizabeth City
Biding Information:
450 Knobbs Creek
Container Preservative Type " Lab Project Manager.
U U U UC-
UF7Yasheka
Brothers
Email To:
" Preservative Types: it) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc acetate,
M methanol, (71 sodium blsulfate, (81 sodium thlosWate, (9) hexane, (A) wcorblc acid, (a) ammonium sulfate,
JQ ammonium hydroxide, (D) TSP, (tl) Unpreserved, (0) Other
Rebecca Miller
Site Collection info/Address:
Analyses
Lab Profile/Line:
Quarterly Sludge
Elizabeth City, NC 27909
ty
X
0
¢
N
--t
Q
F-
2
r'
X
Q
Q
0
�G
Q
trj
O
Z
0
Z
1--
X
Ur
¢
C0
0
J
r[
(-
D
F-
X
0
Q
[�
Q
0
U
x
Q
W
Lil
¢
L[
J
CO
`r
O
Q
}
Cl
X
Q
a
(�'
O
IZ
CO
2
Q
o.l
Q
F-
Lab Sample Receipt Checklist:
Custody Seals Present/Xntact Y N NA
Custody Signatures Present Y N NA
Collecter Signature Present Y N NA
sottles Intact Y N NA
Correct Bottles Y N NA
Sufficient Volume Y N NA
samples Received an Ice Y N NA
VOA .- Headspace Acceptable Y N NA
USDA Regulated Soils Y N NA
Samples in Holding Time Y N NA
Residual Chlorine Present Y N NA
Cl Strips:
Sample pH acceptable Y N NA
pN Strips:
Sulfide Present Y N NA
Lead Acetate Strips:
LAB USE ONLY:
Lab Sample # / Commonta
[phone]
Site/Facility 10 #:
Compliance Monitoring?
[ ] Yes [ ] No
Co cte By, i ):
P se Order # :
OW PWS ID #:
DW Location Code:
lie ted y (signatur };
i
Turnaround Date Required:
I ediateiy packed on Ice:
Yes { ]No
5 p Isposal:
l ] Dispose as appropriate [ ] Return
[ ) Archive:
I ! Hold:
Rush:
[ ] Same Day [ ] Next Day
[ ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
(Expedite Charges Apply)
Re Filtered (if applicable):
[ ] Yes [ ] No
Analysis:
• Matrix Codes Insert in Matrix box below): Drinking Water DW , Ground Water GW , Wastewater WW ,
( ) g { ) { ) { )
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Sloassay (e), Vapor (V), Other (OT)
Customer Sample ID
Matrix
Comp/
Grab
Collected (or
Composite Start)
Composite End
Res
Cl
# of
Ctns
Date
Time
Date
Time
WW PLANT SLUDGE
SL
8
X
X
X
X
X
X
X
AI,Ar,Cd,Ca,Cr,Cu,Pb,Mg,Mo,Ni,K,Se,Na,2n & Hg
Type of Ice Used: Wet Blue Dry None
SHORT HOLDS PRESENT (<72 hours). Y N N/A
LAB Sample Temperature Info:
Temp Blank Received: Y N HA
Therm ID#:
Cooler 1 Temp Upon Receipt: oC
Cooler 1 Thenn Corr. Factor:_oc
Cooler 1 Corrected Temp: oc
Co- ments-
Packing Material Used:
Lab Tracking #:
Radchem sample(s) screene oo cpm): Y NA
Samples received via:
/Laurier Pace Courler
FEDE)( UPS [BentI'll,
li u€sh by/Compan `- (Si r
0 t '/Ti e:
Rece
ve Compan { r
D t /Ti r f
��/ r lJ
MT1L LAB USE ONLY
Table#:
FirVshed by/Company: (Signature)
oat/Time!
Rece€ved y/Company: (Signature)
Date/Time:
Acctnum:
Template:
Preto in: {,��j
PM: '1 +
PB:l j
Trip Blank Recelved: Y N NA
HCL McOH TSP Other
Relinquished by/Company: (Signature)
Date/Time:
Received by/Company: (Signature)
Date/Time;
Non Conformance(s)•
YES / NO
Page:_
of:

1 ,
yr,WID. .
Facility Elizabeth City WWTP
FIELD LOADING ESTIMATES
Sampling Date 7/12/2019
Solids 4.9
Mineralization Rate 0.3
Gallons per DT 4,894.04
pH
Sodium Absorpotion 1.26 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 41,400 lbs./1,000 gal 16.92
Ammonia Nitrogen (mg/Kg) 2,720.00 lbs./1,000 gal 1.11
Nitrate -Nitrite (mg/Kg) 79.60 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 13,044 lbs./1,000 gal 5.33
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 14,404 lbs./1,000 gal 5.89
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.20
Phosphorus lbs./1,000 gal 8.79
Calcium lbs./1,000 gal 54.35
Magnesium lbs./1,000 gal 2.46
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
15.70
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.70
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
226.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
17.30
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
1.20
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
12.40
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
15.70
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
717.00
Zinc lbs./1,000 gal
0.29
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
41,400
13,044 26.09
28,356
41,400
14,404 28.81
26,996
28,356
4,253 8.51
24,103
26,996
4,049 8.10
22,947
24,103
1,808 3.62
22,295
22,947
1,721 3.44
21,226
22,295
836 1.67
21,459
21,226
796 1.59
20,430
21,459
402 0.80
21,057
20,430
383 0.77
20,047
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 20,343 40.69
Total 21,353 42.71

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: QUARTERLY SLUDGE
Pace Project No.: 92436604
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WW PLANT SLUDGE Lab ID: 92436604001 Collected: 07/12/19 08:20 Received: 07/12/19 10:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 07/28/2019 06:47 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
12700
mg/kg
157
1
07/17/19 10:37
07/17/19 21:13
7429-90-5
ND
mg/kg
15.7
1
07/17/19 10:37
07/17/19 21:13
7440-38-2
1.7
mg/kg
1.6
1
07/17/19 10:37
07/17/19 21:13
7440-43-9
133000
mg/kg
157
1
07/17/19 10:37
07/17/19 21:13
7440-70-2
24.8
mg/kg
7.8
1
07/17/19 10:37
07/17/19 21:13
7440-47-3
226
mg/kg
7.8
1
07/17/19 10:37
07/17/19 21:13
7440-50-8
17.3
mg/kg
7.8
1
07/17/19 10:37
07/17/19 21:13
7439-92-1
6020
mg/kg
157
1
07/17/19 10:37
07/17/19 21:13
7439-95-4
ND
mg/kg
7.8
1
07/17/19 10:37
07/17/19 21:13
7439-98-7
12.4
mg/kg
7.8
1
07/17/19 10:37
07/17/19 21:13
7440-02-0
ND
mg/kg
7840
1
07/17/19 10:37
07/17/19 21:13
7440-09-7
ND
mg/kg
15.7
1
07/17/19 10:37
07/17/19 21:13
7782-49-2
ND
mg/kg
7840
1
07/17/19 10:37
07/17/19 21:13
7440-23-5
717
mg/kg
15.7
1
07/17/19 10:37
07/17/19 21:13
7440-66-6
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
1.2
mg/kg
0.075
1
07/16/1910:25
07/16/1912:54
7439-97-6
Analytical Method: SM 254OG-2011
4.9
%
0.10
1
07/16/1914:31
Analytical Method: ASTM D2974-87
95.1
%
0.10
1
07/16/1914:24
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation
Method:
EPA 350.1 Rev 2.0
1993 Mod.
2720
mg/kg
196
1
07/18/19 07:18
07/18/19 12:22
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
41400
mg/kg
4240
5
07/23/19 05:17
07/25/19 03:49
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
79.6
1
07/13/1913:52
07/13/1915:02
ND
mg/kg
79.6
1
07/13/1913:52
07/13/1915:02
14797-55-8
ND
mg/kg
79.6
1
07/13/1913:52
07/13/1915:02
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
21500
mg/kg
408
20
07/15/19 20:06
07/15/19 22:56
7723-14-0 M6
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
8520
mg/kg
1000
5
07/16/1910:56
07/16/1913:34
16887-00-6
Analytical Method: EPA 9056 Preparation
Method: EPA 9056
ND
mg/kg
1020
1
07/26/1912:00
07/26/1912:18
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 17

WO# - 92436604
Q
(D
iigiiupniiunuu
CHAIN -OF -CUSTODY Analytical Request Document
ace Analytical
Chain -of -Custody is aLEGAL DOCUMENT- Complete all relevent fields
LAB OSEONLY-Affix Workorder/Login Label Hereer List Pace Workorder Numberor
h771L Login Number Here
ALL SHADED AREAS are for LAB USE ONLY
City of Elizabeth City
ELAIng lnformatlam
959 Knobbs Creek
Container preservative Type"
LabPro[t. JJlanager, j
�f .--� ]
Yasheka Brother
Email To:
U U U U U U U
' • PreseVauva Types: (1) nitric add, (21 suifurieacid, (3) hydmahioric acid, (41sodium Ndwalde, 151 zImaceune,
(61 methanol, (7) sodium blsu!fate, M sod}um th!osu!fate, (9} heave, (A) ascorbic arid, (n) ammon.um sulfate,
(Cjammor Eum hydroxide, (D)TSP, (U) tlnpreseled, (0) other
Rebecca Miller
Site Collection info/Address:
Quarterly Sludge
Elizabeth City, NC 27909
Analyses
Lab Profile/Une:
0
¢
_
to
-d
Q
H
w
x
Q
¢
0
¢
r')
O
Z
Z
F
X
�_
C7
¢
(n
,�
O
un
_j
F
O
X
Q
W
F,
0
U
X
¢
W
Q
J
X
m
2
Ur
W
y
x
0.
O
0.
0p
2
a
J
9
O
Lab Sau.lc H.c.ipt ChecY-list:
Cu-. tcdy Seals Preaentl Intact Y H NA
Custody 6igcatures Present Y N NA
Cci lactnr Signature Praeent Y N NA
LCtCles IntucC Y N NA
Corre_t 5ortlas Y N NA
Sufficient Vclurne Y N NA
Samples Eocclvcd on Ice Y N Ha
VQA - Na cadspae Acceptable N Y NA
USDA Regulated Soils Y N NA
Samples in Holding Time Y N NA
Residual Chlorin. Prasnat Y N Nh
Cl Stripe:
Sample pH Acceptable Y tt NA
pR Strips:
Sulfide Frecent Y N NA
lead Acetate Strips:
LAB USE ONLY:
Lab Semple A ! corrtcnts,:
(252J337-3331
Site)Fac!iity 10 n:
Compliance Monitoring?
[ [ Yes [ ]No
Ca a BY (Pr
n!}:
P r rdcrn:
=
OW PWSIO R:
DW Location Code:
C Ilea d By (s nature):
urna(dund Date Required:
m edlately Packed on Ice:
Yes I ]No
Sa a .sal:
( ispoxasapproprtato I (Return
[ J Arch[rBr
I INWd'
Rush:
{ ]Same Day [ ]Next Day
[ 12 Day 1 13 Day 1 14 Day 1 15 Day
(Eapedite d+arEes Apply)
is Filtered (If applicable):
I ]Yes ) ]No
Analysis:
•Matrix Codes (Insert In Matrix box below:Dr(nkiag Water [OW), Ground Water(GWJ, Wastewater(WW),
Product fl, Soil lid SI, Oil 01., Wipe WP,Air (AR), TS, Bloassa B,Va or V, Other OT
I I Soil/Solid ( J [ 1 P I ) I) I} v{ 1 P I} (]
Customer Sample iD
Matrix'
comp/
Grab
Collected (or
Composite Start]
Composite End
Res
Cl
Hof
Ctns
Date
Time
Date
Tlme
WW PLANT SLUDGE
SL
I h 2j 19
8
X
X
X
X
X
X
X
AI,Ar,Cd,Ca,Cr,Cu,Pb,Mg,Mo,NI,K,Se,Na,Zn&Hg
Type of ice Used: We Blue Dry None
SHORT 1101-05 PRESENT(<72 hours): Y N N/A
IAB Sample Temperature Info:
e-o Blark Received: Y H riA
;terra IOp:
ocler 1 Tomp upon Receipt: OC
Ccoler 1 Th.—Corr. Factor:—oc
°oler 1 Corrected Temp: �oC
Ct rts;
Packing Material Used:
Lab Trading N:
Radchem samp!e(s) screened (<500 cpm); Y N NA
Samples received via:
FEUEX UPS Client Courier Pace Courier
hedby/Company: a re Date/Ti elyred by/C mpany (Sig 1
1J
quls y/Company: (gna[urej I t nsti Received by/Company; (Signature)
Oat /i'f e: �yMTJL
6V
LAB USE ONLY
Tablet1:1nq
Da me:
Acctnum;
Template:
PreJoglny �} n 4
)14
Trip Blank Received: Y N NA
HCL McCH TSP Other
y�}

1 ,
yr,WID. .
Facility Elizabeth City WWTP
FIELD LOADING ESTIMATES
Sampling Date 10/4/2019
Solids 6.4
Mineralization Rate 0.3
Gallons per DT 3,747.00
pH
Sodium Absorpotion 1.03 <5.0 Safe 5.0 - 10.0 Careful Management >15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 32,600 lbs./1,000 gal 17.40
Ammonia Nitrogen (mg/Kg) 1,980.00 lbs./1,000 gal 1.06
Nitrate -Nitrite (mg/Kg) 62.00 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 10,238 lbs./1,000 gal 5.46
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 11,228 lbs./1,000 gal 5.99
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.26
Phosphorus lbs./1,000 gal 9.07
Calcium lbs./1,000 gal 85.40
Magnesium lbs./1,000 gal 3.27
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
12.20
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
1.20
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
175.00
Copper lbs./1,000 gal
0.09
Lead (mg/Kg)
15.70
Lead lbs./1,000 gal
0.01
Mercury (mg/Kg)
0.27
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
10.90
Nickel lbs./1,000 gal
0.01
Selenium (mg/Kg)
12.20
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
578.00
Zinc lbs./1,000 gal
0.31
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
32,600
10,238 20.48
22,362
32,600
11,228 22.46
21,372
22,362
3,354 6.71
19,008
21,372
3,206 6.41
18,166
19,008
1,426 2.85
17,582
18,166
1,362 2.72
16,804
17,582
659 1.32
16,923
16,804
630 1.26
16,174
16,923
317 0.63
16,605
16,174
303 0.61
15,870
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 15,995 31.99
Total 16,730 33.46

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Sludge
Pace Project No.: 92448332
Sample: Sludge
Lab ID: 92448332001 Collected:
10/04/19 09:32 Received: 10/04/19 14:31 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture,
sample size and any dilutions.
Parameters
Results Units Report
Limit
DF Prepared
Analyzed
CAS No.
Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
14300 mg/kg
122
1 10/15/19 12:07
10/17/19 02:50
7429-90-5
M1,R1
Arsenic
ND mg/kg
12.2
1 10/15/19 12:07
10/17/19 02:50
7440-38-2
Cadmium
ND mg/kg
1.2
1 10/15/19 12:07
10/17/19 02:50
7440-43-9
Calcium
160000 mg/kg
610
5 10/15/19 12:07
10/17/1917:14
7440-70-2
M1,R1
Chromium
21.3 mg/kg
6.1
1 10/15/19 12:07
10/17/19 02:50
7440-47-3
Copper
175 mg/kg
6.1
1 10/15/19 12:07
10/17/19 02:50
7440-50-8
Lead
15.7 mg/kg
6.1
1 10/15/19 12:07
10/17/19 02:50
7439-92-1
Magnesium
6130 mg/kg
122
1 10/15/19 12:07
10/17/19 02:50
7439-95-4
M1
Molybdenum
ND mg/kg
6.1
1 10/15/19 12:07
10/17/19 02:50
7439-98-7
Nickel
10.9 mg/kg
6.1
1 10/15/19 12:07
10/17/19 02:50
7440-02-0
Potassium
ND mg/kg
6100
1 10/15/19 12:07
10/17/19 02:50
7440-09-7
Selenium
ND mg/kg
12.2
1 10/15/19 12:07
10/17/19 02:50
7782-49-2
Sodium
ND mg/kg
6100
1 10/15/19 12:07
10/17/19 02:50
7440-23-5
Zinc
578 mg/kg
12.2
1 10/15/19 12:07
10/17/19 02:50
7440-66-6
M1
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
0.27 mg/kg
0.033
1 10/06/1915:53
10/09/1916:26
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
6.4 %
0.10
1
10/07/19 17:05
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
93.6 %
0.10
1
10/07/19 16:59
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
1980 mg/kg
156
1 10/18/19 08:46
10/18/19 11:43
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
32600 mg/kg
5790
10 10/11/19 23:50
10/13/19 13:43
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
62.0
1 10/05/19 12:08
10/05/19 13:40
Nitrogen, Nitrate
ND mg/kg
62.0
1 10/05/19 12:08
10/05/19 13:40
14797-55-8
Nitrogen, Nitrite
ND mg/kg
62.0
1 10/05/19 12:08
10/05/19 13:40
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
17000 mg/kg
284
20 10/08/19 19:06
10/08/19 23:53
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
2300 mg/kg
155
1 10/17/19 08:57
10/17/19 12:28
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056 Preparation
Method: EPA 9056
Sulfate
ND mg/kg
788
1 10/11/1912:36
10/11/1914:38
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/18/2019 03:46 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 17

WO#:92448332 --
V
0
0.

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 03, 2020
Rececca Miller
Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Dear Rececca Miller:
Enclosed are the analytical results for sample(s) received by the laboratory on January 17, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring for
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Andrew Edwards, City of Elizabeth City
Accounts Payable, City of Elizabeth City
�e pCCRF�i\
TNI
`"eORATOQy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 22

(�Ia'cie Analytical
www.pacelabs.cem
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Pace Analytical Services Pennsylvania
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Florida: Cert E871149 SEKS WET
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PAO14572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 22

(�Ia'cie Analytical
www.pacelabs.cem
SAMPLE ANALYTE COUNT
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
92461246001 SLUDGE EPA 8081 B
PKS
9
PASI-C
EPA 8082A
PKS
8
PASI-C
EPA 601 OD
DS
7
PASI-A
EPA 7470A
SOO
1
PASI-A
EPA 8270E
BPJ
18
PASI-C
EPA 8260D
SAS
14
PASI-C
ASTM D2974-87
VAK
1
PASI-PA
EPA 1010
RTB
1
PASI-PA
EPA 9045C
AJM
1
PASI-PA
EPA 9014
PAS
1
PASI-PA
SM 4500S2F-2011
PAS
1
PASI-PA
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 22

(�Ia'cie Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE Lab ID: 92461246001 Collected: 01/15/20 14:33 Received: 01/17/20 12:50 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters
8081 TCLP Pesticides RVE
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8082 TCLP PCBs RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/22/20 14:52 Initial pH: ; Final pH: 4
ND
ug/L
0.50
1
01/23/2015:55
01/27/2015:35
58-89-9
ND
ug/L
3.0
1
01/23/2015:55
01/27/2015:35
57-74-9
ND
ug/L
0.50
1
01/23/2015:55
01/27/2015:35
72-20-8
ND
ug/L
0.50
1
01/23/2015:55
01/27/2015:35
76-44-8
ND
ug/L
0.50
1
01/23/2015:55
01/27/2015:35
1024-57-3
ND
ug/L
1000
1
01/23/2015:55
01/27/2015:35
72-43-5
ND
ug/L
3.0
1
01/23/2015:55
01/27/2015:35
8001-35-2
73
%
10-138
1
01/23/2015:55
01/27/2015:35
2051-24-3
40
%
10-110
1
01/23/2015:55
01/27/2015:35
877-09-8
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/22/20 14:52 Initial pH: ; Final pH: 4
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
12674-11-2
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
11104-28-2
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
11141-16-5
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
53469-21-9
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
12672-29-6
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
11097-69-1
ND
ug/L
1000
1
01/23/2015:55
01/24/2017:32
11096-82-5
58
%
10-132
1
01/23/2015:55
01/24/2017:32
2051-24-3
6010 MET ICP, TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/27/20 15:30
Initial
pH: 10.87; Final pH: 4.5
Arsenic
ND
mg/L
0.050
1
01/28/2011:18
01/28/2017:02
7440-38-2
Barium
0.35
mg/L
0.25
1
01/28/2011:18
01/28/2017:02
7440-39-3
Cadmium
ND
mg/L
0.0050
1
01/28/2011:18
01/28/2017:02
7440-43-9
Chromium
ND
mg/L
0.050
1
01/28/2011:18
01/28/2017:02
7440-47-3
Lead
ND
mg/L
0.025
1
01/28/2011:18
01/28/2017:02
7439-92-1
Selenium
ND
mg/L
0.10
1
01/28/2011:18
01/28/2017:02
7782-49-2
Silver
ND
mg/L
0.025
1
01/28/2011:18
01/28/2017:02
7440-22-4
7470 Mercury, TCLP
Analytical Method:
EPA 7470A
Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/27/20 15:30
Initial
pH: 10.87; Final pH: 4.5
Mercury
0.00022
mg/L
0.00020
1
01/28/2012:07
01/29/2014:39
7439-97-6
8270E MSSV TCLP Sep Funnel
Analytical Method:
EPA 8270E
Preparation Method: EPA 3510C
1,4-Dichlorobenzene
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
106-46-7
2,4-Dinitrotoluene
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
121-14-2
Hexachloro-1,3-butadiene
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
87-68-3
Hexachlorobenzene
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
118-74-1
Hexachloroethane
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
67-72-1
2-Methyl phenol(o-Cresol)
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
95-48-7
3&4-Methylphenol (m&p Cresol)
ND
ug/L
500
10
01/23/20 12:51
01/28/20 13:03
15831-10-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 22

