WQ0000020_2015 Annual Report_20160223

(' DUKE
ENERGY®
PROGRESS
February 17, 2016
North Carolina Department of Environmental Quality
Attn: Division of Water Resources - Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Duke Energy Progress, LLC (DEP)
2015 Annual Report for Ash Reuse Permit WQ0000020
Dear Sir or Madam:
Duke Energy Progress, LLC
410 S. Wilmington Street/NC15
Raleigh, NC 27601
F?FCFRUED
FEB 2 3 2016
RECEIVEDI NCDEO/M
FEB 2 3 2016
As specified in the Ash Reuse Permit WQ0000020, dated February 17, 2006 and extended byl4ws Rcharge
Law 2009-406 and 2010-177, records of ash utilization and representative ash analyses are t9bitnitting Unit
submitted annually to the Division of Water Resources. During 2015, the Asheville and Roxboro Plants
distributed ash for reuse purposes and were subject to the applicable permit requirements. No ash
distribution projects were conducted during 2015 at the other sources listed in Condition 11.3.a., of the
permit, i.e. Cape Fear, Lee, Mayo, Sutton and Weatherspoon Steam Electric Plants during the time the
permit was applicable.
Roxboro Steam Electric Plant
Enclosed are three copies of: (1) analytical data from representative ash samples for Roxboro, and (2)
ash distribution forms for Roxboro which was subject to the 2006 permit through August 2015. Annual
Toxicity Characteristics Leaching Procedure (TCLP) data can be found in the enclosed table.
Asheville Steam Electric Plant
The Asheville Steam Electric Plant provided ash for fill projects at the Asheville Airport which have
groundwater monitoring wells associated with them.
Enclosed are three copies of: (1) analytical data from representative ash samples for Asheville, and (2)
ash distribution forms for Asheville which was subject to the 2006 permit through August 2015. Annual
Toxicity Characteristics Leaching Procedure (TCLP) data can be found in the enclosed table.
Groundwater results for calendar year 2015 at the Area I background well and review boundary wells
showed the following:
The background well (MW-4A) and all three review boundary wells had pH values below the
range of 6.5 to 8.5 SU for both monitoring events (April and November 2015);
• MW-4A had iron and manganese values above the standard for both events.
• MW-5 had a manganese value above the standard for the April and November events.
Groundwater results for calendar year 2015 at the Area III background well and review boundary wells
showed the following:

WQ0000020 —Annual Submittal
February 17, 2016
• The traditional background well (MW1A) produced values for the April event and was replaced
with background well MW1AR-A4 which produced values for the November event. MW1A had
a pH value below the range of 6.5 to 8.5 SU for the April event. For November, MW1AR-A4 had
a manganese value greater than the standard.
• All review boundary wells had pH values below the range of 6.5 to 8.5 SU for both monitoring
events (April and November).
• MW-1 had iron and manganese values above the standard for both events.
• MW-2 had manganese values above the standard for both events
• MW-3 had an iron value above the standard for April and manganese values above the standard
for both events
• MW-4 had an iron value above the standard for April and manganese values above the standard
for both events
• MW-5 and MW-6 had no parameters above the standards
• MW-7 had iron and manganese values above the standard for the April event
Groundwater results for calendar year 2015 at the Area IV background well and review boundary wells
showed the following:
The traditional background well (MW1A) produced values for the April event and was replaced
with background well MW1AR-A4 which produced values for the November event. MW1A had
a pH value below the range of 6.5 to 8.5 SU for the April event. For November, MW1AR-A4 had
a manganese value greater than the standard.
• For all six review boundary wells, only one, MW-5 had any values above a standard. MW5 had
manganese values above the standard for the April and November events.
The form 'DMSDF' for the Asheville Steam Plant has been marked as 'compliant' during calendar year
2015 with all conditions of the permit as DEP does not believe that a contravention of the groundwater
standards occurred at these fill sites.
Roxboro and Sutton — Post September 2015
As the subject reuse permit expired on September 2, 2015 and was replaced by a permit applicable only
to the Asheville Airport structural fill, ash reuse information after August 2015 from the Roxboro Steam
Electric Plant and the Sutton Steam Electric Plant is enclosed as a courtesy.

WQ0000020 — Annual Submittal
February 17, 2016
As DEP no longer holds a reuse permit for these sites, this will be the final annual submittal as DEP is not
subject to 15A NCAC 02T .1209. DEP will provide ash basin ash reuse information to DEQ if requested by
DEQ in the future.
Please contact me at [e-mail] or 919-546-7863 if you have any questions
concerning the above.
Sincere ,
J6 R. Toepf r, P.E.
Lead Engineer
Attachments
JT/jt
3

WQ0000020—Annual Submittal
February 17, 2016
February 17, 2016
Duke Energy Progress, LLC
Annual coal ash TCLP test required per
Permit WQ0000020 Dated February 17, 2006
Results in (mg/L)
Parameter (limit —
mg/L)
Asheville Plant
Coal Ash
Sample Dated
01/06/2015
Pace Analytical Services, Inc.
Roxboro Plant
Bottom Ash
Sample Dated
07/10/2015
Pace Analytical Services, Inc.
Arsenic (5.0)
0.14
< 0.050
Barium (100.0)
2.9
< 0.25
Cadmium (1.0)
< 0.0050
< 0.0050
Chromium (5.0)
< 0.025
< 0.025
Lead (5.0)
< 0.025
< 0.025
Mercury (0.2)
< 0.00020
< 0.00020
Selenium (1.0)
< 0.10
< 0.10
Silver (5.0)
< 0.025
< 0.025

WQ0000020—Annual Submittal
February 17, 2016
cc/att: Mr. Sean DeNeale — EC13K
Mr. Robert Howard — Roxboro Plant
Mr. E. Shannon Langley — NC15
Mr. Herbert Lea — Mayo Plant
Mr. Tony Mathis - ECO2F
Mr. Mike Graham — Lee Plant
Ms. Teresa Williams —Asheville Plant
Ms. Toya Ogallo — NC15
Ms. Dulcie F. Phillips — Mayo Plant
Mr. Tim Smart - ECO2F
Mr. Jon Stamas — Cape Fear Plant
Mr. Ed Sullivan - EC13K
Mr. R. Kent Tyndall —Sutton and Weatherspoon Plants
5

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION -AND SUMMARY FORM
WQ PERMIT #: WQ0000020 FACILITY
NAME —Duke Energy Progress, LLC Roxboro Plant
PHONE;, 336-597-6284 COUNTY::. Person. OPERATOR: Duke Energy. Progressi LLC
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Sonfee(s) and "Residual In"=Volume only) and Part C):.
a Distribution and Marketing (complete Parts A, B, and C)
Was the facility in operation during the past calendar year? : Yes 0 No ❑ —► If. No skip parts A, B, C and certify form below
- . Part A*::.::: rt B*:::::
:::Pa
Volume (dry tons) Recipient Information
.Month : Sources(s) (include NPDES # if. . ... .
applicable) Amendment/
pp ) Residual In Product Out, .Name(s) Volume (dry tons): Inteoded use(s)
Bulking Agent
_.
January Roxboro Plant bottom ash 0: 0 479$.1 See Supplemental slicers 4798 I - II tiffs u d f -
February
Roxboro Plant bott6ki ash
0
0
3835.69
-
3835.69
aggregate in
March
Roxboro Plant bottom ash
0
0 -
6900.E
6900.6:
cement blocks .
April
Roxboro Plant.bottom ash
0
0
5814.I
5814.1:
May
Roxboro Plant bottom: ash
4084.65
4084:65
June
Roxboro. Plant bottom ash
0
0.
4993.5
4993.5
July.
Roxboro: Plant bottom ash
0
0
5591.75.
5591.75-
August
Roxboro Plant bottom ash
0
0.
6029.8
6029.8
September
Roxboro Plant bottom ash
0:
0
NA
_. .
,NA
October
Roxbom'Plant bottom ash
0
0
NA
NA
November
-Roxboro Plant bottom ash
0
0
NA
NA
December
Roxboro Plant bottom ash
0
0
NA
NA.
Total from FORM DMSDF.{sup)
0
0
:-. _:•:� •,• •� �,��r•
Totals: Annual (dry tons):
0
0
42048.19
'
42048.19
Amendment(s) used: BulkingAgent(s) used:
• If more space is required, attach additional information sheets (FORM DMSDF (supp)): Tota! Number of Form DMSDF (Sapp) 4 .
Part C:
Facility was compliant during the past calendar year with all conditions of the land application permit p: Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: M No ---► If. No, Explain: In Narrative
1. All monitoring was done in accordance with:the permit and reported for the year as required and: three (3) copies: of certified:labomtory. results are attached.
2. All operation and maintenance requirements were compiled with or, iti'the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at.a monitoring well.
"I certify, under penalty of law, that the above in rmation is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties forsubmitting false information; Inc ding: the possibility: of fines -and imprisonment for koowing violations.
Signature of P itt .. . = Date .: Signature of Preparer**
.....
i3a is
(if different from Pennittee)
*"Preparer is defined in 40 CFR Part 503.9(r) and I SA NCAC 2T .1102 (26)
DENR FORM DMSDF (1212006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0000020 FACILITY NAME: Duke Energy Progress, LLC Roxboro Plant
PRONE: 336-597-6284 COUNTY: Person OPERATOR: Duke Energy Progress LLC
FACILITY TYPE (please check one): ® Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
0 Distribution and Marketing (complete Parts A, and B)
Part A*:
Month Sources(s) (include NPDES # if
I applicable)
Volume (dry tons)
Amendment/ I Residual In Product Out
Bulking Agent f
Part B*:
Recipient Information
Name(s) Volume ) dry Intended use(s)
lianuary I Roxboro Plant bottom ash I 1 1 4798.1 1 PriceLite/Adams 1 1478.85 lull used as aggregate
PriceLite/Leonard Block
102.35 in cement blocks
PriceLite/Greystone
206
PriceLite/General Shale
1982.1
PriceLite/Chandler
121.95
PriceLite/Blue Stone'
50.95
PriceLite/Southeastem
855.9
February
Roxboro Plant bottom ash
3835.69
PriceLite/Adams
1690.75
PriceLite/Leonard Block
75.35
PriceLite/Greystone
0
PriceLite/General Shale
1396.49
PriceLite/Chandler
144.65
PriceLite/Blue Stone
25.25
PriceLite/Southeastem
503.2
March
Roxboro Plant bottom ash
6900.6
PriceLite/Adams
2841.4
PriceLite/Leonard Block
301.75
PriceLite/Greystone
104.05
PriceLite/General Shale
2373.3
PriceLite/Chandler
224.7
PriceLite/Blue Stone
51.15
PriceLite/Southeastern
1004.25
Totals:
Annual (dry tons):
0
0
15534.39 15534.39
Amendment(s) used:l I Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) 1 of 4
DENR FORM DMSDF (Supp) (1212006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT 0: WQ0000020 FACILITY NAME: Duke Energy Progress, LLC Roxboro Plant
PHONE: [phone] COUNTY: Person OPERATOR: Duke Energy Progress LLC
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
p Distribution and Marketing (complete Parts A, and B)
Part A*: I Part B*:
Volume (dry tons)
Month Sources(s) (include NPDES # if
applicable) Amendment/ Residual In Product Out
Bulking Agent
aril I Roxboro Plant bottom ash I I I SR l d 1
Recipient Information
Name(s) Volume (dry Intended use(s)
tons)
PArPr.UP/A d--- "I n19 cn n . wa a ,.....
PriceLite/Leonard Block
176.70
in cement blocks
PriceLite/Greystone
390.35
PriceLite/General Shale
1,945.05
PriceLite/Chandler
321.20
PriceLiteBlue Stone
50.90
PriceLite/Southeastem
503.40
May
Roxboro Plant bottom ash
4,084.65
PriceLite/Adams
1,784.65
PriceLite/Leonard Block
76.00
PriceLite/Greystone
51.65
PriceLite/General Shale
982.65
PriceLite/Chandler
501.70
PriceLite/Blue Stone
51.65
PriceLite/Southeastern
636.35
June
Roxboro Plant bottom ash
4,993.50
PriceLite/Adams
2,298.90
PriceLite/Leonard Block
-
PriceLite/Greystone
298.75
PriceLite/General Shale
1,277.15
PriceLite/Chandler
375.20
PriceLiteBlue Stone
52.00
PriceLite/Southeastem
691.50
Totals:
Annual (dry tons):
0
0
14892.25 14892.25
t r►1i1auuu1cuits/ wUu:1 I nuixmg ngengs) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): 'total Number of Form DMSDF (Su pp) 2 of 4
DENR FORM DMSDF (Supp) (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
Supplemental Information
WQ PERMIT #: WQ0000020 FACILITY NAME: Duke Energy Progress, LLC Roxboro Plant
PHONE: [phone] COUNTY: Person OPERATOR: Duke Energy Progress LLC
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
El Distribution and Marketing (complete Parts A, and B)
Part A*:
Month Sources(s) (include NPDES # if
applicable)
Roxboro Plant bottom ash
Volume (dry tons)
Amendment/ I Residual In Product Out
Bulking Agent
5591.75
Part B*:
Recipient Information
Names) Volume (dry Intended use(s)
tons)
PriceLite/Adams 2.800.05 11 used as aeereeatt
PriceLite/Leonard Block
-
in cement blocks
PricaLite/Greystone
752.50
PriceLite/General Shale
1,154.50
PriceLite/Chandler
273.70
-
PriceLiteBiue Stone
103.90
PriceLite/Southeastert
507.10
August
Roxboro Plant bottom ash
6029.8
PriceLite/Adams
3,282.20
PriceLite/Leonard Block
-
PriceLite/Greystone
125.65
PriceLite/General Shale
1,511.65
PriceLite/Chandler
450.60
PriceLiteBlue Stone
26.20
PriceLite/Southeastem
534.60
September
Roxboro Plant bottom ash
NA
Totals:
Annual (dry tons):
0
0
11621.55 11621.55
J Amendment(s) used:l I BUIXIng Agent(s) usea:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp) 3 of 4
DENR FORM DMSDF (Supp) (12/2006)

