NCS000532_Wright Chemical Monofill 2020 Top Water Analysis Results_20200330

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 27, 2020
Bill Oakley
Oak -Bark Corporation
2214 E Wrightsville Ave
Wilmington, NC 28403
RE: Project: Water Analysis
Pace Project No.: 92470703
Dear Bill Oakley:
Enclosed are the analytical results for sample(s) received by the laboratory on March 24, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Amanda Payne
[e-mail]
[phone]
Project Manager
Enclosures
cc: One Time Client
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Water Analysis
Pace Project No.: 92470703
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Water Analysis
Pace Project No.: 92470703
Lab ID Sample ID Matrix Date Collected Date Received
92470703001 Water Analysis A-1 Water 03/23/20 11:51 03/24/20 10:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Water Analysis
92470703
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92470703001
Water Analysis A-1
EPA 200.7 Rev 4.4 1994
RDT
4
PASI-A
EPA 9040C
ECH
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
4
PASI-A
EPA 350.1 Rev 2.0 1993
KDF1
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Water Analysis
Pace Project No.: 92470703
Sample: Water Analysis A-1
Parameters
Lab ID: 92470703001 Collected:
Report
Results Units Limit
03/23/20 11:51
MDL DF
Received: 03/24/20 10:10 Matrix: Water
Prepared Analyzed CAS No. Qual
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Copper
ND ug/L 5.0
2.1
1
03/27/20 00:56
03/27/20 13:58
7440-50-8
Iron
121 ug/L 50.0
19.5
1
03/27/20 00:56
03/27/20 13:58
7439-89-6
Manganese
34.9 ug/L 5.0
0.90
1
03/27/20 00:56
03/27/20 13:58
7439-96-5
Zinc
6.2J ug/L 10.0
3.9
1
03/27/20 00:56
03/27/20 13:58
7440-66-6
9040 pH
Analytical Method: EPA 9040C
pH at 25 Degrees C
7.5 Std. Units 0.10
0.10
1
03/27/20 12:00
H3
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1
1993
Nitrate as N
0.45 mg/L 0.10
0.060
1
03/24/20 19:08
14797-55-8
Nitrate -Nitrite (as N)
0.45 mg/L 0.20
0.11
1
03/24/20 19:08
7727-37-9
Nitrite as N
ND mg/L 0.10
0.050
1
03/24/20 19:08
14797-65-0
Sulfate
4.0 mg/L 1.0
0.50
1
03/24/20 19:08
14808-79-8
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993
Nitrogen, Ammonia
4.4 mg/L 0.10
0.070
1
03/26/20 13:56
7664-41-7
531013 TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
16.6 mg/L 1.0
0.50
1
03/26/20 23:42
7440-44-0
Date: 03/27/2020 03:46 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Water Analysis
Pace Project No.: 92470703
QC Batch: 532848 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Associated Lab Samples: 92470703001
METHOD BLANK: 2844221
Matrix:
Water
Associated Lab Samples: 92470703001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Copper
ug/L
ND
5.0
2.1
03/27/2013:52
Iron
ug/L
ND
50.0
19.5
03/27/2013:52
Manganese
ug/L
ND
5.0
0.90
03/27/2013:52
Zinc
ug/L
ND
10.0
3.9
03/27/2013:52
LABORATORY CONTROL SAMPLE:
2844222
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Copper
ug/L
500
500
100
85-115
Iron
ug/L
5000
4850
97
85-115
Manganese
ug/L
500
487
97
85-115
Zinc
ug/L
500
494
99
85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2844223
2844224
MS
MSD
92470703001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Copper
ug/L
ND
500
500
552
540
110
108
70-130
2
20
Iron
ug/L
121
5000
5000
5200
5190
102
101
70-130
0
20
Manganese
ug/L
34.9
500
500
558
544
105
102
70-130
3
20
Zinc
ug/L
6.2J
500
500
545
532
108
105
70-130