(�Ia'cie Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE Lab ID: 92461246001 Collected: 01/15/20 14:33 Received: 01/17/20 12:50 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8270E MSSV TCLP Sep Funnel
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260D MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
1010 Flashpoint,Closed Cup
Flashpoint
9045 pH Soil
pH in water at 25 degrees C
733C S Reactive Cyanide
Cyanide, Reactive
734S Reactive Sulfide
Sulfide, Reactive
Date: 02/03/2020 08:34 AM
Analytical Method: EPA 8270E Preparation Method: EPA 3510C
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
98-95-3
ND
ug/L
1000
10
01/23/2012:51
01/28/2013:03
87-86-5
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
110-86-1
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
95-95-4
ND
ug/L
500
10
01/23/2012:51
01/28/2013:03
88-06-2
0
%
12-102
10
01/23/2012:51
01/28/2013:03
4165-60-0
D3,S4
0
%
13-107
10
01/23/2012:51
01/28/2013:03
321-60-8
S4
0
%
21-132
10
01/23/2012:51
01/28/2013:03
1718-51-0
S4
0
%
10-110
10
01/23/2012:51
01/28/2013:03
13127-88-3
S4
0
%
10-110
10
01/23/2012:51
01/28/2013:03
367-12-4
S4
0
%
27-108
10
01/23/2012:51
01/28/2013:03
118-79-6
S4
Analytical Method:
EPA 8260D
ND
ug/L
100
20
01/28/20 02:45
71-43-2
ND
ug/L
200
20
01/28/20 02:45
78-93-3
ND
ug/L
100
20
01/28/20 02:45
56-23-5
ND
ug/L
100
20
01/28/20 02:45
108-90-7
ND
ug/L
100
20
01/28/20 02:45
67-66-3
ND
ug/L
100
20
01/28/20 02:45
106-46-7
ND
ug/L
100
20
01/28/20 02:45
107-06-2
ND
ug/L
100
20
01/28/20 02:45
75-35-4
ND
ug/L
100
20
01/28/20 02:45
127-18-4
ND
ug/L
100
20
01/28/20 02:45
79-01-6
ND
ug/L
100
20
01/28/20 02:45
75-01-4
90
%
70-130
20
01/28/20 02:45
17060-07-0
103
%
67-135
20
01/28/20 02:45
2037-26-5
99
%
70-130
20
01/28/20 02:45
460-00-4
Analytical Method: ASTM D2974-87
95.2 %
0.10 1
01/30/2016:00
Analytical Method: EPA 1010
>200 deg F
60.0 1
01/21/20 21:34
Analytical Method: EPA 9045C
11.6 Std. Units
2.0 1
01/20/20 23:54 H3
Analytical Method: EPA 9014 Preparation
Method: SW-846 7.3.3.2
ND mg/kg
20.7 1 01/21/2018:39
01/21/2019:09
Analytical Method: SM 4500S2F-2011
Preparation Method: SW-846 7.3.4.2
ND mg/kg
207 1 01/21/2018:39
01/21/2018:41
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 521782
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92461246001
METHOD BLANK: 2789820
Matrix: Water
Associated Lab Samples: 92461246001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
01/29/2015:31
METHOD BLANK: 2790229
Matrix: Water
Associated Lab Samples: 92461246001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
01/29/2015:07
LABORATORY CONTROL SAMPLE: 2791282
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0028
111 80-120
LABORATORY CONTROL SAMPLE: 2791283
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0028
110 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2791284 2791285
MS MSD
92460983001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units
Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/L
0.00020
0.0025 0.0025 0.0025
0.0029 91 106 75-125 14
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 521769 Analysis Method: EPA6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92461246001
METHOD BLANK: 2789820
Matrix:
Water
Associated Lab Samples: 92461246001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
01/28/2016:21
Barium
mg/L
ND
0.25
01/28/2016:21
Cadmium
mg/L
ND
0.0050
01/28/2016:21
Chromium
mg/L
ND
0.050
01/28/2016:21
Lead
mg/L
ND
0.025
01/28/2016:21
Selenium
mg/L
ND
0.10
01/28/2016:21
Silver
mg/L
ND
0.025
01/28/2016:21
METHOD BLANK: 2790229
Matrix:
Water
Associated Lab Samples: 92461246001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
01/28/2016:27
Barium
mg/L
ND
0.25
01/28/2016:27
Cadmium
mg/L
ND
0.0050
01/28/2016:27
Chromium
mg/L
ND
0.050
01/28/2016:27
Lead
mg/L
ND
0.025
01/28/2016:27
Selenium
mg/L
ND
0.10
01/28/2016:27
Silver
mg/L
ND
0.025
01/28/2016:27
LABORATORY CONTROL SAMPLE:
2791140
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Qualifiers
Spike
LCS
LCS
% Rec
Cone.
Result
% Rec
Limits Qualifiers
2.5
2.3
94
80-120
2.5
2.4
97
80-120
2.5
2.4
95
80-120
2.5
2.3
94
80-120
2.5
2.3
93
80-120
2.5
2.4
98
80-120
1.2
1.2
96
80-120
LABORATORY CONTROL SAMPLE: 2791141
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.4 95 80-120
Barium mg/L 2.5 2.5 100 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC.
Page 7 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2791141
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
Cadmium
mg/L
2.5
2.4
97
80-120
Chromium
mg/L
2.5
2.4
97
80-120
Lead
mg/L
2.5
2.4
96
80-120
Selenium
mg/L
2.5
2.6
103
80-120
Silver
mg/L
1.2
1.2
98
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2791142
2791143
MS
MSD
92460983001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
ND
2.5
2.5
2.4
2.4
95
96
75-125
1
Barium
mg/L
ND
2.5
2.5
2.6
2.6
98
99
75-125
1
Cadmium
mg/L
ND
2.5
2.5
2.5
2.5
98
99
75-125
1
Chromium
mg/L
ND
2.5
2.5
2.4
2.4
96
98
75-125
2
Lead
mg/L
ND
2.5
2.5
2.4
2.4
95
96
75-125
1
Selenium
mg/L
ND
2.5
2.5
2.6
2.6
103
103
75-125
1
Silver
mg/L
ND
1.2
1.2
1.2
1.2
99
100
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 521608 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV TCLP
Associated Lab Samples: 92461246001
METHOD BLANK: 2790462
Associated Lab Samples: 92461246001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1-Dichloroethene
ug/L
ND
5.0
01/27/20 23:46
1,2-Dichloroethane
ug/L
ND
5.0
01/27/20 23:46
1,4-Dichlorobenzene
ug/L
ND
5.0
01/27/20 23:46
2-Butanone (MEK)
ug/L
ND
10.0
01/27/20 23:46
Benzene
ug/L
ND
5.0
01/27/20 23:46
Carbon tetrachloride
ug/L
ND
5.0
01/27/20 23:46
Chlorobenzene
ug/L
38.6
5.0
01/27/20 23:46
Chloroform
ug/L
ND
5.0
01/27/20 23:46
Tetrachloroethene
ug/L
ND
5.0
01/27/20 23:46
Trichloroethene
ug/L
ND
5.0
01/27/20 23:46
Vinyl chloride
ug/L
ND
5.0
01/27/20 23:46
1,2-Dichloroethane-d4 (S)
%
85
70-130
01/27/20 23:46
4-Bromofluorobenzene (S)
%
96
70-130
01/27/20 23:46
Toluene-d8 (S)
%
104
67-135
01/27/20 23:46
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2790461
Units
Spike
Cone.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1-Dichloroethene
ug/L
50
48.1
96
70-130
1,2-Dichloroethane
ug/L
50
48.3
97
70-130
1,4-Dichlorobenzene
ug/L
50
56.2
112
70-130
2-Butanone (MEK)
ug/L
100
88.7
89
64-135
Benzene
ug/L
50
53.6
107
70-130
Carbon tetrachloride
ug/L
50
53.8
108
70-130
Chlorobenzene
ug/L
50
54.1
108
70-130
Chloroform
ug/L
50
51.2
102
70-130
Tetrachloroethene
ug/L
50
56.8
114
69-130
Trichloroethene
ug/L
50
59.3
119
70-130
Vinyl chloride
ug/L
50
42.7
85
70-131
1,2-Dichloroethane-d4 (S)
%
86
70-130
4-Bromofluorobenzene (S)
%
95
70-130
Toluene-d8 (S)
%
95
67-135
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790463 2790464
MS MSD
92460870004 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene ug/L ND 400 400 412 403 103 101 70-154 2
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2790463
2790464
MS
MSD
92460870004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
372
386
93
97
70-137
4
1,4-Dichlorobenzene
ug/L
ND
400
400
421
432
105
108
70-133
3
2-Butanone (MEK)
ug/L
ND
800
800
619
659
77
82
60-139
6
Benzene
ug/L
ND
400
400
437
437
109
109
70-151
0
Carbon tetrachloride
ug/L
ND
400
400
446
450
112
112
70-143
1
Chlorobenzene
ug/L
ND
400
400
461
471
115
118
70-138
2
Chloroform
ug/L
ND
400
400
409
417
102
104
70-139
2
Tetrachloroethene
ug/L
ND
400
400
458
464
115
116
59-143
1
Trichloroethene
ug/L
ND
400
400
473
488
118
122
70-147
3
Vinyl chloride
ug/L
ND
400
400
369
359
92
90
70-156
3
1,2-Dichloroethane-d4 (S)
%
92
94
70-130
4-Bromofluorobenzene (S)
%
96
97
70-130
Toluene-d8(S)
%
97
95
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 521019 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92461246001
METHOD BLANK: 2786421
Matrix:
Water
Associated Lab Samples: 92461246001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
01/27/20 13:55
Endrin
ug/L
ND
0.50
01/27/20 13:55
gamma-BHC (Lindane)
ug/L
ND
0.50
01/27/20 13:55
Heptachlor
ug/L
ND
0.50
01/27/20 13:55
Heptachlor epoxide
ug/L
ND
0.50
01/27/20 13:55
Methoxychlor
ug/L
ND
1000
01/27/20 13:55
Toxaphene
ug/L
ND
3.0
01/27/20 13:55
Decachlorobiphenyl (S)
%
115
10-138
01/27/20 13:55
Tetrachloro-m-xylene (S)
%
88
10-110
01/27/20 13:55
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2787567
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Endrin
ug/L
1.2
1.1
90
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.1
90
20-118
Heptachlor
ug/L
1.2
0.97
78
20-142
Heptachlor epoxide
ug/L
1.2
1.2
93
22-133
Methoxychlor
ug/L
3.8
3.6J
97
44-150
Decachlorobiphenyl (S)
%
94
10-138
Tetrachloro-m-xylene (S)
%
82
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2787568
2787569
MS
MSD
92460983001
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec % Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.1
1.2
85
94
21-133
10
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.0
1.1
82
90
24-119
10
Heptachlor
ug/L
ND
1.2
1.2
0.89
0.97
71
77
16-128
9
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.1
1.2
86
95
50-150
10
Methoxychlor
ug/L
ND
3.8
3.8
3.7J
4J
98
106
50-150
Decachlorobiphenyl (S)
%
118
119
10-138
Tetrachloro-m-xylene (S)
%
75
79
10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 521022 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 TCLP PCB RV
Associated Lab Samples: 92461246001
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 2786421
Matrix:
Water
Associated Lab Samples: 92461246001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
1000
01/24/20 20:13
PCB-1221 (Aroclor 1221)
ug/L
ND
1000
01/24/20 20:13
PCB-1232 (Aroclor 1232)
ug/L
ND
1000
01/24/20 20:13
PCB-1242 (Aroclor 1242)
ug/L
ND
1000
01/24/20 20:13
PCB-1248 (Aroclor 1248)
ug/L
ND
1000
01/24/20 20:13
PCB-1254 (Aroclor 1254)
ug/L
ND
1000
01/24/20 20:13
PCB-1260 (Aroclor 1260)
ug/L
ND
1000
01/24/20 20:13
Decachlorobiphenyl (S)
%
111
10-132
01/24/20 20:13
LABORATORY CONTROL SAMPLE:
2787574
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
25
ND
83 38-113
PCB-1260 (Aroclor 1260)
ug/L
25
ND
93 35-120
Decachlorobiphenyl (S)
%
108 10-132
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2787575
2787576
MS
MSD
92461246001 Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units
Result Cone.
Cone. Result
Result
% Rec
% Rec
Limits RPD Qual
PCB-1016 (Aroclor 1016)
ug/L
ND 25
25 ND
ND
74
55
19-142
PCB-1260 (Aroclor 1260)
ug/L
ND 25
25 ND
ND
49
35
19-142
Decachlorobiphenyl (S)
%
46
34
10-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 520953 Analysis Method: EPA 8270E
QC Batch Method: EPA 3510C Analysis Description: 8270E TCLP MSSV
Associated Lab Samples: 92461246001
METHOD BLANK: 2786421
Associated Lab Samples: 92461246001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
01/23/20 16:01
2,4,5-Trichlorophenol
ug/L
ND
50.0
01/23/20 16:01
2,4,6-Trichlorophenol
ug/L
ND
50.0
01/23/20 16:01
2,4-Dinitrotoluene
ug/L
ND
50.0
01/23/20 16:01
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
01/23/20 16:01
3&4-Methylphenol (m&p Cresol)
ug/L
ND
50.0
01/23/20 16:01
Hexachloro-1,3-butadiene
ug/L
ND
50.0
01/23/20 16:01
Hexachlorobenzene
ug/L
ND
50.0
01/23/20 16:01
Hexachloroethane
ug/L
ND
50.0
01/23/20 16:01
Nitrobenzene
ug/L
ND
50.0
01/23/20 16:01
Pentachlorophenol
ug/L
ND
100
01/23/20 16:01
Pyridine
ug/L
ND
50.0
01/23/20 16:01
2,4,6-Tribromophenol (S)
%
49
27-108
01/23/20 16:01
2-Fluorobiphenyl (S)
%
50
13-107
01/23/20 16:01
2-Fluorophenol (S)
%
35
10-110
01/23/20 16:01
Nitrobenzene-d5 (S)
%
56
12-102
01/23/20 16:01
Phenol-d6 (S)
%
24
10-110
01/23/20 16:01
Terphenyl-d14 (S)
%
64
21-132
01/23/20 16:01
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2787236
Units
Spike
Conc.
1-CS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
358
72
10-110
2,4,5-Trichlorophenol
ug/L
500
342
68
39-108
2,4,6-Trichlorophenol
ug/L
500
356
71
40-104
2,4-Dinitrotoluene
ug/L
500
419
84
42-109
2-Methyl phenol(o-Cresol)
ug/L
500
372
74
31-110
3&4-MethyIphenol (m&p Cresol)
ug/L
500
360
72
30-110
Hexachloro-1,3-butadiene
ug/L
500
311
62
10-110
Hexachlorobenzene
ug/L
500
386
77
39-121
Hexachloroethane
ug/L
500
368
74
10-110
Nitrobenzene
ug/L
500
405
81
32-101
Pentachlorophenol
ug/L
1000
744
74
18-108
Pyridine
ug/L
500
201
40
10-110
2,4,6-Tribromophenol (S)
%
92
27-108
2-Fluorobiphenyl (S)
%
72
13-107
2-Fluorophenol(S)
%
53
10-110
Nitrobenzene-d5 (S)
%
80
12-102
Phenol-d6 (S)
%
37
10-110
Terphenyl-d14 (S)
%
86
21-132
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2787234
2787235
MS
MSD
92460826001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
181
159
36
32
30-150
13
2,4,5-Trichlorophenol
ug/L
ND
500
500
184
173
37
35
30-150
6
2,4,6-Trichlorophenol
ug/L
ND
500
500
185
167
37
33
30-150
10
2,4-Dinitrotoluene
ug/L
ND
500
500
240
246
48
49
30-150
2
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
142
128
28
26
30-150
10 M1
3&4-Methylphenol (m&p
ug/L
ND
500
500
142
124
26
23
30-150
13 M1
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
142
120
28
24
30-150
16 M1
Hexachlorobenzene
ug/L
ND
500
500
222
221
44
44
30-150
0
Hexachloroethane
ug/L
ND
500
500
176
150
35
30
30-150
16
Nitrobenzene
ug/L
ND
500
500
201
170
40
34
30-150
16
Pentachlorophenol
ug/L
ND
1000
1000
422
429
42
43
30-150
2
Pyridine
ug/L
ND
500
500
87.1
86.1
17
17
30-150
1 M1
2,4,6-Tribromophenol (S)
%
57
51
27-108
2-Fluorobiphenyl (S)
%
40
32
13-107
2-Fluorophenol(S)
%
23
19
10-110
Nitrobenzene-d5 (S)
%
44
35
12-102
Phenol-d6 (S)
%
15
12
10-110
Terphenyl-d14 (S)
%
49
43
21-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 381817 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92461246001
SAMPLE DUPLICATE: 1850342
30345598004 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 17.8 19.0 7
SAMPLE DUPLICATE: 1850343
30345598014 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 13.9 12.0 14
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 15 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 380462 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92461246001
METHOD BLANK: 1844534 Matrix: Water
Associated Lab Samples: 92461246001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Flashpoint deg F >200 60.0 01/21/20 20:56
SAMPLE DUPLICATE: 1844535
30346045001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC.
Page 16 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 380257 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Associated Lab Samples: 92461246001
SAMPLE DUPLICATE: 1843569
Parameter
pH in water at 25 degrees C
30345704001 Dup
Units Result Result RPD Qualifiers
Std. Units 11.9 11.8 0 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 380207
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92461246001
METHOD BLANK: 1843405
Matrix: Solid
Associated Lab Samples: 92461246001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND
1.0 01/21/20 19:04
LABORATORY CONTROL SAMPLE: 1843406
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
100 ND
0 0-8
SAMPLE DUPLICATE: 1843407
50247094018 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
<0.40
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 22

(�Ia'cie Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
QC Batch: 380206
Analysis Method:
SM 4500S2F-2011
QC Batch Method: SW-846 7.3.4.2
Analysis Description:
734S Reactive Sulfide
Associated Lab Samples: 92461246001
METHOD BLANK: 1843402
Matrix: Solid
Associated Lab Samples: 92461246001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND
10 01/21/20 18:41
LABORATORY CONTROL SAMPLE: 1843403
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
199 39.9
20 0-52
SAMPLE DUPLICATE: 1843404
50247094018 Dup
Parameter
Units
Result Result
RPD Qualifiers
Sulfide, Reactive
mg/kg
<10 ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 22

(�Ia'cie Analytical
www.pacelabs.cem
QUALIFIERS
Project: TCLP SLUDGE+RCI
Pace Project No.: 92461246
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-PA Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
S4 Surrogate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 08:34 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 22

(�Ia'cie Analytical
www.pacelabs.cem
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
TCLP SLUDGE+RCI
92461246
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92461246001
SLUDGE
EPA 3510C
521019
EPA 8081 B
521337
92461246001
SLUDGE
EPA 3510C
521022
EPA 8082A
521339
92461246001
SLUDGE
EPA 3010A
521769
EPA 6010D
521799
92461246001
SLUDGE
EPA 7470A
521782
EPA 7470A
521814
92461246001
SLUDGE
EPA 3510C
520953
EPA 8270E
521043
92461246001
SLUDGE
EPA 8260D
521608
92461246001
SLUDGE
ASTM D2974-87
381817
92461246001
SLUDGE
EPA 1010
380462
92461246001
SLUDGE
EPA 9045C
380257
92461246001
SLUDGE
SW-846 7.3.3.2
380207
EPA 9014
380450
92461246001
SLUDGE
SW-846 7.3.4.2
380206
SM 4500S2F-2011
380449
Date: 02/03/2020 08:34 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 22

1�7ace Analytical `w
Elizabeth City
450 Knobbs Creek
Yasheka Brothers
REBECCA MILLER
CHAIN -OF -CUSTODY Analytical Request Document
Chain--f-Custody is a LEGAL DOCUMENT - Complete all relevent fields
Kling Information:
rmi[ler(cDcityofec. com
Site Collection Info/Address:
ANNUAL SLUDGE TCLP AND RCI state: County/City: Time Zone Collected:
/ [ }PT [ JMT [ ]CT [ ]ET
Site/Facility ID #: Compliance Monitoring?
1252)337-3331 [ ] Yes [ ]No
II ted y (pri Purchase Order # : DW PWS ID #:
LAB u51~ ONLY- Aw- Work-
Wo# ; 92461246
ALL SHADEI
1111111111111111111111
g2461246
Container Preservative
* * Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (S) zinc acetate,
(6) methanol, (7) sodium bisulfate, {8) sodium thiostitfate, (9) hexane, (A) ascorbic acid, (9) ammonium sulfate,
(C) ammonium hydroxide, (D) TSP, (U) Urpreserved, (0) Other
Analyses Lab Profile/Line:
Q
uo
DW Location Code:
�1
^
o h ted By (signatu
Turnaround Date Required:
l ediateiy Packed on Ice:
] Yes [ 1 No
m00
Q
CD
00
Fiel Filtered (if applicable):
pie Disposal:
Rush:
W
W
[ I Uispow as appropriate [ I Return
[ ] Same Day [ J Next Day
[ ] Yes [ ] No
0
❑
Z
W
W
( }Archive:
[ J 2 Day [ J 3 Day [ ] 4 Day [ J 5 Day
C7
_
U
LLf)
❑
O
[ J Hold:
(Expedite Charges Apply)
Analysis:
W
%"
�
O
CD
0
C:)<
co
U
~
C„)
m
* Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Sioassay (B), Vapor (V), Other (OT)
>
>
fJ)
U
W
W
00
F-
X
tb
CL
0-
d
=
o0
Comp /
Collected (or
Res
# of
Customer Sample ID
Matrix *
Grab
Composite Start)
Composite End
CI
Ctrs
0
<
C)
Q
DY
0.
J
�
—j
0-
-j
0-
J
ID_
J
co
W
W
0
C)U
C)
U
U
C)
Date I
Time
Date
Time
Customer Remarks / Special Conditions/ Possible Hazards: (Type of Ice Used:
' Packing Materiai Used:
by/Company: (Signature)
Blue Dry None
Radchem samples) screened (<500 cpm): Y N l
Da e/Ti e: Received y/Company: (Signature}
I. 11o77n --1 ! C3� (-�-OC
me:
Relinquished by/Company: (Signature} IDate/Time;
ny:
SHORT HOLDS PRESENT (<72 hours) : Y NT N/A
Lab Tracking #:
mples received via:
FEDEX UPS Client Courier Pace 4,rir
Date/Time:
MTJL LAB USE ONLY
Table #:
Date Ti
Acctnum:
p
17 CI I
Template:
Prelogin:
RN .PB
Date/Time:
ry
e4
rV
O I
rV
rV
rn
LAB Sample Temperature Info:
'emp Blank !ic ,_:.Lv Y N r
1honn U-0: __
coolev 1 Tclnp Upnn Receipt.: C
Cooler 1 Thum Corr. Vactor oc
Cooler 1 Corru-,c:tc:d Temp: - cC
t:brzmlF:nt.5
Trip Blank Received: Y N -HA
HCL McOH TSP Other
Non Confurmance(s): Page:
YES / NO I of:

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 03, 2020
Rececca Miller
Elizabeth City
450 Knobbs Creek
Elizabeth City, NC 27909
RE: Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
Dear Rececca Miller:
Enclosed are the analytical results for sample(s) received by the laboratory on January 24, 2020.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
PwtvL
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Andrew Edwards, City of Elizabeth City
Accounts Payable, City of Elizabeth City
�e pCCRF�i\
TNI
ORAT�1 A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 8

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
Pace Analytical Services National
12065 Lebanon Road, Mt. Juliet, TN 37122
Alabama Certification #: 40660
Alaska Certification 17-026
Arizona Certification #: AZ0612
Arkansas Certification #: 88-0469
California Certification #: 2932
Canada Certification #: 1461.01
Colorado Certification #: TN00003
Connecticut Certification #: PH-0197
DOD Certification: #1461.01
EPA# TN00003
Florida Certification #: E87487
Georgia DW Certification #: 923
Georgia Certification: NELAP
Idaho Certification #: TN00003
Illinois Certification #: 200008
Indiana Certification #: C-TN-01
Iowa Certification #: 364
Kansas Certification #: E-10277
Kentucky UST Certification #: 16
Kentucky Certification #: 90010
Louisiana Certification #: A130792
Louisiana DW Certification #: LA180010
Maine Certification #: TN0002
Maryland Certification #: 324
Massachusetts Certification #: M-TNO03
Michigan Certification #: 9958
Minnesota Certification #: 047-999-395
Mississippi Certification #: TN00003
Missouri Certification #: 340
Montana Certification #: CERT0086
Nebraska Certification #: NE-OS-15-05
CERTIFICATIONS
Nevada Certification #: TN-03-2002-34
New Hampshire Certification #: 2975
New Jersey Certification #: TNO02
New Mexico DW Certification
New York Certification #: 11742
North Carolina Aquatic Toxicity Certification #: 41
North Carolina Drinking Water Certification #: 21704
North Carolina Environmental Certificate #: 375
North Dakota Certification #: R-140
Ohio VAP Certification #: CL0069
Oklahoma Certification #: 9915
Oregon Certification #: TN200002
Pennsylvania Certification #: 68-02979
Rhode Island Certification #: LA000356
South Carolina Certification #: 84004
South Dakota Certification
Tennessee DW/Chem/Micro Certification #: 2006
Texas Certification #: T 104704245-17-14
Texas Mold Certification #: LABO152
USDA Soil Permit #: P330-15-00234
Utah Certification #: TN00003
Virginia Certification #: VT2006
Vermont Dept. of Health: ID# VT-2006
Virginia Certification #: 460132
Washington Certification #: C847
West Virginia Certification #: 233
Wisconsin Certification #: 9980939910
Wyoming UST Certification #: via A2LA 2926.01
A2LA-ISO 17025 Certification #: 1461.01
A2LA-ISO 17025 Certification #: 1461.02
AIHA-LAP/LLC EMLAP Certification #:100789
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 8

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92462282001 SLUDGE EPA 8151A RP 3 PAN
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 8

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
Sample: SLUDGE
Lab ID: 92462282001
Collected: 01/23/20 10:46
Received: 01/24/20 09:00 Matrix: Solid
Results reported on a "wet -weight"
basis
Parameters
Results Units
Report Limit DF
Prepared Analyzed
CAS No. Qual
Chlorinated Herb. (GC) 8151A
Analytical Method: EPA8151A
Preparation Method: 8151A
Leachate Method/Date: 1311; 01/28/20 19:18 Initial pH:
10.07; Final pH: 5.23
2,4,5-TP (Silvex)
ND mg/L
0.00200 1
01/30/20 17:33 01/31/20 13:42
93-72-1
2,4-D
ND mg/L
0.00200 1
01/30/2017:33 01/31/2013:42
94-75-7
Surrogates
2,4-DCAA(S)
56.4 %
14.0-158 1
01/30/2017:33 01/31/2013:42
19719-28-9
Date: 02/03/2020 09:54 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 8

