NCG020540_COMPLETE FILE - HISTORICAL_20111216

- STORMWATER-DIVISION CODING -SHEET -
RESCISSIONS.
PERMIT NO.
NC G O a O5y 0
DOCTYPE
[COMPLETE FILE'- HISTORICAL
DATE OF
.RESCISSION
❑ bi o�
YYYYMMDD

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HC®EHR
North Carolina Department of Environment and Natural Resources
Beverly Eaves Perdue
Governor
Division of Water Quality
Coleen H. Sullins
Director
December 16, 2011
Mark Bryan
Williams Sand & Gravel Co - Williams Sand & Gravel Co
PO Box 129
Newton Grove, NC 28366
Dear Permitee:
DEC 21 2011
DWo
Dee Freeman
Secretary
Subject: Rescission of NPDES Stonmwater Permit
Certificate of Coverage Number NCG020540
Williams Sand & Gravel Co - Williams Sand & Gravel
Co
Sampson County
On 8/19/201 1, the Division of Water Quality received your request to rescind your coverage under
Certificate of Coverage Number NCG020540. In accordance with your request, Certificate of Coverage
Number NCG020540 is rescinded effective immediately.
Operating a treatment facility, discharging wastewater or discharging specific types of stormwater to
waters of the State without valid coverage under an NPDES permit will subject the responsible party to a
civil penalty of up to $25,000 per day. It is the intention of DWQ that enforcement proceedings will
occur for persons that have voluntarily relinquished permit coverage when, in fact, continuing permit
coverage was necessary. If, in retrospect, you feel the site still requires permit coverage, you should
notify this office immediately. Furthermore, if in the future you wish to again discharge to the State's
surface waters, you must first apply for and receive a new NPDES permit.
If the facility is in the process of being sold, you will be performing a public service if you would inform
the new or prospective owners of their potential need for NPDES permit coverage.
If you have questions about this matter, please contact Brian Lowther at [phone], or the Water
Quality staff in our Fayetteville Regional Office at NPDES SW.
Sincerely,
4P�
for Colleen H. Sullins, Director
cc: Fayetteville Regional Office
Stormwater Permitting Unit
DWQ Central Files - w/attachments
Fran McPherson, DWQ Budget Office - please waive applicable fees
Wetlands and Stomnvater Branch
One
1617 Mail Service Center, Ralegh, North Carolina 27699-1617
>\ O L "arD'lna
i V 1 Ull., 1
Location: 512 N. Salisbury St. Raleigh, North Carolina 27604
.
Phone: [phone] FAX: [phone] Customer Service: 1.877623-6748
naturally
Naturally
Internet: www.ncwaterqualily.crg
An Equal Opportunity 1 ARrmabve Acton Employer

W A r�R
Mark Bryan
Williams Sand & Gravel Co
PO Box 129
Newton Grove, NC 28366
Dear Permittee:
Michael P. Easley, Governor
William G. Ross Jr., Secretary
North Carolina Department of Environment end Natural Resources
Alan W. Klimek, P.E. Director
Division of Water Quality
February 7, 2005
DENR--FRO
f EB 2 12005
I'DWO
Subject: NPDES Stormwater Permit Coverage Renewal
Williams Sand & Gravel Co
COC Number NCG020540
Sampson County
In response to your renewal application for continued coverage under general permit NCG020000 the Division of Water
Quality (DWQ) is forwarding herewith the reissued stormwater general permit. Please review the new permit to familiarize
yourself with the changes in the reissued permit. The general permit authorizes discharges of stormwater and some types of
wastewater. You must meet the provisions of the permit for the types of discharges present at your facility. This permit is
reissued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement
between the state of North Carolina and the U.S. Environmental Protection Agency, dated December 6, 1983.
The following information is included with your permit package:
• A new Certificate of Coverage
• A copy of General Stormwater Permit NCG020000
• A copy of a Technical Bulletin for the general permit
• Five copies of Discharge Monitoring Report (DMR) Forms - wastewater and stormwater
• Five copies of Qualitative Monitoring Report Form
Your coverage under this general permit is not transferable except after notice to DWQ. The Division may require modification
or revocation and reissuance of the Certificate of Coverage. This permit does not affect the legal requirements to obtain other
permits which may be required by DENR or relieve the permittee from responsibility for compliance with any other applicable
federal, state, or local law, rule, standard, ordinance, order, judgment, or decree.
If you have any questions regarding this permit package please contact Jonathan Diggs of the Central Office Stormwater
Permitting Unit at [phone], ext.537.
