NCG060039_MONITORING INFO_20191209

T2A�
STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
DOC TYPE
❑ HISTORICAL FILE
MONITORING REPORTS
DOC DATE
❑ go �a
YYYYMMDD

;r
GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
-Oil and Grease,
m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
—
120
30
6.0 — 9.0
100
1
11-08-19
ND <10.0
ND <4.8
7.1
3.0
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part R- Vehirle Maintenance Activitv Monitoring Requirements
Outfall
No.
Date
Sample Collected,
mo/dd/ r
00556
00530 -
00400
Oil and Grease,
m /L
Total Suspended Solids,
.m /L
pH,
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
30
100
6.0 — 9.0
RE(,ErN/F®
DEC 0 8 2019
EN RALTILEg
SECTION
ION
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range tot pH, you must implement I ier I or tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-08-19 (first event sampled)
Total Event Precipitation (inches): 0.512
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
11AZ /lei
(Date)
S WU-248- I02107
Page 2 of 2

NCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out thisform, please visit: htto://aortal.ncdenr.org/webAr/npdes-stormwater/
Permit No.: N/C/ G/ 0/ 0/ 0/0/0/0/ or Certificate of Coverage No.:
Facility Name: Grifols Therapeutics Inc
County: Johnston Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection:11-08-19
Time of Inspection: 1:00pm
Total Event Precipitation (inches):
Was this a 'Representative Storm Event' or "Measureable Storm Event' as defined by the permit?
(See information below.)
® Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a "representative storm
event" or "measureablestorm event" (requirements vary, depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a "representative storm event' or during a "measureable storm event" However,
some permits do not have this requirement. Please refer to these definitions, if applicable.
A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A "measurable storm event" is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period, and the permittee
obtains approval from the local DWQ Regional Office.
By this sign ure, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
Pagel of 2
SWU-242, Last modified 7/31/2013

1. Outfall Description:
Outfall No. 1 Structure (pipe, ditch, etc.) Stream
Receiving Stream: Tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area:
Pharmaceutical Manufacturing
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: clear with a medium brown tint
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil,
weak chlorine odor, etc.): None
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is
clear and 5 is very cloudy:
1 2 3 4 5
S. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
d 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
8. Is there an oil sheen in the stormwater discharge? Yes No,
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
i List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
II
Page 2 of 2
SWU-242, Last modified 7/31/2013

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvtical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/ yr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
m /L
pH, -
Standard units
- Total Suspended Solids,
- m /L
Benchmark
120,
30
6.0 — 9.0
100
2
11-08-19
21.4
ND <4.8
7.3
4.3
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier I or "Pier 2 responses. See General Fermat text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month?_ yes X no
(if yes, complete Part B)
Part R: Vehicle Maintenance Activitv Monitoring Reauirements
Outfall
- No.
'
Date.
Sample.Col)ected,
mo/dd/ r
"` 00556
00530
00400 - -
Oil and Grease,
- m /L
Total Suspended Solids,..
m /L
pH,
Standard units
New Motor Oil Usage,
.Average annual al/mo
Benchmark
30
100
6.0 — 9.0
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-08-19 (first event sampled)
Total Event Precipitation (inches): 0.51
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
I I
(Date)
S WU-248-102107
Page 2 of 2

NCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit: http://nortal.ncdenr.org/web/lr/nudes-stormwater/
Permit No.: or Certificate of Coverage No.: NX/G/0/6/0/0/3/9/
Facility Name: Grifols Therapeutics Inc
County: Johnston Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 11-08-19
Time of Inspection: 1:25pm
Total Event Precipitation (inches):
Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit?
(See information below.)
® Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a "representative storm
event" or "measureablestorm event" (requirements vary, depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a "representative storm event" or during a "measureable storm event" However,
some permits do not have this requirement. Please refer to these definitions, if applicable.
A "representative storm event' is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A "measurable storm event' is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period, and the permittee
obtains approval from the local DWQ Regional Office.
By this signalpieQ certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
Page 1 of 2
SWU-242, Last modified 7/31/2013