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
QC Batch: 1419995 Analysis Method: EPA 8151A
QC Batch Method: 8151A Analysis Description: Chlorinated Herb. (GC) 8151A
Associated Lab Samples: 92462282001
METHOD BLANK: R3495893-1
Matrix:
Solid
Associated Lab Samples: 92462282001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4-D
mg/L
ND
0.00200
01/31/2012:43
2,4,5-TP (Silvex)
mg/L
ND
0.00200
01/31/20 12:43
2,4-DCAA(S)
%
75
14.0-158
01/31/2012:43
LABORATORY CONTROL SAMPLE:
R3495893-2
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
2,4-D
mg/L
0.0500
0.0372
74.4 50.0-120
2,4,5-TP (Silvex)
mg/L
0.0500
0.0358
71.6 50.0-125
2,4-DCAA (S)
%
71.2 14.0-158
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 09:54 AM without the written consent of Pace Analytical Services, LLC.
Page 5 of 8

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PAN Pace Analytical National
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 09:54 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 8

aceAnalytical
www.paeelabs.enm
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: TCLP HERB -SLUDGE
Pace Project No.: 92462282
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92462282001 SLUDGE 8151A 1419995 EPA 8151A 1419995
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/03/2020 09:54 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 8

ace Analytical
CHAIN -OF -CUSTODY Ana[yiica' Request Documents
Chain -of -Custody is a LEGAL DOCUMENT • Complete all relevent fields
Elizabeth City
Billing information:
450 Knobbs Creek
Yash eka Brothers
yb rother5rf CityDfeG_ com
Rebecca Miller
Site Collection Info/Address:
TCLP HERBICIDES
Elizabeth City, INC 27909
[phone]
Site/Facility ID #:
Compliance Monitoring?
[ ] Yes [ ) No
I'
(pri
Purchase Order
#:
DW PWS ID #:
DW Location Code:
Ilea d By signatur
Turnaround Date Required:
Immediately Packed on Ice:
( i Yes [ j No {
S�wdple spo-% .
Rush:
Field Filtered (if applicable) j
[ ) Dispose as appropriate [ ]Return [ ( Same Day ] ] Next Day ( l Yes i [ No
I I Archive: ]] 2 Day [ l 3 Day [ ]4 Day [ l 5 Day
[ ) Hold: (Expedite Charges Apply) Analysis:
Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GWJ, Wastewater (W W),
Product (P), Soil/Solid (SL), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (VI, Other (OT)
Corn % Collected (or Composite End
Customer Sample ID Matrix " Grab Composite Start(
Date I Time Date Time
t1� SL -� t IrUl.
Customer Remarks / Special Conditions / Possible Hazards:
(5Tnaturel
LAB USE ONLY -Affix Wcrkard WO# : ` 2462282
f` 1111flIJIMU 1111ALL SHADED 1 924622B2
Ccniainer = _ - ry,_ _ Lwb�pr est Manager: I
}`
•• preservative Types: (1) mtnc a _ - �.. _ ... ;,Ic acid, (4) sodium hydr.,, i5) zinc acekx,
IS) methanol, (7} Sodium buulfafr, i,3) sodun t',�os�i!a tr, (5i F,., ,, (A) ascorbic acid, (6) ammcnmm sulfate,
IC) ammonium hydroxide. (DI ;SP. (D) Unpreserved, (0) Other
Analyses 1nh P'o
{
T
Res # of r I
Cl Ctns
,
r , I
I
I
f f j
i I
of Ice Used: ,(Net Blue Dry Nene
ng Material Used: ( /
Radehtm sample(S) screened (<500 .pmj: Y N
'Time: rt--eJed by/Ccrnpa-,4'-iS,gnC;::rc)
L31 LD - H10 -
Time: lReceived by/Company: (Signature)
SHGRT HOLDS PRESENT (<72 hours) : Y N/A ule 52mple To -roc :lure info:
Lab Tr.ackireg k:
ceived via: -. .
i=EDE UPS CGen- Courser JPace Courier"
'Me
e/Time:
Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature} Date/Time:
r 4 l n 20 ;;4'i
o
V
00
.._ M .73 RAD SCREEN: <0.5 mP)hr
Trip B#ank Received: Y
Template:. - HCL McOH - TSP O
PM .f l �� lj Lz Non Conforr7Ce(s): I Page:
y��za o11
PB' YES / of:
-__

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0002883 Facility Name City of Elizabeth City Source Permit No. 04-70-010 Source Name Elizabeth City WTP
Laboratory 1
Laboratory 2
Sample or CompositeDate
Parameter (mg/Kg) Class A Clas B
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analytical
Pace Analytical
1/25/2019
3/11/2019
5/14/2019
7/15/2019
9/17/2019
11/5/2019
Aluminum
N/A
N/A
12,000
4,370
7,730
3,070
9,770
9,240
Ammonia Nitrogen
N/A
N/A
9
48
35
32
34
45
Arsenic
41
75
1.5
2.9
2.5
3.1
3.2
3.2
Cadmium
39
85
0.15
0.29
0.25
0.31
0.32
0.32
Calcium
N/A
N/A
280,000
105,000
197,000
72,300
226,000
209,000
Copper
1,500
4,300
1.6
1.5
1.3
1.5
1.6
1.9
Lead
300
840
0.77
1.5
12
1.5
1.6
1.6
Magnesium
N/A
N/A
12,300
5,040
8,330
3,190
10,700
10,600
Mercury
17
57
0.023
0.024
0.014
0.0098
0.0064
0.009
Molybdenum
N/A
75
0.77
1.5
1.2
1.3
1.6
1.6
Nickel
420
420
1.5
1.5
1.2
1.5
1.6
1.6
Nitrate -Nitrite Nitrogen
N/A
N/A
32
61
18
14
14
19
Percent Solids
N/A
N/A
21.60
18.60
21.60
28.40
28.60
20.50
pH (no units)
N/A
N/A
10.65
10.62
10.02
9.79
9.37
9.93
Phosphorus
N/A
N/A
60
334
254
228
180
135
Potassium
N/A
N/A
773
41
37
1,460
1,250
1,550
1,390
1,620
PAN (Inj./Inc.)
N/A
N/A
109
53
46
47
31
65
PAN (Surface)
N/A
N/A
85
36
30
42
Selenium
100
100
1.5
2.9
2.5
3.1
3.2
3.2
Sodium
N/A
N/A
773
1,460
1,250
1,550
1,590
1,620
SAR
N/A
N/A
0.18
051
0.35
0.82
0.47
0.42
TKN
N/A
N/A
36
224
193
160
205
195
Zinc
2,800
7,500
3.8
2.9
25
3.1
3.2
32
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
if Preparer *
is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
7 - 20
Date

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 1/25/2019
Solids 21.6
Mineralization Rate 0
Gallons per DT 1,110.22
pH 10.65
Sodium Absorpotion 0.18 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 36 lbs./1,000 gal 0.06
Ammonia Nitrogen (mg/Kg) 9.30 lbs./1,000 gal 0.02
Nitrate -Nitrite (mg/Kg) 32.10 lbs./1,000 gal 0.06
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 37 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 41 lbs./1,000 gal 0.07
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 1.39
Phosphorus lbs./1,000 gal 0.11
Calcium lbs./1,000 gal 504.40
Magnesium lbs./1,000 gal 22.16
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
1.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.15
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.60
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
0.77
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.02
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
1.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.80
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
36
37 0.07
-1
36
41 0.08
-6
-1
0 0.00
-1
-6
0 0.00
-6
-1
0 0.00
-1
-6
0 0.00
-6
-1
0 0.00
-1
-6
0 0.00
-6
1
0 0.00
-1
-6
0 0.00
-6
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 37 0.07
Total 41 0.08

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: WTP SLUDGE
Pace Project No.: 92415510
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE 1 Lab ID: 92415510001 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
12000
mg/kg
15.5
1
02/04/1910:35
02/05/1918:53
7429-90-5
Arsenic
ND
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7440-38-2
Cadmium
ND
mg/kg
0.15
1
02/04/1910:35
02/05/1918:53
7440-43-9
Calcium
280000
mg/kg
1550
100
02/04/1910:35
02/06/1914:09
7440-70-2
Chromium
1.3
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-47-3
Copper
1.6
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-50-8
Lead
ND
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7439-92-1
Magnesium
12300
mg/kg
15.5
1
02/04/1910:35
02/05/1918:53
7439-95-4
Molybdenum
ND
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7439-98-7
Nickel
1.5
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-02-0
Potassium
ND
mg/kg
773
1
02/04/1910:35
02/05/1918:53
7440-09-7
Selenium
ND
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7782-49-2
Sodium
ND
mg/kg
773
1
02/04/1910:35
02/05/1918:53
7440-23-5
Zinc
2.8
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7440-66-6
7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
Mercury ND mg/kg 0.023 1 01/29/1918:07 01/30/1913:13 7439-97-6
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 78.4 % 0.10 1 01/30/19 13:26
M1,R1
M6, R1
M1,R1
M1
Sample: WTP SLUDGE 2 Lab ID: 92415510002 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
Date: 02/07/2019 08:49 AM
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod. Preparation Method: EPA 350.1 Rev 2.0 1993 Mod.
ND mg/kg 9.3 1 02/03/1913:33 02/03/1917:06 7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
ND mg/kg 35.7 1 02/02/19 02:22 02/05/19 00:30 7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
32.1 mg/kg 2.0 1 01/31/19 06:39 01/31/19 10:52
32.1 mg/kg 2.0 1 01/31/19 06:39 01/31/19 10:52 14797-55-8
ND mg/kg 0.99 1 01/31/19 06:39 01/31/19 10:52 14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
60.1 mg/kg 1.0 1 02/04/19 20:06 02/04/19 23:12 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 22

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: WTP SLUDGE
Pace Project No.: 92415510
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE 3 Lab ID: 92415510003 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540G Total Percent Solids Analytical Method: SM 2540G-2011
Total Solids 21.6 % 0.10 1 01/30/19 13:34
1010 Flashpoint,Closed Cup Analytical Method: EPA 1010A
Flashpoint >200 deg F 70.0 1 02/04/19 10:58
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Chloride 34.6 mg/kg 9.8 1 02/04/19 09:01 02/04/19 11:16 16887-00-6
Sample: WTP SLUDGE 4 Lab ID: 92415510004 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 82.6 % 0.10 1 01/30/19 14:18
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Sulfate 995 mg/kg 287 1 02/05/19 08:20 02/06/19 03:00 14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/07/2019 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 22

CHAIN -OF -CUSTODY I Analytical Request Document
��aceAnalyfical" The Chain -of -Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
www.pecela0s.corn
I
Section A Section B Section C
Required Client Inlormation: Required Project Information: Invoice Information:
Company: r— r /-_ Report To: f Attantlon:
-J-� G n . _
N
��.ICUL o
` N
d)
Page: of Il
Address , I C
SG
Copy To:
company Name:
REGULATORY AGENCY
n�7(j /w.
r/J r7-,,k Z RAJ [ 2 7zP
Address:
F NPDES l— GROUND WATER i^ DRINKING WATER
F UST F RCRA !— OTHER
Email To: -
Purchase Order No.:
Pace Quote
Reference:
'375 0� v(Y �__-.• a fif't.-�I / 7- �'� MeneAar.- Site Location
Requested Due DatwTAT: 1pictJoct Numb . Pece Proifle p: STATE:
Requested Analysis Filtered (YIN)
Section D Valid Matrix Codes
Required Client Information MATRIX CODE
o
E.
COLLECTED
Preservatives
DRINK1NO WATER DIN
m
U
Z
WATER WT
u
It
Q
WASTEWATER WW
PRODUCT P
v
m
IK
COMPOSITE
START
COMPOSITE
ENDfGP.A9
U
W
SOIUSOLID SL
OIL OL
SAMPLE ID W PE WP
a
�
�,
0
�
N
W
AIR AR
(A-Z. 0-9 1) O HER OT
LU
00
4
Z
Sample IDs MUST BE UNIQUE TlssuE is
a
N
W
X
ut
O
U
N
6
H
a
IL
LL
m
n
U
Uy
n
O
2(
O
N
v
W
DATE
TIME
DATE
TIME
tit
�
2
S
2
Z
Z
1
w r
rA
(A.1,113
1K
2
3
1 _ L- -r-P c;-/
..
1
a`o
l
8
't
a
9
10
11
12
sL.�l '�11UI y
LQ
C
IiA
4 ,�14t\
U
V m
% Of Pace Proiect No./ Lab
ADDITIONAL -COMMENTS RELINQUISHED BYIAFFILIAT1ON DATE I TIME 4501MDBYIAFRUATION DATE I -nmr= SAMPLE CONDITIONS
i2!3a h7 V I h✓ I I/
SAMPLER NAME AND SIGNATURE
PRINT Name of SAMPLER: - T 7
SIGNATURE of SAMPLE
•Important Note: By signing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.6% per month for any invoices not paid whhin 30 days.
DATE Signed
rulurnnn - 01
m
m
U
o w
m Z
�g
s�
F-ALL-Q-020rev.08, 12-Oct-2007

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 3/11/2019
Solids 18.6
Mineralization Rate 0
Gallons per DT 1,289.29
pH 10.62
Sodium Absorpotion 0.51 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 224 lbs./1,000 gal 0.35
Ammonia Nitrogen (mg/Kg) 48.10 lbs./1,000 gal 0.07
Nitrate -Nitrite (mg/Kg) 60.60 lbs./1,000 gal 0.09
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 85 lbs./1,000 gal 0.13
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 109 lbs./1,000 gal 0.17
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.26
Phosphorus lbs./1,000 gal 0.52
Calcium lbs./1,000 gal 162.88
Magnesium lbs./1,000 gal 7.82
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.90
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.29
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.50
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.50
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.02
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
2.90
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.90
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
224
85 0.17
139
224
109 0.22
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 85 0.17
Total 109 0.22

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Bi-Monthly Residual Sludge
Pace Project No.: 92420834
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92420834001 Collected: 03/11/19 13:20 Received: 03/12/19 10:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
2540G Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 03/26/2019 02:38 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
4370
mg/kg
29.3
1 03/25/19 13:28
03/26/19 02:36
7429-90-5
M1
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7440-38-2
ND
mg/kg
0.29
1 03/25/19 13:28
03/26/19 02:36
7440-43-9
105000
mg/kg
146
5 03/25/19 13:28
03/26/1911:44
7440-70-2
M1
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-47-3
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-50-8
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7439-92-1
5040
mg/kg
29.3
1 03/25/19 13:28
03/26/19 02:36
7439-95-4
M1
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7439-98-7
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-02-0
ND
mg/kg
1460
1 03/25/19 13:28
03/26/19 02:36
7440-09-7
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7782-49-2
ND
mg/kg
1460
1 03/25/19 13:28
03/26/19 02:36
7440-23-5
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7440-66-6
P8
Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
ND
mg/kg
0.024
1 03/21/1919:08
03/22/1915:23
7439-97-6
Analytical Method: SM 2540G-2011
18.6
%
0.10
1
03/13/1916:38
Analytical Method: ASTM D2974-87
81.4
%
0.10
1
03/13/1916:31
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
48.1
1 03/18/1915:02
03/19/1915:05
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
224
1 03/20/19 14:00
03/21/19 00:48
7727-37-9
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
334
mg/kg
9.8
2 03/14/19 19:52
03/15/19 22:24
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
214
mg/kg
53.9
1 03/18/1912:01
03/18/1916:43
16887-00-6
M1
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
185
mg/kg
50.0
1 03/13/1916:11
03/14/1912:57
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 16

CHAIN -OF -CUSTODY Analytical Request Document
LAB USE ONLY -Affix Workorder/Lc
WO# : 92420834
,�7ace,AnalXical'
MTJL
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields
ALL SHADED AR
11111111111111111111111111
92420834
City of Elizabeth City
Billing Information:
1 Wilson St.
U
V
Container
t�
Preservative Type "
t1
iragpr;� :� ��
�'Q"dU
Elizabeth City, NC 27909
ttuckerCC7cityofec.com
Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc aceWte,
(6) methanol, (7) sodium bisulfate, [R) sodium thiosulfate, (9) hexane, (A) ascorbi nd, (8) ammonium sulfate, o�
Travis Tucker
Site Collection info/Address:
(C) ammonium
hydroxide,
(D)
TSP, (U) Unpreserved, (0)
Other = de f �'�, 3
Analyses
Lab Pr e I e:
Bi-Monthly Residuals
Y
County/City:
State: Count Ci Time Zone Collected:
Lab Sample Receipt Checklist:
Custody Seals Present/Intact Y N X-11
Custody Signatures Present y N �A
/ [ ]PT [ ]MT [ ]CT [ ]FT
Site/Facility ID #:
Compliance Monitoring?
252-33S-2196
[ ] Yes [ ] No
Collector Signature Present N NA
Bottles Intact N NA
Correct Bottles Ilt N NA
Cal cted By (prin1� r
Purchase Order # :
DW PWS ID #:
Quote M
DW Location Code:
k
F
_
O
Sufficient volume }' N NA
Samples Received on Ice k N NA
By
Turnaround
Collected (sign r
Date Required:
Immediately Packed on Ice:
VOA — Headspace
[ ] Yes [ ] No
Q
Zm
`
Acceptable Y N/
USDA Regulated Soils Y %A
Sample Disposal:
Rush:
Field Filtered (if applicable):
V�
0
Cii
Caf`
Samples in Holding Time NA
[ ] Dispose as appropriate [ ] Return
[ ] Same Day [ ] Next Day
[ ] Yes [ ] No
2
Q
3
Residual Chlorine Present Y N�
[ ]Archive:
2 [ Da 3 Da A Da 5 Da
] Y [ ] Y [ ] Y [ ] Y
2
Cl Strips: /
] ]�O€d'
(Expedite Charges Apply)
Analysis:
C3
Q
crj
Z
J
2
Sample pH Acceptable Y N jrA
pH Strips:
Sulfide Present Y N
" Matr€x Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (PI, Soil/Solid (SL), oil (OL),
Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
W
Q
W
p
(�
Lead Acetate Strips:
>1
cV
¢
V)
J
0
W
LAB USE ONLY:
Comp/
Collected
Composite End
Res
#of
Customer Sample ID
Matrix `
Grab
Composite Start)
Cl
Ctns
t0
J
�
r
Lab Sample # / Comments:
Date
Time
Date
Time
4
D
0
T
U
Cr-
f�
PT, 1G�Gv
c
&I
ff Z)el
)
I
X
X
X
X
Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: 10 Blue Dry None
Packing Material Used:
Radchem sample(s) screened (<500 cpm): Y N NA
Relinouish�y/Co man : (5' nature} Date/Time: ReCeiv Com any: (Signature)
(� - G i 1 i
Relinquished by/Comps y: (Signature) Date/Time: Received by/Company: (5ignature)
IRT HOLDS PRESENT (<72 hours) : Y,,,< N/A
Tracking N:
pies r eived via:
X UPS Client
Courier Pace Courier
Date/Time:
I MTJL LAB USE ONLY
3'fz711
Table #:
Date/Time:
Acctnum:
Sample Temperature info:
p Blank Received- Y-
rm I DN : >r
ter 1 Temp Upon Receipt, /.roC
ter 1 Therm Corr- Factor: oC
I.er 1 Corrected Temp: C
vents:
Trip Blank Received: Y NA
HCL McOH TSP Other
Pre:
Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: PM: { 1 Non Conformance(s): Page:
PS: f' ,�� 2_ ��,(jj YES / NO Of:_�

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: RESAMPLE NO2/NO3
Pace Project No.: 92422280
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WATER PLANT Lab ID: 92422280001 Collected: 03/20/19 14:11 Received: 03/21/19 10:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
93.5 %
0.10 1
03/25/19 12:50
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24
Nitrogen, Nitrate
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24 14797-55-8
Nitrogen, Nitrite
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24 14797-65-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/29/2019 10:41 AM without the written consent of Pace Analytical Services, LLC.
Page 4 of 9

Wok : 924222s0
CD
�' a$r>�seoii r= ► r1 ?e ���III 1�� lll�l I4
40s1DMOftt'' ,_ _
CHAIN=OF-CUSTODY-Arrarcal Re ncli2280
.�
aceAnal Iea!' .."'
awe '✓ � a :y �"» �Y
�..�,���' --x� ~�- r � �.•.��.u= "„�,' r - � :.
:•_ .:l'••;,''��-. �:�q;i' 1(-Qix';s4'' �s� '+`�"r- -�!k"° `.�!
LEGAL DOCUMENT II r 1 vent fi Id
Chain-of-Custod is a T- Complete a e e e s'Y•,y
Y = �F' -
.K
$ .z
AE. ;,�s4. •iit�' x- <"s�Y.:4 � �r...,v .rec,-" «ate
s':�i'sa'cN "._�'+'. w;;.%..�r.::t i:p .� uz �"•_.z.-"'a-7�s-•;,. ..::i•... �i:��-,-_i�S'`:.._
�. a:,�• ; �' "f(ll��`.���$ �, '•.••'�., 'a�=��.-+'
-�� i� �-s -
n ar _ .:r: • -�r� �,:r'-•--- t -i _- ,�.. -. r.M.:.+r,.. . <:_.:.���-:::� e..a _
n,.
Elizabeth City
BIIUn InformaTlon• ...�,.a#�
g ..,
9.�'.:r'."
1 Wilson StContainer
Lab ro
ContainerPreservabueType P 1
� '��[• -�} ° ��� �� � *£��- �r - -
Travis -tucker
ttueker GI flfEC.GOR) �-
eTypex (1) nitric acid, (2) sulfuric acid (M hydrochloric ac , (4) sodium hydroxide, (5) zinc acefatw
`• Prmern
(r)mctha
,(7) sodium blsulf2ae,(8)mSmmthioudfate,(9)hexane,(Al (B)ammrniim sulfate,
Raymond Staten
Site Collection ininJAddrt:ss:
(C) ammeni
im hydroxide, (D)TSP, tU) Unp, r Rrved, (0) Other
r,.
Analyses
v:-
tiFr:=
� '
iati Prafile?Pis�
fS�mpltr5�ec�apt; �secSc3ist -�` :f
�§
RESAMPLE NO2JN03 Bi-rnon:hy Res Sludge
Elizabeth City, NC 27907
- {�
�,•,`
:."-.''nstod.`a`i9�aitVresA�Rri'-f,'2F-
^k�
l YPa l�
(252)335-21S6
Site/Facility(€? M.
Compliance Monitoring? .. 7., .
[ 1 Yes ( ]No
r
?s
ti +
�"=
lam.
Sa 1{38ntrQ-'t �'. 37 N7t r
SasoFt2es A6GR'f.Y�Qri3A 'iCa'=:,;yi Dr. HA'
Col cteri By riM :
Purchase Order
Quote it:
DW PWS ID p:
t'
]W Location Code:
PL
Packed Ice:
Collect _By (signature):
TumaroUnd Date Required:
Immediately on
I Yes [ } No ;
:
....
UP -
.:�i,�
�;
o�
a. •,
USAA,_R�4qur. gted-irS-�31
3_'-+.•c':•,.
Rush:
d if
Field Fikere ('applicable):r'
Sample Disposal:
r:
`
RC.?dua� Gb?'azi'aw-Frastr?'�i,,,,r-�.?s
( ]C3lspwcas aPProPr,a]e [ ]ReUsrn
[ ]Sa me Day ) ]Next Day
(jyes t ]No
•';
'r3':•'_
I ] Archive:
a 3 D 4 Da 5 Da
[ ) Y [ ) Cary
'�,1c
Y�,Y.+:3
y
•="•
k--
crap a Snra z�
( ]Hold:
(apedlie Cha rges Apply}
Anal is: '-�
ys .:...
_.:_w
Via.
s?e�
-. .. -
''S"�
...
3.
• A: C. }�_r•�";:a'
"Matrix Codes (Insert in Matrix bDx below): Drinking Water (DVO), Ground Water (GWI, Wastewater'�n"•�
£��
Pmduct (P), Soil/Solid (SL), Oil (OIL), Wipe JWP), Air (AR), Tissue (TS), Bioassay (R), Vapor (V), Other (OT) Q
Ni,
rts`-'�:.
F
,
:
ui
�'
�'•si
"'�,�
ItixCt>spt��n�r
7.gad-.tL'v>eta�.te,,,,Stripsc*k•4is.. H',.� �
-'•t75 ONL'l - has vt,,
�'
"
Comp/
C�Ierted(or
Composite End
Res
trof
Customer5ample lD
Matrix
Grab
Campositc:Start)
CI
GrsS �t�'�
-'tiS1F,
'^
-.
Yr
�w,•a, ,,ry �_
Date
Time
Date
Time
-
��.,,�
',s
5'"
.ac-
_r,'"r, e•E'�'r . ''�- r �..:•s't� �-
1
ti
.., .!
'� '.
r^•Y;',:,
r+x'"'R3F"'�'�44��.^y'� �:"':..� p.y,."h?� rMrx-
's'
�'
t�
.'�
' S
sr?:-,
3 _
_�.'�y2� 17�'.i+�:%a::.i`'- ,i�:,, r t�•'" :i�i:.
A� nXJ'�.:i'.i7'-
a•yw+.;,'k,'riiSarM
M.
'�.
y..
44ra >.r , , -:j-rir'
# a'_
� 1--`
r`�
'1YY.:� ��'vwiiYia�:::
i.-�''��x
! v..
�.
M
1.:,��A:�+
:1".T.~.,�T., i}A f'.YR�tr^��..•+"ia"%„Ydp'.
:ei.�.'.':
�`.SM"•
-
.2ki.
w4•
i��G
�.e �a?�"6:� :wayy:��.��f�r-,iK,�'�+,.es.+�ar,Y,R,Maii u•-:..•Ch •vN'..i
-,y�'_•+i':i3.`�:S�i'-TL��_
w S✓:.C�':
L-
.Y.+_•
v>�w�i,'hw xti�iiu _ Y74",.�.`.i 5' •rch
Customer Remarks. /Spccialrenditions/ Possible Hazards: T.�'.$oF:�ce:lied'••-�'•-:Vr� rBllie�"�`•� �r,��T�l%�r.;�':-z
O_R'PiiOl`USPAFSENT�('�`� Ar�:'.a?�.�,;��e_-,. .te#ii(o�?= _,.
p ., OI �e '�, .. %i;�'s •. �i' .;,.�'si:i. .. �"
ul.*
b•'jrd ng3t 5 W . -'psi' �� �..�-3���' '�rei�a' 3 ` .7.r'a',r_nrc.�'�� �..
�••').•�,.S '� •�l.e
-}'�ba,,. r-`"r~a�C
- ..=s��;�"�•�ka_: �...,rr.+3a.
:`. C.£r'1� �t rr�r_'..�r Q.. ,!v.9
rr
O1r;T��.�•x a•.iilabe�....
:�.. +.... ..
� l :a EE" 9 v
_ ::J{ _ ..•�WF�Jt �.u�.:.,w�. �' -,y, ��5�ra.
�rr..,E,,. T,'s rh - •a� •,"wa'a ^�S, t'v.':t si '. :xj
ti.ss rl �.�. yy 'ri:p,i(�^y��du� .x
({idC leElt`SriT:1 S i
J T' Tb". I��
R r' 4 ' ..
_,.
--�.ti.: '-.:i::;.^.r�c7�''rxi :vtzr_...' C.00 „• iy t. B. :'COL•C:^. ory-
CS"Ta'[�NE� Yfd-4`yts, ' 'T=':S'"s' i4Y_' •W z-, rv.;�x'.a�`.�>. '
1' 3 F [v ✓'L''L c�i.�'T.".r h "1a:�+•.•.'3 CorJ3'tw°�EedE 'lest 4C
-,_.
c"'.cler
r,.,.-0 t r r •Yx �
:'-i, h r",fii:.<r-r ..,.i +. u.-�.._-----� :. �,...
�EQh - P$°�,-..�
'�,Pw
,,.,:_ t';F .,�__ .p r CrO�OnY$ -'� r i
..t.-:,�:.�C' - --
ur Dal ime: Received ...Coma(Signature)rrt1e:
Relin u'�shed by/C p . {S�g e� Date/Time: h1r p n7�
.=e•
G'Gc 1� 1Ut
fD TaGle.#'^.,.:
'
R in i hed Corn Si nature Dateffirne:
cl Vu s byl Y� f g )
Received /Com ny-. (Signat re}
by
Dot ime:
!Y¢:i inlY.;k.T - '"�"
�'�-�
F' -.,
ram^: .�:: s • `, .; .
R re
Pager
Relinquished by/Company: (Signature) Date/Time:
Received by/Company: (Signature]
DateNme:
Pliilc =>'•. e.,`x.zta:;gr:

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 5/14/2019
Solids 21.6
Mineralization Rate 0
Gallons per DT 1,110.22
pH 10.02
Sodium Absorpotion 0.35 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 193 lbs./1,000 gal 0.35
Ammonia Nitrogen (mg/Kg) 35.10 lbs./1,000 gal 0.06
Nitrate -Nitrite (mg/Kg) 18.30 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 36 lbs./1,000 gal 0.06
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 53 lbs./1,000 gal 0.10
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.25
Phosphorus lbs./1,000 gal 0.46
Calcium lbs./1,000 gal 354.88
Magnesium lbs./1,000 gal 15.01
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.25
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.30
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.20
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.20
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
2.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.50
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
193
36 0.07
157
193
53 0.11
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 36 0.07
Total 53 0.11

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92429276
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water -Plant Sludge Lab ID: 92429276001 Collected: 05/14/19 13:15 Received: 05/15/19 10:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 05/29/2019 05:58 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
7730
mg/kg
24.9
1
05/28/19 16:47
05/29/19 03:25
7429-90-5
M1
ND
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7440-38-2
ND
mg/kg
0.25
1
05/28/19 16:47
05/29/19 03:25
7440-43-9
197000
mg/kg
249
10
05/28/19 16:47
05/29/1915:07
7440-70-2
M6
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-47-3
1.3
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-50-8
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7439-92-1
8330
mg/kg
24.9
1
05/28/19 16:47
05/29/19 03:25
7439-95-4
M1
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7439-98-7
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-02-0
ND
mg/kg
1250
1
05/28/19 16:47
05/29/19 03:25
7440-09-7
ND
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7782-49-2
ND
mg/kg
1250
1
05/28/19 16:47
05/29/19 03:25
7440-23-5
2.5
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7440-66-6
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
ND
mg/kg
0.014
1
05/16/1915:42
05/17/1910:56
7439-97-6
Analytical Method: SM 254OG-2011
21.6
%
0.10
1
05/16/1914:26
Analytical Method: ASTM D2974-87
78.4
%
0.10
1
05/16/1914:18
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation
Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
35.1
1
05/21/19 07:56
05/21/19 15:16
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
193
1
05/19/1915:08
05/20/1913:23
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
14797-55-8
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
254
mg/kg
4.2
1
05/21/19 18:11
05/21/19 22:31
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
523
mg/kg
92.3
2
05/17/19 21:45
05/17/19 23:44
16887-00-6
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
210
mg/kg
49.7
1
05/20/19 11:43
05/21/19 21:46
14808-79-8
M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 17

CHAIN -Of -CUSTODY Analytical Request Document
aceAnalX cal
Chain-of-CuStodyis a LEGAL DOCUMENT - Complete all relevent fields
City of Elizabeth CityRillIn& Information:
1 Wilson St.
Elizabeth Ciry, NC 279D9 ttt1C[Cer C OtE'C,COfTi
rRAVIS TUCKER
Site Collection Info/Address:
BrMonthly Residuals
State: County/City: Time Zone Collected:
/ [ ]PT I IMT I ]Cf [ ]ET
252-337-6626
Site/Facility ID #:
Compliance Manitaring7
[ ] Yes [ ] Nb
Collected By (print):
� �-'
Purchase Order#:
DIN PW51D #:
S c r
Quote 9:
DW tocateon Code:
Co (sligDatwel.
Turnaround Date Required:
immediately Packed on ice-
Sample Disposal:
Rush:
[ ) Yes [ ] No
[ ] Disposeas appropriate [ ] Rh Wrr
[ ] Same Day [ ] NCxt Day
Field Filtered {if applicable):
] ]Yes [ ] No
[ ] Archive:
[ ] Hold:
I ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
(Expedite Charges Apply]
Analysis:
" Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water {GW), Wastewater (WW),
Product (P), Soil/Solid (5L), Oil (OL), Wipe (WP), Air [AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
Customer Sample ID
Matrix •
Comp /
Grab
Collected (or
Composite Start)
Composite End
Res
# of
Cl
Ctns
Date
Time
Date
Time
SL
S
6
Customer Remarks / Special Conditions / Possible Hazards:
f5
a Relinquished by/Company: (Signature) t]ate/71me:
tv
0
by/Company. (Signature}
el'�,•
A� t��L•WO#:.. 92429276
Y_iS<tl{1 u1�'.4;5)1'iIi1G:�l 1 III
ContainerPreseryativeType"'•
U g2429276
nIl f cic13T,j' U 5;:.NU U wa r
.�11 �!1134t1h,
••,Preservative Types; (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, ) sodium hydroxide, (5) zinc acetate, _
(6) methanol, (7) sodium bisuffate, (a) sodium thiowl(atc, (9) hexane, (Aj a or c1, ooLum sulfate,
(C] ammonium hydroxide, (D) 7SP, (U) Unpreserved, (0) Other
Analyses `l , -4a •.:�a
Jal
k X
O
Q ar if
Oy li -i .,� M-}ice q Nl'h�
nIIII ' 1 :Iy!Fir,
LU
tLb
La �i�!�h �n& ♦— 4t3. �
"..I. X etiil X ! , iiL X
1 VOL,
0.

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 7/15/2019
Solids 28.4
Mineralization Rate 0
Gallons per DT 844.39
pH 9.79
Sodium Absorpotion 0.82 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 160 lbs./1,000 gal 0.38
Ammonia Nitrogen (mg/Kg) 32.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 13.90 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 30 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 46 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.67
Phosphorus lbs./1,000 gal 0.54
Calcium lbs./1,000 gal 171.25
Magnesium lbs./1,000 gal 7.56
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.10
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.31
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.50
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.50
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.10
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.10
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
160
30 0.06
130
160
46 0.09
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 30 0.06
Total 46 0.09

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Bi-Monthly Residuals 07-15-19
Pace Project No.: 92436946
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92436946001 Collected: 07/15/19 13:20 Received: 07/16/19 10:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
Date: 07/30/2019 05:01 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
3070
mg/kg
30.9
1 07/29/1916:50
07/29/1919:55
7429-90-5
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7440-38-2
ND
mg/kg
0.31
1 07/29/1916:50
07/29/1919:55
7440-43-9
72300
mg/kg
155
5 07/29/1916:50
07/30/1912:45
7440-70-2 M1
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-47-3
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-50-8
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7439-92-1
3190
mg/kg
30.9
1 07/29/1916:50
07/29/1919:55
7439-95-4
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7439-98-7
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-02-0
ND
mg/kg
1550
1 07/29/1916:50
07/29/1919:55
7440-09-7
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7782-49-2
ND
mg/kg
1550
1 07/29/1916:50
07/29/1919:55
7440-23-5
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7440-66-6
Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
ND
mg/kg
0.0098
1 07/24/19 08:59
07/24/19 11:18
7439-97-6
Analytical Method: SM 254OG-2011
28.4
%
0.10
1
07/17/1918:23
Analytical Method: ASTM D2974-87
71.6
%
0.10
1
07/17/1918:16
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
32.0
1 07/18/19 07:18
07/18/19 12:28
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
160
1 07/23/19 05:17
07/25/19 03:35
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
14797-55-8
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
228
mg/kg
3.0
1 07/18/19 19:08
07/18/19 22:39
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
149
mg/kg
34.8
1 07/29/19 17:00
07/29/19 20:22
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 16

WO#:92436946
CHAIN -OF -CUSTODY Analytical Request u�i.. o.. VIM -.tier Ini fill
1111111111
y est RocumeRt b l � i�d;�li±l: �}[ l
aceAnalyticaf ,:. �., 92436948
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fietds )y: ;: -: I� f
City of Elizabeth City Ulllltaµ. 7-1
'Pk Billin Information: a [g[)1�1)1$ilU[ffg ':11 ivil,tl!`� Vt�ISi w,lsan St.0
1 6 �li4 ihrsiryair.I: :(d'Xr r+ i rn]u1+FdAmr
Container Preservative Type" I' F ' °,, u t' !s
Elizabeth aty, NC z7sas kllt)i'i' u „it ii u u l Is le �i6 � i� [ I "`>�'�f� +, � ni I i flu*�
#fuckeralcityofec-com ,k[ �, 9 K�illll�!�
" Pr arvative Types: 11) nhric add, (2) sulfuric acid, (3) hydrochloric acid, 44) sodium hydroxide, (5] zinc acetate,
TRAVISTUCKER Site Collection Info/Address {e} m harrol, (?) sodium bisulfate, !$) sodium ihiosulfate, (9) hexane, (a] asc e,
(C) am nium hydroxide, ID) TSP, (U) Unpreserved, (al,other 7 [ 6
Analyses
Bi-MonthlyResiduals State: County/City: Time Zone Collected: "64
+•' n nnIMuFLU' iN
lr,i, y ii: iliSxM@d1}wd a'q,
ON
Site/Facility ID #: Compl lance Monitoring? I I >:=
252-337-6626 [ igii+l�Fj�Yi+
f,i yl>,syzw N`
[ ] Y� I ] No IP,II .~' ( li"tmP
CoNected 8y (printer- Purchase Order # : DW PWS ID ti: +, tl+.:.',:+ ntl ��VA11
r I - Iprtririll Uli�[i�
rijiH 1x luif, i4xin! _. I
❑WLoptlonCode: ' II f , �, 4 p P101�. SG4£Firelph ht Iv_F S�e'M'S4 luh [
ut [.,. .... C.a r
Co lest Igna 7esrnaround Date Required; Immedlately Patked on Ice: ,� a( i I�IIII
.... ( ] Yes [ No 4 �is+fa ltl7flpN![ k�: n 4 Ilffl,r d�l[Fd_: k'
ww iAF+#)!il
Sample sposal: Rush: Field Filtered (if applicable ' ur�s���I�"'
( )Dispose as apPrnPriafr [ )Return [ ]Same Day ) ]Next Day [ ]Yes [ I No '' r'M' 1{(ldllit4 -Itn ' Ih+I; $ems ar '•. y.. - uFlH
I ] Ardilve: [ ] 2 Day [ 1 3 Day [ ] b Day [ ] 5 Day
[ }Hold: (Expedite thagesApply) Analysis_ M co
i I C3 f +3 t P
' Matrix Codes {Insert In Matrix box below): Drinking Water OWL Ground Water G 0
} ng { ( W), Wastewater ni 2+�I K I ^
Product (P), Soil/Soild (51.), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), BioassayB , Va or �� ,I L �� O rt C7 A J Lead. hcb atelf 19 3 iIl e lj r ill
(} P M, Other q � _ I�l�I � _` s r ! •,
I Q)--d;� 4 ) lh "{,MI rri FI `� +:'aE -�„ .t�h.k� kith;:
Comp/ Collected Res #of J '<L''
Composite End
Customer5omplelD Matrix Grab Composite Start) CI Ctns
❑ate Time Date Time O �:S<:[ri.�?`I ? '`ill 1, Ijr; • r: au,h,,,;..1� , I I r
1 5L ,`
5YE�� X i:.._ X ilk X ,�I,il
Customer Remarks / SpeclaI Canditrons / Possible Hazards:
Relinquished by/ ompany:
p Relinquished by/Company-
m
0
rn
DatefFime:
by/Company: (Signature) oatejr me.
Page:

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 9/17/2019
Solids 28.6
Mineralization Rate 0
Gallons per DT 838.49
pH 9.37
Sodium Absorpotion 0.47 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 205 lbs./1,000 gal 0.49
Ammonia Nitrogen (mg/Kg) 33.60 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 13.80 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 31 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 47 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.79
Phosphorus lbs./1,000 gal 0.43
Calcium lbs./1,000 gal 539.06
Magnesium lbs./1,000 gal 25.52
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.20
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.32
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.60
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.20
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.20
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
205
31 0.06
174
205
47 0.09
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 31 0.06
Total 47 0.09

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: BI MONTHLY RESIDUALS
Pace Project No.: 92446061
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WATER PLANT SLUDGE Lab ID: 92446061001 Collected: 09/17/19 13:48 Received: 09/18/19 10:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
9770 mg/kg
31.8
1 09/23/19 11:35
09/25/19 04:45
7429-90-5
Arsenic
ND mg/kg
3.2
1 09/23/19 11:35
09/25/19 04:45
7440-38-2
Cadmium
ND mg/kg
0.32
1 09/23/19 11:35
09/25/19 04:45
7440-43-9
Calcium
226000 mg/kg
318
10 09/23/19 11:35
09/25/1914:40
7440-70-2
Chromium
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-47-3
Copper
1.6 mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-50-8
Lead
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7439-92-1
Magnesium
10700 mg/kg
31.8
1 09/23/19 11:35
09/25/19 04:45
7439-95-4
Molybdenum
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7439-98-7
Nickel
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-02-0
Potassium
ND mg/kg
1590
1 09/23/19 11:35
09/25/19 04:45
7440-09-7
Selenium
ND mg/kg
3.2
1 09/23/19 11:35
09/25/19 04:45
7782-49-2
Sodium
ND mg/kg
1590
1 09/23/19 11:35
09/25/19 04:45
7440-23-5
Zinc
ND mg/kg
3.2
1 09/23/19 11:35
09/25/1915:04
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
ND mg/kg
0.0064
1 09/19/1912:30
09/19/1914:17
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
28.6 %
0.10
1
09/19/19 17:14
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
71.4 %
0.10
1
09/19/19 17:11
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
ND mg/kg
33.6
1 09/18/19 23:45
09/19/19 21:44
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
205 mg/kg
116
1 09/24/19 02:28
09/25/19 03:38
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
Nitrogen, Nitrate
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
14797-55-8
Nitrogen, Nitrite
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
180 mg/kg
3.5
1 09/20/19 19:11
09/23/19 21:12
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
209 mg/kg
34.8
1 09/30/19 15:19
09/30/19 20:16
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
Sulfate
0.068 % (w/w)
0.017
1 09/23/19 15:30
09/23/19 19:50
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/01/2019 09:58 AM without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

WO# : 92446061
��, II ! III
I I!lIII I IIIII !II
CHAIN -CIF -CUSTODY Analyticalq Request Document
eArlalytical'
'f 7 92446061
Chain-aF{uatody Is LEGAL DOCUMENT -Complete a[I rclevent fields
y -b
CRyofEJizabethCity
Milinglnftxmatlon:
I Wilson St.
M
••
CorttalwPreservative Type
�riw't. ' -•''
Elizabeth City, NCX7909 -..
t{i1CkEr(O7CIt1lOfeC,COlp -
U _ U m �, U :M �n
•' Presmatira Yypes: (u nrt*ic and. (215vlfursea6d, (3] hydrochloric add. (a] sodium hydroxJdc 5
Isi mcch-1 nl s�lm hiWVt . (9) SWil lhj*Wtr ce. (91 I.n.�re.IA7 Iel am j'svttarv,
.
TRAVISTUCIffA
Site Collection Info/AGtlmss:
IQ ammonium hydrodde, (D)T5F, IU) Unpgserved, (0) Other
- .
BI-Monthty Residuals
State: County/Oty. Time2one Colleted:
- Analyses . - -
'� .-anti•
'
�F,, ,
q', Y-
'xl
Y
,,.-2'
ie"
_
•. `
❑: c �� cp''
I IPT I IMT { JCT ( JET
252-337-6H26
SJt+e/padlity 10 4;
Compliance Monitonng7
I ] Yes
Co
Purchase Order#:
➢W PWSID
Ouote* -
DW Lo©tinn Coda:n-
g;-
Callected By {si
'
umaround Date Requited:
Immediately Packed on_Ice:�?
I ]yr. f ]Na t r:r%
`f9;
y.-..
O
d
sample Disposal: Rush: Flcld Piltnmd (If
alicahlep
pp
l ] oencsc as aporoprriace i ] neeum ( ] Same Day I ]Next Day J I yes -I i tvo$:,
..a
..
O
[ 1 Ardme: 1 12 Day I 13 DaY I 14Oay I 15 Day
'
[ ]Hold:
Expedite aes Analysis
Apply] Ot {rg
iy,;�
IH_.
III"
c*i
{!II
O
2�p VFIG
'Matrix Codes {insert In Matrix box below]: Drinking Water (OW), Ground Water (GWI, Wastewater W),
.,:
O
(W
I�"-
Product (P), SoR/5011d (stl, Oil (OL), Wipe (WPJ, Air {AR), Tissue rtS). Bioassay (BI. Vapor (V], Other (pT}
'.
-J
Customer Sam le to
Matrix •
Camp/
Grab
Collect djor
CornPaslte start]
Composite Fa+d
Res
#oF
p
Q
r3ns
v-
I
Z
Y
-.J
O
3.r,�'
Date
Time
Date
Time
--
-
r"
F-
h
%
❑
Marl`"
r
SL
C9
1
7
'y`.1,'-7
X
: `
X
V=2
}{ fA
A
t-
of
.l
RM
-
I
�''I_
'�p`
aiaf
IIfN
!i,1:,,R
TI.M.' p>91 .N. '
:l.1
IBM
W
,Aulilrl s t' iii,P�1!Jpqp,'^.�s' .:',4:�_�
'
I Ili
I
ah:i
f:Fppw
i �
lIl
„��
ME
- n
Customer Remarks Special Conditions/Possible Hazards: " �y 1, �, ryyr �1 s qJ�y�i I q "
'I�Norte � �4 d � l�F�l�f�%�ours°X�`z-�
r
�
1
! r
a :iii571 A` t77, dE1L5II9t _ ':`h� ''IYu',14'W , IWtI5FiII;�iipLtillk6'HIFEa
l:
�lri'���us°�yJ��'IR ty'i a
ilr� S- Y 0 :.;. r
IN, 19
Relinquished omPa :(Signature) i?ate/tlrsre. R��.ived�by/ #any.( gnatur Datefilme
. `r,' tt8gr Fr��G Ir•Jv
_'�fflr�i99,U'S�Q4LYJ.
I Cw
Relinquished by/Co ny: (Si urej
Date1nme:
R eived by/Company: ature
Daze rrre:
""" ' "'
'
Relinquished blr/Camparry: {Signature)
Oate/Time:
Received by/Company: (Signature)
Date/Time:
I,e(Vl. 1
"" n e s Page:
I 1 �
�2i
'�"h 'i'fiv�3!�_ 8��� xtP�'
d � I �Il:�iu',. 3.4a.•_�r .I, uF _
v
m
V
O
OD

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 11/5/2019
Solids 20.5
Mineralization Rate 0
Gallons per DT 1,169.80
pH 9.93
Sodium Absorpotion 0.42 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 195 lbs./1,000 gal 0.33
Ammonia Nitrogen (mg/Kg) 45.10 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 19.40 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 42 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 65 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.77
Phosphorus lbs./1,000 gal 0.23
Calcium lbs./1,000 gal 357.33
Magnesium lbs./1,000 gal 18.12
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.20
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.32
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.90
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.20
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.20
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
195
42 0.08
153
195
65 0.13
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 42 0.08
Total 65 0.13

(�Ia'cie Analytical
www.pacelabs.cem
ANALYTICAL RESULTS
Project: BiMonthly Res Sludge (11/5/19)
Pace Project No.: 92452481
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92452481001 Collected: 11/05/19 13:25 Received: 11/06/19 10:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
9240 mg/kg
32.5
1 11/13/1913:50
11/15/1911:07
7429-90-5
Arsenic
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7440-38-2
Cadmium
ND mg/kg
0.32
1 11/13/1913:50
11/15/1911:07
7440-43-9
Calcium
209000 mg/kg
325
10 11/13/1913:50
11/17/1919:31
7440-70-2
Chromium
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-47-3
Copper
1.9 mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-50-8
Lead
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7439-92-1
Magnesium
10600 mg/kg
32.5
1 11/13/1913:50
11/15/1911:07
7439-95-4
Molybdenum
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7439-98-7
Nickel
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-02-0
Potassium
ND mg/kg
1620
1 11/13/1913:50
11/15/1911:07
7440-09-7
Selenium
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7782-49-2
Sodium
ND mg/kg
1620
1 11/13/1913:50
11/15/1911:07
7440-23-5
Zinc
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
ND mg/kg
0.0090
1 11/11/1918:45
11/13/1915:02
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
20.5 %
0.10
1
11/07/19 15:09
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
79.5 %
0.10
1
11/07/19 14:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
ND mg/kg
45.1
1 11/12/19 16:15
11/12/19 22:32
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
ND mg/kg
195
1 11/14/19 04:48
11/15/19 06:49
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
Nitrogen, Nitrate
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
14797-55-8
Nitrogen, Nitrite
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
135 mg/kg
4.8
1 11/13/19 19:03
11/13/19 21:35
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
339 mg/kg
48.1
1 11/19/1917:30
11/19/1919:52
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
Sulfate
803 mg/kg
242
1 11/12/19 15:17
11/12/19 21:43
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /27/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

WOp:92452481
1111111111111111111111
V
O
OD

_ ;a'ne A nalytica(
www.paco;abs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 12, 2019
Travis Tucker
Elizabeth City
1 Wilson Street
Elizabeth City, NC 27909
RE: Project: TCLP SLUDGE
Pace Project No.: 92415518
Dear Travis Tucker:
Enclosed are the analytical results for sample(s) received by the laboratory on January 28, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
PwtvL
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Accounts Payable, City of Elizabeth City
Raymond Staten, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 25

aceAnalyfrcal
..pacelabs.com
i
Project: TCLP SLUDGE
Pace Project No.: 92415518
Atlanta Certification IDs
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 25

Pace Analytical Services, LLC
_ aceAnaly�rcal � 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
..pacelabs.com [phone]
i
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
TCLP SLUDGE
92415518
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92415518001
SLUDGE 5
ASTM D2974-87
AK1
1
PASI-PA
EPA 9014
PAS
1
PASI-PA
SM 4500S2F-00
PAS
1
PASI-PA
92415518002
SLUDGE 6
ASTM D2974-87
AK1
1
PASI-PA
EPA 1010
PJD
1
PASI-PA
EPA9045C
ZMH
1
PASI-PA
92415518003
SLUDGE 7
EPA 8260B
SAS
14
PASI-C
92415518004
SLUDGE 8
EPA 8270D
PKS
18
PASI-C
92415518005
SLUDGE 9
EPA 8081 B
SEM
9
PASI-C
92415518006
SLUDGE 10
EPA 8151A
MZP
3
PASI-GA
92415518007
SLUDGE 11
EPA 6010D
DS
7
PASI-A
EPA 7470A
RDT
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 25

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 5 Lab ID: 92415518001 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 75.0 % 0.10 1 02/07/19 11:59
733C S Reactive Cyanide Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive ND mg/kg 4.0 1 01/31/19 20:24 01/31/19 21:24
734S Reactive Sulfide Analytical Method: SM 4500S2F-00 Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive ND mg/kg 39.8 1 01/31/19 20:24 01/31/19 20:27
Sample: SLUDGE 6 Lab ID: 92415518002 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
73.3 % 0.10 1
02/07/19 11:59
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010
Flashpoint
>200 deg F 60.0 1
02/01/19 18:23
9045 pH Soil
Analytical Method: EPA 9045C
pH in water at 25 degrees C
9.1 Std. Units 2.0 1
01/30/19 21:23 H3
Sample: SLUDGE 7
Lab ID: 92415518003 Collected: 01/25/19 14:02
Received:
01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight"
basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qual
8260 MSV TCLP Analytical Method: EPA8260B Leachate Method/Date: EPA 1311; 01/31/19 08:19
Benzene
ND
ug/L
100
20
01/31/19 23:17
71-43-2
2-Butanone (MEK)
ND
ug/L
200
20
01/31/19 23:17
78-93-3
Carbon tetrachloride
ND
ug/L
100
20
01/31/19 23:17
56-23-5
Chlorobenzene
ND
ug/L
100
20
01/31/19 23:17
108-90-7
Chloroform
ND
ug/L
100
20
01/31/19 23:17
67-66-3
1,4-Dichlorobenzene
ND
ug/L
100
20
01/31/19 23:17
106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
01/31/19 23:17
107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
01/31/19 23:17
75-35-4
Tetrachloroethene
ND
ug/L
100
20
01/31/19 23:17
127-18-4
Trichloroethene
ND
ug/L
100
20
01/31/19 23:17
79-01-6
Vinyl chloride
ND
ug/L
100
20
01/31/19 23:17
75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
99
%
70-130
20
01/31/19 23:17
17060-07-0
Toluene-d8 (S)
103
%
67-135
20
01/31/19 23:17
2037-26-5
4-Bromofluorobenzene (S)
101
%
70-130
20
01/31/19 23:17
460-00-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM
without
the written consent of Pace Analytical Services, LLC.
Page 4 of 25

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 8 Lab ID: 92415518004 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-Methyl phenol(o-Cresol)
3&4-Methylphenol (m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/30/19 18:17
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
106-46-7
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
121-14-2
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
87-68-3
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
118-74-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
67-72-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
95-48-7
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
15831-10-4
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
98-95-3
ND
ug/L
100
1
02/04/19 08:39
02/04/19 18:07
87-86-5
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
110-86-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
95-95-4 M1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
88-06-2
51
%
12-102
1
02/04/19 08:39
02/04/19 18:07
4165-60-0
52
%
13-107
1
02/04/19 08:39
02/04/19 18:07
321-60-8
59
%
21-132
1
02/04/19 08:39
02/04/19 18:07
1718-51-0
19
%
10-110
1
02/04/19 08:39
02/04/19 18:07
13127-88-3
28
%
10-110
1
02/04/19 08:39
02/04/19 18:07
367-12-4
53
%
27-108
1
02/04/19 08:39
02/04/19 18:07
118-79-6
Sample: SLUDGE 9 Lab ID: 92415518005 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/30/19 18:17
gamma-BHC (Lindane)
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
58-89-9
Chlordane (Technical)
ND
ug/L
3.0
1
02/04/19 12:06
02/05/19 12:32
57-74-9
Endrin
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
72-20-8
Heptachlor
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
76-44-8
Heptachlor epoxide
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
1024-57-3
Methoxychlor
ND
ug/L
1000
1
02/04/19 12:06
02/05/19 12:32
72-43-5
Toxaphene
ND
ug/L
3.0
1
02/04/19 12:06
02/05/19 12:32
8001-35-2
Surrogates
Decachlorobiphenyl (S)
63
%
10-138
1
02/04/19 12:06
02/05/19 12:32
2051-24-3
Tetrachloro-m-xylene (S)
74
%
10-110
1
02/04/19 12:06
02/05/19 12:32
877-09-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
Page 5 of 25

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 10
Lab ID: 92415518006 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit DF Prepared Analyzed
CAS No. Qual
8151A Cl Acid Herbicides TCLP
Analytical Method: EPA 8151A Preparation Method: EPA 8151A
Leachate Method/Date: EPA 1311; 02/04/19 14:30 Initial pH: 9.68; Final pH: 5.05
2,4-D
ND mg/L 0.0050 1 02/07/1912:00 02/11/1914:09
94-75-7
2,4,5-TP (Silvex)
ND mg/L 0.010 1 02/07/19 12:00 02/11/19 14:09
93-72-1
Surrogates
2,4-DCAA(S)
134 %. 10-155 1 02/07/1912:00 02/11/1914:09
19719-28-9
Sample: SLUDGE 11 Lab ID: 92415518007 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP, TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/31/19 21:43 Initial pH: 10.19; Final pH: 5
Arsenic
ND mg/L 0.050 1 02/02/1917:57
02/03/1918:25
7440-38-2
Barium
0.48 mg/L 0.25 1 02/02/1917:57
02/03/1918:25
7440-39-3
Cadmium
ND mg/L 0.0050 1 02/02/1917:57
02/03/1918:25
7440-43-9
Chromium
ND mg/L 0.050 1 02/02/1917:57
02/03/1918:25
7440-47-3
Lead
ND mg/L 0.025 1 02/02/1917:57
02/03/1918:25
7439-92-1
Selenium
ND mg/L 0.10 1 02/02/1917:57
02/03/1918:25
7782-49-2
Silver
ND mg/L 0.025 1 02/02/1917:57
02/03/1918:25
7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/31/19 21:43 Initial pH: 10.19; Final pH: 5
Mercury
ND mg/L 0.00020 1 02/03/1918:13
02/05/1911:56
7439-97-6
Date: 02/12/2019 08:32 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455971
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92415518007
METHOD BLANK: 2486987
Matrix: Water
Associated Lab Samples: 92415518007
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
02/05/1911:28
METHOD BLANK: 2487426
Matrix: Water
Associated Lab Samples: 92415518007
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
02/05/1911:33
LABORATORY CONTROL SAMPLE: 2488275
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0025
99 80-120
LABORATORY CONTROL SAMPLE: 2489208
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0026
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2488276 2488277
MS MSD
92415888001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units
Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/L
ND
0.0025 0.0025 0.0026
0.0025 101 98 75-125 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455970 Analysis Method: EPA6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92415518007
METHOD BLANK: 2486987
Matrix:
Water
Associated Lab Samples: 92415518007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
02/03/1917:37
Barium
mg/L
ND
0.25
02/03/1917:37
Cadmium
mg/L
ND
0.0050
02/03/1917:37
Chromium
mg/L
ND
0.050
02/03/1917:37
Lead
mg/L
ND
0.025
02/03/1917:37
Selenium
mg/L
ND
0.10
02/03/1917:37
Silver
mg/L
ND
0.025
02/03/1917:37
METHOD BLANK: 2487426
Matrix:
Water
Associated Lab Samples: 92415518007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
02/03/1917:44
Barium
mg/L
ND
0.25
02/03/1917:44
Cadmium
mg/L
ND
0.0050
02/03/1917:44
Chromium
mg/L
ND
0.050
02/03/1917:44
Lead
mg/L
ND
0.025
02/03/1917:44
Selenium
mg/L
ND
0.10
02/03/1917:44
Silver
mg/L
ND
0.025
02/03/1917:44
LABORATORY CONTROL SAMPLE:
2488268
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Qualifiers
Spike
LCS
LCS
% Rec
Cone.
Result
% Rec
Limits Qualifiers
2.5
2.4
98
80-120
2.5
2.3
94
80-120
2.5
2.4
97
80-120
2.5
2.4
97
80-120
2.5
2.3
94
80-120
2.5
2.6
102
80-120
1.2
1.3
102
80-120
LABORATORY CONTROL SAMPLE: 2488269
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.4 96 80-120
Barium mg/L 2.5 2.4 96 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
Page 8 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2488269
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
Cadmium
mg/L
2.5
2.4
97
80-120
Chromium
mg/L
2.5
2.4
96
80-120
Lead
mg/L
2.5
2.4
95
80-120
Selenium
mg/L
2.5
2.6
103
80-120
Silver
mg/L
1.2
1.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2488270
2488271
MS
MSD
35444773001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
0.0141-1
2.5
2.5
2.4
2.4
96
96
75-125
0
Barium
mg/L
0.16J
2.5
2.5
2.5
2.5
95
95
75-125
1
Cadmium
mg/L
0.0025
2.5
2.5
2.4
2.4
97
97
75-125
0
U
Chromium
mg/L
0.012J
2.5
2.5
2.4
2.4
96
95
75-125
1
Lead
mg/L
0.091
2.5
2.5
2.4
2.4
93
93
75-125
0
Selenium
mg/L
0.0191-1
2.5
2.5
2.6
2.6
103
102
75-125
1
Silver
mg/L
0.00050
1.2
1.2
1.3
1.3
101
100
75-125
1
U
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455666
Analysis Method:
EPA 8260B
QC Batch Method: EPA 8260B
Analysis Description:
8260 MSV TCLP
Associated Lab Samples: 92415518003
METHOD BLANK: 2485805
Matrix: Water
Associated Lab Samples: 92415518003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
1,1-Dichloroethene
ug/L
ND
5.0
01/31/19 21:52
1,2-Dichloroethane
ug/L
ND
5.0
01/31/19 21:52
1,4-Dichlorobenzene
ug/L
ND
5.0
01/31/19 21:52
2-Butanone (MEK)
ug/L
ND
10.0
01/31/19 21:52
Benzene
ug/L
ND
5.0
01/31/19 21:52
Carbon tetrachloride
ug/L
ND
5.0
01/31/19 21:52
Chlorobenzene
ug/L
ND
5.0
01/31/19 21:52
Chloroform
ug/L
ND
5.0
01/31/19 21:52
Tetrachloroethene
ug/L
ND
5.0
01/31/19 21:52
Trichloroethene
ug/L
ND
5.0
01/31/19 21:52
Vinyl chloride
ug/L
ND
5.0
01/31/19 21:52
1,2-Dichloroethane-d4 (S)
%
97
70-130
01/31/19 21:52
4-Bromofluorobenzene (S)
%
98
70-130
01/31/19 21:52
Toluene-d8 (S)
%
104
67-135
01/31/19 21:52
LABORATORY CONTROL SAMPLE: 2486975
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
1,1-Dichloroethene
ug/L
50
49.8
100
70-130
1,2-Dichloroethane
ug/L
50
44.8
90
70-130
1,4-Dichlorobenzene
ug/L
50
46.9
94
70-130
2-Butanone (MEK)
ug/L
100
104
104
64-135
Benzene
ug/L
50
50.0
100
70-130
Carbon tetrachloride
ug/L
50
46.5
93
70-130
Chlorobenzene
ug/L
50
48.0
96
70-130
Chloroform
ug/L
50
45.4
91
70-130
Tetrachloroethene
ug/L
50
50.4
101
69-130
Trichloroethene
ug/L
50
50.1
100
70-130
Vinyl chloride
ug/L
50
49.3
99
70-131
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
96
67-135
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2486976
2486977
MS
MSD
92415497001
Spike
Spike
MS
MSD MS
MSD % Rec
Parameter Units
Result
Cone.
Cone.
Result
Result % Rec
% Rec Limits RPD Qual
1,1-Dichloroethene ug/L
ND
400
400
438
429 109 107 70-154 2
Results presented on this page are in the units indicated by the "Units"
column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2486976
2486977
MS
MSD
92415497001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
395
392
99
98
70-137
1
1,4-Dichlorobenzene
ug/L
ND
400
400
379
395
95
99
70-133
4
2-Butanone (MEK)
ug/L
ND
800
800
802
832
100
104
60-139
4
Benzene
ug/L
ND
400
400
413
438
103
109
70-151
6
Carbon tetrachloride
ug/L
ND
400
400
390
410
98
102
70-143
5
Chlorobenzene
ug/L
ND
400
400
399
408
100
102
70-138
2
Chloroform
ug/L
ND
400
400
399
393
97
95
70-139
2
Tetrachloroethene
ug/L
ND
400
400
418
426
105
107
59-143
2
Trichloroethene
ug/L
ND
400
400
413
433
103
108
70-147
5
Vinyl chloride
ug/L
ND
400
400
438
443
110
111
70-156
1
1,2-Dichloroethane-d4 (S)
%
101
96
70-130
4-Bromofluorobenzene (S)
%
100
102
70-130
Toluene-d8(S)
%
96
98
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 456164 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92415518005
METHOD BLANK: 2486200
Matrix:
Water
Associated Lab Samples: 92415518005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
02/05/19 13:23
Endrin
ug/L
ND
0.50
02/05/19 13:23
gamma-BHC (Lindane)
ug/L
ND
0.50
02/05/19 13:23
Heptachlor
ug/L
ND
0.50
02/05/19 13:23
Heptachlor epoxide
ug/L
ND
0.50
02/05/19 13:23
Methoxychlor
ug/L
ND
1000
02/05/19 13:23
Toxaphene
ug/L
ND
3.0
02/05/19 13:23
Decachlorobiphenyl (S)
%
75
10-138
02/05/19 13:23
Tetrachloro-m-xylene (S)
%
85
10-110
02/05/19 13:23
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2489041
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Endrin
ug/L
1.2
1.2
100
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.2
99
20-118
Heptachlor
ug/L
1.2
1.1
88
20-142
Heptachlor epoxide
ug/L
1.2
1.2
95
22-133
Methoxychlor
ug/L
3.8
ND
99
44-150
Decachlorobiphenyl (S)
%
71
10-138
Tetrachloro-m-xylene (S)
%
89
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2489042
2489043
MS
MSD
92415518005
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec % Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.1
1.2
91
93
21-133
3
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.3
1.2
102
97
24-119
5
Heptachlor
ug/L
ND
1.2
1.2
0.83
0.92
66
74
16-128
10
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.1
1.1
85
86
50-150
1
Methoxychlor
ug/L
ND
3.8
3.8
ND
ND
89
95
50-150
Decachlorobiphenyl (S)
%
58
54
10-138
Tetrachloro-m-xylene (S)
%
77
81
10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 22008
Analysis Method:
EPA 8151A
QC Batch Method: EPA 8151A
Analysis Description:
8151 GCS TCLP Herbicides
Associated Lab Samples: 92415518006
METHOD BLANK: 97873
Matrix:
Water
Associated Lab Samples: 92415518006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4,5-TP (Silvex)
mg/L
ND
0.010
02/11/19 11:33
2,4-D
mg/L
ND
0.0050
02/11/1911:33
2,4-DCAA(S)
%.
183
10-155
02/11/1911:33 S3
METHOD BLANK: 98319
Matrix:
Water
Associated Lab Samples: 92415518006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4,5-TP (Silvex)
mg/L
ND
0.010
02/11/19 12:18
2,4-D
mg/L
ND
0.0050
02/11/1912:18
2,4-DCAA(S)
%.
189
10-155
02/11/1912:18 S3
LABORATORY CONTROL SAMPLE: 99061
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
2,4,5-TP (Silvex)
mg/L
2
2.3
116 39-138
2,4-D
mg/L
2
2.2
110 29-145
2,4-DCAA (S)
%.
146 10-155
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
99062
99063
MS
MSD
2614376001
Spike
Spike MS MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc. Result Result
% Rec
% Rec
Limits RPD Qual
2,4,5-TP (Silvex)
mg/L
<0.010 2
2 2.6 2.5
131
125
10-156 5
2,4-D
mg/L
<0.0050 2
2 2.5 2.4
123
119
10-156 3
2,4-DCAA (S)
%.
150
143
10-155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 456109 Analysis Method: EPA 8270D
QC Batch Method: EPA 3510C Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92415518004
METHOD BLANK: 2486200
Associated Lab Samples: 92415518004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
02/04/19 17:03
2,4,5-Trichlorophenol
ug/L
ND
50.0
02/04/19 17:03
2,4,6-Trichlorophenol
ug/L
ND
50.0
02/04/19 17:03
2,4-Dinitrotoluene
ug/L
ND
50.0
02/04/19 17:03
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
02/04/19 17:03
3&4-Methylphenol (m&p Cresol)
ug/L
ND
50.0
02/04/19 17:03
Hexachloro-1,3-butadiene
ug/L
ND
50.0
02/04/19 17:03
Hexachlorobenzene
ug/L
ND
50.0
02/04/19 17:03
Hexachloroethane
ug/L
ND
50.0
02/04/19 17:03
Nitrobenzene
ug/L
ND
50.0
02/04/19 17:03
Pentachlorophenol
ug/L
ND
100
02/04/19 17:03
Pyridine
ug/L
ND
50.0
02/04/19 17:03
2,4,6-Tribromophenol (S)
%
68
27-108
02/04/19 17:03
2-Fluorobiphenyl (S)
%
59
13-107
02/04/19 17:03
2-Fluorophenol (S)
%
37
10-110
02/04/19 17:03
Nitrobenzene-d5 (S)
%
58
12-102
02/04/19 17:03
Phenol-d6 (S)
%
25
10-110
02/04/19 17:03
Terphenyl-d14 (S)
%
76
21-132
02/04/19 17:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2488769
Units
Spike
Conc.
1-CS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
234
47
30-130
2,4,5-Trichlorophenol
ug/L
500
232
46
40-130
2,4,6-Trichlorophenol
ug/L
500
245
49
40-130
2,4-Dinitrotoluene
ug/L
500
287
57
49-130
2-Methyl phenol(o-Cresol)
ug/L
500
192
38
30-130
3&4-MethyIphenol (m&p Cresol)
ug/L
500
174
35
20-130
Hexachloro-1,3-butadiene
ug/L
500
219
44
10-130
Hexachlorobenzene
ug/L
500
255
51
30-130
Hexachloroethane
ug/L
500
210
42
10-130
Nitrobenzene
ug/L
500
244
49
20-130
Pentachlorophenol
ug/L
1000
592
59
10-140
Pyridine
ug/L
500
79.9
16
10-130
2,4,6-Tribromophenol (S)
%
62
27-108
2-Fluorobiphenyl (S)
%
48
13-107
2-Fluorophenol(S)
%
31
10-110
Nitrobenzene-d5 (S)
%
50
12-102
Phenol-d6 (S)
%
21
10-110
Terphenyl-d14 (S)
%
72
21-132
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2488770
2488771
MS
MSD
92415518004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
192
210
38
42
30-130
9
2,4,5-Trichlorophenol
ug/L
ND
500
500
197
225
39
45
40-130
13 M1
2,4,6-Trichlorophenol
ug/L
ND
500
500
211
228
42
46
40-130
8
2,4-Dinitrotoluene
ug/L
ND
500
500
259
304
52
61
49-130
16
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
160
172
32
34
30-130
7
3&4-Methylphenol (m&p
ug/L
ND
500
500
139
151
28
30
20-130
8
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
187
190
37
38
10-130
1
Hexachlorobenzene
ug/L
ND
500
500
215
250
43
50
30-130
15
Hexachloroethane
ug/L
ND
500
500
176
188
35
38
10-130
7
Nitrobenzene
ug/L
ND
500
500
212
244
42
49
20-130
14
Pentachlorophenol
ug/L
ND
1000
1000
575
658
58
66
10-140
13
Pyridine
ug/L
ND
500
500
58.8
73.9
12
15
10-130
23
2,4,6-Tribromophenol (S)
%
53
60
27-108
2-Fluorobiphenyl (S)
%
40
45
13-107
2-Fluorophenol(S)
%
24
27
10-110
Nitrobenzene-d5 (S)
%
41
46
12-102
Phenol-d6 (S)
%
16
18
10-110
Terphenyl-d 14 (S)
%
63
76
21-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 329388 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92415518001, 92415518002
SAMPLE DUPLICATE: 1602618
30278290001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 1.8 1.8 2
SAMPLE DUPLICATE: 1602619
30278290003 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 46.4 46.1 1
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328824 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92415518002
METHOD BLANK: 1600114 Matrix: Water
Associated Lab Samples: 92415518002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Flashpoint deg F >200 60.0 02/01/19 16:08
SAMPLE DUPLICATE: 1600115
30278299001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
Page 17 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328618 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Associated Lab Samples: 92415518002
SAMPLE DUPLICATE: 1599229
Parameter
pH in water at 25 degrees C
30278210001 Dup
Units Result Result RPD Qualifiers
Std. Units 7.4 7.4 1 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328735
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92415518001
METHOD BLANK: 1599646
Matrix: Solid
Associated Lab Samples: 92415518001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND
1.0 01/31/19 21:15
LABORATORY CONTROL SAMPLE: 1599647
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
99.7 ND
0 0-8
SAMPLE DUPLICATE: 1599648
30278299001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328734
Analysis Method:
SM 4500S2F-00
QC Batch Method: SW-846 7.3.4.2
Analysis Description:
734S Reactive Sulfide
Associated Lab Samples: 92415518001
METHOD BLANK: 1599643
Matrix: Solid
Associated Lab Samples: 92415518001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND
10 01/31/19 20:27
LABORATORY CONTROL SAMPLE: 1599644
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
199 39.8
20 0-52
SAMPLE DUPLICATE: 1599645
30278299001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Sulfide, Reactive
mg/kg
ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALIFIERS
Project: TCLP SLUDGE
Pace Project No.: 92415518
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-C
Pace Analytical Services - Charlotte
PASI-GA
Pace Analytical Services - Atlanta, GA
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 25

aceAnalyfrcal
..pacelabs.com
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
TCLP SLUDGE
92415518
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92415518005
SLUDGE 9
EPA 3510C
456164
EPA 8081 B
456400
92415518006
SLUDGE 10
EPA 8151A
22008
EPA 8151A
22097
92415518007
SLUDGE 11
EPA 3010A
455970
EPA 6010D
456030
92415518007
SLUDGE 11
EPA 7470A
455971
EPA 7470A
456084
92415518004
SLUDGE 8
EPA 3510C
456109
EPA 8270D
456230
92415518003
SLUDGE 7
EPA 8260B
455666
92415518001
SLUDGE 5
ASTM D2974-87
329388
92415518002
SLUDGE 6
ASTM D2974-87
329388
92415518002
SLUDGE 6
EPA 1010
328824
92415518002
SLUDGE 6
EPA 9045C
328618
92415518001
SLUDGE 5
SW-846 7.3.3.2
328735
EPA 9014
328742
92415518001
SLUDGE 5
SW-846 7.3.4.2
328734
SM 4500S2F-00
328741
Date: 02/12/2019 08:32 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 25