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: WQ0000020 FACILITY NAME:
PHONE:[phone] COUNTY:
FACILITY TYPE (please check one):
Supplemental Information
Duke 1
Person
LLC Roxboro Plant
OPERATOR: Duke
❑ Surface Disposal (complete Part A - "Month", "Souree(s)" and "Residual In" columns only)
0 Distribution and Marketing (complete Parts A, and B)
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
October
Roxboro Plant bottom ash
NA
November
Roxboro Plant bottom ash
NA
December
Roxboro Plant bottom ash
NA
0 0
Totals:
Annual (dry tons):
0
0
Amendment(s) used:1
Bulking Agents) used:
(supp)): Total Number of Form DMSDF (Supp) 4 of 4
* If more space is required, attach additional information sheets (FORM DMSDF
DENR FORM DMSDF (Supp) (1212006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM R.SSF -B
Parameter
(in fig)
Conc.
Limit
m a
Sain le or Com osite
Date
01/13/15
02/14/15
03/20/15
04/04/15
05/19/15
06/17/15
07/10/15
08/20/15
09/09/15
'10105115
11/18/15
12/07/15
Percent Solids {%)
NA
80.7
88.8
69.7
84.4
38.5
78.3
. 87.7
.47.8
43.8
811
82.5
80.6
Arsenic
75
2.1
<0.92
1 2.9
5
13.2
1.4
1.9
2.8
<1.9
<1.1
2.4 -
0.99
Cadmium
85
<0.084 :
_ <0.092
: <0.14:
: -4.079
<0.21
-<0.090
. <0.076
�<0:16
<0J9
<6A1.
<0.083 .
0.24
Copper ..:
.41300
4.6
A.9
8.5
8.8 :
24A
7.8
6.5
11.9 -
<0.95
.1.2
6.8
13.4
Chromium :
NA
2
2.3
5.8
5.3
16.6
5:6
4
7.3
<0.95
<0S4
3.6
T.5
Lead::'
840
- :
<0.46
1:1
L1
4.1
0.85
0.93
1.8 '
<0.95 .:
<0.54 .
1.6
615
Mercury
57
<0.0045
<0.0042
<0.0058.
<0.0047
: , 0.018
<0.0030
<0.0044
<0.0080
<0.0095
<0.0037
<0.0049
<0.0051
Molybdenum
75 .
<0.42 .
0.64.
0.8
1.1
2.8
1:.3
0.82
.1.4-
<0' 95
<0.54
0.82:
2S .
Nickel
420 -
3.T
4.1::
6.8
6.7
14.7
6.3
4.1
7.4
<0.95
0.6-4
4:6::
3.1:::
Selenium
100
<0.84
<0.92
1.5
<039
6.2
<0.90.
<036 .
_ <1.6 ,
. . 3.5
<1.1
<0.83
<0.75
Zinc .
-7,500
2.2
2.6
4.6
4.1
17.2
7.5
4.8
6.2 -
<1.9
<1.1
5.5
12.4
Total Phosphorus
NA
.36.1
38.2
-106
47.7.
330:.
58.51 ,
: 713.: ,
177 :.::
126
21.2
9.1
:: 36.5
- TKN
NA
NA
NA
NA
NA
NA:
NA
NA-
NA
NA
NA'
NA
NA
Ammonia -Nitrogen
NA'
NA:
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Nitrate and Nitrite
NA
NA.
NA
NA
NA
NA
NA
NA I
NA.
NA
NA
NA
NA
ror surrace arsposal ractuties the ceiling concentration limits listed to this Corm are not,applicable:.Reference the individual. it for metals limits. - -
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are.significant.: ,
penalties for submitting false inf ation ;luding:the possibility of fines. and imprisonmerlt:for knowing violations."
Signature of Preparer Date .. .
$Preparer is defined in 46'LTR Part 503.9(r) and 15A NCAC 2T .1102.(26)
_. .
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed. for aver the past
calendar yeah. Use additional forms as needed.
WQ Permit Number: WQ0000020 aLaboratory: 1) Pace Analytical Services, Inc.
Facilit = ,
Y bic oro •. ant :Name:.D :Duke Energy rogress2) _
Residual Source 3)...
NPDES # or WQ#:: 4)
WWTP Naine:
Residual Ansdvsis nnfn
.
Parameter
(mg/kg)
.Sampie: or Com osite Date:::::
01/13/15
02/14/15
:03/20/15
04/04/15
05/19/15
06/17/15
0.7/10/15
08/20/15.
"
09/09/15
10/05/15
1.1/18/15
12/07/15
Barium
31.6...
52....
73......
585.
168
54.6.:
: 41 ::::
:60.2 :::
, 14.5 ,
::::11.2 ::
- : 77.1
30.3
Calcium
882
2420-
3110
2740
4640
3540
1840:
2760
-1220
391
1590
-504
Magnesium
129
227
704
454
1080
456
424
624
130
48.2
300
128
Manganese
12.4
-18
35.8
34.9
65.2
26.7
21A
40.3..
3.8
3
30.9
13:4
Potassium''
<419
<461
<689
<395
<1030
679.
<380
<781-
<951
<541.
<415-
<374 .
Silver
<0.42-
<0.46
<0.69
<0.40
<1.0
<0.45
<0.38
<0.78
<0.95
<0.54
<0.42
<0.37
Sodium
<419:
<461
<689
<395
<1030
<450
<380
<781
:<951
<541
<415
<374
pH f S.U.) *
8,
8 :
8.1
8.4:::.
7.9 :
8.6 .:
7.5
: 7.9
7.7
8
7.7
7.1
*pH measured at
time of parameter analyses
"I certify, under penalty of.law,'O;Rt this document was prepared under my direction or supervision in: accordance with a.system
designed to assure that qualified personnel properly: gathered and .evaluated: the information submitted: lam aware that there are. .
significant penalties for submittin :false information,:including the possibility of fines and imprisonment for knowing violations:"
z
Signature of.Prepa ' , _ _ _ Date
.. _ ......
*Preparer is defined :in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DE NR FORM RSSF : - B (1212006)

aceAnalytical
www.pscelabs com
r
ANALYTICAL RESULTS
Project: Rox Ash Resue 1/13
Pace Project No.: 92234542
Pace Analytical Services, Inc,
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: ASH REUSE Lab ID: 92234542001 Collected: 01/13/15 08:00 Received: 01/22/15 12:25 Matrix: Solid
Results reported on a "dry -weight" basis
Parameters
Results Units ReportLimit
OF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method": EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
2.1 mg/kg
0.84
1
01/26/15 17:05 01/26/15 23:47 7440-38-2
Cadmium
31.6 mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7440-39-3
Calcium
NO mg/kg
0.084
1
01/26/15 17:05 01/26/15 23:47 7440-43-9
Chromium
882 mg/kg
8.4
1
01/26/15 17:05 01/26/15 23:47 7440-70-2 M1
Copper
2.0 mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7440-47-3
Lead
4.6 mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7440-50-8
Magnesium
0.68 mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7439-92-1
Manganese
129 mg/kg
8.4
1
01/26/15 17:05 01/26/15 23:47 7439-95-4
Molybdenum
12.4 mg/kg
0.42
1
01/26/15 17:05 01/2611523:47 7439-96-5
Nickel
NO mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7439-98-7
Potassium
3.7 mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7440-02-0
Selenium
NO mg/kg
419
1
01/26/15 17:05 01/26/15 23:47 7440-09-7 M1
Silver
NO mg/kg
0.84
1
01/26/15 17:05 01/26/15 23:47 7782-49-2
Sodium
NO mg/kg
0.42
1
01/26/15 17:05 01/26/15 23:47 7440-22-4
Zinc
NO mg/kg
419
1
01/26/15 17:05 01/26/15 23:47 7440-23-5
2.2 mg/kg
0.84
1
01/26/15 17:05 01/2611523:47 7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
ND mg/kg
0.0045
1
01/27/1512:00 01/27/1514:05 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
19.3 %
0.10
1
01/28/15 18:41
9045 pH Soil
Analytical Method: EPA 9045.
pH at 25 Degrees C
8.0 Std. Units
0.10
1
01/25/15 14:15 D6,H3
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
36.1 m /k
9 9
6.5
1
01 /27/15 10:38 7723-14-0
Date: 01/29/2015 02:59 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

aceAnaljftal
wwwpacelabs.cam
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 2/14115
Pace Project No.: 92239874
Sample: Ash Reuse Lab ID: 92239874001 Collected: 02/14/15 11:30 Received: 03/05/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis
and are adjusted for percent moisture,
sample
size
and any dilutions.
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
ND mg/kg
0.92
1
03/10/15 16:30 03/10/15 22:25 7440-38-2
Cadmium
52.0 mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7440-39-3
Calcium
ND mg/kg,
0.092
1
03/10/15 16:30 03/10/15 22:25 7440-43-9
Chromium
2420 mg/kg
9.2
1
03/10/15 16:30 03/10/15 22:25 7440-70-2 M1
Copper
2.3 mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7440-47-3
Lead
4.9 mg/kg
0.46
1
03/10/15 16:30 -03/10/15 22:25 7440-50-8
Magnesium
ND mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7439-92-1
Manganese
227 mg/kg
9.2
1
03/10/15 16:30 03/10/15 22:25 7439-95-4
Molybdenum
18.0 mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7439-96-5 '
Nickel
0.64 mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7439-98-7
Potassium
4.1 mg/kg
0.46
1
03/10/15 16:30 03/10/15 22:25 7440-02-0
Selenium
ND mg/kg
461
1
03/10/15 16:30 03/10/15 22:25 7440-09-7
Silver
ND mg/kg
0.92
1
03/10/15 16:30 03/10/15 22:25 7782-49-2
Sodium
ND mg/kg
0.46
.1
03/10/15 16:30 03/10/15 22:25 7440-22-4
Zinc
ND mg/kg
461
1
03/10/15 16:30 03/10/15 22:25 7440-23-5
2.6 mg/kg
0.92
1
03/10/15 16:30 03/10/15 2225 7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method:
EPA 7471
Mercury
ND mg/kg
0.0042
1
03/10/1518:30 03/11/1513:49 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
11.2 %
0.10
1
03/12/15 15:11
9045 pH Soil
Analytical Method: EPA 9045
pH at 25 Degrees C
8.0 Std. Units
0.10
1
03/10/15 10:50 D6
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
38.2 mg/kg
4.9
1
03/10/1514:07 7723-14-0 M1,Ri
Date: 03/12/2015 04:27 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

