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HomeMy WebLinkAboutNCG240019_MONITORING INFO_20191118PERMIT NO DOC TYPE DOC DATE STORMWATER DIVISION CODING SHEET NCG PERMITS /vc,&JvuoI q ❑ HISTORICAL FILE N MONITORING REPORTS i ❑ anl� YYYYM M D D Quarterly Stormwater Discharge Monitoring Report for North Carolina Division of Water Quality General Permit No. NCG240000 Date submitted 11/7/2019 CERTIFICATE OF COVERAGE NO. NCG240019 FACILITY NAME Mecklenburg County Compost Central (new) COUNTY Mecklenburg PERSON COLLECTING SAMPLES Khaliem Adams LABORATORY: Pace Analytical Services Lab Cert. # 192 Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR _2019 SAMPLE QUARTER ❑ Jan -March ❑ April -June ❑ July -Sept ❑ Oct -Dec or ® Monthly' October (month) DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA ECEIVED ❑Zero -flow ❑Water Supply ❑SA NOV 19 2019 ❑other CENTRAL FILES DrAfR SECTIOP.r Total event rainfall z 0.68 in or ❑ No discharge this period3 Date Sample Collected' (mo/dd/yr) Outfall No. TSS COD Fecal coliform Total nitrogen Total phosphorus Total copper Total lead Total zinc pH Parameter benchmarks =__> 100 mg/L4 120 mg/L 1000 col./100 mL 30 mg/L 2 mg/L 0.010 mg/L 0.075 mg/L 0.126 mg/L 6-9 10/16/2019 1 17.2 180 6000 4.5 1.1 0.0071 <0.0050 <0.010 6.83 ' Monthly sampling (instead of quarterly) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. 3 For sampling periods with no discharge, you must still submit this discharge monitoring report with a checkmark here. 'The TSS benchmark value is 100 mg/L; except when discharging to ORW, HQW, Trout, and PNA waters in which case the benchmark is 50 mg/L. Permit Date:10/1/2011-9/30/2016 Last Revised 12/02/11 Page 1 of 2 Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month. Date Sample Collected' (mo/dd/yr) Outfall No. pH TPH using method 1664ASGT-HEM TSS Total Rainfa112 Check if No Flow This Period' Average New Motor Oil Usage 6-9 15 mg/L 100 mg/1-4 - - 10/16/2019 1 6.83 c5.0 17.2 0.68 75 gal/mopnth Footnotes from Part A also apply to this Part B FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ® NO ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ® NO ❑ REGIONAL OFFICE CONTACT NAME: Teresa Bradford Mail an oriainal and one copv of this DMR, including all "No Discharge" reports within 30 days of receipt of the lab results for at end of monitoring period in the case of "No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant analties for submitting false information, including the possibility of fines and imprisonment for knowing violations." (Signature of Permit Date: Last Revised 12/02/11 Page 2 of 2 Facility Name I Sample Location I Sample Time I pH I Date I Device Used to Sample Mecklenburg County Compost Central (new) I Outfall 1 1 1236 1 6.83 10/16/2019 Horiba pH-110 meter Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance onfilling our this form, please visit littps://deg.iic.gov/about/divisions/enerev-mineral-land- resources/enerev-mineral-land-perm is/stormrvater-perirtits/npdes-industrial-stv#tab-4 Permit No.: or Certificate of( Facility Name: N60 �1 M e(Umb q -y U County: (IK u I Phone No. Inspector: Kh& 11 PAq, Mums Date of Inspection: 10 161au l l I Time of Inspection: VJ J Total Event Precipitation (itches): 0. � 8 No.: NlC/G/a l7 / /U F r?4fcj (oew All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local stornt events during the sampling period, and the perntittee obtains approval from the local DEMLR Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) 1. Outfall Description: D ,pp pp I Outfall No. I Structure (pipe, ditch, etc.): (! Receiving Stream: Describe the indusgial activities that occur within the outfall drainage area: tl- (' /tJV1d1 n Ct nn n Page 1 of 2 SIVU-242, Last modified 07/2S/2017 2 Color: Describe the color of tlj, discharge using basic colors i (light, medium, dark) as descriptors: IVU AA QM f';D '!l fa ( �'— brown, blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may h ve (i.e., smells strong gly of oil. weak chlorine odor. etc.): S (r C b� C t�71 , m o si I i k l �I �MV � 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 O o 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge. where I is no solids and 5 is/thee surface covered with floating solids: v 1 2 13' 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge. where 1 is no solids and 5 is extremely muddy: 1 2 t / 4 5 �I 7. Is there any foam in the stormwater discharge? () Yes 0/I�10. 8. Is there an oil sheen in the stormwater discharge? ()Yes OK" 0. o 9. Is there evidence of erosion or deposition at the outfall? O Yes VINO. to. Other Obvious A Indicators of Stormwater Pollution: List and describe /7Q Vote: Low clarity, high solids, and/or the presence of foamy oil sheen, or erosion/depositiou may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SRV-242, Last modified 07/2812017 I Ak E '� .�, �^T 1 � i�� e i P.�ti�yy' 111 ♦' 1� c+Ps ��t j i' � lid ���4, }��I ��1!'iEI��• �yE W( !+4 ace Analytical w,rwpacelaaswm October 23, 2019 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: Compost Central 2 Pace Project No.: 92449835 Dear Darren Steinhilber: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on October 16, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wdden consent of Pace Analytical Services, LLC. Page 1 of 17 aceAnalytical wwwpacelabs.com Project: Compost Central 2 Pace Project No.: 92449835 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification It 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinkino Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 17 Pace Analytical Services, LLC ® 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville, NC 28078 wmvpacelbbs.mm (704)875-9092 Project: Pace Project No.: Compost Central 2 92449835 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92449835001 Outfall 1 EPA 1664B HH 1 PAST-C EPA 200.7 Rev 4.41994 IDS 3 PASI-A SM 92220-2006 KDF 1 PASI-C SM 2540D-2011 CEH 1 PASI-A TKN+NO3+NO2 Calculation EWS 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.01993 KDF1 1 PASI-A SM 5220D-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, -LC. Page 3 of 17 lace Analytical w ,pacelsbs.mm ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central 2 Pace Project No.: 92449835 Sample: Outfall 1 Lab ID: 92449835001 Collected: 10/16/19 12:50 Received: 10/16119 13:05 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664E Total Petroleum Hydrocarbons NO mg/L 5.0 1 10/19/19 10:13 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper 0.0071 mg/L 0,0050 1 10/17/1922:15 10119/1920:37 7440-50-8 Lead NO mglL 0.0050 1 10/17/1922:15 10/19/1920:37 7439-92-1 Zinc NO mg/L 0.010 1 10/17/1922:15 10/19/1920:37 7440-66-6 MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 6000 CFU/100 mL 1.0 1 10/16/19 17:12 10/17/19 15:20 u2 2640D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 17.2 mg/L 9.8 1 10/19/19 02:15 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Total Nitrogen 4.5 mg/L 0.52 1 10/23/19 10:38 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total 4.4 mg/L 0.50 1 10/22/19 06:18 10/23/19 02:03 7727-37-9 353.2 Nitrogen, NO2/1403 pros. Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, NO2 plus NO3 0.044 mg/L 0.040 1 10/18/19 22:25 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 1.1 mg/L 0.050 1 10/17/1919:46 10/18/1911:49 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 180 mg/L 25.0 1 10117/1919:10 10118/1915:22 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 17 aceAnalytical wwwpacalabs.cam QUALITY CONTROL DATA Project: Compost Central 2 Pace Project No.: 92449835 QC Batch: 504623 Analysis Method: EPA 1664B �QC Batch Method: EPA 16640 Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92449835001 METHOD BLANK: 2711891 Associated Lab Samples: 92449835001 Parameter Units Total Petroleum Hydrocarbons mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 5.0 10/1911910:01 LABORATORY CONTROL SAMPLE: 2711892 Spike LCS Parameter Units Conc. Result Total Petroleum Hydrocarbons mg/L 20 18.3 MATRIX SPIKE SAMPLE: 2711893 92449809003 Spike Parameter Units Result - Conc. Total Petroleum Hydrocarbons mg/L NO 20 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LCS % Rec e/ Rec Limits Qualifiers 92 64-132 MS MS % Rec Result % Rec Limits Qualifiers 17.4 84 64-132 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC Page 5 of 17 aceAnalytical ii wrpacelebs.wrn QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central 2 Pace Project No.: 92449835 OC Batch: 504348 Analysis Method: EPA 200.7 Rev 4.4 1994 'OC Batch Method: EPA 200.7 Rev 4.41994 Analysis Description: 200.7 MET Associated Lab Samples: 92449835001 METHOD BLANK: 2710597 Matrix: Water Associated Lab Samples: 92449835001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L NO 0.0050 10/1911919:55 Lead mg/L NO 0.0050 10/19/1919:55 Zinc mg/L NO 0.010 10/19/1919*55 LABORATORY CONTROL SAMPLE: 2710598 Spike LCS LCS % Rec Parameter Units Cone. Result e/ Rec Limits Qualifiers Copper mg/L 0.5 0.48 96 85-115 Lead mg/L 0.5 0.47 94 85-115 Zinc mg/L 0.5 0.46 93 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710599 2710600 MS MSD 92449710001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone, Result Result e/ Rec e/ Rec Limits RPD Qual Copper mg/L 76.3 0.5 0.5 0.58 0.59 100 102 70-130 2 ug/L Lead mg/L 11.8 0.5 0.5 0.48 0.49 94 96 70-130 2 ug/L Zinc mg/L 196 0.5 0.5 0.67 0.68 94 98 70-130 2 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710601 2710602 MS MSD 92449873001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result e/ Rec e/ Rec Limits RPD Qual Copper mg/L 39.4 0.5 0.5 0.51 0.52 95 96 70-130 1 ug/L Lead mg/L NO 0.5 0.5 0.47 0.47 93 93 70-130 0 Zinc mg/L 38.5 0.5 0.5 0.51 0.51 94 95 70-130 1 ug/L Results presentee on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, L-C. Page 6 of 17 Pace Analytical Services, LLC 0 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville, NC 28078 wwwpacelaescnm (704)875-9092 QUALITY CONTROL DATA Project: Compost Central 2 Pace Project No.: 92449835 OC Batch: 504018 Analysis Method: SM 9222D-2006 OC Batch Method: SM 92220-2006 Analysis Description: 9222D Fecal Colifonn(MF) - CHT Associated Lab Samples: 92449835001 METHOD BLANK: 2708966 Matrix: Water Associated Lab Samples: 92449835001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 10/17/19 15:20 SAMPLE DUPLICATE: 2708967 92449863001 Cup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 m- 6000 600 164 D6,u2 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written mnsentof Pace Analytical Services, LLC. Page 7 of 17 (�IaceAnalytical rmw.pacelabs con, QUALITY CONTROL DATA Project: Compost Central 2 Pace Project No.: 92449835 QC Batch: 504598 Analysis Method: SM 254OD-2011 OC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92449835001 METHOD BLANK: 2711843 Associated Lab Samples: 92449835001 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 2.5 10/19/19 02:12 LABORATORY CONTROL SAMPLE: 2711844 Spike Parameter Units Conc. Total Suspended Solids mg/L 250 Pace Analytical Services, LLC 9900 Kincey Ave. Suite 100 Huntersville, NC 26078 (704)975-9092 LCS LCS % Rec Result % Rec Limits Qualifiers 242 97 90-110 SAMPLE DUPLICATE: 2711869 92449887003 Dup Parameter Units Result Result Total Suspended Solids mg/L 218 162 SAMPLE DUPLICATE: 2711870 - 92449937001 Dup Parameter Units Result Result Total Suspended Solids mg/L 62900 ug/L 37.1 RPD Qualifiers 29 D6 RPD Qualifiers 52 D6 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/23/2019 10:47 AM without the whiten consent of Pace Analytcal Services, L-C. Page 8 of 17 aceAnalytical mvxpacalabs.mm Project: Compost Central 2 Pace Project No.: 92449835 QC Batch: 504887 QC Batch Method: EPA 351.2 Rev 2.0 1993 Associated Lab Samples: 92449835001 METHOD BLANK: 2713034 Associated Lab Samples: 92449835001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 2713035 Parameter Units Nitrogen, Kjeldahl, Total mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Matrix: Water Blank Reporting Result. Limit. Analyzed Qualifiers ND . 