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC.
Page 6 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Water Analysis
Pace Project No.: 92470703
QC Batch: 532958 Analysis Method: EPA 9040C
QC Batch Method: EPA 9040C Analysis Description: 9040 pH
Associated Lab Samples: 92470703001
SAMPLE DUPLICATE: 2844596
92470703001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
pH at 25 Degrees C Std. Units 7.5 7.6 1 9 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Water Analysis
Pace Project No.: 92470703
QC Batch: 532211 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92470703001
METHOD BLANK: 2841099
Matrix:
Water
Associated Lab Samples: 92470703001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Nitrate as N
mg/L
ND
0.10
0.060
03/24/20 18:40
Nitrate -Nitrite (as N)
mg/L
ND
0.20
0.11
03/24/20 18:40
Nitrite as N
mg/L
ND
0.10
0.050
03/24/20 18:40
Sulfate
mg/L
ND
1.0
0.50
03/24/20 18:40
LABORATORY CONTROL SAMPLE:
2841100
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/L
2.5
2.4
95
90-110
Nitrate -Nitrite (as N)
mg/L
5
4.8
96
90-110
Nitrite as N
mg/L
2.5
2.5
98
90-110
Sulfate
mg/L
50
49.3
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2841101
2841102
MS
MSD
92470703001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Nitrate as N
mg/L
0.45 2.5
2.5
3.0
3.0
102
103
90-110
1
10
Nitrate -Nitrite (as N)
mg/L
0.45 5
5
5.4
5.5
100
102
90-110
2
10
Nitrite as N
mg/L
ND 2.5
2.5
2.5
2.5
97
100
90-110
2
10
Sulfate
mg/L
4.0 50
50
53.5
53.6
99
99
90-110
0
10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Water Analysis
Pace Project No.: 92470703
QC Batch: 532598 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Associated Lab Samples: 92470703001
METHOD BLANK: 2843055 Matrix: Water
Associated Lab Samples: 92470703001
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 0.070 03/26/20 13:31
LABORATORY CONTROL SAMPLE: 2843056
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Nitrogen, Ammonia mg/L 5 5.0 101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2843057 2843058
MS MSD
92470480002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/L ND 5 5 4.8 4.8 96 96 90-110 0 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2843059 2843060
MS MSD
92470480003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Nitrogen, Ammonia mg/L 0.30 5 5 5.2 5.1 97 97 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Water Analysis
Pace Project No.: 92470703
QC Batch: 532818
Analysis Method:
SM 531 OB-2011
QC Batch Method: SM 531 OB-2011
Analysis Description:
5310E TOC
Associated Lab Samples: 92470703001
METHOD BLANK: 2844043
Matrix: Water
Associated Lab Samples: 92470703001
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Total Organic Carbon mg/L
ND 1.0
0.50 03/26/20 19:35
LABORATORY CONTROL SAMPLE: 2844044
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Total Organic Carbon mg/L
25 23.6
94
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2844045 2844046
MS MSD
92469500001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L ND
25 25 22.4
22.9
89 91 90-110 2 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2844047 2844048
MS MSD
92470276002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon mg/L 5.3 25 25 28.3 28.4 92 93 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Water Analysis
Pace Project No.: 92470703
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 03:46 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 22

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Water Analysis
Pace Project No.: 92470703
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method Batch
92470703001
Water Analysis A-1
EPA 200.7 Rev 4.4 1994
532848 EPA 200.7 Rev 4.4 1994 532868
92470703001
Water Analysis A-1
EPA 9040C
532958
92470703001
Water Analysis A-1
EPA 300.0 Rev 2.1 1993
532211
92470703001
Water Analysis A-1
EPA 350.1 Rev 2.0 1993
532598
92470703001
Water Analysis A-1
SM 5310E-2011
532818
Date: 03/27/2020 03:46 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 22

Document Name: Document Revised: February1, 2018
a Sample Condition Upon Recei t(SCUR) Page 1 of 2
Z
r?IIIa1j lCc�I Document No.: Issuing Authority:
F-CAR•CS•033-Rev.06 Pace Carolinas Quality Office
Laboratory receiving sa ies:
Asheville Eden[:]Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
Sample. , `.I Client Name: WO# : 92470703
Upon ,('' Project #
Courier: ZFed Ex ❑UPSrv� ❑USPS� ❑Client IN 11111111111
❑ Commercial []Pace ❑other: 97470703
Custody Seal Present? ❑Yes FZ(No seals Intact? ❑Yes JEfNo
Date/Initla_ls_Person ExaminingContenfs:
3, 21q 2 D
Packing Material: ' ❑Subhle Wrap Bubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermomete : Oyes ❑No ,K/A
` Type o! Ice: 2fwet ❑Blue ❑None
�IR Gun ID:
Cooler Temp (°t): Correction Factor: Add/subtract ('C} Qr
Temp should he above freezing to 6°C
Cooler Temp Corrected C): r []Simples out of temp criteria. Samples an Ice, cooling process
has begun
USDA Regulated Soil N/A, water sample}
Did samples originate In a quarantine zone within the United States: CAA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
r7L,-. 171— Including Hawaii and Puerto RICO)? []Yes [:]No
Chain of Custody Present?
Samples Arrived within Hold Time?
Short Hotd Time Analysis (c32 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Containers Used?
-Pace Containers Used?
Contalners Intact?
Dissolved analysis; Samples Field Flltered?
-Includes Date/Time/iD/Analysis
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
No ❑N/A 1.
No ❑N A
No N/A 3.
No MIA 4.
❑No QN/A I &.
Yes _[:]No ❑N/A 7•
[]Y sC24 N/A 8.
10 []Yes L` N q9e /A la.
[]Yes a N/A 11.
COMMENTS/SAMPLE DISCREPANCY Field Data Requlred? ❑Yes j�J0
A—� T AI 5dw. Oc r
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers;
pat2/TiFne�
Date:
Date:
Page 13 of 22

Document Name:
1 Document Revised: February 7, 2018
fi c?C8Ai1c?Ij/�'Cc?f
Sample Condition U an Recerpt{SOUR}
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033•Rev.06
Pace Carolinas Quality Office
*Check mark top half of box If pH and/or dechlorinstlon Is Project #
verified and within the acceptance range for preservation jO ���O�O�
samples, w 9
Exceptions: VCA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg PM: NMG Due Date: 04/02/20
"Bottom half of box is to list number of bottle CLIENT: 92—ONE TIME
P.e
v
c c
u
a a
t" E
r�
m 'L
G
U
a
S
g
U
m
a
a
in
o
S
E
ry
m
a
O
z
=
a
a
m
z-
m
a
N
U
d
CL
£
m
a
O=
z
u
a
E
`ri
m
a
fO
S
r7
.c
a
E
v_
Z
2
a
7
E
`
.a
4
y
°
2
E
'S
t
d
c
L
N
J
o
`�`
d
a
Z
l7
d
a
O
N
=
£
J
E
z
A
5
Q
.-I
h
N
m
z
A
E
t9
o
0
y
ry
m
a
O
y
z
6
a
J
f
a
?
4
KI
O
E
n
^�^
o
�;'
+,
�
O
7
2
a
d
Q
9
�
m
d
N
E
p
4
a
J
E
Ln
Di13
_
m
N
y
2
-
E
n
a
m
>
n
c
w
c
o
3>>
l7
4
N
y
c
$
p
C
E
0
z
a
J
E
0�
co
t7
1
\LNN\
1
\N
x
3
4
5
8
7
8
1Q
li
12
N=
I
N
pH Adjustment
Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
date preservatlon'adjusted
Time preservation
Amount of Preservative
Lot h
added
Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy ofthls form will hesentto the North Carollna EEHNRCertlfication Office Il,e.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 14 of 22

n
m
m
TEMP in 0
Recehred on
Cooler
YI(-N) --
Samplas
Inlacl
(YIN}
_. __ ...
W.
3
a're
Lo'3r
dl�t¢
Gn.
HI .
sJi
-
ITEM# _
3 o cn
0°
°
a _ ° >
Ck
o
a
R rn
3
t
v
ro
u
.-r
°aW
1 y
e
°a
MATRiXCOBE heevdidcodes ioten)
m
1
p
SAMPLETYPE (G-GRAB C•COMP)
s3s
v
a
SV
N
N-
h
m
h
r
O
`
�
r•
VS
�
fi
a
\
ll`117
i
SAMPLE TEMPAT COLLECTION
!..
fir..
�+'
^
.-�.
•"�
�-..
Y OF CONTAINERS
ro
ro o
"n ° �" N
unpreaerved
4
a
v r{
C
LK
H2804
HNO3
6
m
a
R
i 3
. ^ f
MCI
rD
m
O
NaOH
D
1('
NO25203
N
m
Methanol
g
ROW CA`
Z
t#315 Formaldehyd64
�]
i o
Me(ols
N
M m
NO21N031604
0
PH
s
.�•I
TOC
1 1.
i
i1,5
hq
t:i;
a
d1
1, yd
Iiiiiiiii m
Page 15 of 22

ANALYTICAL ENVIRONMENTAL SERVICES, INC.
AES
March 27, 2020
Amanda Payne
Pace Analytical Services, Inc.
9800 Kincey Ave Suite 100
Huntersville NC 28078-8400
RE: 92470703
Dear Amanda Payne: Order No: 2003P43
Analytical Environmental Services, Inc. received
for the analyses presented in following report.
samples on 3/25/2020 9:46:00 AM
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies associated with the
analyses contained herein will be noted and submitted in the form of a project Case Narrative. AES'
certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non -Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/19-06/30/20.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/20.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/20.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Jessica Shilling
Project Manager
3080 Presi4ential Drive • Atlanta, Georgia 30340 -Tel: 770.457,8177 • Fax: [phone] • Toll F.,e:800.972.4889
__x .tlanta_c
Page 16 of 22
Page 1 of 7

P. b
• u�ul
0
W
Z
g
1
,i��
�SIFN
c
O
IN
N
II;
d
Ul
"jl
Z
W
7"f4"
wN•"
a16.
rMnp
Q
W
y�.
I�Er
P
apA4apjewao3
•i�.'_
"illl
'Li1
Illy/iYiN�'
iI
��lyyyll�l �prl
t E
�r
C
Q
VIA
•Q
AMtl�
� AI
iiM t�'
i•�1
�'I
!
�i
h11
F
r1
�7e' I
ili;,,
NI
e P6N8SBJCIU("I
� rE Ir.
I11 I
Lrrl
Z\LQ�
I
"���nu.
I11
ii
i
N
1
S
1�
m
co13
r.
a �ueni..,
••
B
94ppryI "I
I i-.r M I I u�I1 lYlill
CD
O
M
'
I.I II
4f
V}
•V
jg
n 1II�
C O
I a �., ��,,'lJ'J,N IiuL'11P� A1el
jRl i
n
•_
a
�.P
n'r oohs
Ix
O tl Ipp I I�i y
+,�Ijjr! it"d
�'
j y'i
C
t
°mil
/1
y},
Q n? QI��gIII I• °"��in
FWI
it "E
1� k , II }
,, ,, j
O
N�au
P
o
�
i 14'
I;•�a N jl�g � j�
N
Uirle;
r�,iryG' ��
�„
vi r� �' P I �
I�i
•�
U i�'i`
/ ,
O
p
9[[
j urn^I
r �
cr o N
i 7 0 Ilr �P r^ PI
f6 (n O T L �i. Nrir`
1
0
N
r
��
_ � �, C. � i . Nr I N".9a
Z F- cO C. �Ilill N
aim
�.
j"
0
12
i�'
9 E
T "
N
Q
N
•a
I
�, N co
0 (a 'N r
46
D
+�
E c oo Sc) E
��il
Lu
00
Page 17
7
Q d O= (. W U) .�. ;. c
`-'
N
C'M
V
U.)
N
L
2
m
f MZ
k
d

