NCS000282_Monitoring Data_20140313

c1difill,'�
DEMLR — Stormwater Pern-utting Program
Attn: Stormwater Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
March 11, 2014
RE: Cargill, Incorporated, Raleigh, NC— StortnwaterDischarge PermitNCS000282
Year 5, Period 2 - Analytical Monitoring Results
MAR 13 2014
CENTRAL FILES
DWQ/BUG
In accordance with the Cargill, Raleigh facility's Stormwater Discharge Permit NCS000282, Part III,
Section E, Cargill is submitting Discharge Monitoring Reports for the Year Five, Period Two
monitoring period. The monitoring was completed on February 2l't 2014 during characteristic storm
event.
SD001
Characteristic
Benchmark
Lab
Results
Tier
2/21/2014
COD
120 mg/L
220
2
2/21/2014
BOD
30 mg/L
99
2
2/21/2014
Total Phosphorus
2 mg/L
1.2
2
2/21/2014
TKN
20 mg/L
11
2
SDO02
Characteristic
Benchmark
Lab
Results
Tier
2/21/2014
COD
120 mg/L
500
2
2/21/2014
BOD
30 mg/L
450
2
2/21/2014
Total Phosphorus
20 mg/L
4.1
1
2/21/2014
TSS
100 mg/L
97
1
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
Michael Klauke
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 27603-2506

�wESQ
I
John Whittaker
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
12065 Lebanon Rd.
Mt. Juliet, TN 97122
[phone]
1-800-767-5859
Fax [phone]
Tax 1.D. 62-0814289
Est. 1970
Report Summary
Friday February 28, 2014
Report Number: L684442
Samples Received: 02/22/14
Client Project:
Description:
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have an
questions regarding this data package, please do not hesitate to caly
l.
Entire Report Reviewed By:
T. Alan Harvill , ESC Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BIO041, ND - R-140. NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
This report may not be reproduced, except in full, without written approval from ESC Lab Sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 4

�wESQ
I
REPORT OF ANALYSIS
John Whittaker
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
12065 Lebanon Rd.
Mt. Julie L, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
February 28, 2014
ESC Sample # : L684442-01
Date Received
February 22, 2014
Description
Site ID
Sample ID
OUTFALL 2
Project #
Collected By
John
Collection Date
02/21/14 13:00
Parameter
Result
Det. Limit
Units
Method
Date
Dil.
BOD
450,
2.00
mg/1
5210 B-2011
02/27/14
1
COD
500
10.
mg/1
410.4
02/28/14
1
pH
6.2
su
4500H+ B-2011
02/25/14
1
Nitrate -Nitrite
0.19
0.10
mg/1
353.2
02/25/14
1
Phosphorus,Total
4.1
0.10
mg/l
365.4
02/27/14
1
Kjeldahl Nitrogen,
TKN
40.
0.50
mg/l
351.2
02/27/14
5
Suspended Solids
97.
2.5
mg/l
2540 D-2011
02/26/14
1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 02/28/14 16:10 Printed: 02/28/14 16:11
L684442-01 (PH) - 6.2 @ 18.Oc
Page 2 of 4

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Sampling Event Number
Sample Date
Sampler
Outfall Number
Contract Laboratory
Results
Parameter (Units)
Tier 1 Checklist
SD000282
2/21/2014
John W
RNC-SD001 or RNC SD002
ESC Lab Sciences
Value Benchmark Values Benchmark Exceedance?
BOD
450
30 mg/L
YES
COD
500
120 mg/L
YES
pH
6.2
Standard (6-9)
NO
Nitrate -Nitrite
0.19
10 mg/L
NO
Phosphorus,Total
4.10
2 mg/L
YES
Kjeldahl Nitrogen, TKN
40
20 mg/L
YES
Suspended Solids(TSS)
91
100 mg/L
NO
Tier I Checklist
Stormwater inspection
conducted within 2 weeks? Yes
List of possible Causes
leaves, product on ground from unloading/operations
Potential Solutions
housekeeping
Actions Taken (include
dates of implementation) inform Area supervisor
Keep a record of all Tier 1 actions with facility SWPPP

Tier 2 Checklist
n addition to repeating the steps tor Tier 1, monthly sampling is required for all parameters at
every outfall where an exceedance was recorded until 3 consecutive sampling events results
are below benchmarks.
Sampling Event Number SD000282
Sample Date 2/21/2014
Sampler John W
Outfall Number RNC-SD001 or RNC SD002
Contract Laboratory ESC Lab Sciences
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
450
30 mg/L
YES
COD
500
120 mg/L
YES
pH
6.2
Standard (6-9)
NO
Nitrate -Nitrite
0.19
10 mg/L
NO
Phosphorus,Total
4.10
2 mg/L
YES
Kjeldahl Nitrogen, TKN
40
20 mg/L
NO
Suspended Solids(TSS)
91
100 mg/L
NO
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
N/A
30 mg/L
N/A
TSS
N/A
100 mg/L
N/A
Total Kjeldahl Nitrogen
N/A
20 mg/L
N/A
Nitrate -Nitrite
N/A
10 mg/L
N/A
Total Phosphorus
N/A
2 mg/L
N/A
COD
N/A
120 mg/L
N/A
p H
N/A
Standard
N/A
* Keep a record of all Tier 1 actions with facility SWPPP

Stormwater Discharge Outfall (SDO)
(qualitative Monitoring Report
For guidance on filling out this form, please visit: http://h2o.enr.state.nc.us/su/Forms Documents.htni tmiseforms
Permit No.: N/t=/-5/ �I Gf 0l .51 —�l or Certiii ale of Coverage No.: N!C/G! l_/_/
Facility Name: %/fo/t'pra
County: /¢ +� Phone No. 19 — 89 `% - �(a oaf
Inspector.
Date of Inspection: - Time of Inspection:
_.. Total Event Precipitation (inches): 0 ,
Was this a Representative Storm Event? (See information below) Yes ❑ No
Please check your permit to vet7fy if Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
A "Representative Storm Event" is a storm event that measures greater than 0.l inches of rainfall and that
{ is preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has
occurred. A single storm event may contain up to 10 consecutive hours of no precipitation.
By this signature, I certify that this
is accurate and complete to the best of my knowledge:
63 1 It
(Signature 6ttee or Designee) r
1. Outfall Desc
Outfall No sO°o► Stnqcture (pipe, ditch, etc.)
Receiving Stream: r �f 1�� + � W S X 7`�
Describe the industrial activities t ` t occur within the outfall drainage area:
0
2. Color: Describe the color ofthedischarge i g
// basic colors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: A-J4
3. Odor: Describe any distinct odors that the discharge may have (i.e., smells strongly of oil, weak
chlorine odor, etc.):
Page 1 of 2
S WU-242-t 12608

4. CIarity: Choose the number which best describes the clarity of the discharge, where I is clear
and 5 is very cloudy:
1 3 4 5
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where I is noossolids and 5 is the surface covered with floating solids:
(1 J 2 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where I is no solids and 5 is extremely muddy:
1 2�/ 3 4 5
7. Is there any foam in the stormwater discharge? Yes
a
8. Is there an oil sheen in the stormwater discharge?
9. Is there evidence of erosion or deposition at the outfall?
10. Other Obvious Indicators of Stormwater Pollution:
List and describe
Yes No
Yes No
Note: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SwU-242-112608

Weather History for Raleigh -Durham Airport, NC
Friday, February 21, 2014
Friday, February 21, 2014
Previous Day February
21- 2014- View j
Next Day
Daily Weekly Monthly Custom
Actual
Average
Record
Temperature
Mean Temperature
57 °F
46 °F
Max Temperature
73 °F
57 °F
76 -F (2011)
Min Temperature
41 °F
35 °F
8 °F (1896)
Degree Days
Heating Degree Days
8
19
Month to date heating degree days
450
446
Since 1 July heating degree days
2554
2443
Cooling Degree Days
0
0
Month to date cooling degree days
0
0
Year to date cooling degree days
0
0
Growing Degree Days
8 (Base 50)
Moisture
Dew Point
54 °F
Average Humidity
76
Maximum Humidity
89
Minimum Humidity
62
Precipitation
Precipitation
0.40 in
0.12 in
1.19 in (1961)
Month to date precipitation
3.00
2.37
Year to date precipitation
4.96
5.87
Snow
Snow
0.00 in
0.00 in
10.00 in (1899)
Month to date snowfall
3.7
1.5
Since 1 July snowfall
5.6
5.1
Snow Depth
0.00 in
Sea Level Pressure
Sea Level Pressure
29.90 in
Wind
Wind Speed
11 mph (SW)
Max Wind Speed
32 mph
Max Gust Speed
41 mph
Visibility
9 miles
Events
Fog , Rain , Thunderstorm
T = Trace of Precipitation, MM = Missing Value
Source:
NWS Daily Summary
http://www.wunderground. comlhistorylairportlKRDU12014102121 ID ailyHistory.html?req_... 3 / 10/2014

F Temperatlre Dew Point Normal Highkow
80
70
60
---- -
30
20
midnigM1 2 3 4 5 6 7 8 9 10 11 noon 1 2 3 4 5 6 7 8 9 10 11
in Hg Barometric. Pressure
30.1
30.0
29.9
29 8
midnight1 2 3 4 5 6 7 8 9 10 11 noon 1 2 3 4 5 6 7 8 9 10 11
mh
midnight1 2 3 4 5 6 7 8 9 10 11 noon 1 2 3 4 5 6 7 8 9 10 11
360.0
270.0
180.0
90.0
00
midnight1 2 3 4 5 6 7 8 9 10 11 noon 1 2 3 4 5 6 7 8 9 10 14m u,
Certify This Report
Hourly Weather History & Observations
Time (EST)
Temp.
Dew Point
Humidity
Pressure
12:51 AM
66.0 'F
60.1 `F
81 %
29.96 in
1:51 AM
66.0 'F
60.1 'F
81 %
29.95 in
2:51 AM
66.0 °F
60.1 °F
81 %
29.95 in
3:51 AM
66.9 °F
60.1 °F
79%
29.94 in
4:51 AM
66.0 °F
60.1 °F
81 %
29.92 in
5:03 AM
66.2 'F
60.8 'F
83%
29.92 in
5:51 AM
66.0 'F
60.1 `F
81 %
29.91 in
6:51 AM
66.0 'F
60.1 'F
81 %
29.88 in
7:51 AM
66.0 'F
60.1 'F
81 %
29.88 in
8:51 AM
68.0 °F
61.0 'F
78%
29.89 in
9:51 AM
70.0 'F
61.0 'F
73%
29.85 in
Visibility
Wind Dir
Wind Speed
Gust Speed
10.0 mi
SSW
16.1 mph
26.5 mph
10.0 mi
SSW
17.3 mph
-
10.0 mi
SSW
13.8 mph
26.5 mph
10.0 mi
SSW
17.3 mph
26.5 mph
10.0 mi
SSW
15.0 mph
23.0 mph
10.0 mi
SSW
12.7 mph
25.3 mph
10.0 mi
SSW
16.1 mph
25.3 mph
10.0 mi
South
16.1 mph
25.3 mph
10.0 mi
South
20.7 mph
28.8 mph
10.0 mi
SSW
19.6 mph
32.2 mph
10.0 mi
SSW
20.7 mph
29.9 mph
Show full METARS I METAR FAQ I Comma Delimited File
27
21
16
10
4
-1
_7
hPa
1019
1016
1013
1009
kmhr
Precip
N/A
N/A
N/A
N/A
N/A
N/A
N/A
0.00 in
N/A
N/A
N/A
Events
http://www.wunderground.comlhistorylairportlKRDU12014102121IDailyHistory,html?req_... 3/ 10/2014

