NC0041696_Lab Data_20190507

North Caronm Division of Water Resources
Laboratory (Water Sciences Section)
Water Sample Collection & Submittal Form
i
sit ID:
(optional)
Tog
D
Cob use Onty:
Laboratory
Number
��
motion DesviPtlon:
-
L�t� Cd�Sample
s �0 1 q
Data Recdved:�-----
Watt' Matrix:
LocationTyPe:
-Lake
Ambient
Routine
Compliance
CO+C
Emfergency
QAI
I
Surface
Ground
Waste
Blank
Solution
_
Mvc/Stream
Estuary
Stonmweter
Monitodntg Well
Effluent
Reid Blank
Filter Blank
Canal �
Water Supply
Influent
Trip Blank
Lab DI Water
Other.
Tone Recelred: �f, lJ
V
DWRReglon:
an m.,ty)
OWROSfce=
oravertgrwmeJ C40
Recdved Or.
RhwBasin: i�
v
//��
Dote: r — D-O % Vt
/ I
T
Method:
State Courier
.
NotesO
Time:
Hand Delivered
Other:
Chlorinated
De -chlorinated In
Field
rap
etlrod:
Grab
Other.
mposit a
Filtered In
Field
analysis EMnr'DLS' in ch d-
ba sfurparametea
amPfe
Temperature on S � ,
Coflectors Qorrrmentr:
Field Parameters (oPUonal):
Preservative:Y
aterTemprC):
H(s.u.):
Dissolved Oxygen
(ppm)•
Conductivity
(pmhos/cm)•
Salinity
(Ppt)•
LAB COMMENTS:
.
Microbiology Parameters:
Preservetive
Wet Chemistry Parameters:
Preservative
Metals Parameters:
Preservative
is Parameters Con't:
Preservath7e
Alkalinity, as CaCO3, to pH 45/83
A
Bromide
None
Aluminum (AI)
E
Thallium (Ti)
E
BOD: Biochemical Oxygen Demand, S-day
A
Chloride
None
Antimony (Sb)
E
Tin (Sn)
E
cBOD: Carbonaceous BOD, S-day
A
Fluoride
None
Arsenic (Ps)
E
Titanium (M
E
Conform: Fecal MF
B - C- L - N
Sulfate
A
Barium (Be)
E
Vanadium (V)
E
Coliform Total MF
B - C- L- N
Chlorophyll a
Beryllium (Be)
E
Zinc (Zn)
E
Specific Conductance, at 25 °C
A
lColor ADMI
A
Cadmium (Cd)
E
Mercury 1631, low-level
TOC - Total OrganIcCarbon
A- E- F-G
Color. Platinum Cobalt
A
Calcium (Ca)
E
Boron (B)
E
Turbidity
A
COD: Chemical Oxygen Demand
A-D
Chromiltm(Cr),Total
E
Hardness, Total -Csm3-byutntbn
D-E
Other Parameters:
Cyanide, Total
A,- H - P
Cobalt (Co)
E
Organics
Parameters:
pH
None
Formaldehyde
Copper (Cu)
E
Add Harbkldes
A-C
Hexavalent Chromium (Cr6+)
A - 0
Iron (Fe)
E
Organochlorine Pesticides
A - C - K
Nutrients Parameter:
MBAS (surfactants)
A
Lead (Pb)
E
Organonitrogen Pesticides
A- C- K
Ammonia as N (NH3-N)
A - D - Z
00 and Grease, HEM, Total Recoverable
A - D - F
LJthlum (U)
E
Organophosphorus Pesticides
A - C - K
Nitrate -Nitrite as N (NO3+NO2-N)
A - D - Z
Phenols, Total Recoverable
A - D
Magnesium (Mg)
E
PCBs (polychlorinated bkphem/Ls)
A- K
Total )Qeldahl Nitrogen as N (TKN)
A - D - Z
Residue: Total (Total Sollds) '
A
Manganese (Mn)
E
Semi -Volatile Organics (BNAs)
A- C - K
Total Phosphorus as P (TP)
A - D - Z
Residue: Volatile/Fixed, Total
I A
Mercury (Hg)
E
TPH Diesel Range
A- K
Nitrite as N (NO2-N)
A
Residue: Suspended (Suspended Solids)
A
MolybdeJnum (Mo)
E
Volatile Organics (VOA)
A - C- F - S
Nitrate as N (NO3-N calculated)
A
Residue: Volatlle/Fbted, Suspended
A
Nickel (No
E
1,4-Dloxane
C
Orthophosphate as P (PO4)
A- Z
TDS -Total Dissolved Solids
A
Potassium (IQ
E
TPH Gasoline Range
A- C- F- S
Cyorm told=
Sllka
A
Selenium (Se)
E
Bioloe 1:
Mk7ocystln
Sulfide
A -J
Sliver (Ag)
E
Phytoplankton / Algae
A - R
annln & Lignin
Sodium (Na)
E
Strontium (Sr)
E
LU w y va rw..,..c �qa,.. tu,.aa ..n,�a un, y'y Lwi w �., tv/ mow, .av �, t�•7 u.weio �w2.s3va 1..��a, .a,rv. ���.. .. r�.`.�...,, 1 , .1 v� M, i , tnnw N„ , lr/ nu w Nn �y t.,/ � ��...4 w r„ v., rn/ �� ,w..,n w can �iv.u, 1�/ Vn �.T� , W7 uiw o....w.�
7 ua „w to pH to >9, (K) pH 6 9 ascorbic acid [when chlorine is present] (L) EDT- ( .) NaHSO- to pH Q (N)1596 EDTA (0) ammonium sulfate buffer pH- 9.7, (P) ascorbic add (when chorine B present], (R) Lugols, (S) NaH504 to pH Q, (Y) analyzed within 15
minutes of sample collection, (Z) filtered In field within 15 minutes
Required: 1) Collector initials and Date, 2) Uri of Utilized Preservative next to each Parameter Revision: 2MO18

AC62813 North Carolina Division of Water Resources Water Sciences Section Laboratory Results
Loc. Descr.:
Valdese Lake Rhodhiss WWTP Effluent
County:
Burke Collector:
L WIGGS
VisitlD
Region:
Asheville Report To
ARO
Location ID:
NCO041696
River Basin
CTB Collect Date:
05/07/2019
Priority
ROUTINE
Emergency
Collect Time:
10_40
Sample Matrix:
WASTEWATER
COC Yes/No
Sample Depth
Loc. Type:
EFFLUENT
Final Report
If this report is labeled preliminary report, the results have not been validated. Do not use for Regulatory purposes.
