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HomeMy WebLinkAboutNC0003425_Comments_20200226SOUTHERN ENV IRON MENTAL LAW CENTER Telephone 919-967-1450 601 WEST ROSEMARY STREET, SUITE 220 Facsimile 919-929-9421 CHAPEL HILL, NC 27516-2356 VIA US MAIL February 19, 2020 RECEIVED FEB 2 6 2020 Dr. Sergei Chernikov NCDEQ/DWR/NPDES NCDEQ/DWR/NPDES Water Quality Permitting Section 1617 Mail Service Center Raleigh, North Carolina 27699-1617 Re: Draft NPDES Wastewater Permit — Roxboro Steam Station, # NC0003425 Dear Dr. Chernikov: On behalf of the Roanoke River Basin Association, please find enclosed comments on the draft National Pollutant Discharge Elimination System permit noticed for public comment by the North Carolina Department of Environmental Quality ("DEQ"); Division of Water Resources. If you have any questions, please do not hesitate to get in touch. Sincerely, Jennifer Doucette Legal Administrative Assistant Southern Environmental Law Center Enclosure Charlottesville • Chapel Hill • Atlanta 6 Asheville • Birmingham • Charleston • Nashville • Richmond • Washington, DC SOUTHERN ENVIRONMENTAL LAW CENTER Telephone 919-967-1450 601 WEST ROSEMARY STREET, SUITE 220 Facsimile 919-929-9421 CHAPEL HILL. NC 27516-2356 February 19, 2020 VIA EMAIL AND U.S. MAIL Dr. Sergei Chernikov NCDEQ/DWR/NPDES Water Quality Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 sergei. chernikov@ncdenr.gov RECEIVED FEB 2 6 2020 NCDEQIDWRINPDES Re: Draft NPDES Wastewater Permit — Roxboro Steam Station, # NC0003425 Dear Dr. Chernikov: On behalf of the Roanoke River Basin Association, we submit the following comments on the draft National Pollutant Discharge Elimination System ("NPDES") permit noticed for public comment by the North Carolina Department of Environmental Quality ("DEQ"), Division of Water Resources. In 2016 and 2017, we submitted comments on prior drafts of this permit, and the comments we submitted then remain applicable to this new draft, except as modified below. DEQ should not allow Duke Energy to dump unlimited amounts of coal ash pollutants into Hyco Lake and the other public waters at the Roxboro site, and should do more to protect against impingment and entrainment at Duke Energy's cooling water intakes. 1. DEQ Must Protect Public Waters. As explained in our 2016 and 2017 comments regarding previous drafts of this permit and our 2018 comments regarding Duke Energy's request to expand the boundaries of its coal ash lagoons, DEQ must protect tributary streams at Roxboro, and there is no justification for expanding the waste boundaries of the East and West Ash Basins, as DEQ is now proposing to do (as shown in the attachments to the draft permit, Fig. 1). Similarly, there is no justification for continuing to allow Duke Energy to use Sargents Creek and a bay of Hyco Lake as part of its wastewater treatment system. Sargents Creek is part of the same water system as Hyco Lake, and fish can swim freely from the main body of Hyco Lake into the bay referred to as the "heated water discharge pond." DEQ should regulate the discharges into these waterways as external outfalls. Charlottesville • Chapel Hill • Atlanta • Asheville • Birmingham • Charleston • Nashville • Richmond • Washington. DC 100% recycled paper In addition, while some waters impounded for waste treatment pursuant to Section 404 may be temporarily removed from the definition of waters of the United States, see, e.g., Ohio Valley Envd. Coal. v. Aracoma Coal Co., 556 F.3d 177, 215 (4th Cir. 2009), such waters may not be permanently removed from the Clean Water Act's protections. DEQ should clarify in the final permit that after the coal ash basins are closed and the plant is retired, these waterways will be recognized as protected waters of the United States under the Clean Water Act. 2. DEQ Must Strengthen the Pollution Limits in this Permit. The current draft permit contains virtually no pollution limits to protect Hyco Lake and its tributaries. DEQ has made the already -inadequate limits of the prior draft permits from 2016 and 2017 even weaker in the current draft permit. Hyco Lake is an important public resource that has been harmed over decades by the Roxboro plant's pollution, including fish consumption advisories and multiple fish kills due to selenium and other pollutants. Selenium concentrations of 3-8 µg/L are demonstrably toxic and lethal to fish according to EPA.' Yet this permit would allow unlimited amounts of selenium and many other pollutants from the coal ash basins to enter the main body of Hyco Lake. Recent sampling of the lake shows that coal ash pollution from the Roxboro coal ash site is continuing to have a significant impact: • Arsenic concentrations in surface water and fish tissue (largemouth bass) were higher in samples taken near the Roxboro plant compared with upstream samples. Arsenic concentrations in sediments near the Roxboro plant increased in 2018 compared to 2017. • Cadmium concentrations in sediments are higher near the Roxboro plant than upstream samples, and these concentrations increased in 2018 compared to 2017. • Copper concentrations in bluegill and largemouth bass were higher in 2018 than in previous years since 2013. • Mercury concentrations in sediments increased in 2018 compared to 2017. And mercury concentrations in bluegill were higher near the Roxboro plant than upstream. • Selenium concentrations in sediments near the Roxboro plant increased in 2018 compared to 2017. And selenium concentrations in fish samples are higher near the plant; bluegill samples in particular are "significantly greater" than upstream. See Duke Energy, Roxboro Steam Electric Plant 2017-18 Environmental Monitoring Report (Nov. 2019), at pp. 11-14 and Appendices, Attachment 1. ' EPA, ENVIRONMENTAL ASSESSMENT FOR THE EFFLUENT LIMITATIONS GUIDELINES AND STANDARDS FOR THE STEAM ELECTRIC POWER GENERATING POINT SOURCE CATEGORY, Docket No. EPA-821-R-15-006 (Sept. 2015), at 3-5 (available at https://www.epa.gov/sites/production/files/2015-10/documents/steam-electric-envir 10-20- 15.pdf. ) (hereinafter, ` ELG EA"). 2 Despite these documented impacts from the Roxboro plant, DEQ is proposing to issue a permit that would allow Duke Energy to discharge into the body of Hyco Lake with no limits at all for any of the above -listed pollutants. DEQ must strengthen the permit, as explained in our prior comments and as follows: a. Outfall 003 Outfall 003 is the only "external" outfall recognized in the permit; it is an opening between a bay of Hyco Lake and the main body of the lake, where discharges from Duke Energy's coal ash lagoons, FGD treatment system, contaminated groundwater flow, seeps, and unpermitted drains all flow out into the main body of Hyco Lake. Yet this outfall contains no limits at all for coal ash pollutants, including arsenic, mercury, selenium, and many others. DEQ must add protective limits for these pollutants for the pumping out of Duke Energy's highly -contaminated wastewater. All of the technology -based limits that apply to the "internal" outfalls at Roxboro should also apply at Outfall 003. Doing so is necessary to ensure that the main body of the lake is protected from Duke Energy's coal ash pollution with enforceable limits. The "internal" limits in this draft permit are not enough. The coal ash pollution at Roxboro flows into the bay of Hyco Lake upstream of Outfall 003 via multiple routes: surface water flows from permitted "internal" discharge points, chimney drains not authorized in this permit, and flows of contaminated groundwater. If Duke Energy is not discharging harmful amounts of coal ash pollutants via Outfall 003, it will be able to comply with these limits; but if not, they must be in place and enforceable by the public to ensure Duke Energy does not further contaminate Hyco Lake. DEQ should also add limits for arsenic, selenium, and mercury for the additional reason that DEQ has recognized a protective trigger is needed for the decanting and dewatering process. The effluent limitations for this outfall properly state that "If any one of the pollutants (As, Se, Hg) reaches 85% of the allowable level during the decanting/dewatering, the facility shall immediately discontinue discharge of the wastewater and report it ...." This requirement is an important safeguard against excessive pollution during decanting and dewatering. However, the permit contains no limits for any of the listed pollutants at this outfall. Reaching 85% of "the allowable level" is an impossibility —Duke Energy can discharge unlimited amounts of these pollutants under the current draft permit. Thus, protective limits must be added in order to make this important backstop effective. The lack of coal ash pollution limits is particularly glaring because compared to the prior drafts, the current draft would now allow Duke Energy to release unlimited amounts of thallium into the main body of Hyco Lake through Outfall 003. Thallium is a toxic pollutant, 40 C.F.R. § 401.15. According to the Agency for Toxic Substances and Disease Registry, exposure to thallium can cause vomiting, diarrhea; temporary hair loss; effects on the nervous system, lungs, heart, liver, and kidneys; and death.2 Animal data z https://www.atsdr.cdc.Gov/toxfMs/tfasp?id=308&tid=49 3 suggest that the male reproductive system may be susceptible to damage by even low levels of thallium.3 According to the Centers for Disease Control and Prevention, "thallium was used historically as a rodenticide, but has since been banned in the United States due to its toxicity from accidental exposure."4 The prior draft in 2017 imposed an average and daily maximum limit of 0.24 ug/L of thallium. This limit matches the U.S. EPA's National Recommended Water Quality Criteria (0.24 ug/L for thallium); these EPA criteria are published, peer -reviewed recommendations for states and tribes.5 But now, DEQ is proposing to eliminate that limit and instead allow unlimited thallium discharges into the main body of Hyco Lake. DEQ does not explain this change, but it appears to be based on a decision to use the federal maximum contaminant level of 2 ug/L as the basis for a water quality -based calculation of how much thallium Duke Energy could discharge into Hyco Lake before the entire waterbody of the lake exceeded this level. This approach is fatally flawed. First, DEQ is simply wrong to weaken effluent limits via a water -quality -based approach. The Clean Water Act requires that NPDES permits impose technology -based effluent limitations (TBELs) reflecting the "minimum level of control that must be imposed in a permit" for each pollutant and each wastestream being discharged from the ash ponds. 40 C.F.R. § 125.3(a). If TBELs have not been set by EPA, DEQ must set them on a case -by -case basis. See id. at § .122.44(a)(1). Water -quality -based standards may only be used where they are more stringent than the applicable technology -based standards. Id. § 122.44(d). However, DEQ's approach is the opposite. DEQ appears to be using water -quality -based standards as a weaker standard, undermining the Clean Water Act. DEQ's "reasonable potential analysis" is based on the idea that if a discharge will not cause the surface water of the lake to exceed water quality criteria —potentially rendering the entire lake unsafe or unusable —then the discharge is permitted. In other words, DEQ relies on the dilution of the entirety of Hyco Lake to allow Duke Energy to discharge as much pollution as it can without contaminating billions of gallons of public waters. But the requirements of the Clean Water Act prohibit this approach. Water -quality -based limits may be used only where they are more stringent than technology - based limits, not where they are less stringent. As to thallium in particular: DEQ acknowledges that it lacks "more substantive information" on the toxicology of thallium. Attachment 2 at 3. If full information is not available from EPA, and faced with the choice between a more -protective limit (as reflected in the prior draft permit) and a less -protective, unlimited approach (as reflected in the current permit), DEQ should choose the more protective option. In 2017, DEQ set the limit of 0.24 ug/L for thallium because the agency deemed it necessary to protect the public and Hyco Lake; replacing that limit with no limit at all while acknowledging a lack of definitive information is a serious mistake —all the more so for a substance that has been banned from rat poison because it is too toxic. 3 id. 4 https://www.cdc.gov/niosh/ershdb/emergencyresponsecard 29750026.html 5 See DWR Thallium Review, at 1 (Attachment 2). 4 The current draft also contains self-contradictory language regarding total residual chlorine (TRC). The effluent limit is set at a daily maximum of 28 ug/L. But Note 3 to these effluent limitations states that "[t]he Division shall consider all effluent TRC values reported below 50 ug/L to be in compliance with the permit." This makes no sense —the effluent limit is 28 ug/L, so discharges above that level violate the permit. DEQ cannot "consider" discharges of almost twice the effluent limit to be in compliance. DEQ should also add a protective limit for bromide discharges from Outfall 003. Bromide is naturally present in coal, and is highly soluble in water.6 EPA has concluded that once discharged from steam electric power plants, reaction by bromide with other constituents in water is cause for concern from a human health standpoint.7 The bromide ion in water can form brominated disinfection byproducts when drinking water plants use certain processes including chlorination and ozonation to disinfect the incoming source water for human consumption. According to EPA, some of these byproducts from chlorinated water are associated with human bladder cancer, and bromine -substituted disinfection byproducts (DBPs) "are generally thought to have higher risks of cancer and other adverse human health effects compared to DBPs containing chlorine instead of bromine..."8 Because bromides in surface waters can react with organic matter in the surface water to form disinfection byproducts at drinking water treatment plants downstream,9 monitoring and limits for bromides from the Roxboro facility are needed. This issue is especially urgent for the Roxboro permit because drinking water systems downstream of the Roxboro plant, such as Clarksville, VA10 (which withdraws water from Kerr Lake) and South Hill, VA11 (which withdraws water from Lake Gaston), have total trihalomethane levels above the federal maximum contaminant level. Yet DEQ is not even requiring Duke Energy to monitor bromide discharges from the Roxboro plant —when it should be enforcing protective limits. b. Outfa11001 In the previous draft permit, Duke Energy and DEQ proposed to shield all of its pollution of an unnamed tributary flowing to Hyco Lake by designating the stream as Outfall 001. Fortunately, DEQ has rejected that approach in the current draft permit. Instead, DEQ has located Outfall 001 partway along the rerouted stream flow from the ponded area adjacent to the East Ash Basin that Duke Energy refers to as the "Eastern Extension"; the proposed outfall is located where the rerouted flow from this area joins an unnamed tributary. However, there is still no justification for any "Outfall 001" discharge, since Duke Energy does not treat any wastewater that discharges in this location, and nothing about Duke Energy's operations at this location has changed since the prior permit, which did not contain this outfall. This outfall is 6ELGEAat3-11. ' See id. at 3-10. 8 id. 9 See id. at 3-11. 10 Town Of Clarksville 2018 Annual Drinking Water Quality Report, hops://www.clarksvilleva.or wp- content/uploads/2019/07/Town-of-Clarksville-Water-Quality-Report- .pdf, Attachment 3. " Town of South Hill 2018 Consumer Confidence Drinking Water Quality Report, hqs://www.southhillva.orWimaaes/documents/2018 CCR.pdf, Attachment 4. 5 simply a fictional addition to the permit to excuse Duke Energy's ongoing pollution of the waters upstream of this location. To make matters worse, DEQ is proposing to allow 340 ug/L of arsenic as a daily maximum discharge at this proposed Outfall 001. This is 34 times higher than the limits in the 2016 and 2017 draft permits, and 34 times higher than the state water quality standard for arsenic. There is no justification for this change. Moreover, this daily limit appears to be an error: the monthly average for this outfall is 10 ug/L, which would make DEQ's allowance of 340 ug/L on a single day a mathematical impossibility. DEQ should correct this mistake and return to the protective, technology -based limits of 10 ug/L for arsenic set in the prior draft permits as both the daily maximum and monthly average for this outfall. DEQ is also proposing to allow Duke Energy to discharge unlimited amounts of sulfates, an indicator pollutant for coal ash contamination and a serious risk in its own right. High concentrations of sulfates in drinking water can cause diarrhea; the U.S. EPA has established a secondary maximum contaminant level ("MCL") of 250 mg/L and a health -based advisory of 500 mg/L. The 2016 and 2017 draft permits contained monthly average and daily maximum sulfate limits of 250 mg/L; there is no valid reason to abandon those limits here. DEQ should also add limits for mercury, nickel, and lead. The effluent limitations for this outfall state that "If any one of the pollutants (As, Se, Hg, Ni, and Pb) reaches 85% of the allowable level during the decanting/dewatering, the facility shall immediately discontinue discharge of the wastewater and report it ...." This requirement is an important safeguard against excessive pollution during decanting and dewatering, yet the permit contains no limits for mercury, nickel, or lead at this outfall. These limits must be added to give effect to this provision. c. Outfall 002 DEQ is failing to protect public waters because the draft permit contains no limits for any coal ash pollutants from the ash basins, either during normal operations/decanting or dewatering. The most highly -contaminated wastewater from the bottom of the lagoon will be pumped out during these operations, and DEQ must put in place effluent limits that protect public waters, as it has done at other sites like Riverbend and Sutton. There are no limits at all for any of the key coal ash pollutants, including arsenic, mercury, selenium, and many others, at both this "internal" Outfall 002 and at Outfall 003 within the main body of Hyco Lake. DEQ must fix this fundamental flaw in the permit. n Moreover, DEQ has dramatically increased the decanting and dewatering rates allowed by this draft permit, without demonstrating that Duke Energy can do it safely. The decanting rate for pumping out the freestanding water in the Roxboro ash basins has been limited to one foot per week in the 2016 and 2017 draft permits, consistent with EPA's guidance to DEQ for avoiding rapid drawdown that can weaken earthen dams. DEQ previously concluded that a one - foot per week drawdown rate is necessary to "maintain the integrity of the dams" at Duke Energy's Sutton facility. However, the current draft permit would allow a decanting rate of one foot per day, without any dam safety justification. In addition, DEQ has doubled the dewatering rate for the most toxic wastewater saturating the ash in these basins. In 2016, the draft permit limited dewatering to 1 million gallons per day (MGD), but this draft would allow 2 MGD. These dramatically increased pumping flows are significant from a dam safety perspective, and also because the permit contains no limits for coal ash pollutants from the highly -polluted wastewater that will be pumped out of these coal ash basins, including arsenic and selenium. As we explained in our prior comments, DEQ must consistently apply the limits it has used in permits at other Duke Energy coal ash facilities (Riverbend and Sutton) to ensure that decanted and dewatered wastewater from the lagoons is properly treated. d. Outfall 006 DEQ is proposing to weaken the limits for coal pile runoff via Outfall 006 by removing the monthly average limits for the suspended solids, total selenium, and oil and grease. These limits provided an important check on Duke Energy's pollution. Now, the draft permit would simply allow Duke Energy to discharge the daily maximum amount of these pollutants every single day. This represents a dramatic increase in coal pollution. For example, the 2017 permit limited Duke Energy's selenium discharges to a monthly average of 5 ug/L. Now, that monthly average limit has been removed from the draft, so Duke Energy could discharge the daily maximum of 56 ug/L every day. That amounts to more than a tenfold increase in selenium pollution. Hyco Lake has suffered the effects of Duke Energy's selenium contamination for too long, and there is no justification for this dramatic increase in selenium and other pollutants from this outfall. At a minimum, all the monthly average limits from the 2017 draft should be restored. e. Outfalls 008, 009, 010, 012A and 012B DEQ has removed the pH limit for these outfalls, which include sewage wastewater from the plant, chemical metal cleaning wastes, and the flue gas desulphurization (FGD) system, and low -volume wastes from new settling basins. There is no justification for this change. The prior limit of 6 — 9 S.U. must be restored. 7 f. Outfall 008 Condition A.(7) for this outfall should be corrected to refer to Special Condition A.(22), rather than A.(23). g. Outfall 009 Condition A.(8) for this outfall defines a "discharge event" as being tied to "fly ash containing metal cleaning waste ... discharged into the ash pond." However, fly ash is handled dry at this facility and we understand that it is not discharged into the ash pond. The permit should be clarified to prohibit fly ash from being discharged into the ash pond. h. Outfalls 010 and O11 Duke Energy currently operates a biological treatment system for its FGD wastewaters, which discharges via Outfall 010. Yet the limits proposed by DEQ for this existing system at Outfall 010 would not go into effect until December 31, 2021. This makes no sense —the limits for the existing system should go into effect upon issuance of the permit. There is absolutely no reason to delay these limits, especially when draft permits for Roxboro have been proposed since 2016. Duke Energy has had many years to prepare to comply with FGD discharge limits, and there is no excuse for delaying compliance with limits on its existing treatment system. For the new FGD system discharge at Outfall 011, the Dec. 2021 compliance date is an improvement over the prior draft permit's 2023 compliance date. However, the fundamental problem remains that the limits for the new system are identical to those for the existing system, despite the fact that the new system is supposed to be an improvement. In addition, the mercury limits remain disproportionately high for the rural community around the Roxboro plant, in stark contrast to the limits DEQ put in place for permits in the Charlotte and Wilmington metropolitan areas. The Roxboro permit should be revised to match the mercury limits in place for the Riverbend and Sutton facilities. 3. The Draft Permit Does Not Comply with Cooling Water Intake Requirements. Section 316(b) of the Clean Water Act requires that cooling water intake structures at pollution sources like Roxboro use the "best technology available for minimizing adverse environmental impact." Id. § 1326(b). EPA implemented that Clean Water Act protection in 2014 by issuing the Cooling Water Intake Structure Rule. Final Regulations to Establish Requirements for Cooling Water Intake Structures at Existing Facilities and Amended Requirements at Phase I Facilities, 79 Fed. Reg. 48,300 (Aug. 15, 2014). For power plants taking in more than 125 million gallons of water every day —a threshold the Roxboro facility exceeds many times over —the rule requires utilities to submit additional information analyzing how much the cooling water intake structure harms fish and shellfish through entrainment and on reducing entrainment. 40 C.F.R. § 122.21(r)(7)-(13). 8 To protect against impingement, facilities must meet one of several options EPA has declared "best technology available," including modified traveling screens, flow velocity reductions, and operating a closed -cycle recirculating system. 40 C.F.R. § 125.94(c). For entrainment, permitting agencies must establish a site -specific standard. Id. § 125.94(d). a. The Draft Permit Would Allow Duke Energy to Unreasonably Delay Submitting Required Information First, there appears to be an error in the draft permit. Both the draft permit cover letter and the Fact Sheet state that the date for submission of the required information is May 31, 2022. Yet the text of the permit itself (Condition A.(25)) erroneously lists May 31, 2023 as the deadline. More fundamentally, DEQ must require Duke Energy to submit this required information more promptly. Duke Energy first proposed a schedule for submitting this information back in 2015.12 In the 2016 Fact Sheet, DEQ proposed to allow Duke Energy to delay submitting the required information until the next permit renewal. Now, four years after the 2016 draft permit, DEQ has abandoned that flawed approach, yet is still proposing to give Duke Energy an additional three years, until May 31, 2023 (or 2022), to submit the required information. DEQ should not reward Duke Energy's delay tactics by continually extending the deadline for these submissions. Duke Energy not only should have started these studies by now, but completed them. The Rule provided "advance notice to affected facilities about permit application materials and compliance schedules." See 79 Fed. Reg. 48,359. Duke Energy has known of its obligation to gather and submit this information since the Cooling Water Intake Study Rule issued in 2014. EPA calculated that facilities would need no more than 39 months to complete the studies and another 3 months to obtain peer review. For that reason, EPA stated in rulemaking that "July 14, 2018 reflects the date after which all permit application requirements must be submitted as specified at § 125.95." Id. DEQ's proposed drawn -out timeline violates the Clean Water Act. Facilities with permits expiring before July 14, 2018, may request an extension from permitting agencies that would allow them to submit the required information "as soon as practicable." 79 Fed. Reg. 48,358; see also 40 C.F.R. § 125.95(a)(2). But since this permit renewal has been extended well past July 2018, Duke Energy is not eligible for such an extension. And in any event, Duke Energy does not need, and cannot lawfully receive, eight years or more to submit information that should have taken less than four years to prepare and should have been submitted already. 12.Nathan Craig, Duke Energy, "Alternate Schedule Request" (Mar. 10, 2015), hilps:Hedocs.deg.nc.gov/WaterResources/DocView.aspx?id=482704&dbid=0&repo=WaterResources (Attachment 5). 9 b. DEQ Must Require Additional Measures to Reduce Impingement and Entrainment Duke Energy claims its cooling system at Roxboro is a "closed -cycle" recirculation system, but this draft and prior draft permits have recognized consistently that the cooling water discharge from Roxboro is "once -through." E.g., 2020 Supplement to Permit Cover Sheet (Heated Discharge Pond/Outfall 003); 2017 Fact Sheet at pp. 1-2; 2016 Fact Sheet at pp. 1-2. Moreover, Duke Energy itself did not identify Roxboro as closed -cycle in its 2015 submission to DEQ, supra n.10, in contrast to actual closed -cycle facilities like Mayo and Cliffside. Nonetheless DEQ has rubber-stamped Duke Energy's aging once -through system as a "closed -cycle recirculating system" and the best technology available for impingement. This designation is a charade. True closed -cycle systems reduce impingement and entrainment of fish and shellfish because they drastically reduce water intake in comparison to a once -through system, using up to 95 percent less water. 79 Fed. Reg. 48,342, 48,345. Accordingly, "[a] facility employing a closed -cycle recirculating system will typically reduce impingement by more than 95 percent." Id. at 48,345. The Roxboro cooling water intake structure, which is designed for an intake of 1,114 MGD and sucked in more than half a billion gallons of water per day as of 2018, provides no such benefits. Duke Energy's use of Hyco Lake, a water of the United States, as a cooling water source does not make its cooling water intake structure a closed -cycle system. The Rule allows some cooling ponds that are impounded waters of the United States to qualify as a closed -cycle system only if "the facility demonstrates to the satisfaction of the Director that make-up water withdrawals attributed specifically to the cooling portion of the cooling system have been minimized." 40 C.F.R. § 125.92(c)(2) (emphasis added). But Duke Energy cannot qualify for this provision here. Far from showing that Duke Energy claims minimizes its make-up water withdrawals, the company's submission, quoted in the draft permit Fact Sheet, states only that "the source of all makeup water is the approximately 300 square mile Hyco Lake watershed. No other sources of makeup water are currently available " Fact Sheet at 4. In other words, Duke Energy relies on the entire Hyco Lake watershed for cooling water —and crucially for this provision of the regulation, Duke Energy is not doing anything that minimizes the makeup water for the supposedly "closed -cycle" system it is claiming, which is in fact a water of the United States and is supplied by nothing less than the entire flow of the Hyco Lake watershed. Duke Energy also claims it minimizes its cooling water withdrawals from Hyco Lake, but this is not relevant for the regulatory designation Duke Energy is claiming, and in any event Duke Energy's justifications fail. It claims Units 1-3 have design features to increase their efficiency, yet admits that "Units 1 and 2 operate in a once -through cooling mode year round." Fact Sheet at 3. And "Unit 3 operates in a once -through cooling mode part of the year," but during the hotter months is routed to a cooling tower. Id. In other words, Duke Energy has the ability to operate using a cooling tower to avoid once -through cooling. If Duke Energy were 10 truly minimizing its withdrawals, it would use this cooling tower system to eliminate once - through cooling all year round. Duke Energy also makes the absurd claim that because it runs the Roxboro generating units at less than full capacity, it is somehow minimizing its water withdrawals. Fact Sheet at 4. Of course, the reduced operation of the Roxboro generating units is based on completely unrelated factors, such as the price of natural gas, that have nothing to do with conserving water. The question is not how often Duke Energy runs the generating units, but rather whether it could run them the same amount while using less water. At Roxboro, Duke Energy plainly could do so, but chooses not to. DEQ cannot allow Duke Energy to paint its aging system as the "best technology available." Rather, it must require Duke Energy to comply with the impingement standard with another, actually effective, control technology. In addition to impingement, Duke Energy must also protect against entrainment. To that end, DEQ must determine on a site -specific basis what is the best technology available to minimize entrainment at Roxboro. 40 C.F.R. § 125.94(d). But DEQ has erroneously left out any protections, interim or final, against entrainment. The rule allowed interim requirements prior to July 2018. But for this permit in 2020, DEQ must go beyond interim requirements and include final impingement and entrainment protections in each permit. 40 C.F.R. § 125.98(b)(2). The rule is clear: if issued after July 14, 2018, "the permit must include conditions to implement and ensure compliance with the impingement mortality standard at § 125.94(c) and the entrainment standard at § 125.94(d)." Id. (emphasis added). A true closed -cycle system relying on cooling towers would reduce water intake —and, correspondingly, entrainment —by up to 95 percent. This technology is not new and has in fact been available for decades. Other measures that would improve the situation include finer mesh screens, limited velocity intakes, and fish recovery and return systems. Duke Energy uses these measures at other sites, such as the Dan River makeup intake at Belews Creek, and should be required to implement additional protections at Roxboro. Sincerely, k1�nD � Nicholas S. Torrey Senior Attorney 11 RECEIVED ATTACHMENT 1 FEB 26 2020 NCDEQ/DWR/NPDES ROXBORO STEAM ELECTRIC PLANT 2017-2018 ENVIRONMENTAL MONITORING REPORT November 2019 Water Resources DUKE ENERGY Raleigh, North Carolina Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report. Preface This copy of the report is not a controlled document as detailed in the Environmental Services Biology Program Quality Assurance Manual. Any changes made to the original of this report subsequent to the date of issuance can be obtained from: Water Resources DUKE ENERGY 410 South Wilmington Street Raleigh, North Carolina 27601 Duke Energy Progress i Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table of Contents Pa9c Preface......................................................................................................................................... i Listof Tables............................................................................................................................... iii Listof Figures.............................................................................................................................. iii Listof Appendices....................................................................................................................... iii Metric -English Conversion and Units of Measure...................................................................... v Water Chemistry Abbreviations.................................................................................................. v ExecutiveSummary..................................................................................................................... vi 2017-2018 Environmental Monitoring Report............................................................................ 1 HistoricalOverview............................................................................................................... 1 Reservoir Description............................................................................................................ 3 Objectivesand Methods........................................................................................................ 3 Environmental Monitoring Results for 2017-2018................................................................ 9 Limnology........................................................................................................................ 9 Temperature and Dissolved Oxygen......................................................................... 9 Water Clarity Constituents........................................................................................ 10 Nutrients and Phytoplankton Biomass....................................................................... 10 Ions, Hardness, and Specific Conductance................................................................ 10 Alkalinityand pH...................................................................................................... 11 TraceElements................................................................................................................ 11 Arsenic....................................................................................................................... 11 Cadmium.................................................................................................................... 12 Copper.................................................................................................... I................... 12 Manganese................................................................................................................. 13 Mercury...................................................................................................................... 13 Selenium.................................................................................................................... 14 Thallium..................................................................................................................... 14 Fisheries........................................................................................................................... 15 Fish Species Composition.......................................................................................... 15 Fish Abundance, Distribution, and Size Structure..................................................... 15 Balanced Indigenous Community.............................................................................. 18 FishCommunity Health............................................................................................. 19 BiofoulingMonitoring..................................................................................................... 19 Summary and Conclusions.......................................................................................................... 19 References.................................................................................................................................... 20 Duke Energy Progress ii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report List of Tables Table Page 1 Hyco Reservoir environmental monitoring program ............................................... 6 2 Field sampling and laboratory methods utilized in the Hyco Reservoir environmental monitoring program......................................................................... 7 3 Statistical analyses performed on data collected for the Hyco Reservoir environmental monitoring program......................................................................... 8 List of Figures Fi ug_re Page 1 Hyco Reservoir sampling locations......................................................................... 5 List of Appendices Appendix Page 1 Depth profiles of water temperature, dissolved oxygen, pH, and specific conductance at Hyco Reservoir during 2017........................................................... 22 2 Depth profiles of water temperature, dissolved oxygen, pH, and specific conductance at Hyco Reservoir during 2018........................................................... 24 3 Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2017....................................................... 26 4 Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2018....................................................... 27 5 Concentrations of chemical variables in surface waters of Hyco Reservoir during 2017.................................................................................... ? 8 6 Concentrations of chemical variables in surface waters of Hyco Reservoir during 2018.................................................................................... 31 7 Long-term trends of selected parameters at Station B2 from Hyco Reservoir from2009 through 2018.......................................................................................... 34 8 Long-term trends of selected parameters at Station C2 from Hyco Reservoir from 2009 through 2018............................................................ Duke Energy Progress iii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 9 Long-term trends of selected parameters at Station D2 from Hyco Reservoir from 2009 through 2018.................................................................................. 10 Long-term trends of selected parameters at Station F2 from Hyco Reservoir from 2009 through 2018.......................................................................................... 11 Means and standard errors of trace element concentrations in sediments and fish by transect from Hyco Reservoir during 2017......................................... 12 Means and standard errors of trace element concentrations in sediments and fish by transect from Hyco Reservoir during 2018......................................... 13 Long-term trends of selenium concentrations in Bluegill, Largemouth Bass, and White Catfish muscle tissues at Transect C and Transect D from Hyco Reservoir from 2009 through 2018.............................................................. 14 15 16 17 18 19 20 21 22 23 24 Total number and weight of fish collected with electrofishing from Hyco Reservoir during 2017 and 2018............................................................................. Mean catch per hour of fish collected with electrofishing by transect from Hyco Reservoir during 2017............................................................................................. Mean catch per hour of fish collected with electrofishing by transect from Hyco Reservoirduring 2018............................................................................................. Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2017 ............................. Length -frequency distributions of Bluegill by transect collected by electrofishing from Hyco Reservoir during 2018 ............................. Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2017............................................ Length -frequency distributions of Largemouth Bass by transect collected by electrofishing from Hyco Reservoir during 2018............................................ Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2017...................................... Length -frequency distributions of Gizzard Shad by transect collected by electrofishing from Hyco Reservoir during 2018...................................... 36 37 38 39 40 41 42 43 44 45 46 47 48 Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2017 ............................... 50 Relative weight values versus length for Bluegill, Gizzard Shad, and Largemouth Bass collected by electrofishing from Hyco Reservoir during 2018 ............................... 51 Duke Energy Progress iv Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 Proportional Size Distribution ranges for balanced populations of Bluegill versus Largemouth Bass and Gizzard Shad versus Largemouth Bass collected from Hyco Reservoir during 2017 and 2018.................................................................... 52 Duke Energy Progress v Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Metric -English Conversion and Units of Measure Length 1 micron (µm) = 4.0 x 10' inch 1 millimeter (mm) = 1000 µm = 0.04 inch 1 centimeter (cm) = 10 mm = 0.4 inch 1 meter (m) = 100 cm = 3.28 feet 1 kilometer (km) = 1000 m = 0.62 mile Area 1 square meter (m2) = 10.76 square feet 1 hectare (ha) = 10,000 m2 = 2.47 acres Volume 1 milliliter (ml) = 0.034 fluid ounce 1 liter = 1000 m1= 0.26 gallon 1 cubic meter = 35.3 cubic feet Weight 1 microgram (µg) = 10"3 mg or 10-6 g = 3.5 x 10-8 ounce 1 milligram (mg) = 3.5 x 10"5 ounce 1 gram (g) = 1000 mg = 0.035 ounce 1 kilogram (kg) = 1000 g = 2.2 pounds 1 metric ton = 1000 kg = 1.1 tons 1 kg/hectare = 0.89 pound/acre Temperature Degrees Celsius (°C) = 5/9 (°F-32) Specific Conductance µS/cm = Microsiemens/centimeter Turbidity NTU = Nephelometric Turbidity Unit Water Chemistry Abbreviations Cl- - Chloride TDS - Total dissolved solids Al - Total aluminum SO2-4 - Sulfate TSS - Total suspended solids As - Total arsenic Ca221 - Total calcium TOC - Total organic carbon Cd - Total cadmium Mg" - Total magnesium TP - Total phosphorus Cu - Total copper Na' - Total sodium TN - - Total nitrogen Hg - Total mercury TS - Total solids NH3-N - Ammonia nitrogen Se - Total selenium NO3+ NO2-N - Nitrate +nitrite - nitrogen Duke Energy Progress A Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Executive Summary During 2017 and 2018, surface water temperatures, dissolved oxygen concentrations, pH, specific conductance, and Secchi disk visibility remained within the ranges previously observed in Hyco Reservoir depending on location. A number of limnological variables measured in the reservoir surface waters including calcium, chloride, hardness, total dissolved solids, and specific conductance have stabilized (i.e., trend not increasing) compared to previous years despite some seasonal variation during 2017 and 2018, primarily due to lower power plant dispatch rates and operation of the Flue Gas Desulfurization System. Concentrations of target trace elements, including arsenic, cadmium, copper, mercury, and selenium, measured in the reservoir surface waters remained below water quality criteria during 2017 and 2018. However, selenium concentrations in the muscle tissues of Bluegill, White Catfish, and Largemouth Bass continued to be statistically greater at the monitoring location near the discharge compared to the concentrations at the designated upstream comparison monitoring location during 2017. In 2018, only White Catfish had statistically greater selenium concentrations in muscle tissues at the monitoring location near the discharge compared to the concentrations in the fish located at the upstream monitoring location. Despite receiving a thermal discharge, the fish community in Hyco Reservoir remained a self- sustaining, balanced population of regionally common species during 2017 and 2018. Duke Energy Progress vii Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Historical Overview Duke Energy Progress (DEP; formerly Carolina Power & Light) began construction of Hyco Reservoir in 1963 to serve as a cooling water source and receiving water discharges from the Roxboro Steam Electric Plant (Roxboro Plant). After reaching full pool in 1965, the reservoir was noted as a popular fishery throughout the remainder of the 1960s and most of the 1970s. In 1980, a large-scale fish kill was observed throughout much of the reservoir after the start-up of Unit 4. Biological monitoring conducted by Company biologists showed continued declines in the fishery. Special experimental bioassay studies were conducted and ultimately determined that elevated concentrations of selenium in the water, food chain, and fish tissues were responsible (i.e., reproductive impairment) for the observed sport fishery decline in Hyco Reservoir. As a result of elevated selenium concentrations in fish, the North Carolina Division of Health Services, Department of Health and Human Services, issued an advisory in August 1988 recommending limitations on human consumption of all fish species from Hyco Reservoir. In 1989, DEP completed the constructed a dry ash handling system to reduce selenium input into Hyco Reservoir. After the startup of the dry ash handling system in late 1989, biological monitoring studies conducted under the Roxboro Plant National Pollutant Discharge Elimination System (NPDES) permit demonstrated the effectiveness of the dry fly ash handling system in limiting the amount of selenium entering the reservoir (CP&L 1991 and 2001, PEC 2008). Selenium concentrations quickly decreased in the reservoir after the dry fly ash handling system began operation and have remained below the North Carolina water quality standard of 5µg/liter since 1990. Changes in the aquatic community also reflected the reduced selenium loading into the reservoir. A gradual shift from selenium -tolerant fish species to species more typical of southeastern piedmont impoundments was observed following the commencement of dry ash handling operations. The fish consumption advisory was modified several times during the recovery period to remove species from the consumption advisory list as selenium concentrations in the edible flesh of each individual fish species declined below the established threshold level (i.e., 25 µg/g dry weight at the time; it was revised to 50 µg/g dry weight in the mid-2000s). In August 2001, the fish consumption advisory on reservoir was completely rescinded. Hyco Reservoir limnological variables remained mostly unchanged during the period from 2002 through 2006 and were within the range of values expected for a North Duke Energy Progress 1 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Carolina piedmont impoundment. During 2007, the reservoir was subjected to the most extensive drought on record (based on 110-year USGS streamflow records) in North Carolina, which affected water levels severely. The water levels decreased from full pool of 124.9 meters National Geodetic Vertical Datum (NGVD) during May 2007 to slightly above the critical elevation of 123.4 meters NGVD in October 2007 when a substantial rain event reversed the decreasing trend in reservoir water levels. The drought event and subsequent decrease in lake level was important given that impacts to plant operations begin to occur when reservoir levels reach 123.4 meters NGDV. Despite minimal flushing of the reservoir through most of 2007, no overall changes to limnological variables, including selenium concentrations, were noted that year compared to previous years following dry fly ash operations. However, an increase in the mean selenium concentrations was observed in muscle tissues of fish collected near the power plant discharge to Hyco Reservoir. While no increase in selenium mass loading to Hyco Reservoir occurred during this period due to plant operations, decreased reservoir flushing likely allowed more selenium to enter the food web and thus influenced tissue concentrations in fish and other trophic level species. With the passage of the North Carolina Clean Smokestacks Act of 2002, coal-fired power plants were required to reduce sulfur emissions 73 percent by 2013. To help meet the requirement fleet -wide, Flue Gas Desulfurization (FGD) systems (one on each of the four units) were installed at the Roxboro Plant and wastewater from these treatment systems began discharging in February of 2008. During the period from 2008 until 2016, a number of limnological constituents including calcium, chloride, hardness, and total dissolved solids gradually increased throughout the reservoir until recently. However, trace elements such as arsenic, copper, and selenium in surface waters have continued to remain below water quality criteria and/or below the laboratory reporting limits. Beginning in 2014 with the lower cost of natural gas, the Roxboro Plant annual dispatch rates decreased from the historical 70%-75% range to an average rate of 60% in 2014, 43% in 2015, and even lower dispatch rates through 2018. The lower dispatch rates for the Roxboro Plant have resulted in reduced discharges of constituents from the FGD systems as well as lower overall thermal discharge to the reservoir. With the reduce thermal loading to the reservoir, impacts to the two non-native tilapia species, Blue Tilapia and Redbelly Tilapia, have become apparent with reduce catch of these species during fisheries sampling. Tilapia can help control certain vegetation such as naiad and pondweed It is possible that the reservoir will experience nuisance aquatic vegetation problems as the growth control of these plant species declines along with the tilapia. Duke Energy Progress 2 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Reservoir Description Hyco Reservoir, an impoundment of the Hyco River, is located approximately 5 km south of the North Carolina/Virginia border in Person and Caswell Counties in the northern Piedmont of North Carolina. After impoundment, the reservoir water level reached full pool elevation in 1965. Hyco Reservoir serves as a cooling lake and source of water for the Roxboro Plant. The reservoir has a surface area of 17.6 km2 (1760 ha); a volume of 9.62 x 107 m3; a drainage area of 471 km2; a mean depth of 6.1 in; a normal elevation of 125.1 in NGVD; an average inflow of 5.7 m3/second; and a mean residence time of approximately 6 months. The land use along the 256-km shoreline is primarily residential and secondarily industrial/agricultural. It is classified by the North Carolina Division of Resource as WS-V, B. This is defined as suitable for primary recreation, aquatic life propagation and maintenance, wildlife, and agriculture and is suitable for water supply for use by industry to supply to their employees, but not to municipalities or counties with a raw drinking water supply source. For environmental monitoring purposes, sampling transects and stations throughout the reservoir were selected based on their location relative to the power plant effluents entering the main body of the reservoir at Transect 4 (Figure 1). Transect B is located in the upper reservoir in the North Hyco arm and Transects C and SHHW 1 are located in the upper reservoir in South Hyco arm. Transect F is located in the lower reservoir adjacent to the spillway. Objectives and Methods The primary objective of the Roxboro Plant 2017-2018 environmental monitoring program was to provide an assessment of the effect of power plant operations on the water and aquatic organisms of Hyco Reservoir. Secondary objectives of the program were to document environmental factors impacting the aquatic community that were .not attributable to the power plant, as well as the impact of non-native aquatic plant and animal species on the reservoir. These objectives were consistent with the biological monitoring requirements in the NPDES Permit NC0003425. Limnology (water quality, water chemistry, and chlorophyll a) and trace elements in fish tissues and sediments (Transects C and D only) were assessed in the reservoir (Figure 1; Tables 1 and 2), and the results were analyzed using appropriate statistical methods (Table 3). The water chemistry analysis portion of the limnological variables was performed by laboratories certified by the North Carolina Department of Environmental Quality (NCDEQ) in water and wastewater testing. Trace element analyses of sediment and tissues of fish were conducted by an external laboratory using approved analytical Duke Energy Progress 3 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitorinci Report methods (EPA methods 6020 and 7471). The accuracy and precision of laboratory analyses of water chemistry and trace element data were determined with analytical standards, sample replicates, and reference materials. For calculation of means in this report, concentrations less than the reporting limit and not estimated were assumed to be at one-half the reporting limit. Duke Energy Progress 4 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report A B+ 2 C reek North Hyco River 0 0.5 1 2 Miles ® A 1 C Person -Caswell Lake Authority South Hyco River Afterbay Cane Creek Reservoir Spillway i 9 111 E C. ♦ 6 A ~►► B A (Outfall #006) Auxiliary Intake, Main Dam Discharge is (Outfall #003) . ♦__ Intake Canal 4 Gypsum Storage Pad E q C � BDry A Ash r i Landfill / *--Flush / Pond Gypsum s Settling Ash Pond ; Pond Bioreactor N 3 A--* B V C SHHW� 0 0.75 1.5 3 Kilometers Figure 1. Hyco Reservoir sampling locations. Duke Energy Progress 5 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 1. Hyco Reservoir environmental monitoring program. Program Frequency Location Water quality Alternate calendar months (February, April, June, August, October, December) Water chemistry Alternate calendar months (including trace (February, April, June, August, October, elements in water) December) Phytoplankton+ Alternate calendar months (February, April, June, August, October, December) Chlorophyll a Alternate calendar months (February, April, June, August, October, December) Zebra and quagga Alternate calendar months mussels (February, April, June, August, October, December) Electrofishing Once every three calendar months (March, June, September, December) Trace elements Once per calendar year (fish & sediments) Stations B2, C2, D2, F2, SHHW1 (surface to bottom at 1-m intervals) Stations B2, C2, D2, F2, SHHW 1 (surface) Stations B2, C2, D2, F2 Stations B2, C2, D2, F2 Main intake structure or water quality station buoys Stations Al, A3, B1, B3, C1, C3, Dl, D5, Fl, F3 Transects C and D +Phytoplankton samples were collected and preserved but were not identified because all chlorophyll a concentrations measured during 2017 and 2018 were less than 40 mg/L. Duke Energy Progress 6 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 2. Field sampling and laboratory methods utilized in the Hyco Reservoir environmental monitoring program. Method Water quality Temperature, dissolved oxygen, pH, and specific conductance were measured with calibrated multiparameter instruments. Measurements were taken from the surface to the bottom at 1-m intervals in accordance with procedure NR-00096 Water clarity was measured with a Secchi disk. Turbidity was measured with a HACH model 2100Q turbidimeter in accordance with procedure WR-00070. Water Surface samples were collected either directly or with a nonmetallic sampler, chemistry transferred to appropriate containers, transported to the laboratory on ice, and analyzed according to USEPA (1979) and APHA 2012. Phytoplankton Samples were collected by two methods. Method one used equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth collected with a Van Dorn beta sampler and mixed in a plastic container. Method two used an integrated depth sampler to collect representative photic zone composite samples from the surface to twice Secchi disk transparency depth. The samples were placed in dark bottles, and transported to the laboratory on ice. Chlorophyll a Samples were collected by two methods. Method one used equal amounts of water from the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth collected with a Van Dorn beta sampler and mixed in a plastic container. Method two used an integrated depth sampler to collect representative photic zone composite samples from the surface to twice Secchi disk transparency depth. The samples were placed in 1000 mL dark bottles and transported to the laboratory on ice. In the laboratory, 250-mL subsamples were analyzed (NR-00103). Electrofishing Fifteen -minute samples were collected at each station using a Smith -Root Type 7.5 gpp equipped, Wisconsin -design electrofishing boat with pulsed DC current. Fish were identified, measured to nearest mm, weighed to nearest gram, examined for presence of disease and deformities, and released based NR-00080, Rev 1. Trace elements Water, sediments, and muscle tissue of selected fish were analyzed by standard analytical techniques in the laboratory for selected trace metals and metalloids. All media, except water, were homogenized and freeze-dried. All samples were analyzed by an external laboratory using EPA methods 6020 and 7471. Quality control was achieved by analytical standards, replicates, and certified reference materials Mussel surveys Hardened structures such as docks and buoys were visually inspected for the presence of zebra mussels and quagga mussels during routine water quality monitoring. Duke Energy Progress 7 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Table 3. Statistical analyses performed on data collected for the Hyco Reservoir environmental monitoring program. Program Variable Statistical test(s)/model(s)+ Main effect(s) Water quality Water temperature, specific conductance, Secchi disk transparency depth, and selected chemical variables Water chemistry Selected chemical variables Phytoplankton Chlorophyll a Trace elements Al, As, Cd, Cu, Hg, Se (water) As, Cd, Cu, Hg, Se (sediment and fish) ANOVA, block on month Station ANOVA, block on month Station ANOVA, block on month Station ANOVA, block on month Station ANOVA Transect 'Parametric and non -parametric (rank) one-way Analysis of Variance (ANOVA) statistical models were used. A Type I error rate of 5% (a = 0.05) was used to judge the significance of all tests. Fisher's protected least significant difference (LSD) test was applied to determine where differences in means occurred for significant ANOVA models. Duke Energy Progress 8 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Environmental Monitoring Results for 2017-2018 Limnology Temperature and Dissolved Oxysen • Thermal stratification, defined by changes of at least 2°C per meter of water depth, in Hyco Reservoir was influenced by several factors during 2017 and 2018, including proximity to the plant discharge, variable thermal loading from power plant discharges, summertime use of the auxiliary intake system, and natural ambient conditions and streamflow (Appendices 1 and 2). In Southeastern reservoirs, typically, a pronounced clinograde isotherm (thermocline) is observed throughout hotter months. However, this pronounced thermal stratification pattern was not observed in Hyco Reservoir during 2017 and 2018, in keeping with historical observations. In 2017, no thermal stratification was present in the reservoir during February, August, and December while only weak thermal stratification was observed during April, June, and October. Similarly, during 2018, no thermal stratification was observed during February and October and again, only weak thermal stratification was observed during April, June, August and December. Surface water temperatures at Station D2 near the thermal discharge ranged from 11.3°C in February to 30.6°C in October 2017 (Appendix 3). In 2018, Station D2 ranged from 11.8 in February to 31.8 in August (Appendix 4). The coolest surface water temperature in the reservoir during 2017 was 8.5°C in February at Station SHHW 1 and 8.0 during February at Station C2 during 2018. • The annual mean surface temperature at Station D2 was 23.4°C in 2017 and 22.6 in 2018 (Appendices 3 and 4). There were no significant differences in the annual mean surface temperatures among all sampling stations either year, which is a departure from historical temperature patterns in the reservoir. It is likely that lower power plant dispatch rates each year resulted in the similarities of mean temperature measures throughout each year. • All surface water dissolved oxygen concentrations were greater than 5 mg/L throughout Hyco Reservoir during both 2017 and 2018 monitoring events (Appendices 1 and 2). Oxygen depletion below 1 mg/L was observed in only the deeper hypolimnetic waters (typically below approximately 5 meters) of the reservoir during June and October of 2017 and June, August, and October of 2018. This phenomenon usually occurs within monomictic reservoirs of the southeastern United States. However, Hyco Reservoir does not exhibit strong oxygen depletion as with other reservoirs of the southeast due to the use of an auxiliary intake for withdrawal of hypolimnetic cooling water by the Roxboro Plant. Duke Energy Progress 9 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Water Clarity Constituents • Secchi disk transparency was similar among all stations in Hyco Reservoir during 2017 (Appendix 3), however, minor statistical differences among the stations were noted during 2018 (Appendix 4). Hyco Reservoir was moderately clear both years with Secchi disk visibility greater than one meter on average except for the extreme upstream Station SHHW L Mean turbidity values, a related measure of clarity, were also statistically similar among the reservoir stations during both 2017 and 2018. The 2017-2018 turbidity ranges were within ranges observed in previous years (DEP 2017). Nutrients and Phytoplankton Biomass • All aqueous nitrogen constituents during 2017-2018 including annual mean total ammonia, total nitrogen, nitrite -nitrate nitrogen, and total kjeldahl nitrogen concentrations were similar among the stations and varied by relatively small amounts (Appendices 3 and 4). These minor variations of nutrient concentrations among the stations were not considered to be important to the trophic status of the reservoir. Total phosphorus was also similar among the stations during 2017, however, varied statistically during 2018 among the stations throughout the reservoir total organic carbon (TOC) concentrations were low and consistent throughout the reservoir. Taken altogether, the nutrients and TOC reflect the moderate trophic status of Hyco Reservoir (NCDEQ 2015). • The annual mean chlorophyll a (a measure of phytoplankton biomass) concentration at Station D2 was statistically less than the concentrations at Stations B2, C2, and F2 during 2017 (Appendix 3). During 2018, the annual mean chlorophyll a measurement at Station C2 statistically greater than that at Station F2 but was similar to the mean concentrations at the remaining locations (Appendix 4). Chlorophyll a was not measured at SHHW 1 as part of the monitoring plans. All chlorophyll a measurements in Hyco Reservoir during 2017-2018 were below the North Carolina water quality standard of 40 µg/L (15A NCAC 0213.0211, June 2019). Ions, Hardness, Total Dissolved Solids, and Specific Conductance • The annual mean concentrations of most of the major ions, specific conductance (magnitude), total dissolved solids, and total hardness varied statistically among sampling stations during 2017 and 2018 (Appendices 3 and 4). These constituents generally followed a decreasing pattern in concentration with the following order D2—F2>B2>3C2>SHHW1. The concentration and magnitude pattern has been typically observed since the FGD operations commenced in 2008. Over a 10-year period from 2009-2018, fluctuations in concentration of select constituents observed throughout the reservoir reflected various influencing hydrodynamic processes (i.e., inflow, vertical circulation, turnover) and the inconsistent dispatching (i.e., discharge mass) of the Roxboro Plant (Appendices 5-10). Duke Energy Progress 10 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Alkalinity and PH • The annual mean total alkalinity concentrations during 2017 were similar among all the stations on Hyco Reservoir with overlapping concentration ranges (Appendix 3). Individual values ranged from 17 to 38 mg/L in surface waters with the greatest measured value at Station SHHW 1. During 2018, the total alkalinity concentrations varied statistically among the stations but these variations were considered to be minor and of no biological importance (Appendix 4). The individual values ranged from 23 to 37 mg/L during 2018. Waters less than 40 mg/L are considered to be soft waters (unrelated to hardness) for biological purposes in terms of productivity (Boyd 1979). These alkalinity concentrations coincide with the moderate trophic status of Hyco Reservoir. • Hyco Reservoir generally exhibited annual median pH values slightly above neutral in most cases with circumneutral ranges within approximately one pH unit of neutral throughout the reservoir longitudinally and vertically during both 2017 and 2018 (Appendices 1-4). While no statistical evaluations of pH for 2017 and 2018 were run, which would be inappropriate for log scale data, annual median values both years were tightly grouped within a few tenths decimal fractions of each other at the stations. Individual surface water pH values ranged from 6.8 at Station SHHW 1 to 8.9 at Station C2 during 2017 and 7.0 at both Stations F2 and SHHW 1 to 8.7 at Station C2 during 2018. Deeper waters of the reservoir generally displayed slightly decreasing pH values from surface waters to bottom waters, reflecting different biological and limnological processes with depth. Trace Elements Arsenic • Annual mean total arsenic concentrations at Station D2 and F2 were statistically greater compared to the concentrations at the upper reservoir Station SHHW1 during 2017 (Appendix 3). Stations B2 and C2 annual mean concentrations were intermediate and statistically similar to all other stations throughout the reservoir. During 2018, a similar pattern was observed with the annual means at D2 and F2 being greatest in concentration among the stations (Appendix 4). While the lower reservoir total arsenic concentrations had slightly elevated concentrations during both years due to the Roxboro Plant FGD operations, all of the arsenic values measured in surface waters at all stations were well below the North Carolina surface water quality 02B standard for human health (10 µg/L; fish consumption). Long-term (10-year) trends of arsenic concentrations from 2009-2018 at all stations exhibited small seasonal fluctuations in concentrations. Duke Energy Progress 11 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • The 2017 annual mean arsenic concentration in the sediments at Transect D near the Roxboro Plant discharge was within concentration range considered to be background (3-13µg/g dry weight) but the 2018 annual mean concentration was elevated slightly above the .background concentration range (Forstner and Wittmann 1981; Salomons and Forstner 1984; and Martin and Hartman 1984) (Appendices 11 and 12). At Transect C during 2017, the annual mean arsenic concentration of 6.2 µg/g was below the Laboratory Reporting Limit (LRL) for that year. In 2018, the annual mean arsenic concentration from samples collected at Transect C was 5.0 µg/g, again within the range of background concentrations. Comparing the 2018 sediment concentrations by location showed significant statistical differences. This pattern of arsenic in sediments continues that observed historically in the reservoir (DEP 2017). • The annual mean arsenic concentration in Largemouth Bass at Transect D was statistically greater compared to the Transect C mean concentration during 2017 (Appendix 11). However, these mean values were only a decimal fraction different when compared, and, when converted to wet weight values they were below the EPA recreational fisherman screening level (i.e., 1.2 µg/g wet weight) for human consumption (NCDENR 2013). Mean concentrations in White Catfish and Bluegill were mostly below the LRL during 2017. Similarly, in 2018 only Largemouth Bass annual mean arsenic concentrations were statistically different between Transect C and D (Appendix 12). The mean arsenic values were almost identical at both transects when comparing 2017 and 2018 results for the three fish species sampled, indicating a consistent concentration pattern. Again, the arsenic values in 2018 were below the EPA recreational fisherman screening level. Cadmium • Annual mean cadmium concentrations in sediments and fish tissues at Transect C and D during 2017 were all below the LRL (Appendix 11). In 2018, only sediments measurements for cadmium were above the LRL (Appendix 12). The annual mean concentration at Transect D near the Roxboro Plant discharge location was statistically greater than the mean concentration upstream at Transect C. Copper • The annual mean total copper concentrations in Hyco Reservoir surface waters were statistically similar among all stations during both 2017 and 2018 (Appendices 3-9). The values were mostly below 2.0 µg/L throughout the reservoir. Duke Energy Progress 12 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • The annual mean copper concentration in sediment near the power plant discharge (Transect D) was statistically similar to the mean copper concentration at Transect C (South Hyco Creek arm) during both 2017 and 2018 (Appendices 11 and 12). • Copper concentrations in Bluegill, White Catfish, and Largemouth Bass muscle tissues during 2017 were comparable to those in recent years (DEP 2013, 2014, 2016, and 2017), however, the concentrations measured in Bluegill muscle at Transect D and Largemouth Bass at both Transect C and D were unexpectedly moderately elevated when compared to those same past years (Appendices 12 and 13). Copper levels in water and sediments at the two locations during 2018 did not suggest a cause for the observed elevated copper in fish tissues. Even so, the copper concentrations measured in the fish tissues were not elevated to the point of being biologically important. Manganese • Annual mean total manganese concentrations in surface waters of Hyco Reservoir were statistically similar among all reservoir stations during 2017 but varied statistically during 2018 (Appendices 2-6). Manganese concentrations ranged widely in the reservoir during both years with the greatest concentrations observed in surface waters at Station D2 during December of 2017 and Station SHHW 1 during August of 2018. These observations reflect biogeochemical processes governing manganese that are variable from year to year and are unrelated to power plant operations. Mercury • The annual mean total mercury concentrations in surface waters were statistically similar among all stations during both 2017 and 2018 (Appendices 3 and 4). Also, all of the individual total mercury concentrations measured each year throughout the reservoir were below the North Carolina 15A NCAC 02B water quality standard of 12 ng/L. • Annual mean mercury concentrations in sediments at Transects C and D were less than the LRL of 3.6 µg/g during 2017 (Appendix 11). In 2018, a change in the laboratory methodology for mercury in sediments led to valid measurements below 1 µg/g. The mean values were statistically greater at Transect D compared to transect C during 2018 (Appendix 12). However, mean concentrations measured at both locations were very low and were not considered to be biologically important. • Annual mean mercury concentrations in Bluegill muscle tissues were statistically different between Transect C and Transect D during 2017 and 2018 (Appendices 11 and 12). The mean mercury Duke Energy Progress 1 13 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report concentrations in White Catfish and Largemouth Bass were similar between the two locations each year. Converting the mercury measurements to fresh weight concentrations resulted in all annual mean and individual measured mercury concentrations in muscle tissues during 2017 and 2018 being below the North Carolina Health Director's screening value of 0.4 µg/g fresh weight and the EPA's water quality criterion for methylmercury in fish tissues of 0.3 µg/g fresh weight (NCDENR 2013). Selenium • During both 2017 and 2018, the annual mean total selenium concentrations in surface waters of Hyco Reservoir were statistically similar among all stations, continuing a finding observed in 2016 (DEP 2017) (Appendices 3 and 4). Further, all annual mean selenium concentrations were below 1 µg/L reservoir -wide, which is well below the North Carolina 15A NCAC 02B water quality standard of 5 µg/L for freshwater. • During 2017, the mean selenium concentrations in sediments were statistically similar between Transects C and D while in 2018, the mean selenium concentrations were statistically greater at Transect D than at Transect C (Appendices 11 and 12). All mean selenium concentrations in the muscle tissues of Bluegill, White Catfish, and Largemouth Bass were statistically greater at Transect D near the power plant discharge compared to upstream at Transect C during 2017. During 2018, the mean concentrations in Bluegill muscle were significantly greater at Transect D compared to Transect C. No differences in selenium concentrations of muscle tissue from White Catfish and Largemouth Bass were noted in 2018. The selenium concentrations in the three species continued to trend lower at Transect D since approximately 2013 (Appendix 13). All the selenium values (converted to wet weight concentrations) in edible flesh during 10-year observation period from 2009 through 2018, were well below the North Carolina human health consumption advisory level (10 µg/g wet weight). Thallium • All thallium measurements were below the LRL of 0.1 µg/L during 2017 and 2018 (Appendices 3-6). Duke Energy Progress 14 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Fisheries Fish Species Composition • There were 24 fish species in 2017 and 21 fish species in 2018, belonging to seven families, collected from Hyco Reservoir with electrofishing (Appendix 14). As a whole, the sunfish family (Centrarchidae) dominated the fish population with six fish species present in the reservoir both years. The bullhead catfishes (Ictaluridae), minnows (Cyprinidae) and Catostomidae (suckers) traded with each other in number of species between 2017 and 2018. The fish assemblage observed in Hyco Reservoir was typical of piedmont impoundments in the Southeast. Largemouth Bass was the primary apex predator in the reservoir both years and Black Crappie and Channel Catfish were also prevalent predators during 2017 and 2018. Yellow Perch were collected in reasonably good numbers. The open water schooling species Gizzard Shad and Threadfin Shad were abundant in Hyco Reservoir providing ample forage for the predator species during 2017 and 2018. • As with most man-made reservoirs, the fish assemblage in Hyco Reservoir consisted of species considered widely distributed and common in the Southeastern United States except for introduced species including Blue Tilapia and Threadfin Shad (Appendices 15 and 16). The presence of these introduced species in Hyco Reservoir was unrelated to the operation of the Roxboro Plant except for the heated effluent which allowed for their overwintering. Blue Tilapia, in particular, are likely to decline in numbers due to their intolerance of cold water temperatures as the Roxboro Plant continues to be dispatched at lower rates. Threadfin Shad may also be somewhat affected due to their intolerance of long-term exposure to low temperatures (Strawn 1965). The remaining fish species in Hyco Reservoir were either indigenous or typically found in piedmont reservoirs of North Carolina. • The greatest number of fish species was observed at Transect C both years with 19 species during 2017 and 16 species during 2018 (Appendices 15 and 16). The Transects followed a pattern of species richness both years as follows: C>B>A>D=F. Transects D and F had the lowest species richness likely due to limited shoreline habitat with more open water areas. Fish Abundance, Distribution, and Size Structure • Centrarchidae (sunfishes) were the most the abundant fish group in Hyco Reservoir followed in order by Clupeidae (herrings), Ictaluridae (bullhead catfishes), Cyprinidae (minnows), Catastomidae (suckers), Percidae (perches), and Cichlidae (tilapia) during 2017 and 2018 (Appendix 14). The sunfish family comprised 78% of the total annual electrofishing catch in 2017 and 88% total annual Duke Energy Progress 15 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report electrofishing catch in 2018. Herrings comprised 15% and 8% of the total fish catch while bullhead catfishes comprised 2% both years of the total fish catch during 2017 and 2018, respectively. • Bluegill was the single most abundant fish species present with 53% of the total catch during 2017 and 70% during 2018 (Appendix 14). Largemouth bass was the second most abundant fish species during both 2017 and 2018 with 13% and 10% of the total fish numbers and comprising 33% and 46% of the of the total biomass, respectively. Gizzard Shad was the third most abundant species with 9% during 2017 and 5% during 2018 of the total catch each comprising 16% and 11% of the total biomass. Total fish number and biomass reservoir -wide during 2017 and 2018 were consistent with values observed in recent years (DEP 2017). • Bluegill were most abundant based on electrofishing at Transects A (Cobbs Creek) and D during 2017 and at Transect B during 2018 (Appendix 15 and 16). The mean Bluegill electrofishing catch by transect arranged in approximate decreasing order were Transects A>D>C>F>B during 2017. During 2018, the mean Bluegill catch in approximate decreasing order was B>D>A>C>F. • As in previous years (DEP 2017), Bluegill reproduction continued be good throughout the reservoir in both 2017 and 2018 as indicated by their length -frequency distributions at all transects, except at Transect B during 2017 (Appendices 17 and 18). Transect B is characterized as large flat open areas with little cover for hiding from predators and likely the reason for fewer small Bluegill (< 80 mm) being collected. Also, there is a limited amount of shoreline rip rap habitat in shallow areas of this transect that can provide cover as well, therefore, small fish may be under represented annually in the electrofishing catch. The size class distributions of Bluegill were similar among all transects except at Transect B during 2017 where most fish were greater than 75 mm. This pattern of fewer small Bluegill at Transect B is typical of the electrofishing catches at this reservoir location (DEP 2017). However, in a departure from past monitoring, the electrofishing catch from 2018 at Transect B exhibited a reasonably large number of smaller Bluegill. The appearance of many smaller individuals is not understood completely but could suggest changes to the habitat (e.g., possible vegetation growth) that are not apparent from the reservoir surface. • The mean Relative Weight (Wr) values, which is an indirect measure of health condition, reservoir - wide were 83 during both 2017 and 2018, respectively (Appendices 23 and 24). A Wr of 100 is optimal for a species and suboptimal Wr values, in the absences of diseases or other health related Duke Energy Progress 16 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report factors, may be related to competition for food and the mesotrophic status of Hyco Reservoir for this numerically dominant species. Most fish do not achieve optimal condition in natural settings. • Largemouth Bass of all size classes were well -represented throughout the reservoir during 2017 and 2018 (Appendices 15 and 16). Adequate reproductive success was noted both years as represented by the presence of reasonable numbers of individual fish less than 150 mm at most transects. Transect D near the power plant discharge had the most smaller fish present in electrofishing catches during 2017 while Transect A had the most in 2018. The average size of Largemouth Bass was consistent throughout the reservoir within year and between years having an overall reservoir mean length of 267 mm for 2017 and 251 mm for 2018. • The mean Wr for Largemouth Bass in Hyco Reservoir during 2017 (Wr =85) was slightly lower than the mean Wr during 2018 (Wt=89) (Appendices 23 and 24). Again, the productivity level for the reservoir as a mesotrophic system is probably one of the main influences of suboptimal condition of fish, particularly an apex predator such as Largemouth Bass. • Gizzard Shad were well represented and collected in similar numbers throughout Hyco Reservoir during both years except at Transect F during 2018, where the numbers were somewhat lower (Appendices 15 and 16). Consistent with previous years, Gizzard Shad collected from the reservoir were mostly greater than 200 mm each year. Generally, young -of -year Gizzard Shad are not efficiently collected by electrofishing due to the inherent geartype bias against smaller schooling fish. However, occasionally, schools of small Gizzard Shad are encountered during electrofishing sampling such as occurred at Transect C during 2018. This event illustrates the random nature of encountering a large school of small shad at a particular location while sampling. It is likely that isolated schools like this are randomly located throughout Hyco Reservoir but are seldom encountered. • The mean Wr values of 88 and 92 for Gizzard Shad in Hyco reservoir during 2017 and 2018, respectively, were considered to be reasonably good in terms of health condition (Appendices 23 and 24). This factor along with good numbers collected throughout the reservoir, as noted above, represents a substantial prey base for predator species and a basic sustainability requirement of aquatic communities. Duke Energy Progress 17 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report • Redear Sunfish was reasonably well distributed throughout Hyco Reservoir during 2017 and 2018 (Appendices 15 and 16). Green Sunfish was more abundant downstream of the power plant discharge while Yellow Perch, Black Crappie, and Satinfin Shiner were collected in greater numbers upstream of the plant during each year. Balanced, Indigenous Community • Hyco Reservoir represents a balanced, self-sustaining community. To demonstrate balance, an aquatic population/community must contain both predator and prey species in relative balanced numbers to each other reflecting the overall trophic status of the system. Both fish groups must be reproducing and recruiting adequately to produce the proper balance. Several regionally common predator species including adult Largemouth Bass, Black Crappie, and Channel Catfish continued to exist in Hyco Reservoir during 2017 and 2018 (Appendices 14-17). The apex predator Largemouth Bass, an integral part of the aquatic community, exhibited both adequate reproduction and recruitment for a self-sustaining population based on the presence of sufficient numbers of young -of -year (generally < 150 mm fish) and year class 1+ fish (generally > 150 mm to 250 mm fish) throughout the reservoir.. Many forage species existed throughout the reservoir as well, including the primary prey species Bluegill and sustaining prey species Gizzard Shad and Threadfin Shad. Bluegill exhibited the necessary presence of young -of -year (generally < 80 mm fish) and year class 1+ fish (generally > 80 mm to 125 mm fish) (Appendices 17 and 18). Gizzard Shad and Threadfin Shad were also present in the reservoir with good numbers of adult fish each year. Without adequate reproduction and recruitment of this prey species, the adult shad would not continue to be present in similar numbers compared to previous years. Also, as noted above, a random encounter with a large school of small Gizzard Shad at Transect C during 2018 supports the likelihood of adequate reproduction recruitment of this species in the reservoir. • Fish populations in good balance can indicated by comparing the Proportional Size Distribution (PSD) index values of select predator and prey species. PSD values for balanced populations of Largemouth Bass range from 40 to 70 and for Bluegill from 20 to 60 (Gabelhouse 1984). In Hyco Reservoir, a balanced population for Largemouth Bass population during 2017 and 2018 existed in the reservoir while Bluegill population was balanced in 2017 but fell out of the range for 'balanced populations during 2018 (Appendix 25). No balance range has been determined for Gizzard Shad populations but plotting the PSD values for both Largemouth Bass and Gizzard Shad during 2017 and 2018 shows an interesting relationship of the stock and quality size fish of each species in Hyco Duke Energy Progress 18 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Reservoir. Fish Community Health • No significant disease or pathological anomalies were observed in fish collected by Company Biologists during 2017 or 2018. Winter kills of tilapia were observed in both 2017 and 2018 but were expected with the low dispatch of the Roxboro Plant. No other fish kills were observed or reported from Hyco Reservoir during 2017 and 2018. Biofouling Monitoring • No zebra mussels (Dreissena polymorpha) or quagga mussels .(D. bugensis) were found in Hyco Reservoir during 2017 and 2018. These mussels are potentially serious biofouling organisms to power plant operations. Neither species has been collected from Hyco Reservoir. Asiatic clams (Corbicula fluminea) are known to exist in Hyco Reservoir as in many other Southeastern reservoirs; however, no significant power plant operational issues have been caused by their presence. Summary and Conclusions Hyco Reservoir thermal stratification patterns and water temperature extremes continued to be dependent on the local meteorological conditions, the proximity to the discharge canal outfall area, the influence of the circulating water of the auxiliary intake system, and the inverted siphon (part of the old discharge canal to Cobbs Creek) on the South Hyco Creek arm of the reservoir during 2017 and 2018. The 2017-2018 annual mean reservoir temperatures in surface waters continued to be within the ranges typically observed in Hyco Reservoir. Despite low dispatch of the Roxboro Plant, FGD system operations continued to affect several water chemistry parameters nearer the power plant discharge compared to those at historical background stations in Hyco Reservoir during 2017 and 2018. However, concentrations of a number of constituents have decreased with decreasing FGD discharges over the last several years. In fish tissues, selenium concentrations continued to trend down in Bluegill, White Catfish, and Largemouth Bass in both 2017 and 2018. The edible flesh selenium concentrations of all fish species sampled remained well below the North Carolina consumption advisory level of 10 µg/g wet weight (50 µg/g dry weight). Fish species composition, abundance, and distribution in Hyco Reservoir during 2017 and.2018 Duke Energy Progress 19 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report were similar to that of previous years. Bluegill remained the dominate fish species followed by Largemouth Bass, Gizzard Shad, Redear Sunfish, and Black Crappie within the reservoir both years. The fish community tended to be slightly less diverse in the open -water habitat of the middle and downstream portions of the reservoir compared to the upper, riverine-like areas of Hyco Reservoir. Hyco Reservoir, a man-made water body, contained a fish community that was balanced, and self- sustaining, which indicates a balanced aquatic community characteristic of a mesotrophic piedmont impoundments located in Southeastern United States. References APHA. 2012. Standard methods for the examination of water and wastewater. 22th Ed. American Public Health Association, Washington, DC. Boyd 1979. Water quality in warmwater fish ponds. Agricultural Experiment Station, Auburn University, Aurburn, AL. CP&L. 1991. Roxboro Steam Electric Plant 1990 environmental monitoring report. Carolina Power & Light Company, New Hill, NC. . 2001. Roxboro Steam Electric Plant 2000 environmental monitoring report. Carolina Power & Light Company, New Hill, NC. DEP. 2013. Roxboro Steam Electric Plant 2012 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2014. Roxboro Steam Electric Plant 2013 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2016. Roxboro Steam Electric Plant 2014-2015 environmental monitoring report. Duke Energy Progress, Raleigh, NC. DEP. 2017. Roxboro Steam Electric Plant 2016 environmental monitoring report. Duke Energy Progress, Raleigh, NC. Duke Energy Progress 20 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Gabelhouse, D. W., Jr. 1984. A length -categorization system to asses fish stocks. N. Amer. J. Fish. Manag. 4:371-384. North Carolina Administrative Code. 2019. Title 15A NACA 02B Water Quality Standards for Surface Waters. June 10, 2019. NCDENR. 2013. Standard Operating Procedures; Fish Tissue Assessments. North Carolina Department of Environment and Natural Resources. Intensive Survey Branch. Raleigh, NC. NCDEQ. 2015. Roanoke River basinwide assessment report. North Carolina Department of Environmental Quality. Intensive Survey Branch. Raleigh, NC. Page, L. M., H. Espinsoa-P6rez, L T. Findley, C. R. Gilbert, R. N. Lea, N. E. Mandrak, R. L. Mayden, and J. S. Nelson. 2013. Common and scientific names of fishes from the United States, Canada, and Mexico. 7th edition. American Fisheries Society, Special Publication 34, Bethesda, Maryland. PEC. 2008. Roxboro Steam Electric Plant 2007 environmental monitoring report. Progress Energy Carolinas, Raleigh, NC. Salomons, W., and U. Forstner. 1984. Metals in the hydrocycle. Springer-Verlag, New York, NY. Strawn, K. 1965. Resistance of Threadfin Shad to low temperatures. Proceedings of the Annual Conference Southeastern Association of Game and Fish Commissioners 17(1963):290-293. USEPA. 1979. Methods for the chemical analysis of water and wastes. U.S. Environmental Protection Agency, EPA-60/4-79-020, Cincinnati, OH. Duke Energy Progress 21 Water Resources M M M N 00 00 00 00 I- l- l- [� C% V) -It M N r- h o0 a1 (/I w �r-r-r-r. . . . . . . . . wv�o� . . . . . . . W ooNo . . . . . . . 0 ..y o cn �. 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N N N N N N C W O G (D O O (D Cly p N O O O O O O O O O O y N O O O O O O O O O O � Q O .-• N m 4 V) )D l- w Oi A O ,-• N m 7 V) �D h o0 D, A 0 .• N M V, \O � 00 D\ Q Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 1. (continued) August 29, 2017 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SRUM B2 C2 D2 F2 SHHW1 0.2 27.4 26.6 27.9 27.6 24.7 7.1 6.4 6.8 6.7 7.4 7.4 7.2 7.3 7.3 7.4 175 118 206 180 105 1.0 27.4 26.2 27.9 27.6 24.7 7.1 6.3 6.8 6.6 7.3 7.4 7.2 7.3 7.3 7.3 175 118 206 180 105 2.0 27.4 26.2 . 27.9 27.6 24.7 7.1 6.3 6.7 6.6 7.1 7.4 7.2 7.3 7.3 7.3 175 118 206 180 105 3.0 27.4 26.2 27.8 26.8 7.1 6.3 6.7 6.6 7.4 7.2 7.3 7.3 175 118 207 179 4.0 27.4 26.2 27.8 7.1 6.3 6.7 7.4 7.2 7.3 175 118 207 5.0 27.3 26.1 27.8 7.1 5.9 6.7 7.4 7.1 7.3 174 118 207 6.0 27.0 27.8 6.9 6.7 7.3 7.3 174 207 7.0 27.7 6.8 7.3 211 8.0 27.7 6.8 7.3 211 9.0 27.8 6.8 7.3 209 10.0 27.6 6.8 7.3 213 October 11, 2017 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHWI B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SIUM 0.2 26.2 26.7 30.6 27.3 26.3 9.4 10.6 7.0 8.4 9.8 8.3 8.9 7.7 8.0 8.5 199 144 214 206 122 1.0 26.1 25.8 30.1 26.6 24.4 9.4 10.8 6.9 8.3 10.0 8.4 8.9 7.6 7.9 8.6 199 142 212 206 122 2.0 25.7 24.4 29.5 26.4 22.8 9.2 8.6 6.9 7.8 1.5 8.3 8.1 7.6 7.8 7.2 199 148 210 206 137 3.0 25.1 23.3 28.5 26.2 8.2 5.7 7.0 7.1 7.8 7.6 7.6 7.6 197 146 208 205 4.0 24.5 22.6 26.3 7.2 1.8 6.8 7.5 7.1 7.5 194 140 206 5.0 23.7 22.1 25.8 3.7 0.3 6.5 7.0 7.1 7.4 194 144 205 6.0 23.5 25.6 2.3 5.7 6.9 7.4 194 203 7.0 24.8 4.3 7.2 260 8.0 24.2 3.3 7.1 200 9.0 23.6 2.0 7.0 200 10.0 23.5 0.5 7.2 204 December 6, 2017 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 0.2 12.8 11.2 16.1 14.5 10.6 10.2 10.3 8.1 9.4 11.0 7.5 7.3 7.2 7.4 7.6 204 175 217 208 159 1.0 12.8 11.2 16.1 14.5 10.6 10.2 10.3 8.1 9.3 10.9 7.5 7.3 7.2 7.4 7.5 204 175 216 208 159 2.0 12.8 11.1 16.1 14.5 10.5 10.2 10.3 8.0 9.2 10.8 7.5 7.3 7.2 7.4 7.5 204 175 - 216 208 157 3.0 12.7 11.0 15.7 14.5 10.5 10.1 10.1 7.4 9.2 10.9 7.5 7.2 7.1 7.4 7.5 204 172 213 208 158 4.0 12.5 10.7 15.4 9.5 9.4 7.4 7.3 7.1 7.1 202 172 211 5.0 12.3 10.7 15.4 8.9 9.4 7.4 7.2 7.1 7.1 202 172 211 6.0 11.9 15.2 7.5 7.3 7.1 7.1 196 210 7.0 15.2 7.2 7.0 210 8.0 15.0 6.9 7.0 209 9.0 14.0 6.3 7.0 206 10.0 13.3 5.1 7.0 204 Duke Energy Progress 23 Water Resources C IL V W 0 O 0 w cc cc R U 000mM L 0 .� N N N N N N N N N f 0 N M M M M M M N N W r0 ��. .fir n n n (n N 0 0 0 0 0 0 0 O� f M O, �O ,O �n O A N N C7 N N N N N N N N N N N C �D �O �O V1 V1 <F Ci A N N N N N N N N N N N Ci � N N N 0 0 CD 'n gmm uzN w cr. ^ Nf Ole Offoo U .N. .N. 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U�0000��o 4 =��OO� A o000 0 -0000 A 00 MO O` N r-<t .-• N f r- N N . 00 00 f O 4-4.� �--� O O O O Qi .N-i .-� 00 In O O N v 3 O O N O, .di I'O I'O V N N s. u Qn 00 00 %D 7 In f N O� 00 00 00 N V .N. .N.N. Iw L OO o0 00 00 00 00 \O 7 it o0 .-. O M .-• O f �O M o0 d A 7 M M M it Q - - 00 - - O V - - �-+ O A rn {{{yyy ^ ^ ^ ^ ^ Q V (V (V f`I ^ ^ ^ ^ ^ ^ 00 OG l� l� l� l� h N F1 [� �D N N N N N N N N a: 0 FFLCC�iiY L F 4% N o0 00 O N f M F N o0 �O oo O f O, oo r N fV O O O O O, ,D 'O Wn u o0 00 00 00 r- r- r- r- (, <. M— CD CD O '-' '-' ^ - - ^ F V o0 l- �O �O N w b� L b ,D cD r,r N 00 O f M ON 00 00 vi M O O O N O\ ON f Vl 00 O, In n'o ii o, c, w o r-^^ cq .~ .~ l- r- r, Ln V m N N N N N N N N i W a y N 0 0 0 0 0 0 0 0 0 0 y N O O c o 0 0 0 0 0 0 G N O O O O O O O O O O W O -+ N m V W)�o f 00 O� O --� N m 7, C l-: 0. a, O -� N M.4 vi b f 00 O, A A A Q Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 2. (cont.) August 1, 2018 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHWl B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SEEM 0.2 29.3 29.2 31.8 30.1 29.4 6.7 7.6 7.0 7.6 6.6 7.5 7.8 7.4 7.5 7.4 160 114 186 171 111 1.0 29.3 29.2 31.7 30.0 29.3 6.7 7.6 7.0 7.6 6.5 7.4 7.7 7.4 7.5 7.4 160 114 186 172 111 2.0 29.3 29.1 31.6 29.9 28.8 6.7 7.4 6.8 7.5 4.0 7.5 7.7 7.4 7.5 7.1 160 114 186 173 112 3.0 29.3 28.8 31.5 29.8 28.6 6.7 6.3 6.4 7.5 2.1 7.4 7.3 7.2 7.4 6.9 160 116 185 171 115 4.0 29.3 26.1 30.1 6.6 0.3 4.3 7.4 6.7 7.0 160 148 174 5.0 29.2 22.4 29.6 6.5 0.3 3.1 7.4 6.8 6.8 160 201 170 6.0 28.6 19.1 29.2 0.5 0.4 2.3 6.9 6.5 6.8 159 230 168 7.0 28.1 28.6 0.4 0.8 6.9 6.7 171 163 8.0 27.8 0.2 6.8 166 9.0 24.4 0.3 7.4 218 10.0 20.6 0.3 7.7 267 October 2, 2018 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 F2 SHHWl B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 B2 C2 D2 F2 SHHW1 0.2 26.7 26.7 28.7 27.3 25.6 10. 10.8 6.2 8.5 10.5 8.4 8.7 7.1 7.7 8.4 165 93 175 180 92 1.0 26.6 26.1 28.7 27.2 25.1 10. 10.7 6.4 8.5 10.3 8.5 8.7 7.1 7.6 8.4 165 92 174 179 90 2.0 26.1 25.5 28.5 27.1 24.0 10. 9.8 6.4 8.4 6.9 8.4 8.4 7.1 7.6 7.6 165 92 173 179 92 3.0 25.4 24.5 27.1 26.3 8.3 6.1 3.8 6.3 7.7 7.5 6.9 7.2 162 91 164 177 4.0 25.3 24.1 26.5 8.1 2.5 3.1 7.5 7.1 6.8 157 90 160 5.0 25.2 23.8 25.8 7.8 0.4 1.3 7.4 6.9 6.7 161 107 144 6.0 24.8 25.4 3.0 0.7 7.0 6.6 143 126 7.0 25.2 0.6 6.6 122 8.0 25.0 0.4 6.6 118 9.0 24.6 0.2 6.6 102 10.0 23.9 0.1 6.7 132 December 5, 2018 Temperature Dissolved oxygen pH Specific conductance Depth B2 C2 D2 6B SHHW1 B2 C2 D2 6B SHHW1 B2 C2 D2 6B SHHWl B2 C2 D2 F2 SHHWl 0.2 11.0 8.3 19.6 13.4 8.3 9.8 10.0 8.3 8.2 9.7 7.4 7.2 7.1 7.0 7.1 94 72 116 108 82 1.0 11.0 8.3 19.3 13.4 8.3 9.8 10.0 8.2 8.2 9.7 7.2 7.1 7.1 7.0 7.1 94 72 116 108 82 2.0 11.0 8.3 19.2 13.4 8.3 9.8 10.0 8.2 8.2 9.7 7.2 7.1 7.1 7.0 7.1 94 72 116 108 82 3.0 11.0 8.2 18.0 13.4 8.3 9.8 10.0 8.1 8.2 9.7 7.1 7.0 7.1 7.0 7.3 94 72 111 108 82 4.0 10.9 8.1 16.4 9.8 10.0 7.8 7.1 7.0 7.0 91 72 109 5.0 8.7 8.0 12.6 9.4 10.0 7.7 7.0 6.9 6.9 79 73 103 6.0 7.7 11.5 8.7 7.7 7.0 6.9 72 102 7.0 11.7 7.8 6.9 100 8.0 11.3 6.7 6.9 82 9.0 9.6 6.8 6.8 81 10.0 9.4 6.8 6.8 80 Duke Energy Progress 25 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 3. Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2017 +& Station B2 Station C2 Station D2 Station F2 Station SHHW I Variable Mean Range Mean Range Mean Range Mean Range Mean Range Temperature (°C) 20.7 12.8-28.1 20.5 11.2-27.9 23.4 11.3-30.6 21.8 14.5-29.4 29.9 8.5-28.0 Dissolved oxygen (mg/L) 9.0 7.1-10.2 9.2 6.4-10.6 7.8 6.8-10.2 8.6 6.7-10.8 9.4 7.4-11.0 pH (median value) 7.5 7.2-8.3 7.3 6.9-8.9 7.3 6.9-7.7 7.4 7.1-8.0 7.6 6.8-8.5 Total dissolved solids(mg/L) 109'b 73-145 82'b 47-123 123' 86-153 122' 88-141 74b 59-118 Turbidity (NTU) 19 2-64 17 5-40 8 2-21 5 2-15 15 6-24 Secchi disk transparency (m) 1.3 0.5-1.9 0.7 0.5-1.1 1.5 0.6-2.3 1.6 0.8-2.3 0.7 0.7-0.7 Chlorophyll a (µg1L) 8.5'b 6.3-16 18' 4.8-37 3.9b 1.5-5.1 5.2'b 3.6-7.5 N/A Nutrients (mg/L) Ammonia-N 0.01 < 0.01-0.03 0.01 < 0.01-0.03 0.02 < 0.01-0.05 0.01 < 0.01-0.02 < 0.01 N/A Nitrate + Nitrite N 0.04 < 0.02-0.11 0.08 < 0.02-0.26 0.08 < 0.02-0.19 0.05 < 0.02-0.13 0.06 < 0.02-0.23 Total nitrogen 0.31 <0.12-0.75 0.48 0.28-0.85 0.34 0.21-0.56 0.28 0.12-0.53 0.45 0.28-0.78 Total Kjeldahl Nitrogen 0.20 < 0.10-0.35 0.37 0.23-0.65 0.22 < 0.10-0.41 0.19 0.12-0.25 0.36 0.22-0.51 Total phosphorus 0.043 < 0.005-0.110 0.041 0.022-0.071 0.043 0.006-0.170 0.016 < 0.005-0.035 0.040 0.021-0.063 Total organic carbon (mg/L) 7.1 4.9-10.9 6.8 4.9-8.5 5.8 4.6-6.9 5.8 4.6-7.4 7.0 5.1-8.3 Ions (mg/L) Calcium 13e6 6.4-19 10'b 5.7-16 16' 10-20 16'b 11-19 9b 6.3-15 Chloride 19'b 6.0-30 1Ob 3.0-23 25' 14-32 24' 15-31 8.1b 2.9-20 Magnesium 5.9b 3.1-8.2 4.3b 2.7-6.9 7.3' 5.0-8.7 7.0' 5.2-8.5 4.Ob 2.8-6.4 Sodium < 5.0 N/A < 5.0 N/A < 5 0 N/A < 5.0 N/A < 5.0 N/A Sulfate 14a6 6-20 8.21 3.8-15.8 19, 14-22 18' 15-21 7.lb 4.2-13.3 Total alkalinity (mg/L as 25 17-31 26 20-34 26 23-30 26 18-30 29 24-38 CaCO3) Hardness (mg equiv. CaCO3/L) 57'b 29-81 4lb 26-68 71' 46-86 68' 49-83 39' 27-63 Specific conductance (µS/cm) 153'b 75-204 116'b 70-175 182' 125-217 173' 130-208 108b 75-159 Trace elements (µg(L) Arsenic i.1'b 0.6-1.5 0.8'b 0.4-1.1 1.4' 1.0-1.8 1.4' 0.9-1.7 0.6b 0.3-0.9 Boron 400e6 94-772 192b < 50-580 562' 309-838 535' 317-780 .;; 127b < 50-422 Copper 2.1 1.1-4.2 1.7 0.6-2.7 1.7 1.0-2.6 1.6 0.9-2.1 1.3 < 1.0-2.3 Manganese 61 31-96 88 43-143 151 82-276 101 49-210 127 59-200 Mercury¢ 1.98 < 0.50-9.28 1.51 < 0.50-7.08 1.14 < 0.50-3.32 0.85 < 0.50-2.46 1.17 < 0.50-4.59 Selenium 0.6 < 0.5-1.1 < 0.5 < 0.5 0.7 0.6-1.0 0.7 < 0.5-1.1 < 0.5 N/A Thallium < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A 'Unless otherwise noted, all measurements were taken from the surface. Fisher's protected Least Significant Difference (LSD) test was applied only if the overall F test for the treatment was significant. Means followed by different superscripts were significantly different from each other (P = 0.05). The rows where significant differences occurred are shaded. Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. The variable pH was reported as a median value and was not subjected to statistical analysis. Sample size equaled 6 unless otherwise noted. Statistical testing was conducted on surface water means only. N/A means not applicable and NS means not sampled. ',Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably quantified. Statistical analyses were utilized only when mean concentrations were above the highest analytical LRL and where LRL values occurred, means were calculated by utilizing one half of the absolute value of each LRL. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 26 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 4. Means, ranges, and spatial trends of selected limnological variables from surface waters of Hyco Reservoir during 2018 "' Station B2 Station C2 Station D2 Station F2 Station SHHW1 Variable Mean Range Mean Range Mean Range Mean Range Mean Range Temperature (°C) 20.1 9.7-29.3 19.3 8.0-29.2 22.6 11.8-31.8 21.3 12.6-30.1 21.8 8.3-29.4 Dissolved oxygen (mg/L) 9.9 6.7-12.6 9.9 7.6-11.4 8.6 7.0-11.1 9.1 7.6-11.4 9.8 6.6-12.5 pH (median value) 7.8 7.4-8.4 7.1 7.4-8.7 7.4 7.1-7.8 7.7 7.0-8.0 7.7 7.0-8.4 Turbidity (NTU) 15 3-35 13 5-25 7.3 2.2-22.9 6.1 1.6-23.2 18 10-36 Secchi disk transparency (m) 1.0°b 0.4-1.7 0.8'b 0.5-1.0 1.3b 0.7-1.9 1.7' 0.7-2.6 0.6b 0.5-0.7 Total dissolved solids (mg/L) 120' 98-155 81' 73-88 137' 101-175 137' 108-183 84b 72-105 Turbidity (NTU) 15 3-35 13 5-25 7 2-23 6 2-23 18 10-36 Chlorophyll a (µg/L) 15 °b 7.8-31 22' 7.2-45 6.5'b 2.1-17 4.9b 1.5-9.0 N/A Nutrients (mg/L) Ammonia-N 0.02 <0.01-0.05 0.02 <0.01-0.09 0.04 <0.01-0.13 0.03 <0.01-0.11 0.02 <0.01-0.07 Nitrate + Nitrite N 0.05 <0.02-0.15 0.07 <0.02-0.23 0.10 <0.02-0.22 0.06 <0.02-0.17 0.09 <0.02-0.27 Total nitrogen 0.55 0.21-1.30 0.56 0.19-0.77 0.48 0.20-0.82 0.44 <0.12-0.74 0.57 0.37-0.83 Total Kjeldahl Nitrogen 0.50 0.11-1.20 0.49 0.10-0.77 0.38 <0.10-0.61 0.40 <0.10-0.73 0.49 0.25-0.67 Total phosphorus 0.0521b 0.027-0.095 0.047e' 0.034-0.072 0.028b 0.015-0.061 0.023b 0.009-0.060 0.057' 0.044-0.068 Total organic carbon (mg/L) 7.5 5.8-9.2 8.2 5.5-11.5 6.5 4.8-8.1 6.1 4.8-8.1 7.7 6.0-11.5 Ions (mg/L) Calcium 12'b 8.0-20 7.3' 5.5-10 16' 9.5-23 16' 9.6-23 7.3b 6.3-8.6 Chloride 18a6 9-32 6.9b 4.0-12.8 27 12-44 27' 11-44 5.8b 4.1-9.5 Magnesium 5.4°b 3.5-7.8 3.3b 2.5-4.4 7.0' 4.2-9.7 6.8' 4.0-9.7 3.3b 2.9-3.8 Sodium < 5 N/A < 5 N/A < 5 N/A < 5 N/A < 5 N/A Sulfate 14' 8-21 5.7b 4.0-9.3 19, 10-27 19, 9-27 5.2b 3.7-8.8 Total alkalinity (mg/L as 271b 23-30 30'b 25-35 27'b 25-28 27b 25-28 32' 28-37 CaCO3) Hardness (mg equiv. CaCO3/L) 53°b 34-81 32b 24-44 68' 41-98 67' 40-98 32' 28-37 Specific conductance (µS/cm) 139°b 87-210 133°b 72-238 1881 116-260 185' 108-256 94" 82-111 Trace elements (µg/L) Arsenic 0.9.b 0.6-1.3 0.56 < 0.5-0.9 1.1' 0.8-1.5 1.1' 0.8-1.4 0.5b < 0.5-Lo Boron 367" 181-674 721 < 50-142 592' 277-1070 584' 239-1020 36b < 50-94 Copper 1.9 1.2-2.8 1.5 0.9-1.8 1.6 1.1-2.2 1.5 1.0-2.2 1.5 0.8-2.2 Manganese 56b 24-81 73°b 47-108 97a6 62-149 64°b 34-123 119, 87-186 Mercuryt(ng/L) 2.14 <0.50-4.54 2.71 0.91-4.73 1.78 0.99-4.16 1.75 0.91-4.31 2.68 1.19-5.45 Selenium < 0.5 N/A < 0.5 N/A 0.8 0.6-1.2 0.8 0.6-1.4 < 0.5 N/A Thallium < 0.1- N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A < 0.1 N/A *Unless otherwise noted, all measurements were taken from the surface. Fisher's protected Least Significant Difference (LSD) test was applied only if the overall F test for the treatment was significant. Means followed by different superscripts were significantly different from each other (P = 0.05). The rows where significant differences occurred are shaded. Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. The variable pH was reported as a median value and was not subjected to statistical analysis. Sample size equaled 6 unless otherwise noted. Statistical testing was conducted on surface water means only. N/A means not applicable and NS means not sampled. 'Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably quantified. Statistical analyses were utilized only when mean concentrations were above the highest analytical LRL and where LRL values occurred, means were calculated by utilizing one half of the absolute value of each LRL. §Mercury was measured in nanograms per liter (ng/L). 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(cont.) Station SHHW1 Month TDS Turbidity Secchi Chlorophyll a NH3-N NOi + NOi -N TN TP TN:TP TOC depth Feb 59 22 < 0.01 0.23 0.78 0.050 16 5.8 Apr 59 24 < 0.01 0.11 0.33 0.063 5.2 8.3 Jun 59 10 0.7 < 0.01 < 0.02 0.28 0.033 8.5 7.8 Aug 68 20 < 0.01 < 0.02 0.51 0.021 24 7.4 Oct 81 11 0.7 < 0.01 < 0.02 0.49 0.041 12 7.7 Dec 118 5.9 < 0.01 < 0.02 0.32 0.031 10 5.1 Month Cat+ Cl- Mgt+ Na S042" Alkalinity Hardness As B Cu Feb 7.1 4.5 3.4 < 5.0 6.2 26 32 0.3 < 50 1.8 Apr 6.5 3.4 3.1 < 5.0 5.3 24 29 0.4 < 50 2.3 Jun 6.3 2.9 2.8 < 5.0 4.2 24 27 0.5 < 50 1.5 Aug 8.8 7.4 4.0 < 5.0 6.9 30 38 0.9 114 1.1 Oct 10.7 11 4.5 5.4 6.6 38 45 0.7 151 0.8 Dec 14.6 20 6.4 5.2 13 34 63 0.8 422 < 1.0 Month Hg§ Se Mn TI Feb 2.1 < 0.5 126 < 0.10 Apr 1.1 < 0.5 128 < 0.10 Jun 0.8 < 0.5 101 < 0.10 Aug 0.6 < 0.5 200 < 0.10 Oct 0.1 < 0.5 149 < 0.10 Dec 0.1 <0.10 +Units are in mg/L except for most trace elements (µg/L) turbidity (NTU), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaCO3/L). Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. NS means not sampled. "All variables are surface measurements. §Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 30 Water Resources 0 C CD m CD ca O lD y H F doa-ate doa�aCD CD a CD S S S U a, 00 --1 C, 0 A N O N N N ►� U N -1 N O *] + U W W C\ 00 n n n n n n _ 00 U-. O A U W y f OO -4 b W '�" N W W W N A 7 O O 0 0 A A ft 7 U W 1.0 O IC A + s n s n n n n n n n n n c N N N O y Cl O v O N v m J U D\ A N v O O O O O O N tJ "1 n n x o00000 ►� O o�000 o Av,rnAv�.a � coocoo , /A� �o W z N z a n n n 0 0 0 0 0 0 N N W W N W N' O C O 00 O 00 o O z x O. 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(cont.) Station SHHW1 Month TDS Turbidity Secchi Chlorophyll a NH3-N NOs + NOi -N TN TP TN:TP TOC depth Feb 105 36 0.5 0.03 0.20 0.45 0.061 7.4 6.1 Apr 72 18 0.6 < 0.01 0.02 0.37 0.044 8.4 7.1 Jun 77 9.6 0.7 0.02 < 0.02 0.54 7.5 Aug 84 11 0.6 < 0.01 < 0.02 0.58 0.060 9.7 7.7 Oct 81 11 < 0.01 < 0.02 0.67 0.068 9.9 12 Dec 83 22 0.6 0.07 0.27 0.83 0.053 16 6.0 Month Cat+ CI' Mgt+ Na SO4' Alkalinity Hardness As B Cu Feb 8.1 9.5 3.7 6.6 8.8 28 35 < 0.5 < 50 2.2 Apr 6.3 5.2 3.0 5.4 5.4 28 28 0.4 < 50 1.5 Jun 7.4 4.1 3.2 < 5.0 3.9 33 31 0.6 < 50 1.5 Aug 8.6 7.2 3.8 5.5 4.7 37 37 1.0 94 0.8 Oct 7.0 4.7 3.3 < 5.0 3.7 33 31 0.6 < 50 1.2 Dec 6.4 4.1 2.9 < 5.0 4.7 30 28 0.3 < 50 1.5 Month Hg§ Se Mn TI TKN Feb 5.4 115 < 0.10 0.3 Apr 2.1 < 0.5 87 < 0.10 0.4 Jun 2.3 < 0.5 95 < 0.10 0.5 Aug 1.2 < 0.5 186 < 0.10 0.6 Oct 1.8 < 0.5 126 < 0.10 0.7 Dec 3.3 < 0.5 106 < 0.10 0.6 +Units are in mg/L except for most trace elements (µg/L) turbidity (NTU ), total alkalinity (mg/L as CaCO3), and hardness (calculated as mg equivalents CaM fl. Less than values (<) indicate the Lower Reporting Limit (LRL) for the variable. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. NS means not sampled. "All variables are surface measurements. Mercury was measured in nanograms per liter (ng/L). Duke Energy Progress 33 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 200 J 175 m 150 c 0 125 c 100 m CO 75 0 U 50 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 250 200 J 150 c 0 100 c N U co 50 U 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Copper 15 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids 500 J m 400 E 0 300 m c v 200 c 0 U 100 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic Pi a 4 1 c 3 0 c 2 U c O 1 U 01 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year 5 J 4 OI S Total Selenium 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 7. Long-term trends of selected parameters at Station B2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 34 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride Total Dissolved Solids 100 rn E 75 C 0 @ 50 c m U C (j 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 225 200 — — - — -- - —-------------------------------------- --- E175 —------- -------- -------------------------------------------- C 150 - — - -- ---- -- - — - — 0 100 - — - - — — --—------- ---- c 75 -- — - - -- --- O U50 - - -------- -- - ------- ---- ----- ---------- 25 — - - — — — - 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year 25 20 p 15 10 C 0 U 5 Total Copper 2009 2010 2011 2012 22 2014 2015 2016 2017 2018 Year soo rn 500 E C 400 0 2 300 m c 200 O U 100 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 &4 o3 m N2 U C O M 0 r+ 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 4 C 0 3 C C 2 O U 1 0 � 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 8. Long-term trends of selected parameters at Station C2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 35 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 150 rn 125 E c 100 O 75 c N C 50 0 U 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year 250 a200 E 0 150 (0 y 100 U c 0 U 50 rn s Hardness 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Copper 15 0 1-.......� T 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids 500 E 400 O .g 300 c u 200 c 0 U 100 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic s J =14 c O 3 (0 C N C 2 O U 1 0 +., 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 4 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 9. Long-term trends of selected parameters at Station D2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 36 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Chloride 150 125 C 100 O 25 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Hardness 250 J E 200 C 150 C U 100 C O U 50 0 2009 2010 2011 2012 2012 2014 2015 2016 2017 2018 Year Total Copper 20 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Dissolved Solids Fre II� J rn 300 E C (D 0 0 100 U 0 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Arsenic 5 o. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Total Selenium 5 0. 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year Appendix 10. Long-term trends of selected parameters at Station F2 from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 37 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 11. Means and standard errors of trace element concentrations ()ig/g dry weight) in sediments and fish by transect from Hyco Reservoir during 2017. (Values in parentheses are the corresponding wet weight values.)H Matrix n Transect Element Arsenic Cadmium Copper Mercury Selenium Sediments 3 C <6.2 <2.9 (1.1) 75 (28)t 0.5 (0.2) < 3.6 (1.3) 2.2 (0.8) t 0.2 (0.07) 3 1) 6.2 (3.9)+ 1.6 (1.0) <2.9(1.8) 85(53)t2.6(1.6) <3.6(2.2) 2.7(1.7)+0.1(0.09) Fish muscle White Catfish C <0.2(0.04) <2.0(0.4) 0.6 (0.1)± 0.3 (0.05) 0.6 (0.1)± 0.06 (0.011) 3.1b(0.6)t0.9(0.08) D <0.2(0.04) <2.0(0.4) 0.9 (0.2) ± 0.3 (0.05) 0.5(0.1)t0.06(0.01) 6.31(1.1)t0.4(0.3) Bluegill 10 C <0.2(0.04) <2.0(0.3) 2.61(0.5)t0.7(0.1) 0.9°(0.2)t0.06(0.011) 4.16(0.7)t0.6(0.1) 10 D 0.6 (0.1) f 0.1 (0.03) < 2.0 (0.4) 0.4b (0.07) t 0.08 (0.02) 0.4b (0.07) f 0.04 (0.008) 9.9° (0.5) t 1.9 (0.1) Largemouth Bass 10 C 0.5b (0.1) t 0.08 (0.02) < 2.0 (0.4) 0.3 (0.2) t 0.09 (0.02) 1.1 (0.2) f 0.08 (0.02) 4.26 (0.9) f 0.2 (0.04) 10 D 0.8° (0.2) t 0.06 (0.01) 1 < 2.0 (0.4) 0.3 (0.07) t 0.06 (0.013) 1.1 (0.2) t 0.1 (0.02) 8.61(1.7) t 0.5 (0.1) + To convert to mean dry weight concentrations, divide the mean wet weight concentration by the appropriate mean dry -to -fresh weight ratio as follows: sediments-Transect C-0.36, Transect D-0.62, White Catfish muscle-0.18, Bluegill muscle-0.19, and Largemouth Bass muscle- 0.20. '[Standard errors and statistical analyses are given when mean concentrations were at or above the laboratory reporting limit. Laboratory reporting limits varied between samples. Means separation procedures were applied only if the overall test for transect was significant. Means for each element followed by different superscripts were significantly different at the P = 0.05 level and were shaded gray to denote significant results between transects. Duke Energy Progress 38 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 12. Means and standard errors of trace element concentrations (µg/g dry weight) in sediments and fish by transect from Hyco Reservoir during 2018. (Values in parentheses are the corresponding wet weight values.)% Matrix n l ranscct Element Arsenic Cadmium Copper Mercury Selenium Sediments C' 5.0b (1.9) f 0.03 (0.01) 0.09b (0.03) f 0.002 (0.001) 56 (21) t 0.8 (0.3) 0.08b (0.03) t 0.002 (0.001) 4.4b (2.0) t 0.2 (0.08) 16° (5.8) t 0.7 (0.25) 0.14° (0.05) f 0.01 (0.004) 88 (32) t 2.5 (0.91) 0.16° (0.06) f 0.007 (0.002) 7.6° (3.0) f 0.4 (0.2) Fish muscle White Catfish 4 C <0.5(<0.1) <0.5(<0.1) <4.7(<0.9) 0.7(0.1)f0.2(0.01) 1.8 (0.3) ± 0.1 (0.02) 6 I> <0.5(<0.1) <0.5(<0.1) 3.9(0.7)t1.7(0.3) 0.4 (0.1) ± 0.07 (0.01) 3.4 (0.6) ± 1.2 (0.2) Bluegill 8 c <0.5(<0.1) <0.5(<0.1) <4.7(0.9) 0.4-(0.07)t0.03(0.01) 1.9b(0.4)f0.2(0.04) 10 I> 0.7 (0.1)± 0.09 (0.02) <0.5(<0.1) 10 (1.9) :L 3.8 (0.7) 0.3b(0.05)t0.02(0.004) 7.2-(1.4)t0.4(0.09) Largemouth Bass 10 C 0.5b(0.1)t0.05(0.01) <0.5(<0.1) 13 (2.5) ± 4.1 (0.8) 1.1(0.2)t0.07(0.01) 3.1 (0.6)± 0.08 (0.02) 10 D 0.8- (0.2) t 0.08 (0.02) < 0.5 (< 0.1) 13 (2.5) t 2.0 (0.4) 1.1 (0.2) t 0.1 (0.02) 5.5 (1.0) t 0.4 (0.08) To convert to mean dry weight concentrations, divide the mean wet weight concentration by the appropriate mean dry -to -fresh weight ratio as follows: sediments-0.36, White Catfish muscle- 0.19, Bluegill muscle-0.19, and Largemouth Bass muscle-0.19. '[Standard errors and statistical analyses are given when mean concentrations were at or above the laboratory reporting limit. Laboratory reporting limits varied between samples. Means separation procedures were applied only if the overall test for transect was significant. Means for each element followed by different superscripts were significantly different at the P = 0.05 level and were shaded gray to denote significant results between transects. Duke Energy Progress 39 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report 25 nn 20 3 c 15 0 U E 10 3 C lu v 5 0 25 0 'ii tw n 15 U C 4010 E 3 5 v a iffe 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year -4-Transect C -E-Transect D 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year -f-Transect C-FTransect D White Catfish 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 Year --0-Transect C -E-Transect D Appendix 13. Long-term trends of selenium concentrations (dw) in Bluegill, Largemouth Bass, and White Catfish muscle tissues at Transect C and Transect D from Hyco Reservoir from 2009 through 2018. Duke Energy Progress 40 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 14. Total number and weight (kilograms) of fish collected with electrofishing from Hyco Reservoir during 2017 and 2018. 2017 2018 Scientific name' Common name Total Number Total weight Total number Total weight lupeidae Herrings Dorosoma cepedianum Gizzard Shad 228 51.1 168 30.1 Dorosoma petenense Threadfin Shad 152 0.6 75 0.2 y rinidae Minnows Notemigonus crysoleucas Golden Shiner 2 0.1 2 < 0.1 Cyprinella analostana Satinfin Shiner 40 0.1 30 0.1 Notropis hudsonius Spottail Shiner 0 0.0 6 < 0.1 Cyprinus carpio Common Carp 2 10.5 1 7.0 atostomidae Suckers Erimyzon oblongus Creek Chubsucker 1 0.3 3 1.0 Moxostoma collapsum Notchlip Redhorse 29 31.2 13 12.8 Moxostoma erythrurum Golden Redhorse 7 3.3 2 1.6 Moxostoma pappillosum V-lip Redhorse 2 1.1 0 0.0 Moxostoma commersonii White Sucker 1 0.4 0 0.0 ctaluridae Bullhead catfishes Ameiurus catus White Catfish 12 4.7 34 0.7 Ameiurus platycephalus Flat Bullhead 10 0.9 5 0.7 ktalurus punctatus Channel Catfish 39 35.0 25 27.1 Ameiurus natalis Snail Bullhead 1 < 0.1 1 0.3 entrarchidae Sunfishes Lepomis cyanellus Green Sunfish 38 0.9 20 0.4 Lepomis gulosus Warmouth 5 0.2 4 0.2 Lepomis macrochirus Bluegill 1385 29.4 2,233 29.2 Lepomis microlophus Redear Sunfish 191 25.9 160 24.6 Lepomis hybrid Hybrid Sunfish 11 0.7 1 0.4 Micropterus salmoides Largemouth Bass 349 106.1 330 120.8 Pomoxis nigromaculatus Black Crappie 60 13.1 45 4.7 ercidae Perches Perca flavescens Yellow Perch 31 0.9 34 0.8 Morone chrysops White Bass 2 0.8 0 0.0 Etheostoma nigrum Johnny Darter 1 0.1 0 0.0 ichlidae Cichlids Tilapia aurea Blue Tilapia 5 1.5 4 0.5 Total' 2,606 319.0 3,173 263.4 Total Species 24 21 P- 'Taxonomic nomenclature follows Page et al. (2013). ITotals include only fish identified to species level. Duke Energy Progress 41 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 15. Mean catch per hour (CPUE) of fish collected with electrofishing by transect from Hyco Reservoir during 2017. Common Name Transect Reservoir mean A B C D F Gizzard Shad 19 42 12 22 20 22 Threadfin Shad 2 < 1 74 0 0 15 Satinfin Shiner 7 2 10 0 0 4 Golden Shiner 0 0 1 0 0 < 1 Common Carp 0 < 1 0 < 1 0 < 1 Creek Chubsucker 0 0 < 1 0 0 < 1 Notchlip Redhorse 0 2 12 0 0 3 Golden Redhorse < 1 3 < 1 0 0 < 1 V-lip Redhorse 0 < 1 < 1 0 0 < 1 White Sucker 0 0 < 1 0 0 < 1 White Catfish 1 3 1 < 1 0 1 Flat Bullhead < 1 0 3 0 2 < 1 Snail Bullhead 0 0 0 0 < 1 < 1 Channel Catfish l 4 8 2 3 4 Yellow Bullhead < 1 0 0 0 0 < 1 Green Sunfish 1 0 3 6 9 4 Warmouth < 1 0 0 1 < 1 < 1 Bluegill 203 42 155 199 77 135 Redbreast Sunfish 0 < 1 0 0 0 < 1 Redear Sunfish 21 38 16 10 9 19 Hybrid Sunfish 0 0 0 4 2 1 Largemouth Bass 36 26 40 34 35 34 Black Crappie 9 12 8 0 < 1 6 Yellow Perch < 1 < 1 14 0 0 3 White Bass 0 0 1 0 0 < 1 Blue Tilapia 0 < 1 0 2 0 < 1 Johnny Darter 0 < 1 0 0 0 < 1 Total CPUE' 302 175 360 281 159 254 Total number of species9l 15 17 19 10 10 26 'Total catch per unit effort (CPUE) may vary from column sums due to rounding. 9ITotal number of species does not include hybrid sunfish. Duke Energy Progress 42 Water Resources Roxboro Steam Electric Plant 2017-2018 Environmental Monitoring Report Appendix 16. Mean catch per hour (CPUE) of fish collected with electrofishing by transect from Hyco Reservoir during 2018. Common Name Transect Reservoir mean A B C D F Gizzard Shad 18 22 24 16 6 17 Threadfin Shad 1 3 14 6 14 8 Satinfin Shiner 6 2 6 0 0 3 Spottail Shiner 0 2 1 0 0 < 1 Golden Shiner 0 < 1 0 0 0 < I Common carp 0 0 < 1 0 0 < 1 Creek Chubsucker 1 < 1 0 0 0 < 1 Notchlip Redhorse 0 < 1 6 0 0 1 Golden Redhorse 1 0 0 0 0 < 1 White Catfish < 1 1 0 < 1 < 1 < 1 Flat Bullhead 1 0 0 0 2 < 1 Snail Bullhead 0 0 < 1 0 2 < 1 Channel Catfish < 1 5 2 3 2 2 Green Sunfish 0 0 2 1 7 2 Warmouth 0 0 < 1 < 1 1 < 1 Bluegill 221 367 182 258 126 227 Redbreast Sunfish 0 0 < 1 0 0 < 1 Redear Sunfish 24 34 4 15 6 16 Hybrid Sunfish 0 0 < 1 2 0 < 1 Largemouth Bass 34 16 44 42 30 34 Black Crappie 12 10 2 < 1 0 5 Yellow Perch 2 8 2 4 2 4 Blue Tilapia 0 0 0 2 0 < 1 Total CPUE' 322 472 293 350 196 323 Total number of speciesT 13 14 16 12 12 22 Total catch per unit effort (CPUE) may vary from column sums due to rounding. 9'Total number of species does not include hybrid sunfish. Duke Energy Progress 43 Water Resources RECF-IVE() FEB 2 6 1010 NCDEQIDWR/NPDES ATTACHMENT 2 Thallium (CAS # 7440-28-0) Health Effects Summary Human health effects associated with low environmental exposures to thallium are unknown. Severe neurological, gastrointestinal, cardiovascular, and respiratory effects leading to death as well as alopecia (hair loss) have been reported in humans and animals following large, acute doses. Changes in blood chemistry, kidney and adrenal weights, and sperm quality in addition to alopecia, developmental delays and increased mortality have been reported in animal studies following oral administration of thallium compounds. Necessity for Assessment of Thallium Criteria The Division of Water Resources (DWR) relies upon the US Environmental Protection Agency (US EPA) Section 304(a) publications, when they are available, to assess and control the releases of toxics to the environment. These publications, collectively known as the National Recommended Water Quality Criteria (NRWQC), are published, peer -reviewed recommendations for states and tribes. DWR staff routinely review the NRWQC for possible development of state standards. For thallium, we noted that the thallium criterion has not been updated since approximately 2003. The current thallium values for Water Supply (0.24 µg/L) and Fish Consumption (0.47 µg/L)' do not reflect recent published literature and science. In 2015, the US EPA updated 94 chemical pollutants' to reflect the latest scientific information and federal policies. They did not update the human health criterion for thallium citing "outstanding technical issues". DWR reviewed recent publications for evaluation and consideration of a more appropriate criterion. Examination of Literature US EPA's Integrated Risk Information System (IRIS, 1988)3 established oral reference doses (RfDs) for soluble thallium (1) compounds ranging from 0.000068 to 0.00009 mg/kg-day. An oral RfD assesses the risk for health effects other than cancer and gene mutations. These RfDs were withdrawn and replaced with a "qualitative discussion" in 2009 due to the limitations in the toxicology database and poor quality of the toxicology studies available for thallium°. These RfDs form the basis of the NRWQC and are, therefore, questioned for use in a state criterion. IRIS determined there are inadequate data to assess the carcinogenic potential of thallium. A cancer potency factor is not available. Therefore, a human exposure concentration associated with an incremental lifetime cancer risk estimate cannot be calculated. ' https://www.epa.gov/wqc/national-recommended-water-quality-criteria-human-health-criteria-table ' https://www.epa.gov/wqc/human-health-water-quality-criteria-and-methods-toxics 3 https://cfpub.epa.gov/ncea/iris/iris documents/documents/subst/1012 summary.pdf 4 https://cfpub.epa.gov/ncea/iris/iris documents/documents/toxreviews/1012tr.pdf 1 1 P a g e US EPA's National Center for Environmental Assessment (NCEA, 2012)5 declined calculating a chronic, oral provisional peer -reviewed toxicity value (PPRTV) due to the lack of good quality toxicology studies available for thallium. They chose instead to derive the following screening provisional RfD's (p-RfD's), provided in an Appendix to the document: Screening Chronic p-RfD for thallium (1) sulfate 0.00002 mg/kg-day Screening Chronic p-RfD for soluble thallium 0.00001 mg/kg-day These values have a caveat that reads: "Users of screening toxicity values in an appendix to a PPRTV assessment should understand that there is considerably more uncertainty associated with the derivation of a supplemental screening toxicity value than for a value presented in the body of the assessment." (USEPA, 2012) The screening levels for thallium sulfate"and soluble thallium are not appropriate for developing standards due to the high level of uncertainty associated with such values. The Agency for Toxic Substances and Disease Registry, US Public Health Service (ATSDR, 1992) declined to establish a chronic Minimum Risk Level (MRL) for thallium due to a lack of adequate data.6 A federal Maximum Contaminant Level (MCL) of 2 µg/L has been established for thallium under the Safe Drinking Water Act' along with a Maximum Contaminant Level Goal (MCLG) of 0.5 µg/L. The MCL and MCLG are based on a 90-day gavage study in rats (Stoltz et al., 1986). In this study, the only grossly observed finding at necropsy thought to be treatment -related was alopecia; however, based on the absence of microscopic histopathologic changes, US EPA identified a no observed adverse effect level (NOAEL) of 0.2 mg/kg-day. Due to uncertainties in the NOAEL, US EPA incorporated a 3000-fold uncertainty factor (10 for use of a subchronic study, 10 for intra-species variability, 10 for interspecies variability, and 3 to account for inadequate testing of other endpoints of toxicity.) Based on this NOAEL, a Drinking Water Equivalent Level (DWEL) of 2.45 µg Thallium/L was calculated and rounded to 2 µg TI/L. The federal MCL is the same as the DWEL, and is expressed as 0.002 mg/L (2 µg/L). The MCLG incorporates a Relative Source Contribution (RSC) of 20% to account for exposure routes other than drinking water. The US Department of Health and Human Services, National Toxicology. Program (NTP) nominated Thallium and Thallium salts (N21607-6/2016) for toxicological review$. (Note: We were not able to determine the status of the progress.) The US EPA NRWQC Human Health Calculation Matrix9 lists a Bioconcentration Factor (BCF) of 116; It appears that the BCF factor used in the NRWQC is from US EPA's 1980 Ambient Water Quality Criteria for Thallium (440/5-80-074) and is based upon three studies from 197510. (Zitko, et al). Current accumulation studies are performed differently than those in 1975, however, we have no additional information to base a modification to this value. Recommended Surface Water Criteria for Thallium 5 https://hhpprtv.ornl.gov/ and https://hhpprtv.ornl.gov/issue papers/ThalliumSolubleSalts.pdf 6 https://www.atsdr.cdc.gov/toxprofiles/TP.asp?id=309&tid=49 ' https://www epa.gov/ground-water-and-drinking-water/national-primary-drinking-water-regulations 8 https•//ntp niehs nih.gov/ntp/a bout ntp/bsc/2016/Tune/meetingmaterials/thalliumcompounds 508 pdf 9 https://nepis.epa.gov/Exe/ZVPDF.cgi/200031EI.PDF?Dockev=200031EI.PDF io https://nepis.epa.gov/Exe/ZyPDF.cgi/2000LNGQ.PDF?Dockev=2000LNGQ.PDF 2 1 P a g e The US EPA National Recommended Water Quality Criteria for thallium does not appear to be supportable, as the values were based on a EPA IRIS RfD (Reference Cite: IRIS 09/01/90) and the reference has been withdrawn and replaced with a "qualitative discussion". No new toxicological information relevant to the derivation of a North Carolina specific criterion is available. Staff of the Classifications and Standards/Rules Review Branch recommend the use of the federal MCL of 2 µg/L for thallium in all surface waters of the state, as allowed in 15A NCAC 02B, until such time that more substantive information becomes available. References: Agency for Toxic Substances and Disease Registry. Toxicological Profile for Thallium. 1992. http://www.atsdr.cdc.gov/ MRI (Midwest Research Institute). 1988. Toxicity of thallium (1) sulfate (CAS NO. 7446-18-6) in Sprague Dawley rats. Volume 2: Subchronic (90-day) study [revised final report]. Docket ID: EPA-HQ-ORD-2008- 0057-0002 and EPA-HQ-ORD-2008-0057-0003. US Department of Health and Human Services: https://ntp.niehs.nih.gov/testing/noms/search/summary/nm-n2l607.html#top U.S. EPA Drinking Water Standards and Health Advisories. 2018. Office of Water (EPA 822-F-18-001) https•//www epa gov/sites/production/files/2018-03/documents/dwtable2018.pdf US EPA National Recommended Water Quality Criteria: 2002 Human Health Calculation Matrix (EPA- 822-R-02-012) https://nepis.epa.gov/Exe/ZyPDF.cgi/20003[EI.PDF?Dockey=200031EI.PDF U.S. EPA. Provisional Peer Reviewed Toxicity Values for Thallium and Compounds. 2012. Office of Research and Development, National Center for Environmental Assessment https://hhpprtv.ornl.gov/quickview/pprtv papers.php U.S. EPA Integrated Risk Information System. Chemical Assessment Summary for Thallium (1), soluble salts. 2009. http://www.epa.gov/iris (accessed March 06, 2018). Zitko V, Carson WV.1975 Accumulation of thallium in clams and mussels. Bull Environ Contam Toxicol 14:530-533 April 17, 2018 3(Page ATTACHMENT 3 201 B Annunt Drinking Water Duality Report TOWNOFCIL KSWLLE PWSIO N0. 5117310 INTRODUCTION This ANpa NotingWatw Ouarry Rpari Id 'panda year 2010 a destgnad tO Imam }w nowt }om dlnWng wales quaory Om goal Is to provpe you win a sale aN cmanda in, slay o, dm.rg wrier and we or, Yes to underand IN edme an. Re fo prom -our ywater mo ry 1N puahry or your amkmg ware, mud meat an. alp Ieaeel aa o—'anions neu.tere l by IN Virginia Dpelm.nl of Hedih (VOH( II yes mare pashas about "a report as want mawme,l Inlatnaron mom, arty aspect of your &Inking wale a wail to snow tees to pimp", In Ncrs,ms Ina! may enact IN wain, of your ""no ware, paste cannot "'It"d EHOn Publl[ SarvlpM iN Imes and Iaaron of regu,arM scNdllal Irwn Councls mcehngs are as lol,ows TANdi••d I A n7'l0am al Ma Tawn N.Ilaulldine GENERAL INFORMATION All dmRng 111, k1ho ng milled &mhmg wale may reaearnat N espvTed to'dean at lead lined Sol 'IS Of sane Nrx Tvnlnanls The meeance of conlamrnanrs Eons rM r,ecossanty,nd'ate lhal water poses. NaR, rrsh Mae lnlamahm deity dNered by caning In, Envschn lPrdacbm Age,cy's Safe Drinking Water wends,(800-42SRp1). San. paade may N more --We to con ornows m ask, wafer men me general —I.- ,min ad-l-waswed Plasmas such as Persons wnn edrcv u pig ChemdN by, parsals -no have a gme organ Iranspa's pr ova wnn HIVIAID6 le .,be, mina. Wdem drams rs. sane W., ana'lams can tie pamcularry as ,as non 'fact-, Tice peep. should scent ad"e sooul Winking Ova er hen look health date mickes EPAr DC guitlN,ns at eappopriae means to lessen p Ilse ,Ias of 'lad ool by crypozpadan and dNr on. —;'.al cmfani... a are avalMde has In. 5•M1 Drinking We.' NW(8g0 264?Sl). IN nodes of among wrier (bah lap water and o elk waled Include Iwas. 10kas dleame. poste. laser a livings aN Ovals As wale travels me, IN Sm Face of land or Through The ground, Il dssdver normally-octurong minerals Sol some cam. red08CIIve mderala antl Can p<M W suoslapce3 Fan the presence of anmal3 a Fan !,moan adrvlly Con, o ds mat may N pasenl m Swrn ware Irt�— Ml nd [ontaminan,. each he mods ant butan, onto may came ham sewage treebnem plan%septic syamn egr'ulluraliNedandpaprms ano.scel. ' Inagensc cpnbsonamnh, such as al lh and mete, Which can be neurdy-o[c-fig Or male it- urban mom WAIN IUNR, .-11., or domed' waeewee, dsrnarge O no gas pWu 1- m nog a km,mg • Formal and rerbiades. Which mry come tram a variety Of sources such es aernaftere. urbn Nam w w runoff, and • Organic cnemlcds cdn,minann, includnp rydhent and vdeNa ago,, chemicas, which are bypredu[N of ,NusMa pro pr s and petroleum oduction. and den aim cane Iran gas stations urwn atmmweal rape. and adds' system �Rediaa[dva canteminn,, which to be set, / ecdanng or be the results of ail and gas production end bral vh e.. In maw to endue toss bear wake, sale To*ink EPA meadOes lagr0mons a ,mil the amours of loan wnlanlhadsln Wgle pro— by pmlc w a aydms, Food and Drug Adn,nrslrason arg,ishon san ohstl Imes Ta Combanmml5 m bOtll13d ter. whit, "' prowN,N name mdedpn for mm,c health SOURCE AND TREATMENT OF YOUR DRINKING WATER The.bace d you! d nkag esol a surface wata as OesCrbed Dhow Raw wear MfNa, I ... IN M Bunn. lelnd L9, Mal obtain. I, •ate mom M. Dan and Remain, (Stmnln) RhM. Tr went of the one want consists a chernal w hhon, caagJaNnf1mcoleoon, selling, Mbaoon, Omfidabon end charm idim. All oI mesa prmcesss wok togelha 10 rdnae IN p y,"t chenm2,. ana mdogioal Coadonmmbz fd make IN wee sale to, arnk g tN Vng,da Dpmmmi of Heallh measicled a Sol water assessment of m, system In 2016 ire move, was dMamlned to N of h,gh suacpllplily to conla"napn ueng the creole, devekmd ov the stale m as maimed Samoa Water Asseas'eol Program TN asse.dhml eporl =,,Is of maps Show,ng the swlm war assessmenl area m rnvnlay of kpown IaN use ac kake of 9 n ell 'her lnm of any known <memmatm wnhln tN,sl 5,eMls TN repot d —lade oy canacurg IN Tavn ofGkirkry W al (a3a)37h.B177 v an w oliedvllikoe ao DEFINITIONS Cadanrners, in yes, dmRng wSt., Ase,ci mmaa.d accdang 1. Fedora, ana St.,. ragutaama The laneIN rep page .hows th. rotors a ommodtdinp la [aendv yam 2013. In the tame ana Nsewhve in his rpat You we6nd mern,fms endsobrendsonsyoumightndbalson nth. IN, had, ng denmh pis al Vr dlai W help you belle uoddround Men twine. Arm-kncl (NDf -lab analysis macales Ina! II,a donlam,nanl Is nOl present Pn. per mhbn (ppmJ a Mlayrams per riles amyl) - anepan Pe mtlkon ca,e5pagb 10 arts m,nme In two years a a slrgm pmu, m SI0000 note year bled, food) a sec ograms pv Ne . me pan per bhp, conasywrtas to are minme ,n 2000 most or a single penny m S t0D0).()00 Picocwes pv Ind (pCvil' Plcowrws per lav Is a mcesad ol,N raaoacbmlY In wee, Acton L.-(AL). IN mncemrallm of a cmtenearl wheh. iIe ooken.Irggv.Ircelmdnl a die rewne'nte wNci, a wales ".I -must an. T,Nhom, r bniqus IT � a hw.Ym p'odel mb.NO tO ons—,Is kv 1 or a cmlaminem,n d'krg wake, Men mum Conessrnanl Level a MCL-the hq-l1—Ol a CmlamInam Ina, Is aedwea,n ankmg wee MCL a ore se All die Io IN MCLGs as leesge using the bee avrkINS IreemenT 1.1n gy Masi m Cdnlem,nanl Lelml Goal or MCLG Ins lace oI a comamInanl ,n Wmkng wale) NOW winch Ihan IS Ids known o, expected rskto Nall, MCLG'sallowloramarg-lseay Mamnum Rendual DsmlecldnlLoval Goals MROLG-,N level of drnkvg wa enleclanl ,low wh'h lha.Isnkmwn do Nissan.espedied nak to Nissan. kill do not ofieq the baN6N of use of dienlactents as [nee ork.b M cantellinn,. Maumum Residual Dsroleclanl loyal or MRDL- IN NgNsl lent of a donfecaml allowed,n Winking water iN sc,mlwng w,dmce ana a0alkm or a denfedmnl is rtecem,y fa comrol 0l mrcrof Cor,m,nads. ' i Ma —,heirs s (rHM) a,a a goal W fwr cN hall that are lamed el an She w,fw,m or ago akcs when comoe a dNr the nobanls used to contra mrddbal cornameems In &inking wm h rood wan naturally dcculllrg organ' BN ImgSn 'site, In wale, L—ton. Running Aoo.al vaagdaiwi (Li mne fN.v.r.p. of pe ararylv2l 1e 01Ia spmpes lae kana pn'par mernat IdaNn delrg IN miondi Ire calends, quaN,, .. r...... s .e..w ewe. e..,.�..0 1).Turbiain a. manme.1N doudna.a of thewets and a ana bane 111 A good indicate ofhowmll IN IM.m rsson oy.l a Imdimlrq 21 6an. pam,e wN am, on canmrung Irmrmoss. es I1.1—S .1IN MCL der mom ream may ekake-c. pr—a wmier n,we smal a rste —sym ant may have aera n'ese rsk of gar career 31 lraemam Too-oke (Tit -Boom IOCr del Wrtnq Treatment process R.I. in., ass gee' Ihan aW eal Io iWameal afi to cdrphance coals d( Oe10.anplesesceedm Achm Levis We cishor ay mined, la various ComanmademlNwale VLOOY to mael au,egNMOryegmemnrs TNmgelTzmrylNae --in. IMalaked S. dkve, Oldefecllm Many dha cmtaminanbs laraNn naiy2adbm wva wl masenfawveOelow the Machin forts of IN lab equlgn9e MW of iNresmis in the,ale are Iran Nog amain Kl B Howeve IN elate allows us la moire la Sank,.co,owsanls bn Ihan inn par year aazuse me <aKnlra,Ions of Ibass Catlamnanta ad not clang. frapremry That Em,rmmen,al P,oacNn Agency stye MCL s at very drngwt levels In oevell ollTg Tha simserabSEPA...moss Ina IN Overage mall looks 2liters oI Wee each day lomughwl a 70.yee Ii, span EPA generally sal. MCLS at,ve, Thal wet .San ,nod mWk W Nakl enedb Im Sdms ComaTlNOls or . ma,rvlenHiwusap010 One'-amllLm chance al Nwng IN OesCnped Nanh eaed Id she mrsenlNras TI pose I aevatW shot of lead can Cause rs i Nalco madams dspeaaliy Or megrem wane alma young comes, Lead In a king Walet is Iran'evials and rmlondot assOdead wah serv'elmes and have punting Clarkzv,l, Wale, Thalmem Plain s tespm.me Ia moW&ng high pooh, dnnkmg weer but canna antra IN vale, of —beaks used in punt iag cmnp.... to. When year watv no been st far.evva hour, Year can th dmixe the galena Ia Mad aspotaa by hAkag ,cow tap ra 30 Viddrat 1.2 moods a mS.I . oacanes [rid of, I— a e,.edy rompealure before usrg wow he drinking or mMmg II you a,, caeaned prom man m ywr watea. you may wd, to have yaks water laded Infondlton m kBd m W,nkmg water lading methms and Slags you can lake lO m,nmrzel exposure a avatable Iron the See Drinking Wear H.IIIN I-0 426e701 ce a, Min IAvww eon dav/saleweelhaad VIOLATION INFORMATION The Channeled W.,r TreNnt Plant had . violation In th. ncond sod third quarter of 2010.1 TTHM. that were over the MCL of 00 pp.. An .Ildltlan.l vkdellm we. .lee laaued In the loudh q,,M,r for A RAA vlol.6an pl TTHMI over to MCL of N ppm. III.... the, this Information wM .II the .Mel wN drink our wa,r and n you hev. any q...11... If .... .on,ot Rich and MRS. st (434) 37e-0169 The Drinking Wale, Dually Repw was Preened by Richard Ellmt. Dassid, of Opaekns, Town of ClarksvlN. P 0 Rox I147 Clek-ed VA 23927 Phone 434-37"11 ATTACHMENT 4 Results of Water Quality Analysis Table 1 Roanoke River Service Authority Results Contaminant MCLG MCL Level Found Rantle V.iolatior Sample Date • Typical Source of Contamination Turbidity (NTU) NA TT=1 NTU 0.10 Max. 0.03-0.10 No Continuous testinc Soil Runoff. 100.0% See Footnote #1 MAX RRSA Plant Fluoride (ppm) 4 4 avg= 0.67 0.60-0.78 No Tested daily on Erosion of natural deposits; Water finished water at additive which promotes strong teeth; RRSA plant once Desired level 0.90 per shift. Gross Alpha 0 15 <0.5 NA No 2/6/2013 erosion of natural deposits. Ci/L every 8 yrs Radium -combine 0 5 <0.6 NA No 2n12013 erosion of natural deposits. Ci/L every 8 yrs TOC -Total (ppm) NA TT>1.0 Lowest Running 1.68-1.91 No monthy on raw Naturally present in environment Organic Carbon Av = 1.68 & treated water See footnote #2 Nitrate (ppb) 10 10 0.13 NA No Feb 2018 Annualli Runoff from fertilizer use RRSA Plant I leaching from septic tanks; sewage Barium pm 2 2 0.02 NA No ITestedAnnually .1 erosion of natural deposit Table 2 South Hill System Results Copper (ppm) 1.3 AL=1.3 0.2 ND-0.03 No 9/16/2017 Corrosion of household plumbing; See Footnote #3 90th Percentile every 3 yrs erosion of natural deposits. Lead (ppb) 15 AL=15 <2 ND-34.3 No 9/16/2017 Corrosion of household plumbing; See Footnote #3 90th Percentile eve 3 s erosion of natural deposits. TTHM (ppb) NA 80 90 23-98 Yes Quarterly By-product of drinking water Trihalomethanes 4 Qtr.RunAvg. 2 sites chlorination. HAA5 (ppb) NA 60 23 2.2-45 No Quarterly By-product of drinking water Haloacetic Acids 4 Qtr.Run Avg. 2 sites chlorination. Chlorine (ppm) MRDL= 4 MRDLG= 4 1.05 0.44-1.68 No 6 sites monthly Water additive used to control microbes. AL* Action Level N/A= Not Applicable TT= Treatment Technique ND= Non Detect < Symbol = Less Than, > Symbol Greater Than. Note # I; Treatment Technique (TT) requires that at least 95% of the monthly samples must be below 0.30 NTU. Note # 2: Total Organic Carbon (TOC) has no health effect. However, total organic carbon provides a medium for the formation of disinfec- tid'n'byprodutvs. These byproducts include Trihalomethanes (THMs) and Haloacetic Acids (HAASs). Drinking water containing these byprod- u.cts in excess of the MCL may lead to adverse health effects, liver and kidney problems, or nervous system effects, and may lead to an increased risk of cancer;_ Note #3: None of the 20 sites tested for lead and copper exceeded the copper action level and only one site exceeded the lead action level. MCLs are set at a very stringent level by the U.S. Environmental Protection Agency. In developing the standards the EPA assumes that the aver- age adult drinks 2 liters of water each day throughout a 70 year life span. The EPA generally sets MCLs at levels that will result in adverse health affect for some contaminants or a one -in -ten -thousand to one -in -a -million chance of having the described health effect for other contaminants. Violation Information: The Town exceeded the maximum contaminant level for total trihalomethanes (TTHMs) at one of the two locations required to be sampled during the first three calendar quarters of 2018. Violation notices were previously distributed explaining that this is not an immediate health risk. The Town is increasing flushing and is working with The Roa- noke River Service Authority to correct the situation. For a copy of this report in pdf form visit the town website, www.southhiliva.org/town-of-sh/forms-applications-other- downloads/plans-documents/286.2018-consumer-confidence-drinking-water-quality-reporttfile Want to learn more about drinking water, go to www.drinktap.org presented by AWWA. c c c cffi JD c ? ? ya �o� Ci�O�/� (AZ �""' - i^ x O" 100 i• Cr w c m o ��Z0 o. �• CO 0 = a, o° f 3Xr a. a to o m�Z3� �C oo �m s a > w 0 _ � u 00 In o m m c A io n a a r c 3 o Introduction: This Annual Consumer Confidence Drinking Water Re- port is for the calendar year 2018 and is designed to in- form you about your drinking water quality. Our goal is to provide you with a safe and dependable supply of drinking water, and we want you to understand the efforts we make to protect your water supply. The quality of your drinking water must meet state and federal requirements administered by the Virginia Department of Health (VDH)- Educational Information: All drinking water, including bottled water,, may reasonably be expected to contain at least small amounts of some contaminants. The presence of contaminants does not necessarily indicate that the water poses a health risk. Some people may be more vulnerable to contaminants in drinking water than the general population. Immune com- promised persons such as a person undergoing chemo- therapy, persons who have undergone organ transplants, people with HIV/AIDS or other immune system disor- ders, some elderly, and infants can be particularly at risk for infections. Those persons should seek the advice about drinking water from their health care providers. EPA/CDC guidelines on appropriate means to lessen the risk of infection by cryptosporidium and other microbio- logical contaminants are also available by contacting the Safe Drinking Water Hotline at (800-426-4791). The sources of drinking water (both tap water and bottled water) include rivers, lakes, streams, ponds, reservoirs, springs, and wells. As water travels over the surface or through the ground, it dissolves naturally occurring miner- als and in some cases, radioactive material, and can pick up substances resulting from the presence of animals or from human activity. Contaminants that may be present in source water include: (1) Microbial contaminants, such as viruses and bacteria, which may come from sewage treat- ment plants, septic systems, agricultural livestock opera- tions, and wildlife. (2) Inorganic contaminants. such as salts and metals, which can be naturally occurring or result from urban storm runoff, industrial or domestic wastewater . discharges, oil and gas production, mining, or farming. (3) Pesticides and herbicides, which may come from a variety of sources such as agriculture, urban storm water runoff, and residential uses. (4) Organic chemical contaminants, including synthetic and volatile organic chemicals, which are byproducts of industrial processes and petroleum produc- tion, and can also come from gas stations, urban storm water runoff and septic systems. (5) Radioactive contami- nants, which can be naturally occurring or be the result of oil and gas production and mining activities. To ensure that tap water is safe to drink EPA prescribes regulations which limit the amount of certain contaminants in water provided by public water systems. The Food and Drug Administration regulations establish limits for contaminants imbottled water which must provide the same protection for public health. If present, elevated levels of lead can cause serious health problems, especially for pregnant women and young chil- dren. Lead in drinking water is primarily from materials and components associated with service lines and home plumb- ing. The Town of South Hill is responsible for providing high quality drinking water but cannot control the variety of materials used in plumbing components. When your water has been sitting for several hours, you can minimize the potential for lead exposure by flushing your tap for IS to 30 seconds or until it becomes cold or reaches a steady temperature before using water for drinking or cooking. If you are concerned about lead in your water, testing meth- ods and steps you can take to minimize exposure are avail- able from the Safe Drinking Water Hotline or at httpJ/www.epa.gov/safewater/lead. SOURCE OF YOUR DRINKING WATER The source of your drinking water is surface water as de- scribed below. The Town of South Hill purchases water from the Roanoke River Service Authority (RRSA). The water source is lo- cated on Lake Gaston on the Roanoke River., Treat- ment of the raw water consists of chemicaladdition, coagu- lation, flocculation, settling (superpulsator), filtration, fluori-. dation, and chlorination. ;All of these processes work to- gether to remove physical, chemical, and biological contam- inants to make water safe for drinking., A Source Water Assessment of our water source has been conducted by the Virginia Department of Health. The Lake/River was determined to be of high suscepti- tg to contamination using criteria developed by the state in its approved Water Assessment Program. The assessment report consists of maps showing the source water assessment area, an inventory of known land use activities of concern and documentation of any known contamination within the last 5 years. Additional infor- mation is available by contacting the RRSA (434-689- 7772). DEFINITIONS: Contaminants in your drinking water are routinely moni- tored according to Federal and State Regulations. The tables on the back shows the results of monitoring con- ducted for calendar year 2018. In the table and elsewhere in this report you will find terms and abbreviations you might not be familiar with. The following definitions are provided to help you better understand these terms. Action Level (AU- The concentration of a contaminant which, if exceeded, triggers treatment or other re- quirements which a water system must follow. Non detects (ND)- Lab analysis indicates that the con- taminant is not present within the detection limits of the instrument used. Parts per million (ppm) or milligrams per liter (mg/L)- One part per million corresponds to one minute.in two years or one penny in $10,000. Parts per billion (ppb) or micrograms per liter NA) One part per billion corresponds to one minute in 2,000 years or a single penny in $10,000,000. Picocuries per liter (pCf/L)- Picocuries per liter is a measure of radioactivity in water. Nebhelometric Turbidity Unit (NTU)= Nephelometric turbidity is a measure of cloudiness of the water. Turbidity in excess of 5.0 NTU is just noticeable to the average person. ' Maximum Contaminant Level Goal (MCLQ Is the level of contaminant in drinking water below which there is no known or expected risk to health. MCLGs allow for a margin of safety. Maximum Contaminant Level (MCL-Is the highest level of a contaminant that is allowed in drinking water. MCLs are set as close to the MCLGs as fea- sible using the best available treatment technology. Maximum Residual Disinfection Level Goal (MRDL The level of drinking water disinfectant below which there is no known or expected health risk. MRDLGs do not affect the benefits of the use of disinfectants to control microbial contaminants. Maximum Residual Disinfection Level (MRDL) The highest level of a disinfectant allowed in drinking water. There is convincing evidence that the addi- tion of a disinfectant is necessary for the control of microbial contaminants. r i ' — Is a measure of the cloudiness of the wa- ter and is used because it is a good indicator of how well the filtration system is functioning. Samples for Turbidity are taken at the Water Treatment Plant. Treatment Technique (TT)= A required process in- tended to reduce the level of a contaminant in drinking water. Environmental Protection Agency (EPA) Center for Decease Control (CDC) ATTACHMENT 5 It, `C ENERGY March 10, 2015 North Carolina Department of Environment and Natural Resources Division of Water Resources NPDES Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: 316(b) Alternate Schedule Request Duke Energy Carolina, LLC and Duke Energy Progress, LLC Attention Sergei Chernikov: Environmental Services Duke Energy 526 South Church Street Charlotte, NC 28202 Mailing Address: Mail Code EC13K/ P.Q. Box 1006 Charlotte, NC 28201-1006 RECEIVEDIDENWDWR ,�o I l 20115 Water Q Secryor Permiltttng Final regulations to establish requirements for cooling water intake structures at existing facilities were published in the Federal Register on August 15, 2014 (i.e. regulations implementing §316(b) of the Clean Water Act) with an effective date of October 14, 2014. The regulation applies to stations that commenced construction prior to or on January 17, 2002 and have a design intake flow greater than 2 million gallons per day (MGD), utilize 25% of the water withdrawn for cooling purposes and are point sources per the NDPES program. The stations Duke Energy has identified as being subject to the rule are provided in Table 1. The regulation requires the submission of information listed in 40 CFR 122.21(r). The extent of the information that is required to be submitted per station is based on the actual intake flow (AIF). For stations that have an AIF less than or equal to 125 million gallons per day (MGD), the regulation requires the following information to be submitted: §122.21(r)(2) Source Water Physical Data §122.21(r)(3) Cooling Water Intake Structure Data §122.21(r)(4) Source Water Baseline Biological Characterization Data §122.21(r)(5) Cooling Water System Data §122.21(r)(6) Chosen Method(s) of Compliance with Impingement Mortality Standard §122.21(r)(7) Entrainment Performance Studies §122.21(r)(8) Operational Status For stations that have an AIF greater than 125 MGD, the regulation requires the above information to be submitted and, unless waived, the following additional information: §122.21(r)(9) Entrainment Characterization Study §122.21(r)(10) Comprehensive Technical Feasibility and Cost Evaluation Study §122.21(r)(11) Benefits Valuation Study §122.21(r)(12) Non -water Quality and Other Environmental Impacts Study The timing of the submission of the above information is connected to the timing of the NPDES permit renewal application for the station. The regulation states that for a station whose current effective NPDES permit expires after July 14, 2018, information required to be submitted must be included with the subsequent NPDES permit renewal application. For stations whose current effective permit expires on or before July 14, 2018, the owner may submit a request to the permit Director for an alternate schedule for the submission of the above information'. As shown in Table 1, every Duke Energy station in North Carolina either has an effective permit that expires prior to July 14, 2018 or has a NPDES permit that has been administratively continued while the permit is in the renewal process. Duke Energy hereby requests an alternate schedule for each of these stations. The requested submittal date for the 316(b) information is provided in Table 1. As indicated in Table 1, the Duke Energy stations that have an AIF greater than 125 MGD, with the exception of Brunswick Nuclear Station, are located on reservoirs. Under the remanded Phase II 316(b) Rule, stations located on reservoirs were not required to conduct entrainment monitoring. These stations, therefore, will have to conduct 2-years of entrainment monitoring to complete the §122.21(r)(9) submission. Entrainment monitoring has been conducted at the Brunswick Nuclear Station; however, Duke Energy will need to evaluate whether the data collected is sufficient to satisfy the requirements in the recently finalized rule. The data collected during the 2-years of monitoring are necessary to complete the benefits valuation study (§122.21(r)(11)); therefore, this submittal cannot be finalized until after the entrainment monitoring is completed and results analyzed. Furthermore, the regulations require the Comprehensive Technical Feasibility and Cost Evaluation, Benefits Evaluation and the Non -water Quality and Other Environmental Impacts to be peer reviewed. Duke Energy estimates that approximately five years will be needed to complete all the necessary studies and submission, based on the following: 1 year for the development of the Entrainment Characterization Study plans, which includes preparing the plans, and review and approval of the plans by NCDENR. — 2 years to conduct the entrainment monitoring. 1 year to complete the Entrainment Characterization Study Report, Comprehensive Technical Feasibility and Cost Evaluation Study, Benefits Valuation Study and Non -water Quality and Other Environmental Impacts Study. — 1 year to complete the Peer Review. This timeframe is very similar to the schedule presented in the proposed rule. Upon submission of the above information, North Carolina Department of Natural Resources (NCDENR) determines what, if any, 1 Refer to § 125.95(a)(1) and (2) controls are necessary to address entrainment. Once BTA for entrainment is determined, a compliance schedule will be developed to complete §122.21(r)(6) Chosen Method(s) of Compliance with Impingement Mortality Standard. The stations with an AIF less than or equal to 125 MGD have fewer submittal requirements; however, these stations were either not subject to the remanded rule or have undergone extensive changes to the operation since they were last evaluated. As a result, Duke Energy will need to develop a new submittal for each of these stations. Duke Energy will attempt to use available historical information; however, additional field work may be needed at some sites to complete the Source Water Physical Data and Baseline Biological Characterization Data submissions. EPA concluded that 39 months will be adequate for facilities with an AIF less than 125 MGD to complete all the required submissions. Given the requirements will be implemented through the NDPES permit, Duke Energy request these submittals are due with the NPDES permit renewal applications due after July 14, 2018. If you have any questions or comments, please contact myself at 704-382-9622 or nathan.craie@duke- enerey.com. Si rely, /� c. �Y ath n Crai Senior Environmental Specialist Duke Energy Attachment 4 Table 1: 316(b) Alternate Schedule Request Duke Energy Carolinas, LLC and duke Energy Progress, CLC PIAMT "Ism Nrrmdt Cooing Method Actual Immtaq Flow Gnaws! 11PDE5 Requested Deb to Sew M AntkfPebd Neat NPDES Akemob Sdedade Request SubMthl RaquYe+nnot sedns Number Etylretson Date 316(b) Infice aDom (hemp ExpJretlon Data welted Duke Energy would like to request the 316(b) submittals to be due with the subsequent NPDES r(2) -qS), r(7 r(13 once -through cooling (OTC] Permit application due after July 14, 2019. assuming a Sywr expiration date From the r(6) to be submitted after BTA for BRUNSWICK NC0007D64 estuary AIF > 125 MGD 11/30/2016 61W021 11/29/2021 expiration date of the amrent NPDES permit. entrainment is determined Duke Energy would like to request the 316(b) submittals to be due with the subsequem WOES r(2) -r(S), r(7)- d13 cooling water reservoir defined as 4.5-yean from the effective Permit appllotlon, assuming a S-year expiration date from the eMectl a date of the renewed 0) to be submitted after BTA to OXBORO NCW03425 waters of the U.S. Alf from reservoir > 125 MGD 3/31/2012 date of the renewed permit TBO permit. entrainment is determined Duke Energy would like to request the 316(b) submittals to be due with the subsequent NPDES r12) -r(S), r(7)- r(13) cooling water reservolr defined as 4.5-years from the effective Permit application, assuming a 5-year expiration data from the effected date of the renewed 16) to be submitted after BTA for HEVILLE NC000D396 waters of the U.S. Alf from resenmir > 125 MGD 12/31/2010 date of the renewed permit 781) permit entrainment Is determined A renewal application was submitted rm Aug. 14. 2014. An altemate schedule request for the 316(b) submittals was submitted on Jan. 9, 2015. Duke Energy requested the 316(h) submittals r(2) -r(5), r(7)-113) cooling water reservolr defined as to be due with the subsequent NPDES permit application due after July 14. 2019, assuming a 5- d6) to be submitted after BTA fo GUIRE NCOD24392 waters of the U.S. AIF from reservoir> 12S MGO 2/28/2015 W112019 2/27/2020 year expiration date from the explratlon date of the current NPDES permit. entnl—m Is determined An alternate schedule request was submitted with the NPDES applkatbn renewal submitted on Oct. 9 2014. Duke Energy requested the 3161b) submittals to be due with the subsequent r(2) -r(5), r(7)- 013) cooling water reservoir defined as NPDES permit renewal application due after Jury 14, 2018. assuming a Sitar expiration date r16) to be submitted after BTA for ALLEN NC00O4979 waters of the U.S. Alf from reservoir > 12S MGD SM12015 1Z/112019 S129/Z020 From Me expiration date of the curer permit. entrainment Is determined An alternate sdmedulr request wes submitted with the NPDES application renewal submitted on . Oct. 9 2014. Duke Energy requested the 311ilb) submttab to be due with the subsequent 12) -r(SJ, r(7)- r(13 cooling water reservoir de0nad as NPDES permit renewal application due after July 14, 2018. assuming a 5-year expiration date r(6) to be submitted after BTA for ARSHALL NCO004997 waters of the U-S. MF from reservoir> 125 MGD 4/3O/2DI5 10/31/2019 4/28/20Z0 from the expratbn dote of the current Permit. entralmmem Is detensured Duke Energy would like to request the 316(b) submittals to be due with the subsequent NPDES r(21 ♦(S), r(7} r(13 cooling water nn.rwlr d.AnW as Permit application due after July 14, I011, assuming a S-year explmtlon dab from the r(6) to be submitted after BTA for tEWS CREEK NC0024406 waters of the U.S. AJF from reserwk > 125 MGD 2/28/2017 9/31/2021 2/17/2022 expiration date of the current NPDES permit. entrainment is cltermioned Duke Energy would like to request the 316(b) submittals to be due with the subsequent NPDES cooling pond Iclasslnotion as Alf from coding pond > 225 4.5-years from the effective Permit appli-tiion due after July 14, MR. assuming a S-".' expiration date from the 11TON NCO001422 Waters of the US In review) MGO 12/31/2016- date of the permit TBD expiration date of the current NPDES permit TRIO p a minimum r(2) - r(B) Duke Energy would like to request the 316(b) submittals to be due with the subsegtem NPDES closed -cycle cooling (coding 4.5-years from the effectve Permit application, assuming a 5-yew expiration date from the effective date of the renewed MAYO NC0039377 towers) Alf < 125 MGD 3/31/2012 date of the renewed permit TBO permit. r(2) -48) Duke Energy would like to request the 326(b) submittals to be due with the subsequent NPDES closed -cycle cooling 1coollng 4.5-years from the ~hr. Permit applkatbn, assuming a 5-year expiration date from the effective date of the renewed EARON HARRIS NC00395B6 tower) Alf < 125 MGD 7/31/2011 date of the nenewed permit TRD permit. r12) -r(B) Duke Energy world like to request the 316(b) submittals to be due with the subsequent NPDES closadcWle cooling (cooling P. appllcaton due after July 14, 201a, assuming a S-yeor expintion date from the CLIFFSIDE NC00050B8 tower) Alf <125 MG 7/31/2DIS I/3 M2D 7/291202D expiration date of the current NPDES permit. Dula Energy would like to request the 316(b) submittals to be due within 3-yean of the - closedcyck cooling (cooling effective date of the renewed NPDES permit Assuming an effettFm date of 9/31/2O16. this date SUCK NC00O4774 towers) Alf <1Z5 MGO 313VMIS 8/31/2019 8/30/2021 ld be a/31/2019. Duke Energy would like to request the 316(b) submittals to be due within 3-years of the ciosedcycle cooling (cooling - aflecttve dot. of the renewed NPDES permit Assuming an eflectbe date of 4/3/2017, this date DAN RIVER NODO03468 towers) Alf < IZS MG 4/30/2017 4/3/2020 4/29/2022 would be 4/3/2020. rQ) -r(B Duke Energy would like to request the 316(b) submittals to be due with the subsequent NPDES closed<vcle cooling (cooling pond 4.5iears from the ~No permit application, assuming a Sitar expiration date from the eftect1w date of the renewed F-LEE NCOW 3417 no defined as watersof the U.S.) Alf < 125 MG 5/31/2013 date of the renewed permit TRIO permit. rj2) -481 A NPDES apol-tion for Sutton was submitted to NCDENR on Feb. 23, 2015. Duke Energy requested the 3161b) submittals to be due with the next NPDES permit application, assuming a 5-y.ar permit term. The Smith Energy Complex receives water from a local municipality; therefore, the station Is not sub)ect to the rule