0.50 10/23/19 01:59 Spike LCS LCS % Rec Cone. Result e/ Rec Limits Qualifiers 10 9.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2713068 2713069 MS MSD 92449835001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 4.4 10 10 14.7 13.9 103 94 90-110 6 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 17 aceAnalytical w,v✓/pacelabs.cnm Project: Compost Central 2 Pace Project No.: 92449835 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA QC Batch: 504417 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Associated Lab Samples: 92449835001 METHOD BLANK: 2710770 Associated Lab Samples: 92449835001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 2710771 Parameter Units Nitrogen, NO2 plus NO3 mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.040 10/18/1921:56 Spike LCS LCS % Rec Conic. Result %Rec Limits Qualifiers 2.5 2.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710772 2710773 MS MSD 92449772009 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result a/ Rec % Rec Limits RPD Qual ,Nitrogen, NO2 plus NO3 mg/L 0.043 2.5 2.5 1.2 1.2 47 46 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710774 2710775 MS MSD 92449772010 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual -Nitrogen, NO2 plus NO3 mg/L NO 2.5 2.5 2.5 2.5 98 99 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, L-C. Page 10 of 17 ace Analytical r ..pacelabs.cnrn Project: Compost Central 2 Pace Project No.: 92449835 QC Batch: 504316 QC Batch Method: EPA 365.1 Rev 2.0 1993 .Associated Lab Samples: 92449835001 METHOD BLANK: 2710270 Associated Lab Samples: 92449835001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 2710271 Parameter Units Phosphorus mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 10/18/1911:34 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710272 2710273 MS MSD 92448944002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Phosphorus mg/L 5.2 2.5 2.5 7.7 7.7 102 102 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710274 2710275 MS MSD 92448950002 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Conc Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 4.2 2.5 2.5 6.6 6.7 96 101 90-110 2 Results presented on this page are in the units Indicated by the "Units" column exceplwhere an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 17 aceAnalytical mrwpacelabs.mm `Project: Compost Central 2 Pace Project No.: 92449835 QC Batch: 504334 'QC Batch Method: SM 5220D-2011 Associated Lab Samples: 92449835001 'METHOD BLANK: 2710417 Associated Lab Samples: 92449835001 Parameter Chemical Oxygen Demand QUALITY CONTROL DATA Analysis Method: SM 5220D-2011 Analysis Description: 5220D COD Matrix: Water Blank Reporting Units Result Limit Analyzed mg/L ND 25.0 10/18/1915:18 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, 128078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2710418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand mi 750 750 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710419 2710420 MS MSD 92449632006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec °A Rec Limits RPD Qual Chemical Oxygen Demand mg/L 362 100 100 464 457 102 95 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2710421 2710422 MS MSD 92449936005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Chemical Oxygen Demand mg/L 85.0 100 100 184 189 99 104 90-110 3 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC. Page 12 of 17 aceAnalytical imwpacelabs.com QUALIFIERS Project: Compost Central 2 Pace Project No.: 92449835 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. NO - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) CUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not Detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyle is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. u2 Colonies are too numerous to count. Actual result may be greater than reported. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 10/23/2019 10:47 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 aceAnalytical x,mvpacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Compost Central 2 Pace Project No.: 92449835 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92449835001 Outfall 1 EPA 1664B 504623 92449835001 Outfall1 EPA 200.7 Rev 4.41994 504348 EPA 200.7 Rev 4.41994 504398 —92449835001 Outfall 1 SM 9222D-2006 504018 SM 9222D-2006 504019 92449835001 Outfall 1 SM 2540D-2011 504598 92449835001 Outfall1 TKN+NO3+NO2 505238 Calculation 92449835001 Outfall 1 EPA 351.2 Rev 2.0 1993 504887 EPA 351.2 Rev 2.01993 505157 92449835001 Ouffall 1 EPA 353.2 Rev 2.0 1993 504417 92449835001 Outfall 1 EPA 365.1 Rev 2.0 1993 504316 EPA 365.1 Rev 2.0 1993 504379 92449835001 Outfall 1 SM 5220D-2011 504334 SM 5220D-2011 504536 Date: 10/23/2019 10:47 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, LLC. Page 14 of 17 Document Name: Document Revised: February 7, 2018 ace Analytical` Sample Condition Upon Recei t(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Client Name: Huntersville [l/ Raleigh[] Mechanicsville❑ WO#992449Q35 11111111311111111 B11 � 9244Pd835 Custody Seal Present? ❑Yes Q?To Seals Intact? ❑Yes QNo Datelinitials Person Examining Contents: 1 10 Packing Material: ❑Bubble Wrap ❑BubbleBags 05one ❑ Other Biological Tissue Frozen? / Thermometer; Oyes ❑No ❑N/A /❑Ifl Gun ID: Type of ire: Vet ❑Blue ❑None Cooler Temp ('Q: _ ,$�049. � orrection Factor: Add/Subtract (-C) 0.0 ,(Z, Temp should be above freezing to 6'C Cooler Temp Corrected('C):' - []Samples out of temp criteria. Samples on ice; cooling process USDA Regulated Soil / hasbegun gu (QN/A, water sample) Old samples originate in aquarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, nyer nNG Comments/Discrepancy: Chain pf Custody Present? QYes ONO N/A 1. Samples Arrived within Hold Time? es ❑No ❑N/A 2. Short Hold Time Analysts 02 hr.)? ❑Ye:. No N/A 3. Rush TurnAround Time Requested? Oyes IdN/o ❑N/A q, Sufficient Volume? es ONO N/A S. Correct Containers lased? dyg5 ONO ❑N/q 6. -Pace Containers Used? Y/es No ❑N/A Containers Intact? es ONO N/A 7. Dissolved analysis: Samples Held Filleted? ❑Yes- ❑No N/A B. Sample Labels Match COC? /(Yes ONO ❑N/A 9. _ -Include_; Date/Time/ID/Analysis Matrix:_ j1 —/ - 1 _ Headspacein VOA Vials (x5-6mm)? ❑Yes N ❑N/A 10. Trip Blank Preser.l7 ❑ves o ❑N/A 11. Trip Blank Custody Seals Present? Yes ❑No N/A COMMENTS/SAMPLk DISCREPANCY Field Data Required? ❑Yes []NO CLIENT NOTIFICATION/RESOLUTION Lot ID of split containers' _ Person contacted: Date/Time: Project Manager SCURF Review: I r Date: WN(, I �S —tr Project Manager SRF Review; Date Page 15 of 17 � TCeAnalyhC8/ Document Name: Sample Condition Upon Recel t SCUR Document Revised: February 7, 2018 Page 1 of 2 Document No.: FCAR•CS-033-Rev.06 ISSuing Authority: Pace Carolinas Quality Office 'Check mark top half of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project # WO# : 9244983g — — PM: MWB Due Date: 10/23/19 CLIENT: 92-MECK CO OJ 2 u `o. M a n t a n n o 6 2 a i _ a o N G a v j .Y a d n x n 2 .« n E m O x Y n c 6 N @ `� N = m _ E i O 2 n x Z a E a $T m ' 9 a E v V L 2 . L J a w U n v = Z a u 0 = a u n < of to v a Z d i to Z n O 2 ¢ E H to u ¢ `• a Q E n 1 M a ? S a E O1 z m O Z O > E V a ice O E pz 2 O > E� V Q m VI 1l n O > S Y J s S x 9 V 9 u 6 w ,n E I a e N E G n^ P Z - n E IV M a 2 E. 7 ¢ E 33 z a U a D E G 1 1 l I 2 3 4 5 6 l 7 8 9 i 30 — 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time Preservation adjusted Amount of Preservative added Lot e Note: whenever mere 45 a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, Incorrect preservatNe, out of temp, Incarrect containers. Page 16 of 17 CHAIN -OF -CUSTODY / Analytical Request Document The Chain-of-Custodyisa LEGAL. DOCUMENT. All relevant Gelds must becompleted accurately. Section A section a Required Client Information: Reggimd Protect Infom almn: Invoice Information: Camas: Company. Merhlenpurg Count Solid Wdsle- Report To: Kltaliem Adams Alfmnlion' 11 Page' 1 Of t Adtlrossl 2145 Sultle Ave. Cap, To: N. CturroOe. NC 28209 Emma r g kmaliem.adams metltlenEu must rc. ov Purrttase Order e: E Ra ul- Plane: (980)314-WW Fax Due Data: Prgect Maitre: Compost Central2 Prc w Y: 3201-1 NC . . •�. "s:,_ R usaNE Aiu FiRerad - uArau cane awugwuu „ - o : COLLECTED o Preservatives > 1 ec Ms, _ i ow wu rm d e SAMPLE ID aw u im,. Op wsam a One Character per boa. ww wa START END z x 2 = (AZ, 0-91,-) a, ul a SamPla Ids must be unique Tom -is — =e w xs Na LLN _ p m p wW TIME DATE TIME z Gi/Cp3 Y, i; 2 3, 5f: -•sz: .10 '+12^ a}- �k.,M01TroW1LCOMMFfRS ! .- } T7, - - .':.. .:_ '_-:REL41p1Y5t®6Y .•• I AF'AWTIaN a.• }. WTE „L TNE.-� .-n-oo£n BYlAFR4KTgN _ h0A `TWE SN1 PIE CANO }:±�. r./ _ �_. rflgNfi'S. / 5. ,� d 0 J Quarterly Stormwater Discharge Monitoring Report for North Carolina Division of Water Quality General Permit No. NCG240000 Date submitted 9/10/2019 CERTIFICATE OF COVERAGE NO. NCG240019 FACILITY NAME Mecklenburg County Compost Central (new) COUNTY Mecklenburg PERSON COLLECTING SAMPLES Khaliem Adams LABORATORY: Pace Analytical Services Lab Cert. # 192 Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR 2019 SAMPLE QUARTER ❑ Jan -March ❑ April -June ❑ July -Sept ❑ Oct -Dec c^ � (& Monthly' August (month) DISCHAR NG�O C'LA55 ❑ORW ❑HQW ❑Trout ❑PNA UCT 0 y 2019 ❑Zero -flow ❑Water Supply ❑SA CENTRAL FILES [—]Other DwR SECTION Total event rainfall z 2.2 in or ❑ No discharge this period] Date Sample Collected' (mo/dd/yr) Outfall No. TSS COD Fecal coliform Total nitrogen Total phosphorus Total copper Total lead Total zinc pH Parameter benchmarks =__> 100 mg/L° 120 mg/L 1000 col./100 mL 30 mg/L 2 mg/L 0.010 mg/L 0.075 mg/L 0.126 mg/L 6-9 8/02/2019 1 15.0 148 6000 3.0 1.5 <0.0050 <0.0050 <0.010 7.02 ' Monthly sampling (instead of quarterly) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. 3 For sampling periods with no discharge, you must still submit this discharge monitoring report with a checkmark here. 'The TSS benchmark value is 100 mg/L; except when discharging to ORW, HOW, Trout, and PNA waters in which case the benchmark is 50 mg/L. Permit Date:10/1/2011-9/30/2016- - -- - - ._ Last Revised 12/02/11 Page 1 of 2 Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month. Date Sample Collected' (mo/dd/yr) Outfall No. pH TPH using method 1664A SGT-HEM TSS Total Rainfall' Check if No Flow This Perlod3 Average New Motor Oil Usage 6-9 15 mg/L 100 mg/L4 - - 8/02/2019 1 7.02 <4.9 15.0 2.2 75 gal/month Footnotes from Part A also apply to this Part B FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ® NO ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ® NO ❑ REGIONAL OFFICE CONTACT NAME: Teresa Bradford Mail an original and one copy of this DMR including all "No Discharge" reports within 30 days of receipt of the lab results for at end of monitoring period in the case of No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." We of PeFrWittee) Date:40/1/2011-9/30/2016- F io (Date) _Last Revised 12/02/11 Page 2 of 2 Facility Name I Sample Location Sample Time pH I Date Device used to Sample Mecklenburg County Compost Central (new) I Outfall 1 941 7.02 1 8/2/2019 Horiba pH-110 meter laceAnalyficalo �1 w wpacelabscom August 12, 2019 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: Compost Central 2 Pace Project No.: 92439682 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Darren Steinhilber: Enclosed are the analytical results for sample(s) received by the laboratory on August 02, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste Q PCCRfO 2� 'TKO t� TNI qep pt0Q'L�' '. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 16 aceAnalj6cal ~eacelabs.