WQ0014452_Residual Annual Report 2019_20200225

Initial Review
INITIAL REVIEW
Reviewer Williams, Kendall
Is this submittal an application? (Excluding additional information.)*
� Yes � No
If not an application r Annual Report
what is the submittal r Residual Annual Report
type?* r Additionallnformation
r Other
Annual Report 2019
Year*
Date Paper Copy 2/25/2020
Received:*
Project Number* WQ0014452
Email Notifications
Does this need review by the hydrogeologist?*
� Yes � No
Regional Office
CO Reviewer
Admin Reviewer [e-mail]

Submitted Form
Project Contact Information
Rease provide infornation on the person to be contacted by NAB Staff regarding electronic subrrittal, confirrration of receipt, and other issues.
..........................................................................................................................................................................................................................................................................................................................................................................
Name * Lysa Finnerty
Email Address*
[e-mail]
Project Information
Submittal Type * r New Permit Application
r Renewal
r Annual Report
c' Other
Permit Type * r Wastewater Irrigation
� Other Wastewater
r Closed -Loop Recycle
r Single -Family Residence
Wastewater Irrigation
Is a paper copy of the application being submitted?
� Yes � No � N/A
Permit Number* W00014452
Applicant\Permittee * Synagro
Facility Name * Town of Bladenboro
Phone Number*
4434899026
� Modification (Major or Minor)
r Additional Information
� Residual Annual Report
r High -Rate Infiltration
� Reclaimed Water
r Residuals
c' Other
Please provide comments/notes on your current submittal below.
Bladenboro 2019 Annual Report
Please attach all information required or requested for this submittal to be review here.
Application Forrr� Engineering Rans, Specifications, Calculations, gc.)
BLADENBORO NC 2019 Annual FINAL.pdf 17.54MB
Upload only 1 R7F document. NLRiple docurrents rrust be coni�ined into one R7F file.

For new and modification permit applications, a paper copy maybe required. If you haue any questions
about what is required, please contact the reviewer or Tessa Monday. If a paper =1:ul�ration is required,
be advised, applications accepted for pre-reuiew until both the paper and elect�c ��ic col: ies haue been
receiued. The paper copy shall include the following:
o Application Farm
o All relevant attachments {talcs, sails report, specs, etc.]
o One full-size engineering plan set
o One 11x17" engineering plan set
o One extra set of specifications
o Fee {if required]
Mailine address:
Division of Water Resources !Division of Water Resources
Non -Discharge Branch INon-Discharge Branch
1617 Mail Service Center ! Att: NathanielThomburg, 9"' Floar, Office #942W
Raleigh, NC 27699-1617 S12 N.5alisburySt.
For questions or prohlems contact Tessa Monday at tessa.monday�ncdenr.Qw or 919.707.3666.
* rJ By checking this box I acknowledge that I understand the application will not be accepted
for pre -review until the paper copy (if required) and fee (if required) have been received by
the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with
all parts of the application in correct order (as specified by the application).
Signature
Submission Date 2/21/2020

�F35 Williams Court, Suite 100
Baltimore, I�ID 21320
w«nu s3Tnagro. com
FEBRIJARY 2 I , 2020
NCDEQ
Informatiota Processing Unit
1617 Mail Service Center
Raleigh, NC 27694-1G17
Re: 2019 Annual Report for Permit No. WQ0014�52
Dear NCDEQ:
SYNAGR�
Synagro is submitting one copy and one electronic copy of the above referenced report or!
behalf of the Town of Bladenboro, NC.
If you have any questions or need additional information, please do not hesitate to coatact
Andrew Coleman at 910-234-2371 or Melvin Goad at 919-794-0766.
�1ilCerely,
Derrick Shivar
Environmental Compliance Manager
Enclosures
cc: Andrew Coleman, Towii of I3ladcnboro
Melvin Goad, Synagro
Y®lJR PARTNER F®R�. CLEAI�IER,C�REEI®IER�4RL®

Town of Bladenboro, NC
FZE�iDUAL� LAND APPLICATION PRO(�RA�Ifi
Permit No. WQ0014452
2019 ANNUAL REPORT

Town of Bladenboro, NC
Residuals Land Application Program
2019 Annual Report
TABLE OF CONTENTS
1. Certification Form and Annual Operations Summary
2. Annual Residual Sampling Summary Forms, Residuals Analysis,
& SAR Calculation Page
�. Annual Land Application Field Summary Forms
4. TCLP Analysis
5. Pathogen Reduction/Vector Attraction Reduction
6. Soil pH &Lime Application Records
7. Soil Analyses

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit #: WO0014452 County Bladen Year 2019
Facility Name (as shown on permit) Bladenboro WWTP NPDES No. NC0026352
Land Application Operator Synagro Phone# [phone]
Land application of residuals as allowed by the above permit occurred during the past calendar year?
X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied,
please attach an explanation on how the residuals were handled.
Part A —Residuals Application Summary:
Total number of application fields in the permit: 4
Total number of fields utilized for land application during the year: 1
Total amount of dry tons applied during the year for all application sites: 27.96
Total number of acres utilized for land application during the year: 9_9
Part B —Annual Compliance Statement:
Facility was compliant during calendar year 2019 with all conditions of the land application permit (including but not limited to
items 1-13 below) issued by the Division of Water Quality X YES NO.
If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken.
1. Only residuals approved for this permit were applied to the permitted sites.
2. Soil pH was. adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3 )
copies of certified laboratory results are attached.
6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15ANCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities).
7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503
regulated facilities).
8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified
in the permit.
12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13. All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C —Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete.
am aware that there are significant penalties for submitting false information, including th ossibility of fines and imprisonment for
knowing violations."
H. Blake Proctor, Town Administrator
Permittee Name and Title (type or print)
Signature of Prepares* Date
(if different from Permittee)
�. Rlo� v'� �:-�-�o,�
*Prepares is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006)

2019 ANNUAL OPERATIONS SUMMARY -LAND APPLICATION IN NC
BLADENBORO, NC
BLADENBORO, NC AEROBICALLY DIGESTED LIQUID
MONTH/YEAR AMOUNT UNIT DRY TONS UNIT
June 2019 234,400.00 G 27.96 D
YEARLY TOTAL 234,400.00 G 27.96 D
DRY METRIC
25.35
25.35
1/30/2020

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: W00014452
Facility Name: BLADENBORO, NC
NPDES# : NC0026352
or WQ# (residual only)
WWTP Name: BLADENBORO
Residuals Analysis Data
Product Type AEDLIQ
Date Sampled (grab) or 05/13/19
Date Composited
Percent Solids 2 . 8 6
PARAMETERS (mg/kg dry weight)
Arsenic 5. 37
Cadmium 1.44
Mercury o . 677
Chromium 115
Copper 599
Lead 31.3
Molybdenum 6. 12
Nickel 54.2
Selenium <5
Zinc 754
Total Phosphorus 17300
TKN 43800
Ammonia -Nitrogen 114 0 0
Nitrate and Nitrite 531
Laboratory
Waypoint Analytical Virginia Inc.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submit ' g false information, including the possibility of fines and imprisonment for knowing violations."
X � � �te-- L�-----�,, Date " [ d��
(SIGNA URE OF PREPARER)
DENR FORM RSSF (5/2003) Printed: Wednesday -February 5 2020 at 12:43:24 for: 2004 01

ANNUAL RESIDUALS SAMPLING SUMMARY FORM
Attach this form to the corresponding Annual Report.
Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form.
Permit Number: WQ0014452
Facility Name: BLADENBORO, NC
NPDES# : NC0026352
or WQ# (residual only)
WWTP Name: BLADENBORO
Residuals Analysis Data
Product Type AEDLIQ
Date Sampled (grab) or 05/13/19
Date Composited
Percent Solids 2. 86
PARAMETERS (mg/kg dry weight)
Aluminum
15500
Calcium
16200
Magnesium
2100
pH
Potassium
7.10
2270
Sodium
737
Laboratory
Waypoint Analytical Virginia Inc.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for sy�bmitting false information, including the possibility of fines and imprisonment for knowing violations."
X . `3i �._._�
(SIGNATURE OF PREPARER)
NR -Data Not Reported or Data Not Required
Date ��7--zOaG
DENR FORM RSSF-B (7/2002) Printed: Wednesday -February 5, 2020 at 12:44:23 for: 2004 01

Waypoi nt .,
ANALYTICAL
5/22/2019
Synagro Central LLC/ Bladenboro
Marshal Puryear
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 19-134-0204
Project Description: Bladenboro WWTP
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-94D1 °Fax $04-271-6446
www.waypointanalytical.com
Dear Marshal Puryear:
Waypoint Analytical Virginia, Inc. received samples) on 5/14/2019 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Pam« r�° c�-d.
Pauric McGroary
Agronomist
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Virginia 460014
Page 1 of 7

Ci�
��.
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►� �
Client: Synagro Central LLC/Bladenboro
Project: Bladenboro VWVfP
Lab Report Number: 19-134-0204
Date: 5/21 /2019
7621 Whitepine Road, Richmond, VA 23237
Main $04-743-9401 °Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 6010D
Sample 66367
Analyte: Aluminum
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range due to
the analyte concentration being greater than 25 times the method quantitation limit (MQL). A dilution test was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Iron
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range due to
the analyte concentration being greater than 25 times the method quantitation limit (MQL). A dilution test was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Potassium
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range due to
the analyte concentration being greater than 25 times the method quantitation limit (MQL). A dilution test was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Magnesium
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range due to
the analyte concentration being greater than 25 times the method quantitation limit (MQL). A dilution test was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Manganese
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range due to
the analyte concentration being greater than 25 times the method quantitation limit (MQL). A dilution test was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Lead
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range. Due to
the analyte concentration being less than 25 times the method quantitation limit (MQL) a post digestion spike was
performed and the recovery was within the method limits. No matrix interference is suspected.
Analyte: Selenium
QC Batch No: L436629
The matrix spike (MS) and/or the matrix spike duplicate (MSD) was out of the acceptable recovery range. Due to
the analyte concentration being less than 25 times the method quantitation limit (MQL) a post digestion spike was
performed and the recovery was within the method limits. No matrix interference is suspected.
Page 2 of 7

7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Report Number: 19-134-0204
Client Project Description: Bladenboro WWTP
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
SM-4500-NH3C
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
9045D
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
4500NO3F-2011
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
6010D
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
SW-7471B
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
SM-4500-NH3C-TKN
WTN
66347
Bladenboro
WWTP
Solids
05/13/2019
11:00
05/14/2019
SM-2540G
WTN
WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354
Page 3 of 7

Report Number: 19-134-0204
Account Number: 46437
Send To: Synagro Central LLC/ Bladenboro
Marshal Puryear
284 Boger Road
Mocksville , NC 27028
Wa oint.M
�/p
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa na lytica Isom
Project :Bladenboro WWTP
REPORT OF ANALYSIS Date Sampled: 5/13/2019 11:00:00
Lab Number : 66347 Date Received: 05/14/2019 00:00
Sample Id :Bladenboro WWTP Date Reported: 05/22/2019
Total Solids * 2.86 28600 100.0 CJR 05/15/2019 14:34 SM-2540G
Moisture * 97.10 100.0 CJR 05/15/2019 14:34 SM-2540G
Total Kjeldahl Nitrogen 4.38 43800 250 JPJ 05/21/2019 14:37 SM-4500-NH3C-TKN
Phosphorus 1.73 17300 50.0 JTR 05/18/2019 02:29 6010D
Potassium 0.23 2270 50.0 JTR 05/18/2019 02:29 6010D
Sulfur 1.01 10100 50.0 JTR 05/18/2019 02:29 6010D
Calcium 1.62 16200 250 JTR 05/18/2019 02:29 6010D
Magnesium 0.21 2100 50.0 JTR 05/18/2019 02:29 6010D
Sodium 0.07 737 250 JTR 05/18/2019 02:29 6010D
Iron 20800 50.0 JTR 05/18/2019 02:29 6010D
Aluminum 15500 50.0 JTR 05/18/2019 02:29 6010D
Manganese 197 5.00 JTR 05/18/2019 02:29 6010D
Copper 599 2.50 JTR 05/18/2019 02:29 6010D
Zinc 754 12.5 JTR 05/18/2019 02:29 6010D
Ammonia Nitrogen 1.14 11400 100 JPJ 05/21/2019 13:00 SM-4500-NH3C
Organic N 3.24 32400 250 05/21/2019 13:00 CALCULATION
Nitrate+Nitrite-N 531 4.89 ZBD 05/20/201914:04 4500NO3F-2011
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
B - Analyte detected in blank H -Beyond Holding Time ���G i'�C V���
Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made Pauric McGroary
to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. AgrOnOmlSt
Page 4 of 7

Report Number: 19-134-0204
Account Number: 46437
Send To: Synagro Central LLC/ Bladenboro
Marshal Puryear
284 Boger Road
Mocksville , NC 27028
Wa oint.M
Yp
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointa nalytical.com
Project :Bladenboro WWTP
REPORT OF ANALYSIS Date Sampled: 5/13/2019 11:00:00
Lab Number : 66347 Date Received: 05/14/2019 00:00
Sample Id :Bladenboro WWTP Date Reported: 05/22/2019
Chromium
Nickel
Lead
Arsenic
Mercury
Selenium
pH
Molybdenum
Comments:
1.44
1.00
JTR
05/18/2019
02:29
6010D
115
2.50
JTR
05/18/2019
02:29
6010D
54.2
2.50
JTR
05/18/2019
02:29
6010D
31.3
3.00
JTR
05/18/2019
02:29
6010D
5.37
5.00
JTR
05/18/2019
02:29
6010D
0.677
0.0158
TJS
05/20/201914:52
SW-7471B
<5.00
5.00
JTR
05/18/2019
02:29
6010D
7.1
JSL
05/20/2019
08:08
9045D
6.12
2.50
JTR
05/18/2019
02:29
6010D
All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis.
B - Analyte detected in blank H -Beyond Holding Time
Our reports
and
letters are
for
the exclusive and confidential use
of our clients, and may not be reproduced in whole or part,
nor may
any reference be made
to the work,
the
results, or
the
company in any advertising, news
release, or other public announcements without obtaining
our prior
written authorization.
Pauric McGroary
Agronomist
Page 5 of 7

0:
�..;. ,
• ` �' �
� � �
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 °Fax [phone]
www.waypointanalytical.com
Cooler Receipt Form
Customer Number: 46437
Customer Name: Synagro Central LLC/Bladenboro
Report Number: 19-134-0204
Shipping Method
Fed Ex � US Postal � Lab � Other
UPS � Client 0 Courier Thermometer ID:
Shipping container/cooler uncompromised? ®Yes � No
Number of coolers received 1
Custody seals intact on shipping container/cooler? 0 Yes � No ®Not Required
Custody seals intact on sample bottles? � Yes � No •Not Required
Chain of Custody (COC) present? � Yes � No
COC agrees with sample label(s)? ®Yes 0 No
COC properly completed � Yes � No
Samples in proper containers? � Yes � No
Sample containers intact? � Yes � No
Sufficient sample volume for indicated test(s)? � Yes � No
All samples received within holding time? � Yes 0 No
Cooler temperature in compliance? � Yes � No
Cooler/Samples arrived at the laboratory on ice. ®Yes � No
Samples were considered acceptable as cooling
process had begun.
Water -Sample containers properly preserved � Yes � No � N/A
Water -VOA vials free of headspace 0 Yes � No � N/A
Trip Blanks received with VOAs 0 Yes � No � N/A
Soil VOA method 5035 —compliance criteria met � Yes � No � N/A
� High concentration container (48 hr)
� Low concentration Encore samplers (48 hr)
� High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? � Yes ®No
Comments:
Signature: Brandi Watson Date &Time: i05/14/2019 10:47:43
Page 6 of 7

j{t '� "
. � � ..f I � l�l ( � is f!1 �.t
�� � � �
Phone;
���
A 11c�L CUSTOMER SAMPLING � SAMPLE # OF SAMPLING METHOD METHOD
LAB # SAMPLE I.D. LOCATION TYPE CONITAINERS DATE TIME PRESERVED SHIPPED
L������� ��r�
Relinquished by Sampler: Date Time Recieved by: REMARKS:
Relingwshed by. ate Time Recfeved by;
19-134-0204
IIIIIIIIIIIIIIIIIilllllllliilllll►i►�����������►����niiiiiiiim �5-4,4-20,9
Svnagro Central LLC/ Bladenboro 10:44:37
Bladenboro WWTP
� t i ��i j �I,y
l attest that the proper field sampling procedures
were used during the collection of these samples.
tte�►nquisrted by:
SPECIAL INSTRUCTIONS:
SAMPLE
1'®' SLR SL2
monitoring purposes,
(BTATE7
NHS-N NO3-N Org�anlc Cd Cr
Time
Recieved
ANALYSIS AEiaUEST
PO#:
CaCO I VolatllE
PH equiv3 Solids
SLi: Tota( Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium
SL2: Basic Test SL1 plus Sulfur, Calcium, Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zlnc
Mo � CI (NO2-N
Page 7 of 7

Product Code Product Name Sample Date Report Range Ratio
2004-01-AEDLIQ-NC BLADENBORO, NC AEROBICALLY 5/13/2019 6/1/2019-12/31/2019 0.2442
DIGESTED LIQUID
Na mg/I = (Na mg/kg x %Solids) _ 100 = (737 x 2.8600) _ 100 = 21.0782
Ca mg/I = (Ca mg/kg x %Solids) _ 100 = (16200 x 2.8600) _ 100 = 463.32
Mg mg/I = (mg mg/kg x %Solids) + 100 = (2100 x 2.8600) _ 100 = 60.06
Na meq = Na mg/I + Molec.Wgt.Na = 21.0782 = 23 = 0.916443
Ca meq = Ca mg/I _ Molec.Wgt.Ca = 463.32 = 20 = 23.166
Mg meq = Mg mg/I + Molec.Wgt.Mg = 60.06 + 12 = 5.005
SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.916443 = SgrRoot[0.5(23.166+5.005)] = 0.244185
Printed: 2/5/2020
Page 1 12:47

FACILITY NAME: BLADENBORO, NC
OWNER: TOWN OF BLADENBORO
SITE #: NC BL 00003 FIELD# : BL 00003 0004
RESIDUAL SOURCE(S): See list at bottom of report
ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PREDOMINANT SOIL SERIES: GOLDSBORO
PERMIT #: W00014452
OPERATOR: TOWN OF BLADENBORO
ANNUAL DRY TONS APPLIED : 27.96
CATION EXCHANGE CAPACITY (NON-503):
ACRES UTILIZED: 9.90 ACRES PERMITTED: 9.90
Page : 1
Lime Applied ***
Date Lb�/Ac
DATE or
allons (G) or Cubic Yazds (CY)
or Wet Tons (WT) (specify)
%
Dry
Tons
pet
Residual
Site
Cond.
Dry, Wet,
Inches
Precip.
Past 24
Appli-
cation
Method
Vola-
tili-
zation
Miner -
ali-
zation
TKN
Ammonia
Nitrogen
Nitrate
and
p,�.l
(ppm)
Crop
MONTH
Total
I Per Acre
Solids
Acre
Source
Moist
Hours
*
Rate**
Rate
Nitrite
6/17/19
74,700.00 (G)
7545.455
2.g6
0.900
BLAEDL
DRY
0-<1/2"
SLRIN
1.0
0.30
43,800. p
11,400.00 p
531.00 p
21651
SOYBEANS
6/18/19
134,800.00 (G)
13616.162
2,g6
1.624
BLAEDL
DRY
0-<1/2"
SURIN
1.0
0.30
43,800. p
11,400.00 p
531.00 p
21651
SOYBEANS
6/19/19
24,900.00 (G)
2515.152
2.g6
0.300
BLAEDL
DRY
0-<1/2"
SL'RIN
1.0
0.30
43,800. p
11,400.00 p
531.00 p
21651
SOYBEANS
Jun-19
234,400.00 (G)
23,676.769
Total Gallons/Ac: 23,676.77
Total Wet Tons/Ac:
i u�ai �,uui� i u�r•,�. V.VV
As
Cd
Cr
Cu
Pb
Hg
Mo
Ni
Se
Zn P
PAN
TOTALS
Annual Ibs/acre
0.030
0.008
0.649
3.383
0.177
0.004
0.035
0.306
0.028
4.258 97.70
122
Cumulative lbs/acre
0.131
0.049
2.892
15.598
0.859
0.025
0.137
1.306
0.141
19.335
BLAEDL = BLADENBORO, NC AEROBICALLY DIGESTED LIQUID
x
r
(SIGNATURE OF LAND APPLIER) DATE
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and
evaluated the information submitted. I am aware that there aze significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
N/A
=Not Applicable NR
=Not
Reported
or Not
Required
% =percent p =ppm or mg/kg
** Volatilization Rate :
Surface 0.5, Injection/Incorporation
1.0
*
Application Method:
SUR -Surface,
INJ -Injection,
SURIN -Incorporation
*** See Site pH &Lime
Application Records Section of Report for
Fields where Lime is to be applied in 2020

Sunvntt Environmental Technologies, Inc.
3310 Win St.
�,�
�h��saltt�+Nhl�r�r�.L >rt�a��ac�lc�r.,1F�, 1Nr
June O5, 2019
Melvin Goad
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL: [phone]
FAX: [phone]
RE: Bladenboro WWTP
Cuyahoga Fa[Is, Ohio 44223
TEL: [phone] FAX.• [phone]
Website: http://ivww.settelc.cona
Dear Melvin Goad: Order No.: 19051040
Summit Enviromnental Technologies, Inc. received 1 sample(s) on 5/14/2019 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 07256CA, Colorado, Coamecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois
200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota
409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Olvo DW, Ohio VAP
CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah
OH009232011-1, Virginia VELAP 9456, Washington C891
Page 1 of 33

SIT
�P�trlf�+�Nhi�rttcL r��c�t�,��r�€�r�, �ra�'
AnttPyilcal'�tinr� t� r����
CLIENT: Synagro
Project: Bladenboro WWTP
WorkOrder Narrative:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
Website: http://wwwsettek.cona
Case l�Tarratflve
WO#: 19051040
Date: 6/5/2019
19051040: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -off Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
19051040-OOlA TCLP-SVOC_8270E: The CCV (Batch R98606) exhibited high recovery of 2,4-
Dinitrotoluene. The associated samples are ND for 2,4-Dinitrotoluene.
19051040-OOlA TCLP-SVOC-Herb_NPW(8151): Surrogate recovery biased high due to coeluting
interferant. Sample results are N.D.
19051040-OOlA TCLP-SVOC-CPest(8081B): CCV exhibited high recoveries for Endrin. Associated
samples were ND
Revision v1
Page 2 of 33

���
�h3tiri12ctdrd�n�raL T=crtwcsLc�cir�, 9Nt+
,dr�;�Pylical L�bttixats�r��s
Summit Environmental Technologies, In
3310 Win b
Cuyahoga Fa1Ts, Ohio 442�
TEL: [phone] FAX.' (330) 253-44b
Website: http://www.settek.co
Qualifiers and Acronyms
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
WO#: 19051040
Date: 6/5/2019
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
* The result exceeds the Regulatory Limit or Maximum Contamination Limit.
m Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25%difference.
C The result has been confirmed by GC/MS.
X The result was not confirmed when GC/MS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low (-) or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low (-) or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low (-) or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low (-) or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND Not Detected RL Reporting Limit
QC Quality Control MDL Method Detection Limit
MB Method Blank LOD Level of Detection
LCS Laboratory Control Sample LOQ Level of Quantitation
LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit
QCS Quality Control Sample CRQL Contract Required Quantitation Limit
DUP Duplicate. PL Permit Limit
MS Matrix Spike RegLvl Regulatory Limit
MSD Matrix Spike Duplicate MCL Maximum Contamination Limit
RPD Relative Percent Different MinCL Minimum Compound Limit
ICV Initial Calibration Verification RA Reanalysis
ICB Initial Calibration Blank RE Reextraction
CCV Continuing Calibration Verification TIC Tentatively Identified Compound
CCB Continuing Calibration Blank RT Retention Time
RLC Reporting Limit Check CF Calibration Factor
DF Dilution Factor RF Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Revision v 1
Page 3 of 33

- ���
��tu�ltr�rdr�ti�rara� r�oaictir€�ie�c�i��, 7r�c
�rrs�yt��al i�L��r�l�ra'c�s
CLIENT: Synagro
Project: Bladenboro WWTP
Lab SampleID Client Sample ID
19051040-001 Bladenboro WWTP
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL; [phone] FAX.• [phone]
Website: http://www.settek.com
Tag No Date Collected
5/13/2019 11:00:00 AM
Workorder
Sample Summary
WO#: 19051040
OS-Jun-19
Date Received Matrix
5/14/2019 10:20:00 AM Sludge
Page 4 of 33

- � �' � Summit Environmental Technologies, Inc.
3310 Win St.
EC�4fITtb�1M�r;�r,d.L�c��r�ar�Lo��rs, ahto Cuyahoga Falls, Ohio44223
.�.nsrtyFta��P i�.���1r�t�r��4� TEL: [phone] Ff1X.- [phone]
Website: httn://www.settek.com
DATES REP®RT
WO#: 19051040
OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date
19051040-OOlA Bladenboro WWTP 5/13/2019 11:00:00 AM Sludge Ignitability of Solids (SW-846: 1030) 6/3/2019 5:55:23 PM
pH (SW9045D) 5/31/2019 3:40:31 PM
Reactive Cyanide (9014/7.3.3.2)-Solid 5/17/2019 8:10:00 PM
Reactive Sulfide (9034)/7.3.4.2 5/17/2019 8:10:00 PM
SVOC SW-846: 8151 Herbicides-TCLS/18/2019 6:00:00 PM 5/20/2019 5:00:00 PM 5/30/2019 7:33:00 PM
TCLP Mercury Analysis (SW1311/7475/18/2019 6:00:00 PM 5/21/2019 12:00:00 PM 5/22/2019 3:03:00 PM
TCLP Metals Analysis (SW1311/6010:5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 7:49:41 PM
TCLP Metals Analysis (SW1311/6010:5/18/2019 6:00:00 PM 5/20/2019 8:00:00 AM 5/22/2019 3:27:36 PM
TCLP Pesticides Analysis (SW1311/8C5/18/2019 6:00:00 PM 5/24/2019 1:00:06 PM 5/31/2019 10:24:00 PM
TCLP Semi-Volatiles Analysis 5/18/2019 6:00:00 PM 5/20/2019 1:00:00 PM 5/21/2019 4:55:00 PM
(SW1311/8270)
TCLP Volatiles Analysis 5/18/2019 6:00:00 PM 5/21/2019 2:52:00 PM
Revision vl
Page 5 of 33

- �.�� Sunan�itEnvh�on�nentalTechnologies,Inc. An`dly�lC`c�� �ep�rt
3310 YVin St.
1_P;'+rlti��tdh1�AJTAL r��c��w�?L�rc{�.�., IFtG Cuyahoga Falls, Ohio 44223 (base report)
t1rt�P}rt��t�t f! �5�rad�rJ�s TEL: [phone] FAX.• [phone] WO#: 19051040
Website: lattp://rvivlv.settelc.co»a Date Reported: 6/5/2019
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 5/13/2019 11:00:00 AM
Lab ID: 19051040-OOlA
Project: Bladenboro WWTP
Client Sample ID Bladenboro WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: DNS
TCLP MERCURY ANALYSIS (SW131117470)
TCLP Mercury ND 0.00500 mg/L 1 5/22/2019 3:03:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMO
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As) ND 0.500 mg/L 1 5/22/2019 3:27:36 PM
TCLP Barium(Ba) ND 5.00 mg/L 1 5/22/2019 3:27:36 PM
TCLP Cadmium(Cd) ND 0.100 mg/L 1 5/22/2019 3:27:36 PM
TCLP Chromium(Cr) ND 0.200 mg/L 1 5/22/2019 3:27:36 PM
TCLP Lead(Pb) ND 0.500 mg/L 1 5/22/2019 7:49:41 PM
TCLP Selenium(Se) ND 0.0500 mg/L 1 5/22/2019 3:27:36 PM
TCLP Silver(Ag) ND 0.500 mg/L 1 5/22/2019 3:27:36 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW3510C Analyst: BJH
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene ND 0.0800 mg/L 2 5/21/2019 4:55:00 PM
2,4,5-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 4:55:00 PM
2,4,6-Trichlorophenol ND 0.200 mg/L 2 5/21/2019 4:55:00 PM
2,4-Dinitrotoluene ND 0.0400 QC+ mg/L 2 5/21/2019 4:55:00 PM
Cresols, Total ND 4.00 mg/L 2 5/21/2019 4:55:00 PM
Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 5/21/2019 4:55:00 PM
Hexachlorobenzene ND 0.0400 mg/L 2 5/21/2019 4:55:00 PM
Hexachloroethane ND 0.0800 mg/L 2 5/21/2019 4:55:00 PM
Nitrobenzene ND 0.0800 mg/L 2 5/21/2019 4:55:00 PM
Pentachlorophenol ND 0.200 mg/L 2 5/21/2019 4:55:00 PM
Pyridine ND 0.200 mg/L 2 5/21/2019 4:55:00 PM
Surr: 2-Fluorophenol 55.8 10 - 109 %Rec 2 5/21/2019 4:55:00 PM
Surr: Phenol-d6 62.3 10 - 109 %Rec 2 5/21/2019 4:55:00 PM
Surr: Nitrobenzene-d5 48.8 19 - 120 %Rec 2 5/21/2019 4:55:00 PM
Surr: 2,4,6-Tribromophenol 73.8 10 - 120 %Rec 2 5/21/2019 4:55:00 PM
Surr: 2-Fluorobiphenyl 45.0 22 - 117 %Rec 2 5/21/2019 4:55:00 PM
Surr: p-Terphenyl-d14 78.8 34 - 116 %Rec 2 5/21/2019 4:55:00 PM
Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response MC Value is below Minimum Compound Limit.
N Tentatively identified compounds ND Not Detected
O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits ReVlslon V 1
RL Reporting Detection Limit U Samples with CalcVal < MDL
Page 6 of 33

Su��unit Envirom�7ental Tech��ologies, 1»c. Analytical Re1Dol�t
3310 Win St.
Ehfl��llt[5Nh1ENTA.L i�G9tCvt[71-t'4{;iFS, 'IFf�". Cu��ahoga Falls, Ohio 44223 (base report)
drr�9yl'1Ga!' i�L��rat�t;r���_. TEL: [phone] FAX.• [phone] WO#: 19051040
Website: http:/hvlvlv.settek.cona Date Reported: 6/5/2019
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 5/13/2019 11:00:00 AM
Lab ID: 19051040-OOlA
Project: Bladenboro WWTP
Client Sample ID Bladenboro WWTP
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW3510C Analyst: SFG
TCLP PESTICIDES ANALYSIS (SW1311/8081)
Chlordane, total ND 0.0250 mg/L 10 5/31/2019 10:24:00 PM
Toxaphene ND 0.0500 mg/L 10 5/31/2019 10:24:00 PM
Endrin ND 0.00500 mg/L 10 5/31/2019 10:24:00 PM
gamma-BHC ND 0.00500 d mg/L 10 5/31/2019 10:24:00 PM
Heptachlor ND 0.00500 mg/L 10 5/31/2019 10:24:00 PM
Heptachlor epoxide ND 0.00500 mg/L 10 5/31/2019 10:24:00 PM
Methoxychlor ND 0.00500 d mg/L 10 5/31/2019 10:24:00 PM
Surr: TCMX 59.5 10 - 119 %Rec 10 5/31/2019 10:24:00 PM
Surr: DCB 76.6 10 - 119 %Rec 10 5/31/2019 10:24:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: SFG
SVOC SW-846: 8151 HERBICIDES-TCLP
2,4-D ND 0.0100 mg/L 1 5/30/2019 7:33:00 PM
2,4,5-TP ND 0.00500 mg/L 1 5/30/2019 7:33:00 PM
Surr: 2,4-Dichlorophenylacetic aci 1590 20 - 140 S %Rec 1 5/30/2019 7:33:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 SW1311M Analyst: CTB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
1,2-Dichloroethane ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
MEK ND 5.00 mg/L 50 5/21/2019 2:52:00 PM
Benzene ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
Carbon tetrachloride ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
Chlorobenzene ND 2.50 mg/L 50 5/21/2019 2:52:00 PM
Chloroform ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
Tetrachloroethene ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
Trichloroethene ND 0.250 mg/L 50 5/21/2019 2:52:00 PM
Vinyl chloride ND 0.100 mg/L 50 5/21/2019 2:52:00 PM
Surr: 4-Bromofluorobenzene 91.0 70 - 130 %Rec 50 5/21/2019 2:52:00 PM
Surr: Dibromofluoromethane 84.8 70 - 130 %Rec 50 5/21/2019 2:52:00 PM
Surr: Toluene-d8 98.1 70 - 130 %Rec 50 5/21/2019 2:52:00 PM
Qualifiers: E Value above quantitation range H Holding times for preparation or analysis exceeded
M Manual Integration used to determine area response MC Value is below Minimum Compound Limit.
N Tentatively identified compounds ND Not Detected
0 RSD is greater than RSDlimit P Second column confirniation exceeds
PL Permit Limit R RPD outside accepted recovery limits Revision V 1
RL Reporting Detection Limit U Samples with CalcVal < MDL
Page 7 of 33

���
'�Fttitlft�NhtiENTAL E�G�91P.tiIfSl.t'P€�1F�, 9p'��';
.�n.�tfatdc�al L�Sc�x�raru�s
Szaaavaait Em�ia•onnaental Technologies, Inc.
3310 i�hin St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
YVebsite: http:/hvlvw.settek.cona
Analytical laeport
(base report)
WO#: 19051040
Date Reported: 6/5/2019
CLIENT: Synagro Tag Number:
Matrix: SLUDGE Collection Date: 5/13/2019 11:00:00 AM
Lab ID: 19051040-OOlA
Project: Bladenboro WWTP
Client Sample ID Bladenboro WWTP
Analyses
RCI-SOLID-W/ IGNITABILITY1030
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive
RCI-SOLID-W/ IGNITABILITY1030
IGNITABILITY OF SOLIDS (SW-846: 1030)
Ignitability
RCI-SOLID-W/ IGNITABILITY1030
PH (SW9045D)
pH
RCI-SOLID-W/ IGNITABILITY1030
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive
Result RL Qual Units
nonflammable
6.9
DF Date Analyzed
SW9014 Analyst: MS
0.481 mg/Kg 1 5/17/2019 8:10:00 PM
Qualifiers: E Value above quantitation range
M Manual Integration used to determine area response
N Tentatively identified compounds
O RSD is greater than RSDlimit
PL Permit Limit
RL Reporting Detection Limit
SW1030 Analyst: CXS
1 6/3/2019 5:55:23 P M
SW9045D Analyst: WK
s.u.@20.9C 1 5/31/2019 3:40:31 PM
SW9034 Analyst: MS
25.0 mg/Kg 1 5/17/2019 8:10:00 PM
H Holding times for preparation or analysis exceeded
MC Value is below Minimum Compound Limit.
ND Not Detected
P Second column confirmation exceeds
R RPD outside accepted recovery limits ReVlslon V 1
U Samples with CalcVal < MDL
Page 8 of 33

'� SumnaitEnvironmentalTechnologies,Inc. Accreditation Program
3310 Win st: Anal tes Re ort
�N4�rlf��1}JF�1�tdTAL F�CsiC479�LC1{;{.r_G ��� Cuyahoga Falls, Ohio 44223 Y p
�tn�.lytica! Labr�.rai�rl�fi TEL: [phone] FAX.• [phone] WO#: 19051040
Website: http://www.settekcom OS-Juu-l9
Client: Synagro State: NW
Project: Bladenboro WWTP Program Name: NC WW SCM
Sample ID Matrix Test Name Analyte Status
19051040-OOlA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A
Sludge pH (SW9045D) Hydrogen Ion (pH) A
Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U
Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U
Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4,5-TP A
Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4-D A
Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A
Sludge TCLP Metals Analysis (SW13I1/6010) Arsenic A
Sludge TCLP Metals Analysis (SW1311/6010) Barium A
Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A
Sludge TCLP Metals Analysis (SW1311/6010) Chromium A
Sludge TCLP Metals Analysis (SW1311/6010) Lead A
Sludge TCLP Metals Analysis (SW1311/6010) Selenium A
Sludge TCLP Metals Analysis (SW1311/6010) Silver A
Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A
Sludge TCLP Pesticides Analysis (SW 1311/8081) Endrin A
Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A
Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A
Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A
Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A
Key Key
NC_WW_SCM A Accredited NC WW SCM U Unavailable
Version #4
Page 9 of 33

���
�PV4rIftnN�A�MTAL 7`�iCli6+�C]l:C�f�iFS, 9Nfi
tlrtir11+t1e�P i���r,�t�rl��
Client: Synagro
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.• [phone]
Website: http://www.settekcom
Accreditation Program
Analytes Report
WO#: 19051040
State: NW
OS-Jnn-19
Project: Bladenboro WWTP Program Name: NC WW_SCM
Sample ID Matrix Test Name Analyte Status
19051040-OOlA Sludge TCLP Volatiles Analysis 1,1-Dichloroethene A
Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A
Sludge TCLP Volatiles Analysis 2-Butanone A
Sludge TCLP Volatiles Analysis Benzene A
Sludge TCLP Volatiles Analysis Carbon tetrachloride A
Sludge TCLP Volatiles Analysis Chlorobenzene A
Sludge TCLP Volatiles Analysis Chloroform A
Sludge TCLP Volatiles. Analysis Tetrachloroethene A
Sludge TCLP Volatiles Analysis Trichloroethene A
Sludge TCLP Volatiles Analysis Vinyl chloride A
NC WW SCM A Accredited NC WW SCM U Unavailable
Page 10 of 33
Version #4

Summit Environmental Technologies, Inc.
3310 Win St.
E�.'4pl't�t3t,IML�hlTA.L ��tp�t3Lt3�Ir; �Wfi Cuyahoga Falls, Ohio 44223
�n$fytdcotP i�barat�rlo� TEL: [phone] FAX. [phone]
Website: http://www.settek.com
Client: Synagro
Project: Bladenboro WWTP
QC SUMMARY REP®RT
BatchID: 37505
WO#: 19051040
OS-Jun-19
Sample ID LCS-98614 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98614
Client ID: LCSS Batch ID: 37505 TestNo: SW8260 SW1311M Analysis Date: 5/21/2019 SegNo: 2121428
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 0.0229 0.00500 0.0200 0 115 70 131
1,2-Dichloroethane 0.0204 0.00500 0.0200 0 102 70 137
MEK ND 0.100 0.100 0 99.3 55.1 163
Benzene 0.0201 0.00500 0.0200 0 100 70 132
Carbon tetrachloride 0.0194 0.00500 0.0200 0 97.0 63.7 139
Chlorobenzene ND 0.0500 0.0200 0 103 70 139
Chloroform 0.0204 0.00500 0.0200 0 102 70 130
Tetrachloroethene 0.0233 0.00500 0.0200 0 117 56.2 187
Trichloroethene 0.0208 0.00500 0.0200 0 104 64.1 138
Vinyl chloride 0.0210 0.00200 0.0200 0 105 22.1 147
Surr:4-Bromofluorobenzene 48.7 50.00 97.4 70 130
Surr: Dibromofluoromethane 45.5 50.00 90.9 70 130
Surr: Toluene-d8 50.9 50.00 102 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 11 of �3

���'� Summit Environmental Technologies, Inc. QC SUMMARY REP®RT
3310 Win St.
IEC94�It't�4UH1E1W7�d.L 1rCeiL'Vt3LCb��cS aW;f; Cuyahoga Falls, Ohio 44223
WO#: 19051040
Arr$Pytl.�l iat�orat'rx���==, TEL: [phone] FAX.• [phone]
Website: http://www.sette%.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID MB-37505 SampType: MBLK
Client ID: PBS Batch ID: 37505
Analyte Result
TestCode: tclp-voc-mstr Units: mg/L
TestNo: SW8260 SW1311M
PQL SPK value SPK Ref Val
1,1-Dichloroethene ND 0.00500
1,2-Dichloroethane ND 0.00500
MEK ND 0.100
Benzene ND 0.00500
Carbon tetrachloride ND 0.00500
Chlorobenzene ND 0.0500
Chloroform ND 0.00500
Tetrachloroethene ND 0.00500
Trichloroethene ND 0.00500
Vinyl chloride ND 0.00200
Surr: 4-Bromofluorobenzene 49.9
Surr: Dibromofluoromethane 45.6
Surr: Toluene-d8 54.0
BatchID: 37505
Prep Date: 5/18/2019
Analysis Date: 5/20/2019
%REC LowLimit HighLimit RPD Ref Val
50.00
99.8
70
130
50.00
91.3
70
130
50.00
108
70
130
RunNo: 98525
SegNo: 2119568
%RPD RPDLimit Qual
Sample ID LCS-98525 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98525
Client ID: LCSS Batch ID: 37505 TestNo: SW8260 SW1311M Analysis Date: 5/20/2019 SegNo: 2119589
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 0.0167 0.00500 0.0200 0 83.7 70 131
1,2-Dichloroethane 0.0178 0.00500 0.0200 0 89.2 70 137
MEK ND 0.100 0.100 0 96.1 55.1 163
Benzene 0.0192 0.00500 0.0200 0 96.0 70 132
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds Revision V 1
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 12 of �3

��, �- Summit Environmental Technologies, lnc. QC SUMMARY R]EP®RT
3310 Win St.
Eh4�IIZCSNrdL�9;IT,4L ���!�It�L[��a=�; '�P��". Cuyahoga Falls, Ohio 44223
WO#: 19051040
A.rr�lJrtd�� L�e�r�rard�� TEL: [phone] FAX.• [phone]
Website: http://www.sette%.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
BatchID: 37505
Sample ID LCS-98525 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98525
Client ID: LCSS Batch ID: 37505 TestNo: SW8260 SW1311M Analysis Date: 5/20/2019 SegNo: 2119589
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Carbon tetrachloride 0.0195 0.00500 0.0200 0 97.4 63.7 139
Chlorobenzene ND 0.0500 0.0200 0 94.8 70 139
Chloroform 0.0193 0.00500 0.0200 0 96.5 70 130
Tetrachloroethene 0.0184 0.00500 0.0200 0 92.2 56.2 187
Trichloroethene 0.0193 0.00500 0.0200 0 96.6 64.1 138
Vinyl chloride 0.0189 0.00200 0.0200 0 94.3 22.1 147
Surr:4-Bromofluorobenzene 50.8 50.00 102 70 130
Surr: Dibromofluoromethane 47.6 50.00 95.2 70 130
Surr: Toluene-d8 54.2 50.00 108 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 13 of 33

�.�' � Summit Environmental Technologies, Inc.
3310 Win St.
El�'4�IIt�:NM�A1T,�.L ��9�'84{�Li4�1� ��a�.^ Cuyahoga Falls, Ohio 44223
t�rrt�fSrt/t;�1' L�laoraa°t��rtc� TEL: [phone] FAX. [phone]
Website: htto://www.settelc.com
Client: Synagro
Project: Bladenboro WWTP
QC SUMMARY R]EP®RT
BatchID: 37505
WO#: 19051040
OS-Jun-19
Sample ID LCS-98614 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 98614
Client ID: LCSS Batch ID: 37505 TestNo: SW8260 SW1311M Analysis Date: 5/21/2019 SegNo: 2121429
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,1-Dichloroethene 0.0229 0.00500 0.0200 0 115 79.4 131
1,2-Dichloroethane 0.0204 0.00500 0.0200 0 102 73.6 137
MEK ND 0.100 0.100 0 99.3 55.1 163
Benzene 0.0201 0.00500 0.0200 0 100 73.1 132
Carbon tetrachloride 0.0194 0.00500 0.0200 0 97.0 63.7 139
Chlorobenzene ND 0.0500 0.0200 0 103 72.3 139
Chloroform 0.0204 0.00500 0.0200 0 102 79.3 129
Tetrachloroethene 0.0233 0.00500 0.0200 0 117 56.2 187
Trichloroethene 0.0208 0.00500 0.0200 0 104 64.1 138
Vinyl chloride 0.0210 0.00200 0.0200 0 105 22.1 147
Surr:4-Bromofluorobenzene 48.7 50.00 97.4 80.4 126
Surr: Dibromofluoromethane 45.5 50.00 90.9 70.3 125
Surr: Toluene-d8 50.9 50.00 102 82 117
Qualifiers: B Analyte detected in the associated Method Blaudc
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
O RSD is greater than RSDlimit
R RPD outside accepted recovery limits
H Holding times for preparation or anal
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Revision vl
Page 14 of 3�3

���,� Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Win St.
lcG+�4rl?i�S:IUrAK�ITfi.L rlc�J�2�ICiL���r� j��° Cuyahoga Falls, Ohio 44223 WO#: 19051040
Ain�Pyt�s�l Lat�rxratt�t�d€�� TEL: [phone] FAX.• [phone]
Website: http://www.settelc.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID
19051239-001AMS
SampType:
MS
Client ID:
BatchQC
Batch ID:
37518
Analyte
Result
BatchID: 37518
TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98666
TestNo: SW6010D SW3010A Analysis Date: 5/22/2019 SegNo: 2124011
PQL SPK value SPK Ref Val
%REC LowLimit HighLimit RPD Ref Val
TCLP Arsenic(As) 2.27 0.500 2.000 0 113 70 130
TCLP Barium(Ba) ND 5.00 2.000 0.2309 105 70 130
TCLP Cadmium(Cd) 2.04 0.100 2.000 0 102 70 130
TCLP Chromium(Cr) 2.16 0.200 2.000 0 108 70 130
TCLP Selenium(Se) 2.32 0.0500 2.000 0 116 70 130
TCLP Silver(Ag) 2.43 0.500 2.000 0.0007661 122 70 130
Sample ID 19051239-001AMSD SampType: MSD
Client ID: BatchQC Batch ID: 37518
Analyte
Result
TestCode: Mtl-TCLP-7(6 Units: mg/L
TestNo: SW6010D SW3010A
PQL SPK value SPK Ref Val
Prep Date: 5/20/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
RunNo: 98666
SegNo: 2124012
%RPD RPDLimit Qual
TCLP Arsenic(As) 2.19 0.500 2.000 0 109 70 130 2.267 3.48 20
TCLP Barium(Ba) ND 5.00 2.000 0.2309 101 70 130 0 0 20
TCLP Cadmium(Cd) 1.96 0.100 2.000 0 97.8 70 130 2.036 4.02 20
TCLP Chromium(Cr) 2.08 0.200 2.000 0 104 70 130 2.159 3.78 20
TCLP Selenium(Se) 2.24 0.0500 2.000 0 112 70 130 2.323 3.45 20
TCLP Silver(Ag) 2.34 0.500 2.000 0.0007661 117 70 130 2.432 3.95 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 15 of 33

Summit Environmental Technologies, Inc. Ql. S V lrl�lii� i R P�P�i�T
3310 Win St.
�ik!4�I'iZ�:IVf.1EAlTAL 4��5-6CdCaLCb�f���F �ht4. Cuyahoga Falls, Ohio 44223
WO#: 19051040
- t1.nz�lytA��/ �af�crra�'r3���s TEL: [phone] FAX.• [phone]
Website: htto://www.settek.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID 19051239-001AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L
Client ID: BatchQC Batch ID: 37518 TestNo: SW6010D SW3010A
Analyte Result PQL SPK value SPK Ref Val
TCLP Lead(Pb)
BatchID: 37518
Prep Date: 5/20/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
2.16 0.500 2.000 0.01223 107 70 130
Sample ID 19051239-001AMSD SampType: MSD
Client ID: BatchQC Batch ID: 37518
Analyte
TCLP Lead(Pb)
Result
TestCode:
Mtl-TCLP-7(6
Units:
mg/L
TestNo:
SW6010D
SW3010A
PQL SPK value SPK Ref Val
Prep Date: 5/20/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98666
SegNo: 2124063
%RPD RPDLimit Qual
RunNo: 98666
SegNo: 2124064
%RPD RPDLimit Qual
2.16 0.500 2.000 0.01223 108 70 130 2.157 0.351 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 16 of 33

��' � Summit Environmental Technologies, Inc. Q� SUMMARY REP®RT
3310 Win St.
�)w�4rl't'��bX1td�AJ7A,LE'EG9�di[�Ct'rGfc,, :�t�.:. Cuyahoga Falls, Ohio44223
WO#: 19051040
.� na+;�Cloa.+ �.�f:�rar�r!'eK TEL.• [phone] FAX.• [phone]
Website: http://www.settelz.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
BatchID: 37518
Sample ID MB-37518 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499
Client ID: PBS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118254
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) ND 0.500
TCLP Barium(Ba) ND 5.00
TCLP Cadmium(Cd) ND 0.100
TCLP Chromium(Cr) ND 0.200
TCLP Lead(Pb) ND 0.500
TCLP Selenium(Se) ND 0.0500
TCLP Silver(Ag) ND 0.500
Sample ID LCS-37518 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 5/20/2019 RunNo: 98499
Client ID: LCSS Batch ID: 37518 TestNo: SW6010D SW3010A Analysis Date: 5/20/2019 SegNo: 2118255
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
TCLP Arsenic(As) 2.11 0.500 2.000 0 105 80 120
TCLP Barium(Ba) ND 5.00 2.000 0 106 80 120
TCLP Cadmium(Cd) 1.95 0.100 2.000 0 97.3 80 120
TCLP Chromium(Cr) 2.19 0.200 2.000 0 110 80 120
TCLP Lead(Pb) 2.23 0.500 2.000 0 111 80 120
TCLP Selenium(Se) 2.17 0.0500 2.000 0 108 80 120
TCLP Silver(Ag) 2.32 0.500 2.000 0 116 80 120
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 17 of 33

�I, � Summit Environmental Technologies, Inc.
3310 Win St.
El�!4wI1t�Nh1Et�T,�.L 3���-N�,1[SC�;��lr�; �!�,^ Cuyahoga Falls, Ohio 44223
.4.rP�flrtdc�P La'ur_rrtat�rl�� TEL: [phone] FAX.• [phone]
Website: ham://www.settelc.com
Client: Synagro
Project: Bladenboro WWTP
QC SUMMARY REPORT
BatchID: 37528
WO#: 19051040
OS-Jun-l9
Sample ID 19051350-001AMS SampType: MS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98606
Client ID: BatchQC Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2120533
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
1,4-Dichlorobenzene 0.282 0.0800 0.8000 0 35.3 33.8 126 QMR
2,4,5-Trichlorophenol 0.432 0.200 0.8000 0 54.0 28.7 144 QMR
2,4,6-Trichlorophenol 0.451 0.200 0.8000 0 56.4 12.8 153 QMR
2,4-Dinitrotoluene 0.455 0.0400 0.8000 0 56.9 20.4 155 QC+QMR
o-Cresol 0.387 0.200 0.8000 0 48.4 10 148 QMR
Cresols, Total ND 4.00 1.600 0 50.3 10 148 QMR
Hexachloro-1,3-butadiene 0.281 0.0160 0.8000 0 35.1 29 126 QMR
Hexachlorobenzene 0.352 0.0400 0.8000 0 44.0 33.7 134 QMR
Hexachloroethane 0.267 0.0800 0.8000 0 33.4 32.8 132 QMR
Nitrobenzene 0.358 0.0800 0.8000 0 44.8 20 158 QMR
Pentachlorophenol 0.473 0.200 0.8000 0 59.1 10 176
Pyridine 0.254 0.200 0.8000 0 31.7 10 130
Surr:2-Fluorophenol 0.404 1.000 40.4 3.39 130
Surr: Phenol-d6 0.457 1.000 45.7 5 130
Surr: Nitrobenzene-d5 0.344 1.000 34.4 14.5 154
Surr: 2,4,6-Tribromophenol 0.524 1.000 52.4 19.5 130
Surr:2-Fluorobiphenyl 0.350 1.000 35.0 34.4 130
Surr: p-Terphenyl-d14 0.539 1.000 53.9 8.86 156
Qualifiers: B Analyte detected in the associated Method Blanlc
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
O RSD is greater than RSDlimit
R RPD outside accepted recovery limits
H Holding times for preparation or anal
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Lirnit
Revision vl
Page 18 of 33

�� 1 � Summit Environmental Technologies, Inc.
3310 Win St.
�[sh4rfi��Nh1I1�JTAL �c�9�¢ti1Cit['aGo!=5,. JFk�C; Cuyahoga Falls, Ohio 44223
i�.rr�lyti�c�P i�l��t'a1t�1'��� TEL: [phone] FAX.• [phone]
YT�ebsite: http://www.settelc.com
Client: Synagro
Project: Bladenboro WWTP
Sample ID
19051350-001AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
37528
Analyte
Result
TestCode: SVOC-BNA_T Units: mg/L
TestNo: SW8270 SW3510C
PQL SPK value SPK Ref Val
QC SUMMARY REP®RT
WO#: 19051040
OS-Jun-19
BatchID: 37528
Prep Date: 5/20/2019
Analysis Date: 5/21/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98606
SegNo: 2120534
%RPD RPDLimit Qual
1,4-Dichlorobenzene 0.402 0.0800 1.600 0 25.2 33.8 126 0.2824 35.0 30 RS
2,4,5-Trichlorophenol 0.625 0.200 1.600 0 39.1 28.7 144 0.4320 36.5 30 R
2,4,6-Trichlorophenol 0.634 0.200 1.600 0 39.6 12.8 153 0.4508 33.8 30 R
2,4-Dinitrotoluene 0.654 0.0400 1.600 0 40.9 20.4 155 0.4548 35.9 30 RQC+
o-Cresol 0.537 0.200 1.600 0 33.6 10 148 0.3872 32.4 30 R
Cresols, Total ND 4.00 3.200 0 34.9 10 148 0 0 30 R
Hexachloro-1,3-butadiene 0.423 0.0160 1.600 0 26.4 29 126 0.2808 40.5 30 RS
Hexachlorobenzene 0.498 0.0400 1.600 0 31.2 33.7 134 0.3520 34.4 30 RS
Hexachloroethane 0.374 0.0800 1.600 0 23.4 32.8 132 0.2668 33.6 30 RS
Nitrobenzene 0.513 0.0800 1.600 0 32.1 20 158 0.3580 35.6 30 R
Pentachlorophenol 0.607 0.200 1.600 0 37.9 10 176 0.4728 24.8 30
Pyridine 0.312 0.200 1.600 0 19.5 10 130 0.2536 20.5 30
Surr:2-Fluorophenol 0.590 2.000 29.5 3.39 130 0
Surr: Phenol-d6 0.646 2.000 32.3 10 130 0
Surr: Nitrobenzene-d5 0.500 2.000 25.0 14.5 154 0
Surr: 2,4,6-Tribromophenol 0.776 2.000 38.8 19.5 130 0
Surr:2-Fluorobiphenyl 0.507 2.000 25.4 34.4 130 0 S
Surr: p-Terphenyl-d14 0.754 2.000 37.7 8.86 156 0
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range
M Manual Integration used to determine area response
0 RSD is greater than RSDlimit
R RPD outside accepted recovery limits
H Holding times for preparation or anal
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Revision vl
Page 19 of 3�3

��, � Summit Environmental Technologies, Inc. QC SUMMARY R]C+ P®RT
3310 Win St.
E�C�4rl'R�CYIUWENTAL ����,I[5�-ibGi=�; ��:�" Cuyahoga Falls, Ohio 44223
WO#: 19051040
�:n$fytic��' L���xrattyrles TEL: [phone] FAX. [phone]
Website: http://www.settelr.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID MB-37528 SampType: MBLK
Client ID: PBS Batch ID: 37528
Analyte Result
BatchID: 37528
TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019 RunNo: 98559
TestNo: SW8270 SW3510C Analysis Date: 5/21/2019 SegNo: 2119054
PQL SPK value SPK Ref Val
1,4-Dichlorobenzene ND 0.0400
2,4,5-Trichlorophenol ND 0.100
2,4,6-Trichlorophenol ND 0.100
2,4-Dinitrotoluene ND 0.0200
o-Cresol ND 0.100
Cresols, Total ND 2.00
Hexachloro-1,3-butadiene ND 0.00800
Hexachlorobenzene ND 0.0200
Hexachloroethane ND 0.0400
Nitrobenzene ND 0.0400
Pentachlorophenol ND 0.100
Pyridine ND 0.100
Surr: 2-Fluorophenol 0.486
Surr: Phenol-d6 0.605
Surr: Nitrobenzene-d5 0.501
Surr: 2,4,6-Tribromophenol 0.585
Surr: 2-Fluorobiphenyl 0.566
Surr: p-Terphenyl-d14 0.676
%REC LowLimit HighLimit RPD Ref Val
1.000
48.6
10
109
1.000
60.5
10
109
1.000
50.1
19
120
1.000
58.5
10
120
1.000
56.6
22
117
1.000
67.6
34
116
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 20 of 33

�, � Summit Environmental Technologies, Inc.
3310 Win St.
EMtirli��l',IMENT�tL'��C7�etilt3f.t'��^,I��,_:�tr„ Cuyahoga Falls, Ohio44223
- 11.rraaf�rl��1 i��rraax�t'd€+� TEL: [phone] FAX.• [phone]
Website: httn:/hvww.settek.com
Client: Synagro
Project: Bladenboro WWTP
QC SUMMARY RIEP�RT
WO#: 19051040
OS-Jun-19
BatchID: 37528
Sample ID LCS-37528 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 5/20/2019
Client ID: LCSS Batch ID: 37528 TestNo: SW8270 SW3510C Analysis Date: 5/21/2019
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
1,4-Dichlorobenzene 0.409 0.0400 0.8000 0 51.2 36.4 130
2,4,5-Trichlorophenol 0.571 0.100 0.8000 0 71.4 31.7 132
2,4,6-Trichlorophenol 0.570 0.100 0.8000 0 71.2 31.1 133
2,4-Dinitrotoluene 0.568 0.0200 0.8000 0 71.0 43.3 130
o-Cresol 0.514 0.100 0.8000 0 64.2 32.9 130
Cresols, Total ND 2.00 1.600 0 65.2 31.7 130
Hexachloro-1,3-butadiene 0.403 0.00800 0.8000 0 50.4 31.4 130
Hexachlorobenzene 0.528 0.0200 0.8000 0 66.0 43.1 130
Hexachloroethane 0.396 0.0400 O.S000 0 49.5 36.5 130
Nitrobenzene 0.499 0.0400 0.8000 0 62.4 39.5 130
Pentachlorophenol 0.518 0.100 0.8000 0 64.8 34 130
Pyridine 0.138 0.100 0.8000 0 17.3 10 130
Surr: 2-Fluorophenol 0.604 1.000 60.4 17.1 130
Surr: Phenol-d6 0.648 1.000 64.8 10 130
Surr: Nitrobenzene-d5 0.615 1.000 61.5 32.6 130
Surr:2,4,6-Tribromophenol 0.714 1.000 71.4 4.43 130
Surr: 2-Fluorobiphenyl 0.621 1.000 62.1 41.8 130
Surr: p-Terphenyl-d14 0.814 1.000 81.4 36.4 130
RunNo: 98559
SegNo: 2119055
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
m
Revision vl
Page 21 of 33

��' � Summit Environmental Technologies, Inc. QC SUMMARY R]EP®RT
3310 Win St.
�9l�wff��Nr�1L�t�7,�.L�!c��u�t�C,��tT.9', aFt�` Cuyahoga Falls, Ohio 44223
WO#: 19051040
,4n�fyt�cai Lat��rratcrf�s TEL.• [phone] FAX. [phone]
Website: http://www.settelc.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID 19051239-001AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM
Client ID: BatchQC Batch ID: 37541 TestNo: SW7470A SW7470A
Analyte Result PQL SPK value SPK Ref Val
TCLP Mercury
0.00445 0.00200 0.00400
Sample ID
19051239-001AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
37541
Analyte
TCLP Mercury
Result
BatchID: 37541
Prep Date: 5/21/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
0 111 75 125
TestCode: HG_TCLP(74 Units: PPM
TestNo: SW7470A SW7470A
PQL SPK value SPK Ref Val
0.00451 0.00200 0.00400
Prep Date: 5/21/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98627
SegNo: 2122483
%RPD RPDLimit Qual
RunNo: 98627
SegNo: 2122484
%RPD RPDLimit Qual
0 113 75 125 0.00445 1.34 20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 22 of 33

���,� Summit Environmental Technologies, Inc. QC SUMMARY R]EP®RT
3310 Win St.
EIvh4�l'iit3XJh1ENTAL'1i��tE@VC�L.�+�+E_S,. ��+" Cuyahoga Falls, Ohio 44223
WO#: 19051040
:�:.rTgfyt/,c�P L���raic�t���� TEL: [phone] FAX.• [phone]
Website: http://www.settek.com � OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID MB-37541 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM
Client ID: PBS Batch ID: 37541 TestNo: SW7470A SW7470A
Analyte Result PQL SPK value SPK Ref Val
TCLP Mercury
ND 0.00200
Sample ID LCS-37541 SampType: LCS TestCode: HG_TCLP(74 Units: PPM
Client ID: LCSS Batch ID: 37541 TestNo: SW7470A SW7470A
Analyte Result PQL SPK value SPK Ref Val
TCLP Mercury
0.00440 0.00200 0.00400
BatchID: 37541
Prep Date: 5/21/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
Prep Date: 5/2'I/2019
Analysis Date: 5/22/2019
%REC LowLimit HighLimit RPD Ref Val
0 110 80 120
RunNo: 98623
SegNo: 2122307
%RPD RPDLimit Qual
RunNo: 98623
SegNo: 2122308
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 23 of 33

��' � Summit Environmental Technologies, Inc. QC S V 1rl�RY REP®RT
3310 Win St.
�1lhrtiT�SNh1�]kJTA.L AfC7-vZ"]G3L��^,l�S, ;�;±' Cuyahoga Falls, Ohio 44223
WO#: 19051040
�k_rr�f}rta��l L�Sorattsrle� TEL: [phone] FAX. [phone]
Website: htto://www.settelc.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
BatchID: 37600
Sample ID MB-37600 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799
Client ID: PBS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142057
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Chlordane, total ND 0.00250
Toxaphene ND 0.00500
Endrin ND 0.000500
gamma-BHC ND 0.000500 d
Heptachlor ND 0.000500 d
Heptachlor epoxide ND 0.000500 d
Methoxychlor ND 0.000500 d
Surr: TCMX 9.56 20.00 47.8 10 119
Surr: DCB 16.6 20.00 82.9 10 119
Sample ID LCS-37600 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 5/24/2019 RunNo: 98799
Client ID: LCSS Batch ID: 37600 TestNo: SW8081 SW3510C Analysis Date: 5/24/2019 SegNo: 2142058
Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual
Endrin 0.0101 0.000500 0.0100 0 101 20 216
gamma-BHC 0.00768 0.000500 0.0100 0 76.8 20 197
Heptachlor 0.00679 0.000500 0.0100 0 67.9 20 200
Heptachlor epoxide 0.00803 0.000500 0.0100 0 80.3 20 200
Methoxychlor 0.00978 0.000500 0.0100 0 97.8 20 227
Surr: TCMX 11.5 20.00 57.5 20 143
Surr: DCB 18.7 20.00 93.5 20 151
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds ReViSion V 1
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 24 of 33

���'� Summit Environmental Technologies, Inc. QC SUMMARY R]EP®RT
3310 Win St.
E[�hwl'ii�ShlhlENTt�.L���iVCSL['�vi�,'I�;�^ Cuyahoga Falls, Ohio44223
WO#: 19051040
4 �a�l�rt�ca�!' ia�ta��rraJr�rd€�s TEL: [phone] FAX. [phone]
Website: htto://www.settelc.com OS-Juu-I9
Client: Synagro
Project: Bladenboro WWTP BatchID: R98750
Cyanide, Reactive ND 0.485
Cyanide, Reactive 9.43 0.490 10.00 0 94.3 85 115
Cyanide, Reactive 0.524 0.490 0.5000 0 105 50 150
Cyanide, Reactive 10.0 0.500 10.00 0.3081 97.3 81.3 118
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anab
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds Revlslon vl
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 25 of 3�3

�,� Summit Environmental Technologies, Inc. QC SLT�VIMARY R]EP®RT
3310 Win St.
EEibwltt2f:MJM�h�T�EIL T�e�}��iCa4C4�I�S; ;�k�.^ Cuyahoga Falls, Ohio 44223
WO#: 19051040
— .4.raefyCdc�l L��aCr,ra�cries TEL: [phone] FAX. [phone]
Wehsite: http://www.settelz.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID 19051158-011AMS SampType: MS
Client ID: BatchQC Batch ID: R98750
Analyte
Result
Sample ID
19051158-011AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98750
Analyte
Cyanide, Reactive
Result
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
PQL SPK value SPK Ref Val
TestCode: Cyanide,Rea Units: mg/L
TestNo: SW9014
PQL SPK value SPK Ref Val
BatchID: R98750
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98750
SegNo: 2129319
%RPD RPDLimit Qual
RunNo: 98750
SegNo: 2129320
%RPD RPDLimit Qual
10.2 0.500 10.00 0.3081 98.7 81.3 118 10.04 1.39 5
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Lirnit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 26 of �3

�' � Summit Environmental Technologies, Inc. QC SUMMARY R�+ P®RT
3310 Win St.
E6+;i4PP>t�N�Al=tiT�.L7?cCr�tiit�LiS�I�S, 1�?' Cuyahoga Falls, Ohio 44223
WO#: 19051040
.dn��f;��d.r' Gat�crra�tsrl�� TEL: [phone] FAX.• [phone]
Website: http.•//www.settelc.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP BatchID: R98776
Sulfide, Reactive ND 25.0
Sulfide, Reactive 4560 25.0 4800 0 95.0 85 115 .
Sulfide, Reactive 4720 25.0 4800 0 98.3 75 125
Sulfide, Reactive 4680 25.0 4800 0 97.5 75 125 4720 0.851 30
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
Revision vl
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 27 of 33

���'� Summit Environmental Technologies, Inc. QC SUMMARY REP®RT
3310 Win St.
�t�4rlit�rd�.t�t�TAL���t�[��rr�sr� „; j�a�^ Cuyahoga Falls, Ohio 44223 WO#: 19051040
�.n��PyFt/c�:i' L�l�ora�a�le� TEL: [phone] FAX. [phone]
Website: http://www.settek.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID
19051158-011AMSD
SampType:
MSD
Client ID:
BatchQC
Batch ID:
R98776
Analyte
Result
TestCode: Sulfide,React Units: mg/L
TestNo: SW9034
PQL SPK value SPK Ref Val
BatchID: R98776
Prep Date:
Analysis Date: 5/17/2019
%REC LowLimit HighLimit RPD Ref Val
RunNo: 98776
SegNo: 2130210
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 28 of 33

���,� Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Win St.
E�P4rlt"tCNMEt�TAL�C9�["J€5L��3O1�; a�:�^ Cuyahoga Falls, Ohio 44223
WO#: 19051040
- ,dnei'�tic�1 iatanr�lnrles TEL: [phone] FAX.• [phone]
Website: http://www.settelc.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID LCS-R98995
Client ID: LCSS
Analyte
pH
Sample ID CHECK 7
Client ID: LCSS
Analyte
pH
SampType: LCS
Batch ID: R98995
Result
SampType: LCS
Batch ID: R98995
Result
7.0
BatchID: R98995
TestCode: pH_S(9045D) Units: s.u.@22.(IC Prep Date:
TestNo: SW9045D Analysis Date: 5/31/2019
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
7.0
0 100 90 110
TestCode: pH_S(9045D) Units: s.u.@22.3C
TestNo: SW9045D
Prep Date:
Analysis Date: 5/31/2019
PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val
7.0
0 101 90 110
RunNo: 98995
SegNo: 2139142
%RPD RPDLimit Qual
RunNo: 98995
SegNo: 2140377
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 29 of 33

���,� Summit Environmental Technologies, Inc. QC SiTMMARy REPORT
3310 Win St.
IEN�k�lliOIUME}�77AL 1'�iC9�Ci€5[,C9w,IzSt �h��^. Cuyahoga Falls, Ohio 44223
WO#: 19051040
�1.�rttfl(C}.c,�� L�f��ratc�ra�� TEL: [phone] FAX.• [phone]
Website: http://wwwsettek.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID 19052000-001BDUP SampType: DUP
Client ID: BatchQC Batch ID: R98995
Analyte
pH
Result
6.9
TestCode: pH_NPW(450 Units: s.u.@20.3C
TestNo: SW9045D
PQL SPK value SPK Ref Val %REC
BatchID: R98995
Prep Date:
Analysis Date: 5/31/2019
LowLimit HighLimit RPD Ref Val
RunNo: 98995
SegNo: 2140375
%RPD RPDLimit Qual
6.9 0.6 5
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anah
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 30 of 33

��'� Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Win St.
�644ri��YJtdEb]TItL �C�C4t�L�i^,rrro, �►�.�^ Cuyahoga Falls, Ohio 44223
WO#: 19051040
�lrral�r.P��t i�rt��arate�rie� TEL: [phone] FAX.• [phone]
Website: http://www.settek.com OS-Jun-19
Client: Synagro
Project: Bladenboro WWTP
Sample ID LCS-R99073 SampType: LCS TestCode: Ignitability_S Units:
Client ID: LCSS Batch ID: R99073 TestNo: SW1030
Analyte Result PQL SPK value SPK Ref Val
Ignitability
7.94
7.240
BatchID: R99073
Prep Date:
Analysis Date: 6/3/2019
%REC LowLimit HighLimit RPD Ref Val
0 110 70 130
RunNo: 99073
SegNo: 2142958
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Revision vl
Page 31 of 33

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Page 32 of 33

Sun¢nzit Environmental Technologies, bzc
��.. 3310 YVin St.
F@VS�IItL'�N��1EMIl'�tLTZC�iPv1f5L�PGl�$,�N€: Cuyahoga Falls, Ohio44223 Sample Log -In Check List
_ � �ln�f�t�'c�/ Labhrsrdrteh TEL: [phone] FAX. [phone]
I�ebsite: htto://www.settek.co�n
Client Name: SYN-NC-27028 Work Order Number: 19051040 RcptNo: 1
Logged by: Jesseca E. Westfall
Completed By: Jesseca E. Westfall
Reviewed By: Jennifer Woolf
5/14/2019 10:20:00 AM
5/14/2019 3:56:46 PM
5/15/2019 10:34:36 AM
t t'f�
��
t�
}
i
Chain of Custody
1, Is Chain of Custody complete? Yes � No ❑ Not Present ❑
2, How was the sample delivered? UPS
Log In
3, Coolers are present? Yes❑ No ❑ NA ❑
4. Shipping container/cooler in good condition? Yes d❑ No ❑
Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present❑
No. Seal Date: Signed By:
5, Was an attempt made to cool the samples? Yes❑ No ❑ NA ❑
6, Were all samples received at a temperature of >0° C to 6.0°C Yes � No ❑ NA ❑
7. Sample(s) in proper container(s)? Yes 0 No ❑
$, Sufficient sample volume for indicated test(s)? Yes � No ❑
g_ Are samples (except VOA and ONG) properly preserved? Yes❑ No ❑
10. Was preservative added to bottles? Yes ❑ No❑ NA ❑
11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑�
12. Were any sample containers received broken? Yes ❑ No ❑�
13. Does paperwork match bottle labels? Yes❑ No ❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody? Yes 0 No ❑
15. Is it clear what analyses were requested? Yes❑ No ❑
16. Were all holding times able to be met? Yes � No ❑
(If no, notify customer for authorization.)
Special Handlin_g (if applicable)
17, Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA ❑�
- -- _.
Person Notified: � Date
f---- -
By Whom: Via: ❑ eMail ❑Phone ❑Fax ❑ In Person
Regarding:
T--__.._.—__——__....._....._...._------------ _........-—---___—_—,
Client Instructions:
1 g, Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
Seal Intact
No
Seal Date
Signed By
1
5.7
Good
Not Present
_Seal
Page 33 of 33

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name:
WWTP Name:
Monitoring Period
Town of Bladenboro
Bladenboro WWTP
From O1/O1/2019 To
WQ Permit Number: WQ0014452
NPDES Number: NC0026352
12/31/2019
Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed:
Class A:
Alt. 1/A (time/temp) Alt. 2B (Alk Treatment) Alt. 3/C (Prior Testing)
Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP)
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost Heat Drying Heat Treatment Thermophilic
Beta Ray Gamma Ray Pasteurization
Class B:
Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens
If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization
Anaerobic Digestion
Air Drying
Composting
Aerobic Digestion
Tf annlirahle to alternative nerfnrmed (Class A nr Class Rl complete the following monitoring data:
Parameter
Allowable Level in Sludge
Pathogen Density
No. of
Frequency
Sample
Analytical
Excee-
of
Type
Technique
Minimum Geo. Mean Maximum Units
deuces
Analysis
Fecal
2x10 to the 62h
MPN
MPN/g
Coliform
power per gram
of total solids
Q4700
<16500
18800
CFU/g
0
Once a
grab
9222D -
CFU
year
MF
1000 MPN per gram of
MPN/g
total solids (dry weight)
Salmonella
3 MPN per 4 grams total
bacteria (in
solids (dry weight)
lieu of fecal
coliform)
Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed:
Option/Alt. 1
(VS reduction)
Option/Alt. 5
(14-Day Aerobic)
Option/Alt. 9
(Injection)
Option/Alt. 2
(40-day bench)
Option/Alt. 6
(Alk Stabilization)
Option/Alt. 10
(Incorporation) X
CERTIFICATION STATEMENT (please check the appropriate statement)
Option/Alt. 3
(30-day bench)
Option/Alt. 7
(Drying —Stable)
Option/Alt. 4
(Spec. 02 uptake)
Option/Alt. 8
(Drying —Unstable)
No vector attraction reduction alternatives were performed
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction
reduction requirement m 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an
explanation why you have not met one or both of the requirements.)
"This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified
ersonnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have
en�et.1 I an�vare $hat there�•e signifi�ar}t penaltie�for f, alse certification including fine and imprisonment."
4Ken 4 rya D 1" d �L1,Jk � 1C,,fy
era., r� t h7��rA.,»+A,- �J �'rf,
d m and T't type o pant)
�a�.a_--- l�--A. �%�2o2v
of Preparer* Date
Land Applier Name and Title (if applicable) (type or print)
Signature of Land Applier (if applicable)
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26)

Agricultural Lime Application Log
Year: 2019
Project: Bladenboro WWTP
Fields
Soil
Lime Reauirements
Tons Acre
Date
(state -county -site -field)
PH
(from soil analysis)
Applied
A _died
NC-BL-03-04
5.8
O.OT/AC
N/A
N/A

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY20-SL000326
�G�pD1'TQRF'Wa Predictive Client: Melvin Goad Advisor: Melvin Goad
zoo _ �o2N Synagro Synagro
� � Mehlich-3 Extraction 284 Boger Rd 284 Boger Rd
� y S o i I Report Mocksville, NC 27028 Mocksville, NC 27028
N � �. '" Links to Helpful Information Sampled: 06/11/2019 Sampled County : Bladen
. �� $�
Received: 07/08/2019
Farm: Not Provided Completed: 07/17/2019 Client ID: 404711 Advisor ID: 404711
Sample ID: BL34 Recommendations: Lime Nutrients (Ib/acre) More
Crop (tons/acre) N P2Os K2O Mg S Mn Zn Cu B Information
Lime History: 1-Soybean 0.0 0 0 100 0 0 0 0 0 0 Note: 3
2 _ 0.0
Test Results [units - W/V in g/crr>3; CEC and Na in meq/100 crrr3; NOs-N in mg/drrt3]: Soil Class: Mineral
HM% WN CEC BS% Ac pH P-I K-I Ca% Mg% S-I Mn-I Mn-AI1 Mn-AI2 Zn-I � Zn-AI Cu-I Na ESP SS -I NOs-N
0.41 1.22 4.1 77 0.9 5.8 214 20 61 14 50 32 29 132 132 290 0.1 2
North Carolina
Reprogramming of the laboratory -information -management system that makes this report possible is
being funded through a grant from the North Carolina Tobacco Trust Fund Commission.
bbacco Trust Fund Commission
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

NCDA&CS
Melvin Goad
mic Division Phone: [phone] Website: www.
Understanding the Soil Report: explanation of measurements, abbreviations and units
Recommendations
nomii
Lime
If testing finds that soil pH is too low for the crops) indicated, a lime recommendation will be given in units of either
ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting.
For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at
time, even if the report recommends more. You can apply the rest in similar increments every six months until the full r
is applied. If MG is recommended and lime is needed, use dolomitric lime.
Fertilizer
Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of
Ib/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies
for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they
are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is
an excellent source; 175 to 250 Ib per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear
only on reports for greenhouse soil or problem samples.
Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z
notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not
need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit
ncagr.gov/agronomi/pubs.htm.
Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find
the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/ob,oart4.html�fsfind information that
may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizes
Test Results
The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the- soil and its degree of acidity. The
remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-AI1, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routine)
available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.gov/agronomi/uVrst.htm
Report No. FY20-SL000326
Page 2 of 2
Report Abbreviations
Ac exchangeable acidity
B boron
BS% %CEC occupied by basic cations
Ca% %CEC occupied by calcium
CEC cation exchange capacity
Cu-I copper index
ESP exchangeable sodium percent
HM% percent humic matter
K-I potassium index
K20 potash
Mg% %CEC occupied by magnesium
MIN mineral soil class
Mn manganese
Mn-AI1 Mn-availability index for crop 1
Mn-AI2 Mn-availability index for crop 2
Mn-I manganese index
M-O mineral -organic soil class
N nitrogen
Na sodium
NOs-N
nitrate nitrogen
ORG
organic soil class
pH
current soil pH
P-I
phosphorus index
PzOs phosphate
S-I sulfur index
SS -I soluble salt index
WN weight per volume
Zn-AI zinc availability index
Zn-I zinc index