Sincerely,
for Alan W. Klimek, P.E.
cc: Central Files
Stormwater & General Permits Unit Files
Fayetteville Regional Office
Nwo hCarolina
ahrral/y
North Carolina Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 Phone [phone] Customer Service
Internet: h2o.enrstate.nc.uslsulstormwater.html 512 N. Salisbury St. Raleigh, NC 27604 FAX [phone]
An Equal Opportunity/Affirmative Action Employer— 50% Recycled110% Post Consumer Paper

STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
GENERAL PERMIT NO. NCG020000
CERTIFICATE OF COVERAGE No. NCG020540
STORMWATER AND PROCESS WASTEWATER DISCHARGES
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and
regulations promulgated and adopted by the North Carolina Environmental Management Commission, and
the Federal Water Pollution Control Act, as amended,
Williams Sand & Gravel Co
is hereby authorized to discharge stormwater and to operate treatment systems and discharges associated
with mine dewatering wastewater and process wastewater from a facility located at
Williams Sand & Gravel Co
Sr 1620 Timothy Rd
Dunn
Sampson County
to receiving waters designated as UT to Big Juniper Run, a class c-swp stream in the Cape Fear River
Basin in accordance with the effluent limitations, monitoring requirements, and other conditions set forth in
Parts I, II, III, IV, V, and VI of General Permit No. NCG020000 as attached.
This certificate of coverage shall become effective February 7, 2005.
This Certificate of Coverage shall remain in effect for the duration of the General Permit.
Signed this day February 7, 2005
for Alan W. Klimek, P.E., Director
Division of Water Quality
By Authority of the Environmental Management Commission

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State of North Carolina
Department of Environment
and Natural Resources
Division of Water Quality
James B. Hunt, Jr., Governor
Bill Holman, Secretary
Kerr T. Stevens, Director /
Mr. Mark Bryan g
�7Z7
Vie(/ g10) z37 September 8, 2000
Williams Sand & Gravel, Inc.
PO Box 129
Newton Grove, NC 28366
Dear Mr. Bryan:
ern
NL
NCDENR
NORTH NT AN N DEPARTMENT OF.
ENVIRONMENT AND NATURAL RES . '_'" \tI[( IIL�J1'
U 6 .;y{.' Ccl p
Sf P 2 0 2000
FAYET i EVILLE
REG. OFFICE
Subject: General Permit No. NCG020000
Williams Sand & Gravel, Inc.
COC NCG020540
Sampson County
In accordance with your application for discharge permit received on July 5, 2000, we are
forwarding herewith the subject certificate of coverage to discharge under the subject state - NPDES
general permit. This permit is issued pursuant to the requirements of North Carolina General Statute
143-215 .1 and the Memorandum of Agreement between North Carolina and the US Environmental
Protection agency dated December 6, 1983.
If any parts, measurement frequencies or sampling requirements contained in this permit are
unacceptable to you, you have the right to request an individual permit by submitting an individual
permit application. Unless such demand is made, this certificate of coverage shall be final and binding.
Please take notice that this certificate of coverage is not transferable except after notice to the
Division of Water Quality. The Division of Water Quality may require modification or revocation and
reissuance of the certificate of coverage.
This permit does not affect the legal requirements to obtain other permits which may be required
by the Division of Water Quality or permits required by the Division of Land Resources, Coastal Area
Management Act or any other Federal or Local governmental permit that may be required.
If you have any questions concerning this permit, please contact Mack Wiggins at telephone
number 919/733-5083 ext. 542.
Sincerely,
ORIGINAL SIGNED By
WILLIAM C. MILLS
Kerr T. Stevens
cc: Fayetteville Regional Office
Central Files
Stormwater and General Permits Unit Files
1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper

STATE OF NORTH CAROLINA
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
DIVISION OF WATER QUALITY
GENERAL PERMIT NO. NCG020540
CERTIFICATE OF COVERAGE No. NCG020000
STORMWATER, MINE DEWATERING, AND/OR OVERFLOW FROM
PROCESS WATER RECYCLE SYSTEMS DISCHARGES
NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM
In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and
regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the
Federal Water Pollution Control Act, as amended,
Williams Sand & Gravel, Inc.
is hereby authorized to discharge mine dewatering and stormwater from a facility located at
Williams Mine #3
NCSR 1620 (Timothy Road)
southeast of Dunn
Sampson County
to receiving waters designated as an unnamed tributary to Big Juniper Run, class C-Swamp waters, in the Cape Fear
River Basin in accordance with the effluent limitations, monitoring requirements, and other conditions set forth in
Parts I, II, III, IV, V, VI and VII of General Permit No. NCG020000 as attached.
This certificate of coverage shall become effective September 8, 2000.
This Certificate of Coverage shall remain in effect for the duration of the General Permit.
Signed this day September 8, 2000.
ORIGINAL SIGNED BY
WILLIAM C. MILLS
Kerr T. Stevens, Director
Division of Water Quality
By Authority of the Environmental Management Commission

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Report to: , F-go WATER QUALITY SECTION Page —of
CHAIN OF CUSTODY (COC) RECORD
NC DESWDR'Q LABORATORY (check one): CENTRAL IIARO II \VaRO
For Investigation of: ; I I �.rg S�- �d /_ Vu ✓L
Sample collector (print name) D • A
and DIM-1 forms completed by: � . R¢.V t( S Sample collector's signature: /l.ee,ti'
7) Q .ems
Field storage conditions and location (when applicable):
Lab Use WIN,
-
LAB NO,
STATION NO.