= Project: Compost Central 2 Pace Project No.: 92439682 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntemwile, NC 28078 (704)875-9092 Charlotte Certification IDs 9800 Kinney Ave. Ste 100, Hunlersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #:40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 aceAnalytical mrwpacelses.mm SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: Pace Project No.: Compost Central 92439682 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92439682001 Outfall 1 EPA 1664B JMS 1 PASI-C EPA 200.7 Rev 4.41994 SH1 3 PASI-A SM 254OD-2011 JP1 1 PASI-A TKN+NO3+NO2 Calculation DIN 1 PASI-A EPA 351.2 Rev 2.0 1993 IFO 1 PASI-A EPA 353.2 Rev 2.01993 DMN 1 PASI-A EPA 365.1 Rev 2.01993 MDW 1 PASI-A SM 522OD-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of PaceAnalytical Services, I.I.C. Page 3 of 16 Pace Analytical Services, LLC ace Ap ® 9800 Kincey Ave. Suite 100 r rialyfical Hunteraville, NC 2807B awwPacelatiscon (704)875-9092 ANALYTICAL RESULTS Project: Compost Central 2 Pace Project No.: 92439682 Sample: OutfallI Lab ID: 92439682001 Collected: 08/02/1909:41 Received: 08102/1910:01 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons ND mg/L 4.9 1 08/07/19 06:12 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper NO mg/L 0.0050 1 08/07/1914:49 08/08/1909:41 7440-50-8 (Lead NO mg/L 0.0050 1 08/07/1914:49 08/08/1909:41 7439-92-1 Zinc NO mg/1- 0.010 1 08/07/19 14:49 08/08/19 09,41 7440-66-6 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 15.0 mg/L 12.5 1 08/08/19 05:32 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Total Nitrogen 3.0 mg/L 0.52 1 08/12/19 10:21 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 :Nitrogen, Kjeldahl, Total 3.0 mg/L 0.50 1 08/09/1907:05 08/10M901:25 7727-37-9 i353.2 Nitrogen, NO2/NO3 pros. Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, NO2 plus NO3 NO mg/L 0.040 1 08/07/19 12:01 ''366.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 1.6 mg/L 0.050 1 08/07/19 14:40 08/07/19 21:41 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 148 mg/1- 25.0 1 08/05/1917:00 08/05/1922:14 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 4 of 16 aceAnalytical wwwpacelabccwrl QUALITY CONTROL DATA Project: Compost Central 2 Pace Project No.: 92439682 QC Batch: 490732 Analysis Method: EPA 1664B QC Batch Method: EPA 1664E Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92439682001 METHOD BLANK: 2647150 Matrix: Water Associated Lab Samples: 92439682001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L NO 4.8 08/07/19 06:05 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2647151 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 19.2 19.9 104 64-132 MATRIX SPIKE SAMPLE: 2647152 92438965001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L NO 19.2 18.9 98 64-132 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This repod shall not be reproduced, except in full, Dale: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 16 lceAnalyticala aww.pacelabs.mm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ,Project: Compost Central 2 'Pace Project No.: 92439682 QC Batch: 490446 Analysis Method: EPA 200.7 Rev 4.4 1994 OC Batch Method: EPA 200.7 Rev 4.41994 Analysis Description: 200.7 MET Associated Lab Samples: 92439682001 .,METHOD BLANK: 2645886 Matrix: Water Associated Lab Samples: 92439682001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L ND 0.0050 08/08/1913*37 Lead mg/L NO 0.0050 08/08/1913:37 .Zinc mg/L NO 0.010 08108/1913:37 LABORATORY CONTROL SAMPLE: 2645887 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Copper mg/L 0.5 0.48 96 85-115 Lead mg/L 0.5 0.48 95 85-115 Zinc mg/L 0.5 0.48 96 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2645888 2645889 MS MSD 92439268001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc, Result Result %Rec %Rec Limits RPD Qual Capper mg/L 3790 0.5 0.5 4.3 4.2 97 75 70-130 3 ug/L Lead mg/L NO 0.5 0.5 0.30 0.30 60 60 70-130 0 M1 Zinc mg/L 10400 0.5 0.5 10.6 10.4 46 -4 70-130 2 E,M1 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2645890 2645891 MS MSD 92439604005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Copper mg/L 95.3 0.5 0.5 0.58 0.58 97 97 70-130 0 ug/L Lead mg/L 7.6 ug/L 0.5 0.5 0.45 0.46 89 90 70-130 1 Zinc mg1L 446 0.5 0.5 0.93 0.94 97 99 70-130 1 uglL Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 16 lceAnalyticalo wmypacelabscnm Project: Compost Central 2 Pace Project No.: 92439682 QC Batch: 491038 QC Batch Method: SM 254OD-2011 Associated Lab Samples: 92439682001 METHOD BLANK: 2648415 'Associated Lab Samples: 92439682001 Parameter Total Suspended Solids QUALITY CONTROL DATA Analysis Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers mg/L NO 2.5 08/08/19 05:32 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2648416 Spike LCS LCS % Rec Parameter Units Conic. Result %Rec Limits Qualifiers Total Suspended Solids mg/L 250 240 96 90-110 SAMPLE DUPLICATE: 2648417 92439753001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mglL 242 182 28 D6 SAMPLE DUPLICATE: 2648418 92439682001 Dup Parameter Units. Result Result RPD Qualifiers Total Suspended Solids mg/L 15.0 15.0 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 16 aceAnalytical wawpacelabs.mm QUALITY CONTROL DATA .Project: Compost Central 2 Pace Project No.: 92439682 OC Batch: 491288 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN .Associated Lab Samples: 92439682001 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 2649896 Matrix: Water Associated Lab Samples: 92439682001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Kjeldahl, Total mg/L NO 0.50 08/10/19 01:04 LABORATORY CONTROL SAMPLE: 2649897 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/L 10 9.7 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2649898 2649899 MS MSD 92439088001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 5.3 10 10 11.8 13.3 64 80 90-110 12 M1,Rl MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2649900 2649901 MS MSD 92439665001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result. Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 1.3 10 10 8.9 10 76 87 90-110 11 M1,R1 Results presented on this page are in the units Indicated by the 'Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 16 aceAnalytical awwpacalobs.cam .Project: Compost Central 2 'Pace Project No.: 92439682 QC Batch: 490799 QC Batch Method: EPA 353.2 Rev 2.0 1993 Associated Lab Samples: 92439682001 METHOD BLANK: 2647317 Associated Lab Samples: 92439682001 Parameter Units Nitrogen, NO2 plus NO3 mg/L I LABORATORY CONTROL SAMPLE: 2647322 Parameter Units Nitrogen, NO2 plus NO3 mg/L. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)975-9092 QUALITY CONTROL DATA Analysis Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 08/07/1911:40 Spike LCS LCS e/ Rec Cone. Result %Rec Limits Qualifiers 2.5 2.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2647323 2647324 MS MSD 92439968001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result e/ Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.13 2.5 2.5 2.6 2.6 99 99 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2647325 2647326 MS MSD 92439924001 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Cone. Conic. Result Result % Rec % Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.11 2.5 2.5 2.5 2.6 97 98 90-110 0 Results presented on this page are In the units Indicated by the "Units" Column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 aceAnalytical a �. rvwwpocolobs.mm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central 2 Pace Project No.: 92439682 �QC Batch: 490742 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92439682001 METHOD BLANK: 2647173 Associated Lab Samples: 92439682001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 2647174 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.050 08107/1921:29 Spike LCS LCS % Rec Conc. Result %Rec Limits Qualifiers 2.5 2.5 102 90-110 MATRIX SPIKE& MATRIX SPIKE DUPLICATE: 2647175 2647176 MS MSD 92439511002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.089 2.5 2.5 2.7 2.7 104 105 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2647177 2647178 MS MSD 92439511004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.14 2.5 2.5 2.7 2.8 104 105 90-110 1 Results presented on this page are in the units in Heated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 16 aceAnalytical w wpacelabs.anm Project: Compost Central 2 Pace Project No.: 92439682 QC Batch: 490421 QC Batch Method: SM 522OD-2011 Associated Lab Samples: 92439682001 (METHOD BLANK: 2645781 Associated Lab Samples: 92439682001 Parameter Units Chemical Oxygen Demand mg/L LABORATORY CONTROL SAMPLE: 2645782 l Parameter Units . Chemical Oxygen Demand mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: SM 5220D-2011 Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 25.0 08/05/19 22:09 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 750 758 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2645783 2645784 MS MSD 92439609001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand hi 17600 100 100 17900 17700 282 94 90-110 1 M1 . MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2645785 2645786 MS MSD 92439538001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 143 100 100 219 223 75 80 90-110 2 M1 Results presented on this page arc In the units indicated by the"Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytical Services, LLC, Page 11 of 16 aceAnalytical. w wpaoabbs.can QUALIFIERS (Project: Compost Central 2 'Pace Project No.: 92439682 DEFINITIONS OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit. Pace Analytical Services, Li 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 POL- Practical Quantilation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Chadotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. E Analyte concentration exceeded the calibration range. The reported result is estimated. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 10:24 AM without the written consent of Pace Analytcal Services, LLC. Page 12 of 16 aceAnalytical ' wmvpacalabs.cnm QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central Pace Project No.: 92439682 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92439682001 Outfall 1 EPA 1664B 490732 92439682001 Outfall 1 EPA 200.7 Rev 4.4 1994 490446 EPA 200.7 Rev 4.4 1994 490974 92439682001 Outfall 1 SM 254OD-2011 491038 1,92439682001 Outfall1 TKN+NO3+NO2 491702 Calculation 192439682001 Outfall 1 EPA 351.2 Rev 2.0 1993 491288 EPA 351.2 Rev 2.0 1993 491554 92439682001 OutfallI EPA 353.2 Rev 2.01993 490799 92439682001 Outfall 1 EPA 365.1 Rev 2.0 1993 490742 EPA 365.1 Rev 2.0 1993 490995 92439682001 Outfall 1 SM 5220D-2011 490421 SM 5220D-2011 490463 Date: 08/12/2019 10:24 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 16 Document Name: Document Revised: February7, 2018 Sample Condition Upon Receipt(SCUR page 1 of 2 i ;8CEa4p8�}/fIC2�� Document No.: issuing Authority: F-CAR-CS-033-Aev.06 Pace Carolinas Quality of Ice Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville� Raleigh❑ Mechanicsville❑ : 92439682 Client Name: ProWO# ie� a. LK - < o II �II II I II III III Courier: ❑Fed Ex ❑UPS ❑Commercial ❑Pace PS ❑Other._ Client 92439682 Custody Seal Present? ❑Yes No Sealslntact? []Yes ❑No ccls—z —� Examining Contents. Date/loltlals Person Packing Matedal: []Bubble Wrap ❑Bubble Bags ❑None ❑ Other Thermometer: Gun ID: 92TO48 Typeowet flce: ® ❑Blue _ Cooler Temp ('C): C! Correction Factor: Add/Subtract('C) 0.0 Cooler Temp Corrected(` a USDA Regulated Sail ( -NIA, water sample) Did samplesotiginpte li a quarantine zone within the United Slates: CA, NY, or SC (check maps)? Biological Tissu en? []Yes ❑No N/A []None Tempshould be above freezing to VC ❑samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (inle nally, VYes UNo - Comments/oiscrepancv: . Chain of Custody Present? aM—Yes ❑NO. ❑N/A 1. Sam- les Aalved within Hold Tfine? -QY6 ONO ❑N/A 2. Short Held Time AnalySis (<72 hr.l? es DR3 ❑IV/A 3. Rush Turn Around Time Requested? ❑Yes ❑ff�D ❑N/A 4. Sufficient Volume? OYe No ❑N/a S. Correct Containers Used? Oly¢s ONO ❑N/A 6. -Pace Containers Used? ONO N/A Containers Intact? ❑Y25 ONO ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ONO rl Sample Lapels Match COC? OYI6.