1. Outfall Description:
Outfall No. 2 Structure (pipe, ditch, etc.) Ditch exiting existing pond
Receiving Stream: Tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area:
Pharmaceutical Manufacturing
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: clear with a medium brown tint
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil,.
weak chlorine odor, etc.): None
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is
clear and 5 is very cloudy:
1 2 3 4 5
S. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge, where 1 is no solids and 5 is the surface covered with Floating solids:
l' 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
B. Is there an oil sheen in the stormwater discharge? Yes No
i
9. Is there evidence of erosion or deposition at the outfall? Yes No
u
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
a
Page 2 of 2
SWU-242, Last modified 7/31/2013

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE a
Outfall
No.
Date
Sample Collected,
mo/dd/vr
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L -
Oil and Grease,
mg1L
pH, -
Standard units -
_ Total Suspended Solids,
mg[L
Benchmark
120
30
6.0 — 9.0
'100
3
11-08-19
15.8
ND <4.8
7.3
ND <2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement Tier 1 or Tier 2 responses. See General Permit text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part B: Vehicle Maintenance Activity onitoring Requirements
Outfall
_ No.
Date
Sample Collected,..
mo/dd/vr
00556 -
00530.
00400
Oil and Grease,
m /L
Total .Suspended .Solids,
m /L
pH, -
Standard units
New Motor Oil Usage,
Average annual aUmo
Benchmark
30
100
6.0 — 9.0
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-08-19 (first event sampled)
Total Event Precipitation (inches): 0.51
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S W U-248-102107
Page 1 of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
11 /zz/ig
(Date)
S WU-248-102107
Page 2 of 2

V
CCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
Forguidance on filling out this form, please visit: htto://12ortal.ncdenr.or2/web/Ir/ni2des-stormwater/
Permit No.: N/0/0/0/0/ 0/0/0/0/ or Certificate of Coverage No.:
Facility Name: Grifols Therapeutics Inc
County: Johnston Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 11-08-19
Time of Inspection: 2:15pm
Total Event Precipitation (inches): .51
it
Was this a "Representative Storm Event" or "Measureable Storm Event' as defined by the permit?
(See information below.)
® Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a 'representative storm
I$
event" or "measureable storm event" (requirements vary, depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a "representative storm event' or during a "measureable storm event." However,
some permits do not have this requirement. Please refer to these definitions, if applicable.
A "representative storm event' is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A "measurable storm event' is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period, and the permittee
obtains approval from the local DWQ Regional Office.
By this signatux:e j certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
Pagel of 2
SWU-242, Last modified 7/31/2013

1. Outfall Description:
Outfall No. 3 Structure (pipe, ditch, etc.) Drain Pipe
Receiving Stream: Tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area:
Pharmaceutical Manufacturing
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: clear with a medium brown tint
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil,
weak chlorine odor, etc.): None
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is
clear and 5 is very cloudy:
1 2 3 4 5
S. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
1 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No.
8. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 7/31/2013

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analytical
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/WW cert #012
PLEASE SIGN ON THE REVERSE �
Outfall _ -
No.
-
Date .
Sample Collected,
mo/dd/ r
00340
00556
00400
00530
Chemical Oxygen Demand,
m /L
Oil and Grease,
-m /L
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
120
30
6.0 - 9.0
100
4
11-08-19
18.1
ND <4.8
7.0
11.2
Note: If you report a sampled value in excess of the benchmark value, you must implement -Iler I or I ier 2 responses. fee General rernttt text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes X no
(if yes, complete Part B)
Part R• Vnhirlp Nlaintenanrr Activity Monitoring Renuirements
Outfall
No. i '
- Date
Sample Collected,
mo/dd/ r
.00556
00530 - -
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
PH, -
Standard units
New Motor Oil Usage,
Average annual al/mo
Benchmark
30
100
6.0-9.0
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pfl, you must implement i ter i or i ter 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-08-19 (first event sampled)
Total Event Precipitation (inches): 0.51
Date (list each additional event sampled this reporting period, and rainfall amount)
Total Event Precipitation (inches):
Mail Original and one copy to:
Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Raleigh, NC 27699-1617
S WU-248-102107
Page 1 of 2

STORM WATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"1 certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
o /ZZ /!q
(Date) I
_ - S WU-248-102107
Page 2 of 2