Analytical Environmental Services, Inc
Date: 27-Mar-20
Client:
Pace Analytical Services, Inc.
Client Sample ID:
WATER ANALYSIS A-1
Project Name:
92470703
Collection Date:
3/23/2020 11:51:00 AM
Lab ID:
2003P43-001
Matrix:
Aqueous
Reporting Dilution
Analyses Result Qual Units BatcbID Date Analyzed Analyst
Limit Factor
Formaldehyde by SW8315A
Formaldehyde 430 50 ug/L 294596 1 03/26/202014:11 HL
Qualifiers: • Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated method blank
> Greater than Result value
E Estimated (value above quantiitatiion range)
S Spike Recovery outside limits due to matrix
Nan' See case narrative
F Analyzed in the lab which is a deviation from the method
< Less than Result value
J Estimated value detected below Reporting Limit
Page 18 of 22
Page 3 of 7

U)
m
W
�a
Cl)
U U
are a,�
m
v v
a a
E E
a) F
v o0
v v
O O
V U
V O
u v
J O
v a,
c0 f6
CL O.
E E
F i
N t0
a) aJ
O O
0 U
0 0
00
Y Y
a a
F F
C
Ln a)
a, a E
U U U
ry ri V Vl 6 I, o0 Ol O s4 N m R V1
ci ci ci c-I a -I c-I
vi
0
v
0
U
OZf
E
v
F
a)
V
C
C'
\
Q
H
aJ
F
�
n
E
a5
N
6
�
�
v
s
0
ai
u
v
s
3
o
T
-p
Y
C
�
c
Y
C
L
U
o
Q
N
W
�
a
❑
N
U
=p
LO
E
O v
c
m
U Q
OCCCO
O
•
V
C
f6
C
L
r.
C
O+
M
sti
E
sn
O
a
�
o
t
3
O
n•
^
U
LV
O
U
OV
CO
ON
O
L
'O
C
m
o
c
•cu
L
a
C
—
`
mc
-p
a
0
C
0
v
^
-7
3 no
Q
v
v
ba
>
'F
U
O
o
a
O
aci
N
U
Y
v o
U
•sn
'O
vs
v
y
a)
O
at0+
C
7 O
C
a1
iv
a
c
N
N
O
O
O
wE
'6
r
OV
C
C
O
O
+.
O
E C
,
7
v
7
u
N
of
_
Y
to
C
T
'O
>,
'O
�
aJ
}.. f`
O
O
a1
O
O
s0
E
'a
a
o
0
�
0.
E
C
v p.
O E
c
m
c
m
a
E
y
F
H
t
U
u
H
U .2-.
U
U
v1
a
Q
Q
Z
z
u
U
O
❑ ❑
O
C
v
C N
o >
O
-0
v
o 'aw
v
tio
L
V in 2
N
-
- O
0 O
C
O
C
❑❑
C U
O
-0 C
o
> o
C a
Cti
a -a
E
ti
a a
a a
EEEE
o 0
j
•0®
o
-
O
000000
•qO
O
•
O
•
•
•
a)
a)
T
M1•
a
�
�
C
m
�
rv,
Q/
sti
v
G.
i
N
r.
vs
^'
U
rv•
O
U
2
a)
c
c
C
OV
R
-O
V
C
al
O
w
0
p
a)
E
C
C
C
L
C
O
I
C
m
C
p
aF
s
C
O
C
Y
C
E
O
>
=
j
O
L
7
p
O.
V
a
u
0
0
al
p
On
Q
>'
Y
E
a
E
E
U
°
M
v
C
H
C
C
_
O
N
C
>
i
a
p
c
v
a
V
v
a
+�C+
E
c
c
O
ti
o.
v
'u
>
v
N
ar
C
01
OV
U
a/
H
C
O
C•
C
m
7
f0
'^
C
'^
i
C-
Y
c
v
a
a
v
E
c
a
m
$
E>
v
m
m
w
M
a
a
E
a
T
o
i
E
0
c
m
N
T
T
N
>
>_
a+
a)
o
0
0
v
3
v
v
v
cu
LLLU'
u
H
0
v
Q
w
N
'O
0
w
w
w
Y
E
U
l0 r, o0 an O c4 fV M V V1 l0 I-�
a -I c-I c-I c-I N N N N N N N N
0
0
Ln
Ln
m
a
m �
a
Q
Q 0
V
a)
0)
N
d
ul
m V
f0
C
C W
C
Y E
m O
'O U
6
p
P
O
N
M
l0
00
a -I
N
v7
c
an
c
0
0
u
u
41
C
aC..
w
N
a
a
E
E
V
u
a
s
Cs
N
m
N
CO a7
M
Y
�
W
06 W
y
y
O
—
c —
m
U
10
O
Q)
%
IN
E
O
U
t
V
N
O_
U
O_
\
Z
•
•
•
U
c
0
O
z
Q
C
m
'
o
>
m
`o
t
c
N
■
^.
U
m
�
L
U
aj
Y
a)
N
N
L
co
E
C
al
9
9
�-
C
2?
C
o
�
>
m
cn
N
m
a)
N
C
d
E
—
'O
O
U
E
(n
00
U
C
O Q
c
V
co N
v
O
N
d
m
nca
CL
E
E
Q
aj
a
v
ti
%
aJ
C
`
O_
Y
m
>. N
p,
i
N
N
c >
O 16
C
E
7
C 1,
M
`
a .q
wY
Ou
w
a
c
m
>
I
H U
2
U
Z cYi
N
WENe
a)
19 of 225