Sa
Docurrrent Name: Document Revised: February 7, 2019
Document No.: issuing Autfaarity:
F-CAR-CS-033-RoMls Pace Caroflnas avarity off?co
lahnralefV receSt ng 9araPIGS:
AshouMe ❑ Eden Greenwood ® Huntertsville ® nalGj8h® RReehaei�svllee❑
Client Name: Project Wa# : 92415518
€lljxu�a„aT/k+
Courl©r: []FeCups U5P5 Client f �Jl� j J 111 l��j�l�� �1�
❑ Commercial ace ®Asher: 92413318
Custody Semi Present? ®Yes ;DNN seals intact? ®Yes ❑No
oatiOnlVals Person Emmlrsing Can¢enu; �1%
Packing Material- ❑Bubble Wrap Bags ne Other Biological Tissue Fraten?
Thermorneler: 6-To ®Yes []No gi A
❑IR Gun IF,� $ Tv"oPleo: Wet ❑Biva ❑Nee®
Cooler Temp 7 Correction Factor: Add/Subtract ('C} Qf
Temp should be above Freezing to fi`C
Cooler Temp Corrected (°C); 0. 7 Damples out of temp criteria. Samples on Ice, cooling process
hashegun
USDA Regulated5ail (2f M/A, grater sample)
Did samples or�iginate in a quarantine zone within the United States; CA, NY, or SC {check maps)? Did sa:npiesorigfnate from a Foreign source (internpopally,
[]Yes 05 a tacludlrg Hav+aii and Puerto Rico)? ❑Yes No
Chain of Custody Present?
es
❑No
❑NIA
11.
Sam les Arrived within flald T me?
Yes
ON.
❑N/A
?-
Short HOd Time Analysis (�72 hr.j?
❑Yes
ZN.
[]N/A
3,
Rush Turn Acaund Time Requested?
Dy.
Na
❑N/A
$.
Sufficient Volume?
es
❑No
❑N/A
5.
Correct Containers Used?
-PaceContainers. USed?
2res
RLs
❑No
QN.
❑N/A
❑NIA
5-
Containers Intact?
olrs
No
[JMIA
7.
M5soived analysis: Sam les Field Filtered?
❑Yes
0 Wo
❑N/A
8.
Sample Labels Match CCC7
-Includes Date/Time/ID/Analysis Matrhr:
P es
ON.
❑N/A
9.
Headspace in VOA Vials O5-6mm)?
❑Yes
❑Nn
N/A
Ia.
Trip ®lank Present?
Trip BlankCustodv Seals Present?
Dyes
r1yu
j]No
MNo
/A
t/A
11.
COMM EiNTSJSAMPLE DISCREPANCY
Lot 10 of split containers:
CLIENT NOTTFICATICIN/RF50LUTION
Person contacted: Date/Tirne:
Project Mamgor SCURF Review:
Project Martager SRF Review:
Field Data Required? ❑Yes []NO
Date: _ r `
Dote:-(/y Lq
Page 23 of 25

CHAIN -OF -CUSTODY 1 Analytical Request Document � ,�
U-CASLO
N
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. L O
_ _ aceAnalytical - /i
'-p c'Alb5 Co. N
r� / V 04
(1)
m
N
Section A
Section B
Section C
Required Client Information:
Required Project
Information:
Invoice Information:
En
of
Company: -�
II
R8, To:
r
Attentlon:
--,
Y
Address
�)
Copy To:
Company Name:
REGULATORY AGENCY
J-2,°% - /
Address:
f NPDES 7 GROUND WATER
r LIST {— RCRA
r
r
DRINKING WATER
OTHER
Email To: - I
u C C , E3c - :2-1
Purchase Order ND-:
Pace Quote
Reference:
Phpne; �ry /
ax:
P ect Na
y !
r C
Paco l G Pro e
IC �--5-
Site Location
_
- -
c1.
/ l+�
Manager
STATE:
-
Requested Due DaterrAT:
Project NumG
Pace Prnnle#:
Requested
Analysis
Filtered
(Y1
Section D Valid Matrix Codes
w
z
Required Client Information
MATRIX
cone
o
COLLECTED
Preservatives
>
-
DRINNING WATER
DW
Z
WATER
WASTEWATER
PRODUCT
WT
Y,M'
P
2
m
U
CO TART
START
COMPOSITE
ENDlGRAB
O
W
�
1 1
n
`
•'
SOIVScue
SL
�
�
OIL
OL
n
(7
p
N
-
(+)�✓)
SAMPLE ID
ARE
W
u
JtI
r
(A-Z, 0-9 1,-)
OTHER
CT
Q
W
6¢
Z
'�
V
IJ
J
Sample IDS MUST BE UNIQUE
TISSUE
Ts
p
a
w
m
v_l
.�
cam.
U
EL
CL
U]
O
O
to
w
°'
c
J
-�
s
--f
�]
w
v
1=
DATE
TIME
DATE
TIME
N
�
z
2
Z
Z
Z
20
U
4-�
v
I
�V
��
Pace
Project NoJ Lab I.U.
LJ i 1' i
S
STD
ie
3
X
k
2
r.PC�
X
s
1
`' I
L
X
4
S u.�
(
1
X
5
"
L
X
X
9
7 < 4
(.
..
1
(
X
,U
r-
f
x
X
ADDITIONAL-160MMENTS
RELINQUISHED BY I AFFILIATION
13ATE
TIME
CC ED BY I AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
C :
5T Vf
51
fz8>
/Z a
7
61
SAMPLER NAME AND SIGNATURE
C
o
m
`m
�
PRINT Name of SAMPLER:
I
z
SIGNATURE of SAMPLIEV:--�
DATE Signed
G
(MMlDDfYY}:
I
v
In
a
'Impodarrt Note: By signing this form you are accepting Paces NET 30 day payment terms and agreeing to late charges of 1.5% per month for any Invoices not paid within 30 days. F-ALL-Q-020rev.08, 12-Oct-2007

I Sa
Document Name:
Document No.:
F-CAR-cs-m-ta.v
°Ch(ach frfar(s toP half 56 bore if Ph �md/ar dech!®riroatleaa is
verlfir 0 Ead eoil4&air the accePtartce range for preservation
Sana�lt7�,
EimepUenA: VOA, CaIHArm, TOG flit and Grease, DROJEO15 {water} l7OC, LWg
"I' aRalin ba f of box is to fist number of bottle
oacument Revised-. February 7, 2010
Page I of 2
f5suing Authaffty:
Pare Cara)Ws QuON Office
Pro W0# : 92415518
PM: KPD Due Date: 02/11/19
CLIENT: 92-Elisabeth
I
13
e
]
a
J
a
®
C
]
4
1k
[
]
a
J
E
a.
n
A
S
_
a
4
J
s
`n
Z
n
J
E
yp�
rV
d.
m
o
¢
a,
J
E
�rt
r
a
as
a
J
e
ui
a
t7
e0
E
�'
v
`�
7~L
a�
a
S
=
r+
0
¢
a
E
Q
$
x
r+
l7
d
n
Q
s
a.
,V
V)
6
S
It
0
€
Q
ry
C1
$
�
Q
J
>:
o
ry
m
C7
Q
aE
¢
g
Ri
C7
Q
Z
E
l�
D
O
7
Bpi
Z.
J
n
i7
3
v
O
J
E
Chi
"
®
S
�
�:i
S!
d
S
a
N
E
�/j
Y-
a
A
`
a
N
1=
a
M\J
J
E
a
a
^J
E
L9
E
4
r7
In
7
G
E
a
q
C�
9
1
13
N
2
NNI\L
1,N
I
F
I
i
I
N
I
N
1,
N
.
I
�
'
N
I
=
I
,
N
i
6
7
g
9
10
11
G
I2
PH Ad)ustment Log for Presemed Samples --
sample iD
Type of Preservative
PH upon receipt
Date presarvatian adjusted
Time preservation
adjusted
Anwunt of Preservative
added
Lat fa
Nate W"rlever ltsere Is a disuepanry affecting Narth Carollna compllance samples, a copy or this rarm win t:e mrt to tnarvorm larouna ucnnn Lerraicanon UrslCe p.a.
Out of hold, incorrect preservatlue, out at temp, incorrect containers.
Page 25 of 25

City of Elizabeth City
2019 Class B Annual Report
WQ Permit# WQ0002883
Land Application Field Summary Forms

PernutNumber WQ0002883
Facility Name City of Elizabeth City
LandOwner Lawrence Larabee
Operator
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Site# LL County Pasquotank Crop 1 Wheat, Grain
Field Name 33 SoilSeries Pettigrew Crop 1 Pan 111
Acres Permited 22.37 Soil Abbrevation: PgA Crop 2
Crop 2 Pan
Volume
Acres
Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date
Measurement Applied
% Solids
Used DT/Ac. Tons
Source
Condition Precip
Method
P
Volatilization Mineralization
TKN
Ammonia -Nitrite PAN
PAN Crop
Jan. 2019
Gallons 208,000
21.60
22.37 8.38
187.35
Elizabeth City WTP
Moist 0
Surface
1.01
0.50 0
36
9.30 32.10 0.62
Crop 1
Jan. 2019
Gallons 97,500
4.70
22.37 0.85
19.11
Elizabeth City WWTP
Moist 0
Surface
27.34
0.50 0.3
51,100
989.00 83.00 26.67
Crop 1
Mar. 2019
Gallons 78,000
4.70
22.37 0.68
15.29
Elizabeth City WWTP
Moist 0
Surface
21.87
0.50 0.3
51,100
989.00 83.00 21.34
Crop 1
Total Volume Applied
383,500
Total Dry Tons 221.75
Sum Total P 50.21
Total 48.62
Total
Reported in Gallons
Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel
Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.047
0.008
0.743 0.087
0.069
0.001
0.025
0.059
0.043
2.375
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.081
0.015
1.854
0.215
0.004
0.070
0.099
0.070
5.752
Cumulative Total
0.128
0.023
2.597
0.284
0.005
0.095
0.158
0.113
8.127
Permitted CPLR
36
34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 34 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 19.88 Soil Abbrevation: PgA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization TKN Ammonia -Nitrite
PAN
PAN Crop
Feb. 2019 Gallons
253,500 21.60
19.88 11.49 228.33
Elizabeth City WTP
Moist 0
Surface
1.38
0.50
0 36
9.30 32.10
0.84
Crop 1
Feb. 2019 Gallons
175,500 4.70
19.88 1.73 34.40
Elizabeth City WWTP
Moist 0
Surface
55.37
0.50
0.3 51,100
989.00 83.00
54.02
Crop 1
Total Volume Applied
429,000
Total Dry Tons 262.73
Sum Total P
56.75
Total
54.86
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.059 0.010
0.943 0.104
0.081 0.002
0.031
0.073
0.055
2.684
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.081 0.015
1.854
0.215 0.004
0.070
0.099
0.070
5.752
Cumulative Total
0.140 0.025
2.697
0.296 0.006
0.101
0.172
0.125
8.436
Permitted CPLR
36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 35 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 20.26 Soil Abbrevation: PgA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization TKN Ammonia -Nitrite
PAN
PAN Crop
Feb. 2019 Gallons
149,500 21.60
20.26 6.65 134.66
Elizabeth City WTP
Moist 0
Surface
0.80
0.50
0 36
9.30 32.10
0.49
Crop 1
Feb. 2019 Gallons
221,000 4.70
20.26 2.14 43.31
Elizabeth City WWTP
Moist 0
Surface
68.41
0.50
0.3 51,100
989.00 83.00
66.75
Crop 1
Total Volume Applied
370,500
Total Dry Tons 177.97
Sum Total P
69.21
Total
67.24
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year
0.050 0.010
1.018 0.108
0.088 0.002
0.026
0.067
0.045
3.274
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year
0.081 0.015
1.854
0.215 0.004
0.070
0.099
0.070
5.752
Cumulative Total
0.131 0.025
2.872
0.303 0.006
0.096
0.166
0.115
9.026
Permitted CPLR
36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 36 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 20.31 Soil Abbrevation: PgA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
Mar. 2019 Gallons 292,500 4.70
20.31 2.82 57.33
Elizabeth
City WWTP
Moist 0
Surface
90.32
0.50
0.3 51,100
989.00 83.00 88.13
Crop 1
Total Volume Applied 292,500
Total Dry Tons 57.33
Sum Total P
90.32
Total 88.13
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.040 0.010
1.315 0.120
0.103
0.002
0.021
0.062
0.033
4.273
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 0.081 0.015
1.854
0.215
0.004
0.070
0.099
0.070
5.752
Cumulative Total 0.121 0.025
3.169
0.318
0.006
0.091
0.161
0.103
10.025
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# LL County Pasquotank Crop 1 Wheat, Grain
Facility Name City of Elizabeth City Field Name 37 SoilSeries Pettigrew Crop 1 Pan 111
LandOwner Lawrence Larabee Acres Permuted 18.33 Soil Abbrevation: PgA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
Mar. 2019 Gallons 247,000 4.70
18.33 2.64 48.41
Elizabeth
City WWTP
Moist 0
Surface
84.51
0.50
0.3 51,100
989.00 83.00 82.46
Crop 1
Total Volume Applied 247,000
Total Dry Tons 48.41
Sum Total P
84.51
Total 82.46
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.038 0.010
1.231 0.113
0.097
0.002
0.020
0.058
0.031
3.998
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 0.081 0.015
1.854
0.215
0.004
0.070
0.099
0.070
5.752
Cumulative Total 0.119 0.025
3.085
0.312
0.006
0.090
0.157
0.101
9.750
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 100 SoilSeries Wasda-Conaby Complex Crop 1 Pan 174
LandOwner W.B. Bateman Acres Permuted 11.63 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
Mar. 2019 Gallons 65,000 18.60
11.63 4.33 50.42
Elizabeth City WTP
Moist 0
Surface
2.90
0.50
0 224
48.10 60.60
0.73
Crop 1
Apr. 2019 Gallons 143,000 4.20
11.63 2.15 25.05
Elizabeth City WWTP
Moist 0
Surface
69.77
0.50
0.3 60,200
17,000.00 94.10
92.83
Crop 1
Total Volume Applied 208,000
Total Dry Tons 75.46
Sum Total P
72.67
Total
93.57
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.081 0.009
1.098 0.013
0.091 0.001
0.041
0.056
0.081
3.600
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.233 0.136
1.405
4.738 0.657
0.053
0.316
1.112
3.811
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 101 SoilSeries Wasda-Conaby Complex Crop 1 Pan 174
LandOwner W.B. Bateman Acres Permuted 11.64 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
Apr. 2019 Gallons 78,000 18.60
11.64 5.20 60.50
Elizabeth City WTP
Moist 0
Surface
3.47
0.50
0 224
48.10 60.60
0.88
Crop 1
Apr. 2019 Gallons 123,500 4.20
11.64 1.86 21.63
Elizabeth City WWTP
Moist 0
Surface
60.21
0.50
0.3 60,200
17,000.00 94.10
80.10
Crop 1
Total Volume Applied 201,500
Total Dry Tons 82.13
Sum Total P
63.68
Total
80.98
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.078 0.008
0.952 0.016
0.083 0.001
0.040
0.053
0.078
3.115
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.230 0.135
1.259
4.730 0.657
0.052
0.313
1.109
3.326
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 102 SoilSeries Wasda-Conaby Complex Crop 1 Pan 174
LandOwner W.B. Bateman Acres Permuted 11.70 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1 Crop 2
Date Measurement Applied
% Solids Used DT/Ac. Tons
Source
Condition Precip
Method
P Volatilization Mineralization
THIN Ammonia -Nitrite PAN PAN
May 2019 Gallons 65,000
21.60 11.70 5.00 58.55
Elizabeth City WTP
Moist 0
Surface
2.54 0.50 0
193 35.10 18.30 0.36
May 2019 Gallons 156,000
4.20 11.70 2.34 27.32
Elizabeth City WWTP
Moist 0
Surface
75.66 0.50 0.3
60,200 17,000.00 94.10 100.67
Total Volume Applied
221,000
Total Dry Tons 85.87
Reported in Gallons
Arsenic
Cadmium
Copper Chromium
Lead
Current Year
0.086
0.009
1.190 0.012
0.097
Prior Year
11.152
0.127
0.307
4.647
Cumulative Total
11.238
0.136
1.497
4.744
Permitted CPLR
36
34
1338
267
Mercury Molybdenum
0.001 0.042
0.656 0.012
0.657 0.054
15
Sum Total P 78.20
Nickel
Selenium
Zinc
0.059
0.086
3.901
0.260
1.031
0.211
0.319
1.117
4.112
374
89
2498
Total 101.03
Crop 1
PAN
(lbs./Ac.)
Lime (T/Ac.) Date
Crop
Crop 1
Crop 1
Total
Crop 2
PAN
(lbs./Ac.)
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Perm itNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 103 SoilSeries Belhaven Crop 1 Pan 169
LandOwner W.B. Bateman Acres Permuted 11.59 Soil Abbrevation: BcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
May 2019 Gallons 58,500 21.60
11.59 4.55 52.69
Elizabeth City WTP
Moist 0
Surface
2.31
0.50
0 193
35.10 18.30
0.33
Crop 1
May 2019 Gallons 156,000 4.20
11.59 2.36 27.32
Elizabeth City WWTP
Moist 0
Surface
76.38
0.50
0.3 60,200
17,000.00 94.10
101.62
Crop 1
Total Volume Applied 214,500
Total Dry Tons 80.01
Sum Total P
78.69
Total
101.95
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.084 0.009
1.200 0.011
0.096 0.001
0.042
0.058
0.084
3.936
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.236 0.136
1.507
4.743 0.657
0.054
0.318
1.115
4.147
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Perm itNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 104 SoilSeries Belhaven Crop 1 Pan 169
LandOwner W.B. Bateman Acres Permuted 11.94 Soil Abbrevation: BcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1 Crop 2
Date Measurement Applied
% Solids Used DT/Ac. Tons
Source
Condition Precip
Method
P Volatilization Mineralization
THIN Ammonia -Nitrite PAN PAN
May 2019 Gallons 72,500
21.60 11.94 5.47 65.30
Elizabeth City WTP
Moist 0
Surface
2.78 0.50 0
193 35.10 18.30 0.39
May 2019 Gallons 169,000
4.20 11.94 2.48 29.60
Elizabeth City WWTP
Moist 0
Surface
80.32 0.50 0.3
60,200 17,000.00 94.10 106.86
Total Volume Applied
241,500
Total Dry Tons 94.90
Reported in Gallons
Arsenic Cadmium
Copper Chromium
Lead
Current Year
0.092
0.010
1.264 0.013
0.103
Prior Year
11.152
0.127
0.307
4.647
Cumulative Total
11.244
0.137
1.571
4.750
Permitted CPLR
36
34
1338
267
Mercury Molybdenum
0.002 0.045
0.656 0.012
0.658 0.057
15
Sum Total P 83.10
Nickel
Selenium
Zinc
0.063
0.092
4.142
0.260
1.031
0.211
0.323
1.123
4.353
374
89
2498
Total 107.26
Crop 1
PAN
(lbs./Ac.)
Lime (T/Ac.) Date
Crop
Crop 1
Crop 1
Total
Crop 2
PAN
(lbs./Ac.)
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Perm itNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 105 SoilSeries Belhaven Crop 1 Pan 169
LandOwner W.B. Bateman Acres Permuted 11.82 Soil Abbrevation: BcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
May 2019 Gallons 65,000 21.60
11.82 4.95 58.55
Elizabeth City WTP
Moist 0
Surface
2.52
0.50
0 193
35.10 18.30
0.36
Crop 1
May 2019 Gallons 169,000 4.20
11.82 2.50 29.60
Elizabeth City WWTP
Moist 0
Surface
81.13
0.50
0.3 60,200
17,000.00 94.10
107.95
Crop 1
Total Volume Applied 234,000
Total Dry Tons 88.15
Sum Total P
83.65
Total
108.30
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.090 0.009
1.275 0.012
0.103 0.002
0.044
0.062
0.090
4.182
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.242 0.136
1.582
4.750 0.658
0.056
0.322
1.121
4.393
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
Perm itNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 106 SoilSeries Belhaven Crop 1 Pan 169
LandOwner W.B. Bateman Acres Permuted 9.92 Soil Abbrevation: BcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
May 2019 Gallons 44,500 21.60
9.92 4.04 40.08
Elizabeth City WTP
Moist 0
Surface
2.05
0.50
0 193
35.10 18.30
0.29
Crop 1
May 2019 Gallons 91,000 4.20
9.92 1.61 15.94
Elizabeth City WWTP
Moist 0
Surface
52.05
0.50
0.3 60,200
17,000.00 94.10
69.26
Crop 1
Total Volume Applied 135,500
Total Dry Tons 56.02
Sum Total P
54.11
Total
69.55
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.062 0.007
0.820 0.010
0.068 0.001
0.031
0.042
0.062
2.687
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.214 0.134
1.127
4.715 0.657
0.043
0.302
1.093
2.898
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermitNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Double Crop
Facility Name City of Elizabeth City Field Name 96 SoilSeries Wasda-Conaby Complex Crop 1 Pan 147
LandOwner W.B. Bateman Acres Permuted 11.40 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
June 2019 Gallons 143,000 21.60
11.40 11.30 128.80
Elizabeth City WTP
Moist 0
Surface
5.74
0.50
0 193 35.10 1830 0.81
Crop 1
Total Volume Applied 143,000
Total Dry Tons 128.80
Sum Total P
5.74
Total 0.81
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.056 0.006
0.029 0.027
0.027
0.000
0.027
0.027
0.056
0.056
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647
0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.208 0.133
0.336
4.674
0.656
0.039
0.287
1.087
0.267
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermitNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Double Crop
Facility Name City of Elizabeth City Field Name 97 SoilSeries Wasda-Conaby Complex Crop 1 Pan 147
LandOwner W.B. Bateman Acres Permuted 11.59 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite PAN
PAN Crop
June 2019 Gallons 169,000 21.60
11.59 13.13 152.22
Elizabeth City WTP
Moist 0
Surface
6.67
0.50
0 193 35.10 1830 0.94
Crop 1
Total Volume Applied 169,000
Total Dry Tons 152.22
Sum Total P
6.67
Total 0.94
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead
Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.066 0.007
0.034 0.032
0.032
0.000
0.032
0.032
0.066
0.066
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647
0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.218 0.134
0.341
4.679
0.656
0.044
0.292
1.097
0.277
Permitted CPLR 36 34
1338
267
15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/j *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 98 SoilSeries Wasda-Conaby Complex Crop 1 Pan 174
LandOwner W.B. Bateman Acres Permuted 11.55 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
Mar. 2019 Gallons 58,500 18.60
11.55 3.93 45.37
Elizabeth City WTP
Moist 0
Surface
2.62
0.50
0 224
48.10 60.60
0.67
Crop 1
Apr. 2019 Gallons 143,000 4.20
11.55 2.17 25.05
Elizabeth City WWTP
Moist 0
Surface
70.26
0.50
0.3 60,200
17,000.00 94.10
93.48
Crop 1
Total Volume Applied 201,500
Total Dry Tons 70.42
Sum Total P
72.88
Total
94.14
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.079 0.008
1.105 0.012
0.090 0.001
0.040
0.055
0.079
3.622
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.231 0.135
1.412
4.737 0.657
0.052
0.315
1.110
3.833
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PermutNumber WQ0002883 Site# WB County Pasquotank Crop 1 Soybeans, Full Season
Facility Name City of Elizabeth City Field Name 99 SoilSeries Wasda-Conaby Complex Crop 1 Pan 174
LandOwner W.B. Bateman Acres Permuted 11.53 Soil Abbrevation: WcA Crop 2
Operator Crop 2 Pan
Volume
Acres Dry
Soil
Application
Total
Nitrate Crop 1
Crop 2
Date Measurement Applied % Solids
Used DT/Ac. Tons
Source
Condition Precip Method
P
Volatilization
Mineralization THIN Ammonia -Nitrite
PAN
PAN Crop
Mar. 2019 Gallons 58,500 18.60
11.53 3.94 45.37
Elizabeth City WTP
Moist 0
Surface
2.63
0.50
0 224
48.10 60.60
0.67
Crop 1
Apr. 2019 Gallons 143,000 4.20
11.53 2.17 25.05
Elizabeth City WWTP
Moist 0
Surface
70.38
0.50
0.3 60,200
17,000.00 94.10
93.64
Crop 1
Total Volume Applied 201,500
Total Dry Tons 70.42
Sum Total P
73.01
Total
94.30
Total
Reported in Gallons Arsenic Cadmium
Copper Chromium
Lead Mercury
Molybdenum
Nickel Selenium
Zinc
Crop 1
Crop 2
PAN
PAN
Current Year 0.079 0.008
1.107 0.012
0.090 0.001
0.040
0.055
0.079
3.629
(lbs./Ac.)
(lbs./Ac.)
Lime (T/Ac.) Date
Prior Year 11.152 0.127
0.307
4.647 0.656
0.012
0.260
1.031
0.211
Cumulative Total 11.231 0.135
1.414
4.737 0.657
0.052
0.315
1.110
3.840
Permitted CPLR 36 34
1338
267 15
374
89
2498
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the
information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
/J *Application Method: S - Surface, IN - Injection, INC - Incorporation *** Mineralization Rates: Compost -0. 1, anaerobially digested -0.2,
**Volatilization Rate: Surface 0.5, Injection/Incorporation -1.0 aerobically digested -0.3, raw sludge -0.4
2-21-2020 ****C.P.L.R.: Cumulative Pollutant Loading Rate
Signature of Land Applier Date

City of Elizabeth City
2019 Class B Annual Report
WQ Permit# WQ0002883
Pathogen & Vector Attraction Reduction Forms
Elizabeth City W WP
Lime Stabilization Records

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number. NCO025011
---Monitoring Period: 01/01/2019 to 03/31/2019
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry 0 0 Continuous Grab Samples
Weight)
Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): gilt. 6 (Alk. Stabilization)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Rebecca Miller, WWTP Superintendent
Preparer Name and Title (type or print)
fj&e4�0 1 0
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
IA! w - -C' M
4/7/2020
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Friday, February 21, 2020

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates:1-1-2019 thru:1-31-2019
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
pH After
24 Hours
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#2
1/3/2019
2000
12.23
19
1/3/2019
2201
12.36
20
#2
1/4/2019
2006
12.35
20.31
20000
#1
1/4/2019
1430
12.58
18.5
1/4/2019
1630
12.34
18.4
#1
1/5/2019
1430
12.2
18.9
20000
#2
1/8/2019
2030
12.45
17.9
1/8/2019
2230
12.4
19.6
#2
1/9/2019
2200
12.33
18.8
20000
#1
1/10/2019
900
12.41
16.1
1/10/2019
1100
12.31
15.8
#1
1/11/2019
1300
12.21
15.9
20000
#2
1/12/2019
215
12.29
14.5
1/12/2019
415
12.21
14.5
#1
1/13/2019
215
11.88
15.1
20000
#1
1/13/2019
2000
12.61
15
1/13/2019
2200
12.57
15
#1
1/14/2019
2000
12.5
14.5
20000
#2
1/15/2019
800
12.37
15.2
1/15/2019
1100
12.21
15.8
#1
1/16/2019
900
12.22
15.9
20000
#1
1/16/2019
2240
12.02
15
1/17/2019
40
12.68
14.4
#1
1/18/2019
2325
12.55
15.9
20000
#2
1/19/2019
1615
12.46
17.6
1/19/2019
1819
12.34
16.8
#1
1/20/2019
1618
12.31
17
20000
#2
1/25/2019
930
12.31
18.4
1/25/2019
1130
12.19
19.1
#1
1/26/2019
1209
12.14
17.2
20000
#1
1/26/2019
1635
12.45
16.4
1/26/2019
1835
12.35
13.4
#1
1/27/2019
1633
12.33
15
20000
#2
1/27/2019
1600
12
15.9
1/27/2019
1800
11.93
17
#1
1/28/2019
1700
12.04
14.9
20000
#1
1/29/2019
434
12.38
15.9
1/29/2019
634
12.53
15.1
#1
1/30/2019
434
12.37
16.2
20000
#2
1/30/2019
1200
12.67
17.6
1/30/2019
1400
12.38
18
#1
1/31/2019
1200
12.48
17
20000
SheetTotall
280000
2019 Total 3920000
loads 603.0769231

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates: 2/1/2019 thru:2/28/2019
NPDES Permit # NC0025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#2
1 2/1/2019
2000
12.5
15.7
2/1/2019
2200
12.42
15.1
#1
2/2/2019
2000
11.97
17.51
20000
#1
2/2/2019
2100
12.54
16
2/1/2019
2300
12.32
16.5
#1
2/3/2019
2100
12.69
15.4
20000
#2
2/4/2019
200
12.42
16.6
2/4/2019
400
12.39
17.9
#2
2/5/2019
200
12.43
17.9
20000
#1
2/5/2019
400
12.57
17.6
2/5/2019
600
12.48
17.3
#2
2/6/2019
917
12.14
17.5
20000
#2
2/6/2019
1330
12.44
20.6
2/7/2019
9001
12.39
19.2
#2
2/7/20191
1330
12.4
22.1
20000
#1
2/7/2019
1730
12.66
19.9
2/7/2019
1930
12.7
19.9
#2
2/7/20191
1730
12.39
20.1
20000
#2
2/8/2019
730
12.26
19.9
2/8/2019
1130
12.21
20.7
#1
2/9/2019
730
12.09
17.5
20000
#1
2/9/2019
1000
12.63
16.1
2/9/2019
1200
12.49
15.2
#1
2/10/2019
700
11.99
16.8
20000
#2
2/10/2019
900
12.6
18
2/10/2019
1100
12.54
19.5
#1
2/11/2019
1015
12.49
18.21
20000
#1
2/11/2019
215
12.71
17.4
2/11/2019
415
12.68
17.8
#1
2/12/2019
215
12.73
17.2
20000
#2
2/12/2019
900
12.6
19.6
2/12/2019
1200
12.52
19.9
#1
2/13/2019
1015
12.12
18.6
20000
#1
2/13/2019
145
12.26
18.2
2/13/2019
345
12.18
18.31
#1
2/14/2019
245
11.88
16.5
20000
#2
2/14/2019
415
11.98
15.4
2/14/2019
615
11.83
18.1
#2
2/15/2019
330
12.191
18.5
20000
#1
2/15/2019
500
12.45
18
2/15/2019
800
12.34
18.4
#1
2/16/2019
500
12.42
18.8
20000
#2
2/15/2019
1800
12.27
19.7
2/15/2019
2000
12.23
19.4
#2
2/16/2019
1800
12.13
18.9
20000
#2
2/19/2019
200
12.68
17
2/19/2019
400
12.51
17.9
#2
2/20/2019
200
12.24
17.9
20000
#1
2/19/2019
1515
11.92
16.2
2/19/2019
1715
12.11
16.5
#2
2/20/2019
1515
11.44
17.2
20000
#1
2/21/2019
1800
12.51
16.3
2/21/2019
2000
12.4
17.4
#2
2/22/2019
1800
12.51
16.9
20000
#2
2/22/2019
1000
12.37
16.6
2/22/2019
1200
12.21
17.1
#2
2/23/2019
1000
12.09
17
20000
#2
2/24/2019
530
12.46
18.1
2/24/2019
1000
12.41
18.6
#2
2/25/2019
530
12.39
18.1
20000
#1
2/24/2019
2345
12.24
17.8
2/24/2019
145
12.7
17.5
#1
2/25/2019
2345
12.2
17.6
20000
#1
2/28/2019
200
12.52
17.3
2/28/2019
400
12.38
17.9
#2
3/1/2019
200
12.28
17.8
20000
#2
2/28/2019
1600
12.36
18.1
2/28/2019
1800
12.34
16.6
#2
3/1/2019
1600
11.84
17.4
20000
Sheet Total
460000
*On 2/5/19 LST #1 was transferred before the 24 hour sample was taken so one was grabbed out of SST #2 on 2/6/19 at 0917 and a 12.14 pH was read.
*On 2/6/19 an initial pH sample was grabbed but read below the minimun requirents so lime was added and the 24 hour period started over.

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP NPDES Permit # NC0025011
Class B Biosolids Residuals Permit # WQ0002883
Dates:3-1-2019 thru:3-31-2019
Initial pH
pH After 2 Hours
24 Hour pH
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
3/2/2019
430
12.38
17
3/2/2019
630
12.88
17.2
#1
1 3/3/2019
430
12.39
17.2
20000
#2
3/2/2019
1720
12.36
17.1
3/2/2019
19201
12.3
16.3
#1
3/4/20191
1100
12.1
19
20000
#1
3/11/2019
1000
12.31
18.8
3/11/2019
1200
12.23
19.1
#1
3/12/2019
1000
12.13
17.8
20000
#2
3/12/2019
100
11.93
17.8
3/12/2019
315
11.65
17.3
#2
3/13/2019
100
11.69
18.2
20000
#1
3/13/2019
610
12.06
16.8
3/13/2019
810
12.32
18.3
#2
3/14/2019
630
12.08
16.3
20000
#2
3/13/2019
1900
122.42
3/13/2019
217070
122.8�8
#2
3/14/2019
1900
12.05
18
20000
#4
7 /'I C�
"1
TTJ
�p18
4
/'I7 C�
TTS
�.}
�17.�8
SOT
#1
3/15/2019
1158
12.74
20.6
3/15/2019
1400
12.62
21.1
#2
3/16/2019
1200
12.39
19.2
20000
#2
3/15/2019
2120
12.53
20.3
3/15/2019
2320
12.59
20.1
#2
3/16/2019
2120
12
16
20000
#2
3/17/2019
1100
12.22
18.3
3/17/2019
1300
12.14
18.9
#2
3/18/2019
1100
12.09
18.5
20000
#2
3/18/2019
445
12.47
17.1
3/18/2019
645
12.33
17.1
#2
1 3/19/2019
445
12.44
16.8
20000
#1
3/19/2019
1020
12.57
17.6
3/19/2019
1244
12.47
17.8
#2
3/20/2019
1040
12.2
16.8
20000
#2
3/19/2019
2330
12.17
17.1
3/19/2019
132
12.38
16.7
#2
3/21/2019
200
12.33
18.2
20000
#1
3/22/2019
20
12.28
17.1
3/22/2019
220
12.29
17.2
#2
3/23/2019
200
12.25
17.1
20000
#2
3/23/2019
300
12.41
16.9
3/23/2019
500
13.11
17.8
#1
3/24/2019
300
12.59
17.4
20000
#1
3/24/2019
1230
12.57
18.2
3/24/2019
14301
12.41
18.8
#1
3/25/2019
1230
12.09
19.1
20000
#2
3/25/2019
845
12.29
17.9
1/3/1900
1045
12.19
18.5
#1
3/26/2019
850
12.04
17.1
20000
#1
3/25/2019
1900
12.34
19.8
3/25/2019
2100
12.14
18.8
#2
3/26/2019
1900
12.48
17.4
20000
#1
3/29/2019
350
12.43
17.6
3/29/2019
550
12.49
17.7
#1
3/30/2019
355
12.25
19.71
20000
#2
3/31/2019
205
12.29
20.1
3/31/2019
405
12.66
20.4
#1
4/1/2019
205
12.08
18.2
20000
#1
3/31/20191
1650
12.9
19.2
3/31/2019
1850
12.59
18.6
#1
4/1/2019
1650
12.55
21.6
20000
Sheet Total
400000
On 3/15/19 an initial and 2 hr pH sample was grabbed and neither read the minimum requirements so lime was added and the 24 hr period started over.

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWTP NPDES Number: NC0025011
.vlonitoring Period: 04/01/2019 to 06/30/2019
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not .Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry 0 0 Continuous Grab Samples
Weight)
Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Tilt. 6 (.ilk. Stabilization
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Rebecca Miller, WWTP Superintendent
Preparer Name and Title (type or print)
5
941.//.�i
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
4/7/2020
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Friday, February 21, 2020

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates:4-1-2019 thru:4-30-2019
NPDES Permit # NC0025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
4/2/2019
2200
12.92
17.7
4/3/2019
0
12.33
16.9
#1
4/3/2019
2200
12.67
18.8
20000
#2
4/2/2019
2353
12.87
18.3
4/4/2019
158
12.69
18.6
#2
4/4/2019
2355
12.5
19.5
20000
#1
4/5/2019
830
12.08
18.1
4/5/2019
1030
12.01
18.4
#2
4/6/2019
845
11.74
19.4
20000
#2
4/6/2019
730
12.2
19.5
4/6/2019
930
12.02
20
#2
4/7/2019
830
11.85
21.1
20000
#2
4/9/2019
300
12.28
21.1
4/9/2019
505
12.11
21
#1
4/10/2019
300
11.96
21.1
20000
#1
4/9/2019
1530
12.16
21.8
4/9/2019
17301
12.12
21.1
#2
4/10/2019
1530
12.09
22.1
20000
#1
4/11/2019
1600
12.52
23.6
4/11/2019
1800
12.52
20.7
#1
4/12/2019
1600
12.4
23.7
20000
#2
4/12/2019
815
12.19
20.9
4/12/2019
1015
12.11
21.5
#1
4/13/2019
830
12.06
19.8
20000
#1
4/13/2019
2335
12.47
20.8
4/14/2019
135
12.43
21.4
#1
4/14/2019
2330
11.71
22.1
20000
#2
4/14/2019
1540
12.32
22.8
4/14/2019
1740
12.19
22.4
#1
4/15/2019
1540
12.04
23.2
20000
#1
4/15/2019
0
12.54
19
4/15/2019
200
12.91
19.3
#1
4/16/2019
0
12.71
21.2
20000
#2
4/16/2019
1600
12.37
21.2
4/16/2019
1800
12.21
22.2
#2
4/17/2019
1600
11.72
22.6
20000
#2
4/19/2019
1250
12.72
22
4/19/2019
1450
12.53
22.5
#1
4/20/2019
1300
12.41
21.9
20000
#1
4/20/2019
120
12.49
21.9
4/20/2019
320
12.41
22.1
#1
4/21/2019
145
12.37
21.3
20000
#1
4/21/2019
1700
12.6
21.6
4/21/2019
1900
12.52
21.2
#1
4/23/2019
730
12.17
21.2
20000
#2
4/22/2019
930
12.6
21.1
4/22/2019
1245
12.58
21.8
#1
4/23/2019
930
12.39
22.3
20000
#1
4/24/2019
905
12.37
22
4/24/2019
1111
12.21
21.9
#1
4/25/2019
905
11.99
22
20000
#2
4/26/2019
200
12.21
22.8
4/26/2019
400
12.05
22
#2
4/27/2019
1805
11.63
24.7
20000
#1
4/26/2019
1615
11.95
22.7
4/26/2019
1815
11.85
20.9
#2
4/27/2019
1615
11.47
22.5
20000
#-1-
n i�o�r9
2345
4i.91
244
n i�o��°
4�9
4i.95
244
#1
4/29/2019
1145
12.45
20.6
4/29/2019
1358
12.32
21.3
#2
4/30/2019
1145
12.26
23.21
20000
#2
4/29/2019
1600
12.31
20.8
4/29/20191
1800
12.291
21.3
#2
4/30/2019
1600
12.15
24.8
20000
Sheet Total
420000
*On 4/28/2019 the intital and 2hr pH didn't meet the minium requirements for more lime had to be added and the 24hr process had to be started over.

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates: 5/1/2019 thru:5/31/2019
NPDES Permit # NC0025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
24 Hour pH
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
5/1/2019
1015
12.21
22.2
5/1/2019
1215
12.07
23.9
1
5/2/2019
1030
11.98
24.21
20000
#2
5/2/2019
250
12.45
23.3
5/2/2019
4501
12.34
22.9
#1
5/3/2019
2501
12.34
23.7
20000
#1
5/3/2019
1515
12.3
23.7
5/3/2019
1715
12.32
23.6
#1
5/5/2019
830
12.03
22.5
20000
#2
5/4/2019
2340
12.51
23.5
5/5/2019
145
12.46
23.6
#2
5/5/2019
2340
12.13
23.7
20000
#1
5/6/2019
420
12.21
22.6
5/6/2019
620
12.17
22.3
#1
5/7/2019
510
11.63
22.4
20000
#2
5/6/2019
1945
12.41
23
5/6/2019
2145
12.4
22.6
#2
5/7/2019
1950
11.92
23.41
20000
#1
5/8/2019
415
12.42
21.6
5/8/2019
615
12.4
21.5
#1
5/9/2019
415
12.32
22.3
20000
4-2-
C /Q
3 25
44.
2-3-.4
C /Q
325
3g.4i
224
#2
5/9/2019
1330
12.39
24.2
5/9/2019
1530
12.4
24.1
#1
5/10/2019
1330
12.23
24.6
20000
#1
5/10/2019
1920
12.15
23.1
5/10/2019
2120
12.09
22.3
#1
5/11/2019
1920
11.73
23.6
20000
#2
5/11/2019
1145
12.44
22.7
5/11/2019
1345
12.39
23.5
#1
5/12/2019
1200
12.77
23.1
20000
#1
5/13/2019
750
12.21
22.1
5/13/2019
950
12.16
22.6
#1
5/14/2019
850
12.05
21.7
20000
#2
5/13/2019
2000
12.22
21.3
5/13/2019
1000
12.05
21.3
#2
5/14/2019
2000
11.74
22.1
20000
#1
5/15/2019
315
12.31
20.8
5/15/2019
515
12.42
21
#1
5/16/2019
315
12.19
21.8
20000
#2
5/15/2019
2335
12.23
21.6
5/16/2019
135
12.28
22.3
#2
5/16/2019
2335
11.97
22.61
20000
#2
5/18/2019
0:00
12.26
23.9
5/18/2019
200
12.2
23.5
#1
5/19/2019
0
11.89
23.9
20000
#1
5/18/2019
1600
12.05
24.7
5/18/2019
1800
12.12
24.4
#1
5/19/2019
1600
11.96
25
20000
#1
5/22/2019
540
12.21
23.1
5/22/2019
800
12.14
21.6
#1
5/23/2019
540
12.15
23.6
20000
#2
5/22/2019
2030
12.31
21.9
5/22/2019
2230
12.32
22.2
#1
5/23/2019
2030
12.15
24.2
20000
#1
5/24/2019
105
12.21
23.7
5/24/2019
305
12.16
23
#1
5/25/2019
115
12.34
24
20000
#2
5/25/2019
1330
12.39
23.7
5/25/2019
1530
12.18
24.7
#1
5/26/2019
1330
12.02
25.3
20000
#1
5/26/2019
530
12.23
23.6
5/26/2019
730
12
23.5
#1
5/27/2019
535
12.2
24.1
20000
#1
5/28/2019
1900
12.21
29.8
5/28/2019
2100
12.23
24.2
#1
5/29/2019
1900
12.34
25
20000
#2
5/29/2019
1540
12.32
26.3
5/29/2019
1740
12.32
26.7
#1
5/30/2019
1545
12.3
26.6
20000
#1
5/30/20191
2000
12.43
25.1
5/30/2019
2200
12.45
23.9
#1
5/31/20191
2000
12.17
24
20000
Sheet Total
480000
*On 5/8/2019 the initial and 2 hr pH didn't meet the minimum requirements so more lime had to be added and the 24hr process had to be started over.

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates:6-1-2019 thru:6-30-2019
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
24 Hour pH
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
6/4/2019
200
12.4
22.4
6/4/2019
400
12.35
22.61
#1
6/5/2019
205
12.36
22.4
20000
#2
6/4/2019
2330
12.36
23.4
6/5/2019
1301
12.24
23.3
#2
6/5/2019
2330
12
23.3
20000
#2
6/8/2019
330
12.23
24.4
6/8/2019
530
12.2
24.5
#2
6/9/2019
330
12.17
24.5
20000
#1
6/8/2019
1830
12.23
22.4
6/8/2019
2030
12.17
24.6
#2
6/9/2019
1830
12.1
25.2
20000
#1
6/12/2019
1230
12.15
24.7
6/12/2019
1430
12.01
24.6
#2
6/13/2019
1230
12.02
24.2
20000
#2
6/13/2019
330
12.2
23.9
6/13/2019
535
12.02
25.3
#2
6/14/20191
330
11.85
23.0
20000
#1
6/15/2019
1200
12.19
23.0
6/15/2019
14001
12.12
23.8
#2
6/16/20191
1200
12.07
23.0
20000
#2
6/16/2019
340
12.21
24.0
6/16/2019
540
12.16
23.9
#2
6/17/2019
400
12.01
25.3
20000
#2
6/19/2019
630
12.09
23.6
6/19/2019
1200
12.06
23.4
#2
6/20/2019
630
11.88
26.1
20000
#1
6/20/2019
200
12.19
24.1
6/20/2019
400
12.04
25.6
#2
6/21/2019
200
11.85
24.91
20000
#2
6/21/2019
1300
12.22
21
6/21/2019
1500
12.17
25
#2
6/22/2019
1400
12.03
24.1
20000
#1
6/22/2019
240
12.31
22.8
6/22/2019
4401
12.18
23.9
#1
6/23/2019
340
12.08
24.4
20000
Sheet Total
240000

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WW'IP NPDES Number: NCO025011
Monitoring Period: 07/01/2019 to 09/30/2019
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stablization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry
Weight) 0 0 Continuous Grab Samples
Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Rebecca Miller, WWTP Superintendent
Preparer Name and Title (type or print)
Signature of Preparer*
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
/4rft*�-
4/7/2020
Date Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Friday, February 21, 2020

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates:7/1/2019 thru:7/31/2019
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Date
Time
pH
Temp
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
7/2/2019
0340
12.23
25.1'
0540
12.17
24.3°
#2
7/3/2019
0350
12.09
24.6°
20000
#2
7/2/2019
1820
12.20
27.2°
2020
12.08
24.8°
#2
7/4/2019
0500
12.05
24.9°
20000
#1
7/4/2019
2000
12.04
26.2°
2200
11.99
25.4°
#2
7/5/2019
2000
11.99
26.6°
20000
#2
7/12/2019
1850
12.02
28.0°
2050
12.00
28.5°
#2
7/13/2019
1850
11.84
29.5°
20000
#1
7/12/2019
2050
12.15
27.5°
2250
12.27
25.1'
#1
7/15/2019
0530
11.92
26.7°
20000
#2
7/16/2019
1000
12.21
24.1'
1200
12.06
26.4°
#2
7/17/2019
1000
12.27
26.4°
20000
#1
7/17/2019
0230
12.12
24.3°
0430
12.04
24.6°
#2
7/18/2019
0300
12.01
25.1'
20000
#1
7/19/2019
0400
12.19
24.6°
0600
12.12
24.8°
#2
7/20/2019
0400
12.06
25.2°
20000
#-2-
7 / o 019
1246
12 17
266,
#2
7/19/2019
2230
12.20
25.4°
0100
12.15
25.2°
#2
7/20/2019
2200
12.10
27.6°
20000
#2
7/24/2019
1600
12.12
25.6°
1800
12.16
24.3°
#2
7/25/2019
1600
12.06
26.7°
20000
#1
7/25/2019
1330
12.29
24.4°
1530
12.22
26.2°
#2
7/26/2019
1330
12.07
26.2°
20000
#1
7/28/2019
0500
12.26
23.4°
0700
12.21
23.9°
#1
7/29/2019
0500
12.04
23.5°
20000
#2
7/29/2019
0030
12.16
25.6°
0230
12.00
24.7°
#2
7/29/2019
0030
11.84
24.6°
20000
#1
7/29/2019
2320
12.16
26.2°
0120
12.00
24.0°
#1
7/31/2019
0000
11.85
26.3°
20000
#2
7/31/2019
1345
12.2
24.1'
0600
12.12
23.1'
#2
8/1/2019
1345
11.97
27.6°
20000
Sheet Total
300000
* 7/19/2019: 2 hr pH didn't meet the minimum requiremtents so more lime had to be added and the 24 hr was started over.

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates: 8/1/2019 thru:8/31/2019
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
40CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Date
Time
pH
Temp
Date
Time
pH
Temp
Shipped
SST #1or2
Date
Time
pH
Temp
Stabilization
Amount
#1
8/1/2019
0900
12.18
27.1°
8/1/2019
1100
12.01
26.2°
#2
8/2/2019
0925
11.88
23.0°
20000
#1
8/9/2019
0430
12.15
24.0°
8/9/2019
0630
12.09
24.8°
#2
8/10/2019
0430
12.01
24.3°
20000
#2
8/9/2019
1600
12.1
27.1°
8/9/2019
1800
12.07
25.6°
#2
8/10/2019
1600
12.03
27.5°
20000
#2
8/12/2019
0330
12.26
24.6°
8/12/2019
0530
12.17
24.9°
#2
8/13/2019
0430
12.15
24.8°
20000
#1
8/12/2019
1440
12.18
28.7°
8/12/2019
1640
12.13
26.7°
#1
8/13/2019
1440
12.12
31.0-1
20000
#2
8/14/2019
0600
12.14
29.5°
8/14/2019
0832
12.12
29.3°
#2
8/15/2019
0630
11.98
30.3°
20000
#1
8/15/2019
0915
12.34
31.0°
8/15/2019
1125
12.3
32.2°
#2
8/16/2019
0925
12.24
30.6°
20000
#1
8/19/2019
1900
12.23
30.2°
8/19/2019
2100
12.22
30.1°
#2
8/20/2019
1900
12.02
32.2°
20000
#2
8/20/2019
0905
12.17
30.3°
8/20/2019
1105
12.13
31.2°
#2
8/21/2019
0905
12.06
31.4°
20000
#1
8/22/2019
0100
12.15
26.4°
8/22/2019
0300
12.09
27.8°
#2
8/23/2019
0200
12.14
29.8°
20000
#2
8/22/2019
1200
12.17
30.1°
8/22/2019
1400
12.15
30.7°
#2
8/23/2019
1204
12.1
30.2°
20000
#2
8/31/2019
530
12.17
28.6
8/31/2019
730
12.16
28.7
#2
9/1/2019
530
12.06
29.4
20000
Sheet
Total:
240000

City of Elizabeth City WWTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP
Class B Biosolids
Dates: 9/1/2019 thru:9/30/2019
NPDES Permit # NCO025011
Residuals Permit # WQ0002883
40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
24 Hour pH
Tank
Analyst
Date
Time
pH (su)
Temp (c°)
Analyst
Date
Time
pH (su)
Temp (c°)
7.2or2
Analyst
Date
Time
pH (su)
Temp (c°)
Stabilization
Amount
#1
RT
9/1/2019
1500
12.24
30.5°
RT
9/1/2019
1700
12.19
29.9°
Sc
9/2/2019
1630
12.11
31.11
20000
#2
DR
9/2/2019
0330
12.16
27.4°
DR
9/2/2019
0530
12.11
27.8°
DR
9/3/2019
0400
12.02
28.3°
20000
#2
QS
9/3/2019
2240
12.19
29.5°
DR
9/4/2019
0040
12.08
29.0°
42
QS
9/4/2019
2240
12.14
30.7°
20000
#1
QS
9/4/2019
2205
12.18
29.4°
DR
9/5/2019
0005
12.04
28.9°
41
QS
9/5/2019
2215
12.19
27.1°
20000
#2
Sc
9/5/2019
1724
12.20
28.7°
DR
9/8/2019
1930
12.11
28.3°
42
Sc
9/7/2019
1037
12.08
28.9°
20000
#2
QS
9/12/2019
2135
12.32
28.8°
DR
9/12/2019
2335
12.21
27.8°
42
QS
9/14/2019
1435
12.13
32.0°
20000
#1
DR
9/14/2019
0230
12.18
23.1°
DR
9/14/2019
0430
12.07
26.8°
42
DR
9/15/2019
0230
12.02
28.8°
20000
#1
RT
9/16/2019
1900
12.17
27.8°
RT
9/16/20191
2100
12.20
27.3°
42
RT
9/17/20191
1900
12.13
27.8°
20000
#2
QS
9/17/2019
0445
12.36
28.1°
QS
9/17/2019
0700
12.38
26.9°
42
DR
9/18/2019
0450
12.29
27.3°
20000
#1
RT
9/23/2019
1500
12.20
27.2°
RT
9/23/2019
1700
12.19
27.6°
42
RT
9/24/2019
1500
12.20
27.6°
20000
#1
DR
9/28/2019
0245
12.43
26.5°
DR
9/28/2019
0445
12.32
26.1°
42
DR
9/29/2019
0500
12.18
26.5°
20000
Sheet Total:
220000

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: City of Elizabeth City WQ Permit Number: WQ0002883
WWTP Name: Elizabeth City WWI? NPDES Number: NCO025011
Monitoring Period: 10/01/2019 to 12/31/2019
Pathogen Reduction (15A NCAC 02T .1106) - Please Indicate level achieved and alternative performed:
"Class A" Alternative: Not Applicable
If applicable to alternative performed ("Class A" only) indicate "Process to Further Reduce Pathogens": Not Applicable
"Class B" Alternative: Alternative 2
If applicable to alternative performed ("Class B" only) indicate "Process to Further Reduce Pathogens": Lime Stabilization
Fecal Coliform Minimum Geo. Mean Maximum # of Exceedences Frequency Sample Type
Colonies Per Gram of
Total Solids(Dry
Weight) 0 0 Continuous Grab Samples
Technique
Vector Attraction Reduction Performed (15A NCAC 02T .1107): Alt. 6 (Alk. Stabilization)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
- requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction
❑ requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why
you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that
qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction
reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and
imprisonment."
Rebecca Miller, WVWP Superintendent
Preparer Name and Title (type or print)
A&. RU 0;7-/ (T uo
Signature of Preparer* Date
J. Bryan Smith, President
Land Applier Name and Title (if applicable)(type or print)
/4rm�-
4/7/2020
Signature of Land Applier (if applicable Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Friday, February 21, 2020

City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP NPDES Permit# N00025011
Class B Biosolids Residuals Permit# WQ0002883
Dates: 10/01/2019 thru: 10/31/2019 40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
correctio
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
correctio
Temp (°c)
Shipped
SST#lor2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
correctio
Temp (°c)
Stabilization
Amount
#1
JM
10/1/2019
1230
12.40
0.09
12.49
27.5
JM
10/1/2019
1430
12.39
0.09
12.48
28.1
#2
JM
10/2/2019
1230
12.30
0.09
12.39
28.3
20000
#1
QS
10/5/2019
2300
12.36
0.06
12.42
26.7
DR
10/6/2019
0100
12.21
0.03
12.24
26.0
#2
CIS
10/6/2019
2300
12.24
-0.21
12.03
18.0
20006
#1
RT
10/9/2019
1700
12.41
0.03
12.44
25.6
RT
10/9/2019
1900
12.40
0.00
12.40
25.3
#2
RT
10/10/2019
1700
12.31
0.03
12.34
25.7
20000
#2
DR
10/12/2019
0530
12.45
-0.06
12.39
23.1
JM
10/12/2019
0730
12.39
-0.06
12.33
23.3
#2
DR
10/13/2019
0530
12.16
-0.06
12.10
23.1
20000
#1
RT
10/12/2019
1700
12.36
0.03
12.39
26.0
RT
10/12/2019
1900
12.39
0.00
12.39
25.2
#2
QS
10/13/2019
1800
12.28
0.03
12.31
26.2
20000
#1
QS
10/18/2019
0635
12.41
-0.09
12.32
22.8
JM
10/18/2019
0835
12.40
-0.09
12.31
22.9
#2
JM
10/19/2019
0730
12.38
-0.12
12.26
21.7
20006
#2
DR
10/20/2019
0330
12.64
-0.09
12.55
22.2
DR
10/20/2019
0530
12.41
-0.06
12.35
22.8
#2
DR
10/21/2019
0330
12.44
-0.09
12.35
22.1
20006
#2
DR
10/23/2019
2330
12.14
-0.03
12.11
23.9
DR
10/24/2019
1330
12.11
-0.03
12.08
23.6
#2
DR
10/25/2019
0030
11.91
-0.12
11.79
21.4
20000
Sheet
Total:
160000

City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
City of Elizabeth City W WTP
Monitoring Sheet for Lime Stabilization
Alternative 2 PSRP NPDES Permit # NCO025011 NPDES Permit # NCO025011
Class B Biosolids Residuals Permit# WQ0002883 Residuals Permit# WQ0002883
Dates: 11/1/2019 thru: 11/30/2019 40 CFR Part 503 Subpart D 503.30-503.33 40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
Temp (°c)
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
Temp (°c)
Shipped
SST #1or2
Analyst
Date
Time
pH (su)
Correction
Factor
pH (su)
after
Correction
Temp (°c)
Stabilization
Amount
(Gallons)
#1
RT
11/1/2019
2120
12.27
-0.09
12.18
22.5°
DR
11/1/2019
2320
12.27
-0.06
12.21
23.1°
#2
CIS
11/3/2019
0100
12.18
-0.06
12.12
23.40
20000
#2
RT
11/2/2019
1520
12.43
-0.06
12.37
23.40
RT
11/2/2019
1720
12.40
-0.09
12.31
22.30
#2
RT
11/3/2019
1520
12.35
-0.12
12.23
21.30
20000
#1
JM
11/4/2019
0745
12.31
-0.12
12.19
21.00
1M
11/4/2019
0945
12.27
-0.09
12.18
22.00
#2
1M
11/5/2019
0745
12.12
-0.09
12.03
22.60
20000
#2
DR
11/4/2019
2315
12.31
-0.09
12.22
22.20
DR
11/5/2019
0115
12.24
-0.09
12.15
21.90
#2
DR
11/5/2019
2330
11.80
-0.15
11.65
20.50
20000
#1
DR
11/8/2019
0245
12.52
-0.091
12.43
22.30
DR
11/8/20191
0445
12.40
-0.09
12.31
22.00
#2
DR
11/9/2019
0330
12.22
-0.24
11.98
17.40
20000
#2
RT
11/8/2019
2100
12.61
-0.21
12.40
18.90
DR
11/8/2019
2325
12.54
-0.21
12.33
18.40
#2
RT
11/9/2019
2100
12.55
-0.27
12.28
16.00
20000
#1
CIS
11/12/2019
0535
12.34
-0.12
12.22
21.10
DE
11/12/2019
0805
12.47
-0.12
12.35
21.20
#2
SC
11/13/2019
0535
12.52
-0.30
12.32
15.00
20000
#2
SC
11/13/2019
0535
12.85
-0.30
12.55
15.30
JM
11/13/2019
7030
12.75
-0.27
12.48
16.90
#2
SC
11/14/2019
0535
12.77
-0.39
12.38
12.80
20000
fi1
VW
11/16/2019
0800
12.57
-0.21
12.36
18.80
VW
11/16/2019
1005
12.55
-0.21
12.34
18.60
#2
SC
11/17/2019
0900
12.56
-0.24
12.32
17.50
20000
#2
CIS
11/17/2019
0415
12.73
-0.24
12.49
17.90
CIS
11/17/2019
0615
12.71
-0.24
12.47
17.50
fit
CIS
11/18/2019
0415
12.73
-0.24
12.49
15.80
20000
fi1
JM
11/18/2019
0930
12.62
-0.21
12.41
18.90
JM
11/18/2019
1130
12.51
-0.21
12.30
18.90
fit
JM
11/19/2019
0930
12.45
-0.10
12.27
19.3°
20000
fil
I RT
11/19/2019
1730
12.49
-0.18
12.31
19.30
RT
11/19/2019
1930
12.48
-0.21
12.27
18.60
#2
RT
11/20/2019
1730
12.52
-0.21
12.31
18.91
20000
fit
DR
11/21/2019
0330
12.78
-0.24
12.541
17.10
DR
11/21/2019
0530
12.66
-0.24
12.42
17.00
#2
DR
11/21/2019
0330
12.56
-0.27
12.29
16.30
20000
fil
JM
11/21/2019
1330
12.54
-0.18
12.36
19.80
RT
11/21/2019
1530
12.52
-0.21
12.31
18.80
#1
JM
11/22/2019
1330
12.38
-0.18
12.2
19.91
20000
fil
JM
11/23/2019
1330
12.37
-0.18
12.19
19.50
CIS
11/23/2019
1530
12.35
-0.18
12.17
19.20
#1
CIS
11/24/2019
1330
12.31
-0.12
12.19
21.3°
20000
fit
DR
11/24/2019
0230
12.66
-0.18
12.48
18.90
DR
11/24/2019
0430
12.51
-0.18
12.33
18.70
#2
DR
11/25/2019
0230
13.00
-0.24
12.76
16.80
20000
fil
SC
11/26/2019
1315
12.35
-0.15
12.20
20.40
RT
11/26/2019
1515
12.36
-0.18
12.20
19.40
#2
JM
11/27/2019
1315
12.32
-0.15
12.17
20.10
20000
#2
CIS
11/27/2019
0350
12.54
-0.18
12.36
19.30
CIS
11/27/2019
0550
12.58
-0.18
12.40
19.30
#2
CIS
11/28/2019
0410
12.47
-0.24
12.23
17.90
20000
Sheet Total (Gallons):
360000

Class B Biosolids Residuals Permit # WQ0002883 Residuals Permit # WQ0002883
Dates: 12/1/2019 thru: 12/31/2019 40 CFR Part 503 Subpart D 503.30-503.33 40 CFR Part 503 Subpart D 503.30-503.33
Initial pH
pH After 2 Hours
pH After 24 Hours
Tank
Analyst
Date
Time
PH(su)
Correction
Factor
PH(su)
after
Correction
Temp(°c)
Analyst
Date
Time
PH(su)
Correction
Factor
PH(su)
after
Correction
Temp(°c)
Shipped
to SST
#1or2
Analyst
Date
Time
PH(su)
Correction
Factor
PH(su)
after
Correction
Temp(°c)
Stabilization
Amount
(Gallons)
41
DR
12/4/2019
0600
12.65
-0.24
12.41
17.00
SC
12/4/2019
0800
12.63
-0.24
12.39
17.00
#2
DE
12/5/2019
0742
12.51
-0.24
12.30
17.4°
20000
42
CIS
12/4/2019
2330
12.64
-0.24
12.40
17.6°
CIS
12/5/2019
0130
12.60
-0.24
12.36
17.6°
#2
CIS
12/5/2019
2345
12.55
-0.33
12.22
14.8°
20000
41
CIS
12/5/2019
0415
12.50
-0.27
12.23
16.5°
CIS
12/6/2019
0615
12.46
-0.24
12.22
17.2°
#2
DR
12/7/2019
0100
12.65
-0.24
12.41
17.0°
20000
42
DR
12/7/2019
0100
12.64
-0.24
12.40
17.40
DR
12/7/2019
0300
12.49
-0.24
12.25
17.0°
#2
DR
12/8/2019
0100
12.67
-0.30
12.37
15.2°
20000
41
CIS
12/10/2019
0910
12.61
-0.18
12.43
19.50
SC
12/10/2019
0910
12.59
-0.15
12.44
20.0°
#2
CIS
12/11/2019
0710
12.58
-0.19
12.39
18.6°
20000
#2
RT
12/10/2019
2130
12.66
-0.18
12.48
19.60
DR
12/10/2019
1130
12.64
-0.18
12.46
19.2°
#2
RT
12/11/2019
2130
12.61
-0.27
12.34
16.7°
20000
#1
DR
12/12/2019
0300
12.69
-0.24
12.45
16.70
DR
12/12/2019
0500
12.60
-0.27
12.33
16.3°
#2
CIS
12/13/2019
0300
12.53
-0.30
12.23
15.91
20000
#1
CIS
12/20/2019
0515
12.55
-0.30
12.25
15.70
JM
12/20/2019
0715
12.51
-0.30
12.21
15.60
#1
CIS
12/21/2019
0520
12.58
-0.27
12.31
16.3°
20000
#2
CIS
12/21/2019
0410
12.71
-0.30
12.41
15.6°
CIS
12/21/2019
0610
12.74
-0.30
12.44
15.80
#2
CIS
12/22/2019
0410
12.72
-0.36
12.36
13.7°
20000
#1
CIS
12/22/2019
0650
12.59
-0.30
12.29
15.80
JM
12/22/2019
0850
12.55
-0.27
12.28
16.90
#2
JM
12/23/2019
0745
12.56
-0.24
12.32
17.9°
20000
#2
DR
12/24/2019
0400
12.67
-0.27
12.40
16.40
DR
12/24/2019
0600
12.61
-0.24
12.37
17.00
#2
DR
12/25/2019
0400
12.50
-0.27
12.23
16.1°
20000
#1
SC
12/24/2019
1410
12.56
-0.21
12.35
18.5°
CIS
12/24/2019
1610
12.57
-0.24
12.33
17.90
#1
SC
12/25/2019
1410
12.43
-0.18
12.25
18.5°
20000
#2
CIS
12/25/2019
22501
12.54
-0.24
12.30
17.60
DR
12/26/2019
0050
12.50
-0.24
12.26
17.40
#2
DR
12/26/2019
2250
12.42
-0.24
12.18
17.3°
20000
#1
SC
12/26/2019
9630
12.22
-0.24
11.98
17.00
SC
12/26/2019
11301
12.11
-0.18
11.93
18.70
#1
SC
12/27/2019
940
11.84
-0.21
11.63
17.9°
20000
#2
RT
12/26/2019
2128
12.64
-0.24
12.40
17.2°
DR
12/26/2019
23301
12.60
-0.24
12.36
17.0°
#2
RT
12/27/2019
2130
12.43
-0.15
12.28
20.3°
20006
EJEE
Sheet Total
(Gallons):
300000

City of Elizabeth City
2019 Class B Annual Report
WQ Permit# WQ0002883
Soil Samples

Page 1 of 1
Report No: 20-092-0534
Account No: 04596
Advisor: Soil Plus, LLC
Joyce Barrette
P.O. Box 1396
Oxford NC 27565
Waypoint"'o
ANALYTICAL
Client: Atlantic OBX
2850 Daisy Lane, Wilson, NC 27896
Main 252-206-1721 ° Fax [phone]
www.waypointanalytical.com
Farm: LL
Date Received:04/01/2020
Date of Report: 04/03/2020
Lab No Field ID
Sample ID
Soil Class HM% W/V pH
Ac
P-1
K-1
S-1
Mn-I
Zn-I
Zn-AI
Cur-1
CEC
BS%
Ca%
Mg%
ESP Na SS-1 NOSN
20468
33
MIN 1.7
1.3 5.2
3.0
157
29
35
56
173
173
30
6.0
50
38
9
0.9 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.7
N
160
PZO5
0
KZO
80
S
0
Mn
0
Mn-AI
63
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20469
34
MIN 1.6
1.4 5.3
2.6
143
21
31
38
158
158
30
5.4
52
40
9
1.1 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.4
N
160
PZO5
0
KZO
97
S
0
Mn
0
Mn-AI
50
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20470
35
MIN 1.8
1.4 5.2
2.4
146
20
33
44
155
155
25
5.1
54
41
9
1.4 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.4
N
160
PZO5
0
KZO
100
S
0
Mn
0
Mn-AI
55
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20472
36
MIN 1.5
1.4 5.2
2.9
171
28
37
50
188
188
30
6.2
53
41
9
1.3 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.7
N
160
PZO5
0
KZO
82
S
0
Mn
0
Mn-AI
59
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20473
37
MIN 1.7
1.5 5.2
3.0
177
34
33
50
190
190
30
6.3
52
40
9
1.1 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.7
N
160
PZO5
0
KZO
70
S
0
Mn
0
Mn-AI
59
Zn
0
Cu
0
B
0
Mg
0
Last Crop
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Carolina, Inc.

Page 1 of 2
Report No: 20-093-0571
Account No: 04596
Advisor: Soil Plus, LLC
Joyce Barrette
P.O. Box 1396
Oxford NC 27565
Waypoint"'o
ANALYTICAL
Client: Atlantic OBX
2850 Daisy Lane, Wilson, NC 27896
Main 252-206-1721 ° Fax [phone]
www.waypointanalytical.com
Farm: WB
Date Received: 04/02/2020
Date of Report: 04/06/2020
Lab No Field ID
Sample ID
Soil Class HM% W/V pH
Ac
P-1
K-1
S-1
Mn-I
Zn-I
Zn-AI
Cur-1
CEC
BS%
Ca%
Mg%
ESP Na SS-1 NOSN
20784
96
MIN 2.2
1.2 5.6
2.7
164
23
37
56
213
213
35
7.4
63
51
10
1.0 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.1
N
160
PZO5
0
KZO
93
S
0
Mn
0
Mn-AI
57
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20785
97
MIN 2.7
1.4 5.6
2.7
167
28
37
56
225
225
40
7.6
65
51
10
1.1 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.1
N
160
PZO5
0
KZO
82
S
0
Mn
0
Mn-AI
57
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20786
98
MIN 2.0
1.3 5.6
2.3
166
28
33
63
213
213
40
7.2
68
53
12
0.9 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.9
N
160
PZO5
0
KZO
82
S
0
Mn
0
Mn-AI
61
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20788
99
MIN 2.2
1.2 5.5
2.2
176
29
35
63
228
228
40
7.1
70
55
11
1.1 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
1.0
N
160
PZO5
0
KZO
80
S
0
Mn
0
Mn-AI
62
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20789
100
MIN 2.2
1.4 5.6
2.2
162
22
40
56
225
225
45
7.1
70
56
11
1.2 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.9
N
160
PZO5
0
KZO
95
S
0
Mn
0
Mn-AI
57
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20790
101
MIN 2.2
1.2 5.9
2.5
168
28
27
56
223
223
35
7.6
68
53
12
0.8 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.5
N
160
PZO5
0
KZO
82
S
0
Mn
0
Mn-AI
52
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20791
102
MIN 3.2
1.3 5.7
2.5
162
27
25
56
215
215
35
7.1
65
52
10
0.6 0
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.8
N
160
PZO5
0
KZO
84
S
0
Mn
0
Mn-AI
55
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20792
103
MIN 2.4
1.4 5.7
2.5
160
27
29
56
205
205
35
7.0
64
51
11
0.9 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.8
N
160
PZO5
0
KZO
84
S
0
Mn
0
Mn-AI
55
Zn
0
Cu
0
B
0
Mg
0
Last Crop
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Carolina, Inc.

Page 2 of 2
Report No: 20-093-0571
Account No: 04596
Advisor: Soil Plus, LLC
Joyce Barrette
P.O. Box 1396
Oxford NC 27565
Waypoint"'o
ANALYTICAL
Client: Atlantic OBX
2850 Daisy Lane, Wilson, NC 27896
Main 252-206-1721 ° Fax [phone]
www.waypointanalytical.com
Farm: WB
Date Received: 04/02/2020
Date of Report: 04/06/2020
Lab No Field ID
Sample ID
Soil Class HM% W/V pH
Ac
P-1
K-1
S-1
Mn-I
Zn-I
Zn-AI
Cur-1
CEC
BS%
Ca%
Mg%
ESP Na SS-1 NO N
120793
104
MIN 3.1
1.4 5.7
2.6
156
24
27
56
198
198
35
7.1
63
50
10
0.8 0.1 I
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.9
N
160
PZO5
0
KZO
91
S
0
Mn
0
Mn-AI
55
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20794
105
MIN 2.2
1.3 5.7
2.3
157
26
27
63
203
203
35
6.8
67
53
11
0.8 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.8
N
160
PZO5
0
KZO
86
S
0
Mn
0
Mn-AI
59
Zn
0
Cu
0
B
0
Mg
0
Last Crop
20795
106
MIN 2.7
1.3 5.7
2.4
157
22
27
56
198
198
35
6.7
64
51
11
0.8 0.1
Crop Recommendations:
1- Corn
Rec Uom
lb/acre
Lime (Vacre)
0.8
N
160
PZO5
0
KZO
95
S
0
Mn
0
Mn-AI
55
Zn
0
Cu
0
B
0
Mg
0
Last Crop
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Carolina, Inc.