/55'ceAnalXicala
WM.Pacelabs.com
ANALYTICAL RESULTS
Project: ROX-Ash Reuse 3/19/15
Pace Project No.: 92242887
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 2728E
[phone]
Sample: Ash Reuse Lab ID: 92242887001 Collected: 03/20/15 08:30 Received: 03/26/15 12:35 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units Report Limit
DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3050
Arsenic
Barium
2.9
mg/kg
1.4
1
03/31/15 14:05 03131/1521:40 7440-38-2
Cadmium
73.0
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7440-39-3
Calcium
ND
mg/kg
0.14
1
03/31/15 14:05 03/31/15 21:40 7440-43-9
Chromium
3110
mg/kg
13.8
1
03/31/15 14:05 03/31/15 21:40 7440-70-2
Copper
5.8
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7440-47-3
Lead
8.5
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7440-50-8
Magnesium
1.1
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7439-92-1
Manganese
704
mg/kg
13.8
1
03/31/15 14:05 03/31/15 21:40 7439-95-4
Molybdenum
35.8
mg/kg
0.69
1
03/31/15 14:06 03/31/15 21:40 7439-96-5
Nickel
0.80
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7439-98-7
Potassium
6.8
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7440-02-0
Selenium
ND
mg/kg
689
1
03/31/15 14:05 03/31/15 21:40 7440-09-7
Silver
1.5
mg/kg
1.4
1
03/31/15 14:05 03/31/15 21:40 7782-49-2
Sodium
ND
mg/kg
0.69
1
03/31/15 14:05 03/31/15 21:40 7440-22-4
Zinc
ND
mg/kg
689
1
03131/1514:05 03/31/15 21:40 7440-23-5
4.6
mg/kg
1.4
1
03/31/15 14:05 03/31/15 21:40 7440-66-6
7471 Mercury
Analytical Method: EPA7471 Preparation Method: EPA7471
Mercury
ND
mg/kg
0.0058
1
03/28/1517:50 03/31/1516:55 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
30.3
/
0.10
1
03/31/15 17:25
9045 pH Soil
Analytical Method: EPA9045
PH at 25 Degrees C
8.1
Sid. Units
0.10
1
03/31/15 10:45 H3
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
106
mg/kg
2.9
1
03/31/15 23:44 7723-14-0 M1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2015 04:30 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

1��acmnalXical'
www.pacelahs.com
ANALYTICAL RESULTS
Project: ROX-ASH REUSE 4/4/15
Pace Project No.: 92246794
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: Ash Reuse Lab ID: 92246794001 Collected: 04/04/15 11:00 Received: 04/23/15 12:20 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
5.0 mg/kg
0.79
1
04/28/1516:00 04/29/151527 7440.38-2
Cadmium
58.5 mg/kg
0.40
1
04/28/1516:00 04/29/1515:37 7440-39-3
Calcium
ND mg/kg
0.079
1
04/28/1516:00 04129/1515:37 7440-43-9
Chromium
2740 mg/kg
7.9
1
04128/1516:00 04129/1515:37 7440-70-2
Copper
5.3 mg/kg
0.40
1
04/28/1516:00 04/29/1515:37 7440-47-3
Lead
8.8 mg/kg
0.40
1
04/28/1516:00 04/29/1515:37 7440-50-8
Magnesium
1.1 mg/kg
0.40
1
04/28/1516:00 04/29/1515:37 7439-92-1
Manganese
454 mglkg
7.9
1
04128/1516:00 04/29/1515:37 7439-95-4
Molybdenum
34.9 mg/kg
0.40
1
04/2811516:00 04/29/1515:37 7439-96-5
Nickel
1.1 mg/kg
0.40
1
04/28/1516:00 04/2911515:37 7439-98-7
Potassium
6.7 mglkg
0.40
1
04/28/1516:00 04/29/1515:37 7440-02-0
Selenium
ND mg/kg
395
1
04/2811516:00 04129/1515:37 7440-09-7
Silver
ND mg/kg
0.79
1
04/28/1516:00 04/29/1515:37 7782-49-2
Sodium
ND mg/kg
0.40
1
04/28/1516:00 04/29/1515:37 7440-22-4
Zinc
ND mg/kg
395
1
04/28/1516:00 04/29/1515:37 7440-23-5
4.1 mg/kg
0.79
1
04/28/1516:00 04129/1515:37 7440-66-6
7471 Mercury
Analytical Method: EPA7471 Preparation Method: EPA7471
Mercury
ND mg/kg
0.0047
1
04/25/1516:35 04/28/1513:41 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
15.6 %
0.10
1
05/01/15 11:43
9045 pH Soil
Analytical Method: EPA 9045
PH at 25 Degrees C
8.4 Sid. Units
0.10
1
04/29/15 14:50
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
47.7 mg/kg
4.6
1
04/26/1514:17 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: OS/01/2015 01:00 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

/55'ceAnalytical"
f "M-pacelabs.com
ANALYTICAL RESULTS
Project: ROX-Ash Reuse 5/19/15
Pace Project No.: 922,90905
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: Ash Reuse Lab ID: 92250905001 Collected: 05/19/1508:00 Received: 05121/15 12:30 Matrix: Solid
Results reported on a "dry weight' basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units Report Limit
DF
Prepared Analyzed CAS No. Qua]
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
13.2
mglkg
2.1
1
06/01/16 21:15 06/02/15 15:37 7440-38-2
Cadmium
160
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7440-39-3
Calcium
ND
mg/kg
0.21
1
06/01/15 21:15 06/02/15 15:37 7440-43-9
Chromium
4640
mg/kg
20.6
1
06/01/15 21:15 06/03/15 14:24 7440-70-2
Copper
16.6
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7440-47-3
Lead
24.8
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7440-50-8
Magnesium
4.7
mg/kg
1.0
1
06/01/15 21:15 06/03/15 14:24 7439-92-1
Manganese
1080
mg/kg
20.6
1
06/01/15 21:15 06/02/15 15:37 7439-95-4
Molybdenum
65.2
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7439-96-5
Nickel
2.8
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7439-98-7
Potassium
14.7
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7440-02-0
Selenium
ND
mg/kg
1030
1
06/01/15 21:15 06/02/15 15:37 7440-09-7
Silver
6.2
mg/kg
2.1
1
06/01/15 21:15 06/02/15 15:37 7782-49-2
Sodium
ND
mg/kg
1.0
1
06/01/15 21:15 06/02/15 15:37 7440-22-4
Zinc
ND
mg/kg
1030
1
06/01/15 21:15 06/02/15 15:37 7440.23-5
17.2
mg/kg
2.1
1
06/01/15 21:15 06/02/15 15:37 7440-66-6
7471 Mercury
Analytical Method:
EPA7471 Preparation Method: EPA7471
Mercury
0.018
mg/kg
0.011
1
05/2911513:15 05/29/1514:55 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
61.5
%,
0.10
1
05/28/15 11:31
9045 pH Soil
Analytical Method: EPA9045
pH at 25 Degrees C
7.9
Sid. Units
0.10
1
06/05/15 14:55
365.1 Phosphorus, Total
Analytical Method: EPA365.1
Phosphorus
330
mg/kg
23.6
1
05/29/1515:05 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in full.
Date: 06/07/2015 08:35 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

aceAnalydcal
i www.pacelebs.com
r
ANALYTICAL RESULTS
Project: ROX-Ash Reuse 6/17/15
Pace Project No.: 92256013
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: Ash Reuse Lab ID: 92256013001 Collected: 06/17/15 09:30 Received: 06/25/15 12:25 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA3050
Arsenic
Barium
1.4
mg/kg
0.90
1
06/29/1515:35 06/30/1517:46 7440-38-2
Cadmium
54.6
mg/kg
0.45
1
06/29/1515:35 06130/1517:46 7440-39-3
Calcium
ND
mg/kg
0.090
1
06/29/1515:35 06130/1517:46 7440-43-9
Chromium
3540
mg/kg
9.0
1
06/29/1515:35 0613011517:46 7440-70-2
Copper
5.6
mg/kg
0.45
1
06/29/1515:35 06130/1517:46 7440-47-3
Lead
7.8
mg/kg
0.45
1
06/29/1515:35 06/30/1517:46 7440-50-8
Magnesium
0.85
mg/kg
0.45
1
06/29/1515:35 06/30/1517:46 7439-92-1
Manganese
456
mg/kg
9.0
1
0612911515:35 06/30/1517:46 7439-95-4
Molybdenum
26.7
mg/kg
0.45
1
06129/1515:35 06/30/1517:46 7439-96-5
Nickel
1.3
mg/kg
0.45
1
06/29/1515:35 06/30/1517:46 7439-98-7
Potassium
6.3
mg/kg
0.45
1
06/29/1515:35 06/30/1517:46 7440-02-0
Selenium
679
mg/kg
450
1
06/2911515:35 06/30/1517:46 7440-09-7
Silver
ND
mg/kg
0.90
1
06/2911515:35 06/30/1517:46 7782-49-2
Sodium
ND
mg/kg
0.45
1
06/29/1515:35 06/30/1517:46 7440-22-4
Zinc
ND
mg/kg
450
1
06/29/1515:35 06/30/1517:46 7440-23-5
7.5
mg/kg
0.90
1
06/29/1515:35 06/30/1517:46 7440-66-6
7471 Mercury
Analytical Method: EPA 7471
Preparation Method: EPA 7471
Mercury
ND
mg/kg
0.0030
1
07/02/1512:30 07103/1514:40 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
21.7
/
0.10
1
07/02/15 10:01
9045 pH Soil
Analytical Method: EPA 9045
pH at 25 Degrees C
8.6
Std. Units
0.10
1
06/30/15 16:05
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
58.5
m /k
g g
3.0
1
06/30/1510:07 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/06/2015 03:46 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

01,07
aceAnalXical
/ www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 7/10/15
Pace Project No.: 92260041
Sample: Ash Reuse Lab ID: 92260041001 Collected: 07/10/15 16:45 Received: 07/23/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua[
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
1.9 mg/kg
0.76
1
07/27/15 21:20 07/28/15 16:00 7440-38-2
Cadmium
41.0 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7440-39-3
Calcium
ND mg/kg
0.076
1
07/27/15 21:20 07/28/15 16:00 7440-43-9
Chromium
1840 mg/kg
7.6
1
07/27/15 21:20 07/28/15 16:00 7440-70-2
Copper
4.0 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7440-47-3
Lead
6.5 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7440-50-8
Magnesium
0.93 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7439-92-1
Manganese
424 mg/kg
7.6
1
07/27/15 21:20 07/28/15 16:00 7439-95-4
Molybdenum
21.8 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7439-96-5
Nickel
0.82 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7439-98-7
Potassium
4.1 mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7440-02-0
Selenium
ND mg/kg
380
1
07/27/15 21:20 07/28/15 16:00 7440-09-7
Silver
ND mg/kg
0.76
1
07/27/15 21:20 07/28/15 16:00 7782-49-2
Sodium
ND mg/kg
0.38
1
07/27/15 21:20 07/28/15 16:00 7440-22-4
Zinc
ND mg/kg
380
1
07/27/15 21:20 07/28/15 16:00 7440-23-5
4.8 mg/kg
.0.76
1
07/27/15 21:20 07/28/15 16:00 7440-66-6
7471 Mercury
Analytical Method: EPA7471 Preparation Method: EPA7471
Mercury
ND mg/kg
0.0044
1
07/29/1516:00 07/30/1512:52 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
12.3 %
0.10
1
07/28/15 15:01
9045 pH Soil
Analytical Method: EPA 9045
PH at 25 Degrees C
7.5 Std. Units
0.10
1
07/26/15 16:05
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
73.3 mg/kg
2.0
1
07/31/1517:14 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date; 07/31 /2015 06:45 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

0-1111-7
aceAnalytical
' wrmpacelabs.com
ANALYTICAL RESULTS
Project: Rox Ash Reuse 8/5
Pace Project No.: 92264410
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample- ASH REUSE Lab ID: 92264410001 Collected: 08/20/15 08:00 Received: 08/20/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units Report Limit
DF
Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
2.8
mg/kg
1.6
1
08/25/15 21:00 08/26/15 13:54 7440-38-2
Cadmium
60.2
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7440-39-3
Calcium
ND
mg/kg
0.16
1
08/25/15 21:00 '08/26/15 13:54 7440-43-9
Chromium
2760
mg/kg
15.6
1
08/25/15 21:00 08/26/15 13.54 7440-70-2 M1
Copper
7.3
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7440-47-3
Lead
11.9
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7440-50-8
Magnesium
1.8
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7439-92-1
Manganese
624
mg/kg
15.6
1
08/25/15 21:00 08/26/15 13:54 7439-95-4
Molybdenum
40.3
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7439-96-5
Nickel
1.4
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7439-98-7
Potassium
7.4
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7440-02-0
Selenium
ND
mg/kg
781
1
08/25/15 21:00 08/26/15 13:54 7440-09-7 Mi
Silver
ND
mg/kg
1.6
1
08/25/15 21:00 08/26/15 13:54 7782-49-2
Sodium
ND
mg/kg
0.78
1
08/25/15 21:00 08/26/15 13:54 7440-22-4
Zinc
ND
mg/kg
781
1
08/25/15 21:00 08/26/15 13:54 7440-23-5
6.2
mg/kg
1.6
1
08/25/15 21:00 08/26/15 13:54 7440-66-6
7471 Mercury
Analytical Method: EPA7471 Preparation Method: EPA7471
Mercury
ND
mg/kg
0.0080
1
08/26/1513:20 08/2711513:10 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
52.2
%
0.10
1
08/25/15 12:41
9045 pH Soil
Analytical Method: EPA9045
PH at 25 Degrees C
7.9
Std. Units
0.10
1
08/27/15 14:40
365.1 Phosphorus, Total
Analytical Method: EPA365.1
Phosphorus
177
mg/kg
4.2
1
08/28/1512:51 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: O6/28/2015 03:47 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

aOAnalXical
,
Mvw.p801abs.cvm
r
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 9/9
Pace Project No.: 92269105
Sample: Ash Reuse Lab ID: 92269105001 Collected: 09/09/15 09:52 Received: 09/24/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No.
Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
ND mg/kg
1.9
1
09/28/15 21:00 09/30/15 16:39 7440-38-2
M1,R1
Cadmium
14.5 mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7440-39-3
M1,R1
Calcium
ND mg/kg
0.19
1
09/28/15 21:00 09/30/15 16:39 7440-43.9
R1
Chromium
1220 mg/kg
19.0
1
09/28/15 21:00 09/30/15 16:39 7440-70-2
Mi
Copper
ND mg/kg
0.95
1
09/28/15 21:00 -09/30/15 16:39 7440-47-3
R1
Lead
ND mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7440-50-8
R1
Magnesium
ND mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7439-92-1
M1,R1
Manganese
130 mg/kg
19.0
1
09/28/15 21:00 09/30/15 16:39 7439-95-4
M1,R1
Molybdenum
3.8 mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7439-96-5
M1,R1
Nickel
ND mg/kg
0.95
1
09/28/15 21:00 09/30/1616:39 7439-98-7
M1,R1
Potassium
ND mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7440-02-0
Ri
Selenium
ND mg/kg
951
1
09/28/15 21:00 09/30/15 16:39 7440-09-7
R1
Silver
3.5 mg/kg
1.9
1
09/28/15 21:00 09/30/15 16:39 7782-49-2
R1
Sodium
ND mg/kg
0.95
1
09/28/15 21:00 09/30/15 16:39 7440-22-4
M1,R7
Zinc
ND mg/kg
951
1
09/28/15 21:00 09/30/15 16:39 7440-23-5
R1
ND mg/kg
1.9
1
09/28/15 21:00 09/30/15 16:39 7440-66-6
R1
7471 Mercury
Analytical Method: EPA7471 Preparation Method:
EPA7471
Mercury
ND mg/kg
0.0095
1
09/28/1516:40 09/29/1514:14 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
56.2 %
0.10
1
09/29/15 17:34
9045 pH Soil
Analytical Method: EPA9045
pH at 25 Degrees C
7.7 Std. Units
0.10
1
09/27/15 15:10
D6
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
126 mg/kg
4.6
1
09/29/1511:39 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date: 10/05/2015 02:26 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

aceAnalXical
/ mWacelaba.com
ANALYTICAL RESULTS
Project: ROX-Ash Reuse 10/5115
Pace Project No.: 92271171
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Sample: Ash Reuse Lab ID: 92271171001 Collected: 10/05/15 14:45 Received: 10/08/15 15:05 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results
Units Report Limit
DF
Prepared
Analyzed CAS No. Qua[
6010 MET IcP
Analytical Method:
EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
ND
mg/kg
1.1
1
10/12/15 20:15
10/14/15 04:18 7440-38.2
Cadmium
11.2
mg/kg
0.54
1
10/12/15 20:15
10/14/15 04:16 7440-39-3
Calcium
ND
mg/kg
0.11
1
10/12/15 20:15
10/14/15 04:18 7440-43-9
Chromium
391
mg/kg
10.8
1
10/12/15 20:15
10/14/15 04:1 B 7440-70-2
Copper
ND
mg/kg
0.54
1
10/12/15 20:15
10/14/15 04:18 7440-47-3
Lead
1.2
mg/kg
0.54
1
10/12/15 20:15
10/14/15 04:18 7440-50-8
Magnesium
ND
mgJkg
0.54
1
10/12/15 20:15
10/14/15 04:18 7439-92-1
Manganese
48.2
mg/kg
10.8
1
10/12/15 20:15
10/14/15 04:18 7439-95-4
Molybdenum
3.0
mgJkg
0.54
1
10/12/15 20:15
10/14/15 04:18 7439-96-5
Nickel
ND
mg/kg
0.54
1
10/12/15 20:15
10/14/15 04:18 7439-98-7
Potassium
0.64
mg/kg
0.54
1
10/12/15 20:15
10/14/15 04:18 7440-02-0
Selenium
ND
mg/kg
541
1
10/12/15 20:15
10/14/15 04:18 7440-09-7
Silver
ND
mgJkg
1.1
1
10/12/15 20:15
10/14/15 04:18 7782-49-2
Sodium
ND
mgJkg
0.54
1
10/12/15 20:15
10/14/15 04:18 7440-22-4
Zinc
ND
mg/kg
541
1
10/12/15 20:15
10/14/15 04:18 7440-23-5
ND
mgJkg
1.1
1
10/12/15 20:15
10/14/15 04:18 7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
ND
mg/kg
0.0037
1
10/12/1516:05
10/14/1516:30 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
18.9
%
0.10
1
10/13/15 18:06
9045 pH Soil
Analytical Method: EPA9045
pH at 25 Degrees C
8.0
Std. Units
0.10
1
10/14/15 14:20
365.1 Phosphorus, Total
Analytical Method: EPA365.1
Phosphorus
21.2
m /k
g 9
2.2
1
10/15/1516:48 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/16/2015 08:27 AM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

aceAnalytkal
w mpacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 11/18/15
Pace Project No.: 92276873
Sample: Ash Reuse Lab ID: 92276873001 Collected: 11/18/15 09:30 Received: 11/19/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
2.4 mg/kg
0.83
1
11/24/15 18:00
11/25/15 20:52 7440-38-2
Cadmium
77.1 mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7440-39-3
Calcium
ND mg/kg
0.083
1
11/24/15 18:00
11/25/15 20:52 7440-43-9
Chromium
1590 mg/kg
8.3
1
11/24/15 18:00
11/25/15 20:52 7440-70-2
Copper
3.6 mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7440-47-3
Lead
6.8 mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7440-50-8
Magnesium
1.6 mg/kg
0.42
1
11/24/15 18:00
12/01/1512:07 7439-92-1
Manganese
300 mg/kg
8.3
1
11/24/15 18:00
11/25/15 20:52 7439-95-4
Molybdenum
30.9 mg/kg
0.42
1
11/24/15 18:00
12/01/1512:07 7439-96-5
Nickel
0.82 mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7439-98-7
Potassium
4.6 mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7440-02-0
Selenium
ND mg/kg
415
1
11/24/15 18:00
11/25/15 20:52 7440-09-7
Silver
ND mg/kg
0.83
1
11/24/15 18:00
11/25/15 20:52 7782-49-2
Sodium
ND mg/kg
0.42
1
11/24/15 18:00
11/25/15 20:52 7440-22-4
Zinc
ND mg/kg
415
7
.11/24/15 18:00
11/25/15 20:52 7440-23-5
5.5 mg/kg
0.83
1
11124/1518:00
12/01/1512:07 7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
ND mg/kg
0.0049
1
11/30/1512:20
11/30/1514:64 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
17.5 %
0.10
1
11/23/15 06:20
9045 pH Soil
Analytical Method: EPA 9045
PH at 25 Degrees C
7.7 Std. Units
0.10
1
11/23/15 14:25
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
9.1 mg/kg
2.4
1
11/26/15 05:49 7723-14-0 M1,R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full, Date: 12/02/2015 04:46 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

/� 2aceAnalXical-
WAV-Pacelebs.com
i
r
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 12/7/15
Pace Project No.: 92280289
�Sampte. Ash Reuse Lab ID: 92280289001 Collected: 12/07/15 10:20 Received: 12l17l15 12:30 Matrix: Solid
eported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Analytical Method: EPA6010 Preparation Method: EPA3050
Arsenic
Barium
0.99 mg/kg
0.75
1
12/21/15 22:00
12/22/15 14:30 7440-38-2
Cadmium
30.3 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7440-39-3
Calcium
0.24 mg/kg
0.075
1
12/21/15 22:00
12/22/15 14:30 7440-43-9
Chromium
504 mg/kg
7.5
1
12/21/15 22:00
12/22/15 14:30 7440-70.2
Copper
1.5 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7440-47-3
Lead
13.4 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7440-50-8
Magnesium
6.5 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7439-92-1
Manganese
128 mg/kg
7.5
1
12/21/15 22:00
12/22/15 14:30 7439-95-4
Molybdenum
13.4 mg/kg
0.37
1
12/21/16 22:00
12/22/15 14:30 7439-96-5
Nickel
2.5 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7439-98-7
Potassium
3.1 mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7440-02-0
Selenium
ND mg/kg
374
1
12/21/15 22:00
12/22/15 14:30 7440-09-7
Silver
ND mg/kg
0.75
1
12/21/15 22:00
12/22/15 14:30 7782-49-2
Sodium
ND mg/kg
0.37
1
12/21/15 22:00
12/22/15 14:30 7440-22-4
Zinc
ND mg/kg
374
1
12/21/15 22:00
12/22/15 14:30 7440-23-5
12.4 mg/kg
0.75
1
12/21/15 22:00
12/22/15 14:30 7440-66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
ND mg/kg
0.0051
1
12/22/1517:45
12123/1513:24 7439-97-6
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
19.4 %
0.10
1
12/22/15 11:53
9045 pH Soil
Analytical Method: EPA 9045
PH at 25 Degrees C
7.1 Sid. Units
0.10
1
12/22/15 12:40 D6
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
36.5 mg/kg
2.1
1
12123/1512:21 7723-14-0 R1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/24/2015 02:56 PM without the written consent of Pace Analytical Services, Inc..
Page 4 of 17

/5a'ceAnalytical"
mm-pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
205 East Meadow Road - Suite A
Eden, NC 27288
[phone]
Project: ROX-Ash Reuse 7110115
Pace Project No.: 92260041
Sample: Ash Reuse TCLP Lab ID: 92260041002 Collected: 07/10/15 16:45 Received: 07/23/15 12:30 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quaff
6010 MET ICP, TCLP Analytical Method: EPA 6010 Preparation Method: EPA 3010
Leachate Method/Date: EPA 1311; 07/28/15 02:35
Arsenic
Barium
ND
mg/L
0.050 1
07/29/15 00:00 07/29/15 15:24 7440-38-2
Cadmium
ND
mg/L
0.25 1
07/29/15 00:00 07/29/15 15:24 7440-39-3
Chromium
ND
mg/L
0.0050 1
07/29/15 00:00 07/29/15 15:24 7440-43-9
Lead
ND
mg/L
0.025 1
07/29/15 00:00 07/29/15 15:24 7440-47-3
Selenium
ND
mg/L
0.025' 1
07/29/15 00:00 0712911515:24 7439-92-1
Silver
ND
mg/L
0.10 1
07/29/15 00:00 07/29/15 15:24 7782-49-2
ND
mg/L
0.025 1
07/29/15 00:00 07/29/15 15:24 7440-22-4
7470 Mercury, TCLP
Analytical Method: EPA 7470 Preparation Method: EPA 7470
Leachate Method/Date:
EPA 1311; 07/28/15 02:35
Mercury
ND
mg/L
0.00020 1
07/29/15 09:55 07/29/15 14:31 7439-97-6
Date: 07/31/2015 06:45 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 5 of 17