STATION LOCATION
DATE
SAMPLED
TLME
SAMPLED
NUMRER
OF
CONTAINERS
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Time
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Re 'ved by (si n tine): e i
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Date,
D
Time
`�'
Relinquish' y (signature):
Date
Time
Received by (signature):
Date
"time
Relinquished by (signature):
Date
Time
Received by (signature):
Date
Time
Method of Shipment (circle one):
State Courie Hand -delivered Federal Express UPS
Other:
Security Type and Conditions:
Sealed b
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-e by:
p ' '
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!NTIIAl AnnoATORYCIIAINOFf USTODV - Lahnce Only
LAB NUMBERS
FROM TFIROUGH
NUMBER
BOTTLES
ANALYSES
REQUESTED
RELINQUISHED
BY:
RECEIVED
BY:
DATE
TIME
®ENR-'=K
NOV 10 ,
004
�llilQ
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QA\FormslSaruple Receiving\COC form WQ 4l10101dbs

COUNTY SAMPSON
RIVER BASIN:
REPORTTO FRO Reginal Office
Other
COLLECTORIS): RREVEIS
Eatimaled BOD Range:
Seed; Chlarinaled:
Station p I Date 1b& Dyhanddd)
BOD 310
COD High 340 my/L
COD Lou' 335
Collfori MF Faa131616 /100m1
Colifnoo MF Total 315N /lw.I
Calif.: mte Fecal 31615 Ownal
Coliform: Pccal Sump 31673 /lw.l
Residue: Taal 5W mg(L
Volatile 505 warfl-
Fi.,d 510 uEj
Residue: Suslended 530 mp/1.
Volatile 535
Faed 540
f 403 nits
Acidicy to pH4.3436 mg/L
Acidity to pH gJ 435 EfL
Alkalinity in pHP3415 mg/L
Alkalinity to pH4.5410 fi
TOC 690 man.
%
Tart,iduy 76 330 NTU
Calif. Total Tube '/lint) mis
COMMENTS:
DIVISION OF WATER QUALITY
Chemistq Wwramry Retort / Water Quality
' W CAMP PTYpF
PRIORIT
AM13MP1QA EJ STREAM 0 EFFLUENT
COMPLIANCE .Y❑ CUAI,Y OF CUSTODY 0 LAKE INFLUENT
EMERGENCY VISIT
❑ ESTUARY
I
Smtionl,aeation: WILLIAMS SAND AND GRAVEL
Remark:
Dale End U>/mMdd) Time Itegin Time End I Depth - DM, DB, DRyl Vnlue "F,,-A. It, 1,
Lab Narak, : 4W6962
Date Reeeived : 11/5/2(01
Time Received: 9:20 AM
Received By HMW
Data Releaed : IC
DaieRdwned: 11/16R004
Composite-T,S, I SampleTy,ue
DEN tl-F O
NOV 2 2 2004
EAW10

DIVISION OF ENVIRONMENTAL
MANAGEMENT
WATE ALITY
F LA M (DM1)
COUNTY J �/J SO/✓
PRIORITY
PH I
O
R
❑AMBIENT ❑
I�
❑ N
REPORT TOTO: : AR FRO
RO RRO WaRO WiftO WSRO TS
QA
STREAM EFFLUENT
AT BM
IfC�II
❑COMPLIANCE
❑ ❑
Ot
Othe
IC7 CHAIN
LAKE INFLUENT
OF CUSTODY
Shipped by; Bu Cou er, if, Other ❑EMERGENCY ❑ESTUARY
COLLECTOR(S):(_?
Estimated ROD Range: 0-5/5-25/25-65/40.130 or 100 plus STATION LOCATION: WI �'f4 W S SGN lDV
Seed: Yes No Chlorinated: Yes El No❑ REMARKS:__
For Lab Use ONLY
Lab Number: 69�p(
//��
Date ReceivedY/10—05
/�
Time:O
Rec'd by:
DATA ENTRY BY:
From: Bus ourie
CK:
DATE REPORTED:
te Begin r((yy/mm/d ) I Tire B;�j Date End (Time EndlDepth DM DB DBM I Value Type
t
/ 7 2 i A H L
mg/1
3
COD Low 335 mg/1
4
Coliform: MF Fecal 31616 /100m1
5
Coliform: MF Total 31504 /100m1
6
Coliform: Tube Fecal 31615 /100mi
7
Coliform: Fecal Strep 31673 /100m1
8
Residue: Total 500 mg/I
9
Volatile 505 mg/I
10
Fixed 510 mg/i
11
Residue: Suspended 530 m9/1
12
Volatile 535 mg/1
13
Fixed 540 mg/I
14
IPH 403 units
15
Acidity to PH 4.5 436 mg/I
16
Acidity to pH 8.3 435 mg/I
17
Alkalinity to pH 8.3 415 mg/1
18
Alkalinity to pH 4.5 410 mg/I
19
TOC 680 mg/1
20
y
Turbidity 76 NTU
Chloride 940 mg/I
Chi a: Tri 32217 ug/I
Chi a: Corr 32209 ug/1
Pheophytln a 32213 ug/1
Color: True 80 Pt -Co
C.10r:(PH ) 83 ADMI
Color: pH 7.6 82 ADMI
Cyanide 720 mg/I
Fluoride 951 mg/I
Formaldehyde 71880 mg/I
Grease and Olis 556 mg/1
Hardness Total 900 mg/1
Specific Cond. 95 uMhos/cm2
MBAS 38260 mg/1
Phenols 32730 ug/I
Sulfate 945 mg/I
Sulfide 745 mg/I
NH3 as N 610 mg/1
TKN as N 625 mg/1
NO2 plus NO3 as N 630 mg/1
P: Total as P 665 mg/1
PO4 as P 70507 mgA
P: Dissolved as P 666 mgA
CdCadmium 1027 ug/1
CrChromfum:Tota11034 ugA
Cu-Copper 1042 ug/I
NI -Nickel 1067 usA
Pb-Lead 1051 ug/I
Znt Zinc 1092 ug/I
All -Sliver 1077 ug/I
AI -Aluminum 1105 ug/1
Be -Beryllium 1012 ug/I
Ca -Calcium 916 m9/1
Co -Cobalt 1037 usA
Fe -Iron 1045 ugA
Composite Sample �Ty ge)
T S B C V GNXX
Li-Lithlum 1132 ugA
Mg -Magnesium 927 mgA
Mn-Manganese 1055 ug/1
Na-Sodium 929 mg/1
Arsenic -.Total 1002 ug/I
Se -Selenium 1147 ug/I I
Hg-Mercury 71900 ug/1
Organochlorine Pesticides
Organophosphoms Pesticides
Acid Herbicides
Base/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle reg'd)
Phytoplankton
Sampling Point%
Conductance at 25C
Water Temperature
D.O. mg/1
pH
Alkalinity
Acidity
Air Temperature(C)
PH 83 pH 4.5
pH 4.5 pH 8.3
2
94
10
300 1
400 1
82244 1 431
82243 182242
20
Salinity %
Precipition On/day)
Cloud Cover %
Wind Direction O)eg)
Stream Flow Severity
Turbidity Severity
Wind Velocity M/H
can Stream Depth ft.
Stream Width it
480
45
32
36
1351
1350
35
64
4

COUNTY SAMPSON
RIVER BASIN:
REPORTTO FRO Rcelonal Office
Other
COLLECTOR(S) : R REVEIS
Estimated ROD Range:
Seed: Chlorinated:
Station# I Date BeginDy/mm/dd)
DIVISION OF WATER QUALITY
Chemistry Iatlaraary Be,. /Ivaser Quality
wQ snM� rrvrF.
PRIORITY
❑ AMBIENT CA O S'I REAM ❑ EFFLUENT
COMPLIANCE O CHAINOPCUSIODY ❑ FARE ❑ INFLUENT
EMERGENCY VISIO 1:1ESTUARY
2
Station location: IFRNIGAN MILT. POND AT SPILL WAY
Remarks:
Date End(,tatrldd) Time Begin I Time End I Depth. DM, DR, DBM %'aloe Tyne - A, 11, 1,
ROD 310 me/L
Chloride Wit
COD Dish 140 rJL
Chia: Tri 32217 .,A -
COD Lso, 335
Chi a: Corr 322W ran,
Cnliform: MF FecaI 31 66 /IWml
Phenhytin a 32213 ug/L
Colihato MFTmal JI50J 11wrol
Color Tmc 80
Colifom: tube Fecal 31615 /Imm1
Cnloc(If) 83 IEz
C0'to— Fecal Sla 31673 11M.1
Color: Hl6 82
Residue: Taa1500
CyE J20 .,/L
Volatile 505
Fluondc 951 m,A,
Fled 510
Formaldch Je JI6S0 mg11.
Residue Suspended 530
Gmax and Oils 35b mgA.
volatile 335 Ej
Hardness Total 900 mg/L
Fmd 540
S cifc Cord. 95 umhos/cm2
11403 ..it,
MBAS 392W in,&
Acidity to pit 43436
Et2.4, 32J30 ug/L
Acidityto H83435
SdEuc 945 mg4,
Alkalinity t0 pff83415 mEj
Su1Bdc 745 melt
Alkalinity to pit4.5410 Ej
Boron
TOC 6W
Tannin A LiErm uglL
%
TurbidiF 76 17 WI/
He.awlent Chromium ug/L
Coliform Taal Tuhe "/IM mis
Bii,wbom to r,/L
Cadmnam mgA.
COMMENTS:
NH3 as N 610 mg/L
an N625 me/L
LN
2 plus NO3 as N 630 mg/l.
P: Total av P 665 melt.