AMA
61HR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit: http://portal.ncdenr.org/web/Ir/nodes-stormwater
Permit No.: N/C/ G/ 0/ 0/ 0/0/Q/Q/ or Certificate of Coverage No.: N/Q/Q/Q/6/Q/0/3/9/
Facility Name: Grifols Therapeutics Inc
County: Johnston Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 11-08-19
Time of Inspection: 2:05pm
Total Event Precipitation (inches): .51
Was this a "Representative Storm Event' or "Measureable Storm Event' as defined by the permit?
(See information below.)
® Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a "representative storm
event" or "measureable storm event" (requirements vary, depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a "representative storm event' or during a "measureable storm event." However,
some permits do not have this requirement. Please refer to these definitions, if applicable.
A "representative storm event' is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A "measurable storm event' is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period, and the permittee
obtains approval from the local DWQ Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
Pagel of 2
SWU-242, Last modified 7/31/2013

1. Outfall Description:
Outfall No. 4 Structure (pipe, ditch, etc.) Pipe from Pond
Receiving Stream: Tributary to the Neuse River
Describe the industrial activities that occur within the outfall drainage area:
Pharmaceutical Manufacturing
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: clear with a medium brown tint
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil,
weak chlorine odor, etc.): None
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is
clear and 5 is very cloudy:
1 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of Floating solids in
the stormwater discharge, where 1 is no solids and 5 is the surface covered with Floating solids:
1 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
1 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
8. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution:
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
I Page 2 of 2
SWU-242, Last modified 7/31/2013

GENERAL PERMIT NO. NCG060000
CERTIFICATE OF COVERAGE NO. NCG060039
FACILITY NAME Grifols Therapeutics
PERSON COLLECTING SAMPLES David S. Graham
CERTIFIED LABORATORY Pace Analvdcal
Part A: Specific Monitoring Requirements
STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
SAMPLES COLLECTED DURING CALENDAR YEAR: 2019
(This monitoring report is due at the Division no later than 30 days from the date
the facility receives the sampling results from the laboratory.)
COUNTY Johnston
PHONE NO. [phone]
Lab #NC/" cert #012
PLEASE SIGN ON THE REVERSE 4
Outfall
No.
Date
Sample Collected,
mo/dd/yr
00340
00556
00400
00530
Chemical Oxygen Demand;
m /L
Oil and Grease,
- .. mg/I.
pH,
Standard units
Total Suspended Solids,
m /L
Benchmark
120
30
6.0 — 9.0
100
5
11-08-19
15.5
ND <4.8
7.2
ND <2.5
Note: If you report a sampled value in excess of the benchmark value, you must implement l ter t or 1 ter 2 responses. bee veneral rernin text.
Does this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? yes X no
(if yes, complete Part B)
P—t R• Vnhirin nrn Artivity Mnnitnrina Rrm�irrmnntc
Outfall
No.
Date
Sample Collected;
mo/dd/vr
00556
00530
00400
Oil and Grease,
m /L
Total Suspended Solids,
m /L
pH,
Standard units -
New Motor Oil Usage,
Average annual - al/mo
Benchmark
30
100
6.0 — 9.0-
Note: If you report a sampled value in excess of the benchmark value, or outside the benchmark range for pH, you must implement I ter 1 or I let 2 responses.
See General Permit text.
STORM EVENT CHARACTERISTICS:
Date 11-08-19 (first event sampled) Mail Original and one copy to:
Total Event Precipitation (inches): 0.51 Attn: DWQ Central Files
NCDENR/ DWQ
1617 Mail Service Center
Date (list each additional event sampled this reporting period, and rainfall amount) Raleigh, NC 27699-1617
Total Event Precipitation (inches):
SWU-248-102107
Pagel of 2

STORMWATER DISCHARGE OUTFALL (SDO)
MONITORING REPORT
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the
information submitted. Based on my inquiry of the person or persons who manage the system, or those persons
directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including
the possibility of fines and imprisonment for knowing violations."
(Date)
S WU-248-102107
Page 2 of 2

Ad
Vr
CCDENR
Stormwater Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out thisform, please visit: http://portal.ncdenr.oriz/web/Ir/nudes-stormwater
Permit No.: N/C/ G/ 0/ 0/ 0/0/0/0/ or Certificate of Coverage No.:
Facility Name: Grifols Therapeutics Inc
County: Johnston Phone No. 919-359-5473
Inspector: David S. Graham
Date of Inspection: 11-08-19
Time of Inspection: 1:40pm
Total Event Precipitation (inches): .51
d
Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit?
(See information below.)
® Yes ❑ No
Please verify whether Qualitative Monitoring must be performed during a "representative storm
event" or "measureable storm event" (requirements vary, depending on the permit).
Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be
performed during a "representative storm event" or during a "measureable storm event." However,
some permits do not have this requirement. Please refer to these definitions, if applicable.
A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall
and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than
0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no
precipitation.
A "measurable storm event" is a storm event that results in an actual discharge from the
permitted site outfall. The previous measurable storm event must have been at least 72 hours
prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter
interval is representative for local storm events during the sampling period, and the permittee
obtains approval from the local DWQ Regional Office.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
(Signature of Permittee or Designee)
Pagel of 2
SWU-242, Last modified 7/31/2013

1. Outfall Description:
Outfall No. 5 Structure (pipe, ditch, etc.) Creek
Receiving Stream: Tributary to the Neuse River
Describe the industrial activities that occur within the outfall. drainage area:
!' Pharmaceutical Manufacturing
2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: clear with a medium brown tint
" 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil,
weak chlorine odor, etc.): None
4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is
clear and 5 is very cloudy:
1 2 3 4 5
5. Floating Solids: Choose the number which best describes the amount of Floating solids in
'! the stormwater discharge, where 1 is no solids and 5 is the surface covered with Floating solids:
1 2 3 4' S
6. Suspended Solids: Choose the number which best describes the amount of suspended
solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
ji 2 3 4 5
7. Is there any foam in the stormwater discharge? Yes No
B. Is there an oil sheen in the stormwater discharge? Yes No
9. Is there evidence of erosion or deposition at the outfall? Yes 'No
10. Other Obvious Indicators of Stormwater Pollution:
�i
List and describe: None
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition
may be indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SWU-242, Last modified 7/31/2013

N -
r �
lacieAnalyficail
vww.paah6s.con
November 20, 2019
Sam Vedder
Grifols Therapeutics, LLC
8368 US 70 West
Clayton, NC 27520
RE: Project: Stormwater
Pace Project No.: 92453176
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Dear Sam Vedder:
Enclosed are the analytical results for sample(s) received by the laboratory on November 11, 2019.
The results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
cc: David Graham, Grifols Therapeutics, LLC
REPORT OF LABORATORY ANALYSIS
ii This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 16

aceAnalytical
wim paeelablican
Project: Stormwater
Pace Project No.: 92453176
Pace Analytical services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 633
VirginiaNELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, -LC. Page 2 of 16

aceAnalytical e
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i
SAMPLE ANALYTE COUNT
Project: Stormwater
Pace Project No.: 92453176
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
92453176001
Outfall #1
SM 254OD-2011
NMH
1
PASI-E
EPA 1664B
AACt
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92453176002
#3-South Plant Pipe
SM 254OD-2011
NMH
1
PASI-E
EPA 1664B
AAC1
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92453176003
#4-SE Pond
SM 254OD-2011
NMH
1
PASI-E
EPA 1664E
AAC1
1
PASI-C
SM 5220D-2011
GC
i
PASI-A
92453176004
#5-Consolidated Outfall
SM 254OD-2011
NMH
1
PASI-E
EPA 16646
AAC1
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
92453176005
#2-Basin #2
SM 2540D-2011
NMH
1
PASI-E
EPA 1664E
AAC1
1
PASI-C
SM 5220D-2011
GC
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not tie reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 16

(�IaceAnalytical
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ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92453176
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
sample: uutrau 41 Lab ID: 92453176001 Collected: 11/08/1913:00 Received: 11/11/1913:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. QUal
2540D Total Suspended Solids
Total Suspended Solids
HEM, Oil and Grease
Oil and Grease
5220D COD Low Level
Chemical Oxygen Demand
Date: 11/20/2019 04:36 PM
Analytical Method: SM 254OD-2011
3.0 mg/L 2.5 1 11/13/1909:31
Analytical Method: EPA 1664E
NO mg/L 4.8 1 11/20/1910:20
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
NO mg/L 10.0 1 11/15/19 22:07 11/18/19 16:34
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the wntten consent of Pace Analytical Services, LLC.
Page 4 of 16

Pace Analytical Services, LLC
laceAnalyficale 6701 ConferenceDrive07
Raleigh, NC 27607
www.pecelebc.com [phone]
,
ANALYTICAL RESULTS
' Project: Stormwater
Pace Project No.: 92453176
Sample: #3-South Plant Pipe
lab ID: 92453176002 Collected: 11/08/19 14:15
Received: 11/11/19 13:10 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed CAS No. Qual
,i 2540D Total Suspended Solids
Analytical Method: SM 254OD-2011
!I
Total Suspended Solids
ND mg/L 2.5 1
11/13/19 09:32
HEM, Oil and Grease
Analytical Method: EPA 1664B
Oil and Grease
ND mg/L 4.8 1
11/20/19 10:20
5220D COD Low Level
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
Chemical Oxygen Demand
15.8 mg/L 10.0 1
11/15/19 22:07 11/18/19 16:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/20/2019 04:36 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 16

aceAnalytical
www.pacelebs.cere
ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92453176
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: #4-SE Pond Lab ID: 92453176003 Collected: 11/08/19 14:05 Received: 11/11/19 13:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Total Suspended Solids
HEM, Oil and Grease
Oil and Grease
5220D COD Low Level
Chemical Oxygen Demand
Date: 11/20/2019 04:36 PM
Analytical Method: SM 2540D-2011
11.2 mg/L 2.6 1 11/13/1909:33
Analytical Method: EPA 1664B
NO mg/L 4.8 1 11/20/1910:20
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
18.1 mg/L 10.0 1 11/15/1922:07 11/18/1916:37
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
will the written consent of Pace Analytical Services, LLC,
Page 6 of 16

laceAnalytilical*
rinr.paalsEs.con
ANALYTICAL RESULTS
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Project: Stormwater
Pace Project No.: 92453176
Sample: #5-Consolidated Outfall Lab ID: 92453176004 Collected: 11/08/1913:40 Received: 11/11/1913:10 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Total Suspended Solids
HEM, Oil and Grease
Oil and Grease
5220D COD Low Level
Chemical Oxygen Demand
Date: 11/20/2019 04:36 PM
Analytical Method: SM 254OD-2011
ND mg/L 2.5 1 11/13/1909:45
Analytical Method: EPA 1664E
ND mg/L 4.8 1 11/20/1910:20
Analytical Method: SM 5220D-2011 Preparation Method: SM 52200-2011
15.5 mg/L 10.0 ,1 11/15/19 22:07 11/18/19 16:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, -LC. Page 7 of 16

aceAnalytical e
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ANALYTICAL RESULTS
Project: Stormwater
Pace Project No.: 92453176
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Sample: 02-Basin#2 Lab ID: 92453176005 Collected: 11/0811913:25 Received: 11/11/1913:10 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
2540D Total Suspended Solids
Total Suspended Solids
HEM, Oil and Grease
Oil and Grease
5220D COD Low Level
Chemical Oxygen Demand
Date: 11/20/2019 04:36 PM
Analytical Method: SM 254OD-2011
4.3 mg/L 2.5 1 11/13/1909:53
Analytical Method: EPA 1664B
NO mg/L 4.8 1 11/20/1910:20
Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011
21.4 mg/L 10.0 1 11/15/19 22:07 11/18/19 16:38
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 16

I
aceAnalytical a
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, INC 27607
[phone]
Project: Stormwater
Pace Project No.: 92453176
QC Batch: 509191
Analysis Method: SM 254OD-2011
II QC Batch Method: SM 2540D-2011
Analysis Description: 2540D Total Suspended Solids
" Associated Lab Samples: 92453176001, 92453176002, 92453176003, 92453176004, 92453176005
METHOD BLANK: 2732822
Matrix: Water
Associated Lab Samples: 92453176001, 92453176002, 92453176003, 92453176004, 92453176005
'I
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Suspended Solids
mg/L
NO 2.5 11/13/19 09:29
LABORATORY CONTROL SAMPLE:
2732823
Spike LCS LCS %Rec
Parameter
Units
Conc. Result %Rec Limits Qualifiers
Total Suspended Solids
mg/L
250 246 98 90-110
SAMPLE DUPLICATE: 2732825
92453280001 Dup
Parameter
Units
Result Result RPD Qualifiers
, Total Suspended Solids
mg/L
2590 2520 3
I
SAMPLE DUPLICATE: 2732826
92453280004 Cup
Parameter
Units
Result Result RPD Qualifiers
'I Total Suspended Solids
mg/L
50.9 58.1 13
Results presented on this page are in the units Indicated by the "units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/20/2019 04:36 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16

(�IaceAnajtyfical'
ww.pacelabs.wn
QUALITY CONTROL DATA
Project: Stormwater
Pace Project No.: 92453176
QC Batch: 510614 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease
Associated Lab Samples: 92453176001, 92453176002, 92453176003, 92453176004, 92453176005
METHOD BLANK: 2739395 Matrix: Water
Associated Lab Samples: 92453176001, 92453176002, 92453176003, 92453176004, 92453176005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 4.8 11/20/19 10:20
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
LABORATORY CONTROL SAMPLE:
2739396
Spike LCS
LCS
%Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
Oil and Grease
mg/L
38.5 35.2
91
78-114
MATRIX SPIKE SAMPLE:
2739397
92452591004 Spike
MS
MS
e/ Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Oil and Grease
mg/L
ND 38.5
37.3
92
78-114
Results presented on this page are In the units Indicated by the "Units- column except where an alternate unit is presentee to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/20/2019 04:36 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 16

Pace Analytical Services, LLC
aceAnalytical o
6701 Conference Drive
Raleigh, NC 27607
rww.pacelabs.con
[phone]
QUALITY CONTROL DATA
Project: Stormwater
i Pace Project No.: 92453176
QC Batch: 509898
Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011
Analysis Description: 5220D COD, Low Level
Associated Lab Samples: 92453176001, 92453176002,
92453176003, 92453176004, 92453176005
I, METHOD BLANK: 2736496
Matrix: Water
Associated Lab Samples: 92453176001, 92453176002,
92453176003, 92453176004, 92453176005
�
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
'I Chemical Oxygen Demand mg/L
i
ND 10.0 11/18/1916:23
LABORATORY CONTROL SAMPLE: 2736497
Spike LCS LIDS %Rec
Parameter Units
i
Conc. Result % Rec Limits Qualifiers
Chemical Oxygen Demand mg/L
75 72.9 97 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736498 2736499
MS MSD
92452733001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Conc. Conc. Result Result %Rec %Rec
Limits RPD Qual
Chemical Oxygen Demand mg/L 80.2
75 75 149 148 91 91
90-110 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2736500 2736501
MS MSD
92453807003
Spike Spike MS MSD MS MSD
e/ Rec
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD Qual
Chemical Oxygen Demand mg/L 18.1
75 75 96.6 96.6 105 105
90-110 0
Results presented on this page are In the unite Indicated by Me -Units' column except xTere an alternate unit Is presented to the right of the result.
Date: 11/20/2019 04:36 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 16

aceAnalytical
www.pacelaDs.rom
QUALIFIERS
Project: Stormwater
Pace Project No.: 92453176
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC -Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
PQL - Practical Quanfitation Limit.
RL - Reporting Limit -The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260,
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-E Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11/20/2019 04:36 PM without the wntten consent of Pace Analytical Services, LC. Page 12 of 16