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #: W00000020 FACILITY NAME: Duke Energy Progress, LLC Asheville Plant
PHONE: [phone] COUNTY: Buncombe OPERATOR: Duke Energy Progress, LLC
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C)
Q Distribution and Marketing (complete Parts A, B, and C)
Wu4; the facility in operation durine the vast calendar vear7 Yes 21 No ❑ ---► If No skip parts A, B, C and certify farm below
Pats A*:
Part B�:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
BulkingAgent
Residual In
Product Out
Name(s)
Volume (dry tons)
Intended use(s)
January 2015
Asheville Plant Coal Ash
0
0
45457.65
Charah
45457.65
Structural Fill
February 2015
Asheville Plant Coal Ash
0
0
30696.41
Charah
30696.41
Structural Fill
March 2015
Asheville Plant Coal Ash
0
0
65961.99
Charah
65961.99
Structural Fill
April 2015
Asheville Plant Coal Ash
0
0
59563.77
Charah
1 59563.77
Structural Fill
May 2015
Asheville Plant Coal Ash
0
0
63142.92
Charah
63142.92
Structural Fill
June 2015
Asheville Plant Coal Asti
0
0
78492.16
Charah
78492,16
Structural Fill
July 2015
Asheville Plant Coal Ash
0
0
ID802.42
Charah
10802,42
Structural Fill
August 2015
Asheville Plant Coal Ash
0
0
a
NA
0
NA
September 2015
Asheville Plant Coal Asti
0
0
0
NA
0
NA
October 2015
Asheville Plant Coal Ash
0
0
0
NA
0
NA
November 2015
Asheville Plant Coal Ash
0
0
0
NA
0
NA
December 2015
Asheville Plant Coal Ash
0
0 1
0
NA
0
NA
'total from FORM DMSDF (sup)
Totals: Annual (dry tons):
0
0
354117.32
354117.32
Amendment(s) used:
Bulking Agent(s) used:
* If more space is required, attach additional information sheets (FORM DMSDF (supp)):
Part C:
Total Number of t•orm unnsut• (auppI I
Facility was compliant during the past calendar year with all conditions of the land application permit El Yes
(including but not limited to items 1-3 below) issued by the Division of Water Resources: 0 No ----r If No, Explain In Narritive
1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached.
2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Resources.
3. No contravention of Ground Water Quality Standards occurred at a monitoring well.
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant
penalties for submitting raise information, including the possibility of fines and imprisonment for knowing violations."
A,Ql -- °?1 to
Signature of Permittee Date
•+Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1 102 (26)
Signature of Preparers•
(if different from Permittee)
Date
DENR FORM DMSDF (1212006) .

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number: W00000020 Laboratory: 1) Pace Analytical Services, Inc.
Facility Name: Duke Energy Progress, LLC Asheville Plant 2)
Residual Source WQ # or WQ0000020 3)
NPDES #: 4)
WWTP Name: n/a 5)
Residual Analysis Data
Parameter
(mP g)
Conc.
Limit
m a
Sam le or Composite
Date
0110611S
02/04/15
03/03/15
04/07/15
OSIO5115
0610911S
07/07/15
OSIOS115
09/01/15
10/06/15
11/04/15
12/03/15
Percent Solids (°fo)
NA
75.1
75.1
79.8
77.2
88.4
74.7
74.2
78.2
80.1
73.9
77.6
74.8
Arsenic
75
72.4
86.6
85.2
98.6
7.2
110
66.5
52.5
90.2
88.5
121
78.8
Cadmium
85
0.42
0.78
0.66
0.78
<0.11
0.77
0.45
0.43
1.1
0.87
0.97
0.38
Copper
4,300
363
37.8
33.6
42.1
1.3
34.5
24.1
30.8
33.1
58.1
45.2
48
Chromium
NA
21.6
18.1
24.4
22.7
3.9
20.9
11
19.8
21
34.9
28.4
28.4
Lead
840
13.9
12.9
12.3
14.9
0.73
12.9
6.1
12.5
11.9
25.3
21
17.5
Mercury
57
0.17
0.24
0.1$
1 0.2
0.26
0.19
0.21
0.19
0.2
0.13
0.19
0.19 '.
Molybdenum
75
2.2
2.4
2.7
2.4
0.9
2.5
1.3
1.3
2.2
6.6
2.7
5
Nickel
420
17.3
16.2
15.2
17.7
0.94
14.9
10.6
14.7
15.8
28.4
23.5
18.9
Selenium
100
8.9
12.6
9.4
10.2
8.7
7.7
7.7
6.8
10.1
10.7
8.5
10.4 `
Zinc
7,500
30.4
23.1
25.7
30.5
2.6
25.8
15.4
34
32.1
49.5
44.3
43
Total Phosphorus
NA
329
359
414
588
230
469
500
371
361
333
144
262
TKN
NA
NA I
NAJ
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Ammonia -Nitrogen
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Nitrate and Nitrite
NA
NA I
NA
NA I
NA
NA
NA I
NA
NA
NA
NA
NA
NA
' For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits.
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualifed personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
. - /6 /Z i - , Z l 10 1 /(,,
Signature of Preparer' Date
'Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006)

i
ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ, permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number: W00000020
Facility Name: Duke Energy Progress, LLC Asheville Plant
Residual Source W00000020
NPDiES # or WQ#:
WWTP Name:
TP-AA....1 A....l.... Tot..
Laboratory: 1) Pace Analytical Services, Inc.
2) Asheville Plant Lab for pH only
3)
4)
5)
Parameter
(mg/kg)
Sam le or Composite Date
01/06/15
02/04/15
03/03/15
04/07/15
05/05/15
06/09/15
07/07/15
08/05/15
09/01/15
10/06/15
11/04/15
12/03/15
Barium
312
514
337
407
14.4
262
214
247
286
438
391
401
Calcium
2210
2510
2170
2550
4910
2010
1740
1460
2590
3630
2290
2070
Magnesium
933
795
897
949
137
745
511
1330
989
1500
1330
1350
Manganese
63.6
69.5
71.3
75.6
4.1
53.9
64.9
132
101
70.3
98.3
165
Potassium
1790
1600
1600
1980
<555
1600 .
1030
2150
1730
3020
2000
2830
Silver
<0.58
<0.58
<0.52
0.61
<0.55
0.44
<0.37
<0.46
0.48
<2.8
<1.9
<0.63
Sodium
<584
<584
<522
<588
<555
<368
<370
<457
<381
<2820
<1900
<630
H s.u.) *
7.2
7.6
7.8
7.4
7.4
7.7
7.7
7.5
10.3
8.8
8.3
9.7
* pH of ash pond
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for Imowing violations."
10-0
Signature 6fPreparer • D to
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF - B (12/2006)

Duke Energy Progress
Asheville Station
Ash Reuse Permit
Date Sampled
pH of Ash Pond (su)
1/6/2015
7.2
2/4/2015
7.6
3/3/2015
7.8
4/7/2015
7.4
5/5/2015
7.4
6/9/2015
7.7
7/7/2015
7.7
8/5/2015
7.5
9/1/2015
10.3
10/6/2015
8.8
11/4/2015
8.3
12/3/2015
9.7

4�'PLA17aljdkal*
�xx'paaralsmm
f.
ANALYTICAL RESULTS
Pace Analytical Servlcet+,lnc.
205 Eo31 Meadow Road - Soite A
Eden, NC 27286
(335i623-0921
Pmjegj AVL-Ponded Ash for Reuse 1/6
Pace Prolect No„ 9223207S
Sample: Asb from Ash Pond Lab ID: 92232076001 Collecled; 01106115 11i15
Results reported on a drywelght"basis
Recelved: 011D7/15 08A7 Matrix- Solid
Parameters
Results Units
Report Limit DF
po
Prepared Analyzed CAS No, Dual
6010 MET ICP
Analytical Method: EPA Bolo Preparation Method: EPA 3050
Arsenic
Badum
72 4 !k g
1.2 1
111107/1516.35 01/07/15 21:45 7440-38.2
Cadmium
312 mgikg
0.42 mglkg
0,58 t
011071151625 01/07/15 21,45 7440.39.3
Calcium
2210 mglkg
0,12 t
01/07/1510 35 01/07115 21:45 7440.43.9
Chromium
21.6 mglkg
11.7 1
0110711516:35 01/07/15 21:45 7440,70-2
Copper
36.3 mglkg
0.58 1
01/07/1516 35 01/07/15 21;45 7440-47«3
Lead
i3.9 mglkg
0,58 1
01167/1516 35 01/07/15 21.45 744 NS0,8
Magneslum
933 mg/kg
058 1
01107/1516 35 01/07/15 21.45 7439-92.1
Manganese
63.6 mglkg
117 1
GIA3711516,35 0110711521AS 7439-95.4
Molybdenum
2.2 mgfkg
0.58 1
0110711518:35 0110711521A5 7439-96,5
Nickel
17.3 mgfkg
048 1
01t0711516 35 01/07/15 21A5 7439.98.7
Potassium
1790 rngikg
055 1
(11107115 16:35 01/07/15 2145 7440-020
Selenium
8.2 mgfkg
584 1
(11107115 1625 0111071115 21:45 7440-09-7
Silver
NO mgfkg
1.2 1
01/07/15 15.35 a1/07115 21,45 7782-49.2
Sodium
NO mgfkg
D,58 1
01107/1516 35 01/07115 21AS 7440.22-4
One
30.4 mgfkg
584 1
01/07/1516 35 01/07115 21,,45 7440-23.5
601D MEi ICp, TCLp
1.2 1
01/07/1516 35 01/07/15 21 AS 7440•56.6
AnatyOral Method: EPA 6010 Preparation Method EPA 3010
Leachals Method/Date; EPA 1311; 01112/1517.45
Arsenic
Barium
14 0,rnglL
14 m92
0 050 1
0111311518AS 0111411516,06 7440.38.2
Cadmium
NO mg1L
025 1
01/1311518.45 0111411516�06 7440.39-3
Chromium
0.0050 1
0111311518.45 0111411516,06 7440-43.9
Lead
No mg/L
0.025 1
0111311S 18,45 01/14/1516 06 7440.47.3
Selenium
0 025 1
0111311518:45 01J1411616 06 7439-92-1
Sliver
NO
No mg/L
0,10 1
D1/1311518:45 01/14/1516 06 7782-49.2
7470 Mercury, TCLP
Q025 1
01/13115 18:45 01/14115 16.06 7440-22-4
Method: EPA 7470 Preparation Method, EPA
7470
Melhod/Dale* EPA 1311,
0111211517,46
MercuryLearhate
ND mg1L
0.00020 1
01113/15 17-AS 0111411512.04 7439.97>6
7471 Mercury
AnalyBral Method° EPA7471 Preparation Method: EPA7471
Mercury
0.17 m g/kg
0.021 5
0110911511;15 011D911517„47 7439-97-6
254OG Total Percent Solids
Analytical Method, SM 254OG
Total Solids 751 55
0,000010 1 01/1311515'3D
Percent Moisture AnaIyllCaI Method: ASTM D2974.87
Percent Moisture 24.9 eti
0,10 1 81/14/15 08 11
368,1 Phosphorus, Total An810cat Method; EPA365,1
Phosphorus 329 m Ac
9 9 19,0 5 01/13/15 10.52 7721-14-0
REPORT OF LABORATORY ANALYSIS
Date; 01/14/2015 04:57 PM Thla MPan ahaq not be reproduced, except In full,
wnhout the written can3ent of Pau Analytical Sarvicaa, the
Page 4 of 15

