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NCG030556_MONITORING INFO_20180306
M� STORMWATER DIVISION CODING SHEET NCG PERMITS PERMIT NO. �V �� D J! Jr DOC TYPE ❑ HISTORICAL FILE IX MONITORING REPORTS DOC DATE ❑ C) % 3 YYYYM M D D STORAIWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT GENERAL PERMIT NO. NCG030000 SAMPLES COLLECTED DURING CALENDAR YEAR: a 0 ( � CERTIFICATE OF COVERAGE NO. NCG03 00 0 O (This monitoring report is due al the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACH.ITY NAME ftMeM, -,- , �ty�9o—lz�L >. Vq - _ COUNTY (A P-(- 0 ' 4 %o � r PERSON COLLECTING SAALES O WA^- eS PHONE NO. (`�0 J/ SSCoS CERTIFIED LABORATORY [4(2 i�Ot4lV�cc Lab # Lab # PLEASE SIGN ON THE REVERSE Part A: Specific Monitoring Requirements Nnlr- Ifvnu report a sampled value in excess of the benclunark value, or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses. See General Permit text. Did this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes _no (if yes, complete Part B) cart m Note: If you report a sampled value in excess of the See General Permit text. STORM EVENT CHARACTERISTICS: Date 3 is /K (first event sampled) Total Event Precipitation (inches): o or outside the benchmark range for pH, you must implement Tier 1 or Tier 2 responses. Date (list each additional event sampled this reporting period, and rainfall amount) Total Event Precipitation (inches): Mail Original and one copy to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 hil S WU-245-102107 Page l of 2 F NC®ENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out th isform, please visit.- httn://uortal.ncdennore/web(wq/ws/su/npdessw#tab-4 Permit No.: N/C/tr/0/ 3/Q/U/tl /J/ or Certificate of Coverage No.: N/C/G/_/_/_/_/_/_/ Facility Name: County: -Aeg Date of Inspection: Time of Inspection: 1 Total Event Precipitation (inches): : 4LO Phone No. Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) VIY'es ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event"or "measureablestorm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall 11 and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: of Permittee or Designee) Pagel of 2 NO 1. Outfall Description: Outfall No. A I Structure Receiving Stream: PC.Q,.A Lo -t- Describe the industrial activities that 1—", ' _A /n_ n ditch, etc.) A.-r , / : -\ j within the outfalfdrainage area: 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors b'tavx 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): IN p ye 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 0 4 5 S. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 2 3 4 5 7. Is there any foam in the stormwater discharge? Yes No 8. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 0r NC®ENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out this form, please visit: httn://portal ncdenr org/web/wq/ws/su/npdessw#tab-4 Permit No.: or Certificate of Coverage No.: N/C/G/_/_/_/_/_/_/ Facility Name: AV has r c n -tro-t-h7&6� I eC. -f County: Aec-U�A,oLr'%- Phone No. Inspector: 6�2y- { AO-i C S Date of Inspection: v I IV Time of Inspection: 11' 70,%-- Total Event Precipitation (inches): D Y4 Was this a "Representative Storm Event" or "Measureable Storm Event' as defined by the permit? (See information below.) 2Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a 'representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event' or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall l and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the I permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By tjii1signature, I certify that this report is accurate and complete to the best of my knowledge: of Permittee or Designee) Pagel of 2 1 1. Outfall Description: Outfall No. �� Structure ( ipe, ditch, etc.) Receiving Stream: b1z c i . 'e \ Describe the industrial activities that occur within the outfall drainage area: P- .V � i _ /Mel_ i , �,._ 1 "Tn.. ,k %.%. t _,1_n 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: TeA imgj-V M 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): Al O M 2 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 30 4 5 5. Floating Solids: Choose the number which best describes the amount of Floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 0 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 (D 3 4 5 7. Is there any foam'in the stormwater discharge? Yes No B. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWPPP Form 3: Rain Event Data 1 This form will be used to document any rainfall data starting at least 72 hours before the expected representative storm event. Personnel Date/Time/Rainfall a I a I' 01 Date/Time/Rainfall Date/Time/Rainfall ( �( (g / I pm Date/Time/Rainfall f 3 f Date/Time/Rainfall 3 (41 IV 11 e ;Oe— Date/Time/Rainfall 3 (S/ si : 3JPA, /QOD Date/Time/Rainfall 031 to I I y I� Stormwater Pollution Prevention Plan Appendices (�52ceAnalytical' .pacelaG.mm March 19, 2018 Mr. Gary Harries American Truetzschler, Inc. PC Box669228 12300 Moores Chapel Rd. 28214 Charlotte. NC 28266 RE: Project: Stormwater Samples Pace Project No.: 92375792 Dear Mr. Harries: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, o" W-M . +U)W-I l Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, -LC. Page 1 of 30 aceAnalytical e w idacelabs.com Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florda/NELAP Certification #: E87648 Massachuseds Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 30 aceAnalytical .pecelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Stormwater Samples 92375792 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92375792001 Al EPA 1664E JMS 1 PASI-C EPA 200.7 SH1 12 PASI-A EPA 245.1 SER 1 PASI-A EPA625 BPJ 58 PASI-C EPA624 GAW 38 PASI-C SM 2540D MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA 9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A EPA 420.4 DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A 92375792002 A2 EPA 1664E JMS 1 PASI-C EPA 200.7 SH7 12 PASI-A EPA 245.1 SER 1 PASI-A EPA625 BPJ 58 PASI-C EPA624 GAW 38 PASI-C SM 2540D MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA 9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A EPA 420A DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 3 of 30 aceAnalytical wvwpecNebscom ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[ HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease NO mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Antimony ND ug/L 5.0 1 0310711802:45 03/1611803:22 7440-36-0 Arsenic ND ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7440-38-2 Beryllium NO ug/L 1.0 1 03/07/18 02:45 03/16/18 03:22 7440-41-7 Cadmium ND ug/L 1.0 1 03/07/18 02:45 03116/1803:22 7440-43-9 Chromium ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7440-47-3 Copper 10.3 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7440-50-8 Lead ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7439-92-1 Nickel NO ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7440-02-0 Selenium NO ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7782-49-2 Silver NO ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7440-22-4 Thallium NO ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7440-28-0 Zinc 27.6 ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7440-66-6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA245.1 Mercury ND ug/L 0.20 1 03/07/1813:35 03107/1818:10 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 208-96-8 Anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-12-7 Benzidine ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 56-55-3 Benzo(a)pyrene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 50-32-8 Senzo(b)fluoranthene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 205-99-2 Benzo(g,h,i)perylene NO ug/L 5.0 1 03/0711809:08 03110/1801:21 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/07/1809:08 0311011801:21 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 03/0711809:08 03/10/18 01:21 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/07/18 09:08 03/1011801:21 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 03/0711809:08 03/1011801:21 91-58-7 2-Chlorophenol ND ug/L 5.0 1 03/07/1809:08 03/10/18 01:21 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:21 7005-72-3 Chrysene ND ug/L 5.0 1 03107/1809:08 03/10/18 01:21 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 0310711809:08 03/1011801,21 53-70-3 3,3'-Dichlorobenzidine ND ug/L 25.0 1 03/0711809:08 03/10/1801:21 91-94-1 2,4-Dichlorophenol NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-83-2 Diethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 105-67-9 Dimethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 84-74-2 4.,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/07/1809:08 03/10/18 01:21 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 03/07/1809:08 03110/1801:21 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 30 laceAnalyficalo • aacdabsoom ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua[ 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 2,4-Dinilrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 121-14-2 2,6-Dinitroto[uene ND ug/L 5.0 1 03/07/1809:08 03110/1801:21 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 122-66-7 bis(2-Ethylhexyl)phtha[ate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-81-7 Fluoranthene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 206-44-0 Fluorene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 77-47-4 Hexachloroethane ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 193-39-5 Isophorone NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 78-59-1 Naphthalene NO ug/L 5.0 1 03107/1809:08 03/10/18 01:21 91-20-3 Nitrobenzene NO ug/L 5.0 1 03/0711809:08 03/10/18 01:21 98-95-3 2-Nitrophenol NO ug/L 5.0 1 03/07/1809:08 03/10/18 01:21 88-75-5 4-Nitrophenol NO ug/L 50.0 1 03/07/18 09:08 03/1011801:21 100-02-7 N-Nitrosodimethylamine NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 03/0711809:08 03110/1801:21 86-30-6 Pentachlorophenol ND ug/L 10.0 1 03/07/18 09:08 03110/1801:21 87-86-5 Phenanthrene ND ug/L 5.0 1 03/07/1809:08 03110/1801:21 85-01-8 Phenol ND ug/L 5.0 1 03107/1809:08 03110/1801:21 108-95-2 Pyrene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 120-82-1 2 4,6-Trichlorophenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 88-06-2 Surrogates Nitrobenzene-d5 (S) 45 % 10-120 1 03/07/18 09:08 03/10/18 01:21 4165-60-0 2-Fluorobiphenyl (S) 41 % 15-120 1 03/07/18 09:08 03/10/18 01:21 321-60-8 Terphenyl-d14 (S) 56 % 11-131 1 03/07/18 09:08 03/10/18 01:21 1718-51-0 Phenol-d6 (S) 14 % 10-120 1 03/07/18 09:08 03/10/18 01:21 13127-88-3 2-Fluorophenol(S) 20 % 10-120 1 03/07/18 09:08 03/10/18 01:21 367-12-4 2,4,6-Tnbromophenol (S) 57 % 10-137 1 03/07/18 09:08 03/10/18 01:21 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acrolein ND ug/L 5.0 1 03/08/18 15:06 107-02-8 Acrylonitrile ND ug/L 50.0 1 03/08/18 15:06 107-13-1 Benzene ND ug/L 2.0 1 03/08/1815:06 71-43-2 Bromodichloromethane ND ug/L 2.0 1 03/08/18 15:06 75-27-4 Bromoform ND ug/L 2.0 1 03/08/18 15:06 75-25-2 Bromomethane ND ug/L 2.0 1 03/08/18 15:06 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 03/08/18 15:06 56-23-5 Chlorobenzene ND ug/L 2.0 1 03108/1815:06 108-90-7 Chloroethane ND ug/L 2.0 1 03/08/18 15:06 75-00-3 2-Chloroethy[vinyl ether ND ug/L 5.0 1 03/08/18 15:06 110-75-8 Chloroform ND ug/L 2.0 1 03/08/18 15:06 67-66-3 Chloromethane ND ug/L 2.0 1 03/08/18 15:06 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Date: 03/19/2018 02A6 PM without the wntlen consent of Pace Analytical Services. U.C. Page 5 of 30 aceAnalytical .pace1e6s.com ANALYTICAL RESULTS Pace AnatyticaI Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA624 Dibromochloromelhane ND ug/L 2.0 1 03/08/18 15:06 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 03/081181506 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 03/08/18 15:06 75-35-4 cis-1,2-Dichloroethene NO ug/L 2.0 1 03/08/18 15:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 1506 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 03/0811815*06 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 03/0811815:06 10061-02-6 Ethylbenzene ND ug/L 2.0 1 03/0811815:06 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/08/18 15:06 87-68-3 Methylene Chloride ND ug/L 2.0 1 03/08/18 15:06 75-09-2 Naphthalene NO ug/L 5.0 1 03/0811815:06 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 03/08/18 15:06 79-34-5 Tetrachloroethene ND ug/L 2.0 1 03/08/18 1506 127-18-4 Toluene ND ug/L 2.0 1 03/08/18 15:06 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 03/08/18 15:06 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 03/08/18 15:06 79-00-5 Trichloroethene ND ug/L 2.0 1 03/08/18 15:06 79-01-6 Vinyl chloride ND ug/L 2.0 1 03/08/18 15:06 75-01-4 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 03/08/18 15:06 460-00-4 Toluene-d8(S) 117 % 70-130 1 03/08/18 15:06 2037-26-5 1,2-Dichloroethane-d4 (S) 79 % 70-130 1 03/08/18 15:06 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 38.4 mg/L 5.0 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide ND mg/L 0.10 1 03/0911818:00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 6.1 Std. Units 0.10 1 03/07/18 21:16 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 13.4 mg/L 1.0 1 03/12/18 15:02 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0.010 1 0310911813:18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Cyanide NO mg/L 0.0080 1 0311611804:19 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 30 aceAnalytical w vpecelabsown ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntemville, NC 28078 (704)875-9092 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[ HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method* EPA 200.7 Antimony ND ug/L 5.0 1 0310711802:45 03/1611803*25 7440-36-0 Arsenic ND ug/L 10.0 1 03/0711802:45 03/16/18 03:25 7440-38-2 Beryllium ND ug/L 1.0 1 03/0711802:45 03/16/18 03:25 7440-41-7 Cadmium NO ug/L 1.0 1 03/07/18 02:45 03/16/18 03:25 7440-43-9 Chromium 7.5 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-47-3 Copper 12.2 ug/L 5.0 1 03/07/18 02:45 0311611803:25 7440-50-8 Lead 7.3 ug/L 5.0 1 03107/1802:45 03/16/18 03:25 7439-92-1 Nickel ND ug/L 5.0 1 03107/1802:45 03116/1803:25 7440-02-0 Selenium ND ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7782-49-2 Silver ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-22-4 Thallium ND ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7440-28-0 Zinc 97.7 ug/L 10.0 1 03/0711802:45 03/16/18 03:25 7440-66-6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method : EPA 245.1 Mercury ND ug/L 0.20 1 03/07/1813:35 03/07/1818*12 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene NO ug/L 5.0 1 03/07/18 09:08 03110/1801:51 208-96-8 Anthracene NO ug/L 5.0 1 03/07/18 09:08 03110/1801:51 120-12-7 Benzidine ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:51 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 03/07/18 09:08 0311011801:51 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 50-32-8 Benzo(b)0uoranthene ND ug/L 5.0 1 03107/1809:08 03/1011801:51 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 03107/1809:08 03/1011801:51 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 03/07/18 09:08 0311011801:51 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/0711809:08 03/10/18 01:51 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 85-68-7 4-Chloro-3-methylphenol NO ug/L 5.0 1 03107/1809:08 03/1011801:51 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 111-91-1 bis(2-Chloroethyl) ether NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-58-7 2-Chlorophenol ND ug/L 5.0 1 03107/1809:08 03/10/18 01:51 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 7005-72-3 Chrysene ND ug/L 5.0 1 0310711809:08 03110/1801:51 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 53-70-3 3,3'-Dichlorobenzidine ND ug/L 25.0 1 03/07/18 09:08 03/10/18 01:51 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 03M7/18 09:08 03/10/18 01:51 120-83-2 Diethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 105-67-9 Dimethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 131-11-3 Di-n-butylphthalate NO ug/L 5.0 1 03107/1809:08 03110/1801:51 84-74-2 4.,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/07/18 09:08 03/10/18 01:51 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:51 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02: 16 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 30 aceAnalytical e xwxpacelsAcmrn ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06118 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 2,4-Dinitrotoluene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 03/0711809:08 03110/1801:51 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 03/0711809:08 03110/1801:51 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 03/0711809:08 03/1011801:51 117-81-7 Fluoranthene NO ug/L 5.0 1 03/0711809:08 03/10/18 01 *51 206-44-0 Fluorene ND ug/L 5.0 1 03/07/18 09:08 03/1011801:51 86-73-7 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03107/1809:08 03/10/18 01:51 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 77-47-4 Hexachloroethane NO ug/L 5.0 1 03/07/1809:08 03/10/18 01:51 67-72-1 Indeno(1,2,3-cd)pyrene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 193-39-5 Isophorone NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 78-59-1 Naphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-20-3 Nitrobenzene NO ug/L 5.0 1 03107/1809:08 03/10/18 01:51 98-95-3 2-Nitrophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 88-75-5 4-Nitrophenol ND ug/L 50.0 1 03107/1809:08 03/10/1801:51 100-02-7 N-Nitrosodimethylamine NO ug/L 5.0 1 03107/1809:08 03/10/18 01:51 62-75-9 N-Nitroso-di-n-propylamine NO ug/L 5.0 1 0310711809:08 03/1011801:51 621-64-7 N-Nilrosodiphenylamine ND ug/L 10.0 1 03/07/18 09:08 03/1011801:51 86-30-6 Pentachlorophenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 87-86-5 Phenanthrene ND ug/L 5.0 1 0310711809:08 03110118 01 *51 85-01-8 Phenol ND ug/L 5.0 1 03/07/1809:08 03/10/18 01:51 108-95-2 Pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 129-00-0 1,2,4-Trichlorobenzene NO ug/L 5.0 1 03/0711809:08 03/10/18 01:51 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 03107/1809:08 03/1011801:51 88-06-2 Surrogates Nitrobenzene-d5(S) 56 % 10-120 1 03/07/18 09:08 03/10/18 01:51 4165-60-0 2-Fluorobiphenyl(S) 53 % 15-120 1 03/07/18 09:08 03/1011801:51 321-60-8 Terpheny1-d14(S) 67 % 11-131 1 03/07/18 09:08 03/10/18 01:51 1718-51-0 Phenol-d6 (S) 18 % 10-120 1 03/07/18 09:08 03/10/18 01:51 13127-88-3 2-Fluorophenol(S) 27 % 10-120 1 03/07/18 09:08 03/10/18 01:51 367-12-4 2,4,6-Tribromophenol(S) 71 % 10-137 1 03/07/18 09:08 03/10/18 01:51 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acrolein NO ug/L 5.0 1 03/08/1815:22 107-02-8 Acrylonmle ND ug/L 50.0 1 03/08/18 15:22 107-13-1 Benzene NO ug/L 2.0 1 03/08/1815:22 71-43-2 Bromodichloromethane NO ug/L 2.0 1 03/08/18 15:22 75-27-4 Bromoform NO ug/L 2.0 1 0310811815:22 75-25-2 Bromomethane ND ug/L 2.0 1 03108/1815:22 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 03/08/18 1522 56-23-5 Chlorobenzene NO ug/L 2.0 1 03/08/1815:22 108-90-7 Chloroethane NO ug/L 2.0 1 03/08/18 15:22 75-00-3 2-Chloroethylvinyl ether NO ug/L 5.0 1 03/08/18 15:22 110-75-8 Chloroform NO ug/L 2.0 1 03/08/18 15:22 67-66-3 Chloromethane NO ug/L 2.0 1 03/08/18 15:22 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 30 aceAnalytical .pacelabscoe ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 624 Volatile Organics Analytical Method: EPA 624 Dibromochloromethane ND ug/L 2.0 1 03/0811815:22 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:22 95-50-1 1,3-Dichlorobenzene NO ug/L 2.0 1 03/08/18 15:22 541-73-1 14-Dichlorobenzene ND uglL 2.0 1 03108/1815:22 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:22 75-34-3 1,2-Dichloroethane ND uglL 2.0 1 03/08/18 15:22 107-06-2 1,1-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 75-35-4 cis-1,2-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 156-59-2 trans-1,2-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 156-60-5 1,2-Dichloropropane NO ug/L 2.0 1 03/08/18 15:22 78-87-5 cis-1,3-Dichloropropene NO ug/L 2.0 1 03/08/18 15:22 10061-01-5 trans- 1, 3-Dichloropropene NO ug/L 2.0 1 03/08/18 15:22 10061-02-6 Ethylbenzene ND ug/L 2.0 1 03/0811815:22 100-41-4 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03/08/18 15:22 87-68-3 Methylene Chloride NO ug/L 2.0 1 03/08/18 15:22 75-09-2 Naphthalene NO ug/L 5.0 1 03108/1815:22 91-20-3 1,1,2,2-Tetrachloroethane NO ug/L 2.0 1 03/08/18 15:22 79-34-5 Tetrachloroethene NO ug/L 2.0 1 03/08/18 15:22 127-18-4 Toluene NO ug/L 2.0 1 03/08/18 15:22 108-88-3 1,1, 1-Trichloroethane NO ug/L 2.0 1 03/08/18 1522 71-55-6 1,1,2-Trichloroethane NO ug/L 2.0 1 03/08/18 15:22 79-00-5 Trichloroethene NO ug/L 2.0 1 03/08/18 15:22 79-01-6 Vinyl chloride NO ug/L 2.0 1 03/08/18 15:22 75-01-4 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 03/08/18 15:22 460-00-4 Toluene-d8(S) 116 % 70-130 1 03/08/18 15:22 2037-26-5 1,2-Dichloroethane-d4 (S) 80 % 70-130 1 03/08/18 15:22 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 74.0 mg/L 12.5 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide NO mg/L 0.10 1 03/09/1818*00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 5.0 Slid. Units 0.10 1 03/07/1821:16 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 5.8 mg/L 1.0 1 03/12/18 15:18 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0.010 1 0310911813: 18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Cyanide ND mg/L 0.0080 1 03/16/18 04:20 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 9 0f 30 aceAnalytical w wpacn/abs.aun QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntemville, NC 28078 (704)875-9092 QC Batch: 402480 Analysis Method: EPA 1664B QC Batch Method: EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2232441 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 03/19/18 04:48 LABORATORY CONTROL SAMPLE &LCSD: 2232442 2232443 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Oil and Grease mg/L 40 37.2 37.6 93 94 78-114 1 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 10 of 30 aceAnalytical QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 400949 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223700 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/0711817:13 LABORATORY CONTROL SAMPLE: 2223701 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Mercury ug/L 2.5 2.6 105 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223702 2223703 MS MSD 92375598001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Mercury ug/L NO 2.5 2.5 2.6 2.6 106 102 70-130 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223704 2223705 MS MSD 92375805002 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cana Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L NO 2.5 2.5 2.7 2.7 108 107 70-130 1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 aceAnalytical a .paceraea.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Balch: 400889 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223386 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony uglL ND 5.0 03/17/1818:17 Arsenic ug/L ND 10.0 03/17/1818:17 Beryllium ug/L ND 1.0 03/17/1818:17 Cadmium ug/L NO 1.0 03/17/1818:17 Chromium ug/L NO 5.0 03/17/1818:17 Copper ug/L NO 5.0 0311711818:17 Lead ug/L NO 5.0 0311711818:17 Nickel ug/L NO 5.0 03/17/18 18:17 Selenium ug/L NO 10.0 03/17/18 18:17 Silver ug/L NO 5.0 03/17/18 18:17 Thallium ug/L NO 10.0 03/1711818:17 Zinc ug/L NO 10.0 03117/18 18:17 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2223387 Units Spike Conc. LCS Result LCS °% Rec %Rec Limits Antimony ug/L 500 502 100 85-115 Arsenic ugll- 500 507 101 85-115 Beryllium ug/L 500 518 104 85-115 Cadmium uglL 500 502 100 85-115 Chromium uglL 500 514 103 85-115 Copper ug/L 500 508 102 85-115 Lead ug/L 500 489 98 85-115 Nickel ug/L 500 507 101 85-115 Selenium ug/L 500 487 97 85-115 Silver ug/L 250 254 102 85-115 Thallium ug/L 500 517 103 85-115 Zinc ug/L 500 494 99 85-115 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Antimony ug/L 43.3 500 500 545 527 100 97 70-130 3 Arsenic ug/L NO 500 500 474 458 94 91 70-130 4 Beryllium ug/L NO 500 500 510 494 102 99 70-130 3 Cadmium ug/L NO 500 500 525 506 105 101 70-130 4 Chromium ug/L NO 500 500 534 514 106 102 70-130 4 Results presented on this page are in the units indicated by the "Units" column except where an altemate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 30 aceAnalytical ewwpeceWbaccm QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Dual Copper ug/L 14.5 500 500 549 523 107 102 70-130 5 Lead ug/L NO 500 500 476 458 95 91 70-130 4 Nickel ug/L 7.9 500 500 513 495 101 97 70-130 4 Selenium ug/L NO 500 500 518 502 103 100 70-130 3 Silver ug/L NO 250 250 264 256 106 102 70-130 3 Thallium ug/L NO 500 500 345 328 69 66 70-130 5 M1 Zinc ug/L 60.5 500 500 554 535 99 95 70-130 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 30 0 aceAnalytical .pacelabs.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 OC Batch: 401152 Analysis Method: EPA 624 QC Batch Method: EPA 624 Analysis Description: 624 MSV Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2224898 Associated Lab Samples: 92375792001. 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1-Trichloroethane ug/L NO 2.0 03/08/18 12:33 1,1,2,2-Tetrachloroethane ug/L NO 2.0 0310811812:33 1,1,2-Trichloroethane ug/L NO 2.0 03/08/18 12:33 1,1-Dichloroethane ug/L NO 2.0 03/08/18 12:33 1,1-Dichloroethene ug/L NO 2.0 03/08/18 12:33 1,2-Dichlorobenzene ug/L NO 2.0 03/08/18 12:33 1,2-Dichloroethane ug/L NO 2.0 03/08/18 12:33 1,2-Dichloropropane ug/L NO 2.0 03/08/18 12:33 1,3-Dichlorobenzene ug/L NO 2.0 03/08/18 12:33 1,4-Dichlorobenzene ug/L NO 2.0 0310811812:33 2-Chloroethylvinyl ether ug/L NO 5.0 03/08/18 12:33 Acrolein ug/L NO 5.0 03/08/18 12:33 Acrylonitrile ug/L ND 50.0 03/0811812:33 Benzene ug/L NO 2.0 03/08/18 12:33 Bromodichloromethane ug/L ND 2.0 03/08/18 12:33 Bromoform ug/L ND 2.0 03/08/18 12:33 Bromomethane ug/L ND 2.0 03/08/18 12:33 Carbon tetrachloride ug/L ND 2.0 03/08/18 12:33 Chlorobenzene ug/L ND 2.0 03/08/18 12:33 Chloroethane ug/L NO 2.0 03108/1812:33 Chloroform ug/L ND 2.0 03108/1812:33 Chloromethane ug/L NO 2.0 03108/1812:33 cis-1,2-Dichloroethene ug/L NO 2.0 03/08/18 12:33 cis-1,3-Dichloropropene ug/L NO 2.0 03/08/18 12:33 Dibromochloromethane ug/L NO 2.0 03/08/18 12:33 Ethylbenzene ug/L NO 2.0 03/0811812:33 Hexachloro-1,3-butadiene ug/L NO 5.0 03/08/18 12:33 Methylene Chloride ug/L NO 2.0 03/08/18 12:33 Naphthalene ug/L NO 5.0 03/08/18 12:33 Tetrachloroethene ug/L NO 2.0 03/08/18 12:33 Toluene ug/L NO 2.0 03/08/18 12:33 trans-1,2-Dichloroethene ug/L NO 2.0 03/08/18 12:33 trans-1,3-Dichloropropene ug/L NO 2.0 03/08/18 12:33 Trichloroethene ug/L NO 2.0 03/08/18 12:33 Vinyl chloride ug/L NO 2.0 03/08/18 12:33 1,2-Dichloroethane-d4 (S) % 85 70-130 03/08/18 12:33 4-Bromofluorobenzene (S) % 99 70-130 03/08/18 12:33 Toluene-d8 (S) % 112 70-130 03/08/18 12:33 Qualifiers Results presented on this page are in the units indicated by the'UNts" column except where an aitemate unit Is presented to the fight of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 30 aceAnalytical mrw.pacetabs.cnm QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE: Parameter 2224899 Units Spike Cone. LCS Result LCS % Rec %Rec Limits 1,1,1-Trchloroelhane ug/L 20 22.0 110 52-162 1,1,2,2-Tetrachloroethane ug/L 20 19.8 99 46-157 1,1,2-Trichloroethane ug/L 20 21.0 105 52-150 1,1-Dichloroethane ug/L 20 19.8 99 59-155 1,1-Dichloroethene ug/L 20 23.0 115 1-234 1,2-Dichlorobenzene ug/L 20 19.8 99 18-190 1,2-Dichloroethane ug/L 20 21.3 106 49-155 1,2-Dichloropropane ug/L 20 22.1 111 1-210 1,3-Dichlorobenzene ug/L 20 19.6 98 59-156 1,4-Dichlorobenzene ug/L 20 18.8 94 18-190 2-Chloroethylvinyl ether ug/L 40 32.2 81 1-305 Acrolein ug/L 100 103 103 15-152 Acrylonith a ug/L 100 99.2 99 75-132 Benzene ug/L 20 21.0 105 37-151 Bromodichloromethane ug/L 20 22A 112 35-155 Bromoform ug/L 20 18.5 92 45-169 Bromomethane ug/L 20 18.7 93 1-242 Carbon tetrachloride ug/L 20 21.6 108 70-140 Chlorobenzene ug/L 20 20.2 101 37-160 Chloroelhane ug/L 20 24.2 121 14-230 Chloroform ug/L 20 19.9 99 51-138 Chloromelhane ug/L 20 18.4 92 1-273 cis-1,2-Dichloroethene ug/L 20 21.1 105 68-146 cis-1,3-Dichloropropene ug/L 20 21.3 107 1-227 Dibromochloromethane ug/L 20 21.2 106 53-149 Ethylbenzene ug/L 20 20.3 101 37-162 Hexachloro-1,3-buladiene ug/L 20 18.5 92 70-130 Methylene Chloride ug/L 20 20.7 104 1-221 Naphthalene ug/L 20 20.0 100 70-130 Tetrachloroethene ug/L 20 19.1 95 64-148 Toluene ug/L 20 20A 101 47-150 trans-1,2-Dichloroethene ug/L 20 21.3 107 54-156 trans-1,3-Dichloropropene ug/L 20 21.2 106 17-183 Trichloroelhene ug/L 20 21.6 108 71-157 Vinyl chloride ug/L 20 22.3 112 1-251 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % - 101 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 MS MSD 92375577001 Spike Spike Parameter Units Result Cone. Cone. 2224901 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Qualifiers MS MSD MS MSD % Rec Result Result % Rec % Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L NO 20 20 23.8 23.5 119 118 46-171 1 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.9 21.7 109 108 73-159 1 Results presented on this page are in the units indicated by the -Units" column except where an altemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 30 aceAnalytical w pareJabscom QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 2224901 MS MSD 92375577001 Spike Spike MS MSD MS MSD e/ Rec Parameter Units Result Cone. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,2-Trichloroethane ug/L ND 20 20 23.6 22.2 118 111 64-152 6 1,1-Dichloroethane ug/L ND 20 20 21.3 21.7 107 108 43-172 2 1,1-Dichloroethene ug/L ND 20 20 23.1 23.6 116 118 48-189 2 1,2-Dichlorobenzene ug/L ND 20 20 22.3 22.0 112 110 54-154 2 1,2-Dichloroethane ug/L ND 20 20 22.8 23.2 114 116 42-171 2 1,2-Dichloropropane ug/L ND 20 20 25.2 24.4 126 122 55-157 4 1,3-Dichlorobenzene ug/L ND 20 20 22.7 22.5 114 113 57-148 1 1,4-Dichlorobenzene ug/L ND 20 20 22.8 22.7 114 113 58-149 0 2-Chloroethylvinyl ether ug/L ND 40 40 ND ND 0 0 70-130 M1,c2 Acrolein ug/L ND 100 100 112 108 112 108 70-130 4 Acrylonitrile ug/L ND 100 100 103 108 103 108 70-130 4 Benzene ug/L ND 20 20 24.0 23.3 120 117 54-163 3 Bromodichloromethane ug/L ND 20 20 24.6 23.8 123 119 56-152 3 Bromoform ug/L ND 20 20 20.8 21.6 104 108 53-151 4 Bromomethane ug/L ND 20 20 17.3 18.0 86 90 10-200 4 Carbon tetrachloride ug/L ND 20 20 25A 23.9 126 119 41-175 5 Chlorobenzene ug/L ND 20 20 23.3 23.0 117 115 67-152 1 Chloroelhane ug/L ND 20 20 27.0 25.2 135 126 23-200 7 Chloroform ug/L ND 20 20 21.1 21.7 105 109 51-166 3 Chloromethane ug/L ND 20 20 19.3 18.4 97 92 40-175 5 cis-1,2-Dichloroethene ug/L ND 20 20 22.3 23.1 111 115 45-174 4 cis-1,3-Dichloropropene ug/L ND 20 20 23.8 23.3 119 116 38-146 2 Dibromochloromelhane ug/L ND 20 20 24.2 25.3 121 126 65-144 4 Elhylbenzene ug/L ND 20 20 23.5 23.0 117 115 57-152 2 Hexachloro-1,3-butadiene ug/L ND 20 20 20.7 22.3 104 112 70-130 8 Methylene Chloride ug/L ND 20 20 21.6 22.0 108 110 40-167 2 Naphthalene ug/L ND 20 20 22.0 23.2 110 116 70-130 5 Tetrachloroethene ug/L ND 20 20 22.7 21.3 114 107 59-155 6 Toluene ug/L ND 20 20 22.6 21A 113 106 47-162 7 trans-1,2-Dichloroethene ug/L ND 20 20 23.0 22.5 115 112 47-178 2 trans-1,3-Dichloropropene ug/L ND 20 20 24.0 22.2 120 111 39-148 8 Trichloroethene ug/L ND 20 20 24.3 24.6 121 123 60-153 1 Vinyl chloride ug/L ND 20 20 23.9 22.6 120 113 46-176 6 1,2-Dichloroethane-d4 (S) % 96 104 70-130 4-Bromofluorobenzene (S) e/ 101 100 70-130 Toluene-d8(S) % 97 96 70-130 Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 30 m aceAnalytical w ..jowelxbs.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 400924 Analysis Method: EPA625 QC Batch Method: EPA 625 Analysis Description: 625 MSS Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223509 Associated Lab Samples: 92375792001. Parameter 92375792002 Units Matrix: Blank Result Water Reporting Limit Analyzed 1,2,4-Trichlorobenzene ug/L ND 5.0 03/09/18 21:22 1,2-Diphenylhydrazine ug/L ND 5.0 03/09/18 21:22 2,4,6-Trichlorophenol ug/L ND 10.0 03/09/18 21:22 2,4-Dichlorophenol ug/L ND 5.0 03/09/18 21:22 2,4-Dimethylphenol ug/L ND 10.0 03109/1821:22 2,4-Dinitrophenol ug/L ND 50.0 03/09/18 21:22 2,4-Dinitrotoluene ug/L ND 5.0 03/09/1821:22 2,6-Dinitrotoluene ug/L ND 5.0 03/09/18 21:22 2-Chloronaphthalene ug/L ND 5.0 03/09/18 21:22 2-Chlorophenol ug/L ND 5.0 03/09/18 21:22 2-Nitrophenol ug/L ND 5.0 03/09/18 21:22 3,3'-Dichlorobenzidine ug/L ND 25.0 03/09/18 21:22 4,6-Dinitro-2-methylphenol ug/L ND 20.0 03/09/18 21:22 4-Bromophenylphenyl ether ug/L ND 5.0 03/09/18 21:22 4-Chloro-3-methylphenol ug/L ND 5.0 03/09/18 21:22 4-Chlorophenylphenyl ether ug/L _ ND 5.0 03/09/18 21:22 4-Nitrophenol ug/L ND 50.0 03/09/18 21:22 Acenaphthylene ug/L ND 5.0 03/09/18 21:22 Anthracene ug/L ND 5.0 03/09/18 21:22 Benzidine ug/L ND 50.0 03/09/18 21:22 Benzo(a)anthracene ug/L ND 5.0 03/09/18 21:22 Benzo(a)pyrene ug/L ND 5.0 03/09/18 21:22 Benzo(b)fluoranthene ug/L ND 5.0 03/09/18 21:22 Benzo(g,h,i)perylene ug/L ND 5.0 03/09/18 21:22 Benzo(k)fuoranthene ug/L ND 5.0 03/09/18 21:22 bis(2-Chloroethoxy)methane ug/L ND 10.0 03/09/18 21:22 bis(2-Chloroethyp ether ug/L ND 5.0 03/09/18 21:22 bis(2-Ethylhexypphthalate ug/L ND 5.0 03/09/18 21:22 Butylbenzylphthalate ug/L ND 5.0 03/09/18 21:22 Chrysene ug/L ND 5.0 03109/1821:22 Di-n-butylphthalate ug/L ND 5.0 03/09/18 21:22 Di-n-octylphthalate ug/L ND 5.0 03/09/18 21:22 Dibenz(a,h)anthracene ug/L ND 5.0 03/09/18 21:22 Diethylphthalate ug/L ND 5.0 03/09/18 21:22 Dimethylphthalate ug/L ND 5.0 03/09/18 21:22 Fluoranthene ug/L ND 5.0 03/09/18 21:22 Fluorene ug/L ND 5.0 03/09/18 21:22 Hexachloro-1,3-butadiene ug/L ND 5.0 03/09/18 21:22 Hexachlorobenzene ug/L ND 5.0 03/09/18 21:22 Hexachlorocyclopentadiene ug/L ND 10.0 03/09/18 21:22 Hexachloroethane ug/L ND 5.0 03/09/18 21:22 Qualifiers Results presented on this page are In the units indicated by the"Units" column except where an alternate unit is presented to the night or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 30 0 aceAnalytical .pacelabzmm QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 METHOD BLANK: 2223509 Associated Lab Samples: 92375792001, Parameter 92375792002 Units Matrix: Blank Result Water Reporting Limit Analyzed Indeno(1,2,3-cd)pyrene ug/L ND 5.0 03/09/18 21:22 Isophorone ug/L ND 10.0 03/09/18 21:22 N-Nitroso-di-n-propylamine ug/L ND 5.0 03/09/18 21:22 N-Nitrosodimethylamine ug/L ND 5.0 03/09/18 21:22 N-Nitrosodiphenylamine ug/L NO 10.0 03/09/18 21:22 Naphthalene ug/L NO 5.0 03/09/18 21:22 Nitrobenzene ug/L NO 5.0 03/09/18 21:22 Pentachlorophenol ug/L NO 10.0 03/09/18 21:22 Phenanthrene ug/L NO 5.0 03/09/18 21:22 Phenol ug/L NO 5.0 03/09/18 21:22 Pyrene ug/L NO 5.0 03109/1821:22 2,4,6-Tribromophenol (S) % 70 10-137 03/09/18 21:22 2-Fluorobiphenyl(S) % 76 15-120 03/09/18 21:22 2-Fluorophenol (S) % 38 10-120 03/09/18 21:22 Nitrobenzene-d5(S) % 80 10-120 03/09/1821:22 Phenol-d6(S) % 28 10-120 03/09/18 21:22 Terphenyl-d14(S) % 90 11-131 03/09/18 21:22 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville. NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE 8 LCSD: 2223510 2223511 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers 1,2,4-Trichlorobenzene ug/L 50 29.4 32.0 59 64 44-142 8 30 1,2-Diphenylhydrazine ug/L 50 41.7 44.5 83 89 25-150 6 30 2,4,6-Trichlorophenol ug/L 50 44.2 23.8 88 48 37-144 60 30 R1 2,4-Dichlorophenol ug/L 50 44.8 32.9 90 66 1-191 31 30 R1 2,4-Dimethylphenol ug/L 50 44.2 44.6 88 89 32-119 1 30 2,4-Dinitrophenol ug/L 250 64.6 25.2J 26 10 1-181 30 2,4-Dinitrotoluene ug/L 50 44.7 46.9 89 94 39-139 5 30 2,6-Dinitrotoluene ug/L 50 43.2 47.6 86 95 50-158 10 30 2-Chloronaphthalene ug/L 50 36.2 39.3 72 79 60-118 8 30 2-Chlorophenol ug/L 50 38.7 32.4 77 65 23-134 18 30 2-Nitrophenol ug/L 50 40.1 28.1 80 56 29-182 35 30 R1 3,3'-Dichlorobenzidine ug/L 100 87.4 92.1 87 92 1-262 5 30 4,6-Dinitro-2-methylphenol ug/L 100 54.7 23.1 55 23 1-181 81 30 R1 4-Bromophenylphenyl ether ug/L 50 41.8 44.4 84 89 53-127 6 30 4-Chloro-3-methylphenol ug/L 100 89.4 91.0 89 91 22-147 2 30 4-Chlorophenylphenyl ether ug/L 50 43.7 45.8 87 92 25-158 5 30 4-Nitrophenol ug/L 250 78.7 38.8J 31 16 1-132 30 Acenaphthylene ug/L 50 40.9 42.4 82 85 33-145 4 30 Anthracene ug/L 50 43.6 46.8 87 94 1-166 7 30 Benzidine ug/L 100 61.5 72.5 61 72 25-150 16 30 Benzo(a)anthracene ug/L 50 47.4 49.9 95 100 33-143 5 30 Benzo(a)pyrene ug/L 50 42.3 45.3 85 91 17-163 7 30 Benzo(b)guoranthene ug/L 50 45.0 49.1 90 98 24-159 9 30 Results presented on this page are in the units Indicated by the "Units" column exceptwhere an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 18 of 30 aceAnalytical .pacelebs.mm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE & LCSD: 2223510 2223511 Spike 1-CS LCSD 1-CS LCSD % Rec Max Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers Benzo(g.h,i)perylene ug/L 50 43.8 45.9 88 92 1-219 5 30 Benzo(k)Fluoranthene ug/L 50 41.0 44.4 82 89 11-162 8 30 bis(2-Chloroethoxy)methane ug/L 50 44.0 46.0 88 92 33-184 5 30 bis(2-Chloroethyl) ether ug/L 50 42.1 42.8 84 86 12-158 2 30 bis(2-Ethy1hexy1)ph1ha1ate ug/L 50 50.2 51.3 100 103 8-158 2 30 Butylbenzylphthalate ug/L 50 48.1 49.7 96 99 1-152 3 30 Chrysene ug/L 50 46.1 48.3 92 97 17-168 5 30 Di-n-butylphthalate ug/L 50 47.7 51.4 95 103 1-118 7 30 Di-n-octylphihalate ug/L 50 60.2 62.6 120 125 4-146 4 30 Dibenz(a,h)anthracene ug/L 50 46.5 48.7 93 97 1-227 5 30 Diethylphthalate ug/L 50 46.3 48.4 93 97 1-114 4 30 Dimethylphthalate ug/L 50 45.1 47.3 90 95 1-112 5 30 Fluoranthene ug/L 50 48.9 52.3 98 105 26-137 7 30 Fluorene ug/L 50 43.6 45.8 87 92 59-121 5 30 Hexachloro-1,3-butadiene ug/L 50 25.8 28.6 52 57 24-116 10 30 Hexachlorobenzene ug/L 50 40.3 42.6 81 85 1-152 6 30 Hexachlorocyclopentadiene ug/L 50 25.6 26.0 51 52 25-150 2 30 Hexachloroelhane ug/L 50 22.9 25.1 46 50 40-113 9 30 Indeno(1,2,3-cd)pyrene ug/L 50 44.3 46.7 89 93 1-171 5 30 Isophorone ug/L 50 42.9 44.7 86 89 21-196 4 30 N-Nitroso-di-n-propylamine uglL 50 48.2 47.5 96 95 1-230 1 30 N-Nitrosodimethylamine ug/L 50 27.0 26.0 54 52 25-150 4 30 N-Nitrosodiphenylamine ug/L 50 42.7 45.9 85 92 25-150 7 30 Naphthalene ug/L 50 34.5 36.5 69 73 21-133 6 30 Nitrobenzene ug/L 50 38.9 41.5 78 83 35-180 7 30 Pentachlorophenol ug/L 100 59.1 26.3 59 26 14-176 77 30 Rl Phenanthrene ug/L 50 42.8 46.1 86 92 54-120 7 30 Phenol ug/L 50 18.1 16.9 36 34 5-112 7 30 Pyrene ug/L 50 45.2 47.4 90 95 52-115 5 30 2,4,6-Tribromophenol (S) % 82 47 10-137 2-Fluorobiphenyl(S) % 82 84 15-120 2-Fluorophenol (S) % 44 29 10-120 Nitrobenzene-d5(S) % 81 82 10-120 Phenol-d6 (S) °% 33 31 10-120 Terphenyl-dl4 (S) % 88 87 11-131 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/1912018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 30 aceAnalytical e .pacelabs.ccm March 19, 2018 Mr. Gary Harries American Truetzschler, Inc. PO Box 669228 12300 Moores Chapel Rd. 28214 Charlotte, NC 28266 RE: Project: Stormwater Samples Pace Project No.: 92375792 Dear Mr. Hames: Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNUNELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, a". Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 30 0 aceAnalytical .pacelabs.= Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28076 (704)875-9092 CERTIFICATIONS Project: Stormwater Samples Pace Project No.: 92375792 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LAl70028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 South Carolina Certification # 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 30 aceAnalytical w vwelaes-cam SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Stormwater Samples 92375792 Analytts lab ID Sample ID Method Analysts Reported Laboratory 92375792001 Al EPA 1664E JMS 1 PASI-C EPA 200.7 SH1 12 PASI-A EPA245A SER 1 PASI-A EPA 625 BPJ 58 PASI-C EPA 624 GAW 38 PASI-C SM 25401) MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA 9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A - EPA 420.4 DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A 92375792002 A2 EPA 1664B JMS 1 PASI-C EPA 200.7 SH1 12 PASI-A EPA245.1 SER 1 PASI-A EPA 625 BPJ 58 PASI-C EPA624 GAW 38 PASI-C SM 2540D MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A EPA420.4 DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, LLC. Page 3 of 30 aceAnalytical vmwpecelaes.com ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9600 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method* EPA 200.7 Antimony ND uglL 5.0 1 03/07/18 02:45 03116/1803:22 7440-36-0 Arsenic ND ug/L 10.0 1 03/07/18 02:45 03/16/1803:22 7440-38-2 Beryllium ND ug/L 1.0 1 03/07/18 02:45 03116/1803:22 7440-41-7 Cadmium ND ug/L 1.0 1 03/07/18 02:45 03/16/1803:22 7440-43-9 Chromium ND ug/L 5.0 1 0310711802:45 03/16/1803:22 7440-47-3 Copper 10.3 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:22 7440-50-8 Lead ND ug/L 5.0 1 03107/1802:45 03116/1803:22 7439-92-1 Nickel ND ug/L 5.0 1 03107/1802:45 03116/1803:22 7440-02-0 Selenium ND ug/L 10.0 1 03107/1802:45 03116/1803:22 7782-49-2 Silver ND ug/L 5.0 1 03/0711802:45 03/16/1803:22 7440-22-4 Thallium ND ug/L 10.0 1 03/07/18 02:45 03116/1803:22 7440-28-0 Zinc 27.6 ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7440-66-6 245.1 Mercury Analytical Method: EPA245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 1 03/07/1813:35 03/07/1818:10 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene ND ug/L 5.0 1 03/07/18 09:08 03110/1801:21 208-96-8 Anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-12-7 Benzidine ND ug/L 50.0 1 03/0711809:08 03/10/18 01:21 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 03/0711809:08 03/10/18 01:21 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 191-24-2 Benzo(k)fluoranthene ND uglL 5.0 1 03/07/18 09:08 03/10/18 01:21 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 59-50-7 bis(2-Chloroethoxy)methane ND uglL 10.0 1 03/07/18 09:08 03/10/18 01:21 111-91-1 bis(2-Chloroethyp ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 91-58-7 2-Chlorophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 95-57-8 4-Chlorophenylphenyl ether NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 7005-72-3 Chrysene ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 53-70-3 3,3'-Dichlorobenzidine ND ug/L 25.0 1 03/07/18 09:08 03110/1801:21 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-83-2 Diethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 84-66-2 2,4-Dimelhylphenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 105-67-9 Dimethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 131-11-3 Di-n-butylphthalale ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/0711809:08 03/1011801:21 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the vntlen consent of Pace Analytical Services, LLC. Page 4 of 30 aceAnalytical .pecelabs.com ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 2,4-Dinitrotoluene ND ug/L 5.0 1 03/07/1809*08 03/1011801:21 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 606-20-2 Di-n-ocrylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-81-7 Fluoranthene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 206-44-0 Fluorene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 86-73-7 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 87-68-3 Hexachlorobenzene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 118-74-1 Hexachlorocyclopentadiene NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 77-47-4 Hexachloroethane NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 67-72-1 Indeno(1,2,3-cd)pyrene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 193-39-5 Isophorone NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 78-59-1 Naphthalene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 91-20-3 Nitrobenzene NO ug/L 5.0 1 03/07/18 09:08 03110/1801:21 98-95-3 2-Nitrophenol NO ug/L 5.0 1 03/07/18 09:08 03110/1801:21 88-75-5 4-Nitrophenol NO ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 03/0711809*08 03/10/18 01:21 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 86-30-6 Pentachlorophenol NO ug/L 10.0 1 03107/1809:08 03110/1801:21 87-86-5 Phenanthrene NO ug/L 5.0 1 0310711809:08 03/1011801:21 85-01-8 Phenol ND ug/L 5.0 1 03/0711809:08 03/10/18 01:21 108-95-2 Pyrene ND ug/L 5.0 1 03/0711809:08 03/1011801:21 129-00-0 1,2,4-Trichlorobenzene NO ug1L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-82-1 2,4,6-Trichlorophenol NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 88-06-2 Surrogates Nitrobenzene-d5 (S) 45 % 10-120 1 03/07/18 09:08 03/10/18 01:21 4165-60-0 2-Fluorobiphenyl (S) 41 % 15-120 1 03/07/18 09:08 03/10/18 01:21 321-60-8 Terphenyl-dl4(S) 56 % 11-131 1 03/0711809:08 03/10/1801:21 1718-51-0 Phenol-d6 (S) 14 % 10-120 1 03/07/18 09:08 03/10/18 01:21 13127-88-3 2-Fluorophenol (S) 20 % 10-120 1 03/07/18 09:08 03/10/18 01:21 367-12-4 2,4,6-Tribromophenol(S) 57 % 10-137 1 03/07/18 09:08 0311011801:21 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acrolein ND ug/L 5.0 1 03/08/18 15:06 107-02-8 Acrylonitrile NO ug/L 50.0 1 03/08/18 15:06 107-13-1 Benzene ND ug/L 2.0 1 03/08/18 15:06 71-43-2 Bromodichloromethane NO ug/L 2.0 1 03/0811815:06 75-27-4 . Bromoform NO ug/L 2.0 1 03/08/18 15:06 75-25-2 Bromomethane NO ug/L 2.0 1 03108/1815:06 74-83-9 Carbon tetrachloride NO ug/L 2.0 1 0310811815:06 56-23-5 Chlorobenzene NO ug/L 2.0 1 03108/1815:06 108-90-7 Chloroethane NO ug/L 2.0 1 03/08/18 15:06 75-00-3 2-Chloroethylvinyl ether NO ug/L 5.0 1 03/08/18 15:06 110-75-8 Chloroform ND ug/L 2.0 1 03/08/18 15:06 67-66-3 Chloromethane ND ug/L 2.0 1 0310811815:06 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 30 ace Analytical wwvpacelaDa.com i Project: Stormwater Samples Pace Project No.: 92375792 Sample: Al Parameters Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Lab ID: 92375792001 Collected 03/06/18 11:05 Received: 03/06118 14:06 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. 624 Volatile Organics Analytical Method: EPA624 Dibromochloromethane ND ug/L 2.0 1 03/08/18 15:06 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 03/08/18 1506 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 15:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 15:06 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 03/08/18 15:06 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:06 10061-02-6 Ethylbenzene ND ug/L 2.0 1 03/0811815:06 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/08/18 15:06 87-68-3 Methylene Chloride ND ug/L 2.0 1 03/08/18 15:06 75-09-2 Naphthalene ND ug/L 5.0 1 03108/1815:06 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 03/0811815:06 79-34-5 Tetrachloroethene ND ug/L 2.0 1 03/08/18 15:06 127-18-4 Toluene ND ug/L 2.0 1 0310811815:06 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 03/08/18 15:06 71-55-6 1,1,2-Trichlomethane ND ug/L 2.0 1 03/08/18 15:06 79-00-5 Trichloroethene ND ug/L 2.0 1 03108/1815:06 79-01-6 Vinyl chloride ND ug/L 2.0 1 03/08/18 15:06 75-01-4 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 03/08/18 15:06 460-00-4 Toluene-d8(S) 117 % 70-130 1 03/08/18 15:06 2037-26-5 1,2-Dichloroethane-d4(S) 79 % 70-130 1 03108/1815:06 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 38.4 mg/L 5.0 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide ND mg/L 0.10 1 03/09/1818:00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 6.1 Std. Units 0.10 1 03107/1821: 16 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 13.4 mg/L 1.0 1 03/12/1815:02 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0,010 1 03/09/1813: 18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Qyanide ND mg/L 0.0080 1 03/16/1804:19 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Qual H6 Page 6 of 30 aceAnalytical wwwpecelaes.own ANALYTICAL RESULTS Project: Slormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntemville, NC 28078 (704)875-9092 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Antimony ND uglL 5.0 1 03107/1802:45 0311611803:25 7440-36-0 Arsenic NO ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7440-38-2 Beryllium ND ug/L 1.0 1 03107/1802:45 03/1611803:25 7440-41-7 Cadmium ND ug/L 1.0 1 03/07/18 02:45 03/16/18 03:25 7440-43-9 Chromium 7.5 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-47-3 Copper 12.2 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-50-8 Lead 7.3 ug/L 5.0 1- 03/07/18 02:45 03/16/18 03:25 7439-92-1 Nickel ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-02-0 Selenium ND ug/L 10.0 1 03/0711802:45 03/16/18 03:25 7782-49-2 Silver ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-22-4 Thallium ND ug/L 10.0 1 03107/1802:45 03116/1803:25 7440-28-0 Zinc 97.7 ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7440-66-6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 1 03/07/1813:35 03107/1818:12 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene ND ug/L 5.0 1 03107/1809:08 03/10/18 01:51 208-96-8 Anthracene ND ug/L 5.0 1 03/0711809:08 03/10/18 01:51 120-12-7 Benzidine ND ug/L 50.0 1 03107/1809:08 03/10/18 01:51 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 50-32-8 Benzo(b)0uoranthene ND ug/L 5.0 1 03107/1809:08 03/1011801:51 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 03107/1809:08 03/10/1801:51 191-24-2 Benzo(k)fluoranthene ND uglL 5.0 1 03/07/18 09:08 0311011801:51 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/1011801:51 101-55-3 Burylbenzylphthalate ND ugr- 5.0 1 03/07/18 09:08 03/10/18 01:51 85-68-7 4-Chloro-3-melhylphenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/07/18 09:08 0311011801:51 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-58-7 2-Chlorophenol ND ug/L 5.0 1 03/0711809:08 03/10/18 01:51 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 7005-72-3 Chrysene ND ug/L 5.0 1 03/07/18 09:08 03110/1801:51 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 53-70-3 3,3'-Dichlorobenzidine ND ug/L 25.0 1 03107/1809:08 03110/1801*51 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 120-83-2 Diethylphthalate NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 84-66-2 2,4-Dimethylphenol NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 105-67-9 Dimethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 131-11-3 Di- n-butyl phth a late ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/07/18 09:08 03/10/18 01:51 534-52-1 24-Dinitrophenol ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:51 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 30 aceAnalytical e ..paca/eea.oxn ANALYTICAL RESULTS Project: Slormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)8754092 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method:,EPA 625 2,4-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:51 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 117-84-0 1,2-Diphenylhydrazine - ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 122-66-7 bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01,51 117-81-7 Fluoranthene NO ug/L 5.0 1 03107/1809:08 03110/1801:51 206-44-0 Fluorene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 86-73-7 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 03107/1809:08 03/1011801:51 118-74-1 Hexachlorocyclopentadiene NO ug/L 10.0 1 0310711809:08 03/10/18 01:51 77-47-4 Hexachloroethane ND ug/L 5.0 1 03/0711809:08 03/10/1801:51 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 193-39-5 Isophorone NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 78-59-1 Naphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-20-3 Nitrobenzene ND ug/L 5.0 1 03107/1809:08 0311011801:51 98-95-3 2-Nitrophenol ND ug/L 5.0 1 03/07/18 09:08 03110/1801:51 88-75-5 4-Nitrophenol NO ug/L 50.0 1 03/07/18 09:08 0311011801:51 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 03/07/18 09:08 0311011801:51 62-75-9 N-Nitroso-di-n-propylamine NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 621-64-7 N-Nitrosodiphenylamine NO ug/L 10.0 1 03/0711809:08 03/1011801*51 86-30-6 Pentachlorophenol NO ug/L 10.0 1 03/0711809:08 03/1011801:51 87-86-5 Phenanthrene NO ug/L 5.0 1 03/0711809:08 03/1011801:51 85-01-8 Phenol NO ug/L 5.0 1 03/0711809:08 03/1011801:51 108-95-2 Pyrene ND ug/L 5.0 1 03/0711809:08 03/10/18 01:51 129-00-0 1,2,4-Tdchlorobenzene ND ug/L 5.0 1 0310711809:08 03/1011801:51 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 03107/1809:08 03/1011801:51 88-06-2 Surrogates Nitrobenzene-d5(S) 56 % 10-120 1 03107/1809:08 03/1011801:51 4165-60-0 2-Fluorobiphenyl (S) 53 % 15-120 1 03/07/18 09:08 03/10/18 01:51 321-60-8 Terphenyl-d14(S) 67 % 11-131 1 03107/1809:08 03110/1801:51 1718-51-0 Phenol-d6 (S) 18 % 10-120 1 03/07/18 09:08 03/10/18 01:51 13127-88-3 2-Fluorophenol (S) 27 % 10-120 1 03/07/18 09:08 03/10/18 01:51 367-12-4 2 4,6-Tribromophenol (S) 71 % 10-137 1 03/07/18 09:08 03/10/18 01:51 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acrolein NO ug/L 5.0 1 03/08/1815:22 107-02-8 Acrylonibile NO ug/L 50.0 1 03108/1815:22 107-13-1 Benzene NO ug/L 2.0 1 03/08/1815:22 71-43-2 Bromodichloromethane ND ug/L 2.0 1 03/08/1815:22 75-274 Bromoform ND ug/L 2.0 1 03108/1815:22 75-25-2 Bromomethane ND ug/L 2.0 1 0310811815:22 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 03/08/18 15:22 56-23-5 Chlorobenzene NO ug/L 2.0 1 03/08/1815:22 108-90-7 Chloroethane NO ug/L 2.0 1 03/0811815:22 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 03/08/18 15:22 110-75-8 Chloroform NO ug/L 2.0 1 03/08/18 15:22 67-66-3 Chloromethane NO ug/L 2.0 1 03/08/1815:22 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, -LC. Page 8 of 30 aceAnalytical e .psodaes.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 Dibromochloromelhane ND ug/L 2.0 1 03108/1815:22 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:22 95-50-1 1,3-Dichlorobenzene ND uglL 2.0 1 0310811815:22 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:22 10646-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:22 75-34-3 1,2-Dichloroethane ND uglL 2.0 1 03/08/18 15:22 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 03/08/18 15:22 75-35-4 cis-1,2-Dichloroethene ND uglL 2.0 1 03/08/18 1522 156-59-2 trans-1,2-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 156-60-5 1,2-Dichloropropane NO ug/L 2.0 1 03/08/18 15:22 78-87-5 cis-1,3-Dichloropropene NO ug/L 2.0 1 03/08/18 15:22 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:22 10061-02-6 Ethylbenzene ND ug/L 2.0 1 03108/181522 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/08/18 1522 87-68-3 Methylene Chloride ND ug/L 2.0 1 03/08/18 15:22 75-09-2 Naphthalene ND ug/L 5.0 1 03/08/18 15:22 91-20-3 1,1,2,2-Tetrachloroethane NO ug/L 2.0 1 03/08/18 15:22 79-34-5 Tetrachloroethene ND ug/L 2.0 1 03/08/18 15:22 127-18-4 Toluene ND ug/L 2.0 1 03/08/18 15:22 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 03/08/18 15:22 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 03/08/1815*22 79-00-5 Trichloroethene ND ug/L 2.0 1 03/08/18 15:22 79-01-6 Vinyl chloride ND ug/L 2.0 1 03/08/18 15:22 75-01-4 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 03/08/18 15:22 460-00-4 Toluene-d8(S) 116 % 70-130 1 03/08/18 15:22 2037-26-5 1,2-Dichloroethane-d4 (S) 80 % 70-130 1 03/08/18 15:22 17060-07-0 2640D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 74.0 mg/L 12.5 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide ND mg/L 0.10 1 0310911818:00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 5.0 Sid, Units 0.10 1 03/07/18 21:16 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 5.8 mg/L 1.0 1 03112/1815:18 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0.010 1 03/09/1813:18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Cyanide ND mg/L 0.0080 1 03/16/1804:20 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 9 of 30 aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 402480 Analysis Method: EPA 1664B QC Batch Method EPA 1664B Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92375792001. 92375792002 METHOD BLANK: 2232441 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 03/19/18 04:48 LABORATORY CONTROL SAMPLE 8 LCSD: 2232442 2232443 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Oil and Grease mg/L 40 37.2 37.6 93 94 78-114 1 30 Results presented on this page are In the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/201802:16 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 30 aceAnalytical .pace/abs.cam QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 OC Batch: 400949 Analysis Method: EPA 245.1 QC Batch Method EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223700 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/07/1817: 13 LABORATORY CONTROL SAMPLE: 2223701 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 105 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223702 2223703 MS MSD 92375598001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Mercury ug/L NO 2.5 2.5 2.6 2.6 106 102 70-130 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223704 2223705 MS MSD 92375805002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual Mercury ug/L NO 2.5 2.5 2.7 2.7 108 107 70-130 1 Results presented on this page are In the units indicated by the "units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 aceAnalytical e .,vandabs.00m QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 400889 Analysis Method* EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223386 Matrix: Water Associated Lab Samples: 92375792001. 92375792002 Parameter Blank Units Result Antimony ug/L Arsenic ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Thallium ug/L Zinc ug/L Reporting Limit Analyzed ND 5.0 03117/1818:17 ND 10.0 03117/1818:17 ND 1.0 03/17/1818:17 NO 1.0 03/17/1818:17 ND 5.0 03/17/1818:17 ND 5.0 03117/1818:17 NO 5.0 03/17/1818:17 NO 5.0 03/17/1818:17 NO 10.0 03/17/1818:17 NO 5.0 03/17/1818:17 ND 10.0 03/1711818:17 ND 10.0 03/17/1818:17 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2223387 Units Spike Conc. LCS Result LCS %Rec e/ Rec Limits Antimony ug/L 500 502 100 85-115 Arsenic ug/L 500 507 101 85-115 Beryllium ug/L 500 518 104 85-115 Cadmium ug/L 500 502 100 85-115 Chromium ug/L 500 514 103 85-115 Copper ug/L 500 508 102 85-115 Lead ug/L 500 489 98 85-115 Nickel ug/L 500 507 101 85-115 Selenium ug/L 500 487 97 85-115 Silver ug/L 250 254 102 85-115 Thallium ug/L 500 517 103 85-115 Zinc ug/L 500 494 99 85-115 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conic. Result Result %Rec %Rec Limits RPD Qual Antimony ug/L 43.3 500 500 545 527 100 97 70-130 3 Arsenic ug/L ND 500 500 474 458 94 91 70-130 4 Beryllium ug/L ND 500 500 510 494 102 99 70-130 3 Cadmium ug/L ND 500 500 525 506 105 101 70-130 4 Chromium ug/L ND 500 500 534 514 106 102 70-130 4 Results presented on this page are In the units indicated by the 'Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the wnften consent of Pace Analytical Services, L-C. Page 12 of 30 15ace Analytical wwwpecnWDs.rom QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Pace Project No.: 92375792 Samples MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Copper ug/L 14.5 500 500 549 523 107 102 70-130 5 Lead ug/L ND 500 500 476 458 95 91 70-130 4 Nickel ug/L 7.9 500 500 513 495 101 97 70-130 4 Selenium uglL ND 500 500 518 502 103 100 70-130 3 Silver ug/L ND 250 250 264 256 106 102 70-130 3 Thallium ug/L ND 500 500 345 328 69 66 70-130 5 MI Zinc ug/L 60.5 500 500 554 535 99 95 70-130 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 13 of 30 aceAnalytical .pacdabacav QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 401152 Analysis Method: EPA 624 OC Batch Method: EPA 624 Analysis Description: 624 MSV Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2224898 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1-Trichloroethane ug/L ND 2.0 03108/1812:33 1,1,2,2-Tetrachloroethane ug/L NO 2.0 03/08/18 12:33 1,1,2-Trichloroethane uglL NO 2.0 03/08/18 12:33 1,1-Dichloroethane ug/L NO 2.0 03/08/18 12:33 1,1-Dichloroethene ug/L NO 2.0 03/08/18 12:33 1,2-Dichlorobenzene ug/L NO 2.0 03108/1812,33 1,2-Dichloroethane ug/L NO 2.0 03/08/18 12:33 1,2-Dichloropropane ug/L NO 2.0 03/08/18 12:33 1,3-Dichlorobenzene ug/L NO 2.0 03/08/18 12:33 1,4-Dichlorobenzene ug/L NO 2.0 03/08/18 12:33 2-Chloroethylvinyl ether ug/L NO 5.0 03/08/18 12:33 Acrolein ug/L NO 5.0 03/08/18 12:33 Acrylonitrile ug/L ND 50.0 03/08/1812:33 Benzene ug/L ND 2.0 03/08/18 12:33 Bromodichloromethane ug/L NO 2.0 03/08/18 12:33 Bromoform ug/L NO 2.0 03/0811812:33 Bromomethane ug/L NO 2.0 03/08/1812:33 Carbon tetrachloride ug/L NO 2.0 03/08/18 1233 Chlorobenzene ug/L NO 2.0 03/0811812:33 Chloroelhane ug/L NO 2.0 03/08/18 12:33 Chloroform ug/L NO 2.0 0310811812:33 Chloromethane ug/L NO 2.0 03/0811812:33 cis-1,2-Dichloroethene ug/L NO 2.0 03108/1812:33 cis-1,3-Dichloropropene uglL NO 2.0 03/0811812:33 Dibromochloromethane ug/L NO 2.0 03/08/1812:33 Ethylbenzene ug/L NO 2.0 03/08/18 12:33 Hexachloro-1,3-butadiene ug/L ND 5.0 03/08/18 12:33 Methylene Chloride ug/L ND 2.0 03/08/18 12:33 Naphthalene ug/L ND 5.0 03/08/18 12:33 Tetrachlooethene ug/L NO 2.0 03/08/18 12:33 Toluene ug/L ND 2.0 03/08/18 12:33 trans-1,2-Dichloroethene ug/L NO 2.0 03/08/18 12:33 trans-1,3-Dichloropropene ug/L NO 2.0 03/08/181233 Trichloroethene ug/L NO 2.0 03/08/18 12:33 Vinyl chloride ug/L NO 2.0 03/08/18 12:33 1,2-Dichloroethane-d4 (S) % 85 70-130 03/08/18 12:33 4-Bromofluorobenzene (S) % 99 70-130 03/08/18 12:33 Toluene-d8 (S) % 112 70-130 03/08/18 12:33 Qualifiers Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, -I-C. Page 14 of 30 aceAnalytical wwwpece/ dii QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE: Parameter 2224899 Units Spike Conc. LCS Result LCS %Rec %Rec Limits 1,1, 1-Trichloroethane ug/L 20 22.0 110 52-162 1, 1,2,2-Tetrachloroethane ug/L 20 19.8 99 46-157 1,1,2-Trichloroethane ug/L 20 21.0 105 52-150 1,1-Dichloroethane ug/L 20 19.8 99 59-155 1,1-Dichloroethene ug/L 20 23.0 115 1-234 1,2-Dichlorobenzene ug/L 20 19.8 99 18-190 1,2-Dichloroethane ug/L 20 21.3 106 49-155 1,2-Dichloropropane ug/L 20 22.1 111 1-210 1,3-Dichlorobenzene ug/L 20 19.6 98 59-156 1,4-Dichlorobenzene ug/L 20 18.8 94 18-190 2-Chloroethylvinyl ether ug/L 40 32.2 81 1-305 Acrolein ug/L 100 103 103 15-152 Acrylonilrile ug/L 100 99.2 99 75-132 Benzene ug/L 20 21.0 105 37-151 Bromodichloromethane ug/L 20 22.4 112 35-155 Bromoform ug/L 20 18.5 92 45-169 Bromomethane ug/L 20 18.7 93 1-242 Carbon tetrachloride ug/L 20 21.6 108 70-140 Chlorobenzene ug/L 20 20.2 101 37-160 Chloroethane ug/L 20 24.2 121 14-230 Chloroform ug/L 20 19.9 99 51-138 Chloromethane ug/L 20 18.4 92 1-273 cis-1,2-Dichloroethene ug/L 20 21.1 105 68-146 cis-1,3-Dichloropropene ug/L 20 21.3 107 1-227 Dibromochloromethane ug/L 20 21.2 106 53-149 Ethylbenzene ug/L 20 20.3 101 37-162 Hexachloro-1,3-butadiene ug/L 20 18.5 92 70-130 Methylene Chloride ug/L 20 20.7 104 1-221 Naphthalene ug/L 20 20.0 100 70-130 Tetrachloroethene ug/L 20 19.1 95 64-148 Toluene ug/L 20 20.1 101 47-150 trans-1,2-Dichloroethene ug/L 20 21.3 107 54-156 trans-1,3-Dichloropropene ug/L 20 2L2 106 17-183 Trichloroethene ug/L 20 21.6 108 71-157 Vinyl chloride ug/L 20 22.3 112 1-251 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromolluorobenzene(S) % 101 70-130 Toluene-d8 (S) % 99 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 2224901 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers MS MSD 92375577001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L ND 20 20 23.8 23.5 119 118 46-171 1 1,1,2,2-Tetrachloroethane ug/L NO 20 20 21.9 21.7 109 108 73-159 1 Results presentee on this page are in the units indicated by the "units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 30 0 aceAnalytical wwwpace/dbs.clen QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Pace Project No.: 92375792 Samples MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 2224901 MS MSD 92375577001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Dual 1,1,2-Trichloroethane ug/L ND 20 20 23.6 22.2 118 111 64-152 6 1,1-Dichloroethane ug/L ND 20 20 21.3 21.7 107 108 43-172 2 1,1-Dichloroethene ug/L ND 20 20 23.1 23.6 116 118 48-189 2 1,2-Dichlorobenzene ug/L ND 20 20 22.3 22.0 112 110 54-154 2 1,2-Dichloroethane ug/L ND 20 20 22.8 23.2 114 116 42-171 2 1,2-Dichloropropane ug/L ND 20 20 25.2 24.4 126 122 55-157 4 1,3-Dichlorobenzene ug/L ND 20 20 22.7 22.5 114 113 57-148 1 1,4-Dichlorobenzene ug/L ND 20 20 22.8 22.7 114 113 58-149 0 2-Chloroethylvinyl ether ug/L ND 40 40 ND ND 0 0 70-130 M1,c2 Acrolein uglL ND 100 100 112 108 112 108 70-130 4 Acrylonitrile ug/L ND 100 100 103 108 103 108 70-130 4 Benzene ug/L ND 20 20 24.0 23.3 120 117 54-163 3 Bromodichloromethane ug/L ND 20 20 24.6 23.8 123 119 56-152 3 Bromoform ug/L ND 20 20 20.8 21.6 104 108 53-151 4 Bromomethane ug/L ND 20 20 17.3 18.0 86 90 10-200 4 Carbon tetrachloride ug/L ND 20 20 25.1 23.9 126 119 41-175 5 Chlorobenzene ug/L ND 20 20 23.3 23.0 117 115 67-152 1 Chloroethane ug/L ND 20 20 27.0 25.2 135 126 23-200 7 Chloroform ug/L ND 20 20 21.1 21.7 105 109 51-166 3 Chloromethane ug/L ND 20 20 19.3 18.4 97 92 40-175 5 cis-1,2-Dichloroethene ug/L ND 20 20 22.3 23.1 111 115 45-174 4 cis-1,3-Dichloropropene ug/L ND 20 20 23.8 23.3 119 116 38-146 2 Dibromochloromethane ug/L ND 20 20 24.2 25.3 121 126 65-144 4 Ethylbenzene ug/L ND 20 20 23.5 23.0 117 115 57-152 2 Hexachloro-1,3-butadiene ug/L ND 20 20 20.7 22.3 104 112 70-130 8 Methylene Chloride ug/L ND 20 20 21.6 22.0 108 110 40-167 2 Naphthalene ug/L ND 20 20 22.0 23.2 110 116 70-130 5 Tetrachloroethene ug/L ND 20 20 22.7 21.3 114 107 59-155 6 Toluene ug/L ND 20 20 22.6 21.1 113 106 47-162 7 trans-1,2-Dichloroethene ug/L ND 20 20 23.0 22.5 115 112 47-178 2 trans-1,3-Dichloropropene ug/L ND 20 20 24.0 22.2 120 111 39-148 8 Trichloroethene ug/L ND 20 20 24.3 24.6 121 123 60-153 1 Vinyl chloride ug/L ND 20 20 23.9 22.6 120 113 46-176 6 1,2-Dichloroethane-d4(S) % 96 104 70-130 4-Bromofluorobenzene (S) % 101 100 70-130 Toluene-d8 (S) % 97 96 70-130 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace AnalyUcal Services, L-C. Page 16 of 30 0 aceAnalytical wwwpacelaes.mn QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 400924 Analysis Method: EPA 625 OC Batch Method EPA625 Analysis Description: 625 MSS Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223509 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed 1,2,4-Tdchlorobenzene ug/L ND 5.0 03/09/18 21:22 1,2-Diphenylhydrazine ug/L ND 5.0 03109/1821:22 2,4,6-Trichlorophenol ug/L NO 10.0 03/09/18 21:22 2,4-Dichlorophenol ug/L NO 5.0 03/09/18 21:22 2,4-Dimethylphenol ug/L NO 10.0 03/09/18 21:22 2,4-Dinitrophenol ug/L ND 50.0 03109/1821:22 2,4-Dinitrololuene ug/L ND 5.0 03/09/18 21:22 2,6-Dinitrololuene ug/L NO 5.0 03/09/18 21:22 2-Chloronaphthalene ug/L ND 5.0 03/09/18 21:22 2-Chlorophenol ug/L ND 5.0 03/09/1821:22 2-Nitrophenol ug/L ND 5.0 03/09/18 21:22 3,3'-Dichlorobenzidine ug/L ND 25.0 03/09/18 21:22 4,6-Dinitro-2-methylphenol ug/L ND 20.0 03/09/18 21:22 4-Bromophenylphenyl ether ug/L ND 5.0 03/09/18 21:22 4-Chloro-3-methylphenol ug/L NO 5.0 03/09/18 21:22 4-Chlorophenylphenyl ether ug/L ND 5.0 03/09/18 21:22 4-Nitrophenol ug/L NO 50.0 03109/1821:22 Acenaphthylene ug/L ND 5.0 03109/18 21 *22 Anthracene ug/L ND 5.0 03/0911821:22 Benzidine ug/L NO 50.0 03/09/18 21:22 Benzo(a)anthracene ug/L ND 5.0 03/0911821:22 Benzo(a)pyrene ug/L ND 5.0 03/09/18 21:22 Benzo(b)fluoranthene ug/L ND 5.0 03/09/18 21:22 Benzo(g,h,i)perylene ug/L ND 5.0 03/09/18 21:22 Benzo(k)Fluoranthene ug/L ND 5.0 03/09/18 21:22 bis(2-Chloroelhoxy)methane ug/L ND 10.0 03/09/18 21:22 bis(2-Chloroethyl) ether ug/L ND 5.0 03/09/18 21:22 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 03/09/18 21:22 Butylbenzylphthalate ug/L NO 5.0 03/09/18 21:22 Chrysene ug/L ND 5.0 03/09/18 21:22 Di-n-butylphthalate ug/L NO 5.0 03/09/18 21:22 Di-n-octylphthalate ug/L NO 5.0 03/0911821:22 Dibenz(a,h)anthracene ug/L NO 5.0 03109/1821:22 Diethylphthalate ug/L NO 5.0 03/09/18 21:22 Dimethylphthalate ug/L NO 5.0 03/09/18 21:22 Fluoranthene ug/L NO 5.0 03/09/18 21:22 Fluorene ug/L NO 5.0 03/0911821:22 Hexachloro-1,3-butadiene ug/L ND 5.0 03109/1821:22 Hexachlorobenzene ug/L ND 5.0 03/09/18 21:22 Hexachlorocyclopentadiene ug/L ND 10.0 03/09/1821:22 Hexachloroethane ug/L ND 5.0 03/09/1821:22 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except "ere an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 17 of 30 aceAnalytical ~xpwa/abs.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 METHOD BLANK: 2223509 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Indeno(1,2,3-cd)pyrene ug/L NO 5.0 03/09/18 21:22 Isophorone ug/L NO 10.0 03/09/18 21:22 N-Nitroso-di-n-propylamine ug/L NO 5.0 03/09/18 21:22 N-Nitrosodimethylamine ug/L NO 5.0 03/09/18 21:22 N-Nitrosodiphenylamine ug/L NO 10.0 03/09/18 21:22 Naphthalene ug/L ND 5.0 03/09/18 21:22 Nitrobenzene ug/L NO 5.0 03/09/18 21:22 Pentachlorophenol ug/L NO 10.0 03/09/18 21:22 Phenanthrene ug/L ND 5.0 03/09/1821:22 Phenol ug/L ND 5.0 03/09/18 21:22 Pyrene ug/L ND 5.0 03/09/18 21:22 2,4,6-Tribromophenol(S) % 70 10-137 03/09M821:22 2-Fluorobiphenyl (S) % 76 15-120 03/09/18 21:22 2-Fluorophenol(S) % 38 10-120 03/09/18 21:22 Nitrobenzene-d5(S) % 80 10-120 03/09/18 21:22 Phenol-d6 (S) % 28 10-120 03/09/18 21:22 Terphenyl-dl4 (S) % 90 11-131 03/09/18 21:22 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: 2223510 2223511 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers 1,2,4-Trichlorobenzene ug/L 50 29.4 32.0 59 64 44-142 8 30 1,2-Diphenylhydrazine ug/L 50 41.7 44.5 83 89 25-150 6 30 2,4,6-Trichlorophenol ug/L 50 44.2 23.8 88 48 37-144 60 30 R1 2,4-Dichlorophenol ug/L 50 44.8 32.9 90 66 1-191 31 30 R1 2,4-Dimethylphenol ug/L 50 44.2 44.6 88 89 32-119 1 30 24-Dinitrophenol ug/L 250 64.6 25.2J 26 10 1-181 30 2,4-Dinitrotoluene ug/L 50 44.7 46.9 89 94 39-139 5 30 2,6-Dinitrotoluene ug/L 50 43.2 47.6 86 95 50-158 10 30 2-Chloronaphthalene ug/L 50 36.2 39.3 72 79 60-118 8 30 2-Chlorophenol ug/L 50 38.7 32.4 77 65 23-134 18 30 2-Nitrophenol ug/L 50 40.1 28.1 80 56 29-182 35 30 R1 3.3'-Dichlorobenzidine uglL 100 87A 92.1 87 92 1-262 5 30 4,6-Dinitro-2-methylphenol ug/L 100 54.7 23.1 55 23 1-181 81 30 R1 4-Bromophenylphenyl ether ug/L 50 41.8 44.4 84 89 53-127 6 30 4-Chloro-3-methylphenol ug/L 100 89.4 91.0 89 91 22-147 2 30 4-Chlorophenylphenyl ether ug/L 50 43.7 45.8 87 92 25-158 5 30 4-Nitrophenol ug/L 250 78.7 38.81 31 16 1-132 30 Acenaphthylene ug/L 50 40.9 42.4 82 85 33-145 4 30 Anthracene ug/L 50 43.6 46.8 87 94 1-166 7 30 Benzidine ug/L 100 61.5 72.5 61 72 25-150 16 30 Benzo(a)anthracene ug/L 50 47.4 49.9 95 100 33-143 5 30 Benzo(a)pyrene ug/L 50 42.3 45.3 85 91 17-163 7 30 Senzo(b)Ruoranthene ug/L 50 45.0 49.1 90 98 24-159 9 30 Results presented on this page are in the units indicated by the'UNts' column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 30 aceAnalytical ww,pacelab.cnm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersedle, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE & LCSD: 2223510 2223511 Spike LCS LCSD 1-CS LCSD % Rec Max Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers Benzo(g,h,i)perylene ug/L 50 43.8 45.9 88 92 1-219 5 30 Benzo(k)fluoranthene ug/L 50 41.0 44.4 82 89 11-162 8 30 bis(2-Chloroethoxy)methane ug/L 50 44.0 46.0 88 92 33-184 5 30 bis(2-Chloroelhyl) ether uglL 50 42A 42.8 84 86 12-158 2 30 bis(2-Ethylhexyl)phthalate ug/L 50 50.2 51.3 100 103 8-158 2 30 Butylbenzylphthalate ug/L 50 48.1 49.7 96 99 1-152 3 30 Chrysene ug/L 50 46.1 48.3 92 97 17-168 5 30 Di-n-butylphthalate ug/L 50 47.7 51.4 95 103 1-118 7 30 Di-n-ocrylphthalate ug/L 50 60.2 62.6 120 125 4-146 4 30 Dibenz(a,h)anthracene ug/L 50 46.5 48.7 93 97 1-227 5 30 Diethylphthalate ug/L 50 46.3 48.4 93 97 1-114 4 30 Dimethylphthalate ug/L 50 45.1 47.3 90 95 1-112 5 30 Fluoranthene ug/L 50 48.9 52.3 98 105 26-137 7 30 Fluorene ug/L 50 43.6 45.8 87 92 59-121 5 30 Hexachloro-1,3-butadiene ug/L 50 25.8 28.6 52 57 24-116 10 30 Hexachlorobenzene ug/L 50 40.3 42.6 81 85 1-152 6 30 Hexachlorocyclopentadiene ug/L 50 25.6 26.0 51 52 25-150 2 30 Hexachloroethane ug/L 50 22.9 25.1 46 50 40-113 9 30 - Indeno(1,2,3-cd)pyrene ug/L 50 44.3 46.7 89 93 1-171 5 30 Isophorone ug/L 50 42.9 44.7 86 89 21-196 4 30 N-Nitroso-di-n-propylamine ug/L 50 48.2 47.5 96 95 1-230 1 30 N-Nitrosodimethylamine ug/L 50 27.0 26.0 54 52 25-150 4 30 N-Nitrosodiphenylamine ug/L 50 42Y 45.9 85 92 25-150 7 30 Naphthalene ug/L 50 34.5 36.5 69 73 21-133 6 30 Nitrobenzene ug/L 50 38.9 41.5 78 83 35-180 7 30 Pentachlorophenol ug/L 100 59.1 26.3 59 26 14-176 77 30 R1 Phenanthrene ug/L 50 42.8 46.1 86 92 54-120 7 30 Phenol ug/L 50 18.1 16.9 36 34 5-112 7 30 Pyrene ug/L 50 45.2 47.4 90 95 52-115 5 30 2,4,6-Tribromophenol(S) % 82 47 10-137 2-Fluorobiphenyl(S) % 82 84 15-120 2-Fluorophenol (S) % 44 29 10-120 Nitrobenzene-d5(S) % 81 82 10-120 Phenol-d6 (S) % 33 31 10-120 Terphenyl-dl4 (S) % 88 87 11-131 Results presentee on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 19 of 30 aceAnalytical e ..pecelabstem QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 OC Batch: 401455 Analysis Method: SM 2540D QC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2226951 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L . NO 2.5 03/10/18 08:39 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2226952 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 90-110 SAMPLE DUPLICATE: 2226953 92375661001 Cup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 8.8 18.6 72 D6 SAMPLE DUPLICATE: 2226954 92375713001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L NO NO Results presented on this page are In the units Indicated by the "Units" column except where an altemate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 20 of 30 aceAnalytical wwwpacelxbs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Slormwater Samples Pace Project No.: 92375792 QC Batch: 401426 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92375792001. 92375792002 METHOD BLANK: 2226688 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L NO 0.10 03/0911818:00 LABORATORY CONTROL SAMPLE: 2226689 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.49 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2226888 2226889 MS MSD 92375892013 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Sulfide mg/L NO .5 .5 0.52 0.54 101 107 80-120 5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2226890 2226891 MS MSD 92375936001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfide mg/L NO .5 .5 0.40 0.41 77 78 80-120 2 Ml Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/201802:16 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 30 aceAnalytical ewwpacelaes.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401069 Analysis Method: EPA9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH Associated Lab Samples: 92375792001, 92375792002 SAMPLE DUPLICATE: 2224555 92375644001 Cup Parameter Units Result Result RED Qualifiers pH Std. Units 72 7.1 2 D6,H6 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are In the units indicated by the "Units" column except where an alternate in It is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03119/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 30 aceAnalytical wwwpacelgbs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Humersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 OC Batch: 401567 Analysis Method: EPA 300.0 QC Batch Method: EPA 300.0 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2227308 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfate mg/L NO 1.0 03/12/1811:29 LABORATORY CONTROL SAMPLE: 2227309 Spike LCS LCS % Rec Parameter Units Cone. Result %Rec Limits Qualifiers Sulfate mg/L 50 48.7 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2227310 2227311 MS MSD 92376343001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L 2.5 50 50 50.9 51.7 97 98 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2227312 2227313 MS MSD 92376390003 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfate mg/L NO 50 50 48.6 49.7 97 99 90-110 2 Results presented on this page are in the units Indicated by the "Units" column except where an altemate unit is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Dale: 03119/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 30 aceAnalytical wwxpecetabs.cvm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401174 Analysis Method: EPA 420.4 QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2225030 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phenol mg/L NO 0.010 03109/1812:49 LABORATORY CONTROL SAMPLE: 2225031 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Phenol mg/L .05 0.048 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2225032 2225033 MS MSD 92375017002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc Result Result % Rec % Rec Limits RPD Qual Phenol mg/L ND .05 .05 0.058 0.056 100 97 90-110 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2225034 2225035 MS MSD 92375203001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phenol mg/L 0.24 .05 .05 0,27 0.29 73 106 90-110 6 M1 Results presented on this page are In the units indicated by the "units" column except where an alternate on It Is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 30 aceAnalytical wawpacelabscnm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401894 Analysis Method: SM 4500-CN-E QC Batch Method: SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total Associated Lab Samples: 92375792001. 92375792002 METHOD BLANK: 2229109 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Cyanide mg/L ND 0.0080 03116/1804:09 LABORATORY CONTROL SAMPLE: 2229110 Spike LCS LCS % Rec Parameter Units Conic. Result % Rec Limits Qualifiers Cyanide mg/L .1 0A1 106 80-120 MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 2229111 2229112 MS MSD 92376219002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conic. Conc. Result Result % Rec % Rec Limits RPD Qual Cyanide mg/L 5.7J .1 .1 0.095 0.088 89 82 80-120 8 ug/L MATRIX SPIKE 8 MATRIX SPIKE DUPLICATE: 2229113 2229114 MS MSD 92376219007 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Cyanide mg/L 6.5J .1 .1 0.10 0.098 94 91 80-120 3 ug/L Resu:ts presented on this page are In the units indicated by the "Units" column except where an altemate unit is presentee to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services. -I-C. Page 25 of 30 Pace Ana lyticaI Services, LLC aceAnalytical0 9800 ncey Ave. Suite too Hunlersville, NC 28078078 .pacelabs.com (704)875-9092 QUALIFIERS Project: Stormwater Samples Pace Project No.: 92375792 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MOL- Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA required holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R7 RPD value was outside control limits. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. ly�li7�jiil��i\=i�]:�i1[i7;3L•\`J1R6�" This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 30 0 aceAnalytical nwwpecefass.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Stormwater Samples 92375792 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92375792001 Al EPA 1664E 402480 92375792002 A2 EPA 16646 402480 92375792001 Al EPA200.7 400889 EPA 200.7 400993 92375792002 A2 EPA 200.7 400889 EPA 200.7 400993 92375792001 Al EPA 245.1 400949 EPA 245.1 401005 92375792002 A2 EPA 245.1 400949 EPA 245.1 401005 92375792001 At EPA625 400924 EPA625 401382 92375792002 A2 EPA625 400924 EPA625 401382 92375792001 Al EPA624 401152 92375792002 A2 EPA624 401152 92375792001 Al SM 2540D 401455 92375792002 A2 SM 2540D 401455 92375792001 Al SM 4500-S2D 401426 92375792002 A2 SM 4500-S2D 401426 92375792001 Al EPA 9040 401069 92375792002 A2 EPA 9040 401069 92375792001 At EPA 300.0 401567 92375792002 A2 EPA 300.0 401567 92375792001 Al EPA420.4 401174 92375792002 A2 EPA420.4 401174 92375792001 Al SM 4500-CN-E 401894 92375792002 A2 SM 4500-CN-E 401894 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 30 Document Name: Document Revised: February 7, 2018 aCeAnalytiCaJ y Sample Condition U on Recel t SCUR) Palle 1 of 2 Document No.: Issuing Authority: F•CAR•CS•033•Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ HuntersvilleQ Ralelgh❑ Mechanicsville❑ CliennttName: oJectR:% /� I WO# : 92375792 iin/w) Courier: Fed Es ❑UPS : USPS -Cllen� I IIII I II III III IIII III ❑Commercial ❑Pace '❑Other:_ 92373792 Custody Seal Present? Dyes I❑No Seals Intact? Dyes ❑No ' Date/Initials Person Examining contents: �� Packing Materiel: ❑Bubble Wrap ,GB bu ble Bags ❑None ❑ Other Thermometer] Type of lea: Older []Blue �OIR Gen lo: 92TO36 Cooler Temp J'CI: `.5, 2/ Correction Factor: Add/Subtract ('C) +0, J Cooler Temp Corrected CC): USDA Regulated 5011'(❑ N/A, water sample) Did samples arigmatein a quaraM ne cone within the United States: CA, NY, or SC(check mapsl? Yes NO Biological Tissue Frozen? ❑Yes ❑No `❑N/A ❑None Temp should be above freezing to 6'C []Samples out of temp criteria. Samples on ice, cooling process has begun Old samptes originate from a foreign source (imernationaliv, including Hawaii and Puerto Rico)? [Dyes ONO' comments/Discrepancy: Chain of Custody Present? 1—Yes— ONO N/A 1. Samples Arrived within Hold Time? ' OYel[]No ONJA 2. Short Hold Time Analysts (A2 hr.)? OYes — No N/A 3. Rush Turn Around Time Requested? QYes No N/A 4. Sufficient Volume? -Yes NO ❑N/A S. Garrett Containers used? Pace Containers Used? —❑Yes�• Ya ❑rva No ❑N/A N/A 6. Containers intact? i Yes ONO N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yesi.ONo' ❑N/A g. Sample Labels Match COC? dncludes Date/Time/ID/Analysis Matrix: ,OYes it ONO ❑N/A 9. Head5pace in VOA Vials s5-fimm)? Yes ' No N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑res Dyes QNo ONo N/A H/A� 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: _ Date/Time: Project Manager SCURF Review: ram_ Project Manager SRF Review: Field Date Required? ❑Yes ONO Date: Date: Page 28 of 30 Document Name: Document Revised: February 7, 2018 > ace Analytical Sample Condition Upon Receipt(SCUR) Page 2 of 2 Document No.: Issuing Authority: F-CAP-CS-033.1I Pace Carolinas Clualit Of l— •Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLH8 "Bottom half of box Is to list number of bottle Project M i WO# : 92375792 PM: AMB Due Date: 03/20/18 CLIENT: 92—Am Truets O O z z Y V N ? d n a e di c y c M Z u x '� 1p y! n a a yyy� cI iCi g E z p x p� 9 a i 7 `o_ e J J J M Z G_ N iiJJ 2 Q x n i n J n a a o E E QQ E Q a E qE 5 > > > �n E E E u i E E E E g — E a u qE 1 E E E E '� 9 E 44E qEq E E E E N T O O y N w M H I�n a M l)' P U' 4 P U T V ( Q a rJ n N 6 g >^ yG m C m 6 d G m 1 0 6 al 6 0 6 m f� i Q Q Q Q Q Q O � ra Q i 1 i IV LIrL/ 20 v I 3 _� a 5 6 7 8 9 10 11 11 pH Adjustment Log far Preserved Samples Sample lD Type of Preservative pH upon receipt Date preservatlpn adjusted Time preservation adjusted Amount of Preservative added Lot Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will of sent to the Nonn L.11enea ucn.n s.ennrceuun G.M.L. p.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 29 of 30 °re�M CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. section A Section B Section C Required Client Information: Required Project Infomwtion: Involee Intormetion: Page : 1 Of 1 Company: Amemmm Truetz.H.r. Inc. Report To. Dory Haines Attention: •Aamess'. PO Box Signs Copy T¢ Company Name: Charlotte, NC 18266 Arki R WAto Arm Ernst l maintenance .-Irrozschlecrom Purdll Order#: Pace Costs, Phone'. p0lpgl-5 Fan Project Name: Smrrm ester sampks Pelt Project MarvgeE angels Oaroni pamlabs min, Stete l Locatlon -' Requested Due Date: Pr.iw N. P. Profile #: n,g- NC R dated Mel la Flllered IN wtRu O ri o COLLECTED O Preservatives > Dn�y Wnn Px 't WM R B D e PauueW is 6 W Z iweP SAMPLE ID a D F « One Character per boa. Mw WP w w START END u ex a 6 ] C 31—,J^ a Dorn t ex a u n U mIA¢,091,-) Saple Ida must be unique of O T11I.T1., TI.TETWE O H Le U W a u n p 0 Z Oin H P `m Q$ p e c m ry ~ D M? z 2 o r'e 0 E u F a O �✓ L, ¢o 1� �Np� ✓✓✓✓ r?I ILA 2 2- ccr a a 5 6 7 8 9 10 11 12 ' ADOITIONALCOMMEMS - RIa.NQW1 EDGY/AFmu%n0N DATA TIME lCCEPn1DBYIAFFjuAToN 'DATE TIME �� SAMPLE CONDMONS 6/ x 14 : (77 ti, /7 7 �o 5-, 3 1 A y SAMPLER NAME AND SIGNATURE u - c PRINT Name of SAMPLER: / Z M e- C, (' s. _ SIGNATURE of SAMPLER: DATE signed: / / 'Y u STORMWATER DISCHARGE OUTFALL (SDO) MONITORING REPORT GENERAL PERMIT NO. NCG030000 SAMPLES COLLECTED DURING CALENDAR YEAR: a O CERTIFICATE OF COVERAGE NO. NCG03000 O (This monitoring report is due at the Division no later than 30 days from the date the facility receives the sampling results from the laboratory.) FACILITY NAME ; Q COUNTY •C'C u�' PERSON COLLECTING SALES R rv� S PHONE NO. �) S Ca CERTIFIED LABORATORY M( ()AAk4+- Cc \ Lab # Lab # PLEASE SIGN ON THE REVERSE 4 Part A: Specific Monitoring Requirements Outfall . No. - ate Sample Collected, itto/dd/ r "'00530 00400 '. ° ",A105T }lii ='00556 <. f78141 'Total Suspended Solids, - .; p11, ,. •„ Standard nititsi , .. ��Lcad, mg/L" : , - �.` Otl andGrease;', . �im /L " ' Totaljiixic Organi6" Benchmark 100 i';Witlun 6 0 - 9iU ? 0 033 t. _ti' 30 - Y 3 (o g 3in U N 1 A2- 3 (0 4 1 Note: If you report a sampled value in excess of die benchmark value, or outside the benchmark range for pll, you must inipleutencrier 1 or Tier 2 responses. See General Permit text. , Did this facility perform Vehicle Maintenance Activities using more than 55 gallons of new motor oil per month? _ yes _no (if yes, complete Part B) Part B: Vehicle Maintenance Activity Monitoring Requirements Outfatl No. llate r' �. Sample •,Collected,', b0556r::': r-',' 00530 i,.., �00400'..• Oil and Grease, - ''.' Total Suspended Solids, pH, ! - Standtur iunits New Mdtor,0il Usage, 'Animal rlveiii a aUino. Benchmark 30 ",:, 100 "• 6.0' .9.0 ,,. Note: If you report a sampled value in excess of the benchmark value, or outside die benchmark range for pH, you must implement Tier 1 or Tier 2 responses. See General Permit text. STORM EVENT CHARACTERISTICS: Date 3&/� (first event sampled) Total Event Precipitation (inches): o q �0 Date (list each additional event sampled this reporting period, and rainfall amount) Total Event Precipitation (inches): Mail Original and one copy to: Division of Water Quality Attn: DWQ Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 SWU-245-102107 �� /`� Page I oft �0 r NC®ENR Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report Forguidance onfilling out thisform, please visit: httn://pot-talncdenro,-g/web/wq/ws/sulnpdessw#tab-4 Permit No.: N/C/L-/yZ/ 3/Q/D/SJ /-�)/ or Certificate of Coverage No.: Facility Name: 11,81Qn`cc TNhe:: t \plZT^( County: i c-V i A 6 2r r Phone No. .b4 Inspector;Gr /Z* Date of Inspection: 31(o I S! Time of Inspection: 1 Total Event Precipitation (inches): Was this a `Representative Storm Event" or "Measureable Storm Event' as defined by the permit? (See information below.) VYes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureable storm event" (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event" or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall l and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours I prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional Office. By this signature, I certify that this report is accurate and complete to the best of my knowledge: of Permittee or Designee) Page 1 of 2 1. Outfall Description: Outfall No. A I Structure (pipe, ditch, etc.) ETC " vl Receiving Stream: Lo -h 3 •I ; Describe the industrial activities that occur within the outfal drainage area: 1..., � _ n _ . / 7-r A n _ n- 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors L= _3j'i VN 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): INa NP l 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 0 4 5 S. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 0 2 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 C2) 3 4 5 7. Is there any foam in the stormwater discharge? Yes No 8. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 w � NC®ENik Stormwater Discharge Outfall (SDO) Qualitative Monitoring Report For guidance on filling out thisform, please visit: http://poi-tal.iicdenr.org/web/`wq/ws/su/ni2dessw#tab-4 Permit No.: or Certificate of Coverage No.: N/C/G/_/_/_/_/_/_/ Facility Name: NhQ2 � c-c n '-tl^c i2" i7Sc h. lee - County: " Inspector: t/;_�lZY Date of Inspection: Time of Inspection: Total Event Precipitation (inches): * 4to_ Was this a "Representative Storm Event" or "Measureable Storm Event" as defined by the permit? (See information below.) h/ Yes ❑ No Please verify whether Qualitative Monitoring must be performed during a "representative storm event" or "measureable storm event' (requirements vary, depending on the permit). Qualitative monitoring requirements vary. Most permits require qualitative monitoring to be performed during a "representative storm event' or during a "measureable storm event." However, some permits do not have this requirement. Please refer to these definitions, if applicable. A "representative storm event" is a storm event that measures greater than 0.1 inches of rainfall and that is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has occurred. A single storm event may contain up to 10 consecutive hours of no precipitation. A "measurable storm event" is a storm event that results in an actual discharge from the permitted site outfall. The previous measurable storm event must have been at least 72 hours prior. The 72-hour storm interval does not apply if the permittee is able to document that a shorter interval is representative for local storm events during the sampling period, and the permittee obtains approval from the local DWQ Regional office. By tFilsignature, I certify that this report is accurate and complete to the best of my knowledge: of Permittee or Designee) Page 1 of 2 1. Outfall Description: Outfall No. Structure ( ipe, ditch, etc.) . o P Receiving Stream: �s e4 9' I Describe the industrial activities that occur within the outfall drainage area: _Pr—n�C:Ta r i1 \ j uoJ Zo n l cie2 2. Color: Describe the color of the discharge using basic colors (red, brown, blue, etc.) and tint (light, medium, dark) as descriptors: TeA 64 C 4` � M 3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak chlorine odor, etc.): A(0 Al2 4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear and 5 is very cloudy: 1 2 U 4 5 5. Floating Solids: Choose the number which best describes the amount of floating solids in the stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids: 1 (D 3 4 5 6. Suspended Solids: Choose the number which best describes the amount of suspended solids in the stormwater discharge, where 1 is no solids and 5 is extremely muddy: 1 G 3 4 5 7. Is there any foam in the stormwater discharge? Yes No ' i 8. Is there an oil sheen in the stormwater discharge? Yes No 9. Is there evidence of erosion or deposition at the outfall? Yes No 10. Other Obvious Indicators of Stormwater Pollution: List and describe Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be indicative of pollutant exposure. These conditions warrant further investigation. Page 2 of 2 SWPPP Form 3: Rain Event Data This form will be used to document any rainfall data starting at least 72 hours before the expected representative storm event. Personnel 2 Y Date/Time/Rainfall a� a� �lg I , 30 0, I 0 -0 Date/Time/Rainfall Date/Time/Rainfall Date/Time/Rainfall 1 3 j j' I• 3 J pM L C) 6 Date/Time/Rainfall ((�I (� i i 30Q�^ /D •�J Date/Time/Rainfall I (S-/ I � `I /000 Date/Time/Rainfall D3 I I L Stormwater Pollution Prevention Plan Appendices aceAnalytical w Paca'aesc= March 19, 2018 Mr. Gary Harries American Truetzschler, Inc. PC Box 669228 12300 Moores Chapel Rd. 28214 Charlotte, NC 28266 RE: Project: Stormwater Samples Pace Project No.: 92375792 Dear Mr. Harries: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28076 (704)878-9092 Enclosed are the analytical results for sample(s) received by the laboratory on March 06, 2018. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wntten consent of Pace Analytical Services, LLC. Page 1 of 30 aceAnalytical0 wwwpecefaes.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntern;Wle, NC 28078 (704)875-9092 CERTIFICATIONS Project: Stormwater Samples Pace Project No.: 92375792 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #:40 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 30 aceAnalytical x paceabsmm SAMPLE ANALYTE COUNT Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 92375792001 At EPA 1664E JMS 1 PASI-C EPA 200.7 SH1 12 PASI-A EPA 245.1 SER 1 PASI-A EPA 625 BPJ 58 PASI-C EPA 624 GAW 38 PASI-C SM 2540D MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA 9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A EPA4204 DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A 92375792002 A2 EPA 1664E JMS 1 PASI-C EPA 200.7 SH1 12 PASI-A EPA 245.1 SER 1 PASI-A EPA625 Bpi 58 PASI-C EPA 624 GAW 38 PASI-C SM 2540D MJP 1 PASI-A SM 4500-S2D EJJ 1 PASI-A EPA 9040 MDW 1 PASI-A EPA 300.0 CDC 1 PASI-A EPA420.4 DMN 1 PASI-A SM 4500-CN-E BRJ 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 30 0 aceAnalytical ..MLPJabs.cQT I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual HEM, Oil and Grease Analytical Method: EPA 1664E Oil and Grease ND mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Antimony ND ug/L 5.0 1 03/07/1802:45 03/16/1803:22 7440-36-0 Arsenic ND ug/L 10.0 1 03/0711802:45 03/16/1803:22 7440-38-2 Beryllium ND ug/L 1.0 1 03/0711802:45 03/1611803:22 7440-41-7 Cadmium ND ug/L 1.0 1 03/0711802:45 03/16/1803:22 7440-43-9 Chromium ND ug/L 5.0 1 03/07/1802:45 03/16/1803:22 7440-47-3 Copper 10.3 ug/L 5.0 1 03/07/1802:45 03/16/1803:22 7440-50-8 Lead ND ug/L 5.0 1 03107/1802:45 03/16/1803:22 7439-92-1 Nickel ND ug/L 5.0 1 03/07/1802:45 03116/1803:22 7440-02-0 Selenium ND ug/L 10.0 1 03107/1802:45 03/16/1803:22 7782-49-2 Silver ND ug/L 5.0 1 03107/1802:45 03/16/1803:22 7440-22-4 Thallium ND ug/L 10.0 1 03/07/1802:45 03/1611803:22 7440-28-0 Zinc 27.6 ug/L 10.0 1 03/07/18 02:45 03/16/18 03:22 7440-66-6 245.1 Mercury Analytical Method: EPA245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 1 03/07/1813:35 03/0711818:10 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene ND ug/L 5.0 1 03/0711809:08 03/1011801:21 208-96-8 Anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-12-7 Benzidine ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 92-87-5 Benzo(a)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 03/0711809:08 03/1011801:21 50-32-8 Benzo(b)fuoranthene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 03/0711809:08 03110/1801:21 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/0711809:08 03/10/18 01:21 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 85-68-7 4-Chloro-3-methylphenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 59-50-7 bis(2-Chloroelhoxy)melhane NO ug/L 10.0 1 03/07/18 09:08 03/1011801*21 111-91-1 bis(2-Chloroelhyp ether NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 91-58-7 2-Chlorophenol ND ug/L 5.0 1 03/0711809:08 03/1011801:21 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 7005-72-3 Chrysene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 53-70-3 3,3'-Dichlorobenzidine NO ug/L 25.0 1 03/07/18 09:08 03/10/18 01:21 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:21 120-83-2 Diethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 105-67-9 Dimethylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/1011801:21 131-11-3 Di-n-butylphthalate ND ug/L 5.0 1 03107/1809:08 03/10/18 01:21 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/07/18 09:08 03/10/18 01:21 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 30 aceAnalytical ..pacNabs.00r ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 2,4-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 0310711809:08 03/10/18 01:21 122-66-7 bis(2-Ethylhexypphlhalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 117-81-7 Fluoranthene ND ug/L 5.0 1 03/07/18 09:08 0311011801:21 206-44-0 Fluorene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:21 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 77-47-4 Hexachloroethane ND ug/L 5.0 1 03107/1809:08 03/10/18 01:21 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 193-39-5 Isophorone ND uglL 10.0 1 0310711809:08 03/10118 01 *21 78-59-1 Naphthalene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 91-20-3 Nitrobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 98-95-3 2-Nitrophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 88-75-5 4-Nitrophenol NO ug/L 50.0 1 03/07/18 09:08 03/10/18 01:21 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:21 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 86-30-6 Pentachlorophenol ND ug/L 10.0 1 03107/1809:08 03/10/18 01:21 87-86-5 Phenanthrene ND ug/L 5.0 1 0310711809:08 03/10/18 01:21 85-01-8 Phenol ND ug/L 5.0 1 03/0711809:08 03/10/18 01:21 108-95-2 Pyrene ND ug/L 5.0 1 03107/1809:08 03/10/18 01:21 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:21 120-82-1 2,4,6-Trichlorophenol ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:21 88-06-2 Surrogates Nitrobenzene-d5 (S) 45 % 10-120 1 03/07/18 09:08 03/10/18 01:21 4165-60-0 2-Fluorobiphenyl (S) 41 % 15-120 1 03/07/18 09:08 03/10/18 01:21 321-60-8 Terphenyl-d 14 (S) 56 % 11-131 1 03/07/18 09:08 03/10/18 01:21 1718-51-0 Phenol-d6 (S) 14 % 10-120 1 03/07/18 09:08 03/10/18 01:21 13127-88-3 2-Fluorophenol (S) 20 % 10-120 1 03/07/18 09:08 03/10/18 01:21 367-12-4 2,4,6-Tribromophenol(S) 57 % 10-137 1 03/07/18 09:08 03/10/18 01:21 118-79-6 624 Volatile Organics Analytical Method: EPA 624 Acrolein ND ug/L 5.0 1 03/08/18 15:06 107-02-8 Acrylonitrile ND ug/L 50.0 1 03/0811815:06 107-13-1 Benzene ND ug/L 2.0 1 03/08/18 15:06 71-43-2 Bromodichloromethane NO ug/L 2.0 1 03/08/18 15:06 75-27-4 Bromoform ND ug/L 2.0 1 03/08/18 15:06 75-25-2 Bromomethane ND ug/L 2.0 1 03/0811815:06 74-83-9 Carbon tetrachloride ND ug/L 2.0 1 03/08/18 15:06 56-23-5 Chlorobenzene ND ug/L 2.0 1 03/0811815:06 108-90-7 Chloroethane ND ug/L 2.0 1 03/08/18 15:06 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 03/08/18 15:06 110-75-8 Chloroform ND ug/L 2.0 1 03/08/18 15:06 67-66-3 Chloromethane ND ug/L 2.0 1 03/08/18 15:06 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C, Page 5 of 30 aceAnalytical e ..0ace/abs.cont ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: Al Lab ID: 92375792001 Collected: 03/06/18 11:05 Received: 03106/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 624 Volatile Organics Analytical Method: EPA 624 Dibromochloromethane ND ug/L 2.0 1 03/08/18 15:06 124-48-1 1,2-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 95.50-1 1,3-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:06 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 75-34-3 1,2-Dichloroethane ND ug/L 2.0 1 03/08/18 15:06 107-06-2 1,1-Dichloroethene ND ug/L 2.0 1 03/08/18 15:06 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 15,06 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 15:06 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 03/08/18 15:06 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 0310811815:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:06 10061-02-6 Elhylbenzene ND ug/L 2.0 1 03/08/18 15:06 100-41-4 Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/0811815:06 87-68-3 Methylene Chloride ND ug/L 2.0 1 03/08/18 1506 75-09-2 Naphthalene ND ug/L 5.0 1 03/081181506 91-20-3 1,1,2,2-Tetrachloroethane ND uglL 2.0 1 03/08/18 15:06 79-34-5 Tetrachloroethene ND ug/L 2.0 1 03/08/18 15:06 127-18-4 Toluene IND ug/L 2.0 1 03/08/18 15:06 108-88-3 1,1,1-Trichloroelhane ND ug/L 2.0 1 03/08/18 15:06 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 1 03/08/18 15:06 79-00-5 Trichloroethene ND ug/L 2.0 1 03/08/18 15:06 79-01-6 Vinyl chloride ND ug/L 2.0 1 03/08/18 15:06 75-01-4 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 03/08/18 15:06 460-00-4 Toluene-d8 (S) 117 % 70-130 1 03/08/18 15:06 2037-26-5 1,2-Dichloroethane-d4 (S) 79 % 70-130 1 03/08/18 15:06 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 38.4 ri 5.0 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide NO mg/L 0.10 1 03/0911818:00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 6.1 Sid. Units 0.10 1 03/07/1821:16 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 13.4 mg/L 1.0 1 03112/1815:02 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0.010 1 03109/1813: 18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Cyanide ND mg/L 0.0080 1 03/16/18 04:19 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03119/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. H6 Page 6 of 30 a aceAnalytical mrwpece'abscom ANALYTICAL RESULTS Project: Slormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kinoey Ave. Suite 100 Huntewille, NC 28078 (704)875-9092 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Oual HEM, Oil and Grease Analytical Method: EPA 1664B Oil and Grease ND mg/L 5.0 1 03/19/18 04:50 200.7 MET ICP Analytical Method: EPA 200.7 Preparation Method: EPA 200.7 Antimony ND ug/L 5.0 1 03107/1802:45 0311611803:25 7440-36-0 Arsenic NO ug/L 10.0 1 03/0711802:45 03/16/18 03:25 7440-38-2 Beryllium NO ug/L 1.0 1 03107/1802:45 0311611803:25 7440-41-7 Cadmium NO ug/L 1.0 1 03/07/18 02:45 03/16/18 03:25 7440-43-9 Chromium 7.5 ug/L 5.0 1 03/0711802:45 03/16/18 03:25 7440-47-3 Copper 12.2 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-50-8 Lead 7.3 ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7439-92-1 Nickel NO ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-02-0 Selenium ND ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7782-49-2 Silver ND ug/L 5.0 1 03/07/18 02:45 03/16/18 03:25 7440-22-4 Thallium ND ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7440-28-0 Zinc 97.7 ug/L 10.0 1 03/07/18 02:45 03/16/18 03:25 7440-66-6 245.1 Mercury Analytical Method: EPA 245.1 Preparation Method: EPA 245.1 Mercury ND ug/L 0.20 1 03107/1813:35 0310711818:12 7439-97-6 625 MSSV Analytical Method: EPA 625 Preparation Method: EPA 625 Acenaphthylene ND ug/L 5.0 1 03/07/18 09:08 03110/1801:51 208-96-8 Anthracene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 120-12-7 Benzidine ND ug/L 50.0 1 03/07/18 09:08 03110/1801:51 92-87-5 Benzo(a)anthracene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 03/0711809:08 0311011801:51 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 03107/1809:08 0311011801:51 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 03/07/18 09:08 0311011801:51 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 85-68-7 4-Chloro-3-methylphenol NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 111-91-1 bis(2-Chloroethyp ether NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 111-44-4 2-Chloronaphlhalene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-58-7 2-Chlorophenol NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 95-57-8 4-Chlorophenylphenyl ether NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 7005-72-3 Chrysene NO ug/L 5.0 1 03/07/18 09:08 03/1011801:51 218-01-9 Dibenz(a,h)anthracene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 53-70-3 3,3'-Dichlorobenzidine NO ug/L 25.0 1 03107/1809:08 03110/1801:51 91-94-1 2,4-Dichlorophenol NO ug/L 5.0 1 03/07/18 09:08 03110/1801:51 120-83-2 Diethylphthalate NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 03/0711809:08 03/1011801:51 105-67-9 Dimethylphlhalate ND ug/L 5.0 1 03/0711809:08 03110/1801:51 131-11-3 Di-n-butylphthalate NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 1 03/07/18 09:08 03/10/18 01:51 534-52-1 2,4-Dinitrophenol NO ug/L 50.0 1 03/0711809:08 03/10/1801:51 51-28-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 30 0 aceAnalytical wwwpacebOzwm ANALYTICAL RESULTS Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: A2 Lab ID: 92375792002 Collected: 03/06118 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 625 MSSV Analytical Method: EPA625 Preparation Method: EPA625 2,4-Dinitrotoluene ND ug/L 5.0 1 03/07/18 09:08 03110/1801:51 121-14-2 2,6-Dinitrotoluene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 606-20-2 Di-n-octylphthalate NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 117-84-0 1,2-Diphenylhydrazine ND ug/L 5.0 1 03/07/18 09:08 03/10/1801:51 122-66-7 bis(2-Ethylhexyl)phthalate NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 117-81-7 Fluoranthene NO ug/L 5.0 1 03107/1809:08 0311011801:51 206-44-0 Fluorene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 86-73-7 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 87-68-3 Hexachlorobenzene NO ug/L 5.0 1 03107/1809:08 03/10/18 01:51 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 03/07/1809:08 03110/1801:51 77-47-4 Hexachloroethane NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 67-72-1 Indeno(1,2,3-0d)pyrene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 193-39-5 Isophorone ND ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 78-59-1 Naphthalene NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 91-20-3 Nitrobenzene ND ug/L 5.0 1 03/0711809:08 03/10/18 01 *51 98-95-3 2-Nitrophenol ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 88-75-5 4-Nitrophenol ND ug/L 50.0 1 03/0711809:08 03110/1801:51 100-02-7 N-Nitrosodimethylamine NO ug/L 5.0 1 03/0711809:08 0311011801:51 62-75-9 N-Nitroso-di-n-propylamine NO ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 621-64-7 N-Nitrosodiphenylamine NO ug/L 10.0 1 03107/1809*08 03/10/1801:51 86-30-6 Pentachlorophenol NO ug/L 10.0 1 03/07/18 09:08 0311011801:51 87-86-5 Phenanthrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 85-01-8 Phenol NO ug/L 5.0 1 03/07/18 09:08 0311011801:51 108-95-2 Pyrene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 129-00-0 1,2 4-Trichlorobenzene ND ug/L 5.0 1 03/07/18 09:08 03/10/18 01:51 120-82-1 2,4,6-Trichlorophenol NO ug/L 10.0 1 03/07/18 09:08 03/10/18 01:51 88-06-2 Surrogates Nitrobenzene-d5 (S) 56 % 10-120 1 03/07/18 09:08 03/10/18 01:51 4165-60-0 2-Fluorobiphenyl(S) 53 % 15-120 1 03/07/18 09:08 03/10/18 01:51 321-60-8 Terphenyl-d 14(S) 67 % 11-131 1 03/0711809:08 03/10/18 01:51 1718-51-0 Phenol-d6 (S) 18 % 10-120 1 03/07/18 09:08 03/10/18 01:51 13127-88-3 2-Fluorophenol(S) 27 % 10-120 1 03/07/18 09:08 03/10/18 01:51 367-12-4 2,4,6-Tribromophenol (S) 71 % 10-137 1 03/07/18 09:08 03110/18 01:51 118-79-6 624 Volatile Organics Analytical Method: EPA624 Acrolein NO ug/L 5.0 1 0310811815:22 107-02-8 Acrylonitrile NO ug/L 50.0 1 03/08/18 15:22 107-13-1 Benzene NO ug/L 2.0 1 03/08/18 15:22 71-43-2 Bromodichloromethane NO ug/L 2.0 1 03/08/18 15:22 75-274 Bromoform NO ug/L 2.0 1 03/08/18 15:22 75-25-2 Bromomethane NO ug/L 2.0 1 0310811815:22 74-83-9 Carbon tetrachloride NO ug/L 2.0 1 03/08/18 15:22 56-23-5 Chlorobenzene NO ug/L 2.0 1 03/08/1815:22 108-90-7 Chloroethane ND ug/L 2.0 1 03/08/18 15:22 75-00-3 2-Chloroethylvinyl ether ND ug/L 5.0 1 03/08/18 15:22 110-75-8 Chloroform NO ug/L 2.0 1 03/08/18 15:22 67-66-3 �Chloromelhane NO ug/L 2.0 1 03/08/18 15:22 74-87-3 REPORT OF LABORATORY ANALYSIS c2 This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the wr,ften consent of Pace Analytical Services, LLC. Page 8 of 30 0 aceAnalytical awwpecelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 Sample: A2 Lab ID: 92375792002 Collected: 03/06/18 11:20 Received: 03/06/18 14:06 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Oual 624 Volatile Organics Analytical Method: EPA 624 Dibromochloromethane ND ug/L 2.0 1 03/08/18 15:22 124-48-1 1,2-Dichlorobenzene NO ug/L 2.0 1 03/08/18 15:22 95-50-1 1,3-Dichlorobenzene NO ug/L 2.0 1 03/08/18 15:22 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 1 03/08/18 15:22 106-46-7 1,1-Dichloroethane ND ug/L 2.0 1 03/08/18 15:22 75-34-3 1,2-Dichloroethane NO ug/L 2.0 1 03/08/18 15:22 107-06-2 1,1-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 75-35-4 cis-1,2-Dichloroethene NO ug/L 2.0 1 03/08/18 15:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 1 03/08/18 1522 156-60-5 1,2-Dichloropropane ND ug/L 2.0 1 03/08/18 15:22 78-87-5 cis-1,3-Dichloropropene ND ug/L 2.0 1 03/08/18 15:22 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 1 03108/1815:22 10061-02-6 Ethylbenzene NO ug/L 2.0 1 03/08/18 15:22 100-41-4 Hexachloro-1,3-butadiene NO ug/L 5.0 1 03/08/18 15:22 87-68-3 Methylene Chloride ND ug/L 2.0 1 03/08/18 15:22 75-09-2 Naphthalene NO ug/L 5.0 1 03/08/1815:22 91-20-3 1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 03/08118 15:22 79-34-5 Tetrachloroethene ND ug/L 2.0 1 03/08/18 15:22 127-18-4 Toluene ND ug/L 2.0 1 03/08/18 15:22 108-88-3 1,1,1-Trichloroethane ND ug/L 2.0 1 03/08/18 15:22 71-55-6 1.1,2-Trichloroethane ND ug/L 2.0 1 03/08/18 15:22 79-00-5 Trichloroethene ND ug1L 2.0 1 03/08/18 15:22 79-01-6 Vinyl chloride ND ug/L 2.0 1 03/08/1815:22 75-01-4 Surrogates 4-Bromofiuorobenzene (S) 97 % 70-130 1 03/08/18 15:22 460-00-4 Toluene-d8 (S) 116 % 70-130 1 03/08/18 15:22 2037-26-5 1,2-Dichloroethane-d4 (S) 80 % 70-130 1 03/08/18 15:22 17060-07-0 2540D Total Suspended Solids Analytical Method: SM 2540D Total Suspended Solids 74.0 mg/L 12.5 1 03/10/18 08:43 4500S2D Sulfide Water Analytical Method: SM 4500-S2D Sulfide NO mg/L 0.10 1 03109/1818:00 18496-25-8 9040 pH Analytical Method: EPA 9040 pH 5.0 Slid. Units 0.10 1 03/07/18 21:16 H6 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Sulfate 5.8 mg/L 1.0 1 03/1211815:18 14808-79-8 420.4 Phenolics, Total Analytical Method: EPA 420.4 Phenol 0.014 mg/L 0.010 1 03/09/1813:18 108-95-2 450OCNE Cyanide, Total Analytical Method: SM 4500-CN-E Cyanide ND mg/L 0.0080 1 03/16/1804:20 57-12-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 30 laceAnalytical- .Peceiab&com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 402480 Analysis Method: EPA 1664B QC Batch Method: EPA 16648 Analysis Description: 1664 HEM, Oil and Grease Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2232441 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Oil and Grease mg/L ND 5.0 03119/18 04:48 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (701 LABORATORY CONTROL SAMPLE & LCSD: 2232442 2232443 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Oil and Grease mg/L 40 37.2 37.6 93 94 78-114 1 30 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03119/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 30 aceAnalytical .loticelabs com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 400949 Analysis Method: EPA 245.1 QC Batch Method: EPA 245.1 Analysis Description: 245.1 Mercury Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223700 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 03/07/1817:13 LABORATORY CONTROL SAMPLE: 2223701 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.6 105 85-115 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223702 2223703 MS MSD 92375598001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Cone. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L NO 2.5 2.5 2.6 2.6 106 102 70-130 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223704 2223705 MS MSD 92375805002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Mercury ug/L ND 2.5 2.5 2.7 2.7 108 107 70-130 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 30 aceAnalytical .pacelabs.can QUALITY CONTROL DATA Project: Slormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Humersville, NC 28078 (704)875-9092 QC Batch: 400889 Analysis Method: EPA 200.7 QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET Associated Lab Samples: 92375792001. 92375792002 METHOD BLANK: 2223386 Associated Lab Samples: 92375792001. 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L NO 5.0 03/17/1818:17 Arsenic ug/L NO 10.0 0311711818:17 Beryllium ug/L NO 1.0 03/1711818:17 Cadmium ug/L NO 1.0 03/1711818:17 Chromium ug/L NO 5.0 03/17/1818:17 Copper ug/L NO 5.0 03/17/1818:17 Lead ug/L NO 5.0 03/17/1818:17 Nickel ug/L ND 5.0 03/17/18 18:17 Selenium ug/L ND 10.0 03/17/1818:17 Silver ug/L ND 5.0 03/17/1818:17 Thallium ug/L ND 10.0 03/17/1818:17 Zinc ug/L ND 10.0 03117/1818:17 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2223387 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 502 100 85-115 Arsenic ug/L 500 507 101 85-115 Beryllium ug/L 500 518 104 85-115 Cadmium ug/L 500 502 100 85-115 Chromium ug/L 500 514 103 85-115 Copper ug/L 500 508 102 85-115 Lead ug/L 500 489 98 85-115 Nickel ug/L 500 507 101 85-115 Selenium ug/L 500 487 97 85-115 Silver ug/L 250 254 102 85-115 Thallium ug/L 500 517 103 85-115 Zinc ug/L 500 494 99 85-115 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Antimony ug/L 43.3 500 500 545 527 100 97 70-130 3 Arsenic ug/L NO 500 500 474 458 94 91 70-130 4 Beryllium ug/L NO 500 500 510 494 102 99 70-130 3 Cadmium ug/L NO 500 500 525 506 105 101 70-130 4 Chromium ug/L ND 500 500 534 514 106 102 70-130 4 Results presented on this page are In the units Indicated by the "Units" column except where an alternate on It is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 30 a aceAnalytical waw.perowabs. corn QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Stormwater Samples 92375792 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2223388 2223389 MS MSD 92375729003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Dual Copper ug/L 14.5 500 500 549 523 107 102 70-130 5 Lead ug/L ND 500 500 476 458 95 91 70-130 4 Nickel ug/L 7.9 500 500 513 495 101 97 70-130 4 Selenium ug/L ND 500 500 518 502 103 100 70-130 3 Silver ug/L ND 250 250 264 256 106 102 70-130 3 Thallium ug/L ND 500 500 345 328 69 66 70-130 5 M1 Zinc ug/L 60.5 500 500 554 535 99 95 70-130 3 Results presented on this page are in the units indicated by the"Units" column except where an alternate unit is presented to the right of the result. ) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analyboat Services, -LC. Page 13 of 30 aceAnalytical nwwpacabbs.00m QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 401152 Analysis Method: EPA 624 QC Batch Method: EPA 624 Analysis Description: 624 MSV Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2224898 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1-Trichloroethane ug/L ND 2.0 03/08/18 12:33 1,1,2,2-Tetrachloroethane ug/L ND 2.0 03/08/18 12:33 1,1,2-Trichloroethane ug/L ND 2.0 03/08/18 12:33 1,1-Dichloroethane ug/L ND 2.0 03/08/18 12:33 1,1-Dichloroethene ug/L ND 2.0 03/08/18 12:33 1,2-Dichlorobenzene ug/L ND 2.0 03/08/18 12:33 1,2-Dichloroethane ug/L ND 2.0 03/08/18 12:33 1,2-Dichloropropane ug/L ND 2.0 03/08/18 1233 1,3-Dichlorobenzene ug/L ND 2.0 03/08/1812*33 1,4-Dichlorobenzene ug/L ND 2.0 03/08/18 12:33 2-Chloroelhylvinyl ether ug/L ND 5.0 03/08/18 1233 Acrolein ug/L ND 5.0 03108/1812:33 AcrylonitMe ug/L NO 50.0 03108/1812:33 Benzene ug/L ND 2.0 0310811812:33 Bromodichloromelhane ug/L ND 2.0 0310811812:33 Bromoform ug/L NO 2.0 03/08/18 12:33 Bromomethane ug/L ND 2.0 03/08/18 12:33 Carbon tetrachloride ug/L ND - 2.0 03/08/18 12:33 Chlorobenzene ug/L ND 2.0 03/0811812:33 Chloroethane ug/L ND 2.0 03/08/18 12:33 Chloroform ug/L ND 2.0 03/08/18 12:33 Chloromethane ug/L ND 2.0 03/08/18 12:33 cis-1,2-Dichloroethene ug/L ND 2.0 03/08/18 12:33 cis-1,3-Dichloropropene ug/L ND 2.0 03/08/18 12:33 Dibromochloromethane ug/L ND 2.0 03108/1812:33 Ethylbenzene ug/L ND 2.0 03108/1812:33 Hexachloro-1,3-butadiene uglL NO 5.0 03/08/18 12:33 Methylene Chloride ug/L ND 2.0 03/08/18 12:33 Naphthalene ug/L NO 5.0 03/0811812:33 Telrachloroethene ug/L NO 2.0 03/08/18 12:33 Toluene ug/L ND 2.0 03/08/18 12:33 trans-1,2-Dichloroethene ug/L NO 2.0 03/08/18 12:33 trans-1,3-Dichloropropene ug/L NO 2.0 03/08/18 12:33 Trichloroethene ug/L ND 2.0 03/08/18 12:33 Vinyl chloride ug/L ND 2.0 03/08/18 12:33 1,2-Dichloroethane-d4 (S) % 85 70-130 03/08/18 12:33 4-Bromolluorobenzene (S) % 99 70-130 03/08/18 12:33 Toluene-d8 (S) e/ 112 70-130 03/08/18 12:33 Qualifiers Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, -LC. Page 14 of 30 e aceAnalytical s'u»'pa[dabs con QUALITY CONTROL DATA Project: Slonnwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE: Parameter 2224899 Units Spike Conc. LCS Result 1-CS % Rec % Rec Limits 1,1,1-Trichloroethane ug/L 20 22.0 110 52-162 1,1,2,2-Tetrachloroethane ug/L 20 19.8 99 46-157 1,1,2-Trichloroethane ug/L 20 21.0 105 52-150 1,1-Dichloroethane ug/L 20 19.8 99 59-155 i,t-Dichloroethene ug/L 20 23.0 115 1-234 1,2-Dichlorobenzene ug/L 20 19.8 99 18-190 1,2-Dichloroethane ug/L 20 21.3 106 49-155 1,2-Dichloropropane ug/L 20 22.1 111 1-210 1,3-Dichlorobenzene ug/L 20 19.6 98 59-156 1,4-Dichlorobenzene ug/L 20 18.8 94 18-190 2-Chloroethylvinyl ether ug/L 40 32.2 81 1-305 Acrolein ug/L 100 103 103 15-152 Acrylonitdle ug/L 100 99.2 99 75-132 Benzene ug/L 20 21.0 105 37-151 Bromodichloromethane ug/L 20 22.4 112 35-155 Bromoform ug/L 20 18.5 92 45-169 Bromomethane ug/L 20 18.7 93 1-242 Carbon tetrachloride ug/L 20 21.6 108 70-140 Chlorobenzene ug/L 20 20.2 101 37-160 Chlomethane ug/L 20 24.2 121 14-230 Chloroform ug/L 20 19.9 99 51-138 Chloromethane ug/L 20 18.4 92 1-273 cis-1,2-Dichloroethene ug/L 20 21.1 105 68-146 cis-1,3-Dichloropropene ug/L 20 21.3 107 1-227 Dibromochloromethane ug/L 20 21.2 106 53-149 Ethylbenzene ug/L 20 20.3 101 37-162 Hexachloro-1,3-butadiene ug/L 20 18.5 92 70-130 Methylene Chloride ug/L 20 20.7 104 1-221 Naphthalene ug/L 20 20.0 100 70-130 Tetrachloroethene ug/L 20 19A 95 64-148 Toluene ug/L 20 20.1 101 47-150 trans-1,2-Dichloroethene ug/L 20 21.3 107 54-156 trans-1,3-Dichloropropene ug/L 20 21.2 106 17-183 Trichloroethene ug/L 20 21.6 108 71-157 Vinyl chloride ug/L 20 22.3 112 1-251 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene(S) % 101 70-130 Toluene-d8 (S) % 99 70-130 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntemville, NC 28078 (704)875-9092 Oualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 2224901 MS MSD 92375577001 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual 1,1,1-Trichloroethane ug/L NO 20 20 23.8 23.5 119 118 46-171 1 1.1,2,2-Tetrachloroethane ug/L ND 20 20 21.9 21.7 109 108 73-159 1 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 15 of 30 aceAnalytical .pecelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2224900 2224901 MS MSD 92375577001 Spike Spike MS MSD MS MSD °% Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RED Qual 1,1.2-Trichloroelhane ug/L ND 20 20 23.6 22.2 118 111 64-152 6 1,1-Dichloroethane ug/L ND 20 20 21.3 21.7 107 108 43-172 2 1,1-Dichloroethene uglL ND 20 20 23.1 23.6 116 118 48-189 2 1,2-Dichlorobenzene ug/L ND 20 20 22.3 22.0 112 110 54-154 2 1,2-Dichloroethane ug/L ND 20 20 22.8 23.2 114 116 42-171 2 1,2-Dichloropropane ug/L ND 20 20 25.2 24.4 126 122 55-157 4 1,3-Dichlorobenzene ug/L ND 20 20 22.7 22.5 114 113 57-148 1 1,4-Dichlorobenzene ug/L ND 20 20 22.8 22.7 114 113 58-149 0 2-Chloroethylvinyl ether ug/L ND 40 40 ND ND 0 0 70-130 M1,c2 Acrolein ug/L ND 100 100 112 108 112 108 70-130 4 Acrylonitrile ug/L ND 100 100 103 108 103 108 70-130 4 Benzene ug/L ND 20 20 24.0 23.3 120 117 54-163 3 Bromodichloromethane ug/L ND 20 20 24.6 23.8 123 119 56-152 3 Bromoform ug/L ND 20 20 20.8 21.6 104 108 53-151 4 Bromomethane ug/L ND 20 20 17.3 18.0 86 90 10-200 4 Carbon tetrachloride ug/L ND 20 20 25.1 23.9 126 119 41-175 5 Chlorobenzene ug/L ND 20 20 23.3 23.0 117 115 67-152 1 Chloroethane ug/L ND 20 20 27.0 25.2 135 126 23-200 7 Chloroform ug/L ND 20 20 21.1 21.7 105 109 51-166 3 Chloromethane ug/L ND 20 20 19.3 18.4 97 92 40-175 5 cis-1,2-Dichloroethene ug/L ND 20 20 22.3 23.1 111 115 45-174 4 cis-1,3-Dichloropropene ug/L ND 20 20 23.8 23.3 119 116 38-146 2 Dibromochloromethane ug/L ND 20 20 24.2 25.3 121 126 65-144 4 Ethylbenzene ug/L ND 20 20 23.5 23.0 117 115 57-152 2 Hexachloro-1,3-butadiene ug/L ND 20 20 20.7 22.3 104 112 70-130 8 Methylene Chloride ug/L ND 20 20 21.6 22.0 108 110 40-167 2 Naphthalene ug/L ND 20 20 22.0 23.2 110 116 70-130 5 Tetrachloroelhene ug/L ND 20 20 22.7 21.3 114 107 59-155 6 Toluene ug/L ND 20 20 22.6 21.1 113 106 47-162 7 trans-1,2-Dichloroethene ug/L ND 20 20 23.0 22.5 115 112 47-178 2 trans-1,3-Dichloropropene ug/L ND 20 20 24.0 22.2 120 111 39-148 8 Trichloroelhene ug/L ND 20 20 24.3 24.6 121 123 60-153 1 Vinyl chloride ug/L ND 20 20 23.9 22.6 120 113 46-176 6 1,2-Dichloroethane-d4(S) % 96 104 70-130 4-Bromofluorobenzene(S) % 101 100 70-130 Toluene-d8(S) /° 97 96 70-130 Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 30 0 aceAnalytical .paos/aescun QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 400924 Analysis Method: EPA 625 OC Balch Method: EPA 625 Analysis Description: 625 MSS Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2223509 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,2,4-Trichlorobenzene ug/L NO 5.0 03/09/18 21:22 1,2-Diphenylhydrazine ug/L NO 5.0 03/09/18 21:22 2,4,6-Trichlorophenol ug/L NO 10.0 03/09/18 21:22 2,4-Dichlorophenol ug/L NO 5.0 03/09/18 21:22 2,4-Dimethylphenol ug/L NO 10.0 03/09/18 21:22 2,4-Dinitrophenol ug/L NO 50.0 03/09/18 21:22 2,4-Dinitrotoluene ug/L NO 5.0 03/09/18 21:22 2,6-Dinitrotoluene ug/L NO 5.0 03/09/18 21:22 2-Chloronaphthalene ug/L NO 5.0 03/09/18 21:22 2-Chlorophenol ug/L NO 5.0 03/09/18 21:22 2-Nitrophenol ug/L NO 5.0 03/09/18 21:22 3,3'-Dichlorobenzidine ug/L NO 25.0 03/09/1821:22 4,6-Dinitro-2-methylphenol ug/L NO 20.0 03/09/1821:22 4-Bromophenylphenyl ether ug/L NO 5.0 03/09/18 21:22 4-Chloro-3-methylphenol ug/L NO 5.0 03/09/18 21:22 4-Chlorophenylphenyl ether ug/L NO 5.0 03/0911821:22 4-Nitrophenol ug/L NO 50.0 03/09/18 21:22 Acenaphthylene ug/L NO 5.0 03/09/18 21:22 Anlhracene ug/L ND 5.0 03/09/18 21:22 Benzidine ug/L NO 50.0 03/09/18 21:22 Benzo(a)anthracene ug/L NO 5.0 03/09/18 21:22 Benzo(a)pyrene ug/L NO 5.0 03/09/18 21:22 Benzo(b)fluoranthene ug/L NO 5.0 03109/1821:22 Benzo(g,h,i)perylene ug/L NO 5.0 03/0911821:22 Benzo(k)Fluoranthene ug/L NO 5.0 03/09/18 21:22 bis(2-Chloroethoxy)methane ug/L NO 10.0 03/0911821:22 bis(2-Chloroethyl) ether ug/L NO 5.0 03/0911821:22 bis(2-Ethylhexyl)phthalate ug/L NO 5.0 03/09/1821:22 Butylbenzylphthalate ug/L NO 5.0 03/09/18 21:22 Chrysene ug/L ND 5.0 03/09/18 21,22 Di-n-burylphthalate ug/L NO 5.0 03/09/18 21:22 Di-n-octylphthalate ug/L NO 5.0 03/09/18 21:22 Dibenz(a,h)anthracene ug/L NO 5.0 03/09/18 21:22 Diethylphthalate ug/L NO 5.0 03/09/18 21:22 Dimethylphthalate ug/L NO 5.0 03/09/18 21:22 Fluoranthene ug/L NO 5.0 03/0911821:22 Fluorene ug/L NO 5.0 03/0911821:22 Hexachloro-1,3-butadiene ug/L NO 5.0 03/09/18 21:22 Hexachlorobenzene ug/L NO 5.0 03/09/18 21:22 Hexachlorocyclopentadiene ug/L NO 10.0 03/09/18 21:22 Hexachloroethane ug/L NO 5.0 03/09/18 21:22 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 17 of 30 aceAnalytical wwwpacelabs.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 METHOD BLANK: 2223509 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Indeno(1,2,3-cd)pyrene ug/L ND 5.0 03/09/18 21:22 Isophorone ug/L ND 10.0 03/09/18 21:22 N-Nitroso-di-n-propylamine ug/L ND 5.0 03/09/18 21:22 N-Nitrosodimethylamine ug/L ND 5.0 03/09/18 21:22 N-Nitrosodiphenylamine ug/L ND 10.0 03/09/18 21:22 Naphthalene ug/L ND 5.0 03/09/18 21:22 Nitrobenzene ug/L ND 5.0 03/09/18 21:22 Pentachlorophenol ug/L ND 10.0 03/09/18 21:22 Phenanthrene ug/L ND 5.0 03/09/18 21:22 Phenol ug/L ND 5.0 03/09/18 21:22 Pyrene ug/L ND 5.0 03/09/18 21:22 2,4,6-Tribromophenol(S) % 70 10-137 03/09/18 21:22 2-Fluorobiphenyl(S) % 76 15-120 03109/1821:22 2-Fluorophenol(S) % 38 10-120 03/09/18 21:22 Nitrobenzene-d5(S) % 80 10-120 0310911821*22 Phenol-d6 (S) % 28 10-120 03/09/18 21:22 Terphenyl-d14(S) % 90 11-131 03/0911821:22 Qualifiers Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: 2223510 2223511 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result %Rec %Rec Limits RPD RPD Qualifiers 1,2,4-Trichlorobenzene ug/L 50 29.4 32.0 59 64 44-142 8 30 1,2-Diphenylhydrazine ug/L 50 41.7 44.5 83 89 25-150 6 30 2,4,6-Trichlorophenol ug/L 50 44.2 23.8 88 48 37-144 60 30 Rl 2,4-Dichlorophenol ug/L 50 44.8 32.9 90 66 1-191 31 30 R11 2,4-Dimethylphenol ug/L 50 44.2 44.6 88 89 32-119 1 30 2,4-Dinitrophenol ug/L 250 64.6 25.2J 26 10 1-181 30 2,4-Dinitrotoluene ug/L 50 44.7 46.9 89 94 39-139 5 30 2,6-Dinitrotoluene ug/L 50 43.2 47.6 86 95 50-158 10 30 2-Chloronaphthalene ug/L 50 36.2 39.3 72 79 60-118 8 30 2-Chlorophenol ug/L 50 38.7 32.4 77 65 23-134 18 30 2-Nitrophenol ug/L 50 40.1 28.1 80 56 29-182 35 30 R1 3,3'-Dichlorobenzidine ug/L 100 87.4 92.1 87 92 1-262 5 30 4,6-Dinitro-2-melhylphenol ug/L 100 54.7 23.1 55 23 1-181 81 30 Rl 4-Bromophenylphenyl ether ug/L 50 41.8 44.4 84 89 53-127 6 30 4-Chloro-3-methylphenol ug/L 100 89.4 91.0 89 91 22-147 2 30 4-Chlorophenylphenyl ether ug/L 50 43.7 45.8 87 92 25-158 5 30 4-Nitrophenol ug/L 250 78.7 38.8J 31 16 1-132 30 Acenaphthylene ug/L 50 40.9 42.4 82 85 33-145 4 30 Anthracene ug/L 50 43.6 46.8 87 94 1-166 7 30 Benzidine ug/L 100 61.5 72.5 61 72 25-150 16 30 Benzo(a)anthracene ug/L 50 47.4 49.9 95 100 33-143 5 30 Benzo(a)pyrene ug/L 50 42.3 45.3 85 91 17-163 7 30 Benzo(b)lluoranthene ug/L 50 45.0 49.1 90 98 24-159 9 30 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, L-C. Page 18 of 30 aceAnalytical mvw.Pacefabs.mm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwater Samples Pace Project No.: 92375792 LABORATORY CONTROL SAMPLE & LCSD: 2223510 2223511 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Benzo(g,h,i)perylene ug/L 50 43.8 45.9 88 92 1-219 5 30 Benzo(k)fluoranthene ug/L 50 41.0 44.4 82 89 11-162 8 30 bis(2-Chloroethoxy)methane ug/L 50 44.0 46.0 88 92 33-184 5 30 bis(2-Chloroethyl) ether ug/L 50 42.1 42.8 84 86 12-158 2 30 bis(2-Ethylhexypphthalate ug/L 50 50.2 51.3 100 103 8-158 2 30 Butylbenzylphthalate ug/L 50 48.1 49.7 96 99 1-152 3 30 Chrysene uglL 50 46.1 48.3 92 97 17-168 5 30 Di-n-butylphthalate ug/L 50 47.7 51A 95 103 1-118 7 30 Di-n-octylphthalate ug/L 50 60.2 62.6 120 125 4-146 4 30 Dibenz(a,h)anthracene ug/L 50 46.5 48.7 93 97 1-227 5 30 Diethylphthalale ug/L 50 46.3 48.4 93 97 1-114 4 30 Dimethylphthalate ug/L 50 45.1 47.3 90 95 1-112 5 30 Fluoranthene ug/L 50 48.9 52.3 98 105 26-137 7 30 Fluorene ug/L 50 43.6 45.8 87 92 59-121 5 30 Hexachloro-1,3-butadiene ug/L 50 25.8 28.6 52 57 24-116 10 30 Hexachlorobenzene ug/L 50 40.3 42.6 81 85 1-152 6 30 Hexachlorocyclopentadiene ug/L 50 25.6 26.0 51 52 25-150 2 30 Hexachloroethane ug/L 50 22.9 25.1 46 50 40-113 9 30 Indeno(1,2,3-cd)pyrene ug/L 50 44.3 46.7 89 93 1-171 5 30 Isophorone ug/L 50 42.9 44.7 86 89 21-196 4 30 N-Nitroso-di-n-propylamine ug/L 50 48.2 47.5 96 95 1-230 1 30 N-Nitrosodimethylamine ug/L 50 27.0 26.0 54 52 25-150 4 30 N-Nitrosodiphenylamine ug/L 50 42.7 45.9 85 92 25-150 7 30 Naphthalene ug/L 50 34.5 36.5 69 73 21-133 6 30 Nitrobenzene ug/L 50 38.9 41.5 78 83 35-180 7 30 Pentachlorophenol ug/L 100 59.1 26.3 59 26 14-176 77 30 R7 Phenanthrene ug/L 50 42.8 46.1 86 92 54-120 7 30 Phenol ug/L 50 18.1 16.9 36 34 5-112 7 30 Pyrene ug/L 50 45.2 47.4 90 95 52-115 5 30 2,4,6-Tribromophenol (S) % 82 47 10-137 2-Fluorobiphenyl (S) % 82 84 15-120 2-Fluorophenol (S) e/ 44 29 10-120 Nitrobenzene-d5(S) % 81 82 10-120 Phenol-d6 (S) % 33 31 10-120 Terphenyl-d14 (S) % 88 87 11-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 30 is aceAnalytical .pacelsba.com QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 Pace Analytical services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 OC Batch: 401455 Analysis Method: SM 2540D OC Batch Method: SM 2540D Analysis Description: 2540D Total Suspended Solids Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2226951 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Suspended Solids mg/L ND 2.5 03/10/18 08:39 LABORATORY CONTROL SAMPLE: 2226952 Spike LCS LCS % Rec Parameter Units Conc. Result %Rec Limits Qualifiers Total Suspended Solids mg/L 250 238 95 90-110 SAMPLE DUPLICATE: 2226953 92375661001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 8.8 18.6 72 D6 SAMPLE DUPLICATE: 2226954 92375713001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L ND ND Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the night of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 30 aceAnalytical s .pi,odid renm QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Stormwaler Samples Pace Project No.: 92375792 OC Batch: 401426 Analysis Method: SM 4500-S2D QC Batch Method: SM 4500-S2D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2226688 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide mg/L NO 0.10 03/09/1818:00 LABORATORY CONTROL SAMPLE: 2226689 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Sulfide mg/L .5 0.49 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2226888 2226889 MS MSD 92375892013 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfide mg/L ND .5 .5 0.52 0.54 101 107 80-120 5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2226890 2226891 MS MSD 92375936001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Sulfide mg/L NO .5 .5 0.40 0.41 77 78 80-120 2 M7 Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presenter) to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 30 aceAnalytical e .pece'bbs.mm QUALITY CONTROL DATA Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401069 Analysis Method: EPA 9040 QC Batch Method: EPA 9040 Analysis Description: 9040 pH Associated Lab Samples: 92375792001, 92375792002 SAMPLE DUPLICATE: 2224555 92375644001 Dup Parameter Units Result Result RPD Qualifiers pH Std. Units 7.2 7.1 2 D6,H6 Paco Analytical Services, LLC 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presentee on this page are in the units indicated by the"Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent or Pace Analytical Services, LLC. Page 22 of 30 aceAnalytical ..,bacefees.com Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401567 QC Batch Method: EPA 300.0 Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2227308 Associated Lab Samples: 92375792001, 92375792002 Parameter Units Sulfate mg/L QUALITY CONTROL DATA Analysis Method: EPA 300.0 Analysis Description: 300.0 IC Anions Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 1.0 03/12/1811:29 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE: 2227309 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Sulfate mglL 50 48.7 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2227310 MS 92376343001 Spike Parameter Units Result Cone. Sulfate mg/L 2.5 50 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2227312 MS 92376390003 Spike Parameter Units Result Cone. Sulfate mg/L NO 50 2227311 MSD Spike MS MSD MS MSD % Rec Cone. Result Result % Rec % Rec Limits RPD 50 50.9 51.7 97 98 90-110 2 2227313 MSD Spike MS MSD MS MSD % Rec Cone. Result Result %Rec %Rec Limits RPD 50 48.6 49.7 97 99 90-110 2 Results presented on this page are in the units indicated by the 'Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Qual Qual Page 23 of 30 m aceAnalytical .parnJaba.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Slormwaler Samples Pace Project No.: 92375792 QC Balch: 401174 Analysis Method: EPA 420.4 QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2225030 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phenol mg/L NO 0.010 03/09/1812:49 LABORATORY CONTROL SAMPLE: 2225031 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Phenol mg/L .05 0.048 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2225032 2225033 MS MSD 92375017002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phenol mg/L ND .05 .05 0.058 0.056 100 97 90-110 3 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2225034 2225035 MS MSD 92375203001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result % Rec % Rec Limits RPD Qual Phenol mg/L 0.24 .05 .05 0.27 0.29 73 106 90-110 6 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except In full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 30 rl aceAnalytical mrwpacdabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (701 Project: Stormwater Samples Pace Project No.: 92375792 QC Batch: 401894 Analysis Method: SM 4500-CN-E QC Batch Method* SM 4500-CN-E Analysis Description: 450OCNE Cyanide, Total Associated Lab Samples: 92375792001, 92375792002 METHOD BLANK: 2229109 Matrix: Water Associated Lab Samples: 92375792001, 92375792002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Cyanide mg/L NO 0.0080 03/16/1804:09 LABORATORY CONTROL SAMPLE: 2229110 Spike LCS 1-CS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Cyanide mg/L .1 0.11 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2229111 2229112 MS MSD 92376219002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qual Cyanide mg/L 5.7J A .1 0.095 0,088 89 82 80-120 8 ug/L MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2229113 2229114 MS MSD 92376219007 Spike Spike MS MSD MS MSD %Rec Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Quay Cyanide mg/L 6.5J .1 .1 0.10 0.098 94 91 80-120 3 ug/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 30 aceAnalytical ww cdabs.=n QUALIFIERS Project: Stormwater Samples Pace Project No.: 92375792 DEFINITIONS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RED values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) CUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H6 Analysis initiated outside of the 15 minute EPA required holding time. M1 Matrix spike recovery exceeded OC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. c2 Acid preservation may not be appropriate for the analysis of 2-Chloroethylvinyl ether. 17 � 17i �i7 ���Z�77_� fi77/cl`J_A'l•969 This report shall not be reproduced, except in full. Dale: 03/19/2018 02:16 PM without the wnffen consent of Pace Analytical Services, LLC. Page 26 of 30 aceAnalytical NW W pacelab9.cnm QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: Pace Project No.: Stonnwater Samples 92375792 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92375792001 At EPA 16646 402480 92375792002 A2 EPA 1664E 402480 92375792001 Al EPA 200.7 400889 EPA 200.7 400993 92375792002 A2 EPA 200.7 400889 EPA 200.7 400993 92375792001 Al EPA 245.1 400949 EPA 245.1 401005 92375792002 A2 EPA 245.1 400949 EPA 245.1 401005 92375792001 Al EPA625 400924 EPA625 401382 92375792002 A2 EPA625 400924 EPA625 401382 92375792001 Al EPA 624 401152 92375792002 A2 EPA624 401152 92375792001 Al SM 2540D 401455 92375792002 A2 SM 2540D 401455 92375792001 Al SM 4500-S2D 401426 92375792002 A2 SM 4500-S2D 401426 92375792001 Al EPA 9040 401069 92375792002 A2 EPA 9040 401069 92375792001 Al EPA 300.0 401567 92375792002 A2 EPA 300.0 401567 92375792001 Al EPA 420.4 401174 92375792002 A2 EPA 420.4 401174 92375792001 Al SM 4500-CN-E 401894 92375792002 A2 SM 4500-CN-E 401894 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/19/2018 02:16 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 30 Custody Seal Present? ❑Ves �QN�als tnlac[7 -]Yes ❑N0 Document Name: Document Revised: February 7, 2018 aceAMIXICal ` Sample Condition U on Recel t(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-W-CS-033•Rov.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville0 Raleigh[] Mechanicsville❑ „:WO#:92375792 92375792 Date/Initials Pena n Examining Contents: 7� Packing Material: ❑Bubble Wrap ,OB bu ble Bags []None ❑ Other Biological Tissue Frozen? Thermometer: []Yes ❑No -ON/A QIRuntD: 92TO36 TypeofIce: pwiglue one Cooler Temp ('C): 5' Correction Factor: Add/Subtract ('C) +0.1 .i Tamp should be above freezing to 6'C Cooler Temp Corrected (Q. �� []Samples out o1 temp criteria. Samples an ice, cotiing process _ has begun USDA Regulated So11'(❑ N/A, water sample) Did samples originate In a Quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (Internationally, Yes No including Hawaii and Puerto Rim)? Oyes _ONO, Commersts/01screpancy,. Chain of Custody Present? — - Yes ONO ONJA 1. Samples Arrived within Hold Time? IQYes No N/A 2. Short Hold Time Analysis e72 hr.)? Dyes No ONIA 3. Rush Turn Around Time Requested, Yu No N/A 4. Sufficient Volume? Yef No ONIA S. Correct Containers Used? Pace Containers Used? -- Yes ❑No ' YeNo ❑N/A N/A 6. Containers Intact? / - Yes ONO N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes%9190_ ❑N/A 8. Sample Labels Match COC? -Includes Date/Tme/10/Anal is Matrix: /❑Yes ONO ❑N/A 9. Heads ace in VOA Vials >S.fimm ? i^ QYes No N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes pNo Dyes ONO ❑N/A . H/A� it. ,. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NDTIFICATION/RESOLUTION Person contacted: Date/Time: _ Project Manager SCURF Review: Project Manager SRF Review: YI YY 1 CJ Field Date Required? ❑Ves ONO Date:��,U/�1I� Date: l Page 28 of 30 -, ceAnalytical• Document Name: Sample Condition U Recelpt(SCURI Document Revised: February 7, 2018 Page 1 of 2 Document No.: Issuing Authorlty: F-CAR-CS-033-Rev.06 I Pace Carolinas Qualitv OfOce 'Check mark top half of box If pH and/or dechlorinatlon Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO18015 (water) DOC, UHg a*Bottom half of box Is to list number of bottle Project if WO# : 92375792 i PM: AMB Due Date: 03/20/18, CLIENT: 92—Am Trueta 3 i Z a z S zn °a L O O w _ ,-r v �—' z e i a 9 n a i z n Br 2 u 2 a L v v z v a O d A v 0 E •, n v s z 2 6` Z 2 O A!p n Yn S C C C C > C N ; .Y Q Y $ y =E _ z $, a— a a 7 i JL +y ^{ G ,� A. O 6 E n E 6 E R n v LL E n E 6 E 6 E E 5 E; Q ?! a E E a L a ypE� N �. i' E O04 > E E E s J: E E JgF E E y m m m m m 2 m N m U m LL 3 H a M '� • a t N 4E T a P P P 4 m a q un a q m g a qE 1 2 r L y L L� � N\ I I I NN+- 3 4 5 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples nlfl Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot x NR it n Office (I Note: Whenever there is a discrepancy affecting North Carolina compliance semPles,a copy of this form will be sent to the North Carolina DEH Ce ca o Out of hold. incorrect preservative, out of temp. incorrect containers. Page 29 of 30 f aDn1�. CHAIN -OF -CUSTODY I Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Secdon A Section 8 Seetion C Required Client Infomulon: Required Project Infe rnaeon: Invoice Infomuf an: Page : 1 Of t Company: Am naan Truet tscbler, Inc. lReon To: Gaq Hems Attention: Aaere.- PO Boa fi692]B lCop, To Campany Name: Cnarlale, NC 28268 Address: v' i litaeafi.A, Email: maimarerce amimeUschler.mm flancrase Order I: Pace Ovate. Panne: (704)391-SW5 IF. 1projer Name: slap vatw sam Ms Pace Props Maltapec a M. bmniPpacei.b. mm, +_ :a State l Looa6au t+;°. .'•:. -' ' Requesmd Due Date lPri.,t R; Pace Profile a: 220& NC Reauwabod Mulch Fiherad M 2 Z .TRu apE COLLECTED z Preservatives } w w w ow y O 9 Wr ^ G U a.e,n P SAMPLE ID m ? U O b pma START END a One Character per boa. we. w•v w w i a m o ��. (AZ 0.91,-) ann Di U _ Sample Ids must be unique ,,, w TD.TCT111 ~ E w ~ c jJ `s V o$ i o o O Q w= i u y g 'A[D.TE TIME e s i f m is ram- O J G �Nlln ✓✓✓✓6✓ 1 ril 2 ✓ ✓ CO 2-3 y 3 4 5 6 F97. 12 -'. t •.� ' •ADof1IONAL FMJU191®eY(AFFILIATION r ,� .. 'DAW ,. +'TIE i - ACCEPTEDDYIA ATION 1lY A .ATE. .' TMC } i:= '!UkiLONIX1ION9f -3 b l if I4'od n/Oh l Gf !? /rani 3 A/ SAMP NAIIEANDSIGNATURE 5 z m PRINT Name of SAMPLER: /• 2 M G j V w m C�Y m S raU� m e ulc" SIGNATURE a15AMPLER: DATE sinned: