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HomeMy WebLinkAboutWI0100576_Permit (Issuance)_20200219 (2)4 IP syn,T(erra TRA N S MITTA L 148 River Street, Suite 220 (864) 421-9999 Greenville, South Carolina 29601 FAX (864) 421-9909 TO: Shristi Shrestha DATE: 02/17/2020 NCDEQ DWR UIC Program FROM: Todd Plating 1636 Mail Service Center PROJECT NAME: Asheville Tracer Study Raleigh, NC 27669 PROJECT NUMBER: 1026.102.51 Cc: ® ENCLOSED DELIVERY METHOD ❑ US MAIL ITEMS ❑ ORIGINAL ❑ VENDOR ❑ UNDER SEPARATE COVER ® OVERNIGHT ® PRINTS ® ELECTRONIC FILES ❑ COURIER ❑ SAMPLES ❑ OTTER(Via Email) ❑ SPECIFICATIONS ❑ OTHER Item No. Copies _ Description 1 1 1 — Hardcopy Notification of Intent — Asheville Steam Electric Plant Tracer Stu 2 1 1- Flash Drive — Same as above *ACTION SCHEDULE: NET NO EXCEPTIONS TAKEN MCN MAKE CORRECTIONS NOTED R REJECTED FYU FOR YOUR USE RR REVISE AND RESUBMIT Action* FYU IFA ISSUED FOR APPROVAL IFC ISSUED FOR CONSTRUCTION IFR ISSUED FOR REVIEW IFI ISSUED FOR INFORMATION IFP ISSUED FOR PERMITTING BY: FYU NC Department of Environmental Quality — Division of Water Resources (DWR) NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are "permitted by rule" and do not require an individual permit when constructed in accordance with the rules of ISA NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection AQUIFER TEST WELLS (15A NCAC 02C .02201 These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. INSITU REMEDIATION i15A NCAC 02C .02251 or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells is located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned as Incomplete. DATE: February 14, 2020 PERMIT NO. VV 3-01 O D 5-T(Go (to be filled in by DWR) NOTE- If this NOI is being submitted as notification of a modification of a previously issued NOI for this site (e.g., different injection wells, plume, additives, etc.) and still meets the deemed permitted by rule criteria, provide the previously assigned permit tracking number and any needed relevant information to assess and approve injection: Permit No. WI Issued Date: A. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well......................................Complete sections B through F, J, M (2) Aquifer Test Well.......................................Complete sections B through F, J, M (3) Passive Injection System...............................Complete sections B through F, H-M (4) Small -Scale Injection Operation ......................Complete sections B through M (5) Pilot Test.................................................Complete sections B through M (6) X Tracer Injection Well...................................Complete sections B through M B. STATUS OF WELL OWNER: Business/Organization Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page I C. WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): DUKE ENERGY PROGRESS. LLC — BRYSON ALLISON — ENGINEER Mailing Address: 526 SOUTH CHURCH STREET City: CHARLOTTE State: NC Zip Code: 28202 County: MECKLENBURG Day Tele No.: 980-373-6636 Cell No.: 706-910-9638 EMAIL Address: bryson.allison, duke-energG .. Fax No.: Not Applicable D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: ANTONIO D. PRICE, PE — ASHEVILLE PLANT GENERAL MANAGER Company Name DUKE ENERGY PROGRESS, LLC Mailing Address: 46 DUKE ENERGY LANE City: ARDEN State: NC Zip Code: 28704 County: BUNCOMBE Day Tele No.: _828 650-0620 Cell No.: 919 696-2637 EMAIL Address:_ Antonio.Price(-r-vduke-eneM.com Fax No.: N/A E. PROJECT CONTACT (Typically Environmental Consulting/Engineering Firm) Name and Title: TODD PLATING — PROJECT MANAGER Company Name SYNTERRA CORPORATION Mailing Address: 148 RIVER ST, SUITE 220 City: GREENVILLE State: SC Zip Code: 29601 County: GREENVILLE Day Tele No.: 864-421-9999 Cell No.: 864-420-8656 EMAIL Address: iplatinjz@synterracorp.com Fax No.: 864-421-9909 F. PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: ASHEVILLE STEAM ELECTRIC PLANT 46 DUKE ENERGY LANE City: ARDEN County: BUNCOMBE Zip Code: 28704 (2) Geographic Coordinates: Latitude**: 351 28' 10.37" or ° Longitude**: 820 32' 34.79" or ° Reference Datum: PRIME MERIDIAN Accuracy: 0.01 ARC SECONDS Method of Collection: GOOGLE EARTH PRO **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: square feet NOT APPLICABLE — Tracer Study Land surface area of inj. well network: square feet (< 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated, (must be < 5% of plume for pilot test injections) H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page 2 (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. I. DESCRIPTION OF PROPOSED INJECTION ACTIVITIES AT THE SITE — Provide a brief narrative regarding the cause of the contamination, and purpose, scope, goals of the proposed injection activity: A dye trace study is proposed to identify the source of low pH water that has begun to discharge into a seep. within the Upper East Channel. see attached Figure. The Upper East Channel is a storm water conveyance swale- lined with aggregate. It was designed and installed during the excavation and closure of the former ash basin. The water from the seep has similar characteristics as groundwater from the area of the former coal pile. Sixteen ounces of red fluorescent Rhodamine WT d_e (Kingscote Chemicals Bright Dyes® FWT Red 50 Liquid) is proposed to be infiltrated into the bedrock aquifer flow zone through existing monitoring well CPA-413R, which is located in the vicinity of the former coal pile. Water quality at the seep location will then be monitored at the seep for the appearance of the dye to confirm or rule out a hydraulic connection between the two areas. The elevation of the seep is approximately 10 feet lower in elevation than the screened interval of well CPA- 4BR. J. WELL CONSTRUCTION DATA (1) No. of injection wells: Proposed 1 Existing (provide NC Well Construction Record (GW-1) for each well) — Existing Well CPA4BR (2) Appx. injection depths (BLS):_31 to 41 feet below land surface (3) For Proposed wells or Existing wells not having GW-Is, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): (a) Well type as permanent, Geoprobe/DPT, or subsurface distribution infiltration gallery (b) Depth below land surface of casing, each grout type and depth, screen, and sand pack (c) Well contractor name and certification number K. INJECTION SUMMARY NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at httR:Hdcq.nc.- ov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/,,round-water-approved-injectants. All other substances must be reviewed by the DHHSprior to use. Contact the UIC Program for more info if_ you wish to get approval for a different additive. However. please note it may take 3 months or longer. Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page 3 Injectant_ iodamine WT (FWT Red 50) Total Amt. to be injected (gal)/event: 16 oz 0.125 gal/event Injectant: Total Amt. to be injected (gal)/event: Amt. Water to be injected (gal/event): 5 gallons Total Amt. to be injected (gal/event): 5.125 gallons No. of separate injection events: 1 Est. Total Amt. to be injected (gal): 5.125 gallons Source of Water (if applicable): Steam Plant Potable Water Supph L. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. Water discharging; from the seep into th(- inper East Channel will be monitored for the presence of FWT Red 50 dye using a geochemical sonde and data log,. ger (Cps -7F). The fluorometer performance has a minimum detection limit of 0.01 parts per billion to Rhodamine dye. The geochemical sonde will be programmed to take a measurement once each day. in addition to monitoring the seep, four bedrock monitoring wells will be sampled on a weekly basis to evaluate other potential flow paths from the injection well and to provide an indication of the groundwater flow velocity: • Wells CPA-5BR and CPA-6BR will be monitored to determine if flow from the infection well CPA- 4BR is moving to the west/southwest. • Wells CPA-313R and GW-1 BR will be monitored to determine if flow from the iniection well is eastward from the injection well. Monitorirtg of these wells will be by collecting a.grab sample with a bailer and checking the water column for fluorescence using field screening, procedures. Depths to water in the four monitoring wells and the injection well will also be measured each time the wells are sampled. The tracer dye test is estimated to be conducted over a 3-month period, depending on the results of the field screening. Additional time may, be allocated, if deemed necessary to better evaluate groundwater flow and discharge to the Upper East Channel. Over time, the concentration of dye in the bedrock flow zone will decrease due to dispersion, and dilution within the Nuifer. M. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/Applicant: "I hereby certify, under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submittingfalse information. 1 agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the 15A NCAC 02C 0200 Rules. " Digitally signed by L. Bryson S. L. Bryson S. Allison Allison Date: 2020.02.14 14:23:40-05'00' Signature of Applicant L. Bryson Sheetz Allison, EHS Engineer Print or Type Full Name and Title Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page 4 Property Owner of the property is not owned bA the Well Owner/Applicant) "As owner of the property on which the injection ivell(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection ivell(s) conform to the Well Construction Standards (l--;A rtiVAC 02C.020t). " "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. Signature" of property Owner (if different from applicant) Print or Type Full Name and Title "An access agreement benveen the applicant and property owner may be submitted in lieu of a signature on this form. Please send I (one) hard color copy of this NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 707-9000 Deemed Permitted GW Remediation NOl Rev 10-14-2019 Page 5 Attachments Site Map with Seep and Monitoring Well Locations GW-1 Form for Well CPA-4BR Technical Data Bulletin — FWT Red 50 Dye Safety Data Sheet — FWT Red 50 Dye Cyclops 7 Technical Data Sheet Deemed Permitted GW Remediation NOI Rev. 10-14-2019 Page 6 PROJECT: Asheville Steam Plant WELL / BORING NO: CPA-4BR PROJECT NO: 1026.102 STARTED: 11/27/18 COMPLETED: 12/20/18 DRILLING COMPANY: Geologic Exploration NORTHING: EASTING: DRILLING METHOD: HSA/Air Rotary G.S. ELEV: ft MSL M.P. ELEV: ft MSL BOREHOLE DIAMETER: 10 and 6 IN DEPTH TO WATER: 16.60 ft TOC TOTAL DEPTH: 41.0 ft BGS NOTES: LOGGED BY: G. Barrier CHECKED BY: T. Platin w x U _ O a- O; 0 z WELL o f CONSTRUCTION Q DESCRIPTION g U a s a �J D �v m00 covering SILT, sandy -fine to medium, tan, PWR 5 SILT, sandy -fine to mediium, tan/white/ black, foliation, PWR 10 - Neat cement grout -6" sch 40 PVC surface casing SILT, sandy -fine to mediium, tan/white/ black, more defined foiliation, PWR 15 : -2" sch 40 PVC riser 20 25 - Bentonite seal BEDROCK, fractures at 25', 31', 33', 35', and 41' 30 "w 35 •',_ -Filter pack (#2 silica sand) 2" pre -packed well screen } w "r 40 45 Duke Energy Progress, LLC. SynCLIENT: 48 R PROJECT LOCATION: Arden, NC River 148 River Street, Suite 220 �e Greenville, South Carolina 29601 .synPhone:864-421-9999 PAGE 1 OF 1 WELL CONSTRUCTION RECORD This form can be used for single or multiple wells I. Well Contractor Information: NICHOLAS HAYES Well Contractor Name A - 4121 NC Well Contractor Cenificaiiun Number GEOLOGIC EXPLORATION, INC Company Name 2. Well Construction Permit ff. list ale applicable well construction perudsx (ie. Cannrp, .Sane. Variance, etc.) 3. Well Use (check well use): ❑Agricultural ❑Geothermal (I'leating/Cooling Supply) ❑ IndusiriallCummercial Non -Water Supply ❑Municipal/Public ❑Residential Water Supply (single) ❑Residential Water Supply (shared) C Inlecrtan weu: ❑Aquifer Recharge ❑Groundwater Remediation ❑Aquifer Storage and Recovery ❑Salinity Barrier ❑Aquifer Test ❑Sturmwater Drainage ❑Experimental Technology ❑Subsidence Control ❑Gcothermal (Closed Loop) ❑Tracer ❑Geothermal (Heating/Cooling Return) ❑Other (explain under #21 Remarks) 4. Date Well(s) Completed: 12/20/18 Well ID# CPA-48R 5a. Well Location: ASHEVILLE STEAM STATION Facility/thvner Name Facility ID# (ifapplicable) 200 C P & L DRIVE ARDEN 28704 Physical Address, City, and Zip BUNCOMBE County Parcel Identification No. (PIN) 5b. Latitude and Longitude in degrees/minutes/seconds or decimal degrees: (ifwell field. one faillong is sufficient) 350 28' 10,37" N 82" 32' 34.79" W 6. is (are) the well(s): 21'ermanent or ❑Tempurary 7. is this a repair to an existing well: Dyes or t]No If this is Li repair, fiR am kttmrn treq c'nnslnrc•1/ore injirrnraiiou ant/ expinirr nc�• nnam aflhe reperir iauler 421 remarks section err on the hack (J'this fhrm. 8. Number of wells constructed: 1 bar nruhiplc itlection or non-irater.supply irefls ONLY frith the some construction, tent can snhnrir one form. 9. Total well depth below land surface: 41.0 Far nntlriplr Ire/lr list all depdre ifrl/ffer¢trt (eran+plc- JQ?IXl'a@ ij)•) 10. Static water level below top or casing: 8.0 If crater level is above caring, ose '• . •• 11. Borehole diameter: 6.0110.0 For Internal Use ONLY 14. WATER ZONES i FROM TO DESCRIPTION H. ft. rr. H. 15. OUTER CASING I fur multi cased welts OR LINER Ira licablel FROM TU DIAA1e1'I THICKNESS MATERIAL 0.0 f' 23.0 ft. 6.0 t" SCH 40 PVC 16. INNER CASING OR TUBING eothermel closed-loorpi FROM TO DIAMETER THICKNESS I MATERIAL 0.0 f'• 31.0 ft. 2.0 In' SCH 40 PVC fr. I R, in. 17. SCREEN FROM TO DIAMETER SLOTSIZE THICKNESS MATERIAL 31.0 "' 41.0 fr- 2.0 IF" 010 E SCH 40 PVC* ft. I IS. GROUT FROM 'f0 MATERIAL EMPLACEM ENT MMIOD&AMUUNr 0.0 R. 21.0 rt. Ponnwnarmonirr SLURRY 0.0 f' 23.0 ft. �aat++Mfflr SLURRY ft. €t. 19. SAND/GRAVEL PACE t if applicublel FROM TO MATERIAL EMPLICEMENTMET1101) 29.0 "' 41.0 fr• 20-40 FINE SILICA SAND ft. u. 20. DRILLING LOG tattoch udditional sheeh if necessar, i FROM TO IrESCRIPTIDN Irolar, hardnesr. saiUrork h rain sirs, ete.l 0.0 ft' 5.0 ft- AIR KNIFE 5.0 fr• 17.0 fr. PWR 17.0 fr• 41.0 fe ROCK ft. ft. ft. ft. R. D. 21. REMARKS BENTONITE SEAL FROM 21,0 TO 29.0 FEET ***U-PACK SCREEN'** 22. Certification: 100W f f f 01109119 Signature of Certified Well Contractor Date Hy signing this fornc I hereby certify droi dre well(x) ivas (were) eoirsrructed in accordance with 15A NC•AC 02C .0100 or 15A NCAC 02C,0200 tVrll Construction Stnudnrelr and that u co/+y ofthis record has been provided iu the well owner. 23. Site diagram or additional well details: You may use the back of this page to provide additional well site details or well construction details. You may also attach additional pages ifnecessary. SUBMITTAL INSTUCTIONS 24a. Fur All Wells: Submit this form within 30 days of completion of well construction to the following: Division of Water Quality, Information Processing Unit, 1617 Mail Service Center, Raleigh, NC 27699-1617 24b. For Iniection Wells: In addition to sending the form to the address in 24a above, also submit a copy of this form %vinim 30 days of completion at well 12. Well construction method: AIR construction to the lullowing: (i.e. auger, rotary, cable, direct push, etc ) Division of Water Quality, Underground Injection Control Program, FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center, Raleigh, NC 27699-1636 13a. Yield (gpm) Method of test: 24c. For Water Sit nDly & Injeclion Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of 13b. Disinfection type: Amount: _ completion of well construction to the county health department of the county _ where constructed. (in.) (ft.) Form CiW-1 North Carolina Department of Environment and Natural Resources - Division of Water Quality Revised Rai. 2013 \\ 1 fir DYES Division of Kingscote Chemicals TECHNICAL DATA BULLETIN WATER TRACING DYE FWT RED PRODUCTS Bright Dyes FWT Red liquid products are specially formulated versions of Rhodamine WT dye for convenient use in water tracing and leak detection studies. This bright, fluorescent red dye is certified by NSF International to ANSI/NSF Standard 60 for use in drinking water. It may be detected visually, by ultraviolet light and by appropriate fluoremetric equipment. Today it is most often used visually. Visually the dye appears bright pink to red, depending on its concentration and under ultraviolet light as bright orange. The dye is resistant to absorption on most suspended matter in fresh and salt water. However, compared to Bright Dyes FLT Yellow/Green products it is significantly more resistant to degradation by sunlight and when used in fluoremetry, stands out much more clearly against background fluorescence. As always the suitability of these products for any specific application should be evaluated by a qualified hydrologist or other industry professional. General Properties Tablets L' uids 50 Powders Detectability of active ingredient 1 Visual <100 ppb Visual <100 ppb Visual <100 ppb Maximum absorbance wavelength 2 550/588 nm 550/588 nm 550/588 nm Appearance Dark red convex 1.6cm diameter Clear dark red Nueous solution Dark red fine powder NSF (Max use level in potable water) 0.3 ppb 0.4 ppb 0.1 ppb Weight 1.35 gms + 0.05 Dissolution Time 3 50% < 3 minutes 95% < 6 minutes 50% < 3 minutes 95% < 6 minutes Specific Gravity 1.03 + 0.05 A 250 C Viscosity 4 1.3 cps pH 8.7+0.5 A 250C Coverage of Products One Tablet One Pint Liquid One Pound Powder Light Visual 604 gallons 62,500 gallons 600,000 gallons Strong Visual 60 gallons 6,250 gallons 60,700 gallons Caution: These products may cause irritation and/or staining if allowed to come in contact wit the skin. The use of gloves and goggles is recommended when handling this product, as with any other dye or chemical. To our best knowledge the information and recommendations contained herein are accurate and reliable. However, this information and our recommendations are furnished without warranty, representation, inducement, or license of any kind, including, but not limited to the implied warranties and fitness for a particular use or purpose. Customers are encouraged to conduct their own tests and to read the material safety data sheet carefully before using. 1 In deionized water in 100 ml flask. Actual detectability and coverage in the field will vary with specific water conditions. 2 No significant change in fluorescence between 6 and 11 pH. 3 (One tablet, 1 gram ofpowder), in flowing deionized water in a 10 gallon tank. 4 Measured on a Brookfield viscometer, Model LV, UL adapter, 60 rpm @ 251 C. Kingscote Chemicals, 3334 S. Tech Blvd., Miamisburg, Ohio 45342 Telephone: (937) 886-9100 Fax: (937) 886-9300 Web: www.brightdyes.com gscote CHEMICALS Issue Date: 09-Jan-2014 Revision Date: 18-Jan-2019 1. Identification Product Identifiers Product Name: Bright Dyes® FWT Red 50 Liquid Product Number: 106053 Recommended Use & Restrictions on Use Water tracing & leak detection dye Manufacturer/Su.p_p tier Kingscote Chemicals, Inc. 3334 South Tech Blvd. Miamisburg, OH 45342 U.S.A. Emergency Telephone Number Company Telephone Number: (937) 886-9100 Emergency Telephone (24 hr): INFOTRAC (800) 535-5053 (North America) +1-352-323-3500 (International) 2. Hazards Identification Safety Data Sheet Version Number: 2.2 Classification This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of this product. This SDS should be retained and available for employees and other users of this product. 3. Composition/Information on Ingredients This product is not hazardous according to OSHA 29 CFR 1910.1200. Components not listed are not hazardous or are below reportable limits. 4. First -Aid Measures I First -Aid Measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If eye irritation persists: Get medical advice/attention. Skin Contact Wash thoroughly with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Inhalation Remove to fresh air. If breathing is difficult, administer oxygen; seek medical attention immediately. Page 1 of 6 Bright PyesO FWT Red 50 Liquid Revision Date: 18-Jan-2019 Ingestion Rinse mouth. DO NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Get medical attention if large quantities were ingested or if nausea occurs. Most Important Symptoms and Effects Symptoms Will cause staining of the skin on contact. May cause eye irritation. Inhalation of dust may cause respiratory irritation. Ingestion may cause urine to be a red color until the dye has been washed through the system. Indication of Any Immediate Medical Attention and Special Treatment Needed Notes to Physician Treat symptomatically. S. Fire -Fighting Measures Suitable Extinguishing Media Water spray (fog). Carbon dioxide (CO2). Dry chemical. Regular foam. Unsuitable Extinguishing Media Not determined Specific Hazards Arising from the Chemical Product is not flammable. Burning/combustion may produce oxides of carbon and nitrogen (NOx). Protective Equipment and Precautions for Firefighters Wear self-contained breathing apparatus pressure -demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. Accidental Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protective equipment as recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12 and Section 13. Methods and Material for Containment and Cleaning Up Methods for Containment Methods for Cleaning Up Precautions for Safe Handlin�2 Prevent further leakage or spillage if safe to do so. Sweep up and collect into suitable containers for disposal. Flush area with water. 7. Handling and Storage Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practices. Use personal protection recommended in Section 8. Avoid contact with skin, eyes, or clothing. Avoid breathing dusts. Contaminated clothing should be thoroughly washed before reusing. Page 2 of 6 Bright Dyes6 FWT Red 50 Liquid Revision Date: 18-Jan-2019 Conditions for Safe Storage, Includinp Incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry, and well - ventilated area. Keep from freezing. Incompatible Materials No materials to be especially mentioned 8. Exposure Controls / Personal Protection Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual Protection Measures, Such as Personal Protective Equipment: Eye/Face Protection Goggles. Skin & Body Protection Rubber gloves. Suitable protective clothing. Respiratory Protection No protection is ordinarily required under normal conditions of use. Hygiene Measures Handle in accordance with good industrial hygiene and safety practices. 9. Physical and Chemical Properties Information on Basic Physical and Chemical Properties_ Physical State Liquid Appearance Color Property PH Melting/Freezing Point Boiling Point/Range Flash Point Evaporation Rate Flammability (solid, gas) Upper Flammability Limits Lower Flammability Limits Vapor Pressure Vapor Density Relative Density Specific Gravity Solubility Partition Coefficient Auto -ignition Temperature Decomposition Temperature Viscosity Dark red liquid Dark red Values Not determined Not determined Not determined Not applicable Not applicable Liquid — not applicable Not applicable Not applicable Not applicable Not applicable Not applicable Not determined Highly soluble in water Not determined Not determined Not determined Not determined Odor Mild Odor Threshold Not determined Page 3 of 6 Bright Dyes® FWT Red 50 Liquid Revision Date: 18-Jan-2019 10. Stability and Reactivity Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible Materials No materials to be especially mentioned Hazardous Decomposition Products Oxides of carbon and nitrogen (NOx). 11: Toxicological Information Information on Likely Routes of Exposure Inhalation Avoid breathing vapors or mists. Ingestion Do not ingest. Skin Contact May cause an allergic skin reaction. Eye Contact Avoid contact with eyes. Delayed, Immediate, and Chronic Effects from Short- and Long -Term Exposure May cause an allergic skin reaction. Numerical Measures of Toxicity Not determined Symptoms Associated with Exposure See Section 4 of this SDS for symptoms. Carcinov,eiert NTP None IARC None OSHA None Page 4 of 6 Bright Dyes® FWT Red 50 Liquid Revision Date: 18-Jan-2019 12. Ecological Information EcotoxickV This product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Not available Persistence/Degradability Not determined Bioaccumulation Not determined Mobility Not determined Other Adverse Effects Not determined 13. Disposal Considerations Waste Disposal Methods Dispose of in accordance with federal, state, and local regulations. Contaminated Packaging Do not re -use empty containers. Dispose of containers in accordance with federal, state, and local regulations. 14. Transport Information Note See current shipping paper for most up-to-date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated OMDG Not regulated 15: Regulatory Information International Inventories TSCA Listed U.S. Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). Page 5 of 6 Bri¢ht Dves® FWT Red 50 Liu uid Revision Date: 18-Jan-2019 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right -to -Know This product does not contain any substances regulated under applicable state right -to -know regulations. 16: Other Information HMIS Health Hazards Flammability 1 0 NFPA Health Hazards Flammability 1 0 Issue Date 09-Jan-2014 Revision Date 18-Jan-2019 Revision Note Biennial Review Instability 0 Physical Hazards 0 Special Hazards Not determined Personal Protection B Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 6 of 6 CYCL')P7F SUBMERSIBLE SENSORS Cyclops-71F Submersible Sensors Cyclops-71' Sensors are high performance, compact submersible sensors designed for integration into any platform that provides power and datalogging. Available with multiple optical configurations, Cyclops-7F Sensors have a universal 1/0 for connection to parent systems. Recently updated to have a faster settling time, Cyclops-71' is ready to make measurements 1 second after power up. Configured with DataBank Handheld 1 Datalogger for field sampling `QQQ I Easily integrates with Submersible Loggers for in situ sampling } Cyclops Logger sold by PME Trimeter sold by Eureka Water Probes I Configured with Ayyeka Wavelet for remote monitoring AYYEKA , Reliable Instruments for an Unreliable World Cyclops-7F Highlights • Small and available in multiple housing/connector configurations • Built-in light scatter rejection • Low power consumption • Easily integrates into any third -party platform • Interfaces with DataBank Handheld Datalogger • Submersible Loggers Available • Explorer enables various lab applications Available Sensors • Blue Green Algae Phycoerythrin (marine) Phycocyanin (freshwater) •CDOM/FDOM • Chlorophyll in vivo Blue excitation - Red excitation (high CDOM) • Fluorescent Dye Tracing Fluorescein - PTSA - Rhodamine • Hydrocarbons - Crude Oil - Refined Fuels • Turbidity • Wastewater Monitoring Optical Brighteners Tryptophan Custom Optics Available: 260-900 nm r'YCL r)PS-7F SUBMERSIBLE SENSORS Linearity: 0.99132 CDOM/FDOM 0.1 ppb* 0-1,500 ppb* 0.5 ppb** 0-3,000 ppb** Chlorophyll in vivo Blue excitation 0.03 µg/L 0-500 µg/L Red excitation 0.3 µg/L 0-500 µg/L Fluorescein Dye 0.01 ppb 0-500 ppb Oil - Crude 0.2 ppb** 0-1,500 ppb** Oil - Fine 0.4 ppm*** 0-20 ppm*** Optical Brighteners 0.6 ppb** 0-2,500 ppb** Phycocyanin 2 ppbPc 0-4,500 ppb" Phycoerythrin 0.1 ppbPE 0-750 ppbPE PTSA Dye 0.1 ppb** 0-650 ppb** Rhodamine Dye 0.01 ppb 0-1,000 ppb Tryptophan 3 ppb 0-5,000 ppb Turbidity 0.05 NTU 0-1,500 NTU * Quinine Sulfate ** PTSA (1,3, 6, 8 - Pyre netetrasulfonic Acid Tetrasodium Salt) ** BTEX (Benzene, Toluene, Ethylbenzene, Xylenes) PC Phycocyanin pigment from Prozyme diluted in Deionized water PE Phycoerythrin pigment from Prozyme diluted in Deionized water 240 240 240 145 250 530 200 160 270 320 175 540 120 Ordering Information Stainless Steel, Titanium and Plastic Housings available. Titanium and Plastic withstand corrosion better than stainless steel and are recommended for stationary deployments in highly corrosive environments. ACCESSORIES Solid Secondary Standards Flowthrough Cap Shade Cap (Recommended for most deployments) 0.6 Meter Pigtail Cable with Locking Sleeve 5 Meter Pigtail Cable with Locking Sleeve 10 Meter Pigtail Cable with Locking Sleeve 25 Meter Pigtail Cable with Locking Sleeve Explorer Contact Us Toll -Free : 1.877.316.8049 Email: sales@turnerdesigns.com Address: Phone: 408.749.0994 Web: www.turnerdesigns.com 1995 N. 1 st Street Fax: 408.749.0998 San Jose, CA 95112 Reliable Instruments for an Unreliable World Length x Diameter: 5.7" x 0.9"; 14.48 x 2.23 cm (SSt or Ti) 5.7"x 1.25 , 14.48 x 3.18 cm (Delrin) Weight: 5.0 oz; 142 grams Ili ! ! !E." lid= l+1lnT'ir• '{ -:�r Temperature Range: Ambient: 0 to 50 deg C Water Temp: -2 to 50 deg C Depth Range: 600 meters Signal Output: 0 - 5 VDC Supply Voltage Range: 3 - 15 VDC S-0209 Rev. F