aceAnaljdical10
On psrxtsbscera
I -
ANALYTICAL RESULTS
Prujact: AVL-Ponded Ash 214115
Pace Project No ; 92236449
Pace Ana"cal Services, Inc,
205 East Meadow Road - Sulle A
Eden, NC 272au
(3361623.4921
Sample; Ash from Ash Pond Lab (0: 92236449001 Collected: 02/04/1513.4D Received,, 02►05/15 08:16 Matrix: 5oild
Results reportedOn a dry-welght" basis
Parameters
Results Units _
Report l3tnil
DF
Prepared Analyzed CAS No. Oual
601aMET ICP
Analytical Method. EPA601D Preparation Method: EPA3050
Arsenic
Barium
86.6 mglkg
1,2
1
02/05/1516 55 02/06/15 16:25 744D-38-2
C
Caddmirnlum
514 mglkg
ass
1
02/0511518 55 02INIIS 16.25 7440-29.3
Calcium
0.78 mgAtg
0,12
1
0210511516,55 021D611516 26 744043.9
Chromium
2510 mgAg
18.1 mgfkg
11.7
1
02105/1516.55 02106/1516 26 7440-70-2
Copper
0,58
1
02/05/1516 55 02106/15 16:26 7440-47.3
Lead
37.8 mpq
0..58
1
0210511516,56 021061151E 26 7440.50.8
Magnesium
12.9 mg&q
0,58
1
02/051t516 55 02I0811516.26 7439.92-1
Manganese
795 mglkg
11.7
1
021051151US 02MI516 26 7439.95-4
Molybdenum
69.5 mglkg
0,58
1
02/051t516 55 02/D6/1516 26 7439<96.5
Nickel
2,4 mglkg
ass
1
02/0511516,55 021D611515 26 7439-93-7
Potassium
Potassium
16,2 mglkg
0,58
1
0?l05/1516 55 02/06/1516 26 7440-02.0
Selenium
1600 mg/kg
12.6 mglkg
584
1
02/05/1516 55 02=11515 25 7440.09-T
Solver
1.2
1
0210511615,55 02106115162E 7782-49,2
ND mglkg
0,58
1
02/05/1516;55 02/0611515 26 7440.22-4
Mile MSodium
nc
ND mglkg
564
1
02105/1516 55 0210611516:26 7440-23-5
23.1 nvlkg
1.2
1
0210511616'55 02/08115 16 25 7440-66-6
7471 SMorcury
Analytical Method; EPA 7471 Preparation Method; EPA 7471
Mercury
0.24 mgAcg
0,02E
5
02/08115 15.40 02/07/15 17.05 7439-97.6
254OG Total Parcant Sands
A11- tytical Method. SM 2540G
Total Solids 75,0 55
D,1H10010 1 0211111515R0
Parcent Moisture Analytical Method • ASTM D2974.87
Percent Moisture 24.9 % 0:10 1
02112115 09 58
365.1 Phosphorus, Total Analytical Method, EPA 3651
Phosphorus 359 mglkg 30,3 5
02/09115 15.25 7723-14.0
REPORT OF LABORATORY ANALYSIS
Dale, 02112/2015 0210 PM fhb MPon shall not be roproducad, except In full,
without the wriuen eonsant or Pace Analytical Services, Ins.
Page 4 of 13

aceAnalytical
ANALYTICAL RESULTS
Pace Analytical Services, Ina
205 East Meadow Road - BOB A
Eden, NC 272U
[phone]
Project: AVL-Panded Ash =15
Pace Project No... 92239661
Sample: As trom Ash Pgnd
Results reported on a dry wolght" basis
Letr 10: 92239061001 Collected
; 03/0311513 00
Recelved: 03104115 1500 Matrix,,Solkt
and are adjusted forpercent moisture, sample size and any dilutions.
Parameters
Results units Repoli limit
DF
Prepared Analyzed CAS No, Quaff
601D MET ICP
Analytical Method; EPA Preparaton Method i EPA3050
Arsenic
Barium
85.2 mgikg
1.0
i
03109/15 47.45 03/10/15 0043 7440.38.2
Cadmium
mglkg
0.66
0,52
1
0310911517:45 03/10/15 0043 744D.39.3
calcium
.66 mgnrg
2170
0.10
1
0310911517:45 0311011500:43 744D.43.9
Chromium
mg/kg
24.4
10A
1
0310911617:45 03110115 00.43 7440-70.2
Copper
mgrkg
33.6
0:52
1
0310911517:45 03110/15 00.43 7440.47.3
Lead
mglkg
1Z3
0,52
1
03109/1517A5 03/1011500:43 7440.50•5
Magnesium
mglkg
897
0.52
1
0310911517AS 03/10115 GDA3 7439.92-1
Manganese
mg/kg
71.3
10.4
1
0310911517:45 03110115 GO.43 7439-gS4
Molybdenum
m91k9
Z7
0.52
1
0310911517:45 (13110115 00.43 7439-98.5
Nickel
m91k9
16.2
0.52
1
0310911517.45 03110115 00:43 7439.9E-7
Potassium
mg1k9
1600
0.52
1
0310911517A5 03110115 00:43 744D•02.0
Selenium
mg/kg
9.4
522
1
0310911517:45 03110115 00:43 7440.09-7
Silver
m9lk9
ND
1-0
1
0310911517:45 0311D111500:43 7782-49-2
Sodium
m9/k9
ND
0.52
1
0310911517:45 03/10/15 00:43 7440.22-4
Zinc
m9fk9
25,7
522
1
0310911517:45 03110/15 00:43 7440.23.5
Mercury
mgrk9
1<0
1
0310911517:45 03110/1500:43 7440� "
Analytical Method, EPA7471 Preparation Method',
EPA 7471
Mer.
Mercury
0.18 m91k9
0.024
5
0310511616.45 03/0611515Ag 7439.97.6
26400 Total Pemenl Solids
Analytical Method: SM 2540G
Total Solids
79.8 9b O.00OOID
1
03/05/15 "18:23
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
20.2 y,
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
0.10
1
0310611509:67
Phosphorus 414 mg/kg 26.1 5
03/1711510:21 7723-14-0
REPORT OF LABORATORY ANALYSIS
Date, 031171201511.23 AM This rePerl shall net be reproduced, except In fua,
without the wrItten cement of Pace Anelocal Services-. Inc..
Page 4 of 13

abennQ� %��rn�
"'arjrutJal
Pace Analytical Services, Inc.
285 East Meadcw
Rand. Suite
Eden, NC 27268
[phone]
ANALYTICAL
RESULTS
Project- AVL-Ponded Ash for Reuse 417
Pace Project NO,, 92244887
Sample; Ash fmmAsh Pond
Results reported on a dry welggl"tlasls
'Labla,. 922446a7001 Collected•
(1410711511a10
Received, 04l0911516:55 Malrfx: Solid
and ere adjusted forpercpnt molsturr, sample
sire and any dllutlorts.
Parameters
Resutls Units Report Limit
OF
Prepared Analyzed CAS No., Cual
6010 MET ICP
Analytical Method EPA6o10 Preparation Method.; EPA305D
Arse
Arsenic
Barium
98.6 m9N9
407
1.2
1
D411411516:45 04115/1516:49 7440-36-2
Cadmium
mgArg
0'78
0,59
1
04/14/15 116:45 04115/1516.49 7440.39.3
Calcium
mglkg
2550 mglkg
0.12
1
041t4/1516:45 041i51t516:49 7440�t3.9
Chromium
m9/k9
11„8
1
04/1411516:45 0411511516A9 7440-70.2
Copper
42'7
059
1
0411411516:45 04/1511516:49 7440-47-3,
Lead
.1 mg/kg
14
059
1
0411411516:45 0411511516A9 7440-50.8
Magnesium
'9 mglkg
94
059
1
0411411518:45 (14115115 16:49 7439.92.1
Manganese
mglhg
75.6
11-8
1
0411411S IBAS 04115/15 16:49 7439-95.4
Molybdenum
m9►k9
2A
059
1
0411411516A5 04115/1516:49 7439.96.5
Nickel
mg►k9
17.7
0.59
1
0411411516AS 04115/1516:49 7439.98-7
Potassium
mglkg
1980
0.59
1
0411411516As 04115/1516:49 7440,02-0
Selenium
mgJkg
10.2
588
1
0411411516:45 0411511516A9 7440.09-7
Silver
mg/kg
0.61
1.2
1
041141151GAS 0411511516:49 7782-49-2
Sodium
m91k9
D.59
1
0411411515AS 0411511516:49 7440.22-4
7jnc
30 5 mglk9
586
1
0411411516:45 0411511516.49 7440-23-5
Martyry
m91h9
1,2
1
0411411516:45 0411511516AS 7440,66.6
Analytical Method; EPA 7471 Preparation Method; EPA
7471
Mer
Mercury
0.20 mg1k9
0,021
5
04111115 15 20 0411111519.24 7439,97.6
754OG TOW Percent Solids
Analytical Method, SM 254OG
Talal Solids
77.2 0.000010
1
04/14/1514;47
Percent Motsturro
Analytical Melba& ASTM D2974.67
Percent Moisture
22.8 96
365.1 Phosphorus, Total
Analytical Method: EPA365,1
0,10
1
D4/1411519;02
Phosphorus
Sea mglkg
30,8
5
04/21/15 1112 7723-14-0
REPORT OF LABORATORY ANALYSIS
This t PW"net be reproduced, except in roil,
Date. 0421l2015 02;27 PM
%ithoul the written consent of pace An*gcal Servkea, Inc
Page 4 of 13

5ac(
emalxic'w a
PRco4 xeaa
ANALYTICAL RESULTS
Projects AVL-Ponded Ash for Reuse 515
Pace Pro)ect No.: 92248413
Paco Analytical Sorvices, Inc.
205 Eust Meodaw Road - Sude A
lidan, NC 272E6
[phone]
Samplo: Ash from Ash Pond
Results reported an a "dry weight"
Lab ID: 92248413001
basis
Collected; 05/05/15 10:50
Received: 05/06/115 09AD Matdx-Solid
anofam adjusfad
for percant
molsture, sample s/zc and any dlludons,
Parameters
Results
units
Report Limit
OF
Prepared Analyzed CAS No,
Ouat
solo MET ICP
Analytical Method., EPA6019 Preparation Method; EPA3050
Arsenic
Barium
7.2
mglkg
1,1
1
05118/1510:30 05111IMS 14.46 7440-38.2
M1,R1
Cadmium
14.1
ND
mg/kg
US
1
OS11WIS 10:30 U511811514AS 7440.39-3
M1,R1
Calcium
mglkg
o,ll
1
0511811510:30 05/1811514.46 744DA3.9
Chromium
4910
mglkg
11./
1
0511811510:30 0511811514,45 7440-70.2
M1
Capper
3.9
mglkg
0.55
1
0511811510:30 0511811514:46 7441)47-3
Lead
1.3
mglkg
055
1
05/18/t510:30 0511811514,46 7440.50.8
Mt
Magnesium
0.73
mglkg
055
1
05116/t510:30 0511811514:46 7439.92.1
M1,R1
Manganese
137
mglkg
11,1
1
D5118H510:30 0511811514:46 7439-95-A
M1
Molybdenum
4,1
mglkg
055
1
051t8/1510:30 0511811514:46 7439.96=5
M1
Nickel
0.90
mg/kg
055
1
061181151D30 0511811514:45 7439-98-7
M1,R7
PotassiumND
0.94
mglkg
055
1
0511811510.30 05/18115 i4A6 7440.02-D
Selenium
Sm
mglicg
655
1
051181151920 05118115 14:45 7440-09.7
Sliver
8.7
mglkg
1.1
1
0511511510:30 0511811514:48 77a2-49.2
ND
Mpg
0,55
1
0511811510:30 0511011514:45 7440-22A
M1,Rl
Zinc
��
ND
mg/k9
555
1
05/16/1510:30 0511811514.46 7440.23.5
2.6
m9*9
1„1
1
0511811510:30 0511811514:45 7440-66-6
7471 Mercury
Analytical Method; EPA7471 Preparation Method; EPA7471
Metcury
0.26
mg/kg
0.026
5
051181151230 05/18115 15:41 7439.97-6
MI
254OG Total Percent Solids
Analytical Motitod: SM 254OG
Total Solids $6.4 % 0.000010 1
05/111t512:50
Percent Moisture Analytical Method; ASTM D2974.87
Percent Moisture 11.8 % 0.10 1
0511i115 17:12
365.1 Phosphorus, Total Analytical Method„ EPA 365,1
Phosphorus 230 mglkg 23,6 5 0511811513:33 7723.14.0 M1,R1
REPORT OF LABORATORY ANALYSIS
This reponshaU nal bo reproduced, exceptin tutx,
Dale OS1181Z015 05 00 PM wiftut Uro written consent el PaceAnslyUcel Servkas, tna..
Page 4 of 13