❑NO ❑N/A 9. -Includes Date/Time/ID/Analysis Headspace in VOA Vials (55-6mm)? Trip Blank Present? Matrix: ❑Yes ❑Yes ONO ONO- N/A ❑N/A 10. 11. Trip Blank Custody Seals Present? QYw ONO ❑N/A COMMENTS/SAMPLE DLSCREPANCY - \ Field Data Required? Oyes ❑No np /Iq d 1 L 1 .-__. ,. .C.,o�.. �� zxn nlr%A.-rS ,. ("/t'C Wa I( j;tf I N Lot 10 of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: li � S Date/Time; ll 11 (l `T ids', Date: Project Manager SCURF Review: Da qq" !, —,---- Project Manager SRF Review: wf'\ Date: Page 14 of 16 Document Name: Document No.: . ww•••=••••Pace l of 'Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/9015 (water) DOC, LLHg **Bottom half of boa is to list number of bottle Projectff WO# : 92439682 PM: MWB Due Date: 08/09/19 CLIENT: 92—MECK CO � 4 a V Z Jal E J m ¢ a V Jal E tV J m ¢ C V Ja E J m Z 9 uC n `v J m „ I E 1!1 m n o S E 2 m O N a E N m a ^ 2 E U m V j a E 3 4 3 V Q = ] ¢ .°'. J ,y a 2 n aE m S ,., a Z v d cpo J ¢ o � ,n a x 2 E Q •J[ N a V E a E N T a 2 v Z E N y ,g. a T a U x y E S GI Z N ¢ O > E F Oi C ] O E a J m > 2 T x O. E d �, _ a 2 v x '� a O Z _ Y n 1 Y .9 Y ` Z n = E l- 6 n ? m u E r 6 m q O n z n E ,M1 z u m E m a O 4 2 V �i E N J �•1 n a u a E J el 1 I z 3 4 5 6 7 a 9 10 11 12 Samples pH Adjustment Log for Preservedof Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time pdrlesm Lion Amount addedervouw tot q usted n(ehis farm will 6e sen[Io the Nor[h Carolina DEHNR Certifiation Office(l.e. Note: Out of hold, incorect preservative, out of temp, incorrect containers. Page 15 of 16 CHAIN -OF -CUSTODY I Analytical Request Document Pw_:d,dAic9 The Chain-ob Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section 9 Seelion C Required Client Information: Required Pmjnu Illtnlloatlne; Invoice tntmm nien: Pa e : 1 Of t Corner'. Merhlennuen C—n:v C.111. Wa.te Rermn l0 F:Iiblm Av,11 Aadms: 214= so'Ve Avc Cop' loCompaony Nom, Clmrl.ad. NC M205 Me1e11 Rcnulato peen, Email: AhpLem ohm •rtiu.omlerce.mlvne qev Purchaee Orgd a Pace Quge:: Phono: 15901314-W,(G Pon Pi.,U Nam, Lcmnest Cenva12 I"'t, CMet.,, maahc,b1,lnam upn11l.i,1 C,. State l Location Requested D. Dale: project 0, Pace Profile it. 3207-1 NC Rc uested A,n binds Filtered YM _ s Z wmv cat � COLLECTED _ Preservatives Pnrgw Wr U O r,mw r r'. o i o. SAMPLE ID of U_ $TART ENO O F r One Character per box. wpe wa _ IAZ, 0-9 1 l xx .a Oreuw+ V c Q o re n S V Sample Ids must be unique vqs TIAMTWE TDATeTWE m -� 0 m 4 u O o x a. „ C / (� p• < s s Uer s o in ¢ 'riC,EUt C"t Z6 ON XXV XX X X. Y Y1 I aaj I M411 7 12 z� s' a. 5, -6 1 14 f 7 '.- 9 +It 1, ,2 .� 'AOOrnONAL COMMENTS _ RELJNpt115Nm BYIAFFIWTION _ 4 GATE TIME IA�TFD BY/AFFIWTION ,/.: DAM , TIME SAMGtECONOmONS '- �,cllF �cicn5 Z l 7 i b m O D7 aceAnalytical nww.pacelabs.can August 12, 2019 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: Compost Central 2-Fecal Pace Project No.: 92440530 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Darren Steinhilber: Enclosed are the analytical results for sample(s) received by the laboratory on August 08, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste i PCCRFO �9BORA'fOP� REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 10 aceAnalytical w oacelsbs.corn Project: Compost Central 2-Fecal Pace Project No.: 92440530 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 This ration shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 10 lace Analytical wawpacelabs.mn SAMPLE ANALYTE COUNT Project: Compost Central 2-Fecal 'Pace Project No.: 92440530 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 f704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92440530001 Outfall 1 SM 9222D-2006 KDF 1 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 10 aceAnalytical wmvpacelabs.crom ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Compost Central 2-Fecal Pace Project No.: 92440530 Sample: OutfallI Lab ID: 92440530001 Collected: 08108/1909:53 Received: 08/08/1910:13 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual ,MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 6000 CFU/100 mL 1.0 1 08/08/1915:45 08/09/1913:52 a Date: 08/12/2019 06:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. D6,u2 Page 4 of 10 aceAnalytical wwwpacelebs.com QUALITY CONTROL DATA Project Compost Central 2-Fecal Pace Project No.: 92440530 QC Batch: 491243 Analysis Method: SM 9222D-2006 I!QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) - CHT Associated Lab Samples: 92440530001 METHOD BLANK: 2649684 Matrix: Water ,Associated Lab Samples: 92440530001 Blank Reporting I Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 08/09/19 13:52 SAMPLE DUPLICATE: 2649685 92440530001 Dup Parameter Units Result Result RPD Qualifiers Fecal Coliforms CFU/100 mL 6000 600 164 D6,u2 Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units Indicated by the"Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in futt, Date: 08/12/2019 06:47 PM without the written consent of Pace Analytical services, LLC. Page 5 of 10 aceAnalytical wwwpacelabs.com QUALIFIERS Project: Compost Central 2-Fecal Pace Project No.: 92440530 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunteraville, NC 28078 (704)875-9092 PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) CUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. i LABORATORIES PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. u2 Colonies are too numerous to count. Actual result may be greater than reported. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/12/2019 06:47 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 10 ace Analytical x wpacalsli QUALITY CONTROL DATA CROSS REFERENCE TABLE 'Project: Compost Central 2-Fecal Pace Project No.: 92440530 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 HuntersAle, NC 28078 (704)875-9092 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92440530001 Outfall 1 SM 9222D-2006 491243 SM 9222D-2006 491246 Date: 08/12/2019 06:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 10 Document_Name: Document Revised: February 7, 2018 n�'6,tr a sample Conditioi Up" Recei t(SCUR) Page I cf2 y :acecvmry.rC2r DocumentNo.: Issuing Authority: F-CAR-CS433-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Ralei h Mechanicsville Asheville ❑ Eden❑ Greenwood ❑ Huntersviile D/' B ❑ ❑ • Client Name: Project p WO# : 92440530 11e�A /en but:CC) 0n �IIII�I��II�II�I�I��I� Courier: ❑Fed Ex ❑UPS ❑USPS r dC(ent ❑ Commercial ❑Pace []Other:— 92440530 Custody Seal Present? []Yes No Seals Intact? ❑Yes 06}",� Date/Initials Person Examining Contents;/ Packing Material: []Bubble Wrap ❑Bubble Bags None ❑ Other Biological Tissue Frozen? []Yes[]NoN/A Thermometer 92TO48 Type of Ice: ff]W/,t ❑Blue ❑None IAGunlo: p Cooler Temp(•C): /0 3 Correction Factor: Add/Subtract(-C) 0.0 Temp should be above fieezing to fi'C Cooler Temp Corrected J'C): ❑iampler out of temp titters. Samples on ice, cooling process � hasbegun USDA Regulated Soil (2 N/A, water sample) Did samples origAte In a quarantine zone within the United States: CA, NY, or 5C (check maps)? Did samples originate o om^ nforeignFsloYurce pntem o orally, QYess MNo - - ---_-- — Comments/Discrepancy: . Chain of Custody Present? [}7es ONO ❑N/A 1. Samples Arrived within Hold Time? m ❑No ❑N/A 2. Short Hold Time Analysis(<72 hr.)? es ONO ❑N/A 3. Rush Turn Around Time Requested? DYES o ❑N/A 4. Sufficient Volume? (]Yes ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? o�a/p� (Yes ONO ❑No ❑N/A ❑N A 6. Containers Intact? Qi NO ❑N/A 7. Dissolved analysis: Samples Field Filtered? OY�t ON. /A a. Sample Labels Match COC? QGs ONO ❑N/A 9. -includes Date/Time/ID/Anal sls Matrix:. I� f Heads ace in VOA Vials (s5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? Dyes ❑Yes Qy,ts ONO ❑No ONO /A /A 10. 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of-nt mntalners: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Date/Time: _ Field Data Required? Dyes HNO Dale: Dale: Page 8 of 10 /%Analytical' 'Check mark top half of box if pH and/or dechlorinatlon Is Project WO#- 92 05-30 verified and within the acceptance range for preservation PM: MWB Due Date: 08/15/19 samples. CLIENT: 92-MECK CO Exceptions: VOA, Coliform, TOC, 011 and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Z a c ] a E n J Q 6 m Z a c ] a E 0 N M fl m z c 7 a E oo N N O. m C n 7 r< u M D. m o a rh S 3 a E Q 6 m ,n O Z A u E M 6 m y'' u `� Z u G a E O 6 m ^ x O R a E H Q 6 m a A. j s o E v` LL ti 3 Z u c J E E `m 3 li Q a ' u EE d v S 0 a a E a E ] U a O ry x a g a m 0 Q n V O S a a E N 0 a ac Z Z E E a E r m Q M 0 a Z. S o > E I OI 0 G z, Z 0 > E F m 0 > Z o J 0 > E' "IY J m 0 > r? L o > E 6 M U ] a 2 m «l, Y a > Le Y Q 0 > y a i N 'i Y U' > m E F N 6 N a M u e �, o f N d N m n 0 a 6 m a' a u V a E 0 O 0 a Z y G N 0 N > a v u J L E a of a li D Q E U 1 2 3 9 5 6 7 8 9 10 11 12 PH Adjustment Log for Preserved Samples atlon nto d tlervativa Sample 10 7yVe of Preservative pH upon receipt Dale preservation adjusted Time nmou ad)unedLot If form wtIrL ent to the North Carolina DEHNR Unification Office (i.e. Note: Whenever there is a d6crepancy anecung nartn wuuai,a.w,,,ya^- Out of hold, incorrect preservative, out of temp, incorrect containers. Page 9 of 10 --? CHAIN -OF -CUSTODY I Analytical Request Document nlyliall The Chain -of -Custody is a LEGAL DOCUKILNI. All relevant fields nitzi he complcled becumlely. Scnino A Seclipn D Scclim, C Huyuiec�l CliCnl lnlormalion: Rcpuited PmlC[I lnlorn,ilion: Invoec lnImnimimn: Pa C: t Of Ce�aw�nv Mecklenburg County S.I.I. W:Ilil jRcw,F1 To Kh Lent Annns MienGan: Atl:nm:5 2145 Sunio Ave Copy TO Comry]ny 1J.:ine, Cle!rii. NC 2820E I ACe1CSS. Regulal0 Ammcv El:adrpv Purchase Order<: Pete Oume' PCcne: (S6o)314.3BsC I'a. Prdjccl Nbmm Comppsl CCltuWl 2 FucblAcsan dp Poe. Mn'. A9anaev^' :rt:hc\vbming,,I pacelabseom. Slate l L[cation Requested Due Dale: Project N: Paco Pm6le a', 3207-1 NC -v Requested Anal is FlltomU YIN - • - ��" rt - _ Z uolwx COCE COLLECTED z Preservatives > ' Pmuna wmn pw wt O O w SAMPLE IDS at n U u ... START ENO O U N f C Wi WL One Character per box- a o in P at Sample Ids must he unique rum s x w TIA�TWE TIAT�T.' in o .^. Ory W vepi O_ r in J 1— ? o ¢ p 2 3G •'4 7i 8 -- i9r 'tq TOi - �4 hI\BBmONAL coxxFxis •K^a• ZRRiffj, 5NE0 BYIAFFANTION�'y* �V-, GATE ;r+ TPIE-k 'NLCEPR]I BYII1FFlWtTON -� BATE' ry TME� }SAMPLELONOITIONs �R�.. . .- ..i K ..?.'+"lEn �v, _ na-�cM.' .1 I'i ,; �� . A.— - v '.a 11 c l �zr cio r- � a ik r (0 13 �/, 1 0� �U SAMPLER NAME AND SIGNATURE r ^ PRINT Name of SAMPLER: 1 d1 w " ^ a $ SIGNATURE of SAMPLER: / DATE Signad: Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit littos:Hdeg.iic.goN,/about/divisions/energy-mineral-land- resources/energy-iniuera 1-land-aernrits/stornnvater-pernuts/nudes-industrial-sw#ta b-4 Permit No.: NICI6 I,&I_ I/j / V l_6l or Certifiicateof Coverage No.: N/C/G/,/ // IL1014l4l Facility Name: Me Gnu blAsg 6 l ✓✓ k/ (mad 4 In L( i1 g w County: IN PfIt Inspector: q rr t Date of htspection: Time of Inspection: Total Event Precipitation (inches): r Phone No.' All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DEMLR Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) 1. Outfall Description: n Outfall No. I— Structure (pipe, ditch, etc.): -ti— Receiving Stream: Describe the industrial activities that occur within the outfall drainage area: Page 1 of 2 St147-242, Last modified 07/28/2017 2. Color: Describe the color of tie discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: bro 'I (' "A'VOh) to dc-'f'V_ ^ brOWr� 3. Odor: Describe sty distill t odors hat the discharge may have (i.e., smells strongly of oil, weak chlorine odor; etc.): S. O Y Qc-p 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 O 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge. where 1 is no solids and 5 is tthee surface covered with floating solids: 1 2 I 1 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and //5 is extremely muddy: 1 2 1 3 / 4 5 7. Is there any foam in the stornnvater discharge? 0 Yes �N1 8. Is there an oil sheen in the stonmvater discharge? OYes O/X" 9. Is there evidence of erosion or deposition at the outfail? o Yes 10. Other Obvious Indicators of Stornnvater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 Sw0-'42, Last modified 07/28/2017 Quarterly Stormwater Discharge Monitoring Report for North Carolina Division of Water Quality General Permit No. NCG240000 Date submitted 10/2/2019 CERTIFICATE OF COVERAGE NO. NCG240019 FACILITY NAME Mecklenburg County Compost Central (new) COUNTY Mecklenburg PERSON COLLECTING SAMPLES Khaliem Adams LABORATORY: Pace Analytical Services Lab Cert. # 192 Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR 2019 SAApMPPLE QUARTER jj''❑ Jan -March ❑ April -June ❑ July -Sept ❑ Oct -Dec DISCH,rT46LrAr 2 SS ❑ORW ly❑HQW m❑Trout ❑PNA(month) OCT 07 z019 ❑zero -flow ❑Water Supply ❑SA ❑Other CENTRAL FILES DWR SECTION Total event rainfall 2 in or ® No discharge this period' Date Sample Collected' (mo/dd/yr) Outfall No. TSS COD Fecal coliform Total nitrogen Total phosphorus Total copper Total lead Total zinc pH Parameter benchmarks =__> 100 mg/L4 120 mg/L 1000 col./100 mL 30 mg/L 2 mg/L 0.010 mg/L 0.075 mg/L 0.126 mg/L 6-9 9/2019 ' Monthly sampling (instead of quarterly) must begin with the second consecutive benchmark exceedance for the same parameter at the same outtall. 2The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. ' For sampling periods with no discharge, you must still submit this discharge monitoring report with a checkmark here. "The TSS benchmark value is 100 mg/L; except when discharging to ORW, HQW, Trout, and PNA waters in which case the benchmark is 50 mg/L. Permit Date:-10/1/2011-9/30/2016 - - - - _ Last Revised 12/02/11 - - _ - -- Page oft- -. Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month. Date Sample Collected' (mo/dd/yr) Outfall No. pH TPH using method 1664ASGT-HEM TSS Total Rainfa112 Check if No Flow This Period' Average New Motor Oil Usage 6-9 15 mg/L 100 mg/L4 - - 9/2019 1 - - - - X 75 gal/month Footnotes from Part A also apply to this Part B FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ® NO ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ® NO ❑ REGIONAL OFFICE CONTACT NAME: Teresa Bradford Mail an oriainal and one conv of this DMR, including all "No Discharge" reports, within 30 days of receipt of the lab results for at end of monitoring period in the case of "No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significpnt penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." jc Z l (Date) ' Last Revised 12/02/11 _ -- - - - - Page 2.of2. �NBVgO CO .f� G v �ttls� P oq TN OPFO�® MECKLENBURG COUNTY Land Use & Environmental Services Agency Solid Waste August 1, 2019 Central Files NCDENRIDWQ 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Attention: Central Files Subject: Discharge Monitoring Report Mecklenburg County Compost Central (new) — Certificate of Coverage No. NCG240019 Dear Central Files: Please find enclosed the Discharge Monitoring Report, July 2019, for Mecklenburg County Compost Central (new), a Type 1 facility located at 140 Valleydale Road, North Carolina. If you have any questions, please contact me at 704-634-7705 or by email at khaliem.adams a mecklenbur cg ountync.gov. Sincerely, Khaliem Adams Solid Waste Environmental Specialist Enclosed: 2019 DMR on SM z Co M M M5 c M nr � G oha M VD 0 PEOPLE •PRIDE PROGRESS •PARTNERSHIP 2145 Soule Avenue Charlotte, North Carolina 28208 www. w i peon t waste. corn Quarterly Stormwater Discharge Monitoring Report for North Carolina Division of Water Quality General Permit No. NCG240000 Date submitted 8/1/2019 CERTIFICATE OF COVERAGE NO. NCG240019 FACILITY NAME Mecklenburg County Compost Central (new) COUNTY Mecklenburg PERSON COLLECTING SAMPLES Khaliem Adams LABORATORY: Pace Analytical Services Lab Cert. # 192 Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR _2019 SAMPLE QUARTER ❑ Jan -March ❑ April -June ❑ July -Sept ❑ Oct -Dec . from ®Monthly' July (month) DISK _9G O CLA55 ❑ORW ❑HQW —]Trout ❑PNA -, -T ��J1J ❑Zero -flow ❑Water Supply [:]SA SEP❑Other AL FILES DWR}SECTION Total event rainfall z 0.69 in or ❑ No discharge this period' Date Sample Collected' (mo/dd/yr) Outfall No. TSS COD Fecal coliform Total nitrogen Total phosphorus Total copper Total lead Total zinc pH Parameter benchmarks =__> 100 mg/L1 120 mg/L 1000 col./100 mL 30 mg/L 2 mg/L 0.010 mg/L 0.075 mg/L 0.126 mg/L 6-9 7/22/2019 1 12.9 150 2600 4.4 1.4 <0.0050 <0.0050 <0.010 6.89 1 Monthly sampling (instead of quarterly) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. 'For sampling periods with no discharge, you must still submit this discharge monitoring report with a checkmark here. °The TSS benchmark value is 100 mg/L; except when discharging to ORIN, HOW, Trout, and PNA waters in which case the benchmark is 50 mg/L. Permit Date: 10/1/2011-9/30/2016 - - - - - _ - - -- _ - - LasvRevised-12/02/11 Page 1 of 2 Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month. Date Sample Collected' (mo/dd/yr) Outfall No. PH TPH using method 1664A SGT-HEM TSS Total Rainfall' Check if No Flow This Period' Average New Motor Oil Usage 6-9 15 mg/L 100 mg/O - - 7/22/2019 1 6.89 <4.8 12.9 1.78 0.69 75 gal/month Footnotes from Part A also apply to this Part B FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ® NO ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ® NO ❑ REGIONAL OFFICE CONTACT NAME: Teresa Bradford Mail an original and one copy of this DMR including all "No Discharge" reports within 30 days of receipt of the lab results (or at end of monitoring period in the case of "No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are sippificant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." L (Date -10/1/2011-9/30/2016 Last Revised 12/02/11 Page2of 2 - — Facility Name I Sample Location Sample Time pH Date Device Used to Sample Mecklenburg County Compost Central (new) I Outfall 1 1034 6.89 7/22/2019 Horiba pH-110 meter lceAnalyficale ~Pacelaescom July 29, 2019 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: COMPOST CENTRAL 2 Pace Project No.: 92437831 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Dear Darren Steinhilber: Enclosed are the analytical results for sample(s) received by the laboratory on July 22, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, nn Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L.L.C. Page 1 of 17 aceAnalytical' w mpacelaas.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: COMPOST CENTRAL Pace Project No.: 92437831 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 . Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 i' North Carolina Field Services Certification #: 5342 YrginiaNELAP Certification At: 460221 North Carolina Wastewater Certification #: 12 Asheville Certification IDs .1 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NCO30 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 17 i 0 aceAnalytical *wwpacoobs.com SAMPLE ANALYTE COUNT Project: COMPOST CENTRAL Pace Project No.: 92437831 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92437831001 OUTFALL 1 EPA 1664B JMS 1 PASI-C EPA 200.7 Rev 4.41994 SH1 3 PASI-A SM 9222D-2006 KDF 1 PASI-C SM 254OD-2011 MJP 1 PASI-A TKN+NO3+NO2 Calculation DMN 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.01993 MDW 1 PASI-A SM 5220D-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 17 aceAnalytical wwwpacelabs.wm ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: COMPOST CENTRAL Pace Project No.: 92437831 'Sample: OUTFALL 1 Lab ID: 92437831001 Collected: 07/22/19 10:54 Received: 07/22/19 11:28 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual �1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons NO mg/L 4.8 1 07/26/19 06:35 t 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper NO mg/L 0.0050 1 07/24/1915:16 07/25/19 02:10 7440-50-8 Lead ND mg/L 0.0050 1 07/24/19 15:16 07/25/19 02:10 7439-92-1 Zinc ND mg/L 0.010 1 07/24/1915:16 07/25/1902:10 7440-66-6 MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 2600 CFU/100 mL 1.0 1 07/22/19 16:00 07/23/19 14:02 D6,u2 2540D Total Suspended Solids Analytical Method: SM 254OD-2011 Total Suspended Solids 12.9 mg/L 6.6 1 07/25/19 13:25 "Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Total Nitrogen 4.4 mg/L 0.52 1 07/29/19 13:05 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total 4.4 mg/L 0.50 1 07/26/19 07;03 07/27/19 02:58 7727-37-9 353.2 Nitrogen, N021NO3 pros. Analytical Method: EPA 353.2 Rev 2.0 1993 l Nitrogen, NO2 plus NO3 NO mg/L 0.040 1 07/24/19 13:48 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 1.4 mg/L 0.050 1 07124/1919:12 07/25/1920:08 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 150 mg/L 25.0 1 07124/1916:55 07/2411923:34 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, L-C. Page 4 of 17 aceAnalytical i w pawffaes.mm I QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntems ille, NC 28078 (704)875-9092 Project: COMPOST CENTRAL Pace Project No.: 92437831 QC Batch: 488631 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92437831001 METHOD BLANK: 2637593 Associated Lab Samples: 92437831001 Parameter Units !Total Petroleum Hydrocarbons mg/L LABORATORY CONTROL SAMPLE: 2637594 Parameter Units Total Petroleum Hydrocarbons mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 4.8 07/26/19 06:26 Spike LCS LCS h Rec Conc. Result % Rec Limits Qualifiers 19.2 19.5 101 64-132 MATRIX SPIKE SAMPLE: 2637595 35483765001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 4.8U 19.2 20.2 104 64-132 nl Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, L-C. Page 5 of 17 1' ace Analytical wawpacelahs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: COMPOST CENTRAL ,Pace Project No.: 92437831 OC Batch: 488155 Analysis Method: EPA 200.7 Rev 4.41994 QC Batch Method: EPA 200.7 Rev 4.41994 Analysis Description: 200.7 MET Associated Lab Samples: 92437831001 METHOD BLANK: 2635336 Matrix: Water 'Associated Lab Samples: 92437831001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L NO 0.0050 07/25/1900:51 'Lead mg/L NO 0.0050 07/25/1900:51 Zinc mg/1- ND 0.010 07/25/19 00:51 LABORATORY CONTROL SAMPLE: 2635337 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 'Copper mg/L 0.5 0.50 100 85-115 Lead mg/L 0.5 0.50 99 85-115 Zinc mg/L 0.5 0.48 96 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635338 2635339 MS MSD 92436990001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc Conc. Result Result % Rec % Rec Limits RPD Qual Capper mg/L 18.8 0.5 0.5 0.53 0.52 101 101 70-130 0 ug/L Lead mg/L NO 0.5 0.5 0.50 0.50 99 99 70-130 1 Zinc mg/L 278 0.5 0.5 0.76 0.76 97 96 70-130 1 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635340 2635341 MS MSD 92437705003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Copper mg/L 24.7 0.5 0.5 0.53 0.55 100 104 70-130 4 ug/L Lead mg/L ND 0.5 0.5 0.49 0.50 97 100 70-130 4 Zinc mg/L 131 0.5 0.5 0.60 0.63 95 100 70-130 4 ug/L Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, L-C. Page 6 of 17 aceAnalytical0 wwwpacelabssom Project: COMPOST CENTRAL Pace Project No.: 92437831 QC Batch: 487747 QC Batch Method: SM 9222D-2006 Associated Lab Samples: 92437831001 METHOD BLANK: 2633442 Associated Lab Samples: 92437831001 Parameter Fecal Coliforms .SAMPLE DUPLICATE: 2633443 Parameter Fecal Coliforms QUALITY CONTROL DATA Analysis Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) - CHT Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers CFU/100 mL NO 1.0 07/23/19 14:02 92437831001 Dup Units Result Result RPD Qualifiers CFU/100 mL 2600 600 125 D6,u2 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units Indicated by the"Units" column except where an alternate un It Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the wntten consent of Pace Analytical Services, I.I.C. Page 7 of 17 aceAnalytical w pacalabs.com Project: COMPOST CENTRAL 2 '.Pace Project No.: 92437831 QC Batch: 488455 QC Batch Method: SM 254OD-2011 Associated Lab Samples: 92437831001 I METHOD BLANK: 2636709 Associated Lab Samples: 92437831001 n Parameter Units 'Total Suspended Solids mg/L LABORATORY CONTROL SAMPLE: 2636710 Parameter ' Units Total Suspended Solids mg/L Pace An alyticaI Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 07/25/1913:23 Spike LCS LCS % Rec Cones Result % Rec Limits Qualifiers 250 238 95 90-110 SAMPLE DUPLICATE: 2636711 92438271001 Cup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 232 239 3 SAMPLE DUPLICATE: 2636712 92437913001 Cup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 9.8 9.5 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, -I-C. Page 8 of 17 aceAnalytical eawpacelabs.mm Project: COMPOST CENTRAL 2 ,Pace Project No.: 92437831 OC Balch: 488610 'OC Balch Method: EPA 351.2 Rev 2.0 1993 Associated Lab Samples: 92437831001 METHOD BLANK: 2637531 Associated Lab Samples: 92437831001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 2637532 Parameter Units Nitrogen, Kjeldahl, Total mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.50 07/27/19 02:42 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 10 9.6 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2637533 2637534 MS MSD 92437614001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result e/ Rec k Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L NO 10 10 10 9.6 96 92 90-110 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2637535 2637536 MS MSD 92437387001 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L NO 10 10 9.4 9.5 90 91 90-110 1 Results presented on this page are In the units Indicates by the 'Units" column except where an alternate unit is presented to the right of the result Date: 07/29I2019 01:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, -I-C. Page 9 of 17 aceAnalytical w wpacelaes.t vn Project: COMPOST CENTRAL 2 Pace Project No.: 92437831 QC Batch: 488095 QC Batch Method: EPA 353.2 Rev 2.0 1993 Associated Lab Samples: 92437831001 METHOD BLANK: 2635052 Associated Lab Samples: 92437831001 Parameter Units Nitrogen, NO2 plus NO3 mg/L LABORATORY CONTROL SAMPLE: 2635053 'I Parameter Units Nitrogen, NO2 plus NO3 mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.040 07/2411913:22 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.4 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635054 2635055 MS MSD 92437365057 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.028J 2.5 2.5 2.1 2.1 81 81 90-110 1 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635056 2635057 MS MSD 92437365058 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Conc. Result Result %Rec %Rec Limits RPD Qua[ Nitrogen, NO2 plus NO3 mg/L 0.55 2.5 2.5 2.9 2.9 92 93 90-110 1 Results presented on this page arc in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 17 aceAnall/y'ical J' lvwwpacelabs.crom Project: COMPOST CENTRAL Pace Project No.: 92437831 ,QC Balch: 488212 QC Balch Method: EPA 365.1 Rev 2.0 1993 11 .Associated Lab Samples: 92437831001 METHOD BLANK: 2635725 Associated Lab Samples: 92437831001 i Parameter Units Phosphorus mg/L QUALITY CONTROL DATA Analysis Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 07/2511920:04 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 �. LABORATORY CONTROL SAMPLE: 2635726 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635727 2635728 MS MSD 92437087001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone, Result Result e/ Rec % Rec Limits RPD Qual Phosphorus mg/L 0.52 2.5 2.5 3.1 3.1 102 103 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635729 2635730 MS MSD 92437831001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone, Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 1.4 2.5 2.5 4.0 4.0 103 103 90-110 0 Results presented on this page are in the units indicated by the 'Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 17 aceAnalytical wmvpecetabs.cum Project: COMPOST CENTRAL 2 Pace Project No.: 92437831 QC Batch: 488228 QC Batch Method: SM 5220D-2011 'Associated Lab Samples: 92437831001 METHOD BLANK: 2635845 Associated Lab Samples: 92437831001 Parameter Units .Chemical Oxygen Demand mg/L LABORATORY CONTROL SAMPLE: 2635846 Parameter Units Chemical Oxygen Demand mg/L Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: SM 5220D-2011 Analysis Description: 5220D COD Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 25.0 07/24/1923:31 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 750 751 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635847 2635848 MS MSD 92437078003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 1010 100 100 1100 1100 96 93 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2635849 2635850 MS MSD 92437831001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 150 100 100 274 277 125 127 90-110 1 M1 Results presented on this page are In the units indicated by the"Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 07/29/2019 01:08 PM without the written consent of Pace Analytical services, LLC. Page 12 of 17 aceAnalytical. rrwwpaceWbsmm QUALIFIERS Project: COMPOST CENTRAL Pace Project No.: 92437831 'DEFINITIONS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. NO - Not Detected at or above adjusted reporting limit. TNTC -Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference INC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260, N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ,I i ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. u2 Colonies are too numerous to count. Actual result may be greater than reported. This report shall not be reproduced, except in full, Dale: 07/29/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 aceAnalytical mwepacelabs.mm QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: ,Pace Project No.: COMPOST CENTRAL 92437831 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92437831001 OUTFALLI EPA 1664B 488631 92437831001 OUTFALL 1 EPA 200.7 Rev 4.4 1994 488155 EPA 200.7 Rev 4.4 1994 488282 92437831001 OUTFALL 1 SM 9222D-2006 487747 SM 9222D-2006 487748 92437831001 OUTFALL 1 SM 254OD-2011 488455 92437831001 OUTFALLI TKN+NO3+NO2 489035 Calculation 92437831001 OUTFALL 1 EPA 351.2 Rev 2.0 1993 488610 EPA 351.2 Rev 2.0 1993 488850 [92437831001 OUTFALL 1 EPA 353.2 Rev 2.0 1993 488095 92437831001 OUTFALL 1 EPA 365.1 Rev 2.0 1993 488212 EPA 365.1 Rev 2.0 1993 488292 '92437831001 OUTFALL 1 SM 5220D-2011 488228 SM 5220D-2011 488298 Date: 07/29/2019 01:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytcal Services, LLC. Page 14 of 17 Document Name: Document Revised: February 7, 2018 Analytical' Sample Condition Upon Recei t SCUR Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: �� Asheville ❑ Eden[ Greenwood ❑ Huntersville\I Raleigh[] Mechanicsville❑ Client Name: _ I�WO># : 92437831 Project M: Courier: ❑Fed Ex ❑UPS ❑USPSQClient ❑Commercial ❑Pace ❑Other:_ Custody Seal Present? ❑Yes "/E]NO Sealslntact? []Yes 'QNo I \ / Packing Material: ❑Bubble Wrap 0ubble Bags ❑None ❑ Other Thermo- ry�etyen: un ID: a92TO48 Typeollce: Nwet ❑Blue tjJlR b/ Cooler Temp (-C): 4''J f �- Correction Factor: Add/Subtract ('C) 0.0 Cooler Temp Corrected ('C): y' S I USDA Regulated Soil N/A, water sample) Did samples riginate in aquarantine zone within the United States: CA, NY, or SC (check maps)? rypx Nn HIleII01 IIII11111III 92437831 r` Date/Initials Person Examining Contents: NLR jZ r Biological Tissue f rozen? []None❑Yes ❑No E]WA Temp should be above freeiing to 6'C [-]Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source( er ationally, Including Hawaii and Pueno Rlco)?rlYes MNa Comments/Discrepancy: ti Chain of Custody Present? N�-Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? Yes ONO ❑N/A 2. Short Hold time Analysts <72 hr.)? Yes No ❑rv/A 3. Rush Turn Around Time Requested? ❑Yes JNa ❑N/A 4. Sufficient Volume? Yes NO N/A S. Correct Containers Used? r Yes ONO ❑N/A 6. -Pace Containers Used? ,flyer ❑no ❑N/A Containers Intact? I❑Yes ONO ❑N/A 7. Dissolved analysis: Samples Field Filtered? f ❑Yes []No �614/A B. Sample Labels Match COC? �[ jYes ( ONO '❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? ❑Yes ❑No &A 10, Trip Blank Present? [-]Yes []No 'ObJA 11. I� Trip Blank Custody Seals Present? Elyes ❑No txN/A COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Ir lew: Project Manager SRF Review: f ~ Date/Time: Field Data Required? Oyes ONO Date: / 1 Z z I I � Date: 7711 { Page 15 of 17 Document Name: Document Revised: February 7, 2018 BCeAnaly6Cdl Sample Condition Upon Recel tjSCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 I Pace Carolinas Quality Office "Check mark top half Of box If pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Collform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box Is to list number of bottle Project# I O# ; 92437831 PM: MWB Due Date: 07/29/19 i CLIENT: 92—MECK CO c E O ¢ Z E E' c J E i ¢ i p N w c > E T a 2 C c > E i N _ x n j —n i V a ,n S E r%1 O V m Z x E as = p i N 6 E N /, x o 2 E tJ Z i yny A —U' v 5p i u Z E i n ] a E Q 3 v M i E Q w .r ti L d m j ¢ E 'Q � m N S 9 $ 2 E C Ih . V e x n a E r N u Q u Z n E Q E eV Q n ¢ i, u o > E Y x Of Z m Or ti p C F P 0 c n o > E o J P 0 a = 0 > E o is. e, C ? N N 'g Y O < » L7 a > 6 9 Y a N E c 1 z _ a N E ry —,,,N. i 2 d E a a 2 y c0. E ] a N N E > a V t J Q E J 1 ✓ v/ 2 + 2 IN 3 4 6 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample to Type of preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sprit to the North Carolina DEH NR Cenification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 16 of 17 ,%? CHAIN -OF -CUSTODY / Analytical Request Document -- The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be,completedaccurately. o. 1-1 n oecugn N S.etlon C -- Required Client Information- Required Protect Infomwdon: Imgice Information: Page Of 1 Company: Mecklenburq County Solid Waste Report To: Kholient Adams atenlmn: Address: 2145 Sulfle Ave. Copy To: Company Name: Charlotte, NC 282M Address' .' R ulato enc Email: k liom.aurns meddenbumtours cq.v Ptadvtso Order tl: Pace Queue Phone: (960)314-3856 IF. - Protect Name: Compost Central 2 Pace Project Manager. matlnew.Craigard parolabs.wm, 1 " - . State I Locadon- Requested Due Date: Project tl: Par» Prof l- q: 121-1 NC <R uested Anal .FiRama M- C a 2 unlnu com U0 COLLECTED i Preservatives > - - pmlep W m on- a WT ` s U O Waale Waln wN .4 ¢ W _ h%aU P SAMPLE ID u_ o z = START END One Character per box.- x. x' - v 'cot it (A-2 0-91. -) AR QM1fI ai V a.a. a 2 s, c n V Sample Ids must be unique T— Ts x TDATET1.1 TIAIEIIIE _ `o O jp d g U F La n _ 3 Qi a J i Z � i z' O a N g i r r 1= rc •12 'X `�Cc•N�-'�Z. Tt�T.� !fir -LTC.; L(� f�CiSc 3 '4• -5 6 7 '.8 10' 11 12. ADDITIONAL CAM_MFNiS r 1.��REUNON91Ep BYIAFgUATMN '04TC'. TWE:': .ACCEPTED BY/iFFIWTON�' .DATE• TIME :. -SAMPul C-c N10N8 ' A-)csr < 71alai ill-F ,��1�G/ ���Jr r.- '�'�,.I; f(2S tiSc y. e m Kro Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance on filling out thisfornr, please visit littps://deg.iic.gov/about/divisions/eiierev-mineral-land- resources/enerev-mineral-land-penttits/storimvater-permits/npdes-industrial-sNN-; tab-4 Permit No.: N/C/ G Facility Name: 7 County: Inspector: Date of Inspection: Time of Inspection: lU/O/o/o/ or F1 1 IU rc, Total Event Precipitation (inches): �/ • ;) �. 6 No.: N/C/G/�A/jt)/O/L/J/ All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event' is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DEMLR Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Perinittee or Designee) i 1. Outfall Description: Outfall No. I Structure (pipe, ditch, etc.): z Receiving Stream: Describe the industrial activities that occur within the outfall drainage area: C40f D S-f, 11 G d— Page 1 of 2 SA U-242, Last modified 07/2V2017 2. Color: Describe the color of (light, medium, dark) as descriptors: _ 3. Odor: Describe chlorine odor, etc.): basic colors (red, brown, blue, etc.) and tint odors that the discharge may have (i.e.. smells strongly of oil, weak 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 3 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 2 (3J 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the storniwater discharge, where 1 is no solids and 5 is extremely muddy: 1 2 D 4 5 A/ 7. Is there any foam in the stormwater discharge? O Yes �No. /`� O 8. Is there an oil sheen in the stormwater discharge? OYes Qa"No. 9. Is there evidence of erosion or deposition at the outfall? O Yes c{/1To. AM 10. Other Obvious Indicators of Storntwater, Pollution: List and describe 51 Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWU-242, Last modified 07/28/2017 AA �i filer v."`1R•. I �. �� .�7 dT T.-_ .���,5 �%h� '�'' � �• ���� 1�. n. .l- � 1 � -Y� t � •7j .'. .' I s r� 17 ALg 4= r 41 _ r-_ �� ♦ 1..� C r .�, ar� � -• YAK^` .�`'�..f� / rat �,�". = � ;,�,'' �.� � •. A yIr-6- 2jit 1\ 1 i- _ r • MECKLENBURG COUNTY Land Use & Environmental Services Agency Solid Waste June 28, 2019 Central Files NCDENR/DWQ 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Attention: Central Files r` JUL 0 5 2019 C�WRrSEGitfl�d Subject: Discharge Monitoring Report Mecklenburg County Compost Central (new) — Certificate of Coverage No. NCG240019 Dear Central Files: Please find enclosed the Discharge Monitoring Report, June 2019, for Mecklenburg County Compost Central (new), a Type I facility located at 140 Valleydale Road, North Carolina. If you have any questions, please contact me at 704-634-7705 or by email at khaliem.adaius a mecklenbure,comitync. o�v. Sincerely, �% f Khaliem Adams Solid Waste Environmental Specialist Enclosed: 2019 DMR PEOPLE • PRIDE PROGRESS • PARTNERSHIP 2145 Settle Avenue Charlotte. North Carolina 28208 www.wipeoutwastexona Quarterly Stormwater Discharge Monitoring Report for North Carolina Division of Water Quality General Permit No. NCG240000 Date submitted 6/28/2019 CERTIFICATE OF COVERAGE NO. NCG240019 FACILITY NAME Mecklenburg County Compost Central (new) COUNTY Mecklenburg PERSON COLLECTING SAMPLES Khaliem Adams LABORATORY: Pace Analytical Services Lab Cert. # 192 Comments on sample collection or analysis: Part A: Stormwater Benchmarks and Monitoring Results SAMPLE COLLECTION YEAR 2019 SAMPLE QUARTER ❑ Jan -March ❑ April -June ❑ July -Sept ❑ Oct -Dec or ® Monthly' June (month) DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA ❑Zero -flow ❑Water supply ❑SA ❑Other Total event rainfall' 1.78 in or ❑ No discharge this period' Date Sample Collected' (mo/dd/yr) Outfall No. TSS COD Fecal coliform Total nitrogen Total phosphorus Total copper Total lead Total zinc pH Parameter benchmarks =__> 100 mg/L4 120 mg/L 1000 col./100 mL 30 mg/L 2 mg/L 0.010 mg/L 0.075 mg/L 0.126 mg/L 6-9 6/10/2019 1 14.0 176 3800 3.5 1.4 0.0062 <0.0050 <0.010 7.07 ' Monthly sampling (instead of quarterly) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall. 'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement. 3 For sampling periods with no discharge, you must still submit this discharge monitoring report with a checkmark here. °The TSS benchmark value is 100 mg/L; except when discharging to ORW, HQW, Trout, and PNA waters in which case the benchmark is 50 mg/L. Permit Date: 10/1/2011-9/30/2016 Last Revised 12/02/11 Page 1 of 2 Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new motor oil/month. Date Sample Collected' (mo/dd/yr) Outfall No. pH TPH using method 1664A SGT-HEM TSS Total Rainfall' Check if No Flow This Period3 Average New Motor Oil Usage 6-9 15 mg/L 100 mg/L4 - - 6/10/2019 1 7.07 <5.0 14.0 1.78 75 gal/month Footnotes from Part A also apply to this Part B FOR PART A AND PART B MONITORING RESULTS: • A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B. • 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B. • TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ® NO ❑ IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ® NO ❑ REGIONAL OFFICE CONTACT NAME: Teresa Bradford Mail an original and one copv of this DMR, includina all "No Discharge" reports, within 30 days of receipt of the lab results for at end of monitoring period in the case of "No Discharge" reports) to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED: "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 6 l (date) Permit Diate:1011/2011-9/30/2016 Last Revised 12/02/11 Page 2 of 2 Facility Name Sample Location Sample Time pH I Date I Device Used to Sample Mecklenburg County Compost Central (new) I Outfall 1 1130 7.07 1 6/10/2019 1 Horiba pH-110 meter aceAnalytical aewpacelabs.cem June 17. 2019 Darren Steinhilber Mecklenburg County Solid Waste 2145 Suttle Ave Charlotte, NC 28208 RE: Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 Dear Darren Steinhilber: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Nunlersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on June 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNIINELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Khaliem Adams, Meclenburg County Solid Waste REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 17 0 ace Analytical avrwpacelabs.com Project: COMPOST CENTRAL Pace Project No.: 92432341 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Flohda/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC_ Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Page 2 of 17 aceAnalytical %wwpacelebs.mm SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)B75-9092 Project: Pace Project No.: COMPOST CENTRAL 2 92432341 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92432341001 OUTFALL 001 EPA 1664E JMS 1 PASI-C EPA 200.7 Rev 4.41994 SH1 3 PASI-A SM 9222D-2006 KDF 1 PASI-C SM 254OD-2011 MJP 1 PASI-A TKN+NO3+NO2 Calculation EWS 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A EPA 365.1 Rev 2.01993 GC 1 PAS -A SM 5220D-2011 GC 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, LLC. Page 3 of 17 ace Analytical .pacelabs.corn ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: COMPOST CENTRAL Pace Project No.: 92432341 Sample: OUTFALL 001 Lab ID: 92432341001 Collected: 06/10/19 11:44 Received: 06/10119 12:11 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 1664 SGT-HEM, TPH Analytical Method: EPA 1664B Total Petroleum Hydrocarbons NO mg/L 5.0 1 06/13/19 06:17 200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994 Copper 0.0062 mg/L 0.0050 1 06/12/19 16:49 06/14/19 00:25 7440-50-8 Lead NO mg/L 0.0050 1 06/12/19 16:49 06/14/19 00:25 7439-92-1 Zinc NO mg/L 0.010 1 06112/19 16:49 06/14/19 00:25 7440-66-6 MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2006 Preparation Method: SM 9222D-2006 Fecal Coliforms 3800 CFU/100 mL 1.0 1 06/10/19 14:47 06/11/19 13:28 D6,u2 2540D Total Suspended Solids Analytical Method: SM 2540D-2011 Total Suspended Solids 14.0 mg/L 5.0 1 06/14/19 12:27 D6 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Total Nitrogen 3.5 mg/L 0.52 1 06/13/19 10:28 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Nitrogen, Kjeldahl, Total 3.4 mg/L 0.50 1 06/12/19 12:09 06/13/19 02:37 7727-37-9 353.2 Nitrogen, NO2IN03 pres. Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, NO2 plus NO3 NO mg/L 0.040 1 06/12/19 12:57 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus 1.4 mg/L 0.050 1 06/11/1918:40 06/11/1923:26 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 176 mg1L 25.0 1 06/12/19 17:45 06/13/19 16:43 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, -LC. Page 4 of 17 m aceAnalytical ~..pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 QC Batch: 480856 Analysis Method: EPA 16646 QC Batch Method: EPA 1664B Analysis Description: 1664 SGT-HEM, TPH Associated Lab Samples: 92432341001 METHOD BLANK: 2601099 Matrix: Water Associated Lab Samples: 92432341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Petroleum Hydrocarbons mg/L ND 4.8 06/13/19 06:17 LABORATORY CONTROL SAMPLE: 2601100 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L 19.2 20.4 106 64-132 MATRIX SPIKE SAMPLE: 2601101 92432427001 Spike MS MS %Rec Parameter Units Result Conc. Result %Rec Limits Qualifiers Total Petroleum Hydrocarbons mg/L NO 19.2 19.1 99 64-132 Results presented on this page are In the units indicated by the"units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, I.I.C. Page 5 of 17 aceAnalytical wincpacelabs.com QUALITY CONTROL DATA Project: COMPOST CENTRAL Pace Project No.: 92432341 QC Batch: 480722 Analysis Method: EPA 200.7 Rev 4.41994 QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET Associated Lab Samples: 92432341001 METHOD BLANK: 2600460 Matrix: Water Associated Lab Samples: 92432341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Copper mg/L ND 0.0050 06/14/1913:22 Lead mg/L ND 0.0050 06/13/19 22:56 Zinc mg/L ND 0.010 06/13/19 22:56 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2600461 r Spike LCS LCS % Rec Parameter Units Cone. Result e/ Rec Limits Qualifiers Copper mg/L 0.5 0.50 99 85-115 Lead mg/L 0.5 0.49 97 85-115 Zinc mg/L 0.5 0.51 101 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2600462 2600463 MS MSD 92429955006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L ND 0.5 0.5 0.49 0.48 98 96 70-130 2 Lead mg/L ND 0.5 0.5 0.48 0.47 96 93 70-130 3 Zinc mg/L 0,055 0.5 0.5 0.57 0.56 104 100 70-130 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2600464 2600465 MS MSD 92431938001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Copper mg/L 27.9 0.5 0.5 0.53 0.51 100 96 70-130 4 ug/L Lead mg/L ND 0.5 0.5 0.49 0.47 97 94 70-130 3 Zinc mg/L 57.6 0.5 0.5 0.58 0.56 104 101 70-130 3 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 6 of 17 aceAnalytical wxwpamlabs.mm QUALITY CONTROL DATA Project: COMPOST CENTRAL Pace Project No.: 92432341 QC Batch: 480219 Analysis Method: SM 9222D-2006 QC Batch Method: SM 9222D-2006 Analysis Description: 9222D Fecal Coliform(MF) - CHT Associated Lab Samples: 92432341001 METHOD BLANK: 2598460 Matrix: Water Associated Lab Samples: 92432341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 06/11/19 13:28 SAMPLE DUPLICATE: 2598461 Parameter Fecal Coliforms Units 92432341001 Result Cup Result RPD Qualifiers CFU/100 mL 3800 600 145 D6,u2 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the un Its indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 17 aceAnalytical - ~.pacalabs.mrn QUALITY CONTROL DATA Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 QC Batch: 481178 Analysis Method: SM 254OD-2011 QC Batch Method: SM 254OD-2011 Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92432341001 METHOD BLANK: 2602782 Matrix: Water Associated Lab Samples: 92432341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L. NO 2.5 06/14/19 12:25 LABORATORY CONTROL SAMPLE: 2602783 Spike Parameter Units Conc. Total Suspended Solids mg/L 251 SAMPLE DUPLICATE: 2602784 92432316001 Parameter Units Result Total Suspended Solids mg/L 525 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LCS LCS % Rec Result % Rec Limits Qualifiers 250 100 90-110 Cup Result RPD Qualifiers 572 9 D6 SAMPLE DUPLICATE: 2602785 92432341001 Cup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 14.0 15.2 8 D6 Results presented on this page are In the units Indicated by the "Untu"column except where an alternate unit is presented to the right of the result - REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, L-C. Page 8 of 17 aceAnalytical wmvpacalabs.com Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 QC Batch: 480601 QC Batch Method: EPA 351.2 Rev 2.0 1993 Associated Lab Samples: 92432341001 METHOD BLANK: 2599929 Associated Lab Samples: 92432341001 Parameter Units Nitrogen, Kjeldahl, Total mg/L QUALITY CONTROL DATA Analysis Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers NO 0.50 06/1311902:13 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2599930 Spike 1-CS 1-CS e/ Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Kjeldahl, Total mg/1- 10 9.9 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599931 2599932 MS MSD 92432546001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec e/ Rec Limits RPD Qual Nitrogen, Kjeldahl, Total ni NO 10 10 10.1 9.9 99 97 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599933 2599934 MS MSD 92432546002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L NO 10 10 9.5 10.6 95 106 90-110 11 R1 Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 17 ace Analytical. a» naceWbacnm QUALITY CONTROL DATA Project: COMPOSTCENTRAL2 Pace Project No.: 92432341 QC Batch: 480592 - Analysis Method: EPA 353.2 Rev 2.0 1993 QC Balch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, preserved Associated Lab Samples: 92432341001 METHOD BLANK: 2599897 Matrix: Water Associated Lab Samples: 92432341001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, NO2 plus NO3 mg/L NO 0.040 06/12/19 12:43 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2599898 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599899 2599900 MS MSD 92431439106 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L 0.025J 2.5 2.5 2.4 2.4 95 94 75-125 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599901 2599902 MS MSD 92431439107 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Conc Conc. Result Result %Rec %Rec Limits RPD Qual Nitrogen, NO2 plus NO3 mg/L NO 2.5 2.5 2.4 2A 95 96 75-125 1 Results presented on this page arc In the units indicated by the'Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 17 lace Analytical w pacekbscom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: COMPOSTCENTRAL2 Pace Project No.: 92432341 QC Batch: 480441 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92432341001 METHOD BLANK: 2599329 Associated Lab Samples: 92432341001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 2599330 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 06/11/1923:18 Spike LCS LCS % Rec Cone. Result % Rec Limits Qualifiers 2.5 2.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599331 2599332 MS MSD 92432180001 Spike Spike MS MSD MS. MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L - 0.27 2.5 2.5 3.0 2.9 108 107 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2599333 2599334 MS MSD 92431443041 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.036J 2.5 2.5 2.7 2Y 106 106 90-110 0 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 06117/2019 11:05 AM without the written consent of Pace Analytical Services, -I-C. Page 11 of 17 aceAnalytical .pacalabecam Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 OC Batch: 480787 QC Batch Method: SM 5220D-2011 .Associated Lab Samples: 92432341001 METHOD BLANK: 2600860 Associated Lab Samples: 92432341001 Parameter Units Chemical Oxygen Demand mg/L LABORATORY CONTROL SAMPLE: 2600861 Parameter Units Chemical Oxygen Demand ni Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, INC 28078 (704)875-9092 QUALITY CONTROL DATA Analysis Method: SM 5220D-2011 Analysis Description: 5220D COD MaMx: Water Blank Reporting Result Limit Analyzed Qualifiers NO 25.0 06/13/1916:37 Spike LCS LCS e/ Rec Conc. Result % Rec Limits Qualifiers 750 757 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2600862 2600863 MS MSD 92431794002 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Chemical Oxygen Demand mg/L 31.3 100 100 131 133 99 102 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2600864 2600865 MS MSD 92432237006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result e/ Rec % Rec Limits RPD Qual Chemical Oxygen Demand mg/L 31.3 100 100 138 135 107 104 90-110 2 Results presented on this page are in the units indicated by the"Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/17/201911:05 AM without the written consent of Pace Analytical Services,LLC. Page 12 of 17 0 aceAnalytical wmepeeelabcoxn QUALIFIERS Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL- Adjusted Method Detection Limit, Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270, The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroelhylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PAST -A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. R1 RPD value was outside control limits. u2 Colonies are too numerous to count. Actual result may be greater than reported. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 06/17/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 ace Analytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE .Project: COMPOST CENTRAL 2 Pace Project No.: 92432341 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 92432341001 OUTFALL 001 EPA 1664B 480856 92432341001 OUTFALL 001 EPA 200.7 Rev 4.4 1994 480722 EPA 200.7 Rev 4.4 1994 480773 92432341001 OUTFALL 001 SM 9222D-2006 480219 SM 9222D-2006 480220 92432341001 OUTFALL 001 SM 2540D-2011 481178 92432341001 OUTFALL 001 TKN+NO3+NO2 480916 Calculation 92432341001 OUTFALL 001 EPA 351.2 Rev 2.0 1993 480601 EPA 351.2 Rev 2.0 1993 480847 '92432341001 OUTFALL 001 EPA 353.2 Rev 2.0 1993 480592 92432341001 OUTFALL 001 EPA 365.1 Rev 2.0 1993 480441 EPA 365.1 Rev 2.0 1993 480533 92432341001 OUTFALL 001 SM 5220D-2011 480787 SM 5220D-2011 480835 Dale: 06/17/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 17 Document Name: Document Revised: February 7, 2018 aceAnalytical • Sample Condition Upon Receipt(SCUR) Pa e 1 of 2 Decumen[ No.: Issuing Authority: r F-CA1{5-033-Rev.06 Pace Carolinas Ovall Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersviile Q-�- Raleigh[] Mechanicsville)-1 Client Name: Wo : 92432341 /r/ ie,C 11 / 1b(/{�O/l.meC Courier: ❑Fcd Ex uup ❑p�USPS li nt �IIII�I��OI�II IIIII �II ❑ Commercial ❑Pace ❑Other._ 92432341 Custody Seal Present? []Yes QKI Seals Intact? ❑Yes L2ND— "^"--- Packing Material: ❑Bubble Wrap ❑Bubble Bags None ❑ Other Thermometer: 92TO48 Type oflce: et [:]BlueIRGun ID: Cooler Temp('C): 0-l9 Correction Factor:Add/Subtract ('C) 0.0 Cooler Temp Corrected (Y): USDA Regulated Soil (2r-N/A, water sample) Did samples oriigin�te in a quarantine zone within the United States: CA, NY, or SC (check maps)? Dyes Li1No Date/Initials Person Examining Biologlcal sue Frozen? Orlon ❑Yes FINO ❑N/A Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples on ice, cooling process hasbegun Did samples originate from a foreign source (internationally, nrluAinv Hawaii and Puerrn RIrn17 F'TVo, F-1Nn Comments/Discrepancy: V Chain of Custody Present? es Otto ❑N/A 1. Samples Arrived within Hold Time? Yes ONO ON/A 2. Short Hold Time Analysis <71 hr.)? Flyes No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes ETNo ON/A 4. Sufficient Volume? es No N/A S. Correct Containers Used? -Pace Containers Used? ves v ONO No ❑N/A ON/A 6. Containers Intact? Yei No tJ/A 7. Dissolved analysis: Samples Field Filtered? Oves I]No /A B. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: � I/ es ONO ❑N/A 9. Headspace in VOA Vials (>5-6mm)? Qyes ONO, /A 1 10. Trip Blank Present? Trip Blank Custody Seals Present? Oyes OYes o ONO ON/A A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: I In Project Manager SCURF Review:/ Project Manager SRF Review: Date/Tlme: Field Data Required7 [-]Yes ❑No Date: 1 1 G l( I Date: Page 15 of 17 Issuing Authority: Pace Carolinas Quality Office "Check mark top half of box if pH and/or clechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform; TOC, Oil and Grease, DRO/8015 (water( DOC, LLHg "Bottom half of box is to list number of bottle Project #WOE'; 92432341 PM': MW® Due Date: 06/17 /19 CLCENT: 92-MECK Co x 0 O 9 u m = a 2 u n v uFZ 2 v _ a I n m ? 9 y S y y n c n 3 a E Q n m n c J v a E of M n m n c a E N n m a n j u N a `u M n m g Z = m a E Q n m p Z S 7 m n E T 1 m `a N `—' a E C S m S o 2 —' g a E O 6 or tp a $ 'o E a J 0 3 d m n ¢ e, N U' a y 2 `v f 3 `a M ma n c J a E a E v1u f11 U' a 90 2 u` E a N O N I a E a E m U' a E a E o ,� < m T W a u x a O E O1 V' c>> N z' a p > IT 4 ¢ O E P 6 m a O Eg U'. o>> 1 m n 4 a O > c ly n r yE� N y O a E ul N n 2 _ E n J E E 0 m la c E O N J n ¢ E O A U' 1 I j 2 3 NN5 6 7 a 9 10 ll _- 12 pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot e Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the Nanh Carolina DEHNR Cenifintion Office (i.e. Out of hold, Incorrect preservative, out of temp, incorrect containers. Page 16 of 17 eAnayilaf' -CHAIN-OF-CUSTODY / Analytical Request Document The Chain -Of -Custody is a LEGAL DOCUMENT. All relevant fields must be complet d accurately. ------- ,. aeman o Section C Required Client Information: Required Project Information: Invoice Information: Page : I Of t Company: Mecklenburn County Solid Waste Report To: K,zlicn, Adams JAUemion: Address: 2145 Sunle Ave Copy To.. Company Name: Charlotte. NO 28208 Atldress: Email: khaliem.ada ms mecklenbur count nc. ov Purchase Order e; Pace Quote: '1 Ro uldto q end - Phone: (704)6494034 Fax' Plojeat Name: Compost Central 2 Pace Project Manages matlhew.brainartl aOeabs.COm, ', i RequesledDue Date: Project p: Pace Profile p: 3207-1. __.iSmm/l.ocatlon -'• NO '.'�Re nested Anal sis Filter d fYINIT- - r: MnTnx coos g O COLLECTED ., Preservatives >- ' Rin4inO Waler M Wt U Q ra Imo Walw WN _ a U P SAMPLE ID e;�.a aL _ 0 d' 0 ` T a OL 8 START END Ce O ^- I One Character per box. vex vm a w In a I- _ w w on - Sample Ids must be mete os ~o` m 'ry- — n a m V w ~ as a y ay 2 e a h 0 V 9 DATE TIME DATE TIME e z z z f o ti 8 0 0 1 '1 Outfa11001 Wi� �rlu/ y ��7i.T 71�if/I�'I�• x f)o I y >< x x x x x 2. 3 .4 j 6 .6 7 8 .9 10' 12_. DOITIONAL'EOMMEmTS„'txEUNOU:&EDBYIAFFJLIATION' .'DATE.' TIME+gCLEPTEO BYIAFFlLIATIDM - DATE.} v -SAMPLE _'TIME CONDITIONS K, �r Vl m f!rir?rrn5 r1C l i/ SAMPLER NAME AND SIGNATURE d V PRINT Name oI SAMPLER: u57 4/� u N — p - o z N�, E 3 i SIGNATURE of SAMPLER n GATE : Signed / 0 'rc� r Ce r Environmental Quality Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance onfilling ad thisform, please visit littr)s://deg.tic.eov/about/divisions/eiier,y-mineral-land- resources/encrev-mineral-land-permits/siormwatcr-permits/npdes-ind ustrial-sw#tab-4 Permit T Facility County: Inspectc Date of Time of Total Event Precipitation (inches): LV All permits require qualitative monitoring to be performed during a "measurable storm event." A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DEMLR Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: (Signature of Permittee or Designee) 1. Outfall Description: OutfalI No. I Receiving Stream: Structure (pipe, ditch, etc.): rc�� 1111-e-4 the industrial activities that occur within the outfall drainage area: Page 1 of 2 S W U-242, Last modified 07/28/2017 2. Color: Describe the color of the discharge using basic (light, medium, dark) as descriptors: M AA)rfi b YUw blue, etc.) and tint 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): Alt) fl"r 4. Clarity: Choose the number which best describes the clarity of the discharge, where I is clear and 5 is very cloudy: 1 2 �J 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where I is no solids and 5 is the surface covered with floating solids: 1 2 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where I is no solids and 5 is extremely muddy: I 2 3 4 5 7. Is there any foam in the stormwater discharge? ;Xes o No. 8. Is there an oil sheen in the stormwater discharge? 0Yes bNo. 9. Is there evidence of erosion or deposition at the outfall? O Yes ('� 10. Other Obvious Indicators of Stormwater Pollution: List and describe C4. Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 S W U-242, last modified 0728/2017