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HomeMy WebLinkAboutWQ0001800_Residual Annual Report 2019_20200225Initial Review INITIAL REVIEW Reviewer Williams, Kendall Is this submittal an application? (Excluding additional information.)* r Yes r No If not an application r Annual Report what is the submittal r Residual Annual Report type?* r Additional Information r Other Annual Report 2019 Year* Date Paper Copy 2/25/2020 Received:* Project Number* WQ0001800 Email Notifications Does this need review by the hydrogeologist?* r Yes r No Regional Office CO Reviewer Admin Reviewer Kendall.Williams@ncdenr.gov Submitted Form Project Contact Information Rease provide information on the person to be contacted by MB Staff regarding electronic subnittal, confirmation of receipt, and other issues. .......................................................................................................................................................................................................................................................................................................................................................................... Name * Lysa Finnerty Email Address* Ifinnerty@synagro.com Project Information Submittal Type* r New Permit Application r Renewal r Annual Report r Other Permit Type * r Wastewater Irrigation r Other Wastewater r Closed -Loop Recycle r Single -Family Residence Wastewater Irrigation Is a paper copy of the application being submitted? r Yes r Nor N/A Permit Number* WQ0001800 Applicant\Permittee * Synagro Facility Name * Town of Yadkinville Phone Number* 4434899026 r Modification (Major or Minor) r Additional Information r Residual Annual Report r High -Rate Infiltration r Reclaimed Water r Residuals r Other Please provide comments/notes on your current submittal below. Yadkinville 2019 Annual Report Please attach all information required or requested for this submittal to be review here. Application Form Engineering Rans, Specifications, Calculations, Etc.) YADKIWILLE NC 2019 Annual Report FINAL.pdf 42.95MB Upload only 1 R7F document. NL@iple documents must be combined into one R7F file. For new and modification permit applications, a paper copy may be required. If you have any questions about what is required, please contactthe reviewer or Tessa Monday. If a paper 2-pol cation is required, be advised, applications accepted for pre -review until both the paper and elect-c-ii.- --ol:ies have been received. The paper copy shall include the following: o Application Form o All relevant attachments {talcs, soils report, specs, etc.] o One full-size engineering plan set o One 11x17" engineering plan set o One extra set of specifications o Fee (if required) Mailine address: Division of Water Resources ! Division of Water Resources Non -Discharge Branch I Non -Discharge Branch 1617 Mail Service Center I Att: Nathaniel Thornburg, P Floor, Office #942W - = Raleigh, NC 27699-1617 S12 N.5alisburySt. For questions or problems contact Tessa Monday attessa.monday@)ncdenr.Qov or 919.707.3560. * rJ By checking this box I acknowledge that I understand the application will not be accepted for pre -review until the paper copy (if required) and fee (if required) have been received by the Non -Discharge Branch. I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Signature Submission Date 2/21/2020 435 `Williams Court, Suite 100 Baltimore, 1\,M 21220 wwwsynagro.corn FEBRUARY 21, 2020 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2019 Annual Report for Permit No. WQ0001800 Dear NCDEQ: SYNAGRO Synagro is submitting one copy and one electronic copy of the above referenced report on behalf of the Town of Yadldnville, NC. If you have any questions or need additional information, please do not hesitate to contact Perry Williams at (336) 679-8732 or Alex Fox at (336) 703-8681. Sincerely, Derrick Shivar Environmental Compliance Manager Enclosures cc: Perry Williams — Town of Yadldnville Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF YADKINVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0001800 2019 ANNUAL REPORT Residuals Land Application Program 1. Certification Form and Annual ®perations Summary 2. Annual Residual Sampling Summary Forms, Residuals Analyses, & SAR Calculation Pages 3. Annual Land Application Field Summary Forms &Metal Field Loading Summary Forms 4. TCLP Analyses 5. Pathogen ReductionNectorRttraction Reduction 6. Soil pH &Lime Application Records 7. Soil Analyses ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00001800 County Yadkin Year 2019 Facility Name (as shown on permit) Town of Yadkinville WWTP & WTP NPDES No. NC0020338, NCO079260 Land Application Operator Svnagro Phone# (336) 9984150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip PartA, and PartB and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A —Residuals Application Summary: Total number of application fields in the permit: 19 Total number of fields utilized for land application during the year: 5 Total amount of dry tons applied during the year for all application sites: 67.13 Total number of acres utilized for land application during the year: 44.1 Part B —Annual Compliance Statement: Facility was compliant during calendar year 2019 with all conditions of the land application permit (including but not limited to items 143 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C —Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 7 - Perry Williams, Director of Public Works Permittee Name and Title (type or print) SiOaature of Pe Ott I Date SignatureofPreparer* Date Signatu o andAppli Date (if different from Permittee) (if different from 7ermittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) i YADKINVILLE, NC WWTP LIQUID DRY METRIC MONTH/YEAR AMOUNT UNIT DRY TONS UNIT TONS June 2019 3101000,00 G 22,76 D 20465 November 2019 4277800400 G 31,42 D 28049 YEARLY TOTAL 7377800400 G 54.18 D 49,14 YADKINVILLE, NC WTP LIQUID DRY METRIC MONTHNEAR AMOUNT UNIT DRY TONS UNIT TONS May 2019 751600M G 5.30 D 4.80 June 2019 591500,00 G 4417 D 178 November 2019 49,700.00 G 3648 D 3.16 Y EARL Y I O I AL 184, 800.00 G 12.95v i i .74 1 /30/2020 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: 1NQ0001800 Facility Name: YADKINVILLE, NC NPDES# : NCO020338 or WQ# (residual only) WWTP Name: YADKINVILLE WWTP Residuals Analysis Data Product Type LIQ Date Sampled (grab) or 02/27/19 Date Composited Percent Solids 1. 76 PARAMETERS (mg/kg dry weight) Arsenic <5 Cadmium <1 Mercury 0.513 Chromium 58 . 4 Copper 964 Lead 28.5 Molybdenum 5. 74 Nickel 5509 Selenium <5 Zinc 2320 Total Phosphorus 25200 TKN 72800 Ammonia -Nitrogen 17200 Nitrate and Nitrite <4 . 82 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supE�rvision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated fihe information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." X (SIGNATU OF PREPARER) DENR FORM RSSF (5/2003) Prini:ed: Wednesday - FebruaN 5, 2020 at 12:45:22 for: 2056 01 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Report Please note that your permit may contain additional parameters to be analyzed than those required to be summerized on this form Permit Number Facility Name NPDES# or WQ# (residual only) WWTP Name Residual Analysis Data Product Type Date Sampled Date Composited Percent Soilds WQ0001800 YADKINVILLE, NC NC0020338 YADKINVILLE WWTP LIQ 02/27/19 PARAMETERS (mg/kg dry weight)' Aluminium 31400 Calcium 15100 Magnesium 3140 pH 7.50 Potasium 2810 Sodium 2850 PAN 25285 SAR 0.7291 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in aca�rdiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware thiat there are significant penalties for subrrAting false information, including the possibility of fines and imprisonment for knowing violations." (SIGNATURE PREPARER) n NR -Data Not Reported or Data Not Required Report Run Date:- 2/5/2020 3:42:27 PM i Waypoint. ANALYTICAL 3/7/2019 Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 19-060-0216 Project Description: Yadkinville WV TP 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 0 Fax 804-271-6446 www.waypointanalytical.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 3/1/2019 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 (CFR 136 Method Update Rule May 2012) and NELAC winless otheRvise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Pauric McGroary Agronomist Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014 Florida E871087 North Carolina 257 South Carolina 93007 Page 1 of 6 "0 • j ' � l � Report Number: Client Project Description: Lab No Client Sample ID 19-060-0216 Yadkinville WW7'P 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypo i nta n a l yti ca I. co m Matrix Date Collected Date Received Method 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/Ol/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10;00 03/01/2019 65085 Yadkinville WWTP Solids 02/27/2019 10:00 03/01/2019 WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354 Lab ID SM-4500-NH3C WTN 9045D WTN 4500NO3F-2011 WTN 6010D WTN SW-7471B WTN SM-4500-NH3C-TKN WTN SM-2540G WTN Page 2 of 6 Reps.. Number: 19-060-0216 Account Number: 46507 Send To: Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville , NC 27028 Wa of ntr�, Yp ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Niain 804-743-9401 °Fax 804-271-6446 www.waypointanalytical.com ProJecfi :Yadkinville WWTP REPORT OFANALYSAS Date Sampled: 2/27/2019 10:00:00 Lab Number : 65085 Date Received: 03/01/2019 00:00 Sample Id :Yadkinville WWTP Date Reported: 03/07/2019 Total Solids * Moisture * Total Kjeldahl Nitrogen Phosphorus Potassium Sulfur Calcium Magnesium Sodium Iron Aluminum Manganese Copper Zinc Ammonia Nitrogen Organic N Nitrate+Nitrite-N 17600 72800 25200 2810 10000 15100 3140 2850 22900 31400 3430 964 f►.[cyzi] 17200 55600 <4.82 100.0 100.0 250 50.0 50.0 50.0 250 50.0 250 50.0 50.0 5.00 2.50 12.5 100 CJ R CLP BKN BKN BKN BKN BKN BKN BKN KKM KKM BKN BKN ZBD 03/06/2019 15:50 03/06/2019 15:50 03/06/2019 14:00 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/07/2019 00:25 03/04/2019 15:15 03/04/2019 15:15 03/06/2019 12:45 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B - Analyte detected in blank H -Beyond Holding Time Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to fhe work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. SM-2540G S M-2540 G SM-4500-NH3C-TKN 6010D 6010D 6010D 6010D 6010D 6010D 6010D 6010D 6010D 6010D 6010D SM-4500-NH3C CALCULATION 4500NO3F-2011 Pauric McGroary Agronomist Paae 3 c�F 6 Red., _Number: 19-060-0216 Account Number: 46507 ANALYTICAL Send To: Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville , NC 27028 7621 Whitepine Road, Richmond, vA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypointanalytical.com Project :Yadkinville WWTP REPORT OFANALYS/S Date Sampled: 2/27/2019 10:00:00 Lab Number : 65085 Date Received: 03/01/2019 00:00 Sample Id :Yadkinville WWTP Date Reported: 03/07/2019 Cadmium Chromium Nickel Lead Arsenic Mercury Selenium pH Molybdenum Comments: <1.00 1.00 BKN 03/07/2019 00:25 58.4 2.50 BKN 03/07/2019 00:25 55.9 2.50 BKN 03/07/2019 00:25 28.5 3.00 BKN 03/07/2019 00:25 <5.00 5.00 BKN 03/07/2019 00:25 0.513 0.0153 TJS 03/06/201914:32 <5.00 5.00 BKN 03/07/2019 00:25 7.5 JSL 03/07/201910:50 5.74 2.50 BKN 03/07/2019 00:25 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B - Analyte detected in blank H -Beyond Holding Time Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made to fhe work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. 6010D 6010D 6010D 9045D 6010D Pauric McGroary Agronomist �xo - �- � , \�_ �_ 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9403 °Fax 804-271-6446 www.waypointanalytical.com Cooler Receipt Form Customer Number: 46507 Customer Name: Synagro Central LLC/ Yadkinville Report Number: 19-060-0216 Shipping Method Fed Ex 0 US Postal � Lab � Other UPS 0 Client � Courier Thermometer ID: Shipping container/cooler uncompromised? Yes 0 No Number of coolers received 1 Custody seals intact on shipping container/cooler? � Yes 0 No Not Required Custody seals intact on sample bottles? � Yes 0 No Not Required Chain of Custody (COC) present? Yes � No COC agrees with sample label(s)? Yes � No COC properly completed Yes 0 No Samples in proper containers? Yes � No Sample containers intact? ®Yes � No Sufficient sample volume for indicated test(s)? ®Yes � No All samples received within holding time? ®Yes 0 No Cooler temperature in compliance? ®Yes � No Cooler/Samples arrived at the laboratory on ice. ®Yes � No Samples were considered acceptable as cooling process had begun. Water -Sample containers properly preserved � Yes � No N/A Water -VOA vials free of headspace � Yes � No N/A Trip Blanks received with VOAs � Yes � No N/A Soil VOA method 5035 —compliance criteria met 0 Yes � No N/A � High concentration container (48 hr) � Low concentration Encore samplers (48 hr) High concentration pre -weighed (methanol -14 d) � Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? � Yes No Comments: Signature: Brandi Watson Date &Time 03/01/2019 14:25:00 Page 5 of 6 Iv rn 0 M SAMPLING LOG # A P �L 76� Ric 111111111I11111111111111111111111111111111111111111111ll11111103 06 RECORD Il.�l�a5� 2196 GusTOM>=R: ��YB����� ° eoti �7 Svnaciro Central LLCI Yadkmville 14:24:32 FL YadkinvilleVWVTP PROJECT MANAGER: sampling procedures ....,,mot on of these samples. SAMPLE I.I. L®CATI®N T'IPP.E CONTAINERS Relinquished by Sampler: Date Time Relinquished by: I . a e Time 1 i� �I Relinquished by: Time Recieved by: rtecleved by: aH1VIYLlIIiCa LATE TIME z/Z� ICl�ct, du,. METIi®CI PRESER`JED j REMARKS: METI-lOL3 SKIPPED Cad(zy— SPECIAL INSTRUCTIONS: For. (STATE)monitoring purposes. PO#: SAMPLE ANALYSIS REQUEST 1'C' SLR SL2 NH4�N N�73 N Organic Cd Cr Ni Pb As gig S® N CaCo3 Volatile P equly. Solids Mo Cl NO2-N eOW SLR; Total Solids (Moisture), Total Kjeldahl Nitrogen, Phosphorus, and Potassium SL2: Basic Test SLi plus Sulfur, GalciumI Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc • •� • 1'`� eLIQUID Na mg/I = (Na mg/kg x %Solids) = 100 = (2850 x 1.7600) _ 100 = 50.16 Ca mg/I = (Ca mglkg x %Solids) _ 100 = (15100 x 1.7600) + 100 = 265.76 Mg mg/I = (mg mg/kg x %Solids) + 100 = (3140 x 1.7600) _ 100 = 55.264 Na meq = Na mgll = Molec.Wgt.Na = 50.16 = 23 = 2.18087 Ca meq = Ca mgll + Molec.Wgf.Ca = 265.76 _ 20 = 13.288 Mg meq = Mg mg/I = Molec.Wgt.Mg = 55.264 = 12 = 4.60533 SAR = Na meq = SgrRoot[0.5 x (Ca meq + Mg meq)] = 2.18087 + SgrRoot[0.5(13.288+4.60533)] = 0.72912 Printed: 2/5/2020 Page 1 10:38 ANNUAL RESIDUALS SAMPLING SIJMMARY FORM Attach this form to the corresponding Annual Report. Please note that your permit may contain additional parameters to be analyzed than those required to be summarized on this form. Permit Number: Facility Name: YADKINVILLE, NC NPDES# : WQ0001800 or WQ# (residual only) WWTP Name: YADKINVILLE WTP Residuals Analysis Data Product Type WPL Date Sampled (grab) or 02/27/19 Date Composited Percent Solids 1. 68 PARAMETERS (mg/kg dry weight) Arsenic 8 . 7 2 Cadmium <1 Mercury 0. 0476 Chromium 32. 8 Copper 73.3 Lead 16.9 Molybdenum <2.5 Nickel 12.3 Selenium <5 Zinc 213 Total Phosphorus 2210 TKN 26500 Ammonia -Nitrogen 6470 Nitrate and Nitrite <4 a 89 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance wifih a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 11 (SIGNATJOfj�E OF PREPARER) Date d/lU DENR FORM RSSF (5/2003) Printed: Wednesday -February 5 2020 at 12:45:28 for: 2056 02 ANNUAL RESIDUALS SAMPLING SUMMARY FORM Attach this form to the corresponding Report Please note that your permit may contain additional parameters to be analyzed than those required to be summerized on this form Permit Number Facility Name NPDES# or WQ# (residual only) WWTP Name Residual Analysis Data Product Type Date Sampled Date Composited Percent Soilds YADKINVILLE, NC WQ0001800 YADKINVILLE WTP WPL 02/27/19 PARAMETERS (mg/kg dry weight)' Aluminium 182000 Calcium 1720 Magnesium 822 pH 6.80 Potasium 769 Sodium 607 PAN 11252 SAR 0.3892 Laboratory Waypoint Analytical Virginia Inc. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accardiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for subm{ I g false information, including the possibility of fines and imprisonment for knowing violations." / X � Date 02 �� oZ� (SIGNATURE PREPARER) NR -Data Not Reported or Data Not Required Report Run Date:- 2/5/2020 3:45:16 PM • Waypoint; ANALYTICAL 3/8/2019 Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville, NC, 27028 Ref: Analytical Testing Report Number: 19-060-0215 Project Description: Yadkinville WTP 762I Whitepine Road, Richmond, CIA 23237 Main 804-743-9401 0 Fax 804-271-6446 www,waypointanalocal.com Dear Mary Brewer: Waypoint Analytical Virginia, Inc. received sample(s) on 3/1/2019 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table if applicable. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CrR 136 Method Update Rule iviay 2012) and ivELAC unless otherwise indicated. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Pauric McGroary Agronomist Laboratory's Liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Arizona AZ0629 New Jersey VA011 Pennsylvania 68-03109 Virginia 460014 Florida E871087 North Carolina 257 South Carolina 93007 uC- k Page 1 of 6 �� y •�: i � � 7621 Whitepine Road, Richmond, VA 23237 Main 504-743-9401 ° Fax �04-271-6446 www.waypointanalytical.com Sample Summary Table Report Number: 19-060-0215 Client Project Description: Yadkinville WTP Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 SM-4500-NH3C WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 9045D WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 4500NO3F-2011 WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 6010D WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 SW-7471B WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 SM-4500-NH3C-TKN WTN 65084 Yadkinville WTP Solids 02/27/2019 09:00 03/01/2019 SM-2540G WTN WTN: Waypoint Analytical - TN, Memphis, TN, Certification: #1354 Page 2 of 6 Rep. _Number: 19-060-0215 Account Number: 46507 Send To: Synagro Central LLC/Yadkinville Mary Brewer 284 Boger Road Mocksville , NC 27028 Wa oini�.,� �p ANALYTICAIL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypointanalytical.com Project :Yadkinville WTP REPORT OFANALYS/S Date sampled: 2/27/2019 09:00:00 Lab Number : 65084 Date Received: 03/01/2019 00:00 Sample Id :Yadkinville WTP Date Reported: 03/08/2019 Total Solids * 1.68 16800 100.0 CJR 03/06/2019 15:50 SM-2540G Moisture * 98.30 100.0 CJR 03/06/2019 15:50 SM-2540G Total Kjeldahl Nitrogen 2.65 26500 250 CLP 03/06/2019 14:00 SM-4500-NH3C-TKN Phosphorus 0.22 2210 50.0 BKN 03/07/2019 00:20 6010D Potassium 0.08 769 50.0 BKN 03/07/2019 00:20 6010D Sulfur 0.64 6440 50.0 BKN 03/07/2019 00:20 6010D Calcium 0.17 1720 250 BKN 03/07/2019 00:20 6010D Magnesium 0.08 822 50.0 BKN 03/07/2019 00:20 6010D Sodium 0.06 607 250 BKN 03/07/2019 00:20 6010D Iron 24300 50.0 BKN 03/07/2019 00:20 6010D Aluminum 182000 250 BKN 03/08/201913:08 6010D Manganese 7850 25.0 BKN 03/08/201913:08 6010D Copper 73.3 2.50 BKN 03/07/2019 00:20 6010D Zinc 213 12.5 BKN 03/07/2019 00:20 6010D Ammonia Nitrogen 0.65 6470 100 ZBD 03/04/2019 15:15 SM-4500-NH3C Organic N 2.00 20030 250 03/04/2019 15:15 CALCULATION Nitrate+Nitrite-N <4.89 4.89 ZBD 03/06/201912:44 4500NO3F-2011 All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B - Analyte detected in blank H -Beyond Holding Time �G��6 �� V��� Our reports and letters are for the exclusive and confidential use of ourclients, and may not be reproduced in whole or part, normayany reference be made Pauric McGroary to the work, the results, or the company in any advertising, news re/ease, or other public announcements without obtaining our prior written authorization. AgrorlomlSt Paae 3 of 6 Ret. .Number: 19-060-0215 Account Number: 46507 Send To: Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville , NC 27028 �O1 Val ANALYTICAL 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Project :Yadkinville WTP REPORT OFANALYS/S Date Sampled: 2/27/2019 09:00:00 Lab Number : 65084 Date Received: 03/01/2019 00:00 Sample Id :Yadkinville WTP Date Reported: 03/08/2019 Cadmium <1.00 1.00 BKN 03/07/2019 00:20 6010D Chromium 32.8 2.50 BKN 03/07/2019 00:20 6010D Nickel 12.3 2.50 BKN 03/07/2019 00:20 6010D Lead 16.9 3.00 BKN 03/07/2019 00:20 6010D Arsenic 8.72 5.00 BKN 03/07/2019 00:20 6010D Mercury 0.0476 0.0145 TJS 03/06/2019 14:31 SW-7471 B Selenium <5.00 5.00 BKN 03/07/2019 00:20 6010D pH * 6.8 JSL 03/07/2019 10:50 9045D Molybdenum <2.50 2.50 BKN 03/07/2019 00:20 6010D Comments: All values are on a dry weight basis except as noted by asterisk. Detection limit on all N series is on a wet basis. B - Analyte detected in blank Fi -Beyond Holding Time ��LL �� ���� Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or part, nor may any reference be made Pauric MCGCOary to the work, the results, or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. AgronOmlSt O '`� �= � � � 762! Whitepine Road, Richmond, VA 23237 Main 804-743-9401 °Fax 804-271-6446 www.waypointanalytica l.com Cooler Receipt Form Customer Number: 46507 Customer Name: Synagro Central LLC/ Yadkinville Report Number: 19-060-0215 Shipping Method 0 Fed Ex � US Postal � Lab � Other : �� UPS � Client 0 Courier Thermometer ID: Shipping container/cooler uncompromised? Yes � No Number of coolers received 1 Custody seals intact on shipping container/cooler? � Yes 0 No Not Required Custody seals intact on sample bottles? � Yes 0 No Not Required Chain of Custody (COC) present? Yes � No COC agrees with sample label(s)? Yes 0 No COC properly completed ®Yes � No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? ®Yes � No All samples received within holding time? ®Yes � No Cooler temperature in compliance? Yes � No Cooler/Samples arrived at the laboratory on ice. � Yes � No Samples were considered acceptable as cooling process had begun. Water -Sample containers properly preserved � Yes � No N/A Water -VOA vials free of headspace � Yes � No N/A Trip Blanks received with VOAs � Yes 0 No N/A Soil VOA method 5035 —compliance criteria met � Yes 0 No N/A High concentration container (48 hr) (� Low concentration Encore samplers (48 hr) High concentration pre -weighed (methanol -14 d) (— Low cone pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? � Yes No Comments: Signature: Brandi Watson Date &Time Page 5 of 6 03/01 /2019 14:23:51 SAMPLING LOG # PROJECT MANAGER: �. r33L -� Y.ar IL V� Relinquished by Sampler: Relinquished by: Relinquished by: SPECIAL INSTRUCTIONS: ffiFor. iiiiiiiiiii LOCATE®N A �C �. EAa! II�II'III�IIIIIIIIIIII IIIII�IIII IIIIIIIIII�IIIIIIIIIIIIIIIIII IIII 0 01 20195 p p � L 7621 WhltE Yadkinville WTP 14;22:Y1 F i{�itUSToov Richmond, & ANAILYS a m 804/74344U1 rHn, ciu,/cr I attest that the proper field sampling procedures were used during the collection of these samples. Tav%W Date Date � e Date monitoring purposes. T°IP.E Time 2 3a Time Time CCNTAINEFIS Recleved by: by; py: a7HtY1 f"LIl\11JI ®ATE TIME SlL�: Total Solids (Moisture), Total Kjeldalll Nitrogen, Phosphorus, and Potassium SL2: Basic Test SL1 plus Sulfur, CaleiumI Magnesium, Sodium, Iron, Aluminum, Manganese, Copper and Zinc MET7.1 � C2 I�RESERVED REMARKS: METl�4® Si IIPPELD �C_ C) LIQUID Na mg/I = (Na mg/kg x %Solids) _ 100 = (607 x 1.6800) + 100 = 10.1976 Ca mg/I = (Ca mg/kg x %Solids) = 100 = (1720 x 1.6800) + 100 = 28.896 Mg mg/I = (mg mg/kg x %Solids) _ 100 = (822 x 1.6800) _ 100 = 13.8096 Na meq = Na mg/I _ Molec.Wgt.Na = 10.1976 _ 23 = 0.443374 Ca meq = Ca mg/I = Molec.Wgt.Ca = 28.896 _ 20 = 1.4448 Mg meq = Mg mg/I _ Molec.Wgt.Mg = 13.8096 = 12 = 1.1508 SAR = Na meq + SgrRoot[0.5 x (Ca meq + Mg meq)] = 0.443374 _ SgrRoot[0.5(1.4448+1.1508)] = 0.389194 Printed: 2/5/2020 Page 1 10:38 FACILITY NAME: YADKINVILLE,NC OWNER: TOWN OF YADKINVILLE SITE #: NC YK 00029 FIELD# : YK 00029 0001 RESIDUAL SOURCE(S): See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES : CLIFFORD PERMIT #: W00001800 OPERATOR: TOWN OF YADKINVILLE ANNUAL DRY TONS APPLIED : 12.95 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 11.50 ACRES PERMITTED: 11.50 rage: 1 Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN Total DATE or Solids Per Residual Dry, Wet, Past 24 Method zation zation TK1V Nitrogen and m (pp ) crop p MONTH Per Acre Acre Source Moist Hours * Rate** Rate Nitrite 5/8/19 142400,00 (G) 1252,174 F1.68 0.088 YWPL DRY 0-<1/2" SUR 0.5 0.40 265500. p 6,470.00 p 4.89 p 11252 FESCUE HAY 5/9/19 32,400.00 (G) 2817,391 11.68 0.197 YWPL DRY 0-<1/2" SUR 0.5 0.40 26,500. p 6,470.00 p 4.89 p 11252 I FESCUE HAY 5/10/19 282800,00 (G) 2504,3481 1.68 0.175 YWPL DRY 0-<1/2" SUR 0.5 0.40 26,500. p 6,470.00 p 4.89 p 1.1252 FESCUE HAY May-19 75,600*00 (G) 69571913 6/27/19 10,500.00 (G) 913,043 1.68 0.064 yWPL DRY 0-<1/2" SUR 0.5 0.40 26,500. p 6,470.00 p 4.89 p 11252 I FESCUE HAY 6/28/19 492000,00 (G) 4260,8701 1.68 0.299 YWPL DRY 0-<1/2" SUR 0.5 0.40 26,500. p 6,470.00 p 4.89 p 11252 FESCUE HAY Jun49 59,500.00 (G) 5,173.913 11/6/19 49,700.00 (G) 4321.7391 1.68 0.303 YWPL DRY 1 0-<1/2" SUR 0.5 0.40 26,500. p 6,470.00 p 4.89 p 11212 FESCUE HAY Nov49 491700.00 (G) 4,321.739 I 1 I ( FACILITY NAME: YADKINViLLE,NC OWNER: TOWN OF YADKINVILLE SITE #: NC YK 00029 FIELD# : YK 00029 0001 RESIDUAL SOURCE(S): See list at bottom of report OTNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES : CLIFFORD PERMIT #: WQ0001800 OPERATOR: TOWN OF YADISINMLE ANNUAL DRY TONS APPLIED : 12.95 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 11.50 ACRES PERMITTED: 11.50 Page: 2 Lime Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner - or Wet Tons (WT) (specify) Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN DATE or Per Residual Dry, Wet, Past24 Method zation zation TEN Nitrogen and (ppm) Crop MONTH Total per Acre Solids Acre Source Moist Hours * Rate** Rate Nitrite Total Gallons/Ac: Total Wet Tons/Ac: Total Cubic Yds/Ac: TOTALS: 16,069.57 GI�IO As � Cd I Cr I Cu I Pb Hg I Mo I Ni I Se I Zn I P I PAN Annual lbs/acre 0.020 0.002 0.074 0.165 0.038 <.001 0.006 0.028 0.011 0.480 4.98 25 Cumulative lbs/acre 0.026 0.022 0.167 0.446 0.201 <.001 0.017 0.083 0.016 1.302 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 1 375.0 89.0 2500.0 YWPL = YADKINVILLE, NC WTP LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered azid evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for 1mowing violations." N/A =Not Applicable NR =Not Reported or Not Required % =percent p =ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 Application Method: SUR -Surface, IN7 -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: aerator: Acres Used: Yadkinville, NC WQ0001800 Town of Yadkinville Total Dry Tons Applied (Annual): 12.95 Cation Exchange Capacity (non 503 only): Owner: Town of Yadkinville Predominant Soil Series: Clifford 11.5 Acres Permitted: 11.5 Site #: NC YK 00029 Field #: YK 00029 0001 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 2/27/19 2 3 4 5 6 7 8 9 10 11 12 Solids 1.68 Arsenic 8.72 Cadmium 1 Copper 73.3 Chromi 32.8 Lead 16.9 Mercury 0.0476 Molyb- denum 2.5 Nickel 12.3 Selenium 5 Zmc 2i3 Total Phos- nhorus 2210 inual Heaw Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ � APP• Event 1.13 Arsenic 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.165 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.165 Chromi 0.074 0.000 0.000 0.000 0.000 0.000 0.000' 0.000 0.000 0.000 0.000 0.000 0.074 Lead 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 demon Nickel 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Selenium 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Zinc 0.480 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.480 Total Phos- 4.977 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.977 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and �prisonme�it�for knowing violations". Signature of Land Applier � � �� Date DENR FORM MFLSF (12/2006) FACII.,ITYNAME: YADKINVILLE, NC OWNER: KENNETH GRAY HOBSON SITE #: NC YK 00033 FIELD# : YK 00033 0001 RESIDUAL SOURCE(S): See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SO]L SERIES: CLIFFORD PERMIT #: W00001800 OPERATOR: JAMES HOBSON ANNUAL DRY TONS APPLIED : 15.47 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 7.60 ACRES PERMITTED: 7.60 Page : 1 Lime Applied *** Date Lbs/Ac DATE or MONTH allons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli. cation Method Vola- tili- zation Miner - ali- zation TI<N Ammonia Nitrogen Nitrate and PAN (ppm) Crop Total I Per Acre Acre Source Moist Hours * Rate** Rate Nitrite 615119 6,200.00 (G) 8150789 1.76 0.060 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY 6/26/19 1052400,00 (0) 138684421 136 1.018 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY 6/27/19 12,400.00 (G) 1631,579 L76 0.120 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY Jun-19 1241000.00 (G) 16,31&789 11/10/19 24,800.00 (G) 3263,158 1.76 0.239 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 I FESCUE HAY 11/11/19 372200.00 (G) 4894,737 136 0.359 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY 11/15/19 24,800.00 (G) 3263,158 1.76 0.239 YL MOIST 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY Nov-19 869800.00 (G) 11,421.053 1 nral liauons /Ac: 27,736.84 Total Wet Tons/Au: Total Cubic Yds/Ac: 0.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annual Ibs/acre 0.020 0.004 0.238 1925 0.116 0.002 0.023 0.228 0.020 9.445 102.60 103 Cumulative lbs/acre 0.020 0.004 0.238 1925 0.116 0.002 0.023 0.228 0.020 9.445 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crap 216 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 734,8 7 1339.0 267.9 15.0 375.0 89.0 2500.0 i YL = YADKINVILLE, NC WWTP LIQUID X (SIGNATURE OF LAND APPLIER) DATE "I certify under penalty of law,. that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *** See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 ANN-UAL METALS FIELD LOADING SiIMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: aerator: Acres Used: Yadkinville, NC WQ0001800 3ames Hobson 7.6 Total Dry Tons Applied (Annual): 15.47 Cation Exchange Capacity (non 503 only): Owner: Kenneth Gray Hobson Predoiriinant Soil Series: Clifford Acres Permitted: 7.6 Site #: NC YK 00033 Field #: YK 00033 0001 Residual Analysis Data (Heald Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 2/27/19 2 3 4 5 6 7 8 9 10 11 12 %Solids 1.76 Arsenic 5 Cadmium 1 Copper 964 Chromi 5 8.4 Lead 28.5 Mercury 0.513 Molyb- denum 5.74 Nickel 55.9 Selenium 5 Znlc 2320 Total Phos- nhorus 25200 nnual Heaw Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 H DT/Ac./ � � °� APP• Event 2.04 Arsenic 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 3.923 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.923 Chromi 0.238 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.238 Lead 0.116 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.116 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 denum Nickel 0.228 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.228 Selenimn 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Zinc 9.442 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 9.442 Total Phos- 102.564 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 102.564 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and �prisonlnent for knowing violations". Signature of Land Applier 7/ /J� Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE,NC OWNER: KENNETH GRAY HOBSON SITE #: NC YK 00033 FIELD# : YK 00033 0002 RESIDUAL SOURCE(S): See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES : CLIFFORD PERMIT #: W00001800 OPERATOR: KENNETH GRAY HOBSON ANNUAL DRY TONS APPLIED : 21.39 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 6.40 ACRES PERMITTED: 6.40 rage: 1 Lune Applied *** Date Lbs/Ac allons (G) or Cubic Yards (CY) Dry Site Inches Appli- vola- Miner - or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN Total I Per Acre DATE or MONTH Solids Per Residual Dry, Wet, Past 24 Method zation zation TKN Nitrogen and (ppm) Crop Acre Source Moist Hours * Rate" Rate Nitrite 6/3/19 62,000.00 (G) 