Analytical Environmental Services, Inc
Date: 27-Mar-20
Client: Pace Analytical Services, Inc.
Project Name: 92470703 Dates Report
Lab Order: 2003P43
Lab Sample ID Client Sample ID Collection Date Matrix Test Name TCLP Date Prep Date Analysis Date
2003P43-001A WATER ANALYSIS A-1 3/23/2020 11:51:OOAM Aqueous Formaldehyde by SW8315A 3/26/2020 7:50:57AM 03/26/2020
Page 20 of 22
Page 5 of 7

Analytical Environmental Services, Inc
Client:
Pace Analytical Services, Inc.
Project Name:
92470703
Workorder:
2003P43
Date: 27-Mar-20
ANALYTICAL QC SUMMARY REPORT
BatchID: 294596
Sample ID: MB-294596
Client ID:
Units: ug/L
Prep Date: 03/26/2020
Run No: 421736
SampleType: MBLK
TestCode: Formaldehyde by SW8315A
BatchID: 294596
Analysis Date: 03/26/2020
Seq No: 9540553
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Formaldehyde BRL 50
Sample ID: LCS-294596
Client ID:
Units: ug/L
Prep Date: 03/26/2020
Run No: 421736
SampleType: LCS
TestCode: Formaldehyde by SW8315A
BatchID: 294596
Analysis Date: 03/26/2020
Seq No: 9540554
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Formaldehyde 1013 50 1000 101 70 130
Sample ID: 2003P44-004AMS
Client ID:
Units: ug/L
Prep Date:
03/26/2020 Run No: 421736
SampleType: MS
TestCode: Formaldehyde by SW8315A
BatchID: 294596
Analysis Date:
03/26/2020
Seq No: 9540556
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Formaldehyde 996.3 50 1000 99.6 50.1 139
Sample ID: 2003P44-004AMSD
Client ID:
Units: ug/L
Prep Date: 03/26/2020
Run No: 421736
SampleType: MSD
TestCode: Formaldehyde by SW8315A
BatchID: 294596
Analysis Date: 03/26/2020
Seq No: 9540557
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Formaldehyde 1062 50 1000
Qualifiers: > Greater than Result value
BRL Below reporting limit
J Estimated value detected below Reporting Limit
Rpt Lim Reporting Limit
106 50.1 139 996.3 6.42 16.2
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spike Recovery outside limits due to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 21 of 22
Page 6 of 7

End of Report
Page 22 of 22
Page 7 of 7