WQ0040524_Residual Annual Report 2019_20200302

Initial Review
INITIAL REVIEW
Reviewer Williams, Kendall
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application r Annual Report
what is the submittal r Residual Annual Report
type?* r Additional Information
r Other
Annual Report 2019
Year*
Date Paper Copy 3/2/2020
Received:*
Project Number* WQ0040524
Email Notifications
Does this need review by the hydrogeologist?*
r Yes r No
Regional Office
CO Reviewer
Admin Reviewer [e-mail]

Submitted Form
Project Contact Information
Rease provide information on the person to be contacted by MB Staff regarding electronic subnittal, confirmation of receipt, and other issues.
..........................................................................................................................................................................................................................................................................................................................................................................
Name * David C Coyle
Email Address*
[e-mail]
Project Information
.........................................................................................
Submittal Type* r New Permit Application
r Renewal
r Annual Report
r Other
Permit Type * r Wastewater Irrigation
r Other Wastewater
r Closed -Loop Recycle
r Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?
r Yes r Nor N/A
Permit Number* WQ0040524
Applicant\Permittee * Terra Renewal Services, Inc
Facility Name * Terra Renewal Services, Inc
Phone Number*
4797478192
r Modification (Major or Minor)
r Additional Information
r Residual Annual Report
r High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Annual report for RLAP Permit #WQ0040524 for land sites in Robeson Co administered through the Fayetteville
Regional Office. Residuals sources applied in 2019: Prestage Foods - St. Pauls, NC.
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Rans, Specifications, Calculations, Etc.)
NC WQ0040524 Terra Renewal Annual
4.71 MB
Report_2019.pdf
upload only 1 RDF docurrent. WItiple docurrents rust be corrbined into one RDF file.

For new and modification permit applications, a paper copy may be required. If you have any questions
about what is required, please contactthe reviewer or Tessa Monday. If a paper 2-pol cation is required,
be advised, applications accepted for pre -review until both the paper and elect-c-ii.- --ol:ies have been
received. The paper copy shall include the following:
o Application Form
o All relevant attachments {talcs, soils report, specs, etc.]
o One full-size engineering plan set
o One 11x17" engineering plan set
o One extra set of specifications
o Fee (if required)
Mailine address:
Division of Water Resources ! Division of Water Resources
Non -Discharge Branch I Non -Discharge Branch
1617 Mail Service Center I Att: Nathaniel Thornburg, P Floor, Office #942W
- =
Raleigh, NC 27699-1617 S12 N.5alisburySt.
For questions or problems contact Tessa Monday attessa.monday@)ncdenr.Qov or 919.707.3560.
* rJ By checking this box I acknowledge that I understand the application will not be accepted
for pre -review until the paper copy (if required) and fee (if required) have been received by
the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with
all parts of the application in correct order (as specified by the application).
Signature
Submission Date 2/28/2020

TERRA
renewal
PO BOX 399 • DARDANELLE • ARKANSAS • 72834
479.747.8192
terrarenewal.com
2019 ANNUAL REPORT
for NC Land Application Permit Number:
WQ0040524
(Class B Residuals)
Permittee / Submitted By:
Terra Renewal Services
P.O. Box 399
Dardanelle, AR 72834
Attention:
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section
Non -Discharge Permitting Unit
512 N. Salisbury Street; 6th Floor
Raleigh, NC 27604

11111111111116
TERRA
renewal
February 27, 2020
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permit Section
Non -Discharge Permitting Unit
Information Processing Unit
512 N. Salisbury Street; 61h Floor
Raleigh, NC 27699
East Region Environmental Office
P.O. Box 1746
Watkinsville, GA 30677
phone [phone]
RE: 2019 Annual Report for Land Application Permit No. W00040524
Dear Sir or Madam,
The enclosed documentation is intended to serve as the annual report for the land application of residuals
sources related to the above referenced permit in Robeson County. The following information is provided:
Permittee:
Terra Renewal Services, Inc.
P.O. Box 399
Dardanelle, AR 72834
Preparer & Contact:
David C. Coyle; Environmental Manager
P.O. Box 1746
Watkinsville, GA 30677
phone: [phone]
email: [e-mail]
terrarenewal.com
These items are included with the report (in order):
1) The Annual Land Application Certification Form (ACF)
2) The Annual Residuals Sampling Summary Form (RSSF) and Annual Residuals Sampling Summary Form
— B (RSSF-B) for each residuals source
3) The Annual Metals Field Loading Summary Form (MFLSF), Annual Land Application Field Summary
Form (FSF), and Annual Land Application Field Summary Form Supplement (FSF-SUP)
4) Lab Analyses for Residuals:
— Nutrients, Metals, TCLP, Other
— Fecal Density (Seven Set)
— Vector Attraction Reduction Data (30 Day Bench)
5) Annual Pathogen and Vector Attraction Reduction Form for NCAC 2T Rules (PVRF 2T)
6) Soil Test Reports (for fields applied in 2019)
If additional information is required or there are any questions regarding this annual report, please contact David
Coyle via the information listed above. Thank you for your cooperation and attention to this matter.
Sincerely,
David C. Coyle

Denali
wnrEIt SOLutwws
3308 Bernice Avenue
Russellville, AR 72802
479.498.5000
March 19, 2019
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permits Section
Non -Discharge Permitting Unit
512 N. Salisbury Street
Raleigh, NC 27604
RE: Letter of Delegation for Signature Authority
A�Aw
TERRA
renewal
P.O Box 399
Dardanelle, AR 72834
479.498.5000
This "Letter of Delegation" authorizes David C. Coyle, Environmental Manager, as a
representative and employee of Denali Water Solutions and Terra Renewal to produce, review,
or certify via signature any documentation associated with the following:
- Permit application, modification, and renewal
- Site & residuals source certification
- Reporting
- Permit transfer and termination
This authorization is provided under the guidelines of Rule 15A NCAC 02T .0106(b) and any
other applicable rules regarding compliance with the NC DEQ regulations.
For questions or further information regarding this matter, I may be contacted at
andym(o_)denaliwater.com or 479-668-4502.
Sincerely,
Andy McNeill
Chief Executive Officer
Denali Water Solutions

1
ANNUAL LAND APPLICATION CERTIFICATION FORM (ACF)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0040524 County:
Facility Name (as shown on permit):
Robeson
Year: 2019
Terra Renewal Services, Inc
Land Application Operator:
Terra Renewal Services, Inc Phone:
Land application of residuals as allowed by the permit occurred during the past calendar year?
21 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Suninzarv:
479-747-8192
Total number of ap2lication fields in thepermit:
6
Total number of fields utilized for land application during the year:
5
Total amount of dry tons applied during the year for all application sites:
202
Total number of acres utilizes for land application during the year:
115
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2019 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources.❑ Yes ❑ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T .I 105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
David C. Coyle; Environmental Manager
Permittee Name and Title (type or print)
e. 'L z-7 /tu
Si ature of Pcwdittee Date
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WQ0040524 Laboratory:
Terra Renewal Services, Inc
WQ0001173
WWTP Name: Prestage Foods - St. Paul WWTF
1)
2)
3)
4)
5)
American Interplex
Residual Analysis Data
Conc.
Sample or C mposite Date
Parameter
Limit
(mg/kg)
(m )a
4/1/19
Percent Solids (%)
NA
2.3
Arsenic
75
30
Cadmium
85
1.2
Copper
4,300
610
Chromium
NA
Lead
840
4
Mercury
57
0.1
Molybdenum
75
20
Nickel
420
28
Selenium
100
7
Zinc
7,500
1300
Total Phosphorus
NA
89300
TKN
NA
44000
Ammonia -Nitrogen
NA
6600
Nitrate and Nitrite
NA
30
a V—. —F ro farilitipc
flip rpilincr
r.nnr.pntr
flan limits
listed in this
form are not
annlicable.
Reference
the individual
permit
for metals
limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
e.
Signature o eparer *
Z/z -7 /ze
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
Facility Name:
Residual Source
NPDES # or WQ#:
WWTP Name:
Racirl»al S nalveie data
WQ0040524
Terra Renewal Services, Inc
WQ0001173
Prestage Foods - St. Paul WWTF
Laboratory:
1)
2)
3)
4)
5)
American Interplex
Parameter
(mg/kg)
Sample or • p• Date
Aluminum
SAR (no units)
-----------=
------------
------------
------------
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503 9(r) and 15A NCAC 2T .1102 (26)
Date
DENR FORM RSSF - B (12/2006)

3
ANNUAL METALS FIELD LOADING SUMMARY FORM (MFLSF)
ANNUAL LAND APPLICATION FIELD SUMMARY FORM (FSF)
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
SUPPLEMENT (FSF-SUPP)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 82.08
Permit #: WQ0040524 Cation Exchange Capacity (non 503 only): 3.7
Operator: Terra Renewal Services Owner: Musselwhite Fam. Trust Predominant Soil Series: Wagram
Acres Used: 33.6 Acres Permitted: 33.6 Site #: NC-RO-HK-01 Field #: NC-RO-HK-01
Rpaidlnal Analweie Dntn [i-ienvV Metnlc and Total Phosnhorus use me/kl=. % Solids use Raw Percent ft
d - d
Com-
posite
Date
®
0
Total
ho
phol
�' 11
Ann■zal l-lpnvv Metal Field 1 .narlincm 1( _alculated in lDslacre):
Total
2
-
3
-
4-
5
6 1
-
7 f
8
9
1D
�t
92
H
DT/Ac./
°
App.
14
Event
2.44
Arsenic
0.147
1 0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
1 0.147
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
2.980
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.980
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.020
0.000
0.000
0.000
0.000
0.000 1
0.000
0.000
0.000
0.000
1 0.000
0.000
0.020
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.098
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.098
den um
Nickel
0.137
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
Selenium
0.034
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Zinc
6.352
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.352
Total
Phos-
436.320
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
436.320
horus
"1 certity, under penalty of law, that tnls document was prepareu unuer my uIrcution ur 5upei-vibduu du mxol alm%.0
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature pplier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
Facility Name: Terra Renewal Services, Inc
Land Owner: Musselwhite Family Trust
Operator: Terra Renewal Services, Inc
Crop 1 Name: Bermuda Hay
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
WQ Permit #: WQ0040524 Field #: NC-RO-HK-01
Annual Dry Tons Applied: 82.0990 Site #: NC-RO-HK-01
Predominant Soil Series: Wagram
Crop 1 Max. PAN: 192 Crop 2 Name:
Acres Utilized: 33.6
Acres Permitted: 33.6
Cation Exchange Capacity (non 503): 3.7
Crop 2 Max. PAN:
° y
Q
Volume applied
(enter one) Solids/
Liquid
Cu. Yds I Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
ei
Moist)
Precip.
Past 24
ems•
inches
Y
a
c
;e
*
o•
w y
"
0
TKN
mg/kg
C z
`-_,•
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/1
316000
2.3
0.902
WQ0001173
D
0
S
0.5
0.3 1
44000
6600 1
30
26.249
NA
B.Hay
4/4
300000
2.3
0.856
W00001173
M
0
S
0.5
0.3
44000
6600
30
24.919
NA
B.Hay
4/7
240000
2.3
0.685
WQ0001173
M
0
S
0.5
0.3
44000
6600
30
19.936
NA
B.Hay
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS]
o
ss6000
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
71.104
0.000
Lime Applied
Annuallbs/acre
0.I47
0.006
2.980
0.000
0.020
0,000
0.098
0.137
0.034
6.352
436.320
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
3/19
1600
Current Cumulative lbs/ac
0.147
0.006
2.980
0.000
0.020 .
0.000
0.098
0.137
0.034
6.352
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAID Limit lstl2nd Crop
192
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
C. ��
of Land Applier
Date
*Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0040524
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Matthew King Predominant Soil Series:
57.58
6.2
Norfolk
35.9 Acres Permitted: 35.9 Site #: NC-RO-HK-02 Field #: NC-RO-HK-02
Residual Analysis Data (Heavy Metals and Total Phosphorus use mgJkg, % Solids use Raw Percent #):
6-700110
Com-
posite
Date
i
©
NEI
Q7
Total
• •
. •
�• 11
Annual Heavy Metal Field Loadings (Calculated in lbs acre):
Total
11
2111
3
4
5
6
Al
9J
10
9 t
12
H
DT/Ac./
°
App.
>v
n
Event
1.60
Arsenic
0.096
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.096
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
1.957
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.957
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.064
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
denum
Nickel
0.090
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.090
Selenium
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Zinc
4.170
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.170
Total
Phos-
286.474
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
286.47
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature pplier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Matthew King
Operator: Terra Renewal Services, Inc
Crop 1 Name: Corn (grain)
WQ Permit #: WQ0040524 Field #: NC-RO-HK-02 Acres Utilized: 35.9
Annual Dry Tons Applied: 52.9423 Site #: NC-RO-HK-02 Acres Permitted: 35.9
Cation Exchange Capacity (non 503): 6.2
Crop 2 Max. PAN:
Predominant Soil Series: Norfolk
Crop 1 Max. PAN: 131 Crop 2 Name:
" s
Q
Volume applied
(enter one) Solidsl
Liquid
Cu. Yds I Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Anirnal
Waste, etc)
Soil
Cond.
wry'
Wet,
Moist
Precip.
Past 24
Hrs.
inches
a
°
w '?
o m
a ^.
*
c
N'
* °
o'
o
y
N
*
0
TKN
mg/kg
Z
o o
I.
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
g
Application
Crop 1
FCrop 2
Crop 1
Crop 2
3/23
12000
2.3 1
0.032
W00001173
D
0
S
0.5 1
0.3
44000 1
6600
30
0.933
NA
Corn
3/24
84000
2.3
0.224
WQ0001173
D
0
S
0.5
0.3
44000
6600
30
6.530
NA
Corn
3/27
102000
2.3
0.273
WQ0001173
D
0
S
0.5
0.3
44000
6600
30
7.930
NA
Corn
3/28
240000
2.3
0.641
WQ0001173
D
0
S
0.5
0.3
44000
6600
30
18.658
NA
Corn
3/29
114000
2.3
0.305
W00001173
D
0
S
0.5
0.3
44000
6600
30
8.863
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0 000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
552000
As
Cd
Cu
Cr
Pb
H9
Mo
Ni
Se
Zn
P
42.914
0.000
Lime Applied
Annuallbs/acre
0.096
0.004
1.957
0.000
0.013
0.000
0.064
0.090
0.022
4.170
286.474
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
3/19
1600
Current Cumulative lbs/ac
0.096
0.004
1.957
0.000
0.013
0.000
0.064
0.090
0.022
4.170
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Permit PAN Limit 1sv2nd Crop
131
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
_ �' • z�i-� �� _**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
�- Signature of Land Applier Date* Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0040524
Terra Renewal Services Owner:
31.1 Acres Permitted:
Cation Exchange Capacity (non 503 only):
H. King, D. King, C. Cox Predominant Soil Series:
31.1 Site #: NC-RO-HK-03 Field #:
43.17
6.6
Norfolk
NC-RO-HK-03
Rneidlial Ansahraie Bata lNeaw Metals and Total Phosnhorus use ma/ka. % Solids use Raw Percent ft
Com-
posite
Date.
•
TotalELM
• .
�• 11
Annual l-iaaww Mvtal vioia i .narsinos ii :aseusate[l In ins/acres.
-
Total
r
1
2
3
4
5
6
7
8j
Lqj
10
# 1 j
'12
DT/Ac./
App.
Event
1.39
Arsenic
0.083
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.083
Cadmium
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.003
Copper
1.693
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.693
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
denum
Nickel
0.078
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
Selenium
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Zinc
3.609
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.609
Total
Phos-
247.897
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
247.897
horus
"1 certify, under penalty of law, tnat this document was prepareu under my turec•1011 ur 3uPGrraa•Un .0 MALUI.,a■■��
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature o an pplier
`/ /zJ
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0040524 Field #: NC-RO-HK-03
Land Owner: H. King, D. King, C. Cox Annual Dry Tons Applied: 43.1595 Site #: NC-RO-HK-03
Operator: Terra Renewal Services, Inc
Crop 1 Name: Corn (grain)
Predominant Soil Series: Norfolk
Crop 1 Max. PAN: 131 Crop 2 Name:
Acres Utilized: 31.1
Acres Permitted: 31.1
Cation Exchange Capacity (non 503): 6.6
Crop 2 Max. PAN:
0 �
Y
Q
Volume applied
(enter one) Solids/
Liquid
Cu. Yds I Gallons
%
Solids
Volume
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
e '
Moist)
Precip.
Past 24
Hrs.
inches
>
� '°
?
0 o
°
o
=
* N
Z
'e �
-
rP E.
* '
0
TKN
mg/kg
=
a a
ne c
m
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/29
84000
2.3
0.259 1
W00001173
D
0
S 1
0.5
0.3
44000
6600 1
30
7.538
NA
Corn
3/30
25800C
2.3
0.796
WQ0001173
D
0
S
0.5
0.3
44000
6600
30
23.153
NA
Corn
3/31
108000
2.3
0.333
WQ0001173
D
0
S
0.5
0.3
44000
6600
30
9.692
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS
o
450000
As
Cd
Cu
Cr
Pb
H
Mo
Ni
Se
Zn
P
40.384
0.00o
LimeApplied
Annuallbs/acre
0.083
0.003
1.693
0.000
0.011
0.000
0.056
0.078
0.019
3.609
247.897
Date
lbs/ac
Prior Years Cumulative Ibs/ac
0
0
0
0
0
0
0
0
0
0
3/19
1600
Current Cumulative Ibs/ac
0.083
0.003
1 693
0.000
0.011
0.000
0.056
0.078
0.019
3.609
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
2498
Pcnriit PAN Limit 1st12nd Crop
131
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Signature of Land Applier
Date
*Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0040524
Terra Renewal Services
4.6
Cation Exchange Capacity (non 503 only):
Owner: H. King, MB Thompson Heirs Predominant Soil Series:
Acres Permitted: 6.5 Site #: NC-RO-HK-04 Field #:
6.90
6.4
Norfolk
NC-RO-HK-04
Recirinal Annlvcis nnta lAeavv Metals and Total Phosnhorus use mc!/ke. % Solids use Raw Percent ft
F.-MM,o
Com-
posite
DateTotal
©
o
©
o
• •
. •
�' 11
Annual Hnavv Metnl H'ieid 1 andimys lCaiculated in Instacre]:
Total
2
3
-
4 f
-
5
�
7
8
9
10
11
12
y
DT/Ac./
°
App.
Event
1.50
Arsenic
0.090
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.090
Cadmium
0.004
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
1.831
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.831
Chromiu
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.060
denum
Nickel
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.084
Selenium
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Zinc
3.903
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.903
Total
Phos-
268.079
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
268.079
horus
"1 certify, under penalty of law, that this document was preparea unaer my atrection or supervision in accoruance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signs and Applier
- _/,, /t0
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc WQ Permit #: WQ0040524 Field #: NC-RO-HK-04 Acres Utilized: 4.6
Land Owner: H. King, MB Thompson Heirs Annual Dry Tons Applied: 6.9055 Site #: NC-RO-HK-04 Acres Permitted: 6.5
Operator: Terra Renewal Services, Inc Predominant Soil Series: Norfolk Cation Exchange Capacity (non 503): 6.4
Crop 1 Name: Com (grain) Crop 1 Max. PAN: 131 Crop 2 Name: Crop 2 Max. PAN:
- o
Q 0
Volume applied
(enter one) Soli&
Liquid
Cu. Yds Gallons
%
Solids
Volume I
Applied per
Acre
(Dry Tons/Ac)
Residual Sources
(NpDES #, WQ#,
An
Fert., imal
Waste, etc)
Sod
Cond.
�r1,
Wet
Moist)
Precip.
Past 24
I3rs.
inches
Y
"o
a
"
0 w
o
c
w
" r
* N
°a
7� m
?Y
�, m
* -
*
* ,-
P
TKN
mg/kg
Z Y
q '�
o
oc o
CD
a w
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
pp
Crop 1
Crop 2
Crop 1
Crop 2
4/1
72000
2.3 1
1.501
WQ0001173
D
0
S
0.5
0.3 1
44000
6600
30
43.685
NA
Corn
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
72000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
43.685
0.000
Lime Applied
Annual lbs/acre
0.090
0.004
1 831
0.000
0.012
0 000
0.060
0,084
0.021
3.903
268.079
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
3/19
2000
Current Cumulative lbs/ac
0.090
0.004
1.831
0.000
0.012
0.000
0.060
0.084
0.021
3.903
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
1 2498
Pennit PAN Limit l st/2nd Crop
k 1 131
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
*Application Method: S - Surface, IN - Injection, INC - Incorporation
a e . 2 /+-� / +-o **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 16.69
WQ0040524
Terra Renewal Services Owner:
10 Acres Permitted:
Cation Exchange Capacity (non 503 only): 5.0
Prestage Foods, luc Predominant Soil Series: Wagram
16.8 Site #: NC-RO-PK-05 Field #: NC-RO-PK-05
Rvcirinal Anol►rcis Data (Heavv Metals and Total Phosphorus use mElkm. % Solids use Raw Percent #)'
Sample
or Com-
posite
Date
_!J
4/1/19
3
4
51
6
7
8
9
t0 J
7i
12
% Solids
2.3
Arsenic
30
Cadmium
1.2
Copper
610
hromium
Lead
4
Mercury
0.1
Molyb-
denum
20
Nickel
28
Selenium
7
Zinc
1300
Total
Phos-
horus
89300
Annual Hoavv Metal Field 1.09dinvx IC Iculatetl to IDS/acre!:
Total
1
3
- 4 V
5
6
7
8
9J
10
11
12
H
DT/Ac./
°
App.
m
Event
1.67
Arsenic
0.100
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.100
Cadmium
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.004
Copper
2.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.036
hriamiu
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Mercury
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Molyb-
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
denum
Nickel
0.093
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.093
Selenium
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Zinc
4.339
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.339
Total
Phos-
298.083
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
######
horus
"I certify, under penalty of jaw, tnat tnis aocument was prepareu unuer my ulrecuorr ur Supery 15E011 ,1l 40;cvi U4111-C
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signatu p€ier Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Terra Renewal Services, Inc
Land Owner: Prestage Foods, Inc
Operator: Terra Renewal Services, Inc
Crop 1 Name: Bermuda Hay
WQ Permit#: WQ0040524
Annual Dry Tons Applied: 16.6883
Field #: NC-RO-PK-05 Acres Utilized: 10
Site #: NC-RO-PK-05 Acres Permitted: 16.8
Predominant Soil Series: Wa ram
Crop 1 Max. PAN: 192 Crop 2 Name:
Cation Exchange Capacity (non 503): 5.0
Crop 2 Max. PAN:
s~-�.
Q
Volume applied
PP
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
Applied per
PP P
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(Dry,
Moist)
preci P
past 24
HIS.
inches
a
3
F;
a o
c
7`
a, _
*
X
w
0
TKN
mg/kg
Z 3
o 3
oa o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
(lbs/acre)
Name of Crop Type
Receiving Residual
g
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/8
174000
2.3
1.669
W00001173
D
0
S
0.5
0.3
44000
6600
30
48.563
NA
B.Hay
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0 000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
0
174000
As
Cd
Cu
Cr
Pb
H2
Mo
Ni
Se
Zn P
48.563
0.00o
Lime A lied
Annual lbs/acre
0.100
0 004
2.036
0.000
0.013
0.000
0.067
0.093
0.023
4.339 298.083
0
4.339
L 2498
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.100
0.004
2.036
0.000
0.013
0.000
0.067
0.093
0.023
Permitted C. P. L. R.****
36
34
1338
N/A
267
15
N/A
374
89
Permit PAN Limit I st/2nd Crop
192
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure teat
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
0
Signature of Land Applier
Date
*Application Method: S - Surface, IN - Injection, INC - Incorporation
**Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
*** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant LoadinS Rate
DEN FORM FSF (12/2006)

4
LABORATORY ANALYSES:
- Nutrients, Metals, TCLP, Other

AMERICAN
,041 INTERPLEX
CORPORATION
LABORATORIES
Terra Renewal, LLC.
ATTN: Mr. David Coyle
15797 East State HWY 155
Dardanelle, AR 72834
April 15, 2019
Control No. 233177
Page 1 of 8
This report contains the analytical results and supporting information for the sample received on April 4, 2019. Attached
please find a copy of the Chain of Custody and/or other documents received. Note that any remaining sample will be
discarded two weeks from the original report date unless other arrangements are made.
This report is intended for the sole use of the client listed above. Assessment of the data requires access to the entire
document.
This report has been reviewed by the Chief Operating Officer or a qualified designee.
Steve Brad ord
Deputy Laboratory Director
This document has been distributed to the following:
PDF cc: Terra Renewal, LLC.
ATTN: Mr. John Pipkin
[e-mail]
Terra Renewal, LLC.
ATTN: Ms. Vanya Colburn
[e-mail]
Terra Renewal, LLC.
ATTN: Mr. David Coyle
[e-mail]
Denali Water Solutions
ATTN: Mr. Billy Staton
[e-mail]
8600 Kanis Road • Little Rock, AR 72204 www.Americanlnterplex.com Phone [phone] • FAX [phone]

iAMERICAN
INTERPLEX
CORPORATION
LABORATORIES
Terra Renewal, LLC.
15797 East State HWY 155
Dardanelle, AR 72834
SAMPLE INFORMATION
Prolect Description:
One (1) sludge sample(s) received on April 4, 2019
Prestage - St. Paul Lag
P.O. No. EVT26
Receipt Details:
A Chain of Custody was provided. The samples were delivered in one (1) ice chest.
Ice chest #1 was delivered with shipping documentation.
April 15, 2019
Control No. 233177
Page 2 of 8
Each sample container was checked for proper labeling, including date and time sampled. Sample containers were
reviewed for proper type, adequate volume, integrity, temperature, preservation, and holding times. Any exceptions are
noted below:
Sample Identification:
Laboratory ID Client Sample ID
233177-1 Prestage - St. Paul Lag 2
Notes:
1. Holding time was expired at time of receipt
Sampled Date/Time Notes
01-Apr-2019 1430 1
Qualifiers:
H Analytical holding time exceeded regulatory requirements
Q Analyte is not within quality control limits
W Result is presented on a Wet Weight Basis
X Spiking level is invalid due to the high concentration of analyte in the spiked sample
Case Narrative:
Matrix spike for batch G11325 was not performed on any sample associated with AIC Control No. 233177.
The matrix spike recovery for Polychlorinated Biphenyls failed to meet acceptance criteria due to matrix interference.
Analysis of soils/sludges are reported on a dry -weight basis unless specified.
References:
"Methods for Chemical Analysis of Water and Wastes", EPA/600/4-79-020 (Mar 1983) with updates and supplements
EPA/600/5-91-010 (Jun 1991), EPA/600/R-92-129 (Aug 1992) and EPA/600/R-93-100 (Aug 1993).
"Test Methods for Evaluating Solid Waste Physical/Chemical Methods (SW846)", Third Edition.
"Standard Methods for the Examination of Water and Wastewaters", (SM).
"American Society for Testing and Materials" (ASTM).
"Association of Analytical Chemists" (AOAC).
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AMERICAN iINTERPLEX
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LABORATORIES
Terra Renewal, LLC.
15797 East State HWY 155
Dardanelle, AR 72834
ANALYTICAL RESULTS
AIC No. 233177-1
Sample Identification: Prestage - St. Paul Lag 2 01-Apr-2019 1430
April 15, 2019
Control No. 233177
Page 3 of 8
Analyte
Result RL
Units Qualifier
Ash
34
wt %
Prep: 11-Apr-2019 1000 by 330
Analyzed: 11-Apr-2019 1100 by 330
Batch: W67784
Loss On Ignition
66
wt %
Prep: 11-Apr-2019 1000 by 330
Analyzed: 11-Apr-2019 1100 by 330
Batch: W67784
pH
7.8
Units H
EPA 9045D
Prep: 05-Apr-2019 1324 by 342
Analyzed: 10-Apr-2019 1400 by 342
Batch: W67698
Total Solids
2.3 0.01
wt %
SM 2540 G 2011
Prep: 09-Apr-2019 1123 by 330
Analyzed: 11-Apr-2019 0836 by 330
Batch: W67724
Volatile Solids
66 0.01
wt %
SM 2540 G 2011
Prep: 09-Apr-2019 1124 by 330
Analyzed: 11-Apr-2019 0836 by 330
Batch: W67724
Ammonia as N
6600 500
mg/Kg
SM 4500-NH3 B,G 2011
Prep: 09-Apr-2019 1246 by 339
Analyzed: 10-Apr-2019 1550 by 339
Batch: W67726
Total Kjeldahl Nitrogen
44000 900
mg/Kg
SM 4500-Norg D 2011
Prep: 08-Apr-2019 1453 by 339
Analyzed: 10-Apr-2019 1911 by 342
Batch: W67713
Aluminum
37000 40
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1635 by 328
Batch: S46859
Arsenic
30 5
mg/Kg
EPA 3051A, 6010D
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Cadmium
1.2 0.4
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Calcium
22000 100
mg/Kg
EPA 3051A, 6010D
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1635 by 328
Batch: S46859
Copper
610 1
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Lead
< 4 4
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Magnesium
1900 5
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Molybdenum
20 1
mg/Kg
EPA 3051A, 6010D
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Nickel
28 1
mg/Kg
EPA 3051A, 6010D
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Phosphorus
45000 1000
mg/Kg
EPA 3051A, 6010D
Prep: 09-Apr-2019 0920 by 100
Analyzed: 13-Apr-2019 0003 by 328
Batch: S46859
Potassium
3400 100
mg/Kg
EPA 3051 A. 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 12-Apr-2019 1644 by 328
Batch: S46859
Selenium < 7 7 mg/Kg
EPA 3051A, 601 OD Prep: 09-Apr-2019 0920 by 100 Analyzed: 12-Apr-2019 1644 by 328 Batch: S46859
Sodium 6400 100 mg/Kg
EPA 3051A, 601 OD Prep: 09-Apr-2019 0920 by 100 Analyzed: 12-Apr-2019 1644 by 328 Batch: S46859
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ANALYTICAL RESULTS
AIC No. 233177-1 (Continued)
Sample Identification: Prestage - St. Paul Lag 2 01-Apr-2019 1430
April 15, 2019
Control No. 233177
Page 4 of 8
Anal to
Result RL
Units
Zinc
1300 100
mg/Kg
EPA 3051A, 601 OD
Prep: 09-Apr-2019 0920 by 100
Analyzed: 13-Apr-2019 0003 by 328
Batch: S46859
Mercury
< 0.1 0.1
mg/Kg
EPA 7471B
Prep: 10-Apr-2019 1021 by 100
Analyzed: 11-Apr-2019 0930 by 313
Batch: S46867
Nitrate + Nitrite as N
< 30 30
mg/Kg
EPA 9056A
Prep: 04-Apr-2019 1654 by 07
Analyzed: 04-Apr-2019 1947 by 07
Batch: C22105
Polychlorinated Biphenyls
(PCBs) By EPA 3550C,
8082A
PCB 1016
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1221
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1232
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1242
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1248
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1254
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
PCB 1260
< 0.45 0.45
mg/Kg
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
Surrogate: Decachlorobiphenyl
(0.00-111 %)
62.7
%
EPA 3550C, 8082A
Prep: 10-Apr-2019 1527 by 338
Analyzed: 12-Apr-2019 1528 by 338
Batch: G11325
Qualifier
W
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iAMERICAN
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15797 East State HWY 155
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DUPLICATE RESULTS
Analyte
AIC No.
Result
RPD
RPD
Limit
pH
233177-1
7.8 Units
Batch: W67698
Duplicate
7.8 Units
0.128
5.00
Total Solids
233177-1
2.3 wt %
Batch: W67724
Duplicate
2.2 wt %
1.22
10.0
Volatile Solids
233177-1
66 wt %
Batch: W67724
Duplicate
65 wt %
0.819
20.0
Polychlorinated Biphenyls (PCBs)
PCB 1016
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
30.0
PCB 1221
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
30.0
PCB 1232
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
30.0
PCB 1242
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
30.0
PCB 1248
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0,010 mg/Kg
0.00
30.0
PCB 1254
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
20.0
PCB 1260
233310-3
< 0.010 mg/Kg
Batch: G11325
Duplicate
< 0.010 mg/Kg
0.00
30.0
Decachlorobiphenyl (0.00-111%)
233310-3
55.3
Batch: G11325
Duplicate
52.7 %
April 15, 2019
Control No. 233177
Page 5 of 8
Preparation Date Analysis Date Dil Qua[
05Apr19 1324 by 342 10Apr19 1400 by 342 H
05Apr19 1324 by 342 10Apr19 1400 by 342 H
09Apr19 1123 by 330 11Apr19 0836 by 330
09Apr19 1123 by 330 11 Apr19 0836 by 330
09Apr19 1124 by 330 11Apr19 0836 by 330
09Apr19 1123 by 330 11Apr19 0836 by 330
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
10Apr19 1527 by 338 12Apr19 1506 by 338
10Apr19 1529 by 338 12Apr19 1444 by 338
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Spike
Analyte
Amount
pH
-
Ammonia as N
20.0 mg/Kg
Total Kjeldahl Nitrogen
10.0 mg/Kg
Aluminum
200 mg/Kg
Arsenic
200 mg/Kg
Cadmium
200 mg/Kg
Calcium
400 mg/Kg
Copper
20.0 mg/Kg
Lead
200 mg/Kg
Magnesium
400 mg/Kg
Molybdenum
20.0 mg/Kg
Nickel
20.0 mg/Kg
Phosphorus
200 mg/Kg
Potassium
400 mg/Kg
Selenium
200 mg/Kg
Sodium
400 mg/Kg
Zinc
20.0 mg/Kg
Mercury
1.25 mg/Kg
Nitrate + Nitrite as N
100 mg/Kg
LABORATORY CONTROL SAMPLE RESULTS
% Limits RPD
101 98.0-102
106 80.0-120
109 80.0-120
105 85.0-115
105 85,0-115
102 85.0-115
106 85.0-115
98.6 85.0-115
101 85.0-115
108 85.0-115
103 85.0-115
102 85,0-115
105 85.0-115
94.9 85.0-115
104 85.0-115
96.1 85.0-115
102 85.0-115
88.7 85.0-115
100 90.0-110
Polychlorinated Biphenyls (PCBs)
PCB 1016 0.0500 mg/Kg 69.4
PCB 1260 0.0500 mg/Kg 74.9
Polychlorinated Biphenyls (PCBs) Surrogates:
Decachlorobiphenyl 50.0 ug/Kg 88.7
40.0-140
60.0-130
49.4-107
April 15, 2019
Control No. 233177
Page 6 of 8
Limit Batch Preparation Date Analysis Date Dil Qual
W67698 05Apr1 9 1324 by 14= fOApr19 1100 by 34
W67726 09Apr19 1246 by 339 10Apr19 1542 by 339
W67713 08Apr19 1454 by 339 11Apr19 0816 by 342
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46859 09Apr19 0921 by 100 12Apr19 1536 by 328
S46867 10Apr19 1021 by 100 11Apr19 0923 by 313
C22105 04Apr19 1654 by 07 04Apr19 1836 by 07
G11325 10Apr19 1529 by 338 12Apr19 1400 by 338
G 1 1325 10Apr19 1529 by 338 12Apr19 1400 by 338
G11325 10Apr19 1529 by 338 12Apr19 1400 by 338
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MATRIX SPIKE SAMPLE RESUL
April 15, 2019
Control No. 233177
Page 7 of 8
Spike
Analyte
Sample Amount
%
Limits
Batch
Preparation Date
Analysis Date Dil
Ammonia as N
233217-1 99.3 mg/Kg
81.1
80.0-120
W67726
NApr19 1246 by 339
10Apr113 1812 by 339
233217-1 101 mg/Kg
117
80.0-120
W67726
09Apr19 1246 by 339
10Apr19 1639 by 339
Relative Percent Difference:
16.6
25.0
W67726
Total Kjeldahl Nitrogen
233217-1 100 mg/Kg
-
80.0-120
W67713
08Aprl9 1454 by 339
10Aprl9 1905 by 342
233217-1 101 mg/Kg
-
80.0-120
W67713
08Apr19 1454 by 339
1oApr19 1907 by 342
Relative Percent Difference:
18.5
20.0
W67713
Aluminum
233168-1 200 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1609 by 328
233168-1 199 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1618 by 328
Relative Percent Difference:
0.723
20.0
S46859
Arsenic
233168-1 200 mg/Kg
121
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 199 mg/Kg
110
75.0-125
S46859
09Apr19 0921 by 100
12Aprl9 1555 by 328
Relative Percent Difference:
9.47
20.0
S46859
Cadmium
233168-1 200 mg/Kg
111
75.0-125
S46859
09Apr19 0921 by 100
12Aprl9 1545 by 328
233168-1 199 mg/Kg
101
75.0-125
S46859
09Aprl9 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
9.23
20.0
S46859
Calcium
233168-1 399 mg/Kg
-
75.0-125
S46859
09Aprl9 0921 by 100
12Aprl9 1609 by 328
233168-1 398 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1618 by 328
Relative Percent Difference:
0.138
20.0
S46859
Copper
233168-1 20.0 mg/Kg
75.8
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 19.9 mg/Kg
75.3
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
0.174
20.0
S46859
Lead
233168-1 200 mg/Kg
109
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 199 mg/Kg
101
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
7.57
20.0
S46859
Magnesium
233168-1 399 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 398 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
1.43
20.0
S46859
Molybdenum
233168-1 20.0 mg/Kg
113
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 19.9 mg/Kg
107
75.0-125
S46859
09Aprl9 0921 by 100
12Aprl9 1555 by 328
Relative Percent Difference:
5.54
20.0
S46859
Nickel
233168-1 20.0 mg/Kg
106
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 19.9 mg/Kg
98.5
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
5.34
20.0
S46859
Phosphorus
233168-1 200 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1609 by 328
233168-1 199 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1618 by 328
Relative Percent Difference:
0.564
20.0
S46859
Potassium
233168-1 399 mg/Kg
81.0
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 398 mg/Kg
82.8
75.0-125
S46859
09Aprl9 0921 by 100
12Aprl9 1555 by 328
Relative Percent Difference:
0.567
20.0
S46859
Selenium
233168-1 200 mg1Kg
114
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1545 by 328
233168-1 199 mg/Kg
102
75.0-125
S46859
09Aprl9 0921 by 100
12Aprl9 1555 by 328
Relative Percent Difference:
11.0
20.0
S46859
Sodium
233168-1 399 mg/Kg
108
75.0-125
S46859
09Apr19 0921 by 100
12Aprl9 1545 by 328
233168-1 398 mg/Kg
104
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
2.70
20.0
S46859
Zinc
233168-1 20.0 mg/Kg
-
75.0-125
S46859
09Aprl9 0921 by 100
12Aprl9 1545 by 328
233168-1 19.9 mg/Kg
-
75.0-125
S46859
09Apr19 0921 by 100
12Apr19 1555 by 328
Relative Percent Difference:
2.78
20.0
S46859
Mercury
233168-1 2.49 mg/Kg
95.6
75.0-125
S46867
10Apr19 1021 by 100
11Apr19 0924 by 313
233168-1 2.50 mg/Kg
96.7
75.0-125
S46867
10Apr19 1021 by 100
11Apr19 0926 by 313
Relative Percent Difference:
1.18
20.0
S46867
Qual
x
x
x
x
x
x
x
x
x
x
x
x
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15797 East State HWY 155
Dardanelle, AR 72834
MATRIX SPIKE SAMPLE RESULTS
April 15, 2019
Control No. 233177
Page 8 of 8
Spike
Analyte Sample
Amount
%
Limits
Batch
Preparation Date
Analysis Date Dil Qual
Nilrate + Nitrilfl as N 233177 1
98.0 mg/Kg
99.8
80.0-120
C22105
04Aprl9 1654 by 07
04Apr1 190 by 07
233177-1
97.9 mg/Kg
99.9
80.0-120
C22105
04Apr19 1654 by 07
04Apr19 1924 by 07
Relative Percent
Difference:
0.110
10.0
C22105
Polychlorinated Biphenyls (PCBs)
PCB 1016 233310-3
0.06 mg/K9
265
40.0-140
G11325
10Apr19 1529 by 338
12Apr19 1422 by 338 Q
PCB 1260 233310-3
0.05 mg/K9
51.7
60.0-130
G11325
10Apr19 1529 by 338
12Apr19 1422 by 338 Q
Polychlorinated Biphenyls (PCBs) Surrogates:
Decachlorobiphenyl 233310-3
50 ug/Kg
63.2
0.00-111
G11325
10Aprl9 1529 by 338
12Apr19 1422 by 338
LABORATORY BLANK RESULTS
Qc
Analyte
Result
RL
LOQ
Sample
Preparation Date
Analysis Date Qual
Total Solids
< 0.01 wt %
0.01
0.01
W67724-1
09Apr19 1123 by 330
1 lApr19 by =3
Volatile Solids
< 0.01 wt %
0.01
0.01
W67724-1
09Apr19 1123 by 330
11Apr19 0836 by 330
Ammonia as N
< 5 mg/Kg
5
10
W67726-1
09Apr19 1246 by 339
1OApr19 1540 by 339
Total Kjeldahl Nitrogen
< 5 mg/Kg
5
10
W67713-1
08Apr19 1454 by 339
11Apr19 0814 by 342
Aluminum
< 2 mg/Kg
2
4
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Arsenic
< 3 mg/Kg
3
5
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Cadmium
< 0.2 mg/Kg
0.2
0.4
S46859-1
09Apr19 0921 by 100
12Aprl9 1528 by 328
Calcium
< 5 mg/Kg
5
10
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Copper
< 0.5 mg/Kg
0.5
1
546859-1
09Aprl9 0921 by 100
12Apr19 1528 by 328
Lead
< 2 mg/Kg
2
4
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Magnesium
< 3 mg/Kg
3
5
S46859-1
09Apr19 0921 by 100
12Aprl9 1528 by 328
Molybdenum
< 0.5 mg/Kg
0.5
1
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Nickel
< 0.5 mg/Kg
0.5
1
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Phosphorus
< 5 mg/Kg
5
10
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Potassium
< 50 mg/Kg
50
100
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Selenium
< 4 mg/Kg
4
7
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Sodium
< 50 mg/Kg
50
100
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Zinc
< 0.5 mg/Kg
0.5
1
S46859-1
09Apr19 0921 by 100
12Apr19 1528 by 328
Mercury
< 0.05 mg/Kg
0.05
0.1
S46867-1
10Apr19 1021 by 100
11Aprl9 0921 by 313
Nitrate + Nitrite as N
< 0.03 mg/Kg
0.03
0.5
C22105-1
04Apr19 1654 by 07
04Apr19 1812 by 07
Polychlorinated Biphenyls (PCBs)
PCB 1016
< 0.010 mg/Kg
0.010
0.010
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
PCB 1221
< 0.010 mg/Kg
0.010
0.010
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
PCB 1232
< 0.010 mg/Kg
0.010
0.010
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
PCB 1242
< 0.010 mg/Kg
0.010
0.010
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
PCB 1248
< 0.010 mg/Kg
0.010
0.010
G11325-1
10Aprl9 1529 by 338
12Apr19 1337 by 338
PCB 1254
< 0.010 mg/Kg
0.010
0,010
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
PCB 1260
< 0.0 i0 mg/Kg
0.010
0.01.0
G113P5_1
10Apr19 1529 by 338
12Apr19 1337 by 338
Polychlorinated Biphenyls (PCBs) Surrogates:
Decachlorobiphenyl (49.4-107%)
74.8 %
G11325-1
10Apr19 1529 by 338
12Apr19 1337 by 338
8600 Kanis Road • Little Rock, AR 72204 www.Americanlnterplex.com Phone [phone] • FAX [phone]

N.
AMERICAN
INTERPL.EX
LABORATORIES
CHAIN OF CUSTODY / ANALYSIS REQUEST FORM
8600 Kanis Road
Little Rods AR 72204-2322
(501) 224-SM
FAX [phone]
PAGE 1- OF x-
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ANALYSES
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G = Glass P = Plastic V o VOA vials H = HCI to pH2 T = Sodium Thiosuffate
NO = none S = Sufiuric acid PH2 N = Nitric acid H2 B = NaOH to pH12 Z = Zinc acetate
JTurrniapjmjLndd Tirme Requested: (Please circle)
OR EXPEDITED IN DAYS
resub requested by:
o should AIC contact with questions:
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eport Attention tc:_
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Comments:
5101 _ FORM 0050

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THE SMIFl4NO COMPANY THAT WOM FOR YNq!
Pam told or oa In half
Pmt ■1 1 W% eize eod do NOT p wWaDpp. U*M S Willa Vy wM 66W IM 00y d Paw PKUP nd may nm* In 3"dor M ftpky dupe.
ONISHIPPERS'
THE SMPPWP COMPANY THAI WORKS FOR 1w
Thank you fbr shipping with Unishippers.
UPS standard terms and conditions apply.
Rate Estimate: 90.60 USD
Protection: 100.00 USD
Weight (lbs):
12
Dimensions:
0x0x0
Ship Ref:
LAG
Service Level:
UPS Next Day Air®
Special Svc:
Shipment Date: 2019-04-03
Bill Shipment To: Bill My Account
Bill To Acct: E19925
Description:
RECEIPT
Waybill a#:1ZE199250192270459
To (Company):
AMERICAN INTERPLEX
8600 KANIS RD.
LITTLE ROCK, AR, 72204
UNITED STATES
Attention To:
SAMPLE RECEIVING
501-224-5060
Sent By:
David Coyle
479-747-8192

April 10, 2019
David Coyle
Terra Renewal Services
P.O. Box 399
Dardanelle AR 72834
RE: Prestage-St. Paul LAG
Dear David Coyle:
ANALYTICAL ENVIRONMENTAL SERVICES, INC.
Order No: 1903T56
Analytical Environmental Services, Inc. received 1 samples on 3/29/2019 7:40:00 AM
for the analyses presented in following report.
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies associated with the
analyses contained herein will be noted and submitted in the form of a project Case Narrative. AES'
certifications are as follows:
-NELAP/Florida State Laboratory ID E87582 for analysis of Non -Potable Water, Solid & Chemical Materials,
Air & Emissions for Organics, and Drinking Water Microbiology & Metals, effective 07/01/18-06/30/19.
-North Carolina Certification number 562 for analysis of Surface Water, Groundwater, Effluent, effective until
12/31/19.
-South Carolina Environmental Laboratory Certification number 98016003 effective until 6/30/19.
These results relate only to the items tested as received. This report may only be reproduced in full and with
written permission from the laboratory.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Chris Pafford
Project Manager
/t�iilt 1�1-1'-3EI �'llt t.11 lac nre -A Llaiita, Gi o, 4ia 30340 - Tel; 77()) 457.81f7 - Fax: .! 70_4y7.B 188 • Ttill F,Yc •: 800.972.4889
we•w.wt< adantaxon,
Page 1 of 24

ANALYTICAL ENVIRONMENTAL SERVICES, INC.
3080 Presidential Drive Atlanta, GA 3D340-3704
AES Phone: [phone] / Toll -Free: [phone] / Fax: (770) 4S7-8188
T1t2A ���EwA�
PHONE:
SAMPLED BY: �/�i
A., I JD a•(a_t'
tJ SAMPLE ID
1 �ErtAr+E- kQw�a (,/►` TCIP
2
3
4
5
6
7
8
9
10
11
12
13
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REI INQUISHED BY: //�� DATE/TIME:
'Cl to &'r l4 Soo
CHAIN OF CUSTODY
JAILCA.aGc�G� An-
�2diti r
EMAIL:
SIGNATU Q'
F xZZ1�
DATE TIME o g a
V
ANALYSIS REQUESTED
PRESERVATION (see codes)
Work Order:
Date: r t Page of
Visit our website
www.aesatianta.com for
downloadable COCs and to
log in to your AESAccess
account.
in
`o
`w
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REMARKS
RECEIVED BY: DATE/TIME: PROJECT INFORMATION RECEIPT
PROJECT NAME:
.'j "o �a Total N of Containers
PROJECT #: Turnaround Time (TAT) Request
2. 2.
SITE ADDRESS: p Standard
3. 3 tj L ❑ 2 Business Day Rush
SEND REPORT TO: �- / ❑ Next Business Day Rush
-
SPECIAL INSTRUCTIONS/COMMENTS: SHIPMENT METHOD i t t ,A r of {�lS� ❑ Same -Day Rush (auth req.)
OUT: / / VIA: INVOICE TO (IF DIFFERENT FROM ABOVE): Other
IN: / / VIA: /. // ///� //'� ��11TATE
f`Ot4rA" �A,✓YA V6.�iT�f v'E-mail?GRAMCfana
client Fed Ex uP5 US mail courier -mail? ❑ Fax? ❑
other: QUOTE K: POA: DATA PACKAGE: 1 OII 0111 OIV O
Submission of samples to the laboratory constitutes acceptance of AES's Terms & Conditions. Client assumes sole responsibility for damage or loss of samples before we accept them. Samples received after 3PM or on Saturday are considered as received the following
business day. If no TAT is marked on COC, AES will proceed with standard TAT. Samples are disposed of 30 days after completion of report unless other arrangements are made.
- . -... - - - 7.11.18_Co
Preservative Codes: H+I = Hydrochloric acid + ice I = Ice only N = Nitric acid S+I = Sulfuric acid + ice S/M+I = Sodium RisulfateJMethancl +ice O = Other (specify) NA = None White Copy - Original: Yellow Copy - Client
Page 2 of 24

I qa5717-6-- �
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North Carolina Permit Parameters
Residuals shall be analyzed to demonstrate they are - source Conservation
and Recovery Act (RCRA). The an cs corrosivity, ignitability, ireactivi and toxicity
characteristic leaching procedure TCLP slia requency specified in
Attachment A, and the Pcrmittcc shall maintain these results for a minimum of five years_ Any
exceptions from the requirements in this. condition shall be specified in Attachment A.
The TCLP analysis shall include the following parameters (the regulatory level in milligrams per liter
is in parentheses):
Arsenic (5.0)
1,4-Dichlorobenzene (7.5)
Nitrobenzene (2.0)
Barium (100.0)
1,2-Dichloroethane (0.5)
Pentachlorophenol (100.0)
Benzene (0.5)
1,1-Dichloroethylene (0.7)
Pyridine (5.0)
Cadmium (1.0)
2,4-Dinitrotoluene (0.13)
Selenium (1.0)
Carbon tetrachloride (0.5)
Endrin (0.02)
Silver (5.0)
Chlordane (0.03)
Hexachlorobenzene (0.13)
Tetrachloroethylene (0.7)
Chlorobenzene (100.0)
Heptachlor (and its hydroxide)
(0.008)
Toxaphene (0.5)
Chloroform (6.0)
Hexachloro-1,3-butadiene (0.5)
Trichloroethylene (0.5)
Chromium (5.0)
Hexachloroethane (3.0)
2,4,5-Trichlorophenol (400.0)
m-Cresol (200.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
o-Cresol (200.0)
Lindane (0.4)
2,4,5-TP (Silvex) (1.0)
p-Cresol (200.0)
Mercury (0.2)
Vinyl chloride (0.2)
Cresol (200.0)
Methoxychlor (10.0)
2,4-D 10.0
Methyl ethyl ketone 00.0) _
__
3. An analysis shall be conducted on residuals from each source generating facility at the frequency
specified in Attachment A, and the Permittee shall maintain the results for a minimum of five years.
The analysis shall include the following parameters:
men •l��eeeery �i
n 'Iwtal� �ehnritnxr
�i�rt en
Gem IQ
��esei �1'iit7!ftteSTns wBleNa-SQWs
�neei�n Pt°3B'�
TERRA RENEWAL SERVICES
479-747-8192
AvAcNienrwr To CoC. i2r Pt";yA`C S. Pit-t.
3 /2v-/(9
WQ0036936 Version 1.0 Shell Version 140210
LAG -FCL.e
Page 8 of 12
Page 3 of 24

Analytical Environmental Services, Inc
Date: 10-Apr-19
Client: Terra Renewal Services
Project: Prestage-St. Paul LAC Case Narrative
Lab ID: 1903T56
pH Analysis by Method SW9045D:
Samples for pH analysis by Method SW9045D were received and analyzed outside holding time requirement of "immediate or
15 minutes."
Page 4 of 24

Analytical Environmental Services, Inc
Date: 10-Apr-19
Client:
Tema Renewal Services
Client Sample ID:
Prestage-St. Paul LAG TCLP
Project Name:
Prestage-St. Paul LAG
Collection Date:
3/28/2019 2:30:00 PM
Lab ID:
1903T56-001
Matrix:
Sludge
Reporting Dilution
Analyses Result Qual Units BatchlD Date Analyzed Analyst
Limit Factor
VOLATILES, TCLP SW1311/8260D (SW5030B)
1,1-Dichloroethene
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
1,2-Dichloroethane
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
2-Butanone
BRL
0.20
mg/L
276891
20
04/03/2019 18:53
BK
Benzene
BRL
0.10
Ing/L
276981
20
04/03/2019 18:53
BK
Carbon tetrachloride
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
Chlorobenzene
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
Chloroform
BRL
0.10
mg/L
276881
20
04/03/201918:53
BK
Tetrachloroelhene
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
Trichloroethene
BRL
0.10
mg/L
276881
20
04/03/2019 18:53
BK
Vinyl chloride
BRL
0.040
mg/L
276981
20
04/03/2019 18:53
BK
Surr:4-Brorrofluorobeuzene
95
63.1-120
%REC
276881
20
04/03/2019 18:53
BK
Surr: Dibromofluoromethane
94
76.1-126
%REC
276881
20
04/03/2019 18:53
BK
Surr: Toluene-d8
97.2
753-119
%REC
276881
20
04/03/2019 18:53
BK
Sulfide, Reactive SW846-7.3
(SW7.3.4.2)
Sulfide, Reactive
BRL
100
mgfKg
277091
1
04/03/2019 19:00
CG
SEMIVOLATILES ORGANICS, TCLP
SW1311/8270E
(SW3510C)
1,4-Dichlorobenzene
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
2,4,5-Trichlorophenol
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
2,4,6-Trichloroplienol
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
2,4-Dinitrotoluene
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Hexachlorobenzene
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Hex achlorobutadiene
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Hexachloroethane
BRL
0.10
mg[L
276989
1
04/05/2019 19:14
YH
m,p-Cresol
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Nitrobenzene
BRL
0.10
mg/L
276989
t
04/05/2019 19:14
YH
o-Cresol
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Pentachlorophenol
BRL
0.50
mgfL
276989
[
04/05/2019 19:14
YH
Pyridine
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Cresols. Total
BRL
0.10
mg/L
276989
1
04/05/2019 19:14
YH
Surr:2,4,6-Tribromophenol
80
49.6-128
%REC
276989
I
041051201919:14
YH
Surr:2-Fluorobiphenyl
83
52.2-124
%REC
276989
1
04/05/2019 19:14
YH
Surr:2-Fluorophenol
82
44-129
%REC
276989
1
04/05/2019 19:14
YH
Surr:4-Terphenyl-d14
89.9
63.2-145
%REC
276989
1
04/05/2019 19:14
YH
Surr: Nitrobenzene-d5
93.8
53.6-124
%REC
276989
l
04/05/2019 19:14
YH
Surr: Phenol-d5
81.8
50.6-125
%REC
276989
1
04/05/2019 19:14
YH
PESTICIDES, TCLP SW1311/8081B
(SW3510C)
Chlordane
BRL
0.0050
mg/L
277081
1
04/05/201918:20
UH
Endrin
BRL
0.0010
mg/L
277091
1
04/05/201918:20
UH
Qualifiers: " Value exceeds maximum contaminant level E Estimated (value above quamitation range)
BRL Below reporting limit S Spike Recovery outside limits due to matrix
H Holding times for preparation or analysis excceded Narr See case narrative
N Analyle not NELAC certified NC Not continued
B Analyze detected in the associated melhod blank < Less Than Result value
> (.realer than Result value .I Fstimated value detected below Reporting Limit
Page 5 of 24

Analytical Environmental Services, Inc
Date: 10-Apr-19
Client:
Terra Renewal Services
Client Sample ID:
Prestage-St. Paul LAG TCLP
Project Name:
Prestage-St. Paul LAG
Collection Date:
3/28/2019 2:30:00 PM
Lab ID:
1903T56-001
Matrix:
Sludge
Reporting imunon
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
PESTICIDES, TCLP SW1311/8081B
gamma-BHC
Heptachlor
Heptachlor epoxide
Methoxycblor
Toxaphene
Surr: Decachlorobiphenyl
Surr: Tetrachloro-m-xylene
MERCURY, TCLP SW 1311/7470A
Mercury
Laboratory Hydrogen Ion (pH) SW9045D
pH
Ignitability SW1010A
ignitability
ICP METALS, TCLP SW1311/6010D
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
HERBICIDES, TCLP SW1311/8151A
2,4,5-TP (Silvex)
2,4-D
Surr: DCAA
Cyanide, Reactive SW846-7.3
Cyanide, Reactive
Qualifiers: a Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Arn lyte not NELAC certified
73 Analyle detected in the associated method blank
> Greater than Result value
BRL
0.00050
BRL
0.00050
BRL
0,00050
BRL
0.0050
BRL
0.050
79.6
47.7-136
66.6
44.7-126
BRL 0,00400
7.42 0.01
180
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
BRL
74.4
BRL
(SW3510C)
mg/L
277081 1
04/05/201919:20
UH
mg/L
277081 1
04/05/201918:20
UH
mg/L
277081 1
04/05/201918:20
UH
ing/L
277081 1
04/05/201918:20
UH
mg/L
277081 1
04/05/201918:20
UH
%REC
277081 1
04/05/201918:20
UH
%REC
277081 1
04/05/201918:20
UH
(SW7470A)
mg/L 277126 1 04/08/2019 22:18 CD
(SW9045D)
H pH Units 276663 1 03/29/2019 08:00 BK
0
> T R395348
1 04/09/2019 00:00
SK
(SW3010A)
0.250
mg/L 277063
1 04/05/201915:48
AJ
0.500
mg/L 277063
1 04/05/201915:48
AJ
0.0250
mg/L 277063
1 04/05/201915:48
AJ
0.0500
mg/L 277063
l 04/05/201915:48
AJ
0.0500
mg/L 277063
1 04/05/201915:49
AJ
0.100
mg/L 277063
1 04/05/201915:48
AJ
0.0250
mg/L 277063
1 04/05/201915:48
AJ
(SW3510C)
0.20
ing/l- 276993
l 04/08/201910:36
BB
0.20
mg/L 276993
l 04/08/201910:36
HB
49.4420
%REC 276993
1 04/08/201910:36
HB
(SW7.3.3.2)
0.962 ing/Kg 277187 1 04/08/201915:30 AT
E Estimated (value above quamitation range)
S Spike Recovery outside limits due to matrix
Nttrr spa m'K nairpltvr
NC Not confirmed
< Less [ban Result value
1 Estimated value detected below Reporting Limit
Page 6 of 24

�Axnil.mcAL
Eiv►>zaoxAt�n�rAt.
AES Sl nvtcss, INC.
1. client Name: Terra Renewal Services, Inc.
2. Carrier: FedEx ❑ UPS USPS❑ Client❑ Courier❑ Othei
3.
4.
5.
6.
7.
8.
9.
10.
11,
12.
SAMPLE/COOLER RECEIPT CHECKLIST
Yes No N/A
AES Work Order Number: 1903T56
Details
Clear Save as
Comments
Shipping container/cooler received in good condition?
no
damaged ❑ leaking ❑ other❑
Custody seals present on shipping container?
Custody seals intact on shipping container?
01
•
Temperature blanks present?
•
Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for
temperature recordings.]
®
©
Cooling initiated for recently collected samples / ice
present ❑
Chain of Custody (COC) present?
•
Chain of Custody signed, dated, and timed when relinquished and received?
•
Sampler name and/or signature on COC?
•
Were all samples received within holding time?
•
TAT marked on the COC?
•
If no TAT indicated, proceeded with standard TAT per Terms &Conditions. U
13. Cooler 1 Temperature 3.9 °C Cooler 2 Temperature
14. Cooler 5 Temperature °C Cooler 6 Temperature
15. Comments:
16.
17.
18.
19.
20.
21,
22.
23,
24.
25.
26.
°C Cooler 3 Temperature °C Cooler 4 Temperature °C
°C Cooler 7 Temperature °C Cooler 8 Temperature °C
I certify that I have completed sections 1-15 (dated initials). TD 03/29/19
Yes No N/A Details Comments
Were sample containers intact upon receipt?
•010
Custody seals present on sample containers?
•
Custody seals intact on sample containers?
•
Do sample container labels match the COC?
G
®
O
incomplete info ❑ illegible ❑
no label other ❑
Are analyses requested indicated on the COC?
•
Were all of the samples listed on the COC received.7
©
©
samples received but not listed on COC ❑
samples listed on COC not received ❑
Was the sample collection date/time noted?
•
Did we receive sufficient sample volume for indicated analyses?
•
received in appropriate containers?
•OA
tWeremples
samples received without headspace (< 1/4" bubble)?ip
blanks submitted?
•
listed on COC ❑ not listed on COC ❑
27. Comments:
This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). EW 3/29/19
checked at Sample Receipt. Yes No N/A Details Comments
28. Have containers needing chemical preservation been checked? 0 1 U 1•
29, Containers meet preservation guidelines? 0 101 •
30. Was pH adjusted at Sample Receipt? Q 101 •
Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. Ew 3/z9/19
I certify that I have completed sections 28-30 (dated initials).
Checklist 6 9.17 Rev 2
Locked
Page 7 of 24

Analytical Environmental Services, Inc Date: 10-Apr-19
Client: 'Terra Renewal Services
Project Name: Prestage-St. Paul LAG Dates Report
Lab Order: 1903T56
Lab Sample ID
Client Sample ID
Collection Date
Matrix
Test Name
TCLP Date
Prep Date
Analysis Date
1903T56-001A
Prestage-St. Paul LAG TCLP
3/2812019
2:30:OOPM
Sludge
VOLATILES, TCLP Leached
04102/2019
4/212019 1:09:OOPM
04/0312019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
IGNITABILITY
04/09/2019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
TCLP SEMIVOLATILES ORGANICS
04/04/2019
4/4/2019 9:25:04AM
04/05/2019
1903T56-001B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
HERBICIDES, TCLP Leached
04/0412019
4/4/2019 9:56:47AM
04/08/2019
1903T56-00113
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
MERCURY, TCLP Leached
04/04/2019
4/8/2019 12:10:OOPM
04/08/2019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
ICP METALS, TCLP Leached
04/04/2019
4/5/2019 11:55:OOAM
04/0512019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
PESTICIDES, TCLP Leached
04/0412019
4/5/2019 12:12:02PM
04/05/2019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
Cyanide, Reactive
4/8/2019 12:40:OOPM
04/08/2019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
Sulfide, Reactive
4/3/2019 5:00:OOPM
04/03/2019
1903T56-001 B
Prestage-St. Paul LAG TCLP
3/28/2019
2:30:OOPM
Sludge
Laboratory Hydrogen Ion (pH)
3/29/2019 7:44:52AM
03/29/2019
Page 8 of 24

Analytical Environmental Services, Inc Date: 10-Apr-19
Client: Terra Renewal Services ANALYTICAL QC SUMMARY REPORT
Project Name: Presrage-St. Paul LAC
Workorder: 1903T56 BatchID: 276663
Sample TD: LCS-276663
Client TD:
Units: pH Units Prep Date: 03/29/2019
Run No: 394481
SampleType: LCS
TestCode: Laboratory Hydrogen Ion (pH) SW9045D
BatchID: 276663 Analysis Date: 03/29/2019
Seq No: 8832731
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit High Limit RPD Ref Val %RPD
RPD Limit Qua]
PH 7.030 0.01 7.000 100 90 110 H
Sample ID: 1903T43-001ADUP
Client TD:
Units: pH Units Prep Date: 03/29/2019
Run No: 394481
SampleType: DUP
TestCode: Laboratory Hydrogen Ion (pH) SW9045D
BatchID: 276663 Analysis Date: 03/29/2019
Seq No: 8832733
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit High Limit RPD Ref Val %RPD
RPD Limit Qual
PH 8.270 0.01 8.210 0.728 10 H
Qualifiers: > (heater than Result value
BRL Below reporting limit
J Estirnaiedvalue detected below RepordugLimit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyze nol NELAC certified
S Spike Rccovcry outside limits duc to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 9 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276881
Sample ID: MB-276881
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: MBLK
TestCode: )'OLATILES, TCLP SW1311/8260D
Batch[D: 276881
Analysis Date: 04/02/2019
Seq No: 8839966
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
1,1-Dichloroethene
BRL
0.10
1,2-Dichloroethane
BRL
0.10
2-Butanone
BRL
0.20
Benzene
BRL
0.10
Carbon tetrachloride
BRL
0.10
Chlorobenzene
BRL
0.10
Chloroform
BRL
0.10
Tetrachloroethene
BRL
0.10
Trichloroethene
BRL
0.10
Vinyl chloride
BRL
0.040
Surr:4-Bromofluorobenzene
0.8802
0 1,000 88.0 63.1 120
Sun•: Dibromofluoromethane
1.026
0 1.000 103 76.1 126
Surr: Toluene-d8
0.9600
0 1.000 96.0 75.3 119
Sample TD: LCS-276881
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: LCS
TestCode: `rOLATMES, TCLP SW1311/8260D
BatchID: 276881
Analysis Date: 04/02/2019
Seq No: 8839965
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qua]
1,1-Dichloroethene
0.4344
0.10
0.4000
109
57.3
140
1,2-Dichloroethane
0.3844
0.10
0.4000
96.1
66
134
2-Butanone
0.7696
0.20
0.8000
96.2
60.5
138
Benzene
0.3852
0.10
0.4000
96.3
72.4
129
Carbon tetrachloride
0.4404
0.10
0.4000
110
67.9
140
Chlorobenzene
0.3902
0.10
0.4000
97.6
76
131
Chloroform
0.3836
0.10
0.4000
95.9
63.7
132
Tetrachloroethene
0.3936
0.10
0.4000
98.4
73.7
139
Trichloroethene
0.3768
0.10
0.4000
942
72.2
136
Vinyl chloride
0.4206
0.040
0.4000
105
55.8
136
Qualifiers: > Greater than Result value < Less than Result value 13 Analyte detected in the associated method blank
HRL Below reporting limit E Estimated (value above quamitation range) H Holding times for preparation or analysis exceeded
J Estimated value detected below Reporting Limit, N Analyte wl NELAC certified R RPD outside limits due to matrix
Rpt Lim Reporting Limit S Spike Recovery outside limits due to matrix
Page 10 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276881
Sample ID: LCS-276881
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: LCS
TestCode: voLATILES, TCLP Sw1311/8260D
Batch[D: 276881
Analysis Date: 04/02/2019
Seq No: 8839965
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Surr:4-Bromofluorobenaene
0.9692
0
1.000
96.9
63.1
120
Surr: Dibromofluoromethane
0.9896
0
1.000
99.0
76.1
126
Surr: Toluene-d8
0.9840
0
1.000
98.4
75.3
119
Sample TD: 1903S80-001AMS
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: MS
TestCode: VOLATILES,TCLP SW1311/8260D
BatchID:276881
Analysis Date: 04/02/2019
Seq No: 8840591
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qua]
1,1-Dichloroethene
1.087
0.10
1.000
109
62.3
137
1,2-Dichloroethane
1.124
0.10
1.000
112
65.8
133
2-Butanone
2.151
0.20
2.000
108
57.2
140
Benzene
1.101
0.10
1.000
110
72.2
134
Carbon tetrachloride
1.236
0.10
1.000
124
69.3
140
Chlorobenzene
1.096
0.10
1.000
110
73.8
136
Chloroform
1.041
0.10
1.000
104
61.4
136
Tetrachloroethene
1.135
0.10
1.000
113
73.1
138
Trichloroethene
1.042
0.10
1.000
104
72.5
138
Vinyl chloride
1.104
0.040
1.000
110
60.8
135
Surr:4-Bromofluorobenzene
0.9600
0
1.000
96.0
63.1
120
Surr: Dibromofluoromethane
1,016
0
1.000
102
76.1
126
Surr: Toluene-d8
1.008
0
1.000
101
75.3
119
Sample ID: 1903T69-009BDUP
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: DUP
TestCode: voLAT1LES, TCLP SW131118260D
BatchID: 276881
Analysis Date: 04/02/2019
Seq No: 8840592
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
1,1-Dichloroethene BRL 0.10 0 0 30
1,2-Dichloroethane BRL 0.10 0 0 30
Qualifiers: > Greater Khan Result value
BRL Below reporting limit
7 Esditialed value detected below Reporting L'utul
Rpl Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitution range)
N Aaatyle not NELAC certified
S Spike Recovery outside limits due to matrix
B Analyte detected in the associated method blank
H. Holding times for preparation or analysis exceeded
R RPD outside limits due io matrix
Page 11 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276881
Sample ID: 1903T69-009BDUP
Client ID:
Units: mg/L
Prep Date: 04/02/2019
Run No: 394747
SampleType: DUP
TestCode: voLATILES, TCLP SW1311/8260D
BatchlD: 276881
Analysis Date: 04/02/2019
Seq No: 8840592
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2-Butanone
BRL
0.20
0
0
30
Benzene
BRL
0.10
0
0
30
Carbon tetrachloride
BRL
0.10
0
0
30
Chlorobenzene
BRL
0.10
0
0
30
Chloroform
BRL
0.10
0
0
30
Tetrachloroethene
BRL
0.10
0
0
30
Trichloroethene
BRL
0.10
0
0
30
Vinyl chloride
BRL
0.040
0
0
30
Surr:4-Bromofluorobenzene
0.8934
0 1.000
893 64.3 123 0.8788
0
0
Surr: Dibromofluoromethane
1.002
0 1.000
100 71.7 127 1.004
0
0
Surr: Toluene-d8
0.9424
0 1.000
94.2 75.1 118 0.9454
0
0
Qualifiers: > 6rearer than Result value
BRL Below reporting limit
J Esdinaledvalue deieciedbelovvReponingLimit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyle not NELAC certified
S Spike Recovery outside limits due to matrix
B Analyte derecred in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due io matrix
Page 12 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276989
Sample ID: MB-276989
Client ID:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395059
SampleType: MBLK
TestCode: SEMIVOLATILES ORGANICS. TCLP SW131M270E
BatchlD: 276989
Analysis Date: 04/04/2019
Seq No: 8845353
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qua]
1,4-Dichlorobenzene
BRL
0.10
2,4,5-Trichlorophenol
BRL
0.10
2,4,6-Trichlorophenol
BRL
0.10
2,4-Dinitrotoluene
BRL
0.10
Cresols, Total
BRL
0.10
Hexachlorobenzene
BRL
0.10
Hexachlorobutadiene
BRL
0.10
Hexachloroethane
BRL
0.10
m,p-Cresol
BRL
0.10
Nitrobenzene
BRL
0.10
o-Cresol
BRL
0.10
Pentachlorophenol
BRL
0.50
Pyridine
BRL
0.10
Surr:2,4,6-Tribromophellol
0.8361
0
1.000
83.6
49.6
128
Surr:2-Fluorobiphenyl
0.4098
0
0.5000
82.0
52.2
124
Surr:2-Fluorophenol
0.7381
0
1.000
73.8
44
129
Surr:4-Terphenyl-dl4
0.4051
0
0.5000
81.0
63.2
145
Surr: Nitrobenzene-d5
0.4151
0
0.5000
83.0
53.6
124
Surr: Phenol-d5
0.6834
0
1.000
68.3
50.6
125
Sample TD: LCS-276989
Client TD:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395059
SlunpleType: LCS
TestCode: SEM IVOLATI LES ORGANICS, TCLP SW1311/8270E
BatchID: 276989
Analysis Date: 04/04/2019
Seq No: 8845356
Analyte
Result RPT Limit SPK value SPK Ref Val
%PEC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
1,4-Dichlorobenzene
1.039
0.10
1.000
104
61.9
129
2,4,5-Trichlorophenol
1.003
0.10
1.000
100
66.5
129
2,4,6-Trichlorophenol
1.047
0.10
1.000
105
72.6
134
2,4-Dinitrotoluene
0.9280
0.10
1.000
92.8
69
124
Qualifiers- > (neater than Result value a Less than Result value H Analyte detected in the associated method blank
BRL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded
J Estimated value detected below Reporting Limit N Analyte not NELAC certified R RPD outside limits due to matrix
Rpt Lim Reporting Limit S Spikc Recovery outside limits duc to matrix
Page 13 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276989
Sample ID: LCS-276989
Client ID:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395059
SampleType: LCS
TestCode: SEMIVOLATILES ORGANICS, TCLP SW1311/8270E
BatchlD: 276989
Analysis Date: 04/04/2019
Seq No: 8845356
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Cresols, Total
3.084
0.10
3.000
103
74.5
134
Hexachlorobenzene
1.074
0.10
1.000
107
70.6
129
Hexachlorobutadiene
1.246
0.10
1.000
125
59.2
124 S
Hexachloroethane
1.045
0.10
1.000
104
57.8
131
m,p-Cresol
2.035
0.10
2.000
102
72.3
130
Nitrobenzene
1.029
0.10
1.000
103
72.6
125
o-Cresol
1.049
0.10
1.000
105
75.7
140
Pentachlorophenol
0.6113
0.50
1.000
61.1
50.1
122
Pyridine
0.5637
0.10
1.000
56.4
12.5
120
Surr: 2 4,6-Tribromophenol
1.096
0
1.000
110
49.6
128
Surr:2-Fluorobiphenyl
0.5169
0
0.5000
103
52.2
124
Surr:2-Fluorophenol
0.9189
0
1.000
91.9
44
129
Surr:4-Terphenyl-d14
0.5105
0
0.5000
102
63.2
145
Surr: Nitrobenzene-d5
0.5368
0
0.5000
107
53.6
124
Surr: Phenol-d5
0.8821
0
1.000
88.2
50.6
125
Sample iD: 1904310-OOIBMS
Client 1D:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395059
SampleType: MS
TestCode: SEMIVOLATILES ORGANICS, TCLP SW131118270E
BatchID: 276989
Analysis Date: 04/04/2019
Seq No: 8845776
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
1,4-Dicblorobenzene
0.8679
0.10
1.000
86.8
48.5
131
2,4,5-Trichlorophenol
0.8660
0.10
L000
86.6
52.2
129
2,4,6-Trichlorophenol
0.8487
0.10
1.000
84.9
54.3
132
2,4-Dinitrotoluene
0.7432
0.10
1.000
74.3
56.3
120
Cresols, Total
2.554
0.10
3.000
85.1
61.4
136
Hexachlorobenzene
0.8897
0.10
1.000
89.0
58.1
128
Hexachlorobutadiene
1.030
0.10
1.000
103
46.3
123
Hexachloroethane
0.8813
0.10
1.000
88.1
49
129
Qualifiers: >
Greater than Result value
< Less than Result value
B Analyle detected in the associated method blank
13RL
Below reporting limit
E Estimated (value above quantitation range)
H Holding times for preparation of analysis exceeded
J
Estimated value defected below Reporuag Limit
N Analyle nol NELAC certified
R RPD outside limits due to matrix
Rpt Lim
Reporting Limit
S Spikc Recovery outside limits due to matrix
Page 14 of 24

Analytical Environmental Services, Inc Date: 10-Apr-19
Client: Terra Renewal Services ANALYTICAL QC SUMMARY REPORT
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56 BatchID: 276989
Sample ID: 1904310-OOIBMS
Client ID:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395059
SampleType: NIS
TestCode: SEMIV01 ATtLES ORGANICS, TCLP SW1311/8270E
BatchlD: 276989
Analysis Date: 04/04/2019
Seq No: 8845776
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
m,p-Cresol
1.680
0.10
2.000
84.0
65.2
129
Nitrobenzene
0.8528
0.10
1.000
85.3
61.8
124
o-Cresol
0.8734
0.10
1.000
87.3
65
140
Pentachlorophenol
BRL
0.50
1.000
47.2
42.3
121
Pyridine
0.2415
0.10
1.000
24.2
10
120
Surr: 2 4,6-Tribromophenol
0.9458
0
1.000
94.6
49.6
128
Surr:2-Fluorobiphenyl
0.4500
0
0.5000
90.0
52.2
124
Surr:2-Fluorophenol
0.8253
0
1.000
82.5
44
129
Surr:4-Terphenyl-dl4
0.4484
0
0.5000
89.7
63.2
145
Surr: Nitrobenzene-d5
0.4773
0
0.5000
95.5
53.6
124
Surr: Phenol-d5
0.7851
0
1.000
78.5
50.6
125
Qualifiers: > Greater than Result value
BRL Below reporting limit
J Estimated value detected below Reporting Limil
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spike Recovery outside limits duc to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 15 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 276993
Sample ID: MB-276993
Client ID:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395139
SampleType: MBLK
TestCode: HERBICIDES, TCLP SW1311/8151A
BatchID: 276993
Analysis Date: 04/05/2019
Seq No: 8847506
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex) BRL 0.20
2,4-D BRL 0.20
Surr: DCAA 0.3554 0 0.5000 71.1 49.4 120
Sample TD: LCS-276993
Client TD:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395139
SampleType: LCS
TestCode: HERBICIDES, TCLP SW1311/8151A
BatchID: 276993
Analysis Date: 04/05/2019
Seq No: 8847507
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex)
0.3764
0.20
0.5000
75.3
49
120
2,4-D
0.3725
0.20
0,5000
74.5
50.9
120
Surr: DCAA
0.3649
0
0.5000
73.0
49.4
120
Sample ID: 1904058-001BMS
Client 1D:
Units: mg/L
Prep Date: 04/04/2019
Run No: 395139
SampleType: MS
TestCode: HLRBICIDES,TCLP SW1311/8151A
BatchID:276993
Analysis Date: 04/05/2019
Seq No: 8847510
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
2,4,5-TP (Silvex)
0.3875
0.20
0.5000
77.5
48.2
120
2,4-D
0.4177
0.20
0.5000
83.5
45
130
Surr: DCAA
0.3635
0
0.5000
72.7
49.4
120
Qualifiers: > Greater than Result value
BRL Below reporting limit
J Estimated value detected below Reponing Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spikc Recovery outside limits due to matrix
H Analyte derecied in the associated method blank
H Holding times for prepurarion or analysis exceeded
R RPD outside limits due to matrix
Page 16 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Presl.age-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr 19
ANALYTICAL QC SUMMARY REPORT
BatchID: 277063
Sample ID: MB-277063
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395176
SampleType: MBLK
TestCode: 1CP1v1ETALS, TCLP SW1311/6010D
BatchlD: 277063
Analysis Date: 04/05/2019
Seq No: 8848411
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Arsenic
BRL
0.250
Barium
BRL
0.500
Cadmium
BRL
0.0250
Chromium
BRL
0.0500
Lead
BRL
0.0500
Selenium
BRL
0.100
Silver
BRL
0.0250
Sample ID: LCS-277063
Client TD:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395176
SampleType: LCS
TestCode: 1CP METALS, TCLP SW1311/6010D
BatchlD: 277063
Analysis Date: 04/05/2019
Seq No: 8848412
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Arsenic
4.985
0.250
5.000
99.7
80
120
Barium
4.836
0.500
5.000 0.04445
95.8
80
120
Cadmium
4.999
0.0250
5.000
100.0
80
120
Chromium
4.865
0.0500
5.000
97.3
80
120
Lead
4.985
0.0500
5.000
99.7
80
120
Selenium
5.035
0.100
5.000
101
80
120
Silver
0.5068
0.0250
0.5000
101
80
120
Sample ID: 1904431-001AMS
Client TD:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395176
SampleType: MS
TestCode: 1CP METALS, TCLP SW1311/6010D
BatchlD: 277063
Analysis Date: 04/05/2019
Seq No: 8848414
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qua]
Arsenic
4.771
0.250
5.000
95.4
50
150
Barium
6.536
0.500
5,000 1.913
92.5
50
150
Cadmium
5.035
0.0250
5.000
101
50
150
Chromium
4.893
0.0500
5.000 0.04305
97.0
50
150
Qualifiers: > Greater than Result value < Less than Result value 13 Analyte detected in the associated method blank
13RL Below reporting limit E Estimated (value above quantitation range) H Holding times for preparation or analysis exceeded
J Estimated value detected below Reporting Luuit N Analyte not NELAC certified R RPD outside limits due to matrix
Rpt Lim Reporting Limit S Spikc Recovery outside limits duc to matrix
Page 17 of 24

Analytical Environmental Services, Inc
Date: 10-Apr-19
Client: Terra Renewal Services ANALYTICAL QC SUMMARY REPORT
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56 BatchID: 277063
Sample ID: 1904431-001AMS
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395176
SampleType: MS
TestCode: 1CPMETALS, TCLP SW1311/6010D
BatchlD: 277063
Analysis Date: 04/05/2019
Seq No: 8848414
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Lead
4.996
0.0500
5.000
99.9
50
150
Selenium
5.019
0.100
5.000
100
50
150
Silver
0.5076
0.0250
0.5000
102
50
150
Sample TD: 1904431-001AMSD
Client TD:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395176
SampleType: MSD
TestCode: 1CP METALS, TCLP SW1311/6010D
BatchID: 277063
Analysis Date: 04/05/2019
Seq No: 8848415
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qua]
Arsenic
5.049
0.250
5.000
101
50
150
4.771
5.64
30
Barium
6.707
0.500
5.000 1.913
95.9
50
150
6.536
2.57
30
Cadmium
5.197
0.0250
5.000
104
50
150
5.035
3.17
30
Chromium
5.053
0.0500
5.000 0.04305
100
50
150
4.893
3.22
30
Lead
5.148
0.0500
5.000
103
50
150
4.996
3.00
30
Selenium
5.150
0.100
5.000
103
50
150
5.019
2.57
30
Silver
0.5270
0.0250
0.5000
105
50
150
0.5076
3.75
30
Qualifiers: > Greater than Result value
BRL Below reporting limit
7 Estimated value detected below Reporting Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitution range)
N Analyze not NELAC certified
S Spikc Recovery outside limits duc to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 18 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 277081
Sample ID: MB-277081
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: MBLK
TestCode: PESTICIDES, TCLP SW1311/8081B
BatchlD: 277081
Analysis Date: 04/05/2019
Seq No: 8848996
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Chlordane
BRL
0.0050
Endrin
BRL
0.0010
gamma-BHC
BRL
0,00050
Heptachlor
BRL
0.00050
Heptachlor epoxide
BRL
0.00050
Methoxychlor
BRL
0.0050
Toxaphene
BRL
0.050
Surr: Decachlorobiphenyl
0.004548
0 0.0050 91.0 47.7 136
Surr: Tetrachloro-m-xylene
0.003885
0 0.0050 77.7 44.7 126
Sample ID: LCS-277081-1
Client 1D:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: LCS
TestCode: PESTTCrDES,TCLP SW1311/8081B
BatchID:277081
Analysis Date: 04/05/2019
Seq No: 8848997
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Endrin
0.007653
0.0010
0.0080
95.7
75
141
gamma-BHC
0.006958
0.00050
0.0080
87.0
78.5
131
Heptachlor
0.006750
0.00050
0.0080
84.4
70.5
129
Heptachlor epoxide
0.007190
0.00050
0.0080
89.9
82.8
133
Methoxychlor
0.02640
0.0050
0.0300
88.0
61.6
132
Surr: Decachlorobiphenyl
0.004610
0
0.0050
92.2
47.7
136
Surr: Tetrachloro-m-xylene
0.003510
0
0.0050
70.2
44.7
126
Sample ID: LCS-277081-2
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: LCS
TestCode: PESTICIDES, TCLP S"'1311/8081B
BatchlD: 277081
Analysis Date: 04/05/2019
Seq No: 8848998
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Chlordane
0.03783
0.0050
0.0400
94.6
75.6
130
Toxaphene
0.08335
0.050
0.0800
104
80.4
129
Qualifiers: > Greater than Result value
BRL Below reporting limit
7 Estimated value detected below Repotting Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitatiun range)
N Analyze not NELAC certified
S Spike Recovery outside limits due to matrix
13 Analyte detected in the associated method blank
H Holding times far preparation or analysis exceeded
R RPD outside limits due to matrix
Page 19 of 24

Analytical Environmental Services, Inc Date: 10-A r-19
Client: Terra Renewal Services ANALYTICAL QC SUMMARY REPORT
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56 BatchID: 277081
Sample ID: LCS-277081-2
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: LCS
TestCode: PESTICIDES, TCLP SW1311/8081B
BatchID: 277081
Analysis Date: 04/05/2019
Seq No: 8848998
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Surr: Decachlorobiphenyl 0.004745 0 0.0050 94.9 47.7 136
Surr: Tetrachloro-m-xyleiie 0.003509 0 0.0050 70.2 44.7 126
Sample LD: 1904058-OOIBMSI
Client LD:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: MS
TestCode: PESTiCTDES,TCLP SW1311/8081B
BatchID: 277081
Analysis Date: 04/05/2019
Seq No: 8849004
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Endrin
0.007332
0.0010
0.0080
91.6
62.9
144
gamma-BHC
0.007016
0.00050
0.0080 0.0001918
853
66
132
Heptachlor
0.006553
0.00050
0.0080
81.9
66.2
130
Heptachlor epoxide
0.006952
0.00050
0.0080
86.9
65
130
Metboxychlor
0.02539
0.0050
0.0300
84.6
56.4
134
Surr: Decachlorobiphenyl
0.003518
0
0.0050
70.4
47.7
136
Surr: Tetrachloro-m-xylene
0.003406
0
0.0050
68.1
44.7
126
Sample ID: 1904058-001 BMS2
Client ID:
Units: mg/L
Prep Date: 04/05/2019
Run No: 395209
SampleType: MS
TestCode: PESTICIDES, TCLP SN'1311/8081B
BatchID: 277081
Analysis Date: 04/05/2019
Seq No: 8849007
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Chlordane
0.03614
0.0050
0.0400
90.3
71
134
Toxaphene
0.07770
0.050
0.0800
97.1
67.3
130
Surr: Decachlorobiphenyl
0.003829
0
0.0050
76.6
47.7
136
Surr: Tetrachloro-m-xylene
0.003492
0
0.0050
69.8
44.7
126
Qualifiers: > Greater than Result value
13RL Below reporting limit
f Estimated value detected below Reporting Limit
Rpt Lim Rcporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spike Recovery outsidc limier due to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 20 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestige -St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 277091
Sample ID: MB-277091
Client ID:
Units: mg/Kg
Prep Date: 04/03/2019
Run No: 395190
SampleType: MBLK
TestCode: Sulfide, Reactive SW846-7.3
BatchlD: 277091
Analysis Date: 04/03/2019
Seq No: 8848671
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Sulfide, Reactive BRL 100
Sample ID: LCS-277091
Client ID:
Units: mg/Kg
Prep Date: 04/03/2019
Run No: 395190
SampleType: LCS
TestCode: sulfide, Reactive SW846-7.3
BatchlD: 277091
Analysis Date: 04/03/2019
Seq No: 8848672
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Sulfide, Reactive 400.0 100 400.0 100 65.5 125
Sample ID: 1903T89-002AMS
Client ID:
Units: mg/Kg
Prep Date: 04/03/2019
Run No: 395190
SampleType: MS
TestCode: Sulfide, Reactive SW846-7.3
BatchlD: 277091
Analysis Date: 04/03/2019
Seq No: 8848675
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Sulfide, Reactive 320.0 100 400.0 80.0 28.7 139
Sample ID: 1903T89-002AMSD
Client ID:
Units: mg/Kg
Prep Date: 04/03/2019
Run No: 395190
SampleType: MSD
TestCode: Sulfide, Reactive SW846-7.3
BatchlD: 277091
Analysis Date: 04/03/2019
Seq No: 8848676
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Sulfide, Reactive 352.0 100 400.0
Qualifiers: > (hearer man Result value
BRL Below reporting limit
J Estimated value detected below Reporting Unit
Rpl Lim Reporting Limit
88.0 28.7 139 320.0 9.52 26.9
< Less than Result value
E Estimated (value above gtrantitation target
N Analyle not NELAC certified
S Spike Recovery outside limits due to matrix
li Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 21 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903'1756
Date: 10-A rp 19
ANALYTICAL QC SUMMARY REPORT
BatchID: 277126
Sample ID: MB-277126
Client ID:
Units: mg/L
Prep Date: 04/08/2019
Run No: 395306
SampleType: MBLK
TestCode: MERCLJRY. TCLP SW1311/7470A
BatchlD: 277126
Analysis Date: 04/08/2019
Seq No: 8851502
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Mercury BRL 0.00400
Sample ID: LCS-277126
Client ID:
Units: mg/L
Prep Date: 04/08/2019
Run No: 395306
SampleType: LCS
TestCode: MERCURY. TCLP SW1311/7470A
BatchlD: 277126
Analysis Date: 04/08/2019
Seq No: 8851503
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Mercury 0.03949 0.00400 0.0400 98.7 80 120
Sample ID: 1904431-OOIAMS
Client ID:
Units: mg/L
Prep Date: 04/08/2019
Run No: 395306
SampleType: MS
TestCode: MERCURY. TCLP SW1311/7470A
BatchlD: 277126
Analysis Date: 04/08/2019
Seq No: 8851505
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Mercury 0.03880 0.00400 0.0400 0.0005024 95.7 80 120
Sample ID: 1904431-001AMSD
Client ID:
Units: mg/L
Prep Date: 04/08/2019
Run No: 395306
SampleType: MSD
TestCode: MERCURY, TCLP SW1311/7470A
BatchlD: 277126
Analysis Date: 04/08/2019
Seq No: 8851506
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Mercury 0.03934 0.00400 0.0400 0.0005024 97.1 80 120 0.03880 1.37 20
Qualifiers: > (nearer than Result value
BRL Below reporting limit
J Estimated value detected below Reporting Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitution range)
N Analyze vol NELAC certified
S Spike Recovery outside limit due to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 22 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: 10-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: 277187
Sample ID: MB-277187
Client ID:
Units: mg/Kg
Prep Date: 04/08/2019
Run No: 395274
SampleType: MBLK
TestCode: Cyanide, Reactive SW846-7.3
BatchlD: 277187
Analysis Date: 04/08/2019
Seq No: 8850635
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Cyanide, Reactive BRL 1.00
Sample ID: LCS-277187
Client ID:
Units: mg/Kg
Prep Date: 04/08/2019
Run No: 395274
SampleType: LCS
TestCode: Cyanide, Reactive SW846-7.3
BatchlD: 277187
Analysis Date: 04/08/2019
Seq No: 8850643
Analyte
Result RPT Limit. SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Cyanide, Reactive 9.850 1.00 12.50 78.8 63 121
Sample ID: 1904057-001CMS
Client ID:
Units: mg/Kg
Prep Date: 04/08/2019
Run No: 395274
SampleType: MS
TestCode: Cyanide, Reactive SW846-7.3
BatchlD: 277187
Analysis Date: 04/08/2019
Seq No: 8850661
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Cyanide, Reactive 5.735 0.980 12.25 46.8 28.5 122
Sample ID: 1904057-OO1CMSD
Client ID:
Units: mg/Kg
Prep Date: 04/08/2019
Run No: 395274
SampleType: MSD
TestCode: Cyanide, Reactive SW846-7.3
BatchlD: 277187
Analysis Date: 04/08/2019
Seq No: 8850662
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Cyanide, Reactive 6.116 0.971 12.14 50.4 28.5 122 5.735 6.43 25.1
Qualifiers: > 61 eater than Result value
BRL Below reporting limit
J Eslintated value detected below Reportiuo Limit
Rpt Lim Rcportiny Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyze not NELAC certified
S Spike Recovery outside limits due to matrix
H Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 23 of 24

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestage-St. Paul LAG
Workorder: 1903T56
Date: I O-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchID: R395348
Sample ID: LCS-R395348
Client ID:
Units: OF
Prep Date:
Run No: 395348
SampleType: LCS
TestCode: Ignitability SW1010A
BatchlD: R395348
Analysis Date: 04/09/2019
Seq No: 8852676
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Ignitability 83.00 0 81.00 102 93.8 106.2
Sample ID: 1904414-OOICDUP
Client ID:
Units: OF
Prep Date:
Run No: 395348
SampleType: DUP
TestCode: Ignitability SWI010A
BatchlD: R395348
Analysis Date: 04/09/2019
Seq No: 8852678
Analyze
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit
High Limit RPD Ref Val %RPD
RPD Limit Qual
Ignitability 200.0 0 200.0 0 20 >
Qualifiers: > (ireawr than Result value
BRL Below reporting limit
J EstiniaLed value detected belowReponiagLitnit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N AnaLyte nol NELAC certified
S Spike Recovery outside limits due to matrix
13 Analyze detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside titans due to matrix
Page 24 of 24

LABORATORY ANALYSES:
- Seven Set Fecal Coliform Data

ANALYTICAL ENVIRONMENTAL SERVICES, INC.
April 11, 2019
David Coyle
Terra Renewal Services
P.O. Box 399
Dardanelle AR 72834
RE: Prestige - St. Paul LAG
Dear David Coyle: Order No: 1904411
Analytical Environmental Services, Inc. received 7 samples on April 4, 2019 10:10 am
for the analyses presented in following report.
No problems were encountered during the analyses. Additionally, all results for the associated
Quality Control samples were within EPA and/or AES established limits. Any discrepancies associated with the
analyses contained herein will be noted and submitted in the form of a project Case Narrative. AES'
certifications are as follows:
-South Carolina Certification number 98016003 for Clean Water Act and for Solid and Hazardous Waste,
effective until 6/30/19.
These results relate only to the items tested as received. This report may only be reproduced in fill.
If you have any questions regarding these test results, please feel free to call.
Sincerely,
Chris Pafford
Project Manager
,0, Pre:; ielvniial !hive • AL]aeila, Georgia 30340 - 'Fel: 770.457.81 77 • Fix: 770-457 6188 • 'loll 1'rec: 800.972.4889
www.aecateanra.conn
Page 1 of 11