Result/ Method Analysis
CAS # Analyte Name PQL Qualifier Units Reference Date Validated by
LAB
Sample temperature at receipt by lab 2.5 °C 5/10/19 MSWIFT
Ag by ICPMS
1.0
MET
1.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Antimony by ICPMS
10
48
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
As by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Be by ICP
5.0
5.0 U
ug/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
Ca by ICP
0.10
7.4
mg/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
Cd by ICPMS
0.50
0.50 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Cobalt by ICP
50
50 U
ug/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
Cr by ICPMS
5.0
5.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Cu by ICPMS
2.0
10
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Hg 245.1
0.2
0.20 U
ug/L
EPA245.1 Rev3
5/31/19
ESTAFFORD1
Mg by ICP
0.10
3.0
mg/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
Ni by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Pb by ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Se by ICPMS
1.0
1.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Sri by ICPMS
10
10 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Thallium (TI) ICPMS
2.0
2.0 U
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
Ti (Titanium) by ICP
10
10 U
ug/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
V by ICP
10
10 U
ug/L
EPA200.7 Rev4.4
5/17/19
ESTAFFORD1
Zn by ICPMS
10
30 J2
ug/L
EPA200.8 Rev5.4
5/17/19
ESTAFFORD1
83-32-9
Acenaphthene
SEM
Semivolatile Organics (BNAs) in liquid
10 Not Detected pg/L
EPA625/8270D
5/22/19
CJOHNSON
208-96-8
Acenaphthylene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
62-53-3
Aniline
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
120-12-7
Anthracene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
56-55-3
Benzo(a)anthracene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
50-32-8
Benzo(a)pyrene
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
205-99-2
Benzo(b)fluoranthene
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
191-24-2
Benzo(g,h,i)perylene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
207-08-9
Benzo(k)fluoranthene
30
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
65-85-0
Benzoic acid
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
100-51-6
Benzyl alcohol
30
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or " U" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 1 of 4

NC DW(, Laboratory Section 12esutts/Sampte Comments/Quati fier Definitions
Sample ID: AC62813
CAS #
108-60-1
Analyte Name
Bis(2-chloro-1-methylethyl)ether
PQL
10
Result/
Qualifier
Not Detected
Units
pg/L
Method
Reference
EPA625/8270D
Analysis
Date
5/22/19
Validated by
CJOHNSON
111-91-1
Bis(2-chloroethoxy)methane
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
111-44-4
Bis(2-chloroethyl)ether
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
117-81-7
Bis(2-ethylhexyl)phthalate
30
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
101-55-3
Bromophenyl phenyl ether, 4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
85-68-7
Butylbenzyl phthalate
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
59-50-7
Chloro-3-methyl phenol, 4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
106-47-8
Chloroaniline, 4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
91-58-7
Chloronaphthalene, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
95-57-8
Chlorophenol, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
7005-72-3
Chlorophenyl phenyl ether, 4-
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
218-01-9
Chrysene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
53-70-3
Dibenzo(a,h)anthracene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
132-64-9
Dibenzofuran
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
95-50-1
Dichlorobenzene, 1,2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
541-73-1
Dichlorobenzene, 1,3
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
106-46-7
Dichlorobenzene, 1,4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
91-94-1
Dichlorobenzidine, 3,3'-
30
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
120-83-2
Dichlorophenol, 2,4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
84-66-2
Diethyl phthalate
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
131-11-3
Dimethyl phthalate
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
105-67-9
Dimethylphenol, 2,4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
84-74-2
Di-n-butyl phthalate
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
534-52-1
Dinitro-2-methyl phenol, 4,6-
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
51-28-5
Dinitrophenol, 2,4-
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
121-14-2
Dinitrotoluene, 2,4-
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
606-20-2
Dinitrotoluene, 2,6-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
117-84-0
Di-n-octyl phthalate
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
206-44-0
Fluoranthene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
86-73-7
Fluorene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
118-74-1
Hexachlorobenzene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
87-68-3
Hexachlorobutadiene(SV)
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
77-47-4
Hexachlorocyclopentadiene
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
67-72-1
Hexachloroethane
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
193-39-5
Indeno(1,2,3-cd)pyrene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
78-59-1
Isophorone
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
91-57-6
Methyl naphthalene, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
95-48-7
Methylphenol, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
106-44-5
Methylphenol, 4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
91-20-3
Naphthalene(SV)
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
88-74-4
Nitroaniline, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
99-09-2
Nitroaniline, 3-
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
100-01-6
Nitroaniline, 4-
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or " Ll" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL
Page 2 of 4

NC DW(, Laboratory Section 12esutts/Sampte Comments/Quati fier Definitions
Sample ID: AC62813
CAS #
98-95-3
Analyte Name
Nitrobenzene
PQL
10
Result/
Qualifier
Not Detected
Units
pg/L
Method
Reference
EPA625/8270D
Analysis
Date
5/22/19
Validated by
CJOHNSON
88-75-5
Nitrophenol, 2-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
100-02-7
Nitrophenol, 4-
50
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
621-64-7
N-nitrosodi-n-propylamine
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
86-30-6
N-nitrosodiphenylamine
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
87-86-5
Pentachlorophenol
30
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
85-01-8
Phenanthrene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
108-95-2
Phenol
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
129-00-0
Pyrene
20
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
120-82-1
Trichlorobenzene, 1,2,4-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
95-95-4
Trichlorophenol, 2,4,5-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
88-06-2
Trichlorophenol, 2,4,6-
10
Not Detected
pg/L
EPA625/8270D
5/22/19
CJOHNSON
Sample Comments
Met:Zn:J2,estimeted. LRB over range
WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or " Ll" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
Page 3 of 4

NC DW(, Laboratory Section 12esufts/Sampfe Comments/Quafi fier Definitions
Sample ID: AC62813
CAS # Analyte Name PQL Result/ Method Analysis
Qualifier Units Reference Date Validated by
NCDEQ-WSS-Chemistry Lab Data Qualifiers
The reported value is an average, where at least one result is qualified with a "U". The PQL is used for the qualified result(S) to call
Coliform-Countable membranes with less than 20 colonies. Reported value is estimated or is a total of the counts on all filters repor
Coliform-Counts from all filters were zero. The value reported is based on the number of colonies per 100 ml that would have been
Coliform-Countable membranes with more than 60 or 80 colonies. The value reported is calculated using the count from the smalle
Coliform-Filters have counts of both >60 or 80 and <20. Reported value is estimated or is a total of the counts on all filters reported
Coliform-Too many colonies were present; too numerous to count (TNTC). TNTC is generally defined as >150 colonies.
Col iform-Esti mated Value. Blank contamination evident.
Coliform-Many non-coliform or non-enterococcus colonies or interfering non-coliform or non-enterococcus growth present. In this cc
MPN-No wells or tubes gave a positive reaction. Value based upon the appropriate MPN Index and reported as a less than "<" valu
MPN-All wells or tubes gave positive reactions. Value based upon the MPN Index and reported as a greater than ">" value.
Total residual chlorine was present in sample upon receipt in the laboratory; value is estimated.
BOD-The dissolved oxygen (DO) depletion of the dilution water blank exceeded 0.2 mg/L.
BOD-The bacterial seed controls did not meet the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at lea
BOD-No sample dilution met the requirement of a DO depletion of at least 2.0 mg/L and/or a DO residual of at least 1.0 mg/L.
BOD-Evidence of toxicity. This is generally characterized by a significant increase in the BOD value as the sample concentration de
BOD-The glucose/ glutamic acid standard exceeded the range of 198 ± 30.5 mg/L.
BOD-The calculated seed correction exceeded the range of 0.6 to 1.0 mg/L.
BOD-Less than 1 mg/L DO remained for all dilutions set. The reported value is an estimated greater than value and is calculated foi
BOD-Oxygen usage is less than 2 mg/L for all dilutions set. The reported value is an estimated less than value and is calculated for
BOD-The DO depletion of the dilution water blank produced a negative value.
Surrogate recovery limits have been exceeded.
The reported value failed to meet the established quality control criteria for either precision or accuracy.
The sample matrix interfered with the ability to make any accurate determination.
The data is questionable because of improper laboratory or field protocols (e.g., composite sample was collected instead of grab, p
Temperature limits exceeded (samples frozen or >6°C) during transport or not verifiable (e.g., no temperature blank provided): non -
The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
This qualifier is used to identify analyte concentration exceeding the upper calibration range of the analytical instrument/method. Th
Temperature limits exceeded (samples frozen or >6°C) during storage, the data may not be accurate.
The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
Unidentified peak; estimated value.
The reported value is determined by a one -point estimation rather than against a regression equation. The estimated concentration
The calibration verification did not meet the calibration acceptance criterion for field parameters.
Sample and duplicate results are 'but of control'. The sample is non -homogenous (e.g., VOA soil). The reported value is the lower,
Presumptive evidence and estimated value. The component has been tentatively identified base on mass spectral library.
There is an indication that the analyte is present, but quality control requirements for confirmation were not met (i.e., presence of
This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
This code shall be used if the level is too low to permit accurate quantification, but the estimated concentration is less than the labo
The component has been tentatively identified based on a retention time standard.
Holding time exceeded prior to receipt by lab.
Holding time exceeded following receipt by lab.
Elevated PQL* due to matrix interference and/or sample dilution.
Not enough sample provided to prepare and/or analyze a method -required matrix spike (MS) and/or matrix spike duplicate (MSD).
Indicates that the analyte was analyzed for but not detected above the reported practical quantitation limit*. The number value repo
Sample not screened for this compound.
Sampled, but analysis lost or not performed -field error.
Sampled, but analysis lost or not performed -lab error.
Indicates the analyte was detected in both the sample and the associated method blank. Note: The value in the blank shall not be s
Elevated PQL* due to insufficient sample size.
Inability to analyze the sample.
Questions concerning data reliability.
The laboratory analysis was from an unpreserved or improperly chemically preserved sample. The data may not be accurate.
Indicates that the analyte was not detected by a screen analysis. The number value was determined by a one -point estimation at tl
WSS Chemistry Laboratory>> 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
"Not Detected" or " Ll" does not indicate the sample is analyte free but that the analyte is not detected at or above the PQL.
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