aceAnalytical
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
,i Project: Stormwater
Pace Project No.: 92453176
i
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
I Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92453176001
Outfall #1
SM 254OD-2011
509191
92453176002
#3-South Plant Pipe
SM 254OD-2011
509191
92453176003
#4-SE Pond
SM 2540D-2011
509191
92453176004
#5-Consolidated Outfall
SM 2540D-2011
509191
. 92453176005
#2-Basin#2
SM 2540D-2011
509191
92453176001
Outfall#1
EPA 1664B
510614
" 92453176002
#3-South Plant Pipe
EPA 16646
510614
92453176003
#4-SE Pond
EPA 1664B
510614
i92453176004
#5-Consolidated Outfall
EPA 1664B
510614
92453176005
#2-Basin#2
EPA 1664E
510614
92453176001
Outfall #1
SM 5220D-2011
509898
SM
5220D-2011
510226
�I 92453176002
#3-South Plant Pipe
SM 5220D-2011
509898
SM
5220D-2011
510226
92453176003
#4-SE Pond
SM 52200-2011
509898
SM
5220D-2011
510226
.I 92453176004
#5-Consolidated Outfall
SM 5220D-2011
509898
SM
5220D-2011
510226
92453176005
#2-Basin#2
SM 5220D-2011
509898
SM
5220D-2011
510226
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
:,Date: 11/20/2019 04:36 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 16

Name:
Revised: February 7, 2019
Laboratory receiving samples:
Asheville ❑ Eden[]
Greenwood ❑ Huntersville ❑ Ralel h g ©-- Mechanicsville❑
Client Name:
W0# : QI2 5aq %6
G r/"ta 15 Tine
Project a w sY�P .d �i es d t es
L
r C. e u C S
Courier: ❑Fed Ex ❑UPS
s ❑USPS ❑Uient
❑Commercial QYe0.r
[:]Other:—
— 92453176
Custody Seal Present? Dyes P<o
�,��
Seals Intact? ❑Yes L`<o -
Dato/1nRlalsPerson Examining contents: ZAIl' -11-17
Paddng Material: []Bubble Wrap
ubhle Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer:
❑IRGunID: q>OUS
❑Yes ONO MNI%—
Typo of ice: et ❑Blue ❑None
Cooler Temp ('C)o 3.1 Correction
Factor: Add/Subtract ('C) 0
Cooler 3'
Temp should be above freezing to 6'C
Temp Corrected ('C):
[]Samples out of temp criteria. Samples on ice, cooling process
USDA Regulated Soil
g ( /A, water sample)
has begun
Did samples originate In a quarantine zone within the
❑Yes ❑No _
United States: CA, NY, or SC (check maps)? Old samples originate from a foreign saurce Ilnternallonally,
Indudlna Flawall and Puerto Ricni?I-lYes flNo
Comments/Discrepancy:
ustody Present?
es
❑No
N/A
1.
rrived within Hold Time?
es
_ No
❑N/A
2.
RH-4An
Time Analysis <72 hr.)?
Yes
❑N/A
3.
Around Time Re nested?
Yes
No
/A
4.
SufficientVolume?
es
No
N/A
S.
ntainers Used?
ontainers Used?
—
EVV
❑No
No
❑N/A
N A
6.
es
No
❑N/A
7
lysis: Samples Field Filtered?
No
A
a.
=Intaa?aa?
Match COC? `' rW.
ate/-Rmc/ID/Anal sls Matrix. ,fOA
,ElYes
❑Na
❑N/A
9.
Vials (>5-6mm)7
Yes
Na
/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
Yes
❑No
LJN.
LWA
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review: � O
Project Manager SRF Review:
Date/Time:
Field Data Required? []Yes ❑Na
Date:
Date: tlltli/�
Page 14 of 16

. Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Recei t(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
r ,... aeeArfafytfeat
'
. F-CAR-M033•Rev.06
Pace Carolinas Quality Office
*Check mark top half of box If pH and/or dechlorination Is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box Is to list number of bottle
Project» .WOE ; 92453g76
PM: MWB Due Date: 11/20/19
CLIENT: 91-GrifolEHS
d
a
Z
T
b
rS
z
a
<-
a
s
o
z
2
N
2
m
m
5
9
O
Y
?
N
V
N
V
M
N
Au
J
2
y
N
N
V
N
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8

Grifols Therapeutics Inc
GRIFOLS
November 25, 2019
Central Files
Division of Water Resources (DWR)
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
To whom it may concern:
8368 U.S. Highway 70 Business West
Clayton, NC 27520
Tel. [phone]
www.gdfols.com
Attached you will find the semi-annual analytical SDO monitoring report following a representative storm event
on November 81h for the Grifols Therapeutics Clayton, NC facility. If you have any questions, please don't
hesitate to contact me at 919-359-5473
Sincerely,
c
David S. Graham
Senior ESS