POT as P 70507 mg/L
P: Dissohed as P 666 mgfL
K.Pm:Isslro me/L
Cd-Cadmium 1027 ug/L
CrLhromium.Toa11034 ug1
Cu-Copper WF12 ugfL
Ni-Nickel rWJ ug/L
Pb 1-cad 1051
J -Zire 1092 ug/L
V-Vanadium CIL
A -Silver 1077 ug/L
AI- Aluminum 1105
Be-Bc llium 1012 ug/L
Ca. Calcium 916
Co- Cmuh 1037 ug/L
Fe -Iron IM$ urJL
lab Number : 4W6963
Date Rcccivcd : 11/5/2f1(H
Time Received: 9.20 AM
Ris,m,edBy : HMW
Data Ittkascd : IC
Date R,1m,, : 111162ON
Cmnposite-T, S. 11 Sample Type
U-LBhiam 1132
Mg- Magnm92]
MmManganese 1055
Na- Sodium 929
Arsenic: Total 1002
St. Selenium I147
If Wrtury 719f1(1uEj
Ba Darium ug/L
Or an —him ne Pesticides
Or mm lanphoms Pesticides
Acid HnTicides
B.ul i,utralAAcid Estnaable Organics
TPH Diexal Range
Purgcablc Oreanlcs(VOA latle 'it)
TPI I Gasoline Ran c
TPI VBTE% Gasoline Ranee
PM1 m lanklon
NOV 2 2 ?: 't

DIVISION OF ENVIRONMENTAL MANAGEMENT
WA QUALITjj6([:Lrjd01 s FORM (DM1)
4N+ r/�tlyfPIRRL_
O
COUNTY
PRIORITY E TYPE
RIVER-t1ASIN e ��-- Ftrlli
❑AMBH:NT ❑
®
❑
REPORT TO: AR FRO MRO RRO WaRO WIRO WSRO TS
QA
STREAM
EFFLUENT
AT BM
Oth
F;;7
❑COMPLIANCE r--' CHAIN
❑ LAKE
❑
INFLUENT
ar OF CUSTODY
Shipped by: B Courier tali, Other ❑EMERGENCY ❑ESTUARY
COLLECTOR(S): /c..1'—..t (GeJ� ��`�
STATION LOCATION: J�✓IlliSCn� /VjI(/ r�� �tll �l "�4'' C(%Ow• Sf
Estimated BOD Range: 0-5/5-25/25-65/40-130 or 100 plus I
Seed: Yes ❑ No ❑ Chlorinated: Yes ❑ No ❑ REMARKS:
For Lab Use ONLY
Station
1
_1 [COD High 340 m9/1 1
4
Collform: ME Fecal 31616
/100m1
5
Coli(orm: METotal 31504
/loom]
6
Coil(orm: Tube Fecal 31615
/100ml
7
Co':'Fecal Strep 31673
/loom[
A
Residue: Total 500
mg/I
11
Kesldue: Suspended 530 m9/1
12
Volatile 535 m9/1
13
Fixed 540 mg/1
14
PH 403 units
15
Acidity to PH 4.5 436 mg/I
16
Acidity to pH 8.3 435 mg/I
17
Alkalinity to pH 8.3 415 m9/1
18
Alkalinity to pH 4.5 410 m9/1
19
TOC 680 mg/I
,
Turbidity 76 NTU
Time Begin Date End
z:3S,
Chloride 940 m9/1
Chi a: Tri 32217 ug/1
Chi a: Corr 32209 u9/1
Pheophytin a 32213 ug/I
Color: True 80 Pt -Co
Color:(pH ) 83 ADMI
Color: pH 7.6 82 ADMI
Cyanide 720 mg/I
Fluoride 951 mg/I
Formaldehyde 71880 mg/I
Grease and Oils 556 mg/1
Hardness Total 900 mg/1
Specific Cond. 95 uMhos/cm2
MBAS 38260 mg/I
Phenols 32730 usA
Sulfate 945 mSA
Sulfide 745 mg/I
Lab Number.
s
Date Received
Time-.
Rec'd b
Prom:
Bus- our Hand Del
DATA ENTRY BY:
CK:
DATE REPORTED:
Depth DM DB DBM I Value Type
A H L
NH3 as N 610 mg/1
TKN as N 625 mgA
NO2 plus NO3 as N 630 mgA
P: Total as P 665 mg/I
PO4 as P 70507 mg/1
P: Dissolved as P 666 mgA
CdCadmlum 1027 ug/I
CrCht.mIum:Tota11034 ugA
CuCopper IG42 ug/I
NI-Nlcke11067 ug/I
Pb-Lead 1051 ug/1
Z,Zlnc 1092 ug/I
Ag-Silver 1077 ug/I
AI -Aluminum 1105 ug/I
Be -Beryllium 1012 ug/I
Ca Calcium 916 mgA
.-Cobalt 1037 ug/I
Fe -Iron 1045 ug/I
T S B I C G GN%%
Li -Lithium 1132
ug/1
Mg -Magnesium 927
mgA
Mn-Manganese 1055
ug/I
Na-Sodium 929
mgA
Arsenic:Totai 1002
ug/I
Se -Selenium 1147
ug/I
Hg-Mercury 71900
ug/1
Organochlorine Pesticides
Organophcq*oms Pesticides
Acid Herbicides
Base/ Neutral Extractable Organics
Acid Extractable Organics
Purgeable Organics (VOA bottle reg'd)
Phytoplankton
Sampling Point %
Conductance at 25 C
Water Temperature
D.O. m9A
pli
Alkalinity
Acidity
Air Temperature (C)
PH 8.3 PH 4.5
pH 4.5 pH 8.3
2
94
10
300 .