. AsANALYTICAL ENVIRONMENTAL SERVICES, INC.
3080 Presidential Drive Atlanta, GA 30340-3704
1'1�,+' LS Phone: [phone] / Toll -Free: [phone] / Fax: (770) 4S7-8188
CHAIN OF CUSTODY
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Submission of samples to the laboratory constitutes acceptance of AES's Terms & Conditions. Client assumes sole responsibility for damage or loss of samples before use accept them, Samples received after 3PM or on Saturday are considered as received the following
business day. IF no TAT is marked on COC, AES will proceed with standard TAT. Samples are disposed of 30 days after completion of report unless other arrangements are made.
Matrix Codes: A=Airy GW=Groundwater SE=Sediment SO=Soil SW=Surface Water ST=Stormwater WW=Waste Water W =Water (Blanks) !=DrinklAgWater (Blanks) O=Other(specify) 7.11.18_CD
Preservative Codes: H+I = Hydrochloric acid + ice I = Ice only' N = Nitric acid 5+1= Sulfuric acid + Ice S/M+I = So&m Bisulfate/Methanol + Ice 0 = Other (specify) NA = None White Copy - Original; Yellow Copy - Client
Page 2 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client:
Terra Renewal Services
Client Sample ID:
Prestage-St. Paul Lag F1
Project Name:
Prestige - St. Paul LAG
Collection Date:
4/3/2019 3:00:00 PM
Lab ID:
1904411-001
Matrix:
Sludge
Reporting Dilution
Analyses Result Qual Units BatchlD Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 2710 673 Colonies/gr-dr R395525 100 04/04/2019 12:10 TG
Y
Qualifiers: * Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyle detected in the associated method blank
> (ireater than Result value
E Estimated (value above quantitation range)
S Spike Recovery outside limits due to matrix
Narr Seceascnarmtive
NC Not confirmed
< Less than Result value
J Estimated value detected below Reporting Limit
Page 3 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client:
Terra Renewal Services
Client Sample ID:
Prestage-St. Paul Lag F2
Project Name:
Prestige - St. Paul LAG
Collection Date:
4/3/2019 3:00:00 PM
Lab ID:
1904411-002
Matrix:
Sludge
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 3070 682 Colonies/a -dr R395525 100 04/04/2019 12:10 TG
y
Qualifiers: " Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyle not NELAC certified
B Analyle detected in the associated method blank
> Grenler than Result vnlue
E
Estimated (value above quantitation range)
S
Spike Recovery outside limits due to matrix
Nam
Seecasenarmtive
NC
Not confirmed
<
Less than Result value
J
Estimated value detected below Reporting Limit
Page 4 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client: Terra Renewal Services Client Sample ID: Prestage-St. Paul Lag F3
Project Name: Prestige - St. Paul LAG Collection Date: 4/3/2019 3:00:00 PM
Lab ID: 1904411-003 Matrix: Sludge
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 2090 698 Colonies/a -dr R395525 100 04/04/2019 12:10 TG
Y
Qualifiers: "
Value exceeds maximum contaminant level
BRL
Below reporting limit
H
Holding times for preparation or analysis exceeded
N
Analyze not NELAC certified
B
Analyze detected in the associated method blank
>
Greater than Result value
E Estimated (value above quantization range)
S Spike Recovery outside limits due to matrix
Narr Seccuscnarmtive
NC Not con%mad
< Less than Result value
J Estimated value detected below Reporting Limit
Page 5 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client: Terra Renewal Services Client Sample ID: Prestage-St. Paul Lag F4
Project Name: Prestige - St. Paul LAG Collection Date: 4/3/2019 3:00:00 PM
Lab ID: 1904411-004 Matrix: Sludge
Reporting Dilution Analyses Result Qual Units BatchlD DateAnalyaed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 3160 789 Colonies/gr-dr R395525 100 04/04/2019 12:10 TG
Y
Qualifiers: ° Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Analyte not NELAC certified
B Analyte detected in the associated melbodblank
> Greater than Result value
E
Estimated (value above quantitation range)
S
Spike Recovery outside limits due to matrix
Narr
Seccasenarmtive
NC
Not confirmed
<
Less Than Result value
J
Estimated value detected below Reporting Limit
Page 6 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client:
Terra Renewal Services
Client Sample ID:
Prestage-St. Paul Lag F5
Project Name:
Prestige - St. Paul LAG
Collection Date:
4/3/2019 3:00:00 PM
Lab ID:
1904411-005
Matrix:
Sludge
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 1800 721 Colonies/gr-dr R395525 100 04/04/2019 12:10 TG
Y
t
Qualifiers: a Value exceeds maximum contaminant level E Estimated (value above quantization range)
BRL Below reporting limit S Spike Recovery outside limits due to matrix
H Holding times for preparation or analysis exceeded Narr See case narrative
N Analyte not NELAC certified NC Not confirmed
B Analyze detected in the associated method blank < Less than Result value
> (heater than Result value J Fstimated value detected below Reporting Limit
Page 7 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client:
Terra Renewal Services
Client Sample ID:
Prestage-St. Paul Lag F6
Project Name:
Prestige - St. Paul LAG
Collection Date:
4/3/2019 3:00:00 PM
Lab ID:
1904411-006
Matrix:
Sludge
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soil/Sludge SM9222D
Fecal Coliform, (MF) 2100 700 Colonies/° -dr R395525 100 04/04/2019 12:10 TG
Y
Qualifiers: . Value exceeds maximum contaminant level
BRL Below reporting limit
H Holding times for preparation or analysis exceeded
N Anelyte not NELAC certified
B Analyle detected in the associated method blank
> (ireater than Result value
E
Estimated (value above quantitatiou range)
S
Spike Recovery outside limits due to matrix
Narr
See case narrative
NC
Not confirmed
<
Less than Result value
J
Estimated value detected below Reporting Limit
Page 8 of 11

Analytical Environmental Services, Inc
Date: 11-Apr-19
Client: Terra Renewal Services Client Sample ID: Prestage-St. Paul Lag F7
Project Name: Prestige - St. Paul LAG Collection Date: 4/3/2019 3:00:00 PM
Lab ID: 1904411-007 Matrix: Sludge
Reporting Dilution
Analyses Result Qual Units BatchID Date Analyzed Analyst
Limit Factor
Fecal Coliform-Soit/Sludge SM9222D
Fecal Coliform, (MF) 1990 664 Colonies/e -dr R395525 100 04/04/2019 12:10 TG
Y
Qualifiers: " Value exceeds maximum contaminant level E Estimated (value above quantitation range)
BRL Below reporting limit S Spike Recovery outside limits due to matrix
H Holding times for preparation or analysis exceeded Narr Sec case narrative
N Analyte not NHLAC certified NC Not confumed
H Analyle detected in the associated method blank a Less than Result value
> Greater than Result value J Estimated value detected below Reporting Limit
Page 9 of 11

ANAmncAL Clear Save as
+' FNviRoLNsrvrAi.
AE$ SERvjcFs. jxc. SAMPLE/COOLER RECEIPT CHECKLIST
1. client Name: Terra Renewal Services, Inc. AES Work order Number: 1904411
2. Carrier: Fed Ex ❑ UPS❑• USPS❑ Client❑ Courier❑ Othei
Yes No N/A Details Comments
3.
4.
5.
6.
7.
s.
9.
10.
11.
12,
Shipping container/cooler received in good condition?
•
damaged ❑ leaking ❑ other
Custody seals present on shipping container?
•
Custody seals intact on shipping container?
•
Temperature blanks present?
•
Cooler temperature(s) within limits of 0-6°C? [See item 13 and 14 for
temperature recordings.]
©
®
Cooling initiated for recently collected samples / ice
present ❑
Chain of Custody (COC) present?
■
Chain of Custody signed, dated, and timed when relinquished and received?
•
Sampler name and/or signature on COC? 1
•
Were all samples received within holding time?
##)
TAT marked on the COC?
I
If no TAT indicated, proceeded with standard TAT per Terms & Conditions.
13. Cooler 1 Temperature 0.8 °C Cooler 2 Temperature
14. Cooler 5 Temperature °C Cooler 6 Temperature
15. Comments:
16.
17.
18,
19.
20.
21.
22.
23.
24.
25.
26.
°C Cooler 3 Temperature °C Cooler 4 Temperature °C
°C Cooler 7 Temperature °C Cooler 8 Temperature °C
I certify that I have completed sections 1-15 (dated initials). MH 4/4/19
Yes No N/A Details Comments
Were sample containers intact upon receipt?
CO)
Custody seals present on sample containers?
•
Custody seals intact on sample containers?
•
Do sample container labels match the COC?
®
®
incomplete info ❑ illegible ❑
no lapel ❑ other ❑
Are analyses requested indicated on the COC?
•
Were all of the samples listed on the COC received?
®
©
samples received but not listed on COC ❑
samples listed on COC not received ❑
Was the sample collection date/time noted?
•
Did we receive sufficient sample volume for indicated analyses?
•
re samples received in appropriate containers?re
VOA samples received without headspace (< 1/4" bubble)?re
F
trip blanks submitted?
—s-
•
listed on COC ❑ not listed on COC ❑
27. Comments:
This section only applies to samples where pH can be I certify that I have completed sections 16-27 (dated initials). MH 4/4/19
checked at Sample Receipt. Yes No N/A Details Comments
28.
29.
30.
Have containers needing chemical preservation been checked?
U I U j
•
Containers meet preservation guidelines?
-
Was pH adjusted at Sample Receipt?
•
Note: Certain analyses require chemical preservation but must be checked in the laboratory and not upon Sample Receipt such as Coliforms, VOCs and Oil & Grease/TPH. MH a/4/19
I certify that I have completed sections 28-30 (dated initials).
Checklist 6.9.17 Rev 2 Locked
Page 10 of 11

Analytical Environmental Services, Inc
Client: Terra Renewal Services
Project Name: Prestige - St. Paul LAC
Workorder: 1904411
Date: 11-Apr-19
ANALYTICAL QC SUMMARY REPORT
BatchiD: R395525
Sample TD: MB-11395525
Client ID:
Units: Colonies/gr-dry Prep Date:
Run No: 395525
SampleType: MBLK
TestCode: Fecal Conform-son/Sludge SM9222D
BatchID: R395525 Analysis Date: 04/04/2019
Seq No: 8856255
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit High Limit RPD Ref Val %RPD
RPD Limit Qua]
Fecal Coliform, (MF) BRL 0.200
Sample TD: MB-R395525-2
Client ID:
Units: Colonies/gr-dry Prep Date:
Run No: 395525
SampleType: MBLK
TestCode: Fecal Conform-Soli/Sludge SM9222D
BatchID: R395525 Analysis Date: 04/04/2019
Seq No: 8858026
Analyte
Result RPT Limit SPK value SPK Ref Val
%REC Low Limit High Limit RPD Ref Val %RPD
RPD Limit Qual
Fecal Coliform, (MF) BRL 0.200
Qualifiers: > Greater than Result value
BRL Below reporting limit
S Estimated value detected below Repordug Limit
Rpt Lim Reporting Limit
< Less than Result value
E Estimated (value above quantitation range)
N Analyte not NELAC certified
S Spike Recovery outside limits due to matrix
B Analyte detected in the associated method blank
H Holding times for preparation or analysis exceeded
R RPD outside limits due to matrix
Page 11 of 11

LABORATORY ANALYSES:
- Vector Attraction Reduction Data

Project: Prestage St. Paul Lagoon
Client:
Terra Renewal
Sampled
Received
By D. Coyle
By
S. Bullard
Date 03/28/19
Date
03/28/19
Type
I Grab
Matrix
Sludge
;Sample ID
Lab ID
TS
Start (< 2%)
1.48%
1.44%
1.45%
1.57%
End (+ 30)
1.49%
Final Results FVSR (VK)
Project Manager
Notes: Sample started at TS < 2%.
30D Report Sheet
30 Day Benchtop Test
(EPA 6251R-921013, Appendix D)
Due I Ref. Methods
Date 05/04/19 J Requested Analysis
VS (%)
A"ysis
Date
65.4%
12/30/99
65.0%
414119
FVSR (VK)
1.7%
64.0%
4/12/19
FVSR (VK)
6.0%
66.8%
4118119
FVSR (VK)
-6.6%
63.6%
04R6/19
FVSR (VK)
7.4%
7.4% Pass, < 15%
Page 1
CTS Proj.
Regulatory
Std. Meth. 191' ed.
2540 G - TS
2540 G - VS
os/DJ 11'F
Date:
Analyst

219
SanNC 2733U S. str.
Sanford, NC
Cameron TestingServices, Inc.
Chain of Custody
Phone: $19--20B-4240 NC WWIGW Cert. #654 NC PHHS Cert # 37799 US EPA NC0191a
Page of
CornpauY: - —j ERAA � \ENi�•.iA � _ .
Email:
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CeritacT; 4-+► //r►
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Phone:
Y?g��y�—$f 92
Sample Tamp
(C)
Labl4
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Address (C4, P a . 13mf
Fax:
Ice ff,'Ny
State, Zip)
Notes:
Permit (YRO
Project: /�
r irri£r�s L� Q�� LA
Rush (YIN)
Due:
Collected: Name: ( �i Y�
ftne1'urs: __
-
Sample Information
Number of bottles
Requested Analysis
Sample [Q
m E E
c� W
Preservatives: (U)npreserved, H(C)I,
CTS Lab
0 o
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!i2(S)£74.
Ft{N}03. (Ha)Thfvsulfate, Na(O]H,
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tither (X), Indicate
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Win uishsd:
Received:
DWOMme
ropy
Rusin work will require }'rior approval. Additional charges will apply

5
Annual Pathogen & Vector Attraction Reduction Form for NCAC 2T Rules
(FORM PVRF 2T)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc.
WWTP Name: Prestage Foods - St. Paul WWTF
Monitoring Period: From 3/23/2019 To
WQ Permit Number:
NPDES Number:
4/8/2019
WQ0040524
WQ0001173
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑ 1
Alt B (Alk Treatment) ❑
Alt. C (Prior Testing) ❑
Alt.D (No Prior Test) ❑ I Process to Further Reduce Pathogengs ❑
If applicable to alternative
performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost ❑
Heat Drying ❑ Heat Treatment ❑
Therniophilic ❑
Beta Ray ❑
Gamma Ra ❑ Pasteurization ❑
Class B:
JAIL (1) Fecal Density p Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens". -
Lime Stabilization ❑
Air Drying ❑
Composting ❑
JAerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Class B) complete the following
monitoring data:
Parameter
Allowable Level
in Sludge
g
Pathogen Density
Number o
Excee-
s
Frequency
of Analysis
Y
Sample
T e
Type
Analytical
Tech -
Minimu
Geo. Mean
Maximu
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
664
704
789
CFU/g
0
1/yr
Grab
9222D
1000 mpn per gram
of total solid (dry
wei ht)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
weight)
Vector Attraction Reduction (15A NCAC 02T .1107) -Please indicate alternative performed.
Alt.l (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-day bench) p
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
Alt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note
if you check this statement attach an explanation why you have not met one or both of the
reauirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle; Environmental Manager David C. Coyle; Environmental Manager
Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
Signa teparer* Date Signat Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

6
2019 SOIL TEST REPORTS

Page 1 of 1
Report No: 19-360-0558
Account No: 08494
Advisor: Terra Renewal Services
P O Box 399
Dardanelle AR 72834
a
Waypoint.
ANALYTICAL
Client: TRS
WO0040524-LAG
Prestage-St. Paul
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: Prestage
Date Received:12/26/2019
Date of Report: 02/28/2020
Lab No
Field ID
Sample ID
Soil Class
HM% WN
pH
Ac
P-1
K-1
S-1
Mn-1
Zn-I
Zn-AI
Cu4
CEC
BS%
Ca%
Mg%
ESP
Na SS-1 NO3 N
09652
TR-HK2
TR-HK2
MIN
1.2
6.6
0.4
104
58
58
375
413
413
230
6.2
93
69
16
2.4
0.1
09654
TR-HK4
TR-HK4
MIN
1.3
6.3
0.7
147
43
37
138
493
493
420
6.4
88
69
14
1.6
0.1
09656
TR-HK1
TR-HK1
MIN
0.7
6.1
0.5
81
15
44
131
143
143
90
3.7
86
64
17
2.5
0.1
09657
TR-PF5
MIN
0.9
6.2
0.6
103
20
48
138
265
265
175
5.0
89
66
19
2.2
0.1
09661
TR-HK3
TR-HK3
MIN
1.1
6.7
0.3
257
33
48
88
738
738
545
6.6
96
76
15
1.7
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: W aypoint Analytical Virginia, Inc.