q,,
�c+e &Vcal
paceAnatyticalServices, Inc.
205 East Meadow Road- Suite A
W-11-dahcom
Eden, NC 27288
1778I823.8921
ANALYTICAL
RESULTS
Project;_ AVL-Ponded Ash for Reuse 609
Paco Project Wa 922.93629
Samplo:. Ash from Ash Pond
Results reported on a dry weight-
Lab ID; 92253629001 Ca ected:
basis and
06109H511.36
Received: 06/10115 07:25 Matrix; Sold
are adjusted forparaent moisture, sample size and any dilutions.
Parameters
Results
Units Report Until
DF
Prepared Analyzed CAS No. Cual
6010 MET 1CP
Analytical Method; EPA6070 Preparation Method; EPA 3050
Arsenic
adum
m9M9
074
1
08/17/15 21.00 08/18/15 2125 7440.38.2
C62
Cadmium
2
mglkg
OX
1
08/17/15 21,00 OSIIB115 21,25 7440-39.3
Calcium2010
0.77
rnglkg
0,074
1
O6/t7115 2100 06/76►15 21.25 7441143.9
Chromium
ragikg
7.4
1
0611711521,00 06/18/i52V25 7440-70-2
Copper
20.9
rnglkg
0.37
1
=17115 21:00 06I48115 21,25 744D�7 3
Land
34.6
mglkg
0.37
1
06/17115 21:0o asilel15 2125 7440.50-8
Magnesium
12,9
m91k9
0.37
1
06/17/15 21,00 0511 ally 2V25 7439-92.1
Manganese
745
rn9►k9
7.4
1
06/17/15 21.00 06/18/15 21;25 7439.95-4
Molybdenum
53.9
mgik9
OX
1
061171152100 0011115 21.25 7439.96.5
Nickel
2 5
rngikg
0.37
1
06117115 21h00 O61i8/1521.25 7439.98.7
Potassium
14.9
mglk9
0.37
1
06117115 21,00 06h Oils 21-25 7440.02-0
Seleenium nlu1600
S
mgikg
368
1
0611711521,00 06M 8115 21,25 7440.09-7
Silver
7.7
rn91k9
0.74
1
0611711521.00 0611811521,25 778249.2
Sodium
0.44
rnglkg
0.37
1
06/17/15 21:00 06/18/15 2t25 7440-22.4
Zinc
ND
mgikg
358
1
06/171152t00 0611611521.25 7440-23.5
29.6
mg►k9
0.74
1
W17115 21.00 06118/15 2115 1440.66.6
7471 Mercury
Analytical Method-, EPA 7471 Preparalton Method- EPA 7471
Mercury
0.19
mgIk9
0 025
5
06/1811515 35 0511911517�33 7439-97.6
25406 Total Percent Solids
Analytical Method SM 2540G
Total Solids
74.7
% 0 000010
1
06/1511519.25
Percent Moisture
Analytical Method; ASTM D2974.87
Percent Moisture
25.3
%
OAD
1
06/1611510:22
365.1 Phosphorus, Total
Analytical Method; -EPA 3654
Phosphorus
469
mglk9
23,1
5
0612111510:22 7723-14-0
REPORT OF LABORATORY ANALYSIS
Date; o 'Ws ropon 3hsG not he repiaduced, except in tut,
6f22/2015 02:03 PM without the written Consent or PawAnal yaaal Service, inc, Page 4 of 13

aceAnalyticalm
+r+rw�sul+8smn
ANALYnCAL RESULTS
Pmlect, AVI Ponded Ash 7/7115
Pace Project No,:. 92257721
Pace Analytical Services, Inc.
205 East Meadow Rood, Sure A
Eden, NC 27260
1339)623.0921
Sample: Ash from Ash Pang
reported on a dry weight" has/s
Labit): 92257721001 Collected 0710711515.30
Received: D7/D811510,1Q Matrix: Solid
and are adjusted rorpercent m01s1ure, sample size and any dilutions.
Parameters
Resu:ts
Units
Report Umlt
dF
Prepared Analyzed CAS No, Qual
6010 MET ICP
Analytical Method: EPA6010 Preparation Method; EPA 3050
Arsenic
Badum
6
mglkg
0,74
1
07/08/15 HAS 0711311518,22 7440-38-2
Cadmium
214 14
mglkg
037
1
0710Q115 20,45 D711311518'22 7440-39-3
Calcium
DAS
mglkg
0,074
1
07/08115 20;45 0711311518:22 7440.43.9
Chromium
1740
11.0
mglkg
7,4
1
07108115 20AS 0711311518:22 7440.70-2
Copper
mglkg
0,37
1
07/08/15 20 45 0711311518:22 7440-47-3
Lead
24.1
mglkg
0.37
1
07108/1520;45 07/1311518:22 7440-50.8
Magnesium
5.1
mglkg
0.37
1
07108116 20.45 0711311518:22 7439-924
Manganese
511
mglkg
7.4
1
07108/15 20 45 07113//51822 7439-95.4
Molybdenum
64.9
mg1k9
0.37
1
0710811520-45 0111311518.22 7439-96.5
Nickel
1.3
m9mg
0.37
1
0710311520.45 07113116113:22 7439-98-7
Potassium
10.6
1030
mglkg
0,37
1
0710811520AS 07/1311518.22 7440.02-0
Selenium
mglkg
370
1
07/08/15 2045 0711311518:22 7440.09-7
Silver
7.7
mglkg
0,74
1
07/08/15 2045 0711311518.22 7782-49-2
Sodium
NU
mglkg
0,37
1
07108115 20 45 0711311518,22 7440.22.4
Zinc
NC
mglkg
37D
1
071081152045 0711311518.22 7440.23-5
15.4
mglkg
0,74
1
0710IW15 20.45 0711311518,22 7440-66.6
7471 Mercury
Analytical Method; EPA 7471 Preparation Method,- EPA 7471
Mercury
0.21
mglkg
0.033
5
0711711612.55 0712011515.36 7439-97-6 Ml
254OG Total Percent Solids
Analytical Method, SM 254OG
Total Sands
74.2
%
0.0D0010
1
07/10115 16.52
Percent Moisture AnalyBcal Method. ASTM D2974.87
Percent MolshKe 25.8 %
0,10 1 07111115 01:28
365.1 Phosphorus, Total Analytical Method, EPA 3651 '
Phosphorus fi00 mglkg 250 5
07/21/15 112:12 7723-14.0
REPORT OF LABORATORY ANALYSIS
Clete, 07121/2015 03.02 PM This capon shsa not be reproduced, erupt in full,.
without the wdsen consent of Pace Analytclal 5arvk:es, Inc.,
Page 4 of 13

�.;aceAflalyhca! a
Paco Analytical Services, Inc.
205 East
Meadow Road SuiteA
'fta,
Eden, NC 272aE
1336J623.6921
ANALYTICAL RESULTS
Project:,. AVL-Ponded Ash
for Reuse al5
Pace Projecl No.: 92261997
Sampta; Ash trom Ash Pond
Results reported on a dry weight` basis
Lab ID: 9226i9970o1 Collecled': 081p5115 09;35
Received: 0810511514:20 Matrix; Solid
and are adjusted forpamentmolstura, sampla size and any dilutions.
Parameters
Results Units Report Limit OF
Prepared Analyzed CAS No, goal
6010 MET ICP
"
Analytical Method EPA Bolo Preparation Method: EPA 3050
Arsenic
Badum
52.5 mglkg - 0;91 1
247
0810a/15 21:45 08/10/15 21.46 7440.38-2
Cadmium
mglkg 0,46 1
D'43 mgtkg
=06115 21 AB 08/10115 21:46 7440.39.3
Calcium
0.091 1
1.mpg
081OW15 2i:45 08110115 2VIS 7440.43.9
Chromium
91 1
196 mglkg
08/06115 21.45 08/10/15 21 AS 7440-70.2
Copper
0.46 1
30.8 mpg
0810611S VAS 00/10/15 21;46 7440-47-3
Lead
0,46 1
12.5 mpg
08/06/15 21AS 08/10/15 21AG 7440.50.E
Magnesium
046 1
1330 mglkg
0810611521:45 08110/15 21:46 7439.92-1
Manganese
91 1
132 mglkg
08106115 21AS (18110115 21:46 7439.95.4
Molybdenum
046 1
.m9
08108/t5 2t:45 08110115 21:46 7439.96•S
Nickel
9 0.46 1
14.7 mg✓hg
178106/15 21-45 08110115 21:45 7439-98-7
Potassium
0.46 1
2150 mg*q
0a106/15 21.45 08/10/15 21:45 7440.02.0
Selenium
457 1
6.8 mgikg
(WOOIIS 21:45 08/10/15 21:46 7440.09.7
Silver
091 1
NO mgikg
08106115 21.45 08/10115 21.46 7782-49.2
Sodium
046 1
mg*,
(006115 21.45 08/10115 21.46 7440.22-4
Zinc
3ND
457 1
mgJkg
08105115 21:45 08/10115 21:46 7440.23.5
7471 Mercury
0,91 1
08106115 21:45 08110115 21:46 7440.66.6
Analytical Method: EPA7471 Preparation Method; EPA7471
Mercury
264OG Total Paicont Solids
0.19 mglkg 0,025 5
08/1/115 17:10 0811211S 16.27 7439-97.6
Analytical Method; SM 254OG
Total Solids
78.2 % 0.000010 1
08107/1515:31
Parcont Molslum
Analytical Method, ASTM D2974-87
Percent Moisture
21.8 %
365.1 Phosphorus, Total
0;10 1
Analytical Method- EPA 365,1
08/10/15 07:37
Phosphorus
371 9 11.6 2
08/10/15 17:44 7723-14.0
REPORT OF LABORATORY ANALYSIS
Dale: 08/13/2015 03.42 PM
Thb report shelf flat be rsprsducad, except in ru0.
without the writtemconsent of Pace Analytical Somces, Inc
Page 4 of 13

laceAna4dlcaf®
rnrwpsedabsmm
ANALYTICAL RESULTS
Paco Analytical Services, Inc.
205 East Meadow Road - Sulle A
Eden. NC 27280
1336j623-e921
Project: AV!-PondedAsh for Reuse 911
Pace Project No.: 92266055
Sample: Ash from Ash Pond
Results reported on a dry weight
Lab ID: 9226605S00i
-halls
Collected- 0910111514,30
Received: 09/02/15 14:00 Matrix, Solid
and are adjusfed forpencent moisture, sample
size and any dilutions.
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed CAS No, Qual
6010 MET 1CP
Analytical Method EPA 6010 Preparation Method,, EPA 3050
Arsenic
Barium
90.2
286
m91k9
0.76
1
09MIl521:47 09/0911500:37 7440.38.2
Cadmium
1.1
mglkg
0.38
1
09104/15 21:47 09/09/15 00:37 7440.39.3
Calcium
2590
m9'k9
0.076
1
09/04/15 21:47 09109/15 00:37 7440.43.9
Chrornium
21.0
m91k9
7.6
1
09104/15 21:47 09/09/16 00:37 7440-7D-2
Copper
-9ft
0.38
1
09/04/15 21:47 09/09/15 00:37 7440-47-3
Lend
111
mg/kg
0,38
1
09104115 21:47 09/09115 00;37 7440-50.8
Magnesium
.
989
m91k9
0.38
1
09/04/15 21.47 09/09/15 00:37 7439-92-1
Manganese
101
mglkg
7,6
1
09/04/1521A7 0910911500:37 7439-95-4
Molybdenum
2.2
mglkg
0.38
1
09104115 21,47 09109/15 OD:37 7439-96-5
Nickel
15.8
mgft
0.36
1
0910411521:47 0910911500:37 7439-98-7
Potassium
1730
mg/kg
0,38
1
09104115 2IA7 09/09/15 00:37 7440.02.0
Selenium
10.1
mgikg
381
1
09/04/15 21:47 09109115 00:37 7440.09-7
Silver
OAS
mglkg
0.76
1
09/04115 21:47 09109/15 00:37 7782.49-2
sodium
ND
mglkg
0.38
1
09/04/15 21:47 09109/15 00:37 7440.22.4
Zinc
mg1kg
381
1
09/04/15 21:47 09/09/15 00:37 7440-23.5
7471 IN32.1
mglkg
0,76
1
09/04/15 21:47 09/10115 01:37 7440.66.6
ercury
AnalylicalMethod. EPA7471 Preparation,Method; EPA7471
Mercury
2540G Total Percent Solids
0.20 mg/kg 0.024 5 09/11/15 09,25
09/1111518:23 7439.97-6
Analytical Method; SM 2540G
Total Solids
80.1 eA 01000010 1
0910311513 22
Percent Molsture
Analytical Melhad; ASTM D2974-87
Percent Moisture
19.9 %
365.1 Phosphorus, Total
6�10 1
Analytical Method, EPA 365,1
09/0311517,32
Phosphorus
351 m91kg 12.5 5
09/0911516:54 7723-14.0
REPORT OF LABORATORY ANALYSIS
Date; 09/14/2015 01:26 PM
ThIs report shag not be aProdueed, except in full,
without Ole written consent of PaceAna"cal Services, Inca
Page 4.of 13

�WieAnalj&ale
mtwpacelobxcaet
ANALYTICAL RESULTS
Paco Analytical Services, Inc.
205 Fast Meadow Road - Suite A
Eden. NC 27288
[phone]
Project: AVL-Ponded Ash for Rouse 1016
Pace Project No.: 92270599
Sample: Ash from Ash Pond
Results reported on a "dry weight'
Lab ID: 92270599001 Collected:
basis
10/06/1510:01
Received: 10/06/15 13:40 Matrix: Solid
and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit
DF
Prepared Analyzed CAS No. Dual
6010 MET ICP
Analytical Method: EPA 6010 Preparation Method: EPA 3050
Arsenic
Barium
88.5 mglkg
5.6
5
10/07/15 13:15 10/09/15 05:17 7440.38.2 ,
Cadmium
438 mglkg
2.8
5
10/07/15 13:15 10/09/15 05:17 7440-39.3
Calcium
0.87 mg/kg
0.56
5
10/07/15 13:15 10/09/15 05:17 7440-43-9
Chromium
3530 mglkg
56.4
5
10/07/15 13:15 10/09/15 05:17 7440-70.2
Copper
34.9 mg/kg
2.8
5
10/07/15 13:15 10/09/15 05:17 7440-47-3
Lead
58.1 mg/kg
2.8
5
10/07/15 13:15 10/09/15 05:17 7440.50.8
Magnesium
25.3 mglkg
2.8
5
10/07/15 13:15 ,10109/15 05:17 7439-92-1
Manganese
1500 mglkg
56.4
5
10/07/15 13:15 10/09/15 05:17 7439.95-4
Molybdenum
70.3 mg/kg
2.8
5
10/07/15 13:15 10/09/15 05:17 7439-96-5
Nickel
.mg/kg
2.8
5
10107/15 13:15 10/09/15 05.17 7439.98.7
m l
28.4 mg/kg
2.8
5
10107/1513:15 10/09/15 05:17 7440.02-0
Seleeniuniu
Selenium
3020 mg/kg
2820
5
10/07115 13:15 10/09/15 05:17 7440.09-7
Silver
10.7 mg/kg
5.6
5
10107/1513:16 10/09/15 05:17 7782.49.2
Sodium
ND mglkg
2.86
10107/15 13:15 1 D/09/15 05:17 7440-22-4 D3
Zinc
ND mg/kg
2820
5
10107/15 13:15 10/09/15 05:17 7440.23-5 D3
49.5 mg/kg
5.6
5
10/07/15 13:15 10/09/15 05:17 7440.66-6
7471 Mercury
Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury
0.13 mglkg
0.0054
1
10/0911515:35 10/12/1516:37 7439.97-6
254OG Total Percent Solids
Analytical Method: SM 2540G
Total Solids
73.9 % 0.000010
1
10/07/15 18:45
Percent Moisture
Analytical Method: ASTM D2974-87
Percent Moisture
26.1 %
0.10
1
10/08/15 12:57
9045 pH Soil
Analytical Method: EPA 9046
pH at 25 Degrees C
7.4 Sid. Units
0.10
1
10/19/15 15:15
ASTM D4239.05 Sulfur
Analytical Method: ASTM 04239.05
Sulfur
0.0502 % (w/w)
0.020
i
10/15/1513:45 N2
365.1 Phosphorus, Total
Analytical Method: EPA 365.1
Phosphorus
333 mg/kg
14A
5
10/09/15 13:03 7723-14-0
90561C Anions
Analytical Method: EPA 9056
Sulfate
ND mglkg
330
5
10/18/1511:23 14808-79-8 D3
Date: 10/2012015 1027 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
witt.out the written consent of Pace Analytical Services, Inc..
Page 4 of 16

acemalyil'al
�P�aur+r
ANALYTICAL RESULTS
PacQAnnlytical Services, Inc.
205 Fast Meadow Road K Suite A
Eden, NC 2729B
1338)B23-0921
Protect: AVL-Ponded Ash for Reuse 1114
Pace PmJect Ne.: 92275015
Sample: -Ash from Ash Pond
Results reported on "dry
Lab ID: 92275015001
Collected„ 11/04/151020
Received: 11/05115 %00 Matrix, Solid
a welght"
basis and are adjustedlorparcent molsture, sample size and any dilutions.
Parameters
Results
Units
Report Limit
DF
Prepared
Analyzed CAS No Qual
6010 MET ICP
Analytical Method;
EPA 601a
preparation Method; EPA3D50
Arsenic
Badum
121
mglkg
3.-8
5
11/09/15 21.15
1111011518:27 7440-38-2
Cadmium
391
0.97
mglkg
1.9
5
11/09115 21.15
1111011518`7 7440-39-3
Calcium
z2sa
mglk9
mog
0.38
5
11/0911521.15
11/10115 iB27 744D43-9
Chromium
mglkg
37,9
5
1110911521,15
1111011515,27 744D-70-2
Copper
.4
45
45.2
m9►hg
1.9
5
1110911521:15
111101151827 744D-47-3
Lead
21.0
mgfk9
1,9
5
1110911521;15
111101151827 7440-50.8
Magnesium.
1330
1,9
5
1110911521:15
11/1011515 27 7439-92,1
Manganese
93.3
mg/hg
37.9
5
11/09/15 21„15
11/10/151 B 27 7439.95.4
Molybdenum
2.7
mglkg
1,9
5
11109/152115
111101151827 7439-96-5
Nickel
23-5
mg/kg
1,9
5
/1/09115 2115
1111011518 27 7439-98-7
Potassium
2900
mglkg
11
5
11/09115 2115
111101151827 7440.02.0
Selenium
8.5
mglkg
1900
5
11/09115 21-15
11/10115 la 27 7440.09-7
Silver
ND
mglkg
38
5
11/09/15 2115
11/1011518 27 7782-49-2
Sodium
ND
m9fg
1,9
5
11/09115 21:15
11/1011518 27 7440-224
Zinc
44.3
mglkg
1900
5
11/09/15 21 J 5
111101151827 7440.23.5
111914
38
5
11109115 2.115
1111011510.27 7440.66-6
7471 Mercury
Analytical Method; EPA 7471 Preparation Method:
EPA 7471
Mercury
0.19
mglkg
0,0034
1
111i2►t51715
1111311511;51 7439.97.6
2640G Total Percent Solids Analytical Method-. SM 254OG
Total Solids 77.6 % 0=010 1
11/06/15 13;22
Percent Moisture Analytical Method: ASTM D2974-87
Percent Moisture 22.4 %
0,10 i 11106/1517:38
365.1 Phosphorus, Total Analytical Method: EPA365,1
Phosphorus
144 m9ik9 7,9 5 11110/16 05;19 7723-14.0
REPORT OF LABORATORY ANALYSIS
Date. 11113/2015 04°22 PM fi-s reportshall not be reproduced. except in lud,
without the written consent of Pace Anaytical Services, Inc,, Page 4 of 13

�/��,
E/"'!Jialjd a1
Pace AnalyBoal services, Inc.
2e5 East Meadow Road - SuileA
Kw+►.pe Mice n
Eden, NC 27288
f
[phone]
ANALYTICAL.
RESULTS
Project: AVL-Ash from Ash Pond 1213
Pace P1ajec1 No.: , 92278390
--------------------
Sampb: Ash from Ash.Pond
Results reported on a "dry weight-
Lab ID: 92278390001 Colkded;
basis
12/D3/15 11;05
Received: 1210411507;00 Matrix. .Solid
and are adjusted lorpereent moisture, sample size and any dilutions.
Parameters
Results
Units Report Limit
OF
Prepared
Analyzed CAS No, Qual
6010 MET ICP
Analytical Method EPA 6010 Preparation Method, EPA 3050
Arsenic
sadum
78,11
mglkg
1.3
1
12104/16 22:34
12M7/1514:22 7440-38-2
Cadmium
401
m91kg
0.63
1
12104/15 22:34
12/0711514.22 7440-39-3
Calcium
0.33
2070
mg/kg
0.13
1
12104/15 22:34
1210711514,22 7440-43-9
Chromium
mg/k9
12,fi
1
12JO4115 22:34
1210711514:22 7440-70-2
Copper
28.4
m9Jkg
0.63
1
17JO4115 22:34
1210711514:22 744047-3
Lead
48.0
mgJk9
0.03
1
12/04/15 22:34
12l0711514,22 744D-50.8
Magnesium
17.5
1350
mglkg
0.63
1
12/04/15 22;34
1210711514,22 7439-92-1
Manganese
165
mglkg
12 6
1
12/04/15 22:34
1210711514.22 7439.95�4
Molybdenum
mglkg
0,63
1
12JO4115 22:34
1210711514,22 7439.96-5
Nickel
5.0
mg1k9
0.63
1
12104115 22:34
12JO711514:22 7439-911-7
Potassium
18.9
mglkg
0,63
1
12/04/16 22:34
12/0711514,22 7440.02.0
Selenium
2830
mg1k9
630
1
12/04/15 22:34
1210711514.22 7440.OD-7
Silver
10.4
mglkg
1.3
1
12/04/15 22:34
1210711514..22 7782-49-2
,
Sodium
NO
NO
mglkg
0,63
1
12/04115 22:34
1210711514,,22 7440.22-4
Zinc
mglkg
630
1
12/04115 22:34
1210711514,22 7440.23-5
43.0
mglkg
1.3
1
12/04/15 22:34
1210711514:22 7440.66.E
7471 Mercury
Analytical Method . EPA 7471 Preparation Method- EPA 7471
Mercury
0.19
mg1kg
0,029
5
12ID711516.05
12110/1516.09 7439<97.6
254OG Total Percent Solids
Analytical Method; SM 254OG
Total Solids
74.8
Yo 0,000010
1
1210711547,56
Percent Moisture
Analytical Method, ASTM D2974.87
Percent Molsture
25 2
%
010
]
12107/15 ] 6;09
366.1 Phosphorus, Total
Analytical Method; EPA355,1
Phosphorus
262
mg1k9
5.9
2
12110115 10:34 772344-0
Dale:.12/11/2015 1 OA4 AM
REPORT OF LABORATORY ANALYSIS
This report shad not be reproduced, except in fu ;
without the written consent of Pace Ana. dca! Services, Inc,
Page 4 of 13

CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM
WQ PERMIT #:
PHONE:
Supplemental Information
FACILITY NAME: Duke Energy Progress, LLC Roxboro and Sutton Plants
COUNTY: Person and New Hanover OPERATOR: Duke Energy Progress LLC
FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only)
❑ Distribution and Marketing (complete Parts A, and B)
N/A
Part A*:
Part B*:
Month
Sources(s) (include NPDES # if
applicable)
Volume (dry tons)
Recipient Information
Amendment/
Bulking Agent
Residual In
Product Out
Name(s)
Volume (dry
tons)
Intended use(s)
September
Roxboro Plant bottom ash
3755.7
Sutton Plant ash
0
October
Roxboro Plant bottom ash
2299.5
Sutton Plant ash
77.82
November
Roxboro Plant bottom ash
1569.4
Sutton Plant ash
1356.11
December
Roxboro Plant bottom ash
883.8
Sutton Plant ash
3996.49
Totals:
Annual (dry tons):
0
0
13938.82 0
..........................................
Amendment(s) used:
I
Bulking Agent(s) used:
(supp)): Total Number of Form DMSDF (Supp)
* If more space is required, attach additional information sheets (FORM DMSDF
DENR FORM DMSDF (Supp) (12/2006)