Time (EST)
Temp.
Dew Point
Humidity
Pressure
Visibility
Wind Dir
Wind Speed
Gust Speed
Precip
Events
10:51 AM
72.0 "F
61.0 `F
68%
29.84 in
10.0 mi
SW
26.5 mph
40.3 mph
N/A
Thunder
11:04 AM
69.8 °F
60.8 °F
73%
29.90 in
1.5 mi
WSW
32.2 mph
41.4 mph
0.00 in
Rain,
Thunder
11:27 AM
59.0 °F
55.4 °F
88%
29.89 in
4.0 mi
SW
18.4 mph
-
0.24 in
Rain ,
Thunder
11:51 AM
59.0 °F
55.9 °F
90%
29.86 in
6.0 mi
SW
12.7 mph
19.6 mph
0.28 in
Rain,
Thunder
12:51 PM
60.1 T
55.9 °F
86%
29.82 in
8.0 mi
WSW
12.7 mph
19.6 mph
0.12 in
Rain ,
Thunder
1:26 PM
60.8 °F
57.2 °F
88%
29.81 in
10.0 mi
SW
11.5 mph
-
0.00 in
1:51 PM
62.1 T
57.9 °F
86%
29.81 in
10.0 mi
SW
12.7 mph
0.00 in
2:27 PM
62.6 °F
57.2 °F
82%
29.82 in
10.0 mi
SW
15.0 mph
N/A
2:51 PM
63.0 °F
57.9 `F
84%
29.82 in
10.0 mi
SW
16.1 mph
N/A
3:26 PM
57.2 °F
51.8 °F
82%
29.85 in
7.0 mi
Variable
5.8 mph
19.6 mph
0.00 in
Rain
3:51 PM
57.9 °F
48.9 °F
72%
29.85 in
10.0 mi
NW
8.1 mph
17.3 mph
0.00 in
4:04 PM
57.2 °F
46.4 °F
67%
29.86 in
10.0 mi
WNW
10.4 mph
-
N/A
4:51 PM
59.0 °F
46.9 °F
64%
29.87 in
10.0 mi
Variable
5.8 mph
N/A
5:51 PM
57.0 °F
45.0 °F
64%
29.91 in
10.0 mi
West
3.5 mph
N/A
6:51 PM
52.0 °F
44.1 °F
74%
29.95 in
10.0 mi
Calm
Calm
N/A
7:51 PM
48.9 T
43.0 T
80%
29.97 in
10.0 mi
Calm
Calm
NIA
8:51 PM
45.0 °F
41.0 °F
86%
29.97 in
10.0 mi
Calm
Calm
N/A
9:51 PM
44.1 °F
39.9 °F
85%
29.99 in
10.0 mi
Calm
Calm
N/A
10:51 PM
43.0 °F
39.9 °F
89%
30.02 in
10.0 mi
Calm
Calm
N/A
11:51 PM
42.1 °F
39.0 °F
89%
30.04 in
10.0 mi
Calm
Calm
N/A
Fog
Show full METARS I METAR FAQ I Comma
Delimited File
http: Hwww. wunderground. comlhi story/airp ortlKRDU12 014/02/21 ID ai lyHi story . html?re q_... 3 / 10/2014

CW11T
DEMLR — Stormwater Permitting Program
Attn: Stormwater Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
February 25, 2014
RECEIVE®
RE. Cargill, Incorporated, Raleigh, NC— Stormwater Discharge Permit NCS000282
Year S, Period 2 - Analytical Monitoring Results
FEB 2 7 , 2014
CENTRAL FILES
DWQIBQG
In accordance with the Cargill, Raleigh facility's Stormwater Discharge Permit NCS000282, Part III,
Section E, Cargill is submitting Discharge Monitoring Reports for the Year Five, Period Two
monitoring period. The monitoring was completed on January 14"' 2014 during characteristic storm
event.
SD001
Characteristic
Benchmark
Lab
Results
Tier
01/14/2014
COD
120 mg/L
280
2
01/14/2014
BOD
30 mg/L
130
2
01/14/2014
Total Phosphorus
2 mg/L
3.0
2
01/14/2014
TKN
20 mg/L
19
2
SDO02
Characteristic
Benchmark
Lab
Results
Tier
01/14/2014
COD
120 mg/L
No Flow
2
01/14/2014
BOD
30 mg/L
No Flow
2
01/14/2014
Phosphorus
20 mg/L
No flow
1
01/14/2014
-__k_Total
TSS
100 mg/L
No flow
1 1
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
Michael Klauke
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 2 76032506

Tier 1 Checklist
Sampling Event Number SD000282
Sample Date 1/14/2014
Sampler Bob
Outfall Number RNC-SD001 or RNC SD002
Contract Laboratory ESC Lab Sciences
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
130
30 mg/L
YES
COD
280
120 mg/L
YES
pH
6.6
Standard (6-9)
NO
Nitrate -Nitrite
0.54
10 mg/L
NO
Phosphorus,Total
3.00
2 mg/L
YES
Kjeldah) Nitrogen, TKN
19
20 mg/L
NO
Suspended Solids(TSS)
26
100 mg/L
NO
Tier I Checklist
Stormwater inspection
conducted within 2 weeks? Yes
List of possible Causes
leaves, product on ground from unloading/operations
Potential Solutions
housekeeping
Actions Taken (include
dates of implementation) inform Area supervisor
Keep a record of all Tier 1 actions with facility SWPPP

Tier 2 Checklist
n addition to repeating the steps for Tier 1, monthly sampling is required tor all parameters at
every outfall where an exceedance was recorded until 3 consecutive sampling events results
are below benchmarks.
Sampling Event Number SD000282
Sample Date 1/14/2014
Sampler Bob
Outfall Number RNC-SDO01 or RNC SDO02
Contract Laboratory ESC Lab Sciences
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
130
30 mg/L
YES
COD
280
120 mg/L
YES
pH
6.6
Standard (6-9)
NO
Nitrate -Nitrite
0.54
10 mg/L
NO
Phosphorus,Total
3.00
2 mg/L
YES
Kjeldahl Nitrogen, TKN
19
20 mg/L
NO
Suspended Solids(TSS)
26
100 mg/L
NO
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
N/A
30 mg/L
N/A
TSS
N/A
100 mg/L
N/A
Total Kjeldahl Nitrogen
N/A
20 mg/L
N/A
Nitrate -Nitrite
N/A
10 mg/L
N/A
Total Phosphorus
N/A
2 mg/L
N/A
COD
N/A
120 mg/L
N/A
pH
N/A
Standard
N/A
* Keep a record of all Tier 1 actions with facility SWPPP

*ESC
L�A•B S•C•1•E•N•C-E,S
John Whittaker
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
12065 Lebanon Rd.
Ml. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax 1.G. 62-0814289
Est. 1970
Report Summary
Wednesday January 22, 2014
Report Number: L678026
Samples Received: 01/15/14
Client Project:
Description:
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have an
questions regarding this data package, please do not hesitate to caly
l.
Entire Report Reviewed By:
Linda Cashman , ESC Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab 4364, EPA - TNO02
Accreditation i.s only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
Note: The use of the preparatory EPA Method 3511 is not approved or endorsed by the CA ELAP.
This report may not be reproduced, except in full, without written approval from ESC Lab Sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 4

*ESC
YOUR E..AB -QF'GH DICE;
REPORT OF ANALYSIS
John Whittaker
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
January 22, 2014
ESC Sample # : L678026-01
Date Received
January 15, 2014
Description
Site ID
Sample ID
OUTFALL #1
Project #
Collected By
Bob Melvin
Collection Date
01/14/14 14:00
Parameter
Result
Det, Limit
Units
Method
Date
Dil.
BOD
130.
2.00
mg/l
5210 B-2011
01/20/14
1
COD
280
10.
mg/l
410.4
01/17/14
1
PH
6.6
su
4500H+ B-2011
01/19/14
1
Nitrate -Nitrite
0.54
0.10
mg/l
353.2
01/18/14
1
Phosphorus,Total
3.0
0.10
mg/l
365.4
01/17/14
1
Kjeldahl Nitrogen,
TKN
19.
0.10
mg/l
351.2
01/22/14
1
Suspended Solids
26.
2.5
mg/l
2540 D-2011
01/17/14
1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 01/22/14 13:55 Printed: 01/22/14 13:55
L678026-01 (PH) - 6.6@13.7c
Page 2 of 4

Attachment A
List of Analytes with QC Qualifiers
Sample Work Sample Run
Number Group Type Analyte ID Qualifier
L678026-01
WG702020 SAMP pH
R2877654 T8
Page 3 of 4

Attachment B
Explanation of QC Qualifier Codes
Qualifier Meaning
T8 (ESC) - Additional method/sample information: Sample(s) received past/too
close to holding time expiration.
Qualifier Report Information
ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and
as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted
by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical
results. Each qualifier is designated in the qualifier explanation as either EPA or ESC.
Data qualifiers are intended to provide the ESC client with more detailed information concerning
the potential bias of reported data. Because of the wide range of constituents and variety of
matrices incorporated by most EPA methods,it is common for some compounds to fall outside of
established ranges. These exceptions are evaluated and all reported data is valid and useable
"unless qualified as 'R' (Rejected)."
Definitions
Accuracy- The relationship of the observed value of a known sample to the
true value of a known sample. Represented by percent recovery and
relevant to samples such as: control samples, matrix spike recoveries,
surrogate recoveries, etc.
Precision - The agreement between a set of samples or between duplicate samples.
Relates to how close together the results are and is represented by
Relative Percent Differrence.
Surrogate - Organic compounds that are similar in chemical composition, extraction,
and chromotography to analytes of interest. The surrogates are used to
determine the probable response of the group of analytes that are chem-
ically related to the surrogate compound. Surrogates are added to the
sample and carried through all stages of preparation and analyses.
TIC - Tentatively Identified Compound: Compounds detected in samples that are
not target compounds, internal standards, system monitoring compounds,
or surrogates.
Page 4 of 4

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Total Phosphorous: (Combine w/Nitrate/Nitr to Bottle)
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tnclicative, of lxallttt ant ex A i'ure. Tl '.'sc cf nditiuDs yan' ul further inve.:tiC; lYltw

Weather History for Raleigh -Durham Airport, NC
Tuesday, January 14, 2014
';'uesday, January 14, 2014
« Previous Day January r 14
2014 r View
Next Day
Daily Weekly Monthly Custom
Actual
Average
Record
Mean Temperature
46'F
41 'F
Max Temperature
54 `F
51 'F
79'F (1932)
Min Temperature
38`F
31'F
6'F(1912)
Heating Degree Days
19
24
Month to date heating degree days
348
342
Since 1 July heating degree days
1580
1593
Cooling Degree Days
0
0
Month to date cooling degree days
0
0
Year to date cooling degree days
0
0
Dew Point
45 `F
Average Humidity
78
Maximum Humidity
96
Minimum Humidity
59
Precipitation
0.30 in
0.12 in
1.55 in (2005)
Month to date precipitation
1.61
1.58
Year to date precipitation
1,61
1 58
Snow
0.00111
0.10 in
6,00 in (1982)
Month to date snowfall
0.0
1.1
Since 1 July snowfall
T
1.8
Snow Depth
0.00 in
F., ei Pressure
Sea Level Pressure
29.87 in
Wind Speed
3 mph (SW)
Max Wind Speed
12 mph
Max Gust Speed
16 mph
Visibility
7 miles
Events
Fog, Rain
T = Trace of Precipitation, MM = Missing Value
Source: NWS Daily Summary
http://www.wunderground.com/hi story/airport/KRDU/2014/01 / 14/DailyHistory.html?req_... 2/25/2014

F Tetriperatuip. a?eco
Point
Normal HighlLoud
C
55
13
-
--
10
--,.,
35
2
30
.1
25
.4
midnight 2 3 4 5
6
7
0 9 10
11 noon 1 2
3 4 5
6 7
0 9 10
11
in Hg 8arumh0-ic Pressure.
hPa
30.0
_ _
1016
29.7
1006
midnight1 2 3 4 5
6
7
8 9 10
11 noon 1 2
3 4 5
6 7
8 9 10
11
mph Wild
UTAnd
Gust
krnb
15.0
24
10.0
16
midnight1 2 3 4 5
6
7
8 9 10
11 noon 1 2
3 4 5
6 7
8 9 10
11
'tUnd Dir (deg)
360.0
270,0
180.0
90.0
0.0 .°
midnight1 2 3 4 5
6
7
8 9 10
11 noon 1 2
3 4 5
6 7
8 9 10
1rmuaa�
Certify This Report
Hourly Weather History & Observations
Time (EST)
Temp. Windc€lill
Dew Point
Humidity
Pressure
Visibility
Wind Dir
Wind Speed
Gust Speed Precip
Events
Conditions
12:51 AM
53.1 'F -
43.0 'F
69%
29.93 in
10.0 mi
SSW
8.1 mph
- 0.00 in
Rain
Light Rain
1 51 AM
51.1 "F -
46.9 'F
86%
29.90 in
10.0 mi
South
9.2 mph
- 0.04 in
Rain
Light Rain
2 51 AM
51.1 "F -
48.0 'F
8940
29.89 in
10.0 rni
SSW
6.9 mph
- 0.0511)
Rain
Light Rain
351 AM
50,0'F -
48.0 "F
9300
29.87 in
10.0 mi
SW
3.5 mph
- 0.00 in
Rain
Light Rain
4.51 AM
50.0 `F -
48.0 "F
93%d
29.86 in
10.0 mi
WSW
3,5 mph
- 0.00 in
Rain
Light Rain
5:51 AM
50.0'F -
48.0 "F
93%
29.83 in
10.0 mi
Calm
Calm
- 0.00 in
Rain
Light Rain
6:51 AM
60.0'F -
48.0 `F
93%
29.81 in
5.0 mi
Calm
Calm
- 0.00 in
Rain
Light Rain
7.51 AM
60.0'F -
48.9 "F
96%
29.82 in
2.5 mi
Calm
Calm
- 0,00 in
Rain
Light Rain
8:51 AM
50.0'F -
48.9 'F
96%
29.82 in
2.5 all
SSW
3.5 mph
- 0,00 in
Rain
Light Rain
930 AM
51.8'F -
48.2'F
881%.
29.82 in
3.0 mi
SSW
4.6 mph
- 0,00 in
Overcast
9:51 AM
51.1 "F -
48,9 'F
92'X
29.81 m
3.0 mi
South
3.5 mph
- 0.00 in
Overcast
10:28 AM
51.8'F -
48,2 'F
88%
29.81 in
1.5 mi
West
3.5 mph
- 0.00 in
Rain
Light Rain
10,51 AM
51.1 "F -
48.9 'F
92 %
29.80 in
0.5 mi
Calm
Calm
- 0.02 in
Rain
Light Ram
11:47 AM
48.2 "F -
46.4'F
93%
29.80 in
1.6 mi
WNW
8.1 mph
- 0.0711)
Rain
Light Rain
11 51 AM
50,0 "F -
48.0 'F
93%
29.80 in
1.5 mi
Variable
4.6 mph
- 0.08111
Rain
Light Rain
1251 PM
50.0'1` -
46,9 "F
89 %
29.81 in
1.5 mi
West
6.9 mph
- 0,07111
Rain
Light Rain
12 56 PM
50,0 IF -
46.4 "F
87 iu
29.82 in
3.0 all
NW
8.1 mph
- 0.00'n
Ram
Light Rain
1:27 PM
50.0'F -
48.2'F
94 in
29.80 in
4.0 m,
WNW
5,8 mph
- 0,03 !n
Rain
Light Rain
1:51 PM
60.0 `F -
46.9 'F
89%
29.81 in
9.0 mi
SW
3,5 mph
- 0.03 in
Rain
Light Rain
2:51 PM
63.1 'F -
46.9 "F
80%
29.82 in
10,0 mi
WNW
5.8 mph
- 0.01 in
Scattered Clouds
351 PM
53.1 °F -
45.0 "F
74%
29.86 in
10,0 mi
Variable
4.6 mph
- NIA
Scattered Couds
4:51 PM
52.0 "F -
44.1 'F
7494,
29.89 in
10,0 mi
Calm
Calm
- N/A
Partly Cloudy
Show full METARS I METAR FAQ I Comma Delimited File
http://www.wunderground.com/history/airportlKRDU12014101 / 14IDailyHistory,html?req_... 2/25/2014

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c4rdi'll
DEMLR — Stormwater Permitting Program
Attn: Stormwater Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
July 10, 2014
RE I V EL)
JUL 14 2014
CENTRAL FILES
DWq/BOG
RE: Cargill, Incorporated, Raleigh, NC— Stormwater Discharge Permit NCS000282
Year 5, Period 2 - Analytical Monitoring Results
In accordance with the Cargill, Raleigh facility's Stormwater Discharge Permit NCS000282, Part III,
Section E, Cargill is submitting Discharge Monitoring Reports for the Year Five, Period Two
monitoring period. The monitoring was completed on June 12r1' 2014 during a characteristic storm
event.
SD001
Characteristic
Benchmark
Lab
Results
Tier
6/12/2014
COD
120 mg/L
390
2
6/12/2014
BOD
30 mg/L
150
2
6/12/2014
Total Phosphorus
2 mg/L
4.5
2
6/12/2014
TKN
20 mg/L
26
2
SDO02
Characteristic
Benchmark
Lab
Results
Tier
No Flow
COD
120 mg/L
N/A
2
No Flow
BOD
30 mg/L
N/A
2
No Flow
Total Phosphorus
20 mg/L
N/A
2
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
" , "a�
Michael Klauke
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
1400 S. Blount Street
Raleigh, NC 27603-2506

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Sampling Event Number
Sample Date
Sampler
Outfall Number
Contract Laboratory
Results
Parameter (Units)
Tier 1 Checklist
SD000282
6/12/2014
Jason Bartley
RNC-SD001 or RNC 5D002
ESC Lab Sciences
Value Benchmark Values Benchmark Exceedance?
BOD
150
30 mg/L
YES
COD
390
120 mg/L
YES
pH
6.8
Standard (6-9)
NO
Nitrate -Nitrite
BDL
10 mg/L
NO
Phosphorus,Total
4.50
2 mg/L
YES
Kjeldahl Nitrogen, TKN
26
20 mg/L
YES
Suspended Solids(TSS)
87
100 mg/L
NO
Tier I Checklist
Stormwater inspection
conducted within 2 weeks? Yes
List of possible Causes
leaves, product on ground from loading beans
Potential Solutions
housekeeping, clean storm water drains
Actions Taken (include
dates of implementation) inform Area supervisor
Keep a record of all Tier 1 actions with facility SWPPP

Tier 2 Checklist
n addition to repeating the steps Tor Tier 1, monthly sampling is required for all parameters at
every outfall where an exceedance was recorded until 3 consecutive sampling events results
are below benchmarks.
Sampling Event Number SD000282
Sample Date 6/12/2014
Sampler Jason Bartley
Outfall Number RNC-SDO01 or RNC SDO02
Contract Laboratory ESC Lab Sciences
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
150
30 mg/L
YES
COD
390
120 mg/L
YES
pH
6.8
Standard (6-9)
NO
Nitrate -Nitrite
BDL
10 mg/L
NO
Phosphorus,Total
4.50
2 mg/L
YES
Kjeldahl Nitrogen, TKN
26
20 mg/L
YES
Suspended Solids(TSS)
87
100 mg/L
NO
Results
Parameter (Units)
Value Benchmark Values Benchmark Exceedance?
BOD
N/A
30 mg/L
N/A
TSS
N/A
100 mg/L
N/A
Total Kjeldahl Nitrogen
N/A
20 mg/L
N/A
Nitrate -Nitrite
N/A
10 mg/L
N/A
Total Phosphorus
N/A
2 mg/L
N/A
COD
N/A
120 mg/L
N/A
pH
N/A
Standard
N/A
* Keep a record of all Tier 1 actions with facility SWPPP

Weather History for Raleigh -Durham Airport; NC I Weather Underground Page 1 of 2
Weather History for Raleigh -Durham Airport, NC
Thursday, June 12, 2014
Thursday, June 12, 2014
Previous Day June 12 - 2014 . Vjew Next Day »
Daily Weekly Monthly Custorn
Actual
Average
Record
Mean Temperature
77'F
76 `F
Max Temperature
85'F
87"F
98'F(2002)
Min Temperature
69 `F
65 `F
43'F (1972)
Degee mays.
Heating Degree Days
0
0
Month to date heating degree days
0
0
Since 1 June heating degree days
0
0
Since 1 July heating degree days
3478
3243
Cooling Degree Days
12
11
Month to date cooling degree days
133
114
Year to date, cooling degree days
346
323
Since 1 June cooling degree days
133
114
Growing Degree Days
26 (Base 50)
Dew Point
68'F
Average Humidity
60
Maximum Humidity
97
Minimum Humidity
63
F`mcioitadon
Precipitation
0.08 in
0.11 in
2.29 in (1965)
Month to date precipitation
1.02
1.43
Year to date precipitation
2029.
18.46
Sea Level Pressure
29.89 in
Wind Speed
4 mph (SE)
Max Wind Speed
12 mph
Max Gust Speed
15 mph
Visibility
7 miles
Events
Fog , Rain , Thunderstorm
T = Trace of Precipitation, MM = Missing Value
Source: NWS Daily Summary
http://www.wunderground. com/historylairportlKRDU12014106112/DailyHistory.html?req_c... 7/7/2014

Weather History for Raleigh -Durham Airport, NC I Weather Underground
Page 2 of 2
F Terperaltire Deco
Poa-6 Normal HighMnro
C
9G
32
85
29
80
'- - -
'- -- --
27
75
-....z"
---
24
65
- -
21
midnight
2 3 4 5
6 7 8 9 10 11 noon 1 2 3
4 5 6 7 8 9 10
11
18
in Hy
g;3ram6111c Frt35£Ure
hPa
30.0
1016
29,9
1013
midnightl
2 3 4 5
6 7 8 9 10 11 noon 1 2 3
4 5 6 7 8 9 10
11
mph
Wind Speed
Wnd Gust
kmrh
20.0
32
15.0
24
10.0
16
5.0
00
0
rnidnigFd1 2 3 4 5
6 7 8 9 10 11 noon 1 2 3
4 5 6 7 8 9 10
11
4&nd Dir (deg'
360.0
270.0
1:'
180.0
S
,
90.0
E
r
0.0
midnight1 2 3 4 5
6 7 8 9 10 11 noon 1 2 3
4 5 6 7 8 9 10
1,4 ryn...
Certify This Report
HQrtrty rleather History & Observations
Time tEDT)
Temp.
Heat Index Dew Point
Humidity
Pressure
Visibility
Wind Dir
Wind Speed
Gust Speed Precip
Events
Conditions
12 08 AM
69.8 'F
- 66.2 'F
88V%
29.96 in
9.0 mi
Calm
Calm
- N/A
Mostly Cloudy
1239 AM
69.8 'F
- 66.2 °F
88%
29.93 in
9.0 mi
NE
4.6 mph
N/A
Mostly Cloudy
12:51 AM
69.1 `F
- 66.9'F
9355
29.92 in
8.0 mi
ENE
3.6 mph
- NIA
Mostly Cloudy
127 AM
69.8 `F
- 66.2 `F
68%
29.93 in
7.0 mi
Calm
Calm
- NIA
Mostly Cloudy
151 AM
70.0'F
- 66.9'F
90%
29.91 in
8.0 mi
ENE
5.8 mph
- N/A
Scattered
Clouds
2:51 AM
69.8 `F
- 66.2 'F
88%
29.91 in8.0
mi
East
5.8 mph
- NIA
Scattered
Clouds
3.51 AM
69.1 'F
- 66.0'F
90%
29.90 in
6.0 mi
Calm
Cain)
- NfA
Mostly Cloudy
4.05 AM
69.8 `F
- 66.2'F
883,E
29.91 in
6.0 mi
Calm
Calm
- N/A
Fog
Patches of Fog
420 AM
69.8 'F
- 66.2 'F
88%
29.91 in
6.0 mi
Calm
Calm
- NIA
Fog
Patches of Fog
4 40 AM
69.8 `F
- 66.2 `F
88 %•
29.91 in
5.0 mi
Calm
Calm
- NIA
Fog
Patches of Fog
4.51 AM
70.0'F
- 66.9'F
901.<•
29.89 in
1.0 mi
Calm
Calm
- NIA
Overcast
521 AM
69.8 'F
68.0'F
94%
29.91 in
0.2 mi
Calm
Calm
NIA
Overcast
5:51 AM
70.0'F
- 68.0'F
93%
29.90 in
0.2 mi
Calm
Calm
- N/A
Overcast
6.51 AM
71.1 'F
- 69.1 'F
931/.
29.90 in
0.2 mi
Calm
Calm
- NIA
Fog
Fog
7:51 AM
72.0'F
- 70.0'F
93 rb
29.92 in
0.5 mi
SE
3.5 mph
- NIA
Fog
Fog
8 09 AM
71.6'F
- 69.8 'F
94",
29.93 in
1.2 rm
Calm
Calm
- NIA
Mostly Cloudy
8 38 AM
73.4'F
- 69.8 *F
88°rb
29.93 in
1.2 mi
SSE
3,5 mph
- N/A
Overcast
8.44 AM
73.4 °F
69.8 'F
8896
29.94 in
2.0 mi
South
3.5 mph
N/A
Mostly Cloudy
8 51 AM
73.9 "F
- 70.0'F
87 30
29.93 in
2.0 mi
Calm
Calm
- NIA
Mostly Cloudy
10.51 AM
73.4'F
- 69.8 IF
88°/
29.94 in
4.0 mi
South
5.8 mph
- NIA
Rain
Light Rain
11.19 AM
73.4 `F
- 69.8'F
889%
29.93 in
8.0 mi
SE
5.8 mph
- 0.01 in
Thunderstorm
Thunderstorm
Show full METARS I METAR FAQ I Comma Delimited File
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Weather History for Raleigh -Durham Airport, NC ( Weather Underground
Page 1 of 1
11:51
AM
73.0 °F
68.0 °F
84%
29.92 in
10.0 mi
SE
3.5 mph
0.01 in
Mostly Cl
12:51
PM
79.0 °F
69.1 °F
72%
29.91 in
10.0 mi
Calm
Calm
NIA
Mostly CI
1:02
°F
°F
Rain Light
PM
78.8 -
68.0
69%
29.92 in
8.0 mi
Calm
Calm
- 0.00 in
Thunderstorm Thunders
and Rain
1:27
PM
78.8 °F -
71.6 °F
78%
29.90 in
10.0 mi
WSW
3.5 mph
- 0.00 in
Mostly Cl.
2:51
PM
82.9 °F 85.8 °F
68.0 °F
60%
29.85 in
10.0 mi
ESE
3.5 mph
- N/A
Mostly Cl
3:51
PM
81.0 °F
83.8 °F
68.0 °F
65%
29.83 in
10.0 mi
SSE
3.5 mph
N/A
Mostly Cl,
4:13
PM
80.6 °F
83.2 °F
68.0 °F
65%
29.85 in
10.0 mi
South
5.8 mph
NIA
Thunderstorm Thunders
4:45
PM
80.6 °F
83.9 °F
69.8 °F
70%
29.84 in
10.0 mi
ESE
5.8 mph
N/A
Mostly Cl,
4:51
PM
80.1 °F
83.2 °F
70.0 °F
71%
29.82 in
10.0 mi
SE
6.9 mph
- N/A
Mostly CIi
5:51
PM
80.1 °F
83.2 °F
70.0 °F
71%
29.82 in
10.0 mi
SSE
8.1 mph
N/A
Mostly C6
6:51
PM
80.1 °F
82.9 °F
69.1 °F
69%
29.82 in
10.0 mi
SE
10.4 mph
- N/A
Mostly Cl,
7:51
79.0 °F
-
69.1 °F
72%
29.83 in
10.0 mi
Variable
5.8 mph
- N/A
Scattered
PM
Clouds
8:51
PM
75.9 °F
-
69.1 °F
79%
29.84 in
10.0 mi
SSE
3.5 mph
- N/A
Scattered
Clouds
9:51
73.9 °F
-
68.0 °F
82%
29.84 in
10.0 mi
SE
3.5 mph
- N/A
Scattered
PM
Clouds
10:51
PM
71.6 °F
-
66.2 °F
83%
29.86 in
10.0 mi
South
4.6 mph
- N/A
Mostly Cl,
11:31
PM
71.6 °F
-
66.2 °F
83%
29.85 in
10.0 mi
Calm
Calm
- N/A
Thunderstorm Thunders
11:51
PM
72.0 °F
-
66.9 °F
84%
29.85 in
10.0 mi
Calm
Calm -
N/A
Thunderstorm Thunders
Show full METARS I METAR FAQ I Comma Delimited File
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Stormw ter Discharge Outfall (SDO)
Qualitative Monitoring Report
For guidance on filling out this form, please visit: http:Hb2o.enr.state.nc.tts/su/Forms Documents.httm#miscfonns
Permit No.: NICI 1 a/ / or Certifi ate of Coverage No.: N1C 1 �1 111
FacilityName:
County: Phone No. 1 Sq - G%o 01
Inspector: U-Fs on
Date of Inspection: X0 !
Time of Inspection: 1 �C) m
Total Event Precipitation (inches): a,
Was this a Representative Storm Event? (See information below) "-0 Yes ❑ No
Please check your permit to verify if Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
N "Representative Storm Event" is a storm event that measures greater than 0.1 inches of rainfall and tha
s preceded by at least 72 hours (3 days) in which no storm event measuring greater than 0.1 inches has
accurred. A single storm event may contain up to 10 consecutive hours of no precipitation.
By this signature, I certify that this report is accurate and complete to the best of my knowledge:
Suture of Permittee or Des 11ee)
,1.. Outfall Description:
Outfall No:�d001 —0,5;D00zStrUct e (pipe, ditch, etc.)
Receiving Stream: :. , o{ae=! ,5� 7'� v lic G� ee. .
Describe the industrial activities t occur within the/coif//a/ll drainage area:
S- ax 5 .l Qom` o e- an D P �
2. Color: Describe the color of the discharge using basic co ors (red, brown, blue, etc.) and tint
(light, medium, dark) as descriptors: h t
3. Odor: Describe any distinct odors at the discharge may have (i.., smells strongly of oil, weak
chlorine odor, etc.): 0,oz S i
Page 1 of 2
SWU-242-112508

4. Clarity: Choose the number which best describes the clarity of the discharge, where 1 is clear
and 5 is very cloudy:
5. Floating Solids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where 1 is no solids and 5 is the surface covered with floating solids:
0 3 4 5
6. Suspended Solids: Choose the number which best describes the amount of suspended solids in
the stormwater discharge, where 1 is no solids and 5 is extremely muddy:
2 3 4 5
7. Is there any foam in the stormwater discharge? Yes (No
8. Is there an oil sheen in the stormwater discharge? Yes N
9. Is there evidence of erosion or deposition at the outfall? Yes No
20. Other Obvious Indicators of Stormwater Pollution:
List and describe / 0 0 'C.-
3
Mote: Low clarity, high solids, and/or the presence of foam, oil sheen, or erosion/deposition may be
indicative of pollutant exposure. These conditions warrant further investigation.
Page 2 of 2
SVtTU-242-:12608

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a
-
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1 x 1-Liter HOPE w1no presera.
l«l`` D: 't X 1-Liter HOPE w1no (7reserv,
�Y
{
'f
pH: 1 x 125 mi HDPE wino preserv.
Nitrate/Nitrite: 1 x 500ml H'DPE wf5ml Sulfuric Acid preserv. v
i
COD: {Combine w/Nitrate/Nitrite Bottle)
TKN: (Combine wt Nitrate/Nitrite Bottle)
r.
Total Phosphorous: (Combine w/NitratetNitrite Bottle) ri
i_
),
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Ei ?-- : A'8 -dO F''C H O i C
12065 Lebanon Rd.
Mt. Juliet, TN 37122
[phone]
1-800-767-5859
Fax [phone]
Tax I.D. 62-0814289
Est. 1970
Antwoine Howard
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
Report Summary
Friday June 20, 2014
Report Number: L704491
Samples Received: 06/13/14
Client Project:
Description: Stormwater Sample
The analytical results in this report are based upon information supplied
by you, the client, and are for your exclusive use. If you have any
questions regarding this data package, please do not hesitate to call.
Entire Report Reviewed By:
Linda Cashman , ESC Representative
Laboratory Certification Numbers
A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197,
FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016,
NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002,
SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612,
MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1,
TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02
Accreditation is only applicable to the test methods specified on each scope of accreditation held
by ESC Lab Sciences.
This report may not be reproduced, except in full, without written approval from ESC Lab Sciences.
Where applicable, sampling conducted by ESC is performed per guidance provided
in laboratory standard operating procedures: 060302, 060303, and 060304.
Page 1 of 4

12065 Lebanon Rd.
Mt. Juliet, TN 37122
or'sc
(615)
758-5858
1 - 800-767-5859
Fax
[phone]
L, A - 8 5•C•I•E•N-C E•5
Tax
I.D. 62-0814289
Est.
1970
REPORT
OF ANALYSIS
Antwoine Howard
June 20, 2014
Cargill, Inc.
1400 South Blount Street
Raleigh, NC 27603
ESC Sample #
L704491-01
Date Received June 13, 2014
Description Stormwater Sample
Site ID
Sample ID OUTFALL #1
Project # .
Collected By Jason Bartley
Collection Date 06/12/14 12:00
Parameter
Result
Det. Limit
Units
Method
Date
Dil.
BOD
150.
2.00
mg/1
5210 B-2011
06/18/14
1
COD
390
10.
mg/l
410.4
06/18/14
1
pH
6.8
su
4500H+ B-2011
06/14/14
1
Nitrate -Nitrite
BDL
0.10
mg/l
353.2
06/19/14
1
Phosphorus,Total
4.5
0.10
mg/1
365.4
06/19/14
1
Kjeldahl Nitrogen, TKN
26.
1.2
mg/l
351.2
06/19/14
5
Suspended Solids
87.
2.5
mg/1
2540 D-2011
06/18/14
1
BDL - Below Detection Limit
Det. Limit - Practical Quantitation Limit(PQL)
Note:
The reported analytical results relate only to the sample submitted.
This report shall not be reproduced, except in full, without the written approval from ESC.
Reported: 06/20/14 09:34 Printed: 06/20/14 09:34
L704491-01 (PH) - 6.8 @ 20.4c
Page 2 of 4

Sample
Number
L704491-01
Attachment A
List of Analytes with QC Qualifiers
Work Sample
Group Type Analyte
WG726360 SAMP pH
Run
ID Qualifier
R2941669 T8
Page 3 of 4

Cgirfill,
DELMLR-Stormwater Permitting Program
Attn: Stormwater Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
RECEIVE(
SEP 15 -,o
CENTRAL FILES
°wR SECTION
September 9, 2014
RE: Cargill, Incorporated, Raleigh, NC — Stormwater Discharge Permit NCS000282
Year S, Period 2 - Analytical Monitoring Results
In accordance with the Cargill, Raleigh facility's Stormwater Discharge Permit NCS000282, Part III,
Section E, Cargill is submitting Discharge Monitoring Reports. Monthly monitoring is required for the
Raleigh facility as per the Tiered program requirements in Part H, Section B of the facility permit.
For the month of August, SD041 & SDO02 samples were not obtained due to those trained in storm water
sampling, were not available due to training commitments. For the dates of 8/11, Thru 8/15 /2014
training. And the week of 8/18, thru 8/22/2014 was working at another facility.
For the month of August, samples from SDO01 and SDO02 were not taken as those trained in taking the
stormwater samples were inadvertently scheduled away from the facility at the same times. Going
forward, we will ensure that someone that is trained in stormwater sampling is available at the site during
the measureable storm events.
If there are any questions regarding this submittal please feel free to contact me at [phone].
Sincerely,
Michael Klauke
Plant Superintendent
Cargill, Incorporated
Raleigh, NC
400 S. Blount Street
aleigh, NC27603-2506

NUV 2 0 2014
C,
Stormwater Discharge Outfall (SDO)
Qualitative MoWtoring Report
For guidance on filling out this form, please visit. hM://b2o.,ehrstate.nc.ii-,/su/�"�"-ortni Doc.uments.1ittn#mjscf�=
Permit No.: W of Coverage No.: 1/.4fl. .1
Facility Name:
County- JAJA Phone No. 74 710?1, 4(0
7-
Inspector .',
Date of Inspection:.�Z7
Time of Inspection: 'Q:,a . ..... A fn . .....
Total Event Precipitation (inches):
Was this a RepresehtafiveStorm Event? (See information below) MYes 7NO
Please: check your permit to verify if Qualitative Monitoring must be performed during a representative
storm event (requirements vary).
A "Representative Storm Event" is a. storm event that measures greater than 0.1 inches: of rainfall and that
is preceded -*by: at: least 72 hours: (3 days) in which no storm event rn: pasuring. greater than 0.1 inches has
R,ccu,Leq. A single storm.,event may contain up to .10 consecutive, b64s,.Qfno, Trzipitation., . . ....
Oture, I certify that this report is accurate and corn fete to the best of my knowledge:
A 1�
iattire of Peribittee or
1. Outfall Desen'
Outfall No. -NO 00 1 ar aO° s
A
Describe the ffidiistrial activities OC
within the out, drainage ararea:� within
discharge sing basic: d, brovn� blue,: d ti t
2. :Color- crib, the color .0 Pos. f, f the: b color re eV. an . n
(lig t, me -irjtk) as d In
3. Odor. Describe any di ti ct ado s that the
chlorine odor, etc.): .4:�.CAYI
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SWU.242-1-12609
(i.e., sipells straggly of Vil, weak

4, CIarity: Choose the number which best': describes the clarity of the discharge,where is clear'
and S is very cloudy:
.,. 1 �2�
5. FloatinglSolids: Choose the number which best describes the amount of floating solids in the
stormwater discharge, where l is no solids and 5' is the surface covered with floating solids;
3 4 5
7
6. Suspended Solids: Choose the number ;which best describes the amount of suspended solids in
the stormwater, discharge, where is no: solids and 5 is extremely muddy:
1 (2 J 3 4 5
e
7. Is there any foam in the, stormwater dischargO Yes �J
8, Is there ;an 611 sheen in the stormwater. discharge? Yes, No
9: Is there evidence iof erosion or deposition at the outfall? Yes No
10. Other Obvious Indicators of Stormwater Pollution;
List and describe : Gone A)f3 10
Note: Low clarity, high' solids, and/or the presence of foam, oil sheen, or erosion/degosition may be
indicative of pollutant exposure: These conditions warrant further investigation. t
;t: