NCG030636_MONITORING INFO_20190506

STORMWATER DIVISION CODING SHEET
NCG PERMITS
PERMIT NO.
DOC TYPE
❑ HISTORICAL FILE
0-rMONITORING REPORTS
DOC DATE
❑ 1) U� 0
YYYYM M D D

Semi-annual Stormwater Discharge Monitoring Report
for North Carolina Division of Water Quality General Permit No. NCG030636
Date submitted 4/29/2019
CERTIFICATE OF COVERAGE NO. NCG030363
FACILITY NAME Systems Logistics
COUNTY Buncombe
PERSON COLLECTING SAMPLES Scott Phillips
LABORATORY Pace Analytical Lab Cert. # L1087641
Comments on sample collection or analysis: Total rainfall event 0.72"
Part A: Stormwater Benchmarks and Monitoring Results
SAMPLE COLLECTION YEAR 2019
SAMPLE PERIOD ® Jan -June ❑ July -Dec
or ❑ Monthly' (month)
DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA
RE�EIV ❑Zero -flow ❑Water Supply [:]SA
Ep ®Other SDO
C �A1' B 2019 PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3 4
DWR SEL F/L S
❑ No discharge this period?z
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches'
Total Suspended Solids
pH,
Standard units
Copper
Lead
Zinc
Non -Polar O&G/
Total Petroleum
Hydrocarbons
Total Toxic
Organics'
Benchmarks =__>
-
-
100 mg/L or 50 mg/O
6.0 — 9.0
0.007 mg/L
0.03 mg/L
0.067 mg/L
15 mg/L
1 mg/L
002
4/05/2019
0.72
ND
7.20
ND
ND
0.0503
ND
' Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
Z For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
'The total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
"See General Permit, Table 3 identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
5 Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor
manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date:11/1/2018-10/31/2022 SWU-245, last revised 10/25/2012
Page 1 of 3

Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring
may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General
Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics
(TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the Stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the
solvent management plan included in the Stormwater Pollution Prevention Plan."
Scott Phillips
Name (Print name)
Safety Manager
Title (Print title)
� /
(Signature) (Date)
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical
format. When results are below the applicable limits, they must be reported in the format, "<XX mg/L", where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 1, or Tier 3 responses. see General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
❑ No discharge this period?z
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches'
Non -polar O&G/TPH by
EPA 1664(SGT-HEM)
Total Suspended Solids
pH
Benchmarks =__>
-
-
15 mg/L
100 mg/L or 50 mg/L*
6.0 — 9.0 SU
Footnotes from Part A also apply to this Part B
* See General Permit text, Table 5, identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
Permit Date: 11/1/2018-10/31/2022 SWU-245, last revised 10/25/2012
Page 2 of 3

Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 2, or Tier 3 responses. See General Permit text.
FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ❑ NO
IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ❑ NO ❑
REGIONAL OFFICE CONTACT NAME:
Mail an original and one coov of this DMR, including all "No Discharge" reports within 30 days of receipt of the lab results for at end of monitoring period
in the case of "No Discharge" reports) to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
(Signature of Permittee)
(Date)
Permit Date:11/1/2018-10/31/2022
SWU-245, last revised 10/25/2012
Page 3 of 3

lWAUTOMATIO
AAfNOUSE
N
January 22, 2015
Central Files
Division of Water Quality
1617 Mail Service Center
Raleigh, NC 27699-1617
RE: ITW Warehouse Automation
Semi-annual discharge monitoring reports (DMR)
Monitoring period Year 2-Period 2
To Whom it May Concern,
RECEIVED
FEB 0 4 2015
CENTRAL FILES
DWR SECTION
The ITW Warehouse Automation (`ITW") facility located in Arden, North Carolina is
submitting the following information to the Division of Water Quality ("Division') in regards to
the facility general industrial permit NCG030636. Please note, ITW was formerly named
Vertique, Inc.
The current monitoring period is recognized as July 1, 2014 through December 31, 2014. The
sample analysis attached was collected from outfall 002. The results were not reported within 30
days of the date of collection due to an oversight in permit conditions. In 2014, facility
personnel were trained to the SPPP and best management practices. Also, specific personnel
were identified to properly collect samples and report out as needed. Due to facility management
changes and a change in job classifications, the DMR was not submitted within 30 days of
receiving the sample results. ITW will ensure that all future DMRs will be prepared and
submitted according to permit parameters.
Attached is the discharge monitoring report required for monitoring period year 2-period 2. The
sampling requirements per Section D of the General Permit are below:
a. September 2, 2014/ITW location outfall 002/1:25pm
b. Jose Gomez/Paint Booth Operator
c. January 22, 2015
d. Environmental Science Corporation (ESC)
e. See attached analysis
f. See attached analysis
Appalachian Environmental Resources, Inc. has been contracted to handle the water quality
program at the facility. The Stormwater Pollution Prevention Plan (SPPP) has been developed
and 0 information pertaining to the NPDES permit for Metal Fabrication has been completed.

W A Rs E H 0` LQS fflt,
W A�11��TObM$A�'TIO.�N
If you have any questions or require additional information in regards to this submittal, please
contact me at (828)-654-7500 or Michael Fox at (423)-956-2900.
I certify, under penalty of law, that this document and all attachments were prepared under my
direction or supervision in accordance with a system designed to assure that qualified personnel
properly gather and evaluate the information submitted Based on my inquiry of the person or
persons who manage the system, or those persons directly responsible for gathering the
information, the information submitted is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are signifuant penalties for submitting false information,
including the possibility offines and imprisonmentfor knowing violations.
Sincerely,
Chris Bland
Plant Manager
ITW Warehouse Automation
Cc: File copy
Attachments

Semi-annual Stormwater Discharge Monitoring Report
for North Carolina Division of Water Quality General Permit No. NCG030000
Date submitted 1/22/2015
CERTIFICATE OF COVERAGE NO. NCG030363 SAMPLE COLLECTION YEAR 2014
FACILITY NAME ITW Warehouse Automation SAMPLE PERIOD ❑ Jan -June ® July -Dec
COUNTY Buncombe or ❑ Monthly' (month)
PERSON COLLECTING SAMPLES Michael Fox DISCHARGING TO CLASS ❑ORW ❑HQW ❑Trout ❑PNA
LABORATORY ESC Lab Cert. # L721922 ❑Zero -flow ❑Water Supply []SA
Comments on sample collection or analysis: Total rainfall event 0.95" ®Other SDO
Part A: Stormwater Benchmarks and Monitoring Results
PLEASE REMEMBER TO SIGN ON PAGES 2 AND/OR 3
No discharge this period?'
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches'
Total Suspended Solids
pH,
Standard units
Copper
Lead
Zinc
Non -Polar O&G/
Total Petroleum
Hydrocarbons
Total Toxic
Organics'
Benchmarks =__>
-
-
100 mg/L or 50 mg/O
6.0 — 9.0
0.007 mg/L
0.03 mg/L
0.067 mg/L
15 mg/L
1 mg/L
002
9/02/2014
0.95
1 10.0
1 7.2
1
1 BDL-0.005
I BDL-5.7
' Monthly sampling (instead of semi-annual) must begin with the second consecutive benchmark exceedance for the same parameter at the same outfall.
Z For sampling periods with no discharge at any single outfall, you must still submit this discharge monitoring report with a checkmark here.
IThe total precipitation must be recorded using data from an on -site rain gauge. Unattended sites may be eligible for a waiver of the rain gauge requirement.
° See General Permit, Table 3 identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
' Total Toxic Organics sampling is applicable only for those facilities which perform metal finishing operations, manufacture semiconductors, manufacture
electronic crystals, or manufacture cathode ray tubes. For purposes of this permit the definition of Total Toxic Organics is that definition contained in the EPA
Effluent Guidelines for the facility subject to the requirement to sample (for metal finishing use the definition as found in 40 CFR 433.11; for semiconductor
manufacture use the definition as found in 40 CFR 469.12; for electronic crystal manufacture use the definition as found in 40 CFR 469.22; and for cathode ray
tube manufacture use the definition found in 40 CFR 469.31).
Permit Date: 11/1/2012-10/31/2017 SWU-245, last revised 10/25/2012
Page 1 of 3

Facilities that incorporate a solvent management plan into the Stormwater Pollution Prevention Plan may so certify, and the requirement for TTO monitoring
may be waived. The solvent management plan shall include a list of the total toxic organic compounds used and the other elements listed in the General
Permit. For those facilities electing to employ the TTO monitoring waiver, the discharger shall sign the following certification statement:
"Based upon my inquiry of the person or persons directly responsible for managing compliance with the permit monitoring requirement for total toxic organics
(TTO), I certify that to the best of my knowledge and belief, no dumping of concentrated toxic organics into the stormwater or areas which are exposed to rainfall or
stormwater runoff has occurred since filing the last discharge monitoring report. I further certify that this facility is implementing the all the provisions of the
solvent management plan included in the Stormwater Pollution Prevention Plan."
Chris Bland
Name (Print name)
Plant Manager
Title (Print title) /j /f
(Signature) (Date)
Note: Results must be reported in numerical format. Do not report Below Detection Limit, BDL, <PQL, Non -detect, ND, or other similar non -numerical
format. When results are below the applicable limits, they must be reported in the format, "<XX ma/L", where XX is the numerical value of the detection
limit, reporting limit, etc. in mg/L.
Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier 1, or Tier 3 responses. See General Permit text.
Part B: Vehicle Maintenance Area Monitoring Results: only for facilities averaging > 55 gal of new oil per month.
❑ No discharge this period?2
Outfall No.
Date Sample
Collected'
(mo/dd/yr)
24-hour rainfall
amount,
Inches
Non -polar 0&G/TPH by
EPA 1664 (SGT-HEM)
Total Suspended solids
pH
Benchmarks =__>
15 mg/L
100 mg/L or 50 mg/L*
6.0 — 9.0 Su
Footnotes from Part A also apply to this Part B
' See General Permit text, Table 5, identifying the especially sensitive receiving water classifications where the more protective benchmark applies.
Permit Date: 11/1/2012-10/31/2017 SWU-245, last revised 10/25/2012
Page 2 of 3

Note: If you report a sample value in excess of the benchmark, you must implement Tier 1, Tier Z or Tier 3 responses. See General Permit text.
FOR PART A AND PART B MONITORING RESULTS:
• A BENCHMARK EXCEEDANCE TRIGGERS TIER 1 REQUIREMENTS. SEE PERMIT PART II SECTION B.
• 2 EXCEEDANCES IN A ROW FOR THE SAME PARAMETER AT THE SAME OUTFALL TRIGGER TIER 2 REQUIREMENTS. SEE PERMIT PART If SECTION B.
• TIER 3: HAS YOUR FACILITY HAD 4 OR MORE BENCHMARK EXCEEDENCES FOR THE SAME PARAMETER AT ANY ONE OUTFALL? YES ❑ NO
IF YES, HAVE YOU CONTACTED THE DWQ REGIONAL OFFICE? YES ❑ NO ❑
REGIONAL OFFICE CONTACT NAME:
Mail an original and one copy of this DMR including all "No Discharge" reports within 30 days of receipt of the lab results for at end of monitoring period
in the case of "No Discharge" reports) to:
Division of Water Quality
Attn: DWQ Central Files
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
YOU MUST SIGN THIS CERTIFICATION FOR ANY INFORMATION REPORTED:
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or
those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I
am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
(Signature of
/-��
(Date)
Permit Date:11/1/2012-10/31/2017
SWU-245, last revised 10/25/2012
Page 3 of 3

Appalachian Environmental Resources
Sample Delivery Group: L1087641
Samples Received: 04/10/2019
Project Number:
Description: System Logistics (Vertique)
Report To: Mike Fox
300 W Watauga Ave. Suite 4
Johnson City, TN 37601
Entire Report Reviewed By: J /1�4—
Stacy Kennedy
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This lest report shall not be
reproduced. except in full. without written approval of the laboratory. Where applicable, sampling conducted by Pace National
is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304.
Im
aceAnalytical • ANALYTICAL REPORT
National CenlerM Testlrp6hvavew April 19, 2019
ram,

TABLE OF CONTENTS
ONE LAB. NATIONWIDE.
Cp: Cover Page
1
Cp
Tc: Table of Contents
2
Ss: Sample Summary
3
4¢
Cn: Case Narrative
Sr: Sample Results
4
5
35s
OUTFALL 001 L1O87641-01
5
4
Cn
Qc: Quality Control Summary
6
Gravimetric Analysis by Method 2540 D-2011
6
5Sr
Wet Chemistry by Method 1664A
Metals (ICP) by Method 6010E
7
8
FOCI
GI: Glossary of Terms
9
GI
Al: Accreditations & Locations
10
Sc: Sample Chain of Custody
11
eAl
9Sc
ACCOUNT: PROJECT: SDG: DATEMME: PAGE:
Appalachian Environmental ReSOUrCeS L1087641 04/19/1917:48 2 of 11

SAMPLE
SUMMARY
ONE LAB. NATIONWIDE.
Collected by
Collected date/time
Received dateAnne
CUTFALL001 L1087641-01 GW
Scott Phillips
0410511909:30
04110/1908:00
iC
p
Method
Batch
Dilution Preparation
date/time
Analysis
date/time
Analyst Location
Z
Tc
Gravimetric Analysis by Method 2540 D-2011
WG1264491
1 04112A919:00
04/12/19 22:51
AEC Mt. Juliet. TN
Wet Chemistry by Method 1664A
WG1265781
1 04/14/19 09:02
04114/1914:08
DAD Mi. Juliet, TN
Metals (ICP) by Method 6010E
WG1264466
1 041161191128
04/19119 07:50
TRB Mt. Juliet, TN
4Cn
SSr
6QC
�GI
BAI
aSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Appalachian Environmental Resources L1087641 04119/1917:48 3 of 11

CASE NARRATIVE ONE LAB. NATIONWIDE.
All sample aliquots were received at the correct temperature, in the proper containers, with the 1Cp
appropriate preservatives, and within method specified holding times, unless qualified or notated within z
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples Tc
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form a
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my S5
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
Fri
[GI
Stacy Kennedy aA1
I Project Manager
9Sc
ACCOUNT: PROJECT: SDG: DATEMME: PAGE:
Appalachian Environmental Resources L1087641 04/19/19 17:48 4 of 11

OUTFALL 001
SAMPLE RESULTS - 01
ONE LAB. NATIONWIDE.
Collected date/time: 04/05/19 09:30
L1087641
Additional Information
1C p
Result
Units
z
Analyte
pH (On Site) 7.2
su
TC
Gravimetric Analysis by Method 2540 D-2011
3Ss
Result
Oualifier
ROL
Dilution Analysis
Batch
Analyte m9R
mgll
date/time
4
Cn
Suspended Solids NO
2.50
1 0411M19 22:51
WG1264491
Wet Chemistry by Method 1664A
Result
Oualitier
RDL
Dilution Analysis
Batch
6
Analyte mg/l
mg)1
date/time
Oe
Oil & Grease )Hexane Exit) NO
5.88
1 04114/201914:08
WG1265781
7GI
Metals (ICP) by Method 6010E
Result
Qualifier
RDL
Dilution Analysis
Batch
"Al
Analyte mg/1
mg/I
date)time
Copper NO
0.0100
1 04119/201907:50
WG1264466
9SC
Lead NO
0,00500
1 041191201907:50
WG1264466
Zinc 0.0503
0.0500
1 04119/201907:50
WG1264466
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Appalachian Environmental Resources L1087641 04119/19 17:48 5 of ll

WG1264491 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Gravimetrlc Analysis by Method 2540 D-2011 L1087641.01
Method Blank (MB) 1 C
(MB) R3401530-1 04/12/19 22:51
MB Result
MB Qualifier MB MDL
MB RDL
Analyte mg/I
m9/1
mg/I
Suspended Solids U
0.350
2.50
L1086494-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1086494-01 04/12/19 22:51 • (DUP) R3401530-3 04/12/19 22:51
Original Result
DUP Result
Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyte mg/I
mgll
%
%
Suspended Solids 17.4
26.0
1 39.6
J3 5
L1086559-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1086559-01 04/12/19 22:51 • (DUP) R3401530-4 04/12/19 22:51
Original Result
DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
Analyze
mgll
mg0 %
%
Suspended Solids
245
308 1 22.8
J3 5
Sample Narrative:
OS: All that would filter.
Laboratory Control Sample (LCS)
(LCS) R3401530-2 04/12/19 22:51
Spike Amount LCS Result LCS Rec. Rea. Limits LCS Qualifier
Analyte mgll mg/I % %
Suspended Solids 773 772 99.9 85.0-115
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Appalachian Environmental Resources L1087641 04/19/1917,48 6 of 11

WG1265781 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE.
Wet Chemistry by Method 1664A L1087641.01
Method Blank (MB)
(MB) R3401603-1 04/14/19 14:08
MB Result
Analyte m
Oil & Grease (Hexane Extr) U
MB Qualifier MB MDL MB RDL
BrB�.x�v:
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3401603-2 04/14/19 14:08 • (LCSD) R3401603-3 04/14/19 14:08
Spike Amount LCS Result LCSD Result
LCS Rec.
LCSD Rec
Rec. Limits
LCS 0uallrier LCSD Qualifier RPD RPD Limits
Analyle mg/1 mgfl mg/I
%
%
%
% %
Oil & Grease (Hexane Exh) 40.0 33.1 38.4
828
96.0
78.0-114
14.8 20
ACCOUNT:
Appalachian Environmental Resources
PROJECT:
SDG: DATEITIME:
L1087641 0411911917:48
PAGE:
7 of11

WG1264466 QUALITY
CONTROL
SUMMARY
ONE LAB. NATIONWIDE.
Metals LICP) by Method 6010B
L1087641-01
'
Method Blank (MB)
1 Cp
(MB) R3403589-1 04/19/19 07:33
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mgl) mg/I
FTC]
Copper U 0.00530 0.0100
Lead U 0.00190 0.00500
aSS
Zinc U 0.00590 0.0500
4Cn
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate
(LCSD)
(LCS) R3403589-2 04/19/19 07:35 - (LCSD) R3403589-3 04/19/19 07:38
s Sf
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec
Rec. Limits LCS Qualifier LCSD Qualifier
RPO
RPD Limits
Analyte mgh mg/1 mg/I % %
%
%
%
•
Copper 7.00 0.990 0.998 99.0 99.8
80.0-120
0.854
20
Lead 1.00 0.910 0.916 91.0 91.6
80.0-120
0.637
20
Zinc 1.00 0.883 0.889 88.3 89.9
80.0-120
0.670
20
G�
Matrix Spike Duplicate
eAl
L1O87782-01 Original Sample (OS) • Matrix Spike (MS) • (MSD)
(OS) L1087782-01 04/19/19 07:40 • (MS) R3403589-5 04/19/19 07:45 • (MSD) R3403589-6 04/19/19 07:48
s
Spike Amount Original Result MS Result MSD Result MS Rec.
MSD Rec Dilution Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Sc
Analyte mgn mg4 mg/I mg/I %
%
%
%
%
Copper 1.00 U 0.996 1.02 99.6
102 1
75.0-125
1.98
20
-
Lead 1.00 0.00495 0.932 0.952 92.7
94.7 1
75.0-125
2.20
20
Zinc 1.00 U 0.879 0.900 87.9
90.0 1
75.0-125
2.32
20
ACCOUNT: PROJECT: SDG:
Appalachian Environmental Resources L1087641
DATE/TIME:
04/19/19 1749
PAGE:
8 of 11

GLOSSARY OF.TERMS ONE LAB. NATIONWIDE.
Guide to Reading
and Understanding Your Laboratory Report
C
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
p
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Abbreviations and Definitions
=
Tc
MDL
Method Detection Limit.
a
NO
Not detected at the Reporting Limit (or MDL where applicable),
$S
RDL
Reported Detection Limit
Rec.
Recovery.
4
Cn
RED
Relative Percent Difference.
SDG
Sample Delivery Group.
fiSr
U
Not detected at the Reporting Limit (or MDL where applicable).
❑
The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
Analyte
reported.
fi
If the sample matrix contains an interfering material, the sample preparation volume or weigh[ values differ from the
QC
standard, or If concentrations of analytes in the sample are higher than the highest limit of concentration that the
Dilution
laboratorycan accurately report, the sample maybe diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or %difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful OC Sample analysis will target all analytes recovered or
duplicated within these ranges.
aAl
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
Original Sample
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
SC
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state 'No' (Not Detected) or'BDL'
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyze.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results. including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Quality Control
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
Summary (CC)
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
Sample Summary (Ss)
times of preparation and/or analysis.
Qualifier
Description
J3
The associated batch QC was outside the established quality control range for precision.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
Appalachian Environmental Resources L1087641 04119h917:48 9 of 11

ACCREDITATIONS &.LOCATIONS ONE LAB. NATIONWIDE. V
Pace National Is the only environmental laboratory accrel itedlcenified W support your work nationwide from one location. One phone oil. one point of contact one laboratory. No other Lab is as
accessible or prepared to haMle your needs throughout the country. Our capacity and capability from our single location laboratory Is comparable to itw collective totals of the network
laboratories in our Industry. The most significant benefit to our one location design Is the design of our laboratory campus. The model is conducive to accelerated producihnity, decreasing
turn-0rourea time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt seMCa allows us to be YOUR LAB OF CHOICE.
Not all certifications held by the Laboratory are appll®ble to the results reported In the attached report
' Accreditation Is only applicable to the test methods specified on each scope of accreditation held by Pace National.
State Accreditations
Alabama
40660
Nebraska
NEOS-15-05
Alaska
17-026
Nevada
T"3-200234
Arizona
AZO612
New Hampshire
2975
Arkansas
88-M9
New Jersey—NELAP
TNO02
California
2932
New Mexico'
Na
Colorado
TN00003
New York ,
11742
r—n r,Vrut
PH-0197
North Carolina
Env375
Georgia NELAP
Georgia' 923
IMM TN00003
Indiana C-TN-01
Iowa 364
Kentucky1°
90010
Kentucky'
16
Louisiana
A130792
Lou61ana1
IA180010
Maine
TN0002
Maryland
324
Massachusetts
M-TNO03
Michigan
9958
Minnesoa
047-999-395
Micdccinni
TN00003
Third Party Federal Accreditations
A21A —ISO 17025 1461,01
Canada 1461.01
EPA—Crypto TN00003
North Carolina
DW21704
North Carolina °
Ti
North Dakota
R-140
Ohio—VAP
CLOO69
Oklahoma
9915
Oregon
TN200002
Pena nh2rua
68-02979
Rhode Island
LA000356
South Carolina
84004
South Dakota
Na
Tennessee 14
2006
Texas
T104704245-18-15
Texas'
LABO152
Utah
TN00003
Vermont
VT2006
Virginia
460132
Washington
C947
West Virginia
233
Wisconsin
9980939910
Wvnrra.
A2L1
USDA
'Drinking Water ' Underground Storage Tanks ' Aquatic ToxiCity 4 ChemlcapMlcroblological 'Mold 6Wastewater Na Accreditation not applicable
Our Locations
Pace National has sixty-four client support centers that provide sample pickup anchor the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact
our main office. Pace National performs all testing at our central laboratory.
ACCOUNT: PROJECT: SDG: DATE7TIME:
Appalachian Environmental Resources L1087641 04/1911917:48
PAGE:
f0 of 11

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