WQ0040622_Residual Annual Report 2019_20200228

Initial Review
INITIAL REVIEW
Reviewer Williams, Kendall
Is this submittal an application? (Excluding additional information.)*
r Yes r No
If not an application r Annual Report
what is the submittal r Residual Annual Report
type?* r Additional Information
r Other
Annual Report 2019
Year*
Date Paper Copy 2/28/2020
Received:*
Project Number* WQ0040622
Email Notifications
Does this need review by the hydrogeologist?*
r Yes r No
Regional Office
CO Reviewer
Admin Reviewer [e-mail]

Submitted Form
Project Contact Information
Rease provide information on the person to be contacted by MB Staff regarding electronic subnittal, confirmation of receipt, and other issues.
..........................................................................................................................................................................................................................................................................................................................................................................
Name * Drew Matthews
Email Address*
[e-mail]
Project Information
Submittal Type* r New Permit Application
r Renewal
r Annual Report
r Other
Permit Type * r Wastewater Irrigation
r Other Wastewater
r Closed -Loop Recycle
r Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?
r Yes r Nor N/A
Permit Number* WQ0040622
ApplicantTermittee * Atlantic OBX Inc.
Facility Name * Atlantic OBX DCAR
Phone Number*
2528839301
r Modification (Major or Minor)
r Additional Information
r Residual Annual Report
r High -Rate Infiltration
r Reclaimed Water
r Residuals
r Other
Please provide comments/notes on your current submittal below.
Please attach all information required or requested for this submittal to be review here.
Application Form Engineering Rans, Specifications, Calculations, Etc.)
2019 Atlantic Class A Annual Report.pdf 6.24MB
upload only 1 R7F document. NL@iple documents must be combined into one R7F file.

For new and modification permit applications, a paper copy may be required. If you have any questions
about what is required, please contactthe reviewer or Tessa Monday. If a paper 2-pol cation is required,
be advised, applications accepted for pre -review until both the paper and elect-c-ii.- --ol:ies have been
received. The paper copy shall include the following:
o Application Form
o All relevant attachments {talcs, soils report, specs, etc.]
o One full-size engineering plan set
o One 11x17" engineering plan set
o One extra set of specifications
o Fee (if required)
Mailine address:
Division of Water Resources ! Division of Water Resources
Non -Discharge Branch I Non -Discharge Branch
1617 Mail Service Center I Att: Nathaniel Thornburg, P Floor, Office #942W
- =
Raleigh, NC 27699-1617 S12 N.5alisburySt.
For questions or problems contact Tessa Monday attessa.monday@)ncdenr.Qov or 919.707.3560.
* rJ By checking this box I acknowledge that I understand the application will not be accepted
for pre -review until the paper copy (if required) and fee (if required) have been received by
the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with
all parts of the application in correct order (as specified by the application).
Signature
Submission Date 2/28/2020

ATLANTIC OBX, INC.
2019 ANNUAL LAND APPLICATION OF
RESIDUAL BIOSOLIDS REPORT
CLASS A PROGRAM
WQ0040622
Submitted by:
Soil Plus
PO Box 1396
Oxford, North Carolina 27565
February 28, 2020
SOIL PLUS

SOIL PLUS
February 28, 2020
NCDEQ-DWR
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
Re: 2019 LAND APPLICATION ANNUAL REPORT
Atlantic OBX, Inc. Class A Residuals Program
NC Permit No.: WQ0040622
Soil Plus Project No. 201007.B10
Information Processing Unit:
Soil Plus, LLC (Soil Plus) is submitting all monitoring and reporting requirements as
specified in the above referenced permit for Atlantic OBX, Inc. Soil Plus compiled this
report using data gathered during the compliance year. This data includes (1) a certification
form, (2) residual sampling summary, & (3) distribution & marketing summary form.
Atlantic OBX, Inc. distributed approximately 1,911,000 Gallons or 2,044.18 Dry Tons of
Class A Water Treatment Plant residuals from the City of Elizabeth City's WTP during
2019. The residuals were distributed to farms in Northeastern North Carolina for
agricultural uses.
If there is any further information required or questions regarding this report, please do
not hesitate to contact me or Atlantic OBX, Inc. (252-255-2030) for further assistance.
Respectfully,
Drew Matthews, Soil Plus
J. Bryan Smith, Atlantic OBX
PO Box 1396
Oxford, NC 27565
[phone]
dmatthewsgsoilplus.ne t
www.soilplus.net

Atlantic OBX, Inc.
2019 Annual Land
Application of
Residual Bio s olid s
Report
WQ0040622
ANNUAL LAND
APPLICATION
CERTIFICATION FORM
ANNUAL RESIDUAL
SAMPLING SUMMARY
FORM
City of Elizabeth City WTP
Nutrients
503 Metals
TCLP
ANNUAL
DISTRIBUTION AND
MARKETING
CERTIFICATION AND
SUMMARY FORM

ATLANTIC OBX, INC.
2019 Class A Annual Report
WQ Permit# WQ0040622
Annual Certification Form
Source Summary

ANNUAL LAND APPLICATION CERTIFICATION FORM
PermitNumber FacilityName Land Application Operator County Phone Number
WQ0040622 Atlantic OBX, Inc. Class A J. Bryan Smith Dare [phone]
Year: 2019
Land application of residuals as allowed by the permit occurred during the past calendar year? If No, skip Part A, and Yes No
Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how 0 ❑
the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit: N/A
Total number of fields utilized for land application during the year: N/A
Total amount of dry tons applied during the year for all application sites: 2,044.18
Total number of acres utilizes for land application during the year: N/A
Part B - Annual Compiance Statement:
Facility was compliant during calendar year with all conditions of the land application permit? Yes No
Including but not limited to items 1-13 below) issued by the Division of Water Quality 0 ❑■
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites
2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6
3. Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory
results are attached
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of
certified laboratory results are attached
6.The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T
7. All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated
facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated
facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was
received from the Division of Water Quality
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to
include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and
complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations."
J. Bryan Smith, President
Permittee Name and Title (type or print):
Signature of Preparer* Date
(if different from Permittee)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26)
2/27/2020
Signature of Permittee
Signature of Land Applier Date
(if different from Permittee)
Monday, February 24, 2020

Source Summary Report
Volume plied M Llotal Dry Tons
Elizabeth City W 1P 1,911,000 Gallons 2,044.18
Total 2,044.18
Friday, February 21, 2020 Page 1 of 1

ATLANTIC OBX, INC.
2019 Class A Annual Report
WQ Permit# WQ0040622
Residual SamFling Summary Form
City of Elizabeth City WTP
Field Loading Calculations
2019 Analytical
2019 TCLP

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
WQ Permit No. WQ0040622 Facility Name Atlantic OBX, Inc. Class A Source Permit No. 04-70-010 Source Name Elizabeth City WTP
Laboratory 1
Laboratory 2
Laboratory 3
Sample Date Class A Class B
Paz A-1y""
Pu An.lyu��
Page An.ly�k�
Paz An.lyu��
Paz An lyu��
Paz An lyu��
1/25/2019
3/11/2019
5/14/2019
7/15/2019
9/17/2019
11/5/2019
Aluminum
N/A
N/A
12,000
4,370
7,730
3,070
9,770
9,240
Ammonia Nitrogen
N/A
N/A
9
48
35
32
34
45
Arsenic
41
75
1.5
2.9
2.5
3.1
3.2
3.2
Cadmium
39
85
0.15
0.29
0.25
0.31
0.32
0.32
Calcium
N/A
N/A
280,000
105,000
197,000
72,300
226,000
209,000
Copper
1,500
4,300
1.6
1.5
1.3
1.5
1.6
1.9
Lead
300
840
0.77
1.5
1.2
1.5
1.6
1.6
Magnesium
N/A
N/A
12,300
5,040
8,330
3,190
10,700
10,600
Mercury
17
57
0.023
0.024
0.014
0.0098
0.0064
0.009
Molybdenum
N/A
75
0.77
1.5
1.2
1.5
1.6
1.6
Nickel
420
420
1.5
1.5
1.2
1.5
1.6
1.6
Nitrate -Nitrite Nitrogen
N/A
N/A
32.10
60.60
18.30
13.90
13.80
19.40
Percent Solids
N/A
N/A
21.60
18.60
21.60
28.40
28.60
20.50
PH (no units)
N/A
N/A
10.65
10.62
10.02
9.79
9.37
9.93
Phosphorus
N/A
N/A
60
334
254
228
180
135
Potassium
N/A
N/A
773
1,460
1,250
1,550
1,590
1,620
PAN (Inj./Inc.)
N/A
N/A
41
109
53
46
47
65
PAN (Surface)
N/A
N/A
37
85
36
30
31
42
Selenium
100
100
1.5
2.9
2.5
3.1
3.2
3.2
Sodium
N/A
N/A
773
1,460
1,250
1,550
1,590
1,620
SAR
N/A
N/A
0.18
0.51
0.35
0.82
0.47
0.42
TKN
N/A
N/A
36
224
193
160
205
195
Zinc
2,800
7,500
2.8
2.9
2.5
3.1
3.2
3.2
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to
assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for
submitting false information, including the possibility of fines and imprisonment for knowing violations."
,A� ,QCL 2/28/2020
Signature of Preparer * Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 1/25/2019
Solids 21.6
Mineralization Rate 0
Gallons per DT 1,110.22
pH 10.65
Sodium Absorpotion 0.18 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 36 lbs./1,000 gal 0.06
Ammonia Nitrogen (mg/Kg) 9.30 lbs./1,000 gal 0.02
Nitrate -Nitrite (mg/Kg) 32.10 lbs./1,000 gal 0.06
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 37 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 41 lbs./1,000 gal 0.07
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 1.39
Phosphorus lbs./1,000 gal 0.11
Calcium lbs./1,000 gal 504.40
Magnesium lbs./1,000 gal 22.16
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
1.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.15
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.60
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
0.77
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.02
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
1.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.80
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
36
37 0.07
-1
36
41 0.08
-6
-1
0 0.00
-1
-6
0 0.00
-6
-1
0 0.00
-1
-6
0 0.00
-6
-1
0 0.00
-1
-6
0 0.00
-6
1
0 0.00
-1
-6
0 0.00
-6
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 37 0.07
Total 41 0.08

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: WTP SLUDGE
Pace Project No.: 92415510
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE 1 Lab ID: 92415510001 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
12000
mg/kg
15.5
1
02/04/1910:35
02/05/1918:53
7429-90-5
Arsenic
ND
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7440-38-2
Cadmium
ND
mg/kg
0.15
1
02/04/1910:35
02/05/1918:53
7440-43-9
Calcium
280000
mg/kg
1550
100
02/04/1910:35
02/06/1914:09
7440-70-2
Chromium
1.3
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-47-3
Copper
1.6
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-50-8
Lead
ND
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7439-92-1
Magnesium
12300
mg/kg
15.5
1
02/04/1910:35
02/05/1918:53
7439-95-4
Molybdenum
ND
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7439-98-7
Nickel
1.5
mg/kg
0.77
1
02/04/1910:35
02/05/1918:53
7440-02-0
Potassium
ND
mg/kg
773
1
02/04/1910:35
02/05/1918:53
7440-09-7
Selenium
ND
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7782-49-2
Sodium
ND
mg/kg
773
1
02/04/1910:35
02/05/1918:53
7440-23-5
Zinc
2.8
mg/kg
1.5
1
02/04/1910:35
02/05/1918:53
7440-66-6
7471 Mercury Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
Mercury ND mg/kg 0.023 1 01/29/1918:07 01/30/1913:13 7439-97-6
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 78.4 % 0.10 1 01/30/19 13:26
M1,R1
M6, R1
M1,R1
M1
Sample: WTP SLUDGE 2 Lab ID: 92415510002 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
Date: 02/07/2019 08:49 AM
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod. Preparation Method: EPA 350.1 Rev 2.0 1993 Mod.
ND mg/kg 9.3 1 02/03/1913:33 02/03/1917:06 7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
ND mg/kg 35.7 1 02/02/19 02:22 02/05/19 00:30 7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation Method: EPA 353.2 Rev 2.0 1993
32.1 mg/kg 2.0 1 01/31/19 06:39 01/31/19 10:52
32.1 mg/kg 2.0 1 01/31/19 06:39 01/31/19 10:52 14797-55-8
ND mg/kg 0.99 1 01/31/19 06:39 01/31/19 10:52 14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
60.1 mg/kg 1.0 1 02/04/19 20:06 02/04/19 23:12 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 22

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: WTP SLUDGE
Pace Project No.: 92415510
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WTP SLUDGE 3 Lab ID: 92415510003 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2540G Total Percent Solids Analytical Method: SM 2540G-2011
Total Solids 21.6 % 0.10 1 01/30/19 13:34
1010 Flashpoint,Closed Cup Analytical Method: EPA 1010A
Flashpoint >200 deg F 70.0 1 02/04/19 10:58
4500 Chloride in Soil Analytical Method: SM 4500-CI-E-2011 Preparation Method: SM 4500-CI-E-2011
Chloride 34.6 mg/kg 9.8 1 02/04/19 09:01 02/04/19 11:16 16887-00-6
Sample: WTP SLUDGE 4 Lab ID: 92415510004 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 82.6 % 0.10 1 01/30/19 14:18
9056 IC Anions Analytical Method: EPA 9056 Preparation Method: EPA 9056
Sulfate 995 mg/kg 287 1 02/05/19 08:20 02/06/19 03:00 14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/07/2019 08:49 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 22

CHAIN -OF -CUSTODY I Analytical Request Document
��aceAnalyfical" The Chain -of -Custody Is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
www.pecela0s.corn
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AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 3/11/2019
Solids 18.6
Mineralization Rate 0
Gallons per DT 1,289.29
pH 10.62
Sodium Absorpotion 0.51 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 224 lbs./1,000 gal 0.35
Ammonia Nitrogen (mg/Kg) 48.10 lbs./1,000 gal 0.07
Nitrate -Nitrite (mg/Kg) 60.60 lbs./1,000 gal 0.09
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 85 lbs./1,000 gal 0.13
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 109 lbs./1,000 gal 0.17
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.26
Phosphorus lbs./1,000 gal 0.52
Calcium lbs./1,000 gal 162.88
Magnesium lbs./1,000 gal 7.82
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.90
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.29
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.50
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.50
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.02
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
2.90
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.90
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
224
85 0.17
139
224
109 0.22
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
139
0 0.00
139
115
0 0.00
115
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 85 0.17
Total 109 0.22

aceAnalyfrcal
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i
ANALYTICAL RESULTS
Project: Bi-Monthly Residual Sludge
Pace Project No.: 92420834
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92420834001 Collected: 03/11/19 13:20 Received: 03/12/19 10:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
2540G Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 03/26/2019 02:38 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
4370
mg/kg
29.3
1 03/25/19 13:28
03/26/19 02:36
7429-90-5
M1
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7440-38-2
ND
mg/kg
0.29
1 03/25/19 13:28
03/26/19 02:36
7440-43-9
105000
mg/kg
146
5 03/25/19 13:28
03/26/1911:44
7440-70-2
M1
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-47-3
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-50-8
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7439-92-1
5040
mg/kg
29.3
1 03/25/19 13:28
03/26/19 02:36
7439-95-4
M1
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7439-98-7
ND
mg/kg
1.5
1 03/25/19 13:28
03/26/19 02:36
7440-02-0
ND
mg/kg
1460
1 03/25/19 13:28
03/26/19 02:36
7440-09-7
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7782-49-2
ND
mg/kg
1460
1 03/25/19 13:28
03/26/19 02:36
7440-23-5
ND
mg/kg
2.9
1 03/25/19 13:28
03/26/19 02:36
7440-66-6
P8
Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
ND
mg/kg
0.024
1 03/21/1919:08
03/22/1915:23
7439-97-6
Analytical Method: SM 2540G-2011
18.6
%
0.10
1
03/13/1916:38
Analytical Method: ASTM D2974-87
81.4
%
0.10
1
03/13/1916:31
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
48.1
1 03/18/1915:02
03/19/1915:05
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
224
1 03/20/19 14:00
03/21/19 00:48
7727-37-9
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
334
mg/kg
9.8
2 03/14/19 19:52
03/15/19 22:24
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
214
mg/kg
53.9
1 03/18/1912:01
03/18/1916:43
16887-00-6
M1
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
185
mg/kg
50.0
1 03/13/1916:11
03/14/1912:57
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 16

CHAIN -OF -CUSTODY Analytical Request Document
LAB USE ONLY -Affix Workorder/Lc
WO# : 92420834
,�7ace,AnalXical'
MTJL
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fields
ALL SHADED AR
11111111111111111111111111
92420834
City of Elizabeth City
Billing Information:
1 Wilson St.
U
V
Container
t�
Preservative Type "
t1
iragpr;� :� ��
�'Q"dU
Elizabeth City, NC 27909
ttuckerCC7cityofec.com
Preservative Types: (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, (4) sodium hydroxide, (5) zinc aceWte,
(6) methanol, (7) sodium bisulfate, [R) sodium thiosulfate, (9) hexane, (A) ascorbi nd, (8) ammonium sulfate, o�
Travis Tucker
Site Collection info/Address:
(C) ammonium
hydroxide,
(D)
TSP, (U) Unpreserved, (0)
Other = de f �'�, 3
Analyses
Lab Pr e I e:
Bi-Monthly Residuals
Y
County/City:
State: Count Ci Time Zone Collected:
Lab Sample Receipt Checklist:
Custody Seals Present/Intact Y N X-11
Custody Signatures Present y N �A
/ [ ]PT [ ]MT [ ]CT [ ]FT
Site/Facility ID #:
Compliance Monitoring?
252-33S-2196
[ ] Yes [ ] No
Collector Signature Present N NA
Bottles Intact N NA
Correct Bottles Ilt N NA
Cal cted By (prin1� r
Purchase Order # :
DW PWS ID #:
Quote M
DW Location Code:
k
F
_
O
Sufficient volume }' N NA
Samples Received on Ice k N NA
By
Turnaround
Collected (sign r
Date Required:
Immediately Packed on Ice:
VOA — Headspace
[ ] Yes [ ] No
Q
Zm
`
Acceptable Y N/
USDA Regulated Soils Y %A
Sample Disposal:
Rush:
Field Filtered (if applicable):
V�
0
Cii
Caf`
Samples in Holding Time NA
[ ] Dispose as appropriate [ ] Return
[ ] Same Day [ ] Next Day
[ ] Yes [ ] No
2
Q
3
Residual Chlorine Present Y N�
[ ]Archive:
2 [ Da 3 Da A Da 5 Da
] Y [ ] Y [ ] Y [ ] Y
2
Cl Strips: /
] ]�O€d'
(Expedite Charges Apply)
Analysis:
C3
Q
crj
Z
J
2
Sample pH Acceptable Y N jrA
pH Strips:
Sulfide Present Y N
" Matr€x Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water (GW), Wastewater (WW),
Product (PI, Soil/Solid (SL), oil (OL),
Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
W
Q
W
p
(�
Lead Acetate Strips:
>1
cV
¢
V)
J
0
W
LAB USE ONLY:
Comp/
Collected
Composite End
Res
#of
Customer Sample ID
Matrix `
Grab
Composite Start)
Cl
Ctns
t0
J
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r
Lab Sample # / Comments:
Date
Time
Date
Time
4
D
0
T
U
Cr-
f�
PT, 1G�Gv
c
&I
ff Z)el
)
I
X
X
X
X
Customer Remarks / Special Conditions / Possible Hazards: Type of Ice Used: 10 Blue Dry None
Packing Material Used:
Radchem sample(s) screened (<500 cpm): Y N NA
Relinouish�y/Co man : (5' nature} Date/Time: ReCeiv Com any: (Signature)
(� - G i 1 i
Relinquished by/Comps y: (Signature) Date/Time: Received by/Company: (5ignature)
IRT HOLDS PRESENT (<72 hours) : Y,,,< N/A
Tracking N:
pies r eived via:
X UPS Client
Courier Pace Courier
Date/Time:
I MTJL LAB USE ONLY
3'fz711
Table #:
Date/Time:
Acctnum:
Sample Temperature info:
p Blank Received- Y-
rm I DN : >r
ter 1 Temp Upon Receipt, /.roC
ter 1 Therm Corr- Factor: oC
I.er 1 Corrected Temp: C
vents:
Trip Blank Received: Y NA
HCL McOH TSP Other
Pre:
Relinquished by/Company: (Signature) Date/Time: Received by/Company: (Signature) Date/Time: PM: { 1 Non Conformance(s): Page:
PS: f' ,�� 2_ ��,(jj YES / NO Of:_�

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: RESAMPLE NO2/NO3
Pace Project No.: 92422280
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WATER PLANT Lab ID: 92422280001 Collected: 03/20/19 14:11 Received: 03/21/19 10:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
93.5 %
0.10 1
03/25/19 12:50
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24
Nitrogen, Nitrate
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24 14797-55-8
Nitrogen, Nitrite
ND mg/kg
60.6 1
03/22/19 02:18 03/22/19 03:24 14797-65-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/29/2019 10:41 AM without the written consent of Pace Analytical Services, LLC.
Page 4 of 9

Wok : 924222s0
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Raymond Staten
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Elizabeth City, NC 27907
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Immediately on
I Yes [ } No ;
:
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AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 5/14/2019
Solids 21.6
Mineralization Rate 0
Gallons per DT 1,110.22
pH 10.02
Sodium Absorpotion 0.35 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 193 lbs./1,000 gal 0.35
Ammonia Nitrogen (mg/Kg) 35.10 lbs./1,000 gal 0.06
Nitrate -Nitrite (mg/Kg) 18.30 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 36 lbs./1,000 gal 0.06
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 53 lbs./1,000 gal 0.10
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.25
Phosphorus lbs./1,000 gal 0.46
Calcium lbs./1,000 gal 354.88
Magnesium lbs./1,000 gal 15.01
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
2.50
Arsenic lbs./1,000 gal
0.00
Cadmium (mg/Kg)
0.25
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.30
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.20
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.20
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
2.50
Selenium lbs./1,000 gal
0.00
Zinc (mg/Kg)
2.50
Zinc lbs./1,000 gal
0.00
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
193
36 0.07
157
193
53 0.11
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
157
0 0.00
157
140
0 0.00
140
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 36 0.07
Total 53 0.11

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Bi-Monthly Residuals
Pace Project No.: 92429276
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water -Plant Sludge Lab ID: 92429276001 Collected: 05/14/19 13:15 Received: 05/15/19 10:00 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
9056 IC Anions
Sulfate
Date: 05/29/2019 05:58 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
7730
mg/kg
24.9
1
05/28/19 16:47
05/29/19 03:25
7429-90-5
M1
ND
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7440-38-2
ND
mg/kg
0.25
1
05/28/19 16:47
05/29/19 03:25
7440-43-9
197000
mg/kg
249
10
05/28/19 16:47
05/29/1915:07
7440-70-2
M6
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-47-3
1.3
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-50-8
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7439-92-1
8330
mg/kg
24.9
1
05/28/19 16:47
05/29/19 03:25
7439-95-4
M1
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7439-98-7
ND
mg/kg
1.2
1
05/28/19 16:47
05/29/19 03:25
7440-02-0
ND
mg/kg
1250
1
05/28/19 16:47
05/29/19 03:25
7440-09-7
ND
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7782-49-2
ND
mg/kg
1250
1
05/28/19 16:47
05/29/19 03:25
7440-23-5
2.5
mg/kg
2.5
1
05/28/19 16:47
05/29/19 03:25
7440-66-6
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
ND
mg/kg
0.014
1
05/16/1915:42
05/17/1910:56
7439-97-6
Analytical Method: SM 254OG-2011
21.6
%
0.10
1
05/16/1914:26
Analytical Method: ASTM D2974-87
78.4
%
0.10
1
05/16/1914:18
Analytical Method: EPA 350.1 Rev 2.0 1993 Mod.
Preparation
Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
35.1
1
05/21/19 07:56
05/21/19 15:16
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
193
1
05/19/1915:08
05/20/1913:23
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0 1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
14797-55-8
ND
mg/kg
18.3
1
05/15/19 22:58
05/16/19 00:50
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
254
mg/kg
4.2
1
05/21/19 18:11
05/21/19 22:31
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
523
mg/kg
92.3
2
05/17/19 21:45
05/17/19 23:44
16887-00-6
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
210
mg/kg
49.7
1
05/20/19 11:43
05/21/19 21:46
14808-79-8
M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 17

CHAIN -Of -CUSTODY Analytical Request Document
aceAnalX cal
Chain-of-CuStodyis a LEGAL DOCUMENT - Complete all relevent fields
City of Elizabeth CityRillIn& Information:
1 Wilson St.
Elizabeth Ciry, NC 279D9 ttt1C[Cer C OtE'C,COfTi
rRAVIS TUCKER
Site Collection Info/Address:
BrMonthly Residuals
State: County/City: Time Zone Collected:
/ [ ]PT I IMT I ]Cf [ ]ET
252-337-6626
Site/Facility ID #:
Compliance Manitaring7
[ ] Yes [ ] Nb
Collected By (print):
� �-'
Purchase Order#:
DIN PW51D #:
S c r
Quote 9:
DW tocateon Code:
Co (sligDatwel.
Turnaround Date Required:
immediately Packed on ice-
Sample Disposal:
Rush:
[ ) Yes [ ] No
[ ] Disposeas appropriate [ ] Rh Wrr
[ ] Same Day [ ] NCxt Day
Field Filtered {if applicable):
] ]Yes [ ] No
[ ] Archive:
[ ] Hold:
I ] 2 Day [ ] 3 Day [ ] 4 Day [ ] 5 Day
(Expedite Charges Apply]
Analysis:
" Matrix Codes (Insert in Matrix box below): Drinking Water (DW), Ground Water {GW), Wastewater (WW),
Product (P), Soil/Solid (5L), Oil (OL), Wipe (WP), Air [AR), Tissue (TS), Bioassay (B), Vapor (V), Other (OT)
Customer Sample ID
Matrix •
Comp /
Grab
Collected (or
Composite Start)
Composite End
Res
# of
Cl
Ctns
Date
Time
Date
Time
SL
S
6
Customer Remarks / Special Conditions / Possible Hazards:
f5
a Relinquished by/Company: (Signature) t]ate/71me:
tv
0
by/Company. (Signature}
el'�,•
A� t��L•WO#:.. 92429276
Y_iS<tl{1 u1�'.4;5)1'iIi1G:�l 1 III
ContainerPreseryativeType"'•
U g2429276
nIl f cic13T,j' U 5;:.NU U wa r
.�11 �!1134t1h,
••,Preservative Types; (1) nitric acid, (2) sulfuric acid, (3) hydrochloric acid, ) sodium hydroxide, (5) zinc acetate, _
(6) methanol, (7) sodium bisuffate, (a) sodium thiowl(atc, (9) hexane, (Aj a or c1, ooLum sulfate,
(C] ammonium hydroxide, (D) 7SP, (U) Unpreserved, (0) Other
Analyses `l , -4a •.:�a
Jal
k X
O
Q ar if
Oy li -i .,� M-}ice q Nl'h�
nIIII ' 1 :Iy!Fir,
LU
tLb
La �i�!�h �n& ♦— 4t3. �
"..I. X etiil X ! , iiL X
1 VOL,
0.

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 7/15/2019
Solids 28.4
Mineralization Rate 0
Gallons per DT 844.39
pH 9.79
Sodium Absorpotion 0.82 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 160 lbs./1,000 gal 0.38
Ammonia Nitrogen (mg/Kg) 32.00 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 13.90 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 30 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 46 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.67
Phosphorus lbs./1,000 gal 0.54
Calcium lbs./1,000 gal 171.25
Magnesium lbs./1,000 gal 7.56
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.10
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.31
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.50
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.50
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.50
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.10
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.10
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
160
30 0.06
130
160
46 0.09
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
130
0 0.00
130
114
0 0.00
114
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 30 0.06
Total 46 0.09

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: Bi-Monthly Residuals 07-15-19
Pace Project No.: 92436946
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92436946001 Collected: 07/15/19 13:20 Received: 07/16/19 10:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Arsenic
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Molybdenum
Nickel
Potassium
Selenium
Sodium
Zinc
7471 Mercury
Mercury
254OG Total Percent Solids
Total Solids
Percent Moisture
Percent Moisture
350.1 Ammonia
Nitrogen, Ammonia
351.2 Total Kjeldahl Nitrogen
Nitrogen, Kjeldahl, Total
353.2 Nitrogen, NO2/NO3
Nitrogen, NO2 plus NO3
Nitrogen, Nitrate
Nitrogen, Nitrite
365.1 Phosphorus, Total
Phosphorus
4500 Chloride in Soil
Chloride
Date: 07/30/2019 05:01 PM
Analytical Method: EPA6010D Preparation Method: EPA3050B
3070
mg/kg
30.9
1 07/29/1916:50
07/29/1919:55
7429-90-5
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7440-38-2
ND
mg/kg
0.31
1 07/29/1916:50
07/29/1919:55
7440-43-9
72300
mg/kg
155
5 07/29/1916:50
07/30/1912:45
7440-70-2 M1
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-47-3
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-50-8
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7439-92-1
3190
mg/kg
30.9
1 07/29/1916:50
07/29/1919:55
7439-95-4
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7439-98-7
ND
mg/kg
1.5
1 07/29/1916:50
07/29/1919:55
7440-02-0
ND
mg/kg
1550
1 07/29/1916:50
07/29/1919:55
7440-09-7
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7782-49-2
ND
mg/kg
1550
1 07/29/1916:50
07/29/1919:55
7440-23-5
ND
mg/kg
3.1
1 07/29/1916:50
07/29/1919:55
7440-66-6
Analytical Method: EPA 7471 B Preparation Method: EPA 7471 B
ND
mg/kg
0.0098
1 07/24/19 08:59
07/24/19 11:18
7439-97-6
Analytical Method: SM 254OG-2011
28.4
%
0.10
1
07/17/1918:23
Analytical Method: ASTM D2974-87
71.6
%
0.10
1
07/17/1918:16
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
ND
mg/kg
32.0
1 07/18/19 07:18
07/18/19 12:28
7664-41-7
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation
Method: EPA 351.2 Rev 2.0 1993
ND
mg/kg
160
1 07/23/19 05:17
07/25/19 03:35
7727-37-9
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation
Method: EPA 353.2 Rev 2.0 1993
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
14797-55-8
ND
mg/kg
13.9
1 07/16/19 22:10
07/17/19 00:10
14797-65-0
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation
Method: EPA 365.1 Rev 2.0 1993
228
mg/kg
3.0
1 07/18/19 19:08
07/18/19 22:39
7723-14-0
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
149
mg/kg
34.8
1 07/29/19 17:00
07/29/19 20:22
16887-00-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 16

WO#:92436946
CHAIN -OF -CUSTODY Analytical Request u�i.. o.. VIM -.tier Ini fill
1111111111
y est RocumeRt b l � i�d;�li±l: �}[ l
aceAnalyticaf ,:. �., 92436948
Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevent fietds )y: ;: -: I� f
City of Elizabeth City Ulllltaµ. 7-1
'Pk Billin Information: a [g[)1�1)1$ilU[ffg ':11 ivil,tl!`� Vt�ISi w,lsan St.0
1 6 �li4 ihrsiryair.I: :(d'Xr r+ i rn]u1+FdAmr
Container Preservative Type" I' F ' °,, u t' !s
Elizabeth aty, NC z7sas kllt)i'i' u „it ii u u l Is le �i6 � i� [ I "`>�'�f� +, � ni I i flu*�
#fuckeralcityofec-com ,k[ �, 9 K�illll�!�
" Pr arvative Types: 11) nhric add, (2) sulfuric acid, (3) hydrochloric acid, 44) sodium hydroxide, (5] zinc acetate,
TRAVISTUCKER Site Collection Info/Address {e} m harrol, (?) sodium bisulfate, !$) sodium ihiosulfate, (9) hexane, (a] asc e,
(C) am nium hydroxide, ID) TSP, (U) Unpreserved, (al,other 7 [ 6
Analyses
Bi-MonthlyResiduals State: County/City: Time Zone Collected: "64
+•' n nnIMuFLU' iN
lr,i, y ii: iliSxM@d1}wd a'q,
ON
Site/Facility ID #: Compl lance Monitoring? I I >:=
252-337-6626 [ igii+l�Fj�Yi+
f,i yl>,syzw N`
[ ] Y� I ] No IP,II .~' ( li"tmP
CoNected 8y (printer- Purchase Order # : DW PWS ID ti: +, tl+.:.',:+ ntl ��VA11
r I - Iprtririll Uli�[i�
rijiH 1x luif, i4xin! _. I
❑WLoptlonCode: ' II f , �, 4 p P101�. SG4£Firelph ht Iv_F S�e'M'S4 luh [
ut [.,. .... C.a r
Co lest Igna 7esrnaround Date Required; Immedlately Patked on Ice: ,� a( i I�IIII
.... ( ] Yes [ No 4 �is+fa ltl7flpN![ k�: n 4 Ilffl,r d�l[Fd_: k'
ww iAF+#)!il
Sample sposal: Rush: Field Filtered (if applicable ' ur�s���I�"'
( )Dispose as apPrnPriafr [ )Return [ ]Same Day ) ]Next Day [ ]Yes [ I No '' r'M' 1{(ldllit4 -Itn ' Ih+I; $ems ar '•. y.. - uFlH
I ] Ardilve: [ ] 2 Day [ 1 3 Day [ ] b Day [ ] 5 Day
[ }Hold: (Expedite thagesApply) Analysis_ M co
i I C3 f +3 t P
' Matrix Codes {Insert In Matrix box below): Drinking Water OWL Ground Water G 0
} ng { ( W), Wastewater ni 2+�I K I ^
Product (P), Soil/Soild (51.), Oil (OL), Wipe (WP), Air (AR), Tissue (TS), BioassayB , Va or �� ,I L �� O rt C7 A J Lead. hcb atelf 19 3 iIl e lj r ill
(} P M, Other q � _ I�l�I � _` s r ! •,
I Q)--d;� 4 ) lh "{,MI rri FI `� +:'aE -�„ .t�h.k� kith;:
Comp/ Collected Res #of J '<L''
Composite End
Customer5omplelD Matrix Grab Composite Start) CI Ctns
❑ate Time Date Time O �:S<:[ri.�?`I ? '`ill 1, Ijr; • r: au,h,,,;..1� , I I r
1 5L ,`
5YE�� X i:.._ X ilk X ,�I,il
Customer Remarks / SpeclaI Canditrons / Possible Hazards:
Relinquished by/ ompany:
p Relinquished by/Company-
m
0
rn
DatefFime:
by/Company: (Signature) oatejr me.
Page:

AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 9/17/2019
Solids 28.6
Mineralization Rate 0
Gallons per DT 838.49
pH 9.37
Sodium Absorpotion 0.47 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 205 lbs./1,000 gal 0.49
Ammonia Nitrogen (mg/Kg) 33.60 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 13.80 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 31 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 47 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 3.79
Phosphorus lbs./1,000 gal 0.43
Calcium lbs./1,000 gal 539.06
Magnesium lbs./1,000 gal 25.52
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.20
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.32
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.60
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.20
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.20
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
205
31 0.06
174
205
47 0.09
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
174
0 0.00
174
158
0 0.00
158
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 31 0.06
Total 47 0.09

aceAnalyfrcal
..pacelabs.com
i
ANALYTICAL RESULTS
Project: BI MONTHLY RESIDUALS
Pace Project No.: 92446061
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: WATER PLANT SLUDGE Lab ID: 92446061001 Collected: 09/17/19 13:48 Received: 09/18/19 10:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
9770 mg/kg
31.8
1 09/23/19 11:35
09/25/19 04:45
7429-90-5
Arsenic
ND mg/kg
3.2
1 09/23/19 11:35
09/25/19 04:45
7440-38-2
Cadmium
ND mg/kg
0.32
1 09/23/19 11:35
09/25/19 04:45
7440-43-9
Calcium
226000 mg/kg
318
10 09/23/19 11:35
09/25/1914:40
7440-70-2
Chromium
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-47-3
Copper
1.6 mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-50-8
Lead
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7439-92-1
Magnesium
10700 mg/kg
31.8
1 09/23/19 11:35
09/25/19 04:45
7439-95-4
Molybdenum
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7439-98-7
Nickel
ND mg/kg
1.6
1 09/23/19 11:35
09/25/19 04:45
7440-02-0
Potassium
ND mg/kg
1590
1 09/23/19 11:35
09/25/19 04:45
7440-09-7
Selenium
ND mg/kg
3.2
1 09/23/19 11:35
09/25/19 04:45
7782-49-2
Sodium
ND mg/kg
1590
1 09/23/19 11:35
09/25/19 04:45
7440-23-5
Zinc
ND mg/kg
3.2
1 09/23/19 11:35
09/25/1915:04
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
ND mg/kg
0.0064
1 09/19/1912:30
09/19/1914:17
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
28.6 %
0.10
1
09/19/19 17:14
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
71.4 %
0.10
1
09/19/19 17:11
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
ND mg/kg
33.6
1 09/18/19 23:45
09/19/19 21:44
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
205 mg/kg
116
1 09/24/19 02:28
09/25/19 03:38
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
Nitrogen, Nitrate
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
14797-55-8
Nitrogen, Nitrite
ND mg/kg
13.8
1 09/18/19 23:58
09/19/19 01:45
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
180 mg/kg
3.5
1 09/20/19 19:11
09/23/19 21:12
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
209 mg/kg
34.8
1 09/30/19 15:19
09/30/19 20:16
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
Sulfate
0.068 % (w/w)
0.017
1 09/23/19 15:30
09/23/19 19:50
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/01/2019 09:58 AM without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

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AGMAN
FIELD LOADING ESTIMATES
Facility Elizabeth City W` P
Sampling Date 11/5/2019
Solids 20.5
Mineralization Rate 0
Gallons per DT 1,169.80
pH 9.93
Sodium Absorpotion 0.42 <5.0 Safe 5.0 - 10.0 Careful Management > 15.0 Do Not Land Apply
Ratio
NITROGEN APPLICATION
TKN (mg/Kg) 195 lbs./1,000 gal 0.33
Ammonia Nitrogen (mg/Kg) 45.10 lbs./1,000 gal 0.08
Nitrate -Nitrite (mg/Kg) 19.40 lbs./1,000 gal 0.03
PLANT AVAILABLE NITROGEN SURFACE APPLIED
PAN (mg/Kg) 42 lbs./1,000 gal 0.07
PLANT AVAILABLE NITROGEN INJECTED/INCORPORATED APPLIED
PAN (mg/Kg) 65 lbs./1,000 gal 0.11
Volatization Rate= 0.5 Surface Application
1.0 Injection/Incorporation
EPA METAL LIMITS
Class A Ceiling
Class B Ceiling
Limits (mg/Kg)
Limits (mg/Kg)
41
75
39
85
1,500
4,300
300
840
17
57
420
420
100
100
2,800
7,500
1 st Year
2nd Year
3rd Year
4th Year
5th Year
HEAVY METAL CONCENTRATION
NUTRIENT APPLICATION
Potassium lbs./1,000 gal 2.77
Phosphorus lbs./1,000 gal 0.23
Calcium lbs./1,000 gal 357.33
Magnesium lbs./1,000 gal 18.12
Manganese lbs./1,000 gal
Sulfur lbs./1,000 gal
Molybdenum lbs./1,000 gal 0.00
HEAVY METAL LOADING
Arsenic (mg/Kg)
3.20
Arsenic lbs./1,000 gal
0.01
Cadmium (mg/Kg)
0.32
Cadmium lbs./1,000 gal
0.00
Copper (mg/Kg)
1.90
Copper lbs./1,000 gal
0.00
Lead (mg/Kg)
1.60
Lead lbs./1,000 gal
0.00
Mercury (mg/Kg)
0.01
Mercury lbs./1,000 gal
0.00
Nickel (mg/Kg)
1.60
Nickel lbs./1,000 gal
0.00
Selenium (mg/Kg)
3.20
Selenium lbs./1,000 gal
0.01
Zinc (mg/Kg)
3.20
Zinc lbs./1,000 gal
0.01
RESIDUAL NITROGEN CALCULATION
Surface Application
Injection/Incorporation Application
Remaining
Remaining
Organic
Organic
PAN PAN
Nitrogen
PAN PAN
Nitrogen
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
TKN
(mg/kg) (lbs/DT)
(mg/Kg)
195
42 0.08
153
195
65 0.13
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
153
0 0.00
153
131
0 0.00
131
Equations
1 st Yr. PAN (mg/Kg)-(MR
x (TKN-NH3))+(VR x NH3)+NOx
2nd Yr PAN (mg/Kg)-
2nd Yr. TKN x (MR/2)
3rd Yr PAN (mg/Kg)-
3rd Yr. TKN x (MR/4)
4th Yr PAN (mg/Kg)-
4th Yr. TKN x (MR/8)
5th Yr PAN (mg/Kg)-
5th Yr. TKN x (MR/16)
Total 42 0.08
Total 65 0.13

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ANALYTICAL RESULTS
Project: BiMonthly Res Sludge (11/5/19)
Pace Project No.: 92452481
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: Water Plant Sludge Lab ID: 92452481001 Collected: 11/05/19 13:25 Received: 11/06/19 10:10 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010D Preparation Method: EPA 3050B
Aluminum
9240 mg/kg
32.5
1 11/13/1913:50
11/15/1911:07
7429-90-5
Arsenic
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7440-38-2
Cadmium
ND mg/kg
0.32
1 11/13/1913:50
11/15/1911:07
7440-43-9
Calcium
209000 mg/kg
325
10 11/13/1913:50
11/17/1919:31
7440-70-2
Chromium
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-47-3
Copper
1.9 mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-50-8
Lead
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7439-92-1
Magnesium
10600 mg/kg
32.5
1 11/13/1913:50
11/15/1911:07
7439-95-4
Molybdenum
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7439-98-7
Nickel
ND mg/kg
1.6
1 11/13/1913:50
11/15/1911:07
7440-02-0
Potassium
ND mg/kg
1620
1 11/13/1913:50
11/15/1911:07
7440-09-7
Selenium
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7782-49-2
Sodium
ND mg/kg
1620
1 11/13/1913:50
11/15/1911:07
7440-23-5
Zinc
ND mg/kg
3.2
1 11/13/1913:50
11/15/1911:07
7440-66-6
7471 Mercury
Analytical Method: EPA 7471 B Preparation Method:
EPA 7471 B
Mercury
ND mg/kg
0.0090
1 11/11/1918:45
11/13/1915:02
7439-97-6
254OG Total Percent Solids
Analytical Method: SM 254OG-2011
Total Solids
20.5 %
0.10
1
11/07/19 15:09
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
79.5 %
0.10
1
11/07/19 14:58
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0
1993 Mod.
Preparation Method:
EPA 350.1 Rev 2.0
1993 Mod.
Nitrogen, Ammonia
ND mg/kg
45.1
1 11/12/19 16:15
11/12/19 22:32
7664-41-7
351.2 Total Kjeldahl Nitrogen
Analytical Method: EPA 351.2 Rev 2.0
1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Nitrogen, Kjeldahl, Total
ND mg/kg
195
1 11/14/19 04:48
11/15/19 06:49
7727-37-9
353.2 Nitrogen, NO2/NO3
Analytical Method: EPA 353.2 Rev 2.0
1993 Preparation Method: EPA 353.2 Rev 2.0 1993
Nitrogen, NO2 plus NO3
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
Nitrogen, Nitrate
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
14797-55-8
Nitrogen, Nitrite
ND mg/kg
19.4
1 11/06/19 22:43
11/07/19 00:06
14797-65-0
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.0
1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Phosphorus
135 mg/kg
4.8
1 11/13/19 19:03
11/13/19 21:35
7723-14-0
4500 Chloride in Soil
Analytical Method: SM 4500-CI-E-2011
Preparation
Method: SM 4500-CI-E-2011
Chloride
339 mg/kg
48.1
1 11/19/1917:30
11/19/1919:52
16887-00-6
9056 IC Anions
Analytical Method: EPA 9056A Preparation Method: EPA 9056A
Sulfate
803 mg/kg
242
1 11/12/19 15:17
11/12/19 21:43
14808-79-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 11 /27/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 4 of 18

WOp:92452481
1111111111111111111111
V
O
OD

_ ;a'ne A nalytica(
www.paco;abs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 12, 2019
Travis Tucker
Elizabeth City
1 Wilson Street
Elizabeth City, NC 27909
RE: Project: TCLP SLUDGE
Pace Project No.: 92415518
Dear Travis Tucker:
Enclosed are the analytical results for sample(s) received by the laboratory on January 28, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
PwtvL
Kristi Prater
[e-mail]
[phone]
Project Coordinator
Enclosures
cc: Accounts Payable, City of Elizabeth City
Raymond Staten, City of Elizabeth City
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 25

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Project: TCLP SLUDGE
Pace Project No.: 92415518
Atlanta Certification IDs
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Pennsylvania Certification IDs
1638 Roseytown Rd Suites 2,3&4, Greensburg, PA 15601
ANAB DOD-ELAP Rad Accreditation #: L2417
Alabama Certification #: 41590
Arizona Certification #: AZ0734
Arkansas Certification
California Certification #: 04222CA
Colorado Certification #: PA01547
Connecticut Certification #: PH-0694
Delaware Certification
EPA Region 4 DW Rad
Florida/TNI Certification #: E87683
Georgia Certification #: C040
Guam Certification
Hawaii Certification
Idaho Certification
Illinois Certification
Indiana Certification
Iowa Certification #: 391
Kansas/TNI Certification #: E-10358
Kentucky Certification #: KY90133
KY WW Permit #: KY0098221
KY WW Permit #: KY0000221
Louisiana DHH/TNI Certification #: LA180012
Louisiana DEQ/TNI Certification #: 4086
Maine Certification #: 2017020
Maryland Certification #: 308
Massachusetts Certification #: M-PA1457
Michigan/PADEP Certification #: 9991
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
Missouri Certification #: 235
Montana Certification #: Cert0082
Nebraska Certification #: NE-OS-29-14
Nevada Certification #: PA014572018-1
New Hampshire/TNI Certification #: 297617
New Jersey/TNI Certification #: PA051
New Mexico Certification #: PA01457
New York/TNI Certification #: 10888
North Carolina Certification #: 42706
North Dakota Certification #: R-190
Ohio EPA Rad Approval: #41249
Oregon/TNI Certification #: PA200002-010
Pennsylvania/TNI Certification #: 65-00282
Puerto Rico Certification #: PA01457
Rhode Island Certification #: 65-00282
South Dakota Certification
Tennessee Certification #: 02867
Texas/TNI Certification #: T104704188-17-3
Utah/TNI Certification #: PA014572017-9
USDA Soil Permit #: P330-17-00091
Vermont Dept. of Health: ID# VT-0282
Virgin Island/PADEP Certification
Virginia/VELAP Certification #: 9526
Washington Certification #: C868
West Virginia DEP Certification #: 143
West Virginia DHHR Certification #: 9964C
Wisconsin Approve List for Rad
Wyoming Certification #: 8TMS-L
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 25

Pace Analytical Services, LLC
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Huntersville, NC 28078
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i
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
TCLP SLUDGE
92415518
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92415518001
SLUDGE 5
ASTM D2974-87
AK1
1
PASI-PA
EPA 9014
PAS
1
PASI-PA
SM 4500S2F-00
PAS
1
PASI-PA
92415518002
SLUDGE 6
ASTM D2974-87
AK1
1
PASI-PA
EPA 1010
PJD
1
PASI-PA
EPA9045C
ZMH
1
PASI-PA
92415518003
SLUDGE 7
EPA 8260B
SAS
14
PASI-C
92415518004
SLUDGE 8
EPA 8270D
PKS
18
PASI-C
92415518005
SLUDGE 9
EPA 8081 B
SEM
9
PASI-C
92415518006
SLUDGE 10
EPA 8151A
MZP
3
PASI-GA
92415518007
SLUDGE 11
EPA 6010D
DS
7
PASI-A
EPA 7470A
RDT
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 25

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ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 5 Lab ID: 92415518001 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 75.0 % 0.10 1 02/07/19 11:59
733C S Reactive Cyanide Analytical Method: EPA 9014 Preparation Method: SW-846 7.3.3.2
Cyanide, Reactive ND mg/kg 4.0 1 01/31/19 20:24 01/31/19 21:24
734S Reactive Sulfide Analytical Method: SM 4500S2F-00 Preparation Method: SW-846 7.3.4.2
Sulfide, Reactive ND mg/kg 39.8 1 01/31/19 20:24 01/31/19 20:27
Sample: SLUDGE 6 Lab ID: 92415518002 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
73.3 % 0.10 1
02/07/19 11:59
1010 Flashpoint,Closed Cup
Analytical Method: EPA 1010
Flashpoint
>200 deg F 60.0 1
02/01/19 18:23
9045 pH Soil
Analytical Method: EPA 9045C
pH in water at 25 degrees C
9.1 Std. Units 2.0 1
01/30/19 21:23 H3
Sample: SLUDGE 7
Lab ID: 92415518003 Collected: 01/25/19 14:02
Received:
01/28/19 12:30 Matrix: Solid
Results reported on a "wet -weight"
basis
Parameters
Results Units Report Limit DF
Prepared
Analyzed CAS No. Qual
8260 MSV TCLP Analytical Method: EPA8260B Leachate Method/Date: EPA 1311; 01/31/19 08:19
Benzene
ND
ug/L
100
20
01/31/19 23:17
71-43-2
2-Butanone (MEK)
ND
ug/L
200
20
01/31/19 23:17
78-93-3
Carbon tetrachloride
ND
ug/L
100
20
01/31/19 23:17
56-23-5
Chlorobenzene
ND
ug/L
100
20
01/31/19 23:17
108-90-7
Chloroform
ND
ug/L
100
20
01/31/19 23:17
67-66-3
1,4-Dichlorobenzene
ND
ug/L
100
20
01/31/19 23:17
106-46-7
1,2-Dichloroethane
ND
ug/L
100
20
01/31/19 23:17
107-06-2
1,1-Dichloroethene
ND
ug/L
100
20
01/31/19 23:17
75-35-4
Tetrachloroethene
ND
ug/L
100
20
01/31/19 23:17
127-18-4
Trichloroethene
ND
ug/L
100
20
01/31/19 23:17
79-01-6
Vinyl chloride
ND
ug/L
100
20
01/31/19 23:17
75-01-4
Surrogates
1,2-Dichloroethane-d4 (S)
99
%
70-130
20
01/31/19 23:17
17060-07-0
Toluene-d8 (S)
103
%
67-135
20
01/31/19 23:17
2037-26-5
4-Bromofluorobenzene (S)
101
%
70-130
20
01/31/19 23:17
460-00-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM
without
the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 8 Lab ID: 92415518004 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
1,4-Dichlorobenzene
2,4-Dinitrotoluene
Hexachloro-1,3-butadiene
Hexachlorobenzene
Hexachloroethane
2-Methyl phenol(o-Cresol)
3&4-Methylphenol (m&p Cresol)
Nitrobenzene
Pentachlorophenol
Pyridine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/30/19 18:17
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
106-46-7
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
121-14-2
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
87-68-3
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
118-74-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
67-72-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
95-48-7
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
15831-10-4
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
98-95-3
ND
ug/L
100
1
02/04/19 08:39
02/04/19 18:07
87-86-5
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
110-86-1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
95-95-4 M1
ND
ug/L
50.0
1
02/04/19 08:39
02/04/19 18:07
88-06-2
51
%
12-102
1
02/04/19 08:39
02/04/19 18:07
4165-60-0
52
%
13-107
1
02/04/19 08:39
02/04/19 18:07
321-60-8
59
%
21-132
1
02/04/19 08:39
02/04/19 18:07
1718-51-0
19
%
10-110
1
02/04/19 08:39
02/04/19 18:07
13127-88-3
28
%
10-110
1
02/04/19 08:39
02/04/19 18:07
367-12-4
53
%
27-108
1
02/04/19 08:39
02/04/19 18:07
118-79-6
Sample: SLUDGE 9 Lab ID: 92415518005 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8081 TCLP Pesticides RVE
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
Leachate Method/Date: EPA 1311; 01/30/19 18:17
gamma-BHC (Lindane)
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
58-89-9
Chlordane (Technical)
ND
ug/L
3.0
1
02/04/19 12:06
02/05/19 12:32
57-74-9
Endrin
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
72-20-8
Heptachlor
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
76-44-8
Heptachlor epoxide
ND
ug/L
0.50
1
02/04/19 12:06
02/05/19 12:32
1024-57-3
Methoxychlor
ND
ug/L
1000
1
02/04/19 12:06
02/05/19 12:32
72-43-5
Toxaphene
ND
ug/L
3.0
1
02/04/19 12:06
02/05/19 12:32
8001-35-2
Surrogates
Decachlorobiphenyl (S)
63
%
10-138
1
02/04/19 12:06
02/05/19 12:32
2051-24-3
Tetrachloro-m-xylene (S)
74
%
10-110
1
02/04/19 12:06
02/05/19 12:32
877-09-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: SLUDGE 10
Lab ID: 92415518006 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight"
basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit DF Prepared Analyzed
CAS No. Qual
8151A Cl Acid Herbicides TCLP
Analytical Method: EPA 8151A Preparation Method: EPA 8151A
Leachate Method/Date: EPA 1311; 02/04/19 14:30 Initial pH: 9.68; Final pH: 5.05
2,4-D
ND mg/L 0.0050 1 02/07/1912:00 02/11/1914:09
94-75-7
2,4,5-TP (Silvex)
ND mg/L 0.010 1 02/07/19 12:00 02/11/19 14:09
93-72-1
Surrogates
2,4-DCAA(S)
134 %. 10-155 1 02/07/1912:00 02/11/1914:09
19719-28-9
Sample: SLUDGE 11 Lab ID: 92415518007 Collected: 01/25/19 14:02 Received: 01/28/19 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP, TCLP
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 01/31/19 21:43 Initial pH: 10.19; Final pH: 5
Arsenic
ND mg/L 0.050 1 02/02/1917:57
02/03/1918:25
7440-38-2
Barium
0.48 mg/L 0.25 1 02/02/1917:57
02/03/1918:25
7440-39-3
Cadmium
ND mg/L 0.0050 1 02/02/1917:57
02/03/1918:25
7440-43-9
Chromium
ND mg/L 0.050 1 02/02/1917:57
02/03/1918:25
7440-47-3
Lead
ND mg/L 0.025 1 02/02/1917:57
02/03/1918:25
7439-92-1
Selenium
ND mg/L 0.10 1 02/02/1917:57
02/03/1918:25
7782-49-2
Silver
ND mg/L 0.025 1 02/02/1917:57
02/03/1918:25
7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
Leachate Method/Date: EPA 1311; 01/31/19 21:43 Initial pH: 10.19; Final pH: 5
Mercury
ND mg/L 0.00020 1 02/03/1918:13
02/05/1911:56
7439-97-6
Date: 02/12/2019 08:32 AM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455971
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury TCLP
Associated Lab Samples: 92415518007
METHOD BLANK: 2486987
Matrix: Water
Associated Lab Samples: 92415518007
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
02/05/1911:28
METHOD BLANK: 2487426
Matrix: Water
Associated Lab Samples: 92415518007
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Mercury
mg/L
ND 0.00020
02/05/1911:33
LABORATORY CONTROL SAMPLE: 2488275
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0025
99 80-120
LABORATORY CONTROL SAMPLE: 2489208
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Mercury
mg/L
0.0025 0.0026
104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2488276 2488277
MS MSD
92415888001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units
Result
Cone. Cone. Result
Result % Rec % Rec Limits RPD Qual
Mercury mg/L
ND
0.0025 0.0025 0.0026
0.0025 101 98 75-125 4
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455970 Analysis Method: EPA6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92415518007
METHOD BLANK: 2486987
Matrix:
Water
Associated Lab Samples: 92415518007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
02/03/1917:37
Barium
mg/L
ND
0.25
02/03/1917:37
Cadmium
mg/L
ND
0.0050
02/03/1917:37
Chromium
mg/L
ND
0.050
02/03/1917:37
Lead
mg/L
ND
0.025
02/03/1917:37
Selenium
mg/L
ND
0.10
02/03/1917:37
Silver
mg/L
ND
0.025
02/03/1917:37
METHOD BLANK: 2487426
Matrix:
Water
Associated Lab Samples: 92415518007
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
mg/L
ND
0.050
02/03/1917:44
Barium
mg/L
ND
0.25
02/03/1917:44
Cadmium
mg/L
ND
0.0050
02/03/1917:44
Chromium
mg/L
ND
0.050
02/03/1917:44
Lead
mg/L
ND
0.025
02/03/1917:44
Selenium
mg/L
ND
0.10
02/03/1917:44
Silver
mg/L
ND
0.025
02/03/1917:44
LABORATORY CONTROL SAMPLE:
2488268
Parameter
Units
Arsenic
mg/L
Barium
mg/L
Cadmium
mg/L
Chromium
mg/L
Lead
mg/L
Selenium
mg/L
Silver
mg/L
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Qualifiers
Spike
LCS
LCS
% Rec
Cone.
Result
% Rec
Limits Qualifiers
2.5
2.4
98
80-120
2.5
2.3
94
80-120
2.5
2.4
97
80-120
2.5
2.4
97
80-120
2.5
2.3
94
80-120
2.5
2.6
102
80-120
1.2
1.3
102
80-120
LABORATORY CONTROL SAMPLE: 2488269
Spike LCS LCS % Rec
Parameter Units Cone. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.4 96 80-120
Barium mg/L 2.5 2.4 96 80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2488269
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits Qualifiers
Cadmium
mg/L
2.5
2.4
97
80-120
Chromium
mg/L
2.5
2.4
96
80-120
Lead
mg/L
2.5
2.4
95
80-120
Selenium
mg/L
2.5
2.6
103
80-120
Silver
mg/L
1.2
1.2
99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2488270
2488271
MS
MSD
35444773001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Arsenic
mg/L
0.0141-1
2.5
2.5
2.4
2.4
96
96
75-125
0
Barium
mg/L
0.16J
2.5
2.5
2.5
2.5
95
95
75-125
1
Cadmium
mg/L
0.0025
2.5
2.5
2.4
2.4
97
97
75-125
0
U
Chromium
mg/L
0.012J
2.5
2.5
2.4
2.4
96
95
75-125
1
Lead
mg/L
0.091
2.5
2.5
2.4
2.4
93
93
75-125
0
Selenium
mg/L
0.0191-1
2.5
2.5
2.6
2.6
103
102
75-125
1
Silver
mg/L
0.00050
1.2
1.2
1.3
1.3
101
100
75-125
1
U
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 25

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 455666
Analysis Method:
EPA 8260B
QC Batch Method: EPA 8260B
Analysis Description:
8260 MSV TCLP
Associated Lab Samples: 92415518003
METHOD BLANK: 2485805
Matrix: Water
Associated Lab Samples: 92415518003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Qualifiers
1,1-Dichloroethene
ug/L
ND
5.0
01/31/19 21:52
1,2-Dichloroethane
ug/L
ND
5.0
01/31/19 21:52
1,4-Dichlorobenzene
ug/L
ND
5.0
01/31/19 21:52
2-Butanone (MEK)
ug/L
ND
10.0
01/31/19 21:52
Benzene
ug/L
ND
5.0
01/31/19 21:52
Carbon tetrachloride
ug/L
ND
5.0
01/31/19 21:52
Chlorobenzene
ug/L
ND
5.0
01/31/19 21:52
Chloroform
ug/L
ND
5.0
01/31/19 21:52
Tetrachloroethene
ug/L
ND
5.0
01/31/19 21:52
Trichloroethene
ug/L
ND
5.0
01/31/19 21:52
Vinyl chloride
ug/L
ND
5.0
01/31/19 21:52
1,2-Dichloroethane-d4 (S)
%
97
70-130
01/31/19 21:52
4-Bromofluorobenzene (S)
%
98
70-130
01/31/19 21:52
Toluene-d8 (S)
%
104
67-135
01/31/19 21:52
LABORATORY CONTROL SAMPLE: 2486975
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits Qualifiers
1,1-Dichloroethene
ug/L
50
49.8
100
70-130
1,2-Dichloroethane
ug/L
50
44.8
90
70-130
1,4-Dichlorobenzene
ug/L
50
46.9
94
70-130
2-Butanone (MEK)
ug/L
100
104
104
64-135
Benzene
ug/L
50
50.0
100
70-130
Carbon tetrachloride
ug/L
50
46.5
93
70-130
Chlorobenzene
ug/L
50
48.0
96
70-130
Chloroform
ug/L
50
45.4
91
70-130
Tetrachloroethene
ug/L
50
50.4
101
69-130
Trichloroethene
ug/L
50
50.1
100
70-130
Vinyl chloride
ug/L
50
49.3
99
70-131
1,2-Dichloroethane-d4 (S)
%
97
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
96
67-135
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2486976
2486977
MS
MSD
92415497001
Spike
Spike
MS
MSD MS
MSD % Rec
Parameter Units
Result
Cone.
Cone.
Result
Result % Rec
% Rec Limits RPD Qual
1,1-Dichloroethene ug/L
ND
400
400
438
429 109 107 70-154 2
Results presented on this page are in the units indicated by the "Units"
column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 25

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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2486976
2486977
MS
MSD
92415497001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,2-Dichloroethane
ug/L
ND
400
400
395
392
99
98
70-137
1
1,4-Dichlorobenzene
ug/L
ND
400
400
379
395
95
99
70-133
4
2-Butanone (MEK)
ug/L
ND
800
800
802
832
100
104
60-139
4
Benzene
ug/L
ND
400
400
413
438
103
109
70-151
6
Carbon tetrachloride
ug/L
ND
400
400
390
410
98
102
70-143
5
Chlorobenzene
ug/L
ND
400
400
399
408
100
102
70-138
2
Chloroform
ug/L
ND
400
400
399
393
97
95
70-139
2
Tetrachloroethene
ug/L
ND
400
400
418
426
105
107
59-143
2
Trichloroethene
ug/L
ND
400
400
413
433
103
108
70-147
5
Vinyl chloride
ug/L
ND
400
400
438
443
110
111
70-156
1
1,2-Dichloroethane-d4 (S)
%
101
96
70-130
4-Bromofluorobenzene (S)
%
100
102
70-130
Toluene-d8(S)
%
96
98
67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 456164 Analysis Method: EPA 8081 B
QC Batch Method: EPA 3510C Analysis Description: 8081 TCLP Pesticides RV
Associated Lab Samples: 92415518005
METHOD BLANK: 2486200
Matrix:
Water
Associated Lab Samples: 92415518005
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chlordane (Technical)
ug/L
ND
3.0
02/05/19 13:23
Endrin
ug/L
ND
0.50
02/05/19 13:23
gamma-BHC (Lindane)
ug/L
ND
0.50
02/05/19 13:23
Heptachlor
ug/L
ND
0.50
02/05/19 13:23
Heptachlor epoxide
ug/L
ND
0.50
02/05/19 13:23
Methoxychlor
ug/L
ND
1000
02/05/19 13:23
Toxaphene
ug/L
ND
3.0
02/05/19 13:23
Decachlorobiphenyl (S)
%
75
10-138
02/05/19 13:23
Tetrachloro-m-xylene (S)
%
85
10-110
02/05/19 13:23
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
LABORATORY CONTROL SAMPLE:
2489041
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Endrin
ug/L
1.2
1.2
100
20-134
gamma-BHC (Lindane)
ug/L
1.2
1.2
99
20-118
Heptachlor
ug/L
1.2
1.1
88
20-142
Heptachlor epoxide
ug/L
1.2
1.2
95
22-133
Methoxychlor
ug/L
3.8
ND
99
44-150
Decachlorobiphenyl (S)
%
71
10-138
Tetrachloro-m-xylene (S)
%
89
10-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2489042
2489043
MS
MSD
92415518005
Spike
Spike
MS
MSD
MS MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec % Rec
Limits
RPD Qual
Endrin
ug/L
ND
1.2
1.2
1.1
1.2
91
93
21-133
3
gamma-BHC (Lindane)
ug/L
ND
1.2
1.2
1.3
1.2
102
97
24-119
5
Heptachlor
ug/L
ND
1.2
1.2
0.83
0.92
66
74
16-128
10
Heptachlor epoxide
ug/L
ND
1.2
1.2
1.1
1.1
85
86
50-150
1
Methoxychlor
ug/L
ND
3.8
3.8
ND
ND
89
95
50-150
Decachlorobiphenyl (S)
%
58
54
10-138
Tetrachloro-m-xylene (S)
%
77
81
10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 22008
Analysis Method:
EPA 8151A
QC Batch Method: EPA 8151A
Analysis Description:
8151 GCS TCLP Herbicides
Associated Lab Samples: 92415518006
METHOD BLANK: 97873
Matrix:
Water
Associated Lab Samples: 92415518006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4,5-TP (Silvex)
mg/L
ND
0.010
02/11/19 11:33
2,4-D
mg/L
ND
0.0050
02/11/1911:33
2,4-DCAA(S)
%.
183
10-155
02/11/1911:33 S3
METHOD BLANK: 98319
Matrix:
Water
Associated Lab Samples: 92415518006
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
2,4,5-TP (Silvex)
mg/L
ND
0.010
02/11/19 12:18
2,4-D
mg/L
ND
0.0050
02/11/1912:18
2,4-DCAA(S)
%.
189
10-155
02/11/1912:18 S3
LABORATORY CONTROL SAMPLE: 99061
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits Qualifiers
2,4,5-TP (Silvex)
mg/L
2
2.3
116 39-138
2,4-D
mg/L
2
2.2
110 29-145
2,4-DCAA (S)
%.
146 10-155
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
99062
99063
MS
MSD
2614376001
Spike
Spike MS MSD
MS
MSD
% Rec
Parameter
Units
Result Conc.
Conc. Result Result
% Rec
% Rec
Limits RPD Qual
2,4,5-TP (Silvex)
mg/L
<0.010 2
2 2.6 2.5
131
125
10-156 5
2,4-D
mg/L
<0.0050 2
2 2.5 2.4
123
119
10-156 3
2,4-DCAA (S)
%.
150
143
10-155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 456109 Analysis Method: EPA 8270D
QC Batch Method: EPA 3510C Analysis Description: 8270 TCLP MSSV
Associated Lab Samples: 92415518004
METHOD BLANK: 2486200
Associated Lab Samples: 92415518004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,4-Dichlorobenzene
ug/L
ND
50.0
02/04/19 17:03
2,4,5-Trichlorophenol
ug/L
ND
50.0
02/04/19 17:03
2,4,6-Trichlorophenol
ug/L
ND
50.0
02/04/19 17:03
2,4-Dinitrotoluene
ug/L
ND
50.0
02/04/19 17:03
2-Methyl phenol(o-Cresol)
ug/L
ND
50.0
02/04/19 17:03
3&4-Methylphenol (m&p Cresol)
ug/L
ND
50.0
02/04/19 17:03
Hexachloro-1,3-butadiene
ug/L
ND
50.0
02/04/19 17:03
Hexachlorobenzene
ug/L
ND
50.0
02/04/19 17:03
Hexachloroethane
ug/L
ND
50.0
02/04/19 17:03
Nitrobenzene
ug/L
ND
50.0
02/04/19 17:03
Pentachlorophenol
ug/L
ND
100
02/04/19 17:03
Pyridine
ug/L
ND
50.0
02/04/19 17:03
2,4,6-Tribromophenol (S)
%
68
27-108
02/04/19 17:03
2-Fluorobiphenyl (S)
%
59
13-107
02/04/19 17:03
2-Fluorophenol (S)
%
37
10-110
02/04/19 17:03
Nitrobenzene-d5 (S)
%
58
12-102
02/04/19 17:03
Phenol-d6 (S)
%
25
10-110
02/04/19 17:03
Terphenyl-d14 (S)
%
76
21-132
02/04/19 17:03
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2488769
Units
Spike
Conc.
1-CS
Result
LCS
% Rec
% Rec
Limits
1,4-Dichlorobenzene
ug/L
500
234
47
30-130
2,4,5-Trichlorophenol
ug/L
500
232
46
40-130
2,4,6-Trichlorophenol
ug/L
500
245
49
40-130
2,4-Dinitrotoluene
ug/L
500
287
57
49-130
2-Methyl phenol(o-Cresol)
ug/L
500
192
38
30-130
3&4-MethyIphenol (m&p Cresol)
ug/L
500
174
35
20-130
Hexachloro-1,3-butadiene
ug/L
500
219
44
10-130
Hexachlorobenzene
ug/L
500
255
51
30-130
Hexachloroethane
ug/L
500
210
42
10-130
Nitrobenzene
ug/L
500
244
49
20-130
Pentachlorophenol
ug/L
1000
592
59
10-140
Pyridine
ug/L
500
79.9
16
10-130
2,4,6-Tribromophenol (S)
%
62
27-108
2-Fluorobiphenyl (S)
%
48
13-107
2-Fluorophenol(S)
%
31
10-110
Nitrobenzene-d5 (S)
%
50
12-102
Phenol-d6 (S)
%
21
10-110
Terphenyl-d14 (S)
%
72
21-132
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2488770
2488771
MS
MSD
92415518004
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Cone.
Cone.
Result
Result
% Rec
% Rec
Limits
RPD Qual
1,4-Dichlorobenzene
ug/L
ND
500
500
192
210
38
42
30-130
9
2,4,5-Trichlorophenol
ug/L
ND
500
500
197
225
39
45
40-130
13 M1
2,4,6-Trichlorophenol
ug/L
ND
500
500
211
228
42
46
40-130
8
2,4-Dinitrotoluene
ug/L
ND
500
500
259
304
52
61
49-130
16
2-Methyl phenol(o-Cresol)
ug/L
ND
500
500
160
172
32
34
30-130
7
3&4-Methylphenol (m&p
ug/L
ND
500
500
139
151
28
30
20-130
8
Cresol)
Hexachloro-1,3-butadiene
ug/L
ND
500
500
187
190
37
38
10-130
1
Hexachlorobenzene
ug/L
ND
500
500
215
250
43
50
30-130
15
Hexachloroethane
ug/L
ND
500
500
176
188
35
38
10-130
7
Nitrobenzene
ug/L
ND
500
500
212
244
42
49
20-130
14
Pentachlorophenol
ug/L
ND
1000
1000
575
658
58
66
10-140
13
Pyridine
ug/L
ND
500
500
58.8
73.9
12
15
10-130
23
2,4,6-Tribromophenol (S)
%
53
60
27-108
2-Fluorobiphenyl (S)
%
40
45
13-107
2-Fluorophenol(S)
%
24
27
10-110
Nitrobenzene-d5 (S)
%
41
46
12-102
Phenol-d6 (S)
%
16
18
10-110
Terphenyl-d 14 (S)
%
63
76
21-132
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/12/2019 08:32 AM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 329388 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92415518001, 92415518002
SAMPLE DUPLICATE: 1602618
30278290001 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 1.8 1.8 2
SAMPLE DUPLICATE: 1602619
30278290003 Dup
Parameter Units Result Result RPD Qualifiers
Percent Moisture % 46.4 46.1 1
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328824 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92415518002
METHOD BLANK: 1600114 Matrix: Water
Associated Lab Samples: 92415518002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Flashpoint deg F >200 60.0 02/01/19 16:08
SAMPLE DUPLICATE: 1600115
30278299001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328618 Analysis Method: EPA 9045C
QC Batch Method: EPA 9045C Analysis Description: 9045 pH
Associated Lab Samples: 92415518002
SAMPLE DUPLICATE: 1599229
Parameter
pH in water at 25 degrees C
30278210001 Dup
Units Result Result RPD Qualifiers
Std. Units 7.4 7.4 1 H3
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328735
Analysis Method:
EPA 9014
QC Batch Method: SW-846 7.3.3.2
Analysis Description:
733C Reactive Cyanide
Associated Lab Samples: 92415518001
METHOD BLANK: 1599646
Matrix: Solid
Associated Lab Samples: 92415518001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Cyanide, Reactive
mg/kg
ND
1.0 01/31/19 21:15
LABORATORY CONTROL SAMPLE: 1599647
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Cyanide, Reactive
mg/kg
99.7 ND
0 0-8
SAMPLE DUPLICATE: 1599648
30278299001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Cyanide, Reactive
mg/kg
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: TCLP SLUDGE
Pace Project No.: 92415518
QC Batch: 328734
Analysis Method:
SM 4500S2F-00
QC Batch Method: SW-846 7.3.4.2
Analysis Description:
734S Reactive Sulfide
Associated Lab Samples: 92415518001
METHOD BLANK: 1599643
Matrix: Solid
Associated Lab Samples: 92415518001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Sulfide, Reactive
mg/kg
ND
10 01/31/19 20:27
LABORATORY CONTROL SAMPLE: 1599644
Spike LCS
LCS % Rec
Parameter
Units
Cone. Result
% Rec Limits Qualifiers
Sulfide, Reactive
mg/kg
199 39.8
20 0-52
SAMPLE DUPLICATE: 1599645
30278299001 Dup
Parameter
Units
Result Result
RPD Qualifiers
Sulfide, Reactive
mg/kg
ND ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
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QUALIFIERS
Project: TCLP SLUDGE
Pace Project No.: 92415518
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
LABORATORIES
PASI-A
Pace Analytical Services - Asheville
PASI-C
Pace Analytical Services - Charlotte
PASI-GA
Pace Analytical Services - Atlanta, GA
PASI-PA
Pace Analytical Services - Greensburg
ANALYTE QUALIFIERS
H3 Sample was received or analysis requested beyond the recognized method holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
TCLP SLUDGE
92415518
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92415518005
SLUDGE 9
EPA 3510C
456164
EPA 8081 B
456400
92415518006
SLUDGE 10
EPA 8151A
22008
EPA 8151A
22097
92415518007
SLUDGE 11
EPA 3010A
455970
EPA 6010D
456030
92415518007
SLUDGE 11
EPA 7470A
455971
EPA 7470A
456084
92415518004
SLUDGE 8
EPA 3510C
456109
EPA 8270D
456230
92415518003
SLUDGE 7
EPA 8260B
455666
92415518001
SLUDGE 5
ASTM D2974-87
329388
92415518002
SLUDGE 6
ASTM D2974-87
329388
92415518002
SLUDGE 6
EPA 1010
328824
92415518002
SLUDGE 6
EPA 9045C
328618
92415518001
SLUDGE 5
SW-846 7.3.3.2
328735
EPA 9014
328742
92415518001
SLUDGE 5
SW-846 7.3.4.2
328734
SM 4500S2F-00
328741
Date: 02/12/2019 08:32 AM
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Page 22 of 25

Sa
Docurrrent Name: Document Revised: February 7, 2019
Document No.: issuing Autfaarity:
F-CAR-CS-033-RoMls Pace Caroflnas avarity off?co
lahnralefV receSt ng 9araPIGS:
AshouMe ❑ Eden Greenwood ® Huntertsville ® nalGj8h® RReehaei�svllee❑
Client Name: Project Wa# : 92415518
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Courl©r: []FeCups U5P5 Client f �Jl� j J 111 l��j�l�� �1�
❑ Commercial ace ®Asher: 92413318
Custody Semi Present? ®Yes ;DNN seals intact? ®Yes ❑No
oatiOnlVals Person Emmlrsing Can¢enu; �1%
Packing Material- ❑Bubble Wrap Bags ne Other Biological Tissue Fraten?
Thermorneler: 6-To ®Yes []No gi A
❑IR Gun IF,� $ Tv"oPleo: Wet ❑Biva ❑Nee®
Cooler Temp 7 Correction Factor: Add/Subtract ('C} Qf
Temp should be above Freezing to fi`C
Cooler Temp Corrected (°C); 0. 7 Damples out of temp criteria. Samples on Ice, cooling process
hashegun
USDA Regulated5ail (2f M/A, grater sample)
Did samples or�iginate in a quarantine zone within the United States; CA, NY, or SC {check maps)? Did sa:npiesorigfnate from a Foreign source (internpopally,
[]Yes 05 a tacludlrg Hav+aii and Puerto Rico)? ❑Yes No
Chain of Custody Present?
es
❑No
❑NIA
11.
Sam les Arrived within flald T me?
Yes
ON.
❑N/A
?-
Short HOd Time Analysis (�72 hr.j?
❑Yes
ZN.
[]N/A
3,
Rush Turn Acaund Time Requested?
Dy.
Na
❑N/A
$.
Sufficient Volume?
es
❑No
❑N/A
5.
Correct Containers Used?
-PaceContainers. USed?
2res
RLs
❑No
QN.
❑N/A
❑NIA
5-
Containers Intact?
olrs
No
[JMIA
7.
M5soived analysis: Sam les Field Filtered?
❑Yes
0 Wo
❑N/A
8.
Sample Labels Match CCC7
-Includes Date/Time/ID/Analysis Matrhr:
P es
ON.
❑N/A
9.
Headspace in VOA Vials O5-6mm)?
❑Yes
❑Nn
N/A
Ia.
Trip ®lank Present?
Trip BlankCustodv Seals Present?
Dyes
r1yu
j]No
MNo
/A
t/A
11.
COMM EiNTSJSAMPLE DISCREPANCY
Lot 10 of split containers:
CLIENT NOTTFICATICIN/RF50LUTION
Person contacted: Date/Tirne:
Project Mamgor SCURF Review:
Project Martager SRF Review:
Field Data Required? ❑Yes []NO
Date: _ r `
Dote:-(/y Lq
Page 23 of 25

v • CQ SLO
CHAIN -OF -CUSTODY 1 Analytical Request Document 1 N
The Chain -of -Gusto is a LEGAL DOCUMENT. Ail relevant fields must be completed accurately. O
aceAnalytical J P y_ 1�_ It
--Paceraas Co. �� V (V
N
1 m
to
Section A Section 8 Section C
page; C ar
Required Client Information; Required Project Information invoice Information: C
Company: i_ _ II Report To', Attertion:
V r':
Addross� C J
Capy To:
Company Name,
REGULATORY AGENCY
Address:
( NPDES F- GROUND WATER r DRINKING WATER
UST f RCRA r OOTHER1
Emeil To:
Purchase Order No.:
Pace Quote
U C C E?f _ "-���
Reference'.
Phone: _., - �'t
ax;
P ec1 Na -� h!l I } ) y ]�
I
�-Y
Pace ProeCA
1� �`- ` --
Site Location
;' .Iu / / f" l"
Managerl j 7
STATE. -
Requested Due DaterTAT:
roject Numb
Pace Proflle 4:
Requested
Analysis
Filtered
(Y1Nj
- - -
Section D Valid Matrix Codes
s
--►
z
Required Client Information MATRFX CODE
a
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COLLECTED
Preservatives
'-
DRINKING WATER GW
y
(.]
z
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W
WASTEWATER WW
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ADDITIONAL OMMENTS
RELINQUISHED BY I AFFILIATION
DATE
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GC ED BY! AFFILIATION
DATE
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SAMPLE CONDITIONS
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1✓
SAMPLER NAME AND SIGNATURE
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PRINT Name of SAMPLER: r , ,^I _ � k � � /
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-
SIGNATURE of SAMPLERr DATE Signed G,�
Of
30
P
(MMIDDTYY): I
0
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9mpodant Nate: Sy signing this form you are accepting PacWs NET 30 day payment terms and agreeing to late charges 0 1.5% per month for any InvoiCea not paid within 30 days. F-ALL-0-020rev.08, ,2-OCI-2007

I Sa
Document Name:
Document No.:
F-CAR-cs-m-ta.v
°Ch(ach frfar(s toP half 56 bore if Ph �md/ar dech!®riroatleaa is
verlfir 0 Ead eoil4&air the accePtartce range for preservation
Sana�lt7�,
EimepUenA: VOA, CaIHArm, TOG flit and Grease, DROJEO15 {water} l7OC, LWg
"I' aRalin ba f of box is to fist number of bottle
oacument Revised-. February 7, 2010
Page I of 2
f5suing Authaffty:
Pare Cara)Ws QuON Office
Pro W0# : 92415518
PM: KPD Due Date: 02/11/19
CLIENT: 92-Elisabeth
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PH Ad)ustment Log for Presemed Samples --
sample iD
Type of Preservative
PH upon receipt
Date presarvatian adjusted
Time preservation
adjusted
Anwunt of Preservative
added
Lat fa
Nate W"rlever ltsere Is a disuepanry affecting Narth Carollna compllance samples, a copy or this rarm win t:e mrt to tnarvorm larouna ucnnn Lerraicanon UrslCe p.a.
Out of hold, incorrect preservatlue, out at temp, incorrect containers.
Page 25 of 25

ATLANTIC OBX, INC.
2019 Class A Annual Report
WQ Permit# WQ0040622
Annual Distribution and Marketing Certification Summary Form

ANNUAL DISTRIBUTION AND MARKETING/SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Permit Number: WQ0040622 Facility Name: Atlantic OBX, Inc. Class A
Phone: [phone] County: Dare Operator: J. Bryan Smith
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
❑ Distribution and Marketing (complete Parts X B, and C)
Was the facility in operation during the past calendar year? V Yes ❑ No If No skip parts A, B, C and certify form below
PART A *: PART B *:
Month
Sources &
NPDES
Volume (Dry Tons)
Recipient Information
Amendment/Bulking Agent In
Residual In
Product Out
Name(s)
Volume (Dry Tons)
Intended Use(s)
January
February
March
April
May
June
July
August
September
Elizabeth City WTP
04-70-010
0.00
643.42
643.42
Atlantic OBX
643.42
Coastal Bermuda
October
Elizabeth City WTP
04-70-010
0.00
806.21
806.21
Atlantic OBX
806.21
Coastal Bermuda
November
Elizabeth City WTP
04-70-010
0.00
316.72
316.72
Atlantic OBX
316.72
Annual Rye Hay
December
Elizabeth City WTP
04-70-010
0.00
277.83
277.83
Atlantic OBX
277.83
Annual Rye Hay
TOTAL ANNUAL
DRY TONS
0.00
2044.18
2044.18
2044.18
Part C:
Total Number of DMSDF Forms
1
Facility was compliant during the past calendar year with all conditions of the land application permit �/❑ Yes
(including but not limited to items 1-3 below) issued by the Division of Water Quality: ❑■ No
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
61.0
2/28/2020
Signature of Penn ittee
Date Signature ofPreparer**
(if different from Permittee)
**Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Date