400
82244 431
82243 82242
20
Salinity %
Precipition (in/day)
Cloud Cover %
Wind Direction (Deg)
Stream Flow Severity
Turbidity Severity
Wind Velocity MAI[oan
Stream Depth it
Stream Width it
480
45
32
36
1351
1350
35
4
4
U
wj
DMI/ReWsed 10/96

DIVISION OF WATER QUALITY
Chemistry Laboratory RcPort / Water Quality
-
\V SkMPI FTl'PE
COUNTY SAMPSON
RIVER BASIN:
PR DR Ti
❑ AMBIENT O CA
O STREAM
❑ EFFLUEN'T
REPORTTO FRO Regional Office
❑ COMPLIANCE X� CHAIN OF CUSTODY
LAKE
El INFLUENT
Other
EMERGENCY VISIT
Ej ESTUARY
COLLECTORS) : R REVELS
�
Estimated ROD Range:
Station Location: BIG JUNIPER BRANCH
lab NamMr : 4W6964
Dae Received: 11/5/200I
Time Recei ed: 9:20 AM
Received By : HMW
Data Rd scd : JC
D:rc Repored: 11/16/2004
Seed: Chlorinated: Be.,.,";
SlationN Date Begin(yy/mWdd) Date End(y)/mm]dd) Time Rcgin Tmc End Depth. DM, DII, FIRM Value Type - A, II,L Cumj.,ite-T,S, Sample Type
NH3 as N 610
Li-Lilhium 1132
TEN an N625
ME,- Magmsium 927
NO2 Plus NO3 as N 630
Mr -Man arcs, 1055
P: To1a1 as P 665
Na- Sodium 929
POI as P 70507 fj
ArscnicTotal 1002 ugJL
P: Dissnlmd as P (fih mfL
Se- Selenium 1147
K-Potassium mg/L
Hg-Mercury 7I900 ugA.
ColCadmium1027
Ba Badum
Cr-Chmmium Tolal 1033 uVL
Or .rechlo me Pc,ncidcs
Cu-Cu r 1012 WL
Or,anophosphom% Pesticides
Ni-Nickc1106]
Pb Lead 1051 uFfL
Acid Herbicides
Z.n-ZJrc 102 urJL
V-Vanadiu
Basc/Ncu ra1&Acid Estraclablc Or a
A -Silver 10]] ufJL
TPH Diesel Range
AI- Aluminum 1105
Be- Berlilium 1012
Purgcable Or ,oils (VOA boll, rt 'd)
Ca -Calcium 916 mgJL
TPH Oamline Range
Co- Cobalt 1037
TPH/BTEX Gasoline Range
Fa Iron INNS
Pbpn Iankmn
®Ea R-9 • O
NOV ��/
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REPORT TO: Aft RO RHO WaRO WIRO WSRO TS
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Other
pT
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T WATE ALITY (i�ORM (
PRIORITY /13�111j1RVSE _TYPE
❑AMBIENT ❑ QA I }'J STREAM
❑COMPLIANCE CHAIN ❑ LAKE
OF CUSTODY
Shipped by: Bus ourier/calf. Other ❑EMERGENCY
COLLECTOR(S):
STATION LOCATION:
Estimated HOD Range: 0-5/5.25/25-65/40-130 or 100 plus
Seed: Yes ❑ No ❑ Chlorinated: Yes ❑ No ❑
DM1) O
3
❑ EFFLUENT
❑ INFLUENT
For Lab Use ONLY
❑ ESTUARY
Lab Number. /
Date Recelved: STime:
Rec'd b From: Bus- ourier- land Del
DATA ENTRY BY: CK:
DATE REPORTED:
StationDnate/ /Begin (yy/mm/dd) Time Begin Date End Time End Depth DM DB DBM Value Type Composite Sample Ty e
V i Z. ir- A H L T S B C GNXX
1 RODS 310 mg/1 Chloride 940 mg/I NH3 as N 610 mgA Li -Lithium 1132 ug/1
mg/1 Chi a: Trl 32217 ug/I TKN as N 625 m
2 COD High 340 9/1 Mg-Magnedum 927 mgA
3 COD Low 335 mg/l Chi a: Corr 32209 ug/1 NO2 plus NO3 as N 630 m9A Mn-Manganese 1055 ug/l
4 Coliform: MF Fecal 31616 /loom[ Pheophytin a 32213 ug/l P: Total as P 665 mg/l Na-Sodium 929 mgA
5 Coliform: MF Total 31504 /loom[ Color: True 80 Pt -Co PO4 as P 70507 m9/1 Arsenic:Total 1002 us/]
6 Coliform: Tube Fecal 31615 /loom[ Color:(pH ) 83 ADMI P: Dissolved as P 666 mgA Se -Selenium 1147 ug/I
7 Coliform: Fecal Strep 31673 /100m1 Color. pH 7.6 82 ADMI Hg-Mernury 71900 ug/I
8 Residue: Total 500 mg/i Cyanide 720 mg/I Cd-C dmlum 1027 u,A Organochlodne Pesticides
9 Volatile 505 m9/1 Fluoride 951 mg/l CrChromium:Total 1034 ugA Ortpnoplwsplrorus Pesticides
10 Fixed 510 mg/I Formaldehyde 71880 m9/I Cu-Copper ID42 ug/I
11 Residue: Suspended 530 mg/I Grease and Oils 556 mg/I Ni-Nickel 1067 ug/l Acid Herbicides
12 Volatile 535 mg/l Hardness Total 900 mg/1 Pb-Lead 1051 ug/I
13 Fixed 540 mg/I Specific Cond. 95 uMhos/cm2 Z.-Zinc 1092 ugA Base/ Neutral Extractable Organics
14 PH 403 units MBAS 35260 mg/l Acid Extractable Organics
15 Acidity to PH 4.5 436 mg/I Phenols 32730 ug/l Ag-Silver 1077 ug/l
16 Acidity to pH 8.3 435 mg/1 Sulfate 945 mgA AI -Aluminum 1105 u g/I Pu rgeable Organics (VOA bottle re91d)
17 Alkalinity to pH 8.3 415 mg/l Sulfide 745 mg/I Be -Beryllium 1012 ug/l
18 Alkalinity to pH 4.5 410 m9/1 Ca -Calcium 916 m9/1
19 TOC 680 m9/1 Co -Cobalt 1037 ug/l
2U Turbidity 76 NTU Fe -Iron 1045 ug/I Phytoplankton
Sampling Point % Conductance at 25 C Water Temperature D.O. mgA PH Alkalinity Acidity Air Temperature (C)
pH 83 PH 4.5 PH 4.5 PH 8.3
2 94 10 300 1 400 1 82244 1 431 82243 182242 20
Salinity % Preclpition On/day) Cloud Cover % Wind Direction (Ueg) Stream Flow Severity Turbidity Severity Wind Velocity M/H can Stream Depth it Stream Width it
480 45 32 36 1351 11350_
35 64 4
DM1/Revised
OF CUSTODY
Shipped by: Bus ourier/calf. Other ❑EMERGENCY
COLLECTOR(S):
STATION LOCATION:
Estimated HOD Range: 0-5/5.25/25-65/40-130 or 100 plus
Seed: Yes ❑ No ❑ Chlorinated: Yes ❑ No ❑
DM1) O
3
❑ EFFLUENT
❑ INFLUENT
For Lab Use ONLY
❑ ESTUARY
Lab Number. /
Date Recelved: STime:
Rec'd b From: Bus- ourier- land Del
DATA ENTRY BY: CK:
DATE REPORTED:
StationDnate/ /Begin (yy/mm/dd) Time Begin Date End Time End Depth DM DB DBM Value Type Composite Sample Ty e
V i Z. ir- A H L T S B C GNXX
1 RODS 310 mg/1 Chloride 940 mg/I NH3 as N 610 mgA Li -Lithium 1132 ug/1
mg/1 Chi a: Trl 32217 ug/I TKN as N 625 m
2 COD High 340 9/1 Mg-Magnedum 927 mgA
3 COD Low 335 mg/l Chi a: Corr 32209 ug/1 NO2 plus NO3 as N 630 m9A Mn-Manganese 1055 ug/l
4 Coliform: MF Fecal 31616 /loom[ Pheophytin a 32213 ug/l P: Total as P 665 mg/l Na-Sodium 929 mgA
5 Coliform: MF Total 31504 /loom[ Color: True 80 Pt -Co PO4 as P 70507 m9/1 Arsenic:Total 1002 us/]
6 Coliform: Tube Fecal 31615 /loom[ Color:(pH ) 83 ADMI P: Dissolved as P 666 mgA Se -Selenium 1147 ug/I
7 Coliform: Fecal Strep 31673 /100m1 Color. pH 7.6 82 ADMI Hg-Mernury 71900 ug/I
8 Residue: Total 500 mg/i Cyanide 720 mg/I Cd-C dmlum 1027 u,A Organochlodne Pesticides
9 Volatile 505 m9/1 Fluoride 951 mg/l CrChromium:Total 1034 ugA Ortpnoplwsplrorus Pesticides
10 Fixed 510 mg/I Formaldehyde 71880 m9/I Cu-Copper ID42 ug/I
11 Residue: Suspended 530 mg/I Grease and Oils 556 mg/I Ni-Nickel 1067 ug/l Acid Herbicides
12 Volatile 535 mg/l Hardness Total 900 mg/1 Pb-Lead 1051 ug/I
13 Fixed 540 mg/I Specific Cond. 95 uMhos/cm2 Z.-Zinc 1092 ugA Base/ Neutral Extractable Organics
14 PH 403 units MBAS 35260 mg/l Acid Extractable Organics
15 Acidity to PH 4.5 436 mg/I Phenols 32730 ug/l Ag-Silver 1077 ug/l
16 Acidity to pH 8.3 435 mg/1 Sulfate 945 mgA AI -Aluminum 1105 u g/I Pu rgeable Organics (VOA bottle re91d)
17 Alkalinity to pH 8.3 415 mg/l Sulfide 745 mg/I Be -Beryllium 1012 ug/l
18 Alkalinity to pH 4.5 410 m9/1 Ca -Calcium 916 m9/1
19 TOC 680 m9/1 Co -Cobalt 1037 ug/l
2U Turbidity 76 NTU Fe -Iron 1045 ug/I Phytoplankton
Sampling Point % Conductance at 25 C Water Temperature D.O. mgA PH Alkalinity Acidity Air Temperature (C)
pH 83 PH 4.5 PH 4.5 PH 8.3
2 94 10 300 1 400 1 82244 1 431 82243 182242 20
Salinity % Preclpition On/day) Cloud Cover % Wind Direction (Ueg) Stream Flow Severity Turbidity Severity Wind Velocity M/H can Stream Depth it Stream Width it
480 45 32 36 1351 11350_
35 64 4
DM1/Revised
StationDnate/ /Begin (yy/mm/dd) Time Begin Date End Time End Depth DM DB DBM Value Type Composite Sample Ty e
V i Z. ir- A H L T S B C GNXX
1 RODS 310 mg/1 Chloride 940 mg/I NH3 as N 610 mgA Li -Lithium 1132 ug/1
mg/1 Chi a: Trl 32217 ug/I TKN as N 625 m
2 COD High 340 9/1 Mg-Magnedum 927 mgA
3 COD Low 335 mg/l Chi a: Corr 32209 ug/1 NO2 plus NO3 as N 630 m9A Mn-Manganese 1055 ug/l
4 Coliform: MF Fecal 31616 /loom[ Pheophytin a 32213 ug/l P: Total as P 665 mg/l Na-Sodium 929 mgA
5 Coliform: MF Total 31504 /loom[ Color: True 80 Pt -Co PO4 as P 70507 m9/1 Arsenic:Total 1002 us/]
6 Coliform: Tube Fecal 31615 /loom[ Color:(pH ) 83 ADMI P: Dissolved as P 666 mgA Se -Selenium 1147 ug/I
7 Coliform: Fecal Strep 31673 /100m1 Color. pH 7.6 82 ADMI Hg-Mernury 71900 ug/I
8 Residue: Total 500 mg/i Cyanide 720 mg/I Cd-C dmlum 1027 u,A Organochlodne Pesticides
9 Volatile 505 m9/1 Fluoride 951 mg/l CrChromium:Total 1034 ugA Ortpnoplwsplrorus Pesticides
10 Fixed 510 mg/I Formaldehyde 71880 m9/I Cu-Copper ID42 ug/I
11 Residue: Suspended 530 mg/I Grease and Oils 556 mg/I Ni-Nickel 1067 ug/l Acid Herbicides
12 Volatile 535 mg/l Hardness Total 900 mg/1 Pb-Lead 1051 ug/I
13 Fixed 540 mg/I Specific Cond. 95 uMhos/cm2 Z.-Zinc 1092 ugA Base/ Neutral Extractable Organics
14 PH 403 units MBAS 35260 mg/l Acid Extractable Organics
15 Acidity to PH 4.5 436 mg/I Phenols 32730 ug/l Ag-Silver 1077 ug/l
16 Acidity to pH 8.3 435 mg/1 Sulfate 945 mgA AI -Aluminum 1105 u g/I Pu rgeable Organics (VOA bottle re91d)
17 Alkalinity to pH 8.3 415 mg/l Sulfide 745 mg/I Be -Beryllium 1012 ug/l
18 Alkalinity to pH 4.5 410 m9/1 Ca -Calcium 916 m9/1
19 TOC 680 m9/1 Co -Cobalt 1037 ug/l
2U Turbidity 76 NTU Fe -Iron 1045 ug/I Phytoplankton
Sampling Point % Conductance at 25 C Water Temperature D.O. mgA PH Alkalinity Acidity Air Temperature (C)
pH 83 PH 4.5 PH 4.5 PH 8.3
2 94 10 300 1 400 1 82244 1 431 82243 182242 20
Salinity % Preclpition On/day) Cloud Cover % Wind Direction (Ueg) Stream Flow Severity Turbidity Severity Wind Velocity M/H can Stream Depth it Stream Width it
480 45 32 36 1351 11350_
35 64 4
DM1/Revised
Sampling Point % Conductance at 25 C Water Temperature D.O. mgA PH Alkalinity Acidity Air Temperature (C)
pH 83 PH 4.5 PH 4.5 PH 8.3
2 94 10 300 1 400 1 82244 1 431 82243 182242 20
Salinity % Preclpition On/day) Cloud Cover % Wind Direction (Ueg) Stream Flow Severity Turbidity Severity Wind Velocity M/H can Stream Depth it Stream Width it
480 45 32 36 1351 11350_
35 64 4
DM1/Revised
DM1/Revised