9687,500 1.76 0.711 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY 6/4/19 862800.00 (G) 13562,500 1.76 0.995 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 I FESCUE HAY 615119 37,200.00 (G) 5812,500 1.76 0.427 YL DRY 0-<1/2" SUR 0.5 0.30 7:2,800. p 17,200.00 p 4.82 p 25285 FESCUE HAY Jun49 186,000.00 (G) 299062.500 11/7/19 437400,00 (G) 6781,250 1.76 0.498 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 I FESCUE HAY 11/10/19 182600,00 (G) 2906,250 1.76 0.213 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 I FESCUE HAY 11/11/19 18,600.00 (G) 2906.250 1.76 0.213 YL DRY 0-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 I FESCUE HAY 11/15/19 242800,00 (G) 3875,000 1.76 0.284 yL MOIST 0-<1/2" SUR 0.5 0.30 725800, p 17,200.00 p 4.82 p 25285 FESCUE HAY Nov-19 1051400.00 (G) 169468.750 FACILITY NAME: YADKINVILLE, NC OWNER: KENNETH GRAY HOBSON SITE #: NC YK 00033 FIELD# : YK 00033 0002 RESIDUAL SOURCE(S): See list at bottom of report ViNUAL LAND APPLICATION FIEELD SUMMARY FORM PREDOMINANT SOIL SERIES: CLIFFORD PERMIT #: WQ0001800 OPERATOR: JAMES HOBSON ANNUAL DRY TONS APPLIED : 21.39 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 6.40 ACRES PERMITTED: 6.40 1-age: 2 Lime Applied *** Date Lbs/Ac T Gallons (G) or Cubic Yards (CY) Dry Site Inches Appli- Vola- Miner" or Wet Tons (WT) (specify) % Tons Cond. Precip. cation tili- ali- Ammonia Nitrate PAN Total Per Acre DATE or Solids Per Residual Dry, Wet, Past24 Method zation zation TKN Nitrogen and (pp m ) Crop p MONTH Acre Source Moist Hours * Rate** Rate Nitrite otal Gallons/Ac: 451531 a25 Total Wet Tons/Ac: Total Cubic Yds/Ac: 0.00 TOTALS: As Cd Cr Cu Pb Hg Mo Ni Se Zn P PAN Annuallbs/acre 0.033 0.007 0.390 6.443 0.190 0.003 0.038 0.374 0.033 15.505 168.42 169 Cumulative lbs/acre 0.033 0.007 0.390 6.443 0.190 0.003 0.038 0.374 0.033 15.505 Pernut PAN Limit (lbs/acre) 1st Crop/2nd Crop 202 FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 f 1339.0 267.9 15.0 375.0 89.0 2500.0 YL = YADKINVILLE, NC WWTP LIQUID (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that quaed personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A =Not Applicable NR =Not Reported or Not Required % =percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/incorporation 1.0 * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 ANNUAL METALS FIELD LOADING SiJMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Yadkinville, NC Total Dry Tons Applied (Annual): 21.39 Permit #: WQ0001800 Aerator: Kenneth Gray Hobson Owner: Acres Used: 6.4 Acres Permitted: Cation Exchange Capacity (non 503 only): Kenneth Gray Hobson. Predominant Soil Series: 6.4 Site #: NC YK 00033 Clifford Field #: YK 00033 0002 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 2/27/19 2 3 4 5 6 7 8 9 10 11 12 Solids 1.76 Arsenic 5 Cadmium 1 Copper 964 Chromi 5 8.4 Lead 28.5 Mercury 0.513 Molyb- denum 5.74 Nickel 55.9 Selenium 5 Z1nC 23211 Total Phos- chorus 25200 anual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ °may. App Event 3.34 Arsenic 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Cadmium 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 6.441 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.441 Chromiui 0.390 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.390 Lead 0.190 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.190 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 denum Nickel 0.374 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.374 Selenium 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Zinc 15.502 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 15.502 Total Phos- 168.386 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 168.386 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and prisonmen�fo� knowingons". Signature of Land Applier ����/z� Date DENR FORM MFLSF (12/2006) FACILITY NAVE: YADKINVILLE , NC OWNER: JAMESKHOBSON SITE #: NC YK 00033 FIELD# : YK 00033 0003 RESIDUAL SOURCE(S): See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES: CLIFFORD PERMIT #: WQ0001800 OPERATOR: JAMES K HOBSON ANNUAL DRY TONS APPLIED : 5.46 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 8.50 ACRES PERMITTED: 8.50 rage: 1 Lune Applied *** Date Lbs/Ac DATE or MONTH Gallons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet, Inches Precip. Past 24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (pp )m Crop p Total Per Acre Acre Source Moist Hours * Rate** Rate Nitrite 11/7/19 12,400.00 (G) 1458,824 1.76 0.107 YL DRY 0-<1/2" SUR 0.5 0.30 721800.p 17,200.00 p 4.82 p 25285 WHEAT 11/8/19 62,000.00 (G) 7294,118 1.76 0.535 YL MOIST 0-<1/2" SUR 0.5 0.30 720800.p 17,200.00 p 4.82 p 25285 WHEAT Nov-19 74,400.00 (G) 8,752.942 Total Gallons/Ac: Total Wet Tons/Ac: Total Cubic Yds/Ac: TOTALS 8,752.94 Annuallbs/aore 0.006 0.001 0.075 1.239 0.037 <.001 0.007 0.072 0.006 2.981 32.38 32 Cumulative lbs/acre 0.006 0.001 0.075 1.239 0.037 <.001 0.007 0.072 0.006 2.981 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 50 �i FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 i YL = YADKINVILLE, NC WWTP LIQUID x (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A =Not Applicable NR =Not Reported or Not Required % =percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 Permit PAN Limit (lbs/acre) 1st Crop/2nd Crop 50 �i FD Cumulative Pollutant Loading Rate Limit (lbs/acre) 36.6 34.8 1339.0 267.9 15.0 375.0 89.0 2500.0 i YL = YADKINVILLE, NC WWTP LIQUID x (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A =Not Applicable NR =Not Reported or Not Required % =percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 YL = YADKINVILLE, NC WWTP LIQUID x (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." N/A =Not Applicable NR =Not Reported or Not Required % =percent p = ppm or mg/kg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR -Surface, INJ -Injection, SURIN -Incorporation *** See Site pH &Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 ANNUAL METALS FIELD LOADING SiTMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Yadkuiville, NC Total Dry Tons Applied (Annual): 5.46 permit #: WQ0001800 Cation Exchange Capacity (non 503 only): aerator: James K Hobson Owner: James K Hobson Predominant Soil Series: Acres Used: Clifford 8.5 Acres Permitted: 8.5 Site #: NC YK 00033 Field #: YK 00033 0003 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, %Solids use Raw Percent #): Sample or Com- posite Date 1 2/27/19 2 3 4 5 6 7 8 9 10 11 12 %Solids 1.76 Arsenic 5 Cadmium 1 Copper 964 Chromi 58.4 Lead 28.5 Mercury 0.513 Molyb- denum 5.74 Nickel 55.9 Selenium 5 zlllC 232U Total Phos- chorus 25200 .�nual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 D T /Ac./ App. Event 0.64 Arsenic 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 1.238 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.238 Chromi 0.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Lead 0.037 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.037 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 denum Nickel 0.072 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.072 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 zinc 2.979 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.979 Total Phos- 32.357 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 32.357 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and �rison�►e�pt for knowing violations". Signature of Land Applier �C� �v Date DENR FORM MFLSF (12/2006) FACILITY NAME : YADKINVILLE , NC OWNER: GENEVA & ROGER DAVIS SITE #: NC YK 00035 FIELD# : YK 00035 0002 RESIDUAL SOURCE(S): See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM PREDOMINANT SOIL SERIES : CLIFFORD PERMIT #: W00001800 OPERATOR: GENEVA & ROGER DAVIS ANNUAL DRY TONS APPLIED : 11.83 CATION EXCHANGE CAPACITY (NON-503): ACRES UTILIZED: 10.10 ACRES PERMITTED: 10.10 rage: 1 Lime Applied *** Date Lbs/Ac DATE or Gallons (G) or Cubic Yards (CY) or Wet Tons (WT) (specify) % Solids Dry Tons Per Residual Site Cond. Dry, Wet Inches Precip. Past24 Appli- cation Method Vola- tili- zation Miner - ali- zation TKN Ammonia Nitrogen Nitrate and PAN (pp )m Crop p Total Per Acre MONTH Acre Source Moist Hours * Rate** Rate Nitrite 11/18/19 31,000.00 (G) 3069,307 1.76 0.225 YL MOIST 0-<1/2" SUR 0.5 0.30 72,800. p 172200,00 p 4.82 p 25285 FESCUE PASTURE 11/20/19 68,200.00 (G) 6752.475 L76 0.496 YL MOIST 110-<1/2" SUR 0.5 0.30 72,800. p 17,200.00 p 4.82 p 25285 FESCUE PASTURE 11/21/19 62,000.00 (G) 61380614 1.76 0.451 YL DRY 110=<1/2" SUR 0.5 0.30 72,800. p 172200000 p 4.82 p 25285 FESCUE PASTURE Nov49 161,200.00 (G) 15,960.396 Total Gallons/Ac: Total Wet Tons/Ac: 15,960.40 a vLcu �uviv •�u. V.VV TOTALS: As Cu Cr Cu Pb rig Mo Ni Se Zn P PAN Annuallbs/acre 0.012 0.002 0.137 2.258 0.067 0.001 0.013 0.131 0.012 5.435 59.04 59 Cumulative lbs/acre 0.012 0.002 0.137 2.258 0.067 0.001 0.013 0.131 0.012 5.435 Permit PAN Limit pbs/acre) 1st Crop/2nd Crop 151 FD Cumulative Pollutant LoadingRate Limit lbs/acre ( ) 36.6 34.8 ' 1339.0 267.9 15.0 375.0 89.0 2500.0 YL=YADKINVILLE, NC WWTP LIQUID X (SIGNATURE OF LAND APPLIER) DATE "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for Imowing violations." N/A = Not Applicable NR = Not Reported or Not Required % = percent p = ppm or mg/lcg ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **'k See Site pH & Lime Application Records Section of Report for Fields where Lime is to be applied in 2020 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Yadkinville, NC WQ0001800 Aerator: Geneva &Roger Davis Owner: Acres Used: 10.1 Acres Permitted: Total Dry Tons Applied (Annual): 11.83 Cation Exchange Capacity (non 503 only): Geneva &Roger Davis Predominant Soil Series 10.1 Clifford Site #: NC YK 00035 Field #: YK 00035 0002 Residual Analysis Data (Heavy Metals and Total Phosphorus use m�/k�, %Solids use Raw Percent #): Sample or Com- posite Date 1 2/27/19 2 3 4 5 6 7 8 9 10 11 12 %Solids 1.76 Arsenic 5 Cadmium 1 Copper 964 Chromi 5 8.4 Lead 28.5 Mercury 0.513 Molyb- denum 5.74 Nickel 55.9 Selenium 5 Zinc 2320 Total Phos- nhorus 25200 lnual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 8 9 10 11 12 DT/Ac./ o App• r+ Event 1.17 " Arsenic 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 2.260 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.260 Chromi 0.137 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.137 Lead 0.067 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.067 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 denum Nickel 0.131 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.131 Selenium 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Zinc 5.438 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.438 Total Phos- 59.069 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 59.069 hoius "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and prisonme t or knowing vio�latio�ns". ��I . Signature of Land Applies - � �J Date DENR FORM MFLSF (12/2006) 9-1summill �1GF s1 I' �7trYa:l�rlE� March 14, 2019 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Yadkinville WWTP Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http:11www.settek.com Dear Erik Bruce: Order No.: 19030127 Summit Environmental Technologies, Inc. received 1 sample(s) on 3/1/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon 0112O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466A 1-5, Utah OH009232011-1, Virginia VELAP 9456, Washington C891 Page 1 of 31 ' ' =nISZ IF=5 JN{7 �LIENT: Synagro Project: Yadkinville WWTP WorkOrder Narrative: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: hgp://www.settek.com WO 1: 19030127 Date: 3/14/2019 190301270 This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies,. Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Prep Sample Comments: 19030127-001A 434790a Prep Comments for MtlPrep_TCLP(3010A), Sample 19030127-OOlA: Sample was filtered after digestion. Original Page 2 of 31 S I U M I'T +, y lttrvtirdt_ �r�.L TEMIN'M n ,1-. , ;r C Arratyrs'c �' 1'_aborason.66t SummitEnvironmental Technologies, In 3310 Win 5 Cuyahoga Falls, Ohio 442z' TEL: (330) 253-8211 FAX: (330) 253-446 Wehsite: htW.v11Www.settekco. These commonly used Qualifiers and Acronyms may or may not be present m this report. Quaers WO 1: 19030127 Date: 3/14/2019 U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. In Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GUMS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+), QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit )CS Quality Control Sample CRQL Contract Required Quantitation Limit 31 Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reexiraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 31 Summit Environmental Technologies, Inc. 3310 Win St, Cuyahoga Falls, Ohio 44223 TEL; (330) 253-8211 FAX.• (330) 253-4489 Website: hgp://www.settek.com Warkoi deir mple Summery WO#: 19030127 14-MaY-19 CLIENT: Synagro Project: Yadkinville WWTP Lab SampleID Client Sample ID Tag No Date Collected Date Received Matrix 19030127-001 Yadkinville VJWTP 2/27/2019 3/1/2019 10:15:00 AM Sludge F• FF - Summit Environmental Technologies, Inc. 'X 3310 Win St. Cuyahoga Falls, Ohio 44223 rn ^PfJ r' i 131��Jr��� 2 TEL: (330) 253-8211 FAX(330) 2534489 Website: hgp://www.settelc.com Client: Synagro Project: Yadkinville WWTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19030127-OOlA Yadlcinville WWTP 2/27/2019 Sludge Ignitability of Solids (SW-846: 1030) 3/5/2019 12:00:00 PM pH (SW9045D) 3/5/2019 2:33:00 PM Reactive Cyanide (9014/7.3.3.2)-Solid 3/5/2019 5:16:00 PM Reactive Sulfide (9034)/7.3.4.2 3/5/2019 5:16:00 PM SVOC SW-846: 8151 HerbicidesJU3/4/2019 6:00:00 PM 3/7/2019 3:00:00 PM 3/12/2019 10:00:00 PM TCLP Mercury Analysis (SW1311/7473/4/2019 6:00:00 PM 3/6/201912:40:00 PM 3/6/2019 4:49:00 PM TCLP Metals Analysis (SW1311/6010:3/4/2019 6:00:00 PM 3/6/2019 8:10:00 AM 3/6/2019 5:41:33 PM TCLP Pesticides Analysis (SW1311/8(3/4/2019 6:00:00 PM 3/11/2019 5:20:00 PM 3/12/2019 9:45:00 PM TCLP Semi-Volatiles Analysis 3/4/2019 6:00:00 PM 3/11/2019 12:15:00 PM 3/12/2019 6:11:00 PM (SW1311/8270) TCLP Volatiles Analysis 3/5/2019 2:05:00 PM Original Paae 5 of �;1 Sununit Envirownental Technologies, Inc. sump*mk 3310 Win A E';ti�lf? �N�1�tiTp.L x _�?t�6-�i <;" - Cuyahoga Falls, Ohio 44223 - Anaty0cal TEL: (330) 253-8211 FAX: (330) 253-4489 CLIENT: Matrix: Lab ID: Project: Synagro SLUDGE 19030127-001A Yadkinville WWTP Client Sample ID Yadkinville WWTP Analytical Report (base report) WO#: 19030127 Websate: http://www.settekcona Date Reported: 3/14/2019 Tag Number: Collection Date: 2/27/2017 Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: DNS TCLP MERCURY ANALYSIS (SW131117470) TCLP Mercury ND 0.00500 mg/L 1 3/6/2019 4:49:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010D SW3010A Analyst: KMO TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND 0.500 mg/L 1 3/6/2019 5:41-133 PM TCLP Barium(Ba) ND 5.00 mg/L 1 3/6/2019 5:41:33 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 3/6/2019 5:41-133 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 3/6/2019 5:41:33 PM TCLP Lead(Pb) ND 0.500 mg/L 1 3/6/2019 5:41:33 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 3/6/2019 5:41:33 PM TCLP Silver(Ag) ND 0.500 mg/L 1 3/6/2019 5:41:33 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.0800 mg/L 2 3/12/2019 6:11:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 3/12/2019 6:11:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 3/12/2019 6:11:00 PM 2,4-Dinitrotoluene ND 0.0400 mg/L 2 3/12/2019 6:11:00 PM Cresols, Total ND 4.00 mg/L 2 3/12/2019 6:11:00 PM HexachloroA,3-butadiene ND 0.0160 mg/L 2 3/12/2019 6:11:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 3/12/2019 6:111-00 PM Hexachloroethane ND 0.0800 mg/L 2 3/12/2019 6:11:00 PM Nitrobenzene ND 0.0800 mg/L 2 3/12/2019 6:11:00 PM Pentachlorophenol ND 0.200 mg/L 2 3/12/2019 6:11:00 PM Pyridine ND 0.200 mg/L 2 3/12/2019 6:11:00 PM Surr: 2-Fluorophenol 71.5 10 - 109 %Rec 2 3/12/2019 6:11:00 PM Surr: Phenol-d6 71.7 10 - 109 %Rec 2 3/12/2019 6:11:00 PM Surr: Nitrobenzene-d5 93.7 19 - 120 %Rec 2 3/12/2019 6:11:00 PM Surr: 2,4,6-Tribromophenol 94.2 10 - 120 %Rec 2 3/12/2019 6:11:00 PM Surr: 2-Fluorobiphenyl 92.6 22 - 117 %Rec 2 3/12/2019 6:11:00 PM Surr: p-Terphenyl-d14 117 34 - 130 %Rec 2 3/12/2019 6:11:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 6 of 31 Suininit Environmental Technologies, Inc. 3310Win st. Analytical Report ' 04 Li -J L base re r �'.'li?10WK1 ,•1TAL TIEC!JfWol ; ':5, yNr' Cuyahoga Falls, Ohio 44223 report) Arr'.:T6gr'sRl' L.a'borasoin;;oll TEL (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030127 website: hgp://wwiv.settek.com Date Reported: 3/14/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 2/27/2019 Lab ID: 19030127-OOIA Project: Yadkinville WWTP Client Sample ID Yadkinville WWTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW351OC Analyst: SFG TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0,250 mg/L 10 3/12/2019 9:45:00 PM Toxaphene ND 0.500 mg/L 10 3/12/2019 9:45:00 PM Endrin ND 0,0250 mg/L 10 3/12/2019 9:45:00 PM gamma-BHC ND 0.0250 mg/L 10 3/12/2019 9:45:00 PM Heptachlor ND 0,0250 mg/L 10 3/12/2019 9:45:00 PM Heptachlor epoxide ND 0,0250 mg/L 10 3/12/2019 9:45:00 PM Methoxychlor ND 0,0250 d mg/L 10 3/12/2019 9:45:00 PM Surr: TCMX 100 10 - 119 %Rec 10 3/12/2019 9:45:00 PM Surr: DCB 106 10 - 119 %Rec 10 3/12/2019 9-145:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8151A SW8151A Analyst: SFG SVOC SW-846: 8151 HERBICIDES-TCLP 214-D ND 1,00 mg/L 1 3/12/2019 10:00:00 PM 21415-TP ND 0.500 d mg/L 1 3/12/2019 10:00-100 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: CTB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.250 mg/L 50 3/5120192:05:00 PM 1,2-Dichloroethane ND 0,250 mg/L 50 3/5/2019 2:05:00 PM MEK ND 1,25 mg/L 50 3/5/2019 2:05:00 PM Benzene ND 0,250 mg/L 50 3/5/2019 2:05:00 PM Carbon tetrachloride ND 0,250 mg/L 50 3/5/2019 2:05:00 PM Chlorobenzene ND 0,250 mg/L 50 3/5/2019 2:05-100 PM Chloroform ND 0,250 mg/L 50 3/5/2019 2-105-100 PM Tetrachloroethene ND 0.250 mg/L 50 3/5/2019 2:05:00 PM Trichloroethene ND 0,250 mg/L 50 3/5/2019 2:05:00 PM Vinyl chloride ND 0,100 mg/L 50 3/5/2019 2:05:00 PM Surr: 4-Bromofluorobenzene 92.9 70 - 130 %Rec 50 3/5/2019 2-105:00 PM Surr: Dibrom ofluorom ethane 89.7 70 - 130 %Rec 50 3/5/2019 2:05:00 PM Surr: Toluene-d8 104 70 - 130 %Rec 50 3/5/2019 2:05:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 7 of 31 LIENT: Matrix: Lab ID: Project: Ri$eiliot4rdeid"I'i'! I::rll[iti1 S 'a Synagro SLUDGE 19030127-001A Yadkinville WWTP Client Sample ID Yadkinville W WTP Su7777nit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 Analytical Report (base report) WO#: 19030127 Websate: http://www.settek.co»a Date Reported: 3/14/2019 Tag Number: Collection Date: 2/27/2019 Analyses Result RL Qual Units DF Date Analyzed RCI-SOLID-W/ IGNITABILITY1030 REACTIVE CYANIDE (9014/7112)-SOLID Cyanide, Reactive RCI-SOLID-W/ IGNITABILITY1030 IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability RCI-SOLID-W/ IGNITABILITY1030 PH (SW9045D) D H RCI-SOLID-W/ IGNITABILITY1030 REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive non-flammable 7.6 SW9014 Analyst: MS 0.485 mg/Kg 1 3/5/2019 5:16:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits SW1030 Analyst: AJT 1 3/5/2019 12:00:00 PM SW9045D Analyst: DHC s.u.n19.6C 1 3/5/2019 2:33:00 PM SW9034 Analyst: MS 25.0 mg/Kg 1 3/5/2019 5:16:00 PM E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 8of31 Summit Environmental Technologies, Inc. Accr editafion Frrogrnm w low 3310 Win St, ail►_r tdrlKt.�re.� r c:t. r Rtit -, ,:.s Cuyahoga Falls, Ohio 44223 AIr11a ytes Report t Alrnt' iVezil tabn.rato,F'tjpt TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030127 Website: http:/1www.settek.com 14-Mar49 Client: Synagro State: NC Project: Yadkinville WWTP Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 1903012MOIA Sludge Ignitability of Solids (SW-846: 1030) Ignitability A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Sludge SVOC SW-846: 8151 Herbicides-TCLP 2A5-TP A Sludge SVOC SW-846: 8151 Herbicides-TCLP 2,4-1) A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A . Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A NC_WW SCM A Accredited NC WW SCM U Unavailable Original # 1 Page 9 of 31 l 4 r. _ — �' -� Summit Environmental Technologies, Inc. Acell effitaflon Program 3310 Win St, r":I(:. h1Pe7e •li�.L FEit«:t11 i�4 3 Cuyahoga Falls, Ohio 44223 `������� ���®�� tabaraxonk TEL: (330) 253-8211 FAX: (330) 2534489 WO#: 19030127 Wehsite: hyp://www.settek.com 14-Mar49 Client: Synagro State: NC Project: Yadkinville WWTP Program Name. NC_WW SCM Sample ID Matrix Test Name Analyte Status 19030127-001A Sludge TCLP Volatiles Analysis lj1 Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tefrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Page 10 of 31 Original # 1 --- -- - -` L Summit Environmental Technologies, Inc. QC SUMMARY RE-eORT J �JY 3310 Win St. 1,++ +idf t_ d i +L 7 12 :arn; Cuyahoga Falls, Ohio 44223 WO#: 19030127 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: hge:llwww.settek.corn 14-Mar-19 Client: Synagro Project: Yadldnville WWTP BatchID0 36252 Sample ID 19030086-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 3/6/2019 RunNo: 95376 Client ID: Batch= Batch ID: 36252 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 SegNo: 1987166 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val TCLP Arsenic(As) 2.31 0.500 2.000 0 115 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2767 99A 70 130 TCLP Cadmium(Cd) 1.97 0.100 2.000 0 98.4 70 130 TCLP Chromium(Cr) 2.11 0.200 2.000 0 105 70 130 TCLP Lead(Pb) 2.06 0.500 2.000 0 103 70 130 TCLP Selenium(Se) 2.39 0.0500 2.000 0,02516 118 70 130 TCLP Silver(Ag) 2.37 0.500 2.000 0 118 70 130 Sample ID 19030086-001AMSD SampType: MSD Client ID: BatchQC Batch ID: 36252 Analyte Result TestCode: MTL-TCLP-7( Units: mglL Prep Date: 3/6/2019 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 PQL SPK value SPK Ref Val °1°REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual RunNo: 95376 SegNo: 1987167 %RPD RPDLimit 02ua1 TCLP Arsenic(As) 2.35 0.500 2.000 0 117 70 130 2.310 1.68 20 TCLP Barium(Ba) ND 5.00 2.000 0.2767 101 70 130 0 0 20 TCLP Cadmium(Cd) 1.99 0.100 2.000 0 99.7 70 130 1.967 1.30 20 TCLP Chromium(Cr) 2.15 0.200 2.000 0 107 70 130 2.109 1.77 20 TCLP Lead(Pb) 2.08 0.500 2.000 0 104 70 130 2.061 0.952 20 TCLP Selenium(Se) 2.42 0.0500 2.000 0,02516 120 70 130 2.392 1.33 20 TCLP Silver(Ag) 2040 0.500 2.000 0 120 70 130 2.368 1.48 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to detennine Original Page 11 of 3'I Summit Environmental Technologies, Inc. . L g 3310 Win St. iQC SUMMARY Rf ORT 'fir FPaIrMTAL a4tIl A0.rro,, + C 1 Cuyahoga Falls, Ohio44223 C�• _ > vrhf.i` La-barjlto to_ TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030127 Website: httl2:llwww.settelc.com 14-Mar-19 Client: Synagro Project: Yadldnville WWTP BatchIDa 36252 Sample ID MB-36252 SampType: MBLK TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 3/6/2019 RunNo: 95376 Client ID: PBS Batch ID: 36252 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 SegNo: 1998092 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-36252 SampType: LCS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 3/6/2019 RunNo: 95376 Client ID: LCSS Batch ID: 36252 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 SegNo: 1998093 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.09 0.500 2.000 0 104 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 105 80 120 TCLP Cadmiuni 1.87 0.100 2.000 0 93.6 80 120 TCLP Chromiuni 2.12 0.200 2.000 0 106 80 120 TCLP Lead(Pb) 2.15 0.500 2.000 0 108 80 120 TCLP Selenium(Se) 2.08 0.0500 2.000 0 104 80 120 TCLP Silver(Ag) 2.24 0.500 2.000 0 112 80 120 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 12 of 31 _ - - ILLJ Summit Environmental Technologies, Inc. SUMMARY T n FibJOT u I _ ^3310 Win St. QC lJ AR Y i\Ll K 11ud�!J{7_�di L 'r J'+arn��; _ Cuyahoga Falls, Ohio44223 TEL: (330) 253-8211 FAX.• (330) 2534489 WO#: 19030127 Website: httl2:llwww.settelc.com 14-Mar-19 Client: Synagro Project: Yadldnville WWTP SatchID6 36264 Sample ID MB-36264 SampType: MBLK TestCode: HG_TCLP(74 Units: PPM Prep Date: 3/6/2019 RunNo: 95406 Client ID: PBS Batch ID: 36264 TestNo: SW7470A SW7470A Analysis Date: 3/6/2019 SegNo: 1986470 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua[ TCLP Mercury ND 0.00200 Sample ID LCS-36264 SampType: LCS TestCode: HG_1CLP(74 Units. PPM Prep Date: 3/6/2019 1-1 95406 Client ID: LCSS Batch ID: 36264 TestNo: SW7470A SW7470A Analysis Date: 3/6/2019 SegNo: 1986471 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] TCLP Mercury 0.00409 0.00200 0.00400 Sample ID 19030086-001AMS SampType: MS Client ID: BatchQC Batch ID: 36264 Analyte TCLP Mercury Result 0 102 80 120 TestCode: HG_TCLP(74 Units: PPM TestNo: SW7470A SW7470A PQL SPK value SPK Ref Val 0.00445 0.00200 0.00400 Sample ID 19030086-001AMSD SampType: MSD Client ID: Batch= Batch ID: 36264 Analyte TCLP Mercury Result Prep Date: 3/6/2019 Analysis Date: 3/6/2019 %REC LowLimit HighLimit RPD Ref Val 0 111 75 125 TestCode: HG_TCLP(74 Units: PPM TestNo: SW7470A SW7470A PQL SPK value SPK Ref Val Prep Date: 3/6/2019 Analysis Date: 3/6/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95406 SegNo: 1986475 %RPD RPDLimit Qual RunNo: 95406 SegNo: 1986476 %RPD RPDLimit Qual 0.00443 0.00200 0.00400 0 111 75 125 0.00445 0.450 20 Qualifiers: * Value exceeds Maxhnum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 13 of 31 Summit Environmental Technologies, Inc. i. J J L� �f 3310 Win St. QC SUMMARY RJPORT Cuyahoga Falls, Ohio 44223 WO#: 19030127 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: hO.*11www.settek.com 14-Mar49 Client: Synagro Project: Yadldnville WWTP Sample ID 19030086-001AMSD SampType: MSD Client ID: Batch= Batch ID: 36264 Analyte Result TestCode: HG_TCLP(74 Units: PPM TestNo: SW7470A SW7470A PQL SPK value SPK Ref Val BatchID0 36264 Prep Date: 3/6/2019 RunNo: 95406 Analysis Date: 3/6/2019 SegNo: 1986476 %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank 1J Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 14 of 31 Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY Ri eORT J L_1 E�: Orl O W MENT,RL rz „ 1 U r ;; Cuyahoga Falls, Ohio 44223 +'''��=' 'vfjon: �L abara� dnol TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030127 Website: hQ:Ilwww.settek.corn 14-Mar49 Client: Synagro Project: Yadkinville WWTP BatchID0 36316 Sample ID MB-36316 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/7/2019 RunNo: 95654 Client ID: PBS Batch ID: 36316 TestNo: SW8151A SW8151A Analysis Date: 3/12/2019 SegNo: 1996428 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D ND 1.00 d 21415-TP ND 0.500 d Surr: 2,4-Dichlorophenylacetic acid 373 500.0 74.6 20 140 Sample ID LCS-36316 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/7/2019 RunNo: 95654 Client ID: LCSS Batch ID: 36316 TestNo: SW8151A SW8151A Analysis Date: 3/12/2019 SegNo: 1996429 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 274-D ND 1.00 0.500 0 73.6 43.8 130 Sample ID 19030122-001AMS SampType: MS Client ID: Batch= Batch ID: 36316 Analyte Result TestCode: TCLPSVOC- Units: mg/L TestNo: SW8151A SW8151A PQL SPK value SPK Ref Val Prep Date: 3/7/2019 Analysis Date: 3/12/2019 %REC LowLimit HighLimit RPD Ref Val m RunNo: 95654 SegNo: 1996430 %RPD RPDLimit Qual 214-D ND 1.00 0.500 0 73.7 37 105 m 27475-TP ND 0.500 0.500 0 70A 38 106 m Sum 2,4-Dichlorophenylacetic acid 713 500.0 143 20 140 Sm Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit, ND Not Detected O RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 15 of 311 -- Summit Environmental Technologies, Inc. JLi I� QC SUMMARY REPORT f m if II- L 3310 win St. �C ^a''Ililr rYdh1rdT�r.L T�4tirLR, v ,,7 Cuyahoga Falls, Ohio 44223 WO#: 19030127 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http:/hvww.settek.com 14-Mar49 Client: Synagro Project: Yadldnville WWTP Sample ID 19030122-001AMSD SampType: MSD Client ID: BatchQC Batch ID: 36316 Analyte Result BatchII)0 36316 TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/7/2019 TestNo: SW8151A SW8151A Analysis Date: 3/12/2019 PQL SPK value SPK Ref Val °i°REC LowLimit HighLimit RPD Ref Val RunNo: 95654 SegNo: 1996431 %RPD RPDLimit Qual 2,4-D ND 1.00 0.500 0 67.2 37 105 0 0 30 m 21415-TP ND 0.500 0.500 0 64.6 38 106 0 0 30 m Surr: 2,4-Dichlorophenylacetic acid 875 500.0 175 20 140 0 30 Sm Qualifiers: * Value exceeds Maximum Contaaninant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 16 of 31 ' Summit Environmental Technologies, Inc. 1 Ii I 1 1 3310Win St, ij is l��l i•.1"I L _I�, er�.r; Cuyahoga Falls, Ohio44223 t�3�'; Its ��' i ur dntar TEL: (330) 253-8211 FAX: (330) 253-4489 Website: hQ:11www.settek.com Client: Synagro Project: Yadkinville WWTP QC SUMMARY R LPORT EatchID0 36331a WO#: 19030127 14-Mar-19 Sample ID LCS-36331 SampType: LCS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 3/11/2019 RunNo: 95613 Client ID: LCSS Batch ID: 36331a TestNo: SW8270 Analysis Date: W12/2019 SegNo: 1996811 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.491 0.0400 0.8000 0 61.4 19.1 126 2,4,5-Trichlorophenol 0.633 0.100 0.8000 0 79.2 11.7 151 2,4,6-Trichlorophenol 0.719 0.100 0.8000 0 89.9 12A 150 2,4-Dinitrotoluene 0.741 0.0200 0.8000 0 92.7 20.6 140 o-Cresol 0.623 0.100 0.8000 0 77.9 13.8 137 Cresols, Total ND 2.00 1.600 0 77.2 10 129 Hexachloro-1,3-butadiene 0.378 0,00800 0.8000 0 47.2 14.7 137 Hexachlorobenzene 0.672 0.0200 0.8000 0 84.0 12 139 Hexachloroethane 0.386 0.0400 0.8000 0 48.2 14.8 132 Nitrobenzene 0.676 0.0400 0.8000 0 84.6 15.6 138 Pentachlorophenol 0.721 0.100 0.8000 0 90.2 10 156 Pyridine 0.366 0.100 0.8000 0 45.7 1 130 Surr: 2-Fluorophenol 0.609 1.000 60.9 10 147 Surr: Phenokd6 0.587 1.000 58.7 10 140 Surr: Nitrobenzene-d5 0.763 1.000 76.3 10 169 Surr: 2,4,6-Tribromophenol 0.795 1.000 79.5 10 185 Surr:2-Fluorobiphenyl 0.664 1.000 66A 10 169 Surr: p-Terphenykd14 1.02 1.000 102 10 179 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 17 of 31 Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: htW.//www.settelc.com Client: Synagro Project: Yadldnville WWTP Sample ID MB-36331 SampType: MBLK TestCode: TCLPSVOC_ Units: mg/L Client ID: PBS Batch ID: 36331a TestNo: SW8270 Analyte Result PQL SPK value SPK Ref Val 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0,100 2,4,6-Trichlorophenol ND 0,100 2,4-Dinitrotoluene ND 0.0200 o-Cresol ND 0.100 Cresols, Total ND 2,00 Hexachloro-1,3-butadiene ND 0,00800 Hexachlorobenzene ND 0.0200 Hexachloroethane ND 0.0400 Nitrobenzene ND 0.0400 Pentachlorophenol ND 0,100 Pyridine ND 0.100 Sum 2-Fluorophenol 0,496 Sum Pbenokd6 0.503 Sum Nitrobenzene-d5 0.621 Sum 2,4,6-Tribromophenol 0.623 Sum. 2-Fluorobiphenyl 0.567 Sum p-Terphenyl-d14 0,728 QC SUMMARY RiPORT WO#: 19030127 14-MaY-19 SatchIDa 36331a Prep Date: 3/11/2019 Analysis Date: 3/12/2019 %REC LowLimit HighLimit RPD Ref Val 1.000 49.6 10 109 1.000 50.3 10 109 1.000 62.1 19 120 1.000 62.3 10 120 1.000 56.7 22 117 1.000 72.8 34 116 RunNo: 95613 SegNo: 1998657 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Pen -nit Limit R RPD outside accepted recovery limits Original Page 18 of 31 Summit Environmental Technologies, Inc. QC SUMMARY 7�tT RLeO T l.. V 1V11�'ll-�it 1 it - 3310 Win St. 1 n l :•;'� L �, a P �; , ; Cuyahoga Falls, Ohio 44223 ••+.�I'v Or.�,1' L _wLib�n raidata�PS � TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030127 Website: ha://www.settefc.com 14-Mar49 Client: Synagro Project: Yadkinville WWTP BatchID4 36332 Sample ID MB-36332 SampType: MBLK TestCode: TCLP SVOC•• Units: mg/L Prep Date: W11/2019 RunNo: 95664 Client ID: PBS Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 SegNo: 1996798 Analyte Result PQL SPK value SPK Ref Val Chlordane, total ND 0.0250 Toxaphene ND 0.0500 Endrin ND 0,00250 gamma-BHC ND 0,00250 Heptachlor ND 0.00250 Heptachlor epoxide ND 0,00250 Methoxychlor ND 0,00250 Surr: TCMX 12.1 Surr: DCB 15A %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual d d 20.00 60.3 10 119 m 20.00 77.1 10 119 Sample ID LCS-36332 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/11/2019 Client ID: LCSS Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val RunNo: 95664 SegNo: 1996799 %RPD RPDLimit Qual Endrin 0.0130 0.00250 0.0250 0 52.0 20 157 gamma-BHC 0.0112 0,00250 0.0250 0 44.7 22 137 Heptachlor 0.0105 0,00250 0,0250 0 42.2 24 121 Heptachlor epoxide 0.0117 0,00250 0.0250 0 46.9 27 152 Methoxychlor 0.0131 0,00250 0.0250 0 52A 10 199 Surr: TCMX 12.8 20.00 64.0 10 119 Surr: DCB 16.7 20.00 83.5 10 119 Qualifiers: Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 19 of 31 Summit Environmental Technologies, Inc, QC SUMMARY RhORT W'5 p„,�V,� �lI__; _� i 3310 Win St. �, +4,r11''Ydh1Cri�TL iL� I"nir,:;,, Cuyahoga Falls, Ohio 44223 40 a1' r _;J,' ' Syr uYot0r'd WO#: 19030127 IF aw TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: htt42:llwww.settelc.com 14-Mar49 Client: Synagro Project: Yadlunville WWTP BatchID0 36332 Sample ID 19030122-001AMS SampType: MS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/11/2019 RunNo: 95664 Client ID: BatchQC Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 SegNo: 1996800 Analyte Result PQL SPK value SPK Ref Val °'°REC LowLimit HighLimit RPD Ref Val Endrin ND 0.0250 .0.0250 0 71.1 20 157 gamma-BHC ND 0.0250 0.0250 0 60.3 22 137 Heptachlor ND 0.0250 0.0250 0 59.6 24 121 Heptachlor epoxide ND 0.0250 0.0250 0 67.8 27 152 Methoxychlor ND 0.0250 0.0250 0 77.8 10 199 Surr: TCMX 18.9 20.00 94.4 10 119 Surr: DCB 21.7 20.00 109 10 119 %RPD RPDLimit Qual Sample ID 19030122-001AMSD SampType: MSD TestCode: TCLPSVOC- Units: mg/L Prep Date: 3/11/2019 RunNo: 95664 Client ID: Batch= Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 SegNo: 1996801 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin ND 0.0250 0.0250 0 56.7 20 157 0 0 30 gamma-BHC ND 0.0250 0.0250 0 53.1 22 137 0 0 30 Heptachlor ND 0.0250 0.0250 0 50.2 24 121 0 0 30 Heptachlor epoxide ND 0.0250 0.0250 0 56.6 27 152 0 0 30 Methoxychlor ND 0.0250 0.0250 0 59.1 10 199 0 0 30 Surr: TCMX 16.5 20.00 82.3 10 119 0 Surr: DCB 17.5 20.00 87.7 10 119 0 Qualifiers: y` Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 20 of 31 IL Summit Environmental Technologies, Inc. QC SUMMARY RORT L J 3310 Win St. �:P Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030127 Website: hgg.*11www.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WWTP Sample ID LCS-R95317 SampType: LCS TestCode: Ignitability_S Units: Client ID: LCSS Batch ID: R95317 TestNo: SW1030 Analyte Result PQL SPK value SPK Ref Val Ignitability 7.60 Sample ID 19021576-001ADUP SampType: DUP Client ID: BatchQC Batch ID: R95317 Analyte Ignitability Result Sample ID 19030122-001ADUP SampType: DUP Client ID: BatchQC Batch ID: R95317 Analyte Ignitability Result non-flammable Sample ID 19030124-001ADUP SampType: DUP Client ID: BatchQC Batch ID: R95317 An Ignitability non-flammable 7.240 TestCode: Ignitability_S Units: TestNo: SW1030 BatchID0 R95317 Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val 0 105 70 130 PQL SPK value SPK Ref Val TestCode:lgnitability_S Units: TestNo: SW1030 PQL SPK value SPK Ref Val TestCode: lgnitability_:i Units: TestNo: SW1030 PQL SPK value SPK Ref Val Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val i Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val If Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPDIII Ref Val RunNo: 95317 SegNo: 19835511 %RPD RPDLimit Qual RunNo: 95317 SegNo: 1983553 %RPD RPDLimit Qual 0 20 RunNo: 95317 SegNo: 1983555 %RPD RPDLimit Qual 0 20 RunNo: 95317 SegNo: 1983557 %RPD RPDLimit Qual 0 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 21 of 31 Summit Environmental Technologies, Inc. F- QC SUMMARY R.LPORT � L — i '._.1,k.1 s,}a'i.__ . LJ^ 3310 Win St. Cuyahoga Falls, Ohio44223 WO#: 19030127 I I � , 'f r;J moTEL: (330) 253-8211 FAX.• (330) 253-4489 Website: htt42:llwww.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WWTP BatchID: R95317 Ignitability non-flammable 0 0 20 Sample ID 19030127-001ADUP SampType: DUP TestCode: Ignitabi1ity_5 Units: Prep Date: RunNo: 95317 Client ID: Yadkinville WWTP Batch ID: R95317 TestNo: SW1030 Analysis Date: 3/5/2019 SegNo: 1983561 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Ignitability non-flammable 0 0 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quautitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 22 of 311 4 - i �, L Summit Environmental Technologies, Inc. Q!� SUMMARY 3310WinSt. 1�.. �7V it it ",�k� Nr.,(hlpsi ENJTP1 GIRi v, ,I I'T Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX:* (330) 253-4489 WO#: 19030fl27 Website: hgp://www.settek.com 14-Mar49 �llneIIA Synagro Project: Yadkinville WWTP Sample ID MB-95319 SampType: MBLK Client ID: PBS Batch ID: R95319 Analyte Result TestCode: tclp-voc-mstr Units: mg/L TestNo: SW8260 PQL SPK value SPK Ref Val 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0,00500 MEK ND 0.0250 Benzene ND 0,00500 Carbon tetrachloride ND 0500500 Chlorobenzene ND 0,00500 Chloroform ND 0.00500 Tetrachloroethene ND 0000500 Trichloroethene ND 0,00500 Vinyl chloride ND 0,00200 Surr: 4-Bromof] uorobenzene 46.8 Surr: Dibromofluoromethane 43.4 Surr: Toluene-d8 52.3 Prep Date: Analysis Date: 3/5/2019 °'°REC LowLimit HighLimit RPD Ref VaI 50.00 93.6 70 130 50.00 86.9 70 130 50.00 105 70 130 RunNo: 95319 SegNo: 1983592 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range 13 Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual 1litegration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original I- - L Summit Environmental Technologies, Inc. I _al 3310 Win St. ?,C' i'A M 'U J. y _ya err„yr ,'; Cuyahoga Falls, Ohio44223 +'Zna(vrlt'a)' L1borgy'v not TEL: (330) 253-8211 FAX: (330) 2534489 Website: h=://www.settek.com Client: Synagro Project: Yadkinville WWTP QC SUMMARY REPORT WO#: 19030127 14-ItIar-19 Sample ID LCS-95319 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 95319 Client ID: LCSS Batch ID: R95319 TestNo: SW8260 Analysis Date: 3/5/2019 SegNo: 1984745 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl_imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0206 0.00500 0.0200 0 103 79.4 131 1,2-Dichloroethane 0.0202 0,00500 0.0200 0 101 73.6 137 MEK 0.111 0.0250 0.100 0 111 55.1 163 Benzene 0.0210 0,00500 0.0200 0 105 73.1 132 Carbon tetrachloride 0.0193 0,00500 0.0200 0 96.4 63.7 139 Chlorobenzene 0.0213 0.00500 0.0200 0 106 72.3 139 Chloroform 0.0198 0400500 0.0200 0 99.0 79.3 129 Tetrachloroethene 0.0235 0400500 0.0200 0 117 56.2 187 Trichloroethene 0.0220 0,00500 0.0200 0 110 64.1 138 Vinyl chloride 0.0191 0000200 0.0200 0 95.7 22.1 147 Surr:4-Bromofluorobenzene 48.5 50.00 96.9 80A 126 Surr: Dibromofluorom ethane 50.1 50.00 100 70.3 125 Surr: Toluene-d8 53.6 50.00 107 82 117 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDhmit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Client: Synagro Project: Yadkinville WWTP Summit Environmental Technologies, Inc. L3310 Win St. QC SUMMARY REPORT _i. Cuyahoga Falls, Ohio44223 WO#: 19030127 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htt42:Ilwww.settelc.com 14-Mar49 BatchID0 R95327 Sample ID LCS-R95327 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@19.31C Prep Date: RunNo: 95327 Client ID: LCSW Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 SegNo: 1983688 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Sample ID 19030186-001ADUP SampType: DUP TestCode: pH_Oil(9045 Units: s.u.@20.3C Prep Date: RunNo: 95327 Client ID: BatchQC Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 SegNo: 1983690 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qua] pH 6.0 i 6.0 0.5 10 Sample ID CHECK 7 SampType: LCS TestCode: PH_OIL(9045 Units: s.u.@19.2C Prep Date: RunNo: 95327 Client ID: LCSW Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 SegNo: 1983707 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: * Value exceeds Maximiun Contaminant Level. B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 25 of 31 -- - Summit Environmental Technologies, Inc. �L3310 Win St. �J� QC SUMMARY RLPORT li � •�'1'• : p i r-;4,'w+lROAMNTAL. a cF',r lca9 C. ;i . Cuyahoga FalZs, Ohio 44223 i .�?Nydo—f' Lab rd'worle TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030127 Website: hO.F11www.settek.com 14-Mar49 Client: Synagro Project: Yadlinville WWTP Sample ID 19030127-001AMS SampType: MS Client ID: Yadkinville WWTP Batch ID: R95449 Analyte Sulfide, Reactive Result TestCode: Sulfide,React Units: mg/Kg TestNo: SW9034 PQL SPK value SPK Ref Val 4640 25.0 4800 Sample ID 19030127-001AMSD SampType: MSD Client ID: Yadkinville WWTP Batch ID: R95449 Analyte Sulfide, Reactive Result BatchID: R95449 Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val 0 96.7 80 120 TestCode: Sulfide,React Units: mg/Kg TestNo: SW9034 PQL SPK value SPK Ref Val 4550 25.0 4800 PreDate: Analysis Date: 3/6/2019 p %REC LowLimit HighLimit RPD Ref Val RunNo: 95449 SegNo: 1987979 %RPD RPDLimit Qual RunNo: 95449 SegNo: 1987980 %RPD RPDLimit Qual 0 94.8 80 120 4640 1.96 30 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 26 of 31 - Summit Environmental Technologies, Inc, It I i F I QC SUMMARY X%JUI '�' = i 3310 Win St. l ' E„'oil J;,,� diVI_,iL.L TLC ° 'aal_a Cuyahoga Falls, Ohio44223 WO#: 19030127 V;1Vrc;rn4' La; bari9aritL7 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: httl2://www.settelc.com 14-Mrar49 Client: Synagro Project: Yadkinville WWTP Sample ID MB-R95449 Client ID: PBW Analyte Sulfide, Reactive Sample ID LCS-R95449 Client ID: LCSW Analyte Sulfide, Reactive SampType: MBLK Batch ID: R95449 Result TestCode: Sulfide,Keact Units: mg/L TestNo: SW9034 PQL SPK value SPK Ref Val ND 25.0 SampType: LCS Batch ID: R95449 Result TestCode: Sulfide,React Units: mg/L TestNo: SW9034 PQL SPK value SPK Ref Val 4470 25.0 4800 Prep Date: Analysis Date: 3/5/2019 °ioREC LowLimit HighLimit RPD Ref Val Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val 0 93.1 85 115 RunNo: 95449 SegNo: 1987967 %RPD RPDLimit Qual RunNoI 95449 SegNo: 1987968 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 27 of 31 -- — - - Summit Environmental Technologies, Ina QC SUMMARY REPORT -- J �L V3310 Win St. '1,rJ�W,il{ Cuyahoga Falls, Ohio 44223 f r 9i';i r,+Laas' L ai�LrYaJ'ub&m TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030127 Website: hg2.*11www.settek.com 14-Mar-19 Client: Synagro Project: Yadkinville WWTP BatchIDa R95453 Sample ID 19030127-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 95453 Client ID: Yadkinville WWTP Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988039 Analyte Result PQL SPK value SPK Ref Val °'°REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.23 0.485 10.00 0.1837 90.4 81.6 122 Sample ID 19030127-001AMSD SampType: MSD Client ID: Yadkinville WWTP Batch ID: R95453 Analyte Cyanide, Reactive Result TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988040 PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 8.74 0.459 10.00 0.1837 85.6 81.6 122 9.226 5.42 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quanutation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 28 of 31 Summit Environmental Technologies, Inc. -- - QC SUMMARY R.LPORT - L J 3310 Win St. I 1 h 9 � j, l . _. I r tq IL Cuyahoga Falls, Ohio 44223 WO#: 19030127 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: http://Www.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WWTP BatchID4 R95453 Sample ID Blank SampType: MBLK TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: PBW Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988024 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive Sample ID LCS SampType: LCS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: LCSW Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988025 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.55 0.490 10.00 0 95.5 85 115 Sample ID RLCheck SampType: RLC TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: BatchQC Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988027 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 0.506 0.495 0.5000 0 101 50 150 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank B Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 29 of 31 ul� 3 P AL Fes Paae 30 of 31 S Summit Environmental Technologies, Inc. UMMIT 3310 Win St, FEN1 lirr+t N NTAL TECHtt.CJI- „t ,'a;,^ Cuyahoga Falls, Ohio44223 3 a m p a Lon gmOn Chis c k Ust — . Arfa'joicai L s +;rasonoF TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http:Ilwww.settek.coni Client Name: SYWNC-27028 Work Order Number: 19030127 RcptNo: 1 Logged by: Christopher Livengood 3/1/2019 10:15:00 AM _ Completed By: Jesseca E. Westfall 3/512019 10:12:48 AM 7,L Reviewed By: Jennifer Woolf 3/5/2019 11:24:21 AM Chain of Custody 1. Is Chain of Custody complete? Yes. ❑� No ❑ Not Present ❑ 2, How was the sample delivered? UPS Loeb In 3, Coolers are present? Yes❑ No ❑ NA ❑ 4, Shipping container/cooler in good condition? Yes � No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes � No ❑ NA ❑ g, Were all samples received at a temperature of >0° C to 6.0°C Yes ❑� No ❑ NA ❑ 7, Sample(s) in proper container(s)? Yes � No ❑ $. Sufficient sample volume for indicated test(s)? Yes ❑� No ❑ g. Are samples (except VOA and ONG) properly preserved? Yes❑ No ❑ 10. Was preservative added to bottles? Yes ❑ No ® NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials 12. Were any sample containers received broken? Yes ❑ No ❑� 13. Does paperwork match bottle labels? Yes � No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes � No ❑ 15. Is it clear what analyses were requested? Yes � No ❑ 16. Were all holding times able to be met? Yes ❑� No ❑ (If no, notify customer for authorization.) Special Handlin_g (if applicable) 17, Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA 0 Person Notified: � --� Date By Whom: � Via: ❑ eMail ❑Phone ❑Fax ❑ In Person Regarding: Client Instructions: 18, Additional remarks: COC not received at time of sample receipt. Received pink copy via email 3/5/19 Cooler Information Cooler No Temp °C Condition Seal Intact Seal No Seal Date Si ned B 1 5.2 Good Not Present Page 31 of 31 _ Summit Environmental Technologies, Inc. f 3310 Win St. ��.'Jlii� f•1F1 ,1T�.L 71 C491YCi! - Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 2534489 Website: http://www.settek.com March 14, 2019 Erik Bruce Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 99M450 RE: Yadkinville WTP Dear Erik Bruce: Order No.: 19030122 Summit Environmental Technologies, Inc. received 1 sample(s) on 3/1/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E$7688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah )H0092320114, Virginia VELAP 9456, Washington C891 Page 1 of 31 VIIrt'�MIAIci•JTB,L TECHIN0l 0GI-:3, TNCa JMM l� �LIENT: Synagro Project: Yadkmville WTP WorkOrder Narrative: S ummit Environmental Technologies, Inc. 3310 Win A Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 2534489 Wehsite: http•/hvww.settek.conz WO#: 19030122 Date: 3/14/2019 19030122a This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the. accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Prep Sample Comments: 19030122Jaw 434787: Prep Comments for MtlPrep_TCLP(3010A), Sample 19030122-OOlA: Sample was filtered after digestion. Analytical Sequence QC Notes: 19030122-OOlAMS TCLP-SVOC-Herb_NPW(8151): Surrogate spike recovery possibly indicates matrix interference. The method is in control as indicated by the laboratory control sample (LCS). 19030122-001AMSD TCLP-SVOC-Herb_NPW(8151): Surrogate spike recovery possibly indicates matrix interference. The method is in control as indicated by the laboratory control sample (LCS). 1903012MMAMS TCLP-SVOC-CPest(8081B): High RPD due to suspected sample inhomogeheity. 1903012M01AMSD TCLP-SVOC-CPest(8081B): High RPD due to suspected sample inhomogeneity. Original Sunzntit Environmental Technologies, be 3310 Win S Cuyahoga Falls, Ohio 442� TEL: (330) 253-8211 FAX.• (330) 253-44b Website: htm://wwwsettek.co. �' These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers WO#: 19030122 Date: 3/14/2019 U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit.. r The result exceeds the Regulatory Limit or Maximum Contamination Limit. m Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25%difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). Ii/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QIa1R The MS/MSD R?'D was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit. MB MethodBlank LOD Level ofDetection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quaniitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum ContaminationLimit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial CalibrationBlank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 31 y% p AIN A, M�� A _lik��lr(_5 JP W pe�W1•,lArAL j�y�i.7j. 'vr�� ��tiil ?il'.i , CLIETVT: Synagro Project, Yadkinville WTP Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website; http://www.settek.com Lab SampleID Client Sample ID Tag No 19030122-OOl Yadkinville WTP Date Collected 2/27/2019 9:05:00 AM WO#: 19030122 Date Received 3/1/2019 10:15:00 AM 14 Mar 19 Matrix Solid Page 4 of 31 Summit Environmental Technologies, Inc. '~ i. 1 3310 Win St. elo��_+rl�.iir.aeL rrP Cuyahoga Falls, Ohio44223 z a it td�ar Lr-barnforiE TEL: (330) 2534211 FAX: (330) 253-4489 Website: httn:11www.settek.com DATES R 1OII T WO#: 19030122 14-Ndar-19' CIlienta Synagro roject: Yadkinville WTP Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19030122-001A Yadkinville WTP 2/27/2019 9:05:00 AM Solid Ignitability of Solids (SW-846: 1030) 3/5/2019 12:00:00 PM pH (SW9045D) 3/5/2019 2:30:00 PM Reactive Cyanide (9014/7.3.3.2)-Solid 3/5/2019 5:16:00 PM Reactive Sulfide (9034)/7.3.4.2 3/5/2019 5:16:00 PM SVOC SW-846: 8151 Herbicides-TCL3/4/2019 6:00:00 PM 3/7/2019 3:00:00 PM 3/12/2019 8:41:00 PM TCLP Mercury Analysis (SW1311/7473/4/2019 6:00:00 PM 3/6/2019 12:40:00 PM 3/6/2019 4:43:00 PM TCLP Metals Analysis (SW1311/6010'3/4/2019 6:00:00 PM 3/6/2019 8:10:00 AM 3/6/2019 5:21:25 PM TCLP Pesticides Analysis (SW1311/8(3/4/2019 6:00:00 PM 3/11/2019 5:20:00 PM 3/12/2019 8:26:00 PM TCLP Semi-Volatiles Analysis 3/4/2019 6:00:00 PM 3/11/2019 12:15:00 PM 3/12/2019 4:27:00 PM (SW1311/8270) TCLP Volatiles Analysis 3/5/2019 3:07:00 PM ®riginal Paae5of�=1 Summit Environmental Technologies, Inc. Summoir 3310 Win St. Pd4'I!OWNI�NT"u.L TECRb'01 C!M7ASjTwr1rh Cuyahoga Falls, Ohio 44223 .Ana;{ t,'Cal L2barafovo! TEL: (330) 253-8211 FAX.• (330) 2534489 b:report) • 'I I Webszte:://www.settek.com Date Reported: 3/14/2019 'LIENT: Synagro Tag Number: Matrix• SOLID Collection Date: 2/27/2019 9:05:00 AM Lab ID: 19030122-001A Project: Yadkinville WTP Client Sample ID Yadkinville WTP Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW131117470) TCLP Mercury ND 0.00200 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW131116010) SW7470A SW7470A Analyst: DNS mg/L 1 3!6/2019 4:43:00 PM SW6010D SW3010A Analyst: KMO TCLP Arsenic(As) ND 0.500 mg/L 1 3/6/2019 5:21:25 PM TCLP Barium(Ba) ND 5.00 mg/L 1 3/6/2019 5:21:25 PM TCLP Cadmium(Col) ND 0.100 mg/L 1 3/6/2019 5:21:25 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 3/6/2019 5:21:25 PM TCLP Lead(Pb) ND 0.500 mg/L 1 3/6/2019 5:21:25 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 3/6/2019 5:21:25 PM TCLP Silver(Ag) ND 0.500 mg/L 1 3/6/2019 5:21:25 PM 'CLP METALS, VOC, BNA, PEST; HERB -SOLID SW8270, Analyst: BJH TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.0800 mg/L 2 3/12/2019 4:27:00 PM 2,4,5-Trichlorophenol ND 0.200 mg/L 2 3/12/2019 4:27:00 PM 2,4,6-Trichlorophenol ND 0.200 mg/L 2 3/12/2019 4:27:00 PM 2,4-Dinitrotoluene ND 0.0400 mg/L 2 3/12/2019 4:27:00 PM Cresols, Total ND 4.00 mg/L 2 3/12/2019 4:27:00 PM Hexachloro-1,3-butadiene ND 0.0160 mg/L 2 3/12/2019 4:27:00 PM Hexachlorobenzene ND 0.0400 mg/L 2 3/12/2019 4:27:00 PM Hexachloroethane ND 0.0800 mg/L 2 3/12/2019 4:27:00 PM Nitrobenzene ND 0.0800 mg/L 2 3/12/2019 4:27:00 PM Pentachlorophenol ND 0.200 mg/L 2 3/12/2019 4:27:00 PM Pyridine ND 0.200 mg/L 2 3/12/2019 4:27:00 PM Surr: 2-Fluorophenol 53.2 10 - 109 %Rec 2 3/12/2019 4:27:00 PM Surr: PhenolA6 56.3 10 - 109 %Rec 2 3/12/2019 4:27:00 PM Surr: Nitrobenzene-d5 68A 19 - 120 %Rec 2 3/12/2019 4:27:00 PM Surr: 2,4,6-Tribromophenol 66.6 10 - 120 %Rec 2 3/12/2019 4:27:00 PM Surr: 2-171uorobiphenyl 66.1 22 - 117 %Rec 2 3/12/2019 4:27:00 PM Surr: p-Terphenyl-d14 88.6 34 - 116 %Rec 2 3/12/2019 4:27:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 6 ®f 31 - - Sununit Environmental Technologies, Inc. I,t,Lt " ' � V, A ' ` a i l 3310 Win St. HOWN1_t•JTAL 3Zrr11t'+Qi.')1 ,,,17'� Cuyahoga Falls, Ohio 44223 -- -F Ajta-Vroloal L gbnyafano TEL: (330) 253-8211 FAX: (330) 253-4489 Wb' l // 1 CLIENT: Synagro Matrix: SOLID Lab ID: 19030122-001A Project: Yadkinville WTP Client Sample ID Yadkinville WTP Analytical Report (base report) WO#: 19030122 e stte. 1ttp. www.sette c.cona Date Reported: 3/14/2019 Tag Number: Collection Date: 2/27/2019 9:05:00 AM Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.250 Toxaphene ND 0.500 Endrin ND 0.0250 gamma-BHC ND 0.0250 Heptachlor ND 0.0250 Heptachlor epoxide ND 0.0250 Methoxychlor ND 0.0250 Surr: TCMX 94.5 10 - 119 Surr: DCB 99A 10 - 119 TCLP METALS, VOC, BNA, PEST, HERB -SOLID SVOC SW-846: 8151 HERBICIDES-TCLP 2,4-D 2,4,5-TP ND 1.00 ND 0.500 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS fJ mg/L mg/L mg/L mg/L m g/L m g/L mglL %Rec %Rec SW8081 SW3510C Analyst: SFG SW8151A m g/L d mg/L SW8260 10 3/12/2019 8:26:00 PM 10 3/12/2019 8-126:00 PM 10 3/12/2019 8:261-00 PM 10 3/12/2019 8:26:00 PM 10 3/12/2019 8:26:00 PM 10 3/12/2019 8:26:00 PM 10 3/12/2019 8:26:00 PM 10 3/12/2019 8:26:00 PM 10 3/12/2019 8:26-100 PM SW8151A Analyst: SFG 1 3/12/2019 8:41:00 PM 1 3/12l2019 8:41:00 PM Analyst: CTB 1,1-Dichloroethene ND 0.250 mg/L 50 3/5/2019 3:07:00 PM 1,2-Dichloroethane ND 0.250 mg/L 50 3/5/2019 3:07:00 PM MEK ND 1.25 mg/L 50 3/5/2019 3:07:00 PM Benzene ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Carbon tetrachloride ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Chlorobenzene ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Chloroform ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Tetrachloroethene ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Trichloroethene ND 0.250 mg/L 50 3/5/2019 3:07:00 PM Vinyl chloride ND 0.100 mg/L 50 3/5/2019 3:07-100 PM Sum- 4-Bromofluorobenzene 92.9 70 - 130 %Rec 50 3/5/2019 3-107-100 PM Surr: Dibrom ofluorom ethane 87.7 70 - 130 %Rec 50 3/5/2019 3-107:00 PM Surr: Toluene-d8 101 70 - 130 %Rec 50 3/5/2019 3:07:00 PM Qualifiers: * Value exceeds Maximum Contaminant Level. E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 7 of 31 LIENT: Synagro Matrix. SOLID Lab ID: 19030122-001A Project: Yadkinville WTP Client Sample ID Yadkinville WTP RCI-SOLID-W/ IGNITABILITY1030 REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive RCI-SOLID-W/ IGNITABILITY1030 IGNITABILITY OF SOLIDS (SW-846: 1030) Ignitability RCI-SOLID-W/ IGNITABILITY1030 PH (SW9045D) pu RCI-SOLID-W/ IGNITABILITY1030 REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive Sunanait Environmental Technologies, Inc. 3310 Yf/rin A Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 ND flammable non- 7.1 ND Analytical Report (base report) WO#: 19030122 Webstte. http.//ivwlvsettekcona Date Reported: 3/14/2019 Qualifiers: * Value exceeds Maximum Contaminant Level. H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits Tag Number: Collection Date: 2/27/2019 9:05:00 AM Si/1/9014 Analyst: MS 0.472 mg/Kg 1 3/5/2019 5:16:00 PM SW1030 Analyst: AJT 1 3/5/2019 12:00:00 PM SW9045D Analyst: DHC s.L�.�19.4C 1 3/5/2019230:00PM SW9034 Analyst: MS 25.0 mg/Kg 1 3/5/2019 5:16:00 PM E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds O RSD is greater than RSDlimit PL Permit Limit Original RL Reporting Detection Limit Page 8 of 31 _ _ Summit Environrarental Technologies, Inc. ������' Il��t�®� ����� �� .. _ 3310 Win St. AL��� ��� �(� ��°� ��'."Iltr'�tJP+1_�dT�L 6.` ai�C�l- � �;' Cuyahoga Falls, Ohio 44223 tl�^,i!-_,., sec'; - — .���il�'d4�t' i���Yrat�t'deg TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030122 Website: http://www.settekcom I4-Mar-19 Client: Synagro State: NC Project: Yadkinville WTP Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 19030122-OOlA Solid Ignitability of Solids (SW-846: 1030) Ignitability A Solid pH (SW9045D) Hydrogen Ion (pH) A Solid Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Solid Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Solid SVOC SW-846: 8151 Herbicides-TCLP 2,4,5-TP A Solid SVOC SW-846: 8151 Herbicides-TCLP 2,4-D A Solid TCLP Mercury Analysis (SW1311/7470) Mercury A Solid TCLP Metals Analysis (SW1311/6010) Arsenic A Solid. TCLP Metals Analysis (SW1311/6010) Barium A Solid TCLP Metals Analysis (SW131Z/6010) Cadmium A Solid TCLP Metals Analysis (SW1311/6010) Chromium A Solid TCLP Metals Analysis (SW1311/6010) Lead A Solid TCLP Metals Analysis (SW1311/6010) - Selenium A Solid TCLP Metals Analysis (SW1311/60I0) Silver A Solid TCLP Pesticides Analysis (SW1311/8081) Chlordane,. total A Solid TCLP Pesticides Analysis (SW1311/8081) Endrin A Solid TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Solid TCLP Pesticides Analysis (SW13ll/8081) Heptachlor A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Solid TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Solid TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Solid. TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A NC WW SCM A Accredited NC WW SCM U Unavailable Original # 1 t _ Summit Environmental Technologies, Inc.�rogirn 3310 Win St. Al Ill O tes Report _w"v"1�_" P.1h1rt.Si.L t'i0t + :-�, r, Cuyahoga Falls, Ohio44223 - ARa(yrilcal "W.?baralarw TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030122 Website: hg2:11www.settek.com 14-Mar49 Client: Synagro State: NC Project: Yadkinville WTP Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 1903012M01A Solid TCLP Volatiles Analysis 1,1-Dichloroethene A Solid TCLP Volatiles Analysis 1,2-Dichloroethane A Solid TCLP Volatiles Analysis 2-Butanone A Solid TCLP Volatiles Analysis Benzene A Solid TCLP Volatiles Analysis Carbon tetrachloride A Solid TCLP Volatiles Analysis Chlorobenzene A Solid TCLP Volatiles Analysis Chloroform A Solid TCLP Volatiles Analysis Tetrachloroethene A Solid TCLP Volatiles Analysis Trichloroethene A Solid TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Page 10 of 31 Original # 1 -1 r- - -. -- Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY Rt'ORT L ClI C" P, - Cuyahoga Falls, Ohio 44223 „ _ TEL: (330) 253-8211 FAX (330) 253-4489 WO#: 19030122 Website: hW.&11www.settek.com 14111,Mar49 Client: Synagro Project: Yadldnville WTP )BatchID: 36252 Sample ID 19030086-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 3/6/2019 RunNo: 95376 Client ID: BatchQC Batch ID: 36252 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 SegNo: 1987166 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.31 0.500 2.000 0 115 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2767 99.1 70 130 TCLP Cadmium(Cd) 1.97 0.100 2.000 0 98A 70 130 TCLP Chromium(Cr) 2.11 0.200 2.000 0 105 70 130 TCLP Lead(Pb) 2.06 0.500 2.000 0 103 70 130 TCLP Selenium(Se) 2.39 0.0500 2.000 0,02516 118 70 130 TCLP Silver(Ag) 2.37 0.500 2.000 0 118 70 130 Sample ID 19030086-001AMSD SampType: MSD Client ID: BatchQC Batch ID: 36252 Analyte Result TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 3/6/2019 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 PQL SPK value SPK Ref Val `%REC LowLimit HighLimit RPD Ref Val RunNo: 95376 SegNo: 1987167 %RPD RPDLimit Qual TCLP Arsenic(As) 2.35 0.500 2.000 0 117 70 130 2.310 1.68 20 TCLP Barium(Ba) ND 5.00 2.000 0.2767 101 70 130 0 0 20 TCLP Cadmium(Cd) 1.99 0.100 2.000 0 99.7 70 130 1.967 1.30 20 TCLP Chromium(Cr) 2.15 0.200 2.000 0 107 70 130 2.109 1.77 20 TCLP Lead(Pb) 2.08 0.500 2.000 0 104 70 130 2.061 0.952 20 TCLP Selenium(Se) 2.42 0.0500 2.000 0.02516 120 70 130 2.392 1.33 20 TCLP Silver(Ag) 2.40 0.500 2.000 0 120 70 130 2.368 1.48 20 Qualifiers: * Value exceeds Maximum Contamiriant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Pen -nit Limit R RPD outside accepted recovery limits Original Page 11 of 3'1 Summit Environmental Technologies, Inc. 1 1 1 J L�Jr 3310 Win St, QC SUMMARY R 1,PORT p Cuyahoga FallsOhio 44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030122 Website: htto:llwww.settek.com 14-Mar49 Client: Synagro Project: Yadlcinville WTP �atchIDa 36252 Sample ID MB-36252 SampType: MBLK TestCode: MTL-TCLP-'( Units: mg/L Prep Date: 3/6/2019 RunNo: 95376 Client ID: PBS Batch ID: 36252 TestNo: SW6010D SW3010A Analysis Date: 3/6/2019 SegNo: 1998092 Analyte Result PQL SPK value SPK Ref Val TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-36252 Client ID: LCSS Analyte SampType: LCS Batch ID: 36252 Result TestCode: MTL-TCLP-7'( Units: mg/L TestNo: SW6010D SW3010A PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val Prep Date: 3/6/2019 Analysis Date: 3/6/2019 `%REC LowLimit HighLimit RPD Ref Val TCLP Arsenic(As) 2.09 0.500 2.000 0 104 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 105 80 120 TCLP Cadmium(Cd) 1.87 0.100 2.000 0 93.6 80 120 TCLP Chromium(Cr) 2.12 0.200 2.000 0 106 80 120 TCLP Lead(Pb) 2.15 0.500 2.000 0 108 80 120 TCLP Selenium(Se) 2.08 0.0500 2.000 0 104 80 120 TCLP Silver(Ag) 2.24 0.500 2.000 0 112 80 120 %RPD RPDLimit Qual RunNo: 95376 SegNo: 1998093 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding tunes for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 12 of 30I �- Summit Environmental Technologies, Inc. QC SUMMARYRmOORT — ri- ,r I I �I L 3310 Win St. Cuyahoga Falls, Ohio44223 =:+;i��r,��r' �' F.B,_+��Pbx� WO#: 19030122 .jfTEL: (330) 253-8211 FAX: (330) 253-4489 Website: hgp://www.settek.com 14-Mar49 Client: Synagro Project, Yadkinville WTP BatchID: 36264 TCLP Mercury ND 0.00200 TCLP Mercury 0.00409 0.00200 0.00400 0 102 80 120 TCLP Mercury 0.00445 0.00200 0.00400 0 111 75 125 Sample ID 19030086-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Analyte Result PQL SPK value SPK Ref Val Prep Date: 3/6/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95406 %RPD RPDLimit Oual TCLP Mercury 0.00443 0.00200 0.00400 0 111 75 125 0.00445 0.450 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 13 of 31 r — -- Summit Environmental Technologies, wUMMARY 4 IL QSPORT 11 oil. - 3310 Win St. d SUMMARY Cuyahoga Falls, Ohio44223 Ajr+ t'yNc rd' Laboari �Yonell TEL: (330) 2531-8211 FAX* (330) 2534489 WO#: 19030122 Website: hyg.ii www.settekcom 14-Mar~19 Client: Synagro Project: Yadkinville WTP Sample ID 19030086-001AMSD SampType: MSD Client ID: BatchQC Batch ID: 36264 Analyte Result TestCode: HG_TCLP(74 units: PPM TestNo: SW7470A SW7470A PQL SPK value SPK Ref Val Prep Date: 3/6/2019 Analysis Date: 3/6/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95406 SegNo: 1986476 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 14 of 31 -_ _- Summit Environmental Technologies, Inc. iL 3310 Win St, QC SUMMARY RLP®RT +': r� +L err Cuyahoga Falls, Ohio 44223 i� 1 0 LL m I 1J ^'.+p�+ o' ! _vjJbr tjyoraL� r TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 19030122 Website: http://www.settelzcom 14-Mar49 Client: Synagro Project: Yadkinville WTP �atchID: 36316 Sample ID MB-36316 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 3/7/2019 RunNo: 95654 Client ID: PBS Batch ID: 36316 TestNo: SW8151A SW8151A Analysis Date: 3/12/2019 SegNo: 1996428 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D ND 1.00 d 21415-TP ND 0.500 d Sum 2,4-Dichlorophenylacetic acid 373 500.0 74.6 20 140 Sample ID LCS-36316 SampType: LCS TestCode: TCLPSVOC- Units: mg/L Prep Date: 3/7/2019 RunNo: 95654 Client ID: LCSS Batch ID: 36316 TestNo: SW8151A SW8151A Analysis Date: 311212019 SegNo: 1996429 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 19, 214-D ND 1.00 0.500 0 73.6 43.8 130 21415-TP ND 0.500 0.500 0 67.2 51.5 111 Surr: 2,4-Dichlorophenylacetic acid 468 500.0 93.5 34.2 150 Sample ID 19030122-001AMS SampType: MS Client ID: Yadkinville WTP Batch ID: 36316 Analyte Result TestCode: TCLPSVOC- Units: mg/L TestNo: SW8151A SW8151A PQL SPK value SPK Ref Val Prep Date: 3/7/2019 Analysis Date: 3/12/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95654 SegNo: 1996430 On RPDLimit Qual 214-D ND 1.00 0.500 0 73.7 37 105 m 2,4,5-TP ND 0.500 0.500 0 70A 38 106 m Sum 2,4-Dichlorophenylacetic acid 713 500.0 143 20 140 Sm Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded 7 Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 15 of 301 Summit Environmental Technologies, Inc. _ J L� 'f 3310 Win St. L QC SUMMARY R-eORT l 4I; IDiJVJd1� L �� �Cv, 101 G , - Cuyahoga Falls, Ohio 44223 d �g'rIcfa L-clbexradorJ& TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030122 �,� Website: hW.'11www.settek.com 14-Mar~19 Client: Synagro Project: Yadkinville WTP ]BatchID: 36316 Sample ID 19030122-001AMSD SampType: MSD TestCode: TCLPSVOC- Units: mg/L Prep Date: 3/7/2019 RunNo: 95654 Client ID: Yadkinville WTP Batch ID: 36316 TestNo: SW8151A SW8151A Analysis Date: 3/12/2019 SegNo: 1996431 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 274-D ND 1.00 0.500 0 67.2 37 105 0 0 30 m 21415-TP ND 0.500 0.500 0 64.6 38 106 0 0 30 m Surr: 2,4-Dichlorophenylacetic acid 875 500.0 175 20 140 0 30 Sm Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manua1111tegration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 16 of 301 - - L Summit Environmental Technologies, Inc. � 3310 Win St. JI 1;,, ud 1 ; T° L E C! i, CAI C r Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: htt12:11Www.settek.com Client: Synagro Project: Yadlcinville WTP QC SUMMARY R-L-eORT WO#: 19030122 14-NZaY-I9 BatchID: 36331a Sample ID LCS-36331 Samp I ype: LCS TestCode: TCLPSVOC_ Units: mg/L Prep Date: 3/11/2019 Client ID: LCSS Batch ID: 36331a TestNo: SW8270 Analysis Date: 3/12/2019 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val RunNo: 95613 SegNo: 1996811 %RPD RPDLimit Qual 124-Dichlorobenzene 0.491 0.0400 0.8000 0 61.4 19.1 126 2,4,5-Trichlorophenol 0.633 0.100 0.8000 0 79.2 11.7 151 2,4,6-Trichlorophenol 0.719 0.100 0.8000 0 89.9 12A 150 2,4-Dinitrotoluene 0.741 0.0200 0.8000 0 92.7 20.6 140 o-Cresol 0.623 0.100 0.8000 0 77.9 13.8 137 Cresols, Total ND 2.00 1.600 0 77.2 10 129 Hexachloro-1,3-butadiene 0.378 0,00800 0.8000 0 47.2 14.7 137 Hexachlorobenzene 0.672 0.0200 0.8000 0 84.0 12 139 Hexachloroethane 0.386 0.0400 0.8000 0 48.2 14.8 132 Nitrobenzene 0.676 0.0400 0.8000 0 84.6 15.6 138 Pentachlorophenol 0.721 0.100 0.8000 0 90.2 10 156 Pyridine 0.366 0.100 0.8000 0 45.7 1 130 Surr: 2111Fluorophenol 0.609 1.000 60.9 10 147 Surr: Phenokc[6 0.587 1.000 58.7 10 140 Surr. Nitrobenzene-d5 0.763 1.000 76.3 10 169 Surr: 2,4,6-Tribromophenol 0.795 1.000 79.5 10 185 Surr:2-Fluorobiphenyl 0.664 1.000 66A 10 169 Surr: p-Terphenyl-d14 1.02 1.000 102 10 179 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual hitegration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 17 of 301 -- L: 1 �^ FFI - - 3.i K/ �' LAF7�JLei 9ria Client: Synagro Project: Yadlunville WTP Summit Environmental Technologies, Inc. 3310 Win St, Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htW:Ilwww.settelc.com QC SUMMARY P%i)RT WO#: 19030122 14-Mar-19 BatchTD: 36331a Sample ID 1V1B-36331 SampType: MBLK TeStCode: TCLP SVOG_ Units: mg/L Prep Date: 3/11/2019 Client ID: PBS Batch ID: 36331a TestNo: SW8270 Analysis Date: 311212019 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val RunNo: 95613 SegNo: 1998657 %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0.100 2,4,6-Trichlorophenol ND 0.100 2,4-Dinitrotoluene ND 0.0200 o-Cresol ND 0.100 Cresols, Total ND 2.00 Hexachloro-1,3-butadiene ND 0,00800 Hexachlorobenzene ND 0.0200 Hexachloroethane ND 0.0400 Nitrobenzene ND 0.0400 Pentachlorophenol ND 0.100 Pyridine ND 0.100 Surr: 2-Fluorophenol 0.496 1.000 49.6 10 109 Sum Phenol-d6 0.503 1.000 50.3 10 109 Sum, Nitrobenzene-d5 0.621 1.000 62A 19 120 Sum 2,4,6-Tribromophenol 0.623 1.000 62.3 10 120 Surr:2-Fluorobiphenyl 0.567 1.000 56.7 22 117 Sum p-Terphenyl-d14 0.728 1.000 72.8 34 116 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 18 of 31 Summit Environmental Technologies, Inc. �! +SUMMARY 77 JORT 3310 Win St. 1. 1J V l�ll�.ir�.i` i itLl I +01111 •;r+l 0e r:.,. -. Cuyahoga Falls, Ohio 44223 WO#:. 19030122 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: hZ.*11www.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WTP BatchIDa 36332 Sample ID MB-36332 SampType: MBLK TestCode: TCLPSVOC- Units: mg/L Prep Date: 3/11/2019 RunNo: 95664 Client ID: PBS Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 311212019 SegNo: 1996798 Analyte Result PQL SPK value SPK Ref Val Chlordane, total ND 0.0250 Toxaphene ND 0.0500 Endrin ND 0,00250 gamma-BHC ND 0,00250 Heptachlor ND 0.00250 Heptachlor epoxide ND 0,00250 Methoxychlor ND 0,00250 Surr: TCMX 12.1 Surr: DCB 15A %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual d d 20.00 60.3 10 119 m 20.00 77.1 10 119 Sample ID LCS-36332 SampType: LCS TestCode: TCLPSVOC- Units: mg/L Prep Date: 3/11/2019 RunNo: 95664 Client ID: LCSS Batch ID: 36332 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 SegNo: 1996799 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val Endrin 0.0130 0.00250 0.0250 0 52.0 20 157 gamma-BHC 0.0112 0,00250 0.0250 0 44.7 22 137 Heptachlor 0.0105 0.00250 0.0250 0 42.2 24 121 Heptachlor epoxide 0.0117 0,00250 0.0250 0 46.9 27 152 Methoxychlor 0.0131 0,00250 0.0250 0 52A 10 199 Surr: TCMX 12.8 20.00 64.0 10 119 Surr: DCB 16.7 20.00 83.5 10 119 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit, ND Not Detected 0 RSD is greater than RSDlimit Original P Second column confirmation exceeds PL Pen -nit Limit R RPD outside accepted recovery limits Page 19 of 31 i oil Summit Environmental Technolo ies, Inc. - 'I1 , _. �_�! I� �L�� 3310 Win St, QC SUMMARY R i eORT I-r, Cuyahoga Falls, Ohio 44223 - TEL: (330) 253-8211 FAX.• (330) 253-4489 WO#: 19030122 Website: httl2://www.settek.corn 14-Mar49 Client: Synagro Project: Yadkinville WTP Sample ID 19030122-001AMS SampType: MS Client ID: Yadkinville WTP Batch ID: 36332 Analyte Result BatchID0 36332 TestCode: TCLP SVOC- Units: mg/L Prep Date: 3/11/2019 RunNo: 95664 TestNo: SW8081 SW3510C Analysis Date: 3/12/2019 SegNo: 1996800 PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val Endrin ND 0.0250 0.0250 0 71.1 20 157 gamma-BHC ND 0.0250 0.0250 0 60.3 22 137 Heptachlor ND 0.0250 0.0250 0 59.6 24 121 Heptachlor epoxide ND 0.0250 0.0250 0 67.8 27 152 Methoxychlor ND 0.0250 0.0250 0 77.8 10 199 Surr: TCMX 18.9 20.00 94.4 10 119 Surr: DCB 21.7 20.00 109 10 119 Sample ID 19030122-001AMSD SampType: MSD Client ID: Yadkinville WTP Batch ID: 36332 Analyte Result TestCode: TCLP-SVOC•• Units: mg/L TestNo: SW8081 SW3510C PQL SPK value SPK Ref Val Prep Date: 3/11/2019 Analysis Date: 3/12/2019 %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual m RunNo: 95664 SegNo: 1996801 %RPD RPDLimit Qual Endrin ND 0.0250 0.0250 0 56.7 20 157 0 0 30 gamma-BHC ND 0.0250 0.0250 0 53.1 22 137 0 0 30 Heptachlor ND 0.0250 0.0250 0 50.2 24 121 0 0 30 Heptachlor epoxide ND 0.0250 0.0250 0 56.6 27 152 0 0 30 Methoxychlor ND 0.0250 0.0250 0 59.1 10 199 0 0 30 Surr: TCMX 16.5 20.00 82.3 10 119 0 Surr: DCB 17.5 20.00 87.7 10 119 0 Qualifiers: * Value exceeds Maxnmm� Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 20 of 31 - Summit Environmental Technologies, Inc. (�! SUMMARY 77nJ ?ORT ��I J� 3310WinSt. �Cl. SUMMARY [� �I, �r�rtr•]T�I r,;;� �el�r, ;L,. Cuyahoga Falls, Ohio 44223 WO#: 19030122 TEL: (330) 253-8211 FfIX.• (330) 253-4489 Website: htW:Ilwww.settek.com. 14-MaY-19 Client. Synagro Project: Yadkinville WTP BatchII): R95317 Ignitability 7.60 7.240 0 105 70 130 Ignitability non-flammable 0 0 20 Ignitability non-flammable 0 0 20 Ignitability non-flammable 0 0 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSA is greater than RSDlimit Original P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Page 21 of 31 _ H -- — - L Summit Environmental Technologies, Inc. �y r� - ` � �i 3310 Win St. QC SUMMARY R-LPOR Jl 177 11EN41101COIJPal L;x'�UI . U:Cj ,,4I01 Cb a'� ' , '�l'�l Cuyahoga Falls, Ohio 44223 al 44,r,+j� ytknfi Lsbijr&'arwd . TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030122 Website: http://www.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WTP BatchID: R95317 Sample ID 19030124-001ADUP SampType: DUP Client ID: Batch= Batch ID: R95317 Analyte Result Sample ID 19030125-001ADUP SampType: DUP Client ID: Batch= Batch ID: R95317 Analyte Result TestCode: Ignitability_S Units: Prep Date: RUnNo: 95317 TestNo: SW1030 Analysis Date: 3/5/2019 SegNo: 1983557 PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual TestCode: Ignitability_S Units: TestNo: SW1030 PQL SPK value SPK Ref Val Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95317 SegNo: 1983559 %RPD RPDLimit Qual Ignitability non-flammable 0 0 20 Sample ID 19030127-001ADUP SampType: DUP Client ID: Batch= Batch ID: R95317 Analyte Result TestCode: Ignitability_S Units: TestNo: SW1030 PQL SPK value SPK Ref Val Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val RunNo: 95317 SegNo: 1983561 %RPD RPDLimit Qual Ignitability non-flammable 0 0 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected ni the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to deterul e MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 22 of 31 Summit Environmental Technologies, Inc. 3310 Win St, QC SUMMARY REPORT 1 +e n 9 Vd i •1`r: L„ I o ram: Cuyahoga Falls, Ohio 44223 WO#: 19030122 TEL: (330) 253-8211 FIX: (330) 253-4489 Website: hQ:Ilwww.settelc.com I4-Mar49 Client: Synagro Project: Yadkinville WTP Sample ID MB-95319 SampType: MBLK Client ID: PBS Batch ID: R95319 Analyte Result TestCode: tclp-voc-mstr Units: mg/L TestNo: SW8260 PQL SPK value SPK Ref Val 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0,00500 MEK ND 0.0250 Benzene ND 0,00500 Carbon tetrachloride ND 0,00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0,00500 Trichloroethene ND 0,00500 Vinyl chloride ND 0,00200 Surr: 4-Bromofluorobenzene 46.8 Surr: Dibromofluoromethane 43A Surr: Toluene-d8 52.3 Batchll)a R95319 Prep Date: Analysis Date: W5/2019 %REC LowLimit HighLimit RPD Ref Val 50.00 93.6 70 130 50.00 86.9 70 130 50.00 105 70 130 RunNo: 95319 SegNo: 1983592 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 23 of 31 -Y Summit Environmental Technologies, Inc. 3310 Win St, s,I rJVol arsr u ZIa; �';�r i; Cuyahoga Falls, Ohio44223 TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: hO.*11www.settek.com Client: Synagro Project: Yadkinville WTP QC SUMMARY REPORT WO#: 19030122 14-1�1ar-19 Sample ID LCS-95319 SampType: LCS TestCode: tclp-voc-mstr Units: mg/L Prep Date. RunNo: 95319 Client ID: LOSS Batch ID: R95319 TestNo: SW8260 Analysis Date: 3/5/2019 SegNo: 1984745 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0206 0.00500 0.0200 0 103 79.4 131 1,2-Dichloroethane 0.0202 0,00500 0.0200 0 101 73.6 137 MEK 0.111 0.0250 0.100 0 111 55.1 163 Benzene 0.0210 0400500 0.0200 0 105 73.1 132 Carbon tetrachloride 0.0193 0000500 0.0200 0 96A 63.7 139 Chlorobenzene 0.0213 0000500 0.0200 0 106 7203 139 Chloroform 0.0198 0,00500 0.0200 0 99.0 79.3 129 Tetrachloroethene 0.0235 0.00500 0.0200 0 117 56.2 187 Trichloroethene 0.0220 0,00500 0.0200 0 110 64.1 138 Vinyl chloride 0.0191 0,00200 0.0200 0 95.7 22.1 147 Surr:4-Bromofluorobenzene 48.5 50.00 96.9 80A 126 Surr: Dibromofluoromethane 50.1 50.00 100 70.3 125 Surr: Toluene-d8 53.6 50.00 107 82 117 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Summit Environmental Technologies, Inc. QC SUMMARY 7� PORT LI l� <J Y 1�L JL _J 3310 Win St. IJ A 1 s r s' I 114, 1 _ , li r. L : CA e Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX: (330) 2534489 WO#: 19030122 r Iv'-t �Ipi R1 i - - • Y Website: http://www.settelc.com 14-Mar49 Client: Synagro Project. Yadkinville WTP SatchID: R95327 Sample ID LCS-R95327 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@19.3C Prep Date: Client ID: LCSW Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val pH 7.0 7.0 0 100 90 110 RunNo: 95327 SegNo: 1983688 %RPD RPDLimit Qual Sample ID 19030186-001ADUP SampType: DUP TestCode: pH_Oil(9045 Units: s.u.@20.3C Prep Date: RunNo: 95327 Client ID: BatchQC Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 SegNo: 1983690 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 6.0 0 0 6.0 0.5 10 Sample ID CHECK 7 SampType: LCS TestCode: PH_OIL(9045 Units: s.u.@19.2C Prep Date: RunNo: 95327 Client ID: LCSW Batch ID: R95327 TestNo: SW9045D Analysis Date: 3/5/2019 SegNo: 1983707 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 0 101 90 110 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual wtegration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 25 of 31 Summit Environmental Technologies, Inc. - L r 3310 Win St. QC SUMMARY REPORT 41sir+i9f I :•1`i�L ' e9 r Cuyahoga Falls, Ohio 44223 A.i7a!'y0c: P La orrAlvill TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030122 Website: http:llwww.settek.com 14-Mar49 Client: Synagro Project: Yadkinville WTP Sample ID 19030127-001AMS SampType: MS Client ID: BatchQC Batch ID: R95449 Analyte Sulfide, Reactive Result TestCode: Sulfide,React Units: mg/Kg TestNo: SW9034 PQL SPK value SPK Ref Val 4640 25.0 4800 Sample ID 19030127-001AMSD SampType: MSD Client ID: BatchQC Batch ID: R95449 Analyte Sulfide, Reactive Result BatchID0 R95449 Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val 0 96.7 80 120 TestCode: Sulfide,React Units: mg/Kg TestNo: SW9034 PQL SPK value SPK Ref Val 4550 25.0 4800 Prep Date: Analysis Date: RunNo: 95449 SegNo: 1987979 %RPD RPDLimit Qual RunNo: 95449 3/5/2019 SegNo: 1987980 °�oREC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual 0 94.8 80 120 4640 1.96 30 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual filtegration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 26 of 31 — Summit Environmental Technologies, Inc. L� 3310 Win St, QC SUMMARY RLPORT Wall,' 111' �+J{�i spJT �u Ir+l r, ;;`. �� Cuyahoga Falls, Ohio 44223 WO#: 19030122 ANyU .:n+' LabaraldmG- TEL: (330) 253-8211 FAX.• (330) 253-4489 Website: http://www.settelc.com 14-Mar49 Client: Synagro Project: Yadldnville WTP Sample ID MB-R95449 SampType: MBLK TestCode: Sulfide,React Units: mg/L Client ID: PBW Batch ID: R95449 TestNo: SW9034 Analyte Result PQL SPK value SPK Ref Val %REC Sulfide, Reactive Sample ID LCS-R95449 Client ID: LCSW Analyte Sulfide. Reactive SampType: LCS Batch ID: R95449 Result TestCode: Sulfide,React Units: mg/L TestNo: SW9034 PQL SPK value SPK Ref Val 4470 25.0 4800 BatchID0 R95449 Prep Date: Analysis Date: 3/5/2019 LowLimit HighLimit RPD Ref Val Prep Date: Analysis Date: 3/5/2019 %REC LowLimit HighLimit RPD Ref Val 0 93.1 85 115 RunNo: 95449 SegNo: 1987967 %RPD RPDLimit Qual RunNo: 95449 SegNo: 1987968 %RPD RPDLimit Qual Qualifiers: * Value exceeds Maximum Contaminant Level. B .Analyte detected in the associated Method Blanlc E Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below qumA at on limits M Manual Integration used to determnie MC Value is below Minimum Compound Limit, ND Not Detected O RSD is greater than RSDlimit P Second column confha nation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 27 of 31 C Summit Environmental Technologies, Inc. QC SUMMARY R.LPORT I _ ^ 3310 Win St, I; 9�dt °'r• r l �z n.,� Cuyahoga Falls, Ohio 44223 rPlrp� :u' i i� ldrli �a_ TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 19030122 kf`ebsite: http://www.settek.com 14-MaP49 Client: Synagro Project: Yadldnville WTP BatchID0 R95453 Sample ID 19030127-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 95453 Client ID: BatchQC Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988039 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.23 0.485 10.00 0.1837 90.4 81.6 122 Sample ID 19030127-001AMSD SampType: MSD Client ID: BatchQC Batch ID: R95453 Analyte Cyanide, Reactive Result TestCode: Cyanide,Rea Units: mg/Kg TestNo: SW9014 PQL SPK value SPK Ref Val Prep Date: Analysis Date: 3/5/2019 9%REC LowLimit HighLimit RPD Ref Val RunNo: 95453 SegNo: 1988040 %RPD RPDLimit Qual 8.74 0.459 10.00 0.1837 85.6 81.6 122 9.226 5.42 20 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected ui the associated Method Blank I✓ Value above quantitation range H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected 0 RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery lhnits Original Page 28 of 311 r - Summit Environmental Technologies, Inc. �t - + r I i ' I L'I j 3310 Win St. QC SUMMARY REPORT 1 __. L� � 1C+iJl 4 �1 i''iL 'a �71 106 r; ; Cuyahoga Falls, Ohio 44223 WO#: 19030122 TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htW:11www.settek.com 14-Mar49 Client, Synagro Project. Yadkinville WTP SatchID0 R95453 Sample ID Blank SampType: MBLK TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: PBW Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988024 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive Sample ID LCS SampType: LCS TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: LCSW Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988025 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.55 0.490 10.00 0 95.5 85 115 Sample ID RLCheck SampType: RLC TestCode: Cyanide,Rea Units: mg/L Prep Date: RunNo: 95453 Client ID: BatchQC Batch ID: R95453 TestNo: SW9014 Analysis Date: 3/5/2019 SegNo: 1988027 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 0.506 0.495 0.5000 0 101 50 150 Qualifiers: * Value exceeds Maximum Contaminant Level. B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded 7 Analyte detected below quantitation limits M Manual Integration used to determine MC Value is below Minimum Compound Limit. ND Not Detected O RSD is greater than RSDlimit P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits Original Page 29 0f 311 -. _- - .. - IPaae 30 of 31 :� � � Sunsznit Environmental Technologies, Inc. 3310 Win St. het'��I(?�IdP.i��JT�LT��9PPtitt3lt�ti��=a,rtt' CuyalzogaFalls,Ohio44223 ��(❑��jQ(� �O�oQ� �'�(���� �0�� - - .�.rP�Ptri',�r:��' �' ��rfir,�d�t'dtt TEL: (330) 253-8211 FAX.• (330) 253-4489 I�ebsite: http://www.settekcom Client Name: SYN-NC-27028 Work Order Number: 19030122 RcptNo: 1 Logged by: Christopher Livengood Completed By: Jesseca E. Westfall Reviewed By: Jennifer Woolf 3/1/2019 10:15:00 AM ����� a P, r!,f�* 315/2019 10:11:41 AM 44��"-����� 3/5/2019 10:51:57 AM �{}� ��� _Chain of Custody 1, Is Chain of Custody complete? Yes � No ❑ Not Present ❑ 2, How was the sample delivered? UP5 Log In 3, Coolers are present? Yes ❑� No ❑ NA ❑ 4, Shipping container/cooler in good condition? Yes 0 No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present ❑� No. Seal Date: Signed By: 5, Was an attempt made to cool the samples? Yes ❑� No ❑ NA ❑ g. Were all samples received at a temperature of >0° C to 6.0°C Yes � No ❑ NA ❑ 7, Sample(s) in proper container(s)? Yes � No ❑ $, Sufficient sample volume for indicated test(s)? Yes � No ❑ g, Are samples (except VOA and ONG) properly preserved? Yes❑ No ❑ 1 Q, Was preservative added to boftles? Yes ❑ No❑ i�lA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials 0 12, Were any sample containers received broken? Yes ❑ No 13_ Does paperwork match bottle labels? Yes � No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes❑ No ❑ 15. Is it clear what analyses were requested? Yes 0 No ❑ 16. Were all holding times able to be met? Yes ❑� No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17, Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA Person Notified: By Whom: Regarding: Client Instructions: 18, Additional remarks: Date �I Via: ❑ eMail ❑Phone ❑Fax ❑ In Person -- -_ ___ COC not received at time of sample receipt. Received pink copy via email 3/5/19 Cooler Information Cooler No Temp °G Condition Seal Intact Seal No Seal Date Signed B 1 5.2 Good Not Present Page 31 of 31 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of YadkinVIRC WWTPName: Yadkinville WWTP Monitoring Period: From 01/01/ 2019 To 12/31/19 WQ Permit Number: WQ 00001800 NPDES Number: NC0006190 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) -Please indicate level achieved and alternative performed: Class A: Alt. 1/A (timeRemp) Alt, 2B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": 10 Beta Ray Compost Class B: Alt. (1) Fecal Density X rying Gamma Ray Heat D Pasteurization Alt. (2) Process to Signiftcantly Reduce Pathogens Thhilic eimop If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Au Drying Composting Aerobic Digestion Anaerobic Digestion Tf annlicahle to alternative. nerfnrmed (f acc A nr C'lass Rl emm�lete the fnllnwina mnnitnrina data^ Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units deuces Analysis Fecal 2xl0tothe 6s' M I'N 12921 21221 52980 MPN/g 0 Annual Grab Sm9221C Coliform power per gram E of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR503.33/15A NCAC 02T.1107) -Please indicate option/alternative performed: Option/Alt. 1 (VS reduction) X Option/Alt. 5 (14-Day Aerobic) Option/Alt. 9 (Injection) (40-day bench) Option/Alt. 2 Option/Alt. 6 (Alk Stabilization) Option/Alt. 10 (Incorporation) CERTIFICATION STATEMENT (please check the appropriate statement) (30-day bench) Option/Alt. 3 Option/Alt. 7 (Drying — Stable) (Spec. Option/Alt. 4 02 uptake) Option/Alt. 8 (Drying —Unstable) No vector attraction reduction alternatives were performed "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector atraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A IN 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation whyyou have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been rnet. I am aware that there are significant penalties for false certification m g fine andimprisonment.". ) Grant Trivette Plant Manager , / Preper3P Name and } rtle (type orprint) Land A lie Name and Title (if applicable) (type or print) Signature ofPreparer* Date Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results STA.TESVILLE ANALYTICAL Town of Yadkinville PO Box 816 Yadkinville, NC 27055 Receive Date: 01/24/2019 Reported: 01/25/2019 For: Comments: Geometric Mean 21,221 MPN/g Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 190124A5-01 Fecal Coliforms 1 52980 MPN/g SM92210E-200$ 01/24/2019 WC 190124-15-01 Percent Solids 1 1451 % SM254OB-2011 01/24/2019 WC 190124-15-02 Fecal Coliforms 2 21277 MPN/g SM92210E-2006 01/24/2019 WC 190124-15-02 Percent Solids 2 1041 % SM25408-2011 01/24/2019 WC 190124-15-03 Fecal Coliforms 3 12921 MPN/g SM92210E-2006 01/24/2019 WC 4nn40A 45 n-._�..... Solids n A �n Q// SM254OB-2011 A nAlnnAf C 1 Vu 146+- 10.03 Perce It Solids 3 1 • 1 0 JO l� 1/G'+14U 1:7 WV 190124-15-04 Fecal Coliforms 4 30120 MPN/g SM92210E-2006 01/24/2019 WC 190124-15-04 Percent Solids 4 1,66 % SM2540B-2011 01/24/2019 WC 190124-15-05 Fecal Coliforms 5 18405 MPN/g SM92210E-2006 01/24/2019 WC 190124-15-05 Percent Solids 5 1.63 % SM2540B-2011 01/24/2019 WC 190124-15-06 Fecal Coliforms 6 15132 MPN/a SMMlCE-2006 01/24/2019 WC 190124-15-06 Percent Solids 6 1,52 % SM254OB-2011 01/24/2019 WC 190124-15-07 Fecal Coliforms 7 15862 MPN/g SM92210E-2006 01/24/2019 WC 190124-15-07 Percent Solids 7 1,45 % SM25408-2011 01/24/2019 WC Respectfully submitted, Dena Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 •Statesville, NC 28687 •704/872/4697 Page 1 of 4 vetmjL- 96 TOTA =$� �6.1�' i S -2W GalCulaied EW. Q v e,� DI \L�;/ r USA %imi t iAL ANE)-FINAL AVERAGES OF YOUR % VOLATILE FRACTION TO CALCULATE THE PERCENT REDUCTION (ME. THE VAN tCLEECK: FORMULA) l ae K i xtction: If" :%. vol. Vic. - Final %. Vol, frac. X 100 = % u n tnffi* % VOL `irac. - ((rirflal % vial. €rac x Final 9b vol. €rac.) minus t LP 7 x 1.00 -L64J I f6 * D0 Mul 0at1on inside [( )) before you subtract on bottom of equaWn. s r ` J �•�Z.ZU {r T Agricultural Lime Application Log Year: 2019 Project: Yadkinville WWTP New (state -county -site -field) Soil 1Lime pH Requirement (from soil analysis) Tons/Acre Applied(CCE Eq.) Date Applied YK-33-1 5.9 O.OT/Ac. YK-33-1 6.9 0.OT/Ac. YK-33-3 6.3 0.0 T/AC YK-35-2 5.8 5.OT/Ac. .75tons/ac YK-2M 6.6 O.OT/Ac. *Lime will be applied when conditions improve. NCDA&CS Av )mic Division Phone: (919) 733-2655 Website: wwv igr.gov/agronomi/ Report No. '20-SL004618 lot Client: City of Yadkinville Advisor: Alex Fox ? %`��1� . " Predictive 213 Van Buren St ,r'x�" ¢' Synagro It 1 y:=ll Yadkinville, NC 27055 284 Boger Rd �` r! .`�'�I S o i I Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Yadkin ieyZ III Y°. -__� Links to Helpful Information Client ID: 476642 Advisor ID: 501947 Sampled: 09/11/2019 Received: 09/12/2019 completed: 09/21/2019 Farm: NC-YK-29 Sample ID: 01 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 110 40 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - WN in g1cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P4 K-I Ca% Mg% S-I Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.27 0.99 7.0 92 0.6 6.6 13 48 55 34 38 663 406 182 1 182 98 0.1 1 Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. to Steve Troxler, Commissioner of Agriculture i jn.l^.glir'I'.�,�y;lupi(u11'ia514.�1u NCDA&CS Agronomic Division Phone: (919) 733=2655 Website: www.neagr.gov/agronomi/ Report No. FY20-SL004618 Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. M and P-I values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1Mn-AI2 Mn-availability index for crop 2 Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn-I M-O manganese index soil class mineral -organic notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm, NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft, If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncapr.gov/agronomi/obpart4.htrntsfind information that P-I phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS4 soluble salt index WN weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-I zinc index remaining 16 [P-I, M, Ca%, Mg%, Mrid, Mn-All, Mn-AI2, Znd, Zn-Al, Cud, S.-I, SS -I, Na, ESP, SSd, NO3-1\1 (not routine) available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.goy/agronomi/uyrst.htm Page 1 of 1 Report Number: 19-326-0587 Account Number: 46431 Send To: Synagro Central LLC Marshal Puryear 284 Boger Rd Mocksville NC 27028 Alaypoint ANALYTICAL "Every acre... Every dear. "rM SOIL ANALYSIS REPORT Date Received: 11/22/2019 Date Of Analysis: 11/25/2019 Date Of Report: 11/25/2019 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 1 Fax 804-271-6446 www.waypointanalytical.com Grower: James Hobson Analytical Method(s): Mehlich 3 SMP Buffer pH Loss On Ignition Water pH NC =North Carolina Fertility Index Value OM WN ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Field ID Lab Number % Rate Soil Class Ibs/A M3 pp m Rate pp m Rate pp m Rate K ppm Rate Mg ppm Rate Ca ppm Rate Na ppm Rate Soil p H Buffer Index H meq/100g meg1100g 41K-33-3 16364 3A M 105 37 M NC = 31 70 M NC = 36 140 H 572 M 10 VL 6.3 0.5 4.7 MIN Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample Field ID ID K Mg % Fca Na % H % NO3 N ppm Rate S ppm Rate Zn ppm Rate Mn ppm Rate Fe ppm Rate Cu ppm Rate B ppm Rate SS ms/cm Rate 4K-33-3 3.8 24.8 60.9 0.9 10.6 18 M NC=37 7.0 H NC=175.0 18 M NC=113 148 VH 1.6 H NC=80.0 0.3 VL Values on this report represent the plant available nutrients in the Explanation of symbols: % (percent), ppm (parts per million), Ibs/A soil. Rating after each value: VL (Very Low), L (Low), M (Medium), (pounds per acre), ms/cm (milli -mhos per centimeter), meq/10og H (High), VH (Very High). ENR - Estimated Nitrogen Release. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble C.E.C. - Cation Exchange Capacity. Salts ms/cm x 640 = ppm. This report applies to sample(s) tested. Samples are retained a maximum of thirty days after testing. Analysis prepared by: WaypointAnalytical Virginia, Inc. Pauric McGroary NCDA&CS Ag �mic Division Phone: (919) 733-2655 Website: www gr.gov/agronomi/ Report No. '20-SL004632 -r, a r• ,. a Uj Client: James Hobson Advisor: Alex Fox Predictive 3541 Apperson Rd Synagro �_s u�CF44 'a'`4 East Bend, NC 27018 284 Boger Rd lu 1.'—'.FIxill: y" Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County: Yadkin Links to Helpful Information i Client ID: 493738 Advisor ID: 501947 Sampled: 09/10/2019 Received: 09/12/2019 Completed: 09/21/2019 Farm: NC-YK-33 Sample ID: 01 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH Pool K-1 Ca% Mg% S-I Mn-I Mn-All Mn-AI2 Zn-1 Zn-AI Cu-I Na ESP SS -I NO3-N 0.46 0.95 8.0 82 1 A 5.9 77 34 61 19 44 147 105 355 355 217 0.1 1 Sample ID: 02 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P205 K20 Mg S Mn Zn Cu B Information Lime History: 1 - Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 pH$ 0 0 0 Note: 12 Note: 2 - 0.0 Test Results [units - WN in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% WN CEC BS% Ac pH P4 K-I Ca% Mg% S-I Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS -I NO3-N 0.46 1.06 10.7 94 0.6 6.9 148 34 64 29 42 219 135 890 890 248 0.1 1 .11 '' a 11.111;KS i !rtl".r, I' Ia1;u:I r.,4iCh)fi�itilla�ii Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of A.priculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ James Hobson Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Lime If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. For noAill or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at time, even if the report recommends more. You can apply the rest in similar increments every six months until the full r is applied. If MG is recommended and lime is needed, use dolomitric lime. Fertilizer Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies for the crop being grown, not on soil test results. K-I and P-I values are based on test results and should be > 50. If they are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS -I levels appear only on reports for greenhouse soil or problem samples. Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients, In general, homeowners do not need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit ncagr.gov/agronomi/pubs.htm. Report No. FY20-SL004632 Page 2 of 2 Report Abbreviations Ac exchangeable acidity B boron BS% % CEC occupied by basic cations Ca% % CEC occupied by calcium CEC cation exchange capacity Cu-I copper index ESP exchangeable sodium percent HM% percent humic matter K-I potassium index K2O potash Mg % CEC occupied by magnesium MIN mineral soil class Mn manganese Mn-AI1 Mn-availability index for crop 1 Mn-A Mn-I 12 Mn-availability index for crop 2 manganese index M-O mineral -organic soil class N nitrogen Na sodium NOs-N O RG Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft . If you cannot find pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/agronomi/obpart4.htmf ff,9f nd information that P-1 may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P2O5 S-I Test Results � SS -I WN Zn-AI The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-I remaining 16 [P-I, K-I, Ca %, Mg%, Mn-I, Mn-A11, Mn-AI2, Zn-I, Zn-Al, Cu-I, S-I, Sod, Na, ESP, SS -I, NU3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.gov/agronomi/uyrst.htm nitrate nitrogen organic soil class current soil pH phosphorus index phosphate sulfur index soluble salt index weight per volume zinc availability index zinc index Page 1 of 1 Report No: 19-326-0585 Account No: 46507 Advisor: Synagro Central LLC/ Yadkinville Mary Brewer 284 Boger Road Mocksville NC 27028 Naypolnt.h, ANALYTICAL Client: Roger Davis Yadkinville WWTP 7621 Whitepine Road, Richmond, VA 23237 Main 804443-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm:4K-35 Date Received: 11/22/2019 Date of Report: 12/02/2019 Lab No Field ID Sample ID Soil Class HM% W/V pH AC P-1 K I S-I Mn-1 Zn-I Zn-AI Cu-1 CEC BS% Ca% Mg% ESP Na SS-1 NO3 N 16360 2 MIN 5.8 1.0 9 27 52 250 123 123 25 5.2 80 44 33 0.9 0 ICrop Recommendations; Rec Uom Lime (M/acre) N P205 K2 S Mn Mn-Al Zn Cu B Mg Last Crop I 1- Pasture lb/acre 0.5 50 86 120 0 0 170 0 0 0.5 0 COmmenfi: Test result units =CEC and Na in meq/100cm3; NO3 N in mg/dm3; WN in g/cm3 ni.,.+ti r��„r.,� nt„���,,,, .,f+nra+o� n�r+„ �orf�f��+�,,,, tns� anaivcic a�� fortili+�� rannmmanriatinnc shown nn this ran�rt ara nerfnrmed in accordance within NCDA guidelines. Analysis prepared bv: Wavpoint